National Library of Energy BETA

Sample records for advanced anl cathode

  1. Advanced Cathode Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    nitrogen during synthesis ACNT-2 - nitrogen-incorporated ACNT X-ray Absorption Spectroscopy for Determining Atomic Structure (Example: ANL) iron-aligned carbon nanotube...

  2. Advanced Cathode Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation, which focuses on advanced cathode catalysts, was given by Piotr Zelenay of Los Alamos National laboratory at a February 2007 meeting on new fuel cell projects. PDF icon new_fc_zelenay_lanl.pdf More Documents & Publications Advanced Cathode Catalysts and Supports for PEM Fuel Cells CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europe Catalysis Working Group Kick-Off Meeting Agenda

  3. Advanced Cathode Material Development for PHEV Lithium Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Cathode Material Development for PHEV Lithium Ion Batteries High Energy Novel Cathode Alloy Automotive Cell Develop & evaluate materials & additives that enhance thermal ...

  4. Advanced Cathode Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 3_lanl.pdf More Documents & Publications Advanced Cathode Catalysts Science Magazine Highlight: Moving Towards Near Zero Platinum Fuel Cells 2011 Alkaline Membrane Fuel Cell Workshop Final Report

  5. Advanced Cathode Material Development for PHEV Lithium Ion Batteries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries Vehicle Technologies Office: 2009 Energy Storage R&D Annual Progress...

  6. Advanced Cathode Material Development for PHEV Lithium Ion Batteries |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es006_gardner_2011_p.pdf More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries High Energy Novel Cathode / Alloy Automotive Cell Develop & evaluate materials & additives that enhance thermal & overcharge abuse

  7. Advanced Cathode Catalysts and Supports for PEM Fuel Cells

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on advanced cathode catalysts and supports for PEM fuel cells, was given by Mark Debe of 3M at a February 2007 meeting on new fuel cell projects.

  8. Advanced Cathode Catalysts and Supports for PEM Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cathode Catalysts and Supports for PEM Fuel Cells Mark K. Debe 3M Company May 15, 2012 Project ID: FC 001 This presentation does not contain any proprietary, confidential, or otherwise restricted information 2012 Annual Merit Review DOE Hydrogen and Fuel Cells and Vehicle Technologies Programs 3M Advanced Cathode Catalysts ...... ..................... 2012 DOE Hydrogen Program Review, May 14-18 2 Overview Timeline  Project start : April 1, 2007  Project end : (98% complete)  Original -

  9. Advanced Cathode Material Development for PHEV Lithium Ion Batteries |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es006_gardner_2010_o.pdf More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries Vehicle Technologies Office: 2009 Energy Storage R&D Annual Progress Report Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell

  10. Advanced Cathode Catalysts and Supports for PEM Fuel Cells | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 3_3m.pdf More Documents & Publications Advanced Cathode Catalysts and Supports for PEM Fuel Cells Advanced Cathode Catalysts and Supports for PEM Fuel Cells

  11. Process Development and Scale-up of Advanced Cathode Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es167_krumdick_2012_o.pdf More Documents & Publications Process Development and Scale-up of Advanced Cathode Materials Vehicle Technologies Office Merit Review 2014: Process Development and Scale-up of Advanced Cathode Materials Process Development and Scale up of Advanced Electrolyte

  12. ANL Beams and Applications Seminar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 Seminar Sponsers AAI ASD ATLAS HEP PHY ANL Beams and Applications Seminar The ANL Beam and Applications Seminar is...

  13. Advanced Cathode Catalysts and Supports for PEM Fuel Cells | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon fc001_debe_2012_o.pdf More Documents & Publications Advanced Cathode Catalysts and Supports for PEM Fuel Cells DOE's Fuel Cell Catalyst R&D Activities Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells

  14. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  15. Unique Carbon-Coated Cathodes Improve Electrical Conductivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unique Carbon-Coated Cathodes Improve Electrical Conductivity (ANL-IN-09-043) Procedure Using Carbon Precursors Have Proved Superior to Conventional Methods Argonne National...

  16. Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Devaraj, Arun; Gu, Meng; Colby, Robert J.; Yan, Pengfei; Wang, Chong M.; Zheng, Jianming; Xiao, Jie; Genc, Arda; Zhang, Jiguang; Belharouak, Ilias; et al

    2015-08-14

    The distribution and concentration of lithium in Li-ion battery cathodes at different stages of cycling is a pivotal factor in determining battery performance. Non-uniform distribution of the transition metal cations has been shown to affect cathode performance; however, the Li is notoriously challenging to characterize with typical high-spatial-resolution imaging techniques. Here, for the first time, laser–assisted atom probe tomography is applied to two advanced Li-ion battery oxide cathode materials—layered Li1.2Ni0.2Mn0.6O2 and spinel LiNi0.5Mn1.5O4—to unambiguously map the three dimensional (3D) distribution of Li at sub-nanometer spatial resolution and correlate it with the distribution of the transition metal cations (M) and themore » oxygen. The as-fabricated layered Li1.2Ni0.2Mn0.6O2 is shown to have Li-rich Li2MO3 phase regions and Li-depleted Li(Ni0.5Mn0.5)O2 regions while in the cycled layered Li1.2Ni0.2Mn0.6O2 an overall loss of Li and presence of Ni rich regions, Mn rich regions and Li rich regions are shown in addition to providing the first direct evidence for Li loss on cycling of layered LNMO cathodes. The spinel LiNi0.5Mn1.5O4 cathode is shown to have a uniform distribution of all cations. These results were additionally validated by correlating with energy dispersive spectroscopy mapping of these nanoparticles in a scanning transmission electron microscope. Thus, we have opened the door for probing the nanoscale compositional fluctuations in crucial Li-ion battery cathode materials at an unprecedented spatial resolution of sub-nanometer scale in 3D which can provide critical information for understanding capacity decay mechanisms in these advanced cathode materials.« less

  17. Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes

    SciTech Connect (OSTI)

    Devaraj, Arun; Gu, Meng; Colby, Robert J.; Yan, Pengfei; Wang, Chong M.; Zheng, Jianming; Xiao, Jie; Genc, Arda; Zhang, Jiguang; Belharouak, Ilias; Wang, Dapeng; Amine, Khalil; Thevuthasan, Suntharampillai

    2015-08-14

    The distribution and concentration of lithium in Li-ion battery cathodes at different stages of cycling is a pivotal factor in determining battery performance. Non-uniform distribution of the transition metal cations has been shown to affect cathode performance; however, the Li is notoriously challenging to characterize with typical high-spatial-resolution imaging techniques. Here, for the first time, laserassisted atom probe tomography is applied to two advanced Li-ion battery oxide cathode materialslayered Li1.2Ni0.2Mn0.6O2 and spinel LiNi0.5Mn1.5O4to unambiguously map the three dimensional (3D) distribution of Li at sub-nanometer spatial resolution and correlate it with the distribution of the transition metal cations (M) and the oxygen. The as-fabricated layered Li1.2Ni0.2Mn0.6O2 is shown to have Li-rich Li2MO3 phase regions and Li-depleted Li(Ni0.5Mn0.5)O2 regions while in the cycled layered Li1.2Ni0.2Mn0.6O2 an overall loss of Li and presence of Ni rich regions, Mn rich regions and Li rich regions are shown in addition to providing the first direct evidence for Li loss on cycling of layered LNMO cathodes. The spinel LiNi0.5Mn1.5O4 cathode is shown to have a uniform distribution of all cations. These results were additionally validated by correlating with energy dispersive spectroscopy mapping of these nanoparticles in a scanning transmission electron microscope. Thus, we have opened the door for probing the nanoscale compositional fluctuations in crucial Li-ion battery cathode materials at an unprecedented spatial resolution of sub-nanometer scale in 3D which can provide critical information for understanding capacity decay mechanisms in these advanced cathode materials.

  18. Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells

    SciTech Connect (OSTI)

    R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

    2001-11-05

    During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

  19. ANL-FF-262i

    Office of Legacy Management (LM)

    , v-W&, ANL-FF-262i This document consists of 1 page, No.>f 7 copies. SeriesA. -,-- 22 February 1952 TO; B. Blumenthal Metallurgy From: H, Luetzow Metallurgy Re: HIGH PURITY CRANIUM TO BE ROLLID TO FOIL M r, E. Creutz of the Carnegie Institute of Technology has requested ten square inches of uranium foil 0.1 mil to 1 nil thick., The possibility of pro- ducing foil of this thickness from our foundry's graphite-melted uranium is remote because of the metalIs high carbon content. High purity

  20. Commercial Grade Dedication Record (ANL-746 Revised) | Department...

    Energy Savers [EERE]

    Record (ANL-746 Revised) Commercial Grade Dedication Record (ANL-746 Revised) A sample of a process to recorddocument CGD activities. Forms are included. Commercial Grade...

  1. Advanced Lithium Battery Cathodes Using Dispersed Carbon Fibers as the Current Collector

    SciTech Connect (OSTI)

    Martha, Surendra K; Kiggans, Jim; Nanda, Jagjit; Dudney, Nancy J

    2011-01-01

    To fabricate LiFePO4 battery cathodes, highly conductive carbon fibers of 10-20 m in diameter have been used to replace a conventional aluminum (Al) foil current collector. This disperses the current collector throughout the cathode sheet and increases the contact area with the LiFePO4 (LFP) particles. In addition, the usual organic binder plus carbon-black can be replaced by a high temperature binder of <5 weight % carbonized petroleum pitch (P-pitch). Together these replacements increase the specific energy density and energy per unit area of the electrode. Details of the coating procedure, characterization and approach for maximizing the energy density are discussed. In a side-by-side comparison with conventional cathodes sheets of LFP on Al foil, the carbon fiber composite cathodes have a longer cycle life, higher thermal stability, and high capacity utilization with little sacrifice of the rate performance.

  2. ANL/EAD/TM-9 Derivation

    Office of Legacy Management (LM)

    ANL/EAD/TM-9 Derivation of Uranium Residual Radioactive Material Guidelines for the Former Alba Craft Laboratory Site, Oxford, Ohio _ _ ,_ _., by M. Nimmagadda, E. Faillace, and C. Yu Environmental Assessment Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439 January 1994 Work sponsored by United States Department of Energy MASTER CONTENTS NOTATION ......................................................... v SUMMARY

  3. High Energy Physics Division, ANL Lattice QCD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Physics Division, ANL Lattice QCD in extreme environments D. K. Sinclair (HEP, Argonne) J. B. Kogut (Physics, Illinois) D. Toublan (Physics, Illinois) 1 Lattice QCD Quantum chromodynamics(QCD) de- scribes Hadrons and their strong inter- actions. Hadrons consist of quarks held together by gluons. Lattice QCD is QCD on a 4-dimensional (space-time) lattice. Allows numerical simulation of the functional integrals which define this quantum field theory, and non-perturbative QCD calculations.

  4. presentation_anl-SHORT-aug09

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    magnetic moments of ps states of nuclei far from stability Argonne Workshop: Aug. 8-9,2009 Noémie Benczer-Koller Rutgers University I will not talk about everything, namely: Intermediate Coulomb excitation experiments at MSU with the TF technique Recoil in vacuum (RIV) at ORNL, ANL β-NMR, etc... These require more instrumentation than the experiments I would like to start with, as well as complex calibrations although they are a good option for future experiments.

  5. A User Guide to PARET/ANL

    SciTech Connect (OSTI)

    Olson, A. P.; Dionne, B.; Marin-Lafleche, A.; Kalimullah, M.

    2015-01-01

    PARET was originally created in 1969 at what is now Idaho National Laboratory (INL), to analyze reactivity insertion events in research and test reactor cores cooled by light or heavy water, with fuel composed of either plates or pins. The use of PARET is also appropriate for fuel assemblies with curved fuel plates when their radii of curvatures are large with respect to the fuel plate thickness. The PARET/ANL version of the code has been developed at Argonne National Laboratory (ANL) under the sponsorship of the U.S. Department of Energy/NNSA, and has been used by the Reactor Conversion Program to determine the expected transient behavior of a large number of reactors. PARET/ANL models the various fueled regions of a reactor core as channels. Each of these channels consists of a single flat fuel plate/pin (including cladding and, optionally, a gap) with water coolant on each side. In slab geometry the coolant channels for a given fuel plate are of identical dimensions (mirror symmetry), but they can be of different thickness in each channel. There can be many channels, but each channel is independent and coupled only through reactivity feedback effects to the whole core. The time-dependent differential equations that represent the system are replaced by an equivalent set of finite-difference equations in space and time, which are integrated numerically. PARET/ANL uses fundamentally the same numerical scheme as RELAP5 for the time-integration of the point-kinetics equations. The one-dimensional thermal-hydraulic model includes temperature-dependent thermal properties of the solid materials, such as heat capacity and thermal conductivity, as well as the transient heat production and heat transfer from the fuel meat to the coolant. Temperature- and pressure-dependent thermal properties of the coolant such as enthalpy, density, thermal conductivity, and viscosity are also used in determining parameters such as friction factors and heat transfer coefficients. The code first determines the steady-state solution for the initial state. Then the solution of the transient is obtained by integration in time and space. Multiple heat transfer, DNB and flow instability correlations are available. The code was originally developed to model reactors cooled by an open loop, which was adequate for rapid transients in pool-type cores. An external loop model appropriate for Miniature Neutron Source Reactors (MNSRs) was also added to PARET/ANL to model natural circulation within the vessel, heat transfer from the vessel to pool and heat loss by evaporation from the pool. PARET/ANL also contains models for decay heat after shutdown, control rod reactivity versus time or position, time-dependent pump flow, and loss-of-flow event with flow reversal as well as logic for trips on period, power, and flow. Feedback reactivity effects from coolant density changes and temperature changes are represented by tables. Feedback reactivity from fuel heat-up (Doppler Effect) is represented by a four-term polynomial in powers of fuel temperature. Photo-neutrons produced in beryllium or in heavy water may be included in the point-kinetics equations by using additional delayed neutron groups.

  6. ANL analysis of ZPPR-13A

    SciTech Connect (OSTI)

    Collins, P.J.; Brumbach, S.B.

    1984-08-09

    The ZPPR-13 experiments provide basic physics data for radial heterogeneous LMFBR cores of approximately 700MWe size. Assemblies ZPPR-13A, ZPPR-13B and ZPPR-13C comprised the JUPITER-II cooperative program between the U.S. Department of Energy (US DOE) and PNC of Japan. The measurements were made between August 1982 and April 1984. The core designs and the measurements were planned jointly by the two parties with substantial input from U.S. industrial interests to ensure coverage of the design requirements. This report describes in detail the results of the Argonne National Laboratory (ANL) analyses of phase 13A.

  7. Development of Advanced Diesel Particulate Filtration (DPF) Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (ANL/Corning/Caterpillar CRADA) | Department of Energy (ANL/Corning/Caterpillar CRADA) Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) PDF icon ace_22_lee.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems

  8. The ANL electric vehicle battery R D program for DOE-EHP

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

  9. Miniaturized cathodic arc plasma source

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA)

    2003-04-15

    A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  10. ANL: Prototype Cell Fabrication Facility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ANL: Prototype Cell Fabrication Facility ANL: Prototype Cell Fabrication Facility 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt075_es_jansen_2011_p.pdf More Documents & Publications FY 2011 Annual Progress Report for Energy Storage R&D FY 2012 Annual Progress Report for Energy Storage R&D CX-001384: Categorical Exclusion Determination

  11. ANL Software Improves Wind Power Forecasting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ANL Software Improves Wind Power Forecasting ANL Software Improves Wind Power Forecasting May 1, 2012 - 3:19pm Addthis This is an excerpt from the Second Quarter 2012 edition of the Wind Program R&D Newsletter. Since 2008, Argonne National Laboratory and INESC TEC (formerly INESC Porto) have conducted a research project to improve wind power forecasting and better use of forecasting in electricity markets. One of the main results from the project is ARGUS PRIMA (PRediction Intelligent

  12. Recent advances on the understanding of structural and composition evolution of LMR cathodes for Li-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Pengfei; Zheng, Jianming; Xiao, Jie; Wang, Chong-Min; Zhang, Jiguang

    2015-06-08

    Lithium-rich, magnesium-rich (LMR) cathode materials have been regarded as one of the very promising cathodes for Li-ion battery applications. However, their practical application is still limited by several challenges, especially by their limited electrochemical stability rate capability. In this work, we present recent progresses on the understanding of the structural and composition evolution of LMR cathode materials with emphasis being placed on the correlation between structural/chemical evolution and electrochemical properties. In particular, using Li [Li0.2Ni0.2Mn0.6O2 as a typical example, we clearly illustrate the structural characteristics of the pristine materials and their dependence on the materials processing history, cycling induced structuralmore » degradation/chemical partition and their correlation with degradation of electrochemical performance. The fundamental understanding obtained in this work may also guide the design and preparation of new cathode materials based on ternary system of transitional metal oxide.« less

  13. Recent advances on the understanding of structural and composition evolution of LMR cathodes for Li-ion batteries

    SciTech Connect (OSTI)

    Yan, Pengfei; Zheng, Jianming; Xiao, Jie; Wang, Chong-Min; Zhang, Jiguang

    2015-06-08

    Lithium-rich, magnesium-rich (LMR) cathode materials have been regarded as one of the very promising cathodes for Li-ion battery applications. However, their practical application is still limited by several challenges, especially by their limited electrochemical stability rate capability. In this work, we present recent progresses on the understanding of the structural and composition evolution of LMR cathode materials with emphasis being placed on the correlation between structural/chemical evolution and electrochemical properties. In particular, using Li [Li0.2Ni0.2Mn0.6O2 as a typical example, we clearly illustrate the structural characteristics of the pristine materials and their dependence on the materials processing history, cycling induced structural degradation/chemical partition and their correlation with degradation of electrochemical performance. The fundamental understanding obtained in this work may also guide the design and preparation of new cathode materials based on ternary system of transitional metal oxide.

  14. Evaluating the need for a criticality alarm system at ANL-E

    SciTech Connect (OSTI)

    Washburn, P.; Cohen, A.

    1997-08-01

    Under the current climate of increasing regulation and decreasing budgets, DOE nuclear facilities are forced to become more efficient in operations aimed at satisfying regulatory requirements. Efficiency necessitates increased cooperation between the regulator (DOE) and facility management, and often a mutually agreeable innovative solution. At Argonne National Laboratory - East (ANL-E), one issue that required such an innovative solution and cooperation between contractor and regulator was the determination of whether the risk associated with an inadvertent criticality event justified the purchase and maintenance of a Criticality Alarm System (CAS) meeting ANSI/ANS-8.3-1986 requirements. According to DOE Order 420.1, the need for a CAS is based on the probability of occurrence of a criticality accident. If the probability is <10{sup {minus}6}/yr (i.e., incredible) as determined by {open_quotes}commonly accepted engineering judgement,{close_quotes} then a CAS is not necessary. Installation of a CAS after such a conclusion would be a conservative decision and an unnecessary expense. This paper discusses the use of {open_quotes}commonly accepted engineering judgement{close_quotes} to show that the probability of an inadvertent criticality at a nonreactor nuclear facility (e.g., the Alpha-Gamma Hot Cell Facility) is <10{sup {minus}6}/yr. and is therefore an incredible event.

  15. Cathodes - Technological review

    SciTech Connect (OSTI)

    Cherkouk, Charaf; Nestler, Tina

    2014-06-16

    Lithium cobalt oxide (LiCoO{sub 2}) was already used in the first commercialized Li-ion battery by SONY in 1990. Still, it is the most frequently used cathode material nowadays. However, LiCoO{sub 2} is intrinsically unstable in the charged state, especially at elevated temperatures and in the overcharged state causing volume changes and transport limitation for high power batteries. In this paper, some technological aspects with large impact on cell performance from the cathode material point of view will be reviewed. At first it will be focused on the degradation processes and life-time mechanisms of the cathode material LiCoO{sub 2}. Electrochemical and structural results on commercial Li-ion batteries recorded during the cycling will be discussed. Thereafter, advanced nanomaterials for new cathode materials will be presented.

  16. Advancing Internal Combustion Engine Simulations using Sensitivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advancing Internal Combustion Engine Simulations using Sensitivity Analysis PI Name: Sibendu Som PI Email: ssom@anl.gov Institution: Argonne National Laboratory Allocation Program:...

  17. Arc discharge regulation of a megawatt hot cathode bucket ion source for the experimental advanced superconducting tokamak neutral beam injector

    SciTech Connect (OSTI)

    Xie Yahong; Hu Chundong; Liu Sheng; Jiang Caichao; Li Jun; Liang Lizhen; Collaboration: NBI Team

    2012-01-15

    Arc discharge of a hot cathode bucket ion source tends to be unstable what attributes to the filament self-heating and energetic electrons backstreaming from the accelerator. A regulation method, which based on the ion density measurement by a Langmuir probe, is employed for stable arc discharge operation and long pulse ion beam generation. Long pulse arc discharge of 100 s is obtained based on this regulation method of arc power. It establishes a foundation for the long pulse arc discharge of a megawatt ion source, which will be utilized a high power neutral beam injection device.

  18. The ANL electric vehicle battery R&D program for DOE-EHP. Quarterly progress report, October--December 1990

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EBP). The goal of DOE-EHP is to advance promising EV propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce petroleum consumption in the transportation sector of the US economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, database management, and technical management of industrial R&D contracts on advanced battery and fuel cell technologies for DOE-EBP. This report summarizes the objectives, background, technical progress, and status of ANL electric vehicle battery R&D tasks for DOE-EHP during the period of October 1, 1990 through December 31, 1990. The work is organized into the following six task areas: 1.0 Project Management; 3.0 Battery Systems Technology; 4.0 Lithium/Sulfide Batteries; 5.0 Advanced Sodium/Metal Chloride Battery; 6.0 Aqueous Batteries; 7.0 EV Battery Performance/Life Evaluation.

  19. Studies on Oxide Cathode Crystals | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxide Cathode Crystals Studies on Oxide Cathode Crystals 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es069_chen_2011_o.pdf More Documents & Publications Performance and Safety of Olivines and Layered Oxides Vehicle Technologies Office Merit Review 2014: Design and Synthesis of Advanced High-Energy Cathode Materials Vehicle Technologies Office Merit Review 2015: Design and Synthesis of Advanced High-Energy Cathode

  20. Cathodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cathodes Cathodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es049_thackeray_2010_p.pdf More Documents & Publications Design and Evaluation of Novel High Capacity Cathode Materials Layered Cathode Materials Design and Evaluation of Novel High Capacity Cathode Materials

  1. ANL Study Shows Wind Power Decreases Power Sector Emissions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy ANL Study Shows Wind Power Decreases Power Sector Emissions ANL Study Shows Wind Power Decreases Power Sector Emissions May 1, 2012 - 3:38pm Addthis This is an excerpt from the Second Quarter 2012 edition of the Wind Program R&D Newsletter. A study recently published by the Energy Department's Argonne National Laboratory (ANL) examined the effects of introducing wind energy into the electric power system. After conducting a detailed emissions analysis based on a comprehensive

  2. Atom Trap Trace Analysis at ANL | U.S. DOE Office of Science...

    Office of Science (SC) Website

    Atom Trap Trace Analysis at ANL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science Applications of Nuclear ...

  3. High Energy Novel Cathode / Alloy Automotive Cell | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Energy Novel Cathode / Alloy Automotive Cell High Energy Novel Cathode / Alloy Automotive Cell 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es131_choi_2012_p.pdf More Documents & Publications High Energy Novel Cathode / Alloy Automotive Cell Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell Vehicle Technologies Office Merit Review 2014: Advanced High

  4. A User's Guide to the PLTEMP/ANL Code

    SciTech Connect (OSTI)

    Olson, Arne P.; Kalimullah, M.

    2015-07-07

    PLTEMP/ANL V4.2 is a FORTRAN program that obtains a steady-state flow and temperature solution for a nuclear reactor core, or for a single fuel assembly. It is based on an evolutionary sequence of ''PLTEMP'' codes in use at ANL for the past 20 years. Fueled and non-fueled regions are modeled. Each fuel assembly consists of one or more plates or tubes separated by coolant channels. The fuel plates may have one to five layers of different materials, each with heat generation. The width of a fuel plate may be divided into multiple longitudinal stripes, each with its own axial power shape. The temperature solution is effectively 2-dimensional. It begins with a one-dimensional solution across all coolant channels and fuel plates/tubes within a given fuel assembly, at the entrance to the assembly. The temperature solution is repeated for each axial node along the length of the fuel assembly. The geometry may be either slab or radial, corresponding to fuel assemblies made of a series of flat (or slightly curved) plates, or of nested tubes. A variety of thermal-hydraulic correlations are available with which to determine safety margins such as Onset-of- Nucleate boiling (ONB), departure from nucleate boiling (DNB), and onset of flow instability (FI). Coolant properties for either light or heavy water are obtained from FORTRAN functions rather than from tables. The code is intended for thermal-hydraulic analysis of research reactor performance in the sub-cooled boiling regime. Both turbulent and laminar flow regimes can be modeled. Options to calculate both forced flow and natural circulation are available. A general search capability is available (Appendix XII) to greatly reduce the reactor analyst’s time.

  5. A user's guide to the PLTEMP/ANL code.

    SciTech Connect (OSTI)

    Kalimullah, M.

    2011-07-05

    PLTEMP/ANL V4.1 is a FORTRAN program that obtains a steady-state flow and temperature solution for a nuclear reactor core, or for a single fuel assembly. It is based on an evolutionary sequence of ''PLTEMP'' codes in use at ANL for the past 20 years. Fueled and non-fueled regions are modeled. Each fuel assembly consists of one or more plates or tubes separated by coolant channels. The fuel plates may have one to five layers of different materials, each with heat generation. The width of a fuel plate may be divided into multiple longitudinal stripes, each with its own axial power shape. The temperature solution is effectively 2-dimensional. It begins with a one-dimensional solution across all coolant channels and fuel plates/tubes within a given fuel assembly, at the entrance to the assembly. The temperature solution is repeated for each axial node along the length of the fuel assembly. The geometry may be either slab or radial, corresponding to fuel assemblies made of a series of flat (or slightly curved) plates, or of nested tubes. A variety of thermal-hydraulic correlations are available with which to determine safety margins such as Onset-of-Nucleate boiling (ONB), departure from nucleate boiling (DNB), and onset of flow instability (FI). Coolant properties for either light or heavy water are obtained from FORTRAN functions rather than from tables. The code is intended for thermal-hydraulic analysis of research reactor performance in the sub-cooled boiling regime. Both turbulent and laminar flow regimes can be modeled. Options to calculate both forced flow and natural circulation are available. A general search capability is available (Appendix XII) to greatly reduce the reactor analyst's time.

  6. Using the Apple LaserWriter at ANL

    SciTech Connect (OSTI)

    Errion, S.M.; Thommes, M.M. Caruthers, C.M.

    1987-09-01

    Using the Apple LaserWriter at ANL (ANL/TM 452) explains how Argonne computer users (with CMS, MVS, or VAX/VMS accounts) can print quality text and graphics on the Apple LaserWriter. Currently, applications at Argonne that are compatible with the Apple LaserWriter include Waterloo Script, CA/ISSCO graphics software (i.e., Cuechart, Tellagraf, and Disspla), SAS/Graph, ANSYS (version 4.2), and some personal computer test and graphics software. This manual does not attempt to cover use of the Apple LaserWriter with other applications, though some information on the handling of PostScript-compatible files may be valid for other applications. Refer to the documentation of those applications to learn how they work with the Apple LaserWriter. Most of the information in this manual applies to the Allied Linotype L300P typesetter in Building 222. However, the typesetter is not a high volume output device and should be used primarily for high quality (1250 and 2500 dots per inch) final copy output for Laboratory publications prior to making printing plates. You should print all drafts and proof pages on LaserWriers or other printers compatible with the PostScript page description language. Consult with Graphic Arts (at extension 2-5603) to determine the availability of the typesetter for printing the final copy of your document or graphics application. Since the Apple LaserWriter itself produces good quality output (300 dots per inch), we expect that most internal documents consisting of test or graphics will continue to be printed at LaserWriters distributed throughout the Laboratory. 5 figs., 2 tabs.

  7. Dual Functional Cathode Additives for Battery Technologies - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Dual Functional Cathode Additives for Battery Technologies Brookhaven National Laboratory Contact BNL About This Technology <br type="_moz" /> Schematic demonstrating the cell reactions of an anode less lithium-sulfur cell with a dual functional cathode additive (here a metal sulfide cathode additive). Schematic demonstrating the cell reactions of an anode less lithium-sulfur cell

  8. ANL-14/01 Surveillance of Site A and Plot M

    Office of Legacy Management (LM)

    ANL-14/01 Surveillance of Site A and Plot M Report for 2013 Environment, Safety, and Quality Assurance Argonne National Laboratory is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC ENERGY U.S. DEPARTMENT OF Environment, Safety, and Quality Assurance Division Argonne National Laboratory 9700 South Cass Avenue, Bldg. 201 Argonne, IL 60439-4832 www.anl.gov ANL-14/01 Surveillance of Site A and Plot M Report for 2013 by Lawrence P. Moos Environment, Safety, and Quality

  9. Material and Energy Flows in the Production of Cathode and Anode Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Authors: Dunn, Jennifer B. ; James, Christine ; Gaines, L G ; Gallagher, Kevin Publication Date: 2014-09-30 OSTI Identifier: 1172039 Report Number(s): ANL/ESD-14/10 108520 DOE Contract

  10. Sintered wire cathode

    DOE Patents [OSTI]

    Falce, Louis R. (San Jose, CA); Ives, R. Lawrence (Saratoga, CA)

    2009-06-09

    A porous cathode structure is fabricated from a plurality of wires which are placed in proximity to each other in elevated temperature and pressure for a sintering time. The sintering process produces the porous cathode structure which may be divided into a plurality of individual porous cathodes, one of which may be placed into a dispenser cathode support which includes a cavity for containing a work function reduction material such as BaO, CaO, and Al.sub.2O.sub.3. The work function reduction material migrates through the pores of the porous cathode from a work replenishment surface adjacent to the cavity of the dispenser cathode support to an emitting cathode surface, thereby providing a dispenser cathode which has a uniform work function and therefore a uniform electron emission.

  11. Cathode Coating (IN-09-061) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cathode Coating (IN-09-061) Cathode Coating Enables Faster Battery Charging, Discharging Argonne National Laboratory Contact ANL About This Technology <p> <em>Charge and discharge capacity of pristine, 250&deg;C dry air and 250&deg;C He/5%H<sub>2</sub> heated Li<sub>1.12</sub>Mn<sub>0.55</sub>Ni<sub>0.145</sub>Co<sub>0.1O2</sub>, showing better performance for the material heated with reducing

  12. Cathode R&D for Future Light Sources

    SciTech Connect (OSTI)

    Dowell, D.H.; Bazarov, I.; Dunham, B.; Harkay, K.; Hernandez-Garcia; Legg, R.; Padmore, H.; Rao, T.; Smedley, J.; Wan, W.

    2010-05-26

    This paper reviews the requirements and current status of cathodes for accelerator applications, and proposes a research and development plan for advancing cathode technology. Accelerator cathodes need to have long operational lifetimes and produce electron beams with a very low emittance. The two principal emission processes to be considered are thermionic and photoemission with the photocathodes being further subdivided into metal and semi-conductors. Field emission cathodes are not included in this analysis. The thermal emittance is derived and the formulas used to compare the various cathode materials. To date, there is no cathode which provides all the requirements needed for the proposed future light sources. Therefore a three part research plan is described to develop cathodes for these future light source applications.

  13. Hybrid Radiator-Cooling System (ANL-IN-11-096) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Hybrid Radiator-Cooling System (ANL-IN-11-096) Argonne National Laboratory Contact ANL About This Technology Technology Marketing Summary Coolant radiators in highway trucks are designed to transfer maximum heat at a "design condition." The current standard design condition is a fully-loaded truck climbing up Baker Grade on the hottest summer day. The coolant system, including radiator, is sized to remove 100% of the required heat from the engine

  14. Planar-focusing cathodes.

    SciTech Connect (OSTI)

    Lewellen, J. W.; Noonan, J.; Accelerator Systems Division

    2005-01-01

    Conventional {pi}-mode rf photoinjectors typically use magnetic solenoids for emittance compensation. This provides independent focusing strength but can complicate rf power feed placement, introduce asymmetries (due to coil crossovers), and greatly increase the cost of the photoinjector. Cathode-region focusing can also provide for a form of emittance compensation. Typically this method strongly couples focusing strength to the field gradient on the cathode, however, and usually requires altering the longitudinal position of the cathode to change the focusing. We propose a new method for achieving cathode-region variable-strength focusing for emittance compensation. The new method reduces the coupling to the gradient on the cathode and does not require a change in the longitudinal position of the cathode. Expected performance for an S-band system is similar to conventional solenoid-based designs. This paper presents the results of rf cavity and beam dynamics simulations of the new design. We have proposed a method for performing emittance compensation using a cathode-region focusing scheme. This technique allows the focusing strength to be adjusted somewhat independently of the on-axis field strength. Beam dynamics calculations indicate performance should be comparable to presently in-use emittance compensation schemes, with a simpler configuration and fewer possibilities for emittance degradation due to the focusing optics. There are several potential difficulties with this approach, including cathode material selection, cathode heating, and peak fields in the gun. We hope to begin experimenting with a cathode of this type in the near future, and several possibilities exist for reducing the peak gradients to more acceptable levels.

  15. Permanent Closure of MFC Biodiesel Underground Storage Tank 99ANL00013

    SciTech Connect (OSTI)

    Kerry L. Nisson

    2012-10-01

    This closure package documents the site assessment and permanent closure of the Materials and Fuels Complex biodiesel underground storage tank 99ANL00013 in accordance with the regulatory requirements established in 40 CFR 280.71, Technical Standards and Corrective Action Requirements for Owners and Operators of Underground Storage Tanks: Out-of-Service UST Systems and Closure.

  16. Field Emission Cathode Gating for RF Electron Guns (IN-04-039) - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Industrial Technologies Industrial Technologies Find More Like This Return to Search Field Emission Cathode Gating for RF Electron Guns (IN-04-039) Argonne National Laboratory Contact ANL About This Technology <p> Field emission (FE) gun&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;</p> Field emission (FE) gun <p> <span style="line-height: 115%; font-family:

  17. Cathode materials review

    SciTech Connect (OSTI)

    Daniel, Claus Mohanty, Debasish Li, Jianlin Wood, David L.

    2014-06-16

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403-431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead-acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide-hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J. Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783-789) demonstrated a high-energy and high-power LiCoO{sub 2} cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  18. JUPITER-II Program: ANL analysis of ZPPR-13A and ZPPR-13B

    SciTech Connect (OSTI)

    Collins, P.J.; Brumbach, S.B.

    1984-08-09

    The ZPPR-13 experiments provide basic physics data for radial-heterogeneous LMFBR cores of approximately 700 MWe size. Assemblies ZPPR-13A, ZPPR-13B and ZPPR-13C comprised the JUPITER-II cooperative program between US-DOE and PNC of Japan. The measurements were made between August 1982 and April 1984. This report describes in detail the results of the ANL analyses of phases 13A and 13B/1 and includes preliminary results for the later assemblies of phase 13B. The data were compiled primarily for discussions at the Third Jupiter Analysis Meeting to be held at ANL-West between September 11th and 14th, 1984.

  19. Atom Trap Trace Analysis at ANL | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Atom Trap Trace Analysis at ANL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science Applications of Nuclear Science Archives Small Business Innovation / Technology Transfer Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E:

  20. ANL/ALCF/ESP-13/17 ALCF-2 Early Science Program Technical Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ANL/ALCF/ESP-13/17 ALCF-2 Early Science Program Technical Reports Compendium of Individual Technical Reports for the 16 ESP Projects Argonne Leadership Computing Facility About Argonne National Laboratory Argonne is a U.S. Department of Energy laboratory managed by UChicago Argonne, LLC under contract DE-AC02-06CH11357. The Laboratory's main facility is outside Chicago, at 9700 South Cass Avenue, Argonne, Illinois 60439. For information about Argonne and its pioneering science and technology

  1. ANL-08/04 Surveillance of Site A and Plot M

    Office of Legacy Management (LM)

    ANL-08/04 Surveillance of Site A and Plot M Report for 2007 Environment, Safety, and Health/Quality Assurance Oversight Division Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor UChicago Argonne, LLC, nor any of their employees or offcers, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or

  2. DOEIEV.0005/35 ANL-OHS/HP-83403 FORMERLY UTILIZED MEDIAEC SITES

    Office of Legacy Management (LM)

    p, .' jl&Lj p ' -7 c. .3- 4; .z 1. . . ' 1 DOEIEV.0005/35 ANL-OHS/HP-83403 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF CHEMICALS GROUP, OLIN CORPORATION (Formerly Blockson Chemical Company) JOLIET, ILLINOIS March 27,November 28, 1978 OCCUPATIONAL HEALTH AND SAFETY DIVISION Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY OF CHICAGO for the U. S. DEPARTMENT OF ENERGY under Contract W-31-10%Eng-38 ..__^ --

  3. Microsoft PowerPoint - ANL Process Monitoring NEET Webinar.pptx

    Office of Environmental Management (EM)

    Electrochemical Processing of Used Fuel J. L. Willit (willit@anl.gov) Argonne National Laboratory Introduction Principles followed in establishing the used LWR & FR fuel treatment processes - Industrially practicable and economic - Safeguardable system that meets U.S. non-proliferation objectives - Maximize actinide recovery to maximize resource utilization and enhance repository performance - Encapsulate fission product waste in engineered waste forms that can be disposed in an

  4. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace024_lee_2011_o.pdf More Documents & Publications Development of Advanced Particulate Filters Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA)

  5. Filtered cathodic arc source

    DOE Patents [OSTI]

    Falabella, Steven (Livermore, CA); Sanders, David M. (Livermore, CA)

    1994-01-01

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45.degree. to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles.

  6. Filtered cathodic arc source

    DOE Patents [OSTI]

    Falabella, S.; Sanders, D.M.

    1994-01-18

    A continuous, cathodic arc ion source coupled to a macro-particle filter capable of separation or elimination of macro-particles from the ion flux produced by cathodic arc discharge is described. The ion source employs an axial magnetic field on a cathode (target) having tapered sides to confine the arc, thereby providing high target material utilization. A bent magnetic field is used to guide the metal ions from the target to the part to be coated. The macro-particle filter consists of two straight solenoids, end to end, but placed at 45[degree] to one another, which prevents line-of-sight from the arc spot on the target to the parts to be coated, yet provides a path for ions and electrons to flow, and includes a series of baffles for trapping the macro-particles. 3 figures.

  7. Vehicle Technologies Office Merit Review 2015: ANL IC3P Research Focus on Diagnostic Studies at BNL

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about ANL IC3P research focus on diagnostic...

  8. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2015-01-13

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  9. Cathode material for lithium batteries

    DOE Patents [OSTI]

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  10. Engineering-Scale Liquid Cadmium Cathode Experiments

    SciTech Connect (OSTI)

    D Vaden; B. R. Westphal; S. X. Li; T. A. Johnson; K. B. Davies; D. M. Pace

    2006-08-01

    Recovery of transuranic actinides (TRU) using electrorefining is a process being investigated as part of the Department of Energy (DOE) Advanced Fuel Cycle Initiative (AFCI). TRU recovery via electrorefining onto a solid cathode is very difficult as the thermodynamic properties of transuranics are not favourable for them to remain in the metal phase while significant quantities of uranium trichloride exist in the electrolyte. Theoretically, the concentration of transuranics in the electrolyte must be approximately 106 greater than the uranium concentration in the electrolyte to produce a transuranic deposit on a solid cathode. Using liquid cadmium as a cathode contained within a LiCl-KCl eutectic salt, the co-deposition of uranium and transuranics is feasible because the activity of the transuranics in liquid cadmium is very small. Depositing transuranics and uranium in a liquid cadmium cathode (LCC) theoretically requires the concentration of transuranics to be two to three times the uranium concentration in the electrolyte. Three LCC experiments were performed in an Engineering scale elecdtrorefiner, which is located in the argon hot cell of the Fuel Conditioning Facility at the Materials and Fuels Complex on the Idaho National Laboratory. Figure 1 contains photographs of the LCC assembly in the hot cell prior to the experiment and a cadmium ingot produced after the first LCC test. Figure 1. Liquid Cadmium Cathode (left) and Cadmium Ingot (right) The primary goal of the engineering-scale liquid cadmium cathode experiments was to electrochemically collect kilogram quantities of uranium and plutonium via a LCC. The secondary goal was to examine fission product contaminations in the materials collected by the LCC. Each LCC experiment used chopped spent nuclear fuel from the blanket region of the Experimental Breeder Reactor II loaded into steel baskets as the anode with the LCC containing 26 kg of cadmium metal. In each experiment, between one and two kilograms of heavy metal was collected in the LCC after passing an integrated current over 500 amp hours. Analysis of samples from the liquid cadmium cathode ingots showed detectable amounts of transuranics and rare-earth elements. Acknowledgements K. B. Davies and D. M. Pace for the mechanical and electrical engineering needed to prepare the equipment for the engineering-scale liquid cadmium cathode experiments.

  11. Automated Testing of Supercomputers ANL/ALCF/TM-13/3 Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Automated Testing of Supercomputers ANL/ALCF/TM-13/3 Argonne Leadership Computing Facility Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Offce of Scientifc and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone (865) 576-8401 fax (865) 576-5728 reports@adonis.osti.gov Disclaimer This report was

  12. U. S. Government purposes. ANL-HEP-CP-88-42

    Office of Scientific and Technical Information (OSTI)

    authored bv a comracior>oi the U. S. Government under contract No. W-31-109-ENG-38, Accordingly, the U. S. Government retains a nonexclusive, royalty-tree license to publish or reproduce the published form of this contribution, or allow others to do so, for U. S. Government purposes. ANL-HEP-CP-88-42 DE89 003647 NUCLEAR DEPENDENCE OF STRUCTURE FUNCTIONS IN THE SHADOWING REGION OF DEEP INELASTIC SCATTERING* EDMOND L. BERGER and JIANWEI QIU High Energy Physics Division, Argonne Natiorjd

  13. DOEIEV-0005/39 ANL-OHSIHP-83-101 FORMERLY UTILIZED MED/AEC SITES

    Office of Legacy Management (LM)

    t ,-?/ . DOEIEV-0005/39 ANL-OHSIHP-83-101 FORMERLY UTILIZED MED/AEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE ALBANY METALLURGICAL RESEARCH CENTER UNITED STATES BUREAU OF MINES BIOMASS FACILITY AND THE "BACK FORTY" AREA ALBANY, OREGON OCCUPATIONAL HEALTH AND SAFETY DIVISION pQ^'^'^o,,,oc/c~~ ~Health Physics Section 4,^of, ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS %+Y, ^I~ 60Operated by THE UNIVERSITY OF CHICAGO 0t'~ ^ for the U. S. DEPARTMENT OF ENERGY under

  14. ANL-10/01 Surveillance of Site A and Plot M

    Office of Legacy Management (LM)

    ANL-10/01 Surveillance of Site A and Plot M Report for 2009 Environment, Safety, Health, and Quality Assurance Division Availability of This Report This report is available, at no cost, at http://www.osti.gov/bridge. It is also available on paper to the U.S. Department of Energy and its contractors, for a processing fee, from: U.S. Department of Energy Offce of Scientifc and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone (865) 576-8401 fax (865) 576-5728

  15. DOEIEV-0005/37 ANL=OHS/HP-83406 FORMERLY UTILIZED MEDIAEC SITES

    Office of Legacy Management (LM)

    //, .<.' I ' 1 TL\ t+, -- DOEIEV-0005/37 ANL=OHS/HP-83406 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE FORMER WATERTOWN ARSENAL PROPERTY SITE 34 AND SITE 41 WATERTOWN, MASSACHUSETTS o\o\-0 G /Q e-+ a+ -? q+ mii ' ( . % QL G+ OCCUPATIONAL HEALTH AND SAFETY INViSiON Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY O F CHICAGO for the U. S. DEPARTMENT O F ENERGY under Contract W=314 09.Eng-38 Argonne National

  16. ANL=OHS/HP=83=102 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM

    Office of Legacy Management (LM)

    ' DO E/EV=0005/40 ANL=OHS/HP=83=102 FORMERLY UTILIZED MEDIAEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE ALBANY METALLURGICAL RESEARCH CENTER UNITED STATES BUREAU OF MINES ALBANY, OREGON Q\OLO G/C G- 4& G <iI a,9 ' i . sr do OCCUPATIONAL HEALTH AND SAFETY DIVISION Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Operated by THE UNIVERSITY OF CHICAGO for the U. S. DEPARTMENT OF ENERGY under Contract W=31=109-Eng-38 Distribution Category: Remedial Action

  17. DOE/EV-0005/26 ANL-OHS/HP-82-100

    Office of Legacy Management (LM)

    J-L.f!~: r*' c;,:i &3&j DOE/EV-0005/26 ANL-OHS/HP-82-100 i$; ' ,\ : -ed - *' J&&&g y FORMERLY UTILIZED MED/AEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF THE GEORGE HERBERT JONES CHEMICAL LABORATORY THE UNIVERSITY OF CHICAGO CHICAGO, ILLINOIS June 1347, 1977 OCCUPATIONAL HEALTH AND SAFETY DIVISION Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Prepared for the U. S. DEPARTMENT OF ENERGY under Contract W -31409-Eng=38 The facilities of Argonne

  18. Air cathode structure manufacture

    DOE Patents [OSTI]

    Momyer, William R. (Palo Alto, CA); Littauer, Ernest L. (Los Altos Hills, CA)

    1985-01-01

    An improved air cathode structure for use in primary batteries and the like. The cathode structure includes a matrix active layer, a current collector grid on one face of the matrix active layer, and a porous, nonelectrically conductive separator on the opposite face of the matrix active layer, the collector grid and separator being permanently bonded to the matrix active layer. The separator has a preselected porosity providing low IR losses and high resistance to air flow through the matrix active layer to maintain high bubble pressure during operation of the battery. In the illustrated embodiment, the separator was formed of porous polypropylene. A thin hydrophobic film is provided, in the preferred embodiment, on the current collecting metal grid.

  19. lithium cobalt oxide cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lithium cobalt oxide cathode - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  20. Layered Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Layered Cathode Materials Layered Cathode Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon es_20_thackeray.pdf More Documents & Publications Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Design and Evaluation of Novel High Capacity Cathode Materials

  1. Batteries: Overview of Battery Cathodes

    SciTech Connect (OSTI)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

  2. APS Publications | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Sector(s)CAT(s) beamline(s) where the work was done, and whether or not GUP beam time was used, to apspubs@aps.anl.gov. Reminder for ANL employees: ANL employees are not...

  3. Organic Cathode Materials for Rechargeable Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Qian, Jiangfeng; Zhang, Jiguang; Xu, Wu

    2015-06-28

    This chapter will primarily focus on the advances made in recent years and specify the development of organic electrode materials for their applications in rechargeable lithium batteries, sodium batteries and redox flow batteries. Four various organic cathode materials, including conjugated carbonyl compounds, conducting polymers, organosulfides and free radical polymers, are introduced in terms of their electrochemical performances in these three battery systems. Fundamental issues related to the synthesis-structure-activity correlations, involved work principles in energy storage systems, and capacity fading mechanisms are also discussed.

  4. Hot hollow cathode gun assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1983-11-22

    A hot hollow cathode deposition gun assembly includes a hollow body having a cylindrical outer surface and an end plate for holding an adjustable heat sink, the hot hollow cathode gun, two magnets for steering the plasma from the gun into a crucible on the heat sink, and a shutter for selectively covering and uncovering the crucible.

  5. JUPITER-II Program: ANL analysis of ZPPR-13A and ZPPR-13B

    SciTech Connect (OSTI)

    Collins, P.J.; Brumbach, S.B.

    1984-08-01

    The ZPPR-13 experiments provide basic physics data for radial heterogeneous LMFBR cores of approximately 700MWe size. Assemblies ZPPR-13A, ZPPR-13B and ZPPR-13A comprised the JUPITER-II cooperative program between the U.S. Department of Energy (US DOE) and PNC of Japan. The measurements were made between August 1982 and April 1984. The core designs and the measurements were planned jointly by the two parties with substantial input from U.S. industrial interests to ensure coverage of the design requirements. This report describes in detail the results of the Argonne National Laboratory (ANL) analyses of phases 13A and 13B/1 and includes preliminary results for the later assemblies of phase 13B..

  6. Highly Dispersed Alloy Cathode Catalyst for Durability | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 3_utc.pdf More Documents & Publications Highly Dispersed Alloy Cathode Catalyst for Durability Breakout Group 1: Catalysts and Supports Advance Patent Waiver W(A)2009-002

  7. Analysis of the ANL Test Method for 6CVS Containment Vessels

    SciTech Connect (OSTI)

    Trapp, D.; Crow, G.

    2011-06-06

    In the fall of 2010, Argonne National Laboratory (ANL) contracted with vendors to design and build 6CVS containment vessels as part of their effort to ship Fuel Derived Mixed Fission Product material. The 6CVS design is based on the Savannah River National Laboratory's (SRNL) design for 9975 and 9977 six inch diameter containment vessels. The main difference between the designs is that the 6CVS credits the inner O-ring seal as the containment boundary while the SRNL design credits the outer O-ring seal. Since the leak test must be done with the inner O-ring in place, the containment vessel does not have a pathway for getting the helium into the vessel during the leak test. The leak testing contractor was not able to get acceptable leak rates with the specified O-ring, but they were able to pass the leak test with a slightly larger O-ring. ANL asked the SRNL to duplicate the leak test vendor's method to determine the cause of the high leak rates. The SRNL testing showed that the helium leak indications were caused by residual helium left within the 6CVS Closure Assembly by the leak test technique, and by helium permeation through the Viton O-ring seals. After SRNL completed their tests, the leak testing contractor was able to measure acceptable leak rates by using the slightly larger O-ring size, by purging helium from the lid threads, and by being very quick in getting the bell jar under a full vacuum. This paper describes the leak test vendor's test technique, and other techniques that could be have been used to successfully leak test the 6CVS's.

  8. Non Platinum Bimetallic Cathode Electrocatalysts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Non Platinum Bimetallic Cathode Electrocatalysts Non Platinum Bimetallic Cathode Electrocatalysts Part of a 100 million fuel cell award announced by DOE Secretary Bodman on Oct....

  9. CCD detector development projects by the beamline technical support group at the Advanced Photon Source.

    SciTech Connect (OSTI)

    Lee, J. H.; Fernandez, P.; Madden, T.; Molitsky, M.; Weizeorick, J.

    2007-11-11

    This paper will describe two ongoing detector projects being developed by the Beamline Technical Support Group at the Advanced Photon Source (APS) at Argonne National Laboratory (ANL). The first project is the design and construction of two detectors: a single-CCD system and a two-by-two Mosaic CCD camera for Small-Angle X-ray Scattering (SAXS). Both of these systems utilize the Kodak KAF-4320E CCD coupled to fiber optic tapers, custom mechanical hardware, electronics, and software developed at ANL. The second project is a Fast-CCD (FCCD) detector being developed in a collaboration between ANL and Lawrence Berkeley National Laboratory (LBNL). This detector will use ANL-designed readout electronics and a custom LBNL-designed CCD, with 480 x 480 pixels and 96 outputs, giving very fast readout.

  10. Operation of thoriated tungsten cathodes

    SciTech Connect (OSTI)

    Polk, J.E. )

    1993-01-20

    The operating temperature of thoriated tungsten cathodes used in electric thrusters depends on the surface coverage of thorium, which is determined by a balance of rate processes which supply and deplete the surface layer. The fundamental processes and rates are first reviewed in detail, then a phenomenological model based on these rate processes is described. The model indicates that the thermionic emission capabilities of thoriated tungsten cathodes decay rapidly because of thorium depletion at temperatures encountered in electric thrusters.

  11. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, Gordon E. (Albuquerque, NM)

    1998-01-01

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging.

  12. Magnetic-cusp, cathodic-arc source

    DOE Patents [OSTI]

    Falabella, Steven (Livermore, CA)

    1995-01-01

    A magnetic-cusp for a cathodic-arc source wherein the arc is confined to the desired cathode surface, provides a current path for electrons from the cathode to the anode, and utilizes electric and magnetic fields to guide ions from the cathode to a point of use, such as substrates to be coated. The magnetic-cusp insures arc stability by an easy magnetic path from anode to cathode, while the straight-through arrangement leads to high ion transmission.

  13. Cold cathode vacuum gauging system

    DOE Patents [OSTI]

    Denny, Edward C. (Knoxville, TN)

    2004-03-09

    A vacuum gauging system of the cold cathode type is provided for measuring the pressure of a plurality of separate vacuum systems, such as in a gas centrifuge cascade. Each casing is fitted with a gauge tube assembly which communicates with the vacuum system in the centrifuge casing. Each gauge tube contains an anode which may be in the form of a slender rod or wire hoop and a cathode which may be formed by the wall of the gauge tube. The tube is provided with an insulated high voltage connector to the anode which has a terminal for external connection outside the vacuum casing. The tube extends from the casing so that a portable magnet assembly may be inserted about the tube to provide a magnetic field in the area between the anode and cathode necessary for pressure measurements in a cold cathode-type vacuum gauge arrangement. The portable magnetic assembly is provided with a connector which engages the external high voltage terminal for providing power to the anode within in the gauge tube. Measurement is made in the same manner as the prior cold cathode gauges in that the current through the anode to the cathode is measured as an indication of the pressure. By providing the portable magnetic assembly, a considerable savings in cost, installation, and maintenance of vacuum gauges for pressure measurement in a gas centrifuge cascade is realizable.

  14. Development of Advanced Diesel Particulate Filtration (DPF) Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace024_lee_2010_o.pdf More Documents & Publications Development of Advanced Diesel Particulate Filtration (DPF) Systems Development of Advanced Diesel Particulate Filtration (DPF) Systems (ANL/Corning/Caterpillar CRADA) Development of Advanced Particulate Filters

  15. High power test results of the first SRRC/ANL high current L-band RF gun.

    SciTech Connect (OSTI)

    Ho, C. H.

    1998-09-11

    A joint program is underway between the SRRC (Synchrotrons Radiation Research Center, Taiwan) and ANL (Argonne National Laboratory, USA) for developing a high current L-band photocathode rf guns. We have constructed an L-Band (1.3 Ghz), single cell rf photocathode gun and conducted low power tests at SRRC. High power rf conditioning of the cavity has been completed at ANL. In this paper we report on the construction and high power test results. So far we have been able to achieve > 120 MV/m axial electric field with minimal dark current. This gun will be used to replace the AWA (Argonne Wakefield Accelerator)[l] high current gun.

  16. DOEIEV-0005/33 ANL-OHS/HP-82-104 FORMERLY UTILIZED MED/AEC SITES

    Office of Legacy Management (LM)

    33 ANL-OHS/HP-82-104 FORMERLY UTILIZED MED/AEC SITES REMEDIAL ACTION PROGRAM RADIOLOGICAL SURVEY OF UNIVERSAL CYCLOPS, INC. TITUSVILLE PLANT (Formerly Vulcan Crucible Steel Company) ALIQUIPPA, PENNSYLVANIA May 2-8, 1978 OCCUPATIONAL HEALTH AND SAFETY DIVISION Health Physics Section ARGONNE NATIONAL LABORATORY, ARGONNE, ILLINOIS Prepared for the U. S. DEPARTMENT OF ENERGY under Contract W-31 -109.Eng-38 The facilities of Argonne National Laboratory are owned by the United States Government. Under

  17. Alternative Fuel and Advanced Technology Vehicles Pilot Program...

    Open Energy Info (EERE)

    of Use: Simple Website: www.transportation.anl.govmodelingsimulationAirCredindex.html Web Application Link: www.transportation.anl.govmodelingsimulation...

  18. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    49thackeray2011o.pdf More Documents & Publications Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Layered Cathode Materials

  19. Design and Evaluation of Novel High Capacity Cathode Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 49_thackeray_2011_o.pdf More Documents & Publications Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Layered Cathode Materials

  20. High Current Density, Long Life Cathodes for High Power RF Sources

    SciTech Connect (OSTI)

    Ives, Robert Lawrence; Collins, George; Falce, Lou; Schwartzkopf, Steve; Busbaher, Daniel

    2014-01-22

    This program was tasked with improving the quality and expanding applications for Controlled Porosity Reservoir (CPR) cathodes. Calabazas Creek Research, Inc. (CCR) initially developed CPR cathodes on a DOE-funded SBIR program to improve cathodes for magnetron injection guns. Subsequent funding was received from the Defense Advanced Research Projects Agency. The program developed design requirements for implementation of the technology into high current density cathodes for high frequency applications. During Phase I of this program, CCR was awarded the prestigious 2011 R&D100 award for this technology. Subsequently, the technology was presented at numerous technical conferences. A patent was issued for the technology in 2009. These cathodes are now marketed by Semicon Associates, Inc. in Lexington, KY. They are the worlds largest producer of cathodes for vacuum electron devices. During this program, CCR teamed with Semicon Associates, Inc. and Ron Witherspoon, Inc. to improve the fabrication processes and expand applications for the cathodes. Specific fabrications issues included the quality of the wire winding that provides the basic structure and the sintering to bond the wires into a robust, cohesive structure. The program also developed improved techniques for integrating the resulting material into cathodes for electron guns.

  1. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-04-14

    A cold cathode vacuum discharge tube, and method for making same, with an interior surface of the trigger probe coated with carbon deposited by chemical vapor deposition (CVD) or diamond-like carbon (DLC) deposition are disclosed. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 14 figs.

  2. Cold cathode vacuum discharge tube

    DOE Patents [OSTI]

    Boettcher, G.E.

    1998-03-10

    A cold cathode vacuum discharge tube, and method for making same, are disclosed with an interior surface of the trigger probe coated with carbon deposited by carbon vapor deposition (CVD) or diamond-like carbon (DLC) deposition. Preferably a solid graphite insert is employed in the probe-cathode structure in place of an aluminum bushing employed in the prior art. The CVD or DLC probe face is laser scribed to allow resistance trimming to match available trigger voltage signals and to reduce electrical aging. 15 figs.

  3. Cathodic ALD V2O5 thin films for high-rate electrochemical energy storage

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Cathodic ALD V2O5 thin films for high-rate electrochemical energy storage Citation Details In-Document Search Title: Cathodic ALD V2O5 thin films for high-rate electrochemical energy storage Authors: Chen, X ; Pomerantseva, Ekaterina ; Gregorczyk, Keith ; Ghodssi, Reza ; Rubloff, Gary W Publication Date: 2013-01-01 OSTI Identifier: 1105360 DOE Contract Number: SC0001160 Resource Type: Journal Article Resource Relation: Journal Name: RSC Advances; Journal

  4. Dual-porosity ribbed fuel cell cathode

    DOE Patents [OSTI]

    Johnsen, Richard; Yuh, Chao-Yi; Alexander, Michael

    2005-05-10

    A fuel cell cathode comprising a cathode body having rib regions and base regions which connect the rib regions, the rib regions being of greater thickness and of less porosity than the base regions.

  5. Accelerator Operations and Physics - Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    soliday@aps.anl.gov Lee Teng Physicist, Argonne Emeritus Scientist teng@aps.anl.gov Marion White Senior Physicist mwhite@aps.anl.gov Aimin Xiao Physicist, Deputy Storage Ring...

  6. Innovative Cathode Coating Enables Faster Battery Charging, Dischargin...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating...

  7. Cathode Connector For Aluminum Low Temperature Smelting Cell

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

    2003-07-16

    Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

  8. Remote control for anode-cathode adjustment

    DOE Patents [OSTI]

    Roose, Lars D. (Albuquerque, NM)

    1991-01-01

    An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

  9. Magnetic-cusp, cathodic-arc source

    DOE Patents [OSTI]

    Falabella, S.

    1995-11-21

    A magnetic-cusp for a cathodic-arc source wherein the arc is confined to the desired cathode surface, provides a current path for electrons from the cathode to the anode, and utilizes electric and magnetic fields to guide ions from the cathode to a point of use, such as substrates to be coated. The magnetic-cusp insures arc stability by an easy magnetic path from anode to cathode, while the straight-through arrangement leads to high ion transmission. 3 figs.

  10. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  11. Argonne National Laboratory Partners with Advanced Magnet Lab to Develop First Fully Superconducting Direct-Drive Generator

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) Argonne National Laboratory (ANL) is partnering with Advanced Magnet Lab, in Palm Bay, Florida, on one of six projects recently awarded by DOE to help develop next generation wind turbines and accelerate the deployment of advanced turbines for offshore wind energy in the United States.

  12. Theory, Investigation and Stability of Cathode Electrocatalytic Activity

    SciTech Connect (OSTI)

    Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

    2012-09-30

    The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar conditions. This was also confirmed by x-ray analyses. For example, soft x-ray XANES data reveal that Co cations displace the Mn cations as being more favored to be reduced. Variations in the Sr-O in the annealed LSCF Fourier-transformed (FT) EXAFS suggest that some Sr segregation is occurring, but is not present in the annealed LSM-infiltrated LSCF cathode materials. Further, a surface enhanced Raman technique was also developed into to probe and map LSM and LSCF phase on underlying YSZ substrate, enabling us to capture important chemical information of cathode surfaces under practical operating conditions. Electrochemical models for the design of test cells and understanding of mechanism have been developed for the exploration of fundamental properties of electrode materials. Novel catalyst coatings through particle depositions (SDC, SSC, and LCC) or continuous thin films (PSM and PSCM) were successfully developed to improve the activity and stability of LSCF cathodes. Finally, we have demonstrated enhanced activity and stability of LSCF cathodes over longer periods of time in homemade and commercially available cells by an optimized LSM infiltration process. Microstructure examination of the tested cells did not show obvious differences between blank and infiltrated cells, suggesting that the infiltrated LSM may form a coherent film on the LSCF cathodes. There was no significant change in the morphology or microstructure of the LSCF cathode due to the structural similarity of LSCF and LSM. Raman analysis of the tested cells indicated small peaks emerging on the blank cells that correspond to trace amounts of secondary phase formation during operation (e.g., CoO{sub x}). The formation of this secondary phase might be attributed to performance degradation. In contrast, there was no such secondary phase observed in the LSM infiltrated cells, indicating that the LSM modification staved off secondary phase formation and thus improved the stability.

  13. Nickel-titanium-phosphate cathodes

    DOE Patents [OSTI]

    Belharouak, Ilias; Amine, Khalil

    2008-12-16

    Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.

  14. Filters for cathodic arc plasmas

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA); MacGill, Robert A. (Richmond, CA); Bilek, Marcela M. M. (Engadine, AU); Brown, Ian G. (Berkeley, CA)

    2002-01-01

    Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  15. Sequential Infiltration Synthesis Advances Lithography (IN-10-017, 10-106)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal Industrial Technologies Industrial Technologies Advanced Materials Advanced Materials Find More Like This Return to Search Sequential Infiltration Synthesis Advances Lithography (IN-10-017, 10-106) A unique lithography resist transformation process that dramatically improves image quality while reducing cost. Argonne National Laboratory Contact ANL About This Technology <p> Directed self-assembly (DSA) of block copolymers is targeted as a next-generation

  16. STABILIZED SPINEL AND POLYANION CATHODES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    STABILIZED SPINEL AND POLYANION CATHODES STABILIZED SPINEL AND POLYANION CATHODES 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es051_manthiram_2011_o.pdf More Documents & Publications Stabilized Spinels and Polyanion Cathodes HIGH-VOLTAGE SPINEL AND POLYANION CATHODES Stabilized Spinel and Polyanion Cathodes

  17. Arc initiation in cathodic arc plasma sources

    DOE Patents [OSTI]

    Anders, Andre (Albany, CA)

    2002-01-01

    A "triggerless" arc initiation method and apparatus is based on simply switching the arc supply voltage to the electrodes (anode and cathode). Neither a mechanical trigger electrode nor a high voltage flashover from a trigger electrode is required. A conducting path between the anode and cathode is provided, which allows a hot spot to form at a location where the path connects to the cathode. While the conductive path is eroded by the cathode spot action, plasma deposition ensures the ongoing repair of the conducting path. Arc initiation is achieved by simply applying the relatively low voltage of the arc power supply, e.g. 500 V-1 kV, with the insulator between the anode and cathode coated with a conducting layer and the current at the layer-cathode interface concentrated at one or a few contact points. The local power density at these contact points is sufficient for plasma production and thus arc initiation. A conductive surface layer, such as graphite or the material being deposited, is formed on the surface of the insulator which separates the cathode from the anode. The mechanism of plasma production (and arc initiation) is based on explosive destruction of the layer-cathode interface caused by joule heating. The current flow between the thin insulator coating and cathode occurs at only a few contact points so the current density is high.

  18. Argonne Lab's Breakthrough Cathode Technology Powers Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Courtesy of Audra Capas, 5StarPR David Moore Presidential Management Fellow, Office of ... David Moore: In simple terms, what makes the Argonne cathode material special? Jeff ...

  19. Highly Dispersed Alloy Cathode Catalyst for Durability

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on alloy cathode catalysts, was given by T. D. Jarvi of UTC Power at a February 2007 meeting on new fuel cell projects.

  20. Performance Degradation of LSCF Cathodes

    SciTech Connect (OSTI)

    Alinger, Matthew

    2013-09-30

    This final report summarizes the progress made during the October 1, 2008 - September 30, 2013 period under Cooperative Agreement DE-NT0004109 for the U. S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled Performance Degradation of LSCF Cathodes. The primary objective of this program is to develop a performance degradation mitigation path for high performing, cost-effective solid oxide fuel cells (SOFCs). Strategies to mitigate performance degradation are developed and implemented. In addition, thermal spray manufacturing of SOFCs is explored. Combined, this work establishes a basis for cost-effective SOFC cells.

  1. High-Tech Brain Implant Predicts, Prevents Epileptic Seizures (ANL-IN-08-043)

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2012-02-07

    Epilepsy, a seizure disorder, affects nearly 3 million people in the United States and 50 million worldwide. Although medication can help treat epilepsy, it has not eliminated seizures for all who live with the condition. Researchers at Argonne National Laboratory—together with researchers from Flint Hills Scientific, LLC, and Biofil, Sarov, Russia—have developed an advanced brain implant system that finds and stops seizures before they happen. This innovation offers...

  2. NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES

    SciTech Connect (OSTI)

    John Olson, PhD

    2004-07-21

    This project involved the synthesis of nanowire -MnO2 and characterization as cathode material for high-power lithium-ion batteries for EV and HEV applications. The nanowire synthesis involved the edge site decoration nanowire synthesis developed by Dr. Reginald Penner at UC Irvine (a key collaborator in this project). Figure 1 is an SEM image showing -MnO2 nanowires electrodeposited on highly oriented pyrolytic graphite (HOPG) electrodes. This technique is unique to other nanowire template synthesis techniques in that it produces long (>500 um) nanowires which could reduce or eliminate the need for conductive additives due to intertwining of fibers. Nanowire cathode for lithium-ion batteries with surface areas 100 times greater than conventional materials can enable higher power batteries for electric vehicles (EVs) and hybrid electric vehicles (HEVs). The synthesis of the -MnO2 nanowires was successfully achieved. However, it was not found possible to co-intercalate lithium directly in the nanowire synthesis. Based on input from proposal reviewers, the scope of the project was altered to attempt the conversion into spinel LiMn2O4 nanowire cathode material by solid state reaction of the -MnO2 nanowires with LiNO3 at elevated temperatures. Attempts to perform the conversion on the graphite template were unsuccessful due to degradation of the graphite apparently caused by oxidative attack by LiNO3. Emphasis then shifted to quantitative removal of the nanowires from the graphite, followed by the solid state reaction. Attempts to quantitatively remove the nanowires by several techniques were unsatisfactory due to co-removal of excess graphite or poor harvesting of nanowires. Intercalation of lithium into -MnO2 electrodeposited onto graphite was demonstrated, showing a partial demonstration of the -MnO2 material as a lithium-ion battery cathode material. Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

  3. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon esp13thackeray.pdf More Documents & Publications Design and Evaluation of High Capacity Cathodes Design and Evaluation of Novel High Capacity Cathode Materials Design ...

  4. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Design and Evaluation of High Capacity Cathodes Vehicle Technologies Office Merit Review 2014: Design and Evaluation of High Capacity Cathodes Design and ...

  5. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  6. Surface modified CFx cathode material for ultrafast discharge...

    Office of Scientific and Technical Information (OSTI)

    Surface modified CFx cathode material for ultrafast discharge and high energy density Prev Next Title: Surface modified CFx cathode material for ultrafast discharge and high...

  7. Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur Cells Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication LBNL Commercial Analysis Report (1,062 KB) Technology Marketing Summary A Berkeley Lab team headed by Yuegang Zhang and Elton Cairns has developed

  8. Cathode for an electrochemical cell

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN); Dudney, Nancy J. (Knoxville, TN); Gruzalski, Greg R. (Oak Ridge, TN); Luck, Christopher F. (Knoxville, TN)

    2001-01-01

    Described is a thin-film battery, especially a thin-film microbattery, and a method for making same having application as a backup or primary integrated power source for electronic devices. The battery includes a novel electrolyte which is electrochemically stable and does not react with the lithium anode and a novel vanadium oxide cathode. Configured as a microbattery, the battery can be fabricated directly onto a semiconductor chip, onto the semiconductor die or onto any portion of the chip carrier. The battery can be fabricated to any specified size or shape to meet the requirements of a particular application. The battery is fabricated of solid state materials and is capable of operation between -15.degree. C. and 150.degree. C.

  9. Cathode for molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Mrazek, Franklin C. (Hickory Hills, IL)

    1990-01-01

    A porous sintered cathode for a molten carbonate fuel cell and method of making same, the cathode including a skeletal structure of a first electronically conductive material slightly soluble in the electrolyte present in the molten carbonate fuel cell covered by fine particles of a second material of possibly lesser electronic conductivity insoluble in the electrolyte present in the molten carbonate fuel cell, the cathode having a porosity in the range of from about 60% to about 70% at steady-state cell operating conditions consisting of both macro-pores and micro-pores.

  10. Cells having cathodes containing polycarbon disulfide materials

    DOE Patents [OSTI]

    Okamoto, Yoshi (Fort Lee, NJ); Skotheim, Terje A. (Shoreham, NY); Lee, Hung S. (Rocky Point, NY)

    1995-08-15

    The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS.sub.x).sub.n, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode.

  11. Microsoft Word - NMC_cathodes bh

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Improvements in the high-voltage cycling stability of lithium ion battery cathode materials are needed to enable the wide-spread adoption of renewable energy technologies such as electric vehicles. One cathode material which exhibits significant advantages over the commonly-used commercial material LiCoO 2 in terms of higher capacity, increased thermal stability, and reduced cost is LiNi 0.4 Mn 0.4 Co 0.2 O 2 (referred to as

  12. Cells having cathodes containing polycarbon disulfide materials

    DOE Patents [OSTI]

    Okamoto, Y.; Skotheim, T.A.; Lee, H.S.

    1995-08-15

    The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS{sub x}){sub n}, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode. 5 figs.

  13. Engineering of High Energy Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Energy Cathode Materials Engineering of High Energy Cathode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es015_amine_2011_p.pdf More Documents & Publications Engineering of High Energy Cathode Material Engineering of High Energy Cathode Materials FY 2011 Annual Progress Report for Energy Storage R&D

  14. Stabilized Spinels and Polyanion Cathodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyanion Cathodes Stabilized Spinels and Polyanion Cathodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es051_manthiram_2010_p.pdf More Documents & Publications STABILIZED SPINEL AND POLYANION CATHODES Stabilized Spinels and Nano Olivines Vehicle Technologies Office Merit Review 2014: High-Capacity Polyanion Cathodes

  15. Process Development and Scale-up of Advanced Cathode Materials

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  16. Low temperature aluminum reduction cell using hollow cathode

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

    2002-08-20

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. A plurality of non-consumable anodes are disposed substantially vertically in the electrolyte along with a plurality of monolithic hollow cathodes. Each cathode has a top and bottom and the cathodes are disposed vertically in the electrolyte and the anodes and the cathodes are arranged in alternating relationship. Each of the cathodes is comprised of a first side facing a first opposing anode and a second side facing a second opposing anode. The first and second sides are joined by ends to form a reservoir in the hollow cathode for collecting aluminum therein deposited at the cathode.

  17. Non-Platinum Bimetallic Cathode Electrocatalysts

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on non-platinum bimetallic cathode electrocatalysts, was given by Debbie Myers of Argonne National Laboratory at a February 2007 meeting on new fuel cell projects.

  18. Cathodic protection of storage field well casings

    SciTech Connect (OSTI)

    Dabkowski, J.

    1986-01-01

    Downhole logging of gas storage field wells to determine cathodic protection (CP) levels is expensive and requires removing the well from service. A technique allowing the prediction of downhole CP levels by modeling combined with limiting field measurements would provide the industry with a cost-effective means of implementing and monitoring casing protection. A computer model has been developed for a cathodically protected well casing.

  19. HIGH-VOLTAGE SPINEL AND POLYANION CATHODES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HIGH-VOLTAGE SPINEL AND POLYANION CATHODES HIGH-VOLTAGE SPINEL AND POLYANION CATHODES 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es051_manthiram_2012_p.pdf More Documents & Publications Stabilized Spinel and Polyanion Cathodes Vehicle Technologies Office Merit Review 2014: High-Capacity Polyanion Cathodes STABILIZED SPINEL AND POLYANION CATHODES

  20. High current density cathode for electrorefining in molten electrolyte

    DOE Patents [OSTI]

    Li, Shelly X.

    2010-06-29

    A high current density cathode for electrorefining in a molten electrolyte for the continuous production and collection of loose dendritic or powdery deposits. The high current density cathode eliminates the requirement for mechanical scraping and electrochemical stripping of the deposits from the cathode in an anode/cathode module. The high current density cathode comprises a perforated electrical insulated material coating such that the current density is up to 3 A/cm.sup.2.

  1. Search for High Energy Density Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Energy Density Cathode Materials Search for High Energy Density Cathode Materials 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es018_belharouak_2010_o.pdf More Documents & Publications Evaluation of Li2MnSiO4 Cathode Evaluation of Li2MnSiO4 Cathode Vehicle Technologies Office Merit Review 2014: High-Capacity Polyanion Cathodes

  2. Engineering of High Energy Cathode Material | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Energy Cathode Material Engineering of High Energy Cathode Material 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es015_amine_2010_o.pdf More Documents & Publications Engineering of High Energy Cathode Materials Engineering of High Energy Cathode Materials Development of High-Capacity Cathode Materials with Integrated Structures

  3. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    SciTech Connect (OSTI)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2003-03-31

    This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

  4. Plasma processes inside dispenser hollow cathodes

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.; Jameson, Kristina K.

    2006-06-15

    A two-dimensional fluid model of the plasma and neutral gas inside dispenser orificed hollow cathodes has been developed to quantify plasma processes that ultimately determine the life of the porous emitters inserted in these devices. The model self-consistently accounts for electron emission from the insert as well as for electron and ion flux losses from the plasma. Two cathodes, which are distinctively different in size and operating conditions, have been simulated numerically. It is found that the larger cathode, with outer tube diameter of 1.5 cm and orifice diameter of 0.3 cm, establishes an effective emission zone that spans approximately the full length of the emitter when operated at a discharge current of 25 A and a flow rate of 5.5 sccm. The net heating of the emitter is caused by ions that are produced by ionization of the neutral gas inside the tube and are then accelerated by the sheath along the emitter. The smaller cathode, with an outer diameter of 0.635 cm and an orifice diameter of 0.1 cm, does not exhibit the same operational characteristics. At a flow rate of 4.25 sccm and discharge current of 12 A, the smaller cathode requires 4.5 times the current density near the orifice and operates with more than 6 times the neutral particle density compared to the large cathode. As a result, the plasma particle density is almost one order of magnitude higher compared to the large cathode. The plasma density in this small cathode is high enough such that the Debye length is sufficiently small to allow 'sheath funneling' into the pores of the emitter. By accessing areas deeper into the insert material, it is postulated that the overall emission of electrons is significantly enhanced. The maximum emission current density is found to be about 1 A/mm{sup 2} in the small cathode, which is about one order of magnitude higher than attained in the large cathode. The effective emission zone in the small cathode extends to about 15% of the emitter length only, and the power deposited at the emitter surface by returning electrons is found to be twice that deposited by ions. A previous study suggested that the computed particle flux and energy of ions to the emitter of the 1.5 cm cathode were not high enough to change the barium evaporation rate compared to thermally induced evaporation. The same suggestion is made here for the 0.635 cm cathode. The peak ion flux to the emitter is found to be 1.2 A/cm{sup 2} (7.6x10{sup 18}/s cm{sup 2}), and the corresponding peak sheath drop is 2.9 V. Consequently, once the emitter operating temperature is known it is possible to determine directly the barium depletion-limited life of these cathodes using existing vacuum-cathode data.

  5. Improved cathode materials for microbial electrosynthesis

    SciTech Connect (OSTI)

    Zhang, T; Nie, HR; Bain, TS; Lu, HY; Cui, MM; Snoeyenbos-West, OL; Franks, AE; Nevin, KP; Russell, TP; Lovley, DR

    2013-01-01

    Microbial electrosynthesis is a promising strategy for the microbial conversion of carbon dioxide to transportation fuels and other organic commodities, but optimization of this process is required for commercialization. Cathodes which enhance electrode-microbe electron transfer might improve rates of product formation. To evaluate this possibility, biofilms of Sporomusa ovata, which are effective in acetate electrosynthesis, were grown on a range of cathode materials and acetate production was monitored over time. Modifications of carbon cloth that resulted in a positive-charge enhanced microbial electrosynthesis. Functionalization with chitosan or cyanuric chloride increased acetate production rates 6-7 fold and modification with 3-aminopropyltriethoxysilane gave rates 3-fold higher than untreated controls. A 3-fold increase in electrosynthesis over untreated carbon cloth cathodes was also achieved with polyaniline cathodes. However, not all strategies to provide positively charged surfaces were successful, as treatment of carbon cloth with melamine or ammonia gas did not stimulate acetate electrosynthesis. Treating carbon cloth with metal, in particular gold, palladium, or nickel nanoparticles, also promoted electrosynthesis, yielding electrosynthesis rates that were 6-,4.7- or 4.5-fold faster than the untreated control, respectively. Cathodes comprised of cotton or polyester fabric treated with carbon nanotubes yielded cathodes that supported acetate electrosynthesis rates that were similar to 3-fold higher than carbon cloth controls. Recovery of electrons consumed in acetate was similar to 80% for all materials. The results demonstrate that one approach to increase rates of carbon dioxide reduction in microbial electrosynthesis is to modify cathode surfaces to improve microbe-electrode interactions.

  6. 2013 Estorm - Invited Paper - Cathode Materials Review

    SciTech Connect (OSTI)

    Daniel, Claus; Mohanty, Debasish; Li, Jianlin; Wood III, David L

    2014-01-01

    The electrochemical potential of cathode materials defines the positive side of the terminal voltage of a battery. Traditionally, cathode materials are the energy-limiting or voltage-limiting electrode. One of the first electrochemical batteries, the voltaic pile invented by Alessandro Volta in 1800 (Phil. Trans. Roy. Soc. 90, 403 431) had a copper-zinc galvanic element with a terminal voltage of 0.76 V. Since then, the research community has increased capacity and voltage for primary (nonrechargeable) batteries and round-trip efficiency for secondary (rechargeable) batteries. Successful secondary batteries have been the lead acid with a lead oxide cathode and a terminal voltage of 2.1 V and later the NiCd with a nickel(III) oxide hydroxide cathode and a 1.2 V terminal voltage. The relatively low voltage of those aqueous systems and the low round-trip efficiency due to activation energies in the conversion reactions limited their use. In 1976, Wittingham (J. Electrochem. Soc., 123, 315) and Besenhard (J Power Sources 1(3), 267) finally enabled highly reversible redox reactions by intercalation of lithium ions instead of by chemical conversion. In 1980, Goodenough and Mizushima (Mater. Res. Bull. 15, 783 789) demonstrated a high-energy and high-power LiCoO2 cathode, allowing for an increase of terminal voltage far beyond 3 V. Over the past four decades, the international research community has further developed cathode materials of many varieties. Current state-of-the-art cathodes demonstrate voltages beyond any known electrolyte stability window, bringing electrolyte research once again to the forefront of battery research.

  7. Filtered cathodic arc deposition apparatus and method

    DOE Patents [OSTI]

    Krauss, Alan R. (24461 W. Blvd. De John, Naperville, IL 60564)

    1999-01-01

    A filtered cathodic arc deposition method and apparatus for the production of highly dense, wear resistant coatings which are free from macro particles. The filtered cathodic arc deposition apparatus includes a cross shaped vacuum chamber which houses a cathode target having an evaporable surface comprised of the coating material, means for generating a stream of plasma, means for generating a transverse magnetic field, and a macro particle deflector. The transverse magnetic field bends the generated stream of plasma in the direction of a substrate. Macro particles are effectively filtered from the stream of plasma by traveling, unaffected by the transverse magnetic field, along the initial path of the plasma stream to a macro particle deflector. The macro particle deflector has a preformed surface which deflects macro particles away from the substrate.

  8. Field free, directly heated lanthanum boride cathode

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Moussa, David (San Francisco, CA); Wilde, Stephen B. (Pleasant Hill, CA)

    1991-01-01

    A directly heated cylindrical lanthanum boride cathode assembly is disclosed which minimizes generation of magnetic fields which would interfere with electron emission from the cathode. The cathode assembly comprises a lanthanum boride cylinder in electrical contact at one end with a central support shaft which functions as one electrode to carry current to the lanthanum boride cylinder and in electrical contact, at its opposite end with a second electrode which is coaxially position around the central support shaft so that magnetic fields generated by heater current flowing in one direction through the central support shaft are cancelled by an opposite magnetic field generated by current flowing through the lanthanum boride cylinder and the coaxial electrode in a direction opposite to the current flow in the central shaft.

  9. Field free, directly heated lanthanum boride cathode

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Moussa, D.; Wilde, S.B.

    1987-02-02

    A directly heated cylindrical lanthanum boride cathode assembly is disclosed which minimizes generation of magnetic field which would interfere with electron emission from the cathode. The cathode assembly comprises a lanthanum boride cylinder in electrical contact at one end with a central support shaft which functions as one electrode to carry current to the lanthanum boride cylinder and in electrical contact, at its opposite end with a second electrode which is coaxially position around the central support shaft so that magnetic fields generated by heater current flowing in one direction through the central support shaft are cancelled by an opposite magnetic field generated by current flowing through the lanthanum boride cylinder and the coaxial electrode in a direction opposite to the current flow in the central shaft.

  10. Synchrotron Investigations of SOFC Cathode Degradation

    SciTech Connect (OSTI)

    Idzerda, Yves

    2013-09-30

    The atomic variations occurring in cathode/electrolyte interface regions of La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3-?} (LSCF) cathodes and other SOFC related materials have been investigated and characterized using soft X-ray Absorption Spectroscopy (XAS) and diffuse soft X-ray Resonant Scattering (XRS). X-ray Absorption Spectroscopy in the soft X-ray region (soft XAS) is shown to be a sensitive technique to quantify the disruption that occurs and can be used to suggest a concrete mechanism for the degradation. For LSC, LSF, and LSCF films, a significant degradation mechanism is shown to be Sr out-diffusion. By using the XAS spectra of hexavalent Cr in SrCrO4 and trivalent Cr in Cr2O3, the driving factor for Sr segregation was identified to be the oxygen vacancy concentration at the anode and cathode side of of symmetric LSCF/GDC/LSCF heterostructures. This is direct evidence of vacancy induced cation diffusion and is shown to be a significant indicator of cathode/electrolyte interfacial degradation. X-ray absorption spectroscopy is used to identify the occupation of the A-sites and B-sites for LSC, LSF, and LSCF cathodes doped with other transition metals, including doping induced migration of Sr to the anti-site for Sr, a significant cathode degradation indicator. By using spatially resolved valence mapping of Co, a complete picture of the surface electrochemistry can be determined. This is especially important in identifying degradation phenomena where the degradation is spatially localized to the extremities of the electrochemistry and not the average. For samples that have electrochemical parameters that are measured to be spatially uniform, the Co valence modifications were correlated to the effects of current density, overpotential, and humidity.

  11. ANL News 2006

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    behaves in simulant agent, a chemical that structurally resembles mustard but lacks its toxic properties. The goal is to find disposal methods that do not release toxic mercury to...

  12. tracc.anl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About TRACC Article Count: 10 TRACC Article Count: 22 CFD Article Count: 24 CSM Article Count: 15 TRAFFIC Article Count: 49 Collaboration Article Count: 4 Computing Article Count: 4 TRANSPORTATION RESEARCH Article Count: 2 Polaris Article Count: 10 Blog Article Count: 1

  13. ANL-05/20

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information P.O. Box 62 Oak Ridge, TN 37831-0062 phone (865) 576-8401 fax (865) 576-5728 reports@adonis.osti.gov Argonne National...

  14. Cathodic protection of pipelines in discontinuous permafrost

    SciTech Connect (OSTI)

    Mitchell, C.J.; Wright, M.D.; Waslen, D.W.

    1997-08-01

    This paper discusses the challenges in providing cathodic protection for a pipeline located in an area with discontinuous permafrost. Specific challenges included: unknown time for the permafrost to melt out, unpredictable current distribution characteristics and wet, inaccessible terrain. Based on preliminary pipe-to-soil data, it appears that cathodic protection coverage was achieved in discontinuous permafrost regions without the need of local anodes. Future work is required to verify whether this conclusion can be extended over the course of an annual freeze-thaw cycle.

  15. Cathode architectures for alkali metal / oxygen batteries

    DOE Patents [OSTI]

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  16. Engineering of high energy cathode material | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    high energy cathode material Engineering of high energy cathode material 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_09_amine.pdf More Documents & Publications Engineering of High Energy Cathode Material Design of Safer High-Energy Density Materials for Lithium-Ion Cells Engineering of High Energy Cathode Materials

  17. Developing new high energy gradient concentration cathode material |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy new high energy gradient concentration cathode material Developing new high energy gradient concentration cathode material 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_10_amine.pdf More Documents & Publications New High Energy Gradient Concentration Cathode Material New High Energy Gradient Concentration Cathode Material New High Energy Gradient

  18. Development of high-capacity cathode materials with integrated structures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy high-capacity cathode materials with integrated structures Development of high-capacity cathode materials with integrated structures 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_14_kang.pdf More Documents & Publications Development of High-Capacity Cathode Materials with Integrated Structures Novel Composite Cathode

  19. Engineering of High Energy Cathode Materials | Department of Energy

    Office of Environmental Management (EM)

    Engineering of High Energy Cathode Materials Engineering of High Energy Cathode Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es015_amine_2012_o.pdf More Documents & Publications Studies on Lithium Manganese Rich MNC Composite Cathodes Vehicle Technologies Office Merit Review 2014: Synthetic Solutions for Correcting Voltage Fade in LMR-NMC Cathodes Examining Hysteresis in Lithium- and

  20. Neutronics, steady-state, and transient analyses for the Poland MARIA reactor for irradiation testing of LEU lead test fuel assemblies from CERCA : ANL independent verification results.

    SciTech Connect (OSTI)

    Garner, P. L.; Hanan, N. A.

    2011-06-07

    The MARIA reactor at the Institute of Atomic Energy (IAE) in Swierk (30 km SE of Warsaw) in the Republic of Poland is considering conversion from high-enriched uranium (HEU) to low-enriched uranium (LEU) fuel assemblies (FA). The FA design in MARIA is rather unique; a suitable LEU FA has never been designed or tested. IAE has contracted with CERCA (the fuel supply portion of AREVA in France) to supply 2 lead test assemblies (LTA). The LTAs will be irradiated in MARIA to burnup level of at least 40% for both LTAs and to 60% for one LTA. IAE may decide to purchase additional LEU FAs for a full core conversion after the test irradiation. The Reactor Safety Committee within IAE and the National Atomic Energy Agency in Poland (PAA) must approve the LTA irradiation process. The approval will be based, in part, on IAE submitting revisions to portions of the Safety Analysis Report (SAR) which are affected by the insertion of the LTAs. (A similar process will be required for the full core conversion to LEU fuel.) The analysis required was established during working meetings between Argonne National Laboratory (ANL) and IAE staff during August 2006, subsequent email correspondence, and subsequent staff visits. The analysis needs to consider the current high-enriched uranium (HEU) core and 4 core configurations containing 1 and 2 LEU LTAs in various core positions. Calculations have been performed at ANL in support of the LTA irradiation. These calculations are summarized in this report and include criticality, burn-up, neutronics parameters, steady-state thermal hydraulics, and postulated transients. These calculations have been performed at the request of the IAE staff, who are performing similar calculations to be used in their SAR amendment submittal to the PAA. The ANL analysis has been performed independently from that being performed by IAE and should only be used as one step in the verification process.

  1. Design and Evaluation of Novel High Capacity Cathode Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es049_thackeray_2012_p.pdf More Documents & Publications Design and Evaluation of High Capacity Cathodes Vehicle Technologies Office Merit Review 2014: Design and Evaluation of High Capacity Cathodes Design and Evaluation of Novel High Capacity Cathode Materials

  2. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    2011-03-29

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La.sub.0.8Sr.sub.0.2CoO.sub.3) and lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1).

  3. Cathodic protection of pipelines in discontinuous permafrost

    SciTech Connect (OSTI)

    Mitchell, C.J.; Wright, M.D.; Waslen, D.W.

    1997-10-01

    There are many unknowns and challenges in providing cathodic protection (CP) for a pipeline located in discontinuous permafrost areas. Preliminary pipe-to-soil data indicates that CP coverage was achieved in these regions without needing local anodes. Work is required to verify whether this conclusion can be extended over the course of an annual freeze-thaw cycle.

  4. Contacts | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (on-call pager) From on-site phone: 2-0101 General Inquiries & Media Contact Rick Fenner fenner@aps.anl.gov 630-252-5280 Important Numbers Off-hour access: 630-252-0101 Safety...

  5. Overview of 2007 ANL progress for conversion of HEU- based Mo-99 production as part of the U.S. global threat reduction--conversion program

    SciTech Connect (OSTI)

    Vandegrift, George F.; Bakel, Allen J.; Thomas, Justin W.

    2008-07-15

    ANL effort is divided into five areas: (1) cooperation with Argentina to demonstrate the use of LEU-foil targets in alkaline-based processes, (2) cooperation with Indonesia in converting their HEU-based Cintichem process to LEU-foil targets, (3) technical assistance to two potential U.S. domestic suppliers (MURR and BWTX), (4) responding to the National Academies Study, and (5) participation in the IAEA CRP for Indigenous Mo-99 production. This paper presents highlights of these activities. A short description of how the dose emitted by spent HEU target material compared to spent fuel is also included. (author)

  6. Overview of 2007 ANL progress for conversion of HEU-based Mo-99 production as part of the U.S. Global Threat Reduction--Conversion program.

    SciTech Connect (OSTI)

    Vandegrift, G. F.; Bakel, A. J.; Thomas, J. W.

    2007-01-01

    ANL effort is divided into five areas: (1) cooperation with Argentina to demonstrate the use of LEU-foil targets in alkaline-based processes, (2) cooperation with Indonesia in converting their HEU-based Cintichem process to LEU-foil targets, (3) technical assistance to two potential U.S. domestic suppliers (MURR and BWTX), (4) responding to the National Academies Study, and (5) participation in the IAEA CRP for Indigenous Mo-99 production. This paper presents highlights of these activities. A short description of how the dose emitted by spent HEU target material compared to spent fuel is also included.

  7. Carbon-containing cathodes for enhanced electron emission

    DOE Patents [OSTI]

    Cao, Renyu (Cupertino, CA); Pan, Lawrence (Pleasanton, CA); Vergara, German (Madrid, ES); Fox, Ciaran (Los Altos, CA)

    2000-01-01

    A cathode has electropositive atoms directly bonded to a carbon-containing substrate. Preferably, the substrate comprises diamond or diamond-like (sp.sup.3) carbon, and the electropositive atoms are Cs. The cathode displays superior efficiency and durability. In one embodiment, the cathode has a negative electron affinity (NEA). The cathode can be used for field emission, thermionic emission, or photoemission. Upon exposure to air or oxygen, the cathode performance can be restored by annealing or other methods. Applications include detectors, electron multipliers, sensors, imaging systems, and displays, particularly flat panel displays.

  8. Virtual cathode microwave generator having annular anode slit

    DOE Patents [OSTI]

    Kwan, Thomas J. T.; Snell, Charles M.

    1988-01-01

    A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit therethrough effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators.

  9. Cathode scraper system and method of using the same for removing uranium

    DOE Patents [OSTI]

    Williamson, Mark A; Wiedmeyer, Stanley G; Willit, James L; Barnes, Laurel A; Blaskovitz, Robert J

    2015-02-03

    Embodiments include a cathode scraper system and/or method of using the same for removing uranium. The cathode scraper system includes a plurality of cathode assemblies. Each cathode assembly includes a plurality of cathode rods. The cathode scraper system also includes a cathode scraper assembly configured to remove purified uranium deposited on the plurality of cathode rods. The cathode scraper assembly includes a plurality of scrapers arranged in a lattice, and each scraper of the plurality of scrapers is arranged to correspond to a different cathode rod.

  10. The effect of cathode geometry on barium transport in hollow cathode plasmas

    SciTech Connect (OSTI)

    Polk, James E. Mikellides, Ioannis G.; Katz, Ira; Capece, Angela M.

    2014-05-14

    The effect of barium transport on the operation of dispenser hollow cathodes was investigated in numerical modeling of a cathode with two different orifice sizes. Despite large differences in cathode emitter temperature, emitted electron current density, internal xenon neutral and plasma densities, and size of the plasma-surface interaction region, the barium transport in the two geometries is qualitatively very similar. Barium is produced in the insert and flows to the surface through the porous structure. A buildup of neutral Ba pressure in the plasma over the emitter surface can suppress the reactions supplying the Ba, restricting the net production rate. Neutral Ba flows into the dense Xe plasma and has a high probability of being ionized at the periphery of this zone. The steady state neutral Ba density distribution is determined by a balance between pressure gradient forces and the drag force associated with collisions between neutral Ba and neutral Xe atoms. A small fraction of the neutral Ba is lost upstream. The majority of the neutral Ba is ionized in the high temperature Xe plasma and is pushed back to the emitter surface by the electric field. The steady state Ba{sup +} ion density distribution results from a balance between electrostatic and pressure forces, neutral Xe drag and Xe{sup +} ion drag with the dominant forces dependent on location in the discharge. These results indicate that hollow cathodes are very effective at recycling Ba within the discharge and therefore maintain a high coverage of Ba on the emitter surface, which reduces the work function and sustains high electron emission current densities at moderate temperatures. Barium recycling is more effective in the cathode with the smaller orifice because the Ba is ionized in the dense Xe plasma concentrated just upstream of the orifice and pushed back into the hollow cathode. Despite a lower emitter temperature, the large orifice cathode has a higher Ba loss rate through the orifice because the Xe plasma density peaks further upstream.

  11. Spinel compounds as multivalent battery cathodes: A systematic evaluation based on ab initio calculations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Miao; Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele; Jain, Anubhav; Ceder, Gerbrand; Persson, Kristin A.

    2014-12-16

    In this study, batteries that shuttle multivalent ions such as Mg2+ and Ca2+ ions are promising candidates for achieving higher energy density than available with current Li-ion technology. Finding electrode materials that reversibly store and release these multivalent cations is considered a major challenge for enabling such multivalent battery technology. In this paper, we use recent advances in high-throughput first-principles calculations to systematically evaluate the performance of compounds with the spinel structure as multivalent intercalation cathode materials, spanning a matrix of five different intercalating ions and seven transition metal redox active cations. We estimate the insertion voltage, capacity, thermodynamic stabilitymore » of charged and discharged states, as well as the intercalating ion mobility and use these properties to evaluate promising directions. Our calculations indicate that the Mn2O4 spinel phase based on Mg and Ca are feasible cathode materials. In general, we find that multivalent cathodes exhibit lower voltages compared to Li cathodes; the voltages of Ca spinels are ~0.2 V higher than those of Mg compounds (versus their corresponding metals), and the voltages of Mg compounds are ~1.4 V higher than Zn compounds; consequently, Ca and Mg spinels exhibit the highest energy densities amongst all the multivalent cation species. The activation barrier for the Al³⁺ ion migration in the Mn₂O₄ spinel is very high (~1400 meV for Al3+ in the dilute limit); thus, the use of an Al based Mn spinel intercalation cathode is unlikely. Amongst the choice of transition metals, Mn-based spinel structures rank highest when balancing all the considered properties.« less

  12. Magnetron cathodes in plasma electrode Pockels cells

    DOE Patents [OSTI]

    Rhodes, M.A.

    1995-04-25

    Magnetron cathodes, which produce high current discharges, form greatly improved plasma electrodes on each side of an electro-optic crystal. The plasma electrode has a low pressure gas region on both sides of the crystal. When the gas is ionized, e.g., by a glow discharge in the low pressure gas, the plasma formed is a good conductor. The gas electrode acts as a highly uniform conducting electrode. Since the plasma is transparent to a high energy laser beam passing through the crystal, the plasma is transparent. A crystal exposed from two sides to such a plasma can be charged up uniformly to any desired voltage. A typical configuration utilizes helium at 50 millitorr operating pressure and 2 kA discharge current. The magnetron cathode produces a more uniform plasma and allows a reduced operating pressure which leads to lower plasma resistivity and a more uniform charge on the crystal. 5 figs.

  13. Monitoring cathodic protection of well casings

    SciTech Connect (OSTI)

    Dabkowski, J.

    1980-01-01

    Because conventional downhole logging of gas storage wells to determine cathodic-protection levels is expensive and inconvenient, a program was developed (1) to predict downhole casing-to-soil potentials from wellhead measurements in the presence of interference and (2 )to model the mutual interference effects occurring between the wells and the cathodic-protection systems. In the first phase of this project, a transmission-line model that was developed to represent the well casing electrically adequately predicted the downhole potentials for both ideal and nonideal polarization conditions. By allowing the number of sections used and their parameter values as variables, the model can accommodate different environments and casing configurations. The model's representation of a well casing by a lumped-parameter electrical network will also permit interference studies between mutually coupled wells.

  14. NUMERICAL MODELING OF CATHODE CONTACT MATERIAL DENSIFICATION

    SciTech Connect (OSTI)

    Koeppel, Brian J.; Liu, Wenning N.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-11-01

    Numerical modeling was used to simulate the constrained sintering process of the cathode contact layer during assembly of solid oxide fuel cells (SOFCs). A finite element model based on the continuum theory for sintering of porous bodies was developed and used to investigate candidate low-temperature cathode contact materials. Constitutive parameters for various contact materials under investigation were estimated from dilatometry screening tests, and the influence of processing time, processing temperature, initial grain size, and applied compressive stress on the free sintering response was predicted for selected candidate materials. The densification behavior and generated stresses within a 5-cell planar SOFC stack during sintering, high temperature operation, and room temperature shutdown were predicted. Insufficient constrained densification was observed in the stack at the proposed heat treatment, but beneficial effects of reduced grain size, compressive stack preload, and reduced thermal expansion coefficient on the contact layer densification and stresses were observed.

  15. Cathode Ion Bombardment in RF Photoguns

    SciTech Connect (OSTI)

    Pozdeyev,E.; Kayran, D.; Litvinenko, V.

    2008-09-01

    In this paper, we use the method of rapid oscillating field to solve the equation of ion motion in an RF gun. We apply the method to the BNL 1/2-cell SRF photogun and demonstrate that a significant portion of ions produced in the gun can reach the cathode if no special precautions are taken. Also, the paper proposes a simple mitigation recipe that can reduce the rate of ion bombardment.

  16. Applied Cathode Enhancement and Robustness Technologies (ACERT)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accelerators, Electrodynamics » ACERT Applied Cathode Enhancement and Robustness Technologies (ACERT) World leading experts from fields of accelerator design & testing, chemical synthesis of nanomaterials, and shielding application of nanomaterials. thumbnail of Nathan Moody Nathan Moody Principal Investigator (PI) Email ACERT Logo Team Our project team, a part of Los Alamos National Laboratory (LANL) comprised of world leading experts from fields of accelerator design & testing,

  17. Engineering of High Energy Cathode Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of High energy cathode material K. Amine (PI) H. Wu, I. Belharouak, Y.K. Sun Argonne National Laboratory DOE merit review May 14-18 , 2012 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project ID, ES-015 Overview  Start - October 1 st , 2008.  Finish - September 30, 2014.  65%  Barriers addressed - Very high energy - Long calendar and cycle life - Excellent abuse tolerance * Total project funding:1200K - DOE share: - 2012: 300K

  18. Scanning optical pyrometer for measuring temperatures in hollow cathodes

    SciTech Connect (OSTI)

    Polk, J. E.; Marrese-Reading, C. M.; Thornber, B.; Dang, L.; Johnson, L. K.; Katz, I.

    2007-09-15

    Life-limiting processes in hollow cathodes are determined largely by the temperature of the electron emitter. To support cathode life assessment, a noncontact temperature measurement technique which employs a stepper motor-driven fiber optic probe was developed. The probe is driven inside the hollow cathode and collects light radiated by the hot interior surface of the emitter. Ratio pyrometry is used to determine the axial temperature profile. Thermocouples on the orifice plate provide measurements of the external temperature during cathode operation and are used to calibrate the pyrometer system in situ with a small oven enclosing the externally heated cathode. The diagnostic method and initial measurements of the temperature distribution in a hollow cathode are discussed.

  19. Cathode power distribution system and method of using the same for power distribution

    DOE Patents [OSTI]

    Williamson, Mark A; Wiedmeyer, Stanley G; Koehl, Eugene R; Bailey, James L; Willit, James L; Barnes, Laurel A; Blaskovitz, Robert J

    2014-11-11

    Embodiments include a cathode power distribution system and/or method of using the same for power distribution. The cathode power distribution system includes a plurality of cathode assemblies. Each cathode assembly of the plurality of cathode assemblies includes a plurality of cathode rods. The system also includes a plurality of bus bars configured to distribute current to each of the plurality of cathode assemblies. The plurality of bus bars include a first bus bar configured to distribute the current to first ends of the plurality of cathode assemblies and a second bus bar configured to distribute the current to second ends of the plurality of cathode assemblies.

  20. Molten carbonate fuel cell cathode with mixed oxide coating

    DOE Patents [OSTI]

    Hilmi, Abdelkader; Yuh, Chao-Yi

    2013-05-07

    A molten carbonate fuel cell cathode having a cathode body and a coating of a mixed oxygen ion conductor materials. The mixed oxygen ion conductor materials are formed from ceria or doped ceria, such as gadolinium doped ceria or yttrium doped ceria. The coating is deposited on the cathode body using a sol-gel process, which utilizes as precursors organometallic compounds, organic and inorganic salts, hydroxides or alkoxides and which uses as the solvent water, organic solvent or a mixture of same.

  1. Development of Alternative and Durable High Performance Cathode Supports

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for PEM Fuel Cells | Department of Energy Supports for PEM Fuel Cells Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells This presentation, which focuses on cathode supports for PEM fuel cells, was given by Yong Wang of PNNL at a February 2007 meeting on new fuel cell projects. PDF icon new_fc_wang_pnnl.pdf More Documents & Publications Development of Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Fuel Cell Kickoff

  2. Development of High-Capacity Cathode Materials with Integrated Structures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es019_thackeray_2012_o.pdf More Documents & Publications Development of High-Capacity Cathode Materials with Integrated Structures Vehicle Technologies Office Merit Review 2015: Design and Evaluation of High Capacity Cathodes Development of High-Capacity Cathode Materials with Integrated Structures

  3. Development of High-Capacity Cathode Materials with Integrated Structures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es019_kang_2010_o.pdf More Documents & Publications Development of high-capacity cathode materials with integrated structures Development of High-Capacity Cathode Materials with Integrated Structures Development of High-Capacity Cathode Materials with Integrated Structures

  4. Studies on Lithium Manganese Rich MNC Composite Cathodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Lithium Manganese Rich MNC Composite Cathodes Studies on Lithium Manganese Rich MNC Composite Cathodes 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es106_nanda_2013_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Electrochemical Modeling of LMR-NMC Materials and Electrodes Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for

  5. BASF Catalysts Opens Cathode Production Facility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BASF Catalysts Opens Cathode Production Facility BASF Catalysts Opens Cathode Production Facility March 5, 2015 - 6:27pm Addthis BASF Catalysts, a battery component manufacturer, is running the largest cathode materials manufacturing facility in the country with support from EERE's Vehicle Technologies Office (VTO). The factory was supported by a $25 million American Recovery and Reinvestment Act project. Located in Elyria, Ohio, the facility at full capacity is capable of producing 2,500 metric

  6. Neutronic, steady-state, and transient analyses for the Kazakhstan VVR-K reactor with LEU fuel: ANL independent verification results

    SciTech Connect (OSTI)

    Hanan, Nelson A.; Garner, Patrick L.

    2015-08-01

    Calculations have been performed for steady state and postulated transients in the VVR-K reactor at the Institute of Nuclear Physics (INP), Kazakhstan. (The reactor designation in Cyrillic is BBP-K; transliterating characters to English gives VVR-K but translating words gives WWR-K.) These calculations have been performed at the request of staff of the INP who are performing similar calculations. The selection of the transients considered started during working meetings and email correspondence between Argonne National Laboratory (ANL) and INP staff. In the end the transient were defined by the INP staff. Calculations were performed for the fresh low-enriched uranium (LEU) core and for four subsequent cores as beryllium is added to maintain critically during the first 15 cycles. These calculations have been performed independently from those being performed by INP and serve as one step in the verification process.

  7. Battery Cathode Developed by Argonne Powers Plug-in Electric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photo courtesy of General Motors The 2011 Chevrolet Volt at a charging station. Its battery is based on a cathode technology developed at Argonne National Laboratory, which will ...

  8. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Lithium Source For High Performance Li-ion Cells Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High...

  9. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Development of High-Capacity Cathode Materials with Integrated Structures Vehicle Technologies Office Merit Review 2015: Design and Evaluation of High...

  10. Multi-cathode metal vapor arc ion source

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805)

    1988-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. One embodiment of the appaatus utilizes a multi-cathode arrangement for interaction with the anode.

  11. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Peer Evaluation PDF icon es019kang2011p.pdf More Documents & Publications Development of High-Capacity Cathode Materials with Integrated Structures Development of...

  12. Process for synthesis of a layered oxide cathode composition

    DOE Patents [OSTI]

    Petrovic, Ivan; Thurston, Anthony; Sheargold, Stephen

    2015-03-31

    A method for preparing a layered oxide cathode using a two step calcination procedure, wherein the first step includes pre-calcination utilizing a rotary calciner.

  13. Construction of a Li Ion Battery (LIB) Cathode Production Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ravt008esdicarlo2011p.pdf More Documents & Publications Process for Low Cost Domestic Production of LIB Cathode Materials Process for Low Cost Domestic Production of LIB...

  14. Illinois: High-Energy, Concentration-Gradient Cathode Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Energy, Concentration-Gradient Cathode Material for Plug-in Hybrids and All-Electric Vehicles Could Reduce Batteries' Cost and Size Illinois: High-Energy,...

  15. Surface Characterization of the LCLS RF Gun Cathode

    SciTech Connect (OSTI)

    Brachmann, Axel; Decker, Franz-Josef; Ding, Yuantao; Dowell, David; Emma, Paul; Frisch, Josef; Gilevich, Sasha; Hays, Gregory; Hering, Philippe; Huang, Zhirong; Iverson, Richard; Loos, Henrik; Miahnahri, Alan; Nordlund, Dennis; Nuhn, Heinz-Dieter; Pianetta, Piero; Turner, James; Welch, James; White, William; Wu, Juhao; Xiang, Dao; /SLAC

    2012-06-25

    The first copper cathode installed in the LCLS RF gun was used during LCLS commissioning for more than a year. However, after high charge operation (> 500 pC), the cathode showed a decline of quantum efficiency within the area of drive laser illumination. They report results of SEM, XPS and XAS studies that were carried out on this cathode after it was removed from the gun. X-ray absorption and X-ray photoelectron spectroscopy reveal surface contamination by various hydrocarbon compounds. In addition they report on the performance of the second installed cathode with emphasis on the spatial distribution of electron emission.

  16. EERE Success Story—BASF Catalysts Opens Cathode Production Facility

    Broader source: Energy.gov [DOE]

    BASF Catalysts, a battery component manufacturer, is running the largest cathode materials manufacturing facility in the country with support from EERE’s Vehicle Technologies Office (VTO). The...

  17. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    2011-04-05

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of Perovskite AMeO.sub.3, wherein A is at least one of lanthanum and a combination of lanthanum and strontium and Me is one or more of transition metals, lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1) and X-doped LiMeO.sub.2, wherein X is one of Mg, Ca, and Co.

  18. Single-layer graphene cathodes for organic photovoltaics

    SciTech Connect (OSTI)

    Cox, Marshall P.; Gorodetsky, Alon A.; Kim, Bumjung; Kim, Keun Soo; Jia, Zhang; Kim, Philip; Nuckolls, Colin; Kymissis, Ioannis

    2011-01-01

    A laminated single-layer graphene is demonstrated as a cathode for organic photovoltaicdevices. The measured properties indicate that graphene offers two potential advantages over conventional photovoltaic electrode materials; work function matching via contact doping, and increased power conversion efficiency due to transparency. These findings indicate that flexible, light-weight all carbon solar cells can be constructed using graphene as the cathode material.

  19. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, J.D.

    1984-08-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  20. Self-contained hot-hollow cathode gun source assembly

    DOE Patents [OSTI]

    Zeren, Joseph D. (Boulder, CO)

    1986-01-01

    A self-contained hot-hollow cathode gun source assembly for use in a vacuum chamber includes a crucible block having a hot-hollow cathode gun mounted underneath and providing a hole for the magnetic deflection of the ion/electron beam into a crucible on top the block.

  1. Nanofiber Scaffold for Cathode of Solid Oxide Fuel Cell

    SciTech Connect (OSTI)

    Mingjia Zhi; Nicholas Mariani; Randall Gemmen; Kirk Gerdes; Nianqiang Wu

    2010-10-01

    A high performance solid oxide fuel cell cathode using the yttria-stabilized zirconia (YSZ) nanofibers scaffold with the infiltrated La1-xSrxMnO3 (LSM) shows an enhanced catalytic activity toward oxygen reduction. Such a cathode offers a continuous path for charge transport and an increased number of triple-phase boundary sites.

  2. Development of High Energy Cathode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Development of High Energy Cathode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es056_zhang_2011_o.pdf More Documents & Publications Development of High Energy Cathode for Li-ion Batteries Phase Behavior and Solid State Chemistry in Olivines Low Cost SiOx-Graphite and Olivine Materials

  3. Toda Cathode Materials Production Facility | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cathode Materials Production Facility Toda Cathode Materials Production Facility 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon arravt017_es_han_2013_p.pdf More Documents & Publications Toda Material/Component Production Facilities Toda Material/Component Production Facilities

  4. Material and Energy Flows in the Production of Cathode and Anode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode...

  5. Focused cathode design to reduce anode heating during vircator operation

    SciTech Connect (OSTI)

    Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A.

    2013-10-15

    Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

  6. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH); Turk, Thomas R. (Mentor, OH)

    1988-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  7. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH)

    1987-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  8. Two-dimensional modeling of the cathode sheath formation during the streamer-cathode interaction

    SciTech Connect (OSTI)

    Yan, Wen; Sang, Chaofeng; Wang, Dezhen, E-mail: wangdez@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Liu, Fucheng [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)] [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2014-01-15

    In this paper, a computational simulation of the sheath formation during the streamer-surface interaction at atmospheric pressure is presented. A two-dimensional fluid model of a point-to-plane configuration is applied to investigate the evolution of the discharge in the vicinity of cathode plane. The effects of the surfaces on the properties of streamer have been studied for three cases, i.e., conductive surface with secondary electron emission (SEE), conductive surface without SEE, and dielectric surface. In all cases, we found that the axial propagation velocity of the streamer front decreases as the streamer arrives at the boundary of the cathode sheath. And the simulation results showed that the properties of the surface have a significant effect on the streamer. Besides the influences, the secondary emission coefficient and the relative permittivity on the streamer-surface interactions are also studied.

  9. Cathodic Vacuum Arc Plasma of Thallium

    SciTech Connect (OSTI)

    Yushkov, Georgy Yu.; Anders, Andre

    2006-10-02

    Thallium arc plasma was investigated in a vacuum arc ionsource. As expected from previous consideration of cathode materials inthe Periodic Table of the Elements, thallium plasma shows lead-likebehavior. Its mean ion charge state exceeds 2.0 immediately after arctriggering, reaches the predicted 1.60 and 1.45 after about 100 microsecand 150 microsec, respectively. The most likely ion velocity is initially8000 m/s and decays to 6500 m/s and 6200 m/s after 100 microsec and 150microsec, respectively. Both ion charge states and ion velocities decayfurther towards steady state values, which are not reached within the 300microsec pulses used here. It is argued that the exceptionally high vaporpressure and charge exchange reactions are associated with theestablishment of steady state ion values.

  10. Advanced electrorefiner design

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Gay, Eddie C. (Park Forest, IL); Tomczuk, Zygmunt (Lockport, IL)

    1996-01-01

    A combination anode and cathode for an electrorefiner which includes a hollow cathode and an anode positioned inside the hollow cathode such that a portion of the anode is near the cathode. A retaining member is positioned at the bottom of the cathode. Mechanism is included for providing relative movement between the anode and the cathode during deposition of metal on the inside surface of the cathode during operation of the electrorefiner to refine spent nuclear fuel. A method is also disclosed which includes electrical power means selectively connectable to the anode and the hollow cathode for providing electrical power to the cell components, electrically transferring uranium values and plutonium values from the anode to the electrolyte, and electrolytically depositing substantially pure uranium on the hollow cathode. Uranium and plutonium are deposited at a liquid cathode together after the PuCl.sub.3 to UCl.sub.3 ratio is greater than 2:1. Slots in the hollow cathode provides close anode access for the liquid pool in the liquid cathode.

  11. Advanced electrorefiner design

    DOE Patents [OSTI]

    Miller, W.E.; Gay, E.C.; Tomczuk, Z.

    1996-07-02

    A combination anode and cathode is described for an electrorefiner which includes a hollow cathode and an anode positioned inside the hollow cathode such that a portion of the anode is near the cathode. A retaining member is positioned at the bottom of the cathode. Mechanism is included for providing relative movement between the anode and the cathode during deposition of metal on the inside surface of the cathode during operation of the electrorefiner to refine spent nuclear fuel. A method is also disclosed which includes electrical power means selectively connectable to the anode and the hollow cathode for providing electrical power to the cell components, electrically transferring uranium values and plutonium values from the anode to the electrolyte, and electrolytically depositing substantially pure uranium on the hollow cathode. Uranium and plutonium are deposited at a liquid cathode together after the PuCl{sub 3} to UCl{sub 3} ratio is greater than 2:1. Slots in the hollow cathode provides close anode access for the liquid pool in the liquid cathode. 6 figs.

  12. High Performance Cathodes for Li-Air Batteries

    SciTech Connect (OSTI)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  13. Performance of field emission cathodes in xenon environments

    SciTech Connect (OSTI)

    Marrese, C.M.; Polk, J.E.; Jensen, K.L.; Gallimore, A.D.; Spindt, C.; Fink, R.L.; Tolt, Z.L.; Palmer, W.D.

    1999-07-01

    Field emission (FE) cathodes are currently being considered to supply electrons in electric propulsion systems for propellant ionization and ion beam neutralization. Hollow cathodes with thermionic electron emitters typically used with Hall and ion thrusters require propellant and heaters for operation. Therefore there are lower limits on their size and power. Because FE cathodes do not require propellant or heaters they can be used with small and micropropulsion systems. The primary concern with integrating these two technologies is cathode lifetime. An FE cathode must be capable of operation in a plasma environment where xenon pressures exceed 2 x 10{sup {minus}6} Torr. Experiments were conducted at the Jet Propulsion Laboratory to evaluate the performance of silicon and molybdenum microtip field emission array cathodes, and carbon film cathodes in xenon pressures up to 2 x 10{sup {minus}5} Torr. Experimental and modeling results were used to determine energy thresholds for sputtering silicon and molybdenum by xenon ions. Experiments and theoretical results are presented for performance degradation in xenon environments.

  14. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, Eddie C. (Park Forest, IL); Miller, William E. (Naperville, IL); Laidler, James J. (Burr Ridge, IL)

    1997-01-01

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two.

  15. Electrorefining cell with parallel electrode/concentric cylinder cathode

    DOE Patents [OSTI]

    Gay, E.C.; Miller, W.E.; Laidler, J.J.

    1997-07-22

    A cathode-anode arrangement for use in an electrolytic cell is adapted for electrochemically refining spent nuclear fuel from a nuclear reactor and recovering purified uranium for further treatment and possible recycling as a fresh blanket or core fuel in a nuclear reactor. The arrangement includes a plurality of inner anodic dissolution baskets that are each attached to a respective support rod, are submerged in a molten lithium halide salt, and are rotationally displaced. An inner hollow cylindrical-shaped cathode is concentrically disposed about the inner anodic dissolution baskets. Concentrically disposed about the inner cathode in a spaced manner are a plurality of outer anodic dissolution baskets, while an outer hollow cylindrical-shaped is disposed about the outer anodic dissolution baskets. Uranium is transported from the anode baskets and deposited in a uniform cylindrical shape on the inner and outer cathode cylinders by rotating the anode baskets within the molten lithium halide salt. Scrapers located on each anode basket abrade and remove the spent fuel deposits on the surfaces of the inner and outer cathode cylinders, with the spent fuel falling to the bottom of the cell for removal. Cell resistance is reduced and uranium deposition rate enhanced by increasing the electrode area and reducing the anode-cathode spacing. Collection efficiency is enhanced by trapping and recovery of uranium dendrites scrapped off of the cylindrical cathodes which may be greater in number than two. 12 figs.

  16. Emission mechanism of barium-containing thermionic cathodes

    SciTech Connect (OSTI)

    Enqui, Z.; Xeuque, L.

    1991-03-27

    Through the analysis and synthesis of data obtained from barium containing thermionic cathodes, especially those by modern surface analysis technique, the authors have come to a unified theory--the dynamical surface emission center model. Barium absorbed on the surface of alkaline earth metal oxides in case of oxide cathode or of aluminate, tungstate etc. in case of dispenser cathode may form the emission center. Its size should be large enough to screen off the attractive field produced by the substrate, but small enough to facilitate the transport of electrons from the substrate to the emitting center. The compositions and the dynamical characters of the surface emission center are also discussed.

  17. Characterization of plasma chemistry and ion energy in cathodic arc plasma from Ti-Si cathodes of different compositions

    SciTech Connect (OSTI)

    Eriksson, A. O.; Zhirkov, I.; Dahlqvist, M.; Jensen, J.; Hultman, L.; Rosen, J.

    2013-04-28

    Arc plasma from Ti-Si compound cathodes with up to 25 at. % Si was characterized in a DC arc system with respect to chemistry and charge-state-resolved ion energy. The plasma ion composition showed a lower Si content, diverging up to 12 at. % compared to the cathode composition, yet concurrently deposited films were in accordance with the cathode stoichiometry. Significant contribution to film growth from neutrals is inferred besides ions, since the contribution from macroparticles, estimated by scanning electron microscopy, cannot alone account for the compositional difference between cathode, plasma, and film. The average ion charge states for Ti and Si were higher than reference data for elemental cathodes. This result is likely related to TiSi{sub x} phases of higher cohesive energies in the compound cathodes and higher effective electron temperature in plasma formation. The ion energy distributions extended up to {approx}200 and {approx}130 eV for Ti and Si, respectively, with corresponding average energies of {approx}60 and {approx}30 eV. These averages were, however, not dependent on Si content in the cathode, except for 25 at. % Si where the average energies were increased up to 72 eV for Ti and 47 eV for Si.

  18. Characterization of New Cathode Materials using Synchrotron-based...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials using Synchrotron-based X-ray Techniques and the Studies of Li-Air Batteries Characterization of New Cathode Materials using Synchrotron-based X-ray Techniques and the...

  19. Design and Evaluation of Novel High Capacity Cathode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    17johnson2011p.pdf More Documents & Publications Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells Lithium Source ...

  20. Development of High-Capacity Cathode Materials with Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 -- Washington D.C. PDF icon es019kang2010o.pdf More Documents & Publications Development of high-capacity cathode materials with integrated structures Development of...

  1. Development of high-capacity cathode materials with integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp14kang.pdf More Documents & Publications Development of High-Capacity Cathode Materials ...

  2. Illinois: High-Energy, Concentration-Gradient Cathode Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a high-energy, concentration-gradient cathode material for plug-in hybrid and all-electric vehicles. ... market growth, leading to reductions in carbon pollution and imported oil. ...

  3. Spinel compounds as multivalent battery cathodes: A systematic evaluation based on ab initio calculations

    SciTech Connect (OSTI)

    Liu, Miao; Rong, Ziqin; Malik, Rahul; Canepa, Pieremanuele; Jain, Anubhav; Ceder, Gerbrand; Persson, Kristin A.

    2014-12-16

    In this study, batteries that shuttle multivalent ions such as Mg2+ and Ca2+ ions are promising candidates for achieving higher energy density than available with current Li-ion technology. Finding electrode materials that reversibly store and release these multivalent cations is considered a major challenge for enabling such multivalent battery technology. In this paper, we use recent advances in high-throughput first-principles calculations to systematically evaluate the performance of compounds with the spinel structure as multivalent intercalation cathode materials, spanning a matrix of five different intercalating ions and seven transition metal redox active cations. We estimate the insertion voltage, capacity, thermodynamic stability of charged and discharged states, as well as the intercalating ion mobility and use these properties to evaluate promising directions. Our calculations indicate that the Mn2O4 spinel phase based on Mg and Ca are feasible cathode materials. In general, we find that multivalent cathodes exhibit lower voltages compared to Li cathodes; the voltages of Ca spinels are ~0.2 V higher than those of Mg compounds (versus their corresponding metals), and the voltages of Mg compounds are ~1.4 V higher than Zn compounds; consequently, Ca and Mg spinels exhibit the highest energy densities amongst all the multivalent cation species. The activation barrier for the Al? ion migration in the Mn?O? spinel is very high (~1400 meV for Al3+ in the dilute limit); thus, the use of an Al based Mn spinel intercalation cathode is unlikely. Amongst the choice of transition metals, Mn-based spinel structures rank highest when balancing all the considered properties.

  4. Chromium (V) compounds as cathode material in electrochemical power sources

    DOE Patents [OSTI]

    Delnick, F.M.; Guidotti, R.A.; McCarthy, D.K.

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca/sub 5/(CrO/sub 4/)/sub 3/Cl, Ca/sub 5/(CrO/sub 4/)OH, and Cr/sub 2/O/sub 5/. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  5. Chromium (V) compounds as cathode material in electrochemical power sources

    DOE Patents [OSTI]

    Delnick, Frank M.; Guidotti, Ronald A.; McCarthy, David K.

    1985-01-01

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca.sub.5 (CrO.sub.4).sub.3 Cl, Ca.sub.5 (CrO.sub.4).sub.3 OH, and Cr.sub.2 O.sub.5. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  6. High-Current Cold Cathode Employing Diamond and Related Materials

    SciTech Connect (OSTI)

    Hirshfield, Jay L.

    2014-10-22

    The essence of this project was for diamond films to be deposited on cold cathodes to improve their emission properties. Films with varying morphology, composition, and size of the crystals were deposited and the emission properties of the cathodes that utilize such films were studied. The prototype cathodes fabricated by the methods developed during Phase I were tested and evaluated in an actual high-power RF device during Phase II. These high-power tests used the novel active RF pulse compression system and the X-band magnicon test facility at US Naval Research Laboratory. In earlier tests, plasma switches were employed, while tests under this project utilized electron-beam switching. The intense electron beams required in the switches were supplied from cold cathodes embodying diamond films with varying morphology, including uncoated molybdenum cathodes in the preliminary tests. Tests with uncoated molybdenum cathodes produced compressed X-band RF pulses with a peak power of 91 MW, and a maximum power gain of 16.5:1. Tests were also carried out with switches employing diamond coated cathodes. The pulse compressor was based on use of switches employing electron beam triggering to effect mode conversion. In experimental tests, the compressor produced 165 MW in a ~ 20 ns pulse at ~18× power gain and ~ 140 MW at ~ 16× power gain in a 16 ns pulse with a ~ 7 ns flat-top. In these tests, molybdenum blade cathodes with thin diamond coatings demonstrated good reproducible emission uniformity with a 100 kV, 100 ns high voltage pulse. The new compressor does not have the limitations of earlier types of active pulse compressors and can operate at significantly higher electric fields without breakdown.

  7. Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode

    Office of Scientific and Technical Information (OSTI)

    Materials. (Conference) | SciTech Connect Conference: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Abstract not provided. Authors: Hudak, Nicholas Publication Date: 2014-04-01 OSTI Identifier: 1143066 Report Number(s): SAND2014-3282C 511744 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Conference Resource Relation:

  8. In situ determination of lithium ion cathode/electrolyte interface

    Office of Scientific and Technical Information (OSTI)

    thickness and composition as a function of charge. (Journal Article) | SciTech Connect Journal Article: In situ determination of lithium ion cathode/electrolyte interface thickness and composition as a function of charge. Citation Details In-Document Search Title: In situ determination of lithium ion cathode/electrolyte interface thickness and composition as a function of charge. Abstract not provided. Authors: Jungjohann, Katherine Leigh Publication Date: 2014-01-01 OSTI Identifier: 1140750

  9. Investigations of Cathode Architecture using Graphite Fibers | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Cathode Architecture using Graphite Fibers Investigations of Cathode Architecture using Graphite Fibers 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es087_dudney_2010_p.pdf More Documents & Publications Investigations of electrode interface and architecture Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes Overcoming Processing Cost Barriers

  10. Preparation of redox polymer cathodes for thin film rechargeable batteries

    DOE Patents [OSTI]

    Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

    1994-11-08

    The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

  11. Innovative Cathode Coating Enables Faster Battery Charging, Discharging |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Innovative Cathode Coating Enables Faster Battery Charging, Discharging Technology available for licensing: Coating increases electrical conductivity of cathode materials Coating does not hinder battery performance Provides two coating processes that yield surface-treated, electro-active materials for a variety of applications, such as in a rechargeable lithium battery in both processes, and primary and secondary lithium battery applications in another process.

  12. Examining Hysteresis in Lithium- and Manganese-Rich Composite Cathode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy Hysteresis in Lithium- and Manganese-Rich Composite Cathode Materials Examining Hysteresis in Lithium- and Manganese-Rich Composite Cathode Materials 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es189_gallagher_2013_p.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Electrochemical Modeling of LMR-NMC Materials and Electrodes Vehicle

  13. Development of Alternative and Durable High Performance Cathode Supporst

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for PEM Fuel Cells | Department of Energy Supporst for PEM Fuel Cells Development of Alternative and Durable High Performance Cathode Supporst for PEM Fuel Cells Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. PDF icon 3_pnnl.pdf More Documents & Publications Development of Alternative and Durable High Performance Cathode Supports for PEM Fuel Cells Fuel Cell Kickoff Meeting Agenda 2012 Pathways to Commercial Success: Technologies and Products

  14. Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of

    Energy Savers [EERE]

    Today | Department of Energy Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today Argonne Lab's Breakthrough Cathode Technology Powers Electric Vehicles of Today February 14, 2011 - 6:15pm Addthis Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR Jeff Chamberlain Speaks at Brookings Battery Forum | Photo Courtesy of Audra Capas, 5StarPR David Moore Presidential Management Fellow, Office of Energy Efficiency & Renewable

  15. Cathodic Protection of the Yaquina Bay Bridge

    SciTech Connect (OSTI)

    Bullard, Sophie J.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Laylor, H.M.; Cryer, C.B.

    2001-02-01

    The Yaquina Bay Bridge in Newport, Oregon, was designed by Conde B. McCullough and built in 1936. The 3,223-foot (982 m) structure is a combination of concrete arch approach spans and a steel through arch over the shipping channel. Cathodic protection is used to prevent corrosion damage to the concrete arches. The Oregon Department of Transportation (Oregon DOT) installed a carbon anode coating (DAC-85) on two of the north approach spans in 1985. This anode was operated at a current density of 6.6 mA/m2(0.6 mA/ft2). No failure of the conductive anode was observed in 1990, five years after application, or in 2000, 15 years after application. Thermal-sprayed zinc anodes 20 mils (0.5 mm) thick were applied to half the south approach spans beginning in 1990. Thermal-sprayed zinc anodes 15 mils (0.4 mm) thick were applied to the remaining spans in 1996. These anodes were operated at a current density of 2.2 mA/m2(0.2 mA/ft2). In 1999, four zones on the approach spans were included in a two-year field trial of humectants to improve zinc anode performance. The humectants LiNO3 and LiBr were applied to two zones; the two adjacent zones were left untreated as controls. The humectants substantially reduced circuit resistance compared to the controls.

  16. PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL

    SciTech Connect (OSTI)

    Phelan, B.T.; Myers, D.J.; Smith, M.C.

    2009-01-01

    State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratorys Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

  17. PPPL lends General Electric a hand in developing an advanced power switch |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab lends General Electric a hand in developing an advanced power switch By John Greenwald August 28, 2014 Tweet Widget Google Plus One Share on Facebook Laboratory test of a liquid-metal cathode. (Photo by General Electric Co. ) Laboratory test of a liquid-metal cathode. Scientists at the U.S. Department of Energy's (DOE) Princeton Plasma Physics Laboratory (PPPL) are assisting General Electric Co. in developing an electrical switch that could help lower utility

  18. PNNL Advances Hydrogen-Fueled Vehicle Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PNNL Advances Hydrogen-Fueled Vehicle Technologies PNNL Advances Hydrogen-Fueled Vehicle Technologies July 26, 2013 - 12:00am Addthis Through multiple projects, Pacific Northwest National Laboratory (PNNL) is improving the performance and decreasing the cost of hydrogen fuel production and fuel cell technologies. PNNL's research is developing new materials-like a durable, high-performance cathode support-and improving the manufacturing processes by using a "drop-on-demand" process to

  19. Functionally Graded Cathodes for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Lei Yang; Ze Liu; Shizhone Wang; Jaewung Lee; Meilin Liu

    2008-04-30

    The main objective of this DOE project is to demonstrate that the performance and long-term stability of the state-of-the-art LSCF cathode can be enhanced by a catalytically active coating (e.g., LSM or SSC). We have successfully developed a methodology for reliably evaluating the intrinsic surface catalytic properties of cathode materials. One of the key components of the test cell is a dense LSCF film, which will function as the current collector for the electrode material under evaluation to eliminate the effect of ionic and electronic transport. Since it is dense, the effect of geometry would be eliminated as well. From the dependence of the electrode polarization resistance on the thickness of a dense LSCF electrode and on partial pressure of oxygen, we have confirmed that the surface catalytic activity of LSCF limits the performances of LSCF-based cathodes. Further, we have demonstrated, using test cells of different configurations, that the performance of LSCF-based electrodes can be significantly enhanced by infiltration of a thin film of LSM or SSC. In addition, the stability of LSCF-based cathodes was also improved by infiltration of LSM or SSC. While the concept feasibility of the electrode architecture is demonstrated, many details are yet to be determined. For example, it is not clear how the surface morphology, composition, and thickness of the coatings change under operating conditions over time, how these changes influence the electrochemical behavior of the cathodes, and how to control the microscopic details of the coatings in order to optimize the performance. The selection of the catalytic materials as well as the detailed microstructures of the porous LSCF and the catalyst layer may critically impact the performance of the proposed cathodes. Further, other fundamental questions still remain; it is not clear why the degradation rates of LSCF cathodes are relatively high, why a LSM coating improves the stability of LSCF cathodes, which catalysts would be most effective for LSCF, and how to achieve further enhancement of the performance and stability of SOFC cathodes.

  20. Asymmetric injection of cathodic arc plasma into a macroparticlefilter

    SciTech Connect (OSTI)

    Anders, Andre; MacGill, Robert A.

    2004-02-11

    The cathodic arc plasmas produced by cathode spots usuallyinclude macroparticles, which is undesirable for many applications. Acommon way of removing macroparticles is to use curved solenoid filterswhich guide the plasma from the source to the substrate. In this work, anarc source with relatively small cathode is used, limiting the possiblelocations of plasma production. The relative position of cathodic arcsource and macroparticle filtered was systematically varied and thefiltered plasma current was recorded. It was found that axis-symmetricplasma injection leads to maximum throughput only if an anode aperturewas used, which limited the plasma to near-axis flow by scraping offplasma at larger angles to the axis. When the anode aperture was removed,more plasma could enter the filter. In this case, maximum filtered ioncurrent was achieved when the plasma was injected off-axis, namely offsetin the direction where the filter is curved. Such behavior wasanticipated because the plasma column in the filter is known to beshifted by ExB and centrifugal drift as well as by non-axis-symmetriccomponents of the magnetic field in the filter entrance and exit plane.The data have implications for plasma transport variations caused bydifferent spot locations on cathodes that are not small compared to thefilter cross section.

  1. ANL-FF-262i

    Office of Legacy Management (LM)

    from our foundry's graphite-melted uranium is remote because of the metalIs high carbon content. High purity metal isto be considered a possible solution of many of the...

  2. Djurcic_ANL_June2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from MiniBooNE Zelimir Djurcic Zelimir Djurcic Argonne National Laboratory Argonne National Laboratory Argonne High Energy Physics Seminar Argonne High Energy Physics Seminar June 23rd, 2010 June 23rd, 2010 Outline Outline * * MiniBooNE MiniBooNE Experiment Description Experiment Description * * MiniBooNE MiniBooNE ' ' s s Neutrino Results Neutrino Results * * MiniBooNE MiniBooNE ' ' s s Anti-neutrino Anti-neutrino Results Results * * Next Steps and Summary Next Steps and Summary This signal

  3. Ahn-ANL_User_Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OPPORTUNITIES WITH THE PROTOTYPE AT-TPC AT ATLAS Tan Ahn! National Superconducting Cyclotron Lab, Michigan State University! ! Single-Particle Structure and Reactions Session! ATLAS Users Meeting! May 15, 2014 PROTOTYPE AT-TPC e - e - e - e - e - e - e - e - e - e - e - e - D. Suzuki et al., NIM A 660, 64 (2011) PROTOTYPE AT-TPC e - e - e - e - e - e - e - e - e - e - e - e - active-target volume D. Suzuki et al., NIM A 660, 64 (2011) PROTOTYPE AT-TPC e - e - e - e - e - e - e - e - e - e - e -

  4. ANL2014-JMA.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meeting Heavy-Ion Induced Transfer Reactions using Particle-γ Coincidence Spectroscopy (Sub Coulomb) J.M. Allmond JINPA, Oak Ridge National Laboratory, Oak Ridge, TN 37831 Double-Magic Radioactive 132 Sn Beam and Semi-Magic Radioactive 134 Te, 136 Xe Beam Double-Magic Stable 208 Pb Beam for Comparison Example One-Neutron Transfer Studies Allmond et al., PRC Rapid (2012) Allmond et al., PRL (2014) Inverse Kinematics: ( 9 Be, 8 Be->2α) Energetic/detectable target-like recoils predominately at

  5. ANL's Map and Data Browser

    Energy Science and Technology Software Center (OSTI)

    1998-07-13

    The MaD browser is a web browser Java applet developed to display and interact with vector graphic (map) objects, relational database tables, and other data sources. It was designed for use in remedial action projects to quickly and widely disseminate sampling results but is generally applicable to many other mapping situations. Its primary value is its simplicity and general availability.

  6. LSM-YSZ Cathodes with Reaction-Infiltrated Nanoparticles

    SciTech Connect (OSTI)

    Lu, Chun; Sholklapper, Tal Z.; Jacobson, Craig P.; Visco, StevenJ.; De Jonghe, Lutgard C.

    2006-01-31

    To improve the LSM-YSZ cathode performance of intermediate temperature solid oxide fuel cells (SOFCs), Sm0.6Sr0.4CoO3-sigma (SSC) perovskite nanoparticles are incorporated into the cathodes by a reaction-infiltration process. The SSC particles are {approx}20 to 80nm in diameter, and intimately adhere to the pore walls of the preformed LSM-YSZ cathodes. The SSC particles dramatically enhance single-cell performance with a 97 percent H2+3 percent H2O fuel, between 600 C and 800 C. Consideration of a simplified TPB (triple phase boundary) reaction geometry indicates that the enhancement may be attributed to the high electrocatalytic activity of SSC for electrochemical reduction of oxygen in a region that can be located a small distance away from the strict triple phase boundaries. The implication of this work for developing high-performance electrodes is also discussed.

  7. Carbonaceous cathode with enhanced wettability for aluminum production

    DOE Patents [OSTI]

    Keller, Rudolf; Gatty, David G.; Barca, Brian J.

    2003-09-09

    A method of preparing carbonaceous blocks or bodies for use in a cathode in an electrolytic cell for producing aluminum wherein the cell contains an electrolyte and has molten aluminum contacting the cathode, the cathode having improved wettability with molten aluminum. The method comprises the steps of providing a carbonaceous block and a boron oxide containing melt. The carbonaceous block is immersed in the melt and pressure is applied to the melt to impregnate the melt into pores in the block. Thereafter, the carbonaceous block is withdrawn from the melt, the block having boron oxide containing melt intruded into pores therein, the boron oxide capable of reacting with a source of titanium or zirconium or like metal to form titanium or zirconium diboride during heatup or operation of said cell.

  8. Process system and method for fabricating submicron field emission cathodes

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Hayes, Jeffrey P. (Ripon, CA)

    1998-01-01

    A process method and system for making field emission cathodes exists. The deposition source divergence is controlled to produce field emission cathodes with height-to-base aspect ratios that are uniform over large substrate surface areas while using very short source-to-substrate distances. The rate of hole closure is controlled from the cone source. The substrate surface is coated in well defined increments. The deposition source is apertured to coat pixel areas on the substrate. The entire substrate is coated using a manipulator to incrementally move the whole substrate surface past the deposition source. Either collimated sputtering or evaporative deposition sources can be used. The position of the aperture and its size and shape are used to control the field emission cathode size and shape.

  9. Characteristic of a triple-cathode vacuum arc plasma source

    SciTech Connect (OSTI)

    Xiang, W.; Li, M.; Chen, L.

    2012-02-15

    In order to generate a better ion beam, a triple-cathode vacuum arc plasma source has been developed. Three plasma generators in the vacuum arc plasma source are equally located on a circle. Each generator initiated by means of a high-voltage breakdown between the cathode and the anode could be operated separately or simultaneously. The arc plasma expands from the cathode spot region in vacuum. In order to study the behaviors of expanding plasma plume generated in the vacuum arc plasma source, a Langmuir probe array is employed to measure the saturated ion current of the vacuum arc plasma source. The time-dependence profiles of the saturated current density of the triple vacuum arc plasma source operated separately and simultaneously are given. Furthermore, the plasma characteristic of this vacuum arc plasma source is also presented in the paper.

  10. Rotating dipole and quadrupole field for a multiple cathode system

    SciTech Connect (OSTI)

    Chang, X.; Ben-Zvi, I.; Kewisch, J.; Litvinenko, V.; Meng, W.; Pikin, A.; Ptitsyn, V.; Rao, T.; Sheehy, B.; Skarita, J.; Wang, E.; Wu, Q.; Xin, T.

    2011-03-28

    A multiple cathode system has been designed to provide the high average current polarized electron bunches for the future electron-ion collider eRHIC [1]. One of the key research topics in this design is the technique to generate a combined dipole and quadrupole rotating field at high frequency (700 kHz). This type of field is necessary for combining bunches from different cathodes to the same axis with minimum emittance growth. Our simulations and the prototype test results to achieve this will be presented. The future eRHIC project, next upgrade of EHIC, will be the first electron-heavy ion collider in the world. For polarized-electron and polarized proton collisions, it requires a polarized electron source with high average current ({approx}50 mA), short bunch ({approx}3 mm), emittance of about 20 {micro}m and energy spread of {approx}1% at 10 MeV. The state-of-art polarized electron cathode can generate average current of about more than 1 mA, but much less than 50 mA. The current is limited by the quantum efficiency, lifetime, space charge and ultra-high vacuum requirement of the polarized cathode. A possible approach to achieve the 50 mA beam is to employ multiple cathodes, such as 20 cathodes, and combine the multiple bunched beams from cathodes to the same axis. We name it as 'Gatling gun' because its operations bear similarity to a multi-barrel Gatling gun. The electron spin direction is not affected by electric field but will follow to the direction of the magnetic bending. This requires that, to preserve the spin polarization from cathode, the fixed bending field after the solenoid and the rotating bending field in combiner must be either a pair of electric bendings or a pair of magnetic bendings. We choose the scheme with a pair of magnetic bendings because it is much easier than the scheme with a pair of electric bendings at our 200 keV electron energy level.

  11. Cathode preparation method for molten carbonate fuel cell

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Sim, James W. (Evergreen Park, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1988-01-01

    A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

  12. Modeling electron emission and surface effects from diamond cathodes

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Modeling electron emission and surface effects from diamond cathodes Citation Details In-Document Search Title: Modeling electron emission and surface effects from diamond cathodes Authors: Dimitrov D. ; Ben-Zvi I. ; Cary, J. R. ; Smithe, D. ; Zhou, C. ; Rao, T. ; Smedley, J. ; Wang, E. Publication Date: 2015-05-03 OSTI Identifier: 1228864 Report Number(s): BNL--108604-2015-CP R&D Project: KBCH139; KB0202011 DOE Contract Number: SC00112704

  13. Axis-1 diode simulations I: standard 2-inch cathode

    SciTech Connect (OSTI)

    Ekdahl, Carl [Los Alamos National Laboratory

    2011-01-11

    The standard configuration of the DARHT Axis-I diode features a 5.08-cm diameter velvet emitter mounted in the flat surface of the cathode shroud. The surface of the velvet is slightly recessed {approx}2.5 mm. This configuration produces a 1.75 kA beam when a 3.8-MV pulse is applied to the anode-cathode (AK) gap. This note addresses some of the physics of this diode through the use of finite-element simulations.

  14. Cathodic ALD V2O5 thin films for high-rate electrochemical energy...

    Office of Scientific and Technical Information (OSTI)

    Cathodic ALD V2O5 thin films for high-rate electrochemical energy storage Citation Details In-Document Search Title: Cathodic ALD V2O5 thin films for high-rate electrochemical ...

  15. Testing a GaAs cathode in SRF gun

    SciTech Connect (OSTI)

    Wang, E.; Kewisch, J.; Ben-Zvi, I.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

    2011-03-28

    RF electron guns with a strained superlattice GaAs cathode are expected to generate polarized electron beams of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface and lower cathode temperature. We plan to install a bulk GaAs:Cs in a SRF gun to evaluate the performance of both the gun and the cathode in this environment. The status of this project is: In our 1.3 GHz 1/2 cell SRF gun, the vacuum can be maintained at nearly 10{sup -12} Torr because of cryo-pumping at 2K. With conventional activation of bulk GaAs, we obtained a QE of 10% at 532 nm, with lifetime of more than 3 days in the preparation chamber and have shown that it can survive in transport from the preparation chamber to the gun. The beam line has been assembled and we are exploring the best conditions for baking the cathode under vacuum. We report here the progress of our test of the GaAs cathode in the SRF gun. Future particle accelerators, such as eRHIC and the ILC require high-brightness, high-current polarized electrons. Strained superlattice GaAs:Cs has been shown to be an efficient cathode for producing polarized electrons. Activation of GaAs with Cs,O(F) lowers the electron affinity and makes it energetically possible for all the electrons, excited into the conduction band that drift or diffuse to the emission surface, to escape into the vacuum. Presently, all operating polarized electron sources, such as the CEBAF, are DC guns. In these devices, the excellent ultra-high vacuum extends the lifetime of the cathode. However, the low field gradient on the photocathode's emission surface of the DC guns limits the beam quality. The higher accelerating gradients, possible in the RF guns, generate a far better beam. Until recently, most RF guns operated at room temperature, limiting the vacuum to {approx}10{sup -9} Torr. This destroys the GaAs's NEA surface. The SRF guns combine the excellent vacuum conditions of DC guns and the high accelerating gradient of the RF guns, potentially offering a long lived cathode with very low emittance. Testing this concept requires preparation of the cathode, transportation to the SRF gun and evaluation of the performance of the cathode and the gun at cryogenic temperatures. In our work at BNL, we successfully activated the bulk GaAs in the preparation chamber. The highest quantum efficient was 10% at 532 nm that fell to 0.5% after 100 hours. We explored three different ways to activate the GaAs. We verified that the GaAs photocathode remains stable for 30 hours in a 10{sup -11} Torr vacuum. Passing the photocathode through the low 10{sup -9} Torr transfer section in several seconds caused the QE to drop to 0.8%. The photocathode with 0.8% QE can be tested for the SRF gun. The gun and beam pipe were prepared and assembled. After baking at 200 C baking, the vacuum of the gun and beam pipe can sustain a low 10{sup -11} Torr at room temperature. The final test to extract electrons from the gun is ongoing. In this paper, we discuss our progress with this SRF gun and the results of the photocathode in preparation chamber and in magnet transfer line.

  16. Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating

    SciTech Connect (OSTI)

    Feng Jin

    2009-01-07

    This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

  17. Advanced Gasificatioin

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Gasification Research Team Members Key Contacts Advanced Gasification Carbon feedstock gasification is a promising pathway for high-efficiency, low-pollutant power generation and chemical production. The inability, however, to meet a number of operational goals could create roadblocks to widespread acceptance and commercialization of advanced gasification technologies. We must, for example, achieve gasifier online availability of 85-95 percent in utility applications, and 95 percent for

  18. Corrosion performance of advanced structural materials in sodium.

    SciTech Connect (OSTI)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L.

    2012-05-16

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

  19. A reduced temperature solid oxide fuel cell with three-dimensionally ordered macroporous cathode

    SciTech Connect (OSTI)

    Liang, B.; Suzuki, T.; Hamamoto, K.; Yamaguchi, T.; Sumi, H.; Fujishiro, Y.; Ingram, B. J.; Carter, J. D.

    2012-01-01

    Three-dimensionally ordered macroporous cathode was fabricated for a zirconia based micro-tubular solid oxide fuel cells (SOFCs). Three different cathodes (cathode A, no pore former; cathode B, with pore former (1.5 {micro}m in diameter); cathode C, with pore former (0.8 {micro}m in diameter)) were compared to investigate how the microstructure of it affected the cell performance at various operating temperatures. Micro-sized pores were well distributed within cathode B and C. The total porosity of cathode A is 35%, while it respectively reached 42 and 50% for cathodes B and C. At the same time, the specific surface area of them was 28.8 and 52.0% larger than that of the cathode A. As a result, the peak power density of the zirconia based cell, with cathode C, was 0.25 and 0.56 W cm{sup -2} at 550 and 600 C, while the respective value was just 0.11 and 0.30 W cm{sup -2} for the cell with cathode A. Thus, optimizing microstructure of cathode should be one of the best approaches for lowering the operating temperature for SOFCs.

  20. Evaluation of Li2MnSiO4 Cathode | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_18_belharouak.pdf More Documents & Publications Search for High Energy Density Cathode Materials Evaluation of Li2MnSiO4 Cathode Vehicle Technologies Office Merit Review 2014: High-Capacity Polyanion Cathodes

  1. Individually addressable cathodes with integrated focusing stack or detectors

    DOE Patents [OSTI]

    Thomas, Clarence E.; Baylor, Larry R.; Voelkl, Edgar; Simpson, Michael L.; Paulus, Michael J.; Lowndes, Douglas; Whealton, John; Whitson, John C.; Wilgen, John B.

    2005-07-12

    Systems and method are described for addressable field emission array (AFEA) chips. A plurality of individually addressable cathodes are integrated with an electrostatic focusing stack and/or a plurality of detectors on the addressable field emission array. The systems and methods provide advantages including the avoidance of space-charge blow-up.

  2. Rigid indented cylindrical cathode for X-ray tube

    DOE Patents [OSTI]

    Hudgens, Claude R. (Dayton, OH)

    1985-01-01

    A cathode assembly for a vacuum tube includes a wire filament, a straight bular anode parallel to and surrounding the wire filament, and insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

  3. Rigid indented cylindrical cathode for x-ray tube

    DOE Patents [OSTI]

    Hudgens, C.R.

    1983-06-03

    A cathode assembly for a vacuum tube includes a wire filament, a straight tubular anode parallel to and surrounding the wire filament, insulating spacers for rigidly fastening the filament with respect to the anode, and with one side of the anode indented or flattened such that only one portion of the anode is heated to emitting temperatures by the filament.

  4. Investigating Microbial Fuel Cell Bioanode Performance Under Different Cathode Conditions

    SciTech Connect (OSTI)

    Borole, Abhijeet P; Hamilton, Choo Yieng; Aaron, D; Tsouris, Costas

    2009-01-01

    A compact, three-in-one, flow-through, porous, electrode design with minimal electrode spacing and minimal dead volume was implemented to develop a microbial fuel cell (MFC) with improved anode performance. A biofilm-dominated anode consortium enriched under a multimode, continuous-flow regime was used. The increase in the power density of the MFC was investigated by changing the cathode (type, as well as catholyte strength) to determine whether anode was limiting. The power density obtained with an air-breathing cathode was 56 W/m3 of net anode volume (590 mW/m2) and 203 W/m3 (2160 mW/m2) with a 50-mM ferricyanide- based cathode. Increasing the ferricyanide concentration and ionic strength further increased the power density, reaching 304 W/m3 (3220 mW/m2, with 200 mM ferricyanide and 200 mM buffer concentration). The increasing trend in the power density indicated that the anode was not limiting and that higher power densities could be obtained using cathodes capable of higher rates of oxidation. The internal solution resistance for the MFC was 5 6 X, which supported the improved performance of the anode design. A new parameter defined as the ratio of projected surface area to total anode volume is suggested as a design parameter to relate volumetric and area-based power densities and to enable comparison of various MFC configurations.

  5. Design and Evaluation of Novel High Capacity Cathode Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 17_johnson_2011_p.pdf More Documents & Publications Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells Lithium Source For High Performance Li-ion Cells

  6. Methanol-Tolerant Cathode Catalyst Composite For Direct Methanol Fuel Cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-03-21

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of a platinum-chromium alloy so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  7. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    DOE Patents [OSTI]

    Zhu, Yimin (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

    2006-09-05

    A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant reduction catalyst adjacent the cathode electrode and the membrane, comprises an oxidant reduction catalyst layer of Pt.sub.3Cr/C so that oxidation at the cathode of methanol that crosses from the anode through the membrane to the cathode is reduced with a concomitant increase of net electrical potential at the cathode electrode.

  8. Energy Department Announces New Investments in Advanced Nuclear...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Westinghouse Electric Company partnering with ANL and the University of Pittsburg-- Development of thermo-acoustic sensors for Sodium-cooled Fast Reactors (SFR) Find more ...

  9. 2014 Advanced Grid Modeling Peer Review Presentations - Day Two...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Two Morning Session The Office of Electricity Delivery and Energy Reliability held ... ANL PDF icon Chance-constrained OPF and Unit Commitment -- Incorporating High-Performance ...

  10. Joule heat generation in thermionic cathodes of high-pressure arc discharges

    SciTech Connect (OSTI)

    Benilov, M. S.; Cunha, M. D.

    2013-02-14

    The nonlinear surface heating model of plasma-cathode interaction in high-pressure arcs is extended to take into account the Joule effect inside the cathode body. Calculation results are given for different modes of current transfer to tungsten cathodes of different configurations in argon plasmas of atmospheric or higher pressures. Special attention is paid to analysis of energy balances of the cathode and the near-cathode plasma layer. In all the cases, the variation of potential inside the cathode is much smaller than the near-cathode voltage drop. However, this variation can be comparable to the volt equivalent of the energy flux from the plasma to the cathode and then the Joule effect is essential. Such is the case of the diffuse and mixed modes on rod cathodes at high currents, where the Joule heating causes a dramatic change of thermal and electrical regimes of the cathode. The Joule heating has virtually no effect over characteristics of spots on rod and infinite planar cathodes.

  11. Modular cathode assemblies and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L

    2014-12-02

    Modular cathode assemblies are useable in electrolytic reduction systems and include a basket through which fluid electrolyte may pass and exchange charge with a material to be reduced in the basket. The basket can be divided into upper and lower sections to provide entry for the material. Example embodiment cathode assemblies may have any shape to permit modular placement at any position in reduction systems. Modular cathode assemblies include a cathode plate in the basket, to which unique and opposite electrical power may be supplied. Example embodiment modular cathode assemblies may have standardized electrical connectors. Modular cathode assemblies may be supported by a top plate of an electrolytic reduction system. Electrolytic oxide reduction systems are operated by positioning modular cathode and anode assemblies at desired positions, placing a material in the basket, and charging the modular assemblies to reduce the metal oxide.

  12. Anode-cathode power distribution systems and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

    2014-01-28

    Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

  13. Advanced Combustion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Combustion Fact Sheet Key Contacts Advanced Combustion Background Conventional coal-fired power plants utilize steam turbines to generate electricity, which operate at efficiencies of 35-37 percent. Operation at higher temperatures and pressures can lead to higher efficiencies. Oxy-combustion comes with an efficiency loss, so it will actually increase the amount of CO2 to be captured. But without so much N2 in the flue gas, it will be easier and perhaps more efficient to capture,

  14. Higher harmonics generation in relativistic electron beam with virtual cathode

    SciTech Connect (OSTI)

    Kurkin, S. A. Badarin, A. A.; Koronovskii, A. A.; Hramov, A. E.

    2014-09-15

    The study of the microwave generation regimes with intense higher harmonics taking place in a high-power vircator consisting of a relativistic electron beam with a virtual cathode has been made. The characteristics of these regimes, in particular, the typical spectra and their variations with the change of the system parameters (beam current, the induction of external magnetic field) as well as physical processes occurring in the system have been analyzed by means of 3D electromagnetic simulation. It has been shown that the system under study demonstrates the tendency to the sufficient growth of the amplitudes of higher harmonics in the spectrum of current oscillations in the VC region with the increase of beam current. The obtained results allow us to consider virtual cathode oscillators as promising high power mmw-to-THz sources.

  15. Electroconvection under injection from cathode and heating from above

    SciTech Connect (OSTI)

    Mordvinov, A. N.; Smorodin, B. L.

    2012-05-15

    We study the electroconvection that appears in a nonuniformly heated, poorly conducting liquid in a parallel-plate horizontal capacitor due to the action of an external static electric field on the charge injected from the cathode. It is shown that the heating of the layer from above prevents steady-state convection and that, unlike the isothermal situation, electroconvection can appear in the oscillatory manner as a result of direct Hopf bifurcation. The effect of the heating intensity, the intensity of charge injection from the cathode, and the charge mobility on the thresholds of oscillatory and monotonic electroconvection is analyzed and the characteristic scales and frequencies of critical perturbations are determined. The nonlinear wave and steady-state regimes of the 2D convective structures formed in the poorly conducting liquid under the action of thermogravitational and injection mechanisms of convection are analyzed. The domains of existence of standing, traveling, and modulated waves are determined.

  16. Limitations in using pulsed rectifiers for well casing cathodic protection

    SciTech Connect (OSTI)

    Dabkowski, J. [Electro Sciences, Inc., Crystal Lake, IL (United States)

    1995-11-01

    Due to earth propagation losses the rectifier current pulses suffer considerable waveform deterioration as the penetration depth increases. Hence, cathodic protection benefits attributable to the use of a pulsed rectifier will not be attainable below a certain depth which is a function of the pulse characteristics and the soil resistivity. In this paper a hypothetical 3,000 meter length well casing is modeled as a distributed lossy electrical transmission line. It is shown that below a depth of 300 to 500 meters, the higher frequency content of the pulse is severely attenuated. The cathodic protection process at these and increased depths, therefore, will not differ significantly from that obtained with a non-pulsed dc rectifier.

  17. Vehicle Technologies Office Merit Review 2014: Process Development and Scale-up of Advanced Cathode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about process development and scale...

  18. Vehicle Technologies Office Merit Review 2015: Design and Synthesis of Advanced High-Energy Cathode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Lawrence Berkley National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about design...

  19. Vehicle Technologies Office Merit Review 2014: Design and Synthesis of Advanced High-Energy Cathode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Lawrence Berkeley National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the...

  20. Negative ion source with hollow cathode discharge plasma

    DOE Patents [OSTI]

    Hershcovitch, Ady (Mt. Sinai, NY); Prelec, Krsto (Setauket, NY)

    1983-01-01

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  1. Negative ion source with hollow cathode discharge plasma

    DOE Patents [OSTI]

    Hershcovitch, A.; Prelec, K.

    1980-12-12

    A negative ion source of the type where negative ions are formed by bombarding a low-work-function surface with positive ions and neutral particles from a plasma, wherein a highly ionized plasma is injected into an anode space containing the low-work-function surface is described. The plasma is formed by hollow cathode discharge and injected into the anode space along the magnetic field lines. Preferably, the negative ion source is of the magnetron type.

  2. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  3. John B. Goodenough, Cathode Materials, and Rechargeable Lithium-ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries John B. Goodenough, Cathode Materials, and Rechargeable Lithium-ion Batteries Resources with Additional Information * Awards * Patents John B. Goodenough Photo Credit: Courtesy of The University of Texas at Austin Cockrell School of Engineering On September 17, 2009, U.S. Energy Secretary Steven Chu named John B. Goodenough as a winner of the Enrico Fermi Award ' in recognition for his lasting contributions to materials science and technology, especially the science underlying

  4. LiCoO2 cathode charging simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cathode charging simulation - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  5. Design and Evaluation of Novel High Capacity Cathode Materials | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es017_johnson_2010_o.pdf More Documents & Publications Lithium Source For High Performance Li-ion Cells Design and Evaluation of Novel High Capacity Cathode Materials Lithium Source For High Performance Li-ion Cells

  6. Additive for iron disulfide cathodes used in thermal batteries

    DOE Patents [OSTI]

    Armijo, James R. (Albuquerque, NM); Searcy, Jimmie Q. (Albuquerque, NM)

    1983-01-01

    The invention comprises thermal batteries employing an FeS.sub.2 depolarizer, i.e. cathode material, and the depolarizer itself. A minor amount of CaSi.sub.2 preferably, 1-3% by weight is provided as an additive in the FeS.sub.2 depolarizer to eliminate the voltage transient (spike) which normally occurs upon activation of batteries of this type. The amount of FeS.sub.2 by weight generally comprises 64-90%.

  7. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene (Coram, NY)

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  8. An interchangeable-cathode vacuum arc plasma source

    SciTech Connect (OSTI)

    Olson, David K.; Peterson, Bryan G.; Hart, Grant W.

    2010-01-15

    A simplified vacuum arc design [based on metal vapor vacuum arc (MeVVA) concepts] is employed as a plasma source for a study of a {sup 7}Be non-neutral plasma. The design includes a mechanism for interchanging the cathode source. Testing of the plasma source showed that it is capable of producing on the order of 10{sup 12} charges at confinable energies using a boron-carbide disk as the cathode target. The design is simplified from typical designs for lower energy and lower density applications by using only the trigger spark rather than the full vacuum arc in high current ion beam designs. The interchangeability of the cathode design gives the source the ability to replace only the source sample, simplifying use of radioactive materials in the plasma source. The sample can also be replaced with a completely different conductive material. The design can be easily modified for use in other plasma confinement or full MeVVA applications.

  9. Process for Low Cost Domestic Production of LIB Cathode Materials

    SciTech Connect (OSTI)

    Thurston, Anthony

    2012-10-31

    The objective of the research was to determine the best low cost method for the large scale production of the Nickel-Cobalt-Manganese (NCM) layered cathode materials. The research and development focused on scaling up the licensed technology from Argonne National Laboratory in BASFs battery material pilot plant in Beachwood Ohio. Since BASF did not have experience with the large scale production of the NCM cathode materials there was a significant amount of development that was needed to support BASFs already existing research program. During the three year period BASF was able to develop and validate production processes for the NCM 111, 523 and 424 materials as well as begin development of the High Energy NCM. BASF also used this time period to provide free cathode material samples to numerous manufactures, OEMs and research companies in order to validate the ma-terials. The success of the project can be demonstrated by the construction of the production plant in Elyria Ohio and the successful operation of that facility. The benefit of the project to the public will begin to be apparent as soon as material from the production plant is being used in electric vehicles.

  10. Ion velocities in a micro-cathode arc thruster

    SciTech Connect (OSTI)

    Zhuang Taisen; Shashurin, Alexey; Keidar, Michael; Beilis, Isak

    2012-06-15

    Ion velocities in the plasma jet generated by the micro-cathode arc thruster are studied by means of time-of-flight method using enhanced ion detection system (EIDS). The EIDS triggers perturbations (spikes) on arc current waveform, and the larger current in the spike generates denser plasma bunches propagating along with the mainstream plasma. The EIDS utilizes double electrostatic probes rather than single probes. The average Ti ion velocity is measured to be around 2 Multiplication-Sign 10{sup 4} m/s without a magnetic field. It was found that the application of a magnetic field does not change ion velocities in the interelectrode region while leads to ion acceleration in the free expanding plasma plume by a factor of about 2. Ion velocities of about 3.5 Multiplication-Sign 10{sup 4} m/s were detected for the magnetic field of about 300 mT at distance of about 100-200 mm from the cathode. It is proposed that plasma is accelerated due to Lorentz force. The average thrust is calculated using the ion velocity measurements and the cathode mass consumption rate, and its increase with the magnetic field is demonstrated.

  11. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Russell, James H.; Bullard, Sophie J.; Cramer, Stephen D.; Collins, W.K.; Bennett, J.E.; Laylor, H.M.

    2000-11-01

    Use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete was examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using lithium bromide (LiBr) and lithium nitrate (LiNO{sub 3}) as humectants in galvanic cathodic protection (GCP) and impressed current cathodic protection (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone, zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  12. Apparatus and method for treating a cathode material provided on a thin-film substrate

    DOE Patents [OSTI]

    Hanson, Eric J.; Kooyer, Richard L.

    2001-01-01

    An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

  13. Apparatus and method for treating a cathode material provided on a thin-film substrate

    DOE Patents [OSTI]

    Hanson, Eric J.; Kooyer, Richard L.

    2003-01-01

    An apparatus and method for treating a cathode material provided on a surface of a continuous thin-film substrate and a treated thin-film cathode having increased smoothness are disclosed. A web of untreated cathode material is moved between a feed mechanism and a take-up mechanism, and passed through a treatment station. The web of cathode material typically includes areas having surface defects, such as prominences extending from the surface of the cathode material. The surface of the cathode material is treated with an abrasive material to reduce the height of the prominences so as to increase an 85 degree gloss value of the cathode material surface by at least approximately 10. The web of cathode material may be subjected to a subsequent abrasive treatment at the same or other treatment station. Burnishing or lapping film is employed at a treatment station to process the cathode material. An abrasive roller may alternatively be used to process the web of cathode material. The apparatus and method of the present invention may also be employed to treat the surface of a lithium anode foil so as to cleanse and reduce the roughness of the anode foil surface.

  14. Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Gordon, Keith C. (Berkeley, CA); Kippenham, Dean O. (Castro Valley, CA); Purgalis, Peter (San Francisco, CA); Moussa, David (San Francisco, CA); Williams, Malcom D. (Danville, CA); Wilde, Stephen B. (Pleasant Hill, CA); West, Mark W. (Albany, CA)

    1989-01-01

    A large area directly heated lanthanum hexaboride (LaB.sub.6) cathode system (10) is disclosed. The system comprises a LaB.sub.6 cathode element (11) generally circular in shape about a central axis. The cathode element (11) has a head (21) with an upper substantially planar emission surface (23), and a lower downwardly and an intermediate body portion (26) which diminishes in cross-section from the head (21) towards the base (22) of the cathode element (11). A central rod (14) is connected to the base (22) of the cathode element (11) and extends along the central axis. Plural upstanding spring fingers (37) are urged against an outer peripheral contact surface (24) of the head end (21) to provide a mechanical and electrical connection to the cathode element (11).

  15. Large area directly heated lanthanum hexaboride cathode structure having predetermined emission profile

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Gordon, K.C.; Kippenhan, D.O.; Purgalis, P.; Moussa, D.; Williams, M.D.; Wilde, S.B.; West, M.W.

    1987-10-16

    A large area directly heated lanthanum hexaboride (LaB/sub 6/) cathode system is disclosed. The system comprises a LaB/sub 6/ cathode element generally circular in shape about a central axis. The cathode element has a head with an upper substantially planar emission surface, and a lower downwardly and an intermediate body portion which diminishes in cross-section from the head towards the base of the cathode element. A central rod is connected to the base of the cathode element and extends along the central axis. Plural upstanding spring fingers are urged against an outer peripheral contact surface of the head end to provide a mechanical and electrical connection to the cathode element. 7 figs

  16. Note: Design and development of improved indirectly heated cathode based strip electron gun

    SciTech Connect (OSTI)

    Maiti, Namita; Patil, D. S.; Dasgupta, K.; Bade, Abhijeet; Tembhare, G. U.

    2015-02-15

    An improved design of indirectly heated solid cathode based electron gun (200 kW, 45 kV, 270° bent strip type electron gun) has been presented. The solid cathode is made of thoriated tungsten, which acts as an improved source of electron at lower temperature. So, high power operation is possible without affecting structural integrity of the electron gun. The design issues are addressed based on the uniformity of temperature on the solid cathode and the single long filament based design. The design approach consists of simulation followed by extensive experimentation. In the design, the effort has been put to tailor the non-uniformity of the heat flux from the filament to the solid cathode to obtain better uniformity of temperature on the solid cathode. Trial beam experiments have been carried out and it is seen that the modified design achieves one to one correspondence of the solid cathode length and the electron beam length.

  17. Characterization of Atomic and Electronic Structures of Electrochemically Active SOFC Cathode Surfaces

    SciTech Connect (OSTI)

    Kevin Blinn; Yongman Choi; Meilin Liu

    2009-08-11

    The objective of this project is to gain a fundamental understanding of the oxygen-reduction mechanism on mixed conducting cathode materials by means of quantum-chemical calculations coupled with direct experimental measurements, such as vibrational spectroscopy. We have made progress in the elucidation of the mechanisms of oxygen reduction of perovkite-type cathode materials for SOFCs using these quantum chemical calculations. We established computational framework for predicting properties such as oxygen diffusivity and reaction rate constants for adsorption, incorporation, and TPB reactions, and formulated predictions for LSM- and LSC-based cathode materials. We have also further developed Raman spectroscopy as well as SERS as a characterization tool for SOFC cathode materials. Raman spectroscopy was used to detect chemical changes in the cathode from operation conditions, and SERS was used to probe for pertinent adsorbed species in oxygen reduction. However, much work on the subject of unraveling oxygen reduction for SOFC cathodes remains to be done.

  18. Composite Organic Radical - Inorganic Hybrid Cathode for Lithium-ion Batteries

    SciTech Connect (OSTI)

    Huang, Qian; Cosimbescu, Lelia; Koech, Phillip K.; Choi, Daiwon; Lemmon, John P.

    2013-07-01

    A new organic radical inorganic hybrid cathode comprised of PTMA/LiFePO4 composite system is developed and reported for the first time. The hybrid cathodes demonstrate high pulse power capability resulting in a significant improvement over the pure PTMA or LiFePO4 cathode which is very promising for transportation and other high pulse power applications that require long cycle life and lower cost.

  19. Material and Energy Flows in the Production of Cathode and Anode Materials

    Office of Scientific and Technical Information (OSTI)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect Technical Report: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries The Greenhouse gases, Regulated Emissions and Energy use in Transportation (GREET) model has been expanded to include four new cathode materials that can be used in the

  20. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials | Department of Energy Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es161_burrell_2012_o.pdf More Documents & Publications Studies on Lithium Manganese Rich MNC Composite Cathodes Vehicle Technologies Office Merit Review 2014:

  1. Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Effect of an Ultrathin Coating on Stabilizing Li-ion Battery Cathodes Sunday, January 31, 2016 Improvements in the high-voltage cycling stability of lithium ion battery cathode materials are needed to enable the wide-spread adoption of renewable energy technologies such as electric vehicles. One cathode material which exhibits significant advantages over the commonly-used commercial material LiCoO2 in terms of higher capacity, increased thermal

  2. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect (OSTI)

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  3. Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ohio | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt008_es_dicarlo_2011_p.pdf More Documents & Publications Process for Low Cost Domestic Production of LIB Cathode Materials Process for Low Cost Domestic Production of LIB Cathode Materials Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio

  4. Battery Cathodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center at Cornell Cathodes Figure 1. Acceleration of DMcT Oxidation and Reduction at PEDOT-Modified Electrode Research on new cathodes for lithium-ion batteries has long been directed towards crystalline metal oxide-based materials, with charge stored by lithium insertion into the material matrix. Research in the Energy Frontier Research Center is pursuing an alternate approach to battery cathodes based on the reaction of lithium with naturally abundant, light-weight, and amorphous organic

  5. Surface topography of a palladium cathode after electrolysis in heavy water

    SciTech Connect (OSTI)

    Silver, D.S. ); Dash, J.; Keefe, P.S. )

    1993-12-01

    Electrolysis was performed with a palladium cathode and an electrolyte containing both hydrogen and deuterium ions. The cathode bends toward the anode during this process. Examination of both the concave and the convex surfaces with the scanning electron microscope, scanning tunneling microscope, and atomic force microscope shows unusual surface characteristics. Rimmed craters with faceted crystals inside and multitextural surfaces were observed on an electrolyzed palladium cathode but not on palladium that has not been electrolyzed. 9 refs., 9 figs.

  6. Oxygen reduction and transportation mechanisms in solid oxide fuel cell cathodes

    SciTech Connect (OSTI)

    Li YH, Gemmen R, Liu XB

    2010-06-01

    In recent years, various models have been developed for describing the reaction mechanisms in solid oxide fuel cell (SOFC) especially for the cathode electrode. However, many fundamental issues regarding the transport of oxygen and electrode kinetics have not been fully understood. This review tried to summarize the present status of the SOFC cathode modeling efforts, and associated experimental approaches on this topic. In addition, unsolved problems and possible future research directions for SOFC cathode kinetics had been discussed

  7. Studies on High Voltage Lithium Rich MNC Composite Cathodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy High Voltage Lithium Rich MNC Composite Cathodes Studies on High Voltage Lithium Rich MNC Composite Cathodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es106_nanda_2012_p.pdf More Documents & Publications Studies on Lithium Manganese Rich MNC Composite Cathodes Vehicle Technologies Office Merit Review 2014: High Energy Lithium Batteries for PHEV Applications Vehicle Technologies Office Merit

  8. EERE Success Story-PNNL Advances Hydrogen-Fueled Vehicle Technologies |

    Office of Environmental Management (EM)

    Department of Energy PNNL Advances Hydrogen-Fueled Vehicle Technologies EERE Success Story-PNNL Advances Hydrogen-Fueled Vehicle Technologies July 26, 2013 - 12:00am Addthis Through multiple projects, Pacific Northwest National Laboratory (PNNL) is improving the performance and decreasing the cost of hydrogen fuel production and fuel cell technologies. PNNL's research is developing new materials-like a durable, high-performance cathode support-and improving the manufacturing processes by

  9. Array of virtual Frisch-grid CZT detectors with common cathode...

    Office of Scientific and Technical Information (OSTI)

    We optimized the geometry of the device and improved its spectral response. We found that ... CATHODES; ELECTRODES; ELECTRON LOSS; GEOMETRY; OPTICS; PERFORMANCE; SHIELDING; ...

  10. Array of virtual Frisch-grid CZT detectors with common cathode...

    Office of Scientific and Technical Information (OSTI)

    the device's performance. At the same time, this allowed corrections for electron loss by reading the cathode signals to obtain depth information. Authors: Bolotnikov, A.E. ;...

  11. Methods and apparatuses for making cathodes for high-temperature, rechargeable batteries

    DOE Patents [OSTI]

    Meinhardt, Kerry D; Sprenkle, Vincent L; Coffey, Gregory W

    2014-05-20

    The approaches for fabricating cathodes can be adapted to improve control over cathode composition and to better accommodate batteries of any shape and their assembly. For example, a first solid having an alkali metal halide, a second solid having a transition metal, and a third solid having an alkali metal aluminum halide are combined into a mixture. The mixture can be heated in a vacuum to a temperature that is greater than or equal to the melting point of the third solid. When the third solid is substantially molten liquid, the mixture is compressed into a desired cathode shape and then cooled to solidify the mixture in the desired cathode shape.

  12. Simulations of multipacting in the cathode stalk and FPC of 112 MHz superconducting electron gun

    SciTech Connect (OSTI)

    Xin T.; Ben-Zvi, I.; Belomestnykh, S.; Chang, X.; Rao, T.; Skaritka, J.; Wu, Q.; Wang, E.; Liang, X.

    2012-05-20

    A 112 MHz superconducting quarter-wave resonator electron gun will be used as the injector of the Coherent Electron Cooling (CEC) proof-of-principle experiment at BNL. Furthermore, this electron gun can be used for testing of the performance of various high quantum efficiency photocathodes. In a previous paper, we presented the design of the cathode stalks and a Fundamental Power Coupler (FPC). In this paper we present updated designs of the cathode stalk and FPC. Multipacting in the cathode stalk and FPC was simulated using three different codes. All simulation results show no serious multipacting in the cathode stalk and FPC.

  13. Advanced Combustion

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2013-03-11

    The activity reported in this presentation is to provide the mechanical and physical property information needed to allow rational design, development and/or choice of alloys, manufacturing approaches, and environmental exposure and component life models to enable oxy-fuel combustion boilers to operate at Ultra-Supercritical (up to 650{degrees}C & between 22-30 MPa) and/or Advanced Ultra-Supercritical conditions (760{degrees}C & 35 MPa).

  14. Advanced Biofuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  15. Advanced Imaging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  16. Advanced Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  17. Miniature quadrupole mass spectrometer having a cold cathode ionization source

    DOE Patents [OSTI]

    Felter, Thomas E. (Livermore, CA)

    2002-01-01

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  18. A novel electron gun with an independently addressable cathode array.

    SciTech Connect (OSTI)

    Rudys, Joseph Matthew; Reed, Kim Warren; Pea, Gary Edward; Schneider, Larry X.

    2006-08-01

    The design of a novel electron gun with an array of independently addressable cathode elements is presented. Issues relating to operation in a 6.5 Tesla axial magnetic field are discussed. Simulations with the TriComp [1] electromagnetic field code that were used to determine the space charge limited tube characteristic and to model focusing of the electron beam in the magnetic field are reviewed. Foil heating and stress calculations are discussed. The results of CYLTRAN [2] simulations yielding the energy spectrum of the electron beam and the current transmitted through the foil window are presented.

  19. Pulsed rectifier limitations for well casing cathodic protection

    SciTech Connect (OSTI)

    Dabkowski, J. [Electro Sciences, Inc., Crystal Lake, IL (United States)

    1995-10-01

    Rectifier current pulses applied to deep well casings suffer considerable waveform deterioration as well depth increases. Cathodic protection (CP) attributed to the use of a pulsed rectifier will not be effective below a certain depth, which is a function of pulse characteristics and soil resistivity. A hypothetical 3,000-m length well casing is modeled as a distributed lossy electrical transmission line. Below 300- to 500-m depths, the higher frequency of the pulse is severely attenuated. Therefore, the CP process results at greater depths will not differ significantly from those obtained with a nonpulsed DC rectifier.

  20. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

    SciTech Connect (OSTI)

    Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

    2008-01-20

    Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

  1. Raman Microscopy of Lithium-Manganese-Rich Cathodes

    SciTech Connect (OSTI)

    Ruther, Rose E; Callender, Andrew F.; Zhou, Hui; Martha, Surendra; Nanda, Jagjit

    2014-01-01

    Lithium rich, manganese rich composites with general formula xLi2MnO3 (1-x)LiMO2 are promising candidates for high capacity and high voltage cathodes for lithium ion batteries. Lithium rich oxides crystallize as a nanocomposite of layered phases whose structure further evolves with electrochemical cycling. Raman spectroscopy is potentially a powerful tool to monitor the crystal chemistry and correlate phase changes with electrochemical behavior. While several groups have reported Raman spectra of lithium rich oxides, the data show considerable variability in terms of both the vibrational features observed and their interpretation. In this study Raman microscopy is used to investigate lithium-rich manganese-rich cathodes as a function of average charge and electrochemical cycling. LMR-NMC cycled at elevated temperature (60 C) has a modified crystal structure which may account for some of the observed increase in capacity. Contrary to some reports, no growth of a spinel phase is observed. However, analysis of the Raman spectra does indicate the structure of LMR-NMC deviates significantly from an ideal layered phase. The results also highlight the importance of using low laser power and large sample sizes to obtain consistent data sets.

  2. Raman Microscopy of Lithium-Manganese-Rich Cathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruther, Rose E; Callender, Andrew F.; Zhou, Hui; Martha, Surendra; Nanda, Jagjit

    2014-01-01

    Lithium rich, manganese rich composites with general formula xLi2MnO3 (1-x)LiMO2 are promising candidates for high capacity and high voltage cathodes for lithium ion batteries. Lithium rich oxides crystallize as a nanocomposite of layered phases whose structure further evolves with electrochemical cycling. Raman spectroscopy is potentially a powerful tool to monitor the crystal chemistry and correlate phase changes with electrochemical behavior. While several groups have reported Raman spectra of lithium rich oxides, the data show considerable variability in terms of both the vibrational features observed and their interpretation. In this study Raman microscopy is used to investigate lithium-rich manganese-rich cathodes asmore » a function of average charge and electrochemical cycling. LMR-NMC cycled at elevated temperature (60 C) has a modified crystal structure which may account for some of the observed increase in capacity. Contrary to some reports, no growth of a spinel phase is observed. However, analysis of the Raman spectra does indicate the structure of LMR-NMC deviates significantly from an ideal layered phase. The results also highlight the importance of using low laser power and large sample sizes to obtain consistent data sets.« less

  3. Methods for batch fabrication of cold cathode vacuum switch tubes

    DOE Patents [OSTI]

    Walker, Charles A. (Albuquerque, NM); Trowbridge, Frank R. (Albuquerque, NM)

    2011-05-10

    Methods are disclosed for batch fabrication of vacuum switch tubes that reduce manufacturing costs and improve tube to tube uniformity. The disclosed methods comprise creating a stacked assembly of layers containing a plurality of adjacently spaced switch tube sub-assemblies aligned and registered through common layers. The layers include trigger electrode layer, cathode layer including a metallic support/contact with graphite cathode inserts, trigger probe sub-assembly layer, ceramic (e.g. tube body) insulator layer, and metallic anode sub-assembly layer. Braze alloy layers are incorporated into the stacked assembly of layers, and can include active metal braze alloys or direct braze alloys, to eliminate costs associated with traditional metallization of the ceramic insulator layers. The entire stacked assembly is then heated to braze/join/bond the stack-up into a cohesive body, after which individual switch tubes are singulated by methods such as sawing. The inventive methods provide for simultaneously fabricating a plurality of devices as opposed to traditional methods that rely on skilled craftsman to essentially hand build individual devices.

  4. Measurement of groove features and dimensions of the vertical test cathode and the choke joint of the superconducting electron gun cavity of the Energy Recovery LINAC

    SciTech Connect (OSTI)

    Hammons, L.; Ke, M.

    2011-10-13

    A testing program for the superconducting electron gun cavity that has been designed for the Energy Recovery LINAC is being planned. The goal of the testing program is to characterize the RF properties of the gun cavity at superconducting temperatures and, in particular, to study multipacting that is suspected to be occurring in the choke joint of the cavity where the vertical test cathode is inserted. The testing program will seek to understand the nature and cause of this multipacting and attempt to eliminate it, if possible, by supplying sufficient voltage to the cavity. These efforts are motivated by the multipacting issues that have been observed in the processing of the fine-grain niobium gun cavity. This cavity, which is being processed at Thomas Jefferson National Laboratory for Brookhaven, has encountered multipacting at a gradient of approximately 3 MV/m and, to date, has resisted efforts at elimination. Because of this problem, a testing program is being established here in C-AD that will use the large-grain niobium gun cavity that currently resides at Brookhaven and has been used for room-temperature measurements. The large-grain and fine-cavities are identical in every aspect of construction and only differ in niobium grain size. Thus, it is believed that testing and conditioning of the large-grain cavity should yield important insights about the fine-grain cavity. One element of this testing program involves characterizing the physical features of the choke joint of the cavity where the multipacting is believed to be occurring and, in particular the grooves of the joint. The configuration of the cavity and the vertical test cathode is shown in Figure 1. In addition, it is important to characterize the groove of the vertical test cathode. The grooved nature of these two components was specifically designed to prevent multipacting. However, it is suspected that, because of the chemical processing that the fine-grain gun cavity underwent along with the vertical test cathode, the geometry of these grooves was altered, presenting the possibility that multipacting may, in fact, be occurring in this area and contributing to the low gradients that have been observed in the fine-grain cavity. Therefore, the Survey and Alignment group in C-AD engaged in measurements of the cavity joint, shown in Figure 2 and the cathode weldment, shown in Figure 3 for the purpose of characterizing the grooves in both the cavity and the vertical test cathode and comparing the dimensions of the cathode with those of the prints supplied by Advanced Energy Systems (AES), the original designer and manufacturer of both the test cathode and the electron gun cavity, in preparation to have a new one manufactured. The goal was to ensure that the articles as built matched the design prints in preparation for manufacturing a new vertical test cathode. This report describes the data collected by the Survey group in these efforts. The endeavor was challenging for the group given the millimeter-scale dimensions of the grooves and the requirement for high precision.

  5. Characterization of a Filtered High Current Pulsed Cathodic Vacuum Arc Plasma Source: Plasma Transport Analysis

    SciTech Connect (OSTI)

    Sangines, R.; Tarrant, R. N.; Bilek, M. M. M.; McKenzie, D. R.; Andruczyk, D.

    2008-03-19

    Studies of plasma behavior produced by a filtered high current pulsed cathodic vacuum arc system are reported. Titanium plasma is initiated from the cathode by surface flash over triggering at the centre of the cathode disk. The multiple arc spots move outwards due to their mutual repulsion and the arc current pulse is terminated as the arc spots reach the edge of the cathode disk. The plasma moves into a positively biased quarter-torus magnetic filter and is guided towards the substrate position located 150 mm beyond the filter exit. Electron density and plasma current measurements have been employed to analyze the transport of the plasma associated with different cathode currents, and its dependence on confining magnetic field and bias conditions. For a given cathode current, the optimum plasma transport to the substrate requires the right combination of the strength of the confining magnetic field and the magnetic filter positive bias. The optimum values of these two parameters were found to increase with increasing cathode current. Initially the optimum throughput of plasma increases more strongly than the arc current (roughly 1.5 times the increase in the current); however, at high cathode current regimes (2.4 kA) a significant change of the plasma behavior is seen and transport efficiency is reduced.

  6. On the mechanism of operation of a cathode spot cell in a vacuum arc

    SciTech Connect (OSTI)

    Mesyats, G. A.; Petrov, A. A.; Bochkarev, M. B.; Barengolts, S. A.

    2014-05-05

    The erosive structures formed on a tungsten cathode as a result of the motion of the cathode spot of a vacuum arc over the cathode surface have been examined. It has been found that the average mass of a cathode microprotrusion having the shape of a solidified jet is approximately equal to the mass of ions removed from the cathode within the lifetime of a cathode spot cell carrying a current of several amperes. The time of formation of a new liquid-metal jet under the action of the reactive force of the plasma ejected by the cathode spot is about 10?ns, which is comparable to the lifetime of a cell. The growth rate of a liquid-metal jet is ?10{sup 4}?cm/s. The geometric shape and size of a solidified jet are such that a new explosive emission center (spot cell) can be initiated within several nanoseconds during the interaction of the jet with the dense cathode plasma. This is the underlying mechanism of the self-sustained operation of a vacuum arc.

  7. Evaluation of Li2MnSiO4 Cathode | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es018_belharouak_2011_p.pdf More Documents & Publications Search for High Energy Density Cathode Materials Evaluation of Li2MnSiO4 Cathode Design of Safer High-Energy Density Materials for Lithium-Ion Cells

  8. Cathode for a hall-heroult type electrolytic cell for producing aluminum

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum from alumina in an electrolytic cell including using a cathode comprised of a base material having low electrical conductivity and wettable with molten aluminum to form a reaction layer having a high electrical conductivity on said base layer and a cathode bar extending from said reaction layer through said base material to conduct electrical current from said reaction layer.

  9. Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Franz, Robert; Polcik, Peter; Anders, André

    2015-06-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr2+ ions were dominating in Ar and N2 and Cr+ in O2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected tomore » collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.« less

  10. Element- and charge-state-resolved ion energies in the cathodic arc plasma from composite AlCr cathodes in argon, nitrogen and oxygen atmospheres

    SciTech Connect (OSTI)

    Franz, Robert; Polcik, Peter; Anders, Andr

    2015-06-01

    The energy distribution functions of ions in the cathodic arc plasma using composite AlCr cathodes were measured as a function of the background gas pressure in the range 0.5 to 3.5 Pa for different cathode compositions and gas atmospheres. The most abundant aluminium ions were Al+ regardless of the background gas species, whereas Cr2+ ions were dominating in Ar and N2 and Cr+ in O2 atmospheres. The energy distributions of the aluminium and chromium ions typically consisted of a high-energy fraction due to acceleration in the expanding plasma plume from the cathode spot and thermalised ions that were subjected to collisions in the plasma cloud. The fraction of the latter increased with increasing background gas pressure. Atomic nitrogen and oxygen ions showed similar energy distributions as the aluminium and chromium ions, whereas the argon and molecular nitrogen and oxygen ions were formed at greater distance from the cathode spot and thus less subject to accelerating gradients. In addition to the positively charged metal and gas ions, negatively charged oxygen and oxygen-containing ions were observed in O2 atmosphere. The obtained results are intended to provide a comprehensive overview of the ion energies and charge states in the arc plasma of AlCr composite cathodes in different gas atmospheres as such plasmas are frequently used to deposit thin films and coatings.

  11. Vacuum encapsulated hermetically sealed diamond amplified cathode capsule and method for making same

    DOE Patents [OSTI]

    Rao, Triveni; Walsh, John; Gangone, Elizabeth

    2014-12-30

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first cold-weld ring disposed between the cathode element and the annular insulating spacer and a second cold-weld ring disposed between the annular insulating spacer and the diamond window element. The cathode capsule is formed by a vacuum cold-weld process such that the first cold-weld ring forms a hermetical seal between the cathode element and the annular insulating spacer and the second cold-weld ring forms a hermetical seal between the annular spacer and the diamond window element whereby a vacuum encapsulated chamber is formed within the capsule.

  12. Vacuum encapsulated, high temperature diamond amplified cathode capsule and method for making same

    DOE Patents [OSTI]

    Rao, Triveni; Walsh, Josh; Gangone, Elizabeth

    2015-12-29

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first high-temperature solder weld disposed between the diamond window element and the annular insulating spacer and a second high-temperature solder weld disposed between the annular insulating spacer and the cathode element. The cathode capsule is formed by a high temperature weld process under vacuum such that the first solder weld forms a hermetical seal between the diamond window element and the annular insulating spacer and the second solder weld forms a hermetical seal between the annular spacer and the cathode element whereby a vacuum encapsulated chamber is formed within the capsule.

  13. Final Report on "Development and Testing of Advanced Accelerator Structures and Technologies at 11.424 GHz"

    SciTech Connect (OSTI)

    Gold, Steven H.

    2013-10-13

    This is the final report on the research program ?Development and Testing of Advanced Accelerator Structures and Technologies at 11.424 GHz,? which was carried out by the Naval Research Laboratory (NRL) under Interagency Agreement DE?AI02?01ER41170 with the Department of Energy. The period covered by this report is 15 July 2010 ? 14 July 2013. The program included two principal tasks. Task 1 involved a study of the key physics issues related to the use of high gradient dielectric-loaded accelerating (DLA) structures in rf linear accelerators and was carried out in collaboration with Argonne National Laboratory (ANL) and Euclid Techlabs LLC. Task 2 involved a study of high power active microwave pulse compressors and was carried out in collaboration with Omega-P, Inc. and the Institute of Applied Physics of the Russian Academy of Sciences in Nizhny Novgorod. The studies under Task 1 were focused on rf-induced multipactor and breakdown in externally driven DLA structures at the 200-ns timescale. Suppression of multipactor and breakdown are essential to the practical application of dielectric structures in rf linear accelerators. The structures that were studied were developed by ANL and Euclid Techlabs and their performance was evaluated at high power in the X-band Magnicon Laboratory at NRL. Three structures were designed, fabricated, and tested, and the results analyzed in the first two years of the program: a clamped quartz traveling-wave (TW) structure, a externally copper-coated TW structure, and an externally copper-coated dielectric standing-wave (SW) structure. These structures showed that rf breakdown could be largely eliminated by eliminating dielectric joints in the structures, but that the multipactor loading was omnipresent. In the third year of the program, the focus of the program was on multipactor suppression using a strong applied axial magnetic field, as proposed by Chang et al. [C. Chang et al., J. Appl. Phys. 110, 063304 (2011).], and a successful experiment was carried out that demonstrated suppression of multipactor in the uniform-field region of a TW DLA structure. However, in accordance with theory, the multipactor was enhanced in regions of the structure with lower values of axial magnetic field. Under Task 2, there were two two-month experimental runs at NRL that were used to characterize the performance of high power two-channel dual-mode active microwave pulse compressor configurations that used electron-beam triggered switch cavities. The pulse compressors were designed and fabricated by Omega-P, Inc. and the Russian Institute of Applied Physics and tested in the Magnicon Laboratory at NRL. These pulse compressors made use of an electron beam discharge from a cylindrical knife-edged Mo cathode coated with a CVD diamond film that was driven by a ?100 kV, 100 ns high voltage pulse. The electron beam was used to change the resonant frequency of the switch cavities in order to create the output microwave pulse. The compressor channels included a TE01 input and output section and a TE02 energy storage cavity, followed by a switch assembly that controlled the coupling between the TE01 and TE02 modes. In the initial state, the switch cavity was in resonance, the reflection from the cavity was out of phase, and the mode conversion was only ~2-3%, allowing the energy storage cavity to fill. When the electron beam was discharged into the switch cavity, the cavity was shifted out of resonance, causing the phase of the reflection to change by ~?. As a result of the change in the reflection phase, the mode coupling in the conical taper was greatly increased, and could approach ~100%, permitting the energy storage cavity to empty in one cavity round trip time of the TE02 mode to produce a high power output pulse. The second experiment runs demonstrated a 190 MW, ~20 ns compressed pulse at 25.7 gain and ~50% efficiency, using a 7.4 MW, 1 ?s drive pulse from the magnicon. The success of this experiment suggests a path to future high gain active versions of the SLED 2 pulse compressor at SLAC.

  14. Advanced Scientific Computing Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Scientific Computing Research Advanced Scientific Computing Research Discovering, developing, and deploying computational and networking capabilities to analyze, model,...

  15. Nanosegregated Cathode Catalysts with Ultra-Low Platinum Loading...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2009 PDF icon markovicanlkickoff.pdf More Documents & Publications Advanced Electrocatalysts for PEM Fuel Cells Fuel Cells: Just a Dream - or Future Reality Catalysis Working...

  16. Analysis of deformed palladium cathodes resulting from heavy water electrolysis

    SciTech Connect (OSTI)

    An, H.K.; Jeong, E.J.; Hong, J.H.; Lee, Y.

    1995-07-01

    Earlier experiments suggested that large differences in heat release between the two sides of a palladium electrode coated with gold on one side and manganese oxide on the other cause observed electrode deformation with high-pressure D{sub 2} gas loading in an electrolysis-like cell. Similar experiments were repeated using heavy water electrolysis. Palladium/titanium coatings on one side and gold coating on the other were made for the preparation of the palladium electrodes. Biaxial bending, partial discoloration, and microcracks of palladium electrodes were observed after 18 days of electrolysis. Analysis of the deformed palladium cathodes was performed. It was discovered that to convert this configuration to a practical energy-producing cell, a coating technique must be found to reduce outward diffusion of deuterium, i.e., to maintain a high D/Pd ratio over longer periods of time. 33 refs., 7 figs., 1 tab.

  17. Analyses of palladium cathodes used for heavy water electrolysis

    SciTech Connect (OSTI)

    Kumar, K.; Dauwalter, C.R.; Stecyk, A. )

    1991-01-01

    This paper reports on the sporadic nature of the excess heat reported from heavy water electrolysis which has attributed to variability among the different palladium cathodes used. Experimental repeatability should, therefore, be enhanced if the microstructure of the palladium can be controlled. Toward this end, palladium rod samples from two heavy water electrolysis experiments were compared to a sample representative of the as-installed condition. The samples examined showed equiaxed grains and significant abnormal grain growth. The rod axes had strong textures, which were attributed to their prior thermomechanical history. The postelectrolysis palladium rods were sampled at two locations that were suspected to have operated at different average current densities. The suspected higher current density regions consisted of single-phase Pd-D{sub 0.7} microstructures. Surface-originated cracks were seen along the grain boundaries in one of two such specimens. Cracks were absent in samples from the suspected lower current density regions, which showed two-phase microstructures with Pd-D{sub 0.7} as the dominant phase. The minor phase, indexed as palladium in the X-ray pattern, was dispersed nonuniformly, mostly in the form of stringers, across the grain boundaries. It is concluded that high current densities resulted in high deuterium loadings in palladium. Smoothing effects from the electrolytic process, resulting in preferential material removal from the grain boundaries, were seen on the cathode surface. A number of high-mass impurities were seen to have deposited on the exposed surface. An initial secondary ion mass spectrometry examination of the specimen interior indicated a significant presence of mass 2 species and considerably lower concentrations of mass 3 and 4 species. Repeat analyses failed to confirm the presence of the mass 3 and 4 species.

  18. High-current electron beam generation in a diode with a multicapillary dielectric cathode

    SciTech Connect (OSTI)

    Gleizer, J. Z.; Hadas, Y.; Gurovich, V. Tz.; Felsteiner, J.; Krasik, Ya. E.

    2008-02-15

    Results of high-current electron beam generation in an {approx}200 kV, {approx}250 ns diode with a multicapillary dielectric cathode (MCDC) assisted by either velvet-type or ferroelectric plasma sources (FPSs) are presented. Multicapillary cathodes made of cordierite, glass, and quartz glass samples were studied. It was found that the source of electrons is the plasma ejected from capillaries. The plasma parameters inside capillary channels and in the vicinity of the cathode surface were determined during the accelerating pulse using visible range spectroscopy. It was shown that glass multicapillary cathodes are characterized by less surface erosion than the cordierite cathodes. Also, it was found that multicapillary cathodes assisted by a FPS showed longer lifetime and better vacuum compatibility than multicapillary cathodes assisted by a velvet-type igniter. Finally, it was found that quartz glass MCDC assisted by FPS is characterized by almost simultaneous formation of the plasma in a cross-sectional area of the dielectric sample with respect to the beginning of the accelerating pulse. The latter is explained by intense UV radiation which synchronized formation of parallel discharges due to induced secondary electron emission.

  19. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wongchang

    2014-05-13

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  20. Array of virtual Frisch-grid CZT detectors with common cathode readout and

    Office of Scientific and Technical Information (OSTI)

    pulse-height correction (Conference) | SciTech Connect Conference: Array of virtual Frisch-grid CZT detectors with common cathode readout and pulse-height correction Citation Details In-Document Search Title: Array of virtual Frisch-grid CZT detectors with common cathode readout and pulse-height correction We present our new results from testing 15-mm-long virtual Frisch-grid CdZnTe detectors with a common-cathode readout for correcting pulse-height distortions. The array employs

  1. EERE Success Story-Battery Cathode Developed by Argonne Powers Plug-in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Vehicles | Department of Energy Cathode Developed by Argonne Powers Plug-in Electric Vehicles EERE Success Story-Battery Cathode Developed by Argonne Powers Plug-in Electric Vehicles August 13, 2015 - 12:12pm Addthis The 2011 Chevrolet Volt at a charging station. Its battery is based on a cathode technology developed at Argonne National Laboratory, which will make the battery safer, longer-lived and more powerful. Photo courtesy of General Motors The 2011 Chevrolet Volt at a

  2. IN-SITU XRD OF OPERATING LSFC CATHODES: DEVELOPMENT OF A NEW ANALYTICAL CAPABILITY

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Stevenson, Jeffry W.

    2012-11-19

    A solid oxide fuel cell (SOFC) research capability has been developed that facilitates measuring the electrochemical performance of an operating SOFC while simultaneously performing x-ray diffraction on its cathode. The evolution of this research tools development is discussed together with a description of the instrumentation used for in-situ x-ray diffraction (XRD) measurements of operating SOFC cathodes. The challenges that were overcome in the process of developing this capability, which included seals and cathode current collectors, are described together with the solutions that are presently being applied to mitigate them.

  3. Battery Cathode Developed by Argonne Powers Plug-in Electric Vehicles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Cathode Developed by Argonne Powers Plug-in Electric Vehicles Battery Cathode Developed by Argonne Powers Plug-in Electric Vehicles August 13, 2015 - 12:12pm Addthis The 2011 Chevrolet Volt at a charging station. Its battery is based on a cathode technology developed at Argonne National Laboratory, which will make the battery safer, longer-lived and more powerful. Photo courtesy of General Motors The 2011 Chevrolet Volt at a charging station. Its battery is based on a

  4. Array of virtual Frisch-grid detectors with common cathode and reduced length of shielding electrodes

    DOE Patents [OSTI]

    Bolotnikov, Aleksey; James, Ralph B.; De Geronimo, Gianluigi; Vernon, Emerson

    2015-09-15

    A radiation detector system that effectively solves the electron trapping problem by optimizing shielding of individual virtual Frisch-grid detectors in an array configuration with a common cathode.

  5. Array of virtual Frisch-grid detectors with common cathode and reduced length of shielding electrodes

    DOE Patents [OSTI]

    Bolotnikov, Aleksey E.; Yang, Ge; Camarda, Giuseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B.

    2015-09-01

    A radiation detector system that solves the electron trapping problem by optimizing shielding of the individual virtual Frisch-grid detectors in an array configuration with a common cathode.

  6. Nanocrystallization of LiCoO2 Cathodes for Thin Film Batteries Utilizing Pulse Thermal Processing

    SciTech Connect (OSTI)

    2009-04-01

    This factsheet describes a study whose focus is on the nanocrystallization of the LiCoO2 cathode thin films on polyimide substrates and evaluate the microstructural evolution and resistance as a function of PTP processing conditions.

  7. NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-10-01

    Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

  8. Bent paths of a positive streamer and a cathode-directed spark...

    Office of Scientific and Technical Information (OSTI)

    In our opinion, such propagation of the positive streamer and the cathode-directed spark leader at some angle to the background electric field lines owes to different increase ...

  9. Correlation between cathode properties, burning voltage, and plasma parameters of vacuum arcs

    SciTech Connect (OSTI)

    Anders, Andre; Yotsombat, Banchob; Binder, Robert

    2001-06-15

    Burning voltages of vacuum arcs were measured for 54 cathode materials and compared with literature data. As anticipated, a correlation between the arc burning voltage and the plasma temperature was found. However, more importantly, a correlation between the cohesive energy of the cathode material and the arc burning voltage could be demonstrated. This link between a cathode material property, the cohesive energy, and a discharge property, the arc burning voltage, is essential for the operation of the vacuum arc discharge because is determines the plasma temperature. Energy balance considerations show that this {open_quotes}cohesive energy rule{close_quotes} is responsible for several other secondary relationships, such as the correlation between the mean ion charge state and the boiling temperature of the cathode. {copyright} 2001 American Institute of Physics.

  10. Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy novel cathode / alloy...

  11. Material and Energy Flows in the Production of Cathode and Anode...

    Office of Scientific and Technical Information (OSTI)

    The Greenhouse gases, Regulated Emissions and Energy use in Transportation (GREET) model has been expanded to include four new cathode materials that can be used in the analysis of ...

  12. Material and Energy Flows in the Production of Cathode and Anode...

    Office of Scientific and Technical Information (OSTI)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the ...

  13. Evaluation of plasma-sprayed CoS{sub 2} cathodes for thermal batteries

    SciTech Connect (OSTI)

    Guidotti, R.A.

    1999-12-22

    Conventional electroactive stack components in thermal batteries are constructed from pressed-powder parts. These include the anode, separator, and cathode pellets (discs). Pressing parts that are less than 0.010 inch thick is difficult. The use of plasma spray to deposit thin CoS{sub 2} cathode films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The plasma-sprayed electrodes were tested in single cells under isothermal conditions and constant-current discharge over a temperature range of 400 C to 550 C using standard LiSi anodes and separators based on the LiCl-KCl eutectic. Similar tests were conducted with cells built with conventional pressed-powder cathodes, which were tested under the same conditions for comparative purposes. This paper presents the results of those tests.

  14. Beetlejuice! Secrets of beetle sprays unlocked at the Advanced...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Louise Lerner at (630) 252-5526 or media@anl.gov. Connect Find an Argonne expert by subject. Follow Argonne on Twitter, Facebook, Google+ and LinkedIn. For inquiries on...

  15. Hollow - cathode electrode for high-power, high-pressure discharge devices

    DOE Patents [OSTI]

    Chang, Jim J. (7644 Ashford Way, Dublin, CA 94568); Alger, Terry W. (901 Renown Dr., Tracy, CA 95376)

    1995-01-01

    Several different cold cathode configurations for a gas discharge device each having a plurality of grooves of selected spacing, depth and width to improve the emission of electrons in a gas discharge device. Each of the cold cathode configurations can be machined from a single piece of a selected material. Several of the configurations can be assembled with individual elements which is easily seen from the various figures.

  16. Hollow-cathode electrode for high-power, high-pressure discharge devices

    DOE Patents [OSTI]

    Chang, J.J.; Alger, T.W.

    1995-08-22

    Several different cold cathode configurations are disclosed for a gas discharge device each having a plurality of grooves of selected spacing, depth and width to improve the emission of electrons in a gas discharge device. Each of the cold cathode configurations can be machined from a single piece of a selected material. Several of the configurations can be assembled with individual elements which is easily seen from the various figures. 8 figs.

  17. Material and Energy Flows in the Production of Cathode and Anode Materials

    Office of Scientific and Technical Information (OSTI)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Authors: Dunn, Jennifer B. ; James, Christine ; Gaines, L G ; Gallagher, Kevin Publication Date: 2014-09-30 OSTI Identifier: 1172039 Report

  18. Analytical expression for the electric potential in the plasma sheath near an arc-cathode

    SciTech Connect (OSTI)

    Askari, S.; Minoo, H.

    2008-04-15

    An expression for the spatial dependence of the electric potential in a collisionless plasma sheath near an electron-emitting cathode is presented. The applicability of this expression for an arc cathode is demonstrated. Comparison with the numerical solutions of the model equations indicates that the sheath thickness and potential variation predicted by this expression are accurate in a wide range of the electron-emission yield.

  19. Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells > Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights > Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries

  20. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  1. Development of High Energy Cathode for Li-ion Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy for Li-ion Batteries Development of High Energy Cathode for Li-ion Batteries 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es056_zhang_2010_p.pdf More Documents & Publications Phase Behavior and Solid State Chemistry in Olivines Development of High Energy Cathode Materials Interfacial Processes - Diagnostics

  2. Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells Development of Ultra-low Platinum Alloy Cathode Catalyst for PEM Fuel Cells These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. PDF icon 7_usc_popov.pdf More Documents & Publications DOE's Fuel Cell Catalyst R&D Activities Alkaline Membrane Fuel Cell Workshop Welcome and OverviewInnovation 2006 Alkaline Membrane Fuel Cell Workshop Final Report

  3. Material and Energy Flows in the Production of Cathode and Anode Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Ion Batteries | Argonne National Laboratory Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Publication Type Report Year of Publication 2015 Authors Dunn, JB, James, C, Gaines, LL, Gallagher, K, Dai, Q, Kelly, JC Pagination 56 Date Published 09152015 Institution Argonne National Laboratory City Argonne, IL USA Report

  4. Methanol-tolerant cathode catalyst composite for direct methanol fuel cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Energy Innovation Portal Methanol-tolerant cathode catalyst composite for direct methanol fuel cells Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary A direct methanol fuel cell (DMFC) having a methanol fuel supply, oxidant supply, and its membrane electrode assembly (MEA) formed of an anode electrode and a cathode electrode with a membrane therebetween, a methanol oxidation catalyst adjacent the anode electrode and the membrane, an oxidant

  5. Cell Analysis … High-Energy Density Cathodes and Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Cell Analysis … High-Energy Density Cathodes and Anodes Cell Analysis … High-Energy Density Cathodes and Anodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es053_richardson_2010_p.pdf More Documents & Publications First Principles Calculations of Electrode Materials Vehicle Technologies Office Merit Review 2015: A Commercially Scalable Process for Silicon Anode Prelithiation

  6. Oxygen transport in the internal xenon plasma of a dispenser hollow cathode

    SciTech Connect (OSTI)

    Capece, Angela M. Shepherd, Joseph E.; Polk, James E.; Mikellides, Ioannis G.

    2014-04-21

    Reactive gases such as oxygen and water vapor modify the surface morphology of BaO dispenser cathodes and degrade the electron emission properties. For vacuum cathodes operating at fixed temperature, the emission current drops rapidly when oxygen adsorbs on top of the low work function surface. Previous experiments have shown that plasma cathodes are more resistant to oxygen poisoning and can operate with O{sub 2} partial pressures one to two orders of magnitude higher than vacuum cathodes before the onset of poisoning occurs. Plasma cathodes used for electric thrusters are typically operated with xenon; however, gas phase barium, oxygen, and tungsten species may be found in small concentrations. The densities of these minor species are small compared with the plasma density, and thus, their presence in the discharge does not significantly alter the xenon plasma parameters. It is important, however, to consider the transport of these minor species as they may deposit on the emitter surface and affect the electron emission properties. In this work, we present the results of a material transport model used to predict oxygen fluxes to the cathode surface by solving the species conservation equations in a cathode with a 2.25?mm diameter orifice operated at a discharge current of 15?A, a Xe flow rate of 3.7 sccm, and 100?ppm of O{sub 2}. The dominant ionization process for O{sub 2} is resonant charge exchange with xenon ions. Ba is effectively recycled in the plasma; however, BaO and O{sub 2} are not. The model shows that the oxygen flux to the surface is not diffusion-limited; therefore, the high resistance to oxygen poisoning observed in plasma cathodes likely results from surface processes not considered here.

  7. Low Cost SiOx-Graphite and High Voltage Spinel Cathode | Department of

    Office of Environmental Management (EM)

    Energy Low Cost SiOx-Graphite and High Voltage Spinel Cathode Low Cost SiOx-Graphite and High Voltage Spinel Cathode 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es048_zaghib_2011_o.pdf More Documents & Publications Low Cost SiOx-Graphite and Olivine Materials Low Cost SiOx-Graphite and Olivine Materials BATT Program- Summary and Future Plans

  8. Sandia Energy - Advanced Imaging

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Imaging Home Transportation Energy Predictive Simulation of Engines Reacting Flow Experiments Advanced Imaging Advanced ImagingAshley Otero2015-10-30T01:47:37+00:00...

  9. Numerical simulation of cathode plasma dynamics in magnetically insulated vacuum transmission lines

    SciTech Connect (OSTI)

    Thoma, C.; Genoni, T. C.; Welch, D. R.; Rose, D. V.; Clark, R. E.; Miller, C. L.; Stygar, W. A.; Kiefer, M. L.

    2015-03-15

    A novel algorithm for the simulation of cathode plasmas in particle-in-cell codes is described and applied to investigate cathode plasma evolution in magnetically insulated transmission lines (MITLs). The MITL electron sheath is modeled by a fully kinetic electron species. Electron and ion macroparticles, both modeled as fluid species, form a dense plasma which is initially localized at the cathode surface. Energetic plasma electron particles can be converted to kinetic electrons to resupply the electron flux at the plasma edge (the effective cathode). Using this model, we compare results for the time evolution of the cathode plasma and MITL electron flow with a simplified (isothermal) diffusion model. Simulations in 1D show a slow diffusive expansion of the plasma from the cathode surface. But in multiple dimensions, the plasma can expand much more rapidly due to anomalous diffusion caused by an instability due to the strong coupling of a transverse magnetic mode in the electron sheath with the expanding resistive plasma layer.

  10. Hollow cathode theory and experiment. II. A two-dimensional theoretical model of the emitter region

    SciTech Connect (OSTI)

    Mikellides, Ioannis G.; Katz, Ira; Goebel, Dan M.; Polk, James E.

    2005-12-01

    Despite their long history and wide range of applicability that includes electric propulsion, detailed understanding of the driving physics inside orificed hollow cathodes remains elusive. The theoretical complexity associated with the multicomponent fluid inside the cathode, and the difficulty of accessing empirically this region, have limited our ability to design cathodes that perform better and last longer. A two-dimensional axisymmetric theoretical model of the multispecies fluid inside an orificed hollow cathode is presented. The level of detail attained by the model is allowed by its extended system of governing equations not solved for in the past within the hollow cathode. Such detail is motivated in part by the need to quantify the effect(s) of the plasma on the emitter life, and by the need to build the foundation for future modeling that will assess erosion of the keeper plate. Results from numerical simulations of a 1.2-cm-diam cathode operating at a discharge current of 25 A and a gas flow rate of 5 SCCM show that approximately 10 A of electron current, and 3.45 A of ion current return back to the emitter surface. The total emitted electron current is 33.8 A and the peak emitter temperature is found to be 1440 K. Comparisons with the measurements suggest that anomalous heating of the plasma is possible near the orifice region. The model predicts heavy species temperatures as high as 2034 K and peak voltage drops near the emitting surface not exceeding 8 V.

  11. Pore Scale Modeling of the Reactive Transport of Chromium in the Cathode of a Solid Oxide Fuel Cell

    SciTech Connect (OSTI)

    Ryan, Emily M.; Tartakovsky, Alexandre M.; Recknagle, Kurtis P.; Khaleel, Mohammad A.; Amon, Cristina

    2011-01-01

    We present a pore scale model of a solid oxide fuel cell (SOFC) cathode. Volatile chromium species are known to migrate from the current collector of the SOFC into the cathode where over time they decrease the voltage output of the fuel cell. A pore scale model is used to investigate the reactive transport of chromium species in the cathode and to study the driving forces of chromium poisoning. A multi-scale modeling approach is proposed which uses a cell level model of the cathode, air channel and current collector to determine the boundary conditions for a pore scale model of a section of the cathode. The pore scale model uses a discrete representation of the cathode to explicitly model the surface reactions of oxygen and chromium with a cathode material. The pore scale model is used to study the reaction mechanisms of chromium by considering the effects of reaction rates, diffusion coefficients, chromium vaporization, and oxygen consumption on chromiums deposition in the cathode. The study shows that chromium poisoning is most significantly affected by the chromium reaction rates in the cathode and that the reaction rates are a function of the local current density in the cathode.

  12. Humectant use in the cathodic protection of reinforced concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Covino, B.S. Jr.; Russell, J.H.; Bullard, S.J.; Cramer, S.D.; Collins, W.K.; Bennett, J.E.; H.M. Laylor

    2000-03-01

    The use of humectants to improve the thermal-sprayed zinc anode performance during the cathodic protection (CP) of reinforced concrete is examined. A humectant is a hygroscopic material. It is applied onto the surface of the zinc anode to keep the concrete-anode interface moist and a good conductor. The thermodynamics of humectants are discussed. Laboratory results are presented on the effects of using LiBr and LiNO{sub 3} as humectants in galvanic (GCP) and impressed current (ICCP) systems, in high and low relative humidities, and on new and previously electrochemically aged CP systems. LiNO{sub 3} and LiBr promoted more effective CP performance. Both improved the performance of aged slabs, suggesting that application of humectants onto existing CP systems would be of benefit. Microscopy showed that humectant-treated slabs develop the same cement-reaction zone-zinc anode structures as untreated slabs. Microscopy of LiBr-treated slabs revealed that the highest concentration of bromide was in the reaction zone. In GCP tests, LiBr was more effective than LiNO{sub 3}. In accelerated ICCP tests, LiNO{sub 3} was more effective than LiBr. It was surmised that bromide could be oxidized in the high-voltage accelerated ICCP tests. At the lower impressed currents of most installed ICCP systems, LiBr may perform as well as or better than LiNO{sub 3}.

  13. Neutral beam dump with cathodic arc titanium gettering

    SciTech Connect (OSTI)

    Smirnov, A.; Korepanov, S. A.; Putvinski, S.; Krivenko, A. S.; Murakhtin, S. V.; Savkin, V. Ya.

    2011-03-15

    An incomplete neutral beam capture can degrade the plasma performance in neutral beam driven plasma machines. The beam dumps mitigating the shine-through beam recycling must entrap and retain large particle loads while maintaining the beam-exposed surfaces clean of the residual impurities. The cathodic arc gettering, which provides high evaporation rate coupled with a fast time response, is a powerful and versatile technique for depositing clean getter films in vacuum. A compact neutral beam dump utilizing the titanium arc gettering was developed for a field-reversed configuration plasma sustained by 1 MW, 20-40 keV neutral hydrogen beams. The titanium evaporator features a new improved design. The beam dump is capable of handling large pulsed gas loads, has a high sorption capacity, and is robust and reliable. With the beam particle flux density of 5 x 10{sup 17} H/(cm{sup 2}s) sustained for 3-10 ms, the beam recycling coefficient, defined as twice the ratio of the hydrogen molecular flux leaving the beam dump to the incident flux of high-energy neutral atoms, is {approx}0.7. The use of the beam dump allows us to significantly reduce the recycling of the shine-through neutral beam as well as to improve the vacuum conditions in the machine.

  14. Ignition and extinction phenomena in helium micro hollow cathode discharges

    SciTech Connect (OSTI)

    Kulsreshath, M. K.; Schwaederle, L.; Dufour, T.; Lefaucheux, P.; Dussart, R.; Overzet, L. J.

    2013-12-28

    Micro hollow cathode discharges (MHCD) were produced using 250??m thick dielectric layer of alumina sandwiched between two nickel electrodes of 8??m thickness. A through cavity at the center of the chip was formed by laser drilling technique. MHCD with a diameter of few hundreds of micrometers allowed us to generate direct current discharges in helium at up to atmospheric pressure. A slowly varying ramped voltage generator was used to study the ignition and the extinction periods of the microdischarges. The analysis was performed by using electrical characterisation of the V-I behaviour and the measurement of He*({sup 3}S{sub 1}) metastable atoms density by tunable diode laser spectroscopy. At the ignition of the microdischarges, 2??s long current peak as high as 24?mA was observed, sometimes followed by low amplitude damped oscillations. At helium pressure above 400?Torr, an oscillatory behaviour of the discharge current was observed just before the extinction of the microdischarges. The same type of instability in the extinction period at high pressure also appeared on the density of He*({sup 3}S{sub 1}) metastable atoms, but delayed by a few ?s relative to the current oscillations. Metastable atoms thus cannot be at the origin of the generation of the observed instabilities.

  15. Iron-based perovskite cathodes for solid oxide fuel cells

    DOE Patents [OSTI]

    Ralph, James M.; Rossignol, Cecile C.R.; Vaughey, John T.

    2007-01-02

    An A and/or A' site deficient perovskite of general formula of (A.sub.1-xA'.sub.x).sub.1-yFeO.sub.3-.delta. or of general formula A.sub.1-x-yA'.sub.xFeO.sub.3-67, wherein A is La alone or with one or more of the rare earth metals or a rare earth metal other than Ce alone or a combination of rare earth metals and X is in the range of from 0 to about 1; A' is Sr or Ca or mixtures thereof and Y is in the range of from about 0.01 to about 0.3; .delta. represents the amount of compensating oxygen loss. If either A or A' is zero the remaining A or A' is deficient. A fuel cell incorporating the inventive perovskite as a cathode is disclosed as well as an oxygen separation membrane. The inventive perovskite is preferably single phase.

  16. Sandia Energy - Advanced Research & Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Research & Development Home Stationary Power Energy Conversion Efficiency Solar Energy Photovoltaics Advanced Research & Development Advanced Research & DevelopmentCoryne...

  17. Linear Accelerator | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Linear Accelerator Producing brilliant x-ray beams at the APS begins with electrons emitted from a cathode heated to 1100 C. The electrons are accelerated by high-voltage...

  18. Recent Articles on www.anl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    even" property"content:encoded">

    Microwave heat improves nanostructured molybdenum disulfide catalyst's ability to produce hydrogen.

    Mon, 26 Oct 2015...

  19. ANL Success Stories - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    today that they have signed a licensing agreement for an Argonne-developed, silicon-graphene composite anode material for high-energy lithium batteries. CalBattery plans to...

  20. Advanced Manufacturing Office News

    SciTech Connect (OSTI)

    2013-08-08

    News stories about advanced manufacturing, events, and office accomplishments. Subscribe to receive updates.

  1. Advanced Manufacturing Office Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Workshop: Microwave (MW) and Radio Frequency (RF) as Enabling Technologies for Advanced Manufacturing Venue: The 2nd Global Congress on Microwave Energy Applications (2GCMEA) July 25, 2012 Long Beach Hilton Long Beach, CA Advanced Manufacturing Office U.S. Department of Energy Rob Ivester Acting Deputy Program Manager, Advanced Manufacturing Office Advanced Manufacturing Office Advanced Manufacturing Office Agenda Time Activity 2:00-2:30 PM Opening Session - AMO o Presentation of Industry

  2. A mulitple cathode gun design for the eRHIC polarized electron source

    SciTech Connect (OSTI)

    Chang, X.; Ben-Zvi, I.; Kewisch, J.; Litvinenko, V.; Pikin, A.; Ptitsyn, V.; Rao, T.; Sheehy, B.; Skaritka, J.; Wang, E.; Wu, Q.; Xin, T.

    2011-03-28

    The future electron-ion collider eRHIC requires a high average current ({approx}50 mA), short bunch ({approx}3 mm), low emittance ({approx}20 {micro}m) polarized electron source. The maximum average current of a polarized electron source so far is more than 1 mA, but much less than 50 mA, from a GaAs:Cs cathode. One possible approach to overcome the average current limit and to achieve the required 50 mA beam for eRHIC, is to combine beamlets from multiple cathodes to one beam. In this paper, we present the feasibility studies of this technique. The future eRHIC project, next upgrade of RHIC, will be the first electron-heavy ion collider in the world. It requires polarized electron source with a high average current ({approx}50 mA), short bunch ({approx}3 mm), emittance of about 20 {micro}m and energy spread of {approx}1% at 10 MeV. The state-of-art polarized electron cathode can generate average current of about more than 1 mA, but much less than 50 mA. The current is limited by the low quantum efficiency, space charge and ultra-high vacuum requirement of the polarized cathode. A possible approach to achieve the 50 mA beam is to employ multiple cathodes, such as 20 cathodes, and funnel the multiple bunched beams from cathodes to the same axis. Fig.1 illustrates schematically the concept of combining the multiple beams. We name it as 'Gatling gun' because it bears functional similarity to a Gatling gun. Laser beams strike the cathodes sequentially with revolution frequency of 700 kHz. Each beam bunch is focused by a solenoid and is bent toward the combiner. The combiner with rotating bending field bends all bunches arriving the combiner with a rotational pattern to the same axis. The energy of each bunch is modified by a bunching cavity (112MHz) and a 3rd harmonic cavity (336MHz). The bunch length is compressed ballistically in the drift space and is frozen after energy has been boosted to 10 MeV by the Booster linac. Each beam bunch contains 3.5 nC charge. The space charge is very strong at energy of 200 keV. A long bunch, {sigma} of 250 ps, is adopted to reduce the space charge on cathode. To compress the beam to final length of 3 mm (10 ps) can be achieved by ballistic compression with a 3rd harmonic cavity.

  3. A Method for Monitoring Deposition at a Solid Cathode in an Electrorefiner for a Two-Species System Using Electrode Potentials

    SciTech Connect (OSTI)

    D.S. Rappleye; M.-S. Yim; M.F. Simpson; R.M. Cumberland

    2013-10-01

    Currently, process monitoring of spent nuclear fuel electrorefining relies upon sampling and destructive analysis methods coupled with extrapolative thermodynamic process models for non-interrupted operations. Corrections to those models are performed infrequently, jeopardizing both the control of the process and safeguarding of nuclear material. Furthermore, the timeliness of obtaining the results is inadequate for application of international safeguards protocol. Alternatively, a system that dynamically utilizes electrical data such as electrode potentials and cell current can hypothetically be used to achieve real-time process monitoring and more robust control as well as improved safeguards. Efforts to develop an advanced model of the electrorefiner to date have focused on a forward modeling approach by using feed and salt compositions to determine the product composition, cell current and electrode potential response. Alternatively, an inverse model was developed, and reported here, to predict the product deposition rates on a cathode using the cell current, cathode potential, and fundamental relations of electrochemistry. The model was applied to the following cases: pure uranium deposition, co-deposition of uranium and plutonium, and co-deposition of uranium and zirconium. The deposition rates predicted by the inverse model were compared to those of a forward model, ERAD.

  4. Effect of Ti-Al cathode composition on plasma generation and plasma transport in direct current vacuum arc

    SciTech Connect (OSTI)

    Zhirkov, I. Petruhins, A.; Dahlqvist, M.; Ingason, A. S.; Rosen, J.; Eriksson, A. O.

    2014-03-28

    DC arc plasma from Ti, Al, and Ti{sub 1-x}Al{sub x} (x?=?0.16, 0.25, 0.50, and 0.70) compound cathodes was characterized with respect to plasma chemistry and charge-state-resolved ion energy. Scanning electron microscopy, X-ray diffraction, and Energy-dispersive X-ray spectroscopy of the deposited films and the cathode surfaces were used for exploring the correlation between cathode-, plasma-, and film composition. Experimental work was performed at a base pressure of 10{sup ?6}?Torr, to exclude plasma-gas interaction. The plasma ion composition showed a reduction of Al of approximately 5 at. % compared to the cathode composition, while deposited films were in accordance with the cathode stoichiometry. This may be explained by presence of neutrals in the plasma/vapour phase. The average ion charge states (Ti?=?2.2, Al?=?1.65) were consistent with reference data for elemental cathodes, and approximately independent on the cathode composition. On the contrary, the width of the ion energy distributions (IEDs) were drastically reduced when comparing the elemental Ti and Al cathodes with Ti{sub 0.5}Al{sub 0.5}, going from??150 and ?175?eV to ?100 and ?75?eV for Ti and Al ions, respectively. This may be explained by a reduction in electron temperature, commonly associated with the high energy tail of the IED. The average Ti and Al ion energies ranged between ?50 and ?61?eV, and ?30 and ?50?eV, respectively, for different cathode compositions. The attained energy trends were explained by the velocity rule for compound cathodes, which states that the most likely velocities of ions of different mass are equal. Hence, compared to elemental cathodes, the faster Al ions will be decelerated, and the slower Ti ions will be accelerated when originating from compound cathodes. The intensity of the macroparticle generation and thickness of the deposited films were also found to be dependent on the cathode composition. The presented results may be of importance for choice of cathodes for thin film depositions involving compound cathodes.

  5. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wonchang

    2010-05-18

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  6. Long-pulse arc-discharge plasma source with cold cathode for diagnostic neutral beam injector

    SciTech Connect (OSTI)

    Deichuli, P. P.; Ivanov, A. A.; Stupishin, N. V.

    2008-02-15

    Long-pulse cold cathode arc-discharge plasma generators have been successfully used as high-quality hydrogen ion sources for plasma diagnostic neutral beams. One of the main advantages of this type of plasma source is a high proton fraction (80%-90%). However, the lifetime of the plasma source is limited due to intensive electrode's erosion, especially at the cathode region. An optimized design of the cathode and the nearest electrodes is found which reduces the erosion and allows us to increase the pulse length. The plasma source produces the extracted ion current up to 3 A at a low angular divergence, and at the pulse duration up to 2 s.

  7. Structural and Chemical Evolution of Li- and Mn-rich Layered Cathode Material

    SciTech Connect (OSTI)

    Zheng, Jianming; Xu, Pinghong; Gu, Meng; Xiao, Jie; Browning, Nigel D.; Yan, Pengfei; Wang, Chong M.; Zhang, Jiguang

    2015-02-24

    Lithium (Li)- and manganese-rich (LMR) layered-structure materials are very promising cathodes for high energy density lithium-ion batteries. However, their voltage fading mechanism and its relationships with fundamental structural changes are far from being sufficiently understood. Here we report the detailed phase transformation pathway in the LMR cathode (Li[Li0.2Ni0.2Mn0.6]O2) during cycling for the samples prepared by hydro-thermal assistant method. It is found the transformation pathway of LMR cathode is closely correlated to its initial structure and preparation conditions. The results reveal that LMR cathode prepared by HA approach experiences a phase transformation from the layered structure to a LT-LiCoO2 type defect spinel-like structure (Fd-3m space group) and then to a disordered rock-salt structure (Fm-3m space group). The voltage fade can be well correlated with the Li ion insertion into octahedral sites, rather than tetrahedral sites, in both defect spinel-like structure and disordered rock-salt structure. The reversible Li insertion/removal into/from the disordered rock-salt structure is ascribed to the Li excess environment that can satisfy the Li percolating in the disordered rock-salt structure despite the increased kinetic barrier. Meanwhile, because of the presence of a great amount of oxygen vacancies, a significant decrease of Mn valence is detected in the cycled particle, which is below that anticipated for a potentially damaging Jahn-Teller distortion (+3.5). Clarification of the phase transformation pathway, cation redistribution, oxygen vacancy and Mn valence change undoubtedly provides insights into a profound understanding on the voltage fade, and capacity degradation of LMR cathode. The results also inspire us to further enhance the reversibility of LMR cathode via improving its surface structural stability.

  8. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  9. Quantum efficiency temporal response and lifetime of a GaAs cathode in SRF electron gun

    SciTech Connect (OSTI)

    Wang, E.; Ben-Zvi, I.; Kewisch, J.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

    2010-05-23

    RF electron guns with a strained super lattice GaAs cathode can generate polarized electron beam of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface. In a normal conducting RF gun, the extremely high vaccum required by these cathodes can not be met. We report on an experiment with a superconducting SRF gun, which can maintain a vacuum of nearly 10-12 torr because of cryo-pumping at the temperature of 4.2K. With conventional activation, we obtained a QE of 3% at 532 nm, with lifetime of nearly 3 days in the preparation chamber. We plan to use this cathode in a 1.3 GHz 1/2 cell SRF gun to study its performance. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper. Future particle accelerators such as eRHIC and ILC require high brightness, high current polarized electrons Recently, using a superlattice crystal, the maximum polarization of 95% was reached. Activation with Cs,O lowers the electron affinity and makes it energetically possible for all the electrons excited in to the conduction band and reach the surface to escape into the vacuum. Presently the polarized electron sources are based on DC gun, such as that at the CEBAF at Jlab. In these devices, the life time of the cathode is extended due to the reduced back bombardment in their UHV conditions. However, the low accelerating gradient of the DC guns lead to poor longitudinal emittance. The higher accelerating gradient of the RF gun generates low emittance beams. Superconducting RF guns combine the excellent vacuum conditions of the DC guns with the higher accelerating gradients of the RF guns and provide potentially a long lived cathode with very low transverse and longitudinal emittance. In our work at BNL, we successfully activated the GaAs. The quantum efficient is 3% at 532 nm and is expected to improve further. In addition, we studied the multipacting at the location of cathode. A new model based on the Forkker-Planck equation which can estimate the bunch length of the electron beam is discussed in this paper.

  10. EERE Success Story-Illinois: High-Energy, Concentration-Gradient Cathode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material for Plug-in Hybrids and All-Electric Vehicles Could Reduce Batteries' Cost and Size | Department of Energy Illinois: High-Energy, Concentration-Gradient Cathode Material for Plug-in Hybrids and All-Electric Vehicles Could Reduce Batteries' Cost and Size EERE Success Story-Illinois: High-Energy, Concentration-Gradient Cathode Material for Plug-in Hybrids and All-Electric Vehicles Could Reduce Batteries' Cost and Size February 10, 2014 - 12:00am Addthis With support from EERE, Argonne

  11. Characterization of New Cathode Materials using Synchrotron-based X-ray

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techniques and the Studies of Li-Air Batteries | Department of Energy New Cathode Materials using Synchrotron-based X-ray Techniques and the Studies of Li-Air Batteries Characterization of New Cathode Materials using Synchrotron-based X-ray Techniques and the Studies of Li-Air Batteries 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon es_28_yang.pdf More Documents & Publications In situ

  12. Electron depletion via cathode spot dispersion of dielectric powder into an overhead plasma

    SciTech Connect (OSTI)

    Gillman, Eric D. [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States)] [Naval Research Laboratory, 4555 Overlook Ave SW, Washington, District of Columbia 20375 (United States); Foster, John E. [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)] [Department of Nuclear Engineering and Radiological Sciences (NERS), University of Michigan, 2355 Bonisteel Blvd., Ann Arbor, Michigan 48109 (United States)

    2013-11-15

    The effectiveness of cathode spot delivered dielectric particles for the purpose of plasma depletion is investigated. Here, cathode spot flows kinetically entrain and accelerate dielectric particles originally at rest into a background plasma. The time variation of the background plasma density is tracked using a cylindrical Langmuir probe biased approximately at electron saturation. As inferred from changes in the electron saturation current, depletion fractions of up to 95% are observed. This method could be exploited as a means of communications blackout mitigation for manned and unmanned reentering spacecraft as well as any high speed vehicle enveloped by a dense plasma layer.

  13. Report on sodium compatibility of advanced structural materials.

    SciTech Connect (OSTI)

    Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T.

    2012-07-09

    This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

  14. Cathodes for secondary electrochemical power-producing cells. [layers of porous substrates impregnated with S alternate with layers containing electrolyte

    DOE Patents [OSTI]

    Cairns, E.J.; Kyle, M.; Shimotake, H.

    1973-02-13

    A secondary electrochemical power-producing cell includes an anode containing lithium, an electrolyte containing lithium ions, and a cathode containing sulfur. The cathode comprises plates of a porous substrate material impregnated with sulfur alternating with layers (which may also comprise porous substrate plates) containing electrolyte.

  15. Code qualification of structural materials for AFCI advanced recycling reactors.

    SciTech Connect (OSTI)

    Natesan, K.; Li, M.; Majumdar, S.; Nanstad, R.K.; Sham, T.-L.

    2012-05-31

    This report summarizes the further findings from the assessments of current status and future needs in code qualification and licensing of reference structural materials and new advanced alloys for advanced recycling reactors (ARRs) in support of Advanced Fuel Cycle Initiative (AFCI). The work is a combined effort between Argonne National Laboratory (ANL) and Oak Ridge National Laboratory (ORNL) with ANL as the technical lead, as part of Advanced Structural Materials Program for AFCI Reactor Campaign. The report is the second deliverable in FY08 (M505011401) under the work package 'Advanced Materials Code Qualification'. The overall objective of the Advanced Materials Code Qualification project is to evaluate key requirements for the ASME Code qualification and the Nuclear Regulatory Commission (NRC) approval of structural materials in support of the design and licensing of the ARR. Advanced materials are a critical element in the development of sodium reactor technologies. Enhanced materials performance not only improves safety margins and provides design flexibility, but also is essential for the economics of future advanced sodium reactors. Code qualification and licensing of advanced materials are prominent needs for developing and implementing advanced sodium reactor technologies. Nuclear structural component design in the U.S. must comply with the ASME Boiler and Pressure Vessel Code Section III (Rules for Construction of Nuclear Facility Components) and the NRC grants the operational license. As the ARR will operate at higher temperatures than the current light water reactors (LWRs), the design of elevated-temperature components must comply with ASME Subsection NH (Class 1 Components in Elevated Temperature Service). However, the NRC has not approved the use of Subsection NH for reactor components, and this puts additional burdens on materials qualification of the ARR. In the past licensing review for the Clinch River Breeder Reactor Project (CRBRP) and the Power Reactor Innovative Small Module (PRISM), the NRC/Advisory Committee on Reactor Safeguards (ACRS) raised numerous safety-related issues regarding elevated-temperature structural integrity criteria. Most of these issues remained unresolved today. These critical licensing reviews provide a basis for the evaluation of underlying technical issues for future advanced sodium-cooled reactors. Major materials performance issues and high temperature design methodology issues pertinent to the ARR are addressed in the report. The report is organized as follows: the ARR reference design concepts proposed by the Argonne National Laboratory and four industrial consortia were reviewed first, followed by a summary of the major code qualification and licensing issues for the ARR structural materials. The available database is presented for the ASME Code-qualified structural alloys (e.g. 304, 316 stainless steels, 2.25Cr-1Mo, and mod.9Cr-1Mo), including physical properties, tensile properties, impact properties and fracture toughness, creep, fatigue, creep-fatigue interaction, microstructural stability during long-term thermal aging, material degradation in sodium environments and effects of neutron irradiation for both base metals and weld metals. An assessment of modified versions of Type 316 SS, i.e. Type 316LN and its Japanese version, 316FR, was conducted to provide a perspective for codification of 316LN or 316FR in Subsection NH. Current status and data availability of four new advanced alloys, i.e. NF616, NF616+TMT, NF709, and HT-UPS, are also addressed to identify the R&D needs for their code qualification for ARR applications. For both conventional and new alloys, issues related to high temperature design methodology are described to address the needs for improvements for the ARR design and licensing. Assessments have shown that there are significant data gaps for the full qualification and licensing of the ARR structural materials. Development and evaluation of structural materials require a variety of experimental facilities that have been seriously degraded in the past. The availability and additional needs for the key experimental facilities are summarized at the end of the report. Detailed information covered in each Chapter is given.

  16. Advanced Critical Advanced Energy Retrofit Education and Training...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Critical Advanced Energy Retrofit Education and Training and Credentialing - 2014 BTO Peer Review Advanced Critical Advanced Energy Retrofit Education and Training and...

  17. Advanced Nuclear Technology: Advanced Light Water Reactors Utility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nuclear Technology: Advanced Light Water Reactors Utility Requirements Document Small Modular Reactors Inclusion Summary Advanced Nuclear Technology: Advanced Light Water Reactors ...

  18. Vehicle Technologies Office Merit Review 2015: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

  19. Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

  20. Effect of scandia doping method on the emission uniformity of scandate cathode with Sc{sub 2}O{sub 3}W matrix

    SciTech Connect (OSTI)

    Wang, Jinshu Lai, Chen; Liu, Wei; Yang, Fan; Zhang, Xizhu; Cui, Yuntao; Zhou, Meiling

    2013-09-01

    Graphical abstract: Emission uniformity of the cathodes prepared by mechanical mixing (a) and spray drying method (b). - Highlights: The emission uniformity of scandate cathodes has been quantitively obtained. The nanoparticles on the cathode surface lead to the electric field enhancement. The cathode prepared by spray drying method exhibits good emission uniformity. - Abstract: Scandia doped tungsten matrix dispenser cathodes were manufactured using scandia doped tungsten powder prepared by mechanical mixing, liquidsolid doping and a spray drying method. It is found the macrostructure of the cathode depended on the powder preparation method. The cathode prepared using the powder prepared by spray drying method had a homogenous and porous matrix characterized with grains with a diameter of less than 1 ?m and with many nanoparticles distributing uniformly around these grains. The cathode with submicron structure and uniform distribution of scandia exhibited good emission uniformity. The emission uniformity ?J/J of the cathode prepared by spray drying method was 0.17, about 6 times lower than that of the cathode prepared by mechanical mixing method. The calculation results showed that the nanoparticles led to electric field enhancement. A BaScO multilayer on the cathode surface and nanoparticles distributing mainly on W grains contributed to the emission property of the cathode.

  1. Advanced Technology Vehicle Lab Benchmarking - Level 1

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Vehicle Lab Benchmarking - Level 1 2014 U.S. DOE Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting Kevin Stutenberg - Principal Investigator Argonne National Laboratory June 17, 2014 Project ID # VSS030 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Overview  Timeline - Benchmarking at ANL started in 1998 - FY13 & FY14 Completed Testing: * 10 vehicles tested in FY13, 4 in FY14 * Thermal impact

  2. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-12-31

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  3. Suppressing Manganese Dissolution from Lithium Manganese Oxide Spinel Cathodes with Single-Layer Graphene

    SciTech Connect (OSTI)

    Jaber-Ansari, Laila; Puntambekar, Kanan P.; Kim, Soo; Aykol, Muratahan; Luo, Langli; Wu, Jinsong; Myers, Benjamin D.; Iddir, Hakim; Russell, John T.; Saldana, Spencer J.; Kumar, Rajan; Thackeray, Michael M.; Curtiss, Larry A.; Dravid, Vinayak P.; Wolverton, Christopher M.; Hersam, Mark C.

    2015-06-24

    Spinel-structured LiMn 2 O 4 (LMO) is a desirable cathode material for Li-ion batteries due to its low cost, abundance, and high power capability. However, LMO suffers from limited cycle life that is triggered by manganese dissolution into the electrolyte during electrochemical cycling. Here, it is shown that single-layer graphene coatings suppress manganese dissolution, thus enhancing the performance and lifetime of LMO cathodes. Relative to lithium cells with uncoated LMO cathodes, cells with graphene-coated LMO cathodes provide improved capacity retention with enhanced cycling stability. X-ray photoelectron spectroscopy reveals that graphene coatings inhibit manganese depletion from the LMO surface. Additionally, transmission electron microscopy demonstrates that a stable solid electrolyte interphase is formed on graphene, which screens the LMO from direct contact with the electrolyte. Density functional theory calculations provide two mechanisms for the role of graphene in the suppression of manganese dissolution. First, common defects in single-layer graphene are found to allow the transport of lithium while concurrently acting as barriers for manganese diffusion. Second, graphene can chemically interact with Mn 3+ at the LMO electrode surface, promoting an oxidation state change to Mn 4+ , which suppresses dissolution.

  4. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    SciTech Connect (OSTI)

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  5. Doped carbon-sulfur species nanocomposite cathode for Li--S batteries

    DOE Patents [OSTI]

    Wang, Donghai; Xu, Tianren; Song, Jiangxuan

    2015-12-29

    We report a heteroatom-doped carbon framework that acts both as conductive network and polysulfide immobilizer for lithium-sulfur cathodes. The doped carbon forms chemical bonding with elemental sulfur and/or sulfur compound. This can significantly inhibit the diffusion of lithium polysulfides in the electrolyte, leading to high capacity retention and high coulombic efficiency.

  6. Design and performance of a 30 KV electron gun with ten independent cathodes & a magnetic lens.

    SciTech Connect (OSTI)

    Rudys, Joseph Matthew; Reed, Kim Warren

    2006-08-01

    Measurements on a 30 kV electron gun with ten independent cathodes, operating in a 6.5 Tesla (T) magnetic field are presented. An earlier paper covered the design of this electron gun [1]. Experimental results are compared to model predictions. Beam current is compared to theoretical space charge limited flow.

  7. Ion velocities in direct current arc plasma generated from compound cathodes

    SciTech Connect (OSTI)

    Zhirkov, I.; Rosen, J.; Eriksson, A. O.; Oerlikon Balzers Coating AG, Iramali 18, 9496 Balzers

    2013-12-07

    Arc plasma from Ti-C, Ti-Al, and Ti-Si cathodes was characterized with respect to charge-state-resolved ion energy. The evaluated peak velocities of different ion species in plasma generated from a compound cathode were found to be equal and independent on ion mass. Therefore, measured difference in kinetic energies can be inferred from the difference in ion mass, with no dependence on ion charge state. The latter is consistent with previous work. These findings can be explained by plasma quasineutrality, ion acceleration by pressure gradients, and electron-ion coupling. Increasing the C concentration in Ti-C cathodes resulted in increasing average and peak ion energies for all ion species. This effect can be explained by the cohesive energy rule, where material and phases of higher cohesive energy generally result in increasing energies (velocities). This is also consistent with the here obtained peak velocities around 1.37, 1.42, and 1.55 (10{sup 4} m/s) for ions from Ti{sub 0.84}Al{sub 0.16}, Ti{sub 0.90}Si{sub 0.10}, and Ti{sub 0.90}C{sub 0.10} cathodes, respectively.

  8. Cathode fall model and current-voltage characteristics of field emission driven direct current microplasmas

    SciTech Connect (OSTI)

    Venkattraman, Ayyaswamy

    2013-11-15

    The post-breakdown characteristics of field emission driven microplasma are studied theoretically and numerically. A cathode fall model assuming a linearly varying electric field is used to obtain equations governing the operation of steady state field emission driven microplasmas. The results obtained from the model by solving these equations are compared with particle-in-cell with Monte Carlo collisions simulation results for parameters including the plasma potential, cathode fall thickness, ion number density in the cathode fall, and current density vs voltage curves. The model shows good overall agreement with the simulations but results in slightly overpredicted values for the plasma potential and the cathode fall thickness attributed to the assumed electric field profile. The current density vs voltage curves obtained show an arc region characterized by negative slope as well as an abnormal glow discharge characterized by a positive slope in gaps as small as 10 ?m operating at atmospheric pressure. The model also retrieves the traditional macroscale current vs voltage theory in the absence of field emission.

  9. Palladium deuteride formation in the cathode of an electrochemical cell: An in situ neutron diffraction study

    SciTech Connect (OSTI)

    Rotella, F.J.; Richardson, J.W. Jr.; Redey, L.; Felcher, G.P.; Hitterman, R.L.; Kleb, R.

    1991-01-01

    In this report, neutron diffraction of palladium cathodes is utilized to reveal palladium deuteride formation within the crystal structure of the metal. The experiment described in this report demonstrates the efficacy of neutron powder diffraction as a tool for structural studies of metal deuterides/hydrides and the feasibility of in situ diffraction measurements from a working electrochemical cell. (JL)

  10. A flat-cathode thermionic injector for the PHERMEX Radiographic Facility

    SciTech Connect (OSTI)

    Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S.; Hughes, T.

    1993-06-01

    The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

  11. A flat-cathode thermionic injector for the PHERMEX Radiographic Facility

    SciTech Connect (OSTI)

    Kauppila, T.; Builta, L.; Burns, M.; Gregory, W.; Honaberger, D.; Watson, S. ); Hughes, T. )

    1993-01-01

    The PHERMEX (Pulsed High-Energy Radiographic Machine Emitting X-rays) standing-wave linear accelerator is a high-current electron beam generator used for flash-radiography. An improved electron gun has been designed employing a flat-thermionic cathode to replace the existing Pierce-geometry gun. The flat cathode yields increased current with the same applied voltage and cathode area as the Pierce gun. The ISIS code simulations indicate a beam current of 1.5 kA at 600 kV. The new geometry also reduces the probability for high voltage breakdown in the A-K gap. A reentrant magnet captures the expanding electron beam and a bucking coil nulls cathode-tinge field. A third coil is used to optimize the extraction field profile and reduce the effect of nonlinear space charge on the beam emittance. Time-resolved measurements of beam current and voltage have been made. In addition, a streak camera was used to measure beam emittance and spatial profile. Comparisons of measurements with simulations are presented.

  12. Arc-melting preparation of single crystal LaB.sub.6 cathodes

    DOE Patents [OSTI]

    Gibson, Edwin D.; Verhoeven, John D.

    1977-06-21

    A method for preparing single crystals of lanthanum hexaboride (LaB.sub.6) by arc melting a rod of compacted LaB.sub.6 powder. The method is especially suitable for preparing single crystal LaB.sub.6 cathodes for use in scanning electron microscopes (SEM) and scanning transmission electron microscopes (STEM).

  13. Modification of polymer velvet cathode via metallic Mo coating for enhancement of high-current electron emission performances

    SciTech Connect (OSTI)

    Xiong, Ying; Wang, Bing; Yi, Yong; Xia, Liansheng; Zhang, Huang

    2013-09-15

    The effect of surface Mo coating on the high-current electron emission performances for polymer velvet cathode has been investigated in a diode with A-K gap of 11.5 cm by the combination of time-resolved electrical diagnostic and temporal pressure variation. Compared with uncoated polymer velvet cathode under the single-pulsed emission mode, the Mo-coated one shows lower outgassing levels (?0.40 Pa L), slower cathode plasma expansion velocity (?2.30 cm/?s), and higher emission stability as evidences by the change in cathode current, temporal pressure variation, and diode perveance. Moreover, after Mo coating, the emission consistency of the polymer velvet cathode between two adjacent pulses is significantly improved in double-pulsed emission mode with ?500 ns interval between two pulses, which further confirms the effectiveness of Mo coating for enhancement of electron emission performance of polymer velvet cathodes. These results should be of interest to the high-repetitive high-power microwave systems with cold cathodes.

  14. AdvAnced

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AdvAnced test reActor At the InL advanced Unlike large, commercial power reactors, ATR is a low- temperature, low-pressure reactor. A nuclear reactor is basically an elaborate tool to produce power. reactors work by splitting atoms, the basic building blocks of matter, to release large amounts of energy. In commercial power reactors, that energy heats water, which creates steam. the steam turns turbines, generating electricity. What makes the Advanced test reactor, located at the Idaho national

  15. Institute for Advanced Studies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Video Collaboration » Education Opportunities » Institute for Advanced Studies Institute for Advanced Studies NMC leverages the strengths of three research universities to build joint programs, develop strategic partnerships, provide common organization and facilities. Contact Leader TBD LANL Program Administrator Pam Hundley (505) 663-5453 Email Building regional partnerships in education, leveraging strengths of three research universities The Institute for Advanced Studies (IAS) works with

  16. Advanced Burner Reactor Preliminary NEPA Data Study.

    SciTech Connect (OSTI)

    Briggs, L. L.; Cahalan, J. E.; Deitrich, L. W.; Fanning, T. H.; Grandy, C.; Kellogg, R.; Kim, T. K.; Yang, W. S.; Nuclear Engineering Division

    2007-10-15

    The Global Nuclear Energy Partnership (GNEP) is a new nuclear fuel cycle paradigm with the goals of expanding the use of nuclear power both domestically and internationally, addressing nuclear waste management concerns, and promoting nonproliferation. A key aspect of this program is fast reactor transmutation, in which transuranics recovered from light water reactor spent fuel are to be recycled to create fast reactor transmutation fuels. The benefits of these fuels are to be demonstrated in an Advanced Burner Reactor (ABR), which will provide a representative environment for recycle fuel testing, safety testing, and modern fast reactor design and safeguard features. Because the GNEP programs will require facilities which may have an impact upon the environment within the meaning of the National Environmental Policy Act of 1969 (NEPA), preparation of a Programmatic Environmental Impact Statement (PEIS) for GNEP is being undertaken by Tetra Tech, Inc. The PEIS will include a section on the ABR. In support of the PEIS, the Nuclear Engineering Division of Argonne National Laboratory has been asked to provide a description of the ABR alternative, including graphics, plus estimates of construction and operations data for an ABR plant. The compilation of this information is presented in the remainder of this report. Currently, DOE has started the process of engaging industry on the design of an Advanced Burner Reactor. Therefore, there is no specific, current, vendor-produced ABR design that could be used for this PEIS datacall package. In addition, candidate sites for the ABR vary widely as to available water, geography, etc. Therefore, ANL has based its estimates for construction and operations data largely on generalization of available information from existing plants and from the environmental report assembled for the Clinch River Breeder Reactor Plant (CRBRP) design [CRBRP, 1977]. The CRBRP environmental report was chosen as a resource because it thoroughly documents the extensive evaluation which was performed on the anticipated environmental impacts of that plant. This source can be referenced in the open literature and is publicly available. The CRBRP design was also of a commercial demonstration plant size - 975 MWth - which falls in the middle of the range of ABR plant sizes being considered (250 MWth to 2000 MWth). At the time the project was cancelled, the CRBRP had progressed to the point of having completed the licensing application to the Nuclear Regulatory Commission (NRC) and was in the process of receiving NRC approval. Therefore, it was felt that [CRBRP, 1977] provides some of the best available data and information as input to the GNEP PEIS work. CRBRP was not the source of all the information in this document. It is also expected that the CRBRP data will be bounding from the standpoint of commodity usage because fast reactor vendors will develop designs which will focus on commodity and footprint reduction to reduce the overall cost per kilowatt electric compared with the CRBR plant. Other sources used for this datacall information package are explained throughout this document and in Appendix A. In particular, see Table A.1 for a summary of the data sources used to generate the datacall information.

  17. Advanced Combustion FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen production technology, an air separation unit operating a cryogenic distillation process. For further information, see: - Oxy-Combustion - Advanced Combustion...

  18. Advanced Reciprocating Engine Systems

    Broader source: Energy.gov [DOE]

    The Advanced Reciprocating Engine Systems (ARES) program is designed to promote separate but parallel engine development between the major stationary, gaseous fueled engine manufacturers in the...

  19. Advanced Conversion Roadmap Workshop

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Deliverable: Roadmap for public dissemination which will guide Biomass program out-year R&D directions Workshop Objective Advanced Conversion Technology Roadmap Energy ...

  20. Overview | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APS Overview: Introduction APS Systems Map LINAC Booster Synchrotron Storage Ring Insertion Devices Experiment Hall LOMs & Beamlines Overview of the APS The Advanced Photon Source...

  1. Advanced Simulation Capability for

    Office of Environmental Management (EM)

    Advanced Simulation & Computing pro- grams as well as collaborating with the Offices of Science, Fossil Energy, and Nuclear Energy. Challenge Current groundwater and soil...

  2. Advanced Studies Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this professional development experience to help aspiring young researchers advance and excel in the next stage of their careers in academia or at a national laboratory. For...

  3. Beamlines | Advanced Photon Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamlines Beamlines Home Beamlines Directory Research Techniques Sectors Directory Status and Schedule Safety and Training Beamlines The Advanced Photon Source consists of 34...

  4. Advanced Rooftop Unit Control

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced-Rooftop-Unit-Control Sign In About | Careers | Contact | Investors | bpa.gov Search Policy & Reporting Expand Policy & Reporting EE Sectors Expand EE Sectors...

  5. ANL-85-51 ANL-85-51 FLOW-INDUCED VIBRATION OF CIRCULAR CYLINDRICAL...

    Office of Scientific and Technical Information (OSTI)

    Vibration on Fretting in Shell and Tube Heat Exchangers," Flow- Induced Vibration of Power Plant Components PVP-41, pp. 1-18, 1980, Table 1. Permission granted by the American...

  6. Development of the ANL plant dynamics code and control strategies for the supercritical carbon dioxide Brayton cycle and code validation with data from the Sandia small-scale supercritical carbon dioxide Brayton cycle test loop.

    SciTech Connect (OSTI)

    Moisseytsev, A.; Sienicki, J. J.

    2011-11-07

    Significant progress has been made in the ongoing development of the Argonne National Laboratory (ANL) Plant Dynamics Code (PDC), the ongoing investigation and development of control strategies, and the analysis of system transient behavior for supercritical carbon dioxide (S-CO{sub 2}) Brayton cycles. Several code modifications have been introduced during FY2011 to extend the range of applicability of the PDC and to improve its calculational stability and speed. A new and innovative approach was developed to couple the Plant Dynamics Code for S-CO{sub 2} cycle calculations with SAS4A/SASSYS-1 Liquid Metal Reactor Code System calculations for the transient system level behavior on the reactor side of a Sodium-Cooled Fast Reactor (SFR) or Lead-Cooled Fast Reactor (LFR). The new code system allows use of the full capabilities of both codes such that whole-plant transients can now be simulated without additional user interaction. Several other code modifications, including the introduction of compressor surge control, a new approach for determining the solution time step for efficient computational speed, an updated treatment of S-CO{sub 2} cycle flow mergers and splits, a modified enthalpy equation to improve the treatment of negative flow, and a revised solution of the reactor heat exchanger (RHX) equations coupling the S-CO{sub 2} cycle to the reactor, were introduced to the PDC in FY2011. All of these modifications have improved the code computational stability and computational speed, while not significantly affecting the results of transient calculations. The improved PDC was used to continue the investigation of S-CO{sub 2} cycle control and transient behavior. The coupled PDC-SAS4A/SASSYS-1 code capability was used to study the dynamic characteristics of a S-CO{sub 2} cycle coupled to a SFR plant. Cycle control was investigated in terms of the ability of the cycle to respond to a linear reduction in the electrical grid demand from 100% to 0% at a rate of 5%/minute. It was determined that utilization of turbine throttling control below 50% load improves the cycle efficiency significantly. Consequently, the cycle control strategy has been updated to include turbine throttle valve control. The new control strategy still relies on inventory control in the 50%-90% load range and turbine bypass for fine and fast generator output adjustments, but it now also includes turbine throttling control in the 0%-50% load range. In an attempt to investigate the feasibility of using the S-CO{sub 2} cycle for normal decay heat removal from the reactor, the cycle control study was extended beyond the investigation of normal load following. It was shown that such operation is possible with the extension of the inventory and the turbine throttling controls. However, the cycle operation in this range is calculated to be so inefficient that energy would need to be supplied from the electrical grid assuming that the generator could be capable of being operated in a motoring mode with an input electrical energy from the grid having a magnitude of about 20% of the nominal plant output electrical power level in order to maintain circulation of the CO{sub 2} in the cycle. The work on investigation of cycle operation at low power level will be continued in the future. In addition to the cycle control study, the coupled PDC-SAS4A/SASSYS-1 code system was also used to simulate thermal transients in the sodium-to-CO{sub 2} heat exchanger. Several possible conditions with the potential to introduce significant changes to the heat exchanger temperatures were identified and simulated. The conditions range from reactor scram and primary sodium pump failure or intermediate sodium pump failure on the reactor side to pipe breaks and valve malfunctions on the S-CO{sub 2} side. It was found that the maximum possible rate of the heat exchanger wall temperature change for the particular heat exchanger design assumed is limited to {+-}7 C/s for less than 10 seconds. Modeling in the Plant Dynamics Code has been compared with available data from the Sandia Natio

  7. Advanced uranium enrichment technologies

    SciTech Connect (OSTI)

    Merriman, R.

    1983-03-10

    The Advanced Gas Centrifuge and Atomic Vapor Laser Isotope Separation methods are described. The status and potential of the technologies are summarized, the programs outlined, and the economic incentives are noted. How the advanced technologies, once demonstrated, might be deployed so that SWV costs in the 1990s can be significantly reduced is described.

  8. Cathode performance during two beam operation of the high current high polarization electron gun for eRHIC

    SciTech Connect (OSTI)

    Rahman, O.; Ben-Zvi, I.; Degen, C.; Gassner, D. M.; Lambiase, R.; Meng, W.; Pikin, A.; Rao, T.; Sheehy, B.; Skaritka, J.; Wang, E.; Pietz, J.; Ackeret, M.; Yeckel, C.; Miller, R.; Dobrin, E.; Thompson, K.

    2015-05-03

    Two electron beams from two activated bulk GaAs photocathodes were successfully combined during the recent beam test of the High Current High Polarization Electron gun for eRHIC. The beam test took place in Stangenes Industries in Palo Alto, CA, where the cathodes were placed in diagonally opposite locations inside the high voltage shroud. No significant cross talking between the cathodes was found for the pertinent vacuum and low average current operation, which is very promising towards combining multiple beams for higher average current. This paper describes the cathode preparation, transport and cathode performance in the gun for the combining test, including the QE and lifetimes of the photocathodes at various steps of the experiment.

  9. Co-flow anode/cathode supply heat exchanger for a solid-oxide fuel cell assembly

    DOE Patents [OSTI]

    Haltiner, Jr., Karl J.; Kelly, Sean M.

    2005-11-22

    In a solid-oxide fuel cell assembly, a co-flow heat exchanger is provided in the flow paths of the reformate gas and the cathode air ahead of the fuel cell stack, the reformate gas being on one side of the exchanger and the cathode air being on the other. The reformate gas is at a substantially higher temperature than is desired in the stack, and the cathode gas is substantially cooler than desired. In the co-flow heat exchanger, the temperatures of the reformate and cathode streams converge to nearly the same temperature at the outlet of the exchanger. Preferably, the heat exchanger is formed within an integrated component manifold (ICM) for a solid-oxide fuel cell assembly.

  10. A review comparing cathodic arcs and high power impulse magnetron sputtering (HiPIMS)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Anders, André

    2014-09-02

    In this study, high power impulse magnetron sputtering (HiPIMS) has been in the center of attention over the last years as it is an emerging physical vapor deposition (PVD) technology that combines advantages of magnetron sputtering with various forms of energetic deposition of films such as ion plating and cathodic arc plasma deposition. It should not come at a surprise that many extension and variations of HiPIMS make use, intentionally or unintentionally, of previously discovered approaches to film processing such as substrate surface preparation by metal ion sputtering and phased biasing for film texture and stress control. Therefore, in thismore » review, an overview is given on some historical developments and features of cathodic arc and HiPIMS plasmas, showing commonalities and differences. To limit the scope, emphasis is put on plasma properties, as opposed to surveying the vast literature on specific film materials and their properties.« less

  11. Final Technical Report- Back-gate Field Emission-based Cathode RF Electron Gun

    SciTech Connect (OSTI)

    McGuire, Gary; Martin, Allen; Noonan, John

    2010-10-30

    The objective was to complete the design of an electron gun which utilizes a radio frequency (RF) power source to apply a voltage to a field emission (FE) cathode, a so called cold cathode, in order to produce an electron beam. The concept of the RF electron gun was originally conceived at Argonne National Laboratory but never reduced to practice. The research allowed the completion of the design based upon the integration of the FE electron source. Compared to other electron guns, the RF gun is very compact, less than one third the size of other comparable guns, and produces a high energy (to several MeV), high quality, high power electron beam with a long focal length with high repetition rates. The resultant electron gun may be used in welding, materials processing, analytical equipment and waste treatment.

  12. Nitrogen Atom Energy Distributions in a Hollow-cathode Planar Sputtering Magnetron

    SciTech Connect (OSTI)

    D.N. Ruzic; M.J. Goeckner; Samuel A. Cohen; Zhehui Wang

    1999-06-01

    Energy distributions of N atoms in a hollow-cathode planar sputtering magnetron were obtained by use of optical emission spectroscopy. A characteristic line, N I 8216.3 , well-separated from molecular nitrogen emission bands, was identified. Jansson's nonlinear spectral deconvolution method, refined by minimization of {chi}w , was used to obtain the optimal deconvolved spectra. These showed nitrogen atom energies from 1 eV to beyond 500 eV. Based on comparisons with VFTRIM results, we propose that the energetic N atoms are generated from N2+ ions after these ions are accelerated through the sheath and dissociatively reflect from the cathode.

  13. The evolution of ion charge states in cathodic vacuum arc plasmas: a review

    SciTech Connect (OSTI)

    Anders, Andre

    2011-12-18

    Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the noise in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

  14. Measurements of the Ion Species of Cathodic Arc Plasma in an Axial Magnetic Field

    SciTech Connect (OSTI)

    Oks, Efim; Anders, Andre

    2010-10-19

    Metal and gas ion species and their charge state distributions were measured for pulsed copper cathodic arcs in argon background gas in the presence of an axial magnetic field. It was found that changing the cathode position relative to anode and ion extraction system as well as increasing the gas pressure did not much affect the arc burning voltage and the related power dissipation. However, the burning voltage and power dissipation greatly increased as the magnetic field strength was increased. The fraction of metal ions and the mean ion charge state were reduced as the discharge length was increased. The observations can be explained by the combination of charge exchange collisions and electron impact ionization. They confirm that previously published data on characteristic material-dependent charge state distributions (e.g., Anders and Yushkov, J. Appl. Phys., Vol. 91, pp. 4824-4832, 2002) are not universal but valid for high vacuum conditions and the specifics of the applied magnetic fields.

  15. Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries

    SciTech Connect (OSTI)

    Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

    2011-01-24

    Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

  16. The influence of deposits on palladium cathodes in D[sub 2]O electrolysis

    SciTech Connect (OSTI)

    Lihn, C.J.; Wan, C.C.; Wan, C.M.; Perng, T.P. )

    1993-11-01

    Platinum and silicon have been found deposited on the palladium cathode during the electrolysis of a 0.1 M LiOD solution with a platinum anode in a glass cell. Various techniques including surface analysis, cyclic voltammetry, and electrochemical permeation were used to study the surface deposits, electrochemical deuterium-sorption behavior, and permeation rate of deuterium into palladium, respectively. It was shown that palladium cathodes were contaminated by platinum and silicon deposits after a certain period of electrolysis. These deposits could affect the electrochemical processes during electrolysis. The contamination may be a cause of the sporadic results reported in [open quotes]cold fusion[close quotes] research. 18 refs., 15 figs.

  17. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the Voltage Fade Issue with Li-Mn Rich Oxide Cathode Materials Principal Investigator: Anthony Burrell Ali Abouimrane, Daniel Abraham, Khalil Amine, Mahalingam Balasubramanian, Javier Bareno Garcia-Ontiveros, Ilias Belharouak, Roy Benedek, Ira Bloom, Zonghai Chen, Dennis Dees, Kevin Gallagher, Hakim Iddir, Brian Ingram, Christopher Johnson, Wenquan Lu, Nenad Markovic, Dean Miller, Yan Qin, Yang Ren, Michael Thackeray, Lynn Trahey, and John Vaughey Chemical Sciences and Engineering Division

  18. Investigation of reports of fusion reactions occurring at the cathode in glow discharges

    SciTech Connect (OSTI)

    Ellison, C.H.; Mahaffey, J.A.

    1996-01-01

    Recent reports of deuteron-deuteron (d-d) neutrons resulting from nuclear reactions in or at the palladium cathode of a deuterium glow discharge were investigated. The equipment, techniques, and experimental procedures are discussed in detail, as well as various possible mechanisms to produce such reactions. The results of this investigation do not confirm the presence of d-d reactions. 15 refs., 9 figs.

  19. Facile synthesis of lithium sulfide nanocrystals for use in advanced rechargeable batteries

    SciTech Connect (OSTI)

    Li, Xuemin; Wolden, Colin A.; Ban, Chunmei; Yang, Yongan

    2015-12-03

    This work reports a new method of synthesizing anhydrous lithium sulfide (Li2S) nanocrystals and demonstrates their potential as cathode materials for advanced rechargeable batteries. Li2S is synthesized by reacting hydrogen sulfide (H2S) with lithium naphthalenide (Li-NAP), a thermodynamically spontaneous reaction that proceeds to completion rapidly at ambient temperature and pressure. The process completely removes H2S, a major industrial waste, while cogenerating 1,4-dihydronaphthalene, itself a value-added chemical that can be used as liquid fuel. The phase purity, morphology, and homogeneity of the resulting nanopowders were confirmed by X-ray diffraction and scanning electron microscopy. The synthesized Li2S nanoparticles (100 nm) were assembled into cathodes, and their performance was compared to that of cathodes fabricated using commercial Li2S micropowders (15 ?m). As a result, electrochemical analyses demonstrated that the synthesized Li2S were superior in terms of (dis)charge capacity, cycling stability, output voltage, and voltage efficiency.

  20. Facile synthesis of lithium sulfide nanocrystals for use in advanced rechargeable batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xuemin; Wolden, Colin A.; Ban, Chunmei; Yang, Yongan

    2015-12-03

    This work reports a new method of synthesizing anhydrous lithium sulfide (Li2S) nanocrystals and demonstrates their potential as cathode materials for advanced rechargeable batteries. Li2S is synthesized by reacting hydrogen sulfide (H2S) with lithium naphthalenide (Li-NAP), a thermodynamically spontaneous reaction that proceeds to completion rapidly at ambient temperature and pressure. The process completely removes H2S, a major industrial waste, while cogenerating 1,4-dihydronaphthalene, itself a value-added chemical that can be used as liquid fuel. The phase purity, morphology, and homogeneity of the resulting nanopowders were confirmed by X-ray diffraction and scanning electron microscopy. The synthesized Li2S nanoparticles (100 nm) were assembledmore » into cathodes, and their performance was compared to that of cathodes fabricated using commercial Li2S micropowders (1–5 μm). As a result, electrochemical analyses demonstrated that the synthesized Li2S were superior in terms of (dis)charge capacity, cycling stability, output voltage, and voltage efficiency.« less

  1. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  2. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M.; Peng, Marcus Y.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard C.

    1996-01-01

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  3. Development of Ni1-xCoxO as the cathode/interconnect contact for solid oxide fuel cells

    SciTech Connect (OSTI)

    Lu, Zigui; Xia, Guanguang; Templeton, Joshua D.; Li, Xiaohong S.; Nie, Zimin; Yang, Zhenguo; Stevenson, Jeffry W.

    2011-06-01

    A new type of material, Ni1-xCoxO, was developed for solid oxide fuel cell (SOFC) cathode/interconnect contact applications. The phase structure, coefficient of thermal expansion, sintering behavior, electrical property, and mechanical bonding strength of these materials were evaluated against the requirements of the SOFC cathode/interconnect contact. A dense cathode/interconnect contact layer was developed through reaction sintering from Ni and Co metal powders. An area specific resistance (ASR) as low as 5.5 mohm.cm2 was observed after 1000 h exposure in air at 800 C for the LSM/Ni0.33Co0.67O/AISI441 assembly. Average mechanical strengths of 6.8 and 5.0 MPa were obtained for the cathode/contact/cathode and interconnect/contact/interconnect structures, respectively. The significantly low ASR was probably due to the dense structure and therefore improved electrical conductivity of the Ni0.33Co0.67O contact and the good bonding of the interfaces between the contact and the cathode, and between the contact and the interconnect.

  4. Advanced Vehicles Manufacturing Projects | Department of Energy

    Energy Savers [EERE]

    Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects Advanced Vehicles Manufacturing Projects DOE-LPO_ATVM-Economic-Growth_Thumbnail.png DRIVING ECONOMIC GROWTH: ADVANCED TECHNOLOGY VEHICLES

  5. Advanced Target Effects Modeling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Target Effects Modeling for Ion Accelerators and other High-Energy-Density Experiments Alice Koniges 1,a , Wangyi Liu 1 , Steven Lidia 1 , Thomas Schenkel 1 , John Barnard...

  6. Advanced Combustion Turbines

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that will accelerate turbine performance and efficiency beyond current state-of-the-art and reduce the risk to market for novel and advanced turbine-based power cycles....

  7. Effect of Particle Size and Operating Conditions on Pt3Co PEMFC Cathode Catalyst Durability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gummalla, Mallika; Ball, Sarah; Condit, David; Rasouli, Somaye; Yu, Kang; Ferreira, Paulo; Myers, Deborah; Yang, Zhiwei

    2015-05-29

    The initial performance and decay trends of polymer electrolyte membrane fuel cells (PEMFC) cathodes with Pt3Co catalysts of three mean particle sizes (4.9 nm, 8.1 nm, and 14.8 nm) with identical Pt loadings are compared. Even though the cathode based on 4.9 nm catalyst exhibited the highest initial electrochemical surface area (ECA) and mass activity, the cathode based on 8.1 nm catalyst showed better initial performance at high currents. Owing to the low mass activity of the large particles, the initial performance of the 14.8 nm Pt3Co-based electrode was the lowest. The performance decay rate of the electrodes with themore » smallest Pt3Co particle size was the highest and that of the largest Pt3Co particle size was lowest. Interestingly, with increasing number of decay cycles (0.6 to 1.0 V, 50 mV/s), the relative improvement in performance of the cathode based on 8.1 nm Pt3Co over the 4.9 nm Pt3Co increased, owing to better stability of the 8.1 nm catalyst. The electron microprobe analysis (EMPA) of the decayed membrane-electrode assembly (MEA) showed that the amount of Co in the membrane was lower for the larger particles, and the platinum loss into the membrane also decreased with increasing particle size. This suggests that the higher initial performance at high currents with 8.1 nm Pt3Co could be due to lower contamination of the ionomer in the electrode. Furthermore, lower loss of Co from the catalyst with increased particle size could be one of the factors contributing to the stability of ECA and mass activity of electrodes with larger cathode catalyst particles. To delineate the impact of particle size and alloy effects, these results are compared with prior work from our research group on size effects of pure platinum catalysts. The impact of PEMFC operating conditions, including upper potential, relative humidity, and temperature on the alloy catalyst decay trends, along with the EMPA analysis of the decayed MEAs, are reported.« less

  8. Advanced Materials Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SunShot Grand Challenge: Regional Test Centers Advanced Materials Laboratory Home/Tag:Advanced Materials Laboratory - Structures of the zwitterionic coatings synthesized for this study. Permalink Gallery Investigations on Anti-biofouling Zwitterionic Coatings for MHK Is Now in Press Analysis, Capabilities, Energy, News, News & Events, Renewable Energy, Research & Capabilities, Water Power Investigations on Anti-biofouling Zwitterionic Coatings for MHK Is Now in Press Sandia's Marine

  9. Advanced Ultraviolet Spectroradiometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Ultraviolet Spectroradiometer A specialized instrument used to measure a portion of the ultraviolet (UV) spectrum was recently installed at the SGP central facility. The instrument, called an advanced UV spectroradiometer, was developed by Dr. Lee Harrison of the State University of New York at Albany and is funded by the United States Department of Agriculture (USDA). The sun emits a vast amount of energy in the form of electro- magnetic radiation. We see some of this energy as visible

  10. Advanced Scientific Computing Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Scientific Computing Research Advanced Scientific Computing Research Discovering, developing, and deploying computational and networking capabilities to analyze, model, simulate, and predict complex phenomena important to the Department of Energy. Get Expertise Pieter Swart (505) 665 9437 Email Pat McCormick (505) 665-0201 Email Dave Higdon (505) 667-2091 Email Fulfilling the potential of emerging computing systems and architectures beyond today's tools and techniques to deliver

  11. Advanced Studies Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute » Advanced Studies Institute Science of Signatures Advanced Studies Institute Developing innovative solution strategies for problems that support the forward deployment theme of the Science of Signatures Pillar, and building skills needed for succesful research program development. Contact Institute Director Charles Farrar (505) 665-0860 Email UCSD EI Director Michael Todd (858) 534-5951 Executive Administrator Ellie Vigil (505) 667-2818 Email Administrative Assistant Rebecca Duran

  12. Advances in Performance Assessment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Researchers at Sandia National Laboratories originated an innovative approach to determining the safety of geologic repositories for radioactive waste disposal called "performance assessment", PA. The discipline of PA continues to advance within the Defense Waste Management Programs as computing capabilities advance and as the discipline is used in an expanding portfolio of applications both nationally and internationally. Do Radioactive Waste Disposal Options Assure Safety for

  13. Advanced Optical Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Optical Technologies The Advanced Optical Components and Technologies program develops, creates and provides critical optical components for laser-based missions at LLNL. Past projects focused on kinoform phase plates for LLNL's Nova laser and on large-area, submicron-pitch holographic diffraction gratings for LLNL's Petawatt (1015 watt) ultrashort-pulse laser. Today, the optical team designs and fabricates a variety of custom diffractive optics for researchers worldwide. Included are

  14. Advanced Simulation and Computing

    National Nuclear Security Administration (NNSA)

    NA-ASC-117R-09-Vol.1-Rev.0 Advanced Simulation and Computing PROGRAM PLAN FY09 October 2008 ASC Focal Point Robert Meisner, Director DOE/NNSA NA-121.2 202-586-0908 Program Plan Focal Point for NA-121.2 Njema Frazier DOE/NNSA NA-121.2 202-586-5789 A Publication of the Office of Advanced Simulation & Computing, NNSA Defense Programs i Contents Executive Summary ----------------------------------------------------------------------------------------------- 1 I. Introduction

  15. Novel Fluorescent Cationic Phospholipid, O-4-Napthylimido-1-Butyl...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL ... LIFE SCIENCES; ANHYDRIDES; CARDIOLIPIN; DNA; ENCAPSULATION; HYDRATION; LECITHINS; ...

  16. Nanofilm Coatings Improve Battery Performance - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Nanofilm Coatings Improve Battery Performance Argonne National Laboratory Contact ANL About This Technology <p> TEM 2.5-nm-thick nano-coated ultrathin film on lithium-ion cathode particle surface; coating is highly uniform, in contrast to films applied through conventional technology (for reference, bar in lower-left corner measures 5 nm)</p> TEM 2.5-nm-thick nano-coated ultrathin

  17. Advanced Accelerator Concepts Final Report

    SciTech Connect (OSTI)

    Wurtele, Jonathan S.

    2014-05-13

    A major focus of research supported by this Grant has been on the ALPHA antihydrogen trap. We first trapped antihydrogen in 2010 and soon thereafter demonstrated trapping for 1000s. We now have observed resonant quantum interactions with antihydrogen. These papers in Nature and Nature Physics report the major milestones in anti-atom trapping. The success was only achieved through careful work that advanced our understanding of collective dynamics in charged particle systems, the development of new cooling and diagnostics, and in- novation in understanding how to make physics measurements with small numbers of anti-atoms. This research included evaporative cooling, autoresonant excitation of longitudinal motion, and centrifugal separation. Antihydrogen trapping by ALPHA is progressing towards the point when a important theories believed by most to hold for all physical systems, such as CPT (Charge-Parity-Time) invariance and the Weak Equivalence Principle (matter and antimatter behaving the same way under the influence of gravity) can be directly tested in a new regime. One motivation for this test is that most accepted theories of the Big Bang predict that we should observe equal amounts of matter and antimatter. However astrophysicists have found very little antimatter in the universe. Our experiment will, if successful over the next seven years, provide a new test of these ideas. Many earlier detailed and beautiful tests have been made, but the trapping of neutral antimatter allows us to explore the possibility of direct, model-independent tests. Successful cooling of the anti atoms, careful limits on systematics and increased trapping rates, all planned for our follow-up experiment (ALPHA-II) will reach unrivaled precision. CPT invariance implies that the spectra of hydrogen and antihydrogen should be identical. Spectra can be measured in principle with great precision, and any di#11;erences we might observe would revolutionize fundamental physics. This is the physics motivation for our experiment, one that requires only a few dozen researchers but must effectively integrate plasma, accelerator, atomic, and fundamental physics, as well as combine numerous technologies in the control, manipulation, and measurement of neutral and non-neutral particles. The ELENA ring (to which we hope to contribute, should funding be provided) is expect, when completed, to significantly enhance the performance of antihydrogen trapping by increasing by a factor of 100 the number of antiprotons that can be successfully trapped and cooled. ELENA operation is scheduled to commence in 2017. In collaboration with LBNL scientists, we proposed a frictional cooling scheme. This is an alternative cooling method to that used by ELENA. It is less complicated, experimentally unproven, and produces a lower yield of cold antiprotons. Students and postdoctoral researchers work on the trapping, cooling, transport, and nonlinear dynamics of antiprotons bunches that are provided by the AD to ALPHA; they contribute to the operation of the experiment, to software development, and to the design and operation of experiments. Students are expected to spend at summers at CERN while taking courses; after completion of courses they typically reside at CERN for most of the half-year run. The Antiproton Decelerator [AD] at CERN, along with its experiments, is the only facility in the world where antiprotons can be trapped and cooled and combined with positrons to form cold antihydrogen, with the ultimate goal of studying CPT violation and, subsequently, gravitational interactions of antimatter. Beyond the ALPHA experiment, the group worked on beam physics problems including limits on the average current in a time-dependent period cathode and new methods to create longitudinally coherent high repetition rate soft x-ray sources and wide bandwidth mode locked x-ray lasers. We completed a detailed study of quantum mechanical effects in the transit time cooling of muons.

  18. Conversion Technologies for Advanced Biofuels - Carbohydrates...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Conversion Roadmap Workshop Workshop on Conversion Technologies for Advanced Biofuels - Carbohydrates Conversion Technologies for Advanced Biofuels - Carbohydrates...

  19. Advanced Vehicle Electrification and Transportation Sector Electrifica...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Vehicle Electrification and Transportation Sector Electrification Plug-in Hybrid (PHEV) Vehicle Technology Advancement and Demonstration Activity Advanced Vehicle...

  20. Fact Sheet: Energy Storage Technology Advancement Partnership...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Advancement Partnership (October 2012) Fact Sheet: Energy Storage Technology Advancement Partnership (October 2012) The Energy Storage Technology Advancement Partnership ...

  1. Advanced fuel chemistry for advanced engines.

    SciTech Connect (OSTI)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  2. Advanced servomanipulator development

    SciTech Connect (OSTI)

    Kuban, D.P.

    1985-01-01

    The Advanced Servomanipulator (ASM) System consists of three major components: the ASM slave, the dual arm master controller (DAMC) or master, and the control system. The ASM is remotely maintainable force-reflecting servomanipulator developed at the Oak Ridge National Laboratory (ORNL) as part of the Consolidated Fuel Reprocessing Program. This new manipulator addresses requirements of advanced nuclear fuel reprocessing with emphasis on force reflection, remote maintainability, reliability, radiation tolerance, and corrosion resistance. The advanced servomanipulator is uniquely subdivided into remotely replaceable modules which will permit in situ manipulator repair by spare module replacement. Manipulator modularization and increased reliability are accomplished through a force transmission system that uses gears and torque tubes. Digital control algorithms and mechanical precision are used to offset the increased backlash, friction, and inertia resulting from the gear drives. This results in the first remotely maintainable force-reflecting servomanipulator in the world.

  3. Chemistry of SOFC Cathode Surfaces: Fundamental Investigation and Tailoring of Electronic Behavior

    SciTech Connect (OSTI)

    Yildiz, Bilge; Heski, Clemens

    2013-08-31

    1) Electron tunneling characteristics on La0.7Sr0.3MnO3 (LSM) thin-film surfaces were studied up to 580oC in 10-3mbar oxygen pressure, using scanning tunneling microscopy/ spectroscopy (STM/STS). A threshold-like drop in the tunneling current was observed at positive bias in STS, which is interpreted as a unique indicator for the activation polarization in cation oxygen bonding on LSM cathodes. Sr-enrichment was found on the surface at high temperature using Auger electron spectroscopy, and was accompanied by a decrease in tunneling conductance in STS. This suggests that Sr-terminated surfaces are less active for electron transfer in oxygen reduction compared to Mn-terminated surfaces on LSM. 2) Effects of strain on the surface cation chemistry and the electronic structure are important to understand and control for attaining fast oxygen reduction kinetics on transition metal oxides. Here, we demonstrate and mechanistically interpret the strain coupling to Sr segregation, oxygen vacancy formation, and electronic structure on the surface of La0.7Sr0.3MnO3 (LSM) thin films as a model system. Our experimental results from x-ray photoelectron spectroscopy and scanning tunneling spectroscopy are discussed in light of our first principles-based calculations. A stronger Sr enrichment tendency and a more facile oxygen vacancy formation prevail for the tensile strained LSM surface. The electronic structure of the tensile strained LSM surface exhibits a larger band gap at room temperature, however, a higher tunneling conductance near the Fermi level than the compressively strained LSM at elevated temperatures in oxygen. Our findings suggest lattice strain as a key parameter to tune the reactivity of perovskite transition metal oxides with oxygen in solid oxide fuel cell cathodes. 3) Cation segregation on perovskite oxide surfaces affects vastly the oxygen reduction activity and stability of solid oxide fuel cell (SOFC) cathodes. A unified theory that explains the physical origins of this phenomenon is therefore needed for designing cathode materials with optimal surface chemistry. We quantitatively assessed the elastic and electrostatic interactions of the dopant with the surrounding lattice as the key driving forces for segregation on model perovskite compounds, LnMnO3 (host cation Ln=La, Sm). Our approach combines surface chemical analysis with X-ray photoelectron and Auger electron spectroscopy on model dense thin films, and computational analysis with density functional theory (DFT) calculations and analytical models. Elastic energy differences were systematically induced in the system by varying the radius of the selected dopants (Ca, Sr, Ba) with respect to the host cations (La, Sm) while retaining the same charge state. Electrostatic energy differences were introduced by varying the distribution of charged oxygen and cation vacancies in our models. Varying the oxygen chemical potential in our experiments induced changes in both the elastic energy and electrostatic interactions. Our results quantitatively demonstrate that the mechanism of dopant segregation on perovskite oxides includes both the elastic and electrostatic energy contributions. A smaller size mismatch between the host and dopant cations and a chemically expanded lattice were found to reduce the segregation level of the dopant and to enable more stable cathode surfaces. Ca-doped LaMnO3 was found to have the most stable surface composition with the least cation segregation among the compositions surveyed. The diffusion kinetics of the larger dopants, Ba and Sr, was found to be slower, and can kinetically trap the segregation at reduced temperatures despite the larger elastic energy driving force. Lastly, scanning probe image-contrast showed that the surface chemical heterogeneities made of dopant oxides upon segregation were electronically insulating. The consistency between the results obtained from experiments, DFT calculations and analytical theory in this work provides a predictive capability to tailor the cathode surface compositions for high-performance SO

  4. Advanced Containment System

    DOE Patents [OSTI]

    Kostelnik, Kevin M. (Idaho Falls, ID); Kawamura, Hideki (Tokyo, JP); Richardson, John G. (Idaho Falls, ID); Noda, Masaru (Tokyo, JP)

    2005-02-08

    An advanced containment system for containing buried waste and associated leachate. The advanced containment system comprises a plurality of casing sections with each casing section interlocked to an adjacent casing section. Each casing section includes a complementary interlocking structure that interlocks with the complementary interlocking structure on an adjacent casing section. A barrier filler substantially fills the casing sections and may substantially fill the spaces of the complementary interlocking structure to form a substantially impermeable barrier. Some of the casing sections may include sensors so that the casing sections and the zone of interest may be remotely monitored after the casing sections are emplaced in the ground.

  5. Mechanical and electrochemical response of a LiCoO2 cathode using reconstructed microstructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mendoza, Hector; Roberts, Scott Alan; Brunini, Victor E.; Grillet, Anne M.

    2016-01-02

    As LiCoO2 cathodes are charged, delithiation of the LiCoO2 active material leads to an increase in the lattice spacing, causing swelling of the particles. When these particles are packed into a bicontinuous, percolated network, as is the case in a battery electrode, this swelling leads to the generation of significant mechanical stress. In this study we performed coupled electrochemical-mechanical simulations of the charging of a LiCoO2 cathode in order to elucidate the mechanisms of stress generation and the effect of charge rate and microstructure on these stresses. Energy dispersive spectroscopy combined with scanning electron microscopy imaging was used to createmore » 3D reconstructions of a LiCoO2 cathode, and the Conformal Decomposition Finite Element Method is used to automatically generate computational meshes on this reconstructed microstructure. Replacement of the ideal solution Fickian diffusion model, typically used in battery simulations, with a more general non-ideal solution model shows substantially smaller gradients of lithium within particles than is typically observed in the literature. Using this more general model, lithium gradients only appear at states of charge where the open-circuit voltage is relatively constant. While lithium gradients do affect the mechanical stress state in the particles, the maximum stresses are always found in the fully-charged state and are strongly affected by the local details of the microstructure and particle-to-particle contacts. These coupled electrochemical-mechanical simulations begin to yield insight into the partitioning of volume change between reducing pore space and macroscopically swelling the electrode. Lastly, preliminary studies that include the presence of the polymeric binder suggest that it can greatly impact stress generation and that it is an important area for future research.« less

  6. Lattice Expansion of LSCF-6428 Cathodes Measured by In-situ XRD during SOFC Operation

    SciTech Connect (OSTI)

    Hardy, John S.; Templeton, Jared W.; Edwards, Danny J.; Lu, Zigui; Stevenson, Jeffry W.

    2012-01-03

    A new capability has been developed for analyzing solid oxide fuel cells (SOFCs). This paper describes the initial results of in-situ x-ray diffraction (XRD) of the cathode on an operating anode-supported solid oxide fuel cell. It has been demonstrated that XRD measurements of the cathode can be performed simultaneously with electrochemical measurements of cell performance or electrochemical impedance spectroscopy (EIS). While improvements to the technique are still to be made, the XRD pattern of a lanthanum strontium cobalt ferrite (LSCF) cathode with the composition La0.6Sr0.4Co0.2Fe0.8O3-? (LSCF-6428) was found to continually but gradually change over the course of more than 60 hours of operation in air under typical SOFC operating conditions. It was determined that the most significant change was a gradual increase in the cubic lattice parameters of the LSCF from 3.92502 (as determined from the integration of the first 20 hours of XRD patterns) to 3.92650 (from the integration of the last 20 hours). This analysis also revealed that there were several peaks from unidentified minor phases that increased in intensity over this timeframe. After a temporary loss of airflow early in the test, the cell generated between 225 and 250 mW/cm2 for the remainder of the test. A large low frequency arc in the impedance spectra suggests the cell performance was gas diffusion limited and that there is room for improvement in air delivery to the cell.

  7. Conceptual design of a high throughput electrorefining of a uranium by using graphite cathode

    SciTech Connect (OSTI)

    Lee, J.H.; Kang, Y.H.; Hwang, S.C.; Park, S.B.; Shim, J.B.; Lee, H.S.; Kim, E.H.; Park, S.W.

    2007-07-01

    Conceptual designing of a high throughput electro-refiner was performed by using basic experimental data and a commercial computational fluid dynamic code, CFX. An electro-refiner concept equipped with a graphite cathode bundle was designed to recover a high purity uranium product continuously without a noble metal contamination. The performance of the process for a decontamination of a noble metal in a uranium product was evaluated as a function of the process parameters such as the rotation speeds of the stirrer and the anode basket. (authors)

  8. Method for analyzing the mass of a sample using a cold cathode ionization source mass filter

    DOE Patents [OSTI]

    Felter, Thomas E.

    2003-10-14

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  9. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    DOE Patents [OSTI]

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  10. Theory and simulation of backbombardment in single-cell thermionic-cathode electron guns

    SciTech Connect (OSTI)

    Edelen, J.  P.; Biedron, S.  G.; Harris, J.  R.; Milton, S.  V.; Lewellen, J.  W.

    2015-04-01

    This paper presents a comparison between simulation results and a first principles analytical model of electron back-bombardment developed at Colorado State University for single-cell, thermionic-cathode rf guns. While most previous work on back-bombardment has been specific to particular accelerator systems, this work is generalized to a wide variety of guns within the applicable parameter space. The merits and limits of the analytic model will be discussed. This paper identifies the three fundamental parameters that drive the back-bombardment process, and demonstrates relative accuracy in calculating the predicted back-bombardment power of a single-cell thermionic gun.

  11. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan; Bridges, Craig A.; Paranthaman, Mariappan Parans; Dai, Sheng; Brown, Gilbert M.

    2015-10-07

    A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.

  12. Chemically modified thermal-spray zinc anodes for galvanic cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Bullard, S.J.; Holcomb, G.R.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-12-01

    Humectants, substances that promote the retention of moisture, were applied to new and previously aged thermal-sprayed Zn anodes to improve the performance of galvanic cathodic protection systems. Anodes on steel-reinforced concrete were treated with aqueous solutions of the humectants lithium nitrate (LiNO{sub 3}) and lithium bromide (LiBr). LiBr was the most beneficial humectant, increasing the average galvanic current density of new thermal-sprayed Zn anodes by as much as a factor of six.

  13. Humectants To Augment Current From Metallized Zinc Cathodic Protection Systems on Concrete

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Covino Jr., Bernard S.; Cramer, Stephen D.; Russell, James H. Russell; Bullard, Sophie J.; Collins, W. Keith; Bennett, Jack E.; Soltesz, Steven M.; Laylor, H. Martin

    2002-12-01

    Cathodic protection (CP) systems using thermal-sprayed zinc anodes are employed to mitigate the corrosion process in reinforced concrete structures. However, the performance of the anodes is improved by moisture at the anode-concrete interface. Research was conducted to investigate the effect of hydrophilic chemical additives, humectants, on the electrical performance and service life of zinc anodes. Lithium bromide and lithium nitrate were identified as feasible humectants with lithium bromide performing better under galvanic CP and lithium nitrate performing better under impressed current CP. Both humectants improved the electrical operating characteristics of the anode and increased the service life by up to three years.

  14. Advanced Test Reactor Tour

    ScienceCinema (OSTI)

    Miley, Don

    2013-05-28

    The Advanced Test Reactor at Idaho National Laboratory is the foremost nuclear materials test reactor in the world. This virtual tour describes the reactor, how experiments are conducted, and how spent nuclear fuel is handled and stored. For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

  15. Advanced Bioeconomy Feedstocks Conference

    Broader source: Energy.gov [DOE]

    This year’s Advanced Bioeconomy Feedstocks Conference will be held from June 9–10, 2015 in New Orleans, Louisiana. The conference will gather supply chain leaders of the bioeconomy to examine supply chain technologies, business models, and partnerships. BETO Director Jonathan Male and Technology Manager Steve Thomas will be speaking at the conference.

  16. Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes' effects on thermal & cycling stability

    SciTech Connect (OSTI)

    Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; Zhou, Yong -Ning; Yang, Xiao -Qing

    2015-12-07

    Structural transformation behaviors of several typical oxide cathode materials during a heating process are reviewed in detail to provide in-depth understanding of the key factors governing the thermal stability of these materials. Furthermore, we also discuss applying the information about heat induced structural evolution in the study of electrochemically induced structural changes. All these discussions are expected to provide valuable insights for designing oxide cathode materials with significantly improved structural stability for safe, long-life lithium ion batteries, as the safety of lithium-ion batteries is a critical issue. As a result, it is widely accepted that the thermal instability of the cathodes is one of the most critical factors in thermal runaway and related safety problems.

  17. Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes' effects on thermal & cycling stability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; Zhou, Yong -Ning; Yang, Xiao -Qing

    2015-12-07

    Structural transformation behaviors of several typical oxide cathode materials during a heating process are reviewed in detail to provide in-depth understanding of the key factors governing the thermal stability of these materials. Furthermore, we also discuss applying the information about heat induced structural evolution in the study of electrochemically induced structural changes. All these discussions are expected to provide valuable insights for designing oxide cathode materials with significantly improved structural stability for safe, long-life lithium ion batteries, as the safety of lithium-ion batteries is a critical issue. As a result, it is widely accepted that the thermal instability of themore » cathodes is one of the most critical factors in thermal runaway and related safety problems.« less

  18. Strategies to curb structural changes of lithium/transition metal oxide cathode materials & the changes' effects on thermal & cycling stability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Xiqian; Hu, Enyuan; Bak, Seongmin; Zhou, Yong -Ning; Yang, Xiao -Qing

    2015-12-07

    Structural transformation behaviors of several typical oxide cathode materials during a heating process are reviewed in detail to provide in-depth understanding of the key factors governing the thermal stability of these materials. Furthermore, we also discuss applying the information about heat induced structural evolution in the study of electrochemically induced structural changes. All these discussions are expected to provide valuable insights for designing oxide cathode materials with significantly improved structural stability for safe, long-life lithium ion batteries, as the safety of lithium-ion batteries is a critical issue. As a result, it is widely accepted that the thermal instability of themore »cathodes is one of the most critical factors in thermal runaway and related safety problems.« less

  19. An experiment to test the viability of a gallium-arsenide cathode in a SRF electron gun

    SciTech Connect (OSTI)

    Kewisch,J.; Ben-Zvi, I.; Rao, T.; Burrill, A.; Pate, D.; Wu, Q.; Todd, R.; Wang, E.; Bluem, H.; Holmes, D.; Schultheiss, T.

    2009-05-04

    Strained gallium arsenide cathodes are used in electron guns for the production of polarized electrons. In order to have a sufficient quantum efficiency lifetime of the cathode the vacuum in the gun must be 10{sup -11} Torr or better, so that the cathode is not destroyed by ion back bombardment or through contamination with residual gases. All successful polarized guns are DC guns, because such vacuum levels can not be obtained in normal conducting RF guns. A superconductive RF gun may provide a sufficient vacuum level due to cryo-pumping of the cavity walls. We report on the progress of our experiment to test such a gun with normal GaAs-Cs crystals.

  20. Comparison of SOFC Cathode Microstructure Quantified using X-ray Nanotomography and Focused Ioni Beam-scanning Electron Microscopy

    SciTech Connect (OSTI)

    G Nelson; W Harris; J Lombardo; J Izzo Jr.; W Chiu; P Tanasini; M Cantoni; J Van herle; C Comninellis; et al.

    2011-12-31

    X-ray nanotomography and focused ion beam scanning electron microscopy (FIB-SEM) have been applied to investigate the complex 3D microstructure of solid oxide fuel cell (SOFC) electrodes at spatial resolutions of 45 nm and below. The application of near edge differential absorption for x-ray nanotomography and energy selected backscatter detection for FIB-SEM enable elemental mapping within the microstructure. Using these methods, non-destructive 3D x-ray imaging and FIB-SEM serial sectioning have been applied to compare three-dimensional elemental mapping of the LSM, YSZ, and pore phases in the SOFC cathode microstructure. The microstructural characterization of an SOFC cathode is reported based on these measurements. The results presented demonstrate the viability of x-ray nanotomography as a quantitative characterization technique and provide key insights into the SOFC cathode microstructure.

  1. Comparison of SOFC Cathode Microstructure Quantified using X-ray Nanotomography and Focused Ion Beam - Scanning Electron Microscopy

    SciTech Connect (OSTI)

    Nelson, George J.; Harris, William H.; Lombardo, Jeffrey J.; Izzo, Jr., John R.; Chiu, W. K. S.; Tanasini, Pietro; Cantoni, Marco; Van herle, Jan; Comninellis, Christos; Andrews, Joy C.; Liu, Yijin; Pianetta, Piero; Chu, Yong

    2011-03-24

    X-ray nanotomography and focused ion beam scanning electron microscopy (FIB-SEM) have been applied to investigate the complex 3D microstructure of solid oxide fuel cell (SOFC) electrodes at spatial resolutions of 45 nm and below. The application of near edge differential absorption for x-ray nanotomography and energy selected backscatter detection for FIBSEM enable elemental mapping within the microstructure. Using these methods, non-destructive 3D x-ray imaging and FIBSEM serial sectioning have been applied to compare three-dimensional elemental mapping of the LSM, YSZ, and pore phases in the SOFC cathode microstructure. The microstructural characterization of an SOFC cathode is reported based on these measurements. The results presented demonstrate the viability of x-ray nanotomography as a quantitative characterization technique and provide key insights into the SOFC cathode microstructure.

  2. Fabrication and characterization of lithium manganese nickel oxide sputtered thin film cathodes for lithium-ion batteries

    SciTech Connect (OSTI)

    Baggetto, Loic; Unocic, Raymond R; Dudney, Nancy J; Veith, Gabriel M

    2012-01-01

    Li-rich and stoichiometric Li1Mn1.5Ni0.5O4 (LMNO) cathode films have been prepared by magnetron sputtering. Sputtering from a Li stoichiometric target yields Li-rich films composed of spinel, layered and monoclinic phases. Films obtained from a Li deficient target are mostly made of a spinel phase and little layered material. The resulting cathode thin films have good capacity retention and very high rate capability. The reaction mechanism has been investigated by XRD and HRTEM and evidences the reversible formation of a spinel phase, as is also found for the powder samples. The film geometry enables to understand the effect of coatings (ZnO or LiPON). Coating high voltage cathodes reduces the coulombic losses but at the price of rate performance. Nonetheless, these coated sputtered electrode thin films offer a higher rate capability than other LMNO thin films obtained by other physical vapor deposition techniques.

  3. Advanced Reactor Technologies | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nuclear Reactor Technologies » Advanced Reactor Technologies Advanced Reactor Technologies Advanced Reactor Technologies Advanced Reactor Technologies The Office of Advanced Reactor Technologies (ART) sponsors research, development and deployment (RD&D) activities through its Next Generation Nuclear Plant (NGNP), Advanced Reactor Concepts (ARC), and Advanced Small Modular Reactor (aSMR) programs to promote safety, technical, economical, and environmental advancements of innovative

  4. Development of a high average current polarized electron source with long cathode operational lifetime

    SciTech Connect (OSTI)

    C. K. Sinclair; P. A. Adderley; B. M. Dunham; J. C. Hansknecht; P. Hartmann; M. Poelker; J. S. Price; P. M. Rutt; W. J. Schneider; M. Steigerwald

    2007-02-01

    Substantially more than half of the electromagnetic nuclear physics experiments conducted at the Continuous Electron Beam Accelerator Facility of the Thomas Jefferson National Accelerator Facility (Jefferson Laboratory) require highly polarized electron beams, often at high average current. Spin-polarized electrons are produced by photoemission from various GaAs-based semiconductor photocathodes, using circularly polarized laser light with photon energy slightly larger than the semiconductor band gap. The photocathodes are prepared by activation of the clean semiconductor surface to negative electron affinity using cesium and oxidation. Historically, in many laboratories worldwide, these photocathodes have had short operational lifetimes at high average current, and have often deteriorated fairly quickly in ultrahigh vacuum even without electron beam delivery. At Jefferson Lab, we have developed a polarized electron source in which the photocathodes degrade exceptionally slowly without electron emission, and in which ion back bombardment is the predominant mechanism limiting the operational lifetime of the cathodes during electron emission. We have reproducibly obtained cathode 1/e dark lifetimes over two years, and 1/e charge density and charge lifetimes during electron beam delivery of over 2?105???C/cm2 and 200 C, respectively. This source is able to support uninterrupted high average current polarized beam delivery to three experimental halls simultaneously for many months at a time. Many of the techniques we report here are directly applicable to the development of GaAs photoemission electron guns to deliver high average current, high brightness unpolarized beams.

  5. Oscillation phenomena of a plasma produced by an AC driven hot cathode

    SciTech Connect (OSTI)

    Takahashi, Yuki; Miyamoto, Naoki; Kasuya, Toshiro; Wada, Motoi

    2012-11-06

    Amplitude of oscillating discharge current has been measured for Bernas-type ion source equipped with an alternating current heated hot tungsten filament cathode. Measurements have been made by changing the filament diameter from 0.2 mm to 0.7 mm, and by changing the DC discharge current from 0.1 A to 1.5 A. The fluctuation amplitude of the discharge current was found decreased as the diameter of the filament was enlarged. The fluctuation amplitude took the minimum value at a frequency from several hundred Hz to 1 kHz depending upon the filament diameter and DC discharge current. For example, the relative oscillation amplitude was the smallest at 1 kHz for 0.7 mm diameter filament. Increase in discharge current had reduced the minimum oscillation amplitude, and increased the frequency at which the oscillating amplitude took the minimum. Fundamental mechanisms relevant to these characteristics of oscillation amplitude of discharge current from an AC driven hot cathode filament are discussed.

  6. Simulations for preliminary design of a multi-cathode DC electron gun for eRHIC

    SciTech Connect (OSTI)

    Wu, Q.; Ben-Zvi, I.; Chang, X.; Skaritka, J.

    2010-05-23

    The proposed electron ion collider, eRHIC, requires a large average polarized electron current of 50 mA, which is more than 20 times higher than the present experimental output of a single, highly polarized electron source, based on cesiated super-lattice GaAs. To meet eRHIC's requirement for current, we designed a multicathode DC electron gun for injection. The twenty-four GaAs cathodes emit electrons in sequence, then are combined on axis by a rotating field (or 'funnelled'). In addition to its ultra-high vacuum requirements, the multicathode DC electron gun will place high demand on the electric field symmetry, the magnetic field shielding, and on preventing arcing. In this paper, we discuss our results from a 3D simulation of the latest model for this gun. The findings will guide the actual design in future. Their preliminary design of a multi-cathode electron source for eRHIC demonstrated tolerable fields and reasonable results in both field and particle simulations.

  7. Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Feng; Xin, Huolin L.; Nordlund, Dennis; Li, Yuyi; Quan, Matthew K.; Cheng, Lei; Weng, Tsu -Chien; Liu, Yijin; Doeff, Marca M.

    2016-01-11

    Controlling surface and interfacial properties of battery materials is key to improving performance in rechargeable Li-ion devices. Surface reconstruction from a layered to a rock salt structure in metal oxide cathode materials is commonly observed and results in poor high-voltage cycling performance, impeding attempts to improve energy density. Hierarchically structured LiNi0.4Mn0.4Co0.2O2 (NMC-442) spherical powders, made by spray pyrolysis, exhibit local elemental distribution gradients that deviate from the global NMC-442 composition; specifically, they are Ni-rich and Mn-poor at particle surfaces. These materials demonstrate improved Coulombic efficiencies, discharge capacities, and high-voltage capacity retention in lithium half-cell configurations. The subject powders show superiormore » resistance against surface reconstruction due to the tailored surface chemistry, compared to conventional NMC-442 materials. This paves the way towards the development of a new generation of robust and stable high-energy NMC cathodes for Li-ion batteries.« less

  8. Combined Theoretical and Experimental Analysis of Processes Determining Cathode Performance in Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Kukla, Maija M.; Kotomin, Eugene Alexej; Merkle, R.; Mastrikov, Yuri; Maier, J.

    2013-02-11

    Solid oxide fuel cells (SOFC) are under intensive investigation since the 1980s as these devices open the way for ecologically clean direct conversion of the chemical energy into electricity, avoiding the efficiency limitation by Carnots cycle for thermochemical conversion. However, the practical development of SOFC faces a number of unresolved fundamental problems, in particular concerning the kinetics of the electrode reactions, especially oxygen reduction reaction. We review recent experimental and theoretical achievements in the current understanding of the cathode performance by exploring and comparing mostly three materials: (La,Sr)MnO3 (LSM), (La,Sr)(Co,Fe)O3 (LSCF) and (Ba,Sr)(Co,Fe)O3 (BSCF). Special attention is paid to a critical evaluation of advantages and disadvantages of BSCF, which shows the best cathode kinetics known so far for oxides. We demonstrate that it is the combined experimental and theoretical analysis of all major elementary steps of the oxygen reduction reaction which allows us to predict the rate determining steps for a given material under specific operational conditions and thus control and improve SOFC performance.

  9. Design and operating characteristics of cathodic protection systems associated with large seawater intake reinforced concrete structures in the Arabian Gulf

    SciTech Connect (OSTI)

    Ali, M.; Chaudhary, Z.; Al-Muhid, T.M.M.

    1999-07-01

    The large reinforced concrete seawater intake structures, which are part of a cooling system in several petrochemical plants located in the Arabian Gulf, have been catholically protected to arrest chloride-induced corrosion of the steel reinforcement. The cathodic protection systems have an operating history of 1--5 years. The design and operating features of the cathodic protection systems are described and discussed. Monitoring data of each system collected over the years since commissioning of the systems are described and discussed to evaluate performance of each system.

  10. Advanced Technology Vehicle Testing

    SciTech Connect (OSTI)

    James Francfort

    2004-06-01

    The goal of the U.S. Department of Energy's Advanced Vehicle Testing Activity (AVTA) is to increase the body of knowledge as well as the awareness and acceptance of electric drive and other advanced technology vehicles (ATV). The AVTA accomplishes this goal by testing ATVs on test tracks and dynamometers (Baseline Performance testing), as well as in real-world applications (Fleet and Accelerated Reliability testing and public demonstrations). This enables the AVTA to provide Federal and private fleet managers, as well as other potential ATV users, with accurate and unbiased information on vehicle performance and infrastructure needs so they can make informed decisions about acquiring and operating ATVs. The ATVs currently in testing include vehicles that burn gaseous hydrogen (H2) fuel and hydrogen/CNG (H/CNG) blended fuels in internal combustion engines (ICE), and hybrid electric (HEV), urban electric, and neighborhood electric vehicles. The AVTA is part of DOE's FreedomCAR and Vehicle Technologies Program.

  11. Advanced steel reheat furnace

    SciTech Connect (OSTI)

    Moyeda, D.; Sheldon, M.; Koppang, R.; Lanyi, M.; Li, X.; Eleazer, B.

    1997-10-01

    Energy and Environmental Research Corp. (EER) under a contract from the Department of Energy is pursuing the development and demonstration of an Advanced Steel Reheating Furnace. This paper reports the results of Phase 1, Research, which has evaluated an advanced furnace concept incorporating two proven and commercialized technologies previously applied to other high temperature combustion applications: EER`s gas reburn technology (GR) for post combustion NOx control; and Air Product`s oxy-fuel enrichment air (OEA) for improved flame heat transfer in the heating zones of the furnace. The combined technologies feature greater production throughput with associated furnace efficiency improvements; lowered NOx emissions; and better control over the furnace atmosphere, whether oxidizing or reducing, leading to better control over surface finish.

  12. Advanced Separation Consortium

    SciTech Connect (OSTI)

    2006-01-01

    The Center for Advanced Separation Technologies (CAST) was formed in 2001 under the sponsorship of the US Department of Energy to conduct fundamental research in advanced separation and to develop technologies that can be used to produce coal and minerals in an efficient and environmentally acceptable manner. The CAST consortium consists of seven universities - Virginia Tech, West Virginia University, University of Kentucky, Montana Tech, University of Utah, University of Nevada-Reno, and New Mexico Tech. The consortium brings together a broad range of expertise to solve problems facing the US coal industry and the mining sector in general. At present, a total of 60 research projects are under way. The article outlines some of these, on topics including innovative dewatering technologies, removal of mercury and other impurities, and modelling of the flotation process. 1 photo.

  13. TTU Advanced Doppler Radar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TTU Advanced Doppler Radar - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  14. Accelerating Advanced Material Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials Research in the Information Age Accelerating Advanced Material Development NERSC Science Gateway a 'Google of Material Properties' October 31, 2011 Linda Vu, lvu@lbl.gov, +1 510 495 2402 Kristin Persson is one of the founding scientists behind the Materials Project, a computational tool aimed at taking the guesswork out of new materials discoveries, especially those aimed at energy applications like batteries. (Roy Kaltschmidt, LBNL) New materials are crucial to building a clean energy

  15. Advanced Light Source

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light Source - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  16. Advanced Biofuels Workshop

    Gasoline and Diesel Fuel Update (EIA)

    August 1, 2012 In Attendance U.S. Energy Information Administration 1000 Independence Ave. SW, Room 2E-069 Washington, DC 20585 Adam Sieminski EIA Terry Higgins Hart Downstream Energy Services Peter Ryus RSB Services Foundation Zia Haq DOE Robert Kozak Atlantic Biomass Conversion Leticia Phillips UNICA/Brazillian Sugarecane Industry Assoc. Paul Kamp Leifmark, LLC/Inbicon Biomass Steve Gerber Fiberight Joanne Ivancic Advanced Biofuels USA John G. Cowie Agenda 2020 Technology Alliance Jeff Hazle

  17. Joining of Advanced Thermoplastics

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3, 2012 Joining of Advanced Thermoplastics Ed Herderick, PhD George Ritter, PhD Applications Engineer Principal Engineer Materials Group EWI 614.688.5111 Sean Flowers eherderick@ewi.org Ultrasonics Group Thermoplastic Composites: Outline * Lighter than metals, tougher than thermosets, can be welded and recycled * Examples of joining approaches * Bio-based composites * Nano-reinforced composites * High temperature thermoplastics Joining of Engineering Thermoplastics MATERIAL * Polyether-ether

  18. Advanced Energy Guides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Guides Shanti Pless National Renewable Energy Laboratory shanti.pless@nrel.gov 303-384-6365 April 4 2013 2 | Building Technologies Office eere.energy.gov Advanced Energy Design Guides Provide prescriptive energy savings guidance and recommendations by building type and geographic location: * Design packages and strategies to help owners and designers achieve 50% site energy savings over Standard 90.1 * Two series: - 30% savings over 90.1-1999 - 50% savings over 90.1-2004 * Educational

  19. Advanced Feedstock Preprocessing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 | Bioenergy Technologies Office eere.energy.gov 1.2.2.1 Advanced Feedstock Preprocessing March 25, 2015 David N. Thompson Idaho National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Feedstock Interface 2 | Bioenergy Technologies Office Goal Statement * Problem: - Feedstock properties are managed because they have conversion cost impacts - The meaning of "quality" varies with conversion pathway - The process impact of

  20. Advanced Feedstock Supply System

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Feedstock Supply System Erin M Searcy, PhD November 27, 2012 Biomass Feedstock Logistics Energy Efficiency & Renewable Energy eere.energy.gov 2 * Technologies exist to supply biomass for energy production, but they have limits * Cost, quantity, quality * I'll present a potential solution: biomass commoditization Key Point Energy Efficiency & Renewable Energy eere.energy.gov 3 * There are a variety of lignocellulosic biomass sources that could be used for energy production -