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Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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1

Coal Gasification  

Energy.gov (U.S. Department of Energy (DOE))

DOE's Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically via the process of coal gasification with sequestration. DOE anticipates that coal...

2

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation`s carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. [Energy Research Corp., Danbury, CT (United States); Meyers, S.J. [Fluor Daniel, Inc., Irvine, CA (United States); Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center

1992-12-01T23:59:59.000Z

3

Integration of carbonate fuel cells with advanced coal gasification systems  

SciTech Connect

Carbonate fuel cells have attributes which make them ideally suited to operate on coal-derived fuel gas; they can convert the methane, hydrogen, and carbon monoxide present in coal derived fuel gas directly to electricity, are not subject to thermodynamic cycle limits as are heat engines, and operate at temperatures compatible with coal gasifiers. Some new opportunities for improved efficiency have been identified in integrated coal gasification/carbonate fuel cells which take advantage of low temperature catalytic coal gasification producing a methane-rich fuel gas, and the internal methane reforming capabilities of Energy Research Corporation's carbonate fuel cells. By selecting the appropriate operating conditions and catalyst in the gasifier, methane formation is maximized to improve gasification efficiency and to take advantage of the heat management aspects of the internal reforming carbonate fuel cell. These advanced integrated gasification/carbonate fuel cell systems are projected to have better efficiencies than gasification/carbonate fuel cell systems employing conventional gasification, and also competing non-fuel cell systems. These improved efficiencies would be accompanied by a corresponding reduction in impact on the environment as well.

Steinfeld, G. (Energy Research Corp., Danbury, CT (United States)); Meyers, S.J. (Fluor Daniel, Inc., Irvine, CA (United States)); Hauserman, W.B. (North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center)

1992-01-01T23:59:59.000Z

4

NETL: Coal Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal Gasification Systems News Gasifipedia Gasifier Optimization Feed Systems Syngas Processing Systems Analyses Gasification Plant Databases International Activity Program Plan...

5

NETL: Gasification - Advanced Hydrogen Transport Membranes for Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Advanced Hydrogen Transport Membranes for Coal Gasification Praxair Inc. Project Number: FE0004908 Project Description Praxair is conducting research to develop hydrogen transport membrane (HTM) technology to separate carbon dioxide (CO2) and hydrogen (H2) in coal-derived syngas for IGCC applications. The project team has fabricated palladium based membranes and measured hydrogen fluxes as a function of pressure, temperature, and membrane preparation conditions. Membranes are a commercially-available technology in the chemical industry for CO2 removal and H2 purification. There is, however, no commercial application of membrane processes that aims at CO2 capture for IGCC syngas. Due to the modular nature of the membrane process, the design does not exhibit economy of scale-the cost of the system will increase linearly as the plant system scale increases making the use of commercially available membranes, for an IGCC power plant, cost prohibitive. For a membrane process to be a viable CO2 capture technology for IGCC applications, a better overall performance is required, including higher permeability, higher selectivity, and lower membrane cost.

6

E-Print Network 3.0 - advanced coal-gasification technical Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification to Produce SNG (Beulah, North Dakota, USA) (Source:DakotaGasification Petcoke... Source: NETL, 2009 12;12 Dakota Coal Gasification ... Source: Center for...

7

Development of an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

an Integrated an Integrated Multicontaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems Background The U.S. has more coal than any other country, and it can be converted through gasification into electricity, liquid fuels, chemicals, or hydrogen. However, for coal gasification to become sufficiently competitive to benefit the U.S. economy and help reduce our dependence on foreign fuels, gasification costs must be reduced

8

Technical analysis of advanced wastewater-treatment systems for coal-gasification plants  

SciTech Connect

This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

Not Available

1981-03-31T23:59:59.000Z

9

Entrainment Coal Gasification Modeling  

Science Journals Connector (OSTI)

Entrainment Coal Gasification Modeling ... Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier ... Equivalent Reactor Network Model for Simulating the Air Gasification of Polyethylene in a Conical Spouted Bed Gasifier ...

C. Y. Wen; T. Z. Chaung

1979-10-01T23:59:59.000Z

10

Coal gasification development intensifies  

Science Journals Connector (OSTI)

Coal gasification development intensifies ... Three almost simultaneous developments in coal gasification, although widely divergent in purpose and geography, rapidly are accelerating the technology's movement into an era of commercial exploitation. ... A plant to be built in the California desert will be the first commercialsize coal gasification power plant in the U.S. In West Germany, synthesis gas from a coal gasification demonstration plant is now being used as a chemical feedstock, preliminary to scaleup of the process to commercial size. ...

1980-02-25T23:59:59.000Z

11

NETL: Coal/Biomass Feed and Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed & Gasification Coal/Biomass Feed & Gasification Coal and Coal/Biomass to Liquids Coal/Biomass Feed and Gasification The Coal/Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal and/or coal-biomass mixtures. Activities support research for handling and processing of coal/biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on downstream components, catalyst and reactor optimization, and characterizing the range of products and product quality. Active projects within the program portfolio include the following: Coal-biomass fuel preparation Development of Biomass-Infused Coal Briquettes for Co-Gasification Coal-biomass gasification modeling

12

Catalytic steam gasification of coals  

Science Journals Connector (OSTI)

Catalytic steam gasification of coals ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ...

P. Pereira; G. A. Somorjai; H. Heinemann

1992-07-01T23:59:59.000Z

13

Carbon formation and metal dusting in advanced coal gasification processes  

SciTech Connect

The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

1997-02-01T23:59:59.000Z

14

Advanced CO2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

CO CO 2 Capture Technology for Low Rank Coal Integrated Gasification Combined Cycle (IGCC) Systems Background Gasification of coal or other solid feedstocks (wood waste, petroleum coke, etc.) is a clean way to produce electricity and produce or co-produce a variety of commercial products. The major challenge is cost reduction; current integrated gasification combined cycle (IGCC) technology is estimated to produce power at a cost higher than that of pulverized coal combustion. However, the Gasification

15

Coal Gasification Systems Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

Low Cost Coal Conversion to High Hydrogen Syngas; FE0023577 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation; FE0023497 OTM-Enhanced...

16

Coal gasification: Belgian first  

Science Journals Connector (OSTI)

... hope for Europe's coal production came with the announcement this month that the first gasification of coal at depths of nearly 1,000 metres would take place this May in ... of energy.

Jasper Becker

1982-03-04T23:59:59.000Z

17

Coal Gasification in Australia  

Science Journals Connector (OSTI)

... P. S. Andrews gave a full account of the Federal project for the pressure gasification of non-coking coals for the combined purpose of town's gas ' and the ... of town's gas ' and the production of synthetic liquid fuel. Work on the gasification of brown coal in. Victoria was commenced in 1931 by the technical staff of ...

1955-06-11T23:59:59.000Z

18

Incentives boost coal gasification  

SciTech Connect

Higher energy prices are making technologies to gasify the USA's vast coal reserves attractive again. The article traces the development of coal gasification technology in the USA. IGCC and industrial gasification projects are now both eligible for a 20% investment tax credit and federal loan guarantees can cover up to 80% of construction costs. 4 photos.

Hess, G.

2006-01-16T23:59:59.000Z

19

A Stoichiometric Analysis of Coal Gasification  

Science Journals Connector (OSTI)

A Stoichiometric Analysis of Coal Gasification ... Gasification of New Zealand Coals: A Comparative Simulation Study ... Gasification of New Zealand Coals: A Comparative Simulation Study ...

James Wei

1979-07-01T23:59:59.000Z

20

Status of Coal Gasification: 1977  

Science Journals Connector (OSTI)

High-pressure technology is important to coal gasification for several reasons. When the end product ... of high pressures in all types of coal gasification reduces the pressure drop throughout the equipment,...

F. C. Schora; W. G. Bair

1979-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes  

E-Print Network (OSTI)

Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

Gong, Bo, Ph. D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

22

Coal Gasification Report.indb  

NLE Websites -- All DOE Office Websites (Extended Search)

Integrated Coal Integrated Coal Gasification Combined Cycle: Market Penetration Recommendations and Strategies Produced for the Department of Energy (DOE)/ National Energy Technology Laboratory (NETL) and the Gasification Technologies Council (GTC) September 2004 Coal-Based Integrated Gasification Combined Cycle: Market Penetration Strategies and Recommendations Final Report Study Performed by:

23

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

24

Modelling coal gasification  

Science Journals Connector (OSTI)

Coal gasification processes in a slurry-feed-type entrained-flow gasifier are studied. Novel simulation methods as well as numerical results are presented. We use the vorticity-stream function method to study the characteristics of gas flow and a scalar potential function is introduced to model the mass source terms. The random trajectory model is employed to describe the behaviour of slurry-coal droplets. Very detailed results regarding the impact of the O2/coal ratio on the distribution of velocity, temperature and concentration are obtained. Simulation results show that the methods are feasible and can be used to study a two-phase reacting flow efficiently.

Xiang Jun Liu; Wu Rong Zhang; Tae Jun Park

2001-01-01T23:59:59.000Z

25

Advanced Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

caused by impurities during removal from syngas. Refractory Improvement Coal and petcoke, common carbon feedstock in slagging gasifiers, are typically high in mineral...

26

Gasification of Coal and Oil  

Science Journals Connector (OSTI)

... , said the Gas Council is spending £120,000 this year on research into coal gasification, and the National Coal Board and the Central Electricity Generating Board £680,000 and ... coal utilization. The Gas Council is spending about £230,000 on research into the gasification of oil under a programme intended to contribute also to the improvement of the economics ...

1960-02-13T23:59:59.000Z

27

Underground Gasification of Coal Reported  

Science Journals Connector (OSTI)

Underground Gasification of Coal Reported ... RESULTS of a first step taken toward determining the feasibility of the underground gasification of coal were reported recently to the Interstate Oil Compact Commission by Milton H. Fies, manager of coal operations for the Alabama Power Co. ...

1947-05-12T23:59:59.000Z

28

PNNL Coal Gasification Research  

SciTech Connect

This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

2010-07-28T23:59:59.000Z

29

The Complete Gasification of Coal  

Science Journals Connector (OSTI)

... plant designed by C. B. Tully, and operated at Bedford, for the complete gasification of coal. Altogether, since 1919, about two hundred such plants have been erected ...

J. S. G. THOMAS

1923-06-09T23:59:59.000Z

30

Transport and Other Effects in Coal Gasification  

Science Journals Connector (OSTI)

The paper summarizes the kinetics of coal char gasification excepted surface reactions (mechanisms). The following subjects controlling coal char gasification are treated: Coal as the raw material ... of particle...

K. J. Hüttinger

1988-01-01T23:59:59.000Z

31

Coal gasification vessel  

DOE Patents (OSTI)

A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

Loo, Billy W. (Oakland, CA)

1982-01-01T23:59:59.000Z

32

Beluga Coal Gasification - ISER  

SciTech Connect

ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

Steve Colt

2008-12-31T23:59:59.000Z

33

Underground Coal Gasification in the USSR  

Science Journals Connector (OSTI)

By accomplishing in a single operation the extraction of coal and its conversion into a gaseous fuel, underground gasification makes it possible to avoid the heavy capital investments required for coal gasification

1983-01-01T23:59:59.000Z

34

Integrated Coal Gasification Power Plant Credit (Kansas)  

Energy.gov (U.S. Department of Energy (DOE))

Integrated Coal Gasification Power Plant Credit states that an income taxpayer that makes a qualified investment in a new integrated coal gasification power plant or in the expansion of an existing...

35

Coal Gasification for Power Generation, 3. edition  

SciTech Connect

The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

NONE

2007-11-15T23:59:59.000Z

36

The suitability of coal gasification in India's energy sector  

E-Print Network (OSTI)

Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

Simpson, Lori Allison

2006-01-01T23:59:59.000Z

37

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...appreciably larger sizes than coal to other...they grew to a size to fall upon an...air-blown Winkler gasifier pro-ducing power...additional gasification medium (air or oxygen-steam...provide "pure" gasifier Test revamp Develop larger sizes Develop pressure...

Arthur M. Squires

1974-04-19T23:59:59.000Z

38

Coal gasification apparatus  

DOE Patents (OSTI)

Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

Nagy, Charles K. (Monaca, PA)

1982-01-01T23:59:59.000Z

39

Coal gasification 2006: roadmap to commercialization  

SciTech Connect

Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

NONE

2006-05-15T23:59:59.000Z

40

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

IGCC PC advanced coal-wind hybrid combined cycle power plantnatural gas combined cycle gas turbine power plant carboncrude gasification combined cycle power plant with carbon

Phadke, Amol

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Improved catalysts for carbon and coal gasification  

DOE Patents (OSTI)

This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

McKee, D.W.; Spiro, C.L.; Kosky, P.G.

1984-05-25T23:59:59.000Z

42

Kinetics of steam gasification of bituminous coals in terms of their use for underground coal gasification  

Science Journals Connector (OSTI)

Abstract The kinetics of steam gasification was examined for bituminous coals of a low coal rank. The examined coals can be the raw material for underground coal gasification. Measurements were carried out under isothermal conditions at a high pressure of 4 MPa and temperatures of 800, 900, 950, and 1000 °C. Yields of gasification products such as carbon monoxide and carbon dioxide, hydrogen and methane were calculated based on the kinetic curves of formation reactions of these products. Also carbon conversion degrees are presented. Moreover, calculations were made of the kinetic parameters of carbon monoxide and hydrogen formation reaction in the coal gasification process. The parameters obtained during the examinations enable a preliminary assessment of coal for the process of underground coal gasification.

Stanis?aw Porada; Grzegorz Czerski; Tadeusz Dziok; Przemys?aw Grzywacz; Dorota Makowska

2015-01-01T23:59:59.000Z

43

Apparatus for fixed bed coal gasification  

DOE Patents (OSTI)

An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

44

Catalysts for carbon and coal gasification  

DOE Patents (OSTI)

Catalyst for the production of methane from carbon and/or coal by means of catalytic gasification. The catalyst compostion containing at least two alkali metal salts. A particulate carbonaceous substrate or carrier is used.

McKee, Douglas W. (Burnt Hills, NY); Spiro, Clifford L. (Scotia, NY); Kosky, Philip G. (Schenectady, NY)

1985-01-01T23:59:59.000Z

45

Underground Coal Gasification at Tennessee Colony  

E-Print Network (OSTI)

The Tennessee Colony In Situ Coal Gasification Project conducted by Basic Resources Inc. is the most recent step in Texas Utilities Company's ongoing research into the utilization of Texas lignite. The project, an application of the Soviet...

Garrard, C. W.

1979-01-01T23:59:59.000Z

46

The Role of Oxygen in Coal Gasification  

E-Print Network (OSTI)

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

47

Production of Hydrogen from Underground Coal Gasification  

DOE Patents (OSTI)

A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

Upadhye, Ravindra S. (Pleasanton, CA)

2008-10-07T23:59:59.000Z

48

Underground coal gasification using oxygen and steam  

SciTech Connect

In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

2009-07-01T23:59:59.000Z

49

Coal properties and system operating parameters for underground coal gasification  

SciTech Connect

Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

Yang, L. [China University of Mining & Technology, Xuzhou (China)

2008-07-01T23:59:59.000Z

50

The Public Perceptions of Underground Coal Gasification (UCG)  

E-Print Network (OSTI)

The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Simon Shackley #12;The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Dr Simon Shackley of Underground Coal Gasification (UCG) in the United Kingdom. The objectives were to identify the main dangers

Watson, Andrew

51

Fluidized bed catalytic coal gasification process  

DOE Patents (OSTI)

Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

1984-01-01T23:59:59.000Z

52

Process for fixed bed coal gasification  

DOE Patents (OSTI)

The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

Sadowski, Richard S. (Greenville, SC)

1992-01-01T23:59:59.000Z

53

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network (OSTI)

application (coal gasification, coal combustion followed byversions of advanced gasification processes show promise ofFixed-Bed Low-Btu Coal Gasification Systems for Retrofitting

Ferrell, G.C.

2010-01-01T23:59:59.000Z

54

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

Holten, R.R.

2010-01-01T23:59:59.000Z

55

Coal Gasification in a Transport Reactor  

Science Journals Connector (OSTI)

These simulations were used to compare the response of coals gasified to those combusted substoichiometrically, to evaluate the optimum operating conditions and to predict the performance in larger-scale units with less heat loss. ... Entrained-flow gasifiers use high temperatures (1350?1550 °C) and gasify coals in 2?3 s. ... Kinetic studies were carried out to elucidate the mechanisms of steam and CO2 gasification of char and the interactions of these gasifying agents. ...

Lawrence J. Shadle; Esmail R. Monazam; Michael L. Swanson

2001-05-25T23:59:59.000Z

56

Optimum Design of Coal Gasification Plants  

E-Print Network (OSTI)

This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

Pohani, B. P.; Ray, H. P.; Wen, H.

1982-01-01T23:59:59.000Z

57

Short Communication Catalytic coal gasification: use of calcium versus potassium*  

E-Print Network (OSTI)

Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

58

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...been operated as a "pure" gasifier but to supply power gas for...was the air-blown Winkler gasifier pro-ducing power gas at Leuna...fines, additional gasification medium (air or oxygen-steam) is...partial pressure of steam in a gasifier blown with oxygen and steam...

Arthur M. Squires

1974-04-19T23:59:59.000Z

59

Fluidized bed gasification of extracted coal  

DOE Patents (OSTI)

Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

1986-01-01T23:59:59.000Z

60

Syngas Production from Coal through Microwave Plasma Gasification: Influence of Oxygen, Steam, and Coal Particle Size  

Science Journals Connector (OSTI)

Syngas Production from Coal through Microwave Plasma Gasification: Influence of Oxygen, Steam, and Coal Particle Size ... Plasma gasification is widely applied because of its clean syngas production performance and high chemical reactivity accelerated by the free radicals produced by plasma. ... The syngas composition produced from plasma gasification at same conditions is affected by the physicochemical properties of coals. ...

Sang Jun Yoon; Jae Goo Lee

2011-11-23T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Fluidized bed injection assembly for coal gasification  

DOE Patents (OSTI)

A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

1981-01-01T23:59:59.000Z

62

Key tests set for underground coal gasification  

SciTech Connect

Underground coal gasification (UCG) is about to undergo some tests. The tests will be conducted by Lawrence Livermore National Laboratory (LLNL) in a coal seam owned by Washington Irrigation and Development Co. A much-improved UCG system has been developed by Stephens and his associates at LLNL - the controlled retracting injection point (CRIP) method. Pritchard Corp., Kansas City, has done some conceptual process design and has further studied the feasibility of using the raw gas from a UCG burn as a feedstock for methanol synthesis and/or MTG gasoline. Each method was described. (DP)

Haggin, J.

1983-07-18T23:59:59.000Z

63

Underground coal gasification : overview of an economic and environmental evaluation.  

E-Print Network (OSTI)

??This paper examines an overview of the economic and environmental aspects of Underground Coal Gasification (UCG) as a viable option to the above ground Surface… (more)

Kitaka, Richard Herbertson

2012-01-01T23:59:59.000Z

64

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...A. G. Horsler, Gas Counc. (Gt. Brit...England, 1962; Gas J. 312, 19 (1962...be-come overdependent on natural gas and oil to supply...gasifier at elevated pressure with a downward flow...operability on coals of high ash-fusion temperature...

Arthur M. Squires

1974-04-19T23:59:59.000Z

65

Clean Fuels from Coal Gasification  

Science Journals Connector (OSTI)

...superheating and water-heating sections of the boiler...percent on a higher heating value basis. Conclusions...made historically by heating bitumi-nous coal in...heart of the anthracite district only about 5 years ago...energy, wind, and geothermal steam and brines, will...

Arthur M. Squires

1974-04-19T23:59:59.000Z

66

Site clean up of coal gasification residues  

SciTech Connect

The coal gasification plant residues tested in this research consists of various particle sizes of rock, gravel, tar-sand agglomerates, fine sand and soil. Most of the soils particles were tar free. One of the fractions examined contained over 3000 ppM polyaromatic hydrocarbons (PAHs). The residues were subjected to high pressure water jet washing, float and sink tests, and soil washing. Subsequent PAH analyses found less than 1 ppM PAHs in the water jet washing water. Soils washed with pure water lowered PAH concentrations to 276 ppM; the use of surfactants decreased PAHs to 47, 200, and 240 ppM for different test conditions. In the 47 ppM test, the surfactant temperature had been increased to 80 C, suggesting that surfactant washing efficiency can be greatly improved by increasing the solution temperature. The coal tar particles were not extracted by the surfactants used. Coke and tar-sand agglomerates collected from the float and sink gravimetric separation were tested for heating value. The tar exhibited a very high heating value, while the coke had a heating value close to that of bituminous coal. These processes are believed to have the potential to clean up coal gasification plant residues at a fairly low cost, pending pilot-scale testing and a feasibility study.

Wilson, J.W.; Ding, Y. [Univ. of Missouri, Rolla, MO (United States)

1995-12-31T23:59:59.000Z

67

Coal Gasification Report.indb  

NLE Websites -- All DOE Office Websites (Extended Search)

Booz Allen Hamilton Booz Allen Hamilton Final Report, September 3, 2004 list of acronyms List of Acronyms AEO Annual Energy Outlook ASU Air Separation Unit BACT Best Available Control Technology BTU British Thermal Unit CCPI Clean Coal Power Initiative CFB Circulating Fluidized Bed CO Carbon Monoxide CO 2 Carbon Dioxide COE Cost of Electricity Co-Op Co-Operative CRS Congressional Research Service DG Distributed Generation

68

How Coal Gasification Power Plants Work | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification » How Coal Gasification » How Coal Gasification Power Plants Work How Coal Gasification Power Plants Work How Coal Gasification Power Plants Work The heart of a gasification-based system is the gasifier. A gasifier converts hydrocarbon feedstock into gaseous components by applying heat under pressure in the presence of steam. A gasifier differs from a combustor in that the amount of air or oxygen available inside the gasifier is carefully controlled so that only a relatively small portion of the fuel burns completely. This "partial oxidation" process provides the heat. Rather than burning, most of the carbon-containing feedstock is chemically broken apart by the gasifier's heat and pressure, setting into motion chemical reactions that produce "syngas." Syngas is primarily hydrogen and carbon monoxide, but can include

69

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification  

Science Journals Connector (OSTI)

Effect of Microstructural Changes on Gasification Reactivity of Coal Chars during Low Temperature Gasification ... Pocahontas No. 3, Illinois No. 6, and Beulah-Zap coal char samples were gasified in 1% O2 at 500 °C or 600 °C up to 90% (daf) conversion, and their structure were observed under a high-resolution transmission electron microscope (HRTEM). ...

Atul Sharma; Hayato Kadooka; Takashi Kyotani; Akira Tomita

2001-11-28T23:59:59.000Z

70

Gasification of an Indonesian subbituminous coal in a pilot-scale coal gasification system  

Science Journals Connector (OSTI)

Indonesian Roto Middle subbituminous coal was gasified in a pilot-scale dry-feeding gasification system and the produced syngas was purified...2, and 5–8% CO2. Particulates in syngas were 99.8% removed by metal f...

Yongseung Yun; Seok Woo Chung

2007-07-01T23:59:59.000Z

71

Coal gasification for power generation. 2nd ed.  

SciTech Connect

The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

NONE

2006-10-15T23:59:59.000Z

72

Method for increasing steam decomposition in a coal gasification process  

DOE Patents (OSTI)

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, Marvin W. (Fairview, WV)

1988-01-01T23:59:59.000Z

73

Method for increasing steam decomposition in a coal gasification process  

DOE Patents (OSTI)

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, M.W.

1987-03-23T23:59:59.000Z

74

Wabash River Coal Gasification Repowering Project Final Technical Report  

Office of Scientific and Technical Information (OSTI)

Wabash River Coal Gasification Wabash River Coal Gasification Repowering Project Final Technical Report August 2000 Work Performed Under Cooperative Agreement DE-FC21-92MC29310 For: The U.S. Department of Energy Office of Fossil Energy National Energy Technology Laboratory Morgantown, West Virginia Prepared by: The Men and Women of Wabash River Energy Ltd. For Further Information Contact: Roy A. Dowd, CHMM Environmental Supervisor Wabash River Coal Gasification Repowering Project 444 West Sandford Avenue West Terre Haute, IN 47885 LEGAL NOTICE/DISCLAIMER This report was prepared by the Wabash River Coal Gasification Repowering Project Joint Venture pursuant to a Cooperative Agreement partially funded by the U.S. Department of Energy, and neither the Wabash River Coal Gasification Repowering

75

DIFFUSION COATINGS FOR CORROSION RESISTANT COMPONENTS IN COAL GASIFICATION SYSTEMS  

SciTech Connect

Advanced electric power generation systems use a coal gasifier to convert coal to a gas rich in fuels such as H{sub 2} and CO. The gas stream contains impurities such as H{sub 2}S and HCl, which attack metal components of the coal gas train, causing plant downtime and increasing the cost of power generation. Corrosion-resistant coatings would improve plant availability and decrease maintenance costs, thus allowing the environmentally superior integrated gasification combined cycle plants to be more competitive with standard power-generation technologies. A startup meeting was held at the National Energy Technology Center, Pittsburgh, PA site on July 28, 2003. SRI staff described the technical approach of the project.

Gopala N. Krishnan

2004-05-01T23:59:59.000Z

76

Coal Integrated Gasification Fuel Cell System Study  

SciTech Connect

This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

2004-01-31T23:59:59.000Z

77

Benefits of Integrating PWR and RTI Advanced Gasification Technologies for  

NLE Websites -- All DOE Office Websites (Extended Search)

Syngas Processing Systems Syngas Processing Systems Benefits of Integrating PWR and RTI Advanced Gasification Technologies for Hydrogen-Rich Syngas Production Research Triangle Institute (RTI) Project Number: FE0012066 Project Description The project will assess the potential for integrated advanced technologies to substantially reduce capital and production costs for hydrogen-rich syngas with near-zero emissions from coal gasification for power production with carbon capture and for coal-to-liquids (specifically methanol) with carbon capture. These integrated technologies include those already tested successfully at pilot-scale with a new and innovative water-gas-shift technology, to show how multiple advanced technologies will leverage each other for significant cost and efficiency gains.

78

A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage  

E-Print Network (OSTI)

from combustion and gasification of coal – an equilibriumHolysh, M. 2005. Coke Gasification: Advanced technology forfrom a Coal-Fired Gasification Plant. Final Report, December

Apps, J.A.

2006-01-01T23:59:59.000Z

79

Advanced Gasification By-Product Utilization  

SciTech Connect

With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

2006-08-31T23:59:59.000Z

80

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Study on the Nitric Compounds during Coal Gasification  

Science Journals Connector (OSTI)

This investigation involved the formation and evolution of NO? HCN and NH3 during coal gasification. Since HCN and NH3 are the precursors of NOX, their summation are considered to show the characteristics of the precursors in this paper. The experiments ... Keywords: gasification, NOX precursors, particle size, agent

Jun Xiang; Qingsen Zhao; Song Hu; Lushi Sun; Sheng Su; Kai Xu; Tengfei Lu; Gang Chen

2009-10-01T23:59:59.000Z

82

Selection of Coal Gasification Parameters for Injection of Gasification Products Into a Blast Furnace  

Science Journals Connector (OSTI)

An analytical study was performed on the influence of blast parameters on the course of the processes in the volume of a blast furnace and smelting rates by injection of low-grade coal gasification products. It w...

I. G. Tovarovsky; A. E. Merkulov

2014-01-01T23:59:59.000Z

83

Storing Syngas Lowers the Carbon Price for Profitable Coal Gasification  

Science Journals Connector (OSTI)

There are currently eight gasification facilities operating worldwide producing about 1.7 GW of electricity from coal or petcoke feedstock (10), and in all of these facilities, the syngas is used immediately after it is produced. ...

Adam Newcomer; Jay Apt

2007-10-17T23:59:59.000Z

84

Underground coal gasification: a brief review of current status  

SciTech Connect

Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating costs and also has other advantages, such as no human labor underground. In addition, UCG has the potential to be linked with carbon capture and sequestration. The increasing demand for energy, depletion of oil and gas resources, and threat of global climate change lead to growing interest in UCG throughout the world. In this article, we review the current status of this technology, focusing on recent developments in various countries.

Shafirovich, E.; Varma, A. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

2009-09-15T23:59:59.000Z

85

Solar coal gasification reactor with pyrolysis gas recycle  

DOE Patents (OSTI)

Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

1983-01-01T23:59:59.000Z

86

NETL: Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

use of our domestic energy resources and infrastructure. Gasification Systems | Advanced Combustion | Coal & Coal-Biomass to Liquids | Solid Oxide Fuel Cells | Turbines CO2...

87

Syngas Production from Coal Gasification with CO2 Rich Gas Mixtures  

Science Journals Connector (OSTI)

Coal gasification with CO2 rich gas mixture is one of several promising new technologies associated with CO2 reduction in the atmosphere. Coal gasification with high CO2 concentration is suitable for producing la...

M. S. Alam; A. T. Wijayanta; K. Nakaso…

2013-01-01T23:59:59.000Z

88

Hybrid Combustion-Gasification Chemical Looping Coal Power Technology Development  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Gasification Technologies contacts Gary J. stiegel Gasification Technology Manager National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236 412-386-4499 gary.stiegel@netl.doe.gov Ronald Breault Project Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507 304-285-4486 ronald.breault@netl.doe.gov Herbert E. andrus, Jr. Principal Investigator ALSTOM Power 2000 Day Hill Rd. Windsor, CT 06095 860-285-4770 herbert.e.andrus@power.alstom.com Hybrid Combustion-GasifiCation CHemiCal loopinG Coal power teCHnoloGy development Description Gasification technologies can provide a stable, affordable energy supply for the nation, while also providing high efficiencies and near zero pollutants. With coal

89

Analysis of Biomass/Coal Co-Gasification for Integrated Gasification Combined Cycle (IGCC) Systems with Carbon Capture.  

E-Print Network (OSTI)

?? In recent years, Integrated Gasification Combined Cycle Technology (IGCC) has become more common in clean coal power operations with carbon capture and sequestration (CCS).… (more)

Long, Henry A, III

2011-01-01T23:59:59.000Z

90

NETL: News Release - Tax Credit Program Promotes Advanced Coal Power  

NLE Websites -- All DOE Office Websites (Extended Search)

December 5, 2007 December 5, 2007 Tax Credit Program Promotes Advanced Coal Power Generation and Gasification Technologies DOE Will Assist Internal Revenue Service in Project Selection WASHINGTON, DC - The U.S. Department of Energy (DOE) is partnering with the Internal Revenue Service (IRS) to evaluate five projects that have recently applied for tax credits under the Energy Policy Act of 2005 (EPAct 2005). Accepted projects will help bring about rapid deployment of advanced coal-based power generation and gasification technologies and enable the clean and efficient use of coal, America's most abundant energy resource. In June 2007, the Treasury Department and DOE released revised guidance on the procedures for awarding the tax credits authorized under EPAct 2005 for qualifying advanced coal projects and qualifying gasification projects. Under the revised guidance, applications for DOE certification received before October 31, 2007, will be acted on in 2008.

91

NETL: Gasification Systems - Evaluation of the Benefits of Advanced Dry  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Evaluation of the Benefits of Advanced Dry Feed System for Low Rank Coal Project Number: DE-FE0007902 General Electric Company (GE) is evaluating and demonstrating the benefits of novel dry feed technologies to effectively, reliably, and economically provide feeding of low-cost, low-rank coals into commercial Integrated Gasification Combined Cycle (IGCC) systems. GE is completing comparative techno-economic studies of two IGCC power plant cases, one without and one with advanced dry feed technologies. A common basis of design is being developed so that overall assumptions and methodologies are common in the two cases for both technical and economic areas. The baseline case, without advanced dry feed technologies, will use operational data from the Eastman Chemical Company Kingsport gasification facility in combination with DOE/NETL's Cost and Performance Baseline Low-Rank Coal to Electricity IGCC study for both cost and performance comparisons. Advanced dry feed technologies, based upon the Posimetric® pump currently under development by GE, will be developed to match the proposed plant conditions and configuration, and will be analyzed to provide comparative performance and cost information to the baseline plant case. The scope of this analysis will cover the feed system from the raw coal silo up to, and including, the gasifier injector. Test data from previous and current testing will be summarized in a report to support the assumptions used to evaluate the advanced technologies and the potential value for future applications. This study focuses primarily on IGCC systems with 90 percent carbon capture, utilization, and storage (CCUS), but the dry feed system will be applicable to all IGCC power generating plants, as well as other industries requiring pressurized syngas.

92

Co-gasification Reactivity of Coal and Woody Biomass in High-Temperature Gasification  

Science Journals Connector (OSTI)

(20) Although the total pressure was 0.5 MPa and lower than the usual conditions of the gasifier, it has been confirmed that the total pressure has little influence on the gasification rate of char when the partial pressure of the gasifying agent is the same and the total pressure is less than 2 MPa. ... While the pyrolysis and the char gasification were tested separately in the above experiments, raw samples of coals, cedar bark, and the mixtures were gasified with carbon dioxide at high temperature using the PDTF facility in this section, the same as the reductor in the air-blown two-stage entrained flow coal gasifier. ...

Shiro Kajitani; Yan Zhang; Satoshi Umemoto; Masami Ashizawa; Saburo Hara

2009-09-24T23:59:59.000Z

93

Development of Computational Approaches for Simulation and Advanced Controls for Hybrid Combustion-Gasification Chemical Looping  

NLE Websites -- All DOE Office Websites (Extended Search)

Computational Approaches Computational Approaches for Simulation and Advanced Controls for Hybrid Combustion-Gasification Chemical Looping Background The United States Department of Energy (DOE) National Energy Technology Laboratory (NETL) develops affordable and clean energy from coal and other fossil fuels to secure a sustainable energy economy. To further this mission, NETL funds research and development of advanced control technologies, including chemical looping (CL)

94

Flow Simulation and Optimization of Plasma Reactors for Coal Gasification  

Science Journals Connector (OSTI)

This paper reports a 3-d numerical simulation system to analyze the complicated flow in plasma reactors for coal gasification, which involve complex chemical reaction, two-phase flow and plasma effect. On the basis of analytic results, the distribution of the density, temperature and components' concentration are obtained and a different plasma reactor configuration is proposed to optimize the flow parameters. The numerical simulation results show an improved conversion ratio of the coal gasification. Different kinds of chemical reaction models are used to simulate the complex flow inside the reactor. It can be concluded that the numerical simulation system can be very useful for the design and optimization of the plasma reactor.

Ji Chunjun; Zhang Yingzi; Ma Tengcai

2003-01-01T23:59:59.000Z

95

Coalbed methane production enhancement by underground coal gasification  

SciTech Connect

The sub-surface of the Netherlands is generally underlain by coal-bearing Carboniferous strata at greater depths (at many places over 1,500 m). These coal seams are generally thinner than 3 meter, occur in groups (5--15) within several hundred meters and are often fairly continuous over many square kilometers. In many cases they have endured complex burial history, influencing their methane saturation. In certain particular geological settings, a high, maximum coalbed methane saturation, may be expected. Carboniferous/Permian coals in the Tianjin-region (China) show many similarities concerning geological settings, rank and composition. Economical coalbed methane production at greater depths is often obstructed by the (very) low permeabilities of the coal seams as with increasing depth the deformation of the coal reduces both its macro-porosity (the cleat system) and microporosity. Experiments in abandoned underground mines, as well as after underground coal gasification tests indicate ways to improve the prospects for coalbed methane production in originally tight coal reservoirs. High permeability areas can be created by the application of underground coal gasification of one of the coal seams of a multi-seam cycle with some 200 meter of coal bearing strata. The gasification of one of the coal seams transforms that seam over a certain area into a highly permeable bed, consisting of coal residues, ash and (thermally altered) roof rubble. Additionally, roof collapse and subsidence will destabilize the overburden. In conjunction this will permit a better coalbed methane production from the remaining surrounding parts of the coal seams. Moreover, the effects of subsidence will influence the stress patterns around the gasified seam and this improves the permeability over certain distances in the coal seams above and below. In this paper the effects of the combined underground coal gasification and coalbed methane production technique are regarded for a single injection well. Known geotechnical aspects are combined with results from laboratory experiments on compaction of thermally treated rubble. An axi-symmetric numerical model is used to determine the effects induced by the gasified coal seam. The calculation includes the rubble formation, rubble compaction and induced stress effects in the overlying strata. Subsequently the stress effects are related to changes in coal permeability, based on experimental results of McKee et al.

Hettema, M.H.H.; Wolf, K.H.A.A.; Neumann, B.V.

1997-12-31T23:59:59.000Z

96

Gasification CFD Modeling for Advanced Power Plant Simulations  

SciTech Connect

In this paper we have described recent progress on developing CFD models for two commercial-scale gasifiers, including a two-stage, coal slurry-fed, oxygen-blown, pressurized, entrained-flow gasifier and a scaled-up design of the PSDF transport gasifier. Also highlighted was NETL’s Advanced Process Engineering Co-Simulator for coupling high-fidelity equipment models with process simulation for the design, analysis, and optimization of advanced power plants. Using APECS, we have coupled the entrained-flow gasifier CFD model into a coal-fired, gasification-based FutureGen power and hydrogen production plant. The results for the FutureGen co-simulation illustrate how the APECS technology can help engineers better understand and optimize gasifier fluid dynamics and related phenomena that impact overall power plant performance.

Zitney, S.E.; Guenther, C.P.

2005-09-01T23:59:59.000Z

97

Design of advanced fossil-fuel systems (DAFFS): a study of three developing technologies for coal-fired, base-load electric power generation. Integrated coal gasification/combined cycle power plant with Texaco gasification process  

SciTech Connect

The objectives of this report are to present the facility description, plant layouts and additional information which define the conceptual engineering design, and performance and cost estimates for the Texaco Integrated Gasification Combined Cycle (IGCC) power plant. Following the introductory comments, the results of the Texaco IGCC power plant study are summarized in Section 2. In Section 3, a description of plant systems and facilities is provided. Section 4 includes pertinent performance information and assessments of availability, natural resource requirements and environmental impact. Estimates of capital costs, operation and maintenance costs and cost of electricity are presented in Section 5. A Bechtel Group, Inc. assessment and comments on the designs provided by Burns and Roe-Humphreys and Glasgow Synthetic Fuel, Inc. are included in Section 6. The design and cost estimate reports which were prepared by BRHG for those items within their scope of responsibility are included as Appendices A and B, respectively. Appendix C is an equipment list for items within the BGI scope. The design and cost estimate classifications chart referenced in Section 5 is included as Appendix D. 8 references, 17 figures, 15 tables.

Not Available

1983-06-01T23:59:59.000Z

98

Design of advanced fossil-fuel systems (DAFFS): a study of three developing technologies for coal-fired, base-load electric power generation. Integrated coal-gasification/combined power plant with BGC/Lurgi gasification process  

SciTech Connect

The objectives of this report are to present the facility description, plant layouts and additional information which define the conceptual engineering design, and performance and cost estimates for the BGC/Lurgi Integrated Gasification Combined Cycle (IGCC) power plant. Following the introductory comments, the results of the British Gas Corporation (BGC)/Lurgi IGCC power plant study are summarized in Section 2. In Secion 3, a description of plant systems and facilities is provided. Section 4 includes pertinent performance information and assessments of availability, natural resource requirements and environmental impact. Estimates of capital costs, operating and maintenance costs and cost of electricity are presented in Section 5. A Bechtel Group Inc. (BGI) assessment and comments on the designs provided by Burns and Roe-Humphreys and Glasgow Synthetic Fuels, Inc. (BRHG) are included in Section 6. The design and cost estimate reports which were prepared by BRHG for those items within their scope of responsibility are included as Appendices A and B, respectively. Apendix C is an equipment list for items within the BGI scope. The design and cost estimate classifications chart referenced in Section 5 is included as Appendix D. 8 references, 18 figures, 5 tables.

Not Available

1983-06-01T23:59:59.000Z

99

Preliminary Experimental Studies of Waste Coal Gasification  

Science Journals Connector (OSTI)

Coal mining is one of Australia’s most important industries. It was estimated that coal washery rejects ... . To ensure sustainability of the Australian coal industry, we have explored a new potential pathway to ...

S. Su; Y. G. Jin; X. X. Yu; R. Worrall

2013-01-01T23:59:59.000Z

100

Gasification of New Zealand Coals: A Comparative Simulation Study  

Science Journals Connector (OSTI)

The aim of this study was to conduct a preliminary feasibility assessment of gasification of New Zealand (NZ) lignite and sub-bituminous coals, using a commercial simulation tool. ... Coal is a nonrenewable resource; however, the world’s coal reserves amount to twice the combined oil and gas reserves. ... The reasons for the entrained flow gasifier selection include its high suitability to low rank coals (lignites) and the use of entrained flow gasifiers for an IGCC as the industrially preferred choice dictated through experience. ...

Smitha V. Nathen; Robert D. Kirkpatrick; Brent R. Young

2008-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Preparation and gasification of a Thailand coal-water fuel  

SciTech Connect

In response to an inquiry by the Department of Mineral Resources (DMR) in Thailand, the Energy and Environmental Research Center (EERC) prepared a four-task program to assess the responsiveness of Wiang Haeng coal to the temperature and pressure conditions of hot-water drying (HWD). The results indicate that HWD made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 37.4 wt% for the raw coal to about 20 wt% for the HWD coals. The energy density, determined at 500 cP, indicates an increase from 4450 to 6650 Btu/lb by hydrothermal treatment. Raw and HWD coal were then gasified at various mild gasification conditions of 700 C and 30 psig. The tests indicated that the coal is probably similar to other low-rank coals and will produce high levels of hydrogen and be fairly reactive.

Ness, R.O. Jr.; Anderson, C.M.; Musich, M.A.; Richter, J.J.; Dewall, R.A.; Young, B.C. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Nakanart, A. [Ministry of Industry, Bangkok (Thailand)

1996-12-31T23:59:59.000Z

102

Gasification of New Zealand coals: a comparative simulation study  

SciTech Connect

The aim of this study was to conduct a preliminary feasibility assessment of gasification of New Zealand (NZ) lignite and sub-bituminous coals, using a commercial simulation tool. Gasification of these coals was simulated in an integrated gasification combined cycle (IGCC) application and associated preliminary economics compared. A simple method of coal characterization was developed for simulation purposes. The carbon, hydrogen, and oxygen content of the coal was represented by a three component vapor solid system of carbon, methane, and water, the composition of which was derived from proximate analysis data on fixed carbon and volatile matter, and the gross calorific value, both on a dry, ash free basis. The gasification process was modeled using Gibb's free energy minimization. Data from the U.S. Department of Energy's Shell Gasifier base cases using Illinios No. 6 coal was used to verify both the gasifier and the IGCC flowsheet models. The H:C and O:C ratios of the NZ coals were adjusted until the simulated gasifier output composition and temperature matched the values with the base case. The IGCC power output and other key operating variables such as gas turbine inlet and exhaust temperatures were kept constant for study of comparative economics. The results indicated that 16% more lignite than sub-bituminous coal was required. This translated into the requirement of a larger gasifier and air separation unit, but smaller gas and steam turbines were required. The gasifier was the largest sole contributor (30%) to the estimated capital cost of the IGCC plant. The overall cost differential associated with the processing of lignite versus processing sub-bituminous coal was estimated to be of the order of NZ $0.8/tonne. 13 refs., 9 tabs.

Smitha V. Nathen; Robert D. Kirkpatrick; Brent R. Young [University of Auckland, Auckland (New Zealand). Department of Chemical and Materials Engineering

2008-07-15T23:59:59.000Z

103

Characterization of Filter Elements for Service in a Coal Gasification Environment  

SciTech Connect

The Power Systems Development Facility (PSDF) is a joint Department of Energy/Industry sponsored engineering-scale facility for testing advanced coal-based power generation technologies. High temperature, high pressure gas cleaning is critical to many of these advanced technologies. Barrier filter elements that can operate continuously for nearly 9000 hours are required for a successful gas cleaning system for use in commercial power generation. Since late 1999, the Kellogg Brown & Root Transport reactor at the PSDF has been operated in gasification mode. This paper describes the test results for filter elements operating in the Siemens-Westinghouse particle collection device (PCD) with the Transport reactor in gasification mode. Operating conditions in the PCD have varied during gasification operation as described elsewhere in these proceedings (Martin et al, 2002).

Spain, J.D.

2002-09-19T23:59:59.000Z

104

Thermophysical models of underground coal gasification and FEM analysis  

SciTech Connect

In this study, mathematical models of the coupled thermohydromechanical process of coal rock mass in an underground coal gasification panel are established. Combined with the calculation example, the influence of heating effects on the observed values and simulated values for pore water pressure, stress, and displacement in the gasification panel are fully discussed and analyzed. Calculation results indicate that 38, 62, and 96 days after the experiment, the average relative errors for the calculated values and measured values for the temperature and water pressure were between 8.51-11.14% and 3-10%, respectively; with the passage of gasification time, the calculated errors for the vertical stress and horizontal stress gradually declined, but the simulated errors for the horizontal and vertical displacements both showed a rising trend. On the basis of the research results, the calculated values and the measured values agree with each other very well.

Yang, L.H. [China University of Mining & Technology, Xuzhou (China)

2007-11-15T23:59:59.000Z

105

Case-study of a coal gasification-based energy supply system for China  

E-Print Network (OSTI)

clean fuels derived via coal gasification. Emissions of air pollutants in the SC scenario are compared polygeneration technologies to meet energy needs of coal-rich areas. Polygeneration systems, based on coalCase-study of a coal gasification-based energy supply system for China Zheng Hongtao Department

106

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

107

EIS-0007: Low Btu Coal Gasification Facility and Industrial Park  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy prepared this environmental impact statement which evaluates the potential environmental impacts that may be associated with the construction and operation of a low-Btu coal gasification facility and the attendant industrial park in Georgetown, Scott County, Kentucky.

108

Effect of petroleum coke addition on coal gasification  

Science Journals Connector (OSTI)

The main fuel for power generation is combustion of coal and/or natural gas. Natural gas is expensive but clean and less problematic whereas coal is the reverse of natural gas. Natural gas resources are expected to last until 2020 where else coal has another 200 years expectancy. To replace the natural gas synthetic gas (syngas) can be used as a substitute fuel. Syngas can be produced using coal as fuel. In this study we blend petcoke a cheap solid carboneous fuel as an alternative to coal for the production of syngas using a 30 Kwattheat bubbling fluidized bed gasifier. The equivalent ratio (ER) was set at 2.8 and a gasification temperature was maintained between 680 to 710°C by manipulating between the feed flow rates and fluidizing medium. This condition was chosen as it proved to be the optimum based on the work by the same group. Various blend of coal:petcoke between 0 to 100% was analyzed. It was found that a 20:80 petcoke to coal gives a good correlation with 100% coal gasification.

2014-01-01T23:59:59.000Z

109

Integrated coal cleaning, liquefaction, and gasification process  

DOE Patents (OSTI)

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Chervenak, Michael C. (Pennington, NJ)

1980-01-01T23:59:59.000Z

110

The development of Coke Carried-Heat Gasification Coal-Fired Combined Cycle  

Science Journals Connector (OSTI)

Carried-Heat Partial Gasification Combined cycle is a novel combined cycle which was proposed by Thermal Engineering Department ... technology, Coke Carried-Heat Gasification Coal-Fired Combined Cycle, as the imp...

Li Zhao; Xiangdong Xu

1999-12-01T23:59:59.000Z

111

Materials Challenges for Advanced Combustion and Gasification Fossil Energy Systems  

Science Journals Connector (OSTI)

Through gasification, carbonaceous feedstock such as coal, petroleum coke (petcoke), and biomass is converted into synthesis...12–18] through, e.g., combustion or electrochemical conversion in fuel cells. Syngas ...

S. Sridhar; P. Rozzelle; B. Morreale…

2011-04-01T23:59:59.000Z

112

CoalFleet RD&D augmentation plan for integrated gasification combined cycle (IGCC) power plants  

SciTech Connect

To help accelerate the development, demonstration, and market introduction of integrated gasification combined cycle (IGCC) and other clean coal technologies, EPRI formed the CoalFleet for Tomorrow initiative, which facilitates collaborative research by more than 50 organizations from around the world representing power generators, equipment suppliers and engineering design and construction firms, the U.S. Department of Energy, and others. This group advised EPRI as it evaluated more than 120 coal-gasification-related research projects worldwide to identify gaps or critical-path activities where additional resources and expertise could hasten the market introduction of IGCC advances. The resulting 'IGCC RD&D Augmentation Plan' describes such opportunities and how they could be addressed, for both IGCC plants to be built in the near term (by 2012-15) and over the longer term (2015-25), when demand for new electric generating capacity is expected to soar. For the near term, EPRI recommends 19 projects that could reduce the levelized cost-of-electricity for IGCC to the level of today's conventional pulverized-coal power plants with supercritical steam conditions and state-of-the-art environmental controls. For the long term, EPRI's recommended projects could reduce the levelized cost of an IGCC plant capturing 90% of the CO{sub 2} produced from the carbon in coal (for safe storage away from the atmosphere) to the level of today's IGCC plants without CO{sub 2} capture. EPRI's CoalFleet for Tomorrow program is also preparing a companion RD&D augmentation plan for advanced-combustion-based (i.e., non-gasification) clean coal technologies (Report 1013221). 7 refs., 30 figs., 29 tabs., 4 apps.

NONE

2007-01-15T23:59:59.000Z

113

Advanced coal-fueled gas turbine systems  

SciTech Connect

Several technology advances since the early coal-fueled turbine programs that address technical issues of coal as a turbine fuel have been developed in the early 1980s: Coal-water suspensions as fuel form, improved methods for removing ash and contaminants from coal, staged combustion for reducing NO{sub x} emissions from fuel-bound nitrogen, and greater understanding of deposition/erosion/corrosion and their control. Several Advanced Coal-Fueled Gas Turbine Systems programs were awarded to gas turbine manufacturers for for components development and proof of concept tests; one of these was Allison. Tests were conducted in a subscale coal combustion facility and a full-scale facility operating a coal combustor sized to the Allison Model 501-K industrial turbine. A rich-quench-lean (RQL), low nitrogen oxide combustor design incorporating hot gas cleanup was developed for coal fuels; this should also be applicable to biomass, etc. The combustor tests showed NO{sub x} and CO emissions {le} levels for turbines operating with natural gas. Water washing of vanes from the turbine removed the deposits. Systems and economic evaluations identified two possible applications for RQL turbines: Cogeneration plants based on Allison 501-K turbine (output 3.7 MW(e), 23,000 lbs/hr steam) and combined cycle power plants based on 50 MW or larger gas turbines. Coal-fueled cogeneration plant configurations were defined and evaluated for site specific factors. A coal-fueled turbine combined cycle plant design was identified which is simple, compact, and results in lower capital cost, with comparable efficiency and low emissions relative to other coal technologies (gasification, advanced PFBC).

Wenglarz, R.A.

1994-08-01T23:59:59.000Z

114

Advanced Biomass Gasification Technologies Inc ABGT | Open Energy  

Open Energy Info (EERE)

Gasification Technologies Inc ABGT Gasification Technologies Inc ABGT Jump to: navigation, search Name Advanced Biomass Gasification Technologies Inc. (ABGT) Place New York, New York Zip 10036 Product Company set up by UTEK specifically for its sale to Xethanol, holding the exclusive license for microgasification technology developed at the Energy and Environmental Research Center (EERC) at the University of North Dakota. References Advanced Biomass Gasification Technologies Inc. (ABGT)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Advanced Biomass Gasification Technologies Inc. (ABGT) is a company located in New York, New York . References ↑ "Advanced Biomass Gasification Technologies Inc. (ABGT)"

115

Combined cycle power plant incorporating coal gasification  

DOE Patents (OSTI)

A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

1981-01-01T23:59:59.000Z

116

Underground coal gasification field experiment in the high-dipping coal seams  

SciTech Connect

In this article the experimental conditions and process of the underground gasification in the Woniushan Mine, Xuzhou, Jiangsu Province are introduced, and the experimental results are analyzed. By adopting the new method of long-channel, big-section, and two-stage underground coal gasification, the daily gas production reaches about 36,000 m{sup 3}, with the maximum output of 103,700 m{sup 3}. The daily average heating value of air gas is 5.04 MJ/m{sup 3}, with 13.57 MJ/m{sup 3} for water gas. In combustible compositions of water gas, H{sub 2} contents stand at over 50%, with both CO and CH{sub 4} contents over 6%. Experimental results show that the counter gasification can form new temperature conditions and increase the gasification efficiency of coal seams.

Yang, L.H.; Liu, S.Q.; Yu, L.; Zhang, W. [China University of Mining & Technology, Xuzhou (China). College of Resources & Geoscience

2009-07-01T23:59:59.000Z

117

CAPITAL AND OPERATING COST OF HYDROGEN PRODUCTION FROM COAL GASIFICATION  

NLE Websites -- All DOE Office Websites (Extended Search)

CAPITAL AND OPERATING COST OF HYDROGEN CAPITAL AND OPERATING COST OF HYDROGEN PRODUCTION FROM COAL GASIFICATION Final Report April 2003 Prepared for: The United States Department of Energy National Energy Technology Laboratory (NETL) under: Contract No. DE-AM26-99FT40465 between the NETL and Concurrent Technologies Corporation (CTC) Subcontract No. 990700362 between CTC and Parsons Infrastructure & Technology Group Inc. Task 50611 DOE Task Managers: James R. Longanbach Gary J. Stiegel Parsons Project Manager: Michael D. Rutkowski Principal Investigators: Thomas L. Buchanan Michael G. Klett Ronald L. Schoff PARSONS Capital and Operating Cost of Hydrogen Production from Coal Gasification Page i April 2003 TABLE OF CONTENTS Section Title Page List of Tables iii List of Figures iii

118

Gasification Characteristics of Coal/Biomass Mixed Fuels  

SciTech Connect

A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO2 was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO2. In contrast, mixed char reactivity to H2O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H2O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times and off-gas compositions

Mitchell, Reginald

2013-09-30T23:59:59.000Z

119

New Projects Set to Target Efficiency, Environmental Gains at Advanced Coal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Projects Set to Target Efficiency, Environmental Gains at Projects Set to Target Efficiency, Environmental Gains at Advanced Coal Gasification Facilities New Projects Set to Target Efficiency, Environmental Gains at Advanced Coal Gasification Facilities July 27, 2010 - 1:00pm Addthis Washington, D.C. -- Four projects that will demonstrate an innovative technology that could eventually enhance hydrogen fuel production, lower greenhouse gas (GHG) emissions, improve efficiencies and lower consumer electricity costs from advanced coal gasification power systems have been selected by the U.S. Department of Energy (DOE). The projects will test membrane technology to separate hydrogen and carbon dioxide (CO2) from coal or coal/biomass-derived synthesis gas (syngas), such as from Integrated Gasification Combined Cycle (IGCC) power systems.

120

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

Phadke, Amol

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

NETL: News Release -Treasury, Energy Departments Release New Advanced Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

7, 2007 7, 2007 Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 WASHINGTON, DC - The Treasury Department and the Department of Energy (DOE) released today new instructions for applying for the tax credits for advanced coal projects and gasification projects. The new instructions provide additional time to submit applications for the credits. For the 2007-2008 allocation round, applications for DOE certification are not due to the Energy Department until October 31, 2007. "To further advance our nation's energy security, this Administration had made sustained investments in research, development, and wider use of advanced coal technologies a priority," Deputy Secretary of Energy Clay Sell said. "Through new and innovative programs such as the Clean Coal Power Initiative and FutureGen demonstration, private sector partnerships, and use of tax credits and loan guarantees, the Department of Energy is advancing research to further develop and deploy advanced coal technologies to meet growing energy demand."

122

Site Characterization, Sustainability Evaluation and Life Cycle Emissions Assessment of Underground Coal Gasification.  

E-Print Network (OSTI)

??Underground Coal Gasification (UCG), although not a new concept, is now attracting considerable global attention as a viable process to provide a âcleanâ and economic… (more)

Hyder, Zeshan

2012-01-01T23:59:59.000Z

123

Model-based estimation of adiabatic flame temperature during coal gasification.  

E-Print Network (OSTI)

??Coal gasification temperature distribution in the gasifier is one of the importantissues. High temperature may increase the risk of corrosion of the gasifier wall or… (more)

Sarigul, Ihsan Mert

2012-01-01T23:59:59.000Z

124

Encoal mild coal gasification project: Final design modifications report  

SciTech Connect

The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

NONE

1997-07-01T23:59:59.000Z

125

The ENCOAL Mild Coal Gasification Project, A DOE Assessment  

SciTech Connect

This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective, the following goals were established for the ENCOAL{reg_sign} Project: Provide sufficient quantity of products for full-scale test burns; Develop data for the design of future commercial plants; Demonstrate plant and process performance; Provide capital and O&M cost data; and Support future LFC{trademark} technology licensing efforts. Each of these goals has been met and exceeded. The plant has been in operation for nearly 5 years, during which the LFC{trademark} process has been demonstrated and refined. Fuels were made, successfully burned, and a commercial-scale plant is now under contract for design and construction.

National Energy Technology Laboratory

2002-03-15T23:59:59.000Z

126

NETL: C&CBTL - Investigation of Coal-Biomass Catalytic Gasification Using  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal/Biomass Feed and Gasification Coal/Biomass Feed and Gasification Investigation of Coal-Biomass Catalytic Gasification Using Experiments, Reaction Kinetics and Computational Fluid Dynamics Virginia Polytechnic Institute and State University Project Number: FE0005476 Project Description The objectives of the proposed study are to obtain experimental reactor data and develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations, to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure, to build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and to investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.

127

Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1  

SciTech Connect

Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. (Institute of Gas Technology, Chicago, IL (United States)); Duthie, R.G. (Bechtel Group, Inc., San Francisco, CA (United States)); Wootten, J.M. (Peabody Holding Co., Inc., St. Louis, MO (United States))

1991-09-01T23:59:59.000Z

128

Heat exchanger for coal gasification process  

DOE Patents (OSTI)

This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

Blasiole, George A. (Greensburg, PA)

1984-06-19T23:59:59.000Z

129

Evaluating the feasibility of underground coal gasification in Thailand  

SciTech Connect

Underground coal gasification (UCG) is a clean coal technology that converts in situ coal into a low- to medium-grade product gas without the added expense of mining and reclamation. Potential candidates for UCG are those coal resources that are not economically recoverable or that are otherwise unacceptable for conventional coal utilization processes. The Energy and Environmental Research Center (EERC), through the sponsorship of the US Trade and Development Agency and in collaboration with the Electricity Generating Authority of Thailand (EGAT), is undertaking a feasibility study for the application of UCG in the Krabi coal mining area, 620 miles south of Bangkok in Thailand. The EERC`s objective for this project is to determine the technical, environmental, and economic feasibility of demonstrating and commercializing UCG at a selected site in the Krabi coal mining area. This paper addresses the preliminary developments and ongoing strategy for evaluating the selected UCG site. The technical, environmental, and economic factors for successful UCG operation are discussed, as well as the strategic issues pertaining to future energy expansion in southern Thailand.

Young, B.C.; Harju, J.A.; Schmit, C.R.; Solc, J. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Boysen, J. [B.C. Technologies, Ltd., Laramie, WY (United States); Kuehnel, R.A. [International Inst. for Aerospace Survey and Earth Sciences, Delft (Netherlands)

1996-12-31T23:59:59.000Z

130

Method for using fast fluidized bed dry bottom coal gasification  

DOE Patents (OSTI)

Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

1983-01-01T23:59:59.000Z

131

Numerical study on convection diffusion for gasification agent in underground coal gasification. Part I: establishment of mathematical models and solving method  

SciTech Connect

The aim of this article is to discuss the distribution law of the gasification agent concentration in a deep-going way during underground coal gasification and the new method of solving the problem for the convection diffusion of the gas. In this paper, the basic features of convection diffusion for the gas produced in underground coal gasification are studied. On the basis of the model experiment, through the analysis of the distribution and patterns of variation for the fluid concentration field in the process of the combustion and gasification of the coal seams within the gasifier, the 3-D non-linear unstable mathematical models on the convection diffusion for oxygen are established. In order to curb such pseudo-physical effects as numerical oscillation and surfeit which frequently occurred in the solution of the complex mathematical models, the novel finite unit algorithm, the upstream weighted multi-cell balance method is advanced in this article, and its main derivation process is introduced.

Yang, L.H.; Ding, Y.M. [China University of Mining & Technology, Xuzhou (China). College of Resources and Geoscience

2009-07-01T23:59:59.000Z

132

NETL, USDA design coal-stabilized biomass gasification unit  

SciTech Connect

Coal, poultry litter, contaminated corn, rice hulls, moldly hay, manure sludge - these are representative materials that could be tested as fuel feedstocks in a hybrid gasification/combustion concept studied in a recent US Department of Energy (DOE) design project. DOE's National Energy Technology Laboratory (NETL) and the US Department of Agriculture (USDA) collaborated to develop a design concept of a power system that incorporates Hybrid Biomass Gasification. This system would explore the use of a wide range of biomass and agricultural waste products as gasifier feedstocks. The plant, if built, would supply one-third of electrical and steam heating needs at the USDA's Beltsville (Maryland) Agricultural Research Center. 1 fig., 1 photo.

NONE

2008-09-30T23:59:59.000Z

133

Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996  

SciTech Connect

This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

Sheesley, D.; King, S.B.

1998-12-31T23:59:59.000Z

134

EA-1642S: Small-Scale Pilot Plant for the Gasification of Coal and  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

642S: Small-Scale Pilot Plant for the Gasification of Coal and 642S: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY EA-1642S: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY SUMMARY This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE's proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

135

Co-Production of Substitute Natural Gas/Electricity Via Catalytic Coal Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 Co-ProduCtion of SubStitute natural GaS / eleCtriCity via CatalytiC Coal GaSifiCation Description The United States has vast reserves of low-cost coal, estimated to be sufficient for the next 250 years. Gasification-based technology, such as Integrated Gasification Combined Cycle (IGCC), is the only environmentally friendly technology that provides the flexibility to co-produce hydrogen, substitute natural gas (SNG), premium hydrocarbon liquids including transportation fuels, and electric power in desired combinations from coal and other carbonaceous feedstocks. Rising costs and limited domestic supply of crude oil and natural gas provide a strong incentive for the development of coal gasification-based co-production processes. This project addresses the co-production of SNG and electricity from coal via gasification

136

Treasury, Energy Departments Release New Advanced Coal Project Tax Credit  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Treasury, Energy Departments Release New Advanced Coal Project Tax Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 June 7, 2007 - 1:40pm Addthis WASHINGTON, DC - The Treasury Department and the Department of Energy (DOE) released today new instructions for applying for the tax credits for advanced coal projects and gasification projects. The new instructions provide additional time to submit applications for the credits. For the 2007-2008 allocation round, applications for DOE certification are not due to the Energy Department until October 31, 2007. "To further advance our nation's energy security, this Administration had made sustained investments in research, development, and wider use of

137

Treasury, Energy Departments Release New Advanced Coal Project Tax Credit  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Treasury, Energy Departments Release New Advanced Coal Project Tax Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 Treasury, Energy Departments Release New Advanced Coal Project Tax Credit Applications for 2007-2008 June 7, 2007 - 1:40pm Addthis WASHINGTON, DC - The Treasury Department and the Department of Energy (DOE) released today new instructions for applying for the tax credits for advanced coal projects and gasification projects. The new instructions provide additional time to submit applications for the credits. For the 2007-2008 allocation round, applications for DOE certification are not due to the Energy Department until October 31, 2007. "To further advance our nation's energy security, this Administration had made sustained investments in research, development, and wider use of

138

The commercial feasibility of underground coal gasification in southern Thailand  

SciTech Connect

Underground Coal Gasification (UCG) is a clean coal technology with the commercial potential to provide low- or medium-Btu gas for the generation of electric power. While the abundance of economic coal and natural gas reserves in the United States of America (USA) has delayed the commercial development of this technology in the USA, potential for commercial development of UCG-fueled electric power generation currently exists in many other nations. Thailand has been experiencing sustained economic growth throughout the past decade. The use of UCG to provide electric power to meet the growing power demand appears to have commercial potential. A project to determine the commercial feasibility of UCG-fueled electric power generation at a site in southern Thailand is in progress. The objective of the project is to determine the commercial feasibility of using UCG for power generation in the Krabi coal mining area located approximately 1,000 kilometers south of Bangkok, Thailand. The project team has developed a detailed methodology to determine the technical feasibility, environmental acceptability, and commercial economic potential of UCG at a selected site. In the methodology, hydrogeologic conditions of the coal seam and surrounding strata are determined first. These results and information describing the local economic conditions are then used to assess the commercial potential of the UCG application. The methodology for evaluating the Krabi UCG site and current project status are discussed in this paper.

Solc, J.; Young, B.C.; Harju, J.A.; Schmit, C.R. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Boysen, J.E. [B.C. Technologies, Ltd., Laramie, WY (United States); Kuhnel, R.A. [IIASES, Delft (Netherlands)

1996-12-31T23:59:59.000Z

139

Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Opening New Avenues for High-Efficiency, Low-Emission Coal Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification April 10, 2012 - 1:00pm Addthis A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. Washington, DC - Gasification. It's a versatile technology that uses coal to produce power, chemicals, and fuels. Inherently low in air emissions, solid byproducts, and wastewater, commercial gasification plants have proven capable of exceeding the most stringent regulations for air- and solids-emissions. However, capital and operational costs have prohibited the widespread adoption of gasification, especially for power

140

Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed  

SciTech Connect

Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li [Southeast University, Nanjing (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

2008-05-15T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report  

SciTech Connect

This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

Prausnitz, J.M.

1980-05-01T23:59:59.000Z

142

Status of health and environmental research relative to coal gasification 1976 to the present  

SciTech Connect

Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

Wilzbach, K.E.; Reilly, C.A. Jr. (comps.)

1982-10-01T23:59:59.000Z

143

Forward and reverse combustion gasification of coal with production of high-quality syngas in a simulated pilot system for in situ gasification  

Science Journals Connector (OSTI)

Abstract This research focused on the feasibility and stability of applying the forward and reverse combustion approach to the in situ gasification of lignite and bituminous coal with oxygen or oxygen–steam mixtures as gasification agents, especially reverse combustion gasification. A high-quality syngas (H2 and CO) could be obtained using the reverse combustion gasification technique combined with forward combustion gasification in a pilot system for in situ gasification. The gasification time was extended more than 25% using the reverse combustion approach. The controlling conditions for reverse combustion gasification were obtained by comparing and analyzing experimental data. The results show the relationship between the inject gas flow within certain limits and velocity of the gasification flame was linear during reverse combustion. The underground conditions of the coal seam and strata were simulated in a pilot-scale underground gasifier during experiments. The combustion gasification of coal was carried out experimentally for over 5 days. The average effective content (H2 and CO) of syngas was in the range of 60–70%, meeting the requirement of synthesis gas. The optimal ranges of gasifying lignite and bituminous coal were found to be 1.5–2.0 and 1.3–1.75, respectively. The product gas flow was proportional to oxygen blast. These are expected to provide useful guidance on practical underground coal gasification operations and to give experimental evidence in support of theory.

Yong Cui; Jie Liang; Zhangqing Wang; Xiaochun Zhang; Chenzi Fan; Dongyu Liang; Xuan Wang

2014-01-01T23:59:59.000Z

144

Mathematical Modeling of Coal Gasification Processes in a Well-Stirred Reactor: Effects of Devolatilization and Moisture Content  

E-Print Network (OSTI)

Mathematical Modeling of Coal Gasification Processes in a Well- Stirred Reactor: Effects in coal and biomass play an important role on the gasification performance of these fuels to simulate the gasification processes in a well-stirred reactor. This model is a first

Qiao, Li

145

Thermal-Hydrological Sensitivity Analysis of Underground Coal Gasification  

SciTech Connect

This paper presents recent work from an ongoing project at Lawrence Livermore National Laboratory (LLNL) to develop a set of predictive tools for cavity/combustion-zone growth and to gain quantitative understanding of the processes and conditions (natural and engineered) affecting underground coal gasification (UCG). We discuss the application of coupled thermal-hydrologic simulation capabilities required for predicting UCG cavity growth, as well as for predicting potential environmental consequences of UCG operations. Simulation of UCG cavity evolution involves coupled thermal-hydrological-chemical-mechanical (THCM) processes in the host coal and adjoining rockmass (cap and bedrock). To represent these processes, the NUFT (Nonisothermal Unsaturated-saturated Flow and Transport) code is being customized to address the influence of coal combustion on the heating of the host coal and adjoining rock mass, and the resulting thermal-hydrological response in the host coal/rock. As described in a companion paper (Morris et al. 2009), the ability to model the influence of mechanical processes (spallation and cavity collapse) on UCG cavity evolution is being developed at LLNL with the use of the LDEC (Livermore Distinct Element Code) code. A methodology is also being developed (Morris et al. 2009) to interface the results of the NUFT and LDEC codes to simulate the interaction of mechanical and thermal-hydrological behavior in the host coal/rock, which influences UCG cavity growth. Conditions in the UCG cavity and combustion zone are strongly influenced by water influx, which is controlled by permeability of the host coal/rock and the difference between hydrostatic and cavity pressure. In this paper, we focus on thermal-hydrological processes, examining the relationship between combustion-driven heat generation, convective and conductive heat flow, and water influx, and examine how the thermal and hydrologic properties of the host coal/rock influence those relationships. Specifically, we conducted a parameter sensitivity analysis of the influence of thermal and hydrological properties of the host coal, caprock, and bedrock on cavity temperature and steam production.

Buscheck, T A; Hao, Y; Morris, J P; Burton, E A

2009-10-05T23:59:59.000Z

146

Utilization of lightweight materials made from coal gasification slags  

SciTech Connect

Praxis is working on a DOE/METC funded project to demonstrate the technical and economic feasibility of making lightweight and ultra- lightweight aggregates from slags left as solid by-products from the coal gasification process. These aggregates are produced by controlled heating of the slags to temperatures ranging between 1600 and 1900{degrees}F. Over 10 tons of expanded slag lightweight aggregates (SLA) were produced using a direct-fired rotary kiln and a fluidized bed calciner with unit weights varying between 20 and 50 lb/ft{sup 3}. The slag-based aggregates are being evaluated at the laboratory scale as substitutes for conventional lightweight aggregates in making lightweight structural concrete, roof tiles, blocks, insulating concrete, and a number of other applications. Based on the laboratory data, large-scale testing will be performed and the durability of the finished products evaluated. Conventional lightweight aggregates made from pyroprocessing expansible shales or clays are produced for $30/ton. The net production costs of SLA are in the range of $22 to $24/ton for large systems (44 t/d) and $26-$30/ton for small systems (220 t/d). Thus, the technology provides a good opportunity for economic use of gasification slags.

NONE

1996-07-08T23:59:59.000Z

147

Development of Biomass-Infused Coal Briquettes for Co-Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass-Infused Coal Briquettes for Co-Gasification Biomass-Infused Coal Briquettes for Co-Gasification CoalTek, Inc. Project Number: FE0005293 Project Description This project will demonstrate an application of a CoalTek, Inc. (CoalTek) proprietary microwave process for treating energy feedstock materials. The process combines coal and biomass to produce an economically viable and suitable single-stream feedstock for co-gasification. Phase I of the project will focus on microwave processing, batch-scale production, and laboratory characterizations of briquettes with the objective to identify the combinations of biomass and coal types that provide the most suitable briquetted product for co-gasification. Phase II will use a larger scale, continuous mode process to (1) demonstrate the performance of the co-briquetted fuels during co-gasification in two different pilot-plant designs, i.e., fixed-bed and fluidized-bed gasifiers, and (2) enable realistic cost estimates for the construction and operation of a commercial-scale biomass-coal briquetting plant based on CoalTek's proprietary microwave process.

148

Low-rank coal research: Volume 2, Advanced research and technology development: Final report  

SciTech Connect

Volume II contains articles on advanced combustion phenomena, combustion inorganic transformation; coal/char reactivity; liquefaction reactivity of low-rank coals, gasification ash and slag characterization, and fine particulate emissions. These articles have been entered individually into EDB and ERA. (LTN)

Mann, M.D.; Swanson, M.L.; Benson, S.A.; Radonovich, L.; Steadman, E.N.; Sweeny, P.G.; McCollor, D.P.; Kleesattel, D.; Grow, D.; Falcone, S.K.

1987-04-01T23:59:59.000Z

149

The ENCOAL Mild Coal Gasification Project, A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

71 71 The ENCOAL ® Mild Coal Gasification Project A DOE Assessment March 2002 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 website: www.netl.doe.gov 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference

150

Proceedings of the ninth annual underground coal gasification symposium  

SciTech Connect

The Ninth Underground Coal Gasification Symposium was held August 7 to 10, 1983 at the Indian Lakes Resort and Conference Center in Bloomingdale, Illinois. Over one-hundred attendees from industry, academia, National Laboratories, State Government, and the US Government participated in the exchange of ideas, results and future research plans. Representatives from six countries including France, Belgium, United Kingdom, The Netherlands, West Germany, and Brazil also participated by presenting papers. Fifty papers were presented and discussed in four formal sessions and two informal poster sessions. The presentations described current and future field testing plans, interpretation of field test data, environmental research, laboratory studies, modeling, and economics. All papers were processed for inclusion in the Energy Data Base.

Wieber, P.R.; Martin, J.W.; Byrer, C.W. (eds.)

1983-12-01T23:59:59.000Z

151

Underground Gasification of Coal in the U.S.S.R  

Science Journals Connector (OSTI)

... S.S.R., however, the first practical work was begun in 1933 on the gasification of the coal in tlie seam. This is reached by two shafts connected by ... necessitates the labour of miners to sink the shafts and to tunnel the seam before gasification can begin. In a new installation in the Donetz coalfield, the seam will be ...

1941-04-19T23:59:59.000Z

152

Analysis of a coal fired combined cycle with carried-heat gasification  

Science Journals Connector (OSTI)

In the research of a more efficient, less costly, more environmentally responsible and less technically difficult method for generating electrical power from coal, the Carried-heat Gasification Combined Cycle (CG...

Xiangdong Xu; Weimin Zhu; Li Zhao; F. N. Fett

153

Experimental Study on Co-gasification of Coal Liquefaction Residue and Petroleum Coke  

Science Journals Connector (OSTI)

An experimental study on co-gasification of coal liquefaction residue and petroleum coke in carbon dioxide was investigated by thermogravimetric analysis. The temperature of the experiment was 1173–1323 K, and the isothermal (1273 K) kinetics were ...

Xin Liu; Zhi-jie Zhou; Qi-jing Hu; Zheng-hua Dai; Fu-chen Wang

2011-06-20T23:59:59.000Z

154

EA-1219: Hoe Creek Underground Coal Gasification Test Site Remediation, Campbell County, Wyoming  

Energy.gov (U.S. Department of Energy (DOE))

This EA evaluates the environmental impacts for the proposed Hoe Creek Underground Coal Gasification Test Site Remediation that would be performed at the Hoe Creek site in Campbell County, Wyoming.

155

Co-Gasification of Biomass and Coal in a Pressurised Fluidised Bed Gasifier  

Science Journals Connector (OSTI)

During a 3 year (1996 – 1998) project, partly funded by the EU as part of their JOULE 3 programme, experimental and theoretical research will be done on co-gasification of biomass and coal in a pressurised fluidi...

J. Andries; K. R. G. Hein

1997-01-01T23:59:59.000Z

156

Fixed-bed gasification research using US coals. Volume 16. Gasification of 2-inch Minnesota peat sods  

SciTech Connect

A single, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scubber used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and government agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the sixteenth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific test report describes the gasification of two-inch Minnesota peat sods, which began on June 24, 1985 and was completed on June 27, 1985. 4 refs., 18 figs., 14 tabs.

Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

1985-10-01T23:59:59.000Z

157

Characterizing a lignite formation before and after an underground coal gasification experiment  

E-Print Network (OSTI)

CHARACTERIZING A LIGNITE FORMATION BEFORE AND AFTER AN UNDERGROUND COAL GASIFICATION EXPERIMENT A Thesis by USMAN AHMED Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE Nay, 1981 Major Subject: Petrol eum Engineering CHARACTERIZING A LIGNITE FORMATION BEFORE AND AFTER AN UNDERGROUND COAL GASIFICATION EXPERIMENT A Thesis by USMAN AHMED approved as to sty1e and content by: airma o i ee Head f...

Ahmed, Usman

2012-06-07T23:59:59.000Z

158

Laboratory Study on Gasification Reactivity of Coals and Petcokes in CO2/Steam at High Temperatures  

Science Journals Connector (OSTI)

A diffusion term associated with the carbon structure may be needed for modelling the gasification behaviors of the petcoke-like materials. ... Gasification technology is used to convert feedstocks, not only coal but also petcoke and other carbonaceous materials, to fuel gas or syngas,(1, 2) which can be used to generate electricity and heat or to synthesize liquid fuel and chemicals. ... It is certain that petcoke, derived from oil refinery coke units or other cracking processes, has a much lower gasification reactivity than coal chars, especially at low temperatures. ...

Liwei Ren; Jianli Yang; Feng Gao; Jinding Yan

2013-07-30T23:59:59.000Z

159

Gasification Plant Databases  

NLE Websites -- All DOE Office Websites (Extended Search)

coal gasification projects throughout the world. These databases track proposed gasification projects with approximate outputs greater than 100 megawatts electricity...

160

Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1. Final report  

SciTech Connect

Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. [Institute of Gas Technology, Chicago, IL (United States); Duthie, R.G. [Bechtel Group, Inc., San Francisco, CA (United States); Wootten, J.M. [Peabody Holding Co., Inc., St. Louis, MO (United States)

1991-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Comparative Study of Gasification Performance between Bituminous Coal and Petroleum Coke in the Industrial Opposed Multiburner Entrained Flow Gasifier  

Science Journals Connector (OSTI)

SUMMARY : Co-gasification performance of coal and petroleum coke (petcoke) blends in a pilot-scale pressurized entrained-flow gasifier was studied exptl. ... Two different coals, including a subbituminous coal (Coal A) and a bituminous coal (Coal B), individually blended with a petcoke in the gasifier were considered. ... results suggested that, when the petcoke was mixed with Coal A over 70%, the slagging problem, which could shorten the operational period due to high ash content in the coal, was improved. ...

Zhonghua Sun; Zhenghua Dai; Zhijie Zhou; Jianliang Xu; Guangsuo Yu

2012-09-27T23:59:59.000Z

162

Advanced Coal Wind Hybrid: Economic Analysis  

SciTech Connect

Growing concern over climate change is prompting new thinking about the technologies used to generate electricity. In the future, it is possible that new government policies on greenhouse gas emissions may favor electric generation technology options that release zero or low levels of carbon emissions. The Western U.S. has abundant wind and coal resources. In a world with carbon constraints, the future of coal for new electrical generation is likely to depend on the development and successful application of new clean coal technologies with near zero carbon emissions. This scoping study explores the economic and technical feasibility of combining wind farms with advanced coal generation facilities and operating them as a single generation complex in the Western US. The key questions examined are whether an advanced coal-wind hybrid (ACWH) facility provides sufficient advantages through improvements to the utilization of transmission lines and the capability to firm up variable wind generation for delivery to load centers to compete effectively with other supply-side alternatives in terms of project economics and emissions footprint. The study was conducted by an Analysis Team that consists of staff from the Lawrence Berkeley National Laboratory (LBNL), National Energy Technology Laboratory (NETL), National Renewable Energy Laboratory (NREL), and Western Interstate Energy Board (WIEB). We conducted a screening level analysis of the economic competitiveness and technical feasibility of ACWH generation options located in Wyoming that would supply electricity to load centers in California, Arizona or Nevada. Figure ES-1 is a simple stylized representation of the configuration of the ACWH options. The ACWH consists of a 3,000 MW coal gasification combined cycle power plant equipped with carbon capture and sequestration (G+CC+CCS plant), a fuel production or syngas storage facility, and a 1,500 MW wind plant. The ACWH project is connected to load centers by a 3,000 MW transmission line. In the G+CC+CCS plant, coal is gasified into syngas and CO{sub 2} (which is captured). The syngas is burned in the combined cycle plant to produce electricity. The ACWH facility is operated in such a way that the transmission line is always utilized at its full capacity by backing down the combined cycle (CC) power generation units to accommodate wind generation. Operating the ACWH facility in this manner results in a constant power delivery of 3,000 MW to the load centers, in effect firming-up the wind generation at the project site.

Phadke, Amol; Goldman, Charles; Larson, Doug; Carr, Tom; Rath, Larry; Balash, Peter; Yih-Huei, Wan

2008-11-28T23:59:59.000Z

163

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

th th Annual International Colloquium on Environmentally Preferred Advanced Power Generation, Costa Mesa, CA, February 7, 2012 An Overview of U.S. DOE's Gasification Systems Program Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 U.S. Coal Resources Low rank: lignite and sub-bituminous coal - About 50% of the U.S. coal reserves - Nearly 50% of U.S. coal production - Lower sulfur Bituminous coal

164

Utilization of lightweight materials made from coal gasification slags  

SciTech Connect

The integrated-gasification combined-cycle (IGCC) process is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of as-generated slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, the authors found that it would be extremely difficult for as-generated slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1,400 and 1,700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications.

None

1999-09-30T23:59:59.000Z

165

UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS  

SciTech Connect

The integrated-gasification combined-cycle (IGCC) process is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of ''as-generated'' slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for ''as-generated'' slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 1700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for, various applications. The project goals are to be accomplished in two phases Phase I, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase II, which involves commercial evaluation of these aggregates in a number of applications.

Unknown

2000-04-24T23:59:59.000Z

166

Coal-gasification/MHD/steam-turbine combined-cycle (GMS) power generation  

SciTech Connect

The coal-gasification/MHD/steam-turbine combined cycle (GMS) refers to magnetohydrodynamic (MHD) systems in which coal gasification is used to supply a clean fuel (free of mineral matter and sulfur) for combustion in an MHD electrical power plant. Advantages of a clean-fuel system include the elimination of mineral matter or slag from all components other than the coal gasifier and gas cleanup system; reduced wear and corrosion on components; and increased seed recovery resulting from reduced exposure of seed to mineral matter or slag. Efficiencies in some specific GMS power plants are shown to be higher than for a comparably sized coal-burning MHD power plant. The use of energy from the MHD exhaust gas to gasify coal (rather than the typical approach of burning part of the coal) results in these higher efficiencies.

Lytle, J.M.; Marchant, D.D.

1980-11-01T23:59:59.000Z

167

Investigation of Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal-biomass Catalytic Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics Background The U.S. Department of Energy (DOE) supports research and development efforts targeted to improve efficiency and reduce the negative environmental effects of the use of fossil fuels. One way to achieve these goals is to combine coal with biomass to create synthesis gas (syngas) for use in turbines and refineries to produce energy, fuels,

168

Utilization of lightweight materials made from coal gasification slags  

SciTech Connect

The integrated-gasification combined-cycle (IGCC) process is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of as-generated slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, the authors found that it would be extremely difficult for as-generated slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1,400 and 1,700 F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed by Praxis with funding from the Electric Power Research Institute (EPRI), Illinois Clean Coal Institute (ICCI), and internal resources. The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications. The project goals are to be accomplished in two phases: Phase 1, comprising the production of LWA and ULWA from slag at the large pilot scale, and Phase 2, which involves commercial evaluation of these aggregates in a number of applications. Primary funding for the project is provided by DOE's Federal Energy Technology Center (FETC) at Morgantown, with significant cost sharing by Electric Power Research Institute (EPRI) and Illinois Clean Coal Institute (ICCI).

None

1999-12-30T23:59:59.000Z

169

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

170

advanced-fuels-synthesis-index | netl.doe.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

International Activity Project Information Project Portfolio Publications Coal Gasification Magazine Solicitations The Advanced Fuels Synthesis Key Technology is focused on...

171

Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration  

DOE Patents (OSTI)

Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

1981-09-14T23:59:59.000Z

172

Environmental impact and techno-economic analysis of the coal gasification process with/without CO2 capture  

Science Journals Connector (OSTI)

Abstract Coal gasification, the technology for high-efficient utilization of coal, has been widely used in China. However, it suffers from high CO2 emissions problem due to the carbon-rich character of coal. To reduce CO2 emissions, different CO2 capture technologies are developed and integrated into the coal gasification based processes. However, involving CO2 capture would result in energetic and economic penalty. This paper analyses three cases of coal gasification processes from environmental, technical, and economical points of view. These processes are (1) a conventional coal gasification process; (2) a coal gasification process with CO2 capture and sequestration, in which CO2 is stored by mineral sequestration; (3) a coal gasification process with CO2 capture and utilization, in which CO2 is reused to produce syngas. The results show that the coal gasification process with CO2 capture and sequestration has advantage only in environmental aspect compared to the conventional process. The process with CO2 capture and utilization has advantages in both technical and environmental aspects while disadvantage in economic aspect. However, if the carbon tax higher than 15 USD/t CO2 is introduced, this disadvantage will be negligible.

Yi Man; Siyu Yang; Dong Xiang; Xiuxi Li; Yu Qian

2014-01-01T23:59:59.000Z

173

Entrained-flow dry-bottom gasification of high-ash coals in coal-water slurries  

SciTech Connect

It was shown that the effective use of dry ash removal during entrained-flow gasification of coal-water slurries consists in simplification of the ash storage system and utilization of coal ash, a decrease in the coal demand, a reduction in the atmospheric emissions of noxious substances and particulate matter, and abandonment of the discharge of water used for ash slurry. According to the results of gasification of coal-water slurries (5-10 {mu}m) in a pilot oxygen-blow unit at a carbon conversion of >91%, synthesis gas containing 28.5% CO, 32.5% H{sub 2}, 8.2% CO{sub 2}, 1.5% CH{sub 4}, the rest being nitrogen, was obtained. The fly ash in its chemical composition, particle size, and density meets the requirements of the European standard EN 450 as a cement additive for concrete manufacture.

E.G. Gorlov; V.G. Andrienko; K.B. Nefedov; S.V. Lutsenko; B.K. Nefedov [Institute for Fossil Fuels, Moscow (Russian Federation)

2009-04-15T23:59:59.000Z

174

Advanced Coal Conversion Process Demonstration  

NLE Websites -- All DOE Office Websites (Extended Search)

Clean Coal Technology Program Clean Coal Technology Program Advanced Coal Conversion Process Demonstration A DOE Assessment DOE/NETL-2005/1217 U.S. Department of Energy Office of Fossil Energy National Energy Technology Laboratory April 2005 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name,

175

Structural characteristics and gasification reactivity of chars prepared from K{sub 2}CO{sub 3} mixed HyperCoals and coals  

SciTech Connect

HyperCoal is a clean coal with mineral matter content <0.05 wt %. Oaky Creek (C = 82%), and Pasir (C = 68%) coals were subjected to solvent extraction method to prepare Oaky Creek HyperCoal, and Pasir HyperCoal. Experiments were carried out to compare the gasification reactivity of HyperCoals and parent raw coals with 20, 40, 50 and 60% K{sub 2}CO{sub 3} as a catalyst at 600, 650, 700, and 775{sup o}C with steam. Gasification rates of coals and HyperCoals were strongly influenced by the temperature and catalyst loading. Catalytic steam gasification of HyperCoal chars was found to be chemical reaction controlled in the 600-700{sup o}C temperature range for all catalyst loadings. Gasification rates of HyperCoal chars were found to be always higher than parent coals at any given temperature for all catalyst loadings. However, X-ray diffraction results showed that the microstructures of chars prepared from coals and HyperCoals were similar. Results from nuclear magnetic resonance spectroscopy show no significant difference between the chemical compositions of the chars. Significant differences were observed from scanning electron microscopy images, which showed that the chars from HyperCoals had coral-reef like structures whereas dense chars were observed for coals. 26 refs., 8 figs., 2 tabs.

Atul Sharma; Hiroyuki Kawashima; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

2009-04-15T23:59:59.000Z

176

Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char  

SciTech Connect

In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao [East China University of Science and Technology, Shanghai (China). Department of Chemical Engineering for Energy Resources and Key Laboratory of Coal Gasification of Ministry of Education

2008-11-15T23:59:59.000Z

177

Feasibility study for underground coal gasification at the Krabi Coal Mine site, Thailand. Final report  

SciTech Connect

This study, conducted by Energy and Environmental Research Center, was funded by the U.S Trade and Development Agency. The report summarizes the accomplishments of field, analytical data evaluation and modeling activities focused on assessment of underground coal gasification (UCG) feasibility at Krabi over a two year period. The overall objective of the project was to determine the technical issues, environmental impact, and economic of developing and commercializing UCG at the site in Krabi. The report contains an Executive Summary followed by these chapters: (1) Project Overview; (2) Project Site Characterization; (3) Inorganic and Thermal Materials Characterization; (4) Technical and Economic Feasibility of UCG At the Krabi Site; (5) Conclusions and Recommendations; (6) Acknowledgments; (7) References.

Boysen, J.; Sole, J.; Schmit, C.R.; Harju, J.A.; Young, B.C.

1997-01-01T23:59:59.000Z

178

Air and steam coal partial gasification in an atmospheric fluidized bed  

SciTech Connect

Using the mixture of air and steam as gasification medium, three different rank coal partial gasification studies were carried out in a bench-scale atmospheric fluidized bed with the various operating parameters. The effects of air/coal (Fa/Fc) ratio, steam/coal (Fs/Fc) ratio, bed temperature, and coal rank on the fuel gas compositions and the high heating value (HHV) were reported in this paper. The results show that there is an optimal Fa/Fc ratio and Fs/Fc ratio for coal partial gasification. A rise of bed temperature favors the semigasification reaction of coal, but the concentrations of carbon monoxide and methane and the HHV decrease with the rise of bed temperature, except hydrogen. In addition, the gas HHVs are between 2.2 and 3.4 MJ/Nm{sup 3}. The gas yield and carbon conversion increase with Fa/Fc ratio, Fs/Fc ratio, and bed temperature, while they decrease with the rise of the rank of coal. 7 refs., 9 figs., 2 tabs.

Hongcang Zhou; Baosheng Jing; Zhaoping Zhong; Yaji Huang; Rui Xiao [Nanjing University of Information Science & Technology, Nanjing (China). Department of Environmental Science & Engineering

2005-08-01T23:59:59.000Z

179

Co-gasification of Biomass with Coal and Oil Sand Coke in a Drop Tube Furnace  

Science Journals Connector (OSTI)

From this work, a synergistic effect was observed for blends of coal with petcoke and an increase in the production of H2 and CO was obtained. ... Finally, blending biomass with coal?petcoke blends did not produce any significant change in H2 production, although slight variations were observed in the production of CO and CO2. ... In addn., co-gasification tests of binary blends of a bituminous coal with different types of biomass (up to 10%) and petroleum coke (up to 60%), as well as ternary blends of coal-petcoke-biomass (45-45-10%) were conducted to study the effect of blending on gas prodn. ...

Chen Gao; Farshid Vejahati; Hasan Katalambula; Rajender Gupta

2009-10-13T23:59:59.000Z

180

Production of Middle Caloric Fuel Gas from Coal by Dual-Bed Gasification Technology  

Science Journals Connector (OSTI)

This work demonstrated the dual-bed gasification technology on a pilot plant (1000 tons of coal/a) mainly consisting of a fluidized-bed gasifier and a pneumatic combustor using the coal with a particle size of less than 20 mm. ... It can be seen in Table 1 that the mass fraction of the coal with sizes less than 2.0 mm was about 45 wt %. ... Coal was continuously fed in the gasifier, and meanwhile, air or gas mixture (air and steam) as the fluidizing medium and gasifying reagent was introduced from the bottom of the gasifier. ...

Yin Wang; Wen Dong; Li Dong; Junrong Yue; Shiqiu Gao; Toshiyuki Suda; Guangwen Xu

2010-04-23T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

R&D to Prepare and Characterize Robust Coal/Biomass Mixtures for Direct Co-Feeding into Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

to Prepare and Characterize Robust to Prepare and Characterize Robust Coal/Biomass Mixtures for Direct Co-Feeding into Gasification Background Domestically abundant coal is a significant primary energy source and, when mixed with optimum levels of biomass, has lower carbon footprint compared to conventional petroleum fuels. Coal and biomass mixtures are converted via gasification into synthesis gas (syngas), a mixture of predominantly carbon monoxide and hydrogen, which can be subsequently converted to produce liquid fuels and

182

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

such as synthetic crude gasification combined cycle powerstand-alone integrated gasification combined cycle powertransmission integrated gasification, combined cycle power

Phadke, Amol

2008-01-01T23:59:59.000Z

183

A review of the factors influencing the physicochemical characteristics of underground coal gasification  

SciTech Connect

In this article, the physicochemical characteristics of the oxidation zone, the reduction zone, and the destructive distillation and dry zone in the process of underground coal gasification (UCG) were explained. The effect of such major factors as temperature, coal type, water-inrush or -intake rate, the quantity and quality of wind blasting, the thickness of coal seams, operational pressure, the length, and the section of gasification gallery on the quality of the underground gas and their interrelationship were discussed. Research showed that the temperature conditions determined the underground gas compositions; the appropriate water-inrush or -intake rate was conducive to the improvement in gas heat value; the properties of the gasification agent had an obvious effect on the compositions and heat value of the product gas. Under the cyclically changing pressure, heat losses decreased by 60%, with the heat efficiency and gasification efficiency being 1.4 times and 2 times those of constant pressure, respectively. The test research further proved that the underground gasifier with a long channel and a big cross-section, to a large extent, improved the combustion-gasification conditions.

Yang, L.H. [China University of Mining and Technology, Jiangsu (China)

2008-07-01T23:59:59.000Z

184

NETL: Gasification Systems - Liquid Carbon Dioxide/Coal Slurry for Feeding  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Liquid Carbon Dioxide/Coal Slurry for Feeding Low-Rank Coal to Gasifiers Project Number: DE-FE0007977 There is increased interest in carbon capture and storage (CCS) for future coal-based power plants, and in a CCS integrated gasification plant, relatively pure, high pressure CO2 stream(s) will be available within the power plant. Electric Power Research Institute (EPRI) aims to help reduce the cost and improve the efficiency of integrated gasification combined cycle (IGCC) with CCS by using a portion of the high purity CO2 product stream as the carrier fluid to feed low rank coal (LRC) into the gasifier. EPRI proposes to confirm the potential advantages of LRC/liquid carbon dioxide (LCO2) slurries by: Conducting plant-wide technical and economic simulations.

185

Co-gasification of Biomass and Non-biomass Feedstocks: Synergistic and Inhibition Effects of Switchgrass Mixed with Sub-bituminous Coal and Fluid Coke During CO2 Gasification  

Science Journals Connector (OSTI)

Co-gasification of biomass, namely, switchgrass, with coal and fluid coke was performed to investigate the availability of the gasification catalysts to the mixed feedstock, especially alkali and alkaline earth elements, naturally present on switchgrass. ...

Rozita Habibi; Jan Kopyscinski; Mohammad S. Masnadi; Jill Lam; John R. Grace; Charles A. Mims; Josephine M. Hill

2012-11-21T23:59:59.000Z

186

Catalytic steam gasification reactivity of HyperCoals produced from different rank of coals at 600-775{degree}C  

SciTech Connect

HyperCoal is a clean coal with ash content <0.05 wt %. HyperCoals were prepared from a brown coal, a sub-bituminous coal, and a bituminous raw coal by solvent extraction method. Catalytic steam gasification of these HyperCoals was carried out with K{sub 2}CO{sub 3} at 775, 700, 650, and 600 {degree}C, and their rates were compared. HyperCoals produced from low-rank coals were more reactive than those produced from the high-rank coals. XRD measurements were carried out to understand the difference in gasification reactivity of HyperCoals. Arrhenius plot of ln (k) vs 1/T in the temperature range 600-825{degree}C was a curve rather than a straight line. The point of change was observed at 700{degree}C for HyperCoals from low-rank coals and at 775{degree}C for HyperCoals from high-rank coals. Using HyperCoal produced from low-rank coals as feedstock, steam gasification of coal may be possible at temperatures less than 650{degree}C. 22 refs., 6 figs., 2 tabs.

Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group, Energy Technology Research Institute

2008-11-15T23:59:59.000Z

187

Subtask 4.2 - Coal Gasification Short Course  

SciTech Connect

Major utilities, independent power producers, and petroleum and chemical companies are intent on developing a fleet of gasification plants primarily because of high natural gas prices and the implementation of state carbon standards, with federal standards looming. Currently, many projects are being proposed to utilize gasification technologies to produce a synthesis gas or fuel gas stream for the production of hydrogen, liquid fuels, chemicals, and electricity. Financing these projects is challenging because of the complexity, diverse nature of gasification technologies, and the risk associated with certain applications of the technology. The Energy & Environmental Research Center has developed a gasification short course that is designed to provide technical personnel with a broad understanding of gasification technologies and issues, thus mitigating the real or perceived risk associated with the technology. Based on a review of research literature, tutorial presentations, and Web sites on gasification, a short course presentation was prepared. The presentation, consisting of about 500 PowerPoint slides, provides at least 7 hours of instruction tailored to an audience's interests and needs. The initial short course is scheduled to be presented September 9 and 10, 2009, in Grand Forks, North Dakota.

Kevin Galbreath

2009-06-30T23:59:59.000Z

188

NETL: News Release - Coal Gasification Plant Returns $79 Million to DOE in  

NLE Websites -- All DOE Office Websites (Extended Search)

2, 2006 2, 2006 Coal Gasification Plant Returns $79 Million to DOE in Revenue-Sharing Gas Sales Plant Currently Supplies Carbon Dioxide for DOE Sequestration Project Washington, DC -A coal gasification plant purchased from the U.S. Department of Energy (DOE) in 1988 recently paid millions of dollars to DOE as part of a revenue sharing agreement and continues to be an integral part of a Department project to sequester millions of tons of carbon dioxide while doubling an oil field's recovery rate. MORE INFO Learn more about the Great Plains Synfuels Plant The Dakota Gasification Company (DGC), which purchased the Great Plains Synfuels Plant near Beulah, N.D., recently announced the payment of more than $79 million to DOE as part of a revenue-sharing agreement signed in

189

Development of biological coal gasification (MicGAS Process)  

SciTech Connect

The overall goal of the project is to develop an advanced, clean coal biogasification (MicGAS) Process. The objectives of the research during FY 1993--94 were to: (1) enhance kinetics of methane production (biogasification, biomethanation) from Texas lignite (TxL) by the Mic-1 consortium isolated and developed at ARCTECH, (2) increase coal solids loading, (3) optimize medium composition, and (4) reduce retention time. A closer analysis of the results described here indicate that biomethanation of TxL at >5% solids loading is feasible through appropriate development of nutrient medium and further adaptation of the microorganisms involved in this process. Further understanding of the inhibitory factors and some biochemical manipulations to overcome those inhibitions will hasten the process considerably. Results are discussed on the following: products of biomethanation and enhance of methane production including: bacterial adaptation; effect of nutrient amendment substitutes; effects of solids loading; effect of initial pH of the culture medium; effect of hydrogen donors and carbon balance.

Walia, D.S.; Srivastava, K.C.

1994-10-01T23:59:59.000Z

190

NETL: Gasification Systems - Advanced CO2 Capture Technology for Low-Rank  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced CO2 Capture Technology for Low-Rank Coal IGCC Systems Advanced CO2 Capture Technology for Low-Rank Coal IGCC Systems Project Number: DE-FE0007966 TDA Research, Inc. (TDA) is demonstrating the technical and economic viability of a new Integrated Gasification Combined Cycle (IGCC) power plant designed to efficiently process low-rank coals. The plant uses an integrated carbon dioxide (CO2) scrubber/water gas shift (WGS) catalyst to capture more than 90 percent of the CO2 emissions, while increasing the cost of electricity by less than 10 percent compared to a plant with no carbon capture. TDA is optimizing the sorbent/catalyst and process design, and assessing the efficacy of the integrated WGS catalyst/CO2 capture system, first in bench-scale experiments and then in a slipstream field demonstration using actual coal-derived synthesis gas. The results will feed into a techno-economic analysis to estimate the impact of the WGS catalyst/CO2 capture system on the thermal efficiency of the plant and the cost of electricity.

191

A review of ash in conventional and advanced coal-based power systems  

SciTech Connect

Process conditions are briefly described for conventional and advanced power systems. The advanced systems include both combustion and gasification processes. We discuss problems in coal-based power generation systems, including deposition, agglomeration and sintering of bed materials, and ash attack are discussed. We also discuss methods of mitigating ash problems and anticipated changes anticipated in ash use by converting from conventional to advanced systems.

Holcombe, N.T.

1995-12-31T23:59:59.000Z

192

Integration of coal utilization and environmental control in integrated gasification combined cycle systems  

Science Journals Connector (OSTI)

Integration of coal utilization and environmental control in integrated gasification combined cycle systems ... The Cost of Carbon Capture and Storage for Natural Gas Combined Cycle Power Plants ... The Cost of Carbon Capture and Storage for Natural Gas Combined Cycle Power Plants ...

H. Christopher Frey; Edward S. Rubin

1992-10-01T23:59:59.000Z

193

Studies of the thermal circuit of an advanced integrated gasification combined-cycle power plant  

Science Journals Connector (OSTI)

The results obtained from a study of the thermal circuit of a combined-cycle plant with coal gasification are presented, and ... of producer gas and calculated values of the combined-cycle power plant efficiency ...

D. G. Grigoruk; A. V. Turkin

2010-02-01T23:59:59.000Z

194

Review of underground coal gasification technologies and carbon capture  

Science Journals Connector (OSTI)

It is thought that the world coal reserve is close to 150?years, which only includes recoverable reserves using conventional techniques. Mining is the typical method of extracting coal, but it has been estimat...

Stuart J Self; Bale V Reddy; Marc A Rosen

2012-08-01T23:59:59.000Z

195

Mineral associations in coal and their transformation during gasification  

Science Journals Connector (OSTI)

The principle aim of this investigation was to determine the effect that minerals and mineral associations in dense medium coal fractions have on the ash fusion temperature (AFT) of coal, where the mineral matter...

F. B. Waanders; A. Govender

2005-11-01T23:59:59.000Z

196

Mathematical modelling of some chemical and physical processes in underground coal gasification  

SciTech Connect

Underground coal gasification normally involves two vertical wells which must be linked by a channel having low resistance to gas flow. There are several ways of establishing such linkage, but all leave a relatively open horizontal hole with a diameter on the order of a meter. To increase our understanding of the chemical and physical processes governing underground coal gasification LLNL has been conducting laboratory scale experiments accompanied by mathematical modelling. Blocks of selected coal types are cut to fit 55 gallon oil drums and sealed in place with plaster. A 1 cm. diameter hole is drilled the length of the block and plumbing attached to provide a flow of air or oxygen/steam mixture. After an instrumented burn the block is sawed open to examine the cavity. Mathematical modelling has been directed towards predicting the cavity shape. This paper describes some sub-models and examines their impact on predicted cavity shapes.

Creighton, J. R.

1981-08-01T23:59:59.000Z

197

Hydrogen production by high-temperature steam gasification of biomass and coal  

SciTech Connect

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

198

Product Characterization for Entrained Flow Coal/Biomass Co-Gasification  

SciTech Connect

The U.S. Department of Energy‘s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE‘s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

Maghzi, Shawn; Subramanian, Ramanathan; Rizeq, George; Singh, Surinder; McDermott, John; Eiteneer, Boris; Ladd, David; Vazquez, Arturo; Anderson, Denise; Bates, Noel

2011-09-30T23:59:59.000Z

199

Product Characterization for Entrained Flow Coal/Biomass Co-Gasification  

SciTech Connect

The U.S. Department of Energyâ??s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GEâ??s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

Shawn Maghzi; Ramanathan Subramanian; George Rizeq; Surinder Singh; John McDermott; Boris Eiteneer; David Ladd; Arturo Vazquez; Denise Anderson; Noel Bates

2011-09-30T23:59:59.000Z

200

Underground Gasification: An Alternate Way to Exploit Coal  

Science Journals Connector (OSTI)

...quality of the product gas were pre-dictable...spec-ulate that the cost of gas from the Soviet process...gasification could allow gas to leak out of the chamber...future, and the sole remaining question will be the economics...how it affects marine life are among the most complex...

THOMAs H. MAUGH II

1977-12-16T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Effect of pretreatment and additives on boron release during pyrolysis and gasification of coal  

SciTech Connect

Boron is one of the most toxic and highly volatile elements present in coal. As part of a series of studies carried out on coal cleaning to prevent environmental problems and to promote efficient coal utilization processes, the removal of boron by leaching with water and acetic acid has been investigated. The effects of the addition of ash components, that is, SiO{sub 2}, Al{sub 2}O{sub 3}, and CaO on the control of boron release during pyrolysis and gasification were investigated. Here, 20-70% of boron in coal was removed by leaching the coal with water and acetic acid. Boron leached by water and acetic acid was related to the volatiles released from coal in pyrolysis below 1173 K. The addition of ash components such as SiO{sub 2} and Al{sub 2}O{sub 3} was found to be effective in suppressing the release of boron during pyrolysis at temperatures below and above 1173 K, respectively. The addition of CaO to coal was effective in suppressing the release of boron during gasification at 1173 K. 26 refs., 7 figs., 3 tabs.

Yuuki Mochizuki; Katsuyasu Sugawara; Yukio Enda [Akita University, Akita (Japan). Faculty of Engineering and Resources Science

2009-09-15T23:59:59.000Z

202

Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal  

SciTech Connect

HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

2009-09-15T23:59:59.000Z

203

Subcontracted R and D final report: analysis of samples obtained from GKT gasification test of Kentucky coal. Nonproprietary version  

SciTech Connect

A laboratory test program was performed to obtain detailed compositional data on the Gesellshaft fuer Kohle-Technologie (GKT) gasifier feed and effluent streams. GKT performed pilot gasification tests with Kentucky No. 9 coal and collected various samples which were analyzed by GKT and the Radian Corporation, Austin, Texas. The coal chosen had good liquefaction characteristics and a high gasification reactivity. No organic priority pollutants or PAH compounds were detected in the wash water, and solid waste leachates were within RCRA metals limits.

Raman, S.V.

1983-09-01T23:59:59.000Z

204

Steam gasification of Indonesian subbituminous coal with calcium carbonate as a catalyst raw material  

Science Journals Connector (OSTI)

Abstract The effect of Ca catalysts prepared from CaCO3 on the steam gasification of Indonesian subbituminous coal at 700–800 °C is examined. The char obtained by pyrolyzing the coal with 0.59 wt.% of Ca (dry basis) showed conversions in steam gasification at 750 and 800 °C of around 70 and 90 wt.% (dry ash and catalyst free basis), which were 2 and 1.5 times larger than those of the coal without the Ca catalyst, respectively. The activity of this Ca catalyst was as high as that prepared using an aqueous solution of Ca(OH)2. The TPD and XRD measurements demonstrated that the Ca catalyst from CaCO3 was initially present in the ion-exchanged form, and as a finely dispersed calcium species after pyrolysis. These results confirm that CaCO3 is effective as a catalyst raw material in the steam gasification of subbituminous coal, even at low catalyst loadings.

Kenji Murakami; Masahiko Sato; Naoto Tsubouchi; Yasuo Ohtsuka; Katsuyasu Sugawara

2015-01-01T23:59:59.000Z

205

Fluidised bed co-gasification of coal and olive oil industry wastes  

Science Journals Connector (OSTI)

Co-gasification of bagasse wastes mixed with coal is technically feasible, without major installation changes. The effect of experimental conditions on co-gasification process was analysed, to enhance gas production and improve its composition and energetic content. The rise of bagasse content increased tars and gaseous hydrocarbons contents, which can be reduced by increasing gasification temperature and/or air flow rate. The rise of temperature till 890 °C favoured hydrocarbons further reactions and allowed an increase of 45% in hydrogen release and a decrease in gaseous hydrocarbons of 55%. A reduction of around 30% in gaseous hydrocarbons was also achieved by rising O2/fuel ratio till 0.6 g/g daf, which decreased gas heating value, due to nitrogen diluting effect. Though no significant changes in gaseous hydrocarbons composition were obtained, the presence of dolomite in the fluidised bed had the benefit of decreasing tars content and rising gas yield, being the gas richer in hydrogen content.

Rui Neto André; Filomena Pinto; Carlos Franco; M. Dias; I. Gulyurtlu; M.A.A. Matos; I. Cabrita

2005-01-01T23:59:59.000Z

206

Integrated catalytic coal devolatilization and steam gasification process  

SciTech Connect

Hydrocarbon liquids and a methane-containing gas are produced from carbonaceous feed solids by contacting the solids with a mixture of gases containing carbon monoxide and hydrogen in a devolatilization zone at a relatively low temperature in the presence of a carbon-alkali metal catalyst. The devolatilization zone effluent is treated to condense out hydrocarbon liquids and at least a portion of the remaining methane-rich gas is steam reformed to produce the carbon monoxide and hydrogen with which the carbonaceous feed solids are contacted in the devolatilization zone. The char produced in the devolatilization zone is reacted with steam in a gasification zone under gasification conditions in the presence of a carbon-alkali metal catalyst and the resultant raw product gas is treated to recover a methane-containing gas.

Ryan, D.F.; Wesselhoft, R.D.

1981-09-29T23:59:59.000Z

207

Coal surface control for advanced physical fine coal cleaning technologies  

SciTech Connect

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-01-01T23:59:59.000Z

208

Construction Begins on First-of-its-Kind Advanced Clean Coal Electric  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Construction Begins on First-of-its-Kind Advanced Clean Coal Construction Begins on First-of-its-Kind Advanced Clean Coal Electric Generating Facility Construction Begins on First-of-its-Kind Advanced Clean Coal Electric Generating Facility September 10, 2007 - 3:16pm Addthis ORLANDO, Fla. - Officials representing the U.S. Department of Energy (DOE), Southern Company, KBR Inc. and the Orlando Utilities Commission (OUC) today broke ground to begin construction of an advanced 285-megawatt integrated gasification combined cycle (IGCC) facility near Orlando, Fla. The new generating station will be among the cleanest, most efficient coal-fueled power plants in the world. Southern Company will operate the facility through its Southern Power subsidiary, which builds, owns, and manages the company's competitive generation assets. It will be located at OUC's Stanton Energy Center in

209

Improving process performances in coal gasification for power and synfuel production  

SciTech Connect

This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

2008-11-15T23:59:59.000Z

210

NETL: Gasification Systems - Advanced Virtual Energy Simulation Training  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Virtual Energy Simulation Training And Research (AVESTAR(tm)) Facility Advanced Virtual Energy Simulation Training And Research (AVESTAR(tm)) Facility Project No: Adv Gas-FY131415 Task 6 Developed as a part of NETL's initiative to advance new clean coal technology, the Advanced Virtual Energy Simulation Training And Research (AVESTARTM) Center is focused on training engineers and energy plant operators in the efficient, productive, and safe operation of highly efficient power generation systems that also protect the environment. Comprehensive dynamic simulator-based instruction better prepares operators and engineers to manage advanced energy plants according to economic constraints while minimizing or avoiding the impact of any potentially harmful, wasteful, or inefficient events. Advanced Virtual Energy Simulation Training and Research Center - AVESTAR

211

Wiang Haeng coal-water fuel preparation and gasification, Thailand - task 39  

SciTech Connect

In response to an inquiry by the Department of Mineral Resources (DMR) in Thailand, the Energy & Environmental Research Center (EERC) prepared a four-task program to assess the responsiveness of Wiang Haeng coal to the temperature and pressure conditions of hot-water drying (HWD). The results indicate that HWD made several improvements in the coal, notably increases (HWD). The results indicate that HWD made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 37.4 wt% for the raw coal to about 20 wt% for the HWD coals. The energy density for a pumpable coal-water fuel indicates an increase from 4450 to 6650 Btu/lb by hydrothermal treatment. Raw and HWD coal were then gasified at various mild gasification conditions of 700{degrees}C and 30 psig. The tests indicated that the coal is probably similar to other low-rank coals, will produce high levels of hydrogen, and be fairly reactive.

Anderson, C.M.; Musich, M.A.; Young, B.C. [and others

1996-07-01T23:59:59.000Z

212

In situ formation of coal gasification catalysts from low cost alkali metal salts  

DOE Patents (OSTI)

A carbonaceous material, such as crushed coal, is admixed or impregnated with an inexpensive alkali metal compound, such as sodium chloride, and then pretreated with a stream containing steam at a temperature of 350.degree. to 650.degree. C. to enhance the catalytic activity of the mixture in a subsequent gasification of the mixture. The treatment may result in the transformation of the alkali metal compound into another, more catalytically active, form.

Wood, Bernard J. (Santa Clara, CA); Brittain, Robert D. (Cupertino, CA); Sancier, Kenneth M. (Menlo Park, CA)

1985-01-01T23:59:59.000Z

213

Development of biological coal gasification (MicGAS process); 14th Quarterly report  

SciTech Connect

Reported here is the progress on the Development of Biological Coal Gasification for DOE contract No. DE-AC21-90MC27226 MOD A006. Task 1, NEPA Compliance and Updated Test Plan has been completed. Progress toward Task 2, Enhanced Methane Production, is reported in the areas of bacterial strain improvement, addition of co-substrates, and low cost nutrient amendment. Conclusions reached as a result of this work are presented. Plans for future work are briefly outlined.

NONE

1993-01-28T23:59:59.000Z

214

Gasification Â… Program Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Clearwater Clean Coal Conference, Clearwater, Florida, June 5 to 9, 2011 Gasification Technologies Advances for Future Energy Plants Jenny B. Tennant Technology Manager - Gasification 2 Gasification Program Goal "Federal support of scientific R&D is critical to our economic competitiveness" Dr. Steven Chu, Secretary of Energy November 2010 The goal of the Gasification Program is to reduce the cost of electricity, while increasing power plant availability and efficiency, and maintaining the highest environmental standards 3 Oxygen Membrane - APCI - 25% capital cost reduction - 5.0% COE reduction Warm Gas Cleaning - RTI in combination with H 2 /CO 2 Membrane - Eltron - 2.9 % pt efficiency increase - 12% COE decrease Oxygen CO 2 H 2 rich stream Water Gas Shift*

215

Mineralogical characterization of Sasol feed coals and corresponding gasification ash constituents  

SciTech Connect

Feed coal and coarse ash particles (heated rock fragments and clinkers), produced from Sasol-Lurgi gasifier tests under different operating conditions, have been characterized by quantitative X-ray diffraction, electron microprobe analysis, and associated chemical techniques, as a basis for better understanding of the relations between the mineralogical and physical properties of the ash particles. Crystalline phases in the ashes include quartz particles inherited directly from the feed coal, as well as anorthite, mullite, and diopside, derived from solid-state reactions or crystallization of a silicate melt during the gasification process. Glass, cooled from the melt, is also abundant in the ash materials. The abundance of large particles of hard minerals in the coal or the ash, such as quartz, anorthite, pyrite, and diopside, has been correlated with a laboratory-determined abrasion index and may contribute significantly to wear on mechanical equipment during coal- or ash-handling operations. 21 refs., 3 figs., 9 tabs.

Aivo B. Hlatshwayo; Ratale H. Matjie; Zhongsheng Li; Colin R. Ward [Sasol Technology (Proprietary) Limited, Sasolburg (South Africa)

2009-05-15T23:59:59.000Z

216

Gasification | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Gasification Gasification Gasification The Wabash River Clean Coal Power Plant The Wabash River Clean Coal Power Plant Gasification Technology R&D Coal gasification offers one of the most versatile and clean ways to convert coal into electricity, hydrogen, and other valuable energy products. Coal gasification electric power plants are now operating commercially in the United States and in other nations, and many experts predict that coal gasification will be at the heart of future generations of clean coal technology plants. Rather than burning coal directly, gasification (a thermo-chemical process) breaks down coal - or virtually any carbon-based feedstock - into its basic chemical constituents. In a modern gasifier, coal is typically exposed to steam and carefully controlled amounts of air or oxygen under high

217

Copper-Decorated Hematite as an Oxygen Carrier for in Situ Gasification Chemical Looping Combustion of Coal  

Science Journals Connector (OSTI)

Copper-Decorated Hematite as an Oxygen Carrier for in Situ Gasification Chemical Looping Combustion of Coal ... State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan, 430074 Hubei, People’s Republic of China ... Iron ore is a cheap and nontoxic oxygen carrier in chemical looping combustion (CLC) systems. ...

Weijing Yang; Haibo Zhao; Jinchen Ma; Daofeng Mei; Chuguang Zheng

2014-05-12T23:59:59.000Z

218

Climate VISION: Events - Advanced Clean Coal Workshop  

Office of Scientific and Technical Information (OSTI)

Advanced Clean Coal Workshop Advanced Clean Coal Workshop Objective: Industry and government discussion of key issues and policy options related to deploying clean coal power plants in the marketplace. The following documents are available for download as Adobe PDF documents. Download Acrobat Reader AGENDA July 29, 2004 EEI Conference Center 701 Pennsylvania Avenue, N.W., Washington, DC 8:15 Welcome from Host Thomas Kuhn, President, EEI Opening (Context & Goals) & Introduction Larisa Dobriansky, DOE Kyle McSlarrow, Deputy Secretary, DOE James E. Rogers, Chairman, Cinergy 8:45 Framing the Risks and Challenges for Commercial Clean Coal Plants Results of Risk Framework Analysis, David Berg, DOE (PDF 267 KB) Cost Comparison of IGCC and Advanced Clean Coal Plants, Stu Dalton, EPRI (PDF 684 KB)

219

Effect of CO2 gasification reaction on oxycombustion of pulverized coal char.  

SciTech Connect

For oxy-combustion with flue gas recirculation, as is commonly employed, it is recognized that elevated CO{sub 2} levels affect radiant transport, the heat capacity of the gas, and other gas transport properties. A topic of widespread speculation has concerned the effect of the CO{sub 2} gasification reaction with coal char on the char burning rate. To give clarity to the likely impact of this reaction on the oxy-fuel combustion of pulverized coal char, the Surface Kinetics in Porous Particles (SKIPPY) code was employed for a range of potential CO{sub 2} reaction rates for a high-volatile bituminous coal char particle (130 {micro}m diameter) reacting in several O{sub 2} concentration environments. The effects of boundary layer chemistry are also examined in this analysis. Under oxygen-enriched conditions, boundary layer reactions (converting CO to CO{sub 2}, with concomitant heat release) are shown to increase the char particle temperature and burning rate, while decreasing the O{sub 2} concentration at the particle surface. The CO{sub 2} gasification reaction acts to reduce the char particle temperature (because of the reaction endothermicity) and thereby reduces the rate of char oxidation. Interestingly, the presence of the CO{sub 2} gasification reaction increases the char conversion rate for combustion at low O{sub 2} concentrations, but decreases char conversion for combustion at high O{sub 2} concentrations. These calculations give new insight into the complexity of the effects from the CO{sub 2} gasification reaction and should help improve the understanding of experimentally measured oxy-fuel char combustion and burnout trends in the literature.

Molina, Alejandro (Universidad Nacional de Colombia, Medellin, Colombia); Hecht, Ethan S.; Shaddix, Christopher R.; Haynes, Brian S. (University of Sydney, New South Wales, Australia)

2010-07-01T23:59:59.000Z

220

Hydrogen Production by Catalytic Gasification of Coal in Supercritical Water  

Science Journals Connector (OSTI)

(2) However, the extensive utilization of coal leads to many problems, such as air pollution and resource waste, because of the inefficient and unclean utilization method. ... Argon would sink to the bottom of the reactor, and air would come up because of the difference in density between these two gases. ...

Rihua Lan; Hui Jin; Liejin Guo; Zhiwei Ge; Simao Guo; Ximin Zhang

2014-10-16T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

An evaluation of Substitute natural gas production from different coal gasification processes based on modeling  

Science Journals Connector (OSTI)

Coal and lignite will play a significant role in the future energy production. However, the technical options for the reduction of CO2 emissions will define the extent of their share in the future energy mix. The production of synthetic or substitute natural gas (SNG) from solid fossil fuels seems to be a very attractive process: coal and lignite can be upgraded into a methane rich gas which can be transported and further used in high efficient power systems coupled with CO2 sequestration technologies. The aim of this paper is to present a modeling analysis comparison between substitute natural gas production from coal by means of allothermal steam gasification and autothermal oxygen gasification. In order to produce SNG from syngas several unit operations are required such as syngas cooling, cleaning, potential compression and, of course, methanation reactors. Finally the gas which is produced has to be conditioned i.e. removal of unwanted species, such as CO2 etc. The heat recovered from the overall process is utilized by a steam cycle, producing power. These processes were modeled with the computer software IPSEpro™. An energetic and exergetic analysis of the coal to SNG processes have been realized and compared.

S. Karellas; K.D. Panopoulos; G. Panousis; A. Rigas; J. Karl; E. Kakaras

2012-01-01T23:59:59.000Z

222

Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems  

SciTech Connect

Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we analyzed several coated and exposed samples of 409 steel by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX), and report on the findings of four samples: (1) Analysis of two porous coupons after exposure to the porous metal particulate filter of the coal gasification power plant at 370 C for 2140 hours revealed that corrosion takes place in the bulk of the sample while the most external zone surface survived the test. (2) Coating and characterization of several porous 409 steel coupons after being coated with nitrides of Ti, Al and/or Si showed that adjusting experimental conditions results in thicker coatings in the bulk of the sample. (3) Analysis of coupons exposed to simulated coal gas at 370 C for 300 hours showed that a better corrosion resistance is achieved by improving the coatings in the bulk of the samples.

Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez-Mariano; Angel Sanjurjo

2006-12-31T23:59:59.000Z

223

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

advanced coal-wind hybrid combined cycle power plant naturalwhen the wind generation drops, the power plant needs toa CSP plant, a wind plant produces power during all hours of

Phadke, Amol

2008-01-01T23:59:59.000Z

224

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

G+CC+CCS IGCC+CCS FT HVAC HVDC IGCC PC advanced coal-windthan the Base Case (HVDC Only Transmission) Sensitivity toused in the FEAST model. HVDC transmission lines have lower

Phadke, Amol

2008-01-01T23:59:59.000Z

225

Hanna, Wyoming underground coal gasification data base. Volume 3. The Hanna II, Phase I field test  

SciTech Connect

This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project, and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. Hanna II, Phase I was conducted during the spring and summer of 1975, at a site about 700 feet up dip (to the southwest) of the Hanna I test. The test was conducted in two stages - Phase IA and IB. Phase IA consisted of linking and gasification operations between Wells 1 and 3 and Phase IB of linking from the 1-3 gasification zone to Well 2, followed by a short period of gasification from Well 2 to Well 3 over a broad range of air injection rates, in order to determine system turndown capabilities and response times. This report covers: (1) site selection and characteristics; (2) test objectives; (3) facilities description; (4) pre-operational testing; (5) test operations summary; and (6) post-test activity. 7 refs., 11 figs., 8 tabs.

Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

1985-08-01T23:59:59.000Z

226

Coal surface control for advanced fine coal flotation  

SciTech Connect

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

1992-03-01T23:59:59.000Z

227

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-06-01T23:59:59.000Z

228

Advanced power systems featuring a closely coupled catalytic gasification carbonate fuel cell plant  

SciTech Connect

Pursuing the key national goal of clean and efficient uulization of the abundant domestic coal resources for power generation, a study was conducted with DOE/METC support to evaluate the potential of integrated gasification/carbonate fuel cell power generation systems. By closely coupling the fuel cell with the operation of a catalytic gasifier, the advantages of both the catalytic gasification and the high efficiency fuel cell complement each other, resulting in a power plant system with unsurpassed efficiencies approaching 55% (HHV). Low temperature catalytic gasification producing a high methane fuel gas offers the potential for high gas efficiencies by operating with minimal or no combustion. Heat required for gasification is provided by combination of recycle from the fuel cell and exothermic methanation and shift reactions. Air can be supplemented if required. In combination with internally reforming carbonate fuel cells, low temperature catalytic gasification can achieve very attractive system efficiencies while producing extremely low emissions compared to conventional plants utilizing coal. Three system configurations based on recoverable and disposable gasification catalysts were studied. Experimental tests were conducted to evaluate these gasification catalysts. The recoverable catalyst studied was potassium carbonate, and the disposable catalysts were calcium in the form of limestone and iron in the form of taconite. Reactivities of limestone and iron were lower than that of potassium, but were improved by using the catalyst in solution form. Promising results were obtained in the system evaluations as well as the experimental testing of the gasification catalysts. To realize the potential of these high efficiency power plant systems more effort is required to develop catalytic gasification systems and their integration with carbonate fuel cells.

Steinfeld, G.; Wilson, W.G.

1993-01-01T23:59:59.000Z

229

Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems  

SciTech Connect

Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. The primary activity this period was preparation and presentation of the findings on this project at the Twenty-Third annual Pittsburgh Coal Conference. Dr. Malhotra attended this conference and presented a paper. A copy of his presentation constitutes this quarterly report.

Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez Mariano; Angel Sanjurjo

2006-09-30T23:59:59.000Z

230

Storing syngas lowers the carbon price for profitable coal gasification  

SciTech Connect

Integrated gasification combined cycle (IGCC) electric power generation systems with carbon capture and sequestration have desirable environmental qualities but are not profitable when the carbon dioxide price is less than approximately $50 per metric ton. We examine whether an IGCC facility that operates its gasifier continuously but stores the syngas and produces electricity only when daily prices are high may be profitable at significantly lower CO{sub 2} prices. Using a probabilistic analysis, we have calculated the plant-level return on investment (ROI) and the value of syngas storage for IGCC facilities located in the U.S. Midwest using a range of storage configurations. Adding a second turbine to use the stored syngas to generate electricity at peak hours and implementing 12 h of above-ground high-pressure syngas storage significantly increases the ROI and net present value. Storage lowers the carbon price at which IGCC enters the U.S. generation mix by approximately 25%. 36 refs., 7 figs., 1 tab.

Adam Newcomer; Jay Apt [Carnegie Mellon University, Pittsburgh, PA (USA). Carnegie Mellon Electricity Industry Center

2007-12-15T23:59:59.000Z

231

TRW advanced slagging coal combustor utility demonstration  

SciTech Connect

The TRW Advanced Entrained Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/oil unit to fire 2.5% sulfur coal. The slagging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Environmental Standards. The TRW-Utility Demonstration Unit (UDU) is responsible for the implementation of program policies and overall direction of the project. The following projects will be carried out: process and design development of clean coal technology CCT-1 the development and operation of the entrained coal combustor will enable the boiler to burn low and medium sulfur coal while meeting all the Federal/State emission requirements; demonstrate sulfur dioxide emissions control by pulverized limestone injection into the entrained coal combustor system.

Not Available

1990-01-01T23:59:59.000Z

232

DOE Pens New Agreement with Southern Company to Test Advanced Carbon-Capture & Gasification Technologies  

Energy.gov (U.S. Department of Energy (DOE))

The U.S. Department of Energy has signed a new 5-year cooperative agreement with Southern Company to evaluate advanced carbon-capture and gasification technologies at the National Carbon Capture Center (NCCC) in Wilsonville, Ala.

233

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifier: Commercial Gasifiers Gasifier: Commercial Gasifiers Gasifiers and Impact of Coal Rank and Coal Properties The available commercial gasification technologies are often optimized for a particular rank of coal or coal properties, and in some cases, certain ranks of coal might be unsuitable for utilization in a given gasification technology. On the other hand, there is considerable flexibility in most of the common gasifiers; this is highlighted by the following table, which provides an overview of the level of experience for the various commercially available gasifiers by manufacturer for each coal type. This experience will only continue to expand as more gasification facilities come online and more demonstrations are completed. SOLID FUEL GASIFICATION EXPERIENCE1 High Ash Coals

234

Low-rank coal research  

SciTech Connect

This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

Not Available

1989-01-01T23:59:59.000Z

235

NETL: Gasification Systems - Advanced Acid Gas Separation Technology for  

NLE Websites -- All DOE Office Websites (Extended Search)

Feed Systems Feed Systems Advanced Acid Gas Separation Technology for the Utilization of Low-Rank Coals Project Number: DE-FE0007759 Refinery offgas PSA at Air Products' facility in Baytown, TX Refinery offgas PSA at Air Products' facility in Baytown, TX. Air Products, in collaboration with the University of North Dakota Energy and Environmental Research Center (EERC), is testing its Sour Pressure Swing Adsorption (Sour PSA) process that separates syngas into an hydrogen-rich stream and second stream comprising of sulfur compounds(primarily hydrogen sulfide)carbon dioxide (CO2), and other impurities. The adsorbent technology testing that has been performed to date utilized syngas streams derived from higher rank coals and petcoke. Using data from experiments based on petcoke-derived syngas, replacing the

236

Upgrading of low-rank coals for conventional and advanced combustion systems  

SciTech Connect

Low-rank coals, subbituminous, lignitic, and brown coals, have a ubiquitous presence in the world, being found in all continents. Close to half of the world`s estimated coal resources are low- rank coals. Many countries have no alternative economic source of energy. In the lower 48 states of the United States, there are 220 billion tons of economically recoverable reserves of lignite and subbituminous coal. Add to this quantity 5 trillion tons of predominantly subbituminous coal in Alaska, and the combined amount represents the largest supply of the lowest-cost fuels available for generating electric power in the United States. However, to use these coals cost-effectively and in an environmentally acceptable way, it is imperative that their properties and combustion/gasification behavior be well understood. The Energy and Environmental Research Center (EERC) takes a cradle-to-grave approach (i.e., mining, precleaning, combustion/gasification, postcleaning, and reuse and disposal of residues) for all aspects of coal processing and utilization. The environmental impact of these activities must be matched with the appropriate technologies. Experience over many years has shown that variations in coal and ash properties have a critical impact on design, reliability and efficiency of operation, and environmental compliance when low-rank coals are burned in conventional systems. This chapter reviews the significant technical issues of beneficiation, which includes reduction in moisture as well as ash (including sulfur), in relation to low-rank coal properties and their impact on conventional and advanced power systems. Finally, the development and utilization of low-rank coal resources are briefly discussed in view of policy, economic, and strategic issues.

Young, B.C.; Musich, M.A.; Jones, M.L.

1993-12-31T23:59:59.000Z

237

Field study of disposed solid wastes from advanced coal processes  

SciTech Connect

Radian Corporation and the North Dakota Energy and Environmental Research Center (EERC) are funded to develop information to be used by private industry and government agencies for managing solid waste produced by advanced coal processes. This information will be developed by conducting several field studies on disposed wastes from these processes. Data will be collected to characterize these wastes and their interactions with the environments in which they are disposed. Three sites have been selected for the field studies: Colorado Ute's fluidized bed combustion (FBC) unit in Nucla, Colorado; Ohio Edison's limestone injection multistage burner (LIMB) retrofit in Lorain, Ohio; and Freeman United's site using waste from Midwest Grain's FBC unit in central Illinois. A fourth site is under consideration at the Dakota Gasification Company in North Dakota. The first two tasks of this project involved the development of test plans and obtaining site access.

Not Available

1990-01-01T23:59:59.000Z

238

Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal  

SciTech Connect

The purpose of this project was to evaluate the ability of advanced low rank coal gasification technology to cause a significant reduction in the COE for IGCC power plants with 90% carbon capture and sequestration compared with the COE for similarly configured IGCC plants using conventional low rank coal gasification technology. GE’s advanced low rank coal gasification technology uses the Posimetric Feed System, a new dry coal feed system based on GE’s proprietary Posimetric Feeder. In order to demonstrate the performance and economic benefits of the Posimetric Feeder in lowering the cost of low rank coal-fired IGCC power with carbon capture, two case studies were completed. In the Base Case, the gasifier was fed a dilute slurry of Montana Rosebud PRB coal using GE’s conventional slurry feed system. In the Advanced Technology Case, the slurry feed system was replaced with the Posimetric Feed system. The process configurations of both cases were kept the same, to the extent possible, in order to highlight the benefit of substituting the Posimetric Feed System for the slurry feed system.

Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri, John; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Liber, Pawel; Lopez-Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

2012-03-30T23:59:59.000Z

239

Coal surface control for advanced fine coal flotation  

SciTech Connect

The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

1990-08-15T23:59:59.000Z

240

Future Impacts of Coal Distribution Constraints on Coal Cost  

E-Print Network (OSTI)

coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

McCollum, David L

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Techno-economic analysis of coal gasification based co-production systems  

Science Journals Connector (OSTI)

Abstract Coal gasification based co-production systems are increasing popular in the world because they are assumed to be advantageous in energy efficiency and economic cost. However, there has been seldom researches on quantifying these advantages. In this paper, the co-prouction systems are analyzed from the technical and ecnomic point of views. During the study, the co-production system, of which the products are electricity and methanol, is modeled and simulated. For analysis, the energy analysis model and the economy analysis model are established. Results show that the co-production system has higher energy efficiency and less capital expenditure than tranditional single production systems.

Siyu Yang; Hengchong Li; Yu Qian

2012-01-01T23:59:59.000Z

242

Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass  

SciTech Connect

The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO{sub 2} underground represents negative CO{sub 2} emissions if the biomass is grown sustainably (i.e., if one ton of new biomass growth replaces each ton consumed), and this offsets positive CO{sub 2} emissions associated with the coal used in these systems. Different coal:biomass input ratios will produce different net lifecycle greenhouse gas (GHG) emissions for these systems, which is the reason that attention in our analysis was given to the impact of the biomass input fraction. In the case of systems that produce only products with no carbon content, namely electricity, ammonia and hydrogen, only coal was considered as a feedstock because it is possible in theory to essentially fully decarbonize such products by capturing all of the coal-derived CO{sub 2} during the production process.

Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

2012-03-11T23:59:59.000Z

243

High-Pressure Gasification of Coal Water Ethanol Slurry in an Entrained Flow Gasifier for Bioethanol Application  

Science Journals Connector (OSTI)

In comparison to CWS gasification, gasification with CWES showed a higher performance, such as composition of hydrogen and carbon monoxide, carbon conversion, cold gas efficiency, and total flow rate of syngas. ... As for the preparation of CWS and CWES, viscosity of 2000 cP or under was maintained while maintaining the maximum coal content, so that the coal particles could be atomized when the slurry was injected into the burner. ... The gasifier was preheated to approximately 1100 °C using a LPG burner, and after feeding CWS or CWES into the gasifier, syngas starts to be produced, whereby pressurization proceeds. ...

Jong-Soo Bae; Dong-Wook Lee; Se-Joon Park; Young-Joo Lee; Jai-Chang Hong; Ho Won Ra; Choon Han; Young-Chan Choi

2012-08-10T23:59:59.000Z

244

Modeling and simulation of co-gasification of coal and petcoke in a bubbling fluidized bed coal gasifier  

Science Journals Connector (OSTI)

In this work we discuss the modeling and simulation of a fluidized bed coal gasifier which uses a mixture of coal and petcoke as its feed. A two phase model consisting of the bubble phase and the emulsion phase is used to describe the coal gasification process. We consider a non-isothermal model taking into account the effect of four heterogeneous reactions and four homogeneous reactions. We analyse the effect of various operating parameters such as composition of feed, location of feed point and ash content on the performance of the gasifier. The results of predictions of the simulations have been found to be in good agreement with the experimental results in the literature. It has been found that increase in petcoke content in the feed mixture tends to lower the efficiency and carbon conversion but increases the amount of syngas produced. Also, from the simulations, it has been found that increase in ash content of coal decreases the carbon conversion. We have concluded that the feed point of the solids should be above the point where O2 that is present in the bed gets exhausted, in order to obtain the maximum carbon conversion and efficiency.

Anshul Goyal; S. Pushpavanam; Ravi Kumar Voolapalli

2010-01-01T23:59:59.000Z

245

A feasibility study for underground coal gasification at Krabi Mine, Thailand  

SciTech Connect

A study to evaluate the technical, economical, and environmental feasibility of underground coal gasification (UCG) in the Krabi Mine, Thailand, was conducted by the Energy and Environmental Research Center (EERC) in cooperation with B.C. Technologies (BCT) and the Electricity Generating Authority of Thailand (EGAT). The selected coal resource was found suitable to fuel a UCG facility producing 460,000 MJ/h (436 million Btu/h) of 100--125 Btu/scf gas for 20 years. The raw UCG gas could be produced for a selling price of $1.94/MMBtu. The UCG facility would require a total investment of $13.8 million for installed capital equipment, and annual operating expenses for the facility would be $7.0 million. The UCG gas could be either cofired in a power plant currently under construction or power a 40 MW simple-cycle gas turbine or a 60 MW combined-cycle power plant.

Solc, J.; Steadman, E.N. [Energy and Environmental Research Center, Grand Forks, ND (United States); Boysen, J.E. [BC Technologies, Laramie, WY (United States)

1998-12-31T23:59:59.000Z

246

NETL: Gasification Project Information  

NLE Websites -- All DOE Office Websites (Extended Search)

Project Information Project Information Gasification Systems Reference Shelf - Project Information Active Projects | Archived Projects | All NETL Fact Sheets Feed Systems A Cost-Effective Oxygen Separation System Based on Open Gradient Magnetic Field by Polymer Beads [SC0010151] Development of ITM Oxygen Technology for Low-cost and Low-emission Gasification and Other Industrial Applications [FE0012065] Dry Solids Pump Coal Feed Technology [FE0012062] Coal-CO2 Slurry Feeding System for Pressurized Gasifiers [FE0012500] National Carbon Capture Center at the Power Systems Development Facility [FE0000749] Modification of the Developmental Pressure Decoupled Advanced Coal (PDAC) Feeder [NT0000749] Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems [DE-FC26-98FT40343]

247

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

1987-01-01T23:59:59.000Z

248

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Ghate, M.R.; Yang, R.T.

1985-10-03T23:59:59.000Z

249

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect

This patent describes the method for bulk separation of multi-component gases generated in a coal gasification process wherein coal is gasified in a gasifier to produce gasification products including a mixture of gases comprising hydrogen, carbon monoxide, methane, and acid gas components carbon dioxide and hydrogen sulfide. It consists of the steps of conveying a stream comprising the mixture of gases into one end of an elongated column containing a solid adsorbent for each of the gases forming the mixture of gases and pressurizing the charge of gases within the column to a pressure within a range sufficient to effect the adsorption by the adsorbent of the conveyed gases including the hydrogen defining the least absorbable gas in the mixture of gases. Then, decreasing the partial pressure of the charge of gases in the column to effect the sequential desorption of the gases hydrogen, carbon monoxide, and methane from the adsorbent in the column, and conveying the adsorbed gases from the column upon desorption thereof from the adsorbent.

Ghate, M.H.; Yang, R.T.

1987-09-29T23:59:59.000Z

250

Advanced Gasification Mercury/Trace Metal Control With Monolith Traps  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Technologies Gasification Technologies CONTACTS Jenny Tennant Technology/Project Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880, Morgantown, WV 26507-0880 304-285-4830 jenny.tennant@netl.doe.gov Michael Swanson Principal Investigator University of North Dakota Energy and Environmental Research Center 15 North 23rd Street Grand Forks, ND 58202 701-777-5239 MSwanson@undeerc.org PARTNERS Corning, Inc. PROJECT DURATION

251

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

SciTech Connect

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

2013-08-01T23:59:59.000Z

252

Advanced direct coal liquefaction concepts  

SciTech Connect

During the first quarter of FY 1993, the Project proceeded close to the Project Plan. The analysis of the feed material has been completed as far as possible. Some unplanned distillation was needed to correct the boiling range of the Black Thunder solvent used during the autoclave tests. Additional distillation will be required if the same solvent is to be used for the bench unit tests. A decision on this is still outstanding. The solvent to be used with Illinois No. 6 coal has not yet been defined. As a result, the procurement of the feed and the feed analysis is somewhat behind schedule. Agglomeration tests with Black Thunder coal indicates that small agglomerates can be formed. However, the ash removal is quite low (about 10%), which is not surprising in view of the low ash content of the coal. The first series of autoclave tests with Black Thunder coal was completed as planned. Also, additional runs are in progress as repeats of previous runs or at different operating conditions based on the data obtained so far. The results are promising indicating that almost complete solubilization (close to 90%) of Black Thunder coal can be achieved in a CO/H[sub 2]O environment at our anticipated process conditions. The design of the bench unit has been completed. In contrast to the originally planned modifications, the bench unit is now designed based on a computerized control and data acquisition system. All major items of equipment have been received, and prefabrication of assemblies and control panels is proceeding on schedule. Despite a slight delay in the erection of the structural steel, it is anticipated that the bench unit will be operational at the beginning of April 1993.

Berger, D.J.; Parker, R.J.; Simpson, P.L. (Canadian Energy Development, Inc., Edmonton, AB (Canada))

1992-01-01T23:59:59.000Z

253

Geotechnical/geochemical characterization of advanced coal process waste streams: Task 2  

SciTech Connect

Successful disposal practices for solid wastes produced from advanced coal combustion and coal conversion processes must provide for efficient management of relatively large volumes of wastes in a cost-effective and environmentally safe manner. At present, most coal-utilization solid wastes are disposed of using various types of land-based systems, and it is probable that this disposal mode will continue to be widely used in the future for advanced process wastes. Proper design and operation of land-based disposal systems for coal combustion wastes normally require appropriate waste transfer, storage, and conditioning subsystems at the plant to prepare the waste for transport to an ultimate disposal site. Further, the overall waste management plan should include a by-product marketing program to minimize the amount of waste that will require disposal. In order to properly design and operate waste management systems for advanced coal-utilization processes, a fundamental understanding of the physical properties, chemical and mineral compositions, and leaching behaviors of the wastes is required. In order to gain information about the wastes produced by advanced coal-utilization processes, 55 waste samples from 16 different coal gasification, fluidized-bed coal combustion (FBC), and advanced flue gas scrubbing processes were collected. Thirty-four of these wastes were analyzed for their bulk chemical and mineral compositions and tested for a detailed set of disposal-related physical properties. The results of these waste characterizations are presented in this report. In addition to the waste characterization data, this report contains a discussion of potentially useful waste management practices for advanced coal utilization processes.

Moretti, C.J.; Olson, E.S.

1992-09-01T23:59:59.000Z

254

2007 gasification technologies workshop papers  

SciTech Connect

Topics covered in this workshop are fundamentals of gasification, carbon capture, reviews of financial and regulatory incentives, coal to liquids, and focus on gasification in the Western US.

NONE

2007-03-15T23:59:59.000Z

255

Is Integrated Gasification Combined Cycle with Carbon Capture-Storage the Solution for Conventional Coal Power Plants  

E-Print Network (OSTI)

Engineering Management Field Project Is Integrated Gasification Combined Cycle with Carbon Capture-Storage the Solution for Conventional Coal Power Plants By Manish Kundi Fall Semester, 2011 An EMGT Field Project report... 2.4 Environmental Aspects-Emissions 23 3.0 Procedure & Methodology 3.1 Working technology – Conventional Coal Plants 30 3.2 Working technology – IGCC Power Plants 32 3.3 Carbon Capture and Storage 35 3...

Kundi, Manish

2011-12-16T23:59:59.000Z

256

Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process  

SciTech Connect

Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

2012-01-01T23:59:59.000Z

257

Computational Fluid Dynamics (cfd) Modeling of a Laboratory Scale Coal Gasifier.  

E-Print Network (OSTI)

?? Furthering gasification technology is an essential part of advancing clean coal technologies. In order to seek insight into the appropriate operations for the formation… (more)

Schultheiss, Kiel S

2013-01-01T23:59:59.000Z

258

Feasibility study for underground coal gasification at the Krabi coal mine site, Thailand: Volume 1. Progress report, December 1--31, 1995; Export trade information  

SciTech Connect

The report, conducted by Energy and Environmental Research Center, was funded by the US Trade and Development Agency. The objective of this report was to determine the technical, environmental and economic feasibility of developing, demonstrating, and commercializing underground coal gasification (UCG) at the Krabi coal mine site in Southern Thailand. This is Volume 1, the Progress Report for the period December 1, 1995, through December 31, 1995.

Young, B.C.; Schmit, C.R.

1996-01-01T23:59:59.000Z

259

Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems  

SciTech Connect

Advanced electric power generation systems use a coal gasifier to convert coal to a gas rich in fuels such as H{sub 2} and CO. The gas stream contains impurities such as H{sub 2}S and HCl, which attack metal components of the coal gas train, causing plant downtime and increasing the cost of power generation. Corrosion-resistant coatings would improve plant availability and decrease maintenance costs, thus allowing the environmentally superior integrated-gasification-combined-cycle (IGCC) plants to be more competitive with standard power-generation technologies. Heat-exchangers, particle filters, turbines, and other components in the IGCC system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low cost alloy will improve is resistance to such sulfidation attack and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. The Fe- and Ni-based high-temperature alloys are susceptible to sulfidation attack unless they are fortified with high levels of Cr, Al, and Si. To impart corrosion resistance, these elements need not be in the bulk of the alloy and need only be present at the surface layers. In this study, the use of corrosion-resistant coatings on low alloy steels was investigated for use as high-temperature components in IGCC systems. The coatings were deposited using SRI's fluidized-bed reactor chemical vapor deposition technique. Diffusion coatings of Cr and Al were deposited by this method on to dense and porous, low alloy stainless steel substrates. Bench-scale exposure tests at 900 C with a simulated coal gas stream containing 1.7% H{sub 2}S showed that the low alloy steels such SS405 and SS409 coated with {approx}20%Cr and Al each can be resistant to sulfidation attack for 500 h. However, exposure to an actual coal gasifier gas stream at the Wabash River gasifier facility for 1000 h in the temperature range 900 to 950 C indicated that Cr and Al present in the coating diffused further into the substrate decreasing the protective ability of these elements against attack by H{sub 2}S. Similarly, adherent multilayer coatings containing Si, Ti, Al, and Nb were also deposited with subsequent nitridation of these elements to increase the corrosion resistance. Both dense and porous SS409 or SS 410 alloy substrates were coated by using this method. Multilayer coatings containing Ti-Al-Si nitrides along with a diffusion barrier of Nb were deposited on SS410 and they were found also to be resistant to sulfidation attack in the bench scale tests at 900 C. However, they were corroded during exposure to the actual coal gasifier stream at the Wabash River gasifier facility for 1000 h. The Cr/Al coatings deposited inside a porous substrate was found to be resistant to sulfidation attack in the bench-scale simulated tests at 370 C. The long-term exposure test at the Wabash River gasifier facility at 370 C for 2100 h showed that only a minor sulfidation attack occurred inside the porous SS 409 alloy coupons that contained Cr and Al diffusion coatings. This attack can be prevented by improving the coating process to deposit uniform coatings at the interior of the porous structure. It is recommended that additional studies be initiated to optimize the FBR-CVD process to deposit diffusion coatings of the corrosion resistant elements such as Cr, Al, and Ti inside porous metal filters to increase their corrosion resistance. Long-term exposure tests using an actual gas stream from an operating gasifier need to be conducted to determine the suitability of the coatings for use in the gasifier environment.

Gopala N. Krishnan; Ripudaman Malhotra; Jordi Perez; Marc Hornbostel; Kai-Hung Lau; Angel Sanjurjo

2007-05-31T23:59:59.000Z

260

Feasibility studies of in-situ coal gasification in the Warrior coal field. Quarterly report  

SciTech Connect

Studies in support of in-situ gasification involved experiments in bench-scale combustors where three parameters were varied independently: initial fuel bed temperature, applied air flow and water vapor influx rate. Methods for measuring the thermal conductivity of solids at high temperatures were evaluated and measurements of the thermal conductivity and thermal diffusivity were made over a temperature range for several samples of coke. (LTN)

Douglas G.W.; McKinley, M.D.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Low/medium-Btu coal-gasification-assessment program for potential users in New Jersey. Final report  

SciTech Connect

Burns and Roe Industrial Services Corporation and Public Service Electric and Gas in association with Scientific Design Company have completed a technical and economic evaluation of coal gasification. The evaluation also addressed the regulatory, institutional, and environmental issues of coal gasification. Two uses of coal-derived medium Btu (MBU) gas were explored: (1) substitute boiler fuel for electric generation and (2) substitute fuel for industrial customers using natural gas. The summary and conclusions of his evaluation are: The Sewaren Generating Station was selected as potentially the most suitable site for the coal gasification plant. The Texaco process was selected because it offered the best combination of efficiency and pilot plant experience; in addition, it is a pressurized process which is advantageous if gas is to be supplied to industrial customers via a pipeline. Several large industrial gas customers within the vicinities of Sewaren and Hudson Generating Stations indicated that MBG would be considered as an alternate fuel provided that its use was economically justified. The capital cost estimates for a 2000 tons/day and a 1000 tons/day gasification plant installed at Sewaren Generating Station are $115.6 million and $73.8 million, in 1980 dollars, respectively. The cost of supplying MBG to industrial customers is competitive with existing pipeline natural gas on a Btu heating value basis for gasifier capacity factors of 35% or higher.

Not Available

1981-05-01T23:59:59.000Z

262

NETL: Gasification Systems Video, Images & Photos  

NLE Websites -- All DOE Office Websites (Extended Search)

Video, Images, Photos Video, Images, Photos Gasification Systems Reference Shelf - Video, Images & Photos The following was established to show a variety of Gasification Technologies: Gasfication powerplant photo Gasification: A Cornerstone Technology (Mar 2008) Movie Icon Windows Media Video (WMV-26MB) [ view | download ] NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants. Proposed APS Advanced Hydrogasification Process Proposed APS Advanced Hydrogasification Process* TRDU and Hot-Gas Vessel in the EERC Gasification Tower Transport reactor development unit

263

2007 gasification technologies conference papers  

SciTech Connect

Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

NONE

2007-07-01T23:59:59.000Z

264

Measurement and modeling of advanced coal conversion processes, Volume I, Part 1. Final report, September 1986--September 1993  

SciTech Connect

The objective of this program was the development of a predictive capability for the design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. The foundation to describe coal specific conversion behavior was AFR`s Functional Group and Devolatilization, Vaporization and Crosslinking (DVC) models, which had been previously developed. The combined FG-DVC model was integrated with BYU`s comprehensive two-dimensional reactor model for combustion and coal gasification, PCGC-2, and a one-dimensional model for fixed-bed gasifiers, FBED-1. Progress utilizing these models is described.

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

1995-09-01T23:59:59.000Z

265

ADVANCED GASIFICATION NETL Team Technical Coordinator: James Bennett  

NLE Websites -- All DOE Office Websites (Extended Search)

GASIFICATION NETL Team Technical Coordinator: James Bennett GASIFICATION NETL Team Technical Coordinator: James Bennett Name Project Role Affiliation University Project Title Bhattacharyya, Debangsu CO-PI WVU Turton, Richard CO-PI WVU Jones, Dustin Grad Student WVU Weiland, Nathan PI WVU C3M Kinetic Development Baseline Co-Gasification Kinetics Support Turton, Richard PI WVU Chaudhari, Kiran Grad Student WVU Pisupati, Sarma PI PSU Devolatilization and Char Kinetics Support Song, Xueyan PI WVU Different Gasifier Liner Wear Support Song, Xueyan PI WVU High Vanadium Oxide Study Support Musser, Jordan PI WVU Implement Heat & Mass Transfer to MFIX-PIC Support Dietiker, Jean- Francois PI WVU MFIX Development Verification and Validation Support Kuhlman, John PI WVU Model Development Support Weiland, Nathan PI WVU Bedick, Clinton Researcher

266

Eight Advanced Coal Projects Chosen for Further Development by DOE's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Eight Advanced Coal Projects Chosen for Further Development by Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program July 5, 2011 - 1:00pm Addthis Washington, DC - The Department of Energy has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and use and will help propel technologies for future advanced coal power systems. The selections will conduct investigations in three topic areas -- computational energy sciences, material science, and sensors and controls -- and will be funded at a maximum of $300,000 for 36 months. The Office of Fossil Energy's National Energy Technology Laboratory (NETL) will manage

267

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

Coal Prices..AEO 2007 forecast for coal prices for PRB coal. Transmissionregimes. Sensitivity to Coal Prices Figure 9 is similar to

Phadke, Amol

2008-01-01T23:59:59.000Z

268

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal: Alternatives/Supplements to Coal - Feedstock Flexibility Coal: Alternatives/Supplements to Coal - Feedstock Flexibility As important as coal is as a primary gasification feedstock, gasification technology offers the important ability to take a wide range of feedstocks and process them into syngas, from which a similarly diverse number of end products are possible. Gasifiers have been developed to suit all different ranks of coal, and other fossil fuels, petcoke and refinery streams, biomass including agricultural waste, and industrial and municipal waste. The flexibility stems from the ability of gasification to take any carbon and hydrogen containing feedstock and then thermochemically break down the feedstock to a gas containing simple compounds which are easy to process into several marketable products.

269

Seven Projects Aimed at Advancing Coal Research Selected for DOE's  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Seven Projects Aimed at Advancing Coal Research Selected for DOE's Seven Projects Aimed at Advancing Coal Research Selected for DOE's University Coal Research Program Seven Projects Aimed at Advancing Coal Research Selected for DOE's University Coal Research Program May 13, 2010 - 1:00pm Addthis Washington, DC -- Seven projects aimed at advancing coal research and development while providing research exposure to a new generation of scientists and engineers have been selected to participate in the U.S. Department of Energy's (DOE) University Coal Research (UCR) program. The projects aim to improve the basic understanding of the chemical and physical processes that govern coal conversion and utilization, by-product utilization, and technological development for advanced energy systems. These advanced systems -- efficient, ultra-clean energy plants -- are

270

Advances in pulverized coal combustion  

SciTech Connect

A combustion system has been developed to operate cost effectively in the difficult regulatory and economic climate of the 1980's. The system is designed to reduce auxiliary fuel oil comsumption by at least 30% while meeting all relevant emissions limits. This is achieved with the fewest components consistent with practical reliable design criteria. The Controlled Flow Split/Flame low NO/sub x/ burner, MBF pulverizer and Two-Stage ignition system are integrated into a mutually supporting system which is applicable to both new steam generators and, on a retrofit basis, to existing units. In the future, a pulverized coal ignition system will be available to eliminate fuel oil use within the boiler.

Vatsky, J.

1981-01-01T23:59:59.000Z

271

Advances in mathematical modeling of fluidized bed gasification  

Science Journals Connector (OSTI)

Abstract Gasification is the thermochemical conversion of solid fuel into the gas which contains mainly hydrogen, carbon monoxide, carbon dioxide, methane and nitrogen. In gasification, fluidized bed technology is widely used due to its various advantageous features which include high heat transfer, uniform and controllable temperature and favorable gas–solid contacting. Modeling and simulation of fluidized bed gasification is useful for optimizing the gasifier design and operation with minimal temporal and financial cost. The present work investigates the different modeling approaches applied to the fluidized bed gasification systems. These models are broadly classified as the equilibrium model and the rate based or kinetic model. On the other hand, depending on the description of the hydrodynamic of the bed, fluidized bed models may also be classified as the two-phase flow model, the Euler–Euler model and the Euler–Lagrange model. Mathematical formulation of each of the model mentioned above and their merits and demerits are discussed. Detail reviews of different model used by different researchers with major results obtained by them are presented while the special focus is given on Euler–Euler and Euler–Lagrange CFD models.

Chanchal Loha; Sai Gu; Juray De Wilde; Pinakeswar Mahanta; Pradip K. Chatterjee

2014-01-01T23:59:59.000Z

272

Co-gasification of coal–petcoke and biomass in the Puertollano IGCC power plant  

Science Journals Connector (OSTI)

Abstract Integrated Gasification Combined Cycle plants (IGCC) are efficient power generation systems with low pollutants emissions. Moreover, the entrained flow gasifier of IGCC plants allows the combined use of other lower cost fuels (biomass and waste) together with coal. Co-firing with biomass is beneficial for the reduction of CO2 emissions of fossil source. In this paper the results of co-gasification tests with two types of biomass deriving from agricultural residues, namely 2% and 4% by weight of olive husk and grape seed meal, in the 335 MWeISO IGCC power plant of ELCOGAS in Puertollano (Spain) are reported. No significant change in the composition of both the raw syngas and the clean syngas was observed. Furthermore, a process simulation model of the IGCC plant of Puertollano was developed and validated with available industrial data. The model was used to assess the technical and economic feasibility of the process co-fired with higher biomass contents up to 60% by weight. The results indicate that a 54% decrease of fossil CO2 emissions implies an energy penalty (a loss of net power) of about 20% while does not cause significant change of the net efficiency of the plant. The mitigation cost (the additional cost of electricity per avoided ton of CO2) is significantly dependent on the price of the biomass cost compared to the price of the fossil fuel.

Daniele Sofia; Pilar Coca Llano; Aristide Giuliano; Mariola Iborra Hernández; Francisco García Peña; Diego Barletta

2014-01-01T23:59:59.000Z

273

Assessment of modular IGCC plants based on entrained flow coal gasification supplemental studies  

SciTech Connect

In a previous study (1), Foster Wheeler made an assessment of modular IGCC power systems employing Texaco entrained flow gasification of Illinois No. 6 coal. In that study, five case studies were developed in order to compare the relative performance and economics of air vs. oxygen blown gasification and high temperature vs. low temperature gas cleanup. As a supplemental study, two additional IGCC design cases were developed as alternate to the original Case 2 and Case 3 configurations. The objective of the Case 2 alternate study was to assess the potential of zinc titanate in place of zinc ferrite. Compared to zinc ferrite, the zinc titanate system offered the following potential advantages: Does not require steam conditioning of the feed gas to avoid carbon formation; does not require reductive regeneration and the corresponding use of fuel gas; operates at higher temperature, about 1350{degree}F; and has a longer projected sorbent life. The objective of the alternate Case 3 study was to determine the economic impact of producing sulfuric acid, instead of elemental sulfur, as the by-product from high temperature desulfurization using zinc ferrite. Sulfur recovery as by-product sulfuric acid therefore offered the potential for reducing both the capital and operating costs. 6 refs., 5 figs., 15 tabs.

Fu, R.K.

1989-10-01T23:59:59.000Z

274

DOEIJEA-1219 ENVIRONMENTAL ASSESSMENT HOE CREEK UNDERGROUND COAL GASIFICATION TEST SITE REMEDIATION  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOEIJEA-1219 DOEIJEA-1219 ENVIRONMENTAL ASSESSMENT HOE CREEK UNDERGROUND COAL GASIFICATION TEST SITE REMEDIATION CAMPBELL COUNTY, WYOMING October 1997 U.S. DEPARTMENT OF ENERGY FEDERAL ENERGY TECHNOLOGY CENTER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or use- fulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any spe- cific commercial product, process. or service by trade name, trademark, manufac-

275

DOE/NETL-2002/1164 Wabash River Coal Gasification Repowering Project: A DOE Assessment  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 Wabash River Coal Gasification Repowering Project: A DOE Assessment January 2002 U.S. Department of Energy National Energy Technology Laboratory P.O. Box 880, 3610 Collins Ferry Road Morgantown, WV 26507-0880 and P.O. Box 10940, 626 Cochrans Mill Road Pittsburgh, PA 15236-0940 website: www.netl.doe.gov 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference

276

Stabilization of spent sorbents from coal gasification. Final technical report, September 1, 1992--August 31, 1993  

SciTech Connect

The objective of this investigation was to determine the rates of reactions involving partially sulfided dolomite and oxygen, which is needed for the design of the reactor system for the stabilization of sulfide-containing solid wastes from gasification of high sulfur coals. To achieve this objective, samples of partially sulfided dolomite were reacted with oxygen at a variety of operating conditions in a fluidized-bed reactor. The effect of external diffusion was eliminated by using small quantities of the sorbent and maintaining a high flow rate of the reactant gas. The reacted sorbents were analyzed to determine the extent of conversion as a function of operating variables including sorbent particle size, reaction temperature and pressure, and oxygen concentration. The results of sulfation tests indicate that the rate of reaction increases with increasing temperature, increasing oxygen partial pressure, and decreasing sorbent particle size. The rate of the sulfation reaction can be described by a diffuse interface model where both chemical reaction and intraparticle diffusion control the reaction rate. The kinetic model of the sulfation reaction was used to determine the requirements for the reactor system, i.e., reactor size and operating conditions, for successful stabilization of sulfide-containing solid wastes from gasification of high sulfur coals (with in-bed desulfurization using calcium based sorbents). The results indicate that the rate of reaction is fast enough to allow essentially complete sulfation in reactors with acceptable dimensions. The optimum sulfation temperature appears to be around 800{degrees}C for high pressure as well as atmospheric stabilization of the spent sorbents.

Abbasian, J.; Hill, A.H.; Rue, D.M.; Wangerow, J.R. [Institute of Gas Technology, Chicago, IL (United States)

1993-12-31T23:59:59.000Z

277

Environmental assessment for the Hoe Creek underground, Coal Gasification Test Site Remediation, Campbell County, Wyoming  

SciTech Connect

The U.S. Department of Energy (DOE) has prepared this EA to assess environmental and human health Issues and to determine potential impacts associated with the proposed Hoe Creek Underground Coal Gasification Test Site Remediation that would be performed at the Hoe Creek site in Campbell County, Wyoming. The Hoe Creek site is located south-southwest of the town of Gillette, Wyoming, and encompasses 71 acres of public land under the stewardship of the Bureau of Land Management. The proposed action identified in the EA is for the DOE to perform air sparging with bioremediation at the Hoe Creek site to remove contaminants resulting from underground coal gasification (UCG) experiments performed there by the DOE in the late 1970s. The proposed action would involve drilling additional wells at two of the UCG test sites to apply oxygen or hydrogen peroxide to the subsurface to volatilize benzene dissolved in the groundwater and enhance bioremediation of non-aqueous phase liquids present in the subsurface. Other alternatives considered are site excavation to remove contaminants, continuation of the annual pump and treat actions that have been used at the site over the last ten years to limit contaminant migration, and the no action alternative. Issues examined in detail in the EA are air quality, geology, human health and safety, noise, soils, solid and hazardous waste, threatened and endangered species, vegetation, water resources, and wildlife. Details of mitigative measures that could be used to limit any detrimental effects resulting from the proposed action or any of the alternatives are discussed, and information on anticipated effects identified by other government agencies is provided.

NONE

1997-10-01T23:59:59.000Z

278

Kinetics Of Carbon Gasification  

Science Journals Connector (OSTI)

Kinetics Of Carbon Gasification ... The steam–carbon reaction, which is the essential reaction of the gasification processes of carbon-based feed stocks (e.g., coal and biomass), produces synthesis gas (H2 + CO), a synthetically flexible, environmentally benign energy source. ... Coal Gasification in CO2 and Steam:? Development of a Steam Injection Facility for High-Pressure Wire-Mesh Reactors ...

C. W. Zielke; Everett. Gorin

1957-03-01T23:59:59.000Z

279

Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process  

SciTech Connect

Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300°C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm² degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm² degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

2012-09-15T23:59:59.000Z

280

DOE Selects Nine New University Coal Research Projects to Advance Coal-Based Power  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Selects Nine New University Coal Research Projects to Advance Coal-Based Power Selects Nine New University Coal Research Projects to Advance Coal-Based Power Systems Nine new projects selected by the U.S. Department of Energy (DOE) under the University Coal Research program will seek long-term solutions for the clean and efficient use of our nation's abundant coal resources. The announcement today of the selections marks the 34 th round of the Department's longest-running coal program, which began in 1979. This research continues DOE efforts to improve the understanding of the chemical and physical processes governing coal conversion and utilization, and support the technological development of the advanced coal power systems of the future. These advanced systems include ultra-clean

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Energy recovery from solid waste fuels using advanced gasification technology  

SciTech Connect

Since the mid-1980s, TPS Termiska Processer AB has been working on the development of an atmospheric-pressure gasification process. A major aim at the start of this work was the generation of fuel gas from indigenous fuels to Sweden (i.e. biomass). As the economic climate changed and awareness of the damage to the environment caused by the use of fossil fuels in power generation equipment increased, the aim of the development work at TPS was changed to applying the process to heat and power generation from feedstocks such as biomass and solid wastes. Compared with modern waste incineration with heat recovery, the gasification process will permit an increase in electricity output of up to 50%. The gasification process being developed is based on an atmospheric-pressure circulating fluidized bed gasifier coupled to a tar-cracking vessel. The gas produced from this process is then cooled and cleaned in conventional equipment. The energy-rich gas produced is clean enough to be fired in a gas boiler without requiring extensive flue gas cleaning, as is normally required in conventional waste incineration plants. Producing clean fuel gas in this manner, which facilitates the use of efficient gas-fired boilers, means that overall plant electrical efficiencies of close to 30% can be achieved. TPS has performed a considerable amount of pilot plant testing on waste fuels in their gasification/gas cleaning pilot plant in Sweden. Two gasifiers of TPS design have been in operation in Greve-in-Chianti, italy since 1992. This plant processes 200 tonnes of RDF (refuse-derived fuel) per day.

Morris, M.; Waldheim, L. [TPS Termiska Processer AB, Nykoeping (Sweden)] [TPS Termiska Processer AB, Nykoeping (Sweden)

1998-12-31T23:59:59.000Z

282

Low-Btu coal gasification in the United States: company topical. [Brick producers  

SciTech Connect

Hazelton and other brick producers have proved the reliability of the commercial size Wellman-Galusha gasifier. For this energy intensive business, gas cost is the major portion of the product cost. Costs required Webster/Hazelton to go back to the old, reliable alternative energy of low Btu gasification when the natural gas supply started to be curtailed and prices escalated. Although anthracite coal prices have skyrocketed from $34/ton (1979) to over $71.50/ton (1981) because of high demand (local as well as export) and rising labor costs, the delivered natural gas cost, which reached $3.90 to 4.20/million Btu in the Hazelton area during 1981, has allowed the producer gas from the gasifier at Webster Brick to remain competitive. The low Btu gas cost (at the escalated coal price) is estimated to be $4/million Btu. In addition to producing gas that is cost competitive with natural gas at the Webster Brick Hazelton plant, Webster has the security of knowing that its gas supply will be constant. Improvements in brick business and projected deregulation of the natural gas price may yield additional, attractive cost benefits to Webster Brick through the use of low Btu gas from these gasifiers. Also, use of hot raw gas (that requires no tar or sulfur removal) keeps the overall process efficiency high. 25 references, 47 figures, 14 tables.

Boesch, L.P.; Hylton, B.G.; Bhatt, C.S.

1983-07-01T23:59:59.000Z

283

Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems  

SciTech Connect

Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period, we conducted two 300-hour tests. In the first test, we exposed samples at 900 C under conditions simulating the high-temperature heat recovery unit (HTHRU). The second test was at 370 C, corresponding to the filter units following the HTHRU. The tests were showed the resilience of silicon nitride as a coating component, and the new coating procedures better penetrated the pores in sintered metal filter samples. Finally, we also received samples that were exposed in the Wabash River plant. Unfortunately, all these samples, that were prepared last year, were severely eroded and/or corroded.

Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Jordi Perez-Mariano; Angel Sanjurjo

2005-03-15T23:59:59.000Z

284

Novel hydrogen separation device development for coal gasification system applications. Final report  

SciTech Connect

This study was undertaken for the development of a novel Electrochemical Hydrogen Separator (EHS) technology for low-cost hydrogen separation from coal derived gases. Design and operating parameter testing was performed using subscale cells (25 cm{sup 2}). High H{sub 2} purity, >99% is one of the main features of the EHS. It was found that N{sub 2}, CO{sub 2} and CH{sub 4} behave as equivalent inerts; EHS performance is not affected by the balance of feed gas containing these components. This product purity level is not sacrificed by increased H{sub 2} recovery. CO, however, does adversely affect EHS performance and therefore feed stream pretreatment is recommended. Low levels of H{sub 2}S and NH{sub 3} were added to the feed gas stream and it was verified that these impurities did not affect EHS performance. Task 2 demonstrated the scale-up to full size multi-cell module operation while maintaining a stable energy requirement. A 10-cell full-size module (1050 cm{sup 2} cell active area) was operated for over 3,800 hours and gave a stable baseline performance. Several applications for the EHS were investigated. The most economically attractive systems incorporating an EHS contain low pressure, dilute hydrogen streams, such as coal gasification carbonate fuel cell systems, hydrogen plant purification and fluid catalytic cracker units. In addition, secondary hydrogen recovery from PSA or membrane tailstreams using an EHS may increase overall system efficiency.

Not Available

1993-08-01T23:59:59.000Z

285

Current Gasification Research  

Energy.gov (U.S. Department of Energy (DOE))

With coal gasification now in modern commercial-scale applications, the U.S. Department of Energy's (DOE) Office of Fossil Energy has turned its attention to future gasification concepts that offer...

286

LWA demonstration applications using Illinois coal gasification slag: Phase II. Technical report, 1 March--31 May 1994  

SciTech Connect

The major objective of this project is to demonstrate the suitability of using ultra-lightweight aggregates (ULWA) produced by thermal expansion of solid residues (slag) generated during the gasification of Illinois coals as substitutes for conventional aggregates, which are typically produced by pyroprocessing of perlite ores. To meet this objective, expanded slag aggregates produced from an Illinois coal slag feed in Phase I will be subjected to characterization and applications-oriented testing. Target applications include the following: aggregates in precast products (blocks and rooftiles); construction aggregates (loose fill insulation and insulating concrete); and other applications as identified from evaluation of expanded slag properties. The production of value-added products from slag is aimed at eliminating a solid waste and possibly enhancing the overall economics of the gasification process, especially when the avoided costs of disposal are taken into consideration.

Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States); Steck, P. [Harvey Cement Products, Inc. (United States)

1994-09-01T23:59:59.000Z

287

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/this operational mode, the gasifiers and other parts of the

Phadke, Amol

2008-01-01T23:59:59.000Z

288

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

Phadke, Amol

2008-01-01T23:59:59.000Z

289

NETL: Gasification Archived Projects  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Home > Technologies > Coal & Power Systems > Gasification Systems > Reference Shelf > Archived Projects Gasification Systems Reference Shelf - Archived Projects Archived Projects | Active Projects | All NETL Fact Sheets Feed Systems Reaction-Driven Ion Transport Membranes Gasifier Optimization and Plant Supporting Systems Coal/Biomass Gasification at Colorado School of Mines Co-Production of Electricity and Hydrogen Using a Novel Iron-Based Catalyst Co-Production of Substitute Natural Gas/Electricity via Catalytic Coal Gasification Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals Hybrid Combustion-Gasification Chemical Looping Coal Power Technology Development

290

DOE's Advanced Coal Research, Development, and Demonstration Program to  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE's Advanced Coal Research, Development, and Demonstration DOE's Advanced Coal Research, Development, and Demonstration Program to Develop Low-carbon Emission Coal Technologies DOE's Advanced Coal Research, Development, and Demonstration Program to Develop Low-carbon Emission Coal Technologies March 11, 2009 - 3:18pm Addthis Statement of Victor K. Der, Acting Assistant Secretary, Office of Fossil Energy before the Subcommittee on Energy and Environment, Committee on Science and Technology, U.S. House of Representatives. Thank you, Mr. Chairman and Members of the Committee. I appreciate this opportunity to provide testimony on the U.S. Department of Energy's (DOE's) advanced coal research, development, and demonstration program to develop low-carbon emission coal technologies. Introduction Fossil fuel resources represent a tremendous national asset. An abundance

291

DOE's Advanced Coal Research, Development, and Demonstration Program to  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Advanced Coal Research, Development, and Demonstration Advanced Coal Research, Development, and Demonstration Program to Develop Low-carbon Emission Coal Technologies DOE's Advanced Coal Research, Development, and Demonstration Program to Develop Low-carbon Emission Coal Technologies March 11, 2009 - 3:18pm Addthis Statement of Victor K. Der, Acting Assistant Secretary, Office of Fossil Energy before the Subcommittee on Energy and Environment, Committee on Science and Technology, U.S. House of Representatives. Thank you, Mr. Chairman and Members of the Committee. I appreciate this opportunity to provide testimony on the U.S. Department of Energy's (DOE's) advanced coal research, development, and demonstration program to develop low-carbon emission coal technologies. Introduction Fossil fuel resources represent a tremendous national asset. An abundance

292

Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research  

SciTech Connect

Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

Not Available

1992-01-01T23:59:59.000Z

293

An analysis of cost effective incentives for initial commercial deployment of advanced clean coal technologies  

SciTech Connect

This analysis evaluates the incentives necessary to introduce commercial scale Advanced Clean Coal Technologies, specifically Integrated Coal Gasification Combined Cycle (ICGCC) and Pressurized Fluidized Bed Combustion (PFBC) powerplants. The incentives required to support the initial introduction of these systems are based on competitive busbar electricity costs with natural gas fired combined cycle powerplants, in baseload service. A federal government price guarantee program for up to 10 Advanced Clean Coal Technology powerplants, 5 each ICGCC and PFBC systems is recommended in order to establish the commercial viability of these systems by 2010. By utilizing a decreasing incentives approach as the technologies mature (plants 1--5 of each type), and considering the additional federal government benefits of these plants versus natural gas fired combined cycle powerplants, federal government net financial exposure is minimized. Annual net incentive outlays of approximately 150 million annually over a 20 year period could be necessary. Based on increased demand for Advanced Clean Coal Technologies beyond 2010, the federal government would be revenue neutral within 10 years of the incentives program completion.

Spencer, D.F. [SIMTECHE, Half Moon Bay, CA (United States)

1997-12-31T23:59:59.000Z

294

Changes in char structure during the gasification of a Victorian brown coal in steam and oxygen at 800{degree}C  

SciTech Connect

Char structure is an important factor influencing its reactivity during gasification. This study aims to investigate the changes in char structure during the gasification of brown coal. A Victorian brown coal was gasified in a fluidized-bed/fixed-bed reactor at 800{degree}C in atmospheres containing 15% H{sub 2}O, 2000 ppm O{sub 2}, or 15% H{sub 2}O and 2000 ppm O{sub 2}, respectively. Although the char gasification in 2000 ppm O{sub 2} was mainly rate-limited by the external diffusion of O{sub 2}, the char-H{sub 2}O reaction was mainly rate-limited by the chemical reactions. The structural features of char at different levels of char gasification conversion were examined with FT-Raman spectroscopy. Our results show that the chars from the gasification in the mixture of 2000 ppm O{sub 2} and 15% H{sub 2}O had almost the same features as the chars from the gasification in 15% H{sub 2}O alone when the same levels of char conversion were achieved. Both the thermal decomposition of char and the char gasification reactions could result in changes in char structure during gasification. 29 refs., 5 figs., 1 tab.

Xin Guo; Hui Ling Tay; Shu Zhang; Chun-Zhu Li [Monash University, Vic. (Australia). Department of Chemical Engineering

2008-11-15T23:59:59.000Z

295

E-Print Network 3.0 - advanced multi-product coal Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced... Hydrogen from Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U... 12;Presentation Outline Hydrogen Initiatives Hydrogen from Coal ......

296

E-Print Network 3.0 - advanced coal utilization Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced... Hydrogen from Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U... 12;Presentation Outline Hydrogen Initiatives Hydrogen from Coal ......

297

Pioneering Gasification Plants | Department of Energy  

Energy Savers (EERE)

lighting street lights fueled by "town gas," frequently the product of early forms of coal gasification. Gasification of fuel also provided fuel for steel mills, and toward the...

298

Revised users manual, Pulverized Coal Gasification or Combustion: 2-dimensional (87-PCGC-2): Final report, Volume 2. [87-PCGC-2  

SciTech Connect

A two-dimensional, steady-state model for describing a variety of reactive and non-reactive flows, including pulverized coal combustion and gasification, is presented. Recent code revisions and additions are described. The model, referred to as 87-PCGC-2, is applicable to cylindrical axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using either a flux method or discrete ordinates method. The particle phase is modeled in a Lagrangian framework, such that mean paths of particle groups are followed. Several multi-step coal devolatilization schemes are included along with a heterogeneous reaction scheme that allows for both diffusion and chemical reaction. Major gas-phase reactions are modeled assuming local instantaneous equilibrium, and thus the reaction rates are limited by the turbulent rate mixing. A NO/sub x/ finite rate chemistry submodel is included which integrates chemical kinetics and the statistics of the turbulence. The gas phase is described by elliptic partial differential equations that are solved by an iterative line-by-line technique. Under-relaxation is used to achieve numerical stability. The generalized nature of the model allows for calculation of isothermal fluid mechanicsgaseous combustion, droplet combustion, particulate combustion and various mixtures of the above, including combustion of coal-water and coal-oil slurries. Both combustion and gasification environments are permissible. User information and theory are presented, along with sample problems. 106 refs.

Smith, P.J.; Smoot, L.D.; Brewster, B.S.

1987-12-01T23:59:59.000Z

299

DEVELOPMENT OF NOVEL SPINEL REFRACTORIES FOR USE IN COAL GASIFICATION ENVIRONMENTS  

SciTech Connect

Work has been performed by Oak Ridge National Laboratory (ORNL), in collaboration with industrial refractory manufacturer (Minteq International, Inc.), academic research partner (Missouri University of Science and Technology) and end users to employ novel refractory systems and techniques to reduce energy consumption of refractory lined vessels found in industries such as aluminum, chemical, glass, and pulp and paper. The objective of the project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3 spinel structured unshaped refractory compositions (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. As part of the four-year project funded by the U.S. Department of Energy (DOE), materials have been developed specifically for coal gasification environments. Additionally, work has been performed to develop and apply low cost coatings using a colloidal approach for protection against corrosion attack of the refractory brick and to develop a light-weight back-up refractory system to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the development of these materials, along with preliminary results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment.

Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

2011-01-01T23:59:59.000Z

300

SPINEL-BASED REFRACTORIES FOR IMPROVED PERFORMANCE IN COAL GASIFICATION ENVIRONMENTS  

SciTech Connect

Oak Ridge National Laboratory, in collaboration with refractory manufacturer Minteq International, Inc., academic partner Missouri University of Science and Technology and refractory end users have developed novel refractory systems and techniques to reduce energy consumption of refractory lined vessels. The objective of this U.S. DOE funded project was to address the need for innovative refractory compositions by developing MgO-Al 2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Materials have been developed specifically for coal gasification environments and work has been performed to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the service environment and to develop a light-weight back-up refractory system to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the systematic development of these materials, laboratory testing and evaluation of these materials, and relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Refractory Materials based on Magnesia-Alumina Spinel for Improved Performance in Coal Gasification Environments  

SciTech Connect

As part of a larger project to develop novel refractory systems and techniques to reduce energy consumption of refractory lined vessels, a team composed of Oak Ridge National Laboratory, refractory manufacturer Minteq International, Inc., and academic partner Missouri University of Science and Technology have developed new refractory materials and coating systems specifically for application in coal gasification environments. Materials were developed under this U.S. DOE funded project to address the need for innovative refractory compositions by developing MgO-Al2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Work was conducted to develop and deploy these new materials and to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the serviced environment. Additionally, a light-weight back-up refractory system was developed to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the efforts involved in the development of these materials, along with the laboratory testing and evaluation of these materials leading to relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

2013-01-01T23:59:59.000Z

302

NETL: News Release -Eight Advanced Coal Projects Chosen for Further  

NLE Websites -- All DOE Office Websites (Extended Search)

5, 2011 5, 2011 Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program Washington, D.C. - The Department of Energy has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and use and will help propel technologies for future advanced coal power systems. The selections will conduct investigations in three topic areas - computational energy sciences, material science, and sensors and controls - and will be funded at a maximum of $300,000 for 36 months. The Office of Fossil Energy's National Energy Technology Laboratory (NETL) will manage the projects, which include ultra-clean energy plants that could co-produce electric power, fuels, chemicals and other high-value products from coal with near-zero emissions and substantial increases in efficiency.

303

Biological removal of organic constituents in quench water from a slagging, fixed-bed coal-gasification pilot plant  

SciTech Connect

This study is part of an effort to assess the efficiency of activated-sludge treatment for removal of organic constituents from high-Btu coal-gasification pilot-plant quench waters. A sample of raw-gas quench water was obtained from the Grand Forks Energy and Technology Center's pilot plant, which employs the slagging, fixed-bed gasification process. The quench water generated in the processing of Indian Head lignite was pretreated to reduce ammonia and alkalinity, and then diluted and subjected to long-term biological treatment, followed by detailed characterization and analysis of organic constituents. The pretreated (influent) and treated (effluent) samples were extracted using a methylene chloride, pH-fractionation method to obtain acid, base, and neutral fractions, which were analyzed by capillary-column gas chromatography/mass spectrometry (GC/MS). Over 99% of the total extractable and chromatographable organic material in the influent acid fraction was composed of phenol and alkylated phenols. Biological treatment removed these compounds almost completely. Major components of the influent base fraction were alkylated pyridines, anilines, aminopyrroles, imidazoles and/or pyrazoles, diazines, and quinolines. Removal efficiency of these compounds ranged between 90 and 100%. The influent neutral fraction was composed mainly of cycloalkanes, cycloalkenes, naphthalene, indole, acetophenone, and benzonitrile. Alkylated benzenes were generally absent. Removal efficiencies of these compounds were generally very good, except for certain alkylated cycloalkanes and cycloalkenes. Results are compared with those of a similar study on HYGAS coal-gasification quench water.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

304

NETL: News Release - Seven Projects Aimed at Advancing Coal Research  

NLE Websites -- All DOE Office Websites (Extended Search)

May 13, 2010 May 13, 2010 Seven Projects Aimed at Advancing Coal Research Selected for DOE's University Coal Research Program Department's Longest Running Student-Teacher Initiative Provides Research Exposure for Future Scientists and Engineers Washington, D.C. - Seven projects aimed at advancing coal research and development while providing research exposure to a new generation of scientists and engineers have been selected to participate in the U.S. Department of Energy's (DOE) University Coal Research (UCR) program. The projects aim to improve the basic understanding of the chemical and physical processes that govern coal conversion and utilization, by-product utilization, and technological development for advanced energy systems. These advanced systems - efficient, ultra-clean energy plants - are envisioned to co-produce electric power, fuels, chemicals and other high-value products from coal with near-zero emissions, including greenhouse gases such as carbon dioxide.

305

A Brief Review of Viscosity Models for Slag in Coal Gasification  

SciTech Connect

Many researchers have defined the phenomenon of 'slagging' as the deposition of ash in the radiative section of a boiler, while 'fouling' refers to the deposition of ash in the convective-pass region. Among the important parameters affecting ash deposition that need to be studied are ash chemistry, its transport, deposit growth, and strength development; removability of the ash deposit; heat transfer mechanisms; and the mode of operation for boilers. The heat transfer at the walls of a combustor depends on many parameters including ash deposition. This depends on the processes or parameters controlling the impact efficiency and the sticking efficiency. For a slagging combustor or furnace, however, the temperatures are so high that much of the coal particles are melted and the molten layer, in turn, captures more particles as it flows. The main problems with ash deposition are reduced heat transfer in the boiler and corrosion of the tubes. Common ways of dealing with these issues are soot blowing and wall blowing on a routine basis; however, unexpected or uncontrolled depositions can also complicate the situation, and there are always locations inaccessible to the use of such techniques. Studies have indicated that slag viscosity must be within a certain range of temperatures for tapping and the membrane wall to be accessible, for example, between 1300 C and 1500 C, the viscosity is approximately 25 Pa {center_dot} s. As the operating temperature decreases, the slag cools and solid crystals begin to form. In such cases the slag should be regarded as a non-Newtonian suspension, consisting of liquid silicate and crystals. A better understanding of the rheological properties of the slag, such as yield stress and shear-thinning, are critical in determining the optimum operating conditions. To develop an accurate heat transfer model in any type of coal combustion or gasification process, the heat transfer and to some extent the rheological properties of ash and slag, especially in high-temperature environments need to be understood and properly modeled. The viscosity of slag and the thermal conductivity of ash deposits are among two of the most important constitutive parameters that need to be studied. The accurate formulation or representations of the (transport) properties of coal (and biomass for co-firing cases) present a special challenge of modeling efforts in computational fluid dynamics applications. In this report, we first provide a brief review of the various approaches taken by different researchers in formulating or obtaining a slag viscosity model. In general, these models are based on experiments. Since slag behaves as a non-linear fluid, we discuss the constitutive modeling of slag and the important parameters that must be studied.

Massoudi, Mehrdad; Wang, Ping

2011-11-01T23:59:59.000Z

306

Image analysis measurements of particle coefficient of restitution for coal gasification applications  

SciTech Connect

New robust Lagrangian computational fluid dynamic (CFD) models are powerful tools that can be used to study the behavior of a diverse population of coal particle sizes, densities, and mineral compositions in entrained gasifiers. By using this approach, the responses of the particles impacting the wall were characterized over a range of velocities (1 to 8 m/s) and incident angles (90 to 20°). Within CFD models, the kinematic coefficient of restitution is the boundary condition defining the particle wall behavior. Four surfaces were studied to simulate the physical conditions of different entrained-flow gasification particle–surface collision scenarios: 1) a flat metal plate 2) a low viscosity silicon adhesive, 3) a high viscosity silicon adhesive, and 4) adhered particles on a flat metal plate with Young's modulus of elasticity ranging from 0.9 to 190 GPa. Entrained flow and drop experiments were conducted with granular coke particles, polyethylene beads and polystyrene pellets. The particle normal and tangential coefficients of restitution were measured using high speed imaging and particle tracking. The measured coefficients of restitution were observed to have a strong dependence on the rebound angles for most of the data. Suitable algebraic expressions for the normal and the tangential component of the coefficient of restitution were developed based upon ANOVA analysis. These expressions quantify the effect of normalized Young's modulus, particle equancy, and relative velocity on the coefficient of restitution. The coefficient of restitution did not have a strong dependence on the particle velocity over the range considered as long as the velocity was above the critical velocity. However, strong correlations were found between the degree of equancy of the particles and the mean coefficient of restitution such that the coefficient of restitution decreased for smaller particle equancies. It was concluded that the degree of equancy and the normalized Young's modulus should be considered in applications such as gasification and other cases involving the impact of non-spherical particles and complex surfaces. Sliding was observed when particles impacted on oblique surfaces; however, the resulting effects were within the range of measurement uncertainties.

Gibson, LaTosha M.; Gopalan, Balaji; Pisupati, Sarma V.; Shadle, Lawrence J.

2013-10-01T23:59:59.000Z

307

Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1  

SciTech Connect

The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

1994-06-01T23:59:59.000Z

308

E-Print Network 3.0 - advanced coal combustion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

TRACE ELEMENTS, ALKALI METALS 19.6.2001 8-1 Chapter 8 Trace elements, Summary: ,gasification, incineration etc. is illustrated by Figure 8.2 for a coal combustion process with...

309

E-Print Network 3.0 - advanced coal conversion Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Edward Schmetz Summary: ;Summary of Hydrogen from Coal Cases Case 1 Case 2 Case 3 Gasifier* Conventional Advanced Advanced... Hydrogen from Coal Edward Schmetz Office of...

310

E-Print Network 3.0 - advanced direct coal Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Edward Schmetz Summary: ;Summary of Hydrogen from Coal Cases Case 1 Case 2 Case 3 Gasifier* Conventional Advanced Advanced... Hydrogen from Coal Edward Schmetz Office of...

311

Construction Begins on First-of-its-Kind Advanced Clean Coal...  

Energy Savers (EERE)

Construction Begins on First-of-its-Kind Advanced Clean Coal Electric Generating Facility Construction Begins on First-of-its-Kind Advanced Clean Coal Electric Generating Facility...

312

Reduction of iron oxide as an oxygen carrier by coal pyrolysis and steam char gasification intermediate products  

SciTech Connect

The feasibility of the reduction of oxygen carrier Fe{sub 2}O{sub 3} in chemical-looping combustion using solid fuel (lignite) provided a gasifying agent like steam was introduced into the reactor was investigated with a fixed-bed reactor. The X-ray diffractometer and scanning electron microscope were used for the characterization of the Fe{sub 2}O{sub 3} and its reduction residue. Results strongly supported the feasibility of Fe{sub 2}O{sub 3} reduction by lignite and obtaining pure CO{sub 2} from the off-gases. Fe{sub 2}O{sub 3} can be fully converted to Fe{sub 3}O{sub 4} by pyrolysis and gasification intermediates primarily H{sub 2} and CO, which was confirmed by both the off-gas concentrations and X-ray diffractometer analysis. A 0.75 g portion of Fe{sub 2}O{sub 3} can be completely reduced to Fe{sub 3}O{sub 4} by the volatile matter released from 0.1 g coal, and Fe{sub 2}O{sub 3} can be fully reduced to Fe{sub 3}O{sub 4} by steam char gasification products provided that the molar ratio of carbon in char to Fe{sub 2}O{sub 3} is 1:6. The purity of CO{sub 2} in the outlet gases was higher than 85% when Fe{sub 2}O{sub 3} was reduced by intermediate products during coal pyrolysis, and the purity of CO{sub 2} in the off-gases was higher than 95% when Fe{sub 2}O{sub 3} was reduced by intermediate products resulting from steam char gasification, making CO{sub 2} sequestration disposal desirable for high purity CO{sub 2}. The char gasification reaction rate was slow compared with the reactivity of the iron oxide with the char gasified intermediates, indicating that char gasification was the rate-limiting step in the reduction process. In the steam char gasification process, the times it took to reach 90% carbon conversion for K-10-char and Ca-10-char were 15 and 30 min, respectively, at 1123 K, but the time for the raw char was 50 min at 1173 K. 40 refs., 15 figs., 3 tabs.

Jing-biao Yang; Ning-sheng Cai; Zhen-shan Li [Tsinghua University, Beijing (China). Key Laboratory of Thermal Science and Power Engineering of Ministry of Education

2007-12-15T23:59:59.000Z

313

Development of an advanced, continuous mild gasification process for the production of co-products  

SciTech Connect

Research continued on the production of co-products from mild gasification. This quarter, 10 mild gasification tests were conducted in the 8-inch-I.D. process research unit (PRU). Modifications to the PRU were made during this period to improve mixing and to overcome the caking tendency of the Illinois No. 6 coal. Six of the tests resulted in satisfactory operation at steady conditions for 2.25 to 3.25 hours. Samples of char, gas, water, and organic condensables were collected over a one-hour period from each of these successful tests and analyzed. The effects of process temperature over the range of 1025{degree} to 1390{degree} was studied during this quarter. Compositional effects on the oils and tars observed with increased temperature are increased light oil content, decreased pitch content, decreased oxygen content, increased nitrogen and sulfur content, and increasing aromaticity. Char upgrading studies continued during the quarter. Briquettes made in a laboratory press, using either a pitch binder or Illinois No. 6 coal to provide an in-situ binder, were calcined and tested for diametral compression strength. Char was also subjected to steam activation at a variety of conditions to determine the potential for use as a low-cost absorbent for water treatment. 2 refs., 15 figs., 11 tabs.

Knight, R.A.; Gissy, J.; Onischak, M.; Kline, S.; Babu, S.P.

1990-01-01T23:59:59.000Z

314

Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993  

SciTech Connect

Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

Smith, V.E.

1994-05-01T23:59:59.000Z

315

Advanced Coal-Fueled Gas Turbine Program  

SciTech Connect

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

316

EIS-0432: Department of Energy Loan Guarantee for Medicine Bow Gasification and Liquefaction Coal-to-Liquids, Carbon County, Wyoming  

Energy.gov (U.S. Department of Energy (DOE))

DOE is assessing the potential environmental impacts for its proposed action of issuing a Federal loan guarantee to Medicine Bow Fuel & Power LLC (MBFP), a wholly-owned subsidiary of DKRW Advanced Fuels LLC. MBFP submitted an application to DOE under the Federal loan guarantee program pursuant to the Energy Policy Act of 2005 to support the construction and startup of the MBFP coal-to-liquids facility, a coal mine and associated coal handling facilities.

317

Utilization of lightweight materials made from coal gasification slags. Quarterly report, September--November 1995  

SciTech Connect

Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. Slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln. The potential exists for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The technology to produce lightweight and ultra-lightweight aggregates (ULWA) from slag was subsequently developed. The project scope consists of collecting a 20-ton sample of slag (primary slag), processing it for char removal, and subjecting it to pyroprocessing to produce expanded slag aggregates of various size gradations and unit weights, ranging from 12 to 50 lb/ft{sup 3}. A second smaller slag sample will be used for confirmatory testing. The expanded slag aggregates will then be tested for their suitability in manufacturing precast concrete products (e.g., masonry blocks and roof tiles) and insulating concrete, first at the laboratory scale and subsequently in commercial manufacturing plants. These products will be evaluated using ASTM and industry test methods. Technical data generated during production and testing of the products will be used to assess the overall technical viability of expanded slag production. In addition, a market assessment will be made based on an evaluation of both the expanded slag aggregates and the final products, and market prices for these products will be established in order to assess the economic viability of these utilization technologies.

NONE

1995-12-01T23:59:59.000Z

318

Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal  

SciTech Connect

The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

Siriwardane, Ranjani V. [U.S. DOE; Ksepko, Ewelina; Tian, Hanging [URS

2013-01-01T23:59:59.000Z

319

High-Temperature Air/Steam-Blown Gasification of Coal in a Pressurized Spout-Fluid Bed  

Science Journals Connector (OSTI)

7-10 However, in the MEET system a pebble bed slagging entrained-flow gasifier was used that had to be operated at very high temperatures (1350?1550 °C), which required excessive energy input to maintain such a high gasification temperature when compared with fluidized bed gasifiers, such as spout-fluid bed gasifiers which used medium temperatures (800?1100 °C) to convert coal to fuel gas. ... The typical size distribution is shown in Table 2, where is specific surface-equivalent diameter. ...

Rui Xiao; Mingyao Zhang; Baosheng Jin; Yaji Huang; Hongcang Zhou

2006-02-10T23:59:59.000Z

320

Catalytic Effects of Main Metals in Coal Ash on Advanced Reburning of Pulverized Coal  

Science Journals Connector (OSTI)

Catalytic Effects of Main Metals in Coal Ash on Advanced Reburning of Pulverized Coal ... To further reduce the NOx emission from power plants, an experimental study on the NO reduction during advanced reburning with reburning fuel of raw coal and coals loaded with four kinds of main metals in coal ash (Na, K, Fe, Ca) was performed in a two-staged drop flow reactor (TSDFR). ... By comparing the conversion of five main products during the reactions when using raw coal and coals loaded with different metals as reburning fuel, it is found that some types of metals can improve the NO reduction in reburning via increasing the concentration of CH4 and CO during the reactions. ...

Penghua Qiu; Hui Huang; Jianqiang Zhang; Li Liu; Yuqing Chen

2010-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Coal science for the clean use of coal  

SciTech Connect

Coal will need to be retained as a major source of energy in the next century. It will need to be used more effectively and more cleanly. In order to achieve this, it is necessary to introduce new technology supported by a local community of science and technology. Only in this way can the full benefits of international advances in coal utilization be fully achieved. It is important that full advantage be taken of the advances that have been achieved in laboratory techniques and in the better understanding of fundamental coal science. This paper reviews available technologies in power generation, industrial process heat, coal combustion, coal gasification, and coal analytical procedures.

Harrison, J.S. [Univ. of Leeds (United Kingdom)

1994-12-31T23:59:59.000Z

322

Advanced Process and Decision Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

with evaluating fossil fuel alternatives such as liquefied natural gas, coal and oil shale gasification, tar and oil sands gasification, and coal-bed and coal mine methane...

323

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

at http://web.mit.edu/coal/ NETL, 2007a. “The Cost andbaseline_studies.html NETL, 2007b. “Increasing Security andRole for Coal with Biomass. DOE/NETL- 1298, National Energy

Phadke, Amol

2008-01-01T23:59:59.000Z

324

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Usage in Coal to Electrical Applications Usage in Coal to Electrical Applications The Integrated Gasification Combined Cycle (IGCC) application of gasification offers some water-saving advantages over other technologies for producing electricity from coal. Regions with limited water resources, typical of many parts of the western United States, could conserve resources by meeting increasing electricity demand with IGCC generation. Many of these areas have good coal resources and a need for new generating capacity. Water use in a thermoelectric power plant is described by two separate terms: water withdrawal and water consumption. Water withdrawal is the amount of water taken into the plant from an outside source. Water consumption refers to the portion of the withdrawn water that is not returned directly to the outside source - for example, water lost to evaporative cooling.

325

Corrosion and degradation of test materials in the Westinghouse 15 ton/day Coal Gasification Process Development Unit  

SciTech Connect

Two periods of in-plant exposures of candidate materials in the Westinghouse PDU have been completed. Coupons were exposed in the gasifier, hot-gas cyclone, quench scrubber, and gas cooler vessels. Corrosion monitoring of test materials is currently being conducted in the Westinghouse Coal Gasification Process Development Unit (PDU) coal gasification pilot plant. The corrosion data presented are from work during 1981 through 1984. During these two exposure periods, several coals ranging from lignites to bituminous coals and two petroleum cokes were gasified in the steam-oxygen mode. Fouling was observed on most corrosion racks. The effect of this process-related material was to promote corrosion. In the gasifier environment, alloys 6B, IN 671, and 18SR were the best performing alloys. Nickel-base alloys with Ni/Cr ratios >1.5, namely IN-617, IN-825, and alloy X, incurred severe corrosion attack in both exposures. Other alloys, although generally acceptable in corrosion performance, were not immune to solids-induced corrosion around coupon mounting holes. Several refractories such as Brickram 90, Harbison-Walker Ruby, and Chemal 85B showed little degradation in both gasifier exposures. Nitride bonded silicon carbon Refrax 20 had the greatest reduction in abrasion resistance as well as other properties. Single-phase structural ceramics including siliconized SiC, sintered ..cap alpha..-SiC, and Al/sub 2/O/sub 3/ did not suffer any noticeable damage. Materials evaluation in the hot-gas cyclone showed IN-671 and 26-1 to be more resistant than Type 310 and Type 310 aluminized. 18 refs., 23 figs., 24 tabs.

Yurkewycz, R.

1985-01-31T23:59:59.000Z

326

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1985-01-01T23:59:59.000Z

327

Gasification system  

DOE Patents (OSTI)

A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

1983-01-01T23:59:59.000Z

328

NETL: Gasifipedia - What is Gasification?  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Background Gasification Background Drivers for Gasification Technology The need for low-cost power produced in an environmentally sound way is certain, even if the future of regulations limiting the emission and/or encouraging the capture of CO2, and the price and availability of natural gas and oil are not. Gasification is not only capable of efficiently producing electric power, but a wide range of liquids and/or high-value chemicals (including diesel and gasoline for transportation) can be produced from cleaned syngas, providing the flexibility to capitalize on a range of dynamic changes to either domestic energy markets or global economic conditions. Polygeneration-plants that produce multiple products-is uniquely possible with gasification technologies. Continued advances in gasification-based technology will enable the conversion of our nation's abundant coal reserves into energy resources (power and liquid fuels), chemicals, and fertilizers needed to displace the use of imported oil and, thereby, help mitigate its high price and security supply concerns and to support U.S. economic competitiveness with unprecedented environmental performance.

329

Molten Salt Coal Gasification Process Development Unit. Phase 2. Quarterly technical progress report No. 2, October-December 1980  

SciTech Connect

This represents the second quarterly progress report on Phase 2 of the Molten Salt Coal Gasification Process Development Unit (PDU) Program. Phase 1 of this program started in March 1976 and included the design, construction, and initial operation of the PDU. On June 25, 1980, Phase 2 of the program was initiated. It covers a 1-year operations program utilizing the existing PDU and is planned to include five runs with a targeted total operating time of 9 weeks. During this report period, Run 6, the initial run of the Phase 2 program was completed. The gasification system was operated for a total of 95 h at pressures up to 10 atm. Average product gas HHV values of 100 Btu/scf were recorded during 10-atm operation, while gasifying coal at a rate of 1100 lb/h. The run was terminated when the melt overflow system plugged after 60 continuous hours of overflow. Following this run, melt withdrawal system revisions were made, basically by changing the orifice materials from Monofrax to an 80 Cobalt-20 Chromium alloy. By the end of the report period, the PDU was being prepared for Run 7.

Not Available

1981-01-20T23:59:59.000Z

330

Analysis of char-slag interaction and near-wall particle segregation in entrained-flow gasification of coal  

SciTech Connect

The fate of carbon particles during entrained-flow gasification of coal in the slagging regime is analyzed. More specifically, the study addresses the relevance of segregation of carbon particles in a near-wall region of the gasifier to coal conversion. Segregation of carbon particles is analyzed considering the effects of turbulence- and swirl-promoted particle migration toward the wall, interaction of the impinging particles with the wall ash layer, coverage of the slag layer by refractory carbon particles, accumulation of carbon particles in a dense-dispersed phase near the wall of the gasifier. Operating conditions of the gasifier and slag properties may be combined so as to give rise to a variety of conversion regimes characterized by distinctively different patterns of carbon particles segregation. A simple 1D model of an entrained-flow gasifier has been developed based on the conceptual framework of carbon particle segregation. The model aims at providing a general assessment of the impact of the different patterns of carbon particle segregation on the course and extent of carbon gasification. A sensitivity analysis with reference to selected model parameters is performed to identify key processes controlling carbon segregation and their impact on the gasifier performance. (author)

Montagnaro, Fabio [Dipartimento di Chimica, Universita degli Studi di Napoli Federico II, Complesso Universitario del Monte di Sant'Angelo, 80126 Napoli (Italy); Salatino, Piero [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli Federico II and Istituto di Ricerche sulla Combustione, CNR, Piazzale Vincenzo Tecchio 80, 80125 Napoli (Italy)

2010-05-15T23:59:59.000Z

331

LWA demonstration applications using Illinois coal gasification slag: Phase 2. Technical report, September 1--November 30, 1993  

SciTech Connect

The objectives of this program are to demonstrate the feasibility of producing ultra-lightweight aggregates (ULWA) from solid residues (slag) generated during the gasification of Illinois coals, and to test the products as substitutes for conventional aggregates produced by pyroprocessing of perlite ores. In Phase 1 of this project, Praxis developed a pilotscale production technique and produced a large batch of expanded aggregates from an Illinois coal slag feed. The Phase 2 work focuses on characterization and applications-oriented testing of the expanded slag products as substitutes for conventional ULWAs. Target applications include high-volume uses such as loose fill insulation, insulating concrete, lightweight precast products (blocks), waterproof wallboard, rooftiles, and filtration media. The precast products will be subjected to performance and characterization testing in conjunction with a commercial manufacturer of such products in order to obtain input from a potential user. The production of value-added products from slag will eliminate a solid waste and possibly enhance the overall gasification process economics, especially when the avoided costs of disposal are taken into consideration.

Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States); Steck, P. [Harvey Cement Products, Inc. (United States)

1993-12-31T23:59:59.000Z

332

Gasification Characteristics of Coal/Biomass Blend in a Dual Circulating Fluidized Bed Reactor  

Science Journals Connector (OSTI)

circulating flow/forestry, agricultural waste, industry wastes + coalcoke ... Whereas, a dual fluidized bed gasification technology enables production of the medium calorific value gas (12?18 MJ/Nm3) by separating the combustion and gasification zones in which steam is used as a gasifying agent. ... Since Quercus acutissima is widely used in building, pulp, and shipping industries, its demand and supply in Korea is high. ...

Myung Won Seo; Jeong Hoi Goo; Sang Done Kim; See Hoon Lee; Young Chan Choi

2010-04-23T23:59:59.000Z

333

Review of China's Low-Carbon City Initiative and Developments in the Coal Industry  

E-Print Network (OSTI)

2010. “Development of Coal Gasification & Polygeneration insystem based on coal- gasification. ” Energy for Sustainablethrough oxygen- blown gasification to produce a syngas

Fridley, David

2014-01-01T23:59:59.000Z

334

THE EFFECT OF COAL CHAR ON THE CORROSION OF 304 SS  

E-Print Network (OSTI)

of Materials for Coal Gasification Applications". of Highcommercially proven coal gasification processes exist. Theseprocesses. more efficient gasification Much of this work is

Foerster, Thomas Friedrich Wilhelm

2011-01-01T23:59:59.000Z

335

Portfolio evaluation of advanced coal technology : research, development, and demonstration  

E-Print Network (OSTI)

This paper evaluates the advanced coal technology research, development and demonstration programs at the U.S. Department of Energy since the 1970s. The evaluation is conducted from a portfolio point of view and derives ...

Naga-Jones, Ayaka

2005-01-01T23:59:59.000Z

336

Coal for the future. Proceedings of the 33rd international technical conference on coal utilization and fuel systems  

SciTech Connect

Topics covered include oxy-fuel technology, modelling and simulations, low NOx technology, gasification technology, pre-utilization beneficiation of coal, advanced energy conversion systems, mercury emissions control, improving power plant efficiency and reducing emissions, biomass and wastes, coal to liquids, post-combustion CO{sub 2} capture, multi emission controls, advanced materials, advanced controls, and international highlights.

Sakkestad, B.A. (ed.)

2008-07-01T23:59:59.000Z

337

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network (OSTI)

of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

338

Advanced coal technologies in Czech heat and power systems  

SciTech Connect

Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently necessary steps in making coal utilisation more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. Preparatory steps have been taken in building an advanced combustion unit fuelled by pulverised coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper then coal) do not oblige to increase efficiency of the standing equipment applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalisation of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in near future.

Noskievic, P.; Ochodek, T. [VSB-Technical Univ., Ostrava (Czechoslovakia)

1998-04-01T23:59:59.000Z

339

Fixed bed gasification studies on coal-feedlot biomass and coal-chicken litter biomass under batch mode operation  

E-Print Network (OSTI)

of the processes for energy conversion of biomass fuels is thermochemical gasification. For the current study, a laboratory scale, 10 kW[th], fixed-bed gasifier (reactor internal diameter 0.15 m, reactor height 0.30 m) facility was built at the Texas A...

Priyadarsan, Soyuz

2012-06-07T23:59:59.000Z

340

Advanced pulverized-coal power plants: A U.S. export opportunity  

SciTech Connect

This paper provides an overview of Low Emission Boiler System (LEBS) power generation systems and its potential for generating power worldwide. Based on the fuel availability, power requirements, and environmental regulations, countries have been identified that need to build advanced, clean, efficient, and economical power generation, systems. It is predicted that ``more electrical generation capacity will be built over the next 25 years than was built in the previous century``. For example, China and India alone, with less than 10% of today`s demand, plan to build what would amount to a quarter of the world`s new capacity. For the near- to mid-term, the LEBS program of Combustion 2000 has the promise to fill some of the needs of the international coal-fired power generation market. The high efficiency of LEBS, coupled with the use of advanced, proven technologies and low emissions, make it a strong candidate for export to those areas whose need for additional power is greatest. LEBS is a highly advanced version of conventional coal-based power plants that have been utilized throughout the world for decades. LEBS employs proven technologies and doesn`t require gasification and/or an unconventional combustion environment (e.g., fluidized bed). LEBS is viewed by the utility industry as technically acceptable and commercially feasible.

Ruth, L.A. [USDOE Pittsburgh Energy Technology Center, PA (United States); Ramezan, M.; Izsak, M.S. [Burns and Roe Services Corp., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992  

SciTech Connect

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

1992-03-01T23:59:59.000Z

342

DOE-Supported Project Advances Clean Coal, Carbon Capture Technology |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE-Supported Project Advances Clean Coal, Carbon Capture DOE-Supported Project Advances Clean Coal, Carbon Capture Technology DOE-Supported Project Advances Clean Coal, Carbon Capture Technology January 29, 2013 - 12:00pm Addthis Washington, DC - Researchers at The Ohio State University (OSU) have successfully completed more than 200 hours of continuous operation of their patented Coal-Direct Chemical Looping (CDCL) technology - a one-step process to produce both electric power and high-purity carbon dioxide (CO2). The test, led by OSU Professor Liang-Shih Fan, represents the longest integrated operation of chemical looping technology anywhere in the world to date. The test was conducted at OSU's 25 kilowatt thermal (kWt) CDCL combustion sub-pilot unit under the auspices of DOE's Carbon Capture Program, which is developing innovative environmental control technologies to foster the

343

DOE-Supported Project Advances Clean Coal, Carbon Capture Technology |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

DOE-Supported Project Advances Clean Coal, Carbon Capture DOE-Supported Project Advances Clean Coal, Carbon Capture Technology DOE-Supported Project Advances Clean Coal, Carbon Capture Technology January 29, 2013 - 12:00pm Addthis Washington, DC - Researchers at The Ohio State University (OSU) have successfully completed more than 200 hours of continuous operation of their patented Coal-Direct Chemical Looping (CDCL) technology - a one-step process to produce both electric power and high-purity carbon dioxide (CO2). The test, led by OSU Professor Liang-Shih Fan, represents the longest integrated operation of chemical looping technology anywhere in the world to date. The test was conducted at OSU's 25 kilowatt thermal (kWt) CDCL combustion sub-pilot unit under the auspices of DOE's Carbon Capture Program, which is developing innovative environmental control technologies to foster the

344

NETL: Gasification Systems - Gas Cleaning  

NLE Websites -- All DOE Office Websites (Extended Search)

Cleaning Cleaning Chemicals from Coal Complex Chemicals from Coal Complex (Eastman Company) Novel gas cleaning and conditioning are crucial technologies for achieving near-zero emissions, while meeting gasification system performance and cost targets. DOE's Gasification Systems program supports technology development in the area of gas cleaning and conditioning, including advanced sorbents and solvents, particulate filters, and other novel gas-cleaning approaches that remove and convert gas contaminants into benign and marketable by-products. To avoid the cost and efficiency penalties associated with cooling the gas stream to temperatures at which conventional gas clean-up systems operate, novel processes are being developed that operate at mild to high temperatures and incorporate multi-contaminant control to

345

Improving Process Performances in Coal Gasification for Power and Synfuel Production  

Science Journals Connector (OSTI)

The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. ... Considering the world’s insatiable appetite for energy and oil, the only reasonable large-scale conventional source left in the medium term will have to be coal. ...

M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana

2008-09-17T23:59:59.000Z

346

The O{sub 2}-enriched air gasification of coal, plastics and wood in a fluidized bed reactor  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer The effect of the O{sub 2} in the gasification stream of a BFB gasifier has been studied. Black-Right-Pointing-Pointer Main advantage of the O{sub 2}-enriched air is the increasing of the bed temperature. Black-Right-Pointing-Pointer No remarkable effects on tar reduction. Decreasing of recognized PAHs. Black-Right-Pointing-Pointer Gasification reactions completed inside the dense bed and splashing zone. Black-Right-Pointing-Pointer Polycondensation reactions occur mainly in the freeboard region. - Abstract: The effect of oxygen-enriched air during fluidized bed co-gasification of a mixture of coal, plastics and wood has been investigated. The main components of the obtained syngas were measured by means of on-line analyzers and a gas chromatograph while those of the condensate phase were off-line analysed by means of a gas chromatography-mass spectrometer (GC-MS). The characterization of condensate phase as well as that of the water used as scrubbing medium completed the performed diagnostics. The experimental results were further elaborated in order to provide material and substances flow analyses inside the plant boundaries. These analyses allowed to obtain the main substance distribution between solid, gaseous and condensate phases and to estimate the conversion efficiency of carbon and hydrogen but also to easily visualise the waste streams produced by the process. The process performance was then evaluated on the basis of parameters related to the conversion efficiency of fuels into valuable products (i.e. by considering tar and particulate as process losses) as well as those related to the energy recovery.

Mastellone, Maria Laura, E-mail: mlaura.mastellone@unina2.it [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy); Zaccariello, Lucio; Santoro, Donato; Arena, Umberto [Department of Environmental Sciences-Second University of Naples, Via Vivaldi, 43 81100 Caserta (Italy)

2012-04-15T23:59:59.000Z

347

EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY  

Energy.gov (U.S. Department of Energy (DOE))

This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

348

Advanced Coal Wind Hybrid: Economic Analysis  

E-Print Network (OSTI)

the United States from LNG and Coal. ” DOE/NETL-2006/1227,per MJ and those for imported LNG are about 11 grams of CO2gas, which in the US is imported LNG that has substantially

Phadke, Amol

2008-01-01T23:59:59.000Z

349

Hanna, Wyoming underground coal gasification data base. Volume 4. Hanna II, Phases II and III field test research report  

SciTech Connect

This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. Hanna II, Phases II and III, were conducted during the winter of 1975 and the summer of 1976. The two phases refer to linking and gasification operations conducted between two adjacent well pairs as shown in Figure 1 with Phase II denoting operations between Wells 5 and 6 and Phase III operations between Wells 7 and 8. All of the other wells shown were instrumentation wells. Wells 7 and 8 were linked in November and December 1975. This report covers: (1) specific site selection and characteristics; (2) test objectives; (3) facilities description; (4) pre-operation tests; (5) test operations summary; and (6) post-test activity. 16 refs., 21 figs., 17 tabs.

Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

1985-08-01T23:59:59.000Z

350

Chemistry and mechanism of molten-salt catalysts in coal-gasification processes. Final report, January 1984-January 1985  

SciTech Connect

Alkali metal salts have been recognized as effective catalysts in coal gasification. However, the presence of reducing gases, in particular carbon monoxide, has recently been shown to have serious inhibitory effects on the catalyst performance. This program has addressed the question of the chemical interactions between carbon monoxide gas containing mixtures and the salt catalysts in liquid form by probing the solution chemistry by dynamic electrochemical techniques. The results of this study show that oxalate ions are formed by the reaction between carbonate ions and carbon monoxide gas. At temperatures above 700/sup 0/C, sulfate ions are directly attacked by carbon monoxide. The oxalate ions are electroactive and their electrochemistry has been studied and found to involve adsorption of oxalate and formation of reactive intermediates. The pathway likely involves an ECE sequence. The formation of active adsorbed species such as oxalate or sulfides at high temperature may be the means by which catalytic function of the salts is inhibited.

White, S.H.; Twardoch, U.M.

1985-02-01T23:59:59.000Z

351

LWA demonstration applications using Illinois coal gasification slag. Phase 2, [Quarterly] technical report, December 1, 1993--February 28, 1994  

SciTech Connect

The objectives of this program are to demonstrate the feasibility of producing ultra-lightweight aggregates (ULWA) , from solid residues (slag) generated during the gasification of Illinois coals, and to test the products as substitutes for conventional aggregates produced by pyroprocessing of perlite ores. During this reporting period, major accomplishments were the selection of mix designs and test methods for preparation of specimens of expanded slag for testing in precast applications (Task 3) and construction aggregate applications (Task 4). In addition, characterization data (Task 1) were,analyzed, and evaluation of the expanded slag products as substitutes for conventional ULWAs (Task 2) was completed. Potential applications that were identified are: (1) Loose fill insulation; Insulating concrete (roof, floor, and walls); Precast products (blocks and rooftiles). Experimental work during the project is focused on these applications.

Choudhry, V. [Praxis Engineers, Inc., Milpitas, CA (United States); Steck, P. [Harvey Cement Products, Inc. (United States)

1994-06-01T23:59:59.000Z

352

Power Systems Development Facility Gasification Test Campaign TC17  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results gasification operation with Illinois Basin bituminous coal in PSDF test campaign TC17. The test campaign was completed from October 25, 2004, to November 18, 2004. System startup and initial operation was accomplished with Powder River Basin (PRB) subbituminous coal, and then the system was transitioned to Illinois Basin coal operation. The major objective for this test was to evaluate the PSDF gasification process operational stability and performance using the Illinois Basin coal. The Transport Gasifier train was operated for 92 hours using PRB coal and for 221 hours using Illinois Basin coal.

Southern Company Services

2004-11-30T23:59:59.000Z

353

Behavior of mineral matters in Chinese coal ash melting during char-CO{sub 2}/H{sub 2}O gasification reaction  

SciTech Connect

The typical Chinese coal ash melting behavior during char-CO{sub 2}/H{sub 2}O gasification reaction was studied by using TGA, XRD, and SEM-EDX analysis. It was found that ash melting behavior during char gasification reaction is quite different from that during coal combustion process. Far from the simultaneously ash melting behavior during coal combustion, the initial melting behavior of ash usually occurs at a middle or later stage of char-CO{sub 2}/H{sub 2}O reaction because of endothermic reaction and more reactivity of char gasification reaction as compared with that of mineral melting reactions in ash. In general, the initial melting temperature of ash is as low as 200-300 K below the deformation temperature (T{sub def}) of ash with ASTM test. The initial molten parts in ash are mainly caused by iron bearing minerals such as wustite and iron-rich ferrite phases under gasification condition. Along with the proceeding of ash melting, the melting behavior appears to be accelerated by the presence of calcium to form eutectic mixtures in the FeO-SiO{sub 2}-Al{sub 2}O{sub 3} and CaO-SiO{sub 2}-Al{sub 2}O{sub 3} system. The different states of iron are the dominant reason for different melting behaviors under gasification and combustion conditions. Even under both reducing conditions, the ash fusion temperature (AFT) of coal under char-CO{sub 2} reaction is about 50-100 K lower than that under char-H{sub 2}O reaction condition. The main reason of that is the higher content of CO under char-CO{sub 2} reaction, which can get a lower ratio of Fe{sup 3+}/{Sigma}Fe in NaO-Al{sub 2}O{sub 3}-SiO{sub 2}-FeO melts. 38 refs., 8 figs., 4 tabs.

Xiaojiang Wu; Zhongxiao Zhang; Guilin Piao; Xiang He; Yushuang Chen; Nobusuke Kobayashi; Shigekatsu Mori; Yoshinori Itaya [University of Shanghai for Science & Technology, Shanghai (China). Department of Power Engineering

2009-05-15T23:59:59.000Z

354

NETL: News Release - Clean Coal Technology Report Showcases Advanced Iron  

NLE Websites -- All DOE Office Websites (Extended Search)

April 6, 2000 April 6, 2000 Clean Coal Technology Report Showcases Advanced Iron Making Process, Benefits for the Environment Topical Report Profiles Blast Furnace Granular Coal Injection System; Now Available on DOE's Fossil Energy Web Site An advanced iron making technology demonstrated in the U.S. Department of Energy's Clean Coal Technology Program stands out for its potential to provide major environmental and financial benefits to the United States steel industry. Bethlehem Steel Topical Report The Energy Department has profiled the project in a topical report entitled Blast Furnace Granular Coal Injection System Demonstration Project. The report describes the federal government's partnership demonstration project with Bethlehem Steel Corporation, which tested a new method for reducing

355

Interlaboratory comparison of advanced fine-coal beneficiation processes  

SciTech Connect

The Pittsburgh Energy Technology Center (PETC) recently completed three interlaboratory test programs involving 21 developers of advanced fine-coal-cleaning processes. The processes consisted of specific gravity separation (aqueous or heavy-liquid), electrostatic separation (dry), advanced froth flotation, selective agglomeration, and surface modification (gas). The participating organizations received representative samples of Illinois No. 6, Pittsburgh, and Upper Freeport bed coals. They ground them to a size appropriate for their particular process and then treated each coal. Their goal was to produce a clean coal with 2--3{percent} ash while recovering maximum energy. The products were returned to the PETC for analysis and performance evaluation. This paper will discuss the processes involved in the three test programs and present the results of the beneficiation tests. 4 refs., 4 figs., 3 tabs.

Jacobsen, P.S. (Burns and Roe Services Corp., Pittsburgh, PA (USA)); Killmeyer, R.P.; Hucko, R.E. (USDOE Pittsburgh Energy Technology Center, PA (USA))

1989-12-01T23:59:59.000Z

356

Development of an Advanced Fine Coal Suspension Dewatering Process  

SciTech Connect

With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

B. K. Parekh; D. P. Patil

2008-04-30T23:59:59.000Z

357

NETL: 2010 World Gasification Database Archive  

NLE Websites -- All DOE Office Websites (Extended Search)

Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Home > Technologies > Coal & Power Systems > Gasification Systems > 2010 World Gasification Database Gasification Systems 2010 Worldwide Gasification Database Archive DOE/NETL 2010 Worldwide Gasification Database Worldwide Gasification Database Analysis The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

358

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia > Feedstock Flexibility > Refinery Streams Gasifipedia Coal: Feedstock Flexibility Refinery Streams Gasification is a known method for converting petroleum coke (petcoke) and other refinery waste streams and residuals (vacuum residual, visbreaker tar, and deasphalter pitch) into power, steam and hydrogen for use in the production of cleaner transportation fuels. The main requirement for a gasification feedstock is that it contains both hydrogen and carbon. Below is a table that shows the specifications for a typical refinery feedstock. Specifications for a typical refinery feedstock A number of factors have increased the interest in gasification applications in petroleum refinery operations: Coking capacity has increased with the shift to heavier, more sour crude oils being supplied to the refiners.

359

Gasification advanced research and technology development (AR and TD) cross-cut meeting and review. [US DOE supported  

SciTech Connect

The US Department of Energy gasification advanced research and technology development (AR and TD) cross-cut meeting and review was held June 24 to 26, 1981, at Germantown, Maryland. Forty-eight papers from the proceedings have been entered individually into EDB and ERA. (LTN)

Not Available

1981-01-01T23:59:59.000Z

360

Low-rank coal research. Final technical report, April 1, 1988--June 30, 1989, including quarterly report, April--June 1989  

SciTech Connect

This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

Not Available

1989-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Integrated Sensing and Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier and Syngas Cooler  

SciTech Connect

This report summarizes the achievements and final results of this program. The objective of this program is to develop a comprehensive systems approach to integrated design of sensing and control systems for an Integrated Gasification Combined Cycle (IGCC) plant, using advanced model-based techniques. In particular, this program is focused on the model-based sensing and control system design for the core gasification section of an IGCC plant. The overall approach consists of (i) developing a first-principles physics-based dynamic model of the gasification section, (ii) performing model-reduction where needed to derive low-order models suitable for controls analysis and design, (iii) developing a sensing system solution combining online sensors with model-based estimation for important process variables not measured directly, and (iv) optimizing the steady-state and transient operation of the plant for normal operation as well as for startup using model predictive controls (MPC). Initially, available process unit models were implemented in a common platform using Matlab/Simulink{reg_sign}, and appropriate model reduction and model updates were performed to obtain the overall gasification section dynamic model. Also, a set of sensor packages were developed through extensive lab testing and implemented in the Tampa Electric Company IGCC plant at Polk power station in 2009, to measure temperature and strain in the radiant syngas cooler (RSC). Plant operation data was also used to validate the overall gasification section model. The overall dynamic model was then used to develop a sensing solution including a set of online sensors coupled with model-based estimation using nonlinear extended Kalman filter (EKF). Its performance in terms of estimating key unmeasured variables like gasifier temperature, carbon conversion, etc., was studied through extensive simulations in the presence sensing errors (noise and bias) and modeling errors (e.g. unknown gasifier kinetics, RSC fouling). In parallel, an MPC solution was initially developed using ideal sensing to optimize the plant operation during startup pre-heating as well as steady state and transient operation under normal high-pressure conditions, e.g. part-load, base-load, load transition and fuel changes. The MPC simulation studies showed significant improvements both for startup pre-heating and for normal operation. Finally, the EKF and MPC solutions were coupled to achieve the integrated sensing and control solution and its performance was studied through extensive steady state and transient simulations in the presence of sensor and modeling errors. The results of each task in the program and overall conclusions are summarized in this final report.

Aditya Kumar

2010-12-30T23:59:59.000Z

362

Co-gasification of biomass with coal and oil sands coke in a drop tube furnace.  

E-Print Network (OSTI)

??Chars were obtained from individual fuels and blends with different blend ratios of coal, coke and biomass in Drop Tube Furnace at different temperatures. Based… (more)

Gao, Chen

2010-01-01T23:59:59.000Z

363

A life cycle comparison of greenhouse emissions for power generation from coal mining and underground coal gasification  

Science Journals Connector (OSTI)

For the emissions from energy and equipment use of underground coal mining, the data from the office of Energy Efficiency and Renewable Energy’s (EERE) hypothetical eastern U.S. underground coalmine is used (EERE

Zeshan Hyder; Nino S. Ripepi…

2014-05-01T23:59:59.000Z

364

Modelling and simulation of coal and petcoke gasification in a Co-current flow reactor  

Science Journals Connector (OSTI)

A mathematical model is developed for the simulation of the gasification process in a reactor where a carbon slurry is fed together with oxygen and water vapour. The model considers several heterogeneous and homogeneous reactions to estimate flows and composition of the exit gases, including combustion, gasification and hydro-pyrolysis of carbon. Mass and heat-transfer phenomena are described for the particular physical arrangement, including bulk film diffusion processes with variable particle size and heat transfer by radiation from the hot region downstream to the cooler entrance region. Preliminary results are in good agreement with experimental data from a pilot plant, including exit composition and temperatures, and ignition and highest-temperature points. An analysis of the main operational parameters is given, which could be used for the final design of the plant.

Elida M. López; Vicente Garza; Joaquín Acevedo

2006-01-01T23:59:59.000Z

365

Ash melting behavior and slag infiltration into alumina refractory simulating co-gasification of coal and biomass  

Science Journals Connector (OSTI)

Abstract In the present study melting behavior of ashes from German brown coal and biomass (wheat straw) as well as from two artificial mixtures of both has been investigated. The four fuel samples were ashed at 450 °C over a period of 26 h. Ash fusion tests and all other measurements have been executed under reducing atmosphere, simulating gasification conditions. The ash melting and wetting properties have been studied for ash cylinders placed onto an alumina refractory at temperatures up to 1600 °C. Optical microscopy and SEM/EDX studies have been performed to analyze the infiltration of slag into the refractory and related progression. For the ash fusion behavior and surface wetting of the refractory clear distinctions from pure ashes have been detected for the blend with 50 wt.% biomass addition due to the formation of eutectics. From optical microscopy and SEM/EDX images of the sections different infiltration properties and mechanisms have been identified. The qualitative infiltration depth and deceleration of slag infiltration by a formation of solid phases have been provided by FactSage™ calculations. In these calculations the contact zone between the two materials has been reconstructed by a stepwise change in the amounts of ash and refractory. The experimental results are very well reflected in this model. Finally, the obtained results suggest low corrosive biomass amounts for co-use in the present gasifier types designed for pure coal.

Guanjun Zhang; Markus Reinmöller; Mathias Klinger; Bernd Meyer

2015-01-01T23:59:59.000Z

366

Biological removal of organic constituents in quench waters from high-Btu coal-gasification pilot plants  

SciTech Connect

Studies were initiated to assess the efficiency of bench-scale, activated-sludge treatment for removal of organic constituents from coal-gasification process effluents. Samples of pilot-plant, raw-gas quench waters were obtained from the HYGAS process of the Institute of Gas Technology and from the slagging, fixed-bed (SFB) process of the Grand Forks Energy Technology Center. The types of coal employed were Bituminous Illinois No. 6 for the HYGAS and Indian Head lignite for the SFB process. These pilot-plant quench waters, while not strictly representative of commercial condensates, were considered useful to evaluate the efficiency of biological oxidation for the removal of organics. Biological-reactor influent and effluent samples were extracted using a methylene chloride pH-fractionation method into acid, base, and neutral fractions, which were analyzed by capillary-column gas-chromatography/mass-spectrometry. Influent acid fractions of both HYGAS and SFB condensates showed that nearly 99% of extractable and chromatographable organic material comprised phenol and alkylated phenols. Activated-sludge treatment removed these compounds almost completely. Removal efficiency of base-fraction organics was generally good, except for certain alkylated pyridines. Removal of neutral-fraction organics was also good, except for certain alkylated benzenes, certain polycyclic aromatic hydrocarbons, and certain cycloalkanes and cycloalkenes, especially at low influent concentrations.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

367

Underground coal gasification (UCG) gas to methanol and MTG-gasoline: an economic and sensitivity study, Task B  

SciTech Connect

This report, identified as Task B, examines the technical and economic aspects of the production of methanol and MTG-Gasoline using gas from an underground coal gasification (UCG) facility. The report is a sequel to a previous study performed in 1981 and identified as Task A. The Task A report, titled Cost Saving Concepts on the Production of Methanol from Underground Gasified Coal, examined the economics of producing fuel grade methanol using UCG gas. In this study we examine the economics of producing MTG-Gasoline as well as a number of other aspects of the economics of upgrading UCG gas. Capital and operating costs for three different capacities of MTG-Gasoline plant are presented. These are 1600 BPD, 4800 BPD, and 9600 BPD. These capacities are equivalent to fuel grade methanol plants having capacities of 4000 BPD, 12,000 BPD, and 24,000 BPD - the methanol capacities considered in the previous studies. The economics of the MTG-Gasoline plant were developed using published information and our best estimate of the processing steps in the MTG-Gasoline process. As part of this study, several sensitivity studies were undertaken to examine the sensitivity of both methanol and MTG-Gasoline product cost to changes in technical and economic parameters. Table 1.1 lists the various sensitivity studies undertaken. All cost figures are in first quarter 1982 dollars.

Not Available

1982-06-01T23:59:59.000Z

368

Gasification: A Cornerstone Technology  

ScienceCinema (OSTI)

NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

Gary Stiegel

2010-01-08T23:59:59.000Z

369

Gasification: A Cornerstone Technology  

SciTech Connect

NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

Gary Stiegel

2008-03-26T23:59:59.000Z

370

E-Print Network 3.0 - advanced clean coal Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

clean coal Search Powered by Explorit Topic List Advanced Search Sample search results for: advanced clean coal Page: << < 1 2 3 4 5 > >> 1 ACTION TEAM PROGRESS REPORT Integrated...

371

NETL: Gasification - National Carbon Capture Center at the Power Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Gasification Gasification National Carbon Capture Center at the Power Systems Development Facility National Carbon Capture Center Participants The Power Systems Development Facility (PSDF) is a state-of-the-art test center sponsored by the U.S. Department of Energy (DOE) and dedicated to the advancement of clean coal technology. The PSDF now houses the National Carbon Capture Center (NCCC) to address the nation's need for cost-effective, commercially viable CO2 capture options for flue gas from pulverized coal power plants and syngas from coal gasification power plants. The NCCC focuses national efforts on reducing greenhouse gas emissions through technological innovation, and serve as a neutral test center for emerging carbon capture technologies. PSDF-NCCC Background

372

Power Systems Development Facility Gasification Test Campaing TC14  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details test campaign TC14 of the PSDF gasification process. TC14 began on February 16, 2004, and lasted until February 28, 2004, accumulating 214 hours of operation using Powder River Basin (PRB) subbituminous coal. The gasifier operating temperatures varied from 1760 to 1810 F at pressures from 188 to 212 psig during steady air blown operations and approximately 160 psig during oxygen blown operations.

Southern Company Services

2004-02-28T23:59:59.000Z

373

Advanced Fuels Synthesis  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Fuels Synthesis Advanced Fuels Synthesis Coal and Coal/Biomass to Liquids Advanced Fuels Synthesis The Advanced Fuels Synthesis Key Technology is focused on catalyst and reactor optimization for producing liquid hydrocarbon fuels from coal/biomass mixtures, supports the development and demonstration of advanced separation technologies, and sponsors research on novel technologies to convert coal/biomass to liquid fuels. Active projects within the program portfolio include the following: Fischer-Tropsch fuels synthesis Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Pilot Plant for the Gasification of Coal and Coal/Biomass Blends and Conversion of Derived Syngas to Liquid Fuels Via Fischer-Tropsch Synthesis Coal Fuels Alliance: Design and Construction of Early Lead Mini Fischer-Tropsch Refinery

374

Development of the Shell-Koppers Coal Gasification Process [and Discussion  

Science Journals Connector (OSTI)

...research-article Development of the Shell-Koppers...entrained-bed technology, is characterized...production of a clean gas without by-products...featuring both gas and steam turbines. The integration...feed coals. The development programme includes...

1981-01-01T23:59:59.000Z

375

Polygeneration of Liquid Fuels and Electricity by the Atmospheric Pressure Hybrid Solar Gasification of Coal  

Science Journals Connector (OSTI)

(16, 17, 29, 30) The technical viability of the atmospheric pressure, windowed solar vortex reactor to gasify petroleum coke (petcoke) has been demonstrated on a small scale,(16, 29, 31) and a 300 kW pilot scale reactor has also been tested successfully. ... Inputs to the reactor were the model coal (as discussed above), nitrogen used for the carrier gas for the coal feed, steam used as a gasifying agent, and oxygen that is needed when ? gas turbine for electricity generation. ...

Ashok A. Kaniyal; Philip J. van Eyk; Graham J. Nathan; Peter J. Ashman; Jonathan J. Pincus

2013-05-20T23:59:59.000Z

376

Char–Wall Interaction and Properties of Slag Waste in Entrained-Flow Gasification of Coal  

Science Journals Connector (OSTI)

The poor degree of carbon burnoff, which characterizes slag fines, might be the consequence of a combination of factors: (a) selective accumulation of the less reactive carbon particles (e.g., residual petcoke) in the dense-dispersed phase, once the more reactive ones have been gasified; (b) loss of gasification reactivity of carbon because of the severe heat treatment (thermal annealing) experienced by char particles over their lifetime in the gasifier;(18, 19) and (c) occurrence of char agglomeration phenomena during bulk-to-wall transfer and in the near-wall region, possibly promoted by the molten or semi-molten status of char particles. ...

Fabio Montagnaro; Paola Brachi; Piero Salatino

2011-07-25T23:59:59.000Z

377

Phase Equilibria in Synthetic Coal–Petcoke Slags (Al2O3–CaO–FeO–SiO2–V2O3) under Simulated Gasification Conditions  

Science Journals Connector (OSTI)

Phase Equilibria in Synthetic Coal–Petcoke Slags (Al2O3–CaO–FeO–SiO2–V2O3) under Simulated Gasification Conditions ... Phase equilibria of the Al2O3–CaO–FeO–SiO2–V2O3 system in synthetic slag mixtures simulating coal–petcoke slag chemistry at 1500 °C in an oxygen partial pressure of 10–8 atm were investigated by a series of quench experiments. ... Petroleum coke or petcoke is a waste product of petroleum refining and is an attractive feedstock alternative for carbon. ...

Jinichiro Nakano; Kyei-Sing Kwong; James Bennett; Thomas Lam; Laura Fernandez; Piyamanee Komolwit; Seetharaman Sridhar

2011-06-17T23:59:59.000Z

378

Toward Novel Hybrid Biomass, Coal, and Natural Gas Processes for Satisfying Current Transportation Fuel Demands, 1: Process Alternatives, Gasification Modeling, Process Simulation, and Economic Analysis  

Science Journals Connector (OSTI)

Toward Novel Hybrid Biomass, Coal, and Natural Gas Processes for Satisfying Current Transportation Fuel Demands, 1: Process Alternatives, Gasification Modeling, Process Simulation, and Economic Analysis ... This paper, which is the first part of a series of papers, introduces a hybrid coal, biomass, and natural gas to liquids (CBGTL) process that can produce transportation fuels in ratios consistent with current U.S. transportation fuel demands. ... Steady-state process simulation results based on Aspen Plus are presented for the seven process alternatives with a detailed economic analysis performed using the Aspen Process Economic Analyzer and unit cost functions obtained from literature. ...

Richard C. Baliban; Josephine A. Elia; Christodoulos A. Floudas

2010-07-19T23:59:59.000Z

379

Clean coal technologies market potential  

SciTech Connect

Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

Drazga, B. (ed.)

2007-01-30T23:59:59.000Z

380

Coal gasification system with a modulated on/off control system  

DOE Patents (OSTI)

A modulated control system is provided for improving regulation of the bed level in a fixed-bed coal gasifier into which coal is fed from a rotary coal feeder. A nuclear bed level gauge using a cobalt source and an ion chamber detector is used to detect the coal bed level in the gasifier. The detector signal is compared to a bed level set point signal in a primary controller which operates in proportional/integral modes to produce an error signal. The error signal is modulated by the injection of a triangular wave signal of a frequency of about 0.0004 Hz and an amplitude of about 80% of the primary deadband. The modulated error signal is fed to a triple-deadband secondary controller which jogs the coal feeder speed up or down by on/off control of a feeder speed change driver such that the gasifier bed level is driven toward the set point while preventing excessive cycling (oscillation) common in on/off mode automatic controllers of this type. Regulation of the bed level is achieved without excessive feeder speed control jogging.

Fasching, George E. (Morgantown, WV)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

DOE - Office of Legacy Management -- Hoe Creek Underground Coal...  

Office of Legacy Management (LM)

Hoe Creek Underground Coal Gasification Site - 045 FUSRAP Considered Sites Site: Hoe Creek Underground Coal Gasification Site (045) Designated Name: Alternate Name: Location:...

382

MARKET-BASED ADVANCED COAL POWER SYSTEMS FINAL REPORT  

NLE Websites -- All DOE Office Websites (Extended Search)

MARKET-BASED ADVANCED MARKET-BASED ADVANCED COAL POWER SYSTEMS FINAL REPORT MAY 1999 DOE/FE-0400 U.S. Department of Energy Office of Fossil Energy Washington, DC 20585 Market-Based Advanced Coal Power Systems 1-1 December 1998 1. INTRODUCTION As deregulation unfolds and privatization of the utility market takes shape, priorities for power plant economics have shifted toward those of a "bottom-line" business and away from a regulated industry. Competition in utility generation and the exposure risks of large capital investments have led to a preference to minimize capital costs and fixed and variable operation and maintenance costs. With global competition from independent power producers (IPPs), non- utility generators, and utilities, the present trend of investments is with conventional pulverized

383

NETL: News Release - DOE Advances Production of Hydrogen from Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

6 , 2006 6 , 2006 DOE Advances Production of Hydrogen from Coal Projects Selected to Address Technological Challenges of Hydrogen Production in Large-Scale Facilities WASHINGTON, DC - The Department of Energy today announced the selection of six research and development projects that will promote the production of hydrogen from coal at large-scale facilities. This central approach will combat climate change by allowing for the capture - and subsequent sequestration - of carbon dioxide generated during hydrogen production. The selections support President Bush's Hydrogen Fuel Initiative, which provides funding for research and technology development to realize a future hydrogen economy that minimizes America's dependence on foreign oil and reduces greenhouse gas emissions.

384

Numerical Simulation and Evaluation of Cavity Growth in In Situ Coal Gasification  

Science Journals Connector (OSTI)

Park and Edgar(11) developed an unsteady 1D model with a moving burning front based on the work of Massaquoi and Riggs(10) to describe lateral cavity growth in UCG (with flow perpendicular to the coal surface). ... Abdel-Hadi and Hsu(12) extended previous coal block models by developing pseudo-2D geometry with a moving burn front. ... In this case with low oxygen availability, the amount of combustion cannot supply enough heat, and the reactions that cause the cavity growth gradually stop after turning off the burner at 3000 s. Figure 11b shows the variation of the heating value of the produced syngas with time. ...

Ahad Sarraf Shirazi; Shayan Karimipour; Rajender Gupta

2013-07-26T23:59:59.000Z

385

Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains  

SciTech Connect

Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

1987-04-01T23:59:59.000Z

386

A parametric study on coal gasification for the production of syngas  

Science Journals Connector (OSTI)

In this parametric study, the effects of coal and oxidiser type, air-to-fuel ratio, steam-to-fuel ratio, reactor temperature, and pressure on H2 and CO amounts at the gasifier output, H2/CO, and higher heating va...

Afsin Gungor; Murat Ozbayoglu; Cosku Kasnakoglu; Atilla Biyikoglu…

2012-07-01T23:59:59.000Z

387

Development of biological coal gasification (MicGAS Process). Quarterly report, January--March 1995  

SciTech Connect

This paper reports on the progress of several subtasks of the project. Another test with dual bioreactors was started to confirm the results obtained previously. Coal samples from the experiment in upflow bioreactors were characterized for mineral content. Solid residues from the bioreactor experiment were analyzed for humic acid content. Results are given for all three investigations.

NONE

1995-04-01T23:59:59.000Z

388

Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy  

SciTech Connect

Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

2009-03-15T23:59:59.000Z

389

GEOTECHNICAL/GEOCHEMICAL CHARACTERIZATION OF ADVANCED COAL PROCESS WASTE STREAMS  

SciTech Connect

Thirteen solid wastes, six coals and one unreacted sorbent produced from seven advanced coal utilization processes were characterized for task three of this project. The advanced processes from which samples were obtained included a gas-reburning sorbent injection process, a pressurized fluidized-bed coal combustion process, a coal-reburning process, a SO{sub x}, NO{sub x}, RO{sub x}, BOX process, an advanced flue desulfurization process, and an advanced coal cleaning process. The waste samples ranged from coarse materials, such as bottom ashes and spent bed materials, to fine materials such as fly ashes and cyclone ashes. Based on the results of the waste characterizations, an analysis of appropriate waste management practices for the advanced process wastes was done. The analysis indicated that using conventional waste management technology should be possible for disposal of all the advanced process wastes studied for task three. However, some wastes did possess properties that could present special problems for conventional waste management systems. Several task three wastes were self-hardening materials and one was self-heating. Self-hardening is caused by cementitious and pozzolanic reactions that occur when water is added to the waste. All of the self-hardening wastes setup slowly (in a matter of hours or days rather than minutes). Thus these wastes can still be handled with conventional management systems if care is taken not to allow them to setup in storage bins or transport vehicles. Waste self-heating is caused by the exothermic hydration of lime when the waste is mixed with conditioning water. If enough lime is present, the temperature of the waste will rise until steam is produced. It is recommended that self-heating wastes be conditioned in a controlled manner so that the heat will be safely dissipated before the material is transported to an ultimate disposal site. Waste utilization is important because an advanced process waste will not require ultimate disposal when it is put to use. Each task three waste was evaluated for utilization potential based on its physical properties, bulk chemical composition, and mineral composition. Only one of the thirteen materials studied might be suitable for use as a pozzolanic concrete additive. However, many wastes appeared to be suitable for other high-volume uses such as blasting grit, fine aggregate for asphalt concrete, road deicer, structural fill material, soil stabilization additives, waste stabilization additives, landfill cover material, and pavement base course construction.

Edwin S. Olson; Charles J. Moretti

1999-11-01T23:59:59.000Z

390

The proceedings of the 31st international technical conference on coal utilization and fuel systems  

SciTech Connect

Topics covered include oxy-fuel, gasification, CO{sub 2} sequestration, coal preparation, opportunities and barriers for overall energy efficiency improvement, advanced sensors and controls, co-firing, computer simulations and virtual power plants, hydrogen fuels from coal, advanced materials, combustion optimisation, innovations for existing power plants, CO{sub 2} capture, biomass, alternative methods of hydrogen production, NOx control, mercury, low NOx technology, coal to liquids, and coal compatible fuel cells.

Sakkestad, B.A. (ed.)

2006-07-01T23:59:59.000Z

391

Coal pump  

DOE Patents (OSTI)

A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

1983-01-01T23:59:59.000Z

392

Engineering support services for the DOE/GRI (Gas Research Institute) Coal Gasification Research Program: Quarterly report, March 28--June 26, 1987  

SciTech Connect

The following joint program projects comprised the scope of Foster Wheeler's current monitoring activities: KRW Energy System, Inc.-- Fluidized-Bed Gasification Process Development Unit (PDU), Madison, Pennsylvania. CNG Research Company--Acid Gas Removal System, Cleveland, Ohio. The test program in KRW's fluidized-bed gasifier PDU was resumed, following shutdown for winter maintenance. During this quarter, CNG completed construction on the new flash crystallizer PDU and started shakedown testing of the unit. Details of Foster Wheeler's monitoring activities on these projects are presented in Sections 3.0 and 4.0 of this report. Under the technical evaluation scope of modular integrated coal gasification combined cycle (IGCC) power systems. This study was authorized by DOE in mid-March 1987 and was initiated during the current period. Discussions on the status of the IGCC systems study is included in Section 5.0 of this report. 4 refs.

Mazzella, G.

1987-07-01T23:59:59.000Z

393

Power Systems Development Facility Gasification Test Campaign TC16  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report discusses Test Campaign TC16 of the PSDF gasification process. TC16 began on July 14, 2004, lasting until August 24, 2004, for a total of 835 hours of gasification operation. The test campaign consisted of operation using Powder River Basin (PRB) subbituminous coal and high sodium lignite from the North Dakota Freedom mine. The highest gasifier operating temperature mostly varied from 1,760 to 1,850 F with PRB and 1,500 to 1,600 F with lignite. Typically, during PRB operations, the gasifier exit pressure was maintained between 215 and 225 psig using air as the gasification oxidant and between 145 and 190 psig while using oxygen as the oxidant. With lignite, the gasifier operated only in air-blown mode, and the gasifier outlet pressure ranged from 150 to 160 psig.

Southern Company Services

2004-08-24T23:59:59.000Z

394

NETL: Coal and Coal/Biomass to Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

C&CBTL C&CBTL Coal and Power Systems Coal and Coal/Biomass to Liquids The Coal and Coal/Biomass to Liquids program effort is focused on technologies to foster the commercial adoption of coal and coal/biomass gasification and the production of affordable liquid fuels and hydrogen with excellent environmental performance. U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness Advanced Fuels Synthesis U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness U.S. Economic Competitiveness Advanced Fuels Synthesis Systems Analyses Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits Global Environmental Benefits

395

Clean coal technologies in electric power generation: a brief overview  

SciTech Connect

The paper talks about the future clean coal technologies in electric power generation, including pulverized coal (e.g., advanced supercritical and ultra-supercritical cycles and fluidized-bed combustion), integrated gasification combined cycle (IGCC), and CO{sub 2} capture technologies. 6 refs., 2 tabs.

Janos Beer; Karen Obenshain [Massachusetts Institute of Technology (MIT), MA (United States)

2006-07-15T23:59:59.000Z

396

Advanced Development Of The Coal Fired Oxyfuel Process With CO2...  

Open Energy Info (EERE)

Development Of The Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name: Advanced Development Of The Coal-Fired Oxyfuel Process With CO2...

397

Slang characterization and removal using pulse detonation technology during coal gasification  

SciTech Connect

Boiler slagging and fouling as a result of inorganic impurities in combustion gases being deposited on heat transfer tubes have caused severe problems in coal-fired power plant operation. These problems are fuel, system design, and operating condition dependent. Pulse detonation technology for the purpose of removing slag and fouling deposits in coal-fired utility power plant boilers offers great potential. The detonation wave technique based on high impact velocity with sufficient energy and thermal shock on the slag deposited on gas contact surfaces offers a convenient, inexpensive, yet efficient and effective way to supplement existing slag removal methods. These detonation waves have been demonstrated experimentally to have exceptionally high shearing capability important to the task of removing slag and fouling deposits. The experimental results show that the single shot detonation wave is capable of removing the entire slag (types of slag deposited on economizer) even at a distance of 8 in. from the exit of a detonation engine tube. Wave strength and slag orientation also have different effects on the chipping off of the slag. This paper discusses about the results obtained in effectively removing the economizer slag.

Huque, Z.; Mei, D.; Biney, P.O.; Zhou, J.

1997-03-25T23:59:59.000Z

398

Development of Biological Coal Gasification (MicGAS Process). Topical report, July 1991--February 1993  

SciTech Connect

Laboratory and bench scale reactor research carried out during the report period confirms the feasibility of biomethanation of Texas lignite (TxL) and some other low-rank coals to methane by specifically developed unique anaerobic microbial consortia. The data obtained demonstrates specificity of a particular microbial consortium to a given lignite. Development of a suitable microbial consortium is the key to the success of the process. The Mic-1 consortium was developed to tolerate higher coal loadings of 1 and 5% TxL in comparison to initial loadings of 0.01% and 0.1% TxL. Moreover, the reaction period was reduced from 60 days to 14 to 21 days. The cost of the culture medium for bioconversion was reduced by studying the effect of different growth factors on the biomethanation capability of Mic-1 consortium. Four different bench scale bioreactor configurations, namely Rotating Biological Contactor (RBC), Upflow Fluidized Bed Reactor (UFBR), Trickle Bed Reactor (TBR), and Continuously Stirred Tank Reactor (CSTR) were evaluated for scale up studies. Preliminary results indicated highest biomethanation of TxL by the Mic-1 consortium in the CSTR, and lowest in the trickle bed reactor. However, highest methane production and process efficiency were obtained in the RBC.

Srivastava, K.C.

1993-06-01T23:59:59.000Z

399

An evaluation of integrated-gasification-combined-cycle and pulverized-coal-fired steam plants: Volume 1, Base case studies: Final report  

SciTech Connect

An evaluation of the performance and costs for a Texaco-based integrated gasification combined cycle (IGCC) power plant as compared to a conventional pulverized coal-fired steam (PCFS) power plant with flue gas desulfurization (FGD) is provided. A general set of groundrules was used within which each plant design was optimized. The study incorporated numerous sensitivity cases along with up-to-date operating and cost data obtained through participation of equipment vendors and process developers. Consequently, the IGCC designs presented in this study use the most recent data available from Texaco's ongoing international coal gasification development program and General Electric's continuing gas turbine development efforts. The Texaco-based IGCC has advantages over the conventional PCFS technology with regard to environmental emissions and natural resource requirements. SO/sub 2/, NOx, and particulate emissions are lower. Land area and water requirements are less for IGCC concepts. Coal consumption is less due to the higher plant thermal efficiency attainable in the IGCC plant. The IGCC plant also has the capability to be designed in several different configurations, with and without the use of natural gas or oil as a backup fuel. This capability may prove to be particularly advantageous in certain utility planning and operation scenarios. 107 figs., 114 tabs.

Pietruszkiewicz, J.; Milkavich, R.J.; Booras, G.S.; Thomas, G.O.; Doss, H.

1988-09-01T23:59:59.000Z

400

Advanced Development Of The Coal Fired Oxyfuel Process With CO2 Separation  

Open Energy Info (EERE)

Coal Fired Oxyfuel Process With CO2 Separation Coal Fired Oxyfuel Process With CO2 Separation ADECOS Jump to: navigation, search Name Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) Place Germany Product Dresden based initiative that has been formed to assess oxyfuel CCS technology. References Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS)[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS) is a company located in Germany . References ↑ "Advanced Development Of The Coal-Fired Oxyfuel Process With CO2 Separation (ADECOS)" Retrieved from "http://en.openei.org/w/index.php?title=Advanced_Development_Of_The_Coal_Fired_Oxyfuel_Process_With_CO2_Separation_ADECOS&oldid=341776

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

CO2-gasification of a lignite coal in the presence of an iron-based oxygen carrier for chemical-looping combustion  

Science Journals Connector (OSTI)

Abstract Chemical-looping combustion (CLC) has the inherent property of separating the product CO2 from flue gases. Instead of air, it uses an oxygen carrier, usually in the form of a metal oxide, to provide oxygen for combustion. All techniques so far proposed for chemical looping with solid fuels involve initially the gasification of the solid fuel in order for the gaseous products to react with the oxygen carrier. Here, the rates of gasification of coal were compared when gasification was undertaken in a fluidised bed of either (i) an active Fe-based oxygen carrier used for chemical looping or (ii) inert sand. This enabled an examination of the ability of chemical looping materials to enhance the rate of gasification of solid fuels. Batch gasification and chemical-looping combustion experiments with a German lignite and its char are reported, using an electrically-heated fluidised bed reactor at temperatures from 1073 to 1223 K. The fluidising gas was CO2 in nitrogen. The kinetics of the gasification were found to be significantly faster in the presence of the oxygen carrier, especially at temperatures above 1123 K. A numerical model was developed to account for external and internal mass transfer and for the effect of the looping agent. The model also included the effects of the evolution of the pore structure at different conversions. The presence of Fe2O3 led to an increase in the rate of gasification because of the rapid oxidation of CO by the oxygen carrier to CO2. This resulted in the removal of CO and maintained a higher mole fraction of CO2 in the mixture of gas around the particle of char, i.e. within the mass transfer boundary layer surrounding the particle. This effect was most prominent at about 20% conversion when (i) the surface area for reaction was at its maximum and (ii) because of the accompanying increase in porosity and pore size, intraparticle resistance to gas mass transfer within the particle of char had fallen, compared with that in the initial particle. Excellent agreement was observed between the rates predicted by the numerical model and those observed experimentally.

Marco A. Saucedo; Jin Yang. Lim; John S. Dennis; Stuart A. Scott

2014-01-01T23:59:59.000Z

402

Power Systems Development Facility Gasification Test Campaign TC20  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coal. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of the first demonstration of the Transport Gasifier following significant modifications of the gasifier configuration. This demonstration took place during test campaign TC20, occurring from August 8 to September 23, 2006. The modifications proved successful in increasing gasifier residence time and particulate collection efficiency, two parameters critical in broadening of the fuel operating envelope and advancing gasification technology. The gasification process operated for over 870 hours, providing the opportunity for additional testing of various gasification technologies, such as PCD failsafe evaluation and sensor development.

Southern Company Services

2006-09-30T23:59:59.000Z

403

Utilization of lightweight materials made from coal gasification slags. Quarterly report, September 1, 1996--November 30, 1996  

SciTech Connect

Integrated-gasification combined-cycle (IGCC) technology is an emerging technology that utilizes coal for power generation and production of chemical feedstocks. However, the process generates large amounts of solid waste, consisting of vitrified ash (slag) and some unconverted carbon. In previous projects, Praxis investigated the utilization of {open_quotes}as-generated{close_quotes} slags for a wide variety of applications in road construction, cement and concrete production, agricultural applications, and as a landfill material. From these studies, we found that it would be extremely difficult for {open_quotes}as-generated{close_quotes} slag to find large-scale acceptance in the marketplace even at no cost because the materials it could replace were abundantly available at very low cost. It was further determined that the unconverted carbon, or char, in the slag is detrimental to its utilization as sand or fine aggregate. It became apparent that a more promising approach would be to develop a variety of value-added products from slag that meet specific industry requirements. This approach was made feasible by the discovery that slag undergoes expansion and forms a lightweight material when subjected to controlled heating in a kiln at temperatures between 1400 and 1700{degrees}F. These results confirmed the potential for using expanded slag as a substitute for conventional lightweight aggregates (LWA). The major objectives of the subject project are to demonstrate the technical and economic viability of commercial production of LWA and ULWA from slag and to test the suitability of these aggregates for various applications.

NONE

1997-04-01T23:59:59.000Z

404

Development of biological coal gasification (MicGas process): 12th Quarterly report  

SciTech Connect

Several experiments were conducted to study the efficiency of granulated sludge consortium (GSC) on the biomethanation of Texas lignite (TxL). With an aim of obtaining a better culture than Mic-1, GSC was used as inoculum at different concentrations. The first experiment was conducted under anaerobic conditions in 60-mL vials containing 40 mL 0.01% SNTM + 1% TxL + 10% GSC. Methane production was measured periodically in the vial headspace and after 20 days of incubation, methane was found to be up to 67 mole%. The second experiment was conducted to determine whether methane production was from biogasification of coal or from substrates used for growing the GSC. The effect of two different anaerobic conditions on biomethanation of Texas lignite was also studied.

Not Available

1993-07-29T23:59:59.000Z

405

Power generation plants with carbon capture and storage: A techno-economic comparison between coal combustion and gasification technologies  

Science Journals Connector (OSTI)

Abstract Worldwide energy production requirements could not be fully satisfied by nuclear and renewables sources. Therefore a sustainable use of fossil fuels (coal in particular) will be required for several decades. In this scenario, carbon capture and storage (CCS) represents a key solution to control the global warming reducing carbon dioxide emissions. The integration between CCS technologies and power generation plants currently needs a demonstration at commercial scale to reduce both technological risks and high capital and operating cost. This paper compares, from the technical and economic points of view, the performance of three coal-fired power generation technologies: (i) ultra-supercritical (USC) plant equipped with a conventional flue gas treatment (CGT) process, (ii) USC plant equipped with SNOX technology for a combined removal of sulphur and nitrogen oxides and (iii) integrated gasification combined cycle (IGCC) plant based on a slurry-feed entrained-flow gasifier. Each technology was analysed in its configurations without and with CO2 capture, referring to a commercial-scale of 1000 MWth. Technical assessment was carried out by using simulation models implemented through Aspen Plus and Gate-Cycle tools, whereas economic assessment was performed through a properly developed simulation model. USC equipped with CGT systems shows an overall efficiency (43.7%) comparable to IGCC (43.9%), whereas introduction of SNOX technology increases USC efficiency up to 44.8%. Being the CCS energy penalties significantly higher for USC (about 10.5% points vs. about 8.5 for IGCC), the IGCC with CCS is more efficient (35.3%) than the corresponding CO2-free USC (34.2% for the SNOX-based configuration). Whereas, for the case study, USC is most profitable than IGCC (with a net present value, NPV, of 190 M€ vs. 54 M€) for a conventional configuration, CO2-free IGCC shows a higher NPV (?673 M€) than USC (?711 M€). In any cases, the NPV of all the CO2-free configurations is strongly negative: this means that, with the current market conditions, the introduction of a CCS system cannot be economically justified without a significant incentive.

Vittorio Tola; Alberto Pettinau

2014-01-01T23:59:59.000Z

406

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Conditioning Conditioning Sulfur Recovery and Tail Gas Treating Sulfur is a component of coal and other gasification feed stocks. Sulfur compounds need to be removed in most gasification applications due to environmental regulations or to avoid catalyst poisoning. Whether it is electricity, liquid fuels, or some other product being output, sulfur emissions are regulated, and sulfur removal is important for this reason, along with the prevention of downstream component fouling. In addition to these constraints, recovering saleable sulfur is an important economic benefit for a gasification plant. To illustrate the previous point, in 2011 8.1 million tons of elemental sulfur was produced, with the majority of this coming from petroleum refining, natural gas processing and coking plants. Total shipments were valued at $1.6 billion, with the average mine or plant price of $200 per ton, up from $70.48 in 2010. The United States currently imports sulfur (36% of consumption, mostly from Canada), meaning the market can support more domestic sulfur production.

407

"Integrated Gasification Combined Cycle"  

U.S. Energy Information Administration (EIA) Indexed Site

Status of technologies and components modeled by EIA" Status of technologies and components modeled by EIA" ,"Revolutionary","Evolutionary","Mature" "Pulverized Coal",,,"X" "Pulverized Coal with CCS" " - Non-CCS portion of Pulverized Coal Plant",,,"X" " - CCS","X" "Integrated Gasification Combined Cycle" " - Advanced Combustion Turbine",,"X" " - Heat Recovery Steam Generator",,,"X" " - Gasifier",,"X" " - Balance of Plant",,,"X" "Conventional Natural Gas Combined Cycle" " - Conventional Combustion Turbine",,,"X" " - Heat Recovery Steam Generator",,,"X" " - Balance of Plant",,,"X"

408

Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992  

SciTech Connect

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-12-31T23:59:59.000Z

409

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Power: Typical IGCC Configuration Power: Typical IGCC Configuration Major Commercial Examples of IGCC Plants While there are many coal gasification plants in the world co-producing electricity, chemicals and/or steam, the following are four notable, commercial-size IGCC plants currently in operation solely for producing electricity from coal and/or coke. Tampa Electric, Polk County 250 MW GE Gasifier Wabash, West Terre Haute 265 MW CoP E-Gas(tm) Gasifier Nuon, Buggenum 250 MW Shell Gasifier Elcogas, Puertollano 300 MW Prenflo Gasifier All of the plants began operation prior to 2000 and employ high temperature entrained-flow gasification technology. GE (formerly Texaco-Chevron) and ConocoPhillips (CoP) are slurry feed gasifiers, while Shell and Prenflo are dry feed gasifiers. None of these plants currently capture carbon dioxide (CO2). A simplified process flow diagram of the 250-MW Tampa Electric IGCC plant is shown in Figure 1 to illustrate the overall arrangement of an operating commercial scale IGCC plant. The Tampa Electric plant is equipped with both radiant and convective coolers for heat recovery, generating high pressure (HP) steam.

410

Development of high energy density fuels from mild gasification of coal  

SciTech Connect

The overall objective of the program is the determination of the minimal processing requirements to produce High Energy Density Fuels (HEDF), meeting a minimal energy density of 130,000 Btu/gal (conventional jet fuels have energy densities in the vicinity of 115,000--120,000 Btu/gal) and having acceptable advanced fuel specifications in accordance with the three defined categories of HEDF. The program encompasses assessing current technology capability; selecting acceptable processing and refining schemes; and generating samples of advanced test fuels. A task breakdown structure was developed containing eight key tasks. This report summarizes the work that Amoco Oil Company (AOC), as key subcontractor, performed in the execution of Task 4, Proposed Upgrading Schemes for Advanced Fuel. The intent of the Task 4 study was to represent all the candidate processing options, that were either studied in the experimental efforts of Task 3 or were available from the prior art in the open literature, in a linear program (LP) model. The LP model would allow scaling of the bench-scale Task 3 results to commercial scale and would perform economic evaluations on any combination of the processes which might be used to make HEDF. Section 2.0 of this report summarizes the process and economic bases used. Sections 3.0 and 4.0 details the economics and processing sensitivities for HEDF production. 1 ref., 15 figs., 9 tabs.

Not Available

1990-10-01T23:59:59.000Z

411

E-Print Network 3.0 - advanced coal preparation Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Utilization Summary: Center for By-Products Utilization RECENT ADVANCES IN RECYCLING CLEAN- COAL ASH By Tarun R. Naik... investigation. Two additional ash samples were prepared by...

412

Economic feasibility study: CFR advanced direct coal liquefaction process. Volume 4  

SciTech Connect

Preliminary technical and economic data are presented on the CFR Advanced Coal Liquefaction Process. Operating cost estimates and material balances are given.

Not Available

1994-09-01T23:59:59.000Z

413

Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, July--September 1992  

SciTech Connect

Progress made in five research programs is described. The subtasks in oil shale study include oil shale process studies and unconventional applications and markets for western oil shale.The tar sand study is on recycle oil pyrolysis and extraction (ROPE) process. Four tasks are described in coal research: underground coal gasification; coal combustion; integrated coal processing concepts; and sold waste management. Advanced exploratory process technology includes: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research covers: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; shallow oil production using horizontal wells with enhanced oil recovery techniques; NMR analysis of sample from the ocean drilling program; and menu driven access to the WDEQ hydrologic data management system.

Not Available

1992-12-31T23:59:59.000Z

414

Power Systems Development Facility Gasification Test Campaign TC24  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC24, the first test campaign using a bituminous coal as the feedstock in the modified Transport Gasifier configuration. TC24 was conducted from February 16, 2008, through March 19, 2008. The PSDF gasification process operated for about 230 hours in air-blown gasification mode with about 225 tons of Utah bituminous coal feed. Operational challenges in gasifier operation were related to particle agglomeration, a large percentage of oversize coal particles, low overall gasifier solids collection efficiency, and refractory degradation in the gasifier solids collection unit. The carbon conversion and syngas heating values varied widely, with low values obtained during periods of low gasifier operating temperature. Despite the operating difficulties, several periods of steady state operation were achieved, which provided useful data for future testing. TC24 operation afforded the opportunity for testing of various types of technologies, including dry coal feeding with a developmental feeder, the Pressure Decoupled Advanced Coal (PDAC) feeder; evaluating a new hot gas filter element media configuration; and enhancing syngas cleanup with water-gas shift catalysts. During TC24, the PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane.

Southern Company Services

2008-03-30T23:59:59.000Z

415

Steam gasification of coal at low-medium (600-800{sup o}C) temperature with simultaneous CO{sub 2} capture in fluidized bed at atmospheric pressure: The effect of inorganic species. 1. Literature review and comments  

SciTech Connect

This paper addresses the H{sub 2} production with simultaneous CO{sub 2} capture by steam gasification of coal in a fluidized bed, at low/medium temperatures (600-800{sup o}C) and atmospheric pressure. This work is mainly aimed at reviewing the effects of the inorganic species present in the matrix of the coal or added to the gasifier bed. The most promising species seems to be the calcined limestone (CaO), which intervenes in the overall gasification reaction network in at least five different types of reactions. The effectiveness of the CaO for CO{sub 2} capture in the coal gasifier is, therefore, affected/influenced by the other four simultaneous or competitive types of reactions in the gasifier. The effects of the temperature in the gasifier and of the (CaO/coal) ratio fed to the gasifier are finally reviewed and discussed in detail.

Corella, J.; Toledo, J.M.; Molina, G. [Universidad Complutense de Madrid, Madrid (Spain). Dept. for Chemical Engineering

2006-08-30T23:59:59.000Z

416

Development of an advanced continuous mild gasification process for the production of co-products. Final report, September 1987--September 1996  

SciTech Connect

Char, the major co-product of mild coal gasification, represents about 70 percent of the total product yield. The only viable use for the char is in the production of formed coke. Early work to develop formed coke used char from a pilot plant sized mild gasification unit (MGU), which was based on commercial units of the COALITE plant in England. Formed coke was made at a bench-scale production level using MGU chars from different coals. An evolutionary formed coke development process over a two-year period resulted in formed coke production at bench-scale levels that met metallurgical industries` specifications. In an ASTM D5341 reactivity test by a certified lab, the coke tested CRI 30.4 and CSR 67.0 which is excellent. The standard is CRI < 32 and CSR > 55. In 1991, a continuous 1000 pounds per hour coal feed mild coal gasification pilot plant (CMGU) was completed. The gasification unit is a heated unique screw conveyor designed to continuously process plastic coal, vent volatiles generated by pyrolysis of coal, and convert the plastic coal to free flowing char. The screw reactor auxiliary components are basic solids materials handling equipment. The screw reactor will convert coal to char and volatile co-products at a rate greater than 1000 pounds per hour of coal feed. Formed coke from CMGU char is comparable to that from the MGU char. In pilot-plant test runs, up to 20 tons of foundry coke were produced. Three formed coke tests at commercial foundries were successful. In all of the cupola tests, the iron temperature and composition data indicated that the formed coke performed satisfactorily. No negative change in the way the cupola performed was noticed. The last 20-ton test was 100 percent CTC/DOE coke. With conventional coke in this cupola charging rates were 10 charges per hour. The formed coke charges were 11 to 12 charges per hour. This equates to a higher melt rate. A 10 percent increase in cupola production would be a major advantage. 13 figs., 13 tabs.

NONE

1996-12-31T23:59:59.000Z

417

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids  

NLE Websites -- All DOE Office Websites (Extended Search)

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production Southern Research Institute (SRI) Project Number: FE0012054 Project Description The focus of the project will be to develop, test, and optimize steam-reforming catalysts for converting tars, C2+ hydrocarbons, NH3, and CH4 in high-temperature and sulfur environments, increasing the ratio of hydrogen in syngas, as part of a modified, advanced gasification platform for the conversion of low-rank coals to syngas for coal-to-liquid and integrated gasification combined cycle applications. Project Details Program Background and Project Benefits Project Scope and Technology Readiness Level Accomplishments Contacts, Duration, and Cost Project Images Abstract Performer website: Southern Research Institute

418

Chapter 3 - Coal-fired Power Plants  

Science Journals Connector (OSTI)

Abstract Coal provides around 40% of the world’s electricity, more than any other source. Most modern coal-fired power stations burn pulverized coal in a boiler to raise steam for a steam turbine. High efficiency is achieved by using supercritical boilers made of advanced alloys that produce high steam temperatures, and large, high-efficiency steam turbines. Alternative types of coal-fired power plants include fluidized bed boilers that can burn a variety of poor fuels, as well as coal gasifiers that allow coal to be turned into a combustible gas that can be burned in a gas turbine. Emissions from coal plants include sulfur dioxide, nitrogen oxide, and trace metals, all of which must be controlled. Capturing carbon dioxide from a coal plant is also under consideration. This can be achieved using post-combustion capture, a pre-combustion gasification process, or by burning coal in oxygen instead of air.

Paul Breeze

2014-01-01T23:59:59.000Z

419

Survey of tar sand deposits, heavy oil fields, and shallow light oil fields of the United States for underground coal gasification applications  

SciTech Connect

A literature survey was conducted to identify areas of the United States where tar sand deposits, heavy oil fields, or shallow light oil fields might be suitably associated with coal deposits for production of oil by in situ thermal recovery methods using heat derived from underground coal gasification (UCG) processes. The survey is part of a Department of Energy-sponsored program to develop new applications for UCG technology in utilizing coal resources that are unattractive for mining. Results from the survey indicate tar sand deposits, heavy oil fields, or light oil fields are probably or possibly located within 5 miles of suitable coal in 17 states (Table 1). Especially promising areas are in the Uinta Basin of Utah; the North Slope of Alaska; the San Miguel deposit in southwest Texas; the Illinois-Eastern Interior Basin area of western Kentucky, southwestern Indiana and Illinois; the tri-state area of Missouri, Kansas and Oklahoma; and the northern Appalachian Basin in eastern Ohio and northwestern Pennsylvania. The deposits in these areas warrant further evaluation. 30 refs., 4 figs., 1 tab.

Trudell, L.G.

1986-06-01T23:59:59.000Z

420

In situ gasification chemical looping combustion of a coal using the binary oxygen carrier natural anhydrite ore and natural iron ore  

Science Journals Connector (OSTI)

Abstract CaSO4 is an attractive oxygen carrier for Chemical–looping combustion (CLC), because of its high oxygen capacity and low price. But the utilization of CaSO4 oxygen carrier suffers the problems of low reactivity, deactivation caused by sulfur loss and the incomplete fuel conversion due to the thermodynamic limitations. To improve the stability and reactivity of CaSO4 oxygen carrier, a small amount of natural iron ore were added in. The kinetic behavior and thermodynamics of the reduction of the binary oxygen carrier by coal under steam atmosphere were investigated. The results show that Fe2O3 improves the performance of coal gasification and the subsequent conversion of coal syngas to CO2 and H2O. Besides, the addition of Fe2O3 reduces the chance of CaSO4 reduction to CaO by coal syngas, and the oxygen transfer capacity of CaSO4 is maintained. The optimal reaction conditions in fuel reactor are shifted from 950 °C without Fe2O3 to 900 °C with 7% Fe2O3. And the decreases in CO, SO2 and H2S environmental factors can be well up to 81.48%, 76.35% and 100%, respectively. Meanwhile, the CO2 concentration in the dry gas products increases from 81.63% up to 95.35%.

Min Zheng; Laihong Shen; Xiaoqiong Feng

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced coal gasification" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

Science Journals Connector (OSTI)

These two coals represent the two main types of non-lignite coals currently used in the U.S.: a medium-sulfur eastern bituminous coal and a low-sulfur western sub-bituminous coal. ... At a commercial scale, this would likely mean that there could be a roughly 3-fold decrease in the size of the gasifier compared to the case of dry mixing coal and the regenerated calcium oxide. ...

Nicholas S. Siefert; Dushyant Shekhawat; Shawn Litster; David A. Berry

2013-03-03T23:59:59.000Z

422

Low-rank coal research. Quarterly report, January--March 1990  

SciTech Connect

This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

Not Available

1990-08-01T23:59:59.000Z

423

EIS-0432: Department of Energy Loan Guarantee for Medicine Bow Gasification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2: Department of Energy Loan Guarantee for Medicine Bow 2: Department of Energy Loan Guarantee for Medicine Bow Gasification and Liquefaction Coal-to-Liquids, Carbon County, Wyoming EIS-0432: Department of Energy Loan Guarantee for Medicine Bow Gasification and Liquefaction Coal-to-Liquids, Carbon County, Wyoming Summary DOE is assessing the potential environmental impacts for its proposed action of issuing a Federal loan guarantee to Medicine Bow Fuel & Power LLC (MBFP), a wholly-owned subsidiary of DKRW Advanced Fuels LLC. MBFP submitted an application to DOE under the Federal loan guarantee program pursuant to the Energy Policy Act of 2005 to support the construction and startup of the MBFP coal-to-liquids facility, a coal mine and associated coal handling facilities. Public Comment Opportunities No public comment opportunities available at this time.

424

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network (OSTI)

July 22, 1974. Project Western Coal: Conversion of Coal Intoand Gasification of Western Coals", in proceedings of ERDA/Investigators' Conference - Coal Research, Colorado School

Holten, R.R.

2010-01-01T23:59:59.000Z

425

EIS-0428: Mississippi Gasification, LLC, Industrial Gasification...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS...

426

Gasification world database 2007. Current industry status  

SciTech Connect

Information on trends and drivers affecting the growth of the gasification industry is provided based on information in the USDOE NETL world gasification database (available on the www.netl.doe.gov website). Sectors cover syngas production in 2007, growth planned through 2010, recent industry changes, and beyond 2010 - strong growth anticipated in the United States. A list of gasification-based power plant projects, coal-to-liquid projects and coal-to-SNG projects under consideration in the USA is given.

NONE

2007-10-15T23:59:59.000Z

427

Gasification Product Improvement Facility (GPIF). Final report  

SciTech Connect

The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

NONE

1995-09-01T23:59:59.000Z

428

Power Systems Development Facility Gasification Test Campaing TC18  

SciTech Connect

In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

Southern Company Services

2005-08-31T23:59:59.000Z

429

Engineering development of advanced physical fine coal cleaning for premium fuel applications  

SciTech Connect

The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

Shields, G.L.; Smit, F.J.; Jha, M.C.

1997-08-28T23:59:59.000Z

430

Advanced Coal-Fueled Gas Turbine Program. Final report  

SciTech Connect

The objective of the original Request for Proposal was to establish the technological bases necessary for the subsequent commercial development and deployment of advanced coal-fueled gas turbine power systems by the private sector. The offeror was to identify the specific application or applications, toward which his development efforts would be directed; define and substantiate the technical, economic, and environmental criteria for the selected application; and conduct such component design, development, integration, and tests as deemed necessary to fulfill this objective. Specifically, the offeror was to choose a system through which ingenious methods of grouping subcomponents into integrated systems accomplishes the following: (1) Preserve the inherent power density and performance advantages of gas turbine systems. (2) System must be capable of meeting or exceeding existing and expected environmental regulations for the proposed application. (3) System must offer a considerable improvement over coal-fueled systems which are commercial, have been demonstrated, or are being demonstrated. (4) System proposed must be an integrated gas turbine concept, i.e., all fuel conditioning, all expansion gas conditioning, or post-expansion gas cleaning, must be integrated into the gas turbine system.

Horner, M.W.; Ekstedt, E.E.; Gal, E.; Jackson, M.R.; Kimura, S.G.; Lavigne, R.G.; Lucas, C.; Rairden, J.R.; Sabla, P.E.; Savelli, J.F.; Slaughter, D.M.; Spiro, C.L.; Staub, F.W.

1989-02-01T23:59:59.000Z

431

Low-rank coal research semiannual report, January 1992--June 1992  

SciTech Connect

This semiannual report is a compilation of seventeen reports on ongoing coal research at the University of North Dakota. The following research areas are covered: control technology and coal preparation; advanced research and technology development; combustion; liquefaction and gasification. Individual papers have been processed separately for inclusion in the Energy Science and Technology Database.

Not Available

1992-12-31T23:59:59.000Z

432

Steam Gasification of Coal at Low?Medium (600?800 °C) Temperature with Simultaneous CO2 Capture in a Bubbling Fluidized Bed at Atmospheric Pressure. 2. Results and Recommendations for Scaling Up  

Science Journals Connector (OSTI)

Steam Gasification of Coal at Low?Medium (600?800 °C) Temperature with Simultaneous CO2 Capture in a Bubbling Fluidized Bed at Atmospheric Pressure. ... Once the existence of segregation in the bed of the gasifier with the particles' sizes used for coal and for the CaO in the preliminary tests are confirmed and analyzed, the particle size of the coal was increased to 0.4?2.0 ... In general small differences in d. readily lead to segregation while quite differently sized particles are fairly easily mixed. ...

Jose Corella; Jose M. Toledo; Gregorio Molina

2008-02-15T23:59:59.000Z

433

Economic evaluations of coal-based combustion and gasification power plants with post-combustion CO2 capture using calcium looping cycle  

Science Journals Connector (OSTI)

Abstract Coal-based power generation sector is facing important changes to implement energy efficient carbon capture technologies to comply with emission reduction targets for transition to low carbon economy. This paper assesses CaL (Calcium Looping) as one of the innovative carbon capture options able to deliver low energy and cost penalties. The work evaluates how the integration of post-combustion calcium looping influences the economics of power plants providing up-dated techno-economic indicators. Coal-based combustion plants operated in both sub- and super-critical steam conditions were evaluated, as well as coal gasification plant using an oxygen-blown entrained-flow gasifier. As benchmark options used to quantify the carbon capture energy and cost penalties, the same power generation technologies were evaluated without CCS (Carbon capture and storage). The power plant concepts investigated in the paper generates around 545–560 MW net power with at least 90% carbon capture rate. Introduction of CaL technology for CO2 capture results in a 24–42% increase of specific capital investment, the O&M costs are increasing with 24–30% and the electricity cost with 39–48% (all compared to non-CCS cases). As the techno-economic results suggest, CaL has good application potential in combustion-based power generation.

Calin-Cristian Cormos

2014-01-01T23:59:59.000Z

434

NETL: Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Capture R&D Capture R&D DOE/NETL's pre-combustion CO2 control technology portfolio of R&D projects is examining various CO2 capture technologies, and supports identification of developmental pathways linking advanced fossil fuel conversion and CO2 capture. The Program's CO2 capture activity is being conducted in close coordination with that of advanced, higher-efficiency power generation and fossil fuel conversion technologies such as gasification. Links to the projects can be found here. Finally, an exhaustive and periodically updated report on CO2 capture R&D sponsored by NETL is available: DOE/NETL Advanced CO2 Capture R&D Program: Technology Update (also referred to as the CO2 Handbook). Carbon Dioxide CO2 Capture Commercial CO2 Uses & Carbon Dioxide Enhanced Oil Recovery

435

Development of an advanced, continuous mild gasification process for the production of co-products: Topical report  

SciTech Connect

Research on mild gasification is discussed. The report is divided into three sections: literature survey of mild gasification processes; literature survey of char, condensibles, and gas upgrading and utilization methods; and industrial market assessment of products of mild gasification. Recommendations are included in each section. (CBS) 248 refs., 58 figs., 62 tabs.

Cha, C.Y.; Merriam, N.W.; Jha, M.C.; Breault, R.W.

1988-06-01T23:59:59.000Z

436

Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993  

SciTech Connect

This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

1995-09-01T23:59:59.000Z

437

Advanced Systems for Preprocessing and Characterizing Coal-Biomass Mixtures as Next-Generation Fuels and Feedstocks  

SciTech Connect

The research activities presented in this report are intended to address the most critical technical challenges pertaining to coal-biomass briquette feedstocks. Several detailed investigations were conducted using a variety of coal and biomass feedstocks on the topics of (1) coal-biomass briquette production and characterization, (2) gasification of coal-biomass mixtures and briquettes, (3) combustion of coal-biomass mixtures and briquettes, and (4) conceptual engineering des