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1

Advanced Cathode Material Development for PHEV Lithium Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries High Energy Novel Cathode Alloy Automotive Cell Develop & evaluate...

2

Advanced Cathode Catalysts and Supports for  

E-Print Network [OSTI]

1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells Mark K. Debe 3M Company May 10, 2011 restricted information 2011 Annual Merit Review DOE Hydrogen and Fuel Cells and Vehicle Technologies Programs.125 Performance @ Rated (W/cm2 ) @ 0.8V 1 0.25 1 0.25 Additional Interactions GM Fuel Cell Activities, Nuvera Fuel

3

Advanced Cathode Material Development for PHEV Lithium Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries Vehicle Technologies Office Merit Review 2014: High Energy Novel...

4

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

E-Print Network [OSTI]

1 Advanced Cathode Catalysts and Supports for PEM Fuel Cells Mark K. Debe 3M Company May 15, 2012 group) Project Management - 3M (A. Steinbach, M. Kurkowski, S. Hendricks, A. Hester, P. Kadera, G

5

Cathodes  

Broader source: Energy.gov (indexed) [DOE]

- Y. Shao-Horn, C. Carlton (MIT) - M. Balasubramanian (APS- ANL) - V. Battaglia (LBNL), Jose M. Calderon- Moreno (Romanian Academy) 3 Objectives Design high capacity,...

6

advanced cathode material: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

materials. unknown authors 6 Short communication Mesoporous nitrogen-rich carbon materials as cathode catalysts in Energy Storage, Conversion and Utilization Websites Summary:...

7

Advanced Reactor Thermal Hydraulic Modeling | Argonne Leadership...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fischer (ANL), Aleks Obabko (ANL), and Hank Childs (LBNL) Advanced Reactor Thermal Hydraulic Modeling PI Name: Paul Fischer PI Email: fischer@mcs.anl.gov Institution: Argonne...

8

Advanced Measurement and Modeling Techniques for Improved SOFC Cathodes  

SciTech Connect (OSTI)

The goal of this project was to develop an improved understanding of factors governing performance and degradation of mixed-conducting SOFC cathodes. Two new diagnostic tools were developed to help achieve this goal: (1) microelectrode half-cells for improved isolation of cathode impedance on thin electrolytes, and (2) nonlinear electrochemical impedance spectroscopy (NLEIS), a variant of traditional impedance that allows workers to probe nonlinear rates as a function of frequency. After reporting on the development and efficacy of these tools, this document reports on the use of these and other tools to better understand performance and degradation of cathodes based on the mixed conductor La{sub 1-x}Sr{sub x}CoO{sub 3-{delta}} (LSC) on gadolinia or samaria-doped ceria (GDC or SDC). We describe the use of NLEIS to measure O{sub 2} exchange on thin-film LSC electrodes, and show that O{sub 2} exchange is most likely governed by dissociative adsorption. We also describe parametric studies of porous LSC electrodes using impedance and NLEIS. Our results suggest that O{sub 2} exchange and ion transport co-limit performance under most relevant conditions, but it is O{sub 2} exchange that is most sensitive to processing, and subject to the greatest degradation and sample-to-sample variation. We recommend further work that focuses on electrodes of well-defined or characterized geometry, and probes the details of surface structure, composition, and impurities. Parallel work on primarily electronic conductors (LSM) would also be of benefit to developers, and to improved understanding of surface vs. bulk diffusion.

Stuart Adler; L. Dunyushkina; S. Huff; Y. Lu; J. Wilson

2006-12-31T23:59:59.000Z

9

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

SciTech Connect (OSTI)

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

10

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3-- ------------------------------Chapter 39.208-006 Advance

11

ANL-E Health Physics experience with D and D  

SciTech Connect (OSTI)

The Argonne National Laboratory--East (ANL-E) Health Physics Section provides direct and/or oversight support to various D&D projects at ANL-E. The health physics problems encountered have been challenging, primarily because they involved the potential for high internal exposures as well as actual high external exposures. The lessons learned are applicable to other radiological facilities. A number of D&D projects being conducted concurrently at ANL-E are described. The problems encountered are then categorized, and lessons learned and recommendations are provided. The main focus will be limited to the support and technical assistance provided by personnel from the ANL Health Physics Section during the course of the work activities.

Baker, S.I.; Mosho, G.D.; Munyon, W.J.; Murdoch, B.T.; Sholeen, C.M.; Shuman, J.P.

1996-04-01T23:59:59.000Z

12

Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells  

SciTech Connect (OSTI)

During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

2001-11-05T23:59:59.000Z

13

Sandia National Laboratories: ANL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwardsSafeguardsEngineers Wind EnergyAMF3ANL Predicting

14

Interfacial Processes in EES Systems Advanced Diagnostics  

Broader source: Energy.gov (indexed) [DOE]

power and affects system safety Partners * BATT Cathode and Anode Task Groups: ANL, LBNL, SUNY, UP, HQ and UG. * V. Srinivasan, M. Foure (BATT Program management) * The...

15

E-Print Network 3.0 - anl electric vehicle Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electric vehicle Search Powered by Explorit Topic List Advanced Search Sample search results for: anl electric vehicle Page: << < 1 2 3 4 5 > >> 1 GREET InclGREET Includes More...

16

E-Print Network 3.0 - anl Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: anl Page: << < 1 2 3 4 5 > >> 1 Using VPN with iPad or iPhone How to Install an iPadiPhone VPN...

17

ANL Vol 1- Final.PDF  

Broader source: Energy.gov (indexed) [DOE]

inadequate to prevent recurrence include a failure to conduct OSHA-required annual lockouttagout reviews, which was identified by DOE in 1999, and CHAAO and ANL deficiencies...

18

CAT Guide to the ANL CMS system  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

APS CAT Guide to Using the ANL Chemical Management System (August 30, 2000) The Argonne Chemical Management System (CMS) is a database used to track the ownership and location of...

19

Electrometallurgical treatment demonstration at ANL-West  

SciTech Connect (OSTI)

Electrometallurgical treatment (EMT) was developed by Argonne National Laboratory (ANL) to ready sodium-bonded spent nuclear fuel for geological disposal. A demonstration of this technology was successfully completed in August 1999. EMT was used to condition irradiated EBR-II driver and blanket fuel at ANL-West. The results of this demonstration, including the production of radioactive high-level waste forms, are presented.

Goff, K. M.; Benedict, R. W.; Johnson, S. G.; Mariani, R. D.; Simpson, M. F.; Westphal, B. R.

2000-03-20T23:59:59.000Z

20

Advanced Cathode Catalysts and Supports for PEM Fuel Cells | Department of  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustionImprovement3-- ------------------------------Chapter 39.208-006 AdvanceEnergy This

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Advanced Cathode Catalysts and Supports for PEM Fuel Cells | Department of  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy Cooperation |South ValleyASGovLtr.pdfAboutSheet, April 20142-021 Advance

22

Interfacial Processes in EES Systems Advanced Diagnostics  

Broader source: Energy.gov (indexed) [DOE]

power and affects system safety Partners * BATT Cathode and Anode Task Groups * ANL, LBNL, SUNY, UP, HQ and UU * G. Chen, J. Kerr, J. Cabana,, M. Doeff, K. Persson (LBNL) * V....

23

anl 4-gev microtron: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fermi Ins;tutes 12;www.ci.anl.gov www.ci.uchicago.edu 2 UC Compu;ng Coopera the funding agencies and the University UC3 @ Condor Week 2012 12;www.ci.anl.gov Wisconsin at...

24

Miniaturized cathodic arc plasma source  

DOE Patents [OSTI]

A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA)

2003-04-15T23:59:59.000Z

25

Hydrogen Delivery Analysis Amgad Elgowainy (ANL), Marianne Mintz  

E-Print Network [OSTI]

Hydrogen Truck Liquid Hydrogen Truck Terminal H2 Transmission Compressor H2 Forecourt Compressor Hydrogen Storage Options Geologic gas storage Low cost for very large amounts of hydrogen May not be convenientlyHydrogen Delivery Analysis Models Amgad Elgowainy (ANL), Marianne Mintz (ANL), Jerry Gillette (ANL

26

Using the central VAX cluster at ANL  

SciTech Connect (OSTI)

This report is a manual that discusses the following topics on the Central Vax Cluster at ANL: What the Central Vax Cluster is; how the Vax Cluster works; operational policies; getting started; using tapes; printing on the Vax Cluster; developing programs in VMS; using the X window system on the Central Vax Cluster; and using Central Vax Cluster file sharing services.

Caruthers, C.M.; Vote, S.L. [eds.; Lifka, D.A.; Raffenetti, R.C.

1992-08-01T23:59:59.000Z

27

ANL-14/02 Argonne National Laboratory  

E-Print Network [OSTI]

#12;#12;ANL-14/02 Argonne National Laboratory Site Environmental Report for Calendar Year 2013, and Quality Assurance Division Argonne National Laboratory September 2014 #12;#12;A NOTE FROM THE AUTHORS Argonne Site Environmental Report _____________________________________________________ iii This Site

Kemner, Ken

28

ANL-13/02 Argonne National Laboratory  

E-Print Network [OSTI]

#12;#12;ANL-13/02 Argonne National Laboratory Site Environmental Report for Calendar Year 2012 Assurance Division Argonne National Laboratory September 2013 #12;#12;A NOTE FROM THE AUTHORS Argonne Site (SER) was prepared by the Environment, Safety, and Quality Assurance (ESQ) Division at Argonne National

Kemner, Ken

29

Cathodes - Technological review  

SciTech Connect (OSTI)

Lithium cobalt oxide (LiCoO{sub 2}) was already used in the first commercialized Li-ion battery by SONY in 1990. Still, it is the most frequently used cathode material nowadays. However, LiCoO{sub 2} is intrinsically unstable in the charged state, especially at elevated temperatures and in the overcharged state causing volume changes and transport limitation for high power batteries. In this paper, some technological aspects with large impact on cell performance from the cathode material point of view will be reviewed. At first it will be focused on the degradation processes and life-time mechanisms of the cathode material LiCoO{sub 2}. Electrochemical and structural results on commercial Li-ion batteries recorded during the cycling will be discussed. Thereafter, advanced nanomaterials for new cathode materials will be presented.

Cherkouk, Charaf; Nestler, Tina [Institut für Experimentelle Physik, Technische Universität Bergakademie Freiberg, Leipziger Straße 23, 09596 Freiberg (Germany)

2014-06-16T23:59:59.000Z

30

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries  

E-Print Network [OSTI]

Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney for lithium metal-free rechargeable batteries. It has a theoretical capacity of 1166 mAh/g, which is nearly 1 as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION

Cui, Yi

31

Advanced Reactor Thermal Hydraulic Modeling | Argonne Leadership...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Reactor Thermal Hydraulic Modeling PI Name: Paul Fischer PI Email: fischer@mcs.anl.gov Institution: Argonne National Laboratory Allocation Program: INCITE Allocation Hours...

32

Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants  

E-Print Network [OSTI]

Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants ANL-AFCI-168 of Nuclear Reactor and Chemical Separation Plants ANL-AFCI-168 by G. Palmiotti, J. Cahalan, P. Pfeiffer, T;2 ANL-AFCI-168 Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants G

Anitescu, Mihai

33

Microsoft Word - ANL 2005 ESH - Volume II -FINAL FORMATTED...  

Broader source: Energy.gov (indexed) [DOE]

nuclear facility SARs, quality assurance requirements, the ANL nuclear facility conduct of operations manuals, and quality assurance plans. Contrary to these requirements...

34

The ANL electrochemical program for DOE on electric vehicle R D  

SciTech Connect (OSTI)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

Not Available

1991-01-01T23:59:59.000Z

35

The ANL electric vehicle battery R D program for DOE-EHP  

SciTech Connect (OSTI)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

Not Available

1990-01-01T23:59:59.000Z

36

ANL analysis of ZPPR-13A  

SciTech Connect (OSTI)

The ZPPR-13 experiments provide basic physics data for radial heterogeneous LMFBR cores of approximately 700MWe size. Assemblies ZPPR-13A, ZPPR-13B and ZPPR-13C comprised the JUPITER-II cooperative program between the U.S. Department of Energy (US DOE) and PNC of Japan. The measurements were made between August 1982 and April 1984. The core designs and the measurements were planned jointly by the two parties with substantial input from U.S. industrial interests to ensure coverage of the design requirements. This report describes in detail the results of the Argonne National Laboratory (ANL) analyses of phase 13A.

Collins, P.J.; Brumbach, S.B. [comps.

1984-08-09T23:59:59.000Z

37

ANL supplement to the CA-Disspla user's manual  

SciTech Connect (OSTI)

The ANL Supplement to the CA-DISSPLA USER'S MANUAL (ANL/TM 467) summarizes installation-dependent options and features of Disspla; this Supplement supersedes Using Cuechart, Tellegraf, and Disspla at ANL (ANL/TM 433). The information in this Supplement applies to version 10.5 of Disspla (which is currently installed in CMS, in MVS batch, and in several Argonne VAX/VMS systems), to Disspla 11.0 on the VAX 8700, and to version 10.0 of Disspla (which is currently installed on the Cray X-MP/14 under UNICOS). Unless this Supplement states otherwise, you should write Disspla programs according to instructions in the CA-Disspla User's Manual. This chapter contains information common to Disspla as installed in CMS, MVS, VAX/VMS, and UNICOS. (Chapter Two contains information specific to using Disspla in each of these computer systems.) 9 tabs.

Thommes, M.M.; Larson, E.M. (ed.)

1989-03-01T23:59:59.000Z

38

Production-scale LLW and RMW solidification system operational testing at Argonne National Laboratory-East (ANL-E)  

SciTech Connect (OSTI)

Argonne National Laboratory-East (ANL-E) has begun production-scale testing of a low-level waste and radioactive mixed waste solidification system. This system will be used to treat low-level and mixed radioactive waste to meet land burial requirements. The system can use any of several types of solidification media, including a chemically bonded phosphate ceramic developed by ANL-E scientists. The final waste product will consist of a solidified mass in a standard 208-liter drum. The system uses commercial equipment and incorporates several unique process control features to ensure proper treatment. This paper will discuss the waste types requiring treatment, the system configuration, and operation results for these waste streams.

Wescott, J.; Wagh, A.; Singh, D. [Argonne National Lab., IL (United States); Nelson, R. [Sargent and Lundy, Chicago, IL (United States); No, H. [H and P, Inc., Vienna, VA (United States)

1997-04-01T23:59:59.000Z

39

Status of ANL out-of-pile investigations of severe accident phenomena for liquid metal reactors  

SciTech Connect (OSTI)

Research addressing LMFBR whole core accidents has been terminated, and there is now emphasis on quantifying reactivity feedbacks, and in particular enhancing negative feedback, so that advanced LMR designs will provide inherently safe operation. The status of recent HCDA-related laboratory research performed at ANL, up to the time that such activities were no longer needed to support CRBR licensing, is described. Included are descriptions of programs addressing sodium channel voiding, fuel sweepout, fuel dispersal and plugging, boiled-up pool, UO/sub 2//sodium FCI, and debris coolability. Descriptions of recent investigations involving the metal fuel/sodium system are also included.

Spencer, B.W.; Marchaterre, J.F.; Anderson, R.P.; Armstrong, D.R.; Baker, L.; Cho, D.H.; Gabor, J.D.; Pedersen, D.R.; Sienicki, J.J.; Stein, R.P.

1986-01-01T23:59:59.000Z

40

The ANL electrochemical program for DOE on electric vehicle R&D. Quarterly progress report, January--March 1991  

SciTech Connect (OSTI)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

Not Available

1991-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Novel Composite Cathode Structures  

Broader source: Energy.gov (indexed) [DOE]

Relevance * New cathode materials are required to improve the energy density of Li-ion cells for transportation technologies. * The cathode system in this project directly...

42

The ANL electric vehicle battery R&D program for DOE-EHP. Quarterly progress report, October--December 1990  

SciTech Connect (OSTI)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

Not Available

1990-12-31T23:59:59.000Z

43

ANL-671A (10-06) 1 UCHICAGO ARGONNE, LLC,  

E-Print Network [OSTI]

ANL-671A (10-06) 1 UCHICAGO ARGONNE, LLC, OPERATOR OF ARGONNE NATIONAL LABORATORY GUEST RESEARCH of Argonne is to serve as a center where investigators can pursue research and development work related to the broad field of energy. To this end, Argonne is particularly interested in cooperating with qualified

Kemner, Ken

44

Waste minimization and pollution prevention initiatives within Argonne National Laboratory-East (ANL-E) boiler house operations  

SciTech Connect (OSTI)

The mission of ANL-E Plant Facility and Services-Utilities and Systems (PFS-US) is to operate and maintain utility services in a cost-effective manner, while utilizing new and innovative methods whenever possible. PFS-US operates an on-site coal burning boiler plant that generates steam for use throughout the Laboratory as a source to heat buildings, as well as for use in research experiments. In the recent past, PFS-US has embarked upon a series of initiatives to improve operating efficiency of boiler house operations. The results of these projects have had the following impacts on boiler house performance and operations: (1) boiler house efficiency and operations have improved, (2) boiler house operating costs have been reduced, (3) specific operating and maintenance costs have been avoided or eliminated, and (4) the amount of waste and pollution generated has been reduced. Through the implementation of these initiatives, over $250,000 of revenue and cost savings have been incurred by ANL-E. In addition, the Laboratory and DOE will benefit annually from revenues, cost savings, and the reduction of environmental liability resulting from these initiatives.

NONE

1996-08-01T23:59:59.000Z

45

Cathode R&D for Future Light Sources  

SciTech Connect (OSTI)

This paper reviews the requirements and current status of cathodes for accelerator applications, and proposes a research and development plan for advancing cathode technology. Accelerator cathodes need to have long operational lifetimes and produce electron beams with a very low emittance. The two principal emission processes to be considered are thermionic and photoemission with the photocathodes being further subdivided into metal and semi-conductors. Field emission cathodes are not included in this analysis. The thermal emittance is derived and the formulas used to compare the various cathode materials. To date, there is no cathode which provides all the requirements needed for the proposed future light sources. Therefore a three part research plan is described to develop cathodes for these future light source applications.

Dowell, D.H.; /SLAC; Bazarov, I.; Dunham, B.; /Cornell U., CLASSE; Harkay, K.; /Argonne; Hernandez-Garcia; /Jefferson Lab; Legg, R.; /Wisconsin U., SRC; Padmore, H.; /LBL, Berkeley; Rao, T.; Smedley, J.; /Brookhaven; Wan, W.; /LBL, Berkeley

2010-05-26T23:59:59.000Z

46

E-Print Network 3.0 - anl electrichemical program Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dave Peterson Reg Tyler Lea Yancey ANL Tom Benjamin John Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure Technologies...

47

E-Print Network 3.0 - anl organization plans Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

be substituted Model is available on the ANL website: ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure Technologies...

48

ANL: Prototype Cell Fabrication Facility | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of Energy 601 High Integrity -MagnesiumInstitute |ANDREW W.ANL:

49

RACETRACK AT ANL S. L. Kramer LS-67  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298, and 323 K.Office of Science7a.RACETRACK AT ANL S. L.

50

Novel Composite Cathode Structures  

Broader source: Energy.gov (indexed) [DOE]

Chemical Sciences and Engineering Division Argonne National Laboratory May 16, 2012 Novel Composite Cathode Structures This presentation does not contain any proprietary or...

51

Layered Cathode Materials  

Broader source: Energy.gov (indexed) [DOE]

Layered Cathode Materials presented by Michael Thackeray Chemical Sciences and Engineering Division, Argonne Annual Merit Review DOE Vehicle Technologies Program Washington, D.C....

52

ANL/ESD/10-9 Highway Vehicle Electric Drive in the United States  

E-Print Network [OSTI]

ANL/ESD/10-9 Highway Vehicle Electric Drive in the United States: 2009 Status and Issues Energy Laboratory, or UChicago Argonne, LLC. #12;ANL/ESD/10-9 Highway Vehicle Electric Drive in the United States .............................................................................................................. 1 2 STATE OF ELECTRIC DRIVE VEHICLE TECHNOLOGY .......................................... 4 2

Kemner, Ken

53

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov  

E-Print Network [OSTI]

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov Volume 14 Issue 2 2014 Contents #12;TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov VERIFI Shrinks Combustion Engine Development Cycles to Save Money and Time page 4 Argonne researchers

Kemner, Ken

54

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov  

E-Print Network [OSTI]

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov Volume 14 Issue 2 2014 #12;TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov VERIFI Shrinks Combustion Engine Development Cycles to Save Money and Time page 4 Argonne researchers

Kemner, Ken

55

A user's guide to the PLTEMP/ANL code.  

SciTech Connect (OSTI)

PLTEMP/ANL V4.1 is a FORTRAN program that obtains a steady-state flow and temperature solution for a nuclear reactor core, or for a single fuel assembly. It is based on an evolutionary sequence of ''PLTEMP'' codes in use at ANL for the past 20 years. Fueled and non-fueled regions are modeled. Each fuel assembly consists of one or more plates or tubes separated by coolant channels. The fuel plates may have one to five layers of different materials, each with heat generation. The width of a fuel plate may be divided into multiple longitudinal stripes, each with its own axial power shape. The temperature solution is effectively 2-dimensional. It begins with a one-dimensional solution across all coolant channels and fuel plates/tubes within a given fuel assembly, at the entrance to the assembly. The temperature solution is repeated for each axial node along the length of the fuel assembly. The geometry may be either slab or radial, corresponding to fuel assemblies made of a series of flat (or slightly curved) plates, or of nested tubes. A variety of thermal-hydraulic correlations are available with which to determine safety margins such as Onset-of-Nucleate boiling (ONB), departure from nucleate boiling (DNB), and onset of flow instability (FI). Coolant properties for either light or heavy water are obtained from FORTRAN functions rather than from tables. The code is intended for thermal-hydraulic analysis of research reactor performance in the sub-cooled boiling regime. Both turbulent and laminar flow regimes can be modeled. Options to calculate both forced flow and natural circulation are available. A general search capability is available (Appendix XII) to greatly reduce the reactor analyst's time.

Kalimullah, M. (Nuclear Engineering Division)

2011-07-05T23:59:59.000Z

56

Assessment of the SE2-ANL code using EBR-II temperature measurements  

SciTech Connect (OSTI)

The SE2-ANL code is a modified version of the SUPERENERGY-2 code [1]. This code is used at Argonne National Laboratory (ANL) to compute the core-wide temperature profiles in Liquid Metal Reactor (LMR) cores. The accuracy of this code has recently been tested by comparing the predicted temperatures with measured values in the Experimental Breeder Reactor R (EBR-II). The detailed temperature distributions in two experimental subassemblies and the mixed mean subassembly outlet temperatures were used in this validation study. The SE2-ANL predictions were found to agree well with measured values. It was also found that SE2-ANL yields results with accuracy comparable to the more detailed COBRA-WC [2] calculations at much lower computational cost.

Yang, W.S.; Yacout, A.M.

1995-01-01T23:59:59.000Z

57

A LASER STRAIN GAUGE FOR ACCELERATOR TARGETS A. Hassanein, J. Norem, ANL, Argonne, IL 60439  

E-Print Network [OSTI]

A LASER STRAIN GAUGE FOR ACCELERATOR TARGETS A. Hassanein, J. Norem, ANL, Argonne, IL 60439 tests using the Brookhaven AGS and the Argonne CHM linac. 1 INTRODUCTION The next generation of particle

Harilal, S. S.

58

Cathode materials review  

SciTech Connect (OSTI)

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

Daniel, Claus, E-mail: danielc@ornl.gov; Mohanty, Debasish, E-mail: danielc@ornl.gov; Li, Jianlin, E-mail: danielc@ornl.gov; Wood, David L., E-mail: danielc@ornl.gov [Oak Ridge National Laboratory, 1 Bethel Valley Road, MS6472 Oak Ridge, TN 37831-6472 (United States)

2014-06-16T23:59:59.000Z

59

Electrochemically Stable Cathode Current Collectors for Rechargeable...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stable Cathode Current Collectors for Rechargeable Magnesium Batteries . Electrochemically Stable Cathode Current Collectors for Rechargeable Magnesium Batteries . Abstract:...

60

Tungsten Cathode Catalyst for PEMFC  

SciTech Connect (OSTI)

Final report for project to evaluate tungsten-based catalyst as a cathode catalyst for PEM cell applications.

Joel B. Christian; Sean P. E. Smith

2006-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Engineering-Scale Liquid Cadmium Cathode Experiments  

SciTech Connect (OSTI)

Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

2006-08-01T23:59:59.000Z

62

Cathode material for lithium batteries  

DOE Patents [OSTI]

A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

Park, Sang-Ho; Amine, Khalil

2013-07-23T23:59:59.000Z

63

Air cathode structure manufacture  

DOE Patents [OSTI]

An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

Momyer, William R. (Palo Alto, CA); Littauer, Ernest L. (Los Altos Hills, CA)

1985-01-01T23:59:59.000Z

64

Advanced Cathode Catalysts | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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65

Advanced Cathode Catalysts | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of EnergyAdministrative RecordsBiofuels CostEnergy ThisPart

66

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

67

Toda Cathode Materials Production Facility  

Broader source: Energy.gov (indexed) [DOE]

Cathode Materials Production Facility 2013 DOE Vehicle Technologies Annual Merit Review May 13-17, 2013 David Han, Yasuhiro Abe Toda America Inc. Project ID: ARRAVT017...

68

Stabilized Spinel and Polyanion Cathodes  

Broader source: Energy.gov (indexed) [DOE]

nanostructured phosphate and silicate cathodes and their nanocomposites with graphene - To develop a fundamental understanding of the factors that control the...

69

Cathodes | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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70

Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013  

SciTech Connect (OSTI)

This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, “Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.”

Kerry L. Nisson

2012-10-01T23:59:59.000Z

71

Batteries: Overview of Battery Cathodes  

SciTech Connect (OSTI)

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

Doeff, Marca M

2010-07-12T23:59:59.000Z

72

Attempted RIAPMTQ Benchmarking Study of the ANL RIA Low-Beta LinacDesign  

SciTech Connect (OSTI)

The objective of this work is to compare the simulation results of the RIAPMTQ code with those of the ANL simulation code for the low-beta section of an ANL RIA Driver Linac design. However, the approach taken is not precisely that of a direct comparison of the two simulations of the same linac section, which is what one would normally expect to do. The reason is that the RFQ design approach used by the ANL codes and the LANL codes are approximately but not exactly the same, particularly at the ends of the RFQ, and it did not appear to be easy to make the two RFQ designs exactly identical. The effects on the beam of the different RFQ design approaches are not expected to be large, as long as the beam is properly matched at the transitions. What was done in the RIAPMTQ input file to compensate for the RFQ design difference was to use TRACE3D to adjust the four solenoid strengths and the two matching rf cavities in the MEBT (the beam transport system between the end of the RFQ and the beginning of the superconducting linac) to obtain the same match (Courant-Snyder parameters) into the superconducting linac as was obtained from the ANL code. We also matched the beam into the RFQ. The result is that we generate a RIAPMTQ input file for the low-beta section of the linac, which is not exactly identical to, but should be near to that of the ANL design. Then, what we wish to compare from the two codes are the rms emittances at the beginning of the superconducting linac, and the beam losses in the first or prestripper section of the superconducting (SC) linac. In this report, we describe the procedure and present the results. Section 2 gives the procedures and results, and Section 3 gives the summary.

Billen, J.; Qiang, J.; Wangler, T.

2007-01-01T23:59:59.000Z

73

Hot hollow cathode gun assembly  

DOE Patents [OSTI]

A hot hollow cathode deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, the hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

Zeren, J.D.

1983-11-22T23:59:59.000Z

74

Advances  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout the BuildingInnovation PortalScienceScripting forAdvances in

75

C O N TA C T > Lee Ann Ciarlette | 630.252.4835 | leeann@anl.gov | Nuclear Engineering Division | students.ne.anl.gov Argonne National Laboratory, 9700 South Cass Avenue, Lemont, IL 60439 November 2012  

E-Print Network [OSTI]

C O N TA C T > Lee Ann Ciarlette | 630.252.4835 | leeann@anl.gov | Nuclear Engineering Division of Massachuse s Lowell · University of Michigan · University of Michigan, Ann Arbor · University of Missouri

Kemner, Ken

76

The Linac Injector For The ANL 7 Ge V Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2 and NbSe2DifferentTheInforumLast W-79

77

ANL/APS/TB-16 ADVANCED PHOTON SOURCE ACCELERATOR ULTRAHIGH VACUUM GUIDE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of31 . Wiggler A2146

78

ANL/APS/TB-36, Advanced Photon Source Research No. 2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of31 . Wiggler926

79

ANL/APS/TB-37, Advanced Photon Source Research No. 3  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of31 . Wiggler9267

80

ANL/APS/TB-41, Advanced Photon Source Research No. 4  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of31 . Wiggler92671

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Stabilized Spinels and Polyanion Cathodes  

Broader source: Energy.gov (indexed) [DOE]

process * Synthesis of nano-engineered alloy, carbon-decorated Fe 3 O 4 nanowire, and graphene anodes, but only results on the cathodes are given in the next 11 slides TECHNICAL...

82

Using the central VAX 8700 computer at ANL (Argonne National Laboratory)  

SciTech Connect (OSTI)

This paper is a manual for using the VAX 8700 computer at ANL. The chapters include: The central VAX cluster: What it is and how it works; Training and other available assistance; Getting started with the VAX 8700 computer and VAX/VMS; Using the VAX/VMS file system; Developing programs in VMS; Using batch; Using available software; and Using graphics in VAX/VMS. (LSP)

Lark, D.T.; Caruthers, C.M.; Bragg, R.W. (eds.)

1988-09-01T23:59:59.000Z

83

STATEMENT OF CONSIDERATIONS PETITION FOR ADVANCE WAIVER OF PATENT...  

Broader source: Energy.gov (indexed) [DOE]

cooperative agreement entitled "Advanced Cathode Catalysts and Supports for PEM Fuel Cells." The objectives of the project are development of a durable, low cost (pt...

84

Electropositive surface layer MPD thruster cathodes  

SciTech Connect (OSTI)

Lithium and barium oxide have been used to generate electropositive surface layers on tungsten cathodes in low power steady state MPD thruster experiments. The electropositive surface layer decreases the cathode work function, resulting in substantial reductions in the steady state cathode operating temperature and erosion rate. Cathode temperature is reduced by 300 degrees with a lithium surface layer and by 800 degrees with a barium oxide surface layer at a 500 ampere thruster current level. These temperature reductions substantially reduce the calculated steady state evaporative erosion rate of the cathode by factors of 20 and 10,000 respectively. Cold cathode startup erosion is also reduced dramatically. The surface melting and arc cratering that is characteristic of pure tungsten cathodes does not occur with an electropositive surface layer cathode. In addition to reducing cathode erosion, the use of these materials increases thruster efficiency. 12 refs.

Chamberlain, F.R.; Kelly, A.J.; Jahn, R.G.

1989-01-01T23:59:59.000Z

85

High Current Density, Long Life Cathodes for High Power RF Sources  

SciTech Connect (OSTI)

This program was tasked with improving the quality and expanding applications for Controlled Porosity Reservoir (CPR) cathodes. Calabazas Creek Research, Inc. (CCR) initially developed CPR cathodes on a DOE-funded SBIR program to improve cathodes for magnetron injection guns. Subsequent funding was received from the Defense Advanced Research Projects Agency. The program developed design requirements for implementation of the technology into high current density cathodes for high frequency applications. During Phase I of this program, CCR was awarded the prestigious 2011 R&D100 award for this technology. Subsequently, the technology was presented at numerous technical conferences. A patent was issued for the technology in 2009. These cathodes are now marketed by Semicon Associates, Inc. in Lexington, KY. They are the world’s largest producer of cathodes for vacuum electron devices. During this program, CCR teamed with Semicon Associates, Inc. and Ron Witherspoon, Inc. to improve the fabrication processes and expand applications for the cathodes. Specific fabrications issues included the quality of the wire winding that provides the basic structure and the sintering to bond the wires into a robust, cohesive structure. The program also developed improved techniques for integrating the resulting material into cathodes for electron guns.

Ives, Robert Lawrence [Calabazas Creek Research,, Inc.; Collins, George [Calabazas Creek Research, Inc.; Falce, Lou [Consultant; Schwartzkopf, Steve [Ron Witherspoon, Inc.; Busbaher, Daniel [Semicon Associates

2014-01-22T23:59:59.000Z

86

Cathode Connector For Aluminum Low Temperature Smelting Cell  

DOE Patents [OSTI]

Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2003-07-16T23:59:59.000Z

87

High-current-density, high brightness cathodes for free electron laser applications  

SciTech Connect (OSTI)

This report discusses the following topics: brightness and emittance of electron beams and cathodes; general requirements for cathodes in high brightness electron guns; candidate cathode types; plasma and field emission cathodes; true field emission cathodes; oxide cathodes; lanthanum hexaborides cathodes; laser driven thermionic cathodes; laser driven photocathodes; impregnated porous tungsten dispenser cathodes; and choice of best performing cathode types.

Green, M.C. (Varian Associates, Palo Alto, CA (USA). Palo Alto Microwave Tube Div.)

1987-06-01T23:59:59.000Z

88

Remote control for anode-cathode adjustment  

DOE Patents [OSTI]

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

Roose, Lars D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

89

Cathode for the electrolytic production of hydrogen  

SciTech Connect (OSTI)

The invention relates to a cathode for the electrolytic production of hydrogen. The cathode comprises an active surface consisting of a metal oxide obtained by the thermal decomposition of a thermally decomposable compound of a metal chosen from amongst cobalt, iron, manganese or nickel. The cathode is particularly suitable for the electrolysis of aqueous sodium chloride solutions in cells with a permeable diaphragm.

Nicolas, E.

1983-07-19T23:59:59.000Z

90

Cathodic protection in oilfield brine  

SciTech Connect (OSTI)

In this paper the use of cathodic protection (CP) to mitigate internal and corrosion-related failures that occur in the produced brine phase of oilfield tanks and production vessels is discussed. Unique considerations covered include brine properties, CP system selection, installation details, monitoring, and coatings.

Turnipseed, S.P. (Chevron U.S.A. Inc., Houston, TX (US))

1991-12-01T23:59:59.000Z

91

Cathodes for ceria-based fuel cells  

SciTech Connect (OSTI)

Work is underway to develop a solid oxide fuel cell that has a ceria-based electrolyte and operates at lower temperatures (500-600{degrees}C) than conventional zirconia-based cells. At present the performance of this ceria-based solid oxide fuel cell is limited by the polarization of conventional cathode materials. The performance of alternative cathodes was measured by impedance spectroscopy and dc polarization. The performance was found to improve by using a thin dense interface layer and by using two-phase cathodes with an electrolyte and an electronic phase. The cathode performance was also found to increase with increasing ionic conductivity for single phase cathodes.

Doshi, R.; Krumpelt, M. [Argonne National Lab., IL (United States); Ricvhards, V.L. [Tri-State Univ., Angola, IN (United States). Dept. of Mech. & Aerospace Engr.

1997-08-01T23:59:59.000Z

92

Theory, Investigation and Stability of Cathode Electrocatalytic Activity  

SciTech Connect (OSTI)

The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

2012-09-30T23:59:59.000Z

93

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

SciTech Connect (OSTI)

This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. This period has continued to address the problem of making dense 1/2 to 5 {micro}m thick dense layers on porous substrates (the cathode LSM). Our current status is that we are making structures of 2-5 cm{sup 2} in area, which consist of either dense YSZ or CGO infiltrated into a 2-5 {micro}m thick 50% porous layer made of either nanoncrystalline CGO or YSZ powder. This composite structure coats a macroporous cathode or anode; which serves as the structural element of the bi-layer structure. These structures are being tested as SOFC elements. A number of structures have been evaluated both as symmetrical and as button cell configuration. Results of this testing indicates that the cathodes contribute the most to cell losses for temperatures below 750 C. In this investigation different cathode materials were studied using impedance spectroscopy of symmetric cells and IV characteristics of anode supported fuel cells. Cathode materials studied included La{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF), La{sub 0.7}Sr{sub 0.2}MnO{sub 3} (LSM), Pr{sub 0.8}Sr{sub 0.2}Fe{sub 0.8}O{sub 3} (PSCF), Sm{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF), and Yb{sub .8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF). A new technique for filtering the Fourier transform of impedance data was used to increase the sensitivity of impedance analysis. By creating a filter specifically for impedance spectroscopy the resolution was increased. The filter was tailored to look for specific circuit elements like R//C, Warburg, or constant phase elements. As many as four peaks can be resolved using the filtering technique on symmetric cells. It may be possible to relate the different peaks to material parameters, like the oxygen exchange coefficient. The cathode grouped in order from lowest to highest ASR is LSCF < PSCF < SSCF < YSCF < LSM. The button cell results agree with this ordering indicating that this is an important tool for use in developing our understanding of electrode behavior in fuel cells.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2002-03-31T23:59:59.000Z

94

Nickel-titanium-phosphate cathodes  

DOE Patents [OSTI]

Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.

Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

2008-12-16T23:59:59.000Z

95

Filters for cathodic arc plasmas  

DOE Patents [OSTI]

Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA); Bilek, Marcela M. M. (Engadine, AU); Brown, Ian G. (Berkeley, CA)

2002-01-01T23:59:59.000Z

96

JUPITER-II Program: ANL analysis of ZPPR-13A and ZPPR-13B  

SciTech Connect (OSTI)

The ZPPR-13 experiments provide basic physics data for radial heterogeneous LMFBR cores of approximately 700MWe size. Assemblies ZPPR-13A, ZPPR-13B and ZPPR-13A comprised the JUPITER-II cooperative program between the U.S. Department of Energy (US DOE) and PNC of Japan. The measurements were made between August 1982 and April 1984. The core designs and the measurements were planned jointly by the two parties with substantial input from U.S. industrial interests to ensure coverage of the design requirements. This report describes in detail the results of the Argonne National Laboratory (ANL) analyses of phases 13A and 13B/1 and includes preliminary results for the later assemblies of phase 13B..

Collins, P.J.; Brumbach, S.B. [comps.

1984-08-01T23:59:59.000Z

97

Intermittent cathodic protection using solar power  

SciTech Connect (OSTI)

An intermittent impressed current cathodic protection technique using photovoltaic energy was evaluated to determine it`s ability to protect bridge concrete piles in marine environments against corrosion. The technique uses commercially available anode systems to deliver the cathodic protection current to the concrete and onto the reinforcing steel. Cathodic protection current is only applied during the daytime hours. The magnitude of the applied current was based on sunlight availability. An evaluation was conducted on laboratory specimens as well as in the field. The laboratory work was performed on steel reinforced concrete specimens placed in simulated salt water tanks. For the field evaluation, ten prestressed concrete piles of a bridge structure with an existing rectifier powered cathodic protection system were used. In both cases, intermittent cathodic protection was provided. Polarization and depolarization of the steel reinforcement as well as the protection current delivered were monitored to evaluate the cathodic protection performance as well as the behavior of periodic polarization-depolarization.

Kessler, R.J.; Powers, R.G.; Lasa, I.R. [Florida Dept. of Transportation, Gainesville, FL (United States). Corrosion Research Lab.

1998-12-31T23:59:59.000Z

98

Analysis of the ANL Test Method for 6CVS Containment Vessels  

SciTech Connect (OSTI)

In the fall of 2010, Argonne National Laboratory (ANL) contracted with vendors to design and build 6CVS containment vessels as part of their effort to ship Fuel Derived Mixed Fission Product material. The 6CVS design is based on the Savannah River National Laboratory's (SRNL) design for 9975 and 9977 six inch diameter containment vessels. The main difference between the designs is that the 6CVS credits the inner O-ring seal as the containment boundary while the SRNL design credits the outer O-ring seal. Since the leak test must be done with the inner O-ring in place, the containment vessel does not have a pathway for getting the helium into the vessel during the leak test. The leak testing contractor was not able to get acceptable leak rates with the specified O-ring, but they were able to pass the leak test with a slightly larger O-ring. ANL asked the SRNL to duplicate the leak test vendor's method to determine the cause of the high leak rates. The SRNL testing showed that the helium leak indications were caused by residual helium left within the 6CVS Closure Assembly by the leak test technique, and by helium permeation through the Viton O-ring seals. After SRNL completed their tests, the leak testing contractor was able to measure acceptable leak rates by using the slightly larger O-ring size, by purging helium from the lid threads, and by being very quick in getting the bell jar under a full vacuum. This paper describes the leak test vendor's test technique, and other techniques that could be have been used to successfully leak test the 6CVS's.

Trapp, D.; Crow, G.

2011-06-06T23:59:59.000Z

99

Sun powers Libya cathodic-protection system  

SciTech Connect (OSTI)

Well castings and part of the main 300-mile-long, 32-in diameter pipeline from Sarir to Tobruk are cathodically protected by solar power, which prevents galvanic action by applying an electric direct current of appropriate magnitude and polarity to the steel structures. They then act as cathodes and become the recipients of metallic ions. At each cathodic-protection station, the solar-generaor system consists of solar-panel arrays, electronic controls, and batteries.

Currer, G.W.

1982-03-22T23:59:59.000Z

100

Stabilized Spinel and Nano Olivine Cathodes  

Broader source: Energy.gov (indexed) [DOE]

good storage properties at elevated temperatures - Low cost spinel + layered oxide composite cathodes that can offer a combination of high energy and high power * To develop a...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Investigations of Cathode Architecture using Graphite Fibers  

Broader source: Energy.gov (indexed) [DOE]

Temperature Materials Lab, ORNL * Microscopy, Thermography - Collaboration, external * LBNL independent cathode testing (V. Battaglia) * HydroQuebec for materials (K. Zaghib)...

102

AC corrosion on cathodically protected steel.  

E-Print Network [OSTI]

?? This report deals with the effect of alternating current on cathodically protected steel. AC corrosion has become relevant in the offshore industry due to… (more)

Torstensen, Andreas

2012-01-01T23:59:59.000Z

103

Performance Degradation of LSCF Cathodes  

SciTech Connect (OSTI)

This final report summarizes the progress made during the October 1, 2008 - September 30, 2013 period under Cooperative Agreement DE-NT0004109 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled “Performance Degradation of LSCF Cathodes”. The primary objective of this program is to develop a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). Strategies to mitigate performance degradation are developed and implemented. In addition, thermal spray manufacturing of SOFCs is explored. Combined, this work establishes a basis for cost-effective SOFC cells.

Alinger, Matthew

2013-09-30T23:59:59.000Z

104

Conflicting Roles Of Nickel In Controlling Cathode Performance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries. Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries....

105

Design and Evaluation of Novel High Capacity Cathode Materials...  

Broader source: Energy.gov (indexed) [DOE]

Design and Evaluation of Novel High Capacity Cathode Materials Design and Evaluation of Novel High Capacity Cathode Materials 2009 DOE Hydrogen Program and Vehicle Technologies...

106

Design and Evaluation of Novel High Capacity Cathode Materials...  

Broader source: Energy.gov (indexed) [DOE]

and Evaluation of Novel High Capacity Cathode Materials Design and Evaluation of Novel High Capacity Cathode Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

107

Design and Evaluation of Novel High Capacity Cathode Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

49thackeray2011o.pdf More Documents & Publications Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Stabilization of Layered Metal Oxides...

108

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

109

Electrochemical Performance and Stability of the Cathode for...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

total areal specific resistance (ASR), and (3) understanding cathode polarization with LSCF cathodes. The ASR of a solid oxide fuel cell is a dynamic property, meaning that it...

110

Process for Low Cost Domestic Production of LIB Cathode Materials  

Broader source: Energy.gov (indexed) [DOE]

information" 4 Approach BASF has a low cost production process for Li ion battery cathode materials. In this project, the cathode materials developed in the laboratory will be...

111

Process for Low Cost Domestic Production of LIB Cathode Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio Li-Ion Battery Cell...

112

Design and Evaluation of Novel High Capacity Cathode Materials...  

Broader source: Energy.gov (indexed) [DOE]

Relevance * New cathode materials are required to improve the energy density of Li- ion cells for transportation technologies. * The cathode system in this project directly...

113

A comparison of the PARET/ANL and RELAP5/MOD3 codes for the analysis of IAEA benchmark transients  

SciTech Connect (OSTI)

The PARET/ANL and RELAP5/MOD3 codes are used to analyze the series of benchmark transients specified for the IAEA Research Reactor Core Conversion Guidebook (IAEA-TECDOC-643, Vol. 3). The computed results for these loss-of-flow and reactivity insertion transients with scram are in excellent agreement and agree well with the earlier results reported in the guidebook. Attempts to also compare RELAP5/MOD3 with the SPERT series of experiments are in progress.

Woodruff, W.L.; Hanan, N.A.; Smith, R.S.; Matos, J.E.

1996-12-31T23:59:59.000Z

114

Cathode for an electrochemical cell  

DOE Patents [OSTI]

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

115

Review of recent ANL safety experiments in SLSF and TREAT. [LMFBR  

SciTech Connect (OSTI)

Among the recent significant in-pile experiments conducted by ANL are Sodium Loop Safety Facility (SLSF) experiment P4 in the Engineering Test Facility (ETR) and TREAT experiments F3, F4, and J1. The P4 experiment, which had three heat-generating flow blockages each installed in six coolant channels in a 37-pin bundle of FTR (Fast Test Reactor)-type fuel elements, investigated the bounding consequences of severe local faults. The principal objectives were to eject molten fuel into the bundle geometry and, during subsequent extended operation, to characterize the behavior of (and response of instrumentation to) any subsequent blockage growth; secondary objectives included characterizing the severity of any molten-fuel/coolant interaction and the response of the coolant. The F3 and F4 experiments in TREAT were phenomenological tests to study the fuel-column disruption mode in loss-of-flow accidents. The J1 experiment was the first slow period (approx. 10 s) transient overpower experiment done in TREAT. Results of these experiments will be presented.

Klickman, A.E.; Thompson, D.H.; Ragland, W.A.; Wright, A.E.; Palm, R.G.; Page, R.J.

1982-01-01T23:59:59.000Z

116

Cells having cathodes containing polycarbon disulfide materials  

DOE Patents [OSTI]

The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS.sub.x).sub.n, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode.

Okamoto, Yoshi (Fort Lee, NJ); Skotheim, Terje A. (Shoreham, NY); Lee, Hung S. (Rocky Point, NY)

1995-08-15T23:59:59.000Z

117

Low temperature aluminum reduction cell using hollow cathode  

DOE Patents [OSTI]

A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2002-08-20T23:59:59.000Z

118

Development of High Energy Cathode Materials  

Broader source: Energy.gov (indexed) [DOE]

deposits). Al-coated cell can is suitable for high-voltage cathodes. Polyethylene-based separators (such as Celgard K1640) are stable at high V. Carbon Additives...

119

ANL/APS/TB-44, Guidelines for Beamline and Front-End Radiation Shielding Design at the Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of31 .

120

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

SciTech Connect (OSTI)

This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2003-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Advanced Cathode Material Development for PHEV Lithium Ion Batteries |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of EnergyAdministrative RecordsBiofuels CostEnergy

122

Advanced Cathode Material Development for PHEV Lithium Ion Batteries |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of EnergyAdministrative RecordsBiofuels CostEnergyDepartment of

123

2014 Advanced Grid Modeling Peer Review Presentations - Day Two...  

Broader source: Energy.gov (indexed) [DOE]

Power Grid Optimization under Uncertainty: Formulations, Algorithms, and High-Performance Computing - Victor Zavala, ANL, Jianhui Wang, ANL Chance-constrained OPF and Unit...

124

2013 Estorm - Invited Paper - Cathode Materials Review  

SciTech Connect (OSTI)

The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403 431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783 789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

Daniel, Claus [ORNL] [ORNL; Mohanty, Debasish [ORNL] [ORNL; Li, Jianlin [ORNL] [ORNL; Wood III, David L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

125

Micro-engineered cathode interface studies  

SciTech Connect (OSTI)

The aim of this work is to increase the performance of the cathode in solid oxide fuel cells (SOFCs) operating at 1,000 C by decreasing the polarization resistance from 0.2 {Omega}-cm{sup 2} at 300 mA/cm{sup 2}. Decreased polarization resistance will allow operation at higher current densities. This work is in support of the Westinghouse tubular SOFC technology using YSZ electrolyte and strontium doped lanthanum manganite (LSM) cathode. As a result of work performed last year at Argonne National Laboratory and information derived from the literature, the limitations at the cathode/electrolyte interface can be classified into two main areas. First, the ionic conductivity of the LSM cathode material is low which limits the reaction zone to an area very close to the interface, while the rest of the cathode thickness acts essentially as current collector with channels for gas access. Second, the electronic conductivity in YSZ is very low which limits the reaction zone to areas that are the boundaries between LSM and YSZ rather than the YSZ surface away from LSM at the interface. Possible solutions to this problem being pursued are: (1) introducing an ionic conducting YSZ phase in LSM to form a porous two-phase mixture of LSM and YSZ; (2) applying a thin interlayer between the electrolyte and the cathode where the interlayer has high ionic and electronic conductivity and high catalytic activity for reduction of O{sub 2}; (3) increasing the ionic conductivity in the LSM by suitable doping; and (4) increasing the electronic conductivity in the electrolyte by doping or by depositing an appropriate mixed conducting layer on the YSZ before applying the cathode.

Doshi, R.; Kueper, T.; Nagy, Z.; Krumpelt, M.

1997-08-01T23:59:59.000Z

126

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov  

E-Print Network [OSTI]

page 10 A revolutionary advance in our understanding of how diesel engines work may unlock new at the local and regional level. 16 How Might Increased Biofuel Production Affect Midwest Water Supplies Laboratory recently won a three-year, $3.44 million grant from the U.S. Department of Energy's Advanced

Kemner, Ken

127

TransForumNews from Argonne's Transportation Research Program www.transportation.anl.gov  

E-Print Network [OSTI]

page 10 A revolutionary advance in our understanding of how diesel engines work may unlock new at the local and regional level. 16 How Might Increased Biofuel Production Affect Midwest Water Supplies.S. Department of Energy's Advanced Research Projects Agency-Energy (ARPA-E), a government agency that funds

Kemner, Ken

128

Synchrotron Investigations of SOFC Cathode Degradation  

SciTech Connect (OSTI)

The atomic variations occurring in cathode/electrolyte interface regions of La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3-?} (LSCF) cathodes and other SOFC related materials have been investigated and characterized using soft X-ray Absorption Spectroscopy (XAS) and diffuse soft X-ray Resonant Scattering (XRS). X-ray Absorption Spectroscopy in the soft X-ray region (soft XAS) is shown to be a sensitive technique to quantify the disruption that occurs and can be used to suggest a concrete mechanism for the degradation. For LSC, LSF, and LSCF films, a significant degradation mechanism is shown to be Sr out-diffusion. By using the XAS spectra of hexavalent Cr in SrCrO4 and trivalent Cr in Cr2O3, the driving factor for Sr segregation was identified to be the oxygen vacancy concentration at the anode and cathode side of of symmetric LSCF/GDC/LSCF heterostructures. This is direct evidence of vacancy induced cation diffusion and is shown to be a significant indicator of cathode/electrolyte interfacial degradation. X-ray absorption spectroscopy is used to identify the occupation of the A-sites and B-sites for LSC, LSF, and LSCF cathodes doped with other transition metals, including doping induced migration of Sr to the anti-site for Sr, a significant cathode degradation indicator. By using spatially resolved valence mapping of Co, a complete picture of the surface electrochemistry can be determined. This is especially important in identifying degradation phenomena where the degradation is spatially localized to the extremities of the electrochemistry and not the average. For samples that have electrochemical parameters that are measured to be spatially uniform, the Co valence modifications were correlated to the effects of current density, overpotential, and humidity.

Idzerda, Yves

2013-09-30T23:59:59.000Z

129

Microbial Fuel Cell Cathodes With Poly(dimethylsiloxane) Diffusion  

E-Print Network [OSTI]

applications of MFCs for wastewater treatment and bioenergy production. The main challenges for commercializing limited by cathode surface area and performance (9, 12, 13), and the price of cathode materials can

130

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

lithium battery cathode. Electrochemical and Solid Statebattery performance of LiMn2O4 cathode. Solid State Ionics,

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

131

Tubular Membrane Cathodes for Scalable Power Generation in  

E-Print Network [OSTI]

architecture that provides large surface areas for oxygen reduction at the cathode and bacteria growth, is a promising architecture that is intrinsically scalable for creating larger systems. Further increases and its use is sustainable (13). Exposing one side of the cathode to air (air cathode) has significantly

132

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

SciTech Connect (OSTI)

This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and Testing of Planar Single Cells. During this time period substantial progress has been made in developing low temperature deposition techniques to produce dense, nanocrystalline yttrium-stabilized zirconia films on both dense oxide and polymer substrates. Progress has been made in the preparation and characterization of thin electrolytes and porous LSM substrates. Both of these tasks are essentially on or ahead of schedule. In our proposal, we suggested that the ZrO{sub 2}/Sc system needed to be considered as a candidate as a thin electrolyte. This was because microcrystalline ZrO{sub 2}/Sc has a significantly higher ionic conductivity than YSZ, particularly at the lower temperatures. As a result, some 0.5 micron thick film of ZrO{sub 2}/16% Sc on an alumina substrate (grain size 20nm) was prepared and the electrical conductivity measured as a function of temperature and oxygen activity. The Sc doped ZrO{sub 2} certainly has a higher conductivity that either 20nm or 2400nm YSZ, however, electronic conductivity dominates the conductivity for oxygen activities below 10{sup -15}. Whereas for YSZ, electronic conductivity is not a problem until the oxygen activity decreases below 10{sup -25}. These initial results show that the ionic conductivity of 20nm YSZ and 20nm ZrO{sub 2}/16% Sc are essentially the same and the enhanced conductivity which is observed for Sc doping in microcrystalline specimens is not observed for the same composition when it is nanocrystalline. In addition they show that the electronic conductivity of Sc doped ZrO{sub 2} is at least two orders of magnitude higher than that observed for YSZ. The conclusion one reaches is that for 0.5 to 1 micron thick nanocrystalline films, Sc doping of ZrO{sub 2} has no benefits compared to YSZ. As a result, electrolyte films of ZrO{sub 2}/Sc should not be considered as candidates. However, they have the potential of being useful as an interface on the anode side of the electrolyte. NexTech has focused much of its effort during the past few months on establishing tape casting methods for porous LSM substrates. This work, performed under a separate DOE-funded program, involved tape casting formulations comprising LSM powders with bi-modal particle size distributions and fugitive pore forming additives. Sintered LSM substrates with porosities in the 30 to 40 vol% range, and pore sizes of 10 {approx} 20 microns have been prepared. In addition, tape casting formulations involving composite mixtures of LSM and Sm-doped ceria (SDC) have been evaluated. The LSM/SDC cathode substrates are expected to provide better performance at low temperatures. Characterization of these materials is currently underway.

Harlan U. Anderson

2000-03-31T23:59:59.000Z

133

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

SciTech Connect (OSTI)

This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. In this portion of study we have focused on producing YSZ films on porous LSM substrates. When using the polymer precursor there are a number of obstacles to overcome in order to form dense electrolyte layers on porous substrates (cathode or anode). Probably the most difficult problems are: (1) Extreme penetration of the polymer into the substrate must be prevented. (2) Shrinkage cracking must be avoided. (3) Film thickness in the 1 to 5{micro}m range must be achieved. We have demonstrated that cracking due to shrinkage involved during the elimination of solvents and organic matter and densification of the remaining oxide is not a problem as long as the resulting oxide film is < {approx} 0.15 {micro}m in thickness. We have also shown that we can make thicker films by making multiple depositions if the substrate is smooth (roughness {le} 0.1 {micro}m) and contains no surface pores > 0.2 {micro}m. The penetration of the polymer into the porous substrate can be minimized by increasing the viscosity of the polymer and reducing the largest pore at the surface of the substrate to {le} 0.2 {micro}m. We have shown that this can be done, but we have also shown that it is difficult to make dense films that are defect free with areas > 1 cm{sup 2}. This is because of the roughness of the substrate and the difficulty in making a substrate which does not have surface voids > 0.2 {micro}m. Thus the process works well for dense, smooth substrates for films < 1 {micro}m thick, but is difficult to apply to rough, porous surfaces and to make film thickness > 1 {micro}m. As a result of these problems, we have been addressing the issue of how to make dense films in the thickness range of 1 to 5 {micro}m on sintered porous substrates without introducing cracks and holes due to shrinkage and surface voids? These endeavors have lead us to a solution which we think is quite unique and should allow us to obtain flaw free dense films of thickness in the 0.5 to 5 {micro}m range at processing temperatures {le} 900{sup o}. The process involves the deposition of a slurry of nanocrystalline YSZ onto a presintered porous LSM substrate. The key element in the deposition is that the slurry contains sufficient YSZ polymer precursor to allow adhesion of the YSZ particles to each other and the surface after annealing at about 600 C. This allows the formation of a porous film of 0.5 to 5 {micro}m thick which adheres to the surface. After formation of this film, YSZ polymer precursor is allowed to impregnate the porous surface layer (capillary forces tend to confine the polymer solution in the nanoporous layer). After several impregnation/heat treatment cycles, a dense film results. Within the next few months, this process should be developed to the point that single cell measurements can be made on 0.5 to 5 {micro}m films on a LSM substrate. This type of processing allows the formation of essentially flaw free films over areas > 1 cm{sup 2}.

Harlan U. Anderson; Wayne Huebner; Igor Kosacki

2001-09-30T23:59:59.000Z

134

Bimetallic Cathode Materials for Lithium Based Batteries  

E-Print Network [OSTI]

Bimetallic Cathode Materials for Lithium Based Batteries Frontiers in Materials Science Seminar / Chemistryg g g g g y University at Buffalo ­ The State University of New York (SUNY) Abstract Batteries for implantable cardiac defibrillators (ICDs) are based on the Lithium/Silver vanadium oxide (SVO, Ag2V4O11

135

Cathode side hardware for carbonate fuel cells  

DOE Patents [OSTI]

Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La.sub.0.8Sr.sub.0.2CoO.sub.3) and lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1).

Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

2011-03-29T23:59:59.000Z

136

Carbon-containing cathodes for enhanced electron emission  

DOE Patents [OSTI]

A cathode has electropositive atoms directly bonded to a carbon-containing substrate. Preferably, the substrate comprises diamond or diamond-like (sp.sup.3) carbon, and the electropositive atoms are Cs. The cathode displays superior efficiency and durability. In one embodiment, the cathode has a negative electron affinity (NEA). The cathode can be used for field emission, thermionic emission, or photoemission. Upon exposure to air or oxygen, the cathode performance can be restored by annealing or other methods. Applications include detectors, electron multipliers, sensors, imaging systems, and displays, particularly flat panel displays.

Cao, Renyu (Cupertino, CA); Pan, Lawrence (Pleasanton, CA); Vergara, German (Madrid, ES); Fox, Ciaran (Los Altos, CA)

2000-01-01T23:59:59.000Z

137

Virtual cathode microwave generator having annular anode slit  

DOE Patents [OSTI]

A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit therethrough effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators.

Kwan, Thomas J. T. (Los Alamos, NM); Snell, Charles M. (Los Alamos, NM)

1988-01-01T23:59:59.000Z

138

The effect of cathode geometry on barium transport in hollow cathode plasmas  

SciTech Connect (OSTI)

The effect of barium transport on the operation of dispenser hollow cathodes was investigated in numerical modeling of a cathode with two different orifice sizes. Despite large differences in cathode emitter temperature, emitted electron current density, internal xenon neutral and plasma densities, and size of the plasma-surface interaction region, the barium transport in the two geometries is qualitatively very similar. Barium is produced in the insert and flows to the surface through the porous structure. A buildup of neutral Ba pressure in the plasma over the emitter surface can suppress the reactions supplying the Ba, restricting the net production rate. Neutral Ba flows into the dense Xe plasma and has a high probability of being ionized at the periphery of this zone. The steady state neutral Ba density distribution is determined by a balance between pressure gradient forces and the drag force associated with collisions between neutral Ba and neutral Xe atoms. A small fraction of the neutral Ba is lost upstream. The majority of the neutral Ba is ionized in the high temperature Xe plasma and is pushed back to the emitter surface by the electric field. The steady state Ba{sup +} ion density distribution results from a balance between electrostatic and pressure forces, neutral Xe drag and Xe{sup +} ion drag with the dominant forces dependent on location in the discharge. These results indicate that hollow cathodes are very effective at recycling Ba within the discharge and therefore maintain a high coverage of Ba on the emitter surface, which reduces the work function and sustains high electron emission current densities at moderate temperatures. Barium recycling is more effective in the cathode with the smaller orifice because the Ba is ionized in the dense Xe plasma concentrated just upstream of the orifice and pushed back into the hollow cathode. Despite a lower emitter temperature, the large orifice cathode has a higher Ba loss rate through the orifice because the Xe plasma density peaks further upstream.

Polk, James E., E-mail: james.e.polk@jpl.nasa.gov; Mikellides, Ioannis G.; Katz, Ira [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, California 91109 (United States); Capece, Angela M. [California Institute of Technology, 1200 E. California Blvd., Pasadena, California 91125 (United States)

2014-05-14T23:59:59.000Z

139

Polymers For Advanced Lithium Batteries  

Broader source: Energy.gov (indexed) [DOE]

Barriers: -(1) Energy density -(2) Safety -(3) Low cycle fife. * Partners: ANL, ALS (at LBNL) and NCEM (at LBNL) Objectives * A) Develop cost-effective method for creating...

140

NUMERICAL MODELING OF CATHODE CONTACT MATERIAL DENSIFICATION  

SciTech Connect (OSTI)

Numerical modeling was used to simulate the constrained sintering process of the cathode contact layer during assembly of solid oxide fuel cells (SOFCs). A finite element model based on the continuum theory for sintering of porous bodies was developed and used to investigate candidate low-temperature cathode contact materials. Constitutive parameters for various contact materials under investigation were estimated from dilatometry screening tests, and the influence of processing time, processing temperature, initial grain size, and applied compressive stress on the free sintering response was predicted for selected candidate materials. The densification behavior and generated stresses within a 5-cell planar SOFC stack during sintering, high temperature operation, and room temperature shutdown were predicted. Insufficient constrained densification was observed in the stack at the proposed heat treatment, but beneficial effects of reduced grain size, compressive stack preload, and reduced thermal expansion coefficient on the contact layer densification and stresses were observed.

Koeppel, Brian J.; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Cathode power distribution system and method of using the same for power distribution  

DOE Patents [OSTI]

Embodiments include a cathode power distribution system and/or method of using the same for power distribution. The cathode power distribution system includes a plurality of cathode assemblies. Each cathode assembly of the plurality of cathode assemblies includes a plurality of cathode rods. The system also includes a plurality of bus bars configured to distribute current to each of the plurality of cathode assemblies. The plurality of bus bars include a first bus bar configured to distribute the current to first ends of the plurality of cathode assemblies and a second bus bar configured to distribute the current to second ends of the plurality of cathode assemblies.

Williamson, Mark A; Wiedmeyer, Stanley G; Koehl, Eugene R; Bailey, James L; Willit, James L; Barnes, Laurel A; Blaskovitz, Robert J

2014-11-11T23:59:59.000Z

142

Optogalvanic effect in a hollow cathode discharge with nonlaser sources  

SciTech Connect (OSTI)

Several atomic emission sources were investigated for their potential to induce optogalvanic signals in hollow cathode lamps. The sources included an inductively coupled argon plasma, a H/sub 2/--O/sub 2/ flame, a high-temperature furnace, electrodeless microwave discharge lamps, and hollow cathode lamps. Successful results were obtained with argon emission from the inductively coupled plasma focused into an argon-filled hollow cathode tube and with atomic emission from one hollow cathode discharge focused into a hollow cathode tube containing the same element. Very low level optogalvanic signals were observed from the other sources but could not be unambiguously ascribed to emission from a specific element. A problem encountered was the presence of a background signal due to photoelectric emission and possibly radiative heating of the cathode.

Apel, C.T.; Keller, R.A.; Zalewski, E.F.; Engleman, R. Jr.

1982-04-15T23:59:59.000Z

143

Molten carbonate fuel cell cathode with mixed oxide coating  

DOE Patents [OSTI]

A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

Hilmi, Abdelkader; Yuh, Chao-Yi

2013-05-07T23:59:59.000Z

144

Comments on cathode contaminants and the LBNL test stand  

E-Print Network [OSTI]

LBNL-61978 Comments oncathode contaminants and the LBNL test stand F. Bieniosek,the process of operating the LBNL DARHT cathode test stand.

Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

2006-01-01T23:59:59.000Z

145

Cell Analysis ? High-Energy Density Cathodes and Anodes  

Broader source: Energy.gov (indexed) [DOE]

does not contain any proprietary, confidential, or otherwise restricted information LBNL Project ID: ES053 OVERVIEW Timeline * PI Joined BATT 2001 * Cathodes Task Started 2001...

146

Development of spray coated cathodes for RITS-6.  

SciTech Connect (OSTI)

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean; Leckbee, Joshua J.; Miller, Stephen Samuel

2013-09-01T23:59:59.000Z

147

Secondary-electrons-induced cathode plasma in a relativistic magnetron  

SciTech Connect (OSTI)

Results of time- and space-resolved spectroscopic studies of cathode plasma during a S-band relativistic magnetron operation and a magnetically insulated diode having an identical interelectrode gap are presented. It was shown that in the case of the magnetron operation, one obtains an earlier, more uniform plasma formation due to energetic electrons' interaction with the cathode surface and ionization of desorbed surface monolayers. No differences were detected in the cathode's plasma temperature between the magnetron and the magnetically insulated diode operation, and no anomalous fast cathode plasma expansion was observed in the magnetron at rf power up to 350 MW.

Queller, T.; Gleizer, J. Z.; Krasik, Ya. E. [Physics Department, Technion, Haifa 32000 (Israel)

2012-11-19T23:59:59.000Z

148

Cathode Synthesis and Voltage Fade: Designed Solutions Based...  

Broader source: Energy.gov (indexed) [DOE]

(PI), Eungje Lee, and Michael Slater Chemical Sciences and Engineering Division Argonne National Laboratory Annual Merit review, Washington DC May 13-17, 2013 Cathode Synthesis and...

149

Cathode dissolution: Quarterly report, January-March 1987  

SciTech Connect (OSTI)

One important mode of degradation of current MCFCs is the dissolution of the NiO cathode into the electrolyte tile and the subsequent precipitation of Ni in the tile. Over time the performance of the cell degrades, and evantually the cell may short out locally via a bridge of Ni particles between the cathode and anode. The purpose of this program is to further the understanding of the processes which cause degradation of the NiO cathode in MCFCs, especially those processes involving dissolution of the cathode and the transport of soluble Ni species in the electrolyte. 6 figs., 3 tabs.

Shores, D.A.

1987-07-01T23:59:59.000Z

150

Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode Materials Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing...

151

Design and Evaluation of Novel High Capacity Cathode Materials  

Broader source: Energy.gov (indexed) [DOE]

Design and Evaluation of Novel High Capacity Cathode Materials Christopher Johnson and Michael Thackeray Chemical Sciences and Engineering Division, Argonne Annual Merit Review DOE...

152

Cathode side hardware for carbonate fuel cells  

DOE Patents [OSTI]

Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO.sub.3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1) and X-doped LiMeO.sub.2, wherein X is one of Mg, Ca, and Co.

Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

2011-04-05T23:59:59.000Z

153

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

as cathode materials for Li-ion battery. Physica B-CondensedHigh Energy High Power Li-ion Battery Cathode Materials AHigh Energy High Power Li-ion Battery Cathode Materials A

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

154

CHROMIUM POISONING OF COMPOSITE LSM/YSZ CATHODES  

E-Print Network [OSTI]

-Lin Liu and Mogens Mogensen Risø National Laboratory, Materials Research Department, DK-4000 Roskilde, Denmark Introduction Degradation of composite SOFC cathodes consisting of lanthanum strontium manganate during simulated SOFC operation at ~850°C with current densities from 0 to 0.5 A/cm2. The cathodes were

155

Self-contained hot-hollow cathode gun source assembly  

DOE Patents [OSTI]

A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

Zeren, Joseph D. (Boulder, CO)

1986-01-01T23:59:59.000Z

156

Self-contained hot-hollow cathode gun source assembly  

DOE Patents [OSTI]

A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

Zeren, J.D.

1984-08-01T23:59:59.000Z

157

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

of cathode materials for lithium batteries guided by first-facing rechargeable lithium batteries. Nature, 2001. 414(M.S. Whittingham, Lithium batteries and cathode materials.

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

158

Focused cathode design to reduce anode heating during vircator operation  

SciTech Connect (OSTI)

Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A. [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)] [Center for Pulsed Power and Power Electronics, Department of Electrical and Computer Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)

2013-10-15T23:59:59.000Z

159

Design and Evaluation of High Capacity Cathodes  

Broader source: Energy.gov (indexed) [DOE]

to prepare advanced electrodes and surfaces with stable architectural designs Use atomic-scale modeling as a guide to identify, design and understand the structural...

160

High Performance Cathodes for Li-Air Batteries  

SciTech Connect (OSTI)

The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

Xing, Yangchuan

2013-08-22T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents [OSTI]

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two.

Gay, Eddie C. (Park Forest, IL); Miller, William E. (Naperville, IL); Laidler, James J. (Burr Ridge, IL)

1997-01-01T23:59:59.000Z

162

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents [OSTI]

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two. 12 figs.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1997-07-22T23:59:59.000Z

163

Mixed polyanion glass cathodes: Iron phosphate vanadate glasses  

SciTech Connect (OSTI)

Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

2014-01-01T23:59:59.000Z

164

Efficient bottom cathodes for organic light-emitting devices  

SciTech Connect (OSTI)

Bilayers of aluminum and an alkali fluoride are well-known top cathode contacts for organic light-emitting devices but have never been successfully applied as bottom contacts. We describe a bilayer bottom cathode contact for organic electronic devices based on reversing the well-known top cathode structure such that the aluminum, rather than the alkali fluoride, contacts the organic material. Electron-only devices were fabricated showing enhanced electron injection from this bottom contact. Kelvin probe, x-ray photoelectron spectroscopy experiments, and thermodynamic calculations suggest that the enhancement results from n doping of the organic material by dissociated alkali metals.

Liu Jie; Duggal, Anil R.; Shiang, Joseph J.; Heller, Christian M. [General Electric Global Research, 1 Research Circle, Niskayuna, New York 12309 (United States)

2004-08-02T23:59:59.000Z

165

Neutronics, steady-state, and transient analyses for the Poland MARIA reactor for irradiation testing of LEU lead test fuel assemblies from CERCA : ANL independent verification results.  

SciTech Connect (OSTI)

The MARIA reactor at the Institute of Atomic Energy (IAE) in Swierk (30 km SE of Warsaw) in the Republic of Poland is considering conversion from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel assemblies (FA). The FA design in MARIA is rather unique; a suitable LEU FA has never been designed or tested. IAE has contracted with CERCA (the fuel supply portion of AREVA in France) to supply 2 lead test assemblies (LTA). The LTAs will be irradiated in MARIA to burnup level of at least 40% for both LTAs and to 60% for one LTA. IAE may decide to purchase additional LEU FAs for a full core conversion after the test irradiation. The Reactor Safety Committee within IAE and the National Atomic Energy Agency in Poland (PAA) must approve the LTA irradiation process. The approval will be based, in part, on IAE submitting revisions to portions of the Safety Analysis Report (SAR) which are affected by the insertion of the LTAs. (A similar process will be required for the full core conversion to LEU fuel.) The analysis required was established during working meetings between Argonne National Laboratory (ANL) and IAE staff during August 2006, subsequent email correspondence, and subsequent staff visits. The analysis needs to consider the current high-enriched uranium (HEU) core and 4 core configurations containing 1 and 2 LEU LTAs in various core positions. Calculations have been performed at ANL in support of the LTA irradiation. These calculations are summarized in this report and include criticality, burn-up, neutronics parameters, steady-state thermal hydraulics, and postulated transients. These calculations have been performed at the request of the IAE staff, who are performing similar calculations to be used in their SAR amendment submittal to the PAA. The ANL analysis has been performed independently from that being performed by IAE and should only be used as one step in the verification process.

Garner, P. L.; Hanan, N. A. (Nuclear Engineering Division)

2011-06-07T23:59:59.000Z

166

Transient analysis for the tajoura critical facility with IRT-2M HEU fuel and IRT-4M leu fuel : ANL independent verification results.  

SciTech Connect (OSTI)

Calculations have been performed for postulated transients in the Critical Facility at the Tajoura Nuclear Research Center (TNRC) in Libya. These calculations have been performed at the request of staff of the Renewable Energy and Water Desalinization Research Center (REWDRC) who are performing similar calculations. The transients considered were established during a working meeting between ANL and REWDRC staff on October 1-2, 2005 and subsequent email correspondence. Calculations were performed for the current high-enriched uranium (HEU) core and the proposed low-enriched uranium (LEU) core. These calculations have been performed independently from those being performed by REWDRC and serve as one step in the verification process.

Garner, P. L.; Hanan, N. A.

2005-12-02T23:59:59.000Z

167

PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL  

SciTech Connect (OSTI)

State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratory’s Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

Phelan, B.T.; Myers, D.J.; Smith, M.C.

2009-01-01T23:59:59.000Z

168

Development of Ultra-low Platinum Alloy Cathode Catalyst for...  

Energy Savers [EERE]

Alloy Cathode Catalyst for PEM Fuel Cells These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. 7uscpopov.pdf More Documents &...

169

Studies on High Voltage Lithium Rich MNC Composite Cathodes  

Broader source: Energy.gov (indexed) [DOE]

the U.S. Department of Energy Improve the current state-of-the art Li-ion cathode materials to achieve overall USABC EV energy density of 300 WhL (long-term ) at C3 and...

170

High Energy Materials for PHEVs: Cathodes (New Project)  

Broader source: Energy.gov (indexed) [DOE]

new cathode materials and to use surplus lithium in precursor structures to load thin film metal- or metal-alloy anode substrates. Collaborators Co-investigators: Sun-Ho...

171

anode cathodic protection: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OLEDs have been fabricated using a new anode-cathode-layer (ACL) that connects light emitting diode (OLED) 1, much development has been made to improve this device for...

172

Characterization of New Cathode Materials using Synchrotron-based...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Techniques and the Studies of Li-Air Batteries Characterization of New Cathode Materials using Synchrotron-based X-ray Techniques and the Studies of Li-Air Batteries 2009 DOE...

173

Design and Evaluation of Novel High Capacity Cathode Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

17johnson2011p.pdf More Documents & Publications Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells Lithium Source...

174

Carbon Dioxide Addition to Microbial Fuel Cell Cathodes Maintains  

E-Print Network [OSTI]

States Department of Agriculture, Agricultural Research Service (ARS), National Center for Agricultural-cathode MFC, CO2 addition resulted in a stable catholyte film pH of 6.61 ( 0.12 and a 152% increase in steady

Angenent, Lars T.

175

Construction of a Li Ion Battery (LIB) Cathode Production Plant...  

Broader source: Energy.gov (indexed) [DOE]

Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio Project ID ARRAVT008 Joe DiCarlo BASF Corporation May 11, 2011 "This presentation does not contain...

176

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents [OSTI]

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

177

Electrochemically Stable Cathode Current Collectors for Rechargeable Magnesium Batteries  

SciTech Connect (OSTI)

Rechargeable Mg batteries are attractive energy storage systems and could bring cost-effective energy solutions. Currently, however, no practical cathode current collectors that can withstand high voltages in Mg2+ electrolytes has been identified and therefore cathode research is greatly hindered. Here we identified that two metals, Mo and W, are electrochemically stable through formation of surface passive layers. The presented results could have significant impacts on the developments of high voltage Mg batteries.

Cheng, Yingwen; Liu, Tianbiao L.; Shao, Yuyan; Engelhard, Mark H.; Liu, Jun; Li, Guosheng

2014-01-01T23:59:59.000Z

178

Advanced Technology Vehicle Lab Benchmarking - Level 1  

Broader source: Energy.gov (indexed) [DOE]

- 7 speed dual clutch transmissions Jetta TDI (bio-fuels) Ford TADA PHEV Supplier BEV prototype BEV Tesla Hydrogen Fuel cell Hydrogen internal combustion engine ANL PHEV prototype...

179

A one-dimensional model illustrating virtual-cathode formation in a novel coaxial virtual-cathode oscillator  

SciTech Connect (OSTI)

A one-dimensional electrostatic sheet model of a coaxial geometry Virtual Cathode Oscillator (VCO) is presented. The cathode is centrally located and connects to a peripherally located plate electrode to form a resonant cavity, and is thus considered to be a novel design. Charge is modelled as concentric sheets about the cathode whose absolute position and velocity are determined as a function of time by solving the relativistic equations of motion. The model predicts the formation of a virtual cathode between the grid and plate electrodes for the case of a space-charge limited current. Setting the electron reflexing frequency (as a function of the grid potential) comparable with the cavity resonant frequency is predicted to improve the efficiency of microwave emission.

Turner, Geoffrey R., E-mail: gturner@csir.co.za [Council for Scientific and Industrial Research, PO Box 395, Pretoria 0001 (South Africa)

2014-09-15T23:59:59.000Z

180

Advanced electrorefiner design  

DOE Patents [OSTI]

A combination anode and cathode is described for an electrorefiner which includes a hollow cathode and an anode positioned inside the hollow cathode such that a portion of the anode is near the cathode. A retaining member is positioned at the bottom of the cathode. Mechanism is included for providing relative movement between the anode and the cathode during deposition of metal on the inside surface of the cathode during operation of the electrorefiner to refine spent nuclear fuel. A method is also disclosed which includes electrical power means selectively connectable to the anode and the hollow cathode for providing electrical power to the cell components, electrically transferring uranium values and plutonium values from the anode to the electrolyte, and electrolytically depositing substantially pure uranium on the hollow cathode. Uranium and plutonium are deposited at a liquid cathode together after the PuCl{sub 3} to UCl{sub 3} ratio is greater than 2:1. Slots in the hollow cathode provides close anode access for the liquid pool in the liquid cathode. 6 figs.

Miller, W.E.; Gay, E.C.; Tomczuk, Z.

1996-07-02T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Advanced electrorefiner design  

DOE Patents [OSTI]

A combination anode and cathode for an electrorefiner which includes a hollow cathode and an anode positioned inside the hollow cathode such that a portion of the anode is near the cathode. A retaining member is positioned at the bottom of the cathode. Mechanism is included for providing relative movement between the anode and the cathode during deposition of metal on the inside surface of the cathode during operation of the electrorefiner to refine spent nuclear fuel. A method is also disclosed which includes electrical power means selectively connectable to the anode and the hollow cathode for providing electrical power to the cell components, electrically transferring uranium values and plutonium values from the anode to the electrolyte, and electrolytically depositing substantially pure uranium on the hollow cathode. Uranium and plutonium are deposited at a liquid cathode together after the PuCl.sub.3 to UCl.sub.3 ratio is greater than 2:1. Slots in the hollow cathode provides close anode access for the liquid pool in the liquid cathode.

Miller, William E. (Naperville, IL); Gay, Eddie C. (Park Forest, IL); Tomczuk, Zygmunt (Lockport, IL)

1996-01-01T23:59:59.000Z

182

anl_mira.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2013 IBM Corporation Evaluation - CG Iteration and Sparse Matrix The conjugate gradient method is frequently used to solve linear systems The CG method requires...

183

ANL-678A  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Non-NRTLModified NRTL Listed Electrical Equipment Approval Form For use at Argonne National Laboratory Equipment Location Unlisted equipment that is determined to be safe to...

184

anl_mira.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout SRNL HomeYoung InventorNothing AboutPowerupdated:IBM T.

185

ANL News 2006  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of Energytt^ \APS

186

ANL-05/20  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite JC-118794Argonne National Laboratory is managed by

187

ANL/NDH-111  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite JC-118794Argonne National Laboratory is

188

Cathodic Protection of the Yaquina Bay Bridge  

SciTech Connect (OSTI)

The Yaquina Bay Bridge in Newport, Oregon, was designed by Conde B. McCullough and built in 1936. The 3,223-foot (982 m) structure is a combination of concrete arch approach spans and a steel through arch over the shipping channel. Cathodic protection is used to prevent corrosion damage to the concrete arches. The Oregon Department of Transportation (Oregon DOT) installed a carbon anode coating (DAC-85) on two of the north approach spans in 1985. This anode was operated at a current density of 6.6 mA/m2(0.6 mA/ft2). No failure of the conductive anode was observed in 1990, five years after application, or in 2000, 15 years after application. Thermal-sprayed zinc anodes 20 mils (0.5 mm) thick were applied to half the south approach spans beginning in 1990. Thermal-sprayed zinc anodes 15 mils (0.4 mm) thick were applied to the remaining spans in 1996. These anodes were operated at a current density of 2.2 mA/m2(0.2 mA/ft2). In 1999, four zones on the approach spans were included in a two-year field trial of humectants to improve zinc anode performance. The humectants LiNO3 and LiBr were applied to two zones; the two adjacent zones were left untreated as controls. The humectants substantially reduced circuit resistance compared to the controls.

Bullard, Sophie J.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Laylor, H.M.; Cryer, C.B.

2001-02-01T23:59:59.000Z

189

Inert Anode/Cathode Program: Fiscal Year 1986 annual report. [For Hall-Heroult cells  

SciTech Connect (OSTI)

Purpose of the program is to develop long-lasting, energy-efficient anodes, cathodes, and ancillary equipment for Hall-Heroult cells used by the aluminum industry. The program is divided into four tasks: Inert Anode Development, Cathode Materials Evaluation, Cathode Bonding Development, and Sensor Development. To devise sensors to control the chemistry of Hall-Heroult cells using stable anodes and cathodes. This report highlights the major FY86 technical accomplishments, which are presented in the following sections: Management, Materials Development, Materials Evaluation, Thermodynamic Evaluation, Laboratory Cell Tests, Large-Scale Tests, Cathode Materials Evaluation, Cathode Bonding Development, and Sensor Development.

Brenden, B.B.; Davis, N.C.; Koski, O.H.; Marschman, S.C.; Pool, K.H.; Schilling, C.H.; Windisch, C.F.; Wrona, B.J.

1987-06-01T23:59:59.000Z

190

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

2008-04-30T23:59:59.000Z

191

Fuel Cell Projects Kickoff Meeting February 13, 2007  

E-Print Network [OSTI]

:40 Aligned Carbon Nanotube-Based MEA and PEMFC D-J Liu, ANL 4:00 Light Weight Low Cost PEM Fuel Cell Stacks J in PEM Fuel Cells: Advanced Modeling, Material Selection, testing, and Design Characterization V. Cole Performance Cathode Supports for PEM Fuel Cells Y. Wang, PNNL 3:10 Break #12;Innovative Fuel Cell Concepts 3

192

Process system and method for fabricating submicron field emission cathodes  

DOE Patents [OSTI]

A process method and system for making field emission cathodes exists. The deposition source divergence is controlled to produce field emission cathodes with height-to-base aspect ratios that are uniform over large substrate surface areas while using very short source-to-substrate distances. The rate of hole closure is controlled from the cone source. The substrate surface is coated in well defined increments. The deposition source is apertured to coat pixel areas on the substrate. The entire substrate is coated using a manipulator to incrementally move the whole substrate surface past the deposition source. Either collimated sputtering or evaporative deposition sources can be used. The position of the aperture and its size and shape are used to control the field emission cathode size and shape.

Jankowski, Alan F. (Livermore, CA); Hayes, Jeffrey P. (Ripon, CA)

1998-01-01T23:59:59.000Z

193

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles  

SciTech Connect (OSTI)

To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ.; De Jonghe, Lutgard C.

2006-01-31T23:59:59.000Z

194

Pulsed hollow-cathode ion lasers: pumping and lasing parameters  

SciTech Connect (OSTI)

Optimal discharge conditions have been experimentally found for ion lasers excited in the hollow-cathode discharge plasma by microsecond current pulses by pumping working atoms in secondkind collisions with ions and metastable buffer-gas atoms. Measurements of the output power of krypton ion and zinc-, cadmium-, mercury-, thallium-, copper-, and gallium-vapour lasers in tubes with cathodes of different diameters showed that the pulse power reaches several tens of watts, and the average power obtained with cathodes 2 cm in diameter and a length of 40 cm or more approaches 1 W. Lasing in most media is observed simultaneously at several lines (the multi-wavelength regime). Lasing on a three-component (He - Kr - Hg) mixture is realised in the multi-wavelength regime at blue, red, and IR lines.

Zinchenko, S P; Ivanov, I G

2012-06-30T23:59:59.000Z

195

Cathodic protection of carbon steel in simulated geothermal environments  

SciTech Connect (OSTI)

The applicability of cathodic protection to mitigate corrosion of carbon steel in two different environments containing H{sub 2}S has been investigated using impressed current and sacrificial anode techniques. Results of impressed current tests conducted under potential control shows that the weight loss can be reduced significantly by shifting the potential of the metal 60 to 80 mV cathodic to the open circuit potential. The relationship between the applied current and the potential shift shows that the current requirement does not necessarily increase with the voltage shift, thus implying that the cost of cathodic protection may not increase in proportion to the protection achieved. The feasibility of using zinc as a sacrificial anode in the environment of interest has also been studied.

Bandy, R.; van Rooyen, D.

1982-10-08T23:59:59.000Z

196

Transient analyses for the Uzbekistan VVR-SM reactor with IRT-3M HEU fuel and IRT-4M LEU fuel : ANL independent verification results.  

SciTech Connect (OSTI)

Calculations have been performed for postulated transients in the VVR-SM Reactor at the Institute of Nuclear Physics (INP) of the Academy of Sciences in the Republic of Uzbekistan. (The reactor designation in Cyrillic is BBP-CM; transliterating characters to English gives VVRSM but translating words gives WWR-SM.) These calculations have been performed at the request of staff of the INP who are performing similar calculations. The transients considered were established during working meetings between Argonne National Laboratory (ANL) and INP staff during summer 2006 [Ref. 1], subsequent email correspondence, and subsequent staff visits. Calculations were performed for the current high-enriched uranium (HEU) core, the proposed low-enriched uranium (LEU) core, and one mixed HEU-LEU core during the transition. These calculations have been performed independently from those being performed by INP and serve as one step in the verification process.

Garner, P. L.; Hanan, N. A.; Nuclear Engineering Division

2007-09-24T23:59:59.000Z

197

Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Free Synthesis of LiV3O8 Nanorods as a Cathode Material for High-Rate Secondary Lithium Batteries . Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material for...

198

Preparation and electrochemical investigation of Li2CoPO4F cathode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

electrochemical investigation of Li2CoPO4F cathode material forlithium-ion batteries. Preparation and electrochemical investigation of Li2CoPO4F cathode material forlithium-ion...

199

Performance and Stability of Barium Strontium Cobaltite Composite Cathodes for SOFC  

E-Print Network [OSTI]

cathode materials than LSM. Studies of the (La,Sr)(Co,Fe)O3 (LSCF) have been one of the most popular topics in the cathode research toward to intermediate temperature operation [8-14]. LSCF is a Mixed

200

E-Print Network 3.0 - arc cathode spots Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 32, NO. 5, OCTOBER 2004 A High-Current, Large-Area, Summary: over 3000 shots, the cathode failed. Upon examina- tion of the cathode, a...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating  

SciTech Connect (OSTI)

This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

Feng Jin

2009-01-07T23:59:59.000Z

202

Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries  

E-Print Network [OSTI]

Oxides Cathodes for Lithium-ion Batteries Kinson C. Kam andusing rechargeable lithium-ion batteries has become an

Kam, Kinson

2012-01-01T23:59:59.000Z

203

Testing a GaAs cathode in SRF gun  

SciTech Connect (OSTI)

RF electron guns with a strained superlattice GaAs cathode are expected to generate polarized electron beams of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface and lower cathode temperature. We plan to install a bulk GaAs:Cs in a SRF gun to evaluate the performance of both the gun and the cathode in this environment. The status of this project is: In our 1.3 GHz 1/2 cell SRF gun, the vacuum can be maintained at nearly 10{sup -12} Torr because of cryo-pumping at 2K. With conventional activation of bulk GaAs, we obtained a QE of 10% at 532 nm, with lifetime of more than 3 days in the preparation chamber and have shown that it can survive in transport from the preparation chamber to the gun. The beam line has been assembled and we are exploring the best conditions for baking the cathode under vacuum. We report here the progress of our test of the GaAs cathode in the SRF gun. Future particle accelerators, such as eRHIC and the ILC require high-brightness, high-current polarized electrons. Strained superlattice GaAs:Cs has been shown to be an efficient cathode for producing polarized electrons. Activation of GaAs with Cs,O(F) lowers the electron affinity and makes it energetically possible for all the electrons, excited into the conduction band that drift or diffuse to the emission surface, to escape into the vacuum. Presently, all operating polarized electron sources, such as the CEBAF, are DC guns. In these devices, the excellent ultra-high vacuum extends the lifetime of the cathode. However, the low field gradient on the photocathode's emission surface of the DC guns limits the beam quality. The higher accelerating gradients, possible in the RF guns, generate a far better beam. Until recently, most RF guns operated at room temperature, limiting the vacuum to {approx}10{sup -9} Torr. This destroys the GaAs's NEA surface. The SRF guns combine the excellent vacuum conditions of DC guns and the high accelerating gradient of the RF guns, potentially offering a long lived cathode with very low emittance. Testing this concept requires preparation of the cathode, transportation to the SRF gun and evaluation of the performance of the cathode and the gun at cryogenic temperatures. In our work at BNL, we successfully activated the bulk GaAs in the preparation chamber. The highest quantum efficient was 10% at 532 nm that fell to 0.5% after 100 hours. We explored three different ways to activate the GaAs. We verified that the GaAs photocathode remains stable for 30 hours in a 10{sup -11} Torr vacuum. Passing the photocathode through the low 10{sup -9} Torr transfer section in several seconds caused the QE to drop to 0.8%. The photocathode with 0.8% QE can be tested for the SRF gun. The gun and beam pipe were prepared and assembled. After baking at 200 C baking, the vacuum of the gun and beam pipe can sustain a low 10{sup -11} Torr at room temperature. The final test to extract electrons from the gun is ongoing. In this paper, we discuss our progress with this SRF gun and the results of the photocathode in preparation chamber and in magnet transfer line.

Wang, E.; Kewisch, J.; Ben-Zvi, I.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

2011-03-28T23:59:59.000Z

204

1st Workshop on Photo-cathodes: 300nm-500nm July 20-21, 2009: University of Chicago  

E-Print Network [OSTI]

-function engineering 10:30 - 11:00 Enhancing Photon Absorption: Anti-reflection Coatings, Reflecting Sub- strates:15 - 11:45 Aerogel Photocathodes Michael Pellin (ANL) 11:45 - 12:15 New Ideas Daniel Ferenc (UC Davis

205

Project Description In the search for superior batteries, the road to success is paved with advanced materials: better  

E-Print Network [OSTI]

Project Description In the search for superior batteries, the road to success is paved with advanced materials: better cathodes, better anodes, better electrolytes. The universe of candidates is so of this proposal is that by leveraging the advances in informatics and high-throughput experimental

Sadoway, Donald Robert

206

Operational test report -- Project W-320 cathodic protection systems  

SciTech Connect (OSTI)

Washington Administrative Code (WAC) 173-303-640 specifies that corrosion protection must be designed into tank systems that treat or store dangerous wastes. Project W-320, Waste Retrieval Sluicing System (WRSS), utilizes underground encased waste transfer piping between tanks 241-C-106 and 241-AY-102. Corrosion protection is afforded to the encasements of the WRSS waste transfer piping through the application of earthen ionic currents onto the surface of the piping encasements. Cathodic protection is used in conjunction with the protective coatings that are applied upon the WRSS encasement piping. WRSS installed two new two rectifier systems (46 and 47) and modified one rectifier system (31). WAC 173-303-640 specifies that the proper operation of cathodic protection systems must be confirmed within six months after initial installation. The WRSS cathodic protection systems were energized to begin continuous operation on 5/5/98. Sixteen days after the initial steady-state start-up of the WRSS rectifier systems, the operational testing was accomplished with procedure OTP-320-006 Rev/Mod A-0. This operational test report documents the OTP-320-006 results and documents the results of configuration testing of integrated piping and rectifier systems associated with the W-320 cathodic protection systems.

Bowman, T.J.

1998-06-16T23:59:59.000Z

207

The fractal nature of vacuum arc cathode spots  

SciTech Connect (OSTI)

Cathode spot phenomena show many features of fractals, for example self-similar patterns in the emitted light and arc erosion traces. Although there have been hints on the fractal nature of cathode spots in the literature, the fractal approach to spot interpretation is underutilized. In this work, a brief review of spot properties is given, touching the differences between spot type 1 (on cathodes surfaces with dielectric layers) and spot type 2 (on metallic, clean surfaces) as well as the known spot fragment or cell structure. The basic properties of self-similarity, power laws, random colored noise, and fractals are introduced. Several points of evidence for the fractal nature of spots are provided. Specifically power laws are identified as signature of fractal properties, such as spectral power of noisy arc parameters (ion current, arc voltage, etc) obtained by fast Fourier transform. It is shown that fractal properties can be observed down to the cutoff by measurement resolution or occurrence of elementary steps in physical processes. Random walk models of cathode spot motion are well established: they go asymptotically to Brownian motion for infinitesimal step width. The power spectrum of the arc voltage noise falls as 1/f {sup 2}, where f is frequency, supporting a fractal spot model associated with Brownian motion.

Anders, Andre

2005-05-27T23:59:59.000Z

208

ENVIRONMENTAL BIOTECHNOLOGY Brewery wastewater treatment using air-cathode  

E-Print Network [OSTI]

. 1994; Parawira et al. 2005). Biological treatment processes are particularly effective for wastewaterENVIRONMENTAL BIOTECHNOLOGY Brewery wastewater treatment using air-cathode microbial fuel cells wastewater treatment using microbial fuel cells (MFCs) will require a better understanding of how operational

209

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells  

DOE Patents [OSTI]

A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

2006-03-21T23:59:59.000Z

210

Methanol-tolerant cathode catalyst composite for direct methanol fuel cells  

DOE Patents [OSTI]

A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

2006-09-05T23:59:59.000Z

211

Corrosion performance of advanced structural materials in sodium.  

SciTech Connect (OSTI)

This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

2012-05-16T23:59:59.000Z

212

Modular cathode assemblies and methods of using the same for electrochemical reduction  

DOE Patents [OSTI]

Modular cathode assemblies are useable in electrolytic reduction systems and include a basket through which fluid electrolyte may pass and exchange charge with a material to be reduced in the basket. The basket can be divided into upper and lower sections to provide entry for the material. Example embodiment cathode assemblies may have any shape to permit modular placement at any position in reduction systems. Modular cathode assemblies include a cathode plate in the basket, to which unique and opposite electrical power may be supplied. Example embodiment modular cathode assemblies may have standardized electrical connectors. Modular cathode assemblies may be supported by a top plate of an electrolytic reduction system. Electrolytic oxide reduction systems are operated by positioning modular cathode and anode assemblies at desired positions, placing a material in the basket, and charging the modular assemblies to reduce the metal oxide.

Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L

2014-12-02T23:59:59.000Z

213

Anode-cathode power distribution systems and methods of using the same for electrochemical reduction  

DOE Patents [OSTI]

Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

2014-01-28T23:59:59.000Z

214

A MULTI-LENGTH SCALE APPROACH TO CORRELATING SOLID OXIDE FUEL CELL POROUS CATHODE MICROSTRUCTURE TO ELECTROCHEMICAL PERFORMANCE  

E-Print Network [OSTI]

........................................................................................................27 3 COMPREHENSIVE QUANTIFICATION OF POROUS LSCF CATHODE MICROSTRUCTURE AND ELECTROCHEMICAL IMPEDANCE

Florida, University of

215

Using Multispectral Imaging to Measure Temperature Profiles and Emissivity of Large Thermionic Dispenser, Cathodes  

SciTech Connect (OSTI)

Thermionic dispenser cathodes are widely used in modern high-power microwave tubes. Use of these cathodes has led to significant improvement in performance. In recent years these cathodes have been used in electron linear accelerators (LINACs), particularly in induction LINACs, such as the Experimental Test Accelerator at Lawrence Livermore National Laboratory and the Relativistic Test Accelerator at Lawrence Berkeley National Laboratory. For induction LINACs, the thermionic dispenser cathode provides greater reproducibility, longer pulse lengths, and lower emittance beams than does a field emission cathode. Los Alamos National Laboratory is fabricating a dual-axis X-ray radiography machine called dual-axis radiograph hydrodynamic test (DARHT). The second axis of DARHT consists of a 2-kA, 20-MeV induction LINAC that uses a 3.2-MeV electron gun with a tungsten thermionic-dispenser cathode. Typically the DARHT cathode current density is 10 A/cm{sup 2} at 1050 C. Under these conditions current density is space-charge limited, which is desirable since current density is independent of temperature. At lower temperature (the temperature-limited regime) there are variations in the local current density due to a nonuniform temperature profile. To obtain the desired uniform current density associated with space-charge limited operation, the coolest area on the cathode must be at a sufficiently high temperature so that the emission is space-charge limited. Consequently, the rest of the cathode is emitting at the same space-charge-limited current density but is at a higher temperature than necessary. Because cathode lifetime is such a strong function of cathode temperature, there is a severe penalty for nonuniformity in the cathode temperature. For example, a temperature increase of 50 C means cathode lifetime will decrease by a factor of at least four. Therefore, we are motivated to measure the temperature profiles of our large-area cathodes.

D.F. Simmons; C.M. Fortgang; D.B. Holtkamp

2001-09-01T23:59:59.000Z

216

Inert anodes and advanced smelting of aluminum  

SciTech Connect (OSTI)

This report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issued associated with these technologies from a technical, environmental, and economic viewpoint. It discusses the outlook for the direct retrofit of advanced reduction technologies to existing aluminum smelters, and compares retrofits to ''brown field'' usage and ''green field'' adoption of the technologies. A number of observations and recommendations are offered for consideration concerning further research and development efforts that may be directed toward these advanced technologies. The opportunities are discussed in the context of incremental progress that is being made in conventional Hall-Heroult cell systems.

ASME Technical Working Group on Inert Anode Technologies

1999-07-01T23:59:59.000Z

217

Performance of Magnesium Cathode in the S Band RF Gun  

SciTech Connect (OSTI)

In this paper, we present the preliminary results of the performance of magnesium cathode in a high frequency RF gun. The quantum efficiency of magnesium showed a dramatic improvement upon laser cleaning, increasing from 10{sup -5} to 4x10{sup -4} after two hours of cleaning. The spatial uniformity of emission also improved from a spot to spot variation of 10 to a variation of 2. Measurements with charges >1 nC indicate that the transient variation of the field due to the shielding effect of the electron in the vicinity of the cathode may play a critical role in the efficient extraction of electrons. Comprehensive theory that includes the electron emission in the presence of a time dependent Schottky effect and RF effects will be discussed.

Srinivasan-Rao, T.; /Brookhaven; Palmer, D.T.; /SLAC; Ben-Zvi, I.; /Brookhaven; Miller, R.H.; /SLAC; Wang, X.J.; Woodle, M.; /Brookhaven

2011-09-01T23:59:59.000Z

218

Heterogeneous electrocatalysis in porous cathodes of solid oxide fuel cells  

E-Print Network [OSTI]

A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas dissociative adsorption and surface diffusion of the oxygen intermediate to the triple phase boundary, where charge transfer occurs. The model accurately captures the Gerischer-like frequency dependence and the oxygen partial pressure dependence of the impedance of symmetric cathode cells. Digital image analysis of the microstructure of the cathode functional layer in four different cells directly confirms the predicted connection between geometrical properties and the impedance response. As in classical catalysis, the electrocatalytic activity is controlled by an effective Thiele modulus, which is the ratio of the surface diffusion length (mean distance from an adsorption site to the triple phase boundary) to the surface boundary layer length (square root of surface diffusivity div...

Fu, Y; Bertei, A; Qi, C; Mohanram, A; Pietras, J D; Bazant, M Z

2014-01-01T23:59:59.000Z

219

Depth Profile Analysis of New Materials in Hollow Cathode Discharge  

SciTech Connect (OSTI)

In this review the possibility of hollow cathode discharge for depth profile analysis is demonstrated for several new materials: planar optical waveguides fabricated by Ag+-Na+ ion exchange process in glasses, SnO2 thin films for gas sensors modified by hexamethildisilazane after rapid thermal annealing, W- and WC- CVD layers deposited on Co-metalloceramics and WO3- CVD thin films deposited on glass. The results are compared with different standard techniques.

Djulgerova, R.; Mihailov, V.; Gencheva, V.; Popova, L.; Panchev, B. [Institute of Solid State Physics - Bulgarian Academy of Sciences, 1784 Sofia (Bulgaria); Michaylova, V. [Technical University of Sofia, 1797 Sofia (Bulgaria); Szytula, A.; Gondek, L.; Dohnalik, T.M. [Smoluchowski Institute of Physics - Jagellonian University, 30-059 Cracow (Poland); Petrovic, Z.Lj. [Institute of Physics, 11080 Zemun, Belgrade (Serbia and Montenegro)

2004-12-01T23:59:59.000Z

220

Fuel cell having dual electrode anode or cathode  

DOE Patents [OSTI]

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Negative ion source with hollow cathode discharge plasma  

DOE Patents [OSTI]

A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

Hershcovitch, A.; Prelec, K.

1980-12-12T23:59:59.000Z

222

Fuel cell having dual electrode anode or cathode  

DOE Patents [OSTI]

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

223

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents [OSTI]

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2001-01-01T23:59:59.000Z

224

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents [OSTI]

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2003-01-01T23:59:59.000Z

225

Optical and electrical investigations into cathode ignition and diode closure  

SciTech Connect (OSTI)

The temporal behavior of high-power diodes is closely related to the impedance collapse caused by the movement of the cathode and/or anode plasmas. This impedance collapse can be especially problematic when a constant power electron beam is required. This is the case for the very large area (square meters) diodes used to pump the amplifiers within the Aurora KrF laser system. The electron beam technology development program at Los Alamos utilizes the Electron Beam Test Facility (EGTF) to study diode physics in an attempt to better understand the basic phenomenology of ignition and closure. A combination of optical and electric diagnostics has been fielded on the Electron Beam Test Facility to study ignition and closure in large area electron beam diodes. A four-channel framing camera is used to observe the formation of microplasmas on the surface of the cathode and the subsequent movement of these plasmas toward the anode. Additionally, a perveance model is used to extract information about this plasma from voltage and current profiles. Results from the two diagnostics are compared. Closure velocity measurements are presented showing little dependence on applied magnetic field for both velvet and carbon felt emitters. We also report the first observation of the screening effect in large area cold cathode diodes. 13 refs., 11 figs.

Coogan, J.J.; Rose, E.A.; Shurter, R.P.

1991-01-01T23:59:59.000Z

226

Process for Low Cost Domestic Production of LIB Cathode Materials  

SciTech Connect (OSTI)

The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASF’s battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASF’s already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEM’s and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

Thurston, Anthony

2012-10-31T23:59:59.000Z

227

A knife-edge array field emission cathode  

SciTech Connect (OSTI)

many cathode applications require a new type of cathode that is able to produce short pulsed electron beams at high emission current. Gated field emitter arrays of micrometer size are recognized as candidates to meet this need and have become the research focus of vacuum microelectronics. Existing fabrication methods produce emitters that are limited either in frequency response or in current emission. One reason is that the structure of these emitters are not sufficiently optimized. In this study, the author investigated the factors that affect the performance of field emitters. An optimum emitter structure, the knife-edge field emitter array, was developed from the analysis. Large field enhancement factor, large effective emission area, and small emitter capacitance are the advantages of the structure. The author next explored various options of fabricating the knife-edge emitter structure. He proposed a unique thin film process procedure and developed the fabrication techniques to build the emitters on (110) silicon wafers. Data from the initial cathode tests showed very low onset voltages and Fowler-Nordheim type emission. Emission simulation based on the fabricated emitter structure indicated that the knife-edge emitter arrays have the potential to produce high performance in modulation frequency and current emission. Several fabrication issues that await further development are discussed and possible solutions are suggested.

Lee, B.

1994-08-01T23:59:59.000Z

228

Development of Polymer Electrolytes for Advanced Lithium Batteries  

Broader source: Energy.gov (indexed) [DOE]

* Barriers: (1) Energy density (2) Safety (3) Low cycle life * Partners: * ANL, ALS (at LBNL) and NCEM (at LBNL) Objectives * A) Develop cost-effective method for creating...

229

Novel Composite Materials for SOFC Cathode-Interconnect Contact  

SciTech Connect (OSTI)

This report summarized the research efforts and major conclusions of our University Coal Research Project, which focused on developing a new class of electrically-conductive, Cr-blocking, damage-tolerant Ag-perovksite composite materials for the cathode-interconnect contact of intermediate-temperature solid oxide fuel cell (SOFC) stacks. The Ag evaporation rate increased linearly with air flow rate initially and became constant for the air flow rate {ge} {approx} 1.0 cm {center_dot} s{sup -1}. An activation energy of 280 KJ.mol{sup -1} was obtained for Ag evaporation in both air and Ar+5%H{sub 2}+3%H{sub 2}O. The exposure environment had no measurable influence on the Ag evaporation rate as well as its dependence on the gas flow rate, while different surface morphological features were developed after thermal exposure in the oxidizing and reducing environments. Pure Ag is too volatile at the SOFC operating temperature and its evaporation rate needs to be reduced to facilitate its application as the cathode-interconnect contact. Based on extensive evaporation testing, it was found that none of the alloying additions reduced the evaporation rate of Ag over the long-term exposure, except the noble metals Au, Pt, and Pd; however, these noble elements are too expensive to justify their practical use in contact materials. Furthermore, the addition of La{sub 0.8}Sr{sub 0.2}MnO{sub 3} (LSM) into Ag to form a composite material also did not significantly modify the Ag evaporation rate. The Ag-perovskite composites with the perovskite being either (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.8}Fe{sub 0.2})O{sub 3} (LSCF) or LSM were systematically evaluated as the contact material between the ferritic interconnect alloy Crofer 22 APU and the LSM cathode. The area specific resistances (ASRs) of the test specimens were shown to be highly dependent on the volume percentage and the type of the perovskite present in the composite contact material as well as the amount of thermal cycling that the specimens were subjected to during testing. The Ag-LSCF composite contact materials proved more effective in trapping Cr within the contact material and preventing Cr migration into the cathode than the Ag-LSM composites. Ag-perovskite composite contact materials are promising candidates for use in intermediate-temperature SOFC stacks with ferritic stainless steel interconnects due to their ability to maintain acceptably low ASRs while reducing Cr migration into the cathode material.

J. H. Zhu

2009-07-31T23:59:59.000Z

230

Characterization of Atomic and Electronic Structures of Electrochemically Active SOFC Cathode Surfaces  

SciTech Connect (OSTI)

The objective of this project is to gain a fundamental understanding of the oxygen-reduction mechanism on mixed conducting cathode materials by means of quantum-chemical calculations coupled with direct experimental measurements, such as vibrational spectroscopy. We have made progress in the elucidation of the mechanisms of oxygen reduction of perovkite-type cathode materials for SOFCs using these quantum chemical calculations. We established computational framework for predicting properties such as oxygen diffusivity and reaction rate constants for adsorption, incorporation, and TPB reactions, and formulated predictions for LSM- and LSC-based cathode materials. We have also further developed Raman spectroscopy as well as SERS as a characterization tool for SOFC cathode materials. Raman spectroscopy was used to detect chemical changes in the cathode from operation conditions, and SERS was used to probe for pertinent adsorbed species in oxygen reduction. However, much work on the subject of unraveling oxygen reduction for SOFC cathodes remains to be done.

Kevin Blinn; Yongman Choi; Meilin Liu

2009-08-11T23:59:59.000Z

231

Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile  

DOE Patents [OSTI]

A large area directly heated lanthanum hexaboride (LaB.sub.6) cathode system (10) is disclosed. The system comprises a LaB.sub.6 cathode element (11) generally circular in shape about a central axis. The cathode element (11) has a head (21) with an upper substantially planar emission surface (23), and a lower downwardly and an intermediate body portion (26) which diminishes in cross-section from the head (21) towards the base (22) of the cathode element (11). A central rod (14) is connected to the base (22) of the cathode element (11) and extends along the central axis. Plural upstanding spring fingers (37) are urged against an outer peripheral contact surface (24) of the head end (21) to provide a mechanical and electrical connection to the cathode element (11).

Leung, Ka-Ngo (Hercules, CA); Gordon, Keith C. (Berkeley, CA); Kippenham, Dean O. (Castro Valley, CA); Purgalis, Peter (San Francisco, CA); Moussa, David (San Francisco, CA); Williams, Malcom D. (Danville, CA); Wilde, Stephen B. (Pleasant Hill, CA); West, Mark W. (Albany, CA)

1989-01-01T23:59:59.000Z

232

Composite Organic Radical - Inorganic Hybrid Cathode for Lithium-ion Batteries  

SciTech Connect (OSTI)

A new organic radical inorganic hybrid cathode comprised of PTMA/LiFePO4 composite system is developed and reported for the first time. The hybrid cathodes demonstrate high pulse power capability resulting in a significant improvement over the pure PTMA or LiFePO4 cathode which is very promising for transportation and other high pulse power applications that require long cycle life and lower cost.

Huang, Qian; Cosimbescu, Lelia; Koech, Phillip K.; Choi, Daiwon; Lemmon, John P.

2013-07-01T23:59:59.000Z

233

Three-Dimensional Reconstruction of Porous LSCF Cathodes D. Gostovic,*,z  

E-Print Network [OSTI]

Three-Dimensional Reconstruction of Porous LSCF Cathodes D. Gostovic,*,z J. R. Smith,* D. P In this initial study the electrochemically active region of a La0.8Sr0.2Co0.2Fe0.8O3- LSCF cathode an actual three-dimensional 3D model of a La0.8Sr0.2Co0.2Fe0.8O3- LSCF cathode and its interface

Florida, University of

234

Vehicle Technologies Office Merit Review 2014: Design and Synthesis of Advanced High-Energy Cathode Materials  

Broader source: Energy.gov [DOE]

Presentation given by Lawrence Berkeley National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the...

235

Studies on High Capacity Cathodes for Advanced Lithium-ion Systems  

Broader source: Energy.gov (indexed) [DOE]

C. Idrobo J. Nanda and V. Cooper, Spring Meeting, American Physical Society, March 02-07, 2014. * Confocal Raman Imaging and Spectroscopy of Energy Storage Materials, J. Nanda, 10...

236

Vehicle Technologies Office Merit Review 2014: Process Development and Scale-up of Advanced Cathode Materials  

Broader source: Energy.gov [DOE]

Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about process development and scale...

237

Advanced Cathode Catalysts and Supports for PEM Fuel Cells | Department of  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartment of EnergyAdministrative RecordsBiofuels Cost

238

Process Development and Scale-up of Advanced Cathode Materials | Department  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d FNEPA/309Department of EnergyProcess Design andof Energy 2

239

Process Development and Scale-up of Advanced Cathode Materials | Department  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d FNEPA/309Department of EnergyProcess Design andof Energy 2of

240

E-Print Network 3.0 - advanced cathode catalyst Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of fuel ... Source: DOE Office of Energy Efficiency and Renewable Energy, Hydrogen, Fuel Cells and Infrastructure Technologies Program Collection: Energy Storage, Conversion...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Cathodic disbondment resistance with reactive ethylene terpolymer blends and composite coatings  

E-Print Network [OSTI]

epoxide groups within epoxy resins have been utilized forfor covalent bonding with epoxy resins. A full review ofdelamination of an epoxy resin on cathodically polarized

Love, Corey T.

2008-01-01T23:59:59.000Z

242

A Micro-Scale Model for Oxygen Reduction on LSM-YSZ Cathode  

SciTech Connect (OSTI)

In this study, a micro-scale model is developed to simulate the oxygen reduction on LSM-YSZ composite cathode. The model incorporates the effects of cathode microstructural properties on the local transport phenomena and electrochemistry inside the cathode. A detailed reaction mechanism is used in the model which has two parallel routes for oxygen conversion into oxide ions, namely two-phase boundary and three-phase boundary pathways. The model predicts field distributions of local thermodynamic values, over-potential, Faradaic current and other parameters relevant to cathode performance. Electrochemical impedance simulations are performed using the current model to analyze the contribution of various processes to the overall impedance.

Pakalapati, Suryanarayana Raju; Celik, Ismail; Finklea, Harry; Gong, Mingyang; Liu, Xingbo

2011-05-01T23:59:59.000Z

243

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network [OSTI]

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

244

Power control architectures for cold cathode fluorescent lamp and light emitting diode based light sources.  

E-Print Network [OSTI]

?? In this dissertation, two different energy efficient power supply topologies are introduced for controlling cold cathode fluorescent lamp (CCFL) and high-brightness light emitting diode… (more)

Doshi, Montu V.

2010-01-01T23:59:59.000Z

245

Methods and apparatuses for making cathodes for high-temperature, rechargeable batteries  

DOE Patents [OSTI]

The approaches for fabricating cathodes can be adapted to improve control over cathode composition and to better accommodate batteries of any shape and their assembly. For example, a first solid having an alkali metal halide, a second solid having a transition metal, and a third solid having an alkali metal aluminum halide are combined into a mixture. The mixture can be heated in a vacuum to a temperature that is greater than or equal to the melting point of the third solid. When the third solid is substantially molten liquid, the mixture is compressed into a desired cathode shape and then cooled to solidify the mixture in the desired cathode shape.

Meinhardt, Kerry D; Sprenkle, Vincent L; Coffey, Gregory W

2014-05-20T23:59:59.000Z

246

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries  

E-Print Network [OSTI]

Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–O 2 Cathode Material in Lithium Ion Batteries. Adv. Energydecomposition in lithium ion batteries: first-principles

Lin, Feng

2014-01-01T23:59:59.000Z

247

E-Print Network 3.0 - air-cathode microbial fuel Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bioelectronics 30 (2011) 267271 Summary: .elsevier.comlocatebios Air-cathode structure optimization in separator-coupled microbial fuel cells Xiaoyuan Zhanga , Haotian... :...

248

Electrocatalysis of anodic and cathodic oxygen-transfer reactions  

SciTech Connect (OSTI)

The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

Wels, B.R.

1990-09-21T23:59:59.000Z

249

Code qualification of structural materials for AFCI advanced recycling reactors.  

SciTech Connect (OSTI)

This report summarizes the further findings from the assessments of current status and future needs in code qualification and licensing of reference structural materials and new advanced alloys for advanced recycling reactors (ARRs) in support of Advanced Fuel Cycle Initiative (AFCI). The work is a combined effort between Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL) with ANL as the technical lead, as part of Advanced Structural Materials Program for AFCI Reactor Campaign. The report is the second deliverable in FY08 (M505011401) under the work package 'Advanced Materials Code Qualification'. The overall objective of the Advanced Materials Code Qualification project is to evaluate key requirements for the ASME Code qualification and the Nuclear Regulatory Commission (NRC) approval of structural materials in support of the design and licensing of the ARR. Advanced materials are a critical element in the development of sodium reactor technologies. Enhanced materials performance not only improves safety margins and provides design flexibility, but also is essential for the economics of future advanced sodium reactors. Code qualification and licensing of advanced materials are prominent needs for developing and implementing advanced sodium reactor technologies. Nuclear structural component design in the U.S. must comply with the ASME Boiler and Pressure Vessel Code Section III (Rules for Construction of Nuclear Facility Components) and the NRC grants the operational license. As the ARR will operate at higher temperatures than the current light water reactors (LWRs), the design of elevated-temperature components must comply with ASME Subsection NH (Class 1 Components in Elevated Temperature Service). However, the NRC has not approved the use of Subsection NH for reactor components, and this puts additional burdens on materials qualification of the ARR. In the past licensing review for the Clinch River Breeder Reactor Project (CRBRP) and the Power Reactor Innovative Small Module (PRISM), the NRC/Advisory Committee on Reactor Safeguards (ACRS) raised numerous safety-related issues regarding elevated-temperature structural integrity criteria. Most of these issues remained unresolved today. These critical licensing reviews provide a basis for the evaluation of underlying technical issues for future advanced sodium-cooled reactors. Major materials performance issues and high temperature design methodology issues pertinent to the ARR are addressed in the report. The report is organized as follows: the ARR reference design concepts proposed by the Argonne National Laboratory and four industrial consortia were reviewed first, followed by a summary of the major code qualification and licensing issues for the ARR structural materials. The available database is presented for the ASME Code-qualified structural alloys (e.g. 304, 316 stainless steels, 2.25Cr-1Mo, and mod.9Cr-1Mo), including physical properties, tensile properties, impact properties and fracture toughness, creep, fatigue, creep-fatigue interaction, microstructural stability during long-term thermal aging, material degradation in sodium environments and effects of neutron irradiation for both base metals and weld metals. An assessment of modified versions of Type 316 SS, i.e. Type 316LN and its Japanese version, 316FR, was conducted to provide a perspective for codification of 316LN or 316FR in Subsection NH. Current status and data availability of four new advanced alloys, i.e. NF616, NF616+TMT, NF709, and HT-UPS, are also addressed to identify the R&D needs for their code qualification for ARR applications. For both conventional and new alloys, issues related to high temperature design methodology are described to address the needs for improvements for the ARR design and licensing. Assessments have shown that there are significant data gaps for the full qualification and licensing of the ARR structural materials. Development and evaluation of structural materials require a variety of experimental facilities that have been seriously degraded

Natesan, K.; Li, M.; Majumdar, S.; Nanstad, R.K.; Sham, T.-L. (Nuclear Engineering Division); (ORNL)

2012-05-31T23:59:59.000Z

250

Miniature quadrupole mass spectrometer having a cold cathode ionization source  

DOE Patents [OSTI]

An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

Felter, Thomas E. (Livermore, CA)

2002-01-01T23:59:59.000Z

251

Cathode Coating (IN-09-061) - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Healthcatalysts . | EMSLNEPA25Cathode

252

Synthesis and Characterization of Cathode Materials | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage »of Energy Strain Rate4SuperhardSuspectEngines | Department ofSyngasCathode

253

High Energy Novel Cathode / Alloy Automotive Cell | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii CleanHeatinHigh Efficiency| -4Novel Cathode

254

Effect of energetic electrons on near-wall sheath voltage in the cathode region of a cold cathode direct current discharge  

SciTech Connect (OSTI)

It is experimentally demonstrated that energetic electrons originating from the cathode or produced in volumetric processes in the cathode region of a cold cathode direct current discharge can create a large potential drop in the near-wall sheath. This voltage drop may be much greater than kT{sub e}/e (where k is the Boltzmann constant, T{sub e} is the electron temperature, and e is the electron charge). Due to the large near-wall sheath voltage, slow and moderately energetic electrons cannot reach the wall and move toward the anode. Application of additional potentials to the wall can change the amount of energetic electrons reaching the wall. This effect can be used for regulation of the near-cathode plasma and near-wall sheath properties and thus may be useful in technical applications.

Blessington, J. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States); Adams, S. F. [Air Force Research Laboratory, Wright-Patterson AFB, Ohio 45433 (United States); Demidov, V. I. [UES, Inc., 4401 Dayton-Xenia Road, Beavercreek, Ohio 45432 (United States); Department of Physics, West Virginia University, Morgantown, West Virginia 26506 (United States); Williamson, J. M. [Innovative Scientific Solutions, Inc., 2766 Indian Ripple Road, Ohio 45440-3638 (United States)

2009-10-15T23:59:59.000Z

255

Cold-Cathodes for Sensors and Vacuum Microelectronics  

SciTech Connect (OSTI)

The aim of this laboratory-directed research and development project was to study amorphous carbon (a-C) thin films for eventual cold-cathode electron emitter applications. The development of robust, cold-cathode emitters are likely to have significant implications for modern technology and possibly launch a new industry: vacuum micro-electronics (VME). The potential impact of VME on Sandia`s National Security missions, such as defense against military threats and economic challenges, is profound. VME enables new microsensors and intrinsically radiation-hard electronics compatible with MOSFET and IMEM technologies. Furthermore, VME is expected to result in a breakthrough technology for the development of high-visibility, low-power flat-panel displays. This work covers four important research areas. First, the authors studied the nature of the C-C bonding structures within these a-C thin films. Second, they determined the changes in the film structures resulting from thermal annealing to simulate the effects of device processing on a-C properties. Third, they performed detailed electrical transport measurements as a function of annealing temperature to correlate changes in transport properties with structural changes and to propose a model for transport in these a-C materials with implications on the nature of electron emission. Finally, they used scanning atom probes to determine important aspects on the nature of emission in a-C.

Siegal, M.P.; Sullivan, J.P.; Tallant, D.R.; Simpson, R.L. [Sandia National Labs., Albuquerque, NM (United States); DiNardo, N.J.; Mercer, T.W. [Drexel Univ., Philadelphia, PA (United States). Dept. of Physics and Astronomy; Martinez-Miranda, L.J. [Univ. of Maryland, College Park, MD (United States). Dept. of Materials Science and Engineering

1998-05-01T23:59:59.000Z

256

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect (OSTI)

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

257

Self-pulsing of hollow cathode discharge in various gases  

SciTech Connect (OSTI)

In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

2014-07-15T23:59:59.000Z

258

Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells  

E-Print Network [OSTI]

Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

Stockie, John

259

Effect of A-site Non-stoichiometry on LSCF Cathodes  

SciTech Connect (OSTI)

LSCF Cathodes were explored when effected with A-site non-stoichiometry. At 700-800 C, the operating temperatures of intermediate temperature (IT-) SOFCs have enabled the use of stainless steels in the SOFC framework and current collectors, allowing significant reductions in cost. However, the lower operating temperatures of IT-SOFC's also result in significant decreases in power densities of cells with LSM cathodes due to their high activation energies. LSCF is a mixed ionic electronic conducting perovskite that exhibits higher performance than LSM/YSZ composites and shows potential as a replacement cathode. This study investigates the effect of A-site stoichiometry on the performance of LSCF cathodes. Cell tests showed that A-site and Sr-deficient LSCF cathodes consistently outperformed stoichiometric LSCF cathodes, exhibiting up to 10% higher cell power densities. It was also observed that all stoichiometric, A-site, and Sr-deficient LSCF cathodes degraded over time at similar rates. Contributions of ohmic and electrode polarization losses to cell degradation rates were similar regardless of cathode composition.

Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.; Hardy, John S.

2011-09-01T23:59:59.000Z

260

On the mechanism of operation of a cathode spot cell in a vacuum arc  

SciTech Connect (OSTI)

The erosive structures formed on a tungsten cathode as a result of the motion of the cathode spot of a vacuum arc over the cathode surface have been examined. It has been found that the average mass of a cathode microprotrusion having the shape of a solidified jet is approximately equal to the mass of ions removed from the cathode within the lifetime of a cathode spot cell carrying a current of several amperes. The time of formation of a new liquid-metal jet under the action of the reactive force of the plasma ejected by the cathode spot is about 10?ns, which is comparable to the lifetime of a cell. The growth rate of a liquid-metal jet is ?10{sup 4}?cm/s. The geometric shape and size of a solidified jet are such that a new explosive emission center (spot cell) can be initiated within several nanoseconds during the interaction of the jet with the dense cathode plasma. This is the underlying mechanism of the self-sustained operation of a vacuum arc.

Mesyats, G. A.; Petrov, A. A. [P. N. Lebedev Physical Institute, RAS, 53 Leninsky Ave., Moscow 119991 (Russian Federation); Bochkarev, M. B. [Institute of Electrophysics, UB, RAS, 106 Amundsen St., Ekaterinburg 620016 (Russian Federation); Barengolts, S. A., E-mail: sb@nsc.gpi.ru [A. M. Prokhorov General Physics Institute, RAS, 38 Vavilov St., Moscow 119991 (Russian Federation)

2014-05-05T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC  

E-Print Network [OSTI]

Electrochemical characterization of cobalt-encapsulated nickel as cathodes for MCFC Anand an electroless deposition process. The electrochemical oxidation behavior of the Co-coated electrodes is similar when compared to bare nickel oxide electrodes in the presence of cathode gas. The solubility decreased

Popov, Branko N.

262

Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy  

E-Print Network [OSTI]

Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy to study the performance of cathode materials in lithium-ion batteries. The methodology takes into account. Published September 26, 2008. Lithium-ion batteries are state-of-the-art power sources1 for por- table

Subramanian, Venkat

263

Single-layer graphene cathodes for organic photovoltaics Marshall Cox,1,a  

E-Print Network [OSTI]

Single-layer graphene cathodes for organic photovoltaics Marshall Cox,1,a Alon Gorodetsky,2 Bumjung single-layer graphene is demonstrated as a cathode for organic photovoltaic devices. The measured properties indicate that graphene offers two potential advantages over conventional photovoltaic electrode

Kim, Philip

264

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network [OSTI]

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

265

Vacuum encapsulated hermetically sealed diamond amplified cathode capsule and method for making same  

DOE Patents [OSTI]

A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first cold-weld ring disposed between the cathode element and the annular insulating spacer and a second cold-weld ring disposed between the annular insulating spacer and the diamond window element. The cathode capsule is formed by a vacuum cold-weld process such that the first cold-weld ring forms a hermetical seal between the cathode element and the annular insulating spacer and the second cold-weld ring forms a hermetical seal between the annular spacer and the diamond window element whereby a vacuum encapsulated chamber is formed within the capsule.

Rao, Triveni; Walsh, John; Gangone, Elizabeth

2014-12-30T23:59:59.000Z

266

Characterization of Uranium Codeposited with Hydrogen on Nickel Cathodes  

SciTech Connect (OSTI)

Previously, it has been reported that nuclear transmutation reactions are accelerated when radioactive elements are subjected to low-level electric fields during electrolysis of aqueous electrolytes. Our research investigated the codeposition of U{sub 3}O{sub 8} and H on Ni cathodes, using an acidic electrolyte and a Pt anode. Then, the radiation emitted by the electroplated U{sub 3}O{sub 8} was compared with radiation emitted by unelectrolyzed U{sub 3}O{sub 8} from the same batch. The electroplated U{sub 3}O{sub 8} initially produced {approx}2900 counts in 3 min (April 17, 2000). This rose sporadically in steps to {approx} 3700 counts in 3 min on May 11, 2000, and it remained relatively constant at this level until the GM measurements ended on June 8, 2000. The unelectrolyzed U{sub 3}O{sub 8} from the same batch emitted radiation at a much lower rate, {approx}1250 counts in 3 min, and this remained almost constant over the entire period of measurement. After the GM measurements, a gamma-ray spectrometer was used to measure radiation from the same two, 10-mg electroplated and unelectrolyzed U{sub 3}O{sub 8} samples. The net integral of the same 36 peaks for the same measurement time (25 h) gave 53 000 counts for the electroplated sample, 1.7 times as many as the 31 000 counts for the unelectrolyzed sample. Alpha and beta measurements are under way for both samples. Figure 2 shows a scanning electron microscope micrograph of a typical surface structure of uranium electroplated on a nickel cathode. The donut-like features appear to be the result of microscopic surface eruptions that produced voids surrounded by raised circular rims. Figure 3 shows an energy dispersive spectrometer spectrum from electroplated U{sub 3}O{sub 8} on a nickel cathode. In addition to oxygen and uranium, cesium, iron, and nickel are present. A peak at 16.36 keV, which overlaps with a uranium peak at 16.44 keV, is tentatively labeled as fermium. Mass spectrometer and X-ray diffraction studies are also underway.

G. Goddard; S. Frantz

2000-11-12T23:59:59.000Z

267

Studies on Lithium Manganese Rich MNC Composite Cathodes  

Broader source: Energy.gov (indexed) [DOE]

America Inc. 3 Presentation name Project Objectives - Relevance Undertake advanced materials research in the area of high energy (capacity) electrode materials for lithium-ion...

268

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advanced Electrocatalysts for PEM Fuel Cells Fuel Cells: Just a Dream - or Future Reality Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

269

Design and Evaluation of Novel High Capacity Cathode Materials...  

Broader source: Energy.gov (indexed) [DOE]

processing routes to prepare advanced electrodes with new architectural designs Use atomic-scale modeling as a guide to identify, design and understand the structural...

270

Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries  

E-Print Network [OSTI]

0 lithium batteries. J. Electrochem. Soc.for rechargeable lithium batteries. Advanced Materials 1998,for rechargeable lithium batteries. J. Electrochem. Soc.

Zhu, Jianxin

2014-01-01T23:59:59.000Z

271

Development of High-Capacity Cathode Materials with Integrated...  

Broader source: Energy.gov (indexed) [DOE]

electrode structures at the Advanced Photon Source (APS) by X-ray diffraction, X-ray absorption and pair-distribution-function (pdf) analyses - initiated October 2011 4 ...

272

A Lithium Superionic Sulfide Cathode for Lithium-Sulfur Batteries  

SciTech Connect (OSTI)

This work presents a facile synthesis approach for core-shell structured Li2S nanoparticles, which have Li2S as the core and Li3PS4 as the shell. This material functions as lithium superionic sulfide (LSS) cathode for long-lasting, energy-efficient lithium-sulfur (Li-S) batteries. The LSS has an ionic conductivity of 10-7 S cm-1 at 25 oC, which is 6 orders of magnitude higher than that of bulk Li2S (~10-13 S cm-1). The high lithium-ion conductivity of LSS imparts an excellent cycling performance to all-solid Li-S batteries, which also promises safe cycling of high-energy batteries with metallic lithium anodes.

Lin, Zhan [ORNL] [ORNL; Liu, Zengcai [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Liang, Chengdu [ORNL] [ORNL

2013-01-01T23:59:59.000Z

273

Atlas of uranium emission intensities in a hollow cathode discharge  

SciTech Connect (OSTI)

The uranium emission spectrum from a hollow cathode discharge is displayed from 11,000 to 26,000 cm/sup -1/. This atlas lists 4928 spectral lines of uranium; 3949 are classified to the neutral spectrum and 431 are classified to the singly ionized spectrum. Listed wavenumbers are accurate to +-0.003 cm/sup -1/ and the listed relative intensities to +-8%. The richness of the spectrum makes this atlas useful for wavenumber calibration of lasers, spectrographs, and monochromators to an accuracy of 1 part in 10/sup 7/. This atlas is also useful as a guide to the uranium spectrum, and relative oscillator strengths (gf values) can be calculated from the intensities to a precision of +-20%.

Palmer, B.A.; Keller, R.A.; Engleman, R. Jr.

1980-07-01T23:59:59.000Z

274

Final Report on "Development and Testing of Advanced Accelerator Structures and Technologies at 11.424 GHz"  

SciTech Connect (OSTI)

This is the final report on the research program ?Development and Testing of Advanced Accelerator Structures and Technologies at 11.424 GHz,? which was carried out by the Naval Research Laboratory (NRL) under Interagency Agreement DE?AI02?01ER41170 with the Department of Energy. The period covered by this report is 15 July 2010 ? 14 July 2013. The program included two principal tasks. Task 1 involved a study of the key physics issues related to the use of high gradient dielectric-loaded accelerating (DLA) structures in rf linear accelerators and was carried out in collaboration with Argonne National Laboratory (ANL) and Euclid Techlabs LLC. Task 2 involved a study of high power active microwave pulse compressors and was carried out in collaboration with Omega-P, Inc. and the Institute of Applied Physics of the Russian Academy of Sciences in Nizhny Novgorod. The studies under Task 1 were focused on rf-induced multipactor and breakdown in externally driven DLA structures at the 200-ns timescale. Suppression of multipactor and breakdown are essential to the practical application of dielectric structures in rf linear accelerators. The structures that were studied were developed by ANL and Euclid Techlabs and their performance was evaluated at high power in the X-band Magnicon Laboratory at NRL. Three structures were designed, fabricated, and tested, and the results analyzed in the first two years of the program: a clamped quartz traveling-wave (TW) structure, a externally copper-coated TW structure, and an externally copper-coated dielectric standing-wave (SW) structure. These structures showed that rf breakdown could be largely eliminated by eliminating dielectric joints in the structures, but that the multipactor loading was omnipresent. In the third year of the program, the focus of the program was on multipactor suppression using a strong applied axial magnetic field, as proposed by Chang et al. [C. Chang et al., J. Appl. Phys. 110, 063304 (2011).], and a successful experiment was carried out that demonstrated suppression of multipactor in the uniform-field region of a TW DLA structure. However, in accordance with theory, the multipactor was enhanced in regions of the structure with lower values of axial magnetic field. Under Task 2, there were two two-month experimental runs at NRL that were used to characterize the performance of high power two-channel dual-mode active microwave pulse compressor configurations that used electron-beam triggered switch cavities. The pulse compressors were designed and fabricated by Omega-P, Inc. and the Russian Institute of Applied Physics and tested in the Magnicon Laboratory at NRL. These pulse compressors made use of an electron beam discharge from a cylindrical knife-edged Mo cathode coated with a CVD diamond film that was driven by a ?100 kV, 100 ns high voltage pulse. The electron beam was used to change the resonant frequency of the switch cavities in order to create the output microwave pulse. The compressor channels included a TE01 input and output section and a TE02 energy storage cavity, followed by a switch assembly that controlled the coupling between the TE01 and TE02 modes. In the initial state, the switch cavity was in resonance, the reflection from the cavity was out of phase, and the mode conversion was only ~2-3%, allowing the energy storage cavity to fill. When the electron beam was discharged into the switch cavity, the cavity was shifted out of resonance, causing the phase of the reflection to change by ~?. As a result of the change in the reflection phase, the mode coupling in the conical taper was greatly increased, and could approach ~100%, permitting the energy storage cavity to empty in one cavity round trip time of the TE02 mode to produce a high power output pulse. The second experiment runs demonstrated a 190 MW, ~20 ns compressed pulse at 25.7 gain and ~50% efficiency, using a 7.4 MW, 1 ?s drive pulse from the magnicon. The success of this experiment suggests a path to future high gain active versions of the SLED 2 pulse compressor at SLAC.

Gold, Steven H. [Naval Research Laboratory

2013-10-13T23:59:59.000Z

275

ANL-FF-262i  

Office of Legacy Management (LM)

consists of 1 page, No.>f 7 copies. SeriesA. -,-- 22 February 1952 TO; B. Blumenthal Metallurgy From: H, Luetzow Metallurgy Re: HIGH PURITY CRANIUM TO BE ROLLID TO FOIL M r, E....

276

Djurcic_ANL_June2010  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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277

ANL-FF-262i  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou areDowntown Site -MiamiYVE r

278

ANL Beams and Applications Seminar  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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279

ANL/APS/TB-11  

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280

ANL/APS/TB-13  

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Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
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281

ANL/APS/TB-17  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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282

ANL/APS/TB-18  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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283

ANL/APS/TB-2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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284

ANL2014-JMA.ppt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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285

July2006ANL40.ppt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJeffersonJonathan Pershing AboutJuly13, 2012 1:00July 20146,

286

Ahn-ANL_User_Meeting  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre theAdministratorCFM LEAPAgenda

287

Advanced Combustion  

SciTech Connect (OSTI)

The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

Holcomb, Gordon R. [NETL

2013-03-11T23:59:59.000Z

288

Characterization of Cathode Materials for Rechargeable Lithium Batteries using Synchrotron Based In Situ X-ray Techniques  

SciTech Connect (OSTI)

The emergence of portable telecommunication, computer equipment and ultimately hybrid electric vehicles has created a substantial interest in manufacturing rechargeable batteries that are less expensive, non-toxic, operate for longer time, small in size and weigh less. Li-ion batteries are taking an increasing share of the rechargeable battery market. The present commercial battery is based on a layered LiCoO{sub 2} cathode and a graphitized carbon anode. LiCoO{sub 2} is expensive but it has the advantage being easily manufactured in a reproducible manner. Other low cost layered compounds such as LiNiO{sub 2}, LiNi{sub 0.85}Co{sub 0.15}O{sub 2} or cubic spinels such as LiMn{sub 2}O{sub 4} have been considered. However, these suffer from cycle life and thermal stability problems. Recently, some battery companies have demonstrated a new concept of mixing two different types of insertion compounds to make a composite cathode, aimed at reducing cost and improving self-discharge. Reports clearly showed that this blending technique can prevent the decline in ·capacity caused by cycling or storage at elevated temperatures. However, not much work has been reported on the charge-discharge characteristics and phase transitions for these composite cathodes. Understanding the structure and structural changes of electrode materials during the electrochemical cycling is the key to develop better .lithium ion batteries. The successful commercialization of the· lithium-ion battery is mainly built on the advances in solid state chemistry of the intercalation compounds. Most of the progress in understanding the lithium ion battery materials has been obtained from x-ray diffraction studies. Up to now, most XRD studies on lithium-ion battery materials have been done ex situ. Although these ex situ XRD studies have provided important information· about the structures of battery materials, they do face three major problems. First of all, the pre-selected charge (discharge) states may not be representative for the full picture of the structural changes during charge (discharge). In other words, the important information might be missed for those charge (discharge) states which were not selected for ex situ XRD studies. Secondly, the structure of the sample may have changed after removed from the cell. Finally, it is impossible to use the ex situ XRD to study the dynamic effects during high rate charge-discharge, which is crucial for the application of lithium-ion batteries for electric vehicle. A few in situ studies have been done using conventional x-ray tube sources. All of the in situ XRD studies using conventional x-ray tube sources have been done in the reflection mode in cells with beryllium windows. Because of the weak signals, data collection takes a long time, often several hundred hours for a single charge-discharge cycle. This long time data collection is not suitable for dynamic studies at all. Furthermore, in the reflection mode, the x-ray beam probes mainly the surface layer of the cathode materials. Iri collaboration with LG Chemical Ltd., BNL group designed and constructed the cells for in situ studies. LG Chemical provided several blended samples and pouch cells to BNL for preliminary in situ study. The LG Chemical provided help on integrate the blended cathode into these cells. The BNL team carried out in situ XAS and XRD studies on the samples and pouch cells provided by LG Chemical under normal charge-discharge conditions at elevated temperature.

Yang, Xiao-Qing

2007-05-23T23:59:59.000Z

289

Generalized space-charge limited current and virtual cathode behaviors in one-dimensional drift space  

SciTech Connect (OSTI)

This paper reports the space-charge limited current (SLC) and virtual cathode behaviors in one-dimensional grounded drift space. A simple general analytical solution and an approximate solution for the planar diode are given. Through a semi-analytical method, a general solution for SLC in one-dimensional drift space is obtained. The behaviors of virtual cathode in the drift space, including dominant frequency, electron transit time, position, and transmitted current, are yielded analytically. The relationship between the frequency of the virtual cathode oscillation and the injected current presented may explain previously reported numerical works. Results are significant in facilitating estimations and further analytical studies.

Yang, Zhanfeng; Liu, Guozhi [Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049 (China) [Key Laboratory for Physical Electronics and Devices of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049 (China); Northwest Institute of Nuclear Technology, P.O. Box 69-13, Xi'an 710024 (China); Shao, Hao; Chen, Changhua; Sun, Jun [Northwest Institute of Nuclear Technology, P.O. Box 69-13, Xi'an 710024 (China)] [Northwest Institute of Nuclear Technology, P.O. Box 69-13, Xi'an 710024 (China)

2013-10-15T23:59:59.000Z

290

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wongchang

2014-05-13T23:59:59.000Z

291

Degradation Mechanisms of La-Sr-Co-Fe-O3 SOFC Cathodes  

SciTech Connect (OSTI)

The long-term stability of anode-supported YSZ electrolyte SOFCs utilizing (La0.6Sr0.4)0.98Co0.2Fe0.8O3-? (LSCF-6428) cathodes was assessed. Samples tested for 500 hours at 750 C and 0.7V indicated ?50% degradation. While scanning electron microscopy (SEM) and energy dispersive x-ray (EDX) analysis indicated no obvious microstructural or chemical phenomena that could explain the high degradation, x-ray photon spectroscopy (XPS) revealed that enrichment of Sr at the cathode-electrolyte and cathode-current collector interfaces was at least partially responsible for the observed degradation.

Simner, Steve P.; Anderson, Michael D.; Engelhard, Mark H.; Stevenson, Jeffry W.

2006-08-17T23:59:59.000Z

292

The evidence of cathodic micro-discharges during plasma electrolytic oxidation process  

SciTech Connect (OSTI)

Plasma electrolytic oxidation (PEO) processing of EV31 magnesium alloy has been carried out in fluoride containing electrolyte under bipolar pulse current regime. Unusual PEO cathodic micro-discharges have been observed and investigated. It is shown that the cathodic micro-discharges exhibit a collective intermittent behavior, which is discussed in terms of charge accumulations at the layer/electrolyte and layer/metal interfaces. Optical emission spectroscopy is used to determine the electron density (typ. 10{sup 15}?cm{sup ?3}) and the electron temperature (typ. 7500?K) while the role of F{sup ?} anions on the appearance of cathodic micro-discharges is pointed out.

Nominé, A., E-mail: alexandre.nomine@univ-lorraine.fr [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation); Martin, J.; Noël, C.; Henrion, G.; Belmonte, T. [Institut Jean Lamour, UMR 7198 CNRS, Université de Lorraine, Parc de Saurupt, 54011 Nancy (France); Bardin, I. V.; Kovalev, V. L.; Rakoch, A. G. [National Institute of Science and Technology “MISiS,” 4, Leninskij Prospekt, Moscow 119049 (Russian Federation)

2014-02-24T23:59:59.000Z

293

Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials  

SciTech Connect (OSTI)

Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

2012-02-01T23:59:59.000Z

294

Advanced Combustion  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout the Building TechnologiesS1!4T opAddress:AdolphusAdvanced Energy

295

Advanced Vehicle Testing & Evaluation  

Broader source: Energy.gov (indexed) [DOE]

Provide benchmark data for advanced technology vehicles Develop lifecycle cost data for production vehicles utilizing advanced power trains Provide fleet...

296

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)  

SciTech Connect (OSTI)

Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

Not Available

2012-10-01T23:59:59.000Z

297

SURFACE SEGREGATION STUDIES OF SOFC CATHODES: COMBINING SOFT X-RAYS AND ELECTROCHEMICAL IMPEDENCE SPECTROSCOPY  

SciTech Connect (OSTI)

A system to grow heteroepitaxial thin-films of solid oxide fuel cell (SOFC) cathodes on single crystal substrates was developed. The cathode composition investigated was 20% strontium-doped lanthanum manganite (LSM) grown by pulsed laser deposition (PLD) on single crystal (111) yttria-stabilized zirconia (YSZ) substrates. By combining electrochemical impedance spectroscopy (EIS) with x-ray photoemission spectroscopy (XPS) and x-ray absorption spectroscopy XAS measurements, we conclude that electrically driven cation migration away from the two-phase gas-cathode interface results in improved electrochemical performance. Our results provide support to the premise that the removal of surface passivating phases containing Sr2+ and Mn2+, which readily form at elevated temperatures even in O2 atmospheric pressures, is responsible for the improved cathodic performance upon application of a bias.

Miara, Lincoln J.; Piper, L.F.J.; Davis, Jacob N.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Basu, Soumendra; Smith, K. E.; Pal, Uday B.; Gopalan, Srikanth

2010-12-01T23:59:59.000Z

298

E-Print Network 3.0 - affecting pulsed-cathodic protection Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hall thruster with low-sputtering carbon-velvet electrodes Summary: of a similar carbon fiber velvet material for short-pulse cathodes of high-power microwave tubes,7 for...

299

Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial  

E-Print Network [OSTI]

Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial electrolysis cell Roland D. Cusick*, Mark L. Ullery, Brian A. Dempsey, Bruce E. Logan Department of Civil January 2014 Available online 6 February 2014 Keywords: Microbial electrolysis cell Electrochemical

300

Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell  

Broader source: Energy.gov [DOE]

Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy novel cathode / alloy...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Short communication Performance of microbial fuel cells with and without Nafion solution as cathode  

E-Print Network [OSTI]

Short communication Performance of microbial fuel cells with and without Nafion solution as cathode online 31 March 2010 Keywords: Microbial fuel cell (MFC) Nafion Electrochemical impedance spectroscopy (EIS) Internal resistance Electricity production The performance of tubular microbial fuel cells (MFC

302

Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries  

E-Print Network [OSTI]

A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

Moore, Charles J. (Charles Jacob)

2012-01-01T23:59:59.000Z

303

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network [OSTI]

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

304

Cathodic disbondment resistance with reactive ethylene terpolymer blends and composite coatings  

E-Print Network [OSTI]

EPDM EVA ethylene vinyl acetate FBE fusion-bonded epoxy GMACoating Thickness on FBE ………………. Figure 7.13: NormalizedWhen XANES was applied to FBE-coated iron, the cathodically

Love, Corey T.

2008-01-01T23:59:59.000Z

305

Supply and demand in the material recovery system for cathode ray tube glass  

E-Print Network [OSTI]

This paper presents an analysis of the material recovery system for leaded glass from cathode ray tubes (CRTs). In particular, the global mass flow of primary and secondary CRT glass and the theoretical capacities for using ...

Nadeau, Marie-Claude

306

Corrosion mechanisms in aqueous solutions containing dissolved H2S. Part 2: Mode! ofthe cathodic reactions.  

E-Print Network [OSTI]

Corrosion mechanisms in aqueous solutions containing dissolved H2S. Part 2: Mode! ofthe cathodicFP Energies nouvelles, Rond-point de 1'Ă©changeur de Solaize BP3, 69360 Solaize, France. J. Corrosion

Paris-Sud XI, Université de

307

The role of phase transformation in the rate performance limited Lix? V? O? battery cathode  

E-Print Network [OSTI]

It has recently been reported that the rate performance of Lix? V?O?, a widely studied candidate Li-ion battery cathode material, can be significantly improved through a variety of particle size reduction techniques, (e.g. ...

Avery, Kenneth Charles

2009-01-01T23:59:59.000Z

308

Development of High-Capacity Cathode Materials with Integrated...  

Broader source: Energy.gov (indexed) [DOE]

structures at the Advanced Photon Source (APS) by X-ray diffraction (XRD), X-ray absorption (XAS) and pair-distribution-function (PDF) analyses - on-going 4 ...

309

Advanced LIGO  

E-Print Network [OSTI]

The Advanced LIGO gravitational wave detectors are second generation instruments designed and built for the two LIGO observatories in Hanford, WA and Livingston, LA. The two instruments are identical in design, and are specialized versions of a Michelson interferometer with 4 km long arms. As in initial LIGO, Fabry-Perot cavities are used in the arms to increase the interaction time with a gravitational wave, and power recycling is used to increase the effective laser power. Signal recycling has been added in Advanced LIGO to improve the frequency response. In the most sensitive frequency region around 100 Hz, the design strain sensitivity is a factor of 10 better than initial LIGO. In addition, the low frequency end of the sensitivity band is moved from 40 Hz down to 10 Hz. All interferometer components have been replaced with improved technologies to achieve this sensitivity gain. Much better seismic isolation and test mass suspensions are responsible for the gains at lower frequencies. Higher laser power, larger test masses and improved mirror coatings lead to the improved sensitivity at mid- and high- frequencies. Data collecting runs with these new instruments are planned to begin in mid-2015.

The LIGO Scientific Collaboration

2014-11-17T23:59:59.000Z

310

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes  

SciTech Connect (OSTI)

Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385°C for 2 h, and subsequently creep-flattened at 1350°C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500°C to 750°C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650°C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

2010-05-08T23:59:59.000Z

311

Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell  

E-Print Network [OSTI]

. Researchers all over the world are focusing on optimizing this system to be cost competitive with energy conversion devices currently available. It is a well known fact that the cathode of the PEM fuel cell is the performance limiting component due...THREE DIMENSIONAL EFFECTS OF LIQUID WATER FLOODING IN THE CATHODE OF A PEM FUEL CELL by Dilip Natarajan and Trung Van Nguyen* Department of Chemical and Petroleum Engineering University of Kansas Lawrence, KS 66045, USA Submitted...

Natarajan, Dilip; Van Nguyen, Trung

2003-03-27T23:59:59.000Z

312

Oxygen transport in the internal xenon plasma of a dispenser hollow cathode  

SciTech Connect (OSTI)

Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O{sub 2} partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25?mm diameter orifice operated at a discharge current of 15?A, a Xe flow rate of 3.7 sccm, and 100?ppm of O{sub 2}. The dominant ionization process for O{sub 2} is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O{sub 2} are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

Capece, Angela M., E-mail: acapece@pppl.gov; Shepherd, Joseph E. [California Institute of Technology, Pasadena, California 91125 (United States); Polk, James E.; Mikellides, Ioannis G. [Jet Propulsion Laboratory, 4800 Oak Grove Dr., Pasadena, California 91109 (United States)

2014-04-21T23:59:59.000Z

313

The design of a cathode to operate in an oxygen-rich environment  

SciTech Connect (OSTI)

The primary problem with Hall plasma accelerator operation on oxygen is poor cathode performance and short lifetime. The primary problem with micro Hall thrusters is the absence of a stable low power cathode. Cathodes traditionally used for both applications employ thermionic emitters which are not efficient and which are easily oxidized in an oxygen-rich environment. The field emitter cathode presented in this report has the potential of filling both vacancies since it does not require a high-power heater and can be scaled down with the size of the thruster. The advantages to using Hf and HfC as emitting materials are low work functions and high resistance to oxygen poisoning. Preliminary investigations proved that HfC emitters can operate in 7.6 mTorr oxygen pressure environments. The initial cathode design employs an electrostatic lens that also acts as an ion filter to prevent thruster ions from bombarding the field emitters while decelerating the electron beam and keeping it focused to ensure efficient performance. Electron trajectories through the cathode and ion filtering capabilities are presented in this report as predicted by the charged particle code, MAGIC.

Marrese, Colleen M.; Gallimore, Alec D.; Mackie, William A.; Evans, David E. [Plasmadynamic and Electric Propulsion Lab., University of Michigan Dept. of Aerospace Engineering FXB Building, 1320 Beal Ann Arbor, Michigan 48109-2118 (United States); Linfield Research Institute 900 Baker St. McMinnville, Oregon 97128-6894 (United States)

1997-01-10T23:59:59.000Z

314

Neutral beam dump with cathodic arc titanium gettering  

SciTech Connect (OSTI)

An incomplete neutral beam capture can degrade the plasma performance in neutral beam driven plasma machines. The beam dumps mitigating the shine-through beam recycling must entrap and retain large particle loads while maintaining the beam-exposed surfaces clean of the residual impurities. The cathodic arc gettering, which provides high evaporation rate coupled with a fast time response, is a powerful and versatile technique for depositing clean getter films in vacuum. A compact neutral beam dump utilizing the titanium arc gettering was developed for a field-reversed configuration plasma sustained by 1 MW, 20-40 keV neutral hydrogen beams. The titanium evaporator features a new improved design. The beam dump is capable of handling large pulsed gas loads, has a high sorption capacity, and is robust and reliable. With the beam particle flux density of 5 x 10{sup 17} H/(cm{sup 2}s) sustained for 3-10 ms, the beam recycling coefficient, defined as twice the ratio of the hydrogen molecular flux leaving the beam dump to the incident flux of high-energy neutral atoms, is {approx}0.7. The use of the beam dump allows us to significantly reduce the recycling of the shine-through neutral beam as well as to improve the vacuum conditions in the machine.

Smirnov, A.; Korepanov, S. A.; Putvinski, S. [Tri Alpha Energy Inc., Rancho Santa Margarita, California 92688 (United States); Krivenko, A. S.; Murakhtin, S. V.; Savkin, V. Ya. [Budker Institute of Nuclear Physics, Novosibirsk 630090 (Russian Federation)

2011-03-15T23:59:59.000Z

315

Iron-based perovskite cathodes for solid oxide fuel cells  

DOE Patents [OSTI]

An A and/or A' site deficient perovskite of general formula of (A1-xA'x)1-yFeO3-.delta. or of general formula A1-x-yA'xFeO3-67, wherein A is La alone or with one or more of the rare earth metals or a rare earth metal other than Ce alone or a combination of rare earth metals and X is in the range of from 0 to about 1; A' is Sr or Ca or mixtures thereof and Y is in the range of from about 0.01 to about 0.3; .delta. represents the amount of compensating oxygen loss. If either A or A' is zero the remaining A or A' is deficient. A fuel cell incorporating the inventive perovskite as a cathode is disclosed as well as an oxygen separation membrane. The inventive perovskite is preferably single phase.

Ralph, James M.; Rossignol, Cecile C.R.; Vaughey, John T.

2007-01-02T23:59:59.000Z

316

Ignition and extinction phenomena in helium micro hollow cathode discharges  

SciTech Connect (OSTI)

Micro hollow cathode discharges (MHCD) were produced using 250??m thick dielectric layer of alumina sandwiched between two nickel electrodes of 8??m thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*({sup 3}S{sub 1}) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2??s long current peak as high as 24?mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400?Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the extinction period at high pressure also appeared on the density of He*({sup 3}S{sub 1}) metastable atoms, but delayed by a few ?s relative to the current oscillations. Metastable atoms thus cannot be at the origin of the generation of the observed instabilities.

Kulsreshath, M. K.; Schwaederle, L.; Dufour, T.; Lefaucheux, P.; Dussart, R. [GREMI, CNRS/Université d'Orléans (UMR7344), Orléans (France); Sadeghi, N. [LIPhy, CNRS and Universite Joseph Fourier (UMR5588), Grenoble (France); Overzet, L. J. [GREMI, CNRS/Université d'Orléans (UMR7344), Orléans (France); PSAL, UTDallas, Richardson, Texas 75080-3021 (United States)

2013-12-28T23:59:59.000Z

317

A Method for Monitoring Deposition at a Solid Cathode in an Electrorefiner for a Two-Species System Using Electrode Potentials  

SciTech Connect (OSTI)

Currently, process monitoring of spent nuclear fuel electrorefining relies upon sampling and destructive analysis methods coupled with extrapolative thermodynamic process models for non-interrupted operations. Corrections to those models are performed infrequently, jeopardizing both the control of the process and safeguarding of nuclear material. Furthermore, the timeliness of obtaining the results is inadequate for application of international safeguards protocol. Alternatively, a system that dynamically utilizes electrical data such as electrode potentials and cell current can hypothetically be used to achieve real-time process monitoring and more robust control as well as improved safeguards. Efforts to develop an advanced model of the electrorefiner to date have focused on a forward modeling approach by using feed and salt compositions to determine the product composition, cell current and electrode potential response. Alternatively, an inverse model was developed, and reported here, to predict the product deposition rates on a cathode using the cell current, cathode potential, and fundamental relations of electrochemistry. The model was applied to the following cases: pure uranium deposition, co-deposition of uranium and plutonium, and co-deposition of uranium and zirconium. The deposition rates predicted by the inverse model were compared to those of a forward model, ERAD.

D.S. Rappleye; M.-S. Yim; M.F. Simpson; R.M. Cumberland

2013-10-01T23:59:59.000Z

318

Overview and Progress of United States Advanced Battery Research...  

Broader source: Energy.gov (indexed) [DOE]

* Targets Timeline Budget Barriers * Chrysler, Ford, GM, DOE * INL, ANL, SNL, NREL, LBNL, ORNL Partners Overview DOE Goals HEV 2010 PHEV 2015 EV 2020 Cost System 500-800...

319

Overview and Progress of United States Advanced Battery Consortium...  

Broader source: Energy.gov (indexed) [DOE]

FY11 - 26.9M Timeline Budget Barriers * Chrysler, Ford, GM, DOE * INL, ANL, SNL, NREL, LBNL, ORNL Partners Overview DOE Goals HEV 2010 PHEV 2015 EV 2020 Cost System 500-800...

320

Two types of diffusions at the cathode/electrolyte interface in IT-SOFCs  

SciTech Connect (OSTI)

Analytical transmission electron microscopy, in particular with the combination of energy dispersive X-ray spectroscopy (EDX) and electron energy-loss spectroscopy (EELS), has been performed to investigate the microstructure and microchemistry of the interfacial region between the cathode (La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3}, LSCF) and the electrolyte (Gd-doped ceria, GDC). Two types of diffusions, mutual diffusion between cathode and electrolyte as well as the diffusion along grain boundaries, have been clarified. These diffusions suggest that the chemical stability of LSCF and GDC are not as good as previously reported. The results are more noteworthy if we take into consideration the fact that such interdiffusions occur even during the sintering process of cell preparation. - Graphical Abstract: Two types of diffusions, the mutual diffusion and the diffusion along grain boundaries, occurred at the cathode/electrolyte interface of intermediate temperature solid state fuel cells, during cell preparation. The mutual diffusion is denoted by black arrows and the diffusion along grain boundaries assigned by pink arrows. Highlights: > All the cations in cathode (LSCF) and electrolyte (GDC) can mutually diffuse into each other. > Diffusing elements will segregate at grain boundaries or triple junctions around the cathode/electrolyte interface. > Two types of diffusions, the mutual diffusion and diffusion along grain boundaries, have been clarified thereafter.

Li Zhipeng, E-mail: LI.Zhipeng@nims.go.jp [Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Mori, Toshiyuki [Global Research Center for Environment and Energy based on Nanomaterials Science, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Auchterlonie, Graeme John [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Zou Jin [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Division of Materials, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia); Drennan, John [Centre for Microscopy and Microanalysis, University of Queensland, St. Lucia, Brisbane, Queensland 4072 (Australia)

2011-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
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321

An intermediate-temperature solid oxide fuel cell with electrospun nanofiber cathode  

SciTech Connect (OSTI)

Lanthanum strontium cobalt ferrite (LSCF) nanofibers have been fabricated by the electrospinning method and used as the cathode of an intermediate-temperature solid oxide fuel cell (SOFC) with yttria-stabilized zirconia (YSZ) electrolyte. The three-dimensional nanofiber network cathode has several advantages: (i) high porosity; (ii) high percolation; (iii) continuous pathway for charge transport; (iv) good thermal stability at the operating temperature; and (v) excellent scaffold for infiltration. The fuel cell with the monolithic LSCF nanofiber cathode exhibits a power density of 0.90 W cm{sup ?2} at 1.9 A cm{sup ?2} at 750 °C. The electrochemical performance of the fuel cell has been further improved by infiltration of 20 wt% of gadolinia-doped ceria (GDC) into the LSCF nanofiber cathode. The fuel cell with the LSCF–20% GDC composite cathode shows a power density of 1.07 W cm{sup ?2} at 1.9 A cm{sup ?2} at 750 °C. The results obtained show that one-dimensional nanostructures such as nanofibers hold great promise as electrode materials for intermediate-temperature SOFCs.

Zhi, Mingjia; Lee, Shiwoo; Miller, Nicholas; Menzler, Norbert H.; Wu, Nianqiang

2012-05-01T23:59:59.000Z

322

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wonchang

2010-05-18T23:59:59.000Z

323

Cathodic protection system design for steel pilings of a wharf structure  

SciTech Connect (OSTI)

Corrosion of steel pilings in sea and brackish water is mostly due to the establishment of localized corrosion cells and the effects of the tidal changes. The most frequently used corrosion protection systems are coatings and/or cathodic protection. These protective systems when properly designed, installed and operated are very effective in preventing corrosion problems. The design of a cathodic protection system, in order to be effective and reliable, must take into consideration all technical design criteria, the type of materials used, the geometric shape of the structure, environmental conditions, site restrictions, and any outside interferences. These design considerations, as well as the use of design data and an overall design methodology for a cathodic protection system for pipe and sheet piling used in a wharf structure, are discussed in this paper.

Nikolakakos, S.

1999-07-01T23:59:59.000Z

324

Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process  

SciTech Connect (OSTI)

Pristine and cycled layered structure cathode of Li[Li0.2Ni0.2M0.6]O2 samples are characterized by aberration-corrected scanning transmission electron microscopy and electron energy loss spectroscopy. These analyses provide new insights on capacity/voltage fading mechanism of Li[Li0.2Ni0.2M0.6]O2. Sponge-like structure and fragment pieces were found on the surface of cathode after cycling. Mn2+ species and reduced Li content in the fragments caused significant capacity loss. These results also reveal the functional mechanism of surface coatings, e.g. AlF3, which can protect the electrode from etching by acidic species in the electrolyte, suppress cathode degradation and improve long-term cycling stability.

Zheng, Jianming; Gu, Meng; Xiao, Jie; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang

2013-06-26T23:59:59.000Z

325

Development of a Compact Ion Source with a Hot Hollow Cathode  

SciTech Connect (OSTI)

A compact ion source with 14 mm diameter, 30 mm long discharge region was developed. A total size of the ion source including the beam extraction system was 60 mm in diameter and 160 mm in length. A high temperature coaxial cathode consisting of thin-wall tantalum and tungsten tubes produced a discharge plasma. A source gas was supplied through the inner W tube of the coaxial cathode. A stable plasma of H{sub 2} was maintained with the discharge current of 2.0 A at 68 A cathode heating current. The optimum H{sub 2} gas pressure for ion beam extraction was 2x10{sup -2} Pa. Hydrogen ion beam current was 120 {mu}A (1 mA/cm{sup 2}) at 2.0 A discharge current and 3.0 kV extraction voltage.

Miyamoto, N. [Nissin Ion Equipment Co. LTD., 575 Kuzetonoshiro-Cho Minamiku Kyoto 601-8205 (Japan); Demura, Y.; Imakita, S.; Kasuya, T.; Vasquez, M. R. Jr.; Wada, M. [Graduated School of Engineering Doshisha University, Tatar a-Miyakodani Kyotanabe Kyoto 610-0394 (Japan)

2011-01-07T23:59:59.000Z

326

Amp\\`ere-Class Pulsed Field Emission from Carbon-Nanotube Cathodes in a Radiofrequency Resonator  

E-Print Network [OSTI]

Pulsed field emission from cold carbon-nanotube cathodes placed in a radiofrequency resonant cavity was observed. The cathodes were located on the backplate of a conventional $1+\\frac{1}{2}$-cell resonant cavity operating at 1.3-GHz and resulted in the production of bunch train with maximum average current close to 0.7 Amp\\`ere. The measured Fowler-Nordheim characteristic, transverse emittance, and pulse duration are presented and, when possible, compared to numerical simulations. The implications of our results to high-average-current electron sources are briefly discussed.

Mihalcea, D; Hartzell, J; Panuganti, H; Boucher, S M; Murokh, A; Piot, P; Thangaraj, J C T

2015-01-01T23:59:59.000Z

327

The pipe coating as an engineered part of the cathodic protection system  

SciTech Connect (OSTI)

The basic corrosion process is reviewed and the factors influencing the thermodynamic driving forces are discussed. The roles played by both the coating and the cathodic protection system are discussed, and the relationship between the two systems relating to corrosion under a coating film is shown. The importance of treating the coating as part of the cathodic protection system is explained. The need to be aware of the engineering variables of the pipe coating, not only as applied, but also as a function of time, is presented.

Mills, G.

1988-12-01T23:59:59.000Z

328

Composite Cathode for High-Power Density Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

Reduction of solid oxide fuel cell (SOFC) operating temperature will play a key role in reducing the stack cost by allowing the use of low-cost metallic interconnects and new approaches to sealing, while making applications such as transportation more feasible. Reported results for anode-supported SOFCs show that cathode polarization resistance is the primary barrier to achieving high power densities at operating temperatures of 700 C and lower. This project aims to identify and develop composite cathodes that could reduce SOFC operating temperatures below 700 C. This effort focuses on study and use of (La,Sr)(Co,Fe)O{sub 3} (LSCF) based composite cathodes, which have arguably the best potential to substantially improve on the currently-used, (La,Sr)MnO{sub 3}-Yttria-stabilized Zirconia. During this Phase I, it was successfully demonstrated that high performances can be achieved with LSCF/Gadolinium-Doped Ceria composite cathodes on Ni-based anode supported cells operating at 700 C or lower. We studied electrochemical reactions at LSCF/Yttria-stabilized Zirconia (YSZ) interfaces, and observed chemical reactions between LSCF and YSZ. By using ceria electrolytes or YSZ electrolytes with ceria diffusion barrier layers, the chemical reactions between LSCF and electrolytes were prevented under cathode firing conditions necessary for the optimal adhesion of the cathodes. The protection provided by ceria layer is expected to be adequate for stable long-term cathode performances, but more testing is needed to verify this. Using ceria-based barrier layers, high performance Ni-YSZ anode supported cells have been demonstrated with maximum power densities of 0.8W/cm2 at 700 C and 1.6W/cm{sup 2} at 800 C. Ni-SDC anode supported cells with SDC electrolytes yielded >1W/cm{sup 2} at 600 C. We speculate that the power output of Ni-YSZ anode supported cell at 700 C and lower, was limited by the quality of the Ceria and Ceria YSZ interface. Improvements in the low-temperature performances are expected based on further development of barrier layer fabrication processes and optimization of cathode microstructure.

Ilwon Kim; Scott Barnett; Yi Jiang; Manoj Pillai; Nikkia McDonald; Dan Gostovic; Zhongryang Zhan; Jiang Liu

2004-01-31T23:59:59.000Z

329

Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts  

DOE Patents [OSTI]

Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

2014-08-12T23:59:59.000Z

330

ACTIVE CATHODES FOR SUPER-HIGH POWER DENSITY SOLID OXIDE FUEL CELLS THROUGH SPACE CHARGE EFFECTS  

SciTech Connect (OSTI)

This report summarizes the work done during the sixth quarter of the project. Effort was directed in three areas: (1) Further development of the model on the role of connectivity on ionic conductivity of porous bodies, including the role of grain boundaries and space charge region. (2) Calculation of the effect of space charge and morphology of porous bodies on the effective charge transfer resistance of porous composite cathodes. (3) The investigation of the three electrode system for the measurement of cathodic polarization using amperometric sensors.

Anil V. Virkar

2004-05-17T23:59:59.000Z

331

Quantum efficiency temporal response and lifetime of a GaAs cathode in SRF electron gun  

SciTech Connect (OSTI)

RF electron guns with a strained super lattice GaAs cathode can generate polarized electron beam of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface. In a normal conducting RF gun, the extremely high vaccum required by these cathodes can not be met. We report on an experiment with a superconducting SRF gun, which can maintain a vacuum of nearly 10-12 torr because of cryo-pumping at the temperature of 4.2K. With conventional activation, we obtained a QE of 3% at 532 nm, with lifetime of nearly 3 days in the preparation chamber. We plan to use this cathode in a 1.3 GHz 1/2 cell SRF gun to study its performance. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper. Future particle accelerators such as eRHIC and ILC require high brightness, high current polarized electrons Recently, using a superlattice crystal, the maximum polarization of 95% was reached. Activation with Cs,O lowers the electron affinity and makes it energetically possible for all the electrons excited in to the conduction band and reach the surface to escape into the vacuum. Presently the polarized electron sources are based on DC gun, such as that at the CEBAF at Jlab. In these devices, the life time of the cathode is extended due to the reduced back bombardment in their UHV conditions. However, the low accelerating gradient of the DC guns lead to poor longitudinal emittance. The higher accelerating gradient of the RF gun generates low emittance beams. Superconducting RF guns combine the excellent vacuum conditions of the DC guns with the higher accelerating gradients of the RF guns and provide potentially a long lived cathode with very low transverse and longitudinal emittance. In our work at BNL, we successfully activated the GaAs. The quantum efficient is 3% at 532 nm and is expected to improve further. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper.

Wang, E.; Ben-Zvi, I.; Kewisch, J.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

2010-05-23T23:59:59.000Z

332

Condensation in the Cathode of a PEM Fuel Cell M. J. Kermani J. M. Stockie A. G. Gerber  

E-Print Network [OSTI]

Condensation in the Cathode of a PEM Fuel Cell M. J. Kermani J. M. Stockie A. G. Gerber University@unb.ca. ABSTRACT Three species condensing flow in the cathode of a Proton Exchange Membrane (PEM) fuel cell of an ongoing effort to carefully model individual elements of the PEM fuel cell, with a par- ticular focus

Stockie, John

333

Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz  

E-Print Network [OSTI]

Nanorod PEM Fuel Cell Cathodes with Controlled Porosity M. D. Gasda, G. A. Eisman,* and D. Gallz as cathode electrodes in proton exchange membrane PEM fuel cells. Deposition on flat substrates yields February 4, 2010. Proton exchange membrane PEM fuel cells are promising for future automotive applications

Gall, Daniel

334

Use of Pyrolyzed Iron Ethylenediaminetetraacetic Acid Modified Activated Carbon as Air-Cathode Catalyst in Microbial Fuel Cells  

E-Print Network [OSTI]

. Logan*,, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, P. R. China Department of Civil and Environmental better than Pt-catalyzed cathodes. After 4.5 months of operation, the maximum power density of Pt cathode

335

Parameter Estimates for a PEMFC Cathode Qingzhi Guo,* Vijay A. Sethuraman,* and Ralph E. White**,z  

E-Print Network [OSTI]

PEMFC cathode the volume fraction of gas pores in the gas diffusion layer, the volume fraction of gas in this work indicate that ionic conduction and gas-phase transport are two processes significantly influencing submitted air cathode model8 that includes gas pores in the CAL to estimate the values of the volume

Sethuraman, Vijay A.

336

Single-layer graphene cathodes for organic photovoltaics Marshall Cox, Alon Gorodetsky, Bumjung Kim, Keun Soo Kim, Zhang Jia et al.  

E-Print Network [OSTI]

Single-layer graphene cathodes for organic photovoltaics Marshall Cox, Alon Gorodetsky, Bumjung Kim-layer graphene cathodes for organic photovoltaics Marshall Cox,1,a Alon Gorodetsky,2 Bumjung Kim,2 Keun Soo Kim,3-layer graphene is demonstrated as a cathode for organic photovoltaic devices. The measured properties indicate

Hone, James

337

Effect of nitrate on the performance of single chamber air cathode microbial fuel cells  

E-Print Network [OSTI]

Effect of nitrate on the performance of single chamber air cathode microbial fuel cells Chontisa Accepted 26 August 2008 Published online 11 September 2008 Keywords: Microbial fuel cell Denitrification microbial fuel cells (MFCs) has drawn much attention recently as a new approach of waste- water treatment

Tullos, Desiree

338

Supporting Information Power generation by packed-bed air-cathode microbial fuel cells  

E-Print Network [OSTI]

1 Supporting Information Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan b a State Key Joint Laboratory of Environment Simulation and Pollution Control, THU­ VEOLIA Informatics, China University of Mining and Technology, Xuzhou 221116, PR China * Corresponding author: E

339

A flat-cathode thermionic injector for the PHERMEX Radiographic Facility  

SciTech Connect (OSTI)

The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S. (Los Alamos National Lab., NM (United States)); Hughes, T. (Mission Research Corp., Albuquerque, NM (United States))

1993-01-01T23:59:59.000Z

340

A flat-cathode thermionic injector for the PHERMEX Radiographic Facility  

SciTech Connect (OSTI)

The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S. [Los Alamos National Lab., NM (United States); Hughes, T. [Mission Research Corp., Albuquerque, NM (United States)

1993-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Facile synthesis of Li2Spolypyrrole composite structures for high-performance Li2S cathodes  

E-Print Network [OSTI]

Facile synthesis of Li2S­polypyrrole composite structures for high-performance Li2S cathodes Zhi demon- strate facile, in situ synthesis of Li2S­polypyrrole composites for use as high-performance Li2S polysulfides during cycling. Poly- pyrrole, being a conducting polymer, also helps to facilitate elec- tronic

Cui, Yi

342

Microstructural Characterization Using Orientational Imaging Microscopy of SOFC Cathodes Subjected to Thermal and Electrochemical Loads  

SciTech Connect (OSTI)

Cathodes in SOFCs consist of interconnecting and contacting two-phase interfaces and three-phase lines in a complex three-phase microstructure. Furthermore, the interfacial crystallography is dynamic and changes in response to thermal loads and to interfacial electrochemical polarizations. Owing to this inherent complexity, a complete and fundamental understanding of both the basic mechanisms of cathodic processes and their performance degradation has not been achieved. We have carried out quantitative orientational imaging microscopy (OIM) on button-cell geometry SOFCs containing porous cathodes of yttria-stabilized zirconia and lanthanum strontium manganese oxide. A series of cathodes, taken from cells subjected to both open-circuit and current-loaded fuel-cell conditions, were characterized with OIM to determine their microstructural and crystallographic properties as a function of thermal and electrochemical history. In this presentation we will discuss the results of these studies, focusing on the crystallographic nature of the statistically important two-phase interfaces and three-phase lines.

Cao, Y. (Carnegie Mellon University); Miller, H.M. (Carnegie Mellon University); Johnson, C.; Wilson, L.C.; Rohrer, G. (Carnegie Mellon University); Salvador, P. (Carnegie Mellon University)

2006-10-01T23:59:59.000Z

343

innovati nNREL Enhances the Performance of a Lithium-Ion Battery Cathode  

E-Print Network [OSTI]

potential environmental and safety issues. The search for a replacement cathode material has led to lithium, the chemical reaction of the anode with the electrolyte causes electrons to enter the wire, moving throughFePO4 is due to the particular geometry of its electronic struc- ture--in technical terms, it has

344

Beam characterization of a lab bench cold cathode ultra-soft x-ray generator  

E-Print Network [OSTI]

-source. Keywords: Ultra-soft X-rays (USX), USX Cold cathode generator, Gafchromic dosimetry, Aluminium K line. 1 and cell transformation) [1]. USX, however,5 pose significant problems in dosimetry and experimental design References hal-00858423,version1-5Sep2013 Author manuscript, published in "Nuclear Instruments and Methods

Paris-Sud XI, Université de

345

Spectroscopic diagnostics of the plasma in the cathode region of a nitrogen glow discharge  

E-Print Network [OSTI]

323 Spectroscopic diagnostics of the plasma in the cathode region of a nitrogen glow discharge A of the characteristic quantities of the plasma, the diagnostics must be made in situ by non-intrusive methods that offer. Margulis and J. Jolly Laboratoire de Physique des Gaz et des Plasmas, Bâtiment 212, Université de Paris

Paris-Sud XI, Université de

346

The use and optimization of stainless steel mesh cathodes in microbial electrolysis cells  

E-Print Network [OSTI]

electrolysis cells (MECs) provide a high-yield method for producing hydrogen from renewable biomass. One cost MEC systems for hydrogen production. ÂŞ 2010 Professor T. Nejat Veziroglu. Published by Elsevier for water electrolysis) [1,2], hydrogen can be evolved on the cathode under anoxic conditions, usually

347

Ion velocities in direct current arc plasma generated from compound cathodes  

SciTech Connect (OSTI)

Arc plasma from Ti-C, Ti-Al, and Ti-Si cathodes was characterized with respect to charge-state-resolved ion energy. The evaluated peak velocities of different ion species in plasma generated from a compound cathode were found to be equal and independent on ion mass. Therefore, measured difference in kinetic energies can be inferred from the difference in ion mass, with no dependence on ion charge state. The latter is consistent with previous work. These findings can be explained by plasma quasineutrality, ion acceleration by pressure gradients, and electron-ion coupling. Increasing the C concentration in Ti-C cathodes resulted in increasing average and peak ion energies for all ion species. This effect can be explained by the “cohesive energy rule,” where material and phases of higher cohesive energy generally result in increasing energies (velocities). This is also consistent with the here obtained peak velocities around 1.37, 1.42, and 1.55 (10{sup 4} m/s) for ions from Ti{sub 0.84}Al{sub 0.16}, Ti{sub 0.90}Si{sub 0.10}, and Ti{sub 0.90}C{sub 0.10} cathodes, respectively.

Zhirkov, I.; Rosen, J. [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden)] [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden); Eriksson, A. O. [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden) [Thin Film Physics Division, Department of Physics, Chemistry and Biology (IFM), Linköping University, SE-581 83 Linköping (Sweden); Oerlikon Balzers Coating AG, Iramali 18, 9496 Balzers (Liechtenstein)

2013-12-07T23:59:59.000Z

348

Novel anti-flooding poly(dimethylsiloxane) (PDMS) catalyst binder for microbial fuel cell cathodes  

E-Print Network [OSTI]

Novel anti-flooding poly(dimethylsiloxane) (PDMS) catalyst binder for microbial fuel cell cathodes) was tested as a catalyst binder in a microbial fuel cell. 2012 Keywords: Microbial fuel cell Poly(dimethylsiloxane) Anti-flooding Catalyst binder a b s t r a c

349

Design and performance of a 30 KV electron gun with ten independent cathodes & a magnetic lens.  

SciTech Connect (OSTI)

Measurements on a 30 kV electron gun with ten independent cathodes, operating in a 6.5 Tesla (T) magnetic field are presented. An earlier paper covered the design of this electron gun [1]. Experimental results are compared to model predictions. Beam current is compared to theoretical space charge limited flow.

Rudys, Joseph Matthew; Reed, Kim Warren

2006-08-01T23:59:59.000Z

350

Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes  

DOE Patents [OSTI]

Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

2014-01-28T23:59:59.000Z

351

An interchangeable-cathode vacuum arc plasma source David K. Olson,a  

E-Print Network [OSTI]

design based on metal vapor vacuum arc MeVVA concepts is employed as a plasma source for a study of a 7 using a boron-carbide disk as the cathode target. The design is simplified from typical designs with a proton beam. We create our 7 Be on the surface of a sample of enriched boron carbide. Because 7

Hart, Gus

352

Mitigating Voltage Fade in Cathode Materials by Improving the Atomic Level Uniformity of Elemental Distribution  

SciTech Connect (OSTI)

Li-rich and Mn-rich (LMR) layered structured materials are very promising cathodes for high-energy lithium-ion batteries. However, their fundamental structure and voltage fading mechanisms are far from being well understood. Here we report the first evidence on the reduced voltage and energy fade of LMR cathode by improving the atomic level spatial distribution of the chemical species. LMR cathode (Li[Li0.2Ni0.2M0.6]O2) prepared by co-precipitation and sol-gel methods are dominated by R-3m phase and show significant Ni-segregation at the surface of the particles. They exhibit large voltage-fade and fast capacity degradation. In contrast, LMR cathode prepared by hydrothermal assisted method is dominated by C2/m phase and minimal Ni-segregation. It also demonstrates much smaller voltage-fade and excellent capacity retention. The fundamental correlation between the atomic level spatial distribution of the chemical species and the functional stability of the materials found in this work also guide the design of other functional materials with enhanced stabilities.

Zheng, Jianming; Gu, Meng; Genc, Arda; Xiao, Jie; Xu, Pinghong; Chen, Xilin; Zhu, Zihua; Zhao, Wenbo; Pullan, Lee; Wang, Chong M.; Zhang, Jiguang

2014-04-07T23:59:59.000Z

353

Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells  

E-Print Network [OSTI]

Computational Modeling of Electrolyte/Cathode Interfaces in Proton Exchange Membrane Fuel Cells Dr Proton exchange membrane fuel cells (PEMFCs) are alternative energy conversion devices that efficiently. The fundamental relationship between operating conditions and device performance will help to optimize the device

Bjørnstad, Ottar Nordal

354

Comparison of Nonprecious Metal Cathode Materials for Methane Production by Electromethanogenesis  

E-Print Network [OSTI]

a methanogenic biofilm on the cathode by either direct electron transfer or evolved hydrogen. To optimize methane, Microbial electrolysis cell, Power-to-gas, Microbially influenced corrosion, Carbon black, Graphite, hydro- gen gas production by water electrolysis often requires expensive precious metals to reduce

355

Growth and characterization of rare-earth monosulfides for cold cathode applications  

E-Print Network [OSTI]

of chalco- genides of the rare-earth elements.4,5 The possibility was analyzed theoretically basedGrowth and characterization of rare-earth monosulfides for cold cathode applications Y. Modukuru, J phonons at 261 284 and 100 92 cm 1 with LaS NdS , respectively. These rare-earth monosulfides offer

Boolchand, Punit

356

SUPPLEMENTAL INFORMATION The Use and Optimization of Stainless Steel Mesh Cathodes in  

E-Print Network [OSTI]

of Hydrogen Energy (IJHE) #12;Mesh Surface Area Calculation Figure S1: SS 304 woven mesh configuration, where (or cm2 / cm2 ) Specific area per 7 cm2 cathode: 2 cm45.107 =Ă?S Specific area per reactor volume: 3232

357

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified Computationally  

E-Print Network [OSTI]

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified ABSTRACT: The tremendous growth of Li-ion batteries into a wide variety of applications is setting new applications from portable electronics to electric vehicles. A critical element of a Li-ion battery is the Li

Ceder, Gerbrand

358

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network [OSTI]

. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediateOxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights oxide fuel cells are of technological interest as they offer high efficiency for energy conversion

Yildiz, Bilge

359

Gold and gold-graphene used as cathodic interfaces for scission of carbon-halogen bonds.  

E-Print Network [OSTI]

. Application to the building of anthraquinone-Au electrodes. Jacques Simonet a * and Viatcheslav Jouikov b a as cathode material. This first work points out the immobilization of anthraquinone (AQ) in organic polar.12.024 #12;2 Graphical Abstract Key Words: Graphene; 2-Bromomethylanthraquinone; Anthraquinone electrodes

Paris-Sud XI, Université de

360

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform  

E-Print Network [OSTI]

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R of hydrogen H2 and oxygen O2 . Operating fuel cells in alkaline media, as opposed to acidic media, has on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing

Kenis, Paul J. A.

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Field emission from strained carbon nanotubes on cathode substrate D. Roy Mahapatra a,  

E-Print Network [OSTI]

Field emission from strained carbon nanotubes on cathode substrate D. Roy Mahapatra a, *, N. Sinha, Waterloo, Ont. N2L3C5, Canada 1. Introduction Field emission from carbon nanotube (CNT) was first reported Available online 27 June 2008 Keywords: Field emission Current density Carbon nanotube Strain phonon A B

Melnik, Roderick

362

Report on sodium compatibility of advanced structural materials.  

SciTech Connect (OSTI)

This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

2012-07-09T23:59:59.000Z

363

HIGH-CURRENT COLD CATHODE FIELD EMISSION ARRAY FOR ELECTRON LENS APPLICATION  

SciTech Connect (OSTI)

During Phase I, the following goals were achieved: (1) design and fabrication of a novel, nano-dimensional CNT field emitter assembly for high current density application, with high durability; (2) fabrication of a ceramic based micro channel plate (MCP) and characterization of its secondary electron emission; and (3) characterizing the CNT/MCP cathode for high field emission and durability. As a result of these achievements, a relatively high current density of ~ 1.2 A/cm2 from a CNT cathode and single channel MCP were measured. The emission current was also extremely stable with a peak-to-peak variation of only 1.8%. The emission current could be further enhanced to meet requirements for electron lens applications by increasing the number of MCP channels. A calculation for maximum possible current density with a 1200 channel/cm2 MCP, placed over a cathode with 1200 uniformly functioning CNTs, would be ~1.46 kA/cm2, neglecting space charge limitations. Clearly this level of emission is far greater than what is needed for the electron lens application, but it does offer a highly comforting margin to account for sub-standard emitters and/or to allow the lesser challenge of building a cathode with fewer channels/cm2. A satisfactory goal for the electron lens application would be a controllable emission of 2-4 mA per channel in an ensemble of 800-1200 uniformly-functioning channels/cm2, and a cathode with overall area of about 1 cm2.

Hirshfield, Jay L

2012-12-28T23:59:59.000Z

364

Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems  

Broader source: Energy.gov [DOE]

Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

365

Advanced Critical Advanced Energy Retrofit Education and Training...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Critical Advanced Energy Retrofit Education and Training and Credentialing - 2014 BTO Peer Review Advanced Critical Advanced Energy Retrofit Education and Training and...

366

Advanced Recyclable Media System{reg_sign}. Innovative technology summary report  

SciTech Connect (OSTI)

The objective of the Large-Scale Demonstration Project (LSDP) is to select and demonstrate potentially beneficial technologies at the Argonne National Laboratory East`s (ANL) Chicago Pile-5 (CP-5) Research Reactor. The purpose of the LSDP is to demonstrate that using innovative and improved deactivation and decommissioning (D and D) technologies from various sources can result in significant benefits, such as decreased cost and increased health and safety, as compared with baseline D and D technologies. This report describes a demonstration of the Advanced Recyclable Media System{reg_sign} technology which was employed by Surface Technology Systems, Inc. to remove coatings from a concrete floor. This demonstration is part of the CP-5 LSDP sponsored by the US Department of Energy (DOE) Office of Science and Technology Deactivation and Decommissioning Focus Area (DDFA). The Advanced Recyclable Media System{reg_sign} (ARMS) technology is an open blast technology which uses a soft recyclable media. The patented ARMS Engineered Blast Media consists of a fiber-reinforced polymer matrix which can be manufactured in various grades of abrasiveness. The fiber media can be remade and/or reused up to 20 times and can clean almost any surface (e.g., metal, wood, concrete, lead) and geometry including corners and the inside of air ducts.

NONE

1998-12-01T23:59:59.000Z

367

Observation of radio frequency ring-shaped hollow cathode discharge plasma with MgO and Al electrodes for plasma processing  

SciTech Connect (OSTI)

Various high-density plasma sources have been proposed for plasma processing. Especially, the hollow cathode discharge is one of the powerful ones. In this work, radio-frequency (RF) driven ring-shaped hollow cathode discharges with high secondary-electron emission have been investigated, using an aluminum (Al) cathode, coated or not with magnesium oxide (MgO). The thickness of MgO thin film is approximately 200?nm. The RF discharge voltage for the coated cathode is almost the same as that for the uncoated one, in a wide range of Ar gas pressure, from 5.3 to 53.2?Pa. The results reveal that the plasma density has a peak at an Ar gas pressure of 10.6?Pa for both cathodes. The plasma density for the coated cathode is about 1.5–3 times higher than that for the uncoated one, at various gas pressures. To the contrary, the electron temperature for the coated cathode is lower than temperature obtained with the uncoated cathode, at various gas pressures. Radial profiles of electron saturation current, which is proportional to plasma flux, are also examined for a wide range of gas pressure. Radial profiles of electron temperature at various axial positions are almost uniform for both cathodes so that the diffusion process due to density gradient is dominant for plasma transport. The secondary electrons emitted from the coated cathode contribute to the improvement of the plasma flux radial profile obtained using the uncoated cathode.

Ohtsu, Yasunori, E-mail: ohtsuy@cc.saga-u.ac.jp; Matsumoto, Naoki [Department of Electrical and Electronic Engineering, Graduate School of Science and Engineering, Saga University, 1 Honjo-machi, Saga 840-8502 (Japan)

2014-05-15T23:59:59.000Z

368

Italian Academy Advanced Studies  

E-Print Network [OSTI]

The Italian Academy for Advanced Studies in America at Columbia University Annual Report 2006­2007 The Italian Academy for Advanced Studies in America at Columbia University Annual Report 2006­2007 #12;italian academy for advanced studies in america 1161 Amsterdam Avenue New York, NY 10027 tel: (212) 854-2306 fax

Qian, Ning

369

Advanced Search Search Tips  

E-Print Network [OSTI]

Advanced Search Search Tips Advanced Search Search Tips springerlink.com SpringerLink 2,000 40,000 20,000 2010 11 Please visit 7 http://www.springerlink.com GO 1997 1997 SpringerLink Advanced Search Search Tips CONTENT DOI CITATION DOI ISSN ISBN CATEGORY AND DATE LIMITERS Journals Books Protocols

Kinosita Jr., Kazuhiko

370

Design and Implementation of a Liquid Nitrogen-Cooled Hollow Cathode Discharge Source for the Study of the Reaction H+  

E-Print Network [OSTI]

Design and Implementation of a Liquid Nitrogen-Cooled Hollow Cathode Discharge Source for the Study in the first place and providing me with this incredible opportunity! You guys rock! 2 #12;Introduction Work

McCall, Benjamin J.

371

Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing  

E-Print Network [OSTI]

Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

Mueller, Tim

372

Designing materials for energy storage with high power and energy density : LiFePO? cathode material  

E-Print Network [OSTI]

LiFePO? has drawn a lot of attention as a cathode material in lithium rechargeable batteries because its structural and thermal stability, its inexpensive cost, and environmental friendliness meet the requirements of power ...

Kang, Byoungwoo

2010-01-01T23:59:59.000Z

373

New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron microscopy, electrochemical and X-ray absorption studies  

E-Print Network [OSTI]

1 New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron: manganese oxide, lithium batteries, nanomaterials Corresponding author: Pierre Strobel, tel. 33 476 887 940 with lithium iodide in aqueous medium at room temperature. Transmission electron microscopy (TEM) showed

Paris-Sud XI, Université de

374

Optimization of the Cathode Catalyst Layer Composition of a PEM Fuel Cell Using a Novel 2-Step Preparation Method  

E-Print Network [OSTI]

For good performance and high durability PEM fuel cells run at high water saturation levels. However, excess liquid water generated by the oxygen reduction reaction at the cathode can block pores in the catalyst layer so ...

Friedmann, Roland

2009-03-05T23:59:59.000Z

375

High-Rate Cathodes Based on Li3V2(PO4)3 Nanobelts Prepared via...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cathodes Based on Li3V2(PO4)3 Nanobelts Prepared via Surfactant-Assisted Fabrication. Abstract: In this work, we synthesized monoclinic Li3V2(PO4)3 nanobelts via a single-step,...

376

Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes  

E-Print Network [OSTI]

Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated “Pt[subscript 3]Co ” catalyst particles in a H[subscript ...

Chen, Shuo

377

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

378

A review comparing cathodic arcs and high power impulse magnetron sputtering (HiPIMS)  

SciTech Connect (OSTI)

High power impulse magnetron sputtering (HiPIMS) has been in the center of attention over the last years as it is an emerging physical vapor deposition (PVD) technology that combines advantages of magnetron sputtering with various forms of energetic deposition of films such as ion plating and cathodic arc plasma deposition. It should not come at a surprise that many extension and variations of HiPIMS make use, intentionally or unintentionally, of previously discovered approaches to film processing such as substrate surface preparation by metal ion sputtering and phased biasing for film texture and stress control. Therefore, in this review, an overview is given on some historical developments and features of cathodic arc and HiPIMS plasmas, showing commonalities and differences. To limit the scope, emphasis is put on plasma properties, as opposed to surveying the vast literature on specific film materials and their properties.

Anders, Andre

2014-08-17T23:59:59.000Z

379

A model for the self-pulsing regime of microhollow cathode discharges  

SciTech Connect (OSTI)

Microhollow cathode discharges may operate in different regimes depending of the discharge current. They are subject to relaxation oscillations in the so-called self-pulsing regime in which the discharge oscillates between two quasiequilibria: at low current it remains confined in the microhole whereas it expands on the cathode backside during short high-current pulses. A model based on a nonlinear discharge resistance is proposed to describe the phenomenon. The analysis of the dynamics reveals that the current pulse rises in an extremely short time while the characteristic (longer) decay time is imposed by the resistance when the discharge is expanded outside the hole. It is shown how the nonlinear discharge resistance may be inferred from the experimental current-voltage signals.

Chabert, P.; Lazzaroni, C.; Rousseau, A. [LPP, Ecole Polytechnique, UPMC, CNRS, Paris XI, 91128 Palaiseau (France)

2010-12-01T23:59:59.000Z

380

The effect of cathodic protection on duplex stainless steels in sea water  

SciTech Connect (OSTI)

The report reviews the available data on the embrittlement of duplex stainless steels under cathodic protection in sea water. Much of this data has previously been unpublished. The results show that while hydrogen enters duplex alloys at typical protection potentials ({minus}1V SCE) the risk of failure is very low. The austenite phase tends to block cracks in the ferrite, and very high stresses are needed to produce fracture of the austenite or austenite-ferrite phase boundaries to enable crack propagation to occur. The smaller the grain size the more resistant duplex stainless steel is to embrittlement. The report also shows that currently used design stresses for duplex alloys are well below the stresses needed to produce failure. The service experiences with cathodically protected duplex are reviewed and the few failures explained. The report concludes that at normal protection potentials the risk of failure of duplex stainless steel due to hydrogen embrittlement is extremely low.

Francis, R.; Byrne, G.; Warburton, G.R. [Weir Materials Ltd., Manchester (United Kingdom)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Final Technical Report- Back-gate Field Emission-based Cathode RF Electron Gun  

SciTech Connect (OSTI)

The objective was to complete the design of an electron gun which utilizes a radio frequency (RF) power source to apply a voltage to a field emission (FE) cathode, a so called cold cathode, in order to produce an electron beam. The concept of the RF electron gun was originally conceived at Argonne National Laboratory but never reduced to practice. The research allowed the completion of the design based upon the integration of the FE electron source. Compared to other electron guns, the RF gun is very compact, less than one third the size of other comparable guns, and produces a high energy (to several MeV), high quality, high power electron beam with a long focal length with high repetition rates. The resultant electron gun may be used in welding, materials processing, analytical equipment and waste treatment.

McGuire, Gary; Martin, Allen; Noonan, John

2010-10-30T23:59:59.000Z

382

The evolution of ion charge states in cathodic vacuum arc plasmas: a review  

SciTech Connect (OSTI)

Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after “Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources” appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the “noise” in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

Anders, Andre

2011-12-18T23:59:59.000Z

383

A review comparing cathodic arcs and high power impulse magnetron sputtering (HiPIMS)  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

High power impulse magnetron sputtering (HiPIMS) has been in the center of attention over the last years as it is an emerging physical vapor deposition (PVD) technology that combines advantages of magnetron sputtering with various forms of energetic deposition of films such as ion plating and cathodic arc plasma deposition. It should not come at a surprise that many extension and variations of HiPIMS make use, intentionally or unintentionally, of previously discovered approaches to film processing such as substrate surface preparation by metal ion sputtering and phased biasing for film texture and stress control. Therefore, in this review, an overview is given on some historical developments and features of cathodic arc and HiPIMS plasmas, showing commonalities and differences. To limit the scope, emphasis is put on plasma properties, as opposed to surveying the vast literature on specific film materials and their properties.

Anders, Andre

2014-10-01T23:59:59.000Z

384

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

SciTech Connect (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

385

Nanostructured ceria based thin films ({<=}1 {mu}m) As cathode/electrolyte interfaces  

SciTech Connect (OSTI)

Gadolinium doped cerium oxide (CGO: Ce{sub 0,9}Gd{sub 0,1}O{sub 2-{delta}}) films were used as an oxygen anion diffusion layer at the cathode/electrolyte interface of Solid Oxide Fuel Cells (SOFCs), between LSCF (lanthanum strontium cobalt ferrite) and YSZ (yttria-stabilized zirconia). Thin ({approx}100 nm) and thick ({approx}700 nm) mesoporous CGO layers were synthesized through a sol-gel process including organic template coupled with the dip-coating method. Structural and microstructural characterizations were performed, highlighting a well-bonded crystalline CGO nanoparticles network which delineates a 3-D inter-connected mesoporous network. Their electrical behaviors were investigated by impedance spectroscopy analysis of YSZ/mesoporous-CGO/LSCF half-cell. Anode-supported SOFCs, operating at 800 Degree-Sign C, with either dense or mesoporous CGO dip-coated interlayers were also fabricated [NiO-YSZ anode/YSZ/CGO/LSCF cathode]. The impact of the mesoporous CGO interlayers on SOFCs performances was investigated by galvanostatic analysis and compared to the behavior of a dense CGO interlayer. The polarization curves revealed an enhancement in the electrical performance of the cell, which is assigned to a decrease of the polarization resistance at the cathode/electrolyte interface. The integrity and connectivity of the CGO nanoparticles bonded network facilitates O{sup 2-} transport across the interface. - Graphical abstract: Thin and thick CGO films have been prepared through a sol-gel process and their potential application as SOFC cathode/electrolyte interlayer in SOFC has been investigated. Highlights: Black-Right-Pointing-Pointer Mesoporous ceria based thin films exhibit interesting performances for Solid Oxide Fuel Cell. Black-Right-Pointing-Pointer Mesoporous films were synthesized through the sol-gel process combined with the dip-coating. Black-Right-Pointing-Pointer Integrity and connectivity of the nanoparticles facilitates O{sup 2-} transport across the interface.

Hierso, J. [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France); Boy, P.; Valle, K. [CEA-Le Ripault, LSCG, BP 15, 37000 Monts (France); Vulliet, J.; Blein, F. [CEA-Le Ripault, LCCA, BP 15, 37000 Monts (France); Laberty-Robert, Ch., E-mail: christel.laberty@upmc.fr [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France); Sanchez, C. [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France)

2013-01-15T23:59:59.000Z

386

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

DOE Patents [OSTI]

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

1996-09-24T23:59:59.000Z

387

Magnetic dipole discharges. II. Cathode and anode spot discharges and probe diagnostics  

SciTech Connect (OSTI)

The high current regime of a magnetron-type discharge has been investigated. The discharge uses a permanent magnet as a cold cathode which emits secondary electrons while the chamber wall or a grounded electrode serves as the anode. As the discharge voltage is increased, the magnet develops cathode spots, which are short duration arcs that provide copious electrons to increase the discharge current dramatically. Short (1 ?s), high current (200 A) and high voltage (750 V) discharge pulses are produced in a relaxation instability between the plasma and a charging capacitor. Spots are also observed on a negatively biased plane Langmuir probe. The probe current pulses are as large as those on the magnet, implying that the high discharge current does not depend on the cathode surface area but on the properties of the spots. The fast current pulses produce large inductive voltages, which can reverse the electrical polarity of the magnet and temporarily operate it as an anode. The discharge current may also oscillate at the frequency determined by the charging capacitor and the discharge circuit inductance. Each half cycle of high-current current pulses exhibits a fast (?10 ns) current rise when a spot is formed. It induces high frequency (10–100 MHz) transients and ringing oscillations in probes and current circuits. Most probes behave like unmatched antennas for the electromagnetic pulses of spot discharges. Examples are shown to distinguish the source of oscillations and some rf characteristics of Langmuir probes.

Stenzel, R. L.; Urrutia, J. M. [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States)] [Department of Physics and Astronomy, University of California, Los Angeles, California 90095-1547 (United States); Ionita, C.; Schrittwieser, R. [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)] [Institute for Ion Physics and Applied Physics, University of Innsbruck, A-6020 Innsbruck (Austria)

2013-08-15T23:59:59.000Z

388

Prevention of crevice corrosion in duplex SS flanges using carbon steel bolts with cathodic protection  

SciTech Connect (OSTI)

Achieving reliable long-term performance of high strength bolts for flange connections in subsea service is a critical issue for the offshore industry. Viable bolting materials with high strength that are not susceptible to embrittlement or galvanic corrosion when the flanges are made of stainless steels are limited. A laboratory study was performed to determine the viability of using B7 carbon steel stud bolts and 316 stainless steel (SS) seal rings in a Duplex SS flange for subsea service The laboratory test system used full size commercial flanges, bolts and seal rings to simulate electrochemical conditions that will occur in crevices associated with carbon steel bolts in a Duplex SS flange and with the use of a 316 stainless steel seal ring in a Duplex SS flange. The flange systems were instrumented to enable monitoring of current densities and potentials at precise locations within the crevices throughout the tests as test parameters were changed. Test parameters included cathodic protection level, temperature, and sealing the outer flange gap. Cathodic protection was provided by remote aluminum sacrificial anodes to achieve potentials typical for a sub sea manifold. Both electrochemical data and examination of the components at the end of the 164 day exposure indicated that sufficient cathodic protection occurred in the crevices to provide long term corrosion control to all of the components involved. The capability to use B7 bolts rather than high alloy bolts enables a significant project savings.

Thomason, W.H.; Ivie, R.G.; Marlow, J.A.

1999-07-01T23:59:59.000Z

389

Cathodic reduction of sulfur dioxide in nonaqueous electrolytes. polarization curves at porous Electrodes  

SciTech Connect (OSTI)

This paper describes some results obtained from studying the poloarization characteristics of cathodic sulfur dioxide reduction at porous electrodes made by applying a mixture of carbon black, graphite, and binder to a metal screen serving as current collector. Solutions of lithium perchlorate in propylene carbonate and in a mixture of propylene carbonate and acetonitrile were used as the electrolytes. Some typical galvanostatic discharge curves are shown for sulfur dioxide reduction at porous electrodes. The discharge capacity increases with increasing electrode porosity and decreasing current density. One can see when comparing the curves that the discharge capacities differ substantially for highly porous electrodes which had practically the same porosity of about 70%. The effect of current density is more important in solutions with a high SO/sub 2/ concentration. The operating efficiency of porous electrodes which serve as cathodes in high power Li-SO/sub 2/ power sources can be predicted on the basis of polorization curves for the porous electrodes which reflect the influence of macrostructure on the cathodic process.

Shembel, E.M.; Danilova, N.P.; Ksenzhek, O.S.

1986-03-01T23:59:59.000Z

390

Advanced Studies Institute  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Engineering Institute Advanced Studies Institute Contact Institute Director Charles Farrar (505) 663-5330 Email UCSD EI Director Michael Todd (858) 534-5951 Professional Staff...

391

Advanced Reciprocating Engine Systems  

Broader source: Energy.gov [DOE]

The Advanced Reciprocating Engine Systems (ARES) program is designed to promote separate but parallel engine development between the major stationary, gaseous fueled engine manufacturers in the...

392

Advanced Propulsion Technology Strategy  

Broader source: Energy.gov (indexed) [DOE]

Alternative Sources) Hydrogen Time ADVANCED PROPULSION TECHNOLOGY STRATEGY DOWNSIZED TURBO GAS ENGINE CHEVROLET CRUZE 1.4L TURBO ECOTEC Downsized SIDI Turbo Boosting HCCI -...

393

Advanced Fuel Cycle Initiative  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Working with INL Community Outreach Visitor Information Calendar of Events ATR National Scientific User Facility Center for Advanced Energy Studies Light Water Reactor...

394

Advanced Fuel Cycle Program  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Working with INL Community Outreach Visitor Information Calendar of Events ATR National Scientific User Facility Center for Advanced Energy Studies Light Water Reactor...

395

Advances in Physical Chemistry  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hindawi Publishing Corporation Advances in Physical Chemistry Volume 2011, Article ID 907129, 18 pages doi:10.11552011907129 Review Article Contrast and Synergy between...

396

Preparation of Pt deposited nanotubular TiO{sub 2} as cathodes for enhanced photoelectrochemical hydrogen production using seawater electrolytes  

SciTech Connect (OSTI)

The purpose of this study was to develop effective cathodes to increase the production of hydrogen and use the seawater, an abundant resource in the earth as the electrolyte in photoelectrochemical systems. In order to fabricate the Pt/TiO{sub 2} cathodes, various contents of the Pt precursor (0-0.4 wt%) deposited by the electrodeposition method were used. On the basis of the hydrogen evolution rate, 0.2 wt% Pt/TiO{sub 2} was observed to exhibit the best performance among the various Pt/TiO{sub 2} cathodes with the natural seawater and two concentrated seawater electrolytes obtained from single (nanofiltration) and combined membrane (nanofiltration and reverse osmosis) processes. The surface characterizations exhibited that crystal structures and morphological properties of Pt and TiO{sub 2} found the results of XRD pattern and SEM/TEM images, respectively. - Graphical abstract: On the basis of photoelectrochemical hydrogen production, 0.2 wt% Pt/TiO{sub 2} was observed to exhibit the best performance among the various Pt/TIO{sub 2} cathodes with natural seawater. In comparison of hydrogen evolution rate with various seawater electrolytes, 0.2 wt% Pt/TiO{sub 2} was found to show the better performance as cathode with the concentrated seawater electrolytes obtained from membrane. Highlights: > Pt deposited TiO{sub 2} electrodes are used as cathode in PEC H{sub 2} production. > Natural and concentrated seawater by membranes are used as electrolytes in PEC. > Pt/TiO{sub 2} shows a good performance as cathode with seawater electrolytes. > H{sub 2} evolution rate increases with more concentrated seawater electrolyte. > Highly saline seawater is useful resource for H{sub 2} production.

Nam, Wonsik [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Korea University of Technology and Education, Department of Applied Chemical Engineering, 1800 Chungjeollo, Byeongcheon-myun, Chungnam 330-708 (Korea, Republic of); Oh, Seichang [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Yonsei University, Department of Chemical and Biomolecular Engineering, 134 Shinchon-dong, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Joo, Hyunku [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of); Yoon, Jaekyung, E-mail: jyoon@kier.re.kr [Korea Institute of Energy Research, New and Renewable Energy Research Division, Hydrogen Energy Research Center, 71-2 Jang-dong, Yuseong-gu, Daejeon 305-343 (Korea, Republic of)

2011-11-15T23:59:59.000Z

397

Advanced Demand Responsive Lighting  

E-Print Network [OSTI]

Advanced Demand Responsive Lighting Host: Francis Rubinstein Demand Response Research Center demand responsive lighting systems ­ Importance of dimming ­ New wireless controls technologies · Advanced Demand Responsive Lighting (commenced March 2007) #12;Objectives · Provide up-to-date information

398

Kansas Advanced Semiconductor Project  

SciTech Connect (OSTI)

KASP (Kansas Advanced Semiconductor Project) completed the new Layer 0 upgrade for D0, assumed key electronics projects for the US CMS project, finished important new physics measurements with the D0 experiment at Fermilab, made substantial contributions to detector studies for the proposed e+e- international linear collider (ILC), and advanced key initiatives in non-accelerator-based neutrino physics.

Baringer, P.; Bean, A.; Bolton, T.; Horton-Smith, G.; Maravin, Y.; Ratra, B.; Stanton, N.; von Toerne, E.; Wilson, G.

2007-09-21T23:59:59.000Z

399

Structural and Electrochemical Investigation of Li(Ni0.4Co0.2-yAlyMn0.4)O2 Cathode Material  

E-Print Network [OSTI]

demand for less expensive batteries with longer life timescommercial use in L i - ion batteries since their inceptionas a cathode for lithium-ion batteries especially for hybrid

Rumble, C.

2010-01-01T23:59:59.000Z

400

Extended reaction zone of La0.6Sr0.4Co0.2Fe0.8O3 cathode for solid oxide fuel cell  

SciTech Connect (OSTI)

The oxygen reduction reaction at the cathode of solid oxide fuel cell (SOFC) is a complicated process which involves the interaction of oxygen molecules, electrons, and oxygen ions. Therefore, it can only proceed at locations where gas, electronic conductor, and an oxygen ion conductor meet. Although the extension of the reaction zone beyond the traditional so-called triple-phase-boundary (TPB) is widely accepted for a mixed ionically and electronically conductive cathode, work in this area has yet to reach a consensus on how far the reaction zone can be extended. In this study, anode-supported fuel cells with a variety of LSCF cathode thicknesses were fabricated and tested in two cathode environments, flowing oxygen and flowing air. In flowing oxygen, the cell performance increased with LSCF cathode thickness over the entire range investigated (from 5 to 33 ?m). In flowing air, the cell performance also increased with the LSCF cathode thickness from 5 to 13 ?m, but then remained almost constant with further increase in cathode thickness. In flowing oxygen, since there was no concentration polarization related to oxygen diffusion, the polarization resistance of oxygen reduction decreased with the LSCF cathode thickness because of the increased number of reaction sites. A linear relationship was established between the reciprocal of the polarization resistance and the cathode thickness, which was explained by a model developed for aqueous gas diffusion electrodes.

Lu, Zigui; Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

2012-01-03T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
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401

OPTIMIZATION OF THE CATHODE LONG TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect (OSTI)

The cathode materials for molten carbonate fuel cells (MCFCs) must have low dissolution rate, high structural strength and good electrical conductivity. Currently available cathodes are made of lithiated NiO which have acceptable structural strength and conductivity. However a study carried out by Orfeld et al. and Shores et al. indicated that the nickel cathodes dissolved, then precipitated and reformed as dendrites across the electrolyte matrix. This results in a decrease in cell utilization and eventually leads to shorting of the cell. The solubility of NiO was found to depend upon the acidity/basicity of the melt (basicity is directly proportional to log P{sub CO2}), carbonate composition, H{sub 2}O partial pressure and temperature. Urushibata et al. found that the dissolution of the cathode is a primary life limiting constraint of MCFCs, particularly in pressurized operation. With currently available NiO cathodes, the goal of 40,000 hours for the lifetime of MCFC appears achievable with cell operation at atmospheric pressure. However, the cell life at 10 atm and higher cell pressures is in the range between 5,000 to 10,000 hours. The overall objective of this research is to develop a superior cathode for MCFC's with improved catalytic ability, enhanced corrosion resistance with low ohmic losses, improved electronic conductivity. We also plan to understand the corrosion processes occurring at the cathode/molten carbonate interface. The following cathode materials will be subjected to detailed electrochemical, performance, structural and corrosion studies. (i) Passivated NiO alloys using chemical treatment with yttrium ion implantation and anodic yttrium molybdate treatment; (ii) Novel composite materials based on NiO and nanosized Ce, Yt, Mo; (iii) Co doped LiNiO{sub 2} LiNiO{sub 2} doped with 10 to 20% Co (LiCo{sub 0.2}NiO{sub 2}) and NiO cathodes; and (iv) CoO as a replacement for NiO. Passivation treatments will inhibit corrosion and increase the stability of the cathode at high temperatures. Deposition of refractory metals (Mo, W, Li{sub 2}NiCrO{sub 4}) will impart stability to the cathode at high temperatures. Further it will also increase the electrocatalytic activity and corrosion resistance of the cathode. Doping with Co will decrease the alloy dissolution and increase the cycle life of the cathode. In the reporting period the oxidation behavior of Ni and Co in Li + Na carbonate eutectic was investigated under oxidizing environment using cyclic voltammetry, electrochemical impedance spectroscopy and potentiodynamic technique. The open circuit potential was monitored as a function of time in order to evaluate the material's reactivity in the melt.

Anand Durairajan; Bala Haran; Branko N. Popov; Ralph E. White

2000-05-01T23:59:59.000Z

402

Chemistry of SOFC Cathode Surfaces: Fundamental Investigation and Tailoring of Electronic Behavior  

SciTech Connect (OSTI)

1) Electron tunneling characteristics on La0.7Sr0.3MnO3 (LSM) thin-film surfaces were studied up to 580oC in 10-3mbar oxygen pressure, using scanning tunneling microscopy/ spectroscopy (STM/STS). A threshold-like drop in the tunneling current was observed at positive bias in STS, which is interpreted as a unique indicator for the activation polarization in cation oxygen bonding on LSM cathodes. Sr-enrichment was found on the surface at high temperature using Auger electron spectroscopy, and was accompanied by a decrease in tunneling conductance in STS. This suggests that Sr-terminated surfaces are less active for electron transfer in oxygen reduction compared to Mn-terminated surfaces on LSM. 2) Effects of strain on the surface cation chemistry and the electronic structure are important to understand and control for attaining fast oxygen reduction kinetics on transition metal oxides. Here, we demonstrate and mechanistically interpret the strain coupling to Sr segregation, oxygen vacancy formation, and electronic structure on the surface of La0.7Sr0.3MnO3 (LSM) thin films as a model system. Our experimental results from x-ray photoelectron spectroscopy and scanning tunneling spectroscopy are discussed in light of our first principles-based calculations. A stronger Sr enrichment tendency and a more facile oxygen vacancy formation prevail for the tensile strained LSM surface. The electronic structure of the tensile strained LSM surface exhibits a larger band gap at room temperature, however, a higher tunneling conductance near the Fermi level than the compressively strained LSM at elevated temperatures in oxygen. Our findings suggest lattice strain as a key parameter to tune the reactivity of perovskite transition metal oxides with oxygen in solid oxide fuel cell cathodes. 3) Cation segregation on perovskite oxide surfaces affects vastly the oxygen reduction activity and stability of solid oxide fuel cell (SOFC) cathodes. A unified theory that explains the physical origins of this phenomenon is therefore needed for designing cathode materials with optimal surface chemistry. We quantitatively assessed the elastic and electrostatic interactions of the dopant with the surrounding lattice as the key driving forces for segregation on model perovskite compounds, LnMnO3 (host cation Ln=La, Sm). Our approach combines surface chemical analysis with X-ray photoelectron and Auger electron spectroscopy on model dense thin films, and computational analysis with density functional theory (DFT) calculations and analytical models. Elastic energy differences were systematically induced in the system by varying the radius of the selected dopants (Ca, Sr, Ba) with respect to the host cations (La, Sm) while retaining the same charge state. Electrostatic energy differences were introduced by varying the distribution of charged oxygen and cation vacancies in our models. Varying the oxygen chemical potential in our experiments induced changes in both the elastic energy and electrostatic interactions. Our results quantitatively demonstrate that the mechanism of dopant segregation on perovskite oxides includes both the elastic and electrostatic energy contributions. A smaller size mismatch between the host and dopant cations and a chemically expanded lattice were found to reduce the segregation level of the dopant and to enable more stable cathode surfaces. Ca-doped LaMnO3 was found to have the most stable surface composition with the least cation segregation among the compositions surveyed. The diffusion kinetics of the larger dopants, Ba and Sr, was found to be slower, and can kinetically trap the segregation at reduced temperatures despite the larger elastic energy driving force. Lastly, scanning probe image-contrast showed that the surface chemical heterogeneities made of dopant oxides upon segregation were electronically insulating. The consistency between the results obtained from experiments, DFT calculations and analytical theory in this work provides a predictive capability to tailor the cathode surface compositions for high-performance SO

Yildiz, Bilge; Heski, Clemens

2013-08-31T23:59:59.000Z

403

Lattice Expansion of LSCF-6428 Cathodes Measured by In-situ XRD during SOFC Operation  

SciTech Connect (OSTI)

A new capability has been developed for analyzing solid oxide fuel cells (SOFCs). This paper describes the initial results of in-situ x-ray diffraction (XRD) of the cathode on an operating anode-supported solid oxide fuel cell. It has been demonstrated that XRD measurements of the cathode can be performed simultaneously with electrochemical measurements of cell performance or electrochemical impedance spectroscopy (EIS). While improvements to the technique are still to be made, the XRD pattern of a lanthanum strontium cobalt ferrite (LSCF) cathode with the composition La0.6Sr0.4Co0.2Fe0.8O3-? (LSCF-6428) was found to continually but gradually change over the course of more than 60 hours of operation in air under typical SOFC operating conditions. It was determined that the most significant change was a gradual increase in the cubic lattice parameters of the LSCF from 3.92502 Ĺ (as determined from the integration of the first 20 hours of XRD patterns) to 3.92650 Ĺ (from the integration of the last 20 hours). This analysis also revealed that there were several peaks from unidentified minor phases that increased in intensity over this timeframe. After a temporary loss of airflow early in the test, the cell generated between 225 and 250 mW/cm2 for the remainder of the test. A large low frequency arc in the impedance spectra suggests the cell performance was gas diffusion limited and that there is room for improvement in air delivery to the cell.

Hardy, John S.; Templeton, Jared W.; Edwards, Danny J.; Lu, Zigui; Stevenson, Jeffry W.

2012-01-03T23:59:59.000Z

404

advanced ceramics advanced: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. . . . 18 3.4.1 Heat Exchanger - Code description . . . . . . . . . . . . . . . 18 3.4.2 Simulation ResultsADVANCED POWER PLANT MODELING WITH APPLICATIONS TO THE ADVANCED BOILING...

405

Electro-catalytically Active, High Surface Area Cathodes for Low Temperature SOFCs  

SciTech Connect (OSTI)

This research focused on developing low polarization (area specific resistance, ASR) cathodes for intermediate temperature solid oxide fuel cells (IT-SOFCs). In order to accomplish this we focused on two aspects of cathode development: (1) development of novel materials; and (2) developing the relationships between microstructure and electrochemical performance. The materials investigated ranged from Ag-bismuth oxide composites (which had the lowest reported ASR at the beginning of this contract) to a series of pyrochlore structured ruthenates (Bi{sub 2-x}M{sub x}Ru{sub 2}O{sub 7}, where M = Sr, Ca, Ag; Pb{sub 2}Ru{sub 2}O{sub 6.5}; and Y{sub 2-2x}Pr{sub 2x}Ru{sub 2}O{sub 7}), to composites of the pyrochlore ruthenates with bismuth oxide. To understand the role of microstructure on electrochemical performance, we optimized the Ag-bismuth oxide and the ruthenate-bismuth oxide composites in terms of both two-phase composition and particle size/microstructure. We further investigated the role of thickness and current collector on ASR. Finally, we investigated issues of stability and found the materials investigated did not form deleterious phases at the cathode/electrolyte interface. Further, we established the ability through particle size modification to limit microstructural decay, thus, enhancing stability. The resulting Ag-Bi{sub 0.8}Er{sub 0.2}O{sub 1.5} and Bi{sub 2}Ru{sub 2}O{sub 7{sup -}}Bi{sub 0.8}Er{sub 0.2}O{sub 1.5} composite cathodes had ASRs of 1.0 {Omega} cm{sup 2} and 0.73 {Omega}cm{sup 2} at 500 C and 0.048 {Omega}cm{sup 2} and 0.053 {Omega}cm{sup 2} at 650 C, respectively. These ASRs are truly impressive and makes them among the lowest IT-SOFC ASRs reported to date.

Eric D. Wachsman

2006-09-30T23:59:59.000Z

406

Note: Hollow cathode lamp with integral, high optical efficiency isolation valve: A modular vacuum ultraviolet source  

SciTech Connect (OSTI)

The design and operating conditions of a hollow cathode discharge lamp for the generation of vacuum ultraviolet radiation, suitable for ultrahigh vacuum (UHV) application, are described in detail. The design is easily constructed, and modular, allowing it to be adapted to different experimental requirements. A thin isolation valve is built into one of the differential pumping stages, isolating the discharge section from the UHV section, both for vacuum safety and to allow lamp maintenance without venting the UHV chamber. The lamp has been used both for ultraviolet photoelectron spectroscopy of surfaces and as a “soft” photoionization source for gas-phase mass spectrometry.

Sloan Roberts, F.; Anderson, Scott L. [Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, Utah 84112 (United States)] [Department of Chemistry, University of Utah, 315 S. 1400 E., Salt Lake City, Utah 84112 (United States)

2013-12-15T23:59:59.000Z

407

High current, low emittance, steady state electron guns with plasma cathodes  

SciTech Connect (OSTI)

Major limitations of plasma cathodes have been overcome in an electron gun based on extraction of superthermal electrons with a low thermal spread. A grid is employed to select these electrons for extraction while retaining the bulk electrons in the discharge. Steady state extraction of electron beams corresponding to over 60% of the total arc discharge current has been observed. A perveance of over 280 microperv was reached with the extraction of 9A at 1KeV from a 6 mm aperture. Some of the characteristics of the electron gun described in this paper are very attractive for electron beam melting.

Herschovitch, A. [Brookhaven National Laboratory, Upton, NY (United States)

1995-12-31T23:59:59.000Z

408

Humectants To Augment Current From Metallized Zinc Cathodic Protection Systems on Concrete  

SciTech Connect (OSTI)

Cathodic protection (CP) systems using thermal-sprayed zinc anodes are employed to mitigate the corrosion process in reinforced concrete structures. However, the performance of the anodes is improved by moisture at the anode-concrete interface. Research was conducted to investigate the effect of hydrophilic chemical additives, humectants, on the electrical performance and service life of zinc anodes. Lithium bromide and lithium nitrate were identified as feasible humectants with lithium bromide performing better under galvanic CP and lithium nitrate performing better under impressed current CP. Both humectants improved the electrical operating characteristics of the anode and increased the service life by up to three years.

Holcomb, Gordon R.; Covino Jr., Bernard S.; Cramer, Stephen D.; Russell, James H. Russell; Bullard, Sophie J.; Collins, W. Keith; Bennett, Jack E. (J.E. Bennett Consulting, Inc.); Soltesz, Steven M. (ODOT); Laylor, H. Martin (ODOT)

2002-12-01T23:59:59.000Z

409

In-Situ Monitoring of Particle Growth at PEMFC Cathode under Accelerated Cycling Conditions  

SciTech Connect (OSTI)

An in-situ method to measure changes in catalyst particle size at the cathode of a proton exchange membrane fuel cell is demonstrated. Synchrotron X-rays, 58 keV, were used to measure the pair distribution function on an operating fuel cell and observe the growth of catalyst particles under accelerated degradation conditions. The stability of Pt/C and PtCo/C with different initial particle sizes was monitored over 3000 potential cycles. The increase in particle size was fit to a linear trend as a function of cycles. The most stable electrocatalyst was found to be the alloyed PtCo with the larger initial particle size.

Redmond, Erin L.; Setzler, Brian P.; Juhas, Pavol; Billinge, Simon J.L.; Fuller, Thomas F. (GIT); (Columbia)

2012-10-25T23:59:59.000Z

410

Method for analyzing the mass of a sample using a cold cathode ionization source mass filter  

DOE Patents [OSTI]

An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

Felter, Thomas E.

2003-10-14T23:59:59.000Z

411

Cathodic reduction of sulfur dioxide at porous, phthalocyanine-containing electrodes in nonaqueous electrolytes  

SciTech Connect (OSTI)

Electrodes containing catalysts, particularly electrodes containing metal chelate compounds, were studied for their effect on reducing cathodic sulfur dioxide. The electrodes were prepared with an iron phthalocyanine polymer deposited onto activated carbon. Fluoropolymer dispersions was used as the binder and electrochemical studies were performed in a glove box under dry argon. Lithium perchlorate solution in propylene carbonate was used as the electrolyte solution. The results indicate that materials with high catalytic activity show promise in raising the discharge voltage in power sources of the lithium-sulfur dioxide system.

Shembel', E.M.; Ksenzhek, O.S.; Danilova, N.P.; Shustov, V.A.

1988-03-01T23:59:59.000Z

412

Draft Advanced Nuclear Energy Projects Solicitation | Department...  

Broader source: Energy.gov (indexed) [DOE]

Draft Advanced Nuclear Energy Projects Solicitation Draft Advanced Nuclear Energy Projects Solicitation INFORMATIONAL MATERIALS DRAFT ADVANCED NUCLEAR ENERGY PROJECTS SOLICITATION...

413

Fact Sheet: Energy Storage Technology Advancement Partnership...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Advancement Partnership (October 2012) Fact Sheet: Energy Storage Technology Advancement Partnership (October 2012) The Energy Storage Technology Advancement Partnership...

414

ANL-LWRS-14-01  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

temperature (300 O C) and high purity water condition, with 0.136 mm (5.347mil) stroke amplitude and 0.0272 mmS (1.0694 milS) stroke rate (test number- F11) Environmental...

415

Investigation of GOSIP technology at ANL  

SciTech Connect (OSTI)

This document describes testing of OSI products conducted at Argonne National Laboratory. Sun, IBM, and Clsco hardware platforms were used. Various software packages that implement file transfer and gateway applications were evaluated. The OSI model and GOSIP compliance are briefly discussed. Technical details on OSI addressing and routing are presented. The relationship of this testing to other OSI activities at Argonne and to activities of the national networking community is discussed. Mention is also made of the relationship of DECnet Phase V transition issues.

Winkler, L.

1992-01-01T23:59:59.000Z

416

Filling out the ANL-126C  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

enter the name of the person items are being shipped to. Use the magnifying glass to search for a PARIS vendor. *Date Required at Destination Enter the date required at...

417

ANL/EAD/TM-9 Derivation  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofofOxford SiteToledo SiteTonawanda North Site Unit3.1 03/13[NJ.07

418

presentation_anl-SHORT-aug09  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 Industrial Carbon CaptureFY08 Joint JOULECorrective Actions3 Conceptuallyupdate

419

Recent Articles on www.anl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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420

High Energy Physics Division, ANL Lattice QCD  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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421

ANL-W EM Report.pmd  

Broader source: Energy.gov (indexed) [DOE]

the identified hazards. The emergency management plan defines and conveys the management philosophy, organizational structure, administrative controls, decision-making...

422

ANL/ALCF/ESP-13/16  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of3 Ab-initio4 NAMD

423

ANL/ALCF/ESP-13/3  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of3 Ab-initio4 NAMD73

424

ANL/ALCF/ESP-13/4  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of3 Ab-initio4

425

ANL/APS/LS-330 March  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered‰PNGExperience4AJ01) (See95TI07)Operations2 Print258Department of3 Ab-initio4580

426

ANL Success Stories - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011Astudies Colorado Steamboat Deployment AMFGraphic

427

CAT Guide to the ANL CMS system  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route Segments (notCAMDL20-000

428

Three-Dimensional Reconstruction and Microstructure Modeling of Porosity-Graded Cathode Using Focused Ion Beam and Homogenization Techniques  

SciTech Connect (OSTI)

In this study, microstructure of a porosity-graded lanthanum strontium manganite (LSM) cathode of solid oxide fuel cells (SOFCs) has been characterized using focused ion beam (FIB) and scanning electron microscopy(SEM) combined with image processing. Two-point correlation functions of the two-dimensional (2D) images taken along the direction of porosity gradient are used to reconstruct a three-dimensional (3D) microstructure. The effective elastic modulus of the two-phase porosity-graded cathode is predicted using strong contrast (SC) and composite inclusion (CI) homogenization techniques. The effectiveness of the two methods in predicting the effective elastic properties of the porositygraded LSM cathode is investigated in comparison with the results obtained from the finite element model (FEM).

Hamedani, Amani; Baniassadi, Majid; Sheidaei, A.; Pourboghrat, F.; Remond, Y.; Khaleel, Mohammad A.; Garmestani, Hamid

2014-02-28T23:59:59.000Z

429

Comparison of SOFC Cathode Microstructure Quantified using X-ray Nanotomography and Focused Ion Beam - Scanning Electron Microscopy  

SciTech Connect (OSTI)

X-ray nanotomography and focused ion beam scanning electron microscopy (FIB?SEM) have been applied to investigate the complex 3D microstructure of solid oxide fuel cell (SOFC) electrodes at spatial resolutions of 45 nm and below. The application of near edge differential absorption for x-ray nanotomography and energy selected backscatter detection for FIB–SEM enable elemental mapping within the microstructure. Using these methods, non?destructive 3D x-ray imaging and FIB–SEM serial sectioning have been applied to compare three?dimensional elemental mapping of the LSM, YSZ, and pore phases in the SOFC cathode microstructure. The microstructural characterization of an SOFC cathode is reported based on these measurements. The results presented demonstrate the viability of x-ray nanotomography as a quantitative characterization technique and provide key insights into the SOFC cathode microstructure.

Nelson, George J.; Harris, William H.; Lombardo, Jeffrey J.; Izzo, Jr., John R.; Chiu, W. K. S.; Tanasini, Pietro; cantoni, Marco; Van herle, Jan; Comninellis, Christos; Andrews, Joy C.; Liu, Yijin; Pianetta, Piero; Chu, Yong

2011-01-01T23:59:59.000Z

430

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

SciTech Connect (OSTI)

This project focused on addressing the two main problems associated with state of art Molten Carbonate Fuel Cells, namely loss of cathode active material and stainless steel current collector deterioration due to corrosion. We followed a dual approach where in the first case we developed novel materials to replace the cathode and current collector currently used in molten carbonate fuel cells. In the second case we improved the performance of conventional cathode and current collectors through surface modification. States of art NiO cathode in MCFC undergo dissolution in the cathode melt thereby limiting the lifetime of the cell. To prevent this we deposited cobalt using an electroless deposition process. We also coated perovskite (La{sub 0.8}Sr{sub 0.2}CoO{sub 3}) in NiO thorough a sol-gel process. The electrochemical oxidation behavior of Co and perovskites coated electrodes is similar to that of the bare NiO cathode. Co and perovskite coatings on the surface decrease the dissolution of Ni into the melt and thereby stabilize the cathode. Both, cobalt and provskites coated nickel oxide, show a higher polarization compared to that of nickel oxide, which could be due to the reduced surface area. Cobalt substituted lithium nickel oxide (LiNi{sub 0.8}Co{sub 0.2}O{sub 2}) and lithium cobalt oxide were also studied. LiNi{sub x}Co{sub 1-x}O{sub 2} was synthesized by solid-state reaction procedure using lithium nitrate, nickel hydroxide and cobalt oxalate precursor. LiNi{sub x}Co{sub 1-x}O{sub 2} showed smaller dissolution of nickel than state of art nickel oxide cathode. The performance was comparable to that of nickel oxide. The corrosion of the current collector in the cathode side was also studied. The corrosion characteristics of both SS304 and SS304 coated with Co-Ni alloy were studied. This study confirms that surface modification of SS304 leads to the formation of complex scales with better barrier properties and better electronic conductivity at 650 C. A three phase homogeneous model was developed to simulate the performance of the molten carbonate fuel cell cathode and the complete fuel cell. The homogeneous model is based on volume averaging of different variables in the three phases over a small volume element. This approach can be used to model porous electrodes as it represents the real system much better than the conventional agglomerate model. Using the homogeneous model the polarization characteristics of the MCFC cathode and fuel cell were studied under different operating conditions. Both the cathode and the full cell model give good fits to the experimental data.

Hector Colonmer; Prabhu Ganesan; Nalini Subramanian; Dr. Bala Haran; Dr. Ralph E. White; Dr. Branko N. Popov

2002-09-01T23:59:59.000Z

431

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network [OSTI]

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

Widom, A; Larsen, L

2012-01-01T23:59:59.000Z

432

Erroneous Wave Functions of Ciuchi et al for Collective Modes in Neutron Production on Metallic Hydride Cathodes  

E-Print Network [OSTI]

There is a recent comment (Ciuchi et al., 2012) concerning the theory of collective many body effects on the neutron production rates in a chemical battery cathode. Ciuchi et al employ an inverse beta decay expression that contains a two body amplitude. Only one electron and one proton may exist in the Ciuchi et al model initial state wave function. A flaw in their reasoning is that one cannot in reality describe collective many body correlations with only a two particle wave function. One needs very many particles to describe collective effects. In the model wave functions of Ciuchi et al there are no metallic hydrides, there are no cathodes and there are no chemical batteries. Employing a wave function with only one electron and one proton is inadequate for describing collective metallic hydride surface quantum plasma physics in cathodes accurately.

A. Widom; Y. N. Srivastava; L. Larsen

2012-10-17T23:59:59.000Z

433

Array of virtual Frisch-grid CZT detectors with common cathode readout and pulse-height correction  

SciTech Connect (OSTI)

We present our new results from testing 15-mm-long virtual Frisch-grid CdZnTe detectors with a common-cathode readout for correcting pulse-height distortions. The array employs parallelepiped-shaped CdZnTe (CZT) detectors of a large geometrical aspect ratio, with two planar contacts on the top and bottom surfaces (anode and cathode) and an additional shielding electrode on the crystal's sides to create the virtual Frisch-grid effect. We optimized the geometry of the device and improved its spectral response. We found that reducing to 5 mm the length of the shielding electrode placed next to the anode had no adverse effects on the device's performance. At the same time, this allowed corrections for electron loss by reading the cathode signals to obtain depth information.

Bolotnikov, A.E.; Camarda, G.S.; Cui, Y.; Egarievwe, E.U.; Fochuk, P.M.; Fuerstnau, M.; Gul, R.; Hossain, A.; Jones, F.; Kim, K.; Kopach, O.V.; Taggart, R.; Yang, G.; Ye, Z.; Xu, L.; and James, R.B.

2010-08-01T23:59:59.000Z

434

An experiment to test the viability of a gallium-arsenide cathode in a SRF electron gun  

SciTech Connect (OSTI)

Strained gallium arsenide cathodes are used in electron guns for the production of polarized electrons. In order to have a sufficient quantum efficiency lifetime of the cathode the vacuum in the gun must be 10{sup -11} Torr or better, so that the cathode is not destroyed by ion back bombardment or through contamination with residual gases. All successful polarized guns are DC guns, because such vacuum levels can not be obtained in normal conducting RF guns. A superconductive RF gun may provide a sufficient vacuum level due to cryo-pumping of the cavity walls. We report on the progress of our experiment to test such a gun with normal GaAs-Cs crystals.

Kewisch,J.; Ben-Zvi, I.; Rao, T.; Burrill, A.; Pate, D.; Wu, Q.; Todd, R.; Wang, E.; Bluem, H.; Holmes, D.; Schultheiss, T.

2009-05-04T23:59:59.000Z

435

Search Asia Advanced Search  

E-Print Network [OSTI]

Asia Times Search Asia Times Advanced Search Southeast Asia Malaysia tackles illegal logging:52:14 AM Search #12;Asia Times illegal logging," he said, adding that nine Malaysians had been arrested

436

Search Asia Advanced Search  

E-Print Network [OSTI]

Asia Times Search Asia Times Advanced Search Southeast Asia Indonesia looks to curb log smuggling.html (1 of 2)9/4/2007 12:59:34 PM Search #12;Asia Times No material from Asia Times Online may

437

Advanced Review Geometry optimization  

E-Print Network [OSTI]

Advanced Review Geometry optimization H. Bernhard Schlegel Geometry optimization is an important part of most quantum chemical calcu- lations. This article surveys methods for optimizing equilibrium geometries, lo- cating transition structures, and following reaction paths. The emphasis is on optimizations

Schlegel, H. Bernhard

438

Advanced Materials | More Science | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials SHARE Advanced Materials ORNL has the nation's most comprehensive materials research program and is a world leader in research that supports the development of...

439

Renewable Chemicals and Advanced Biofuels  

Broader source: Energy.gov [DOE]

Afternoon Plenary Session: Current Trends in the Advanced Bioindustry Advanced Biofuels & Policy—Brett Lund, Executive Vice President, General Counsel and Secretary, Gevo Inc.

440

Development of a high average current polarized electron source with long cathode operational lifetime  

SciTech Connect (OSTI)

Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory) require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2?105???C/cm2 and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

C. K. Sinclair; P. A. Adderley; B. M. Dunham; J. C. Hansknecht; P. Hartmann; M. Poelker; J. S. Price; P. M. Rutt; W. J. Schneider; M. Steigerwald

2007-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Combined Theoretical and Experimental Analysis of Processes Determining Cathode Performance in Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

Solid oxide fuel cells (SOFC) are under intensive investigation since the 1980’s as these devices open the way for ecologically clean direct conversion of the chemical energy into electricity, avoiding the efficiency limitation by Carnot’s cycle for thermochemical conversion. However, the practical development of SOFC faces a number of unresolved fundamental problems, in particular concerning the kinetics of the electrode reactions, especially oxygen reduction reaction. We review recent experimental and theoretical achievements in the current understanding of the cathode performance by exploring and comparing mostly three materials: (La,Sr)MnO3 (LSM), (La,Sr)(Co,Fe)O3 (LSCF) and (Ba,Sr)(Co,Fe)O3 (BSCF). Special attention is paid to a critical evaluation of advantages and disadvantages of BSCF, which shows the best cathode kinetics known so far for oxides. We demonstrate that it is the combined experimental and theoretical analysis of all major elementary steps of the oxygen reduction reaction which allows us to predict the rate determining steps for a given material under specific operational conditions and thus control and improve SOFC performance.

Kukla, Maija M.; Kotomin, Eugene Alexej; Merkle, R.; Mastrikov, Yuri; Maier, J.

2013-02-11T23:59:59.000Z

442

Generation of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube-based field-emission cathode  

E-Print Network [OSTI]

-ray radiation can be generated using a carbon nanotube CNT -based field-emission cathode. The device can readilyGeneration of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube-based field-emission cathode G. Z. Yue Department of Physics, University of North Carolina, Chapel Hill, North

443

Advanced Accelerator Concepts Final Report  

SciTech Connect (OSTI)

A major focus of research supported by this Grant has been on the ALPHA antihydrogen trap. We first trapped antihydrogen in 2010 and soon thereafter demonstrated trapping for 1000s. We now have observed resonant quantum interactions with antihydrogen. These papers in Nature and Nature Physics report the major milestones in anti-atom trapping. The success was only achieved through careful work that advanced our understanding of collective dynamics in charged particle systems, the development of new cooling and diagnostics, and in- novation in understanding how to make physics measurements with small numbers of anti-atoms. This research included evaporative cooling, autoresonant excitation of longitudinal motion, and centrifugal separation. Antihydrogen trapping by ALPHA is progressing towards the point when a important theories believed by most to hold for all physical systems, such as CPT (Charge-Parity-Time) invariance and the Weak Equivalence Principle (matter and antimatter behaving the same way under the influence of gravity) can be directly tested in a new regime. One motivation for this test is that most accepted theories of the Big Bang predict that we should observe equal amounts of matter and antimatter. However astrophysicists have found very little antimatter in the universe. Our experiment will, if successful over the next seven years, provide a new test of these ideas. Many earlier detailed and beautiful tests have been made, but the trapping of neutral antimatter allows us to explore the possibility of direct, model-independent tests. Successful cooling of the anti atoms, careful limits on systematics and increased trapping rates, all planned for our follow-up experiment (ALPHA-II) will reach unrivaled precision. CPT invariance implies that the spectra of hydrogen and antihydrogen should be identical. Spectra can be measured in principle with great precision, and any di#11;erences we might observe would revolutionize fundamental physics. This is the physics motivation for our experiment, one that requires only a few dozen researchers but must effectively integrate plasma, accelerator, atomic, and fundamental physics, as well as combine numerous technologies in the control, manipulation, and measurement of neutral and non-neutral particles. The ELENA ring (to which we hope to contribute, should funding be provided) is expect, when completed, to significantly enhance the performance of antihydrogen trapping by increasing by a factor of 100 the number of antiprotons that can be successfully trapped and cooled. ELENA operation is scheduled to commence in 2017. In collaboration with LBNL scientists, we proposed a frictional cooling scheme. This is an alternative cooling method to that used by ELENA. It is less complicated, experimentally unproven, and produces a lower yield of cold antiprotons. Students and postdoctoral researchers work on the trapping, cooling, transport, and nonlinear dynamics of antiprotons bunches that are provided by the AD to ALPHA; they contribute to the operation of the experiment, to software development, and to the design and operation of experiments. Students are expected to spend at summers at CERN while taking courses; after completion of courses they typically reside at CERN for most of the half-year run. The Antiproton Decelerator [AD] at CERN, along with its experiments, is the only facility in the world where antiprotons can be trapped and cooled and combined with positrons to form cold antihydrogen, with the ultimate goal of studying CPT violation and, subsequently, gravitational interactions of antimatter. Beyond the ALPHA experiment, the group worked on beam physics problems including limits on the average current in a time-dependent period cathode and new methods to create longitudinally coherent high repetition rate soft x-ray sources and wide bandwidth mode locked x-ray lasers. We completed a detailed study of quantum mechanical effects in the transit time cooling of muons.

Wurtele, Jonathan S.

2014-05-13T23:59:59.000Z

444

Electrolytes - Advanced Electrolyte and Electrolyte Additives  

Broader source: Energy.gov (indexed) [DOE]

testing Cathode: LiNi13Mn13Co13O2 Anode: MCMB Electrolyte: 1.2M LiPF6 ECEMC 37 with or without additive - Separator: Celgard 2325 Voltage for cycling:...

445

Advanced Hydride Laboratory  

SciTech Connect (OSTI)

Metal hydrides have been used at the Savannah River Tritium Facilities since 1984. However, the most extensive application of metal hydride technology at the Savannah River Site is being planned for the Replacement Tritium Facility, a $140 million facility schedules for completion in 1990 and startup in 1991. In the new facility, metal hydride technology will be used to store, separate, isotopically purify, pump, and compress hydrogen isotopes. In support of the Replacement Tritium Facility, a $3.2 million, cold,'' process demonstration facility, the Advanced Hydride Laboratory began operation in November of 1987. The purpose of the Advanced Hydride Laboratory is to demonstrate the Replacement Tritium Facility's metal hydride technology by integrating the various unit operations into an overall process. This paper will describe the Advanced Hydride Laboratory, its role and its impact on the application of metal hydride technology to tritium handling.

Motyka, T.

1989-01-01T23:59:59.000Z

446

Advanced Hydride Laboratory  

SciTech Connect (OSTI)

Metal hydrides have been used at the Savannah River Tritium Facilities since 1984. However, the most extensive application of metal hydride technology at the Savannah River Site is being planned for the Replacement Tritium Facility, a $140 million facility schedules for completion in 1990 and startup in 1991. In the new facility, metal hydride technology will be used to store, separate, isotopically purify, pump, and compress hydrogen isotopes. In support of the Replacement Tritium Facility, a $3.2 million, ``cold,`` process demonstration facility, the Advanced Hydride Laboratory began operation in November of 1987. The purpose of the Advanced Hydride Laboratory is to demonstrate the Replacement Tritium Facility`s metal hydride technology by integrating the various unit operations into an overall process. This paper will describe the Advanced Hydride Laboratory, its role and its impact on the application of metal hydride technology to tritium handling.

Motyka, T.

1989-12-31T23:59:59.000Z

447

Advanced Vehicle Electrification and Transportation Sector Electrifica...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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448

The primary components of a fuel cell are an ion conducting electrolyte, a cathode, and an anode, as  

E-Print Network [OSTI]

The primary components of a fuel cell are an ion conducting electrolyte, a cathode, and an anode chemical driving force for the oxygen and the hydrogen to react to produce water. In the fuel cell, however for the many categories of fuel cells under development today. Desirable characteristics of fuel cell

Haile, Sossina M.

449

Scalable air cathode microbial fuel cells using glass fiber separators, plastic mesh supporters, and graphite fiber brush anodes  

E-Print Network [OSTI]

Bioelectrochemical Microbial fuel cell Biofuels Separators a b s t r a c t The combined use of brush anodes and glass was 75 ± 1 W/m3 . Removing the separator decreased power by 8%. Adding a second cathode increased power into the anode chamber. The use of a cloth separator (J-cloth, JC) substan- tially improved power generation

450

Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b  

E-Print Network [OSTI]

Power generation by packed-bed air-cathode microbial fuel cells Xiaoyuan Zhang a,b , Juan Shi c Laboratory of Environment Simulation and Pollution Control, THU­VEOLIA Environment Joint Research Center Park, PA 16802, USA c School of Environment Science and Spatial Informatics, China University of Mining

451

X-ray Absorption Measurements on Nickel Cathode of Sodium-beta Alumina batteries: Fe-Ni-CI Chemical Associations  

SciTech Connect (OSTI)

Sections of Na-Al-NiCl2 cathodes from sodium-beta alumina ZEBRA batteries have been characterized with X-ray fluorescence mapping, and XANES measurements to probe the microstructure, elemental correlation, and chemical speciation after voltage cycling. Cycling was performed under identical load conditions at either 240 or 280 °C operating temperature and subsequently quenched in either the charged or discharged state. X-ray fluorescence mapping and XANES measurements were made adjacent to the current collector and ?"-Al2O3 solid electrolyte interfaces to detect possible gradients in chemical properties across the cathode. An FeS additive, introduced during battery synthesis, was found to be present as either Fe metal or an Fe(II) chloride in all cathode samples. X-ray fluorescence mapping reveals an operating temperature and charge-state dependent spatial correlation between Fe, Ni, and Cl concentration. XANES measurements indicate that both Ni and Fe are chemically reactive and shift between metallic and chloride phases in the charged and discharged states, respectively. However the percentage of chemically active Ni and Fe is significantly less in the cell operated at lower temperature. Additionally, the cathode appeared chemically homogeneous at the scale of our X-ray measurements.

Bowden, Mark E.; Alvine, Kyle J.; Fulton, John L.; Lemmon, John P.; Lu, Xiaochuan; Webb-Robertson, Bobbie-Jo M.; Heald, Steve M.; Balasubramanian, Mahalingam; Mortensen, Devon R.; Seidler, Gerald T.; Hess, Nancy J.

2014-02-01T23:59:59.000Z

452

Experimental study of a Ne-H{sub 2} Penning Recombination Laser in a helical hollow cathode discharge  

SciTech Connect (OSTI)

Penning recombination lasers (PRL), as first proposed in, operate in non-equilibrium recombination plasma where the upper laser level (ULL) is populated by the recombination flux and the lower laser level (LLL) is depopulated by Penning reactions. The lack of chemical activity and degradation of the laser mixture, lasing in the visible spectral region and high output power obtained attract the attention to the Ne-H{sub 2} PRL operating on the NeI 585.3 nm line (the 2p{sub 1}-1s{sub 2} transition). Despite the most powerful PRL are pumped by electron beams of relativistic energies, it is of practical interest to realize PRL pumped in a hollow cathode discharge where beam of high energy primary electrons exists. In this study a detailed experimental investigation of a Ne-H{sub 2} PRL operating in a helical hollow cathode discharge is carried out. The obtained data are compared with the results of the theoretical model. The laser tube design is similar to that used in our previous work. The cathode is made of Mo band 10 mm wide, helically wound with a 15 mm pitch to form a cylindrical hollow. Five laser tubes with different cathode diameters (5.5-12 mm) and lengths (110-280 mm) are investigated.

Pramatarov, P.M.; Stefanova, M.S.; Petrov, G.M. [Georgy Nadjakov Institute of Solid State Physics, Sofia (Bulgaria)

1995-12-31T23:59:59.000Z

453

Process for the manufacture of an electrode for electrochemical process and a cathode for the electrolytic production of hydrogen  

SciTech Connect (OSTI)

An electrically conductive substrate is coated with a material containing an unsintered powder of a metal active for electrochemical proton reduction and colloidal silica and the said material is heated on the substrate successively in an oxidizing atmosphere and then in a reducing atmosphere. The electrode may be employed as a cathode for electrolytic production of hydrogen in an alkaline medium.

Nicolas, E.; Merckaert, L.

1985-08-13T23:59:59.000Z

454

Synthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol fuel cells  

E-Print Network [OSTI]

Available online 3 August 2010 Keywords: Fuel cell Alkaline direct ethanol fuel cell Oxygen reduction Carbon in large quantities from agricultural products or biomass. Hence, direct ethanol fuel cells (DEFCs) haveSynthesis and characterization of the Au-modified Pd cathode catalyst for alkaline direct ethanol

Zhao, Tianshou

455

A Hybrid Laser-driven E-beam Injector Using Photo-cathode Electron Gun and superconducting Cavity*  

E-Print Network [OSTI]

A Hybrid Laser-driven E-beam Injector Using Photo-cathode Electron Gun and superconducting Cavity as a continuing effort towards a high-brightness superconducting RF injector. Various species of photo and one (betasuperconducting cavities operating under 2 K is to be constructed

Geng, Rong-Li

456

Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode  

E-Print Network [OSTI]

Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode Yancheng Zhang of lithium- ion batteries for electric vehicles EVs and hybrid EVs HEVs . Substantial research has been- face, which is critical to the cycle life and calendar life of lithium- ion batteries.1,2 Unfortunately

457

Vacuum-free lamination of low work function cathode for efficient solution-processed organic light-emitting diodes  

E-Print Network [OSTI]

-coated organic light-emitting diode is transferred from a soft polydimethylsiloxane (PDMS) mold by lamination, or blade coating [1,2] for organic light emitting diode (OLED) as well as solar cell. The top electrodeVacuum-free lamination of low work function cathode for efficient solution-processed organic light-emitting

Meng, Hsin-Fei

458

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through Electrode  

E-Print Network [OSTI]

Sputter-Deposited Pt/CrN Nanoparticle PEM Fuel Cell Cathodes: Limited Proton Conductivity Through for proton exchange membrane PEM fuel cells. X-ray diffraction and scanning electron microscopy show manuscript received September 17, 2009. Published November 13, 2009. Proton exchange membrane PEM fuel cells

Gall, Daniel

459

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N A Siddique  

E-Print Network [OSTI]

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N of Texas at Arlington, Arlington, Texas 76019, USA High-capacity Li-ion batteries are among the best of the major challenges in Li-ion batteries is to improve mass transport across multiple phase interfaces

Liu, Fuqiang

460

Advanced Optical Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch Highlights MediaFuelAbout Us >Portal AdvancedAdvanced

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461

Advanced fuel chemistry for advanced engines.  

SciTech Connect (OSTI)

Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

2009-09-01T23:59:59.000Z

462

Surface and bulk modified high capacity layered oxide cathodes with low irreversible capacity loss  

DOE Patents [OSTI]

The present invention includes compositions, surface and bulk modifications, and methods of making of (1-x)Li[Li.sub.1/3Mn.sub.2/3]O.sub.2.xLi[Mn.sub.0.5-yNi.sub.0.5-yCo.sub.2- y]O.sub.2 cathode materials having an O3 crystal structure with a x value between 0 and 1 and y value between 0 and 0.5, reducing the irreversible capacity loss in the first cycle by surface modification with oxides and bulk modification with cationic and anionic substitutions, and increasing the reversible capacity to close to the theoretical value of insertion/extraction of one lithium per transition metal ion (250-300 mAh/g).

Manthiram, Arumugam (Austin, TX); Wu, Yan (Austin, TX)

2010-03-16T23:59:59.000Z

463

La(Sr)FeO3 SOFC Cathodes with Marginal Copper Doping  

SciTech Connect (OSTI)

Abstract (La0.8Sr0.2)0.98Fe0.98Cu0.02O3-? can be sintered directly onto YSZ (without the need for a protective ceria interlayer to prevent inter-diffusion). Though subject to an extended “burn-in” period (~200 hours), anode-supported YSZ cells utilizing the Cu-doped LSF achieve power densities ranging from 1.3-1.7 W/cm2 at 750şC and 0.7V. These cells have also demonstrated 500 hours of stable performance. The results are somewhat surprising given that XRD indicates an interaction between (La0.8Sr0.2)0.98Fe0.98Cu0.02O3-? and YSZ resulting in the formation of strontium zirconate and/or monoclinic zirconia. The amount and type of reaction product was found to be dependent on cathode and electrolyte powder pre-calcination temperatures.

Simner, Steve P.; Anderson, Michael D.; Stevenson, Jeffry W.

2004-08-01T23:59:59.000Z

464

Study on a negative hydrogen ion source with hot cathode arc discharge  

SciTech Connect (OSTI)

A negative hydrogen (H{sup ?}) ion source with hot cathode arc discharge was designed and fabricated as a primary injector for a 10 MeV PET cyclotron at IMP. 1 mA dc H{sup ?} beam with ? {sub N,} {sub RMS} = 0.08 ??mm?mrad was extracted at 25 kV. Halbach hexapole was adopted to confine the plasma. The state of arc discharge, the parameters including filament current, arc current, gas pressure, plasma electrode bias, and the ratio of I{sub e{sup ?}}/I{sub H{sup ?}} were experimentally studied. The discussion on the result, and opinions to improve the source were given.

Lin, S. H., E-mail: linshh@impcas.ac.cn; Fang, X. [Institute of Modern Physics (IMP), Chinese Academy of Sciences, Lanzhou 730000 (China) [Institute of Modern Physics (IMP), Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100039 (China); Zhang, H. J.; Qian, C.; Ma, B. H.; Wang, H.; Li, X. X.; Zhang, X. Z.; Sun, L. T.; Zhang, Z. M.; Yuan, P.; Zhao, H. W. [Institute of Modern Physics (IMP), Chinese Academy of Sciences, Lanzhou 730000 (China)] [Institute of Modern Physics (IMP), Chinese Academy of Sciences, Lanzhou 730000 (China)

2014-02-15T23:59:59.000Z

465

High current, low emittance, steady state electron guns with plasma cathodes  

SciTech Connect (OSTI)

Major limitations of plasma cathodes have been overcome in an electron gun based on extraction of superthermal electrons from a discharge characterized by a large component of high energy electrons with a low thermal spread. A grid is employed to select these electrons for extraction while retaining the bulk electrons in the discharge. Steady state extraction of electron beams corresponding to over 60% of the total arc discharge current has been observed. A perveance of over 280 microperv was reached with the extraction of 9A at 1 keV from a 6 nun aperture. Some of the characteristics of the electron beam described in this paper are very attractive for electron beam melting.

Hershcovitch, A.

1995-12-31T23:59:59.000Z

466

Internal cathodic protection of seawater piping system by the use of the RCP method  

SciTech Connect (OSTI)

Since the early eighties high alloyed stainless steels like austenitic steels with about 6% molybdenum (called 6Mo-steel) and duplex stainless steels with 25% Cr (called super duplex) have been widely used in seawater systems in connection with oil- and gas production. During the last ten years high alloyed stainless steels with 6% molybdenum (6Mo) or 25%Cr (super duplex) have been the most popular materials for seawater systems on offshore installations in the North Sea. The basis for this material selection was to obtain maintenance free systems with long lifetime. However, practical experience has shown that corrosion failures can occur. This paper presents a simple and economical method to avoid corrosion problems internally in piping systems transporting chlorinated seawater. The method is called RCP--Resistor controlled Cathodic Protection. Principles of the method including protection potential, current density requirements and anode design in addition to different practical applications are described.

Johnsen, R.; Gartland, P.O.; Valen, S. [CorrOcean as, Trondheim (Norway); Drugli, J.M. [SINTEF Corrosion Centre, Trondheim (Norway)

1996-10-01T23:59:59.000Z

467

Modeling a short dc discharge with thermionic cathode and auxiliary anode  

SciTech Connect (OSTI)

A short dc discharge with a thermionic cathode can be used as a current and voltage stabilizer, but is subject to current oscillation. If instead of one anode two anodes are used, the current oscillations can be reduced. We have developed a kinetic model of such a discharge with two anodes, where the primary anode has a small opening for passing a fraction of the discharge current to an auxiliary anode. The model demonstrates that the current-voltage relationship of the discharge with two anodes is characterized everywhere by positive slope, i.e., positive differential resistance. Therefore, the discharge with two anodes is expected to be stable to the spontaneous oscillation in current that is induced by negative differential resistance. As a result, such a discharge can be used in an engineering application that requires stable plasma, such as a current and voltage stabilizer.

Bogdanov, E. [St. Petersburg State University, St. Petersburg 199034 (Russian Federation) [St. Petersburg State University, St. Petersburg 199034 (Russian Federation); University ITMO, Kronverkskiy pr. 49, St. Petersburg 197101 (Russian Federation); Demidov, V. I. [St. Petersburg State University, St. Petersburg 199034 (Russian Federation) [St. Petersburg State University, St. Petersburg 199034 (Russian Federation); West Virginia University, Morgantown, West Virginia 26506 (United States); Kaganovich, I. D. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Koepke, M. E. [West Virginia University, Morgantown, West Virginia 26506 (United States)] [West Virginia University, Morgantown, West Virginia 26506 (United States); Kudryavtsev, A. A. [St. Petersburg State University, St. Petersburg 199034 (Russian Federation)] [St. Petersburg State University, St. Petersburg 199034 (Russian Federation)

2013-10-15T23:59:59.000Z

468

Demonstration of Cathode Emittance Dominated High Bunch Charge Beams in a DC gun-based Photoinjector  

E-Print Network [OSTI]

We present the results of transverse emittance and longitudinal current profile measurements of high bunch charge (greater than or equal to 100 pC) beams produced in the DC gun-based Cornell Energy Recovery Linac Photoinjector. In particular, we show that the cathode thermal and core beam emittances dominate the final 95% and core emittance measured at 9-9.5 MeV. Additionally, we demonstrate excellent agreement between optimized 3D space charge simulations and measurement, and show that the quality of the transverse laser distribution limits the optimal simulated and measured emittances. These results, previously thought achievable only with RF guns, demonstrate that DC gun based photoinjectors are capable of delivering beams with sufficient single bunch charge and beam quality suitable for many current and next generation accelerator projects such as Energy Recovery Linacs (ERLs) and Free Electron Lasers (FELs).

Gulliford, Colwyn; Bazarov, Ivan; Dunham, Bruce; Cultrera, Luca

2015-01-01T23:59:59.000Z

469

Effect of energetic electrons on dust charging in hot cathode filament discharge  

SciTech Connect (OSTI)

The effect of energetic electrons on dust charging for different types of dust is studied in hydrogen plasma. The hydrogen plasma is produced by hot cathode filament discharge method in a dusty plasma device. A full line cusped magnetic field cage is used to confine the plasma elements. To study the plasma parameters for various discharge conditions, a cylindrical Langmuir probe having 0.15 mm diameter and 10.0 mm length is used. An electronically controlled dust dropper is used to drop the dust particles into the plasma. For different discharge conditions, the dust current is measured using a Faraday cup connected to an electrometer. The effect of secondary emission as well as discharge voltage on charging of dust grains in hydrogen plasma is studied with different dust.

Kakati, B.; Kausik, S. S.; Saikia, B. K. [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur 782 402, Kamrup, Assam (India); Bandyopadhyay, M. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)

2011-03-15T23:59:59.000Z

470

Recovery of yttrium from cathode ray tubes and lamps’ fluorescent powders: experimental results and economic simulation  

SciTech Connect (OSTI)

Highlights: • Fluorescent powder of lamps. • Fluorescent powder of cathode ray rubes. • Recovery of yttrium from fluorescent powders. • Economic simulation for the processes to recover yttrium from WEEE. - Abstract: In this paper, yttrium recovery from fluorescent powder of lamps and cathode ray tubes (CRTs) is described. The process for treating these materials includes the following: (a) acid leaching, (b) purification of the leach liquors using sodium hydroxide and sodium sulfide, (c) precipitation of yttrium using oxalic acid, and (d) calcinations of oxalates for production of yttrium oxides. Experimental results have shown that process conditions necessary to purify the solutions and recover yttrium strongly depend on composition of the leach liquor, in other words, whether the powder comes from treatment of CRTs or lamp. In the optimal experimental conditions, the recoveries of yttrium oxide are about 95%, 55%, and 65% for CRT, lamps, and CRT/lamp mixture (called MIX) powders, respectively. The lower yields obtained during treatments of MIX and lamp powders are probably due to the co-precipitation of yttrium together with other metals contained in the lamps powder only. Yttrium loss can be reduced to minimum changing the experimental conditions with respect to the case of the CRT process. In any case, the purity of final products from CRT, lamps, and MIX is greater than 95%. Moreover, the possibility to treat simultaneously both CRT and lamp powders is very important and interesting from an industrial point of view since it could be possible to run a single plant treating fluorescent powder coming from two different electronic wastes.

Innocenzi, V., E-mail: valentina.innocenzi1@univaq.it; De Michelis, I.; Ferella, F.; Vegliň, F.

2013-11-15T23:59:59.000Z

471

Oxygen Transport Kinetics in Infiltrated SOFCs Cathode by Electrical Conductivity Relaxation Technique  

SciTech Connect (OSTI)

Infiltration has attracted increasing attention as an effective technique to modify SOFC cathodes to improve cell electrochemical performance while maintaining material compatibility and long-term stability. However, the infiltrated material's effect on oxygen transport is still not clear and detailed knowledge of the oxygen reduction reaction in infiltrated cathodes is lacking. In this work, the technique of electrical conductivity relaxation (ECR) is used to evaluate oxygen exchange in two common infiltrated materials, Ce{sub 0.8}Sm{sub 0.2}O{sub 1.9} and La{sub 0.6}Sr{sub 0.4}CoO{sub 3-?}. The ECR technique is also used to examine the transport processes in a composite material formed with a backbone of La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3-?} and possessing a thin, dense surface layer composed of the representative infiltrate material. Both the surface oxygen exchange process and the oxygen exchange coefficient at infiltrate/LSCF interface are reported. ECR testing results indicate that the application of infiltrate under certain oxygen partial pressure conditions produces a measureable increase in the fitted oxygen exchange parameter. It is presently only possible to generate hypotheses to explain the observation. However the correlation between improved electrochemical performance and increased oxygen transport measured by ECR is reliably demonstrated. The simple and inexpensive ECR technique is utilized as a direct method to optimize the selection of specific infiltrate/backbone material systems for superior performance.

Li, Yihong; Gerdes, Kirk; Liu, Xingbo

2013-07-01T23:59:59.000Z

472

Arnold Schwarzenegger ADVANCEMENT OF  

E-Print Network [OSTI]

Arnold Schwarzenegger Governor ADVANCEMENT OF ELECTROCHROMIC WINDOWS Prepared For: California the time to provide insightful technical and market-related input into the direction of this R&D: Carl Mechoshade Systems, Inc. Grant Brohard Pacific Gas & Electric Company Charles Hayes SAGE Electrochromics, Inc

473

Advanced fossil energy utilization  

SciTech Connect (OSTI)

This special issue of Fuel is a selection of papers presented at the symposium ‘Advanced Fossil Energy Utilization’ co-sponsored by the Fuels and Petrochemicals Division and Research and New Technology Committee in the 2009 American Institute of Chemical Engineers (AIChE) Spring National Meeting Tampa, FL, on April 26–30, 2009.

Shekhawat, D.; Berry, D.; Spivey, J.; Pennline, H.; Granite, E.

2010-01-01T23:59:59.000Z

474

Standard version Advanced version  

E-Print Network [OSTI]

Minimum octane 8.5 7 4.5 To produce these products, Margaret purchases crude oil at a price of ÂŁ11 per version Margaret Oil - basic (2) Before crude can be used to produce products for sale, it must version Advanced version Margaret Oil - basic (3) Crude Distill Naphtha Gasoline Distilled 1 Jet fuel

Hall, Julian

475

Advanced Test Reactor Tour  

SciTech Connect (OSTI)

The Advanced Test Reactor at Idaho National Laboratory is the foremost nuclear materials test reactor in the world. This virtual tour describes the reactor, how experiments are conducted, and how spent nuclear fuel is handled and stored. For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

Miley, Don

2011-01-01T23:59:59.000Z

476

Advanced Test Reactor Tour  

ScienceCinema (OSTI)

The Advanced Test Reactor at Idaho National Laboratory is the foremost nuclear materials test reactor in the world. This virtual tour describes the reactor, how experiments are conducted, and how spent nuclear fuel is handled and stored. For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

Miley, Don

2013-05-28T23:59:59.000Z

477

International for Advanced Studies  

E-Print Network [OSTI]

and Technology at the University of Ulm ICAS-Affiliations The International Center for Advanced Studies in Health in medical technology and pharma- ceutical industry. The International Advisory Panel of ICAS consists, transfer of state-of-the-art clinical technologies, and utilization of methodologies appropriate

Pfeifer, Holger

478

Advanced Biotechnology and Medicine  

E-Print Network [OSTI]

, Training and Technology Transfer 43 Lectures and Seminars 44 CABM Lecture Series 45 Annual Retreat 46 15th An Advanced Technology Center of The New Jersey Commission on Science and Technology Jointly Administered from CABM laboratories have appeared in high impact international journals including Development, Genes

479

Advanced Biotechnology and Medicine  

E-Print Network [OSTI]

Shatkin 41 Education, Training and Technology Transfer 43 Lectures and Seminars 44 CABM Lecture Series 45 An Advanced Technology Center of The New Jersey Commission on Science and Technology Jointly Administered for the improvement of human health. In 2002 peer-reviewed CABM studies were published in leading international

480

Advanced Biotechnology and Medicine  

E-Print Network [OSTI]

Vikas Nanda 63 Protein Crystallography Ann Stock 67 Education, Training and Technology Transfer 71 Report An Advanced Technology Center of the New Jersey Commission on Science and Technology Jointly, the CIPR will house the Rutgers-based Protein Data Bank (PDB), an international repository directed

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Advanced simulation of intelligent transportation systems  

SciTech Connect (OSTI)

A large-scale, comprehensive, scaleable simulation of an Intelligent Transportation System (ITS) has been developed which is capable of running on parallel computers and distributed (networked) computer systems. The simulator currently models instrumented {open_quotes}smart{close_quotes} vehicles with in-vehicle navigation units capable of optimal route planning and Traffic Management Centers (TMC). The TMC has probe vehicle tracking capabilities (display position and attributes of instrumented vehicles), and can provide two-way interaction with traffic to provide advisories and link times. Both the in-vehicle navigation module and the TMC feature detailed graphical user interfaces to support human-factors studies. The prototype has been developed on a distributed system of networked UNIX computers but is designed to run on parallel computers, such as ANL`s IBM SP-2, for large-scale problems. A novel feature of this approach is that vehicles are represented by autonomous computer processes which exchange messages with other processes. The vehicles have a behavior model which governs route selection and driving behavior, and can react to external traffic events much like real vehicles. With this approach, the simulation is scaleable to take advantage of emerging massively parallel processor (MPP) systems.

Ewing, T.; Doss, E.; Hanebutte, U.; Tentner, A. [Argonne National Lab., IL (United States)

1996-11-01T23:59:59.000Z

482

Herty Advanced Materials Development Center  

Broader source: Energy.gov [DOE]

Session 1-B: Advancing Alternative Fuels for the Military and Aviation Sector Breakout Session 1: New Developments and Hot Topics Jill Stuckey, Acting Director, Herty Advanced Materials Development Center

483

Search Advanced Search Home > News  

E-Print Network [OSTI]

Search Advanced Search Home > News [-] Text [+] Email Print tweet 0 tweets RSS Feeds Newsletters with bodily tissues, "these approaches might have the potential to redefine design strategies for advanced

Rogers, John A.

484

Advanced Technology Vehicle Testing  

SciTech Connect (OSTI)

The goal of the U.S. Department of Energy's Advanced Vehicle Testing Activity (AVTA) is to increase the body of knowledge as well as the awareness and acceptance of electric drive and other advanced technology vehicles (ATV). The AVTA accomplishes this goal by testing ATVs on test tracks and dynamometers (Baseline Performance testing), as well as in real-world applications (Fleet and Accelerated Reliability testing and public demonstrations). This enables the AVTA to provide Federal and private fleet managers, as well as other potential ATV users, with accurate and unbiased information on vehicle performance and infrastructure needs so they can make informed decisions about acquiring and operating ATVs. The ATVs currently in testing include vehicles that burn gaseous hydrogen (H2) fuel and hydrogen/CNG (H/CNG) blended fuels in internal combustion engines (ICE), and hybrid electric (HEV), urban electric, and neighborhood electric vehicles. The AVTA is part of DOE's FreedomCAR and Vehicle Technologies Program.

James Francfort

2004-06-01T23:59:59.000Z

485

Advanced Separation Consortium  

SciTech Connect (OSTI)

The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

NONE

2006-01-01T23:59:59.000Z

486

Soft X-Ray Spectroscopic Study of Dense Strontium-Doped Lanthanum Manganite Cathodes for Solid Oxide Fuel Cell Applications  

SciTech Connect (OSTI)

The modification of the Mn charge-state, chemical composition and electronic structure of La0.8Sr0.2MnO3 (LSMO) cathodes for solid oxide fuel cell (SOFC) applications remains an area of interest, due to the poorly understood enhanced catalytic activity (often referred to as the "burn-in" phenomenon) observed after many hours of operation. Using a combination of core-level X-ray photoemission spectroscopy (XPS), X-ray emission/absorption spectroscopy (XES/XAS), resonant inelastic X-ray scattering (RIXS) and resonant photoemission spectroscopy (RPES), we have monitored the evolution of these properties in LSMO at various stages of fabrication and operation. By rapidly quenching and sealing in vacuum, we were able to directly compare the pristine (as-fabricated) LSMO with both "heat-treated" (800°C in air, and no bias) and "burnt-in" (800°C in air, -1 V bias) LSMO cathodes i.e. before and after the activation observed in our electrochemical impendence spectroscopy measurements. Comparison between the O K-edge XAS/XES and Mn L3,2-edge XAS of pristine and “burnt-in” LSMO cathodes revealed a severe change in the oxygen environment along with a reduced Mn2+ presence near the surface following activation. The change in the oxygen environment is attributed to SrxMnyOz formation, along with possible passive SrO and Mn3O4 species. We present evidence from our “heat-treated” samples that SrxMnyOz regions form at elevated temperatures in air before the application of a cathodic bias. Our core-level XPS, Mn L3,2-edge RIXS and Mn L3 RPES studies of “heat-treated” and pristine LSMO determined that SOFC environments result in La-deficiency (severest near the surface) and stronger Mn4+ contribution, leading to the increased insulating character of the cathode prior to activation. The passive Mn2+ species near the surface and increased hole-doping (>0.6) of the LSMO upon exposure to the operating environment are considered responsible for the initially poor performance of the SOFC. Meanwhile, the improved oxygen reduction following the application of a cathodic bias is considered to be due to enhanced bulk oxygen-ion diffusion resulting from the migration of Mn2+ ions towards the LSMO/electrolyte interface and the SrxMnyOz regions facilitating enhanced bulk oxygen reduction reaction kinetics.

Piper, L.F.J.; Preston, Andrew R.H.; Cho, Sang Wan; DeMasi, Alexander; Chen, Bin; Laverock, J.; Smith, K. E.; Miara, Lincoln J.; Davis, Jacob N.; Basu, Soumendra; Pal, Uday B.; Gopalan, Srikanth; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Matsuura, A. Y.; Glans, P.A.; Guo, Jianzhong

2010-12-02T23:59:59.000Z

487

Advanced Photon Source Upgrade Project  

ScienceCinema (OSTI)

Upgrade to Advanced Photon Source announced by Department Of Energy. Read more: http://go.usa.gov/ivZ

Mitchell, John; Gibson, Murray; Young, Linda; Joachimiak, Andrzej

2013-04-19T23:59:59.000Z

488

Advanced Polymer Processing Facility  

SciTech Connect (OSTI)

Some conclusions of this presentation are: (1) Radiation-assisted nanotechnology applications will continue to grow; (2) The APPF will provide a unique focus for radiolytic processing of nanomaterials in support of DOE-DP, other DOE and advanced manufacturing initiatives; (3) {gamma}, X-ray, e-beam and ion beam processing will increasingly be applied for 'green' manufacturing of nanomaterials and nanocomposites; and (4) Biomedical science and engineering may ultimately be the biggest application area for radiation-assisted nanotechnology development.

Muenchausen, Ross E. [Los Alamos National Laboratory

2012-07-25T23:59:59.000Z

489

ADVANCED CHEMISTRY BASINS MODEL  

SciTech Connect (OSTI)

The advanced Chemistry Basin Model project has been operative for 48 months. During this period, about half the project tasks are on projected schedule. On average the project is somewhat behind schedule (90%). Unanticipated issues are causing model integration to take longer then scheduled, delaying final debugging and manual development. It is anticipated that a short extension will be required to fulfill all contract obligations.

William Goddard III; Lawrence Cathles III; Mario Blanco; Paul Manhardt; Peter Meulbroek; Yongchun Tang

2004-05-01T23:59:59.000Z

490

Advanced Materials Manufacturing | ORNL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout the BuildingInnovation Portal Advanced Material

491

Advanced Microturbine Systems  

SciTech Connect (OSTI)

Dept. of Energy (DOE) Cooperative Agreement DE-FC02-00-CH11061 was originally awarded to Honeywell International, Inc. â?? Honeywell Power Systems Inc. (HPSI) division located in Albuquerque, NM in October 2000 to conduct a program titled Advanced Microturbine Systems (AMS). The DOE Advanced Microturbines Systems Program was originally proposed as a five-year program to design and develop a high efficiency, low emissions, durable microturbine system. The period of performance was to be October 2000 through September 2005. Program efforts were underway, when one year into the program Honeywell sold the intellectual property of Honeywell Power Systems Inc. and HPSI ceased business operations. Honeywell made an internal decision to restructure the existing program due to the HPSI shutdown and submitted a formal request to DOE on September 24, 2001 to transfer the Cooperative Agreement to Honeywell Engines, Systems and Services (HES&S) in Phoenix, AZ in order to continue to offer support for DOE's Advanced Microturbine Program. Work continued on the descoped program under Cooperative Agreement No. DE-FC26-00-CH11061 and has been completed.

None

2005-12-31T23:59:59.000Z

492

Advanced Technology Vehicle Testing  

SciTech Connect (OSTI)

The light-duty vehicle transportation sector in the United States depends heavily on imported petroleum as a transportation fuel. The Department of Energy’s Advanced Vehicle Testing Activity (AVTA) is testing advanced technology vehicles to help reduce this dependency, which would contribute to the economic stability and homeland security of the United States. These advanced technology test vehicles include internal combustion engine vehicles operating on 100% hydrogen (H2) and H2CNG (compressed natural gas) blended fuels, hybrid electric vehicles, neighborhood electric vehicles, urban electric vehicles, and electric ground support vehicles. The AVTA tests and evaluates these vehicles with closed track and dynamometer testing methods (baseline performance testing) and accelerated reliability testing methods (accumulating lifecycle vehicle miles and operational knowledge within 1 to 1.5 years), and in normal fleet environments. The Arizona Public Service Alternative Fuel Pilot Plant and H2-fueled vehicles are demonstrating the feasibility of using H2 as a transportation fuel. Hybrid, neighborhood, and urban electric test vehicles are demonstrating successful applications of electric drive vehicles in various fleet missions. The AVTA is also developing electric ground support equipment (GSE) test procedures, and GSE testing will start during the fall of 2003. All of these activities are intended to support U.S. energy independence. The Idaho National Engineering and Environmental Laboratory manages these activities for the AVTA.

James Francfort

2003-11-01T23:59:59.000Z

493

Advanced Energy Design Guides | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Advanced Energy Design Guides Advanced Energy Design Guides EERE Building Technologies Program - This fact sheet discusses the Advanced Energy Design Guides (AEDGs) and how they...

494

Development of the ANL plant dynamics code and control strategies for the supercritical carbon dioxide Brayton cycle and code validation with data from the Sandia small-scale supercritical carbon dioxide Brayton cycle test loop.  

SciTech Connect (OSTI)

Significant progress has been made in the ongoing development of the Argonne National Laboratory (ANL) Plant Dynamics Code (PDC), the ongoing investigation and development of control strategies, and the analysis of system transient behavior for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycles. Several code modifications have been introduced during FY2011 to extend the range of applicability of the PDC and to improve its calculational stability and speed. A new and innovative approach was developed to couple the Plant Dynamics Code for S-CO{sub 2} cycle calculations with SAS4A/SASSYS-1 Liquid Metal Reactor Code System calculations for the transient system level behavior on the reactor side of a Sodium-Cooled Fast Reactor (SFR) or Lead-Cooled Fast Reactor (LFR). The new code system allows use of the full capabilities of both codes such that whole-plant transients can now be simulated without additional user interaction. Several other code modifications, including the introduction of compressor surge control, a new approach for determining the solution time step for efficient computational speed, an updated treatment of S-CO{sub 2} cycle flow mergers and splits, a modified enthalpy equation to improve the treatment of negative flow, and a revised solution of the reactor heat exchanger (RHX) equations coupling the S-CO{sub 2} cycle to the reactor, were introduced to the PDC in FY2011. All of these modifications have improved the code computational stability and computational speed, while not significantly affecting the results of transient calculations. The improved PDC was used to continue the investigation of S-CO{sub 2} cycle control and transient behavior. The coupled PDC-SAS4A/SASSYS-1 code capability was used to study the dynamic characteristics of a S-CO{sub 2} cycle coupled to a SFR plant. Cycle control was investigated in terms of the ability of the cycle to respond to a linear reduction in the electrical grid demand from 100% to 0% at a rate of 5%/minute. It was determined that utilization of turbine throttling control below 50% load improves the cycle efficiency significantly. Consequently, the cycle control strategy has been updated to include turbine throttle valve control. The new control strategy still relies on inventory control in the 50%-90% load range and turbine bypass for fine and fast generator output adjustments, but it now also includes turbine throttling control in the 0%-50% load range. In an attempt to investigate the feasibility of using the S-CO{sub 2} cycle for normal decay heat removal from the reactor, the cycle control study was extended beyond the investigation of normal load following. It was shown that such operation is possible with the extension of the inventory and the turbine throttling controls. However, the cycle operation in this range is calculated to be so inefficient that energy would need to be supplied from the electrical grid assuming that the generator could be capable of being operated in a motoring mode with an input electrical energy from the grid having a magnitude of about 20% of the nominal plant output electrical power level in order to maintain circulation of the CO{sub 2} in the cycle. The work on investigation of cycle operation at low power level will be continued in the future. In addition to the cycle control study, the coupled PDC-SAS4A/SASSYS-1 code system was also used to simulate thermal transients in the sodium-to-CO{sub 2} heat exchanger. Several possible conditions with the potential to introduce significant changes to the heat exchanger temperatures were identified and simulated. The conditions range from reactor scram and primary sodium pump failure or intermediate sodium pump failure on the reactor side to pipe breaks and valve malfunctions on the S-CO{sub 2} side. It was found that the maximum possible rate of the heat exchanger wall temperature change for the particular heat exchanger design assumed is limited to {+-}7 C/s for less than 10 seconds. Modeling in the Plant Dynamics Code has been compared with available data from the Sandia Natio

Moisseytsev, A.; Sienicki, J. J. (Nuclear Engineering Division)

2011-11-07T23:59:59.000Z

495

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells. I. Cross Validation of Polarization Measurements by Impedance Spectroscopy and Current-Potential Sweep  

SciTech Connect (OSTI)

The aim of this paper is to address three issues in solid oxide fuel cells: (1) cross-validation of the polarization of a single cell measured using both dc and ac approaches, (2) the precise determination of the total areal specific resistance (ASR), and (3) understanding cathode polarization with LSCF cathodes. The ASR of a solid oxide fuel cell is a dynamic property, meaning that it changes with current density. The ASR measured using ac impedance spectroscopy (low frequency interception with real Z´ axis of ac impedance spectrum) matches with that measured from a dc IV sweep (the tangent of dc i-V curve). Due to the dynamic nature of ASR, we found that an ac impedance spectrum measured under open circuit voltage or on a half cell may not represent cathode performance under real operating conditions, particularly at high current density. In this work, the electrode polarization was governed by the cathode activation polarization; the anode contribution was negligible.

Zhou, Xiao Dong; Pederson, Larry R.; Templeton, Jared W.; Stevenson, Jeffry W.

2009-12-09T23:59:59.000Z

496

Recovery of yttrium from fluorescent powder of cathode ray tube, CRT: Zn removal by sulphide precipitation  

SciTech Connect (OSTI)

Highlights: • Treatment of fluorescent powder of CRT waste. • Factorial experimental designs to study acid leaching of fluorescent powder and the purification of leach liquors. • Recover of yttrium by precipitation using oxalic acid. • Suitable flowsheet to recover yttrium from fluorescent powder. - Abstract: This work is focused on the recovery of yttrium and zinc from fluorescent powder of cathode ray tube (CRT). Metals are extracted by sulphuric acid in the presence of hydrogen peroxide. Leaching tests are carried out according to a 2{sup 2} full factorial plan and the highest extraction yields for yttrium and zinc equal to 100% are observed under the following conditions: 3 M of sulphuric acid, 10% v/v of H{sub 2}O{sub 2} concentrated solution at 30% v/v, 10% w/w pulp density, 70 °C and 3 h of reaction. Two series of precipitation tests for zinc are carried out: a 2{sup 2} full factorial design and a completely randomized factorial design. In these series the factors investigated are pH of solution during the precipitation and the amount of sodium sulphide added to precipitate zinc sulphide. The data of these tests are used to describe two empirical mathematical models for zinc and yttrium precipitation yields by regression analysis. The highest precipitation yields for zinc are obtained under the following conditions: pH equal to 2–2.5% and 10–12% v/v of Na{sub 2}S concentrated solution at 10% w/v. In these conditions the coprecipitation of yttrium is of 15–20%. Finally further yttrium precipitation experiments by oxalic acid on the residual solutions, after removing of zinc, show that yttrium could be recovered and calcined to obtain the final product as yttrium oxide. The achieved results allow to propose a CRT recycling process based on leaching of fluorescent powder from cathode ray tube and recovery of yttrium oxide after removing of zinc by precipitation. The final recovery of yttrium is 75–80%.

Innocenzi, Valentina, E-mail: valentina.innocenzi1@univaq.it [Department of Industrial Engineering and Information and Economy, University of L’Aquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 L’Aquila (Italy); De Michelis, Ida; Ferella, Francesco [Department of Industrial Engineering and Information and Economy, University of L’Aquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 L’Aquila (Italy); Beolchini, Francesca [Department of Marine Sciences, Polytechnic Institute of Marche, Via Brecce Bianche, 60131 Ancona (Italy); Kopacek, Bernd [SAT, Austrian Society for Systems Engineering and Automation, Gurkasse 43/2, A-1140 Vienna (Austria); Vegliň, Francesco [Department of Industrial Engineering and Information and Economy, University of L’Aquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 L’Aquila (Italy)

2013-11-15T23:59:59.000Z