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1

Advanced Cathode Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Research 1 HFCIT Program Kick-off Meeting, Arlington, VA, February 13-14, 2007 Program Kick-off Meeting Arlington, Virginia, February 13-14, 2007 Advanced Cathode...

2

The Linac Injector For The ANL 7 Ge V Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Injector For The ANL 7 Ge V Injector For The ANL 7 Ge V Advanced Photon Source A. Nassiri, W. Wesolowski, and G. Mavrogenes Argonne National Laboratory Submitted to the 1990 LINAC Conferece Albuquerque, New Mexico LS-154 9/28/90 TEE LINAC INJECTOR FOR TEE ANL 7 G<.iJ,V ADVANCED PHOTON SOORCE* A. Nassiri, W. Wesolowski, and G. Mavrogenes Argonne National Laboratory 9700 South Cass Avenue Argonne, IL 60439 USA Abstract The Argonne Advanced Photon Source (APS) linac system consists of a 200 MeV electron linac, a positron converter, and a 450 MeV positron linac. Design parameters and computer simulations of the two linac systems are presented. Introduction The Argonne Advanced Photon Source is a 7 GeV synchrotron X-Ray facility. The APS machine parameters have been described.

3

Unique Carbon-Coated Cathodes Improve Electrical Conductivity (ANL-IN-09-043)  

Scientists at Argonne National Laboratory have developed a coating process for cathodes that improves their electrical conductivity. This procedure, which uses carbon precursors, has proved superior to conventional methods that involve high ...

4

ANL's electric vehicle battery activities for USABC. [US Advanced Battery Consortium (USABC)  

DOE Green Energy (OSTI)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides advanced battery R D; technology transfer to industry; technical analyses, assessments, modeling, and databases; and independent testing and post-test analyses of advanced batteries. These capabilities and services are being offered to the US Advanced Battery Consortium (USABC) and Cooperative Research and Development Agreements (CRADA) are being negotiated for USABC-sponsored work at ANL. A small portion of DOE's cost share for USABC projects has been provided to ANL to continue R D and testing activities on key technologies that were previously supported directly by DOE. This report summarizes progress on these USABC projects during the period of April I through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Lithium/Sulfide Batteries; 2.0 Nickel/Metal Hydride Support 3.0 EV Battery Performance and Life Evaluation.

Not Available

1992-01-01T23:59:59.000Z

5

ANL's electric vehicle battery activities for USABC. [US Advanced Battery Consortium (USABC)  

SciTech Connect

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides advanced battery R D; technology transfer to industry; technical analyses, assessments, modeling, and databases; and independent testing and post-test analyses of advanced batteries. These capabilities and services are being offered to the US Advanced Battery Consortium (USABC) and Cooperative Research and Development Agreements (CRADA) are being negotiated for USABC-sponsored work at ANL. A small portion of DOE's cost share for USABC projects has been provided to ANL to continue R D and testing activities on key technologies that were previously supported directly by DOE. This report summarizes progress on these USABC projects during the period of April I through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Lithium/Sulfide Batteries; 2.0 Nickel/Metal Hydride Support 3.0 EV Battery Performance and Life Evaluation.

1992-01-01T23:59:59.000Z

6

High Temperature Membrane & Advanced Cathode Catalyst Development  

DOE Green Energy (OSTI)

Current project consisted of three main phases and eighteen milestones. Short description of each phase is given below. Table 1 lists program milestones. Phase 1--High Temperature Membrane and Advanced Catalyst Development. New polymers and advanced cathode catalysts were synthesized. The membranes and the catalysts were characterized and compared against specifications that are based on DOE program requirements. The best-in-class membranes and catalysts were downselected for phase 2. Phase 2--Catalyst Coated Membrane (CCM) Fabrication and Testing. Laboratory scale catalyst coated membranes (CCMs) were fabricated and tested using the down-selected membranes and catalysts. The catalysts and high temperature membrane CCMs were tested and optimized. Phase 3--Multi-cell stack fabrication. Full-size CCMs with the down-selected and optimized high temperature membrane and catalyst were fabricated. The catalyst membrane assemblies were tested in full size cells and multi-cell stack.

Protsailo, Lesia

2006-04-20T23:59:59.000Z

7

ANL/APS/TB-44, Guidelines for Beamline and Front-End Radiation Shielding Design at the Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

APS/TB-44 Rev. 4 APS/TB-44 Rev. 4 Guidelines for Beamline and Front-End Radiation Shielding Design at the Advanced Photon Source Revision 4 Advanced Photon Source About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology programs, see www.anl.gov. Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Office of Scientific and Technical Information

8

Advanced Cathode Catalysts and Supports for PEM Fuel Cells -...  

NLE Websites -- All DOE Office Websites (Extended Search)

Dahn, David Stevens) * Argonne National Laboratory (ANL), Argonne, IL (V. Stamenkovic, Dennis van der Vliet, Nenad Markovic) * Jet Propulsion Laboratory (JPL), Pasadena, CA...

9

Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Catalysts and Cathode Catalysts and Supports for PEM Fuel Cells DE-FG36-07GO17007 Mark K. Debe 3M Company Feb. 13, 2007 2007 DOE HFCIT Kick-off Meeting This presentation does not contain any proprietary or confidential information Overview Advanced Cathode Catalysts and Supports for PEM FC's - 2007 DOE HFCIT Kick-off, Feb. 13-14, 2007 2 3 Barriers A. Electrode and MEA Durability B. Stack Material & Mfg Cost C. Electrode and MEA Performance DOE Technical Targets Electrocatalyst (2010, 2015) * Durability w/cycling: hrs < 80 o C - (5000, 5000) > 80 o C - (2000, 5000) * Cost: $/kW (5,4) * Mass activity: A/mg ( 0.44, 0.44) * PGM Total, g/ kW rated: (0.3, 0.2) MEA (2010, 2015) * Cost: $/kW (10,5) * Performance: W/cm 2 at Rated Pwr. (1,1) ; 0.8V (0.25, 0.25) Budget * Total Project funding $10.43MM

10

ANL/APS/TB-16 ADVANCED PHOTON SOURCE ACCELERATOR ULTRAHIGH VACUUM GUIDE  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 ADVANCED PHOTON SOURCE ACCELERATOR ULTRAHIGH VACUUM GUIDE Chian Liu and John Noonan CONTENTS 1. Ultrahigh Vacuum Overview ............................................................................... 1 1.1 Vacuum ..................................................................................................... 1 1.2 Sources of Residual Gas ........................................................................... 2 1.3 Material Selections in Ultrahigh Vacuum ................................................. 9 1.4 Pumps and Pumping Processes ................................................................. 11 1.5 Common Sense in Ultrahigh Vacuum Related Work ................................ 15 1.6 Vacuum Safety Issues ...............................................................................

11

ANL/APS/LS-309 Design Calculations for the Advanced Photon Source Safety Shutters P. K. Job, Advanced Photon Source  

E-Print Network (OSTI)

A safety shutter at the Advanced Photon Source (APS) is a remotely actuated device that prevents a photon beam from traveling down a beamline into an experimental enclosure. All APS safety shutters are designed to be redundant. When the shutter is closed, two shielding blocks are positioned to stop bremsstrahlung and the synchrotron

B. J. Micklich; Intense Pulsed; Neutron Source

2005-01-01T23:59:59.000Z

12

Advanced Measurement and Modeling Techniques for Improved SOFC Cathodes  

DOE Green Energy (OSTI)

The goal of this project was to develop an improved understanding of factors governing performance and degradation of mixed-conducting SOFC cathodes. Two new diagnostic tools were developed to help achieve this goal: (1) microelectrode half-cells for improved isolation of cathode impedance on thin electrolytes, and (2) nonlinear electrochemical impedance spectroscopy (NLEIS), a variant of traditional impedance that allows workers to probe nonlinear rates as a function of frequency. After reporting on the development and efficacy of these tools, this document reports on the use of these and other tools to better understand performance and degradation of cathodes based on the mixed conductor La{sub 1-x}Sr{sub x}CoO{sub 3-{delta}} (LSC) on gadolinia or samaria-doped ceria (GDC or SDC). We describe the use of NLEIS to measure O{sub 2} exchange on thin-film LSC electrodes, and show that O{sub 2} exchange is most likely governed by dissociative adsorption. We also describe parametric studies of porous LSC electrodes using impedance and NLEIS. Our results suggest that O{sub 2} exchange and ion transport co-limit performance under most relevant conditions, but it is O{sub 2} exchange that is most sensitive to processing, and subject to the greatest degradation and sample-to-sample variation. We recommend further work that focuses on electrodes of well-defined or characterized geometry, and probes the details of surface structure, composition, and impurities. Parallel work on primarily electronic conductors (LSM) would also be of benefit to developers, and to improved understanding of surface vs. bulk diffusion.

Stuart Adler; L. Dunyushkina; S. Huff; Y. Lu; J. Wilson

2006-12-31T23:59:59.000Z

13

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

SciTech Connect

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

14

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

DOE Green Energy (OSTI)

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

15

APS, CNM, ANL to Receive $3M for Fuel Cell Research  

NLE Websites -- All DOE Office Websites (Extended Search)

APS, CNM, ANL to Receive $3M for Fuel Cell Research APS, CNM, ANL to Receive $3M for Fuel Cell Research The funding, from the U.S. Department of Energy's Office of Basic Energy Sciences, will be used to study the molecular basis of catalysis, with a particular interest in the oxygen reduction reaction in fuel cells. "We are looking to understand the behavior of oxygen in the low-temperature fuel cell cathodes," said Hoydoo You, leader of the group project. "The project builds on Argonne's scientific strengths, bringing collaboration between physicists and chemists, between theorists and experimentalists." The high-intensity X-rays from the Advanced Photon Source and nanoscale science at the Center for Nanoscale Materials are key enabling resources. The project includes researchers from Argonne's Materials Science,

16

Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells  

SciTech Connect

During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

2001-11-05T23:59:59.000Z

17

ANL-678A  

NLE Websites -- All DOE Office Websites (Extended Search)

Division: Division: Equipment Name: Multiple Single Manufacturer: Model Number: Building Room Serial Number: ANL Property Number: Label Number: Indoor Use Only Damp/Wet Locations Hazardous/Classified Locations This equipment is approved for installation or use at ANL. This equipment is rejected for use at ANL. (See comments above) Inspection Date: Inspector (Name): Inspector (Signed) Reputable Manufacturer Unlisted Electrical Equipment Approval Form For use at Argonne National Laboratory Use the following factors when evaluating equipment [NEC 110-3]. Unlisted equipment that is determined to be safe to operate will have a tracking sticker attached for identification. Equipment that does not pass this evaluation will have a REJECTED sticker attached. NOTE: APPROVED EQUIPMENT SHALL BE INSTALLED AND USED IN ACCORDANCE

18

MCFC component development at ANL.  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathode and electrolyte components for the molten carbonate fuel cell (MCFC). Working in support of the MCFC developers, the goal of this effort is to extend the life of the MCFC cell and to improve its performance.

Bloom, I.

1998-09-15T23:59:59.000Z

19

ANL-678A  

NLE Websites -- All DOE Office Websites (Extended Search)

Label Number: Label Number: Indoor Use Only Damp/Wet Locations Hazardous/Classified Locations This equipment is approved for installation or use at ANL. This equipment is rejected for use at ANL. (See comments above) Inspection Date: Inspector (Name): Inspector (Signed) Facility Electrical Equipment Approval Form For use at Argonne National Laboratory Use the following factors when evaluating equipment [NEC 110-3]. Unlisted equipment that is determined to be safe to operate will have a tracking sticker attached for identification. Equipment that does not pass this evaluation will have a REJECTED sticker attached. NOTE: APPROVED EQUIPMENT SHALL BE INSTALLED AND USED IN ACCORDANCE WITH THE INSTRUCTIONS PROVIDED BY THE DESIGNER/BUILDER. 1. Suitability for installation and use in conformity with the provisions of the NEC, including properly

20

Assessment of Electrical, Efficiency, and Photometric Performance of Advanced Lighting Sources: Dimmable Advanced Lighting Technolog ies -- Electronic (Hot and Cold Cathode) Compact Fluorescent Lamps and Ballasts  

Science Conference Proceedings (OSTI)

This EPRI Technical Update (EPRI report 1018477) is one of four in a series that addresses basic dimming performance of advanced lighting sourceselectronic (hot and cold cathode) compact fluorescent lamps and ballasts Chapter 1 discusses basic lighting control, the importance of considering power quality in lighting control, lighting control methods and parameters, and the advantages and future of lighting control. Chapter 2 addresses in more depth dimming methods used in advanced lighting sources and co...

2008-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

July2006ANL40.ppt  

NLE Websites -- All DOE Office Websites (Extended Search)

Forces K. McElroy et al., cond-mat0404005 Nature 430, 1001 ('04) Checkerboard (Tweed) Stripes STS Imaging of HTC Cuprates July2006ANL-7 High Sensitivities of Transition Metal...

22

www.sbc.anl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

sbc.anl.gov The Structural Biology Center enables the atomic-scale study of macromolecular systems using very small crystal samples. It also offers the most efficient data...

23

ANL`s electric vehicle battery activities for USABC. Progress report, April--September 1992  

SciTech Connect

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides advanced battery R&D; technology transfer to industry; technical analyses, assessments, modeling, and databases; and independent testing and post-test analyses of advanced batteries. These capabilities and services are being offered to the US Advanced Battery Consortium (USABC) and Cooperative Research and Development Agreements (CRADA) are being negotiated for USABC-sponsored work at ANL. A small portion of DOE`s cost share for USABC projects has been provided to ANL to continue R&D and testing activities on key technologies that were previously supported directly by DOE. This report summarizes progress on these USABC projects during the period of April I through September 30, 1992. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Lithium/Sulfide Batteries; 2.0 Nickel/Metal Hydride Support 3.0 EV Battery Performance and Life Evaluation.

1992-12-31T23:59:59.000Z

24

Advanced Lithium Battery Cathodes Using Dispersed Carbon Fibers as the Current Collector  

SciTech Connect

To fabricate LiFePO4 battery cathodes, highly conductive carbon fibers of 10-20 m in diameter have been used to replace a conventional aluminum (Al) foil current collector. This disperses the current collector throughout the cathode sheet and increases the contact area with the LiFePO4 (LFP) particles. In addition, the usual organic binder plus carbon-black can be replaced by a high temperature binder of <5 weight % carbonized petroleum pitch (P-pitch). Together these replacements increase the specific energy density and energy per unit area of the electrode. Details of the coating procedure, characterization and approach for maximizing the energy density are discussed. In a side-by-side comparison with conventional cathodes sheets of LFP on Al foil, the carbon fiber composite cathodes have a longer cycle life, higher thermal stability, and high capacity utilization with little sacrifice of the rate performance.

Martha, Surendra K [ORNL; Kiggans, Jim [ORNL; Nanda, Jagjit [ORNL; Dudney, Nancy J [ORNL

2011-01-01T23:59:59.000Z

25

Argonne TDC: Quallion - ANL  

... Department of Energy's FreedomCAR and Vehicle Technologies Office, aimed at advanced batteries for hybrid electric vehicles. ... and safety properties. "This ...

26

ANL News 1998  

NLE Websites -- All DOE Office Websites (Extended Search)

has included 6.7 million in the state's fiscal 1999 budget for an innovative public-private project to encourage small companies to use Argonne's Advanced Photon Source...

27

ANL News 1999  

NLE Websites -- All DOE Office Websites (Extended Search)

link (Mar. 22) X-ray analysis of hair could become an early-warning test for breast cancer, according to research done at Argonne's Advanced Photon Source (APS). Physicist...

28

ANL News 2002  

NLE Websites -- All DOE Office Websites (Extended Search)

2 Articles 2 Articles Argonne News is the Argonne weekly employee newsletter. This page contains Argonne News articles that focus on the APS. Student is youngest APS poster award winner (Jan. 28) Seventeen-year-old Wenyi Cai was the youngest winner ever of a student poster presentation award at the 11th User Meeting at the Advanced Photon Source (APS). Argonne promoteslocal economic opportunity (Feb. 11) Hi-tech companies are increasingly turning to Argonne's research facilities to keep their products on top of the market. New APS beamlines target protein structure (Mar. 25) An agreement to build new biological research capabilities at Argonne's Advanced Photon Source has been signed by Argonne officials and the directors of two institutes of the National Institute of Health.

29

Final Report - Advanced Cathode Catalysts and Supports for PEM Fuel Cells  

Science Conference Proceedings (OSTI)

The principal objectives of the program were development of a durable, low cost, high performance cathode electrode (catalyst and support), that is fully integrated into a fuel cell membrane electrode assembly with gas diffusion media, fabricated by high volume capable processes, and is able to meet or exceed the 2015 DOE targets. Work completed in this contract was an extension of the developments under three preceding cooperative agreements/grants Nos. DE-FC-02-97EE50473, DE-FC-99EE50582 and DE-FC36- 02AL67621 which investigated catalyzed membrane electrode assemblies for PEM fuel cells based on a fundamentally new, nanostructured thin film catalyst and support system, and demonstrated the feasibility for high volume manufacturability.

Mark Debe

2012-09-28T23:59:59.000Z

30

Business Case Slide 34: Regulatory Constraints Analysis (ANL...  

NLE Websites -- All DOE Office Websites (Extended Search)

Regulatory Constraints Analysis (ANL) - Program Focus Program focus ANL will be preparing a risk analysis and regulatory plan for a specific case: use of DU in catalysts Enhance...

31

ANL/APS/TB-3 Undulator A Characteristics and Specifications  

NLE Websites -- All DOE Office Websites (Extended Search)

ANL/APS/TB-3 ANL/APS/TB-3 Undulator A Characteristics and Specifications by B. Lai, A. Khounsary,R. Savoy, L. Moog, and E. Gluskin February 1993 Advanced Photon Source . & Argonne National Laboratory, Argonne, Illinois 60439 o operated by The University of Chicago for the United States Department of Energy under Contract W-31-1 09-Eng-38 '"~ Argonne National Laboratory, with facilties in the states of Ilinois and Idaho, is owned by the United States government, and operated by The University of Chicago under the provisions of a contract with the Department of Energy. . DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any waranty, express

32

ANL Workshop on the EoS in Astrophysics - 2008  

NLE Websites -- All DOE Office Websites (Extended Search)

Equation of State at Nonzero Density and Temperature, and its Equation of State at Nonzero Density and Temperature, and its Application in Astrophysics ANL Workshop, 25-29 August 2008, TheoryGroup in the ANL Physics Division JINA News Location Program 1st Circular Restaurants Links Contact News 08/30/08 - Last news on this workshop: It seems like everybody made it home safely. We take this opportunity to thank all our speakers and participants for their interesting and instructive contributions to this workshop. Thank you! 08/26/08 - Our workshop dinner will be held tomorrow, Wednesday 08/27 at the Saffron Restaurant on 6020 Cass Ave Westmont, IL 60559 at 7pm. Please gather at about 6:30pm at the entrance to the Physics Division's building to ensure everyone will be able to get to the restaurant. I'll collect the fee in advance.

33

ANL-FF-262i  

Office of Legacy Management (LM)

, v-W&, , v-W&, ANL-FF-262i This document consists of 1 page, No.>f 7 copies. SeriesA. -,-- 22 February 1952 TO; B. Blumenthal Metallurgy From: H, Luetzow Metallurgy Re: HIGH PURITY CRANIUM TO BE ROLLID TO FOIL M r, E. Creutz of the Carnegie Institute of Technology has requested ten square inches of uranium foil 0.1 mil to 1 nil thick., The possibility of pro- ducing foil of this thickness from our foundry's graphite-melted uranium is remote because of the metalIs high carbon content. High purity metal isto be considered a possible solution of many of the difficulties experienced in producing foil from relatively high carbon uranium. Therefore, a sample of high purity uranium of sufficient size for the project outlined above is requested. CLASSIFICATION CPNCELLED

34

ANL-85-51 ANL-85-51 FLOW-INDUCED VIBRATION OF CIRCULAR CYLINDRICAL STRUCTURES  

Office of Scientific and Technical Information (OSTI)

ANL-85-51 ANL-85-51 ANL-85-51 ANL-85-51 FLOW-INDUCED VIBRATION OF CIRCULAR CYLINDRICAL STRUCTURES by ShoeiSheng Chen BASE TECHNOLOGY ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY OF CHICAGO for the U. S. DEPARTMENT OF ENERGY under Contract W-31-109-Eng-38 A major purpose of the Techni- cal information Center is to provide the broadest dissemination possi- ble of information contained in DOE's Research and Development Reports to business, industry, the academic community, and federal, state and local governments. Although a small portion of this report is not reproducible, it is being made available to expedite the availability of information on the research discussed herein. Distribution Category: LMFBR-Components: Base Technology (UC-79k) ANL-85-51 ANL-85-51

35

Argonne TDC: Gregar Extractor - ANL  

The result is the "Gregar extractor" -- a major advance in ... The Gregar Extractor is the winner of a 1999 R&D 100 ... , Office of Science, Basic ...

36

Miniaturized cathodic arc plasma source  

DOE Patents (OSTI)

A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA)

2003-04-15T23:59:59.000Z

37

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries  

E-Print Network (OSTI)

Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION Rechargeable lithium-ion batteries have been widely used in portable electronics and are promising

Cui, Yi

38

ANL/EAD/TM-9 Derivation  

Office of Legacy Management (LM)

ANL/EAD/TM-9 ANL/EAD/TM-9 Derivation of Uranium Residual Radioactive Material Guidelines for the Former Alba Craft Laboratory Site, Oxford, Ohio _ _ ,_ _., by M. Nimmagadda, E. Faillace, and C. Yu Environmental Assessment Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 January 1994 Work sponsored by United States Department of Energy MASTER CONTENTS NOTATION ......................................................... v SUMMARY ......................................................... 1 1 INTRODUCTION AND BRIEF HISTORY ............................... 3 1.1 Site Description and Setting ...................................... 3 1.2 Site History .................................................. 4 1.3 Derivation of Cleanup Guidelines .................................. 6 2 SCENARIO DEFINITIONS ..........................................

39

Spent fuel treatment at ANL-West  

SciTech Connect

At Argonne National Laboratory-West (ANL-West) there are several thousand kilograms of metallic spent nuclear fuel containing bond sodium. This fuel will be treated in the Fuel Cycle Facility at ANL-West to produce stable waste forms for storage and disposal. The treatment operations will employ a pyrochemical process that also has applications for treating most of the fuel types within the Department of Energy complex. The treatment equipment is in its last stage of readiness, and operations will begin in the Fall of 1994.

Goff, K.M.; Benedict, R.W.; Levinskas, D.

1994-12-31T23:59:59.000Z

40

Software: SE2-ANL - Nuclear Engineering Division (Argonne)  

NLE Websites -- All DOE Office Websites (Extended Search)

OutLoud on Nuclear Energy Argonne Energy Showcase 2012 Software SE2-ANL (Thermal-Hydraulic Codes) Bookmark and Share Standard Code Description SE2-ANL is a modified version of...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

ANL/APS/TB-11  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 . Wiggler A Characteristics and Specifications by B. Lai, A. Khounsary, and E. Gluskin February 1993 . Advanced Photon Source .~ Argonne National Laboratory, Argonne, Ilinois 60439 o operated by The University of Chicago for the United States Department of Energy under Contract W-31-1 09-Eng-38 "'--...... Argonne National Laboratory, with facilities in the states of Ilinois and Idaho, is owned by the United States government, and operated by The University of Chicago under the provisions of a contract with the Deparment of Energy. . DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any waranty, express

42

ANL/APS/TB-17  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 1 Undulator A Characteristics and Specifications: Enhanced Capabilities Roger J. Dejus, Barry Lai, Elizabeth R. Moog, and Efim Gluskin Introduction The undulator A for the Advanced Photon Source (APS) is a planar insertion device that will generate high-intensity x-ray radiation in the spectral range 3.2 keV to 45 keV by using the first, third, and fifth harmonics of radiation. The device has been optimized for the APS so that the variation in brilliance is small when tuning from one harmonic energy to the next. This has been achieved by an increase of the magnetic field for a given gap and by allowing a smaller minimum gap when installed in the storage ring. This document describes the modification of the magnetic structure and the enhanced on- axis magnetic fields. The enhanced spectral performance is discussed and illustrated in tuning

43

ANL/APS/TB-2  

NLE Websites -- All DOE Office Websites (Extended Search)

. Use of a Mirror as the First Optical Component for an Undulator Beamline at the APS by W. Yun, A. Khounsary, B. Lai, and E. Gluskin September 1992 . Advanced Photon Source . @ Argonne National Laboratory, Argonne, Illinois 60439 o operated by The University of Chicago for the United States Department of Energy under Contract W-31-1 09-Eng-38 Argonne National Laboratory, with facilities in the states of Ilinois and Idaho, is owned by the United States government, and operated by The University of Chicago under the provisions of a contract with the Deparment of Energy. DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any waranty, express

44

CAT Guide to the ANL CMS system  

NLE Websites -- All DOE Office Websites (Extended Search)

APS CAT Guide to Using the ANL Chemical Management System APS CAT Guide to Using the ANL Chemical Management System (August 30, 2000) The Argonne Chemical Management System (CMS) is a database used to track the ownership and location of primary (original) containers1 of hazardous chemicals. It provides for a current listing of hazardous chemicals to which individuals working at Argonne might be exposed and it provides for automated generation of reports required by the EPA and OSHA. Finally, each inventory entry is linked to the MSDS for the product. Applicability APS CATs should use the Chemical Management System (CMS) as described below: Container Description Barcode & CMS Record Creation Required? Comments Any container received with an Argonne barcode. Yes, label already present. The corresponding CMS record must be updated when the container is permanently moved to a new location, when ownership changes, or when the container is emptied and discarded.

45

CH-ANL Report.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 2.0 STATUS AND RESULTS ..................................................................... 1 3.0 CONCLUSIONS .................................................................................... 5 4.0 RATING ................................................................................................. 5 5.0 OPPORTUNITIES FOR IMPROVEMENT .......................................... 6 APPENDIX A: SUPPLEMENTAL INFORMATION ................................... 7 APPENDIX B: SITE-SPECIFIC FINDINGS ................................................. 8 Abbreviations Used in This Report ANL Argonne National Laboratory CH Offi ce of Science Chicago Offi ce CIC Classifi cation and Information Control DOE U.S. Department of Energy NNSA National Nuclear Security Administration

46

6th ANL/MSU/JINA/INT FRIB Theory Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Home Participants Program & Talks Location Access Lodging Transportation Restaurants Forms 6th ANL/MSU/JINA/INT FRIB Theory Workshop Computational Forefront in Nuclear Theory: Preparing for FRIB Argonne National Laboratory, March 23 - 26, 2010 This workshop will concentrate on advances in theoretical methods for computing properties of nuclei and reactions relevant to the experimental program at FRIB. Although we expect a significant number of talks on methods that require the largest available and planned computers, there will also be talks on new methods that do not require such large machines. Topics quantum Monte Carlo -- no-core shell model -- coupled-cluster method -- unitary correlated-operator method -- shell model -- continuum shell model -- Gamow shell model -- energy density functionals -- cranking -- heavy-ion

47

Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants  

E-Print Network (OSTI)

Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants ANL-AFCI-168 of Nuclear Reactor and Chemical Separation Plants ANL-AFCI-168 by G. Palmiotti, J. Cahalan, P. Pfeiffer, T;2 ANL-AFCI-168 Requirements for Advanced Simulation of Nuclear Reactor and Chemical Separation Plants G

Anitescu, Mihai

48

Business Case Slide 32: Regulatory Constraints Analysis (ANL...  

NLE Websites -- All DOE Office Websites (Extended Search)

Regulatory Constraints Analysis (ANL) - Description Description Enabling activity cross-cutting all potential uses of DU in radiologically unregulated areas Tasks Evaluate...

49

Business Case Slide 33: Regulatory Constraints Analysis (ANL...  

NLE Websites -- All DOE Office Websites (Extended Search)

Previous Slide Next Slide Table of Contents Regulatory Constraints Analysis (ANL) - Status Status Evaluation of current status completed in FY02 All manufacturing of DU products...

50

South Korea-ANL Distributed Energy Resources and Demand Side...  

Open Energy Info (EERE)

Korea-ANL Distributed Energy Resources and Demand Side Management Jump to: navigation, search Name Distributed Energy Resources and Demand Side Management in South Korea Agency...

51

ANL-W EM Report.pmd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5 5 4.0 RATINGS ................................................................................................ 7 APPENDIX A - SUPPLEMENTAL INFORMATION .............................. 9 APPENDIX B - SITE-SPECIFIC FINDINGS ......................................... 11 APPENDIX C - EMERGENCY PLANNING.......................................... 12 APPENDIX D - EMERGENCY RESPONSE .......................................... 21 APPENDIX E - DOE LINE MANAGEMENT OVERSIGHT ................ 28 ANL-W Argonne National Laboratory - West ASO Argonne Site Office ASO-W Argonne Site Office - West BED Building Emergency Director CAT Consequence Assessment Team CFR Code of Federal Regulations CH Chicago Operations Office DOE U.S. Department of Energy DOT Department of Transportation DSA Documented Safety Analysis

52

The ANL electrochemical program for DOE on electric vehicle R D  

DOE Green Energy (OSTI)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

Not Available

1991-01-01T23:59:59.000Z

53

The ANL electric vehicle battery R D program for DOE-EHP  

DOE Green Energy (OSTI)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

Not Available

1990-01-01T23:59:59.000Z

54

The ANL electric vehicle battery R D program for DOE-EHP  

SciTech Connect

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

1990-01-01T23:59:59.000Z

55

Microsoft Word - ANL-INL-EVS24-Dyno_to_fleet_comparison Final 4-16-09.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Correlating Dynamometer Testing to In-Use Fleet Results Correlating Dynamometer Testing to In-Use Fleet Results of Plug-In Hybrid Electric Vehicles Michael Duoba 1 , Richard Carlson 2 , Forrest Jehlik 3 , John Smart 4, Sera White 5 1 Argonne National Laboratory, 9700 South Cass Ave, Argonne, IL 60439, mduoba@anl.gov 2 Argonne National Laboratory, 9700 South Cass Ave, Argonne, IL 60439, fjehlik@anl.gov 3 Argonne National Laboratory, 9700 South Cass Ave, Argonne, IL 60439, rwcarlson@anl.gov 4 Idaho National Laboratory, 2351 N Blvd, Idaho Falls, ID, 83415, john.smart@inl.gov 5 Idaho National Laboratory, 2351 N Blvd, Idaho Falls, ID, 83415, sera.white@inl.gov Abstract The Untied States Department of Energy is engaged in the research, development and deployment of PHEV technology through the "Advanced Vehicle Testing Activity." In this program, data has been

56

Argonne Leadership Computing Facility | www.alcf.anl.gov | info@alcf.anl.gov | (877) 737-8615 Materials Science  

E-Print Network (OSTI)

CONTACT Argonne Leadership Computing Facility | www.alcf.anl.gov | info@alcf.anl.gov | (877) 737 and computational readiness. For more information about ALCC and other programs at the ALCF, visit: http://www.alcf 2012 alcf-alcc_list-0212 ALCC ASCR Leadership Computing Challenge ENERGY U.S. DEPARTMENT OF Argonne

Kemner, Ken

57

ANL/ALCF/ESP-13/16  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 Multiscale Molecular Simulations at the Petascale (Parallelization of Reactive Force Field Model for Blue Gene/Q) ALCF-2 Early Science Program Technical Report Argonne Leadership Computing Facility About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology programs, see www.anl.gov. Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from:

58

High Energy Physics Division, ANL Lattice QCD  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Energy Physics Division, ANL Lattice QCD in extreme environments D. K. Sinclair (HEP, Argonne) J. B. Kogut (Physics, Illinois) D. Toublan (Physics, Illinois) 1 Lattice QCD Quantum chromodynamics(QCD) de- scribes Hadrons and their strong inter- actions. Hadrons consist of quarks held together by gluons. Lattice QCD is QCD on a 4-dimensional (space-time) lattice. Allows numerical simulation of the functional integrals which define this quantum field theory, and non-perturbative QCD calculations. Physics - properties of hadrons (masses, etc.), hadronic matrix elements (HEP), hadronic matter at finite temperature and/or densities (RHIC, early universe, neutron stars). 2 Computational Methods * Functional integral is mapped to the partition function for a classical sys- tem. Molecular-dynamics methods are used to calculate the observables for this classical system.

59

presentation_anl-SHORT-aug09  

NLE Websites -- All DOE Office Websites (Extended Search)

magnetic moments of ps states of nuclei far magnetic moments of ps states of nuclei far from stability Argonne Workshop: Aug. 8-9,2009 Noémie Benczer-Koller Rutgers University I will not talk about everything, namely: Intermediate Coulomb excitation experiments at MSU with the TF technique Recoil in vacuum (RIV) at ORNL, ANL β-NMR, etc... These require more instrumentation than the experiments I would like to start with, as well as complex calibrations although they are a good option for future experiments. ************************************************************ I will mention possible Transient Field (TF) measurements with CARIBU beams. Measurements of magnetic moments of ps states with radioactive beams 2 Motivation : Microscopic structure of individual low-lying states in nuclei far from stability, with TF techniques and Coulomb

60

Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Tomography Interest Group Contact: Robert Winarski, Center for Nanoscale Materials winarski@anl.gov Contact: Francesco De Carlo, Advanced Photon Source decarlo@aps.anl.gov The tomography special interest group of the Advanced Photon Source (APS) at Argonne National Laboratory has been created to promote awareness of the tomography facilities at the APS and to foster communications between the various research groups. Through this group, we believe we can build a strong user community for tomography. The following beamlines have active tomography research programs: 2-BM-B (XOR) http://www.aps.anl.gov/Xray_Science_Division/Xray_Microscopy_and_Imaging/Science_and_Research/Techniques/Tomography/index.html Information about the beamline: http://beam.aps.anl.gov/pls/apsweb/beamline_display_pkg.display_beamline?p_beamline_num_c=31

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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61

Microsoft Word - ANL L2 Report_123111_FINAL.doc  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

year 2012 under the ANL FY12 Work Package Engineering Materials Experimental. This report highlights the results of completed Phase I testing of high-burnup M5 cladding and...

62

Microsoft Word - ANL 2005 ESH - Volume II -FINAL FORMATTED...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

87 ii This page intentionally left blank. iii Acronyms AGHC Alpha-Gamma Hot Cell AGHCF Alpha-Gamma Hot Cell Facility ALARA As Low As Reasonably Achievable ANL...

63

The ANL electric vehicle battery R D program for DOE-EHP. [ANL (Argonne National Laboratory); EHP (Electric and Hybrid Propulsion Division)  

SciTech Connect

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce air pollution and petroleum consumption due to the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, and project management on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of January 1, 1993 through March 31, 1993. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Project Management; 2.0 Sodium/Metal Chloride R D; 3.0 Microreference Electrodes for Lithium/Polymer Batteries.

1993-06-15T23:59:59.000Z

64

The ANL electric vehicle battery R D program for DOE-EHP  

DOE Green Energy (OSTI)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and Coordination; 2.0 Lithium/Sulfide Batteries; 3.0 Advanced Sodium/Beta Batteries; 4.0 Advanced Ambient-Temperature Batteries; 5.0 EV Battery Performance and Life Evaluation.

Not Available

1992-01-01T23:59:59.000Z

65

The ANL electric vehicle battery R D program for DOE-EHP  

SciTech Connect

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and Coordination; 2.0 Lithium/Sulfide Batteries; 3.0 Advanced Sodium/Beta Batteries; 4.0 Advanced Ambient-Temperature Batteries; 5.0 EV Battery Performance and Life Evaluation.

1992-01-01T23:59:59.000Z

66

Evaluating the need for a criticality alarm system at ANL-E  

SciTech Connect

Under the current climate of increasing regulation and decreasing budgets, DOE nuclear facilities are forced to become more efficient in operations aimed at satisfying regulatory requirements. Efficiency necessitates increased cooperation between the regulator (DOE) and facility management, and often a mutually agreeable innovative solution. At Argonne National Laboratory - East (ANL-E), one issue that required such an innovative solution and cooperation between contractor and regulator was the determination of whether the risk associated with an inadvertent criticality event justified the purchase and maintenance of a Criticality Alarm System (CAS) meeting ANSI/ANS-8.3-1986 requirements. According to DOE Order 420.1, the need for a CAS is based on the probability of occurrence of a criticality accident. If the probability is <10{sup {minus}6}/yr (i.e., incredible) as determined by {open_quotes}commonly accepted engineering judgement,{close_quotes} then a CAS is not necessary. Installation of a CAS after such a conclusion would be a conservative decision and an unnecessary expense. This paper discusses the use of {open_quotes}commonly accepted engineering judgement{close_quotes} to show that the probability of an inadvertent criticality at a nonreactor nuclear facility (e.g., the Alpha-Gamma Hot Cell Facility) is <10{sup {minus}6}/yr. and is therefore an incredible event.

Washburn, P. [Department of Energy, Argonne, IL (United States). Chicago Operations Office; Cohen, A. [Argonne National Lab., IL (United States)

1997-08-01T23:59:59.000Z

67

SALT-ANL. Systems Analysis Process Simulation  

Science Conference Proceedings (OSTI)

SALT (Systems Analysis Language Translator), a systems- analysis and process-simulation program for steady-state and dynamic systems, can also be used for optimization and sensitivity studies. SALT employs state-of-the-art numerical techniques including a hybrid steepest-descent/quasi-Newtonian multidimensional nonlinear equation solver, sequential quadratic programming methods for optimization, and multistep integration methods for both stiff and nonstiff systems of differential equations. Based on a preprocessor concept where a `new` system driver can be written for each application, SALT-ANL contains precompiled component models, several flow types, and a number of thermodynamic and transport property routines, including a gas chemical-equilibrium code. It has been applied to the study of open-cycle and liquid-metal magnetohydrodynamic systems, fuel cells, ocean thermal energy conversion, municipal solid-waste processing, fusion, breeder reactors, and geothermal and solar-energy systems. Models available include: combustor, compressor, deaerator, gas-diffuser, fuel-dryer, feedwater-heater, flash-tank, gas-turbine, heater, heat-exchanger, flow-initiator, fuel-flow-initiator, molten-carbonate fuel-cell, liquid-metal diffuser, magnetohydrodynamic-generator, liquid-metal magnetohydrodynamic-generator, liquid-metal nozzle, liquid-metal pipe, flow-mixer, gas-nozzle, phosphoric acid fuel-cell, pump, pipe-calculator, steam-condenser, steam-drum, liquid-gas separator, stack, solid-oxide fuel-cell, flow-splitter, steam-turbine, two-phase diffuser, two-phase mixer, and two-phase nozzle. Input data to the SALT program describe the system configuration for the specific problem to be analyzed and provide instructions defining system constraints, objective functions, parameter sweeps, etc. to generate a PL/I program representing the system problem and performing the various analytic tasks.

Berry, G.F.; Geyer, H.K. [Argonne National Lab., IL (United States)

1992-02-26T23:59:59.000Z

68

Status of ANL out-of-pile investigations of severe accident phenomena for liquid metal reactors  

SciTech Connect

Research addressing LMFBR whole core accidents has been terminated, and there is now emphasis on quantifying reactivity feedbacks, and in particular enhancing negative feedback, so that advanced LMR designs will provide inherently safe operation. The status of recent HCDA-related laboratory research performed at ANL, up to the time that such activities were no longer needed to support CRBR licensing, is described. Included are descriptions of programs addressing sodium channel voiding, fuel sweepout, fuel dispersal and plugging, boiled-up pool, UO/sub 2//sodium FCI, and debris coolability. Descriptions of recent investigations involving the metal fuel/sodium system are also included.

Spencer, B.W.; Marchaterre, J.F.; Anderson, R.P.; Armstrong, D.R.; Baker, L.; Cho, D.H.; Gabor, J.D.; Pedersen, D.R.; Sienicki, J.J.; Stein, R.P.

1986-01-01T23:59:59.000Z

69

The ANL electrochemical program for DOE on electric vehicle R&D. Quarterly progress report, January--March 1991  

DOE Green Energy (OSTI)

This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of January 1 through March 31, 1991. The work is organized into the following six task areas: Project management; battery systems technology; lithium/sulfide batteries; advanced sodium/metal chloride battery; aqueous batteries; and EV Battery performance/life evaluation.

Not Available

1991-12-31T23:59:59.000Z

70

The ANL electric vehicle battery R&D program for DOE-EHP. Quarterly progress report, October--December 1990  

DOE Green Energy (OSTI)

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

Not Available

1990-12-31T23:59:59.000Z

71

RACETRACK AT ANL S. L. Kramer LS-67  

NLE Websites -- All DOE Office Websites (Extended Search)

RACETRACK AT ANL RACETRACK AT ANL S. L. Kramer LS-67 April, 1986 1 LS-67 S. Kramer RACETRACK AT ANL Thanks to the assistance and patience of Albin Wrulich at LBL, the most recent version of the accelerator tracking code RACETRACK is now opera- tional at Argonne on ANLHEP. Access to this program can be obtained by run- ning the program HEP2:[AR.KRAMER.RACETRAC]RACE.EXE. An input file FOROOS and output file FOR006 are all that is required. A sample data file DEMO.DAT (Table I) and an instruction file RACETRACK. GUIDE are included in this directory. This program has been tested in a mode which should agree with PATRICIA-84.9 for the "ideal" CDR lattice. Figure 1 shows the comparison of the dynamic aperture for both programs. The op/p = 0 apertures agree exactly,

72

ANL Wind Power Forecasting and Electricity Markets | Open Energy  

Open Energy Info (EERE)

ANL Wind Power Forecasting and Electricity Markets ANL Wind Power Forecasting and Electricity Markets Jump to: navigation, search Logo: Wind Power Forecasting and Electricity Markets Name Wind Power Forecasting and Electricity Markets Agency/Company /Organization Argonne National Laboratory Partner Institute for Systems and Computer Engineering of Porto (INESC Porto) in Portugal, Midwest Independent System Operator and Horizon Wind Energy LLC, funded by U.S. Department of Energy Sector Energy Focus Area Wind Topics Pathways analysis, Technology characterizations Resource Type Software/modeling tools Website http://www.dis.anl.gov/project References Argonne National Laboratory: Wind Power Forecasting and Electricity Markets[1] Abstract To improve wind power forecasting and its use in power system and electricity market operations Argonne National Laboratory has assembled a team of experts in wind power forecasting, electricity market modeling, wind farm development, and power system operations.

73

ANL/APS/LS-330 March  

NLE Websites -- All DOE Office Websites (Extended Search)

0 March 10, 2012 Explicit formulas for 2nd-order driving terms due to sextupoles and chromatic effects of quadrupoles Chun-xi Wang Advanced Photon Source, Argonne National...

74

THE PLUTONIUM AEROSOL MONITORING PROGRAM AT ANL-IDAHO FACILITIES  

SciTech Connect

The physical and radiation characteristics of plutonium aerosols are reviewed briefly. A number of detecting and sampling devices and techniques are discussed for application to plutonium aerosols under conditions of reactor operations. The monitoring program and the Pu-fueled reactors at ANL-Idaho are described. (D.L.C.)

Stoddart, P.G.

1963-07-01T23:59:59.000Z

75

Waste minimization and pollution prevention initiatives within Argonne National Laboratory-East (ANL-E) boiler house operations  

Science Conference Proceedings (OSTI)

The mission of ANL-E Plant Facility and Services-Utilities and Systems (PFS-US) is to operate and maintain utility services in a cost-effective manner, while utilizing new and innovative methods whenever possible. PFS-US operates an on-site coal burning boiler plant that generates steam for use throughout the Laboratory as a source to heat buildings, as well as for use in research experiments. In the recent past, PFS-US has embarked upon a series of initiatives to improve operating efficiency of boiler house operations. The results of these projects have had the following impacts on boiler house performance and operations: (1) boiler house efficiency and operations have improved, (2) boiler house operating costs have been reduced, (3) specific operating and maintenance costs have been avoided or eliminated, and (4) the amount of waste and pollution generated has been reduced. Through the implementation of these initiatives, over $250,000 of revenue and cost savings have been incurred by ANL-E. In addition, the Laboratory and DOE will benefit annually from revenues, cost savings, and the reduction of environmental liability resulting from these initiatives.

NONE

1996-08-01T23:59:59.000Z

76

ANL-AAI-PUB-2008-004  

NLE Websites -- All DOE Office Websites (Extended Search)

AAI-PUB-2008-004 AAI-PUB-2008-004 March 2008 An X-Ray Free-Electron Laser Oscillator with an Energy Recovery Linac Kwang-Je Kim and Yuri Shvyd'ko Argonne National Laboratory, Advanced Photon Source, 9700 S. Cass Ave, Argonne, IL, 60439 Sven Reiche UCLA, Physics and Astronomy Department, Los Angeles, CA 90095 ABSTRACT We show that a free-electron laser oscillator generating x-rays with a wavelengths of about 1 Å is feasible using ultra-low emittance electron beams of a multi-GeV energy recovery linac, combined with a low-loss crystal cavity. The device will produce x-ray pulses with 109 photons at a repetition rate of 1-100 MHz. The pulses are temporarily and transversely coherent, with an rms bandwidth of about 2 meV, and rms pulse length of about 1 ps.

77

Si-Graphene Anodes (ANL-10-018 and ANL-11-034)  

AV AILABLE FOR LICENSING Production process for low-cost, long-life, high-energy anodes with five times the specific energy. The Invention An advanced ...

78

A. A. Abrikosov Publications at Argonne National Laboratory (ANL)  

NLE Websites -- All DOE Office Websites (Extended Search)

A. A. Abrikosov Publications A. A. Abrikosov Publications Argonne National Laboratory Abrikosov · Resources with Additional Information "The Order Parameter in HTSC"; Abrikosov, A. A.; International Conference on Superconductivity (TICS '95), Hualien, Taiwan; Aug 8-11, 1995 (ANL/MSD/CP-91998) "Some Consequences of the Layered Structure of HTSC"; Abrikosov, A. A.; International Conference on Superconductivity (TICS '95), Hualien, Taiwan; Aug 8-11, 1995; Chin. J. Phys., 34(2-II): 330-39 (ANL/MSD/CP-91922, Apr. 1996) "The Dependance of Delta and Tc on Hopping and the Temperature Variation of {delta} in a Layered Model of HTSC"; Abrikosov, A. A.; Klemm, R. A.; Physica C, 191: 224-36; 1992 "Raman Light Scattering by Electrons in Layered Superconductors"; Abrikosov, A. A.; Physica C, 182: 191-202; 1991

79

The ANL electric vehicle battery R&D program for DOE-EHP. Progress report, October 1991--March 1992  

DOE Green Energy (OSTI)

The Electrochemical Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby. significantly reduce petroleum consumption in the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of October 1, 1991 through March 31, 1992. In this report, the objective, background, technical progress, and status are described for each task. These tasks are structured into the following task areas: 1.0 Project Management and Coordination; 2.0 Lithium/Sulfide Batteries; 3.0 Advanced Sodium/Beta Batteries; 4.0 Advanced Ambient-Temperature Batteries; 5.0 EV Battery Performance and Life Evaluation.

Not Available

1992-12-31T23:59:59.000Z

80

Cathodes - Materials and Operation  

Science Conference Proceedings (OSTI)

Feb 15, 2010 ... The increasing trend in line current over recent years has seen the erosion rate of graphitized cathode blocks also increasing, which has led to...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Cathode Design and Operation  

Science Conference Proceedings (OSTI)

Mar 2, 2011 ... Electrically heating collector bar/cathode block assemblies uses less than 15% of the energy required for propane gas burner heating.

82

Microsoft Word - Poster Abstract_2010_ANL_Electrical Polarization...  

NLE Websites -- All DOE Office Websites (Extended Search)

electrical polarization on solid oxide fuel cell cathode thin films B.J. Ingram * , M. Krumpelt * , K.-C. Chang ** , H.D. You ** , H. Du , and P.A. Salvador * Chemical Sciences...

83

Cathodic Arc Plasma Deposition  

Office of Scientific and Technical Information (OSTI)

Cathodic Arc Plasma Deposition Cathodic Arc Plasma Deposition André Anders Lawrence Berkeley National Laboratory, University of California, 1 Cyclotron Road, Mailstop 53, Berkeley, California 94720 aanders@lbl.gov Abstract Cathodic arc plasma deposition is one of oldest coatings technologies. Over the last two decades it has become the technology of choice for hard, wear resistant coatings on cutting and forming tools, corrosion resistant and decorative coatings on door knobs, shower heads, jewelry, and many other substrates. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions are reviewed. Cathodic arc plasmas stand out due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. The

84

Advanced Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Super HigH-TemperaTure alloyS and Super HigH-TemperaTure alloyS and CompoSiTeS From nb-W-Cr SySTemS Description The U.S. Department of Energy's Office of Fossil Energy (DOE-FE) has awarded a three-year grant to the University of Texas at El Paso (UTEP) and Argonne National Laboratory (ANL) to jointly explore the high-temperature properties of alloys composed of niobium (Nb), tungsten (W), and chromium (Cr). The grant is administered by the Advanced Research (AR) program of the National

85

The ANL electric vehicle battery R&D program for DOE-EHP. Progress report: January--March 1993  

SciTech Connect

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce air pollution and petroleum consumption due to the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, and project management on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of January 1, 1993 through March 31, 1993. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Project Management; 2.0 Sodium/Metal Chloride R&D; 3.0 Microreference Electrodes for Lithium/Polymer Batteries.

1993-06-15T23:59:59.000Z

86

Cathode/Interconnect Interactions  

DOE Green Energy (OSTI)

The objectives of this project were to examine chromium poisoning in full cell tests, evaluate chromium release rates for oxides, and examine the effects of chromium in the cathode.

Krumpelt, M.; Cruse, T.A.; Hash, M.

2005-01-27T23:59:59.000Z

87

ANL/TD/TM03-01: Lasers and Beam Delivery for Rock Drilling  

NLE Websites -- All DOE Office Websites (Extended Search)

Development ANL/TD/TM03-01 Development ANL/TD/TM03-01 Division Technology Development Division Technology Development Division Technology Development Division Technology Development Lasers and Beam Delivery for Division Rock Drilling Technology Development Division Technology Development Division by Technology Development K.H. Leong, Z. Xu, C.B. Reed, and Division R.A. Parker Technology Development Division

88

AvAilAble for licensing A unique method for anode and cathode manufacture.  

E-Print Network (OSTI)

and portable device battery markets. Lithium-ion batteries offer significant advantages in weight and energy is developing advanced cell components that will enable new market applications for lithium-ion (Li-ion batteries. Battery Technology 20-cell 80-volt 8-kW Li-ion battery module designed by ANL for Hybrid Electric

Kemner, Ken

89

Definition: Cathode | Open Energy Information  

Open Energy Info (EERE)

Cathode Cathode Jump to: navigation, search Dictionary.png Cathode The negative pole of a battery (electrolytic cell), where electrons enter (and current leaves) the system.[1] View on Wikipedia Wikipedia Definition A cathode is an electrode through which electric current flows out of a polarized electrical device. The direction of electric current is, by convention, opposite to the direction of electron flow-thus, electrons are considered to flow toward the cathode electrode while current flows away from it. This convention is sometimes remembered using the mnemonic CCD for cathode current departs. Cathode polarity is not always negative. Although positively charged cations always move towards the cathode (hence their name) and negatively charged anions move away from it, cathode

90

ANL-78-XX-95 Energy Level Structure and Transition Probabilities  

Office of Scientific and Technical Information (OSTI)

j j ANL-78-XX-95 Energy Level Structure and Transition Probabilities in the Spectra of the Trivalent Lanthanides in LaF- W. T. Carnal! Chemistry Division Argonne National Laboratory Hannah Crosswhite and H. M. Crosswhite Department of Physics The Johns Hopkins University - N O T I C E - Thi* report w u prepared u an account of work sponsored by the United Slates Covemment. Neither the United State* nor ih* United States Department of Energy, nor any of their employees, nor *ny of their contractors, nbcontradon, or their employees, mikes any w i n i n t y , expreis ot implied, or aitumei any legal liability or responsibility for the accuracy, completenea or tisefulrten of any information, apparatus, product or procen disclosed, or represent! that its tat would not infringe privately owned rights.

91

A user's guide to the PLTEMP/ANL code.  

SciTech Connect

PLTEMP/ANL V4.1 is a FORTRAN program that obtains a steady-state flow and temperature solution for a nuclear reactor core, or for a single fuel assembly. It is based on an evolutionary sequence of ''PLTEMP'' codes in use at ANL for the past 20 years. Fueled and non-fueled regions are modeled. Each fuel assembly consists of one or more plates or tubes separated by coolant channels. The fuel plates may have one to five layers of different materials, each with heat generation. The width of a fuel plate may be divided into multiple longitudinal stripes, each with its own axial power shape. The temperature solution is effectively 2-dimensional. It begins with a one-dimensional solution across all coolant channels and fuel plates/tubes within a given fuel assembly, at the entrance to the assembly. The temperature solution is repeated for each axial node along the length of the fuel assembly. The geometry may be either slab or radial, corresponding to fuel assemblies made of a series of flat (or slightly curved) plates, or of nested tubes. A variety of thermal-hydraulic correlations are available with which to determine safety margins such as Onset-of-Nucleate boiling (ONB), departure from nucleate boiling (DNB), and onset of flow instability (FI). Coolant properties for either light or heavy water are obtained from FORTRAN functions rather than from tables. The code is intended for thermal-hydraulic analysis of research reactor performance in the sub-cooled boiling regime. Both turbulent and laminar flow regimes can be modeled. Options to calculate both forced flow and natural circulation are available. A general search capability is available (Appendix XII) to greatly reduce the reactor analyst's time.

Kalimullah, M. (Nuclear Engineering Division)

2011-07-05T23:59:59.000Z

92

Filtered cathodic arc source  

DOE Patents (OSTI)

Disclosed is a continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45{degrees} to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles.

Falabella, S.; Sanders, D.M.

1992-12-31T23:59:59.000Z

93

Filtered cathodic arc source  

DOE Patents (OSTI)

A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge is described. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45[degree] to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles. 3 figures.

Falabella, S.; Sanders, D.M.

1994-01-18T23:59:59.000Z

94

Microsoft Word - Vilas Pol_ANL_CV.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

Laboratory. Jan. 2005 - Dec. 2006. Postdoctoral Fellow, Bar-Ilan Institute of Nanotechnology and Advanced Materials, Israel. Education * Ph. D. Center for Advanced Materials...

95

NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES  

DOE Green Energy (OSTI)

Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

John Olson, PhD

2004-07-21T23:59:59.000Z

96

Batteries: Overview of Battery Cathodes  

E-Print Network (OSTI)

lithium ion battery can be built, using LiVPO 4 F as both the anode and the cathode!ion battery configurations, as all of the cycleable lithium must originate from the cathode.

Doeff, Marca M

2011-01-01T23:59:59.000Z

97

Ceramic Films Using Cathodic Electrodeposition  

Science Conference Proceedings (OSTI)

Electrodeposition is evolving as an important method in ceramic processing. Two processes for forming ceramic films by cathodic electrodeposition are...

98

Tungsten Cathode Catalyst for PEMFC  

DOE Green Energy (OSTI)

Final report for project to evaluate tungsten-based catalyst as a cathode catalyst for PEM cell applications.

Joel B. Christian; Sean P. E. Smith

2006-09-22T23:59:59.000Z

99

Cathode material for lithium batteries  

DOE Patents (OSTI)

A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

Park, Sang-Ho; Amine, Khalil

2013-07-23T23:59:59.000Z

100

Engineering-Scale Liquid Cadmium Cathode Experiments  

SciTech Connect

Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

2006-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Survey of ANL organization plans for word processors, personal computers, workstations, and associated software  

SciTech Connect

The Computing and Telecommunications Division (CTD) has compiled this Survey of ANL Organization Plans for Word Processors, Personal Computers, Workstations, and Associated Software to provide DOE and Argonne with a record of recent growth in the acquisition and use of personal computers, microcomputers, and word processors at ANL. Laboratory planners, service providers, and people involved in office automation may find the Survey useful. It is for internal use only, and any unauthorized use is prohibited. Readers of the Survey should use it as a reference that documents the plans of each organization for office automation, identifies appropriate planners and other contact people in those organizations, and encourages the sharing of this information among those people making plans for organizations and decisions about office automation. The Survey supplements information in both the ANL Statement of Site Strategy for Computing Workstations and the ANL Site Response for the DOE Information Technology Resources Long-Range Plan.

Fenske, K.R.

1991-11-01T23:59:59.000Z

102

Survey of ANL organization plans for word processors, personal computers, workstations, and associated software. Revision 3  

SciTech Connect

The Computing and Telecommunications Division (CTD) has compiled this Survey of ANL Organization Plans for Word Processors, Personal Computers, Workstations, and Associated Software to provide DOE and Argonne with a record of recent growth in the acquisition and use of personal computers, microcomputers, and word processors at ANL. Laboratory planners, service providers, and people involved in office automation may find the Survey useful. It is for internal use only, and any unauthorized use is prohibited. Readers of the Survey should use it as a reference that documents the plans of each organization for office automation, identifies appropriate planners and other contact people in those organizations, and encourages the sharing of this information among those people making plans for organizations and decisions about office automation. The Survey supplements information in both the ANL Statement of Site Strategy for Computing Workstations and the ANL Site Response for the DOE Information Technology Resources Long-Range Plan.

Fenske, K.R.

1991-11-01T23:59:59.000Z

103

Air cathode structure manufacture  

DOE Patents (OSTI)

An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

Momyer, William R. (Palo Alto, CA); Littauer, Ernest L. (Los Altos Hills, CA)

1985-01-01T23:59:59.000Z

104

Hollow cathode life time modelling.  

E-Print Network (OSTI)

??Hollow Cathodes (HCs) are of primary importance in the field of electric space propulsion, being used as electron sources in ion and Hall-effect thrusters. Hence, (more)

Coletti, Michele

2008-01-01T23:59:59.000Z

105

Inert Anodes and Wettable Cathodes  

Science Conference Proceedings (OSTI)

Mar 3, 2011... Development of Wettable Cathodes: Hamed Heidari1; Houshang Alamdari1; Dominique Dub1; Robert Schulz2; 1Universit Laval; 2Hydro-...

106

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

107

Batteries: Overview of Battery Cathodes  

SciTech Connect

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

Doeff, Marca M

2010-07-12T23:59:59.000Z

108

Batteries: Overview of Battery Cathodes  

SciTech Connect

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this

Doeff, Marca M

2010-07-12T23:59:59.000Z

109

Graphene-based composites as cathode materials for lithium ion batteries  

Science Conference Proceedings (OSTI)

Owing to the superior mechanical, thermal, and electrical properties, graphene was a perfect candidate to improve the performance of lithium ion batteries. Herein, we review the recent advances in graphene-based composites and their application as cathode ...

Libao Chen, Ming Zhang, Weifeng Wei

2013-01-01T23:59:59.000Z

110

Atom Trap Trace Analysis at ANL | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

Atom Trap Trace Analysis at ANL Atom Trap Trace Analysis at ANL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Spinoff Applications Spinoff Archives SBIR/STTR Applications of Nuclear Science and Technology Funding Opportunities Nuclear Science Advisory Committee (NSAC) News & Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: sc.np@science.doe.gov More Information » Spinoff Archives Atom Trap Trace Analysis at ANL Print Text Size: A A A RSS Feeds FeedbackShare Page Application/instrumentation: Atom Trap Trace Analysis (ATTA) to determine isotopic abundances. Developed at: Argonne National Laboratory Developed in: 1999-current

111

ANL-13/01 Surveillance of Site A and Plot M  

NLE Websites -- All DOE Office Websites (Extended Search)

ANL-13/01 ANL-13/01 Surveillance of Site A and Plot M Report for 2012 Environment, Safety, and Quality Assurance About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology programs, see www.anl.gov. Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Office of Scientific and Technical Information

112

ANL-10/01 Surveillance of Site A and Plot M  

Office of Legacy Management (LM)

ANL-10/01 Surveillance of Site A and Plot M Report for 2009 Environment, Safety, Health, and Quality Assurance Division Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available

113

Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013  

SciTech Connect

This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.

Kerry L. Nisson

2012-10-01T23:59:59.000Z

114

Argonne Leadership Compu2ng Facility www.alcf.anl.gov Katherine Riley  

E-Print Network (OSTI)

Argonne Leadership Compu2ng Facility ­ www.alcf.anl.gov Katherine Riley Manager and feasibility Managed By INCITE management commi^ee (ALCF & OLCF) DOE Office. Communica2on with ALCF is extremely helpful. You can request 2me on Mira

Kemner, Ken

115

Batteries: Overview of Battery Cathodes  

E-Print Network (OSTI)

Challenges in Future Li-Battery Research. Phil Trans. RoyalBatteries: Overview of Battery Cathodes Marca M. Doeffduring cell discharge. Battery-a device consisting of one or

Doeff, Marca M

2011-01-01T23:59:59.000Z

116

Synopsis of Cathode #4 Activation  

E-Print Network (OSTI)

with the cathode in a bell jar with no immediate heataround the inside of the bell jar to minimize heating of theglass. The bell jar pressure, filament voltage and current,

Ekdahl, C.

2008-01-01T23:59:59.000Z

117

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

Boettcher, Gordon E. (Albuquerque, NM)

1998-01-01T23:59:59.000Z

118

Cold cathode vacuum gauging system  

DOE Patents (OSTI)

A vacuum gauging system of the cold cathode type is provided for measuring the pressure of a plurality of separate vacuum systems, such as in a gas centrifuge cascade. Each casing is fitted with a gauge tube assembly which communicates with the vacuum system in the centrifuge casing. Each gauge tube contains an anode which may be in the form of a slender rod or wire hoop and a cathode which may be formed by the wall of the gauge tube. The tube is provided with an insulated high voltage connector to the anode which has a terminal for external connection outside the vacuum casing. The tube extends from the casing so that a portable magnet assembly may be inserted about the tube to provide a magnetic field in the area between the anode and cathode necessary for pressure measurements in a cold cathode-type vacuum gauge arrangement. The portable magnetic assembly is provided with a connector which engages the external high voltage terminal for providing power to the anode within in the gauge tube. Measurement is made in the same manner as the prior cold cathode gauges in that the current through the anode to the cathode is measured as an indication of the pressure. By providing the portable magnetic assembly, a considerable savings in cost, installation, and maintenance of vacuum gauges for pressure measurement in a gas centrifuge cascade is realizable.

Denny, Edward C. (Knoxville, TN)

2004-03-09T23:59:59.000Z

119

http://www.aps.anl.gov/aps/news/20030616.html  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Supports SSRL Sub-Picosecond Particle Source Technology Supports SSRL Sub-Picosecond Particle Source The SPPS multilayer monochromator designed and fabricated at the APS. (Courtesy of Stanford Synchrotron Radiation Laboratory) A new photon source, the Sub-Picosecond Particle Source (SPPS), that promises to image the movement of objects down to the atomic level in subpicosecond time scales will benefit from the contributions of the Advanced Photon Source, the Optics Fabrication and Metrology Group of Argonne's Experimental Facilities Division (XFD), and BioCARS (The University of Chicago). The SPPS is being constructed at the Stanford Synchrotron Radiation Laboratory (SSRL), part of the Stanford Linear Accelerator Center (SLAC) in California. According to the article on the SSRL Web site, the SPPS "will produce and deliver x-rays from bright electron beam pulses. This project provides a fast, relatively inexpensive way to

120

SHIELDING ESTIMATES FOR THE ANL 6.0 GeV SYNCHROTRON LIGHT SOURCE  

NLE Websites -- All DOE Office Websites (Extended Search)

SHIELDING ESTIMATES FOR THE ANL 6.0 GeV SHIELDING ESTIMATES FOR THE ANL 6.0 GeV SYNCHROTRON LIGHT SOURCE H. J. Moe V. R. Veluri LS-55-Revised Harch 1987 2 1.0 Introduction Shielding estimates for the linac, positron converter, booster synchrotron and the positron storage ring have been computed using preliminary design information. Calculations have been made of the resulting radiation for several types of operations involving normal beam loss, as well as, certain accidental beam losses. When available, experimental data from existing accelerator and light source facilities have been used in lieu of theoretical estimates. 2.0 Shielding Design Objective The Department of Energy's basic occupational exposure limit is 5 rem per year (DOE 81). However, in its guidance for maintaining exposures "as

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While these samples are representative of the content of NLEBeta,
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121

ANL-12/01 Surveillance of Site A and Plot M  

Office of Legacy Management (LM)

ANL-12/01 ANL-12/01 Surveillance of Site A and Plot M Report for 2011 Environment, Safety, and Quality Assurance Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Office of Scientific and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone (865) 576-8401 fax (865) 576-5728 reports@adonis.osti.gov Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor UChicago Argonne, LLC, nor any of their employees or officers, makes any warranty, express

122

ANL=OHS/HP=83=102 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM  

Office of Legacy Management (LM)

' DO E/EV=0005/40 ' DO E/EV=0005/40 ANL=OHS/HP=83=102 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE ALBANY METALLURGICAL RESEARCH CENTER UNITED STATES BUREAU OF MINES ALBANY, OREGON Q\OLO G/C G- 4& G ANL-OHS/HP-83-102 ARGONNE NATIONAL LABORATORY 9700 South Cass Avenue Argonne, Illinois 60439 FORMERLY UTILIZED MED/AEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE ALBANY METALLURGICAL RESEARCH CENTER

123

Cathode Contact Materials for Anode-Supported Cell Development - Lawrence Berkeley National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Contact Materials for Anode- Cathode Contact Materials for Anode- Supported Cell Development- Lawrence Berkeley National Laboratory Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

124

Characterization of PEO-based composite cathodes. I. Morphological, thermal, mechanical and electrical properties  

SciTech Connect

This report describes the fabrication and characterization of polymer-based composite cathode membranes intended for use in polymer-electrolyte batteries operating at moderate temperatures (60--100 C). The present work is focused on the determination of morphological, thermal, mechanical, and electrical properties of PEO-based composite cathodes. The work was developed within the Advanced Lithium Polymer Electrolyte project (ALPE), an Italian integrated project devoted to the realization of lithium polymer batteries for electric vehicle applications.

Appetecchi, G.B.; Carewska, M.; Alessandrini, F.; Prosini, P.P.; Passerini, S.

2000-02-01T23:59:59.000Z

125

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

Boettcher, G.E.

1998-03-10T23:59:59.000Z

126

Cold cathode vacuum discharge tube  

DOE Patents (OSTI)

A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

Boettcher, G.E.

1998-04-14T23:59:59.000Z

127

Cathode Connector For Aluminum Low Temperature Smelting Cell  

DOE Patents (OSTI)

Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2003-07-16T23:59:59.000Z

128

Modeling Cathode Cooling Due to Power Interruption  

Science Conference Proceedings (OSTI)

Presentation Title, Modeling Cathode Cooling Due to Power Interruption ... Development and Application of SAMI's Low Voltage Energy-Saving Technology.

129

Degradation Mechanism of SOFC Cathode Electrolyte Systems ...  

Science Conference Proceedings (OSTI)

Presentation Title, Degradation Mechanism of SOFC Cathode Electrolyte Systems Incorporating Doped Lathanum Gallates. Author(s), Chuan Zhang, Anh T.

130

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

Roose, Lars D. (Albuquerque, NM)

1991-01-01T23:59:59.000Z

131

Cathode for the electrolytic production of hydrogen  

SciTech Connect

The invention relates to a cathode for the electrolytic production of hydrogen. The cathode comprises an active surface consisting of a metal oxide obtained by the thermal decomposition of a thermally decomposable compound of a metal chosen from amongst cobalt, iron, manganese or nickel. The cathode is particularly suitable for the electrolysis of aqueous sodium chloride solutions in cells with a permeable diaphragm.

Nicolas, E.

1983-07-19T23:59:59.000Z

132

Remote control for anode-cathode adjustment  

DOE Patents (OSTI)

An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode. 3 figs.

Roose, L.D.

1989-10-04T23:59:59.000Z

133

Novel Cathodes Prepared by Impregnation Procedures  

DOE Green Energy (OSTI)

(1) We showed that similar results were obtained when using various LSM precursors to produce LSM-YSZ cathodes. (2) We showed that enhanced performance could be achieved by adding LSCo to LSMYSZ cathodes. (3) We have preliminary results showing that there is a slow deactivation with LSFYSZ cathodes.

Eduardo Paz

2006-09-30T23:59:59.000Z

134

Cathodic protection diagnostic expert system  

Science Conference Proceedings (OSTI)

A knowledge-based diagnostic system has been developed for troubleshooting cathodic protection systems. The expert system is designed to work in conjunction with a database that stores inventory and field measurement information and flags problem areas. The system is described, and examples of troubleshooting using the system are presented.

Van Blaricum, V.L.; Kumar, A. (Army Construction Engineering Research Labs., Champaign, IL (United States)); Park, Y.T. (Soong Sil Univ., Seoul (Korea, Republic of). Dept. of Computer Science)

1994-12-01T23:59:59.000Z

135

Cathode for molten salt batteries  

DOE Patents (OSTI)

A molten salt electrochemical system for battery applications comprises tetravalent sulfur as the active cathode material with a molten chloroaluminate solvent comprising a mixture of AlCl.sub.3 and MCl having a molar ratio of AlCl.sub.3 /MCl from greater than 50.0/50.0 to 80/20.

Mamantov, Gleb (Knoxville, TN); Marassi, Roberto (Camerino, IT)

1977-01-01T23:59:59.000Z

136

High-emission cold cathode  

DOE Patents (OSTI)

A field-emission cathode having a multitude of field emission points for emitting a copious stream of electrons when subjected to a high field is described. The cathode is constructed by compressing a multitude of tungsten strips alternately arranged with molybdenum strips and copper ribbons or compressing alternately arranged copper plated tungsten and molybdenum strips, heating the arrangement to braze the tungsten and molybdenum strips together with the copper, machining and grinding the exposed strip edges of one side of the brazed arrangement to obtain a precisely planar surface, etching a portion of the molybdenum and copper to leave the edges of the tungsten strips protruding for electron emission, and subjecting the protruding edges of the tungsten strips to a high electric field to degas and roughen the surface to pnovide a large number of emitting points. The resulting structure is particularly useful as a cathode in a transversely excited gaseous laser where the cathode is mounted in a vacuum chamber for emitting electrons under the influence of a high electric field between the cathode and an extractor grid. The electrons pass through the extractor grid, a thin window in the wall of the laser chamber and into the laser chamber which is filled with a gaseous mixture of helium, nitrogen, and carbon dioxide. A second grid is mounted on the gaseous side of the window. The electrons pass into the laser chamber under the influence of a second electric field between the second grid and an anode in the laser chamber to raise selected gas atoms of the gaseous mixture to appropriately excited states so that a subsequent coherent light beam passing through the mixture transversely to the electron stream through windows in opposite ends of the laser chamber stimulates the excited atoms to amplify the beam. (Official Gazette)

Mancebo, L.

1974-01-29T23:59:59.000Z

137

Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

For the 2013 APSCNMEMC Users Meeting, please go to http:usersmeeting2013.conference.anl.gov 020513...

138

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

DOE Green Energy (OSTI)

This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. This period has continued to address the problem of making dense 1/2 to 5 {micro}m thick dense layers on porous substrates (the cathode LSM). Our current status is that we are making structures of 2-5 cm{sup 2} in area, which consist of either dense YSZ or CGO infiltrated into a 2-5 {micro}m thick 50% porous layer made of either nanoncrystalline CGO or YSZ powder. This composite structure coats a macroporous cathode or anode; which serves as the structural element of the bi-layer structure. These structures are being tested as SOFC elements. A number of structures have been evaluated both as symmetrical and as button cell configuration. Results of this testing indicates that the cathodes contribute the most to cell losses for temperatures below 750 C. In this investigation different cathode materials were studied using impedance spectroscopy of symmetric cells and IV characteristics of anode supported fuel cells. Cathode materials studied included La{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF), La{sub 0.7}Sr{sub 0.2}MnO{sub 3} (LSM), Pr{sub 0.8}Sr{sub 0.2}Fe{sub 0.8}O{sub 3} (PSCF), Sm{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF), and Yb{sub .8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF). A new technique for filtering the Fourier transform of impedance data was used to increase the sensitivity of impedance analysis. By creating a filter specifically for impedance spectroscopy the resolution was increased. The filter was tailored to look for specific circuit elements like R//C, Warburg, or constant phase elements. As many as four peaks can be resolved using the filtering technique on symmetric cells. It may be possible to relate the different peaks to material parameters, like the oxygen exchange coefficient. The cathode grouped in order from lowest to highest ASR is LSCF < PSCF < SSCF < YSCF < LSM. The button cell results agree with this ordering indicating that this is an important tool for use in developing our understanding of electrode behavior in fuel cells.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2002-03-31T23:59:59.000Z

139

Theory, Investigation and Stability of Cathode Electrocatalytic Activity  

SciTech Connect

The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

2012-09-30T23:59:59.000Z

140

ANL-08/04 Surveillance of Site A and Plot M  

Office of Legacy Management (LM)

ANL-08/04 Surveillance of Site A and Plot M Report for 2007 Environment, Safety, and Health/Quality Assurance Oversight Division Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor UChicago Argonne, LLC, nor any of their employees or officers, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus,

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Filters for cathodic arc plasmas  

DOE Patents (OSTI)

Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA); Bilek, Marcela M. M. (Engadine, AU); Brown, Ian G. (Berkeley, CA)

2002-01-01T23:59:59.000Z

142

Nickel-titanium-phosphate cathodes  

DOE Patents (OSTI)

Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.

Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

2008-12-16T23:59:59.000Z

143

Cathodic Protection of Offshore Structures  

Science Conference Proceedings (OSTI)

Table 4   Design criteria for cathodic protection systems...Africa 20??30 5??21 Low Low 130 (12) 90 (8) 90 (8) Indonesia 19 24 Moderate Moderate 110 (10) 75 (7) 75 (7) South China Sea 18 30 Low Low 100 (9) 35 (3) 35 (3) Sea mud 100 Same as water N/A N/A 21.5 (2) 10.8 (1) 10.8 (1) (a) Typical values and ratings

144

Lithium-ferrate-based cathodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at approximately 650 degrees Centigrade. These cathodes are based on lithium ferrate (LiFeO[sub 2]) which is attractive because of its very low solubility in the molten (Li,K)[sub 2]CO[sub 3] electrolyte. Because of its high resistivity, LiFeO[sub 2] cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. The effect of cation substitution on the resistivity and deformation of LiFeO[sub 2] was determined. The substitutes were chosen because their respective oxides as well as LiFeO[sub 2] crystallize with the rock-salt structure.

Lanagan, M.T.; Wolfenstine, J. [Argonne National Lab., IL (United States). Energy Technology Div.; Bloom, I.; Kaun, T.D.; Krumpelt, M. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-12-31T23:59:59.000Z

145

ANL Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Activities of the DOD Activities of the DOD Project Office focus today on the Navy's Free Electron Laser Program Argonne Accelerator Institute Meeting June 16, 2009 2 Several Beam Activities and Interests Ongoing  Terahertz sources and applications  Navy Free Electron Laser (Focus area today)  Free Electron Laser Applications  Electromagnetic Interference Technology Review Committees  Novel Fiber Optic Materials with Army Research Lab  Optical Diagnostics for next-generation light sources  Neutron detection schemes  NATO Sensors and Electronics Panel, international field tests of directed energy source applications  Controls  Radiation Oncology 3 Background, Naval Directed Energy History The U.S Navy has been investigating utility of lasers since the 1960's and the

146

ANL PAdmin  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Argonne National Laboratory Argonne National Laboratory OAS-M-04-01 March 2004 Competition and Property Protection Practices Details of Finding ........................................................................1 Recommendations and Comments .............................................4 Appendices 1. Objective, Scope, and Methodology ......................................6 2. Prior Reports ..........................................................................8 3. Management Comments ........................................................9 MANAGEMENT CONTROLS OVER SUBCONTRACT ADMINISTRATION BY THE ARGONNE NATIONAL LABORATORY TABLE OF CONTENTS Page 1 Competition and Property Protection Argonne National Laboratory (Argonne) did not always ensure adequate competition when procuring goods and services, awarded

147

Lighting Group: Sources and Ballasts: OLED Cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

OLED Cathodes OLED Cathodes Development of New Cathodes for OLED's Objective The objective of this project is to develop improved cathodes for use in organic light emitting diodes (OLEDs). Approach A major challenge for organic light emitting diode (OLED) technology is to improve electron injection into the organic electroluminescent layer, which limits the efficiency of the device and the luminous flux per unit area. This project aims at overcoming such barriers by developing “structured cathodes” based on functional materials (nanotubes and nanoclusters) with characteristic size smaller than the optical wavelength. The incorporation of such nanostructured cathodes in OLEDs can significantly improve device efficiency by lowering operating voltage, and increase device stability and light extraction.

148

Non-Carbon Materials in Cathodes  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Electrode Technology for Aluminum Production: Non-Carbon Materials in Cathodes Sponsored by: The Minerals, Metals and Materials Society,...

149

Dry Barrier Mix in Reduction Cell Cathodes  

Science Conference Proceedings (OSTI)

Presentation Title, Dry Barrier Mix in Reduction Cell Cathodes ... successfully tested as a replacement for barrier bricks in several reduction cell technology types...

150

Emission properties of explosive field emission cathodes  

Science Conference Proceedings (OSTI)

The research results of the explosive field emission cathode plasma expansion velocity and the initial emission area in the planar diode configuration with cathodes made of graphite, stainless steel, polymer velvet, carbon coated, and carbon fiber (needle type) cathodes are presented. The experiments have been performed at the electron accelerator LIA-200 (200 kV, 100 ns, and 4 kA). The diode voltage has been varied from 28-225 kV, whereas the current density has been varied from 86-928 A/cm{sup 2} with 100 ns pulse duration. The experimentally obtained electron beam diode perveance has been compared with the 1 dimensional Child-Langmuir- law. It was found that initially only a part of the cathode take part in the emission process. The plasma expands at 1.7-5.2 cm/{mu}s for 4 mm anode-cathode gap for various cathode materials. It was found that the plasma expansion velocity increases with the decrease in the cathode diameter. At the beginning of the accelerating pulse, the entire cathode area participates in the electron emission process only for the multiple needle type carbon fiber cathode.

Roy, Amitava; Patel, Ankur; Menon, Rakhee; Sharma, Archana; Chakravarthy, D. P. [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Patil, D. S. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India)

2011-10-15T23:59:59.000Z

151

Available Technologies: Improved Cathode Contact Materials for ...  

For Industry; For Researchers; Success Stories; About Us; ... The stainless steel interconnect that brings oxygen to the cathode of a SOFC is a critical feature of ...

152

Electrical Resistance of Graphitic and Graphitized Cathode ...  

Science Conference Proceedings (OSTI)

The electrical resistance of graphitic and graphitized cathode materials before and after electrolysis was also measured at temperatures from 30C to 965C. An ...

153

Layered Nickel Oxide-Based Cathodes for Lithium Cells: Analysis ofPerformance Loss Mechanisms  

DOE Green Energy (OSTI)

Spectroscopic and electrochemical diagnostic measurements are reported for the cell components of a Generation 2 (Gen 2) Li-Ion cell from the US Department of Energy's Advanced Technology Development (ATD) project. The cells are composed of LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} positive electrodes (cathode), carbon graphite anodes and electrolyte consisting of 1.2 M LiPF{sub 6} in EC:EMC 3:7. Fluorophosphates were observed by {sup 19}F and {sup 31}P NMR in the electrolyte obtained from a Gen 2 cell aged 72 weeks at 45 C and presenting 50% power fade. These electrolyte decomposition products were also observed by {sup 31}P solid-state NMR on the surface of the cathode of the same cell. Samples were cut from the aged cathode from the original cell, subjected to different treatments (ultrasonic washing in anhydrous DMC, pressing, ultrasonic washing and pressing), and subsequently reassembled into small lab cells for electrochemical characterization. These treatments recovered the capacity of the electrodes to within a few percent of the original value, with the most improvement being obtained with the washed and pressed cathode. The impedance of the cathodes was also lowered after the ultrasonic washing and pressing treatments. Electron microscopy revealed that the ultrasonic washing of the aged Gen 2 cathode material resulted in the removal of small particles covering the surface of the active cathode. These findings are interpreted in terms of a model whereby capacity loss, and thus power capability, is restored by removing the fluorophosphate deposit and restoring electronic contact to the active cathode material.

Kerlau, Marie; Reimer, Jeffrey A.; Cairns, Elton J.

2004-10-01T23:59:59.000Z

154

ANL/NE-13/9 SHARP Assembly-Scale Multiphysics Demonstration  

NLE Websites -- All DOE Office Websites (Extended Search)

NE-13/9 NE-13/9 SHARP Assembly-Scale Multiphysics Demonstration Simulations Mathematics and Computation Division & Nuclear Engineering Division About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology programs, see www.anl.gov. Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Office of Scientific and Technical Information

155

DOEIEV-0005/37 ANL=OHS/HP-83406 FORMERLY UTILIZED MEDIAEC SITES  

Office of Legacy Management (LM)

//, .<.' //, .<.' I ' 1 TL\ t+, -- DOEIEV-0005/37 ANL=OHS/HP-83406 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE FORMER WATERTOWN ARSENAL PROPERTY SITE 34 AND SITE 41 WATERTOWN, MASSACHUSETTS o\o\-0 G /Q e-+ a+ -? q+ mii ' ( . % QL G+ OCCUPATIONAL HEALTH AND SAFETY INViSiON Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY O F CHICAGO for the U. S. DEPARTMENT O F ENERGY under Contract W=314 09.Eng-38 Argonne National Laboratory, with facilities in the states of Illinois and Idaho, is owned by the United States government, and operated by The University of Chicago under the provisions of a contract with the Department of Energy. r----- DISCLAIMER I This report was prepared as an account of work sponsored by an

156

ANL/ALCF/ESP-13/14 NAMD - The Engine for Large-Scale Classical MD  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 NAMD - The Engine for Large-Scale Classical MD Simulations of Biomolecular Systems Based on a Polarizable Force Field ALCF-2 Early Science Program Technical Report Argonne Leadership Computing Facility About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology programs, see www.anl.gov. Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from:

157

Microsoft Word - ANL_L2_ST Exp_093013_R2  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Campaign Campaign Embrittlement and DBTT of High- Burnup PWR Fuel Cladding Alloys Prepared for U.S. Department of Energy Used Fuel Disposition Campaign M.C. Billone, T.A. Burtseva, Z. Han and Y.Y. Liu Argonne National Laboratory September 30, 2013 FCRD-UFD-2013-000401 ANL-13/16 DISCLAIMER This information was prepared as an account of work sponsored by an agency of the U.S. Government. Neither the U.S. Government nor any agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness, of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. References herein

158

ANL/MCS-TM-331 Mathematics and Computer Science Division Availability of This Report  

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Performance Analysis of Darshan 2.2.3 Performance Analysis of Darshan 2.2.3 on the Cray XE6 Platform ANL/MCS-TM-331 Mathematics and Computer Science Division Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Office of Scientific and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone (865) 576-8401 fax (865) 576-5728 reports@adonis.osti.gov Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor UChicago Argonne, LLC, nor any of their employees or officers, makes any warranty, express

159

DOE/EV-0005/26 ANL-OHS/HP-82-100  

Office of Legacy Management (LM)

J-L.f!~: J-L.f!~: r*' c;,:i &3&j DOE/EV-0005/26 ANL-OHS/HP-82-100 i$; ' ,\ : -ed - *' J&&&g y FORMERLY UTILIZED MED/AEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE GEORGE HERBERT JONES CHEMICAL LABORATORY THE UNIVERSITY OF CHICAGO CHICAGO, ILLINOIS June 1347, 1977 OCCUPATIONAL HEALTH AND SAFETY DIVISION Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Prepared for the U. S. DEPARTMENT OF ENERGY under Contract W -31409-Eng=38 The facilities of Argonne National Laboratory are owned by the United States Government. Under the terms of a contract (W-31-109-Eng-38) among the U. S. Department of Energy, Argonne Universities Association and The University of Chicago, the University employs the staff and operates the Laboratory in

160

Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol...  

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Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells A direct methanol fuel cell...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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to obtain the most current and comprehensive results.


161

Cell properties for modified PTMA cathodes of organic radical...  

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Cell properties for modified PTMA cathodes of organic radical batteries Title Cell properties for modified PTMA cathodes of organic radical batteries Publication Type Journal...

162

High-rate capable organic radical cathodes for lithium rechargeable...  

NLE Websites -- All DOE Office Websites (Extended Search)

High-rate capable organic radical cathodes for lithium rechargeable batteries Title High-rate capable organic radical cathodes for lithium rechargeable batteries Publication Type...

163

Analysis of the ANL Test Method for 6CVS Containment Vessels  

Science Conference Proceedings (OSTI)

In the fall of 2010, Argonne National Laboratory (ANL) contracted with vendors to design and build 6CVS containment vessels as part of their effort to ship Fuel Derived Mixed Fission Product material. The 6CVS design is based on the Savannah River National Laboratory's (SRNL) design for 9975 and 9977 six inch diameter containment vessels. The main difference between the designs is that the 6CVS credits the inner O-ring seal as the containment boundary while the SRNL design credits the outer O-ring seal. Since the leak test must be done with the inner O-ring in place, the containment vessel does not have a pathway for getting the helium into the vessel during the leak test. The leak testing contractor was not able to get acceptable leak rates with the specified O-ring, but they were able to pass the leak test with a slightly larger O-ring. ANL asked the SRNL to duplicate the leak test vendor's method to determine the cause of the high leak rates. The SRNL testing showed that the helium leak indications were caused by residual helium left within the 6CVS Closure Assembly by the leak test technique, and by helium permeation through the Viton O-ring seals. After SRNL completed their tests, the leak testing contractor was able to measure acceptable leak rates by using the slightly larger O-ring size, by purging helium from the lid threads, and by being very quick in getting the bell jar under a full vacuum. This paper describes the leak test vendor's test technique, and other techniques that could be have been used to successfully leak test the 6CVS's.

Trapp, D.; Crow, G.

2011-06-06T23:59:59.000Z

164

Cathode for an electrochemical cell  

SciTech Connect

Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

2001-01-01T23:59:59.000Z

165

Safety aspects of the US advanced LMR (liquid metal reactor) design  

SciTech Connect

The cornerstones of the United States Advanced Liquid Metal Cooled Reactor (ALMR) program sponsored by the Department of Energy are: the plant design program at General Electric based on the PRISM (Power Reactor Innovative Small Module) concept, and the Integral Fast Reactor program (IFR) at Argonne National Laboratory (ANL). The goal of the US program is to produce a standard, commercial ALMR, including the associated fuel cycle. This paper discusses the US regulatory framework for design of an ALMR, safety aspects of the IFR program at ANL, the IFR fuel cycle and actinide recycle, and the ALMR plant design program at GE. 6 refs., 5 figs.

Pedersen, D.R.; Gyorey, G.L.; Marchaterre, J.F.; Rosen, S. (Argonne National Lab., IL (USA); General Electric Co., San Jose, CA (USA); Argonne National Lab., IL (USA); USDOE Assistant Secretary for Nuclear Energy, Washington, DC (USA))

1989-01-01T23:59:59.000Z

166

Cathode for electrolytic production of hydrogen  

SciTech Connect

A cathode for use in the electrochemical production of hydrogen and a process for making it which involves direct electrochemical cathodic action on a thermally produced adherent oxide on a nickel cathode surface are disclosed. Examples include a nickel sheet thermally oxidized in air at 600/sup 0/ C. for one hour and used directly in the production of electrolytic hydrogen and an iron sheet plasma sprayed with nickel to provide a surface containing thermal oxidation product of nickel and again used directly in the electrolytic production of hydrogen.

Hall, D.E.

1983-10-18T23:59:59.000Z

167

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

Disclosed are a porous sintered cathode for a molten carbonate fuel cell and method of making same. The cathode includes a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell. The cathode has a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, T.D.; Mrazek, F.C.

1986-04-25T23:59:59.000Z

168

Cathode for molten carbonate fuel cell  

DOE Patents (OSTI)

A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1990-01-01T23:59:59.000Z

169

An Electrical Cathode Model of a High Pressure Sodium Lamp  

Science Conference Proceedings (OSTI)

An electrical cathode model (ECM) of a high pressure sodium lamp (HPS) based on physical laws has been developed. The proposed ECM calculates the instantaneous voltage drop in a cathode sheath and the temperature distribution inside the cathode using ... Keywords: cathode model, HPS lamp ballast designs

Jose Luis Tapia; Joel O. Pacheco Sotelo; Eduardo Diaz Rodriguez; Yulia Nikolaevna Ledeneva; Rene Arnulfo Garcia Hernandez

2010-09-01T23:59:59.000Z

170

Cathodic Arc Plasma System with Twist Filter: Advanced ...  

See More Ion Sources and Beams Technologies. Contact Us. Receive Customized Tech Alerts. Tech Transfer Site Map. Last updated: 09/17/2009.

171

Low temperature aluminum reduction cell using hollow cathode  

DOE Patents (OSTI)

A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

2002-08-20T23:59:59.000Z

172

Cathode Coating (IN-09-061)  

A team of scientists at Argonne National Laboratory has developed a special coating for the cathodes used in lithium batteries. With the coating, batteries charge and discharge more quickly, without a loss in performance.

173

Continuum and Quantum-Chemical Modeling of Oxygen Reduction on the Cathode in a Solid Oxide Fuel Cell  

DOE Green Energy (OSTI)

Solid oxide fuel cells (SOFCs) have several advantages over other types of fuels cells such as high-energy efficiency and excellent fuel flexibility. To be economically competitive, however, new materials with extraordinary transport and catalytic properties must be developed to dramatically improve the performance while reducing the cost. This article reviews recent advancements in understanding oxygen reduction on various cathode materials using phenomenological and quantum chemical approaches in order to develop novel cathode materials with high catalytic activity toward oxygen reduction. We summarize a variety of results relevant to understanding the interactions between O2 and cathode materials at the molecular level as predicted using quantum-chemical cal-culations and probed using in situ surface vibrational spectroscopy. It is hoped that this in-depth understanding may provide useful insights into the design of novel cath-ode materials for a new generation of SOFCs.

Choi, Yongman; Mebane, David S.; Wang, Jeng-Han; Liu, Meilin

2009-10-08T23:59:59.000Z

174

Interfacial phenomena on selected cathode materials  

DOE Green Energy (OSTI)

We have carried out a series of surface studies of selected cathode materials. Instrumental techniques such as Raman microscopy, surface enhanced Raman spectroscopy (SERS), and atomic force microscopy were used to investigate the cathode surfaces. The goal of this study was to identify detrimental processes which occur at the electrode/electrolyte interface and can lead to electrode degradation and failure during cycling and/or storage at elevated temperatures.

Kostecki, Robert; Matsuo, Yoshiaki; McLarnon, Frank

2001-06-22T23:59:59.000Z

175

Ballast technique for laser cathode pins  

SciTech Connect

The discrete ballast resistors associated with the multiple pin array of laser cathode structures are replaced by a bulk resistive material in the form of an integral bar or slab which is maintained in contact with the plurality of pin electrodes comprising the laser cathode assembly to provide a stable ballast means. The bulk resistive member employed to provide the ballast for the pin electrodes can exhibit non-linear resistive characteristics to provide greater laser discharge stability with less power dissipation.

Hundstad, R.L.; Wutzke, S.A.

1979-09-04T23:59:59.000Z

176

LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES  

DOE Green Energy (OSTI)

This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

2003-03-31T23:59:59.000Z

177

Proceedings of the symposium and workshop on advanced battery research and design, March 22--24, 1976. [Held at ANL  

DOE Green Energy (OSTI)

Separate abstracts are presented for 30 of the papers in these proceedings. An additional paper has already been cited in ERA. (RWR)

Selman, J.R.; Steuenberg, R.K.; Barghusen, J.J.; Howard, W.G. (eds.)

1976-01-01T23:59:59.000Z

178

Development of Ultra-Low Platinum Alloy Cathode Catalyst for PEM Fuel Cells - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Branko N. Popov University of South Carolina (USC) 301 Main Street Columbia, SC 29208 Phone: (803) 777-7314 Email: popov@cec.sc.edu DOE Managers HQ: Donna Lee Ho Phone: (202) 586-8000 Email: Donna.Ho@ee.doe.gov GO: David Peterson Phone: (720) 356-1747 Email: David.Peterson@go.doe.gov Technical Advisor Thomas Benjamin Phone: (630) 252-1632 Email: benjamin@anl.gov Contract Number: DE-EE0000460 Subcontractor: Dr. Hansung Kim (Co-PI) Yonsei University, S. Korea. Project Start Date: September 1, 2010 Project End Date: May 31, 2014 Objectives Develop low-cost and durable hybrid cathode catalyst * (HCC). Develop Pt alloy/activated graphitic carbon catalyst. * Develop corrosion resistant supports. *

179

Engineered Cathodes for High Performance SOFCs  

Science Conference Proceedings (OSTI)

Computational design analysis of a high performance cathode is a cost-effective means of exploring new microstructure and material options for solid oxide fuel cells. A two-layered porous cathode design has been developed that includes a thinner layer with smaller grain diameters at the cathode/electrolyte interface followed by a relatively thicker outer layer with larger grains at the electrode/oxidant interface. Results are presented for the determination of spatially dependent current generation distributions, assessment of the importance of concentration polarization, and sensitivity to measureable microstructural variables. Estimates of the electrode performance in air at 700C indicate that performance approaching 3.1 A/cm2 at 0.078 V is theoretically possible. The limitations of the model are described, along with efforts needed to verify and refine the predictions. The feasibility of fabricating the electrode configuration is also discussed.

Williford, Rick E.; Singh, Prabhakar

2004-03-29T23:59:59.000Z

180

Cathodic protection in simulated geothermal environments  

DOE Green Energy (OSTI)

The results of cathodic protection of carbon steel and AISI Type 316 stainless steel in simulated geothermal brines are described. Impressed current tests on carbon steel and stainless steel were conducted under controlled potential, and cathodic protection of carbon steel using zinc sacrificial anodes was studied by monitoring the galvanic current and potential of the couple with a zero-resistance ammeter. Weight-loss measurements and photomicrographs of test coupons were taken whenever necessary to determine the nature of attack and degree of protection. Tests were generally conducted at 90/sup 0/C. However, some tests on carbon steel were conducted up to 150/sup 0/C in a titanium autoclave. Results show that the weight loss of carbon steel can be reduced significantly and the pitting corrosion of the stainless steel can be prevented by shifting the potentials of the metals 60 to 80 mV cathodic to their respective open-circuit potentials.

Bandy, R.; van Rooyen, D.

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Theory, Investigation, and Stability of Cathode Electro-catalytic Activity„Georgia Institute of Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory, Investigation, and Stability of Theory, Investigation, and Stability of Cathode Electro-catalytic Activity- Georgia Institute of Technology Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide fuel cells (SOFCs) for

182

A cathodically protected electrical substation ground grid  

SciTech Connect

This paper presents a discussion on the design of a cathodically protected electrical substation grounding system in which a steel ground grid and steel ground rods were used in place of the commonly used copper ground grid and copperweld ground rods. Several electrical constraints are presented which discuss common electrical utility requirements, safety considerations and economic factors. The grounding system materials which were chosen are discussed along with the means of cathodic protection. Finally, the design, construction and testing considerations are presented as an aid to others who wish to design a similar system.

Nelson, J.P.; Holm, W.K.

1983-09-01T23:59:59.000Z

183

Workshop on Catalysis Research at the Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalysis Workshop Home Program Registration Poster Registration Organizing Committee: * Chris Marshall (ANL) * Peter Stair (NWU) * Simon Bare (UOP) * Hoydoo You (ANL) * Randy...

184

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network (OSTI)

Coating for Lithium-Ion Battery Cathodes", Chemistry ofas the cathode of the lithium ion battery by Thackeray et

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

185

New OLED Cathode Materials with Tailored Low Work Function  

offer a viable alternative to the standard metal cathode technology. ... energy than the conventional technology available today. Features and Benefits

186

Cathodic Protection System Application and Maintenance Guide  

Science Conference Proceedings (OSTI)

Typically, cathodic protection system equipment includes rectifiers, anodes, anode junction boxes, reference cells (electrodes), and test stations. The scope of this guide includes addressing the maintenance and testing of the system, its components, and providing appropriate recommendations. These recommendations will provide the basis for a suitable preventive (PM) and predictive (PdM) maintenance program.

2005-12-23T23:59:59.000Z

187

Microsoft Word - 49047_ANL_NDE for Ceramic Composites.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

of oxide-based ceramic composite materials in advanced , low-emission, high efficiency gas turbines. Components made from oxide-based composites will be studied with and without...

188

Carbon-containing cathodes for enhanced electron emission  

DOE Patents (OSTI)

A cathode has electropositive atoms directly bonded to a carbon-containing substrate. Preferably, the substrate comprises diamond or diamond-like (sp.sup.3) carbon, and the electropositive atoms are Cs. The cathode displays superior efficiency and durability. In one embodiment, the cathode has a negative electron affinity (NEA). The cathode can be used for field emission, thermionic emission, or photoemission. Upon exposure to air or oxygen, the cathode performance can be restored by annealing or other methods. Applications include detectors, electron multipliers, sensors, imaging systems, and displays, particularly flat panel displays.

Cao, Renyu (Cupertino, CA); Pan, Lawrence (Pleasanton, CA); Vergara, German (Madrid, ES); Fox, Ciaran (Los Altos, CA)

2000-01-01T23:59:59.000Z

189

Carbon fiber paper cathodes for lithium ion batteries  

Science Conference Proceedings (OSTI)

A novel lithium ion battery cathode structure was produced which has the potential for excellent capacity retention and good thermal management. In these cathodes, the active cathode material (lithium iron phosphate) was carbon bonded to a thermally and electrically conductive carbon fiber paper (CFP) support. Electrochemical testing was performed on Swagelok cells consisting of CFP cathodes and lithium anodes. High specific energy, near-theoretical capacity, and good cycling performance were demonstrated for 0.11 mm and 0.37 mm thick CFP cathodes.

Kercher, Andrew K [ORNL; Kiggans, Jim [ORNL; Dudney, Nancy J [ORNL

2010-01-01T23:59:59.000Z

190

Advanced Burner Test Reactor - Preconceptual Design Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Burner Test Reactor Preconceptual Design Report ANL-ABR-1 (ANL-AFCI-173) Nuclear Engineering Division Disclaimer This report was prepared as an account of work sponsored by an...

191

Magnetron cathodes in plasma electrode pockels cells  

DOE Patents (OSTI)

Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating. pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal.

Rhodes, Mark A. (Pleasanton, CA)

1995-01-01T23:59:59.000Z

192

Impedance studies on Li-ion cathodes  

DOE Green Energy (OSTI)

This paper describes the author's 2- and 3-electrode impedance results of metal oxide cathodes. These results were extracted from impedance data on 18650 Li-ion cells. The impedance results indicate that the ohmic resistance of the cell is very nearly constant with state-of-charge (SOC) and temperature. For example, the ohmic resistance of 18650 Li-ion cells is around 60 m{Omega} for different SOCS (4.1V to 3.0V) and temperatures from 35 C to {minus}20 C. However, the interfacial impedance shows a modest increase with SOC and a huge increase of between 10 and 100 times with decreasing temperature. For example, in the temperature regime (35 C down to {minus}20 C) the overall cell impedance has increased from nearly 200 m{Omega} to 8,000 m{Omega}. Most of the increase in cell impedance comes from the metal oxide cathode/electrolyte interface.

NAGASUBRAMANIAN, GANESAN

2000-04-17T23:59:59.000Z

193

NUMERICAL MODELING OF CATHODE CONTACT MATERIAL DENSIFICATION  

Science Conference Proceedings (OSTI)

Numerical modeling was used to simulate the constrained sintering process of the cathode contact layer during assembly of solid oxide fuel cells (SOFCs). A finite element model based on the continuum theory for sintering of porous bodies was developed and used to investigate candidate low-temperature cathode contact materials. Constitutive parameters for various contact materials under investigation were estimated from dilatometry screening tests, and the influence of processing time, processing temperature, initial grain size, and applied compressive stress on the free sintering response was predicted for selected candidate materials. The densification behavior and generated stresses within a 5-cell planar SOFC stack during sintering, high temperature operation, and room temperature shutdown were predicted. Insufficient constrained densification was observed in the stack at the proposed heat treatment, but beneficial effects of reduced grain size, compressive stack preload, and reduced thermal expansion coefficient on the contact layer densification and stresses were observed.

Koeppel, Brian J.; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-11-01T23:59:59.000Z

194

Progress on diamond amplified photo-cathode  

SciTech Connect

Two years ago, we obtained an emission gain of 40 from the Diamond Amplifier Cathode (DAC) in our test system. In our current systematic study of hydrogenation, the highest gain we registered in emission scanning was 178. We proved that our treatments for improving the diamond amplifiers are reproducible. Upcoming tests planned include testing DAC in a RF cavity. Already, we have designed a system for these tests using our 112 MHz superconducting cavity, wherein we will measure DAC parameters, such as the limit, if any, on emission current density, the bunch charge, and the bunch length. The diamond-amplified photocathode, that promises to support a high average current, low emittance, and a highly stable electron beam with a long lifetime, is under development for an electron source. The diamond, functioning as a secondary emitter amplifies the primary current, with a few KeV energy, that comes from the traditional cathode. Earlier, our group recorded a maximum gain of 40 in the secondary electron emission from a diamond amplifier. In this article, we detail our optimization of the hydrogenation process for a diamond amplifier that resulted in a stable emission gain of 140. We proved that these characteristics are reproducible. We now are designing a system to test the diamond amplifier cathode using an 112MHz SRF gun to measure the limits of the emission current's density, and on the bunch charge and bunch length.

Wang, E.; Ben-Zvi, I.; Burrill, A.; Kewisch, J.; Chang, X.; Rao, T.; Smedley, J.; Wu, Q.; Muller, E.; Xin, T.

2011-03-28T23:59:59.000Z

195

People | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

User Contacts New to the APS? How to Become an APS User If you need any assistance, please contact the APS User Office (630) 252-9090 apsuser@aps.anl.gov Beamline phone numbers...

196

Industrial User Office | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Industrial Liaison Office Industrial Liaison Office Industrial Liaison Office registration page New to Synchrotron Radiation New to the APS Already a User Advanced Photon Source Industrial Liaison Office Welcome to the Advanced Photon Source (APS) Industrial Liaison Office home page. The purpose of this Office is to provide outreach from the APS to the industrial community. As we develop the Office and this website to better address the needs of industrial users of the APS, both current and prospective, we are soliciting input by requesting projects and measurements that you would like to perform at the APS. Please complete the form below so that we can begin communicating with you. Questions? Email aps-i@aps.anl.gov. General Information Company Name *required First Name *required Last Name *required

197

ANL Technical Support Program for DOE Environmental Restoration and Waste Management; Annual report, October 1992--September 1993  

SciTech Connect

This report is an overview of the progress during FY 1993 for the Technical Support Program that is part of the ANL Technology Support Activity for DOE Environmental Restoration and Waste Management (EM). The purpose is to evaluate, before hot start-up of the Defense Waste Processing Facility (DWPF) and the West Valley Demonstration Project (WVDP), factors that are anticipated to affect glass reaction in an unsaturated environment typical of what may be expected for the candidate Yucca Mountain repository site. Specific goals for the testing program include the following: reviewing and evaluating available data on parameters that will be important in establishing the long-term performance of glass in a repository environment; performing tests to further quantify the effects of important variables where there are deficiencies in the available data; and initiating long-term tests to determine glass performance under a range of conditions applicable to repository disposal.

Bates, J.K.; Bourcier, W.L.; Bradley, C.R. [and others

1994-06-01T23:59:59.000Z

198

ANL Technical Support Program for DOE Environmental Restoration and Waste Management. Annual report, October 1990--September 1991  

SciTech Connect

This report provides an overview of progress during FY 1991 for the Technical Support Program that is part of the ANL Technology Support Activity for DOE, Environmental Restoration and Waste Management (EM). The purpose is to evaluate, before hot start-up of the Defenses Waste Processing Facility (DWPF) and the West Valley Demonstration Project (WVDP), factors that are likely to affect glass reaction in an unsaturated environment typical of what may be expected for the candidate Yucca Mountain repository site. Specific goals for the testing program include the following: (1) to review and evaluate available information on parameters that will be important in establishing the long-term performance of glass in a repository environment; (2) to perform testing to further quantify the effects of important variables where there are deficiencies in the available data; and (3) to initiate long-term testing that will bound glass performance under a range of conditions applicable to repository disposal.

Bates, J.K.; Bradley, C.R.; Buck, E.C.; Cunnane, J.C.; Dietz, N.L.; Ebert, W.L.; Emery, J.W.; Feng, X.; Gerding, T.J.; Gong, M.; Hoh, J.C.; Mazer, J.J.; Wronkiewicz, D.J. [Argonne National Lab., IL (United States); Bourcier, W.L.; Morgan, L.E.; Nielsen, J.K.; Steward, S.A. [Lawrence Livermore National Lab., CA (United States); Ewing, R.C.; Wang, L.M. [New Mexico Univ., Albuquerque, NM (United States); Han, W.T.; Tomozawa, M. [Rensselaer Polytechnic Inst., Troy, MI (United States)

1992-03-01T23:59:59.000Z

199

Stibine/arsine monitoring during EV operation: summary report on preliminary tests at ANL and at LILCO  

DOE Green Energy (OSTI)

A series of tests was performed to monitor the evolution and dispersal of stibine and arsine from the lead-acid propulsion batteries in three different Electra-Van Model 600 vehicles operated by Argonne National Laboratory (ANL) and by the Long Island Lighting Company (LILCO). Ambient air was sampled at several locations inside the vehicles and in the garages where testing was done during charge, equalization charge, and on-the-road discharge operations. In addition, direct sampling of cell off-gases was performed with the ANL van. Interpretation of the individual test results was carried out in the context of vehicle characteristics, sampling protocol, and operating conditions. The test results demonstrated that under the test conditions only small concentrations of stibine and arsine accumulated in occupiable work areas. Measured concentrations in the vehicles and in the garages never exceeded 25% of the Threshold Limit Value-Time Weighted Average (TLV-TWA) standards. A threshold voltage for hydride production, at about 2.45 V per cell, was reflected in the results of the experiments performed during charging of the batteries. Hydride evolution rates were lower during equalization charge than during the overcharge portion of a charge cycle when the on-board charger was used in a normal operating mode. A delayed release of the metal hydrides from the battery cells was observed during on-the-road operation of the vehicles. The implications of these observations for electric vehicle (EV) operation are discussed. An engineering analysis of the generation and dispersal of the metal hydrides is presented, and equations are derived for estimating minimum ventilation requirements for the EV battery compartment and for garages housing EV operations. Recommendations are made regarding safe handling procedures for battery off-gases, procedures for conducting stibine/arsine monitoring tests and future work.

Loutfy, R.O.; Graczyk, D.G.; Varma, R.; Hayes, E.R.; Williams, F.L.; Yao, N.P.

1981-02-01T23:59:59.000Z

200

ANL/APS/TB-32 Test of Horizontal Field Measurements Using Two-Axis Hall  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 Test of Horizontal Field Measurements Using Two-Axis Hall Probes at the APS Magnetic Measurement Facility I. Vasserman Advanced Photon Source Argonne National Laboratory Argonne, IL 60439 1. Introduction The free-electron laser (FEL) project at the Advanced Photon Source (APS) will use a 400-MeV particle beam from the APS linac with RMS beam transverse size of 100 µm and requires very high performance of the insertion devices in order to achieve high intensity radiation. Averaged over period, the trajectory must deviate from the ideal on-axis trajectory by not more than 10% of the RMS beam size. Meaning that the second field integral should be straight within ±1300 G-cm 2 over the length of the device for both horizontal and vertical directions for the 400-MeV particle

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

ANL/APS/TB-14 APS Beamline Design and Construction Requirements:  

NLE Websites -- All DOE Office Websites (Extended Search)

14 14 APS Beamline Design and Construction Requirements: A Reference Manual for Designers and Builders Version 1.0 May 1994 iii TABLE OF CONTENTS SECTION I DEFINITIONS, GUIDELINES, AND REVIEW CRITERIA ............................1 1. Introduction (July 21, 1998) ...............................................................................................1 1.1 About the Advanced Photon Source ...........................................................................1 1.2 About this Manual.......................................................................................................1 2. Beamline Definitions and Responsibilities (July 21, 1998) .................................................2 2.1 Definitions...................................................................................................................2

202

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

LBNL-55226 Catalyst-Infiltrated Supporting Cathode for Thin-demonstrate that cobalt catalyst-infiltrated LSM can beinfiltrating nano- sized catalyst particles into its pores

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

203

Multi-cathode metal vapor arc ion source  

DOE Patents (OSTI)

An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. One embodiment of the appaatus utilizes a multi-cathode arrangement for interaction with the anode.

Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805)

1988-01-01T23:59:59.000Z

204

Defective Carbon Nanomaterials as the Cathodes for High ...  

Science Conference Proceedings (OSTI)

Defective carbon nanotubes used as the cathodes for lithium batteries show capacitance of ~580 F/g, which can store lithium ions up to an energy density of...

205

Surface Characterization of the LCLS RF Gun Cathode  

Science Conference Proceedings (OSTI)

The first copper cathode installed in the LCLS RF gun was used during LCLS commissioning for more than a year. However, after high charge operation (> 500 pC), the cathode showed a decline of quantum efficiency within the area of drive laser illumination. They report results of SEM, XPS and XAS studies that were carried out on this cathode after it was removed from the gun. X-ray absorption and X-ray photoelectron spectroscopy reveal surface contamination by various hydrocarbon compounds. In addition they report on the performance of the second installed cathode with emphasis on the spatial distribution of electron emission.

Brachmann, Axel; /SLAC; Decker, Franz-Josef; /SLAC; Ding, Yuantao; /SLAC; Dowell, David; /SLAC; Emma, Paul; /SLAC; Frisch, Josef; /SLAC; Gilevich, Sasha; /SLAC; Hays, Gregory; /SLAC; Hering, Philippe; /SLAC; Huang, Zhirong; /SLAC; Iverson, Richard; /SLAC; Loos, Henrik; /SLAC; Miahnahri, Alan; /SLAC; Nordlund, Dennis; /SLAC; Nuhn, Heinz-Dieter; /SLAC; Pianetta, Piero; /SLAC; Turner, James; /SLAC; Welch, James; /SLAC; White, William; /SLAC; Wu, Juhao; /SLAC; Xiang, Dao; /SLAC

2012-06-25T23:59:59.000Z

206

Cathode/Anode Selection and Full Cell Performance for Stationary ...  

Science Conference Proceedings (OSTI)

Presentation Title, Cathode/Anode Selection and Full Cell Performance for Stationary Li-ion Battery System. Author(s), Daiwon Choi, Donghai Wang, Vilayanur...

207

Development of spray coated cathodes for RITS-6.  

SciTech Connect

This report documents work conducted in FY13 to conduct a feasibility study on thermal spray coated cathodes to be used in the RITS-6 accelerator in an attempt to improve surface uniformity and repeatability. Currently, the cathodes are coated with colloidal silver by means of painting by hand. It is believed that improving the cathode coating process could simplify experimental setup and improve flash x-ray radiographic performance. This report documents the experimental setup and summarizes the results of our feasibility study. Lastly, it describes the path forward and potential challenges that must be overcome in order to improve the process for creating uniform and repeatable silver coatings for cathodes.

Simpson, Sean; Leckbee, Joshua J.; Miller, Stephen Samuel

2013-09-01T23:59:59.000Z

208

New OLED Cathode Materials with Tailored Low Work Function  

Colorado State University offer a viable alternative to the standard metal cathode ... The metal complex can be specifically chosen to match the energy and

209

New OLED Cathode Materials with Tailored Low Work Function ...  

The requirements of the cathode and anode limit the types of organic material that can be used for the light emitting ... Energy-saving displays on televisions, ...

210

Phase-Field Modeling of Microstructural Evolution of SOFC Cathode  

Science Conference Proceedings (OSTI)

Presentation Title, Phase-Field Modeling of Microstructural Evolution of SOFC Cathode. Author(s), Qun Li, Long-Qing Chen. On-Site Speaker (Planned), Qun Li.

211

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles  

E-Print Network (OSTI)

58757 INTRODUCTION For practical SOFC cathodes, the selectedthe high temperatures where SOFC membranes are fabricated.costs, lowering of the SOFC operating temperatures has been

Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, Steven J.; DeJonghe, Lutgard C.

2006-01-01T23:59:59.000Z

212

Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance ...  

Science Conference Proceedings (OSTI)

Presentation Title, Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance of Ionic and Electronic Carriers. Author(s), Rotraut Merkle, Lei Wang,

213

Cathode Coating (IN09-061) - Argonne National Laboratory  

A cathode coating that leads to faster battery charging and discharging without a loss ... Charge and discharge capacity of pristine, 250C dry air and

214

Preheating Collector Bars and Cathode Blocks Prior to Rodding with ...  

Science Conference Proceedings (OSTI)

Electrically heating collector bar/cathode block assemblies uses less than 15% of the energy required for propane gas burner heating. The method is quiet,...

215

Modeling of Energy Savings by Using Cathode Design and Inserts  

Science Conference Proceedings (OSTI)

Electrical modeling can easily explain the energy savings in the cathode. Magneto-hydrodynamic modeling shows why and how specific energy can be saved in...

216

Advanced Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Materials Advanced Materials Availability Technology Express Licensing Active Terahertz Metamaterial Devices Express Licensing Anion-Conducting Polymer, Composition, And...

217

Studies of local degradation phenomena in composite cathodes for  

NLE Websites -- All DOE Office Websites (Extended Search)

Studies of local degradation phenomena in composite cathodes for Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Title Studies of local degradation phenomena in composite cathodes for lithium-ion batteries Publication Type Journal Article Year of Publication 2007 Authors Kerlau, Marie, Marek Marcinek, Venkat Srinivasan, and Robert Kostecki Journal Electrochimica Acta Volume 52 Pagination 5422-5429 Keywords cathode, degradation, li-ion battery, raman microscopy Abstract LiNi0.8Co0.15Al0.05O2 and LiNi1/3Co1/3Mn1/3O2 composite cathodes were cycled in model cells to study interfacial phenomena that could lead to electrode degradation. Ex situ spectroscopic analysis of the tested cathodes, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite the deep discharge of the Li-ion cell at the end of the test. The inconsistent kinetic behavior of individual oxide particles was attributed to the degradation of electronic pathways within the composite cathodes. A simple theoretical model based on a distributed network showed that an increase of the contact resistance between composite electrode particles may be responsible for non-uniform local kinetic behavior of individual oxide particles and the overall degradation of electrochemical performance of composite electrodes.

218

Electrorefining cell with parallel electrode/concentric cylinder cathode  

DOE Patents (OSTI)

A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium and a mixture of uranium and plutonium for use as a fresh blanket and core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped cathode is disposed about the outer anodic dissolution baskets. Uranium is deposited from the anode baskets in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium collection efficiency enhanced by increasing the electrode area and reducing the anode-cathode spacing for enhanced trapping and recovery of uranium dendrites scraped off of the cylindrical cathodes which may be greater in number than two.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1995-12-31T23:59:59.000Z

219

ANL/APS/TB-21 Radiation Shielding of Insertion Device Beamlines  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 Radiation Shielding of Insertion Device Beamlines Using a Mirror as the First Optical Element W. Yun, B. Lai, K. J. Randall, S. Davey, D. R. Haeffner, P. K. Job, and D. Shu February 1995 Abstract The radiation shielding for an Advanced Photon Source (APS) insertion device beamline using a mirror as the first optical component is discussed. The beamline layout for a specific Synchrotron Radiation Instrumentation Collaborative Access Team beamline (sector 2 of SRI CAT) is described, and the methodology used to determine the radiation shielding is presented. Results indicate that, by using a x-ray mirror with a critical energy of 32 keV for total reflection, an undulator beam containing nearly all x-rays in the 0 - 32 keV spectral range can be delivered

220

ANL/APS/TB-5 Functional Description of APS Beamline Front Ends  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Description of APS Beamline Front Ends by Tuncer Kuzay February 1993 Advanced Photon Source & Argonne National Laboratory, Argonne, Illinois 60439 o operated by The University of Chicago for the United States Department of Energy under Contract W-31-1 09-Eng-38 Argonne National Laboratory, with facilties in the states of Ilinois and Idaho, is owned by the United States government, and operated by The University of Chicago under the provisions of a contract with the Deparment of Energy. DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any waranty, express or implied, or assumes any legal liability or responsibility for the accuracy,

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH)

1987-01-01T23:59:59.000Z

222

Battery with modular air cathode and anode cage  

DOE Patents (OSTI)

A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH); Turk, Thomas R. (Mentor, OH)

1988-01-01T23:59:59.000Z

223

Beam discharge excited by distributed virtual cathode  

Science Conference Proceedings (OSTI)

A new type of beam discharge, i.e., beam discharge with a distributed virtual cathode (VC) is proposed and considered by numerical simulation. The discharge is established during counter motion of high-current electron beams in a gas-filled equipotential cavity and is characterized by a state of hot dense electron plasma of primary electrons. The discharge temporal dynamics is studied. It is shown that the VC lifetime depends linearly from this sum in a wide range of the sum of beam currents, from the boundary current of two-beam instability to the critical current of Pierce instability. Generation of nonlinear electrostatic structures shaped as phase bubbles in the discharge is detected, and their dynamics is studied. The parameters are determined, at which the multiple coexistence of phase bubbles and their coalescence during collisions is observed.

Barabanov, V. N.; Dubinov, A. E.; Loiko, M. V.; Saikov, S. K.; Selemir, V. D. [All-Russia Research Institute of Experimental Physics, Russian Federal Nuclear Center (Russian Federation); Tarakanov, V. P. [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation)

2012-02-15T23:59:59.000Z

224

ANL progress in minimizing effects of LEU conversion on calcination of fission-product {sup 99}Mo acid waste solution.  

SciTech Connect

A partnership between Argonne National Laboratory (ANL), MDS Nordion (MDSN), Atomic Energy Canada Limited (AECL) and SGN (France) has addressed the conversion of the MAPLE Reactor 99Mo production process from high-enriched uranium (HEU) targets to low-enriched uranium (LEU) targets. One effect of the conversion would be to increase the amount of solid uranium waste five-fold; we have worked to minimize the effect of the additional waste on the overall production process and, in particular, solid waste storage. Two processes were investigated for the treatment of the uranium-rich acidic waste solution: direct calcination, and oxalate precipitation as a prelude to calcination. Direct calcination generates a dense UO3 solid that should allow a significantly greater amount of uranium in one waste container than is planned for the HEU process, but doing so results in undesirable sputtering. These results suggest that direct calcination could be adapted for use with LEU targets without a large effect on the uranium waste treatment procedures. The oxalate-calcination generates a lower-density granular U3O8 product; sputtering is not significant during calcination of the uranyl oxalate precipitate. A physical means to densify the product would need to be developed to increase the amount of uranium in each waste container. Future work will focus on the specific chemical reactions that occur during the direct and oxalate calcination processes.

Bakel, A.; Vandegrift, G.; Quigley, K.; Aase, S.; Neylon, M.; Carney, K.

2003-01-01T23:59:59.000Z

225

Alternative Fuel and Advanced Technology Vehicles Pilot Program Emissions  

Open Energy Info (EERE)

Alternative Fuel and Advanced Technology Vehicles Pilot Program Emissions Alternative Fuel and Advanced Technology Vehicles Pilot Program Emissions Benefit Tool Jump to: navigation, search LEDSGP green logo.png FIND MORE DIA TOOLS This tool is part of the Development Impacts Assessment (DIA) Toolkit from the LEDS Global Partnership. Tool Summary LAUNCH TOOL Name: Alternative Fuel and Advanced Technology Vehicles Pilot Program Emissions Benefit Tool Agency/Company /Organization: Argonne National Laboratory Sector: Energy Focus Area: Transportation Phase: Determine Baseline, Evaluate Options Topics: Co-benefits assessment, GHG inventory Resource Type: Online calculator, Software/modeling tools User Interface: Spreadsheet Complexity/Ease of Use: Moderate Website: www.transportation.anl.gov/modeling_simulation/AirCred/index.html

226

Advanced Vehicle Technology Analysis & Evaluation Team  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Technology Analysis and Evaluation Team Lee Slezak Manager, AVTAET Office of FreedomCAR and Vehicle Technologies DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. 2 Charter * AVTAET's mission is to develop and apply the tools and skills necessary to: - Identify technology development needs and requirements to support OFCVT goals and - Collect, analyze, and disseminate unbiased information on advanced transportation technology components, systems, and vehicles that potentially support OFCVT goals. * Goal of analytical groups at ANL, NREL and ORNL - Develop and apply modeling and simulation tools to help DOE, manufacturers and suppliers design and develop clean, energy efficient components and systems for

227

Advanced electrorefiner design  

DOE Patents (OSTI)

This invention relates to a process and apparatus for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium and a mixture of uranium and plutonium for use as fresh blanket and core fuel in a nuclear reactor. A combination anode and cathode is described for an electrorefiner which includes a hollow cathode and an anode positioned inside the hollow cathode such that a portion of the anode is near the cathode. A retaining member is positioned at the bottom of the cathode. Mechanism is included for providing relative movement between the anode and the cathode during deposition of metal on the inside surface of the cathode during operation of the electrorefiner to refine spent nuclear fuel. A method is also disclosed which includes electrical power means selectively connectable to the anode and the hollow cathode for providing electrical power to the cell components, electrically transferring uranium values and plutonium values from the anode to the electrolyte, and electrolytically depositing substantially pure uranium on the hollow cathode. Uranium and plutonium are deposited at a liquid cathode together after the PuCl{sub 3} to UCl{sub 3} ratio is greater than 2:1. Slots in the hollow cathode provides close anode access for the liquid pool in the liquid cathode.

Miller, W.E.; Gay, E.C.; Tomczuk, Z.

1994-12-31T23:59:59.000Z

228

Microsoft PowerPoint - Cathode contact materials PNNL.ppt [Compatibility Mode]  

NLE Websites -- All DOE Office Websites (Extended Search)

Cathode Cathode Contact Development of Cathode Contact Materials for SOFC J.W. Stevenson, G.G. Xia, Z. Lu, X. Li, Z. Nie, T. Oh, and J.D.Templeton Pacific Northwest National Laboratory Pacific Northwest National Laboratory Richland, WA 99352 July 27-29, 2010 July 27 29, 2010 11 th Annual SECA Workshop Pittsburgh, PA Cathode/Interconnect Contact Materials Cathode/Interconnect Contact Materials Cathode Chromia-forming Protective Coating Contact layer Chromia-forming alloy interconnect 2 Cathode/Interconnect Contact Materials Cathode/Interconnect Contact Materials Requirements: High electrical conductivity to reduce interfacial electrical resistance between cathode and interconnect Contact layer Chemical and structural stability in air at SOFC operating temperature Chemical compatibility with adjacent materials (perovskite cathode,

229

Comments on cathode contaminants and the LBNL test stand  

E-Print Network (OSTI)

stand: - replaced the brass piece with copper-tungsten -important to eliminate any brass parts that could exceed aof the cathode include brass, silver, zinc, non-OFHC copper,

Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

2006-01-01T23:59:59.000Z

230

Three-dimensional batteries using a liquid cathode  

E-Print Network (OSTI)

battery since lithium ions migrate back and forth between the anode and cathodelithium ions batteries. 54 This battery, which consists of mesocarbon microbeads (MCMB) anode and MoO y S z cathode

Malati, Peter Moneir

2013-01-01T23:59:59.000Z

231

Pulsed neutron generator using shunt between anode and cathode  

SciTech Connect

A pulsed neutron generator for well logging is provided having a resistor connected between the anode and cathode. The resistor provides a direct current path whereby corona current can flow between the cathode and a corona point without the necessity for the ion source to conduct. In an alternative embodiment, the secondary coil of a pulsing transformer is connected in series with a resistor between the anode and cathode. In an alternative embodiment, a corona regulator in series with the collector-emitter of a transistor is connected between the cathode and anode of the neutron source and the base drive to the transistor is provided by a light-responsive solar cell activatable by an external lamp. Circuitry is provided for utilizing the various neutron sources.

Culver, R.B.

1976-12-07T23:59:59.000Z

232

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

Jacobson, L.C. De Jonghe, in SOFC VI, S. C. Singhal and M.Y. Takeda, R. kanno, in SOFC I, S.C. Singhal Editor, p. 242,co-fired cathode-supported SOFC; reduced temperature SOFCs;

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

233

Various Cathodic Processes during Electro-Reduction of Solid ...  

Science Conference Proceedings (OSTI)

Cathodic Behavior of Silicon (?) in BaF2-CaF2 SiO2 Melts ... Electrochemical Impedance Spectroscopy of Uranium Chloride in Molten LiCl-KCl Eutectic.

234

Effect of Electrical Conductivity and Porosity of Cathode on Electro ...  

Science Conference Proceedings (OSTI)

Cathodic Behavior of Silicon (?) in BaF2-CaF2 SiO2 Melts ... Electrochemical Impedance Spectroscopy of Uranium Chloride in Molten LiCl-KCl Eutectic.

235

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

E-Print Network (OSTI)

hydrogen as a fuel. Co-firing of bi-layers and tri-layersstabilized zirconia (YSZ) [1]. Co-firing multi-layered cellssupporting cathode. Thus, the co-firing temperature and the

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2004-01-01T23:59:59.000Z

236

Development and processing of LEU targets for {sup 99}Mo production-overview of the ANL program  

SciTech Connect

Most of the world`s supply of {sup 99m}Tc for medical purposes is currently produced from the decay of {sup 99}Mo derived from the fissioning of high-enriched uranium (HEU). Substitution of low-enriched uranium (LEU) silicide fuel for the HEU alloy and aluminide fuels used in most current target designs will allow equivalent {sup 99}Mo yields with little change in target geometries. Substitution of uranium metal for uranium oxide films in other target designs will also allow the substitution of LEU for HEU. During 1995, we have continued to study the modification of current targets and processes to allow the conversion from HEU to LEU. A uranium-metal-foil target was fabricated at ANL and irradiated to prototypic burnup in the Indonesian RSG-GAS reactor. Postirradiation examination indicated that minor design modifications will be required to allow the irradiated foil to be removed for chemical processing. Means to dissolve and process LEU foil have been developed, and a mock LEU foil target was processed in Indonesia. We have also developed means to dissolve the LEU foil in alkaline peroxide, where it can be used to replace HEU targets that are currently dissolved in base before recovering and purifying the {sup 99}Mo. We have also continued work on the dissolution of U{sub 3}Si{sub 2} and have a firm foundation on dissolving these targets in alkaline peroxide. The technology-exchange agreement with Indonesia is well underway, and we hope to expand our international cooperations in 1996.

Snelgrove, J.L.; Hofman, G.L.; Wiencek, T.C. [and others

1995-09-01T23:59:59.000Z

237

Preparation of redox polymer cathodes for thin film rechargeable batteries  

DOE Patents (OSTI)

The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

1994-11-08T23:59:59.000Z

238

Li batteries with porous sol-gel cathodes  

Science Conference Proceedings (OSTI)

The structure presented is a high-capacity micro battery, lithium based, consisting of porous cathode, solid electrolyte and silver anode. A spinel LiNi"0"."4La"0"."1Mn"1"."5O"4 sol-gel layer was deposited on a porous ceramic substrate to give high specific ... Keywords: Layer oxides, Li ion batteries, Porous cathode, Sol-gel

Antonela Dima; Francesco Della Corte; Maurizio Casalino; Ivo Rendina

2007-04-01T23:59:59.000Z

239

Chromium (V) compounds as cathode material in electrochemical power sources  

SciTech Connect

A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca.sub.5 (CrO.sub.4).sub.3 Cl, Ca.sub.5 (CrO.sub.4).sub.3 OH, and Cr.sub.2 O.sub.5. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

Delnick, Frank M. (Albuquerque, NM); Guidotti, Ronald A. (Albuquerque, NM); McCarthy, David K. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

240

Cathodic Protection of the Yaquina Bay Bridge  

SciTech Connect

The Yaquina Bay Bridge in Newport, Oregon, was designed by Conde B. McCullough and built in 1936. The 3,223-foot (982 m) structure is a combination of concrete arch approach spans and a steel through arch over the shipping channel. Cathodic protection is used to prevent corrosion damage to the concrete arches. The Oregon Department of Transportation (Oregon DOT) installed a carbon anode coating (DAC-85) on two of the north approach spans in 1985. This anode was operated at a current density of 6.6 mA/m2(0.6 mA/ft2). No failure of the conductive anode was observed in 1990, five years after application, or in 2000, 15 years after application. Thermal-sprayed zinc anodes 20 mils (0.5 mm) thick were applied to half the south approach spans beginning in 1990. Thermal-sprayed zinc anodes 15 mils (0.4 mm) thick were applied to the remaining spans in 1996. These anodes were operated at a current density of 2.2 mA/m2(0.2 mA/ft2). In 1999, four zones on the approach spans were included in a two-year field trial of humectants to improve zinc anode performance. The humectants LiNO3 and LiBr were applied to two zones; the two adjacent zones were left untreated as controls. The humectants substantially reduced circuit resistance compared to the controls.

Bullard, Sophie J.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Laylor, H.M.; Cryer, C.B.

2001-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Three-Dimensional Thermal Tomography Advances Cancer Treatment  

Jiangang Sun Contact Argonne Technology Development and Commercialization partners@anl.gov ne_TT3Dfs_0812. Title:

242

Operations Analysis - Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Ring Chief of Operations Argonne National Laboratory Bldg 401B2150 9700 S. Cass Avenue Argonne, IL 60439 (630) 252-5949 office (630) 252-5703 FAX schroedr@aps.anl.gov...

243

Operations Analysis - Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

9700 S. Cass Avenue Argonne, IL 60439 (630) 252-1148 office (630) 252-5703 FAX gfystro@aps.anl.gov Areas of interest Operator training program development Operations Group Wiki...

244

Operations Analysis - Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

401-B2205 9700 S. Cass Avenue FAX number: 5703 Argonne, IL 60439 Email Internet: xiaoam@aps.anl.gov Areas of interest Design and simulation of damping rings for linear colliders....

245

Operations Analysis - Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

9700 S. Cass Avenue Argonne, IL 60439 (630)-252-8689 office (630)-252-5703 fax shang@aps.anl.gov Areas of Interest Parellel computing SDDS ToolKit development SDDSEPICS...

246

Operations Analysis - Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

S. Cass Avenue FAX number: 5703 Argonne, IL 60439 Email pager: 1766 Email Internet: cyao@aps.anl.gov Areas of interest Operations-related accelerator physics for storage ring, PAR,...

247

Neutronics, steady-state, and transient analyses for the Poland MARIA reactor for irradiation testing of LEU lead test fuel assemblies from CERCA : ANL independent verification results.  

Science Conference Proceedings (OSTI)

The MARIA reactor at the Institute of Atomic Energy (IAE) in Swierk (30 km SE of Warsaw) in the Republic of Poland is considering conversion from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel assemblies (FA). The FA design in MARIA is rather unique; a suitable LEU FA has never been designed or tested. IAE has contracted with CERCA (the fuel supply portion of AREVA in France) to supply 2 lead test assemblies (LTA). The LTAs will be irradiated in MARIA to burnup level of at least 40% for both LTAs and to 60% for one LTA. IAE may decide to purchase additional LEU FAs for a full core conversion after the test irradiation. The Reactor Safety Committee within IAE and the National Atomic Energy Agency in Poland (PAA) must approve the LTA irradiation process. The approval will be based, in part, on IAE submitting revisions to portions of the Safety Analysis Report (SAR) which are affected by the insertion of the LTAs. (A similar process will be required for the full core conversion to LEU fuel.) The analysis required was established during working meetings between Argonne National Laboratory (ANL) and IAE staff during August 2006, subsequent email correspondence, and subsequent staff visits. The analysis needs to consider the current high-enriched uranium (HEU) core and 4 core configurations containing 1 and 2 LEU LTAs in various core positions. Calculations have been performed at ANL in support of the LTA irradiation. These calculations are summarized in this report and include criticality, burn-up, neutronics parameters, steady-state thermal hydraulics, and postulated transients. These calculations have been performed at the request of the IAE staff, who are performing similar calculations to be used in their SAR amendment submittal to the PAA. The ANL analysis has been performed independently from that being performed by IAE and should only be used as one step in the verification process.

Garner, P. L.; Hanan, N. A. (Nuclear Engineering Division)

2011-06-07T23:59:59.000Z

248

Transient analysis for the tajoura critical facility with IRT-2M HEU fuel and IRT-4M leu fuel : ANL independent verification results.  

SciTech Connect

Calculations have been performed for postulated transients in the Critical Facility at the Tajoura Nuclear Research Center (TNRC) in Libya. These calculations have been performed at the request of staff of the Renewable Energy and Water Desalinization Research Center (REWDRC) who are performing similar calculations. The transients considered were established during a working meeting between ANL and REWDRC staff on October 1-2, 2005 and subsequent email correspondence. Calculations were performed for the current high-enriched uranium (HEU) core and the proposed low-enriched uranium (LEU) core. These calculations have been performed independently from those being performed by REWDRC and serve as one step in the verification process.

Garner, P. L.; Hanan, N. A.

2005-12-02T23:59:59.000Z

249

anl_mira.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

Blue Gene Performance Data Repository and Blue Gene Performance Data Repository and Application Data Prefetching I-Hsin Chung ihchung@us.ibm.com © 2013 IBM Corporation Performance Data Repository § Goal - To characterize the applications on existing systems - To understand the system resource usage * To provide inputs for next generation system design § Objective - Collect performance data and store them into a relational database - Uniform storage format * to support queries and presentation * To make comparisons cross applications or platforms © 2013 IBM Corporation Application Performance data/trace Application Job execution Performance data/trace instrumentation collection © 2013 IBM Corporation 4 Performance Data Repository DB2 bgqsn2 grotius Blue Gene Compute nodes mgmt

250

ANL News 2004  

NLE Websites -- All DOE Office Websites (Extended Search)

4 Articles 4 Articles Argonne News is the Argonne weekly employee newsletter. This page contains Argonne News articles that focus on the APS. Structure of germanium-dioxide glass Glass gives up secrets under pressure (Dec. 10) Glass is a mysterious material, but when researchers apply pressure, it reveals secrets. Using a variety of techniques at the APS and the IPNS, Argonne researchers saw for the first time ever, the atomic structure of a dense, purely octahedral glass that has eluded scientists for decades. They also witnessed a continuous structural change in the glass, disproving the theory that tetrahedral glasses go through a distinct transition between low- and high-density phases. A µSXRF map showing the heterogeneous uranium distribution occurring at the micrometer scale. This and related research is helping learn more about how to clean up contaminated soil at nuclear weapons production sites.

251

ANL-678A  

NLE Websites -- All DOE Office Websites (Extended Search)

Systems Approval Form Systems Approval Form For use at Argonne National Laboratory Division: Responsible Person: System Name: System Description: Manufacturer: Number of pieces of equipment: Date Built: Date last modified: Building: Room: Subsystems 1. Electrical hazard classification 2. Stored electrical energy in capacitors (E and V) 3. Batteries, including UPSs 4. Electromagnetic fields produced (dc to 300 GHz, pulsed) 5. Infrared, optical and ultraviolet 6. X-Rays 7. Heat and sparks 8. Acoustical energy 9. Stored mechanical energy 10. Other (chemical, high pressure, cryogen, water, etc.) Label Number: SECTION 1 - EQUIPMENT DATA: SECTION 2 - HAZARD ASSESSMENT: Determine all electrical and non-electrical hazards that could injure an employee, including the operation and maintenance workers.

252

ANL-678A  

NLE Websites -- All DOE Office Websites (Extended Search)

Non-NRTL/Modified NRTL Listed Electrical Equipment Approval Form Non-NRTL/Modified NRTL Listed Electrical Equipment Approval Form For use at Argonne National Laboratory Equipment Location Unlisted equipment that is determined to be safe to operate will have a tracking sticker attached for identification. Equipment that does not pass this evaluation will have a REJECTED sticker attached. Operator not exposed to any hazard Not damaged Enclosure Appropriate materials used Protects contents from operating environment Adequate shock protection (components well secured) Will contain any arcs, sparks and electrical explosions Grounding Approve N/A Ground is properly terminated All non-current carrying exposed metal is properly bonded All non-current carrying internal subsystems are properly bonded Equipment ground is run with circuit conductors

253

ANL News 2005  

NLE Websites -- All DOE Office Websites (Extended Search)

themselves in alternating layers one atom thick Mixed metals not so mixed up at the nano-level (Nov. 25) With the help of the Western Hemisphere's most brilliant hard X-ray...

254

ANL-01/1  

NLE Websites -- All DOE Office Websites (Extended Search)

for the CP-3 reactor located at Site A, together with various pipes, valves, and building debris, was buried in place in 1956. 1-2 1-3 1-4 Burial of radioactive waste at Plot M...

255

mcs.anl.gov  

E-Print Network (OSTI)

Sep 19, 2005... Department of Energy, under Contract W-31-109-ENG-38. .... The first description (green circles) was generated from a uniform distribution.

256

ANL/ES-79 ANL/ES-79 ENVIRONMENTAL ANALYSIS OF A FORMERLY UTILIZED...  

NLE Websites -- All DOE Office Websites (Extended Search)

Kankakee River to form the Illinois River. The major uses of the waterway are navigation, waste dilution for sewage treatment effluent and storm runoff from Chicago, and channeling...

257

Argonne TDC: Baxter - ANL  

Michael Pellin (left) and Dieter Gruen (both of Argonne's Materials Sciences Division) co-discovered the medical applications of the excimer laser with the late ...

258

I. PURPOSE - ANL  

What is the current value of a share of stock? What is the equity position, in dollars and shares, provided in exchange for the license (or upfront fee)?

259

ANL News 2006  

NLE Websites -- All DOE Office Websites (Extended Search)

could lead to environmentally safe disposal methods. APS X-rays reveal the real chemistry behind mercury mixed in mustard agent (Jan. 13) The U.S government's effort to...

260

anl_mira.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

Relational Database 2013 IBM Corporation IBM Confidential 5 How to use it? Link the application with performance tool - Link the profiler libraries (e.g.,...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

ANL/ES-80 ANL/ES-80 ENGINEERING EVALUATION OF A FORMERLY UTILIZED...  

NLE Websites -- All DOE Office Websites (Extended Search)

Bulldozer 31,750 20 6,400 Air ram hoe 8,900 30 2,700 Overhead clamshell 167,500 30 50,000 Pneumatic saw 1,000 30 300 Rock splitter 33,550 30 10,100 Jackhammers, compressors 23,600...

262

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

2008-04-30T23:59:59.000Z

263

TransForumNews from Argonne's Transportation Technology R&D Center www.transportation.anl.gov  

E-Print Network (OSTI)

Giovanni Ramirez Gonzalez prepares a nanolubricant for friction and wear measurement. #12;Volume 12 | Issue-based advanced nanolubricants that can be added to existing oils to improve lubricity by up to 50 percent

Kemner, Ken

264

TransForumNews from Argonne's Transportation Technology R&D Center www.transportation.anl.gov  

E-Print Network (OSTI)

friction, including: 4 Boron-based advanced nanolubricants that can be added to existing oils to improve Ramirez Gonzalez prepares a nanolubricant for friction and wear measurement. From left to right: Jair

Kemner, Ken

265

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading  

NLE Websites -- All DOE Office Websites (Extended Search)

2009 DOE EERE Kick-off Meeting 2009 DOE EERE Kick-off Meeting Announcement No: DE-PS36-08GO98010 Topic: 1A Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading Argonne National Laboratory Materials Science Division PI: Nenad M. Markovic Co-PI: Vojislav R. Stamenkovic Subcontractors: * Oak Ridge National Laboratory - Karren More * Jet Propulsion Laboratory - NASA - S.R. Narayan * Brown University - Shouheng Sun * Indiana University Purdue - Goufeng Wang * 3M Company - Radoslav Atanasoski Overview Timeline * Project start: 9/2009 * Project end: 9/2012 Barriers ~ 30-40% (!!!) Cathode kinetics * The main losses: CATHODE 1) High content of Pt 2) Poor activity: Pt/C = Pt-poly/10 3) Durability (Pt dissolves: power loss) 4) Carbon support corrosion Budget * Total Project funding $ 6.5M

266

A filtered cathodic arc deposition apparatus and method  

DOE Patents (OSTI)

A filtered cathodic arc deposition method and apparatus are described for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

Krauss, Alan R.

1997-12-01T23:59:59.000Z

267

Process system and method for fabricating submicron field emission cathodes  

SciTech Connect

A process method and system for making field emission cathodes exists. The deposition source divergence is controlled to produce field emission cathodes with height-to-base aspect ratios that are uniform over large substrate surface areas while using very short source-to-substrate distances. The rate of hole closure is controlled from the cone source. The substrate surface is coated in well defined increments. The deposition source is apertured to coat pixel areas on the substrate. The entire substrate is coated using a manipulator to incrementally move the whole substrate surface past the deposition source. Either collimated sputtering or evaporative deposition sources can be used. The position of the aperture and its size and shape are used to control the field emission cathode size and shape.

Jankowski, Alan F. (Livermore, CA); Hayes, Jeffrey P. (Ripon, CA)

1998-01-01T23:59:59.000Z

268

Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Argonne Lab's Breakthrough Cathode Technology Powers Electric Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today February 14, 2011 - 6:15pm Addthis Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR David Moore Presidential Management Fellow, Office of Energy Efficiency & Renewable Energy The Department of Energy has been investing in vehicle electrification for more than a decade, with results that speak for themselves: The battery technologies in almost all of the electric vehicles and hybrids on the road today were developed with support from the Department. As you may have read

269

Electron current extraction from a permanent magnet waveguide plasma cathode  

SciTech Connect

An electron cyclotron resonance plasma produced in a cylindrical waveguide with external permanent magnets was investigated as a possible plasma cathode electron source. The configuration is desirable in that it eliminates the need for a physical antenna inserted into the plasma, the erosion of which limits operating lifetime. Plasma bulk density was found to be overdense in the source. Extraction currents over 4 A were achieved with the device. Measurements of extracted electron currents were similar to calculated currents, which were estimated using Langmuir probe measurements at the plasma cathode orifice and along the length of the external plume. The influence of facility effects and trace ionization in the anode-cathode gap are also discussed.

Weatherford, B. R.; Foster, J. E. [University of Michigan, Ann Arbor, Michigan 48109 (United States); Kamhawi, H. [NASA Glenn Research Center, Cleveland, Ohio 44135 (United States)

2011-09-15T23:59:59.000Z

270

LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles  

DOE Green Energy (OSTI)

To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ.; De Jonghe, Lutgard C.

2006-01-31T23:59:59.000Z

271

Axis-1 diode simulations I: standard 2-inch cathode  

SciTech Connect

The standard configuration of the DARHT Axis-I diode features a 5.08-cm diameter velvet emitter mounted in the flat surface of the cathode shroud. The surface of the velvet is slightly recessed {approx}2.5 mm. This configuration produces a 1.75 kA beam when a 3.8-MV pulse is applied to the anode-cathode (AK) gap. This note addresses some of the physics of this diode through the use of finite-element simulations.

Ekdahl, Carl [Los Alamos National Laboratory

2011-01-11T23:59:59.000Z

272

Cathode-preparation method for molten-carbonate fuel cell  

DOE Green Energy (OSTI)

A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

Smith, J.L.; Sim, J.W.; Kucera, E.H.

1982-01-28T23:59:59.000Z

273

Thermal Instability of Olivine-type LiMnPO4 Cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermal Instability of Olivine-type LiMnPO4 Cathodes Title Thermal Instability of Olivine-type LiMnPO4 Cathodes Publication Type Journal Article Year of Publication 2010 Authors...

274

Monolithic solid oxide fuel cell technology advancement for coal-based power generation  

DOE Green Energy (OSTI)

The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

Not Available

1992-04-14T23:59:59.000Z

275

Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating  

DOE Green Energy (OSTI)

This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

Feng Jin

2009-01-07T23:59:59.000Z

276

Comments on cathode contaminants and the LBNL test stand  

Science Conference Proceedings (OSTI)

This report collects information on cathode contaminants we have gathered in the process of operating the LBNL DARHT cathode test stand. Information on contaminants is compiled from several sources. The attachment, ''Practical Aspects of Modern Dispenser Cathodes'', is from Heat Wave Corp. (TB-134) and was originally published in Microwave Journal, September 1979. Cathode contamination depends on both material choices and residual gases. Table 1 of TB-134 lists materials that can poison dispenser cathodes. These include reactive residual gases or vapors such as oxygen, water vapor, benzene, chlorine, fluorine, sulfur, silicon, and most metals other than molybdenum, rhenium, tungsten, and copper. The metals interact with the cathode surface through their vapor pressure. A paper by Nexsen and Turner, J. Appl. Phys. 68, 298-303 (1990) shows the threshold effects of some common residual gases or vapors on cathode performance. The book by Walter H. Kohl, Handbook of Materials and Techniques for Vacuum Devices, also contains useful information on cathodes and poisoning agents. A plot of the vapor pressures and poisoning effect of certain metals (from Kohl) is shown below. Note that the vapor pressure of zinc is 1.1 x 10{sup -8} Torr at 400 K = 127 C, and 2.7 x 10{sup -5} at 500 K = 227 C. By contrast iron reaches a vapor pressure 1 x 10{sup -8} between 800 and 900 C. Therefore it is important to eliminate any brass parts that could exceed a temperature of 100 C. Many structural components of the cathode assembly contain steel. At 500-600 C in an oxygen atmosphere chromium oxide may outgas from the steel. [Cho, et.al., J. Vac. Sci. Technol. A 19, p. 998 (2001)]. Steel may also contain silicon, and sulfur at low concentrations. Therefore use of steel should be limited or avoided at high temperature near the cathode. Materials that should be avoided in the vicinity of the cathode include brass, silver, zinc, non-OFHC copper, silicates, and sulfur-containing lubricants such molybdenum disulfide. Macor is an aluminosilicate-based insulator that is not stable at high temperature. Macor near the cathode should be replaced by a high-temperature insulator such as alumina ceramic. Other insulating materials that contain silicates, such as fiber insulating sleeves, should be avoided. Copper that is not OFHC contains oxygen and other impurities and should be avoided. Lubricating screw coatings should be chosen carefully to have no sulfur content. Common sources of contamination that can cause low emission include water, saliva, silicates such as glass dust, etc. Cathodes should be handled in near clean-room conditions to minimize the amount of water vapor on the cathode surface from breathing, etc. Cathodes should also be stored in such as a way as to avoid contact with materials such as glass dust and water vapor. Attached are plots of SEM data for several test pieces that were taken from the LBNL test stand after activation of the 311x scandate DARHT cathode. Several copper pieces in the anode region were tested, showing the presence of zinc. Two stainless steel nuts coated with a contaminant were also tested. The SEM data indicates the presence of zinc and some sulfur. The zinc has been traced to a brass piece, and the sulfur to the possible use of molybdenum disulfide lubricant on a nut in the system. Finally a swipe of contaminant on the vacuum vessel wall analyzed by a commercial testing laboratory shows again the presence of zinc. In order to improve system cleanliness, we have implemented the following modifications to the test stand: replaced the brass piece with copper-tungsten; replaced Macor insulators with alumina ceramic; used boron nitride lubricant; replaced copper beam stop with OFHC copper; and replaced steel pieces near the cathode where possible with copper or copper-tungsten. A clean fire of high-temperature components and a high-current filament test have shown no evidence to date for contaminants since the modifications.

Bieniosek, F.; Baca, D.; Greenway, W.; Leitner, M.; Kwan, J.W.

2006-11-13T23:59:59.000Z

277

Corrosion Resistance of Cathode to NaF-KF-ALF3-Based Electrolyte  

Science Conference Proceedings (OSTI)

Electrical Resistance of Graphitic and Graphitized Cathode Materials at Elevated Temperatures Electrochemical Investigation of Potassium Intercalation into...

278

Advanced Gasification  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Gasification Carbon feedstock gasification is a promising pathway for high-efficiency, low-pollutant power generation and chemical production. The inability, however, to...

279

Advanced Ceramics  

Science Conference Proceedings (OSTI)

Table 3   Raw materials for advanced structural and magnetic (ferrite) ceramics...conductivity Wear resistance Oxygen sensors, fuel cells (potential), high-temperature

280

Advanced Manufacturing  

Science Conference Proceedings (OSTI)

... new metrologically-based methods for industry as well ... for Advanced Catalyst Development and Durability ... Electron-Beam Irradiation of Solar Cells. ...

2013-07-29T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High-current electron beam generation by a pulsed hollow cathode  

Science Conference Proceedings (OSTI)

In this paper the parameters of a hollow-cathode electron source and the generatedelectron beam are presented. A gas puff valve is used to provide a sharp pressure gradient between the cathode cavity and the accelerating gap. To produce the plasma inside the hollow cathode we used a pulse forming network (10 kV

J. Z. Gleizer; A. Krokhmal; Ya. E. Krasik; J. Felsteiner

2002-01-01T23:59:59.000Z

282

Cathode porous transport irreversibility model for PEM fuel cell design  

Science Conference Proceedings (OSTI)

The influence is studied of slip-irreversibility at the interface between the gas diffusion layer, also referred to here as the porous transport layer, and the catalyst layer of a proton exchange membrane fuel cell (PEMFC). A two-dimensional cathode ... Keywords: catalyst layer, exergy, gas diffusion layer, slip flow irreversibility

E. O. B. Ogedengbe; M. A. Rosen

2009-02-01T23:59:59.000Z

283

Rigid indented cylindrical cathode for X-ray tube  

DOE Patents (OSTI)

A cathode assembly for a vacuum tube includes a wire filament, a straight bular anode parallel to and surrounding the wire filament, and insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

Hudgens, Claude R. (Dayton, OH)

1985-01-01T23:59:59.000Z

284

Operational test report -- Project W-320 cathodic protection systems  

Science Conference Proceedings (OSTI)

Washington Administrative Code (WAC) 173-303-640 specifies that corrosion protection must be designed into tank systems that treat or store dangerous wastes. Project W-320, Waste Retrieval Sluicing System (WRSS), utilizes underground encased waste transfer piping between tanks 241-C-106 and 241-AY-102. Corrosion protection is afforded to the encasements of the WRSS waste transfer piping through the application of earthen ionic currents onto the surface of the piping encasements. Cathodic protection is used in conjunction with the protective coatings that are applied upon the WRSS encasement piping. WRSS installed two new two rectifier systems (46 and 47) and modified one rectifier system (31). WAC 173-303-640 specifies that the proper operation of cathodic protection systems must be confirmed within six months after initial installation. The WRSS cathodic protection systems were energized to begin continuous operation on 5/5/98. Sixteen days after the initial steady-state start-up of the WRSS rectifier systems, the operational testing was accomplished with procedure OTP-320-006 Rev/Mod A-0. This operational test report documents the OTP-320-006 results and documents the results of configuration testing of integrated piping and rectifier systems associated with the W-320 cathodic protection systems.

Bowman, T.J.

1998-06-16T23:59:59.000Z

285

Inert anodes and advanced smelting of aluminum  

SciTech Connect

This report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issued associated with these technologies from a technical, environmental, and economic viewpoint. It discusses the outlook for the direct retrofit of advanced reduction technologies to existing aluminum smelters, and compares retrofits to ''brown field'' usage and ''green field'' adoption of the technologies. A number of observations and recommendations are offered for consideration concerning further research and development efforts that may be directed toward these advanced technologies. The opportunities are discussed in the context of incremental progress that is being made in conventional Hall-Heroult cell systems.

ASME Technical Working Group on Inert Anode Technologies

1999-07-01T23:59:59.000Z

286

Preprint of a paper to appear in Proc. 14th Unmanned Untethered Submersible Technology, Durham, New Hampshire  

E-Print Network (OSTI)

(EV, HEV, and Plug-in hybrid) · Presently, the focus is on lithium-based systems (Li-ion and Li ­ Composite cathode materials (ANL) licensed to one materials company and one battery company #12;BATT ProgramOverview of the Batteries for Advanced Transportation Technologies (BATT) Program Venkat Srinivasan

Griffiths, Gwyn

287

Microsoft PowerPoint - 9-04 Westsik Hanford SWFT EM Tech Exchange PNNL-SA-76075 ANL r2.pptx  

NLE Websites -- All DOE Office Websites (Extended Search)

Secondary Waste Form Secondary Waste Form Testing Joseph H. Westsik, Jr. EM Pierce, W Um, RP Pires, RJ Serne, SK Sundaram, GB Josephson Pacific Northwest National Laboratory W Gong, W Lutze, CUA/VSL, D Singh, ANL EM Waste Processing Technical Exchange November 16-18, 2010 Print Close Secondary Waste Form Testing Purpose: Conduct a testing program to support a waste form down selection and the long-term durability evaluation of a waste form(s) for the solidification of secondary wastes from the treatment and immobilization of Hanford radioactive tank wastes. Client: Washington River Protection Solutions Phase 1: Identify and assess viability of waste form candidates Phase 2: Develop, optimize, and characterize waste forms to support down selection Phase 3: Provide data on the selected waste form to

288

Transient analyses for the Uzbekistan VVR-SM reactor with IRT-3M HEU fuel and IRT-4M LEU fuel : ANL independent verification results.  

Science Conference Proceedings (OSTI)

Calculations have been performed for postulated transients in the VVR-SM Reactor at the Institute of Nuclear Physics (INP) of the Academy of Sciences in the Republic of Uzbekistan. (The reactor designation in Cyrillic is BBP-CM; transliterating characters to English gives VVRSM but translating words gives WWR-SM.) These calculations have been performed at the request of staff of the INP who are performing similar calculations. The transients considered were established during working meetings between Argonne National Laboratory (ANL) and INP staff during summer 2006 [Ref. 1], subsequent email correspondence, and subsequent staff visits. Calculations were performed for the current high-enriched uranium (HEU) core, the proposed low-enriched uranium (LEU) core, and one mixed HEU-LEU core during the transition. These calculations have been performed independently from those being performed by INP and serve as one step in the verification process.

Garner, P. L.; Hanan, N. A.; Nuclear Engineering Division

2007-09-24T23:59:59.000Z

289

Advanced Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Materials Advanced Materials Advanced Materials Express Licensing Active Terahertz Metamaterial Devices Express Licensing Anion-Conducting Polymer, Composition, And Membrane Express Licensing Analysis Of Macromolecule, Liggands And Macromolecule-Lingand Complexes Express Licensing Carbon Microtubes Express Licensing Chemical Synthesis Of Chiral Conducting Polymers Express Licensing Forming Adherent Coatings Using Plasma Processing Express Licensing Hydrogen Scavengers Express Licensing Laser Welding Of Fused Quartz Express Licensing Multiple Feed Powder Splitter Negotiable Licensing Boron-10 Neutron Detectors for Helium-3 Replacement Negotiable Licensing Insensitive Extrudable Explosive Negotiable Licensing Durable Fuel Cell Membrane Electrode Assembly (MEA) Express Licensing Method of Synthesis of Proton Conducting Materials

290

Corrosion performance of advanced structural materials in sodium.  

SciTech Connect

This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L. (Nuclear Engineering Division)

2012-05-16T23:59:59.000Z

291

Advanced Photon Source | Combining Scanning Probe Microscopy and  

NLE Websites -- All DOE Office Websites (Extended Search)

0.21.2013 0.21.2013 Scientists study old photos for new solutions to corrosion Each week, Viewpoints features interviews with guests that have expertise and real-word experience regarding specific issues. The program is aired on over 450 radio stations throughout the country. This weeks featured guests are Volker Rose, Physicist with the Advanced Photon Source and Center for Nanoscale Materials, Argonne National Laboratory, (www.anl.gov). and Edward Vicenzi, Research scientist at the Smithsonian Institution's Museum Conservation Institute, (www.si.edu/mci). Material failure caused by corrosion is dangerous and costs billions of dollars every year. What if you could figure out how to prevent and treat corrosion at the tiniest "nano" level before it has a chance to cause a

292

1st Workshop on Photo-cathodes: 300nm-500nm July 20-21, 2009: University of Chicago  

E-Print Network (OSTI)

-function engineering 10:30 - 11:00 Enhancing Photon Absorption: Anti-reflection Coatings, Reflecting Sub- strates:15 - 11:45 Aerogel Photocathodes Michael Pellin (ANL) 11:45 - 12:15 New Ideas Daniel Ferenc (UC Davis

293

Advanced Ceramics  

Science Conference Proceedings (OSTI)

Table 2   Classification of advanced ceramics...solid electrolytes, piezoelectrics, dielectrics, superconductors Optical Low absorption coefficient Lamps, windows, fiber optics, infrared optics Nuclear Irradiation resistance, high absorption coefficient,

294

Advanced Manufacturing Office: Solicitations  

NLE Websites -- All DOE Office Websites (Extended Search)

Solicitations on Twitter Bookmark Advanced Manufacturing Office: Solicitations on Google Bookmark Advanced Manufacturing Office: Solicitations on Delicious Rank Advanced...

295

Advanced Manufacturing Office: Webcasts  

NLE Websites -- All DOE Office Websites (Extended Search)

Office: Webcasts on Twitter Bookmark Advanced Manufacturing Office: Webcasts on Google Bookmark Advanced Manufacturing Office: Webcasts on Delicious Rank Advanced...

296

Advanced Manufacturing Office: Subscribe  

NLE Websites -- All DOE Office Websites (Extended Search)

Office: Subscribe on Twitter Bookmark Advanced Manufacturing Office: Subscribe on Google Bookmark Advanced Manufacturing Office: Subscribe on Delicious Rank Advanced...

297

Advanced Manufacturing Office: Workshops  

NLE Websites -- All DOE Office Websites (Extended Search)

Office: Workshops on Twitter Bookmark Advanced Manufacturing Office: Workshops on Google Bookmark Advanced Manufacturing Office: Workshops on Delicious Rank Advanced...

298

Internal cathodic protection of cement-lined steel pipes  

SciTech Connect

Internally coated, cement-lined, carbon steel pipes have been used extensively for ballast- and service-water systems offshore. Mechanical cracking of the lining, undercutting, and erosion have resulted in corrosion and system leaks. Cathodic protection is one alternative that has been evaluated as a solution. Cathodic protection normally gives limited protection when applied internally to a pipeline system. Tests have been performed to evaluate this hypothesis and the possibility of improved current distribution due to the cement lining. This paper presents the test results as well as a solution to the problem. Internally coated, cement-lined steel pipes are used for ballast-water, service-water, and fire-water systems in the offshore oil and gas production industry.

Jensen, F.O. (Sharpnord Corrosion, P.O. Box 46, 3971 Langesund (NO)); Tems, R.D. (Mobil Exploration Norway, Inc., P.O. Box 510, 4001 Stavanger (NO))

1988-07-01T23:59:59.000Z

299

Negative ion source with hollow cathode discharge plasma  

SciTech Connect

A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

Hershcovitch, Ady (Mt. Sinai, NY); Prelec, Krsto (Setauket, NY)

1983-01-01T23:59:59.000Z

300

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, Eugene (Coram, NY)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Additive for iron disulfide cathodes used in thermal batteries  

DOE Patents (OSTI)

The invention comprises thermal batteries employing an FeS.sub.2 depolarizer, i.e. cathode material, and the depolarizer itself. A minor amount of CaSi.sub.2 preferably, 1-3% by weight is provided as an additive in the FeS.sub.2 depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS.sub.2 by weight generally comprises 64-90%.

Armijo, James R. (Albuquerque, NM); Searcy, Jimmie Q. (Albuquerque, NM)

1983-01-01T23:59:59.000Z

302

Formation of metal oxides by cathodic arc deposition  

DOE Green Energy (OSTI)

Metal oxide thin films are of interest for a number of applications. Cathodic arc deposition, an established, industrially applied technique for formation of nitrides (e.g. TiN), can also be used for metal oxide thin film formation. A cathodic arc plasma source with desired cathode material is operated in an oxygen atmosphere, and metal oxides of various stoichiometric composition can be formed on different substrates. We report here on a series of experiments on metal oxide formation by cathodic arc deposition for different applications. Black copper oxide has been deposited on ALS components to increase the radiative heat transfer between the parts. Various metal oxides such as tungsten oxide, niobium oxide, nickel oxide and vanadium oxide have been deposited on ITO glass to form electrochromic films for window applications. Tantalum oxide films are of interest for replacing polymer electrolytes. Optical waveguide structures can be formed by refractive index variation using oxide multilayers. We have synthesized multilayers of Al{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/AI{sub 2}O{sub 3}/Si as possible basic structures for passive optoelectronic integrated circuits, and Al{sub 2-x}Er{sub x}O{sub 3} thin films with a variable Er concentration which is a potential component layer for the production of active optoelectronic integrated devices such as amplifiers or lasers at a wavelength of 1.53 {mu}m. Aluminum and chromium oxide films have been deposited on a number of substrates to impart improved corrosion resistance at high temperature. Titanium sub-oxides which are electrically conductive and corrosion resistant and stable in a number of aggressive environments have been deposited on various substrates. These sub-oxides are of great interest for use in electrochemical cells.

Anders, S.; Anders, A.; Rubin, M.; Wang, Z.; Raoux, S.; Kong, F.; Brown, I.G.

1995-03-01T23:59:59.000Z

303

Negative ion source with hollow cathode discharge plasma  

DOE Patents (OSTI)

A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

Hershcovitch, A.; Prelec, K.

1980-12-12T23:59:59.000Z

304

Fuel cell having dual electrode anode or cathode  

DOE Patents (OSTI)

A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

Findl, E.

1984-04-10T23:59:59.000Z

305

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, further measurements of the oxygen deficient double perovskite PrBaCo{sub 2}O{sub 5.5+{delta}} are reported. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. Preliminary measurements in symmetric cells have shown low ASR values at 600 C. Here we describe the first complete cell measurements on Ni/CGO/CGO/PBCO/CGO cells.

Allan J. Jacobson

2006-06-30T23:59:59.000Z

306

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode--electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. In this report, the oxygen exchange kinetics of a P2 composition are described in detail. The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) have been determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells.

Allan J. Jacobson

2005-11-17T23:59:59.000Z

307

Process for Low Cost Domestic Production of LIB Cathode Materials  

DOE Green Energy (OSTI)

The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASFs battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASFs already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEMs and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

Thurston, Anthony

2012-10-31T23:59:59.000Z

308

Development of improved cathodes for solid oxide fuel cells  

DOE Green Energy (OSTI)

The University of Missouri-Rolla conducted a 17 month research program focused on the development and evaluation of improved cathode materials for solid oxide fuel cells (SOFC). The objectives of this program were: (1) the development of cathode materials of improved stability in reducing environments; and (2) the development of cathode materials with improved electrical conductivity. The program was successful in identifying some potential candidate materials: Air sinterable (La,Ca)(Cr,Co)O{sub 3} compositions were developed and found to be more stable than La{sub .8}Sr{sub .2}MnO{sub 3} towards reduction. Their conductivity at 1000{degrees}C ranged between 30 to 60 S/cm. Compositions within the (Y,Ca)(Cr,Co,Mn)O{sub 3} system were developed and found to have higher electrical conductivity than La{sub .8}Sr{sub .2}MnO{sub 3} and preliminary results suggest that their stability towards reduction is superior.

Anderson, H.U.

1991-03-01T23:59:59.000Z

309

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents (OSTI)

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2001-01-01T23:59:59.000Z

310

Apparatus and method for treating a cathode material provided on a thin-film substrate  

DOE Patents (OSTI)

An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

Hanson, Eric J. (Hudson, WI); Kooyer, Richard L. (Hastings, MN)

2003-01-01T23:59:59.000Z

311

Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Annual report, October 1991--September 1992  

DOE Green Energy (OSTI)

The program is being conducted by a team consisting of AlliedSignal Aerospace Systems & Equipment (ASE) (formerly AiResearch Los Angeles Division) and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

Not Available

1993-05-01T23:59:59.000Z

312

Advanced Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Systems: Advanced Systems: high Performance fenestration systems Research areas: Research activities to improve the performance of windows and other fenestration products must address window systems issues as well as Glazing Materials research. LBNL activities in the area of Advanced Systems include research at both the product level and the building envelope and building systems levels. Highly insulating windows - using non structural center layers Lower cost solutions to more insulating three layer glazing systems, with the potential to turn windows in U.S. heating dominated residential applications into net-energy gainers. Highly Insulating Window Frames In collaboration with the Norwegian University of Science and Technology, we are researching the potentials for highly insulating window frames. Our initial work examines European frames with reported U-factors under 0.15 Btu/hr-ft2-F. Future research aims to analyze these designs, verify these performance levels and ensure that procedures used to calculate frame performance are accurate.

313

NEW CATHODE MATERIALS FOR INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELLS  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and of Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} samples are reported and compared with results from previous studies. Studies of the crystallization of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are reported. Such studies are a preliminary to the combinatorial synthesis approach described in the first report.

Allan J. Jacobson

2004-05-11T23:59:59.000Z

314

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode - electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study are perovskite oxides based on Sr substituted LaFeO{sub 3}, where significant data in single cell tests exists at PNNL for cathodes on both YSZ and CSO/YSZ, and Ln{sub 2}NiO{sub 4} compositions. A key component of the research strategy is to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. Results on electrical conductivity relaxation measurements on additional compositions in the La{sub 2}NiO{sub 4+x} and Pr{sub 2}NiO{sub 4+x} series are presented in this report. Studies of the inter-diffusion of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} bilayer films prepared by pulsed laser deposition are described. Such studies are a preliminary to the combinatorial synthesis approach discussed in previous reports.

Allan J. Jacobson

2004-07-23T23:59:59.000Z

315

ANL/APS/TB-54, Dose Calculations using MARS for Bremsstrahlung Beam Stops and Collimators in APS Beamline Stations  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 DOSE CALCULATIONS USING MARS FOR BREMSSTRAHLUNG BEAM STOPS AND COLLIMATORS IN APS BEAMLINE STATIONS Jeffrey C. Dooling Accelerator Systems Division Advanced Photon Source August 2010 This work is sponsored by the US Department of Energy Office of Science The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display

316

Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile  

DOE Patents (OSTI)

A large area directly heated lanthanum hexaboride (LaB/sub 6/) cathode system is disclosed. The system comprises a LaB/sub 6/ cathode element generally circular in shape about a central axis. The cathode element has a head with an upper substantially planar emission surface, and a lower downwardly and an intermediate body portion which diminishes in cross-section from the head towards the base of the cathode element. A central rod is connected to the base of the cathode element and extends along the central axis. Plural upstanding spring fingers are urged against an outer peripheral contact surface of the head end to provide a mechanical and electrical connection to the cathode element. 7 figs

Leung, Ka-Ngo; Gordon, K.C.; Kippenhan, D.O.; Purgalis, P.; Moussa, D.; Williams, M.D.; Wilde, S.B.; West, M.W.

1987-10-16T23:59:59.000Z

317

Exposing Valence-Bond Model Inadequacies | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

field that has already given us high-capacity computer hard drives based on the giant magnetoresistance effect. - Vic Comello (VComello@anl.gov) See: Narcizo M....

318

Electrochemical kinetics of thin film vanadium pentoxide cathodes for lithium batteries  

E-Print Network (OSTI)

Electrochemical experiments were performed to investigate the processing-property-performance relations of thin film vanadium pentoxide cathodes used in lithium batteries. Variations in microstructures were achieved via ...

Mui, Simon C., 1976-

2005-01-01T23:59:59.000Z

319

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells  

A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed a method to fabricate battery cathodes from nanoscale flakes of graphene ...

320

STRUCTURE AND PERFORMANCE RELATIONSHIP IN HIGH PERFORMANCE LITHIUM ION BATTERY CATHODES.  

E-Print Network (OSTI)

??The goal of this dissertation is to study the structure and performance relationship in cathodes material used in lithium-ion battery applications. In addition, functional materials (more)

Zhu, Pengyu

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Improving lithium-ion battery power and energy densities using novel cathode architectures and materials.  

E-Print Network (OSTI)

??Lithium-ion batteries are commonly used as energy storage devices in a variety of applications. The cathode architectures and materials have a large influence on the (more)

Lange, Jonathan

2012-01-01T23:59:59.000Z

322

Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion batteries at elevated temperatures. Author(s), Dawei Liu, Jasper Wright, Wei...

323

Thermal Instability of Olivine-Type LiMnP04 Cathodes  

E-Print Network (OSTI)

commercialization as a lithium ion battery cathode material.in the presence of a lithium-ion battery electrolyte is also

Chen, Guoying

2010-01-01T23:59:59.000Z

324

Recovery and Refunctionalization of LiFePO4 Cathode from End-of ...  

Science Conference Proceedings (OSTI)

Symposium, Battery Recycling. Presentation Title, Recovery and Refunctionalization of LiFePO4 Cathode from End-of-Life Commercial Lithium Ion Batteries.

325

Observation of high-power millimeter wave emission from a virtual cathode  

SciTech Connect

Intense bursts of mm wave power have been observed in microwave generation experiments with a relativistic electron beam (REB) virtual cathode oscillator. In this device an electron beam is injected into a drift space at a current above the space-charge-limit, and a potential develops downstream which is large enough to reflect electrons back to the source region. Two mechanisms can give rise to microwave oscillations in a virtual cathode device: electrons reflexing between the real and virtual cathodes, and oscillations in the amplitude and position of the virtual cathode. Typically both mechanisms are present, but in the present experiments reflexing has been shown to be dominant.

Davis, H.A.; Bartsch, R.R.; Sherwood, E.G.; Stringfield, R.M.; Thode, L.E.

1985-01-01T23:59:59.000Z

326

Simulations of multipacting in the cathode stalk and FPC of 112 MHz superconducting electron gun  

Science Conference Proceedings (OSTI)

A 112 MHz superconducting quarter-wave resonator electron gun will be used as the injector of the Coherent Electron Cooling (CEC) proof-of-principle experiment at BNL. Furthermore, this electron gun can be used for testing of the performance of various high quantum efficiency photocathodes. In a previous paper, we presented the design of the cathode stalks and a Fundamental Power Coupler (FPC). In this paper we present updated designs of the cathode stalk and FPC. Multipacting in the cathode stalk and FPC was simulated using three different codes. All simulation results show no serious multipacting in the cathode stalk and FPC.

Xin T.; Ben-Zvi, I.; Belomestnykh, S.; Chang, X.; Rao, T.; Skaritka, J.; Wu, Q.; Wang, E.; Liang, X.

2012-05-20T23:59:59.000Z

327

Power control architectures for cold cathode fluorescent lamp and light emitting diode based light sources.  

E-Print Network (OSTI)

?? In this dissertation, two different energy efficient power supply topologies are introduced for controlling cold cathode fluorescent lamp (CCFL) and high-brightness light emitting diode (more)

Doshi, Montu V.

2010-01-01T23:59:59.000Z

328

Optimization of Na 0.44 MnO 2 Cathode Material - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage: Materials, Systems, and Applications. Presentation Title, Optimization of Na0.44MnO2 Cathode Material for Use in Aqueous...

329

Cathodic Protection Criteria for Controlling Microbially Influenced Corrosion in Power Plants  

Science Conference Proceedings (OSTI)

Recent EPRI research demonstrated that cathodic protection (CP) prevented corrosion of materials, although the number density of bacteria increased. Interruption of CP, therefore, must be done with care.

1991-05-24T23:59:59.000Z

330

Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube ...  

Science Conference Proceedings (OSTI)

Presentation Title, Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube Glasses by SEP-TCLP. Author(s), Mengjun Chen, Fu-Shen Zhang, Jianxin ...

331

A Novel Process for Lead Extraction from Scrap Cathode Ray Tube ...  

Science Conference Proceedings (OSTI)

Leaching Toxicity of Pb and Ba Containing in Cathode Ray Tube Glasses by SEP -TCLP Mechanical Recycling of Electronic Wastes for Materials Recovery.

332

Electrocatalysis of anodic and cathodic oxygen-transfer reactions  

SciTech Connect

The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

Wels, B.R.

1990-09-21T23:59:59.000Z

333

STATEMENT OF CONSIDERATIONS REQUEST BY MOTOROLA LABS FOR AN ADVANCE WAIVER OF DOMESTIC AND  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

MOTOROLA LABS FOR AN ADVANCE WAIVER OF DOMESTIC AND MOTOROLA LABS FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN INVENTION RIGHTS UNDER PROPOSED SUBCONTRACT WITH ARGONNE NATIONAL LABORATORY, RFP NO. BAA-N66001-03-X-6010, UNDER M&O CONTRACT W-31-109-ENG-38; W(A)-05-015, CH-1278 The Petitioner, Motorola Labs (Motorola) will be entering into a subcontract with Argonne National Laboratory (ANL) for the performance of work entitled, "Co-integration of Multi- functional Diamond MEMS (Micro-Electro-Mechanical Systems) Technology." The waiver will apply to inventions made by Motorola employees and its subcontractors' employees, regardless of tier, except inventions made by subcontractors eligible to retain title to inventions pursuant to P.L. 96-517, as amended, and National Laboratories. The purpose of the subcontract is to demonstrate the co-integration of a diamond-based

334

Advanced Combustion Engine Program 2005 Merit Review and Peer Evaluation Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Less dependence on foreign oil, and eventual transition to an emissions-free, petroleum-free vehicle ADVANCED COMBUSTION ENGINE PROGRAM F r e e d o m C A r A n d V e h i C l e T e C h n o l o g i e s P r o g r A m MERIT REVIEW & PEER EVALUATION REPORT Department of Energy Washington, DC 20585 October 5, 2005 Dear Colleague: This document summarizes the comments provided by the Review Panel for the FY 2005 Department of Energy (DOE) Advanced Combustion Engine R&D Merit Review and Peer Evaluation Meeting, the "ACE Review," held on April 19-21, 2005 at Argonne National Laboratory (ANL). The raw evaluations and comments of the panel were provided (with reviewers' names deleted) to the presenters in early June and were used by national laboratory researchers in the development of Annual Operating Plans (AOPs) for fiscal year (FY) 2006. The panel's

335

Advanced Combustion  

NLE Websites -- All DOE Office Websites (Extended Search)

Systems Systems Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to generate electricity, which operate at efficiencies of 35-37 percent. Operation at higher temperatures and pressures can lead to higher efficiencies, resulting in reduced fuel consumption and lower greenhouse gas emissions. Higher efficiency also reduces CO2 production for the same amount of energy produced, thereby facilitating a reduction in greenhouse gas emissions. When combined, oxy-combustion comes with an efficiency hit, so it will actually increase the amount of CO2 to be captured. But without so much N2 in the flue gas, it will be easier and perhaps more efficient to capture, utilize and sequester. NETL's Advanced Combustion Project and members of the NETL-Regional University

336

Advanced Search  

NLE Websites -- All DOE Office Websites (Extended Search)

Publications Publications Advanced Search Most publications by Environmental Energy Technologies Division authors are searchable from this page, including peer-reviewed publications, book chapters, conference proceedings and LBNL reports. Filter Advanced Search Publications list This publications database is an ongoing project, and not all Division publications are represented here yet. For additional help see the bottom of this page. Documents Found: 4418 Title Keyword LBNL Number Author - Any - Abadie, Marc O Abbey, Chad Abdolrazaghi, Mohamad Aberg, Annika Abhyankar, Nikit Abraham, Marvin M Abshire, James B Abushakra, Bass Acevedo-Ruiz, Manuel Aceves, Salvador Ache, Hans J Ackerly, David D Ackerman, Andrew S Adamkiewicz, Gary Adams, J W Adams, Carl Adamson, Bo Addy, Nathan Addy, Susan E Aden, Nathaniel T Adesola, Bunmi Adhikari,

337

Advanced Combustion  

Science Conference Proceedings (OSTI)

The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

Holcomb, Gordon R. [NETL

2013-03-11T23:59:59.000Z

338

Code qualification of structural materials for AFCI advanced recycling reactors.  

Science Conference Proceedings (OSTI)

This report summarizes the further findings from the assessments of current status and future needs in code qualification and licensing of reference structural materials and new advanced alloys for advanced recycling reactors (ARRs) in support of Advanced Fuel Cycle Initiative (AFCI). The work is a combined effort between Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL) with ANL as the technical lead, as part of Advanced Structural Materials Program for AFCI Reactor Campaign. The report is the second deliverable in FY08 (M505011401) under the work package 'Advanced Materials Code Qualification'. The overall objective of the Advanced Materials Code Qualification project is to evaluate key requirements for the ASME Code qualification and the Nuclear Regulatory Commission (NRC) approval of structural materials in support of the design and licensing of the ARR. Advanced materials are a critical element in the development of sodium reactor technologies. Enhanced materials performance not only improves safety margins and provides design flexibility, but also is essential for the economics of future advanced sodium reactors. Code qualification and licensing of advanced materials are prominent needs for developing and implementing advanced sodium reactor technologies. Nuclear structural component design in the U.S. must comply with the ASME Boiler and Pressure Vessel Code Section III (Rules for Construction of Nuclear Facility Components) and the NRC grants the operational license. As the ARR will operate at higher temperatures than the current light water reactors (LWRs), the design of elevated-temperature components must comply with ASME Subsection NH (Class 1 Components in Elevated Temperature Service). However, the NRC has not approved the use of Subsection NH for reactor components, and this puts additional burdens on materials qualification of the ARR. In the past licensing review for the Clinch River Breeder Reactor Project (CRBRP) and the Power Reactor Innovative Small Module (PRISM), the NRC/Advisory Committee on Reactor Safeguards (ACRS) raised numerous safety-related issues regarding elevated-temperature structural integrity criteria. Most of these issues remained unresolved today. These critical licensing reviews provide a basis for the evaluation of underlying technical issues for future advanced sodium-cooled reactors. Major materials performance issues and high temperature design methodology issues pertinent to the ARR are addressed in the report. The report is organized as follows: the ARR reference design concepts proposed by the Argonne National Laboratory and four industrial consortia were reviewed first, followed by a summary of the major code qualification and licensing issues for the ARR structural materials. The available database is presented for the ASME Code-qualified structural alloys (e.g. 304, 316 stainless steels, 2.25Cr-1Mo, and mod.9Cr-1Mo), including physical properties, tensile properties, impact properties and fracture toughness, creep, fatigue, creep-fatigue interaction, microstructural stability during long-term thermal aging, material degradation in sodium environments and effects of neutron irradiation for both base metals and weld metals. An assessment of modified versions of Type 316 SS, i.e. Type 316LN and its Japanese version, 316FR, was conducted to provide a perspective for codification of 316LN or 316FR in Subsection NH. Current status and data availability of four new advanced alloys, i.e. NF616, NF616+TMT, NF709, and HT-UPS, are also addressed to identify the R&D needs for their code qualification for ARR applications. For both conventional and new alloys, issues related to high temperature design methodology are described to address the needs for improvements for the ARR design and licensing. Assessments have shown that there are significant data gaps for the full qualification and licensing of the ARR structural materials. Development and evaluation of structural materials require a variety of experimental facilities that have been seriously degraded

Natesan, K.; Li, M.; Majumdar, S.; Nanstad, R.K.; Sham, T.-L. (Nuclear Engineering Division); (ORNL)

2012-05-31T23:59:59.000Z

339

Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition  

SciTech Connect

Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

2008-01-20T23:59:59.000Z

340

Office of Science and Technology & International Year End Report - 2005  

E-Print Network (OSTI)

located in the Advanced Photon Source (APS), a third-in situ at ANLs Advanced Photon Source (APS), Materials

Bodvarsson, G.S.

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Advanced Energy Storage Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Energy Storage Publications Reports: Advanced Technology Development Program For Lithium-Ion Batteries: Gen 2 Performance Evaluation Final Report Advanced Technology...

342

Advanced Manufacturing Office: News  

NLE Websites -- All DOE Office Websites (Extended Search)

Manufacturing Office: News on Twitter Bookmark Advanced Manufacturing Office: News on Google Bookmark Advanced Manufacturing Office: News on Delicious Rank Advanced Manufacturing...

343

Degradation of Ionic Pathway in PEM Fuel Cell Cathode  

SciTech Connect

The degradation of the ionic pathway throughout the catalyst layer in proton exchange membrane fuel cells was studied under an accelerated stress test of catalyst support (potential hold at 1.2 V). Electrochemical behaviors of the cathode based on graphitic mesoporous carbon supported Pt catalyst were examined using electrochemical impedance spectroscopy and cyclic voltammetry. Impedance data were plotted and expressed in the complex capacitance form to determine useful parameters in the transmission line model: the double-layer capacitance, peak frequency, and ionic resistance. Electrochemical surface area and hydrogen crossover current through the membrane were estimated from cyclic voltammogram, while cathode Faradaic resistance was compared with ionic resistance as a function of test time. It was observed that during an accelerated stress test of catalyst support, graphitic mesoporous carbon becomes hydrophilic which increases interfacial area between the ionomer and the catalyst up to 100 h. However, the ionic resistance in the catalyst layer drastically increases after 100 h with further carbon support oxidation. The underlying mechanism has been studied and it was found that significant degradation of ionic pathway throughout the catalyst layer due to catalyst support corrosion induces uneven hydration and mechanical stress in the ionomer.

Park, Seh Kyu; Shao, Yuyan; Wan, Haiying; Viswanathan, Vilayanur V.; Towne, Silas A.; Rieke, Peter C.; Liu, Jun; Wang, Yong

2011-11-12T23:59:59.000Z

344

Catalyst-infiltrated supporting cathode for thin-film SOFCs  

DOE Green Energy (OSTI)

The fabrication and electrochemical performance of co-fired,LSM-SYSZ [i.e., La0.65Sr0.30MnO3 (LSM) - (Sc2O3)0.1(Y2O3)0.01(ZrO2)0.89] supported thin-film cells were examined using humidified hydrogen as a fuel. Co-firing of bi-layers and tri-layers was successful at 1250 C by optimizing the amount of carbon pore formers. A power density of a factor of 2.5 higher than that recently reported for the same type of cell at 800 C [3] was obtained for a cell with cobalt infiltration into the supporting cathode: the peak power densities were 455, 389, 285, 202, 141mW/cm2 at 800, 750, 700, 650, 600 C, respectively, and in most cases power densities at 0.7V exceeded more than 90 percent of the peak output. Increasing the cathode porosity from 43 to 53 percent improved peak power densities by as much as 1.3, shifting the diffusion limitation to high current densities. Cobalt infiltration into the support improved those by as much as a factor of 2 due to a significant reduction in non-ohmic resistance. These results demonstrate that cobalt catalyst-infiltrated LSM can be effective and low-cost supporting electrodes for reduced temperature, thin film SOFCs.

Yamahara, Keiji; Jacobson, Craig P.; Visco, Steven J.; De Jonghe,Lutgard C.

2004-04-12T23:59:59.000Z

345

Measurement of groove features and dimensions of the vertical test cathode and the choke joint of the superconducting electron gun cavity of the Energy Recovery LINAC  

Science Conference Proceedings (OSTI)

A testing program for the superconducting electron gun cavity that has been designed for the Energy Recovery LINAC is being planned. The goal of the testing program is to characterize the RF properties of the gun cavity at superconducting temperatures and, in particular, to study multipacting that is suspected to be occurring in the choke joint of the cavity where the vertical test cathode is inserted. The testing program will seek to understand the nature and cause of this multipacting and attempt to eliminate it, if possible, by supplying sufficient voltage to the cavity. These efforts are motivated by the multipacting issues that have been observed in the processing of the fine-grain niobium gun cavity. This cavity, which is being processed at Thomas Jefferson National Laboratory for Brookhaven, has encountered multipacting at a gradient of approximately 3 MV/m and, to date, has resisted efforts at elimination. Because of this problem, a testing program is being established here in C-AD that will use the large-grain niobium gun cavity that currently resides at Brookhaven and has been used for room-temperature measurements. The large-grain and fine-cavities are identical in every aspect of construction and only differ in niobium grain size. Thus, it is believed that testing and conditioning of the large-grain cavity should yield important insights about the fine-grain cavity. One element of this testing program involves characterizing the physical features of the choke joint of the cavity where the multipacting is believed to be occurring and, in particular the grooves of the joint. The configuration of the cavity and the vertical test cathode is shown in Figure 1. In addition, it is important to characterize the groove of the vertical test cathode. The grooved nature of these two components was specifically designed to prevent multipacting. However, it is suspected that, because of the chemical processing that the fine-grain gun cavity underwent along with the vertical test cathode, the geometry of these grooves was altered, presenting the possibility that multipacting may, in fact, be occurring in this area and contributing to the low gradients that have been observed in the fine-grain cavity. Therefore, the Survey and Alignment group in C-AD engaged in measurements of the cavity joint, shown in Figure 2 and the cathode weldment, shown in Figure 3 for the purpose of characterizing the grooves in both the cavity and the vertical test cathode and comparing the dimensions of the cathode with those of the prints supplied by Advanced Energy Systems (AES), the original designer and manufacturer of both the test cathode and the electron gun cavity, in preparation to have a new one manufactured. The goal was to ensure that the articles as built matched the design prints in preparation for manufacturing a new vertical test cathode. This report describes the data collected by the Survey group in these efforts. The endeavor was challenging for the group given the millimeter-scale dimensions of the grooves and the requirement for high precision.

Hammons, L.; Ke, M.

2011-10-13T23:59:59.000Z

346

STATEMENT OF CONSIDERATIONS REQUEST BY OSRAM SYLVANIA PRODUCTS, INC. FOR AN ADVANCE  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OSRAM SYLVANIA PRODUCTS, INC. FOR AN ADVANCE OSRAM SYLVANIA PRODUCTS, INC. FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN PATENT RIGHTS UNDER DOE GRANT NO. DE-FG36-05GO85042 ENTITLED "TUNGSTEN CATHODE FUEL CELL CATALYST PROJECT"; W(A)-05-031; CH-1300 As set out in the attached waiver petitioner, the Petitioner, OSRAM SYLVANIA Products, Inc., has requested an advance waiver of domestic and foreign patent rights for all subject inventions made by its employees under the above-identified award. Referring to item 2 of the waiver petition, the purpose of this award relates generally to fuel cells and specifically to the design, fabrication and evaluation of the cathodic, catalytic activity of a tungsten-based (platinum-free) material in a prototype membrane electrode assembly at 1 / 1 5 t h the output of a comparable platinum containing unit to

347

Mission Advancing  

NLE Websites -- All DOE Office Websites (Extended Search)

NETL Accomplishments NETL Accomplishments - the lab 2 Mission Advancing energy options to fuel our economy, strengthen our security, and improve our environment. Renewed Prosperity Through Technological Innovation - Letter from the Director NETL: the ENERGY lab 4 6 3 Contents Technology Transfer Patents and Commercialization Sharing Our Expertise Noteworthy Publications 60 62 63 64 66 Environment, Economy, & Supply Carbon Capture and Storage Partnerships Work to Reduce Atmospheric CO 2 Demand-Side Efficiencies New NETL Facility Showcases Green Technologies Environment & Economy Materials Mercury Membranes NETL Education Program Produces Significant Achievement Monitoring Water Economy & Supply NETL's Natural Gas Prediction Tool Aids Hurricane Recovery Energy Infrastructure

348

Advanced Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Ductility EnhancEmEnt of molybDEnum Ductility EnhancEmEnt of molybDEnum PhasE by nano-sizED oxiDE DisPErsions Description Using computational modeling techniques, this research aims to develop predictive capabilities to facilitate the design and optimization of molybdenum (Mo), chromium (Cr), and other high-temperature structural materials to enable these materials to withstand the harsh environments of advanced power generation systems, such as gasification-based systems. These types of materials are essential to the development of highly efficient, clean energy technologies such as low-emission power systems that use coal or other fossil fuels.

349

Reprint of "Studies of local degradation phenomena in composite cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Reprint of "Studies of local degradation phenomena in composite cathodes Reprint of "Studies of local degradation phenomena in composite cathodes for lithium-ion batteries" Title Reprint of "Studies of local degradation phenomena in composite cathodes for lithium-ion batteries" Publication Type Journal Article Year of Publication 2007 Authors Kerlau, Marie, Marek Marcinek, Venkat Srinivasan, and Robert Kostecki Journal Electrochimica Acta Volume 53 Pagination 1385-1392 Keywords cathode, degradation, li-ion battery, raman microscopy Abstract LiNi0.8Co0.15Al0.05O2 and LiNi1/3Co1/3Mn1/3O2 composite cathodes were cycled in model cells to study interfacial phenomena that could lead to electrode degradation. Ex situ spectroscopic analysis of the tested cathodes, which suffered substantial power and capacity loss, showed that the state of charge (SOC) of oxide particles on the cathode surface was highly non-uniform despite the deep discharge of the Li-ion cell at the end of the test. The inconsistent kinetic behavior of individual oxide particles was attributed to the degradation of electronic pathways within the composite cathodes. A simple theoretical model based on a distributed network showed that an increase of the contact resistance between composite electrode particles may be responsible for non-uniform local kinetic behavior of individual oxide particles and the overall degradation of electrochemical performance of composite electrodes.

350

Direct methanol fuel cell cathodes with sulfur and nitrogen-based carbon functionality  

Science Conference Proceedings (OSTI)

The effect of carbon functionality on the electrocatalytic performance of carbon black-supported, Pt-based, direct methanol fuel cell cathodes was investigated. Polarization data show that cathodes with nitrogen and sulfur functionality have enhanced catalytic activity toward oxygen reduction. Transmission electron microscopy results indicate that this behavior may be ascribed to a platinum particle size effect.

Roy, S.C.; Christensen, P.A.; Hamnett, A.; Thomas, K.M.; Trapp, V. [Univ. of Newcastle, Newcastle-upon-Tyne (United Kingdom)

1996-10-01T23:59:59.000Z

351

Lithium Hectorite Clay as the Ionic Conductor in LiCoO2 Cathodes  

E-Print Network (OSTI)

Lithium Hectorite Clay as the Ionic Conductor in LiCoO2 Cathodes Michael W. Riley,* Peter S. Fedkiw Carolina 27695-7905, USA Cathodes based on LiCoO2 that contain various lithium-conducting species lithium hectorite, lithium Laponite, and lithium- exchanged Nafion are studied in conjunction with lithium metal

Khan, Saad A.

352

Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells  

DOE Green Energy (OSTI)

Two-phase flow and transport of reactants and products in the air cathode of proton exchange membrane (PEM) fuel cells is studied analytically and numerically. Four regimes of water distribution and transport are classified by defining three threshold current densities and a maximum current density. They correspond to first appearance of liquid water at the membrane/cathode interface, extension of the gas-liquid two-phase zone to the cathode/channel interface, saturated moist air exiting the gas channel, and complete consumption of oxygen by the electrochemical reaction. When the cell operates above the first threshold current density, liquid water appears and a two-phase zone forms within the porous cathode. A two-phase, multi-component mixture model in conjunction with a finite-volume-based computational fluid dynamics (CFD) technique is applied to simulate the cathode operation in this regime. The model is able to handle the situation where a single-phase region co-exists with a two-phase zone in the air cathode. For the first time, the polarization curve as well as water and oxygen concentration distributions encompassing both single- and two-phase regimes of the air cathode are presented. Capillary action is found to be the dominant mechanism for water transport inside the two-phase zone. The liquid water saturation within the cathode is predicted to reach 6.3% at 1.4 A/cm{sup 2}.

WANG,Z.H.; WANG,C.Y.; CHEN,KEN S.

2000-03-20T23:59:59.000Z

353

Quantifying the Water Content in the Cathode of Enzyme Fuel Cells via Neutron Imaging  

SciTech Connect

Neutron imaging was used to study cathode water content over time in a three-dimensional-cathode enzyme fuel cell (EFC). A porous carbon felt cathode allowed air to flow through the electrode. A solution with laccase and a mediator formed an aqueous layer on the electrode surface. Water loss was observed in situ via neutron imaging for varying experimental conditions, including flow rates of hydrogen and air, cathode inlet humidity, volume of enzyme solution, and its composition. Cathode water loss occurred for all experimental conditions, but the loss rate was noticeably reduced when a high-salt-concentration enzyme solution was used in the cathode in conjunction with increased humidity in the air feed stream. Results from neutron imaging and power density analysis were used in analyzing the causes that could contribute to EFC water loss. An increase in temperature due to the exothermic cathode reaction is considered a plausible cause of cathode water loss via evaporation. This is the first reported application of neutron imaging as a technique to study EFC water management. The results suggest that neutron imaging can be employed to provide a better understanding of EFC phenomena and thereby contribute to design and operational improvements of EFCs.

Aaron, D [Georgia Institute of Technology; Borole, Abhijeet P [ORNL; Hussey (NIST), Daniel [National Institute of Standards and Technology (NIST); Jacobson, David [National Institute of Standards and Technology (NIST); Yiacoumi, Sotira [Georgia Institute of Technology; Tsouris, Costas [ORNL

2011-01-01T23:59:59.000Z

354

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network (OSTI)

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

355

Effect of A-site Non-stoichiometry on LSCF Cathodes  

DOE Green Energy (OSTI)

LSCF Cathodes were explored when effected with A-site non-stoichiometry. At 700-800 C, the operating temperatures of intermediate temperature (IT-) SOFCs have enabled the use of stainless steels in the SOFC framework and current collectors, allowing significant reductions in cost. However, the lower operating temperatures of IT-SOFC's also result in significant decreases in power densities of cells with LSM cathodes due to their high activation energies. LSCF is a mixed ionic electronic conducting perovskite that exhibits higher performance than LSM/YSZ composites and shows potential as a replacement cathode. This study investigates the effect of A-site stoichiometry on the performance of LSCF cathodes. Cell tests showed that A-site and Sr-deficient LSCF cathodes consistently outperformed stoichiometric LSCF cathodes, exhibiting up to 10% higher cell power densities. It was also observed that all stoichiometric, A-site, and Sr-deficient LSCF cathodes degraded over time at similar rates. Contributions of ohmic and electrode polarization losses to cell degradation rates were similar regardless of cathode composition.

Templeton, Jared W.; Lu, Zigui; Stevenson, Jeffry W.; Hardy, John S.

2011-09-01T23:59:59.000Z

356

External Mass Injection to Reduce Energetic Ion Production in the Discharge Plume of High Current Hollow Cathodes  

E-Print Network (OSTI)

flow Voltage Spread (V) Volt at Max Ion Energy (V) Externalfor 10 sccm cathode flow. Volt at Max Ion Energy (V) 16 sccm10 sccm cathode 10 sccm injected Volt at Max Ion Energy (V)

Chu, Emily

2012-01-01T23:59:59.000Z

357

NEURO-FUZZY CONTROLLER IMPLEMENTATION FOR AN ADAPTIVE CATHODIC PROTECTION ON IRAQ-TURKEY CRUDE OIL PIPELINE  

Science Conference Proceedings (OSTI)

Impressed current cathodic protection is widely used to prevent corrosion of structural steels, especially, those used in a crude oil pipeline. The potential required for cathodic protection depends upon the steel being protected from the environment. ...

M. A. Akcayol; S. Sagiroglu

2007-03-01T23:59:59.000Z

358

Environmental Assessment and (FONSI) Of The Proposed 7-GeV Advanced Photon Source  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and (FONSI) OF THE PROPOSED and (FONSI) OF THE PROPOSED 7-GeV ADVANCED PHOTON SOURCE Table of Contents LIST OF ABBREVIATIONS AND ACRONYMS ABSTRACT 1.0 INTRODUCTION 1.1 PURPOSE 1.2 THE APS PROJECT AT ANL 1.3 SUMMARY OF THE PROPOSED ACTION 1.4 NEED FOR ACTION 2.0 THE PROPOSED ACTION AND ALTERNATIVES 2.1 DESCRIPTION OF APS AND CONSTRUCTION ACTIVITIES (PROPOSED ACTION) 2.1.1 APS Facility Description 2.1.2 Utility Services 2.1.3 Gaseous Emissions, Liquid Effluents, and Wastes 2.1.4 Construction Activities 2.1.5 Decommissioning 2.2 ALTERNATIVES 2.2.1 No Action 2.2.2 Construction at Another ANL Site 3.0 THE AFFECTED ENVIRONMENT 3.1 SITE DESCRIPTION 3.2 CLIMATOLOGY AND AIR QUALITY 3.2.1 Climatology 3.2.2 Air Quality 3.3 DEMOGRAPHY AND SOCIOECONOMIC PROFILE 3.4 LAND USE 3.4.1 Site and Vicinity

359

Linear Accelerator | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

electrons emitted from a cathode heated to 1100 C. The electrons are accelerated by high-voltage alternating electric fields in a linear accelerator (linac; photo below)....

360

John B. Goodenough, Cathode Materials, and Rechargeable Lithium...  

Office of Scientific and Technical Information (OSTI)

Batteries for Advanced Transportation Technologies (BATT) Program at Lawrence Berkeley National Laboratory (LBNL).4 1 Edited excerpt from Secretary Chu Names 2009 Enrico Fermi...

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Supporting Advanced Scientific Computing Research Basic Energy Sciences Biological  

E-Print Network (OSTI)

· NERSC / LBNL · ALCF / ANL ­ Will provide multiple 10's of teraflops and multiple petabytes of storageNetwork Sunnyvale NYC Nashville Chicago OLCF/ ORNL 100G ALCF/ANL NERSC Magellan Magellan 6 #12;ARRA/ANI Testbed (Oakland, CA) and ALCF (Argonne, IL) 9 #12;Network Testbed Components · Network Testbed will consist of

362

Monolithic solid oxide fuel cell technology advancement for coal-based power generation. Quarterly technical status report, January--March 1992  

DOE Green Energy (OSTI)

The program is conducted by a team consisting of AiResearch Los Angeles Division of Allied-Signal Aerospace Company and Argonne National Laboratory (ANL). The objective of the program is to advance materials and fabrication methodologies to develop a monolithic solid oxide fuel cell (MSOFC) system capable of meeting performance, life, and cost goals for coal-based power generation. The program focuses on materials research and development, fabrication process development, cell/stack performance testing and characterization, cost and system analysis, and quality development.

Not Available

1992-04-14T23:59:59.000Z

363

Advanced Research  

NLE Websites -- All DOE Office Websites (Extended Search)

05/2007 05/2007 NitrogeN evolutioN aNd CorrosioN MeChaNisMs With oxyCoMbustioN of Coal Description Under a grant from the University Coal Research (UCR) program, Brigham Young University (BYU) is leading a three-year research effort to investigate the physical processes that several common types of coal undergo during oxy-fuel combustion. Specifically, research addresses the mixture of gases emitted from burning, particularly such pollutants as nitrogen oxides (NO X ) and carbon dioxide (CO 2 ), and the potential for corrosion at the various stages of combustion. The UCR program is administered by the Advanced Research Program at the National Energy Technology Laboratory (NETL), under the U.S. Department of Energy's Office of

364

A Lithium Superionic Sulfide Cathode for Lithium-Sulfur Batteries  

SciTech Connect

This work presents a facile synthesis approach for core-shell structured Li2S nanoparticles, which have Li2S as the core and Li3PS4 as the shell. This material functions as lithium superionic sulfide (LSS) cathode for long-lasting, energy-efficient lithium-sulfur (Li-S) batteries. The LSS has an ionic conductivity of 10-7 S cm-1 at 25 oC, which is 6 orders of magnitude higher than that of bulk Li2S (~10-13 S cm-1). The high lithium-ion conductivity of LSS imparts an excellent cycling performance to all-solid Li-S batteries, which also promises safe cycling of high-energy batteries with metallic lithium anodes.

Lin, Zhan [ORNL; Liu, Zengcai [ORNL; Dudney, Nancy J [ORNL; Liang, Chengdu [ORNL

2013-01-01T23:59:59.000Z

365

Filtered cathodic arc deposition with ion-species-selectivebias  

SciTech Connect

A dual-cathode arc plasma source was combined with acomputer-controlled bias amplifier such as to synchronize substrate biaswith the pulsed production of plasma. In this way, bias can be applied ina material-selective way. The principle has been applied to the synthesismetal-doped diamond-like carbon films, where the bias was applied andadjusted when the carbon plasma was condensing, and the substrate was atground when the metal was incorporated. In doing so, excessive sputteringby too-energetic metal ions can be avoided while the sp3/sp2 ratio can beadjusted. It is shown that the resistivity of the film can be tuned bythis species-selective bias. The principle can be extended tomultiple-material plasma sources and complex materials

Anders, Andre; Pasaja, Nitisak; Sansongsiri, Sakon; Lim, SunnieH.N.

2006-10-05T23:59:59.000Z

366

Heat treatment of cathodic arc deposited amorphous hard carbon films  

SciTech Connect

Amorphous hard carbon films of varying sp{sup 2}/sp{sup 3} fractions have been deposited on Si using filtered cathodic are deposition with pulsed biasing. The films were heat treated in air up to 550 C. Raman investigation and nanoindentation were performed to study the modification of the films caused by the heat treatment. It was found that films containing a high sp{sup 3} fraction sustain their hardness for temperatures at least up to 400 C, their structure for temperatures up to 500 C, and show a low thickness loss during heat treatment. Films containing at low sp{sup 3} fraction graphitize during the heat treatment, show changes in structure and hardness, and a considerable thickness loss.

Anders, S.; Ager, J.W. III; Brown, I.G. [and others

1997-02-01T23:59:59.000Z

367

Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

1 1 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Nenad M. Markovic (Primary Contact) and Vojislav R. Stamenkovic Argonne National Laboratory (ANL) Argonne, IL 60439 Phone: (630) 252-5181 Email: nmmarkovic@anl.gov DOE Manager HQ: Nancy Garland Phone: (202) 586-5673 Email: Nancy.Garland@ee.doe.gov Subcontractors: * Karren More, Oak Ridge National Laboratory, Oak Ridge, TN * Charles Hays, Jet Propulsion Laboratory, Pasadena, CA * Shuoheng Sun, Brown University, Providence, RI * Guofeng Wang, University of Pittsburgh, Pittsburgh, PA * Radoslav Atanasoski, 3M Company, Saint Paul, MN

368

New Cathode Materials for Intermediate Temperature Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Operation of SOFCs at intermediate temperatures (500-800 C) requires new combinations of electrolyte and electrode materials that will provide both rapid ion transport across the electrolyte and electrode-electrolyte interfaces and efficient electrocatalysis of the oxygen reduction and fuel oxidation reactions. This project concentrates on materials and issues associated with cathode performance that are known to become limiting factors as the operating temperature is reduced. The specific objectives of the proposed research are to develop cathode materials that meet the electrode performance targets of 1.0 W/cm{sup 2} at 0.7 V in combination with YSZ at 700 C and with GDC, LSGM or bismuth oxide based electrolytes at 600 C. The performance targets imply an area specific resistance of {approx}0.5 {Omega}cm{sup 2} for the total cell. The research strategy is to investigate both established classes of materials and new candidates as cathodes, to determine fundamental performance parameters such as bulk diffusion, surface reactivity and interfacial transfer, and to couple these parameters to performance in single cell tests. The initial choices for study were perovskite oxides based on substituted LaFeO{sub 3} (P1 compositions), where significant data in single cell tests exist at PNNL for example, for La{sub 0.8}Sr{sub 0.2}FeO{sub 3} cathodes on both YSZ and CSO/YSZ. The materials selection was then extended to La{sub 2}NiO{sub 4} compositions (K1 compositions), and then in a longer range task we evaluated the possibility of completely unexplored group of materials that are also perovskite related, the ABM{sub 2}O{sub 5+{delta}}. A key component of the research strategy was to evaluate for each cathode material composition, the key performance parameters, including ionic and electronic conductivity, surface exchange rates, stability with respect to the specific electrolyte choice, and thermal expansion coefficients. In the initial phase, we did this in parallel with the perovskite compositions that were being investigated at PNNL, in order to assess the relative importance of the intrinsic properties such as oxygen ion diffusion and surface exchange rates as predictors of performance in cell tests. We then used these measurements to select new materials for scaled up synthesis and performance evaluation in single cell tests. The results of the single cell tests than provided feedback to the materials synthesis and selection steps. In this summary, the following studies are reported: (1) Synthesis, characterization, and DC conductivity measurements of the P1 compositions La{sub 0.8}Sr{sub 0.2}FeO{sub 3-x} and La{sub 0.7}Sr{sub 0.3}FeO{sub 3-x} were completed. A combinational approach for preparing a range P1 (La,Sr)FeO{sub 3} compositions as thin films was investigated. Synthesis and heat treatment of amorphous SrFeO{sub 3-x} and LaFeO{sub 3-x} films prepared by pulsed laser deposition are described. (2) Oxygen transport properties of K1 compositions La{sub x}Pr{sub 2-x}NiO{sub 4+d} (x =2.0, 1.9, 1.2, 1.0 and 0) measured by electrical conductivity relaxation are presented in this report. Area specific resistances determined by ac impedance measurements for La{sub 2}NiO{sub 4+{delta}} and Pr{sub 2}NiO{sub 4+{delta}} on CGO are encouraging and suggest that further optimization of the electrode microstructure will enable the target to be reached. (3) The oxygen exchange kinetics of the oxygen deficient double perovskite LnBaCo{sub 2}O{sub 5.5+{delta}} (Ln=Pr and Nd) were determined by electrical conductivity relaxation. The high electronic conductivity and rapid diffusion and surface exchange kinetics of PBCO suggest its application as cathode material in intermediate temperature solid oxide fuel cells. The first complete cell measurements were performed on Ni/CGO/CGO/PBCO/CGO cells. (4) The oxygen exchange kinetics of highly epitaxial thin films of PrBaCo{sub 2}O{sub 5.5+{delta}} (PBCO) has been determined by electrical conductivity relaxation and isotope exchange and depth profiling and confirm the high electronic conductivit

Allan J. Jacobson

2006-09-30T23:59:59.000Z

369

Assessment of Electrical, Efficiency, and Photometric Performance of Advanced Lighting Technologies: Dimmable Advanced Lighting Tech nologies -- Electronic Fluorescent, High-Intensity Discharge, and Light-Emitting Diode  

Science Conference Proceedings (OSTI)

This EPRI Technical Report is a compilation of four technical updates that address the basic dimming performance of advanced lighting sources: EPRI report 1018476 for linear fluorescent ballasts, 1018477 for hot and cold cathode compact fluorescent lamps, 1018479 for electronic high-intensity discharge (HID) ballasts, and 1018480 for light-emitting diode (LED) lighting. Chapter 1 provides a discussion of basic lighting control, the importance of considering power quality in lighting control, lighting con...

2008-12-22T23:59:59.000Z

370

Summary of advanced LMR (Liquid Metal Reactor) evaluations: PRISM (Power Reactor Inherently Safe Module) and SAFR (Sodium Advanced Fast Reactor)  

Science Conference Proceedings (OSTI)

In support of the US Nuclear Regulatory Commission (NRC), Brookhaven National Laboratory (BNL) has performed independent analyses of two advanced Liquid Metal Reactor (LMR) concepts. The designs, sponsored by the US Department of Energy (DOE), the Power Reactor Inherently Safe Module (PRISM) (Berglund, 1987) and the Sodium Advanced Fast Reactor (SAFR) (Baumeister, 1987), were developed primarily by General Electric (GE) and Rockwell International (RI), respectively. Technical support was provided to DOE, RI, and GE, by the Argonne National Laboratory (ANL), particularly with respect to the characteristics of the metal fuels. There are several examples in both PRISM and SAFR where inherent or passive systems provide for a safe response to off-normal conditions. This is in contrast to the engineered safety systems utilized on current US Light Water Reactor (LWR) designs. One important design inherency in the LMRs is the inherent shutdown'', which refers to the tendency of the reactor to transition to a much lower power level whenever temperatures rise significantly. This type of behavior was demonstrated in a series of unscrammed tests at EBR-II (NED, 1986). The second key design feature is the passive air cooling of the vessel to remove decay heat. These systems, designated RVACS in PRISM and RACS in SAFR, always operate and are believed to be able to prevent core damage in the event that no other means of heat removal is available. 27 refs., 78 figs., 3 tabs.

Van Tuyle, G.J.; Slovik, G.C.; Chan, B.C.; Kennett, R.J.; Cheng, H.S.; Kroeger, P.G. (Brookhaven National Lab., Upton, NY (USA))

1989-10-01T23:59:59.000Z

371

Factors Affecting the Battery Performance of Anthraquinone-based Organic Cathode Materials  

Science Conference Proceedings (OSTI)

Two organic cathode materials based on poly(anthraquinonyl sulfide) structure with different substitution positions were synthesized and their electrochemical behavior and battery performances were investigated. The substitution positions on the anthraquinone structure, binders for electrode preparation and electrolyte formulations have been found to have significant effects on the battery performances of such organic cathode materials. The substitution position with less steric stress has higher capacity, longer cycle life and better high-rate capability. Polyvinylidene fluoride binder and ether-based electrolytes are favorable for the high capacity and long cycle life of the quinonyl organic cathodes.

Xu, Wu; Read, Adam L.; Koech, Phillip K.; Hu, Dehong; Wang, Chong M.; Xiao, Jie; Padmaperuma, Asanga B.; Graff, Gordon L.; Liu, Jun; Zhang, Jiguang

2012-02-01T23:59:59.000Z

372

Electrical Contacts between Cathodes and Metallic Interconnects in Solid Oxide Fuel Cells  

Science Conference Proceedings (OSTI)

To minimize electrical resistance, contact layers are often included between interconnects and electrodes during construction of a SOFC stack. In this work, simulated cathode/interconnect structures were used to investigate the effects of different contact materials on the contact resistance between a LSF cathode and a Crofer22 APU interconnect.. The results from the resistance measurements are reported and correlated to interfacial interactions occurring between the metallic interconnect and the contact materials, particularly perovskites. The materials requirements for the contact layers between cathodes and metallic interconnects in intermediate temperature SOFCs are also discussed.

Yang, Z Gary; Xia, Gordon; Singh, Prabhakar; Stevenson, Jeffry W.

2006-04-21T23:59:59.000Z

373

IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY  

Science Conference Proceedings (OSTI)

A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tools development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

2012-11-19T23:59:59.000Z

374

Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries  

DOE Green Energy (OSTI)

The electrochemical properties of LiFePO4 cathodes with different carbon contents were studied to find out the role of carbon as conductive additive. LiFePO4 cathodes containing from 0 percent to 12 percent of conductive additive (carbon black or mixture of carbon black and graphite) were cycled at different C rates. The capacity of LiFePO4 cathode increased, as conductive additive content increased. Carbon increased the utilization of active material and the electrical conductivity of electrode, but decreased volumetric capacity of electrode.

Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

2003-11-25T23:59:59.000Z

375

PolymerGraphene Nanocomposites as Ultrafast-Charge and -Discharge Cathodes for Rechargeable Lithium Batteries  

Science Conference Proceedings (OSTI)

Electroactive polymers are a new generation of 'green' cathode materials for rechargeable lithium batteries. We have developed nanocomposites combining graphene with two promising polymer cathode materials, poly(anthraquinonyl sulfide) and polyimide, to improve their high-rate performance. The polymer-graphene nanocomposites were synthesized through a simple in-situ polymerization in the presence of graphene sheets. The highly dispersed graphene sheets in the nanocomposite drastically enhanced the electronic conductivity and allowed the electrochemical activity of the polymer cathode to be efficiently utilized. This allows for ultrafast charging and discharging - the composite can deliver more than 100 mAh/g within just a few seconds.

Song, Zhiping; Xu, Terrence (Tianren); Gordin, Mikhail; Jiang, Yingbing; Bae, In-Tae; Xiao, Qiangfeng; Zhan, Hui; Liu, Jun; Wang, Donghai

2012-05-09T23:59:59.000Z

376

Argonne TDC: Glass Blower - ANL  

... scientific glassblowers in-house, and that means a shrinking ability to meet demands for highly specialized, custom glassware. ...

377

Office of Technology Transfer - ANL  

Using in-house bench-laboratories, and a pilot-scale plant, Argonne researchers evaluate the effectiveness of recycling strategies and how they may benefit

378

ANL-FF-262i  

Office of Legacy Management (LM)

from our foundry's graphite-melted uranium is remote because of the metalIs high carbon content. High purity metal isto be considered a possible solution of many of the...

379

Argonne TDC: Optodyne, Inc. - ANL  

Subangstrom-Level Laser Doppler Linear Actuator System. Optodyne, Inc. Compton, CA. In the second phase of a cooperative R&D agreement (CRADA) with Optodyne, Inc., a ...

380

Glass Furnace Model (GFM) - ANL  

R&D 100 Award by R&D Magazine as one of the most technologically significant new ... to generate the best results. ... degree in computer science to use the ...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Argonne TDC: Applied Geomechanics - ANL  

As a result of interacting with Knapp and exhibiting at the conference, ... U.S. Department of Energy Office of Science | UChicago Argonne LLC:

382

Argonne TDC: 3M - ANL  

... with analytical results equivalent to those obtained ... This innovative technology has won a 1996 R&D 100 ... U.S. Department of Energy Office of Science ...

383

ANL/APS/TB-18  

NLE Websites -- All DOE Office Websites (Extended Search)

both analytical and finite element, on crystals of various shapes and with different heat exchanger designs. The liquid nitrogen pump has now been delivered, and we have begun...

384

Argonne Software Licensing: RESTORE - ANL  

RESTORE. RESTORE is a program management tool that permits the modeling of a required complex set of steps, including time, or costs, to accomplish the repair of a ...

385

Argonne TDC: Ceramicrete: Potholes - ANL  

... using the same tools." That was in February 1999. ... where winter temperatures and weather conditions wreak havoc with road materials, ...

386

ANL/APS/TB-13  

NLE Websites -- All DOE Office Websites (Extended Search)

heat transfer capabilities. 7 , 8 The tube is filled with a copper foam (copper wool) brazed to the inside walls of the tube for good thermal contact. In addition to...

387

Argonne TDC: Nondisclosure Agreements - ANL  

Nondisclosure Agreements . As some of the research work carried our at Argonne National Laboratory is not yet published or is in the process of being protected ...

388

Recent advances in solid polymer electrolyte fuel cell technology  

DOE Green Energy (OSTI)

With methods used to advance solid polymer electrolyte fuel cell technology, we are close to obtaining the goal of 1 A/cm/sup 2/ at 0.7. Higher power densities have been reported (2 A/cm/sup 2/ at 0.5 V) but only with high catalyst loading electrodes (2 mg/cm/sup 2/ and 4 mg/cm/sup 2/ at anode and cathode, respectively) and using a Dow membrane with a better conductivity and water retention characteristics. Work is in progress to ascertain performances of cells with Dow membrane impregnated electrodes and Dow membrane electrolytes. 5 refs., 6 figs.

Ticianelli, E.A.; Srinivasan, S.; Gonzalez, E.R.

1988-01-01T23:59:59.000Z

389

ANODE, CATHODE AND THIN FILM STUDIES FOR LOW TEMPERATURE SOFC'S  

DOE Green Energy (OSTI)

In this research the microstructure {leftrightarrow} property relations in solid oxide fuel cells (SOFC's) are being studied to better understand the mechanisms involved in cell performance. The overall aim is to fabricate SOFC's with controlled, stable, high performance microstructure. Most cathode studies were completed in the last DOE contract; studies during this year focused more on the influence of nonstoichiometry on the electrical performance. Studies indicate that nonstoichiometric La{sub x}Sr{sub 0.20}MnO{sub 3}(x = 0.70, 0.75, and 0.79) cathode compositions exhibit the best properties. A series of studies using these compositions fired on at temperatures of 1100, 1200, 1300 and 1400 C were performed. In all instances, 1200 C was the optimum, with the x = 0.70 composition being the best. It has an overpotential of only 0.04V at 1 A/cm{sup 2}. SEM analyses indicated no second phases or interdiffusion is detectable. Studies on optimization of anode compositions yielded the optimum volume fraction of Ni (45vol%), the best sintering temperature/time (1400 C/2 h), and the best starting materials (glycine-nitrate derived NiO and normal YSZ). In essence these results simply reflect the optimum microstructure. As such, they are being used to guide the development of optimized anodes for lower temperature operation based on Cu/CeO{sub 2} cermets. Marked success has been achieved on the placement of thin YSZ electrolytes on porous Ni/YSZ electrodes. The process being used is a transfer technique in which dense YSZ films are initially fabricated on NaCl or polymeric substrates, followed by partial dissolution of the substrate and placement of the film on the porous substrate. This technique has allowed us to produce structures with film thicknesses ranging from 70 to 3000 nm, and grain sizes ranging from 2 to 300 nm. Cells based on electrolytes this thick should operate in the 400--700 C range.

Dr. Wayne Huebner; Dr. Harlan U. Anderson

1999-11-01T23:59:59.000Z

390

STATEMENT OF CONSIDERATIONS PETITION FOR ADVANCE WAIVER OF PATENT RIGHTS FOR  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

FOR FOR TECHNOLOGY DEVELOPED UNDER A PROPOSED ANL SUB- CONTRACT UNDER DOE CONTRACT NO. DE-AC02-06CH-11357, W(A)-09-054; CH-1521 As set out in the attached waiver petition and in subsequent discussions with DOE patent counsel, United Technologies Research Center. (UTRC) has requested an advance waiver of domestic and foreign patent rights for all subject inventions made under the identified proposed subcontract by its employees and its subcontractors' employees, regardless of tier, except inventions made by subcontractors eligible to retain title to inventions pursuant to P.L. 96-517, as amended, and National Laboratories. The work under the proposed subcontract is related to, and emanates from, DOE Solicitation No. DE-PS36-08G098010, entitled "Laboratory Call for

391

On-Axis Brilliance and Power of In-Vacuum Undulators for The Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 On-Axis Brilliance and Power of In-Vacuum Undulators for the Advanced Photon Source (formerly MD-TN-2009-004) R. Dejus, M. Jaski, and S.H. Kim - MD Group/ASD Rev. 1, November 25, 2009: Updated the fitted B eff in Tables 1 - 3, and 5 to use two decimals in the fitted equation. Explained chosen gaps. Added clarifications in the text and added additional references. Edited by C. Eyberger for release as cleared document ANL/APS/LS-314; updated in ICMS. Rev. 0a, June 17, 2009: ICMS Initial Release (minor clarifications and corrections of typographical errors, added footnote "d" to Table 4). Rev. 0, June 16, 2009: First Release as Technical Note MD-TN-2009-004. Table of Contents Introduction ......................................................................................................................... 2

392

Methanol-tolerant cathode catalyst composite for direct methanol fuel cells  

oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the ...

393

MANGANESE OXIDE AS A NEW CATHODE CATALYST IN MICROBIAL FUEL CELLS (MFCs).  

E-Print Network (OSTI)

??This study focused on manganese oxides with a cryptomelane-type octahedral molecular sieve (OMS-2) structure to replace platinum as a cathode catalyst in microbial fuel cells (more)

Li, Xiang

2011-01-01T23:59:59.000Z

394

Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries  

E-Print Network (OSTI)

A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

Moore, Charles J. (Charles Jacob)

2012-01-01T23:59:59.000Z

395

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network (OSTI)

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

396

Evaluation of plasma-sprayed CoS{sub 2} cathodes for thermal batteries  

DOE Green Energy (OSTI)

Conventional electroactive stack components in thermal batteries are constructed from pressed-powder parts. These include the anode, separator, and cathode pellets (discs). Pressing parts that are less than 0.010 inch thick is difficult. The use of plasma spray to deposit thin CoS{sub 2} cathode films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The plasma-sprayed electrodes were tested in single cells under isothermal conditions and constant-current discharge over a temperature range of 400 C to 550 C using standard LiSi anodes and separators based on the LiCl-KCl eutectic. Similar tests were conducted with cells built with conventional pressed-powder cathodes, which were tested under the same conditions for comparative purposes. This paper presents the results of those tests.

Guidotti, R.A.

1999-12-22T23:59:59.000Z

397

Short pulse high power microwave generation from an axially extracted virtual cathode oscillator  

Science Conference Proceedings (OSTI)

Preliminary experimental results of an axially extracted virtual cathode oscillator (vircator) built on the low impedance pulsed electron beam accelerator AMBICA-600 is reported. The AMBICA-600 pulsed power system mainly comprises of a coaxial waterline ...

Rishi Verma; Anurag Shyam; Tushar Patel; Y. C. Saxena

2011-02-01T23:59:59.000Z

398

SURFACE SEGREGATION STUDIES OF SOFC CATHODES: COMBINING SOFT X-RAYS AND ELECTROCHEMICAL IMPEDENCE SPECTROSCOPY  

DOE Green Energy (OSTI)

A system to grow heteroepitaxial thin-films of solid oxide fuel cell (SOFC) cathodes on single crystal substrates was developed. The cathode composition investigated was 20% strontium-doped lanthanum manganite (LSM) grown by pulsed laser deposition (PLD) on single crystal (111) yttria-stabilized zirconia (YSZ) substrates. By combining electrochemical impedance spectroscopy (EIS) with x-ray photoemission spectroscopy (XPS) and x-ray absorption spectroscopy XAS measurements, we conclude that electrically driven cation migration away from the two-phase gas-cathode interface results in improved electrochemical performance. Our results provide support to the premise that the removal of surface passivating phases containing Sr2+ and Mn2+, which readily form at elevated temperatures even in O2 atmospheric pressures, is responsible for the improved cathodic performance upon application of a bias.

Miara, Lincoln J.; Piper, L.F.J.; Davis, Jacob N.; Saraf, Laxmikant V.; Kaspar, Tiffany C.; Basu, Soumendra; Smith, K. E.; Pal, Uday B.; Gopalan, Srikanth

2010-12-01T23:59:59.000Z

399

The role of phase transformation in the rate performance limited Lix? V? O? battery cathode  

E-Print Network (OSTI)

It has recently been reported that the rate performance of Lix? V?O?, a widely studied candidate Li-ion battery cathode material, can be significantly improved through a variety of particle size reduction techniques, (e.g. ...

Avery, Kenneth Charles

2009-01-01T23:59:59.000Z

400

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)  

DOE Green Energy (OSTI)

Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

Not Available

2012-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Advanced Technologies for Manufacturing (Fact Sheets)  

Science Conference Proceedings (OSTI)

... cathodes for significantly increased battery performance together ... novel, nanostructured silicon-based anode material for lithium batteries. ...

2011-02-24T23:59:59.000Z

402

Electrochemical Performance and Stability of the Cathode for Solid Oxide Fuel Cells IV. On the Ohmic loss in anode supported button cells with LSM or LSCF cathodes  

Science Conference Proceedings (OSTI)

Anode-supported solid oxide fuel cells (SOFC) with a variety of YSZ electrolyte thicknesses were fabricated by tape casting and lamination. The preparation of the YSZ electrolyte tapes with various thicknesses was accomplished by using doctor blades with different gaps between the precision machined, polished blade and the casting surface. The green tape was cut into discs, sintered at 1385C for 2 h, and subsequently creep-flattened at 1350C for 2 h. Either LSCF with an SDC interlayer or LSM+YSZ composite was used as the cathode material for the fuel cells. The ohmic resistances of these anode-supported fuel cells were characterized by electrochemical impedance spectroscopy at temperatures from 500C to 750C. A linear relationship was found between the ohmic resistance of the fuel cell and the YSZ electrolyte thickness at all the measuring temperatures for both LSCF and LSM+YSZ cathode fuel cells. The ionic conductivities of the YSZ electrolyte, derived for the fuel cells with LSM+YSZ or LSCF cathodes, were independent of the cathode material and cell configuration. The ionic conductivities of the YSZ electrolyte was slightly lower than that of the bulk material, possibly due to Ni-doping into the electrolyte. The fuel cell with a SDC interlayer and LSCF cathode showed larger intercept resistance than the fuel cell with LSM+YSZ cathode, which was possibly due to the imperfect contact between the SDC interlayer and the YSZ electrolyte and the migration of Zr into the SDC interlayer to form an insulating solid solution during cell fabrication. Calculations of the contribution of the YSZ electrolyte to the total ohmic resistance showed that YSZ was still a satisfactory electrolyte at temperatures above 650C. Explorations should be directed to reduce the intercept resistance to achieve significant improvement in cell performance.

Lu, Zigui; Zhou, Xiao Dong; Templeton, Jared W.; Stevenson, Jeffry W.

2010-05-08T23:59:59.000Z

403

II.AdvancedTcl Advanced Tcl  

E-Print Network (OSTI)

119 P A R T II.AdvancedTcl II Advanced Tcl Part II describes advanced programming techniques that support sophisticated applications. The Tcl interfaces remain simple, so you can quickly construct pow- erful applications. Chapter 10 describes eval, which lets you create Tcl programs on the fly

Chen, Yuanzhu Peter

404

Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC and LSCF  

E-Print Network (OSTI)

1 Characterization and Comparison of Different Cathode Materials for SC-SOFC: LSM, BSCF, SSC cathode materials for Single Chamber Solid Oxide Fuel Cell (SC-SOFC) (La0.8Sr0.2MnO3- (LSM), Ba0.5Sr0.5Co0 Chamber, Solid Oxide Fuel cell, SSC. 1 Introduction Single Chamber Solid Oxide Fuel Cells (SC-SOFC) show

405

IN SITU STUDIES ON THE CATALYTIC AND ELECTRONIC PROPERTIES OF MULTI-DIMENSIONAL CATHODE  

DOE Green Energy (OSTI)

The overall objective of this program was to provide the fundamental background to enable SECA Industrial Team Members to select and develop oxide cathodes for the operation of solid oxide fuel cells in the intermediate temperature (500-700 C). A number of experimental techniques were used to address the specific obstacles within the program. The work expanded our existing experimental techniques to the use of in situ diffraction and spectroscopic techniques that are sensitive to the oxygen and iron structural and chemical environment. Such measurements were coupled with the evaluation and determination of the catalytic properties of potential cathode oxides. The scope of the work was to prepare carefully controlled cathode samples of various compositions and microstructure and perform fundamental measurements of their physical properties. The measurement of physical properties of the cathode materials systems were used to correlate those properties to the overall effectiveness of the material as a constituent of an SOFC cell. The measurements techniques of neutron scattering and Moessbauer are relatively unique capabilities which have significance to the LSCF cathode system. The unique ability to make thin film samples can provide special samples for surface science efforts to understand cathodic catalytic activity. The data obtained from neutron diffraction, Moessbauer Spectroscopy, electrical measurements and modeling show that the oxygen vacancy content at 500 C in air for La{sub 0.8}Sr{sub 0.2}MnO{sub 3}, La{sub 0.6}Sr{sub 0.4}FeO{sub 3} and La{sub 0.6}Sr{sub 0.4}Fe{sub 0.8}Co{sub 0.2}O{sub 3-{delta}} are 0, 1% and 5% respectively. This is a significant finding that should relate to performance as a cathode, and gives criteria for the selection of new cathode materials.

Harlan U. Anderson

2003-12-01T23:59:59.000Z

406

Role of surface coating on cathode materials for lithium-ion batteries.  

Science Conference Proceedings (OSTI)

Surface coating of cathode materials has been widely investigated to enhance the life and rate capability of lithium-ion batteries. The surface coating discussed here was divided into three different configurations which are rough coating, core shell structure coating and ultra thin film coating. The mechanism of surface coating in achieving improved cathode performance and strategies to carry out this surface modification is discussed. An outlook on atomic layer deposition for lithium ion battery is also presented.

Chen, Z.; Qin, Y.; Amine, K.; Sun, Y.-K. (Chemical Sciences and Engineering Division); (Hanyang Univ.)

2010-01-01T23:59:59.000Z

407

Overview of the Batteries for Advanced Transportation  

E-Print Network (OSTI)

cobaltate batteries have been in commercial use since 1991. A new lithium-ion battery with different cathodeMn2O4 cathode in lithium ion batteries by using surface modification. Since one of the main reasons cathode material for rechargeable lithium ion batteries because of its high voltage, low cost, and safety

Knowles, David William

408

Alternative and Advanced Fuels  

Energy.gov (U.S. Department of Energy (DOE))

There are a variety of alternative and advanced fuels available, which are used to fuel alternative and advanced vehicles. Learn more about:

409

Help - Advanced Search  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Search The advanced search form will help you create a more specific search in the Publications database. First, specify your search criteria. You can search by author,...

410

Super-iron Nanoparticles with Facile Cathodic Charge Transfer  

Science Conference Proceedings (OSTI)

Super-irons contain the + 6 valence state of iron. One advantage of this is that it provides a multiple electron opportunity to store additional battery charge. A decrease of particle size from the micrometer to the nanometer domain provides a higher surface area to volume ratio, and opportunity to facilitate charge transfer, and improve the power, voltage and depth of discharge of cathodes made from such salts. However, super-iron salts are fragile, readily reduced to the ferric state, with both heat and contact with water, and little is known of the resultant passivating and non-passivating ferric oxide products. A pathway to decrease the super-iron particle size to the nano-domain is introduced, which overcomes this fragility, and retains the battery capacity advantage of their Fe(VI) valence state. Time and power controlled mechanosynthesis, through less aggressive, dry ball milling, leads to facile charge transfer of super-iron nanoparticles. Ex-situ X-ray Absorption Spectroscopy is used to explore the oxidation state and structure of these iron oxides during discharge and shows the significant change in stability of the ferrate structure to lower oxidation state when the particle size is in the nano-domain.

M Farmand; D Jiang; B Wang; S Ghosh; D Ramaker; S Licht

2011-12-31T23:59:59.000Z

411

Advanced Materials in MML  

Science Conference Proceedings (OSTI)

... Advanced Materials Characterization. Fusion Wall Development Research by Neutron Depth Profiling. < Previous 1 2 3 Next . ...

2012-06-12T23:59:59.000Z

412

Office of Science and Technology & International Year End Report - 2005  

E-Print Network (OSTI)

University of Michigan | 2 Argonne National Laboratory (ANL)the Advanced Photon Source at Argonne National Laboratory,Degradation James Jerden, Argonne National Laboratory (ANL)

Bodvarsson, G.S.

2005-01-01T23:59:59.000Z

413

Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries  

SciTech Connect

A variety of approaches are being made to enhance the performance of lithium ion batteries. Incorporating multi-valence transition metal ions into metal oxide cathodes has been identified as an essential approach to achieve the necessary high voltage and high capacity. However, the fundamental mechanism that limits their power rate and cycling stability remains unclear. The power rate strongly depends on the lithium ion drift speed in the cathode. Crystallographically, these transition metal-based cathodes frequently have a layered structure. In the classic wisdom, it is accepted that lithium ion travels swiftly within the layers moving out/in of the cathode during the charge/discharge. Here, we report the unexpected discovery of a thermodynamically driven, yet kinetically controlled, surface modification in the widely explored lithium nickel manganese oxide cathode material, which may inhibit the battery charge/discharge rate. We found that during cathode synthesis and processing before electrochemical cycling in the cell nickel can preferentially move along the fast diffusion channels and selectively segregate at the surface facets terminated with a mix of anions and cations. This segregation essentially blocks the otherwise fast out/in pathways for lithium ions during the charge/discharge. Therefore, it appears that the transition metal dopant may help to provide high capacity and/or high voltage, but can be located in a wrong location that blocks or slows lithium diffusion, limiting battery performance. In this circumstance, limitations in the properties of Li-ion batteries using these cathode materials can be determined more by the materials synthesis issues than by the operation within the battery itself.

Gu, Meng; Belharouak, Ilias; Genc, Arda; Wang, Zhiguo; Wang, Dapeng; Amine, Khalil; Gao, Fei; Zhou, Guangwen; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

2012-09-17T23:59:59.000Z

414

BOUT++: Performance Characterization and Recent Advances in Design  

NLE Websites -- All DOE Office Websites (Extended Search)

BOUT++: BOUT++: Performance Characterization and Recent Advances in Design Sean Farley, 1,2 Ben Dudson, 3 Praveen Narayanan, 4 Lois Curfman McInnes, 1 Maxim Umansky, 5 Xueqiao Xu, 5 Satish Balay, 1 John Cary, 6 Alice Koniges, 4 Carol Woodward, 5 Hong Zhang 1 Edge Localized Modes ￿ Fast (∼ 100µs) eruption from the edge of tokamak plasmas ￿ If uncontrolled in ITER, these would release ∼ 20 MJ ￿ World-wide effort to understand and control these events The BOUT++ Simulation Code ￿ Based on BOUT written by X. Xu, et. al. from LLNL [1] ￿ New 3D simulation code developed at York with LLNL and ANL ￿ Simulates plasma fluid equations in curvilinear coordinate systems ￿ Runs on workstations, clusters, large-scale machines, e.g., Cray XE6 ELM Equations ρ 0 dω dt = B 2 0 b · ∇ ￿ J || B 0 ￿ + 2b 0 × κ 0 · ∇p ∂A || ∂t = -∇ || φ dp dt = - 1 B 0 b 0 × ∇φ · ∇p 0 ω = 1 B 0 ∇ 2 ⊥ φ J || = J ||0 - 1 µ

415

Advanced Photon Source (APS) Colloquium Series Video Collection from 2011  

DOE Data Explorer (OSTI)

The Advanced Photon Source (APS) at Argonne National Laboratory allows scientists to pursue new knowledge in many different scientific disciplines. The monthly APS Colloquium series brings these distinguished scientists to Illinois from all around the world to lecture on topics of general interest. Some of these presentations are available as integrated video and slides. The 2011 talks are posted on the APS website after their presentation dates. Titles include: 1) Atomic Resolution Coherent Diffractive Imaging and Ultrafast Science, Jian-min Zuo (University of Illinois); 2) Opportunties for X-ray Science in Future Computing Architectures, Ian Foster (ANL); 3) Fifth-Generation Free-Electron Laser Light Sources, Claudio Pellegrini (UCLA); 4) Observing Structure and Motion in Molecules with Ultrafast Strong Field and Short Wavelength Laser Radiation, Philip H. Bucksbaum (National Academy of Sciences); 5) The Cambrian Evolutionary Explosion: Novel Evidence from Fossils Studied by X-ray Tomography, Jun-Yuan Chen (Nanjing University, China); 6) Emerging Properties of Quantum Matter: Case Studies of Topological and Superconducting Phases, Zhi-Xun Shen (Stanford University); 7) X-ray Imaging Based on Compton Scattering, Joseph Callerame (American Scient and Engineering, Inc.); 8) Using Synchrotron Radiation and Electron Microscopy to Map the Huge Structural Changes that Occur in Viruses During Their Life Cycle, Michael Rossman (Purdue University); 9) Coherent Control of Quantum Matter, Andrea Cavalleri (Max Planck Institute); 10) Gravitational-Wave Detectors: First, Second, and Third Generation, Vuk Mandic (University of Minnesota).

416

A comparative study of PtCo/C Alloys and Pt/C as cathode catalysts for fuel cell applications.  

E-Print Network (OSTI)

??Commercialisation of fuel cells for automotive applications requires catalysts with both improved activity, particularly for the cathodic oxygen reduction reaction (ORR), and stability over commercial (more)

Burton, Sarah

2009-01-01T23:59:59.000Z

417

Single Phase LiNixFe1-xPO4 Solid Solution as Cathode Material for ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Olivine type materials are extensively studied as cathode materials in lithium ion batteries due to their high discharge capacity, long cycling life...

418

A Method for Monitoring Deposition at a Solid Cathode in an Electrorefiner for a Two-Species System Using Electrode Potentials  

SciTech Connect

Currently, process monitoring of spent nuclear fuel electrorefining relies upon sampling and destructive analysis methods coupled with extrapolative thermodynamic process models for non-interrupted operations. Corrections to those models are performed infrequently, jeopardizing both the control of the process and safeguarding of nuclear material. Furthermore, the timeliness of obtaining the results is inadequate for application of international safeguards protocol. Alternatively, a system that dynamically utilizes electrical data such as electrode potentials and cell current can hypothetically be used to achieve real-time process monitoring and more robust control as well as improved safeguards. Efforts to develop an advanced model of the electrorefiner to date have focused on a forward modeling approach by using feed and salt compositions to determine the product composition, cell current and electrode potential response. Alternatively, an inverse model was developed, and reported here, to predict the product deposition rates on a cathode using the cell current, cathode potential, and fundamental relations of electrochemistry. The model was applied to the following cases: pure uranium deposition, co-deposition of uranium and plutonium, and co-deposition of uranium and zirconium. The deposition rates predicted by the inverse model were compared to those of a forward model, ERAD.

D.S. Rappleye; M.-S. Yim; M.F. Simpson; R.M. Cumberland

2013-10-01T23:59:59.000Z

419

Determination of the cathode and anode voltage drops in high power low-pressure amalgam lamps  

Science Conference Proceedings (OSTI)

For the first time, cathode and anode drops of powerful low-pressure amalgam lamps were measured. The lamp discharge current is 3.2 A, discharge current frequency is 43 kHz, linear electric power is 2.4 W/cm. The method of determination of a cathode drop is based on the change of a lamp operating voltage at variation of the electrode filament current at constant discharge current. The total (cathode plus anode) drop of voltage was measured by other, independent ways. The maximum cathode fall is 10.8 V; the anode fall corresponding to the maximal cathode fall is 2.4 V. It is shown that in powerful low pressure amalgam lamps the anode fall makes a considerable contribution (in certain cases, the basic one) to heating of electrodes. Therefore, the anode fall cannot be neglected, at design an electrode and ballast of amalgam lamps with operating discharge current frequency of tens of kHz.

Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute for High Temperatures (Russian Federation); Vasiliev, A. I., E-mail: vasiliev@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V.; Startsev, A. Yu. [Joint Stock Company NPO LIT (Russian Federation); Kudryavtsev, N. N. [Moscow Institute of Physics and Technology (State University) (Russian Federation)

2011-12-15T23:59:59.000Z

420

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

DOE Green Energy (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Microsoft Word - Poster Abstract_2010_GATech_LSM-Infiltrated LSCF Cathodes.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

and Interfaces and Interfaces in LSM-Infiltrated LSCF Cathodes Wentao Qin, Mingfei Liu, Matthew E. Lynch, Jong-jin Choi and Meilin Liu Center for Innovative Fuel Cell and Battery Technologies School of Materials Science and Engineering Georgia Institute of Technology 771 Ferst Dr., Atlanta, GA 30332-0245 Telephone: 404-894-6114 Email: meilin.liu@mse.gatech.edu Recent studies suggest that the stability and performance of a porous La x Sr 1-x Co y Fe 1-y O 3- (LSCF) cathode may be enhanced by the infiltration of a thin-film La x Sr 1-x MnO 3- (LSM) coating. However, the mechanism of the observed enhancement is still unknown. This poster will present our recent findings in microanalyses of the structure, composition, and morphology of the LSM and LSCF surfaces as well as the LSM/LSCF interfaces in LSM-infiltrated LSCF cathodes. Results indicate that a

422

Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative and Durable High Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Development of Alternative and Durable High Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Performance Cathode Supports for PEM Fuel Cells PNNL: Yong Wang Conrad Zhang Vilayanur Viswanath Yuehe Lin Jun Liu Project kick Project kick - - off meeting off meeting Feb 13 Feb 13 - - 14, 2007 14, 2007 Ballard Power Systems: Stephen Campbell University of Delaware: Jingguang Chen ORNL: Sheng Dai 2 Technical Issues and Objective Technical Issues and Objective Current technical issues z Carbon support „ Susceptible to oxidation under fuel cell operating conditions. „ Oxidation further catalyzed by Pt „ Corrosion leads to Pt migration and agglomeration

423

DC sputtered indium-tin oxide transparent cathode for organic light-emitting diodes  

E-Print Network (OSTI)

AbstractThe performance of top-emitting organic light-emitting diodes depends not just on the choice of the transparent cathodes but also on their techniques of formation. Compared to the damage induced by radio frequency sputtering of indium-tin oxide cathode, that induced by dc sputtering was verified to be less severe and relatively independent of the sputtering power. Consequently, a high dc sputtering power of 120 W could be employed to achieve a high deposition rate of 0.1 nm/s. Adequate emission efficiency was maintained, even with a relatively thin 7-nm copper (II) phthalocyanine buffer layer. Index TermsIndium-tin oxide, organic light-emitting diodes, sputtering, top-emission, transparent cathode. I.

Haiying Chen; Chengfeng Qiu; Man Wong; Hoi Sing Kwok

2003-01-01T23:59:59.000Z

424

Nuclear fusion advances  

Science Conference Proceedings (OSTI)

The last decade has seen advances in the shaping and confinement of plasmas, and in approaches to noninductive current drive. Here, the author presents an overview of nuclear fusion advances between 1983-93 examining: fusion milestones; plasma shaping; ...

W. Sweet

1994-02-01T23:59:59.000Z

425

AdvAnced  

NLE Websites -- All DOE Office Websites (Extended Search)

AdvAnced test reActor At the InL advanced Unlike large, commercial power reactors, ATR is a low- temperature, low-pressure reactor. A nuclear reactor is basically an elaborate tool...

426

Cathode limited charge transport and performance of thin-film rechargeable lithium batteries  

DOE Green Energy (OSTI)

Several types of thin-film rechargeable batteries based on lithium metal anodes and amorphous V{sub 2}O{sub 5} (aV{sub 2}O{sub 5}), LiMn{sub 2}O{sub 4}, and LiCoO{sub 2} cathodes have been investigated in this laboratory. In all cases, the current density of these cells is limited by lithium ion transport in the cathodes. This paper, discusses sources of this impedance in Li-aV{sub 2}O{sub 5} and Li-LiMn{sub 2}O{sub 4} thin-film cells and their effect on cell performance.

Bates, J.B.; Hart, F.X.; Lubben, D.; Kwak, B.S.; van Zomeren, A.

1994-11-01T23:59:59.000Z

427

Composite Cathode for High-Power Density Solid Oxide Fuel Cells  

DOE Green Energy (OSTI)

Reduction of solid oxide fuel cell (SOFC) operating temperature will play a key role in reducing the stack cost by allowing the use of low-cost metallic interconnects and new approaches to sealing, while making applications such as transportation more feasible. Reported results for anode-supported SOFCs show that cathode polarization resistance is the primary barrier to achieving high power densities at operating temperatures of 700 C and lower. This project aims to identify and develop composite cathodes that could reduce SOFC operating temperatures below 700 C. This effort focuses on study and use of (La,Sr)(Co,Fe)O{sub 3} (LSCF) based composite cathodes, which have arguably the best potential to substantially improve on the currently-used, (La,Sr)MnO{sub 3}-Yttria-stabilized Zirconia. During this Phase I, it was successfully demonstrated that high performances can be achieved with LSCF/Gadolinium-Doped Ceria composite cathodes on Ni-based anode supported cells operating at 700 C or lower. We studied electrochemical reactions at LSCF/Yttria-stabilized Zirconia (YSZ) interfaces, and observed chemical reactions between LSCF and YSZ. By using ceria electrolytes or YSZ electrolytes with ceria diffusion barrier layers, the chemical reactions between LSCF and electrolytes were prevented under cathode firing conditions necessary for the optimal adhesion of the cathodes. The protection provided by ceria layer is expected to be adequate for stable long-term cathode performances, but more testing is needed to verify this. Using ceria-based barrier layers, high performance Ni-YSZ anode supported cells have been demonstrated with maximum power densities of 0.8W/cm2 at 700 C and 1.6W/cm{sup 2} at 800 C. Ni-SDC anode supported cells with SDC electrolytes yielded >1W/cm{sup 2} at 600 C. We speculate that the power output of Ni-YSZ anode supported cell at 700 C and lower, was limited by the quality of the Ceria and Ceria YSZ interface. Improvements in the low-temperature performances are expected based on further development of barrier layer fabrication processes and optimization of cathode microstructure.

Ilwon Kim; Scott Barnett; Yi Jiang; Manoj Pillai; Nikkia McDonald; Dan Gostovic; Zhongryang Zhan; Jiang Liu

2004-01-31T23:59:59.000Z

428

ADVANCED DATA SECURITY  

Science Conference Proceedings (OSTI)

ADVANCED DATA SECURITY. NVLAP Lab Code: 200968-0. Address and Contact Information: 1933 O'Toole Avenue San ...

2013-11-08T23:59:59.000Z

429

Fatigue of Advanced Materials  

Science Conference Proceedings (OSTI)

Oct 19, 2011... isolate the internal components from the external environment while ... overall thermal efficiency of advanced internal combustion engines...

430

Advancement of Electrochromic Windows  

E-Print Network (OSTI)

advanced spectrally selective low-e double-pane windows and the same type of daylighting control system

2006-01-01T23:59:59.000Z

431

Advanced High Frequency Devices  

Science Conference Proceedings (OSTI)

... External agencies, including the Defense Advanced Research Projects Agency (DARPA) and the Office of Naval Research (ONR), have ...

2010-10-05T23:59:59.000Z

432

Supporting Advanced Communications Networks  

Science Conference Proceedings (OSTI)

... it will rely on revolutionary advances in network architecture. ... telemedicine), sensor and control networks (eg, Smart Grid, environmental monitoring ...

2012-02-13T23:59:59.000Z

433

Cathodes for secondary electrochemical power-producing cells. [layers of porous substrates impregnated with S alternate with layers containing electrolyte  

DOE Patents (OSTI)

A secondary electrochemical power-producing cell includes an anode containing lithium, an electrolyte containing lithium ions, and a cathode containing sulfur. The cathode comprises plates of a porous substrate material impregnated with sulfur alternating with layers (which may also comprise porous substrate plates) containing electrolyte.

Cairns, E.J.; Kyle, M.; Shimotake, H.

1973-02-13T23:59:59.000Z

434

Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

That Will Advance Solid Oxide Fuel Cell Research That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development July 27, 2012 - 1:00pm Addthis Washington, D.C. - Seven projects that will help develop low-cost solid oxide fuel cell (SOFC) technology for environmentally responsible central power generation from the Nation's abundant fossil energy resources have been selected for further research by the Department of Energy (DOE). The projects, managed by the Office of Fossil Energy's National Energy Technology Laboratory (NETL), are valued at a total of $4,391,570, with DOE contributing $3,499,250 and the remaining cost provided by the recipients. Four of the selected projects will pursue advances in cathode performance,

435

Advanced Manufacturing Office: Better Plants  

NLE Websites -- All DOE Office Websites (Extended Search)

Better Plants on Twitter Bookmark Advanced Manufacturing Office: Better Plants on Google Bookmark Advanced Manufacturing Office: Better Plants on Delicious Rank Advanced...

436

Advanced Manufacturing Office: Pump Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Pump Systems on Twitter Bookmark Advanced Manufacturing Office: Pump Systems on Google Bookmark Advanced Manufacturing Office: Pump Systems on Delicious Rank Advanced...

437

Session: CSP Advanced Systems -- Advanced Overview (Presentation)  

DOE Green Energy (OSTI)

The project description is: (1) it supports crosscutting activities, e.g. advanced optical materials, that aren't tied to a single CSP technology and (2) it supports the 'incubation' of new concepts in preliminary stages of investigation.

Mehos, M.

2008-04-01T23:59:59.000Z

438

STATEMENT OF CONSIDERATIONS PETITION FOR ADVANCE WAIVER OF PATENT RIGHTS BY 3M  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

COMPANY C'3M") UNDER COOPERATIVE AGREEMENT NO. DE-FC36 07G017006 BETWEEN 3M AND DOE; W(A)-OS-01S; CH-1441 The Petitioner, 3M, has requested a waiver of domestic and certain foreign patent rights for all subject inventions that may be conceived or first actually reduced to practice by 3M arising from its participation under the above referenced cooperative agreement entitled "Advanced Cathode Catalysts and Supports for PEM Fuel Cells." The objectives of the project are development of a durable, low cost (pt group metal content and manufacturability), high performance cathode catalyst and support system capable of demonstrating mass activity greater than or equal to 0.44 AlmgPt, generating a stack specific power density of less than

439

STATEMENT OF CONSIDERATIONS PETITION FOR ADVANCE WAIVER OF PATENT RIGHTS BY  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

JOHNSON MATTHEY FUEL CELL INC. ("JMFC") UNDER A SUB- JOHNSON MATTHEY FUEL CELL INC. ("JMFC") UNDER A SUB- AWARD OF COOPERATIVE AGREEMENT NO. DE-FC36-07G017019 BETWEEN UTC POWER CORPORATION (UTC) AND DOE; W(A)-09- 002; CH·1468 The Petitioner, JMFC, has requested a waiver of domestic and certain foreign patent rights for all subject inventions that may be conceived or first actually reduced to practice by JMFC Of: its affiliates arising from their participation under a sub-award to the above referenced cooperative agreement entitled "Highly Dispersed Alloy Cathode Catalyst for Durability." ' The objective of the sub-award is to develop an advanced PEMFC cathode alloy catalyst with high mass activity and outstanding catalyst stability, meeting DOE's Energy Efficiency and Renewable Energy (EERE) targets. More specifically, the object

440

Report on sodium compatibility of advanced structural materials.  

SciTech Connect

This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T. (Nuclear Engineering Division)

2012-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder  

E-Print Network (OSTI)

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder Zhi lithium­sulfur batteries have attracted great interest in recent years because of their high theoretical specific energy, which is several times that of current lithium-ion batteries. Compared to sulfur, fully

Cui, Yi

442

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode Particles  

E-Print Network (OSTI)

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode sur- faces in postmortem analysis of batteries.5-7 Stress generation results from lithium-ion, as will be discussed later. Heat transfer analyses of lithium-ion batteries have stemmed from work on full cells.10

Sastry, Ann Marie

443

Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga  

E-Print Network (OSTI)

1 Nitrogen atom energy distributions in a hollow-cathode planar sputtering magnetron Zhehui Wanga.O. Box 451, Princeton, NJ 08543 May 31, 1999 Abstract Energy distributions of N atoms in a hollow, University of Illinois c Varian Associates, Inc. #12;2 atom energy distributions for atomic ions

444

Arc-melting preparation of single crystal LaB.sub.6 cathodes  

DOE Patents (OSTI)

A method for preparing single crystals of lanthanum hexaboride (LaB.sub.6) by arc melting a rod of compacted LaB.sub.6 powder. The method is especially suitable for preparing single crystal LaB.sub.6 cathodes for use in scanning electron microscopes (SEM) and scanning transmission electron microscopes (STEM).

Gibson, Edwin D. (Ames, IA); Verhoeven, John D. (Ames, IA)

1977-06-21T23:59:59.000Z

445

Effect of Cathode Pore Volume on PEM Fuel Cell Cold Start Ashis Nandy,a  

E-Print Network (OSTI)

of the intraelectrode ice formation theory,5 which explains ice formation in the cathode catalyst layer CCL as the key with resulting tem- perature rise and water production or ice formation in the CCL. Ice formation in the CCL mainly through back-diffusion into the membrane and through vapor-phase transport from CCL

446

Effect of cycling rate, particle size and transport properties on lithium-ion cathode performance  

E-Print Network (OSTI)

voltage. The extension of such energy sys- tems from portable electronics to hybrid and electric vehicles, University of Michigan, Ann Arbor, MI 48109, USA a r t i c l e i n f o Article history: Received 5 November and electrical conductivity of the solid cathode material, on the specific energy and power have been studied

Shyy, Wei

447

Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study  

DOE Green Energy (OSTI)

In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

1991-12-31T23:59:59.000Z

448

Synchrotron X-ray diffraction studies of phase transitions and mechanical properties of nanocrystalline materials at high pressure  

E-Print Network (OSTI)

unlike the Advanced Photon Source (APS) or the StanfordReport ANL/APS/TB-30, Advanced Photon Source, Argonne

Prilliman, Gerald Stephen

2003-01-01T23:59:59.000Z

449

Comparison of the PLTEMP code flow instability predictions with measurements made with electrically heated channels for the advanced test reactor.  

SciTech Connect

When the University of Missouri Research Reactor (MURR) was designed in the 1960s the potential for fuel element burnout by a phenomenon referred to at that time as 'autocatalytic vapor binding' was of serious concern. This type of burnout was observed to occur at power levels considerably lower than those that were known to cause critical heat flux. The conversion of the MURR from HEU fuel to LEU fuel will probably require significant design changes, such as changes in coolant channel thicknesses, that could affect the thermal-hydraulic behavior of the reactor core. Therefore, the redesign of the MURR to accommodate an LEU core must address the same issues of fuel element burnout that were of concern in the 1960s. The Advanced Test Reactor (ATR) was designed at about the same time as the MURR and had similar concerns with regard to fuel element burnout. These concerns were addressed in the ATR by two groups of thermal-hydraulic tests that employed electrically heated simulated fuel channels. The Croft (1964), Reference 1, tests were performed at ANL. The Waters (1966), Reference 2, tests were performed at Hanford Laboratories in Richland Washington. Since fuel element surface temperatures rise rapidly as burnout conditions are approached, channel surface temperatures were carefully monitored in these experiments. For self-protection, the experimental facilities were designed to cut off the electric power when rapidly increasing surface temperatures were detected. In both the ATR reactor and in the tests with electrically heated channels, the heated length of the fuel plate was 48 inches, which is about twice that of the MURR. Whittle and Forgan (1967) independently conducted tests with electrically heated rectangular channels that were similar to the tests by Croft and by Walters. In the Whittle and Forgan tests the heated length of the channel varied among the tests and was between 16 and 24 inches. Both Waters and Whittle and Forgan show that the cause of the fuel element burnout is due to a form of flow instability. Whittle and Forgan provide a formula that predicts when this flow instability will occur. This formula is included in the PLTEMP/ANL code.Error! Reference source not found. Olson has shown that the PLTEMP/ANL code accurately predicts the powers at which flow instability occurs in the Whittle and Forgan experiments. He also considered the electrically heated tests performed in the ANS Thermal-Hydraulic Test Loop at ORNL and report by M. Siman-Tov et al. The purpose of this memorandum is to demonstrate that the PLTEMP/ANL code accurately predicts the Croft and the Waters tests. This demonstration should provide sufficient confidence that the PLTEMP/ANL code can adequately predict the onset of flow instability for the converted MURR. The MURR core uses light water as a coolant, has a 24-inch active fuel length, downward flow in the core, and an average core velocity of about 7 m/s. The inlet temperature is about 50 C and the peak outlet is about 20 C higher than the inlet for reactor operation at 10 MW. The core pressures range from about 4 to about 5 bar. The peak heat flux is about 110 W/cm{sup 2}. Section 2 describes the mechanism that causes flow instability. Section 3 describes the Whittle and Forgan formula for flow instability. Section 4 briefly describes both the Croft and the Waters experiments. Section 5 describes the PLTEMP/ANL models. Section 6 compares the PLTEMP/ANL predictions based on the Whittle and Forgan formula with the Croft measurements. Section 7 does the same for the Waters measurements. Section 8 provides the range of parameters for the Whittle and Forgan tests. Section 9 discusses the results and provides conclusions. In conclusion, although there is no single test that by itself closely matches the limiting conditions in the MURR, the preponderance of measured data and the ability of the Whittle and Forgan correlation, as implemented in PLTEMP/ANL, to predict the onset of flow instability for these tests leads one to the conclusion that the same method should be able to predict the

Feldman, E. (Nuclear Engineering Division)

2011-06-09T23:59:59.000Z

450

Advanced Manufacturing Office: Technical Assistance  

NLE Websites -- All DOE Office Websites (Extended Search)

Assistance on Twitter Bookmark Advanced Manufacturing Office: Technical Assistance on Google Bookmark Advanced Manufacturing Office: Technical Assistance on Delicious Rank...

451

Advanced Manufacturing Office: Financial Opportunities  

NLE Websites -- All DOE Office Websites (Extended Search)

on Twitter Bookmark Advanced Manufacturing Office: Financial Opportunities on Google Bookmark Advanced Manufacturing Office: Financial Opportunities on Delicious Rank...

452

HIGH-CURRENT COLD CATHODE FIELD EMISSION ARRAY FOR ELECTRON LENS APPLICATION  

SciTech Connect

During Phase I, the following goals were achieved: (1) design and fabrication of a novel, nano-dimensional CNT field emitter assembly for high current density application, with high durability; (2) fabrication of a ceramic based micro channel plate (MCP) and characterization of its secondary electron emission; and (3) characterizing the CNT/MCP cathode for high field emission and durability. As a result of these achievements, a relatively high current density of ~ 1.2 A/cm2 from a CNT cathode and single channel MCP were measured. The emission current was also extremely stable with a peak-to-peak variation of only 1.8%. The emission current could be further enhanced to meet requirements for electron lens applications by increasing the number of MCP channels. A calculation for maximum possible current density with a 1200 channel/cm2 MCP, placed over a cathode with 1200 uniformly functioning CNTs, would be ~1.46 kA/cm2, neglecting space charge limitations. Clearly this level of emission is far greater than what is needed for the electron lens application, but it does offer a highly comforting margin to account for sub-standard emitters and/or to allow the lesser challenge of building a cathode with fewer channels/cm2. A satisfactory goal for the electron lens application would be a controllable emission of 2-4 mA per channel in an ensemble of 800-1200 uniformly-functioning channels/cm2, and a cathode with overall area of about 1 cm2.

Hirshfield, Jay L

2012-12-28T23:59:59.000Z

453

Advanced Concepts Breakout Group  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop Workshop Advanced Concepts Working Group Facilitator: John J. Petrovic Scribe: Sherry Marin Advanced Storage Techniques/ Approaches in Priority Order 1. Crystalline Nanoporous Materials (15) 2. Polymer Microspheres (12) Self-Assembled Nanocomposites (12) 3. Advanced Hydrides (11) Metals - Organic (11) 4. BN Nanotubes (5) Hydrogenated Amorphous Carbon (5) 5. Mesoporous materials (4) Bulk Amorphous Materials (BAMs) (4) 6. Iron Hydrolysis (3) 7. Nanosize powders (2) 8. Metallic Hydrogen (1) Hydride Alcoholysis (1) Overarching R&D Questions for All Advanced Materials * Maximum storage capacity - theoretical model * Energy balance / life cycle analysis * Hydrogen absorption / desorption kinetics * Preliminary cost analysis - potential for low cost, high

454

Institute for Advanced Studies  

NLE Websites -- All DOE Office Websites (Extended Search)

Institute for Advanced Studies Institute for Advanced Studies Institute for Advanced Studies NMC leverages the strengths of three research universities to build joint programs, develop strategic partnerships, provide common organization and facilities. Contact Leader TBD LANL Program Administrator Pam Hundley (505) 663-5453 Email Building regional partnerships in education, leveraging strengths of three research universities The Institute for Advanced Studies (IAS) works with the three New Mexico research universities (University of New Mexico, New Mexico Tech, and New Mexico State University) to develop research and educational collaborations and partnerships. To facilitate interactions between the universities and LANL, the three New Mexico schools established the New Mexico Consortium (NMC), a nonprofit

455

Advanced Materials | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

Research Areas Research Areas Research Highlights Facilities and Capabilities Science to Energy Solutions News & Awards Events and Conferences Supporting Organizations Directionally Solidified Materials Using high-temperature optical floating zone furnace to produce monocrystalline molybdenum alloy micro-pillars Home | Science & Discovery | Advanced Materials Advanced Materials | Advanced Materials SHARE ORNL has the nation's most comprehensive materials research program and is a world leader in research that supports the development of advanced materials for energy generation, storage, and use. We have core strengths in three main areas: materials synthesis, characterization, and theory. In other words, we discover and make new materials, we study their structure,

456

Advanced Research Materials Program  

NLE Websites -- All DOE Office Websites (Extended Search)

materials requirements for all fossil energy systems, including materials for advanced power generation and coal fuels technologies. Examples of these technologies include coal...

457

Project: Advanced Fire Detection  

Science Conference Proceedings (OSTI)

... residential fire deaths through development of measurement ... Beyond advances in sensing technologies, a key ... data will be used to develop and test ...

2013-05-30T23:59:59.000Z

458

advance meeting brochure  

Science Conference Proceedings (OSTI)

May 23, 1999 ... Ponte Vedra Beach, Florida, USA. ADVANCE PROGRAM ..... but she has two enclosed glass-sided decks, an out- side balcony and the...

459

Brochures | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Podcasts Image Gallery external site Video Library Syndicated Feeds (RSS) The Advanced Photon Source: Lighting the Way to a Better Tomorrow aps brochure The APS helps...

460

Divisions | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Chart Argonne Research Divisions APS Research Divisions In May 2002, The Advanced Photon Source was reorganized into three divisions: the Accelerator Systems Division...

Note: This page contains sample records for the topic "advanced anl cathode" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Advanced Mixing Models  

Propose mixing indicators. Turbulence kinetic energy ... (Turbulence intensity observed at Point 8 in Tank B & C) Advanced Mixing Models. Computational Sciences. 13.

462

Advancement in Battery Materials  

Science Conference Proceedings (OSTI)

Oct 18, 2010 ... Advanced Electrochemical Storage for Renewable Integration and Utility Applications: Zhenguo "Gary" Yang1; Dawon Choi1; Gordon Graff1;...

463

OpenADR Advances  

NLE Websites -- All DOE Office Websites (Extended Search)

Volume 54 Issue 11 Date Published 112012 Keywords communication and standards, openadr, smart grid Abstract An important goal for the advancement of smart grid deployments is to...

464

DOE Advanced Protection Project  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Task 3 - Advanced Protection - Evaluate measures - 2009 - Design, model Irvine Smart Grid Demo protection system - 2010 6 Copyright 2010, Southern California Edison Task 1 -...

465

Advanced Combustion, Emission Control, Health Impacts, and Fuels Merit Review and Peer Evaluation  

NLE Websites -- All DOE Office Websites (Extended Search)

06 06 a n n u a l p r o g r e s s r e p o r t L e s s d e p e n d e n c e o n f o r e i g n o i l t o d a y, a n d t r a n s i t i o n t o a p e t r o l e u m - f r e e , e m i s s i o n s - f r e e v e h i c l e t o m o r r o w . F r e e d o m C A r A n d V e h i C l e T e C h n o l o g i e s P r o g r A m AdvAnced combustion, emission controls, HeAltH impActs, And Fuels merit review And peer evAluAtion Department of Energy Washington, DC 20585 October 2006 Dear Colleague: This document summarizes the comments provided by the Review Panel for the FY 2006 Department of Energy (DOE) Advanced Combustion, Emission Controls, Health Impacts, and Fuels Merit Review and Peer Evaluation Meeting, the "ACE Review," held on May 15-18, 2006 at Argonne National Laboratory (ANL). The raw evaluations and comments of the panel were provided (with reviewers' names deleted) to the presenters in early June and were used by national laboratory

466

Advanced Recyclable Media System{reg_sign}. Innovative technology summary report  

SciTech Connect

The objective of the Large-Scale Demonstration Project (LSDP) is to select and demonstrate potentially beneficial technologies at the Argonne National Laboratory East`s (ANL) Chicago Pile-5 (CP-5) Research Reactor. The purpose of the LSDP is to demonstrate that using innovative and improved deactivation and decommissioning (D and D) technologies from various sources can result in significant benefits, such as decreased cost and increased health and safety, as compared with baseline D and D technologies. This report describes a demonstration of the Advanced Recyclable Media System{reg_sign} technology which was employed by Surface Technology Systems, Inc. to remove coatings from a concrete floor. This demonstration is part of the CP-5 LSDP sponsored by the US Department of Energy (DOE) Office of Science and Technology Deactivation and Decommissioning Focus Area (DDFA). The Advanced Recyclable Media System{reg_sign} (ARMS) technology is an open blast technology which uses a soft recyclable media. The patented ARMS Engineered Blast Media consists of a fiber-reinforced polymer matrix which can be manufactured in various grades of abrasiveness. The fiber media can be remade and/or reused up to 20 times and can clean almost any surface (e.g., metal, wood, concrete, lead) and geometry including corners and the inside of air ducts.

NONE

1998-12-01T23:59:59.000Z

467

APS Visitor Registration Form | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

APS Visitor Registration Form APS Visitor Registration Form To request access as a visitor who will not do hands-on work, please complete this form. For assistance, contact the APS User Office by phone at (630) 252-9090 or by email at apsuser@aps.anl.gov. Please request access directly by contacting the APS User Office by phone at (630) 252-9090 or by email at apsuser@aps.anl.gov. If you are concerned about sending your passport and visa information, leave those fields blank and fax a letter to (630) 252-9250. To Request APS Visitor Registration, please enter the following: * indicates required field First Name*: Middle Initial/Name*: Last Name*: Title: Organization*: Department: Address 1*: Address 2: City*: State*: Zip Code*: Country: Phone*: Fax: E-mail Address*: Gender*: Female

468

Kansas Advanced Semiconductor Project  

SciTech Connect

KASP (Kansas Advanced Semiconductor Project) completed the new Layer 0 upgrade for D0, assumed key electronics projects for the US CMS project, finished important new physics measurements with the D0 experiment at Fermilab, made substantial contributions to detector studies for the proposed e+e- international linear collider (ILC), and advanced key initiatives in non-accelerator-based neutrino physics.

Baringer, P.; Bean, A.; Bolton, T.; Horton-Smith, G.; Maravin, Y.; Ratra, B.; Stanton, N.; von Toerne, E.; Wilson, G.

2007-09-21T23:59:59.000Z

469

Advanced Windows Test Facility  

NLE Websites -- All DOE Office Websites (Extended Search)

Exterior of Advanced Windows Test Facility Exterior of Advanced Windows Test Facility Advanced Windows Test Facility This multi-room laboratory's purpose is to test the performance and properties of advanced windows and window systems such as electrochromic windows, and automatically controlled shutters and blinds. The lab simulates real-world office spaces. Embedded instrumentation throughout the lab records solar gains and losses for specified time periods, weather conditions, energy use, and human comfort indicators. Electrochromic glazings promise to be a major advance in energy-efficient window technology, helping to achieve the goal of transforming windows and skylights from an energy liability in buildings to an energy source. The glazing can be reversibly switched from a clear to a transparent, colored

470

Advanced Fuels Synthesis  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Fuels Synthesis Advanced Fuels Synthesis Coal and Coal/Biomass to Liquids Advanced Fuels Synthesis The Advanced Fuels Synthesis Key Technology is focused on catalyst and reactor optimization for producing liquid hydrocarbon fuels from coal/biomass mixtures, supports the development and demonstration of advanced separation technologies, and sponsors research on novel technologies to convert coal/biomass to liquid fuels. Active projects within the program portfolio include the following: Fischer-Tropsch fuels synthesis Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Pilot Plant for the Gasification of Coal and Coal/Biomass Blends and Conversion of Derived Syngas to Liquid Fuels Via Fischer-Tropsch Synthesis Coal Fuels Alliance: Design and Construction of Early Lead Mini Fischer-Tropsch Refinery

471

Recent Publications | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Entries in the APS Publications Database for the week ending 01.05.2014 Entries in the APS Publications Database for the week ending 01.05.2014 This list of entries in the APS Publications Database includes Journal Articles (9,003), Conference Proceedings (7), Books (4), and Book Chapters (76), and Dissertations (0). This list of entries in the APS Publications Database does not include abstracts, invited talks, awards, magazine articles, or patents. For the complete list, search the APS Publications Database. Inquiries about or submissions to the publications database should be directed to apspubs@aps.anl.gov. Journal Article Z. Aabdin, N. Peranio, O. Eibl, Tö W. llner, K. Nielsch, D. Bessas, R.P. Hermann, M. Winkler, Kö J. nig, Bö H. ttner, V. Pacheco, J. Schmidt, A. Hashibon, Elsä C. sser, Nanostructure, Excitations, and Thermoelectric

472

Recent Publications | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Entries in the APS Publications Database for the week ending 12.29.2013 Entries in the APS Publications Database for the week ending 12.29.2013 This list of entries in the APS Publications Database includes Journal Articles (9,007), Conference Proceedings (7), Books (4), and Book Chapters (76), and Dissertations (0). This list of entries in the APS Publications Database does not include abstracts, invited talks, awards, magazine articles, or patents. For the complete list, search the APS Publications Database. Inquiries about or submissions to the publications database should be directed to apspubs@aps.anl.gov. Journal Article Z. Aabdin, N. Peranio, O. Eibl, Tö W. llner, K. Nielsch, D. Bessas, R.P. Hermann, M. Winkler, Kö J. nig, Bö H. ttner, V. Pacheco, J. Schmidt, A. Hashibon, Elsä C. sser, Nanostructure, Excitations, and Thermoelectric

473

Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing  

E-Print Network (OSTI)

Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

Mueller, Tim

474

Platinum-Alloy Cathode Catalyst Degradation in Proton Exchange Membrane Fuel Cells: Nanometer-Scale Compositional and Morphological Changes  

E-Print Network (OSTI)

Electrochemical measurements showed an ?75% Pt surface area loss and an ?40% specific activity loss for a membrane electrode assembly (MEA) cathode with acid-treated Pt[subscript 3]Co catalyst particles in a H[subscript ...

Chen, Shuo

475

Designing materials for energy storage with high power and energy density : LiFePO? cathode material  

E-Print Network (OSTI)

LiFePO? has drawn a lot of attention as a cathode material in lithium rechargeable batteries because its structural and thermal stability, its inexpensive cost, and environmental friendliness meet the requirements of power ...

Kang, Byoungwoo

2010-01-01T23:59:59.000Z

476

Advanced Burner Reactor Preliminary NEPA Data Study.  

Science Conference Proceedings (OSTI)

The Global Nuclear Energy Partnership (GNEP) is a new nuclear fuel cycle paradigm with the goals of expanding the use of nuclear power both domestically and internationally, addressing nuclear waste management concerns, and promoting nonproliferation. A key aspect of this program is fast reactor transmutation, in which transuranics recovered from light water reactor spent fuel are to be recycled to create fast reactor transmutation fuels. The benefits of these fuels are to be demonstrated in an Advanced Burner Reactor (ABR), which will provide a representative environment for recycle fuel testing, safety testing, and modern fast reactor design and safeguard features. Because the GNEP programs will require facilities which may have an impact upon the environment within the meaning of the National Environmental Policy Act of 1969 (NEPA), preparation of a Programmatic Environmental Impact Statement (PEIS) for GNEP is being undertaken by Tetra Tech, Inc. The PEIS will include a section on the ABR. In support of the PEIS, the Nuclear Engineering Division of Argonne National Laboratory has been asked to provide a description of the ABR alternative, including graphics, plus estimates of construction and operations data for an ABR plant. The compilation of this information is presented in the remainder of this report. Currently, DOE has started the process of engaging industry on the design of an Advanced Burner Reactor. Therefore, there is no specific, current, vendor-produced ABR design that could be used for this PEIS datacall package. In addition, candidate sites for the ABR vary widely as to available water, geography, etc. Therefore, ANL has based its estimates for construction and operations data largely on generalization of available information from existing plants and from the environmental report assembled for the Clinch River Breeder Reactor Plant (CRBRP) design [CRBRP, 1977]. The CRBRP environmental report was chosen as a resource because it thoroughly documents the extensive evaluation which was performed on the anticipated environmental impacts of that plant. This source can be referenced in the open literature and is publicly available. The CRBRP design was also of a commercial demonstration plant size - 975 MWth - which falls in the middle of the range of ABR plant sizes being considered (250 MWth to 2000 MWth). At the time the project was cancelled, the CRBRP had progressed to the point of having completed the licensing application to the Nuclear Regulatory Commission (NRC) and was in the process of receiving NRC approval. Therefore, it was felt that [CRBRP, 1977] provides some of the best available data and information as input to the GNEP PEIS work. CRBRP was not the source of all the information in this document. It is also expected that the CRBRP data will be bounding from the standpoint of commodity usage because fast reactor vendors will develop designs which will focus on commodity and footprint reduction to reduce the overall cost per kilowatt electric compared with the CRBR plant. Other sources used for this datacall information package are explained throughout this document and in Appendix A. In particular, see Table A.1 for a summary of the data sources used to generate the datacall information.

Briggs, L. L.; Cahalan, J. E.; Deitrich, L. W.; Fanning, T. H.; Grandy, C.; Kellogg, R.; Kim, T. K.; Yang, W. S.; Nuclear Engineering Division

2007-10-15T23:59:59.000Z

477

Sulfur-graphene oxide material for lithium-sulfur battery cathodes  

NLE Websites -- All DOE Office Websites (Extended Search)

Sulfur-graphene oxide material for lithium-sulfur battery cathodes Sulfur-graphene oxide material for lithium-sulfur battery cathodes Theoretical specific energy and theoretical energy density Scanning electron micrograph of the GO-S nanocomposite June 2013 Searching for a safer, less expensive alternative to today's lithium-ion batteries, scientists have turned to lithium-sulfur as a possible chemistry for next-generation batteries. Li/S batteries have several times the energy storage capacity of the best currently available rechargeable Li-ion battery, and sulfur is inexpensive and nontoxic. Current batteries using this chemistry, however, suffer from extremely short cycle life-they don't last through many charge-discharge cycles before they fail. A research team led by Elton Cairns and Yuegang Zhang has developed a new

478

Stable cycling of lithium sulfide cathodes through strong affinity with a bifunctional binder  

SciTech Connect

Rechargeable lithium-sulfur batteries have attracted great interest in recent years because of their high theoretical specific energy, which is several times that of current lithium-ion batteries. Compared to sulfur, fully-lithiated Li{sub 2}S represents a more attractive cathode material because it enables pairing with safer, lithium metal-free anodes. Here, we demonstrate stable and high-performance Li{sub 2}S cathodes by using ab initio simulations to guide our rational selection of poly(vinylpyrrolidone) binder which exhibits strong affinity with both Li{sub 2}S and lithium polysulfides. A high discharge capacity of 760 mA h g{sup -1} of Li{sub 2}S (~ 1090 mA h g{sup -1} of S) was achieved at 0.2 C with stable cycling over prolonged 500 charge/discharge cycles.

Seh, Zhi Wei; Zhang, Qianfan; Li, Weiyang; Zheng, Guangyuan; Yao, Hongbin; Cui, Yi

2013-01-01T23:59:59.000Z

479

The evolution of ion charge states in cathodic vacuum arc plasmas: a review  

Science Conference Proceedings (OSTI)

Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the noise in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

Anders, Andre

2011-12-18T23:59:59.000Z

480

Model of High Current Breakdown from Cathode Field Emission in Aged Wire Chambers  

SciTech Connect

Observing single electron pulses provides insight into the mechanism that leads to sudden high current jumps (breakdown) in aged wire chambers. This single electron activity is found to be consistent with the Fowler-Nordheim equation for field emission of electrons from a cathode surface in a high electric field. The high electric field arises from the positive ion buildup on a very thin insulating layer on the cathode surface. A model is presented to explain the transient behavior of single electron pulses in response to abrupt changes in chamber ionization, as well as the steady state rate during a long term aging run. The model is based on properties of the insulating layer (dielectric constant, conductivity, and hole-mobility) as well as the Fowler-Nordheim equation.

Boyarski, A

2004-02-25T23:59:59.000Z

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481

Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries  

Science Conference Proceedings (OSTI)

Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

2011-01-24T23:59:59.000Z

482

A SYSTEMATIC STUDY OF INTERCALATION COMPOUNDS AS CATHODE MATERIALS FOR LITHIUM BATTERIES.  

DOE Green Energy (OSTI)

Three types of intercalation Compounds, LiMn{sub 2}O{sub 4} with spinel structure, LiNiO{sub 2} and LiCoO{sub 2} with layered structure are widely studied as cathode materials for lithium-ion batteries. Among them, LiCoO{sub 2} is the most widely used cathode material in commercial lithium battery cells. LiNiO{sub 2} has same theoretical capacity as LiCoO{sub 2}, but is less expensive. However its application in lithium batteries has not been realized due to serious safety concerns. Substituting a portion of Ni in LiNiO{sub 2} with other cations has been pursued as a way to improve its safety characteristics. It was reported that Co doped LiNi{sub 0.8}Co{sub 0.2}O{sub 2} showed better thermal stability than pure LiNiO{sub 2}. Many new materials have been developed aimed in increasing the capacity and improving the thermal stability and cyclability. Most of these new materials are based on these three types of materials and modified their compositions and structures by doping. However, most of the efforts on developing new cathode materials have been done on the empirical base without guidelines from the systematic studies on the relationship between the performance and the structural changes of the cathode materials. Exploring this relationship is very important not only in guiding the development of new materials, but also in improving the performance and safety aspect for the existing cathode materials for lithium ion batteries. Using conventional x-ray source and a specially designed battery cell with beryllium windows, Dahn and co-workers have published several papers on the structural changes of LiNiO{sub 2} cathodes 1 and LiCoO{sub 2} cathodes 2 during charge. Unfortunately, the charging voltage was limited to below 4.3 V due to the problem of beryllium window corrosion at higher voltage. However, the voltage range between 4.3 V and 5.2 V is the most important region for studying the relationship between the thermal stability and structural changes during charge, because the thermal instability occurs at the overcharged state of the cathodes. Taking advantage of the strong x-ray beam from a synchrotron light source, we have constructed lithium battery cells for in situ XRD study with Mylar windows replacing the beryllium windows. Using the state of art synchrotron based in situ XRD technique, new phases and new phase transitions during charge have been observed in all of these three systems. These new phases and phase transitions have not been reported or correctly identified in the literature. The relationship between the performance (capacity, thermal stability and cyclability) and the structural changes during cycling has been thoroughly studied. The results of these studies will be summarized in this presentation.

YANG,X.Q.; MCBREEN,J.

2001-06-08T23:59:59.000Z

483

OPTIMIZATION OF THE CATHODE LONG-TERM STABILITY IN MOLTEN CARBONATE FUEL CELLS: EXPERIMENTAL STUDY AND MATHEMATICAL MODELING  

DOE Green Energy (OSTI)

The dissolution of NiO cathodes during cell operation is a limiting factor to the successful commercialization of molten carbonate fuel cells (MCFCs). Microencapsulation of the NiO cathode has been adopted as a surface modification technique to increase the stability of NiO cathodes in the carbonate melt. The material used for surface modification should possess thermodynamic stability in the molten carbonate and also should be electro catalytically active for MCFC reactions. A simple first principles model was developed to understand the influence of exchange current density and conductivity of the electrode material on the polarization of MCFC cathodes. The model predictions suggest that cobalt can be used to improve the corrosion resistance of NiO cathode without affecting its performance. Cobalt was deposited on NiO cathode by electroless deposition. The morphology and thermal oxidation behavior of Co coated NiO was studied using scanning electron microscopy and thermal gravimetric analysis respectively. The electrochemical performance of cobalt encapsulated NiO cathodes were investigated with open circuit potential measurement and current-potential polarization studies. These results were compared to that of bare NiO. The electrochemical oxidation behavior of cobalt-coated electrodes is similar to that of the bare NiO cathode. Dissolution of nickel into the molten carbonate melt was less in case of cobalt encapsulated nickel cathodes. Co coated on the surface prevents the dissolution of Ni in the melt and thereby stabilizes the cathode. Finally, cobalt coated nickel shows similar polarization characteristics as nickel oxide. A similar surface modification technique has been used to improve the performance of the SS 304 current collectors used in MCFC cells. SS 304 was encapsulated with nanostructured layers of NiCo and NiMo by electroless deposition. The corrosion behavior of bare and surface modified SS 304 in molten carbonate under cathode gas atmosphere was investigated with cyclic voltammetry, open circuit potential studies, Tafel polarization, impedance analysis and atomic absorption spectroscopy. This study confirms that the presence of surface modification leads to the formation of complex scales with better barrier properties and electronic conductivity.

Dr. Ralph E. White

2000-09-30T23:59:59.000Z

484

Time dependant quantum efficiency and dark current measurements in an RF photocathode injector with a high quantum efficiency cathode  

SciTech Connect

Studies of photo-emission and field emission behavior in an RF gun have been carried out. Unexpected phenomena were observed. In situ changes in the cathode's quantum efficiency and dark current with time were seen during operation of the photo-injector. These changes were correlated with the magnetostatic field at the cathode. In addition, multipacting has been observed under certain conditions. Recent measurements indicate a correlation between multipacting and anomalous photo- and field emission behavior.

Fliller, R.P., III; Edwards, H.; /Fermilab; Hartung, W.; /Michigan State U., NSCL

2005-05-01T23:59:59.000Z

485

Cathode Performance as a Function of Inactive Materials and Void Fractions  

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Cathode Performance as a Function of Inactive Materials and Void Fractions Cathode Performance as a Function of Inactive Materials and Void Fractions Title Cathode Performance as a Function of Inactive Materials and Void Fractions Publication Type Journal Article Year of Publication 2010 Authors Zheng, Honghe, Gao Liu, Xiangyun Song, Paul L. Ridgway, Shidi Xun, and Vincent S. Battaglia Journal Journal of Electrochemical Society Abstract Li[Ni1/3Co1/3Mn1/3]O2 -based laminates of approximately the same loading and of varying levels of poly(vinylidene fluoride) (PVDF) binder and acetylene black (ratio held constant) were fabricated and calendered to different porosities, with the objective to investigate performance on a volume basis. The electronic conductivity of the laminates depends strongly on the inactive material content but not significantly on porosity. Electrochemical impedance spectroscopy studies found that charge-transfer resistance with calendering varied greatly with inactive material content. When the electrode contains low levels of inactive material (2% PVDF and 1.6% carbon), calendering significantly reduced the bulk resistance of the electrode. With high levels of inactive material (8% PVDF and 6.4% carbon), charge-transfer resistance increased with increased calendering. Above a certain level, depending on the overall composition, the inactive material reduces ionic transport to the active material surface. For a plug-in hybrid electric vehicle required to go 40 miles at an average rate of 20 miles/h with a 38 kW 10 s power-pulse capability, the cell chemistry studied is energy-limited. Therefore, based on the results of this study, the cathode should be compressed to 10% porosity with a minimal amount of inactive material

486

Investigating the First-Cycle Irreversibility of Lithium Metal Oxide Cathodes for Li Batteries  

DOE Green Energy (OSTI)

Layered lithium metal oxide cathodes typically exhibit irreversibility during the first cycle in lithium cells when cycled in conventional voltage ranges (e.g., 3-4.3 V vs. Li+/Li). In this work, we have studied the first-cycle irreversibility of lithium cells containing various layered cathode materials using galvanostatic cycling and in situ synchrotron X-ray diffraction. When cycled between 3.0 and 4.3 V vs. Li+/Li, the cells containing LiCoO2, LiNi0.8Co0.15Al0.05O2, and Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 as cathodes showed initial coulombic efficiencies of 98.0, 87.0, and 88.6%, respectively, at relatively slow current (8 mA/g). However, the 'lost capacity' could be completely recovered by discharging the cells to low voltages (<2 V vs Li+/Li). During this deep discharge, the same cells exhibited voltage plateaus at 1.17, 1.81, and 1.47 V, respectively, which is believed to be associated with formation of a Li2MO2-like phase (M = Ni, Co, Mn) on the oxide particle surface due to very sluggish lithium diffusion in LieMO2 with {var_epsilon}{yields} 1 (i.e., near the end of discharge). The voltage relaxation curve and in situ X-ray diffraction patterns, obtained from a Li/Li1.048(Ni1/3Co1/3Mn1/3)0.952O2 cell, showed that the oxide cathode reversibly returned to its original state [i.e., Li1.048(Ni1/3Co1/3Mn1/3)0.952O2] during relaxation following the deep discharge to achieve 100% cycle efficiency.

Kang,S.; Yoon , W.; Nam, K.; Yang, X.; Abraham, D.

2008-01-01T23:59:59.000Z

487

High energy cathode material for long-life and safe lithium batteries.  

DOE Green Energy (OSTI)

Layered lithium nickel-rich oxides, Li[Ni{sub 1-x}M{sub x}]O{sub 2} (M=metal), have attracted significant interest as the cathode material for rechargeable lithium batteries owing to their high capacity, excellent rate capability and low cost. However, their low thermal-abuse tolerance and poor cycle life, especially at elevated temperature, prohibit their use in practical batteries. Here, we report on a concentration-gradient cathode material for rechargeable lithium batteries based on a layered lithium nickel cobalt manganese oxide. In this material, each particle has a central bulk that is rich in Ni and a Mn-rich outer layer with decreasing Ni concentration and increasing Mn and Co concentrations as the surface is approached. The former provides high capacity, whereas the latter improves the thermal stability. A half cell using our concentration-gradient cathode material achieved a high capacity of 209 mA h g{sup -1} and retained 96% of this capacity after 50 charge-discharge cycles under an aggressive test profile (55 C between 3.0 and 4.4 V). Our concentration-gradient material also showed superior performance in thermal-abuse tests compared with the bulk composition Li[Ni{sub 0.8}Co{sub 0.1}Mn{sub 0.1}]O{sub 2} used as reference. These results suggest that our cathode material could enable production of batteries that meet the demanding performance and safety requirements of plug-in hybrid electric vehicles.

Sun, Y.-K.; Myung, S.-T.; Park, B.-C.; Prakash, J.; Belharouak, I.; Amine, K.; Chemical Sciences and Engineering Division; Hanyang Univ.; Iwate Univ.; Illinois Inst. of Tech.

2009-04-01T23:59:59.000Z

488

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

DOE Green Energy (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechan