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Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Selection and preparation of activated carbon for fuel gas storage  

DOE Patents [OSTI]

Increasing the surface acidity of active carbons can lead to an increase in capacity for hydrogen adsorption. Increasing the surface basicity can facilitate methane adsorption. The treatment of carbons is most effective when the carbon source material is selected to have a low ash content i.e., below about 3%, and where the ash consists predominantly of alkali metals alkali earth, with only minimal amounts of transition metals and silicon. The carbon is washed in water or acid and then oxidized, e.g. in a stream of oxygen and an inert gas at an elevated temperature.

Schwarz, James A. (Fayetteville, NY); Noh, Joong S. (Syracuse, NY); Agarwal, Rajiv K. (Las Vegas, NV)

1990-10-02T23:59:59.000Z

2

Ammonia-Activated Mesoporous Carbon Membranes for Gas Separations  

SciTech Connect (OSTI)

Porous carbon membranes, which generally show improved chemical and thermal stability compared to polymer membranes, have been used in gas separations for many years. In this work, we show that the post-synthesis ammonia treatment of porous carbon at elevated temperature can improve the permeance and selectivity of these membranes for the separation of carbon dioxide and hydrocarbons from permanent gases. Hierarchically structured porous carbon membranes were exposed to ammonia gas at temperatures ranging from 850 C to 950 C for up to 10 min and the N{sub 2}, CO{sub 2}, and C{sub 3}H{sub 6} permeances were measured for these different membranes. Higher treatment temperatures and longer exposure times resulted in higher gas permeance values. In addition, CO{sub 2}/N{sub 2} and C{sub 3}H{sub 6}/N{sub 2} selectivities increased by a factor of 2 as the treatment temperature and time increased up to a temperature and time of 900 C, 10 min. Higher temperatures showed increased permeance but decreased selectivity indicating excess pore activation. Nitrogen adsorption measurements show that the ammonia treatment increased the porosity of the membrane while elemental analysis revealed the presence of nitrogen-containing surface functionalities in the treated carbon membranes. Thus, ammonia treatment at high temperature provides a controlled method to introduce both added microporosity and surface functionality to enhance gas separations performance of porous carbon membranes.

Mahurin, Shannon Mark [ORNL; Lee, Jeseung [ORNL; Wang, Xiqing [ORNL; Dai, Sheng [ORNL

2011-01-01T23:59:59.000Z

3

The production of activated silica with carbon dioxide gas  

E-Print Network [OSTI]

the titratable alkalinity is not reduced. The by-product of the reaction is ammonium hydroxI. de which keeps the alkalinity of the sol the same as that of the starting diluted sodium silicate. The usual method for producing N-Sol A Is to mix dI. lute sodium... safely at about twice the safe storage concen- tration of the Baylis sol. This permits a twofold de- crease in the capaci. ty of the storage tanks (10). Hay also has done a great deal of development wozk 10 in which he has suggested the use of carbon...

Hayes, William Bell

1956-01-01T23:59:59.000Z

4

Capture of CO2 from flue gas by vacuum pressure swing adsorption using activated carbon beads  

Science Journals Connector (OSTI)

Vacuum pressure swing adsorption (VPSA) for CO2 capture has attracted much research effort with the...2...adsorbent materials. In this work, a new adsorbent, that is, pitch-based activated carbon bead (AC bead), ...

Chunzhi Shen; Jianguo Yu; Ping Li; Carlos A. Grande; Alirio E. Rodrigues

2011-02-01T23:59:59.000Z

5

Modeling high-pressure adsorption of gas mixtures on activated carbon and coal using a simplified local-density model  

SciTech Connect (OSTI)

The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO{sub 2} sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO{sub 2} on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO{sub 2} on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties.

Fitzgerald, J.E.; Robinson, R.L.; Gasem, K.A.M. [Oklahoma State University, Stillwater, OK (United States). School of Chemical Engineering

2006-11-07T23:59:59.000Z

6

Continuous process preparation of activated silica with low carbon dioxide content gas  

E-Print Network [OSTI]

for storage to prevent gel formation. This sol hns loss tendency to gel and. csn be sai'ely stored and used st approxirately twice the safe storage concentrat1on of the ILsylis sol, Hay (8) bas published. the results of a great deal of de- velopment work... of equipment operation which gave an activated product should. be accurate enough to cause activation in different, but similar equipment. Operating conditions found. 8o /0 /0 Figure ~ /oo /00o /moog C e/ Time, //oorq Gel Time oF Activated Sols Based...

Burdett, Joseph Walton

1954-01-01T23:59:59.000Z

7

Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil fuels such as coal, oil, and gas, have caused a substantial increase  

E-Print Network [OSTI]

Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil-caused CO2 emissions and to remove CO2 from the atmosphere. 2.0 What is carbon sequestration? The term "carbon sequestration" is used to describe both natural and deliberate CARBON,INGIGATONSPERYEAR 1.5 Fossil

8

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D.; Bourcier, William L.

2014-08-19T23:59:59.000Z

9

Carbon ion pump for removal of carbon dioxide from combustion gas and other gas mixtures  

DOE Patents [OSTI]

A novel method and system of separating carbon dioxide from flue gas is introduced. Instead of relying on large temperature or pressure changes to remove carbon dioxide from a solvent used to absorb it from flue gas, the ion pump method, as disclosed herein, dramatically increases the concentration of dissolved carbonate ion in solution. This increases the overlying vapor pressure of carbon dioxide gas, permitting carbon dioxide to be removed from the downstream side of the ion pump as a pure gas. The ion pumping may be obtained from reverse osmosis, electrodialysis, thermal desalination methods, or an ion pump system having an oscillating flow in synchronization with an induced electric field.

Aines, Roger D. (Livermore, CA); Bourcier, William L. (Livermore, CA)

2010-11-09T23:59:59.000Z

10

Activated Carbon Injection  

ScienceCinema (OSTI)

History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

None

2014-07-22T23:59:59.000Z

11

Activated Carbon Injection  

SciTech Connect (OSTI)

History of the Clean Air Act and how the injection of carbon into a coal power plant's flu smoke can reduce the amount of mercury in the smoke.

None

2014-07-16T23:59:59.000Z

12

Nano Structured Activated Carbon for Hydrogen Storge  

SciTech Connect (OSTI)

Development of a nanostructured synthetic carbons materials that have been synthesized by thermal-decomposition of aromatic rich polyether such as poly(ether ether ketone) (PEEK) is reported. These polymers based nanostructured carbons efficacious for gas adsorption and storage and have Brunauer-Emmett-Teller (BET) surface area of more than 3000 m2/g, and with average pore diameter of < 2nm. Surface-area, pore characteristics, and other critical variables for selecting porous materials of high gas adsorption capacities are presented. Analysis of the fragments evolved under various carbonization temperatures, and the correlation between the activation and carbonization temperatures provides a mechanistic perspective of the pore evolution during activation. Correlations between gas (N2 and H2) adsorption capacity and porous texture of the materials have been established. The materials possess excellent hydrogen storage properties, with hydrogen storage capacity up to 7.4 wt% (gravimetric) and ~ 45 g H2 L-1 (volumetric) at -196oC and 6.0 MPa.

Israel Cabasso; Youxin Yuan

2013-02-27T23:59:59.000Z

13

New Funding Boosts Carbon Capture, Solar Energy and High Gas...  

Office of Environmental Management (EM)

Boosts Carbon Capture, Solar Energy and High Gas Mileage Cars and Trucks New Funding Boosts Carbon Capture, Solar Energy and High Gas Mileage Cars and Trucks June 11, 2009 -...

14

Activated carbon to the rescue  

SciTech Connect (OSTI)

This article describes the response to pipeline spill of ethylene dichloride (EDC) on the property of an oil company. Activated carbon cleanup proceedure was used. During delivery, changeout, transport, storage, thermal reactivation, and return delivery to the site, the carbon never came into direct contact with operating personnel or the atmosphere. More than 10,000 tones of dredge soil and 50 million gallons of surface water were processed during the emergency response.

Sen, S. [Calgon Carbon Corp., Pittsburgh, PA (United States)

1996-03-01T23:59:59.000Z

15

Carbon Dioxide Capture and Sequestration by Adsorption on Activated Carbon  

Science Journals Connector (OSTI)

Abstract Activated Carbon (AC) materials was selected as suitable adsorbent for the carbon dioxide (CO2) capture and a numerical analysis was carried out to study the rate of adsorption of the gas on ACs. A one dimensional mathematical model was proposed based on the Dubinin's Theory of Volume Filling of Micropores, and analyzed along with the unsteady heat transfer. A parametric analysis was carried out to study the effect of various crucial parameters like radius of bed, cooling fluid temperature, initial bed temperature and heat transfer coefficient on the adsorption amount. The results show that lower bed radius was ideal for obtaining high amount of CO2 adsorbed assuming constant packing density. Also, a high heat transfer coefficient up to 100 Wm-2K-1 and low cooling fluid temperature of 283 K was necessary for speeding up the process. High initial bed temperature also supports greater adsorption amount under the same conditions.

Reema Saxena; Vinod Kumar Singh; E. Anil Kumar

2014-01-01T23:59:59.000Z

16

System and method for coproduction of activated carbon and steam/electricity  

DOE Patents [OSTI]

A system and method for producing activated carbon comprising carbonizing a solid carbonaceous material in a carbonization zone of an activated carbon production apparatus (ACPA) to yield a carbonized product and carbonization product gases, the carbonization zone comprising carbonaceous material inlet, char outlet and carbonization gas outlet; activating the carbonized product via activation with steam in an activation zone of the ACPA to yield activated carbon and activation product gases, the activation zone comprising activated carbon outlet, activation gas outlet, and activation steam inlet; and utilizing process gas comprising at least a portion of the carbonization product gases or a combustion product thereof; at least a portion of the activation product gases or a combustion product thereof; or a combination thereof in a solid fuel boiler system that burns a solid fuel boiler feed with air to produce boiler-produced steam and flue gas, the boiler upstream of an air heater within a steam/electricity generation plant, said boiler comprising a combustion zone, a boiler-produced steam outlet and at least one flue gas outlet.

Srinivasachar, Srivats (Sturbridge, MA); Benson, Steven (Grand Forks, ND); Crocker, Charlene (Newfolden, MN); Mackenzie, Jill (Carmel, IN)

2011-07-19T23:59:59.000Z

17

Gas flux and carbonate occurrence at a shallow seep of thermogenic natural gas  

E-Print Network [OSTI]

010-0184-0 ORIGINAL Gas flux and carbonate occurrence atof thermogenic natural gas Franklin S. Kinnaman & Justine B.comprehensive survey of gas flux at Brian Seep yielded a

2010-01-01T23:59:59.000Z

18

Removing a small quantity of THT from gas storage groundwater through air stripping and gas-phase carbon adsorption  

SciTech Connect (OSTI)

This paper deals with the response to a case of contaminated groundwater located in France. The natural gas is stored during summer in porous underground rocks. When energy requirements increase (particularly in winter), gas is drawn off, but water is also pumped during this operation. The water has a strong characteristic odour of the TetraHydroThiophene (THT), which has been used by Gaz de France as an additive in order to detect gas leakages because of its strong odour. Unfortunately, the presence of THT in medium other than natural gas can be responsible for safety problems. Gas stripping combined with adsorption on granular activated carbon was chosen to obtain removal of THT from the groundwater. The gas to water ratio for stripping column is higher than usual and the gas used for stripping was recycled in order to prevent air pollution. Carbon consumption is approximately 3 tons a year. 8 refs., 5 figs., 2 tabs.

Girod, J.F.; Leclerc, J.P.; Muhr, H. [CNRS, Nancy (France)] [and others

1996-12-31T23:59:59.000Z

19

Activated carbon fiber composite material and method of making  

DOE Patents [OSTI]

An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

2001-01-01T23:59:59.000Z

20

Activated carbon fiber composite material and method of making  

DOE Patents [OSTI]

An activated carbon fiber composite for separation and purification, or catalytic processing of fluids is described. The activated composite comprises carbon fibers rigidly bonded to form an open, permeable, rigid monolith capable of being formed to near-net-shape. Separation and purification of gases are effected by means of a controlled pore structure that is developed in the carbon fibers contained in the composite. The open, permeable structure allows the free flow of gases through the monolith accompanied by high rates of adsorption. By modification of the pore structure and bulk density the composite can be rendered suitable for applications such as gas storage, catalysis, and liquid phase processing.

Burchell, Timothy D. (Oak Ridge, TN); Weaver, Charles E. (Knoxville, TN); Chilcoat, Bill R. (Knoxville, TN); Derbyshire, Frank (Lexington, KY); Jagtoyen, Marit (Lexington, KY)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Compare All CBECS Activities: Natural Gas Use  

U.S. Energy Information Administration (EIA) Indexed Site

Natural Gas Use Natural Gas Use Compare Activities by ... Natural Gas Use Total Natural Gas Consumption by Building Type Commercial buildings in the U.S. used a total of approximately 2.0 trillion cubic feet of natural gas in 1999. Natural gas use was not dominated by any single activity, with seven activities each accounting for between 9 and 13 percent of all commercial natural gas use. Figure showing total natural gas consumption by building type. If you need assistance viewing this page, please call 202-586-8800. Natural Gas Consumption per Building by Building Type Inpatient health care buildings used by far the most natural gas per building. Figure showing natural gas consumption per building by building type. If you need assistance viewing this page, please call 202-586-8800.

22

Carbon Dioxide Hydrate Process for Gas Separation from a Shifted Synthesis Gas Stream  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sequestration and Sequestration and Gasification Technologies Carbon DioxiDe HyDrate ProCess for Gas seParation from a sHifteD syntHesis Gas stream Background One approach to de-carbonizing coal is to gasify it to form fuel gas consisting predominately of carbon monoxide and hydrogen. This fuel gas is sent to a shift conversion reactor where carbon monoxide reacts with steam to produce carbon dioxide (CO 2 ) and hydrogen. After scrubbing the CO 2 from the fuel, a stream of almost pure hydrogen stream remains, which can be burned in a gas turbine or used to power a fuel cell with essentially zero emissions. However, for this approach to be practical, it will require an economical means of separating CO 2 from mixed gas streams. Since viable options for sequestration or reuse of CO

23

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Broader source: Energy.gov (indexed) [DOE]

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

24

Carbon Dioxide Capture from Flue Gas Using Dry Regenerable Sorbents  

SciTech Connect (OSTI)

Regenerable sorbents based on sodium carbonate (Na{sub 2}CO{sub 3}) can be used to separate carbon dioxide (CO{sub 2}) from coal-fired power plant flue gas. Upon thermal regeneration and condensation of water vapor, CO{sub 2} is released in a concentrated form that is suitable for reuse or sequestration. During the research project described in this report, the technical feasibility and economic viability of a thermal-swing CO{sub 2} separation process based on dry, regenerable, carbonate sorbents was confirmed. This process was designated as RTI's Dry Carbonate Process. RTI tested the Dry Carbonate Process through various research phases including thermogravimetric analysis (TGA); bench-scale fixed-bed, bench-scale fluidized-bed, bench-scale co-current downflow reactor testing; pilot-scale entrained-bed testing; and bench-scale demonstration testing with actual coal-fired flue gas. All phases of testing showed the feasibility of the process to capture greater than 90% of the CO{sub 2} present in coal-fired flue gas. Attrition-resistant sorbents were developed, and these sorbents were found to retain their CO{sub 2} removal activity through multiple cycles of adsorption and regeneration. The sodium carbonate-based sorbents developed by RTI react with CO{sub 2} and water vapor at temperatures below 80 C to form sodium bicarbonate (NaHCO3) and/or Wegscheider's salt. This reaction is reversed at temperatures greater than 120 C to release an equimolar mixture of CO{sub 2} and water vapor. After condensation of the water, a pure CO{sub 2} stream can be obtained. TGA testing showed that the Na{sub 2}CO3 sorbents react irreversibly with sulfur dioxide (SO{sub 2}) and hydrogen chloride (HCl) (at the operating conditions for this process). Trace levels of these contaminants are expected to be present in desulfurized flue gas. The sorbents did not collect detectable quantities of mercury (Hg). A process was designed for the Na{sub 2}CO{sub 3}-based sorbent that includes a co-current downflow reactor system for adsorption of CO{sub 2} and a steam-heated, hollow-screw conveyor system for regeneration of the sorbent and release of a concentrated CO{sub 2} gas stream. An economic analysis of this process (based on the U.S. Department of Energy's National Energy Technology Laboratory's [DOE/NETL's] 'Carbon Capture and Sequestration Systems Analysis Guidelines') was carried out. RTI's economic analyses indicate that installation of the Dry Carbonate Process in a 500 MW{sub e} (nominal) power plant could achieve 90% CO{sub 2} removal with an incremental capital cost of about $69 million and an increase in the cost of electricity (COE) of about 1.95 cents per kWh. This represents an increase of roughly 35.4% in the estimated COE - which compares very favorable versus MEA's COE increase of 58%. Both the incremental capital cost and the incremental COE were projected to be less than the comparable costs for an equally efficient CO{sub 2} removal system based on monoethanolamine (MEA).

Thomas Nelson; David Green; Paul Box; Raghubir Gupta; Gennar Henningsen

2007-06-30T23:59:59.000Z

25

Estimation of Carbon Credits in Carbon Dioxide Sequestration Activities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Credits in Carbon Credits in Carbon Dioxide Sequestration Activities K. Thomas Klasson and Brian H. Davison Oak Ridge National Laboratory * Oak Ridge, Tennessee 37831-6226 Presentation First National Conference on Carbon Sequestration May 14-17, 2001 Washington, DC "The submitted manuscript has been authored by a contractor of the U.S. Government under contract No. DE-AC05-00OR22725. Accordingly, the U.S. Government retains a nonexclusive, royalty-free license to publish or reproduce the published form of this contribution, or allow others to do so, for U.S. Government purposes." * Managed by UT-Battelle, LLC, for the U.S. Department of Energy under contract DE-AC05-00OR22725 1 Estimation of Carbon Credits in Carbon Dioxide Sequestration Activities

26

Local structures - key to improved gas adsorption in carbon materials |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functional Materials for Energy Functional Materials for Energy Local structures - key to improved gas adsorption in carbon materials September 23, 2013 (Inset, top left) A simulated disordered carbon structure. (Inset, bottom right) Same structure, with dense colored regions showing the strongest adsorption positions. (Main figure) Isosteric heat of adsorption as a function of carbon density, showing the strong change of adsorption with pore size. Combined results from electron microscopy, neutron scattering, and theory, illustrate the link between local structures and adsorption properties in carbon materials. The achieved understanding at the atomic scale is a crucial step towards predicting and designing materials with enhanced gas adsorption properties, with important implications for applications such as

27

Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Organoclay Sorbent for Removal of Carbon Dioxide from Gas Organoclay Sorbent for Removal of Carbon Dioxide from Gas Streams at Low Temperatures Contact NETL Technology Transfer Group techtransfer@netl.doe.gov October 2012 Significance * Energy mixing is maximized * Mobilizing of the particulates is complete * No "dead zones" exist * Packing of material is minimized * Eroding effects are significantly reduced Applications * Mixing nuclear waste at Hanford * Any similar industrial process involving heavy solids in a carrier fluid Opportunity Research is currently active on the patent-pending technology "Organoclay Sorbent for Removal of Carbon Dioxide from

28

Carbon dioxide capture-related gas adsorption and separation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks Previous Next List Jian-Rong Li, Yuguang Ma, M. Colin McCarthy, Julian Sculley, Jiamei Yu,...

29

Carbon Dioxide Capture with Amine-Grafted Activated Carbon  

Science Journals Connector (OSTI)

There are several possible methods by which amine groups can be grafted on the surface of activated carbon (AC) to improve their capacity for...2 adsorption. Ethylenediamine and diethylenetriamine were selected a...

Amirhossein Houshmand; Wan Mohd Ashri Wan Daud; Min-Gyu Lee…

2012-02-01T23:59:59.000Z

30

EIA - Greenhouse Gas Emissions - Carbon Dioxide Emissions  

Gasoline and Diesel Fuel Update (EIA)

2. Carbon Dioxide Emissions 2. Carbon Dioxide Emissions 2.1. Total carbon dioxide emissions Annual U.S. carbon dioxide emissions fell by 419 million metric tons in 2009 (7.1 percent), to 5,447 million metric tons (Figure 9 and Table 6). The annual decrease-the largest over the 19-year period beginning with the 1990 baseline-puts 2009 emissions 608 million metric tons below the 2005 level, which is the Obama Administration's benchmark year for its goal of reducing U.S. emissions by 17 percent by 2020. The key factors contributing to the decrease in carbon dioxide emissions in 2009 included an economy in recession with a decrease in gross domestic product of 2.6 percent, a decrease in the energy intensity of the economy of 2.2 percent, and a decrease in the carbon intensity of energy supply of

31

EFRC Carbon Capture and Sequestration Activities at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

EFRC Carbon Capture and EFRC Carbon Capture and Sequestration Activities at NERSC EFRC Carbon Capture and Sequestration Activities at NERSC Why it Matters: Carbon dioxide (CO2) gas is considered to be present in only trace proportions in our atmosphere but it has a leading role in the cast of greenhouse gases, with a thermal radiative effect nearly three times as large as the next biggest contributor. Energy related processes are the biggest sources of atmospheric CO2, especially the burning of fossil fuels and the production of hydrogen from methane. Since both human-caused CO2 concentrations and global average temperatures have been increasing steadily since the mid-20th century it could very well be that our energy future depends on our ability to effectively remove CO2

32

Life Cycle Carbon Footprint of Shale Gas: Review of Evidence and Implications  

Science Journals Connector (OSTI)

Life Cycle Carbon Footprint of Shale Gas: Review of Evidence and Implications ... Most of the studies utilize US EPA’s Greenhouse Gas Emissions Reporting Background Technical Support Document (TSD) for their assumptions regarding the amount of gas released per completion and the flaring rate for completions, the two critical parameters that describe the amount of greenhouse gases released per completion. ... These ?13C-CH4 data, coupled with the ratios of methane-to-higher-chain hydrocarbons, and ?2H-CH4 values, are consistent with deeper thermogenic methane sources such as the Marcellus and Utica shales at the active sites and matched gas geochem. ...

Christopher L. Weber; Christopher Clavin

2012-04-30T23:59:59.000Z

33

The Transport Properties of Activated Carbon Fibers  

DOE R&D Accomplishments [OSTI]

The transport properties of activated isotropic pitch-based carbon fibers with surface area 1000 m{sup 2}/g have been investigated. We report preliminary results on the electrical conductivity, the magnetoresistance, the thermal conductivity and the thermopower of these fibers as a function of temperature. Comparisons are made to transport properties of other disordered carbons.

di Vittorio, S. L.; Dresselhaus, M. S.; Endo, M.; Issi, J-P.; Piraux, L.

1990-07-00T23:59:59.000Z

34

EA-1692: Red River Environmental Products, LLC Activated Carbon...  

Broader source: Energy.gov (indexed) [DOE]

2: Red River Environmental Products, LLC Activated Carbon Manufacturing Facility, Red River Parish, LA EA-1692: Red River Environmental Products, LLC Activated Carbon Manufacturing...

35

The Effect of Acid Additives on Carbonate Rock Wettability and Spent Acid Recovery in Low Permeability Gas Carbonates  

E-Print Network [OSTI]

Spent acid retention in the near-wellbore region causes reduction of relative permeability to gas and eventually curtailed gas production. In low-permeability gas carbonate reservoirs, capillary forces are the key parameters that affect the trapping...

Saneifar, Mehrnoosh

2012-10-19T23:59:59.000Z

36

Active carbon filter health condition detection with piezoelectric wafer active sensors  

E-Print Network [OSTI]

Active carbon filter health condition detection with piezoelectric wafer active sensors Jingjing Chemical Biological Center, 5183 Blackhawk Road, APG, MD USA 21010 ABSTRACT The impregnated active carbon in active carbon filters by combining the electromechanical impedance spectroscopy (EMIS

Giurgiutiu, Victor

37

Demonstration of a Carbonate Fuel Cell on Coal Derived Gas  

E-Print Network [OSTI]

system has run on actual syn-gas. Consequently, the Electric Power Research Institute (“EPRI”) has sponsored a 20 kW carbonate fuel cell pilot plant that will begin operating in March at Destec Energy’s coal gasification plant in Plaquemine, Louisiana...

Rastler, D. M.; Keeler, C. G.; Chi, C. V.

38

Carbon Dioxide Capture from Flue Gas Using Dry, Regenerable Sorbents  

SciTech Connect (OSTI)

This report describes research conducted between July 1, 2006 and September 30, 2006 on the use of dry regenerable sorbents for removal of carbon dioxide (CO{sub 2}) from coal combustion flue gas. Modifications to the integrated absorber/ sorbent regenerator/ sorbent cooler system were made to improve sorbent flow consistency and measurement reliability. Operation of the screw conveyor regenerator to achieve a sorbent temperature of at least 120 C at the regenerator outlet is necessary for satisfactory carbon dioxide capture efficiencies in succeeding absorption cycles. Carbon dioxide capture economics in new power plants can be improved by incorporating increased capacity boilers, efficient flue gas desulfurization systems and provisions for withdrawal of sorbent regeneration steam in the design.

David A. Green; Thomas O. Nelson; Brian S. Turk; Paul D. Box Raghubir P. Gupta

2006-09-30T23:59:59.000Z

39

Membrane-based carbon capture from flue gas: A review  

Science Journals Connector (OSTI)

Abstract There has been an increasing interest in the application of membranes to flue gas separation, primarily driven by the need of carbon capture for significantly reducing greenhouse gas emissions. Historically, there has not been general consensus about the advantage of membranes against other methods such as liquid solvents for carbon capture. However, recent research indicates that advances in materials and process designs could significantly improve the separation performance of membrane capture systems, which make membrane technology competitive with other technologies for carbon capture. This paper mainly reviews membrane separation for the application to post-combustion CO2 capture with a focus on the developments and breakthroughs in membrane material design, process engineering, and engineering economics.

Rajab Khalilpour; Kathryn Mumford; Haibo Zhai; Ali Abbas; Geoff Stevens; Edward S. Rubin

2014-01-01T23:59:59.000Z

40

Shale Gas Formations and Their Potential for Carbon Storage: Opportunities and Outlook  

Science Journals Connector (OSTI)

Shale gas resources are proving to be globally abundant...2...(carbon dioxide) to mitigate the climate impacts of global carbon emissions from power and industrial sectors. This paper reviews global shale gas res...

Roozbeh Khosrokhavar; Steve Griffiths; Karl-Heinz Wolf

2014-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Emission and Chemistry of Organic Carbon in the Gas and Aerosol...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Chemistry of Organic Carbon in the Gas and Aerosol Phase at a Sub-Urban Site Near Mexico City in March 2006 During Emission and Chemistry of Organic Carbon in the Gas and...

42

Process for producing methane from gas streams containing carbon monoxide and hydrogen  

DOE Patents [OSTI]

Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

Frost, Albert C. (Congers, NY)

1980-01-01T23:59:59.000Z

43

Carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction (the CAMERE process)  

SciTech Connect (OSTI)

The CAMERE process (carbon dioxide hydrogenation to form methanol via a reverse-water-gas-shift reaction) was developed and evaluated. The reverse-water-gas-shift reactor and the methanol synthesis reactor were serially aligned to form methanol from CO{sub 2} hydrogenation. Carbon dioxide was converted to CO and water by the reverse-water-gas-shift reaction (RWReaction) to remove water before methanol was synthesized. With the elimination of water by RWReaction, the purge gas volume was minimized as the recycle gas volume decreased. Because of the minimum purge gas loss by the pretreatment of RWReactor, the overall methanol yield increased up to 89% from 69%. An active and stable catalyst with the composition of Cu/ZnO/ZrO{sub 2}/Ga{sub 2}O{sub 3} (5:3:1:1) was developed. The system was optimized and compared with the commercial methanol synthesis processes from natural gas and coal.

Joo, O.S.; Jung, K.D.; Han, S.H.; Uhm, S.J. [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.] [Korea Inst. of Science and Technology, Seoul (Korea, Republic of). Catalysis Lab.; Moon, I. [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering] [Yonsei Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Rozovskii, A.Y.; Lin, G.I. [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)] [A.V. Topchiev Inst. of Petrochemical Synthesis, Moscow (Russian Federation)

1999-05-01T23:59:59.000Z

44

Amorphous silicon-carbon alloys and amorphous carbon from direct methane and ethylene activation by ECR  

SciTech Connect (OSTI)

Hydrogenated amorphous silicon-carbon alloys are prepared using electron-cyclotron resonance (ECR) plasma-enhanced chemical vapor deposition. Hydrogen is introduced into the source resonance cavity as an excitation gas. Silane is introduced in the main chamber in the vicinity of the plasma stream, whereas the carbon source gases, methane or ethylene, are introduced either with the silane or with the hydrogen as excitation gases. The effect of the type of carbon-source gas, excitation gas mixture and silane-to-carbon source gas flow ratio on the deposition rate, bandgap, subgap density of states, spin density and hydrogen evolution are studied.

Conde, J.P.; Chu, V.; Giorgis, F.; Pirri, C.F.; Arekat, S.

1997-07-01T23:59:59.000Z

45

Effect of palladium loaded activated carbons on hydrogen storage  

Science Journals Connector (OSTI)

Pd-loaded high surface area activated carbon (BAC-Pd) was produced from bamboo by carbonization and activation using potassium hydroxide with subsequent loading of palladium. The palladium loaded onto BACs appear...

Masaki Ohno; Nami Okamura; Tomohiro Kose; Takashi Asada…

2012-12-01T23:59:59.000Z

46

Carbon-Carbon Composites as Recuperator Material for Direct Gas Brayton Systems  

SciTech Connect (OSTI)

Of the numerous energy conversion options available for a space nuclear power plant (SNPP), one that shows promise in attaining reliable operation and high efficiency is the direct gas Brayton (GB) system. In order to increase efficiency, the GB system incorporates a recuperator that accounts for nearly half the weight of the energy conversion system (ECS). Therefore, development of a recuperator that is lighter and provides better performance than current heat exchangers could prove to be advantageous. The feasibility of a carbon-carbon (C/C) composite recuperator core has been assessed and a mass savings of 60% and volume penalty of 20% were projected. The excellent thermal properties, high-temperature capabilities, and low density of carbon-carbon materials make them attractive in the GB system, but development issues such as material compatibility with other structural materials in the system, such as refractory metals and superalloys, permeability, corrosion, joining, and fabrication must be addressed.

RA Wolf

2006-07-19T23:59:59.000Z

47

Oil and Gas CDT Gas hydrate distribution on tectonically active continental  

E-Print Network [OSTI]

Oil and Gas CDT Gas hydrate distribution on tectonically active continental margins: Impact on gas. Gregory F. Moore, University of Hawaii (USA) http://www.soest.hawaii.edu/moore/ Key Words Gas Hydrates, Faults, Fluid Flow, gas prospectivity Overview Fig. 1. Research on gas hydrates is often undertaken

Henderson, Gideon

48

Modeling impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils in China  

E-Print Network [OSTI]

Modeling impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils impacts of carbon sequestration on net greenhouse gas emissions from agricultural soils in China, Global Biogeochem. Cycles, 23, GB1007, doi:10.1029/2008GB003180. 1. Introduction [2] Carbon (C) sequestration has

49

Gas-Surface Energy Exchange in Collisions of Helium Atoms with Aligned Single-Walled Carbon  

E-Print Network [OSTI]

1 Gas-Surface Energy Exchange in Collisions of Helium Atoms with Aligned Single-Walled Carbon #12;2 ABSTRACT Since gas flows in micro/nano devices are dominated by the interaction of gas molecules accommodation of gas molecules on surfaces. The scattering of gas molecules on quartz surfaces covered with VA

Maruyama, Shigeo

50

Carbon Dioxide Capture from Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate-Ammonium Bicarbonate Process  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integrated Integrated Gasification Combined Cycle Gas Streams Using the Ammonium Carbonate- Ammonium Bicarbonate Process Description Current commercial processes to remove carbon dioxide (CO 2 ) from conventional power plants are expensive and energy intensive. The objective of this project is to reduce the cost associated with the capture of CO 2 from coal based gasification processes, which convert coal and other carbon based feedstocks to synthesis gas.

51

CeO2 Promoted Ni/Al2O3 Catalyst in Combined Steam and Carbon Dioxide Reforming of Methane for Gas to Liquid (GTL) Process  

Science Journals Connector (OSTI)

The effect of ceria promotion over Ni/Al2O3...catalysts on the catalytic activity and coke formation was investigated in combined steam and carbon dioxide reforming of methane (CSCRM) to produce synthesis gas (H2

Kee Young Koo; Hyun-Seog Roh; Un Ho Jung; Wang Lai Yoon

2009-06-01T23:59:59.000Z

52

Catalyst for the methanation of carbon monoxide in sour gas  

DOE Patents [OSTI]

The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

1985-01-01T23:59:59.000Z

53

Carbon Dioxide Capture and Gas Separation on B80 Fullerene  

Science Journals Connector (OSTI)

Carbon Dioxide Capture and Gas Separation on B80 Fullerene ... All other clusters show the optimized chemisorbed configurations of CO2 captured on B80. ... Although air capture will cost more than capture at power generating facilities when both are operated under the same economic conditions, air capture allows one to apply industrial economies of scale to small and mobile emission sources and enables a partial decoupling of C capture from the energy infrastructure; advantages which may compensate for the intrinsic difficulty of capturing C from air. ...

Qiao Sun; Meng Wang; Zhen Li; Aijun Du; Debra J. Searles

2014-01-09T23:59:59.000Z

54

Speaker to Address Impact of Natural Gas Production on Greenhouse Gas Emissions When used for power generation, Marcellus Shale natural gas can significantly reduce carbon  

E-Print Network [OSTI]

generation, Marcellus Shale natural gas can significantly reduce carbon dioxide emissions, but questions have, that using natural gas for electricity generation is better than coal for the long-term healthSpeaker to Address Impact of Natural Gas Production on Greenhouse Gas Emissions When used for power

Boyer, Elizabeth W.

55

Impact of carbon dioxide sequestration in depleted gas-condensate reservoirs.  

E-Print Network [OSTI]

??Depleted gas-condensate reservoirs are becoming important targets for carbon dioxide sequestration. Since depleted below the dew point, retrograde condensate has been deposited in the pore… (more)

Ramharack, Richard M.

2010-01-01T23:59:59.000Z

56

Carbon sequestration and greenhouse gas emissions in urban turf  

E-Print Network [OSTI]

D. C. Lal, R. (2004), Carbon emission from farm operations,facts: Average carbon dioxide emissions resulting fromcalculation of carbon dioxide (CO 2 ) emissions from fuel

Townsend-Small, Amy; Czimczik, Claudia I

2010-01-01T23:59:59.000Z

57

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA as well as flue gas from coal combustion. This topical report covers Phase 2b, which is the construction phase of pilot demonstration subsystems that make up the integrated plant. The subsystems included are the mineralization subsystem, the Alkalinity Based on Low Energy (ABLE) subsystem, the waste calcium oxide processing subsystem, and the fiber cement board production subsystem. The fully integrated plant is now capable of capturing CO2 from various sources (gas and coal) and mineralizing into a reactive calcium carbonate binder and subsequently producing commercial size (4ftx8ft) fiber cement boards. The topical report provides a description of the “as built” design of these subsystems and the results of the commissioning activities that have taken place to confirm operability. At the end of Phase 2b, the CCMP pilot demonstration is fully ready for testing.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2014-06-01T23:59:59.000Z

58

Reduction on Synthesis Gas Costs by Decrease of Steam/Carbon and Oxygen/Carbon Ratios in the Feedstock  

Science Journals Connector (OSTI)

The costs for syngas production at low steam/carbon and oxygen/carbon ratios have been analyzed for simplified process schemes of the main syngas production technologies (steam?CO2 reforming, autothermal reforming, and combined reforming) and different synthesis gas compositions. ... The process scheme is shown in Figure 2. Natural gas, saturated steam, and CO2 are preheated to 300?500 °C and mixed in the reactor burner at a pressure of 30 kg/cm2. ...

L. Basini; L. Piovesan

1998-01-05T23:59:59.000Z

59

Waterjet injection of powdered activated carbon for sediment remediation .  

E-Print Network [OSTI]

??"In situ sediment remediation through waterjet-activated carbon amendment delivery is an innovative means to mitigate the dangers posed by hydrophobic organic compounds. Ease of use… (more)

Redell, Chris J.

2011-01-01T23:59:59.000Z

60

Carbon Sequestration as a Greenhouse Gas Mitigation Strategy: A Comparative  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 Conference Proceedings 3 Conference Proceedings NETL-sponsored Symposia at the AAAS Annual Meeting February, 2003 Table of Contents Disclaimer Papers and Presentations Carbon Sequestration as a Greenhouse Gas Mitigation Strategy: A Comparative Assessment of Options Climate Change Mitigation Strategy: Technical Challenges for Carbon Sequestration Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Landfill Gas Cleanup for Carbonate Fuel Cell Power Generation: Final Report  

SciTech Connect (OSTI)

Landfill gas represents a significant fuel resource both in the United States and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

62

Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen in the  

E-Print Network [OSTI]

1 Clathrate hydrate equilibrium data for the gas mixture of carbon dioxide and nitrogen the mole fraction of CO2 in the carbon dioxide + nitrogen + cyclopentane mixed hydrate phase, both defined;2 {water +carbon dioxide + nitrogen}, the equilibrium pressure of the mixed hydrate is reduced by 0.95 up

Paris-Sud XI, Université de

63

Geology of Bravo Dome carbon dioxide gas field, New Mexico  

SciTech Connect (OSTI)

The Bravo Dome carbon dioxide gas field is located in Union and Harding Counties of northeast New Mexico. The Bravo Dome field covers approximately 800,000 acres, but areal boundaries of the field have not been fully defined. Production in 1989 was 113 bcf of gas from 272 wells. Cumulative production at the end of 1989 was 626 bcf. Estimated recoverable reserves are more than 10 tcf. The gas is 98-99% CO{sub 2}. Most CO{sub 2} produced from Bravo Dome is used for enhanced oil recovery in the Permian basin. The Bravo Dome is a faulted, southeast-plunging, basement-cored anticlinal nose. It is bordered on the east and south by large high-angle faults of Pennsylvanian and Wolfcampian (Early Permian) age. The principal reservoir in the Bravo Dome field is the Tubb sandstone (Leonardian-Permian) at depths of 1,900 to 2,950 ft. The Tubb consists of 0-400 ft of fine- to medium-grained, well-sorted, orange feldspathic sandstone. It rests unconformably on Precambrian basement on the highest parts of the Bravo Dome and is not offset by late Paleozoic faults that form the dome. The Cimmaron Anhydrite (Leonardian-Permian) conformably overlies the Tubb and is a vertical seal. The trap at Bravo Dome has structural and stratigraphic aspects. Drape of Tubb sandstone over the dome created structural closure on the northeast, southeast, and southwest flanks of the field. Trapping on the northwest flank of the field is associated with regional northwest thinning of the Tubb.

Broadhead, R.F. (New Mexico Bureau of Mines and Mineral Resources, Socorro (United States))

1991-03-01T23:59:59.000Z

64

Improvement of LNG production technology in gas-distribution stations with an increased content of carbon dioxide in supply-line gas  

Science Journals Connector (OSTI)

The possibility is considered of reducing the weight of absorbent in a carbon dioxide gas cleaning system during liquefied natural gas production in gas-distribution stations (due to use of a pressure drop ... is...

S. P. Gorbachev; S. V. Lyugai

2009-11-01T23:59:59.000Z

65

Greenhouse Gas Reductions Under Low Carbon Fuel Standards?  

E-Print Network [OSTI]

capping an industry’s carbon emissions per unit of output.be an increase in carbon emissions. The LCFS may also reducestandard, which limits carbon emissions per unit of output,

Holland, Stephen P.; Knittel, Christopher R; Hughes, Jonathan E.

2007-01-01T23:59:59.000Z

66

Geological controls on gas accumulation in a unique Zechstein carbonate reservoir  

E-Print Network [OSTI]

potentially contribute and combine favourably to Wissey's reservoir quality and gas reserves. It is nowGeological controls on gas accumulation in a unique Zechstein carbonate reservoir Craig Duguid, The King's Buildings, West Mains Road, Edinburgh, EH9 3JW, Scotland, UK Email: S0567834@sms.ed.ac.uk Gas

67

Ozone Removal by Filters Containing Activated Carbon: A Pilot Study  

SciTech Connect (OSTI)

This study evaluated the ozone removal performance of moderate-cost particle filters containing activated carbon when installed in a commercial building heating, ventilating, and air conditioning (HVAC) system. Filters containing 300 g of activated carbon per 0.09 m2 of filter face area were installed in two 'experimental' filter banks within an office building located in Sacramento, CA. The ozone removal performance of the filters was assessed through periodic measurements of ozone concentrations in the air upstream and downstream of the filters. Ozone concentrations were also measured upstream and downstream of a 'reference' filter bank containing filters without any activated carbon. The filter banks with prefilters containing activated carbon were removing 60percent to 70percent of the ozone 67 and 81 days after filter installation. In contrast, there was negligible ozone removal by the reference filter bank without activated carbon.

Fisk, William; Spears, Mike; Sullivan, Douglas; Mendell, Mark

2009-09-01T23:59:59.000Z

68

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black  

E-Print Network [OSTI]

Enhanced Activated Carbon Cathode Performance for Microbial Fuel Cell by Blending Carbon Black-based materials that have good catalytic activity, but the electrical conductivity of the AC is poor compared as a binder, as opposed to Nafion with Pt, which greatly reduces the cost of the cathode materials. AC

69

Selecting activated carbon for water and wastewater treatability studies  

SciTech Connect (OSTI)

A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C. [East China University of Chemical Technology, Shanghai (China)

2007-10-15T23:59:59.000Z

70

E-Print Network 3.0 - activated carbon pac Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Engineering 55 Letters to the editor Carbon 40 (2002) 445467 447 using continuous carbon-fiber carbon-matrix and polymeruntreated fibers are used. The activation treatment...

71

E-Print Network 3.0 - activated carbon-based adsorbents Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

two primary elements, the filter media (activated carbon or lignite coke) to adsorb pollutants... in that Marker's past experience has been that Hg capture with carbon or carbon...

72

Gas sorption properties of zwitterion-functionalized carbon nanotubes  

SciTech Connect (OSTI)

We have functionalized carbon nanotubes with carboxylic acid and zwitterion groups. We have evaluated the effect of functionalization by measuring the sorption of CO{sub 2}, CH{sub 4}, and N{sub 2} at 35? for pressures up to 10 bar. Zwitterion functionalized nanotubes were found to be highly hygroscopic. Thermal gravimetric analysis indicates that water can be desorbed at about 200°C. The adsorption of gases in zwitterion functionalized nanotubes is dramatically reduced compared with nanotubes functionalized with carboxylic acid groups. The presence of water on the zwitterion functionalized nanotube reduces the sorption even further. Molecular simulations show that three or more zwitterion groups per tube entrance are required to significantly reduce the flux of CO{sub 2} into the tubes. Simulations also show that gas phase water is rapidly sorbed into the zwitterion functionalized nanotubes, both increasing the free energy barrier to CO{sub 2} entering the tube and also lowering the equilibrium adsorption through competitive adsorption.

Surapathi, Anil; Chen, Hang-yan; Marand, Eva; Johnson, J Karl, Zdenka Sedlakova

2013-02-15T23:59:59.000Z

73

Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning  

Science Journals Connector (OSTI)

A high-negative voltage at the cathode initiates a dark discharge resulting in a reduction of the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. An experiment indicated that nearly 44% of the carbon dioxide in exhaust gas disappears after a high-voltage application to the cathode. The energy needed for the endothermic reaction of the carbon dioxidedissociation corresponding to this concentration reduction is provided mainly by the internal energy reduction of the discharge gas which is nearly 20 times the electrical energy for electron emission.

Han S. Uhm; Chul H. Kim

2009-01-01T23:59:59.000Z

74

Next Generation Natural Gas Vehicle Activity: Natural Gas Engine and Vehicle Research & Development (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the status of the Next Generation Natural Gas Vehicle (NGNGV) activity, including goals, R&D progress, NGV implementation, and the transition to hydrogen.

Not Available

2003-09-01T23:59:59.000Z

75

Landfill gas cleanup for carbonate fuel cell power generation. Final report  

SciTech Connect (OSTI)

Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

Steinfield, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

76

Greenhouse Gas Reductions Under Low Carbon Fuel Standards?  

E-Print Network [OSTI]

LCFS limits carbon emissions per unit of current energycarbon fuel standard expressed as a limit on the emissions per energy

Holland, Stephen P.; Knittel, Christopher R; Hughes, Jonathan E.

2007-01-01T23:59:59.000Z

77

Greenhouse Gas Reductions under Low Carbon Fuel Standards?  

E-Print Network [OSTI]

LCFS limits carbon emissions per unit of current energycarbon fuel standard expressed as a limit on the emissions per energy

Holland, Stephen P.; Knittel, Christopher R; Hughes, Jonathan E.

2008-01-01T23:59:59.000Z

78

Activated carbon fibers and engineered forms from renewable resources  

DOE Patents [OSTI]

A method of producing activated carbon fibers (ACFs) includes the steps of providing a natural carbonaceous precursor fiber material, blending the carbonaceous precursor material with a chemical activation agent to form chemical agent-impregnated precursor fibers, spinning the chemical agent-impregnated precursor material into fibers, and thermally treating the chemical agent-impregnated precursor fibers. The carbonaceous precursor material is both carbonized and activated to form ACFs in a single step. The method produces ACFs exclusive of a step to isolate an intermediate carbon fiber.

Baker, Frederick S

2013-02-19T23:59:59.000Z

79

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc) Previous Next List Thomas M. McDonald, Woo Ram Lee, Jarad A....

80

Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas  

DOE Patents [OSTI]

The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

2014-10-07T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Carbon dioxide sequestration in petrochemical industries with the aim of reduction in greenhouse gas emissions  

Science Journals Connector (OSTI)

The mitigation of greenhouse gas emissions to acceptable levels is arguably the greatest...2 increase in the atmosphere. Carbon dioxide sequestration that consists of separation, transportation and...2..., is one...

Maryam Takht Ravanchi; Saeed Sahebdelfar…

2011-06-01T23:59:59.000Z

82

Experimental and simulation studies of sequestration of supercritical carbon dioxide in depleted gas reservoirs  

E-Print Network [OSTI]

he feasibility of sequestering supercritical CO2 in depleted gas reservoirs. The experimental runs involved the following steps. First, the 1 ft long by 1 in. diameter carbonate core is inserted into a viton Hassler sleeve and placed inside...

Seo, Jeong Gyu

2004-09-30T23:59:59.000Z

83

DOE Study Monitors Carbon Dioxide Storage in Norway's Offshore Sleipner Gas  

Broader source: Energy.gov (indexed) [DOE]

DOE Study Monitors Carbon Dioxide Storage in Norway's Offshore DOE Study Monitors Carbon Dioxide Storage in Norway's Offshore Sleipner Gas Field DOE Study Monitors Carbon Dioxide Storage in Norway's Offshore Sleipner Gas Field May 21, 2009 - 1:00pm Addthis Washington, D.C. -- In a newly awarded project, researchers funded by the U.S. Department of Energy (DOE) are partnering with European scientists to track injected carbon dioxide (CO2) in the world's first and longest running carbon storage operation located at the Sleipner gas field in the North Sea. The researchers--from the Scripps Institution of Oceanography at the University of California, San Diego, and the Lamont-Doherty Earth Observatory (LDEO) in New York--will conduct surveys on the seafloor to monitor injected CO2 in the 1 kilometer-deep reservoir, where more than

84

New Funding Boosts Carbon Capture, Solar Energy and High Gas Mileage Cars  

Broader source: Energy.gov (indexed) [DOE]

New Funding Boosts Carbon Capture, Solar Energy and High Gas New Funding Boosts Carbon Capture, Solar Energy and High Gas Mileage Cars and Trucks New Funding Boosts Carbon Capture, Solar Energy and High Gas Mileage Cars and Trucks June 11, 2009 - 12:00am Addthis WASHINGTON D.C. --- U.S. Energy Secretary Steven Chu today announced more than $300 million worth of investments that will boost a range of clean energy technologies - including carbon capture from coal, solar power, and high efficiency cars and trucks. The move reflects the Obama Administration's commitment to a broad based strategy that will create millions of jobs while transforming the way we use and produce energy. "There's enormous potential for new jobs and reduced carbon pollution just by implementing existing technologies like energy efficiency and wind

85

Storage characteristics of fresh fish packed in modified gas atmospheres containing carbon dioxide  

E-Print Network [OSTI]

STORAGE CHARACTERISTICS OF FRESH FISH PACKED IN MODIFIED GAS ATMOSPHERES CONTAINING CARBON DIOXIDE A Thesis by MICHEL LANNELONGUE FAVRE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE December 1980 Major Subject: Food Science and Technology STORAGE CHARACTERISTICS OF FRESH FISH PACKED IN MODIFIED GAS ATMOSPHERES CONTAINING CARBON DIOXIDE A Thesis by MICHEL LANNELONGUE FAVRE Approved as to style...

Lannelongue-Favre, Michel

2012-06-07T23:59:59.000Z

86

Liquid-phase adsorption of organic compounds by granular activated carbon and activated carbon fibers  

SciTech Connect (OSTI)

Liquid-phase adsorption of organic compounds by granular activated carbon (GAC) and activated carbon fibers (ACFs) is investigated. Acetone, isopropyl alcohol (IPA), phenol, and tetrahydrofuran (THF) were employed as the model compounds for the present study. It is observed from the experimental results that adsorption of organic compounds by GAC and ACF is influenced by the BET (Brunauer-Emmett-Teller) surface area of adsorbent and the molecular weight, polarity, and solubility of the adsorbate. The adsorption characteristics of GAC and ACFs were found to differ rather significantly. In terms of the adsorption capacity of organic compounds, the time to reach equilibrium adsorption, and the time for complete desorption, ACFs have been observed to be considerably better than GAC. For the organic compounds tested here, the GAC adsorptions were shown to be represented well by the Langmuir isotherm while the ACF adsorption could be adequately described by the Langmuir or the Freundlich isotherm. Column adsorption tests indicated that the exhausted ACFs can be effectively regenerated by static in situ thermal desorption at 150 C, but the same regeneration conditions do not do as well for the exhausted GAC.

Lin, S.H.; Hsu, F.M. [Yuan Ze Inst. of Tech., Taoyuan (Taiwan, Province of China). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

87

GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2)  

E-Print Network [OSTI]

GLOBAL EMISSIONS Greenhouse gas (GHG) emissions, largely carbon dioxide (CO2) from the combustion. Figure 1 Global Carbon Dioxide Emissions: 1850­2030 1850 1860 1870 1880 1890 1900 1910 1920 1930 1940- related CO2 emissions have risen 130-fold since 1850--from 200 million tons to 27 billion tons a year

Green, Donna

88

Hydrogen storage on activated carbon. Final report  

SciTech Connect (OSTI)

The project studied factors that influence the ability of carbon to store hydrogen and developed techniques to enhance that ability in naturally occurring and factory-produced commercial carbon materials. During testing of enhanced materials, levels of hydrogen storage were achieved that compare well with conventional forms of energy storage, including lead-acid batteries, gasoline, and diesel fuel. Using the best materials, an electric car with a modern fuel cell to convert the hydrogen directly to electricity would have a range of over 1,000 miles. This assumes that the total allowable weight of the fuel cell and carbon/hydrogen storage system is no greater than the present weight of batteries in an existing electric vehicle. By comparison, gasoline cars generally are limited to about a 450-mile range, and battery-electric cars to 40 to 60 miles. The project also developed a new class of carbon materials, based on polymers and other organic compounds, in which the best hydrogen-storing factors discovered earlier were {open_quotes}molecularly engineered{close_quotes} into the new materials. It is believed that these new molecularly engineered materials are likely to exceed the performance of the naturally occurring and manufactured carbons seen earlier with respect to hydrogen storage.

Schwarz, J.A. [Syracuse Univ., NY (United States). Dept. of Chemical Engineering and Materials Science

1994-11-01T23:59:59.000Z

89

Carbon dioxide removal and capture for landfill gas up-grading  

Science Journals Connector (OSTI)

Within the frame of an EC financially supported project - LIFE05 ENV/IT/000874 GHERL (Greenhouse Effect Reduction from Landfill)–a pilot plant was set up in order to demonstrate the feasibility of applying chemical absorption to remove carbon dioxide from landfill gas. After proper upgrading - basically removal of carbon dioxide, hydrogen sulphide, ammonia and other trace gas compound–the gas might be fed into the distribution grid for natural gas or used as vehicle fuel, replacing a fossil fuel thus saving natural resources and carbon dioxide emissions. Several experiences in Europe have been carried out concerning the landfill gas - and biogas from anaerobic digestion - quality up-grading through CO2 removal, but in all of them carbon dioxide was vented to the atmosphere after separation, without any direct benefit in terms of greenhouse gases reduction. With respect to those previous experiences, in this work the attention was focused on CO2 removal from landfill gas with an effective capture process, capable of removing carbon dioxide from atmosphere, through a globally carbon negative process. In particular, processes capable of producing final solid products were investigated, with the aim of obtaining as output solid compounds which can be either used in the chemical industry or disposed off. The adopted absorption process is based on using aqueous solutions of potassium hydroxide, with the final aim of producing potassium carbonate. Potassium carbonate is a product which has several applications in the chemical industry if obtained with adequate quality. It can be sold as a pulverised solid, or in aqueous solution. Several tests were carried out at the pilot plant, which was located at a landfill site, in order to feed it with a fraction of the on-site collected landfill gas. The results of the experimental campaign are reported, explained and commented in the paper. Also a discussion on economic issues is presented.

Lidia Lombardia; Andrea Corti; Ennio Carnevale; Renato Baciocchi; Daniela Zingaretti

2011-01-01T23:59:59.000Z

90

Flue gas carbon dioxide sequestration during water softening with ion-exchange fibers  

SciTech Connect (OSTI)

This study examines the use of ion-exchange fibers (IX fibers) to permanently sequester carbon dioxide present in flue gas into an aqueous phase as calcium or magnesium alkalinity while concurrently softening hard water. The only process inputs besides carbon dioxide (or flue gas) are snowmelt (or rainwater); no other chemicals are required for the regeneration of the IX fibers. Importantly, the process is not energy intensive and carbon dioxide does not need to be compressed to excessive pressures (>150 psi) for efficient use. Sources of carbon dioxide do not require concentration and, therefore, the use of raw flue gas (similar to 17% CO{sub 2}) is feasible with the rate of sequestration governed only by the partial pressure of carbon dioxide. While valid for flue gas obtained from any combustion process (e.g., coal, oil, natural gas, etc.), emissions from oil or gas combustion may be more appropriate for use in the described process due to the absence of mercury and particulates. It should also be noted that the presence of sulfur dioxide in flue gas would not adversely affect the process and may even enhance regeneration efficiency. The only product of the proposed process is an environmentally benign regenerant stream containing calcium and/or magnesium alkalinity. The unique property of IX fibers that makes the proposed process both environmentally sustainable and economically feasible is amenability to efficient regeneration with carbon dioxide and harvested snowmelt. Low intraparticle diffusional resistance is the underlying reason why IX fibers are amenable to efficient regeneration using snowmelt sparged with carbon dioxide; 95% calcium recovery was attained at a CO{sub 2} partial pressure of 6.8 atm. The energy balance for a typical electric utility shows that up to 1% of carbon dioxide emitted during combustion would be sequestered in the softening process.

Greenleaf, J.E.; SenGupta, A.K. [Lafayette College, Easton, PA (United States). Dept. of Civil & Environmental Engineering

2009-06-15T23:59:59.000Z

91

Carbon Nanotube Materials for Substrate Enhanced Control of Catalytic Activity  

SciTech Connect (OSTI)

Carbon SWNTs are attractive materials for supporting electrocatalysts. The properties of SWNTs are highly tunable and controlled by the nanotube's circumferential periodicity and their surface chemistry. These unique characteristics suggest that architectures constructed from these types of carbon support materials would exhibit interesting and useful properties. Here, we expect that the structure of the carbon nanotube support will play a major role in stabilizing metal electrocatalysts under extreme operating conditions and suppress both catalyst and support degradation. Furthermore, the chemical modification of the carbon nanotube surfaces can be expected to alter the interface between the catalyst and support, thus, enhancing the activity and utilization of the electrocatalysts. We plan to incorporate discrete reaction sites into the carbon nanotube lattice to create intimate electrical contacts with the catalyst particles to increase the metal catalyst activity and utilization. The work involves materials synthesis, design of electrode architectures on the nanoscale, control of the electronic, ionic, and mass fluxes, and use of advanced optical spectroscopy techniques.

Heben, M.; Dillon, A. C.; Engtrakul, C.; Lee, S.-H.; Kelley, R. D.; Kini, A. M.

2007-05-01T23:59:59.000Z

92

Carbon nanotube (CNT) gas sensors for emissions from fossil fuel burning  

Science Journals Connector (OSTI)

Abstract Fossil fuels endow wide applications in industrial, transportation, and power generation sectors. However, smoke released by burning fossil fuels contains toxic gases, which pollutes the environment and severely affects human health. Carbon nanotubes (CNTs) are potential material for gas sensors due to their high structural porosity and high specific surface area. Defects present on the CNT sidewalls and end caps facilitate adsorption of gas molecules. The chemical procedures adopted to purify and disperse carbon nanotubes create various chemical groups on their surface, which further enhance the adsorption of gas molecules and thus improve the sensitivity of CNTs. Present review focuses on CNT chemiresistive gas sensing mechanisms, which make them suitable for the development of next generation sensor technology. The resistance of carbon nanotubes decreases when oxidizing gas molecules adsorb on their surface, whereas, adsorption of reducing gas molecules results in increasing the resistance of CNTs. Sensing ability of carbon nanotubes for the gases namely, NO, NO2, CO, CO2 and SO2, released on burning of fossil fuels is reviewed. This review provides basic understanding of sensing mechanisms, creation of adsorption sites by chemical processes and charge transfer between adsorbed gas molecules and surface of CNTs. In addition, useful current update on research and development of CNT gas sensors is provided.

M. Mittal; A. Kumar

2014-01-01T23:59:59.000Z

93

Effect of low steam/carbon ratio on water gas shift reaction  

Science Journals Connector (OSTI)

Cu/ZnO/Al2O3 catalysts prepared by reverse co-precipitation and an industrial catalyst were used for the low-temperature water gas shift reaction. The catalysts were characterized by chemical analysis (atomic absorption spectroscopy), BET surface area, nitrous oxide chemisorption, X-ray diffraction (XRD), temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS) and catalytic activity in the target reaction. The catalyst prepared by reverse co-precipitation showed higher BET and copper surface areas, as well as higher catalytic activity. XRD patterns showed that the aurichalcite and hydrozincite precursors were converted into crystalline CuO and ZnO oxides when calcined in air at 623 K. TPR profiles revealed that Cu(I) oxide forms prior to Cu. Binding energies corresponding to several copper states on fresh catalysts were observed by XPS, but copper was in the metallic state during the reaction conditions (reduced catalyst). By varying the catalytic reaction conditions, such as vapor/carbon ratio and the time of contact, it is possible to obtain different conversion rates of carbon monoxide and thus operate under conditions of lower vapor consumption.

Renan Tavares Figueiredo; André Luis Dantas Ramos; Heloysa Martins Carvalho de Andrade; J.L.G. Fierro

2005-01-01T23:59:59.000Z

94

A method for the determination of dissolved organic carbon in sea water by gas chromatography  

E-Print Network [OSTI]

of organic matter was carried out at elevated temperature and pressure after collection of a large number of samples. The resulting carbon dioxide was flushed through a gas chromatograph with helium as the carrier gas and the signal was recorded on a strip... chart recorder. Chromatographic analysis time was approximately eleven minutes per sample with a precision of + Q. 1 mg C/l. The organic carbon content of the sample was determined by measurement of the peak area using an appropriate carbon dioxide...

Fredericks, Alan D

1965-01-01T23:59:59.000Z

95

Effect of flue gas impurities on the process of injection and storage of carbon dioxide in depleted gas reservoirs  

E-Print Network [OSTI]

Previous experiments - injecting pure CO2 into carbonate cores - showed that the process is a win-win technology, sequestrating CO2 while recovering a significant amount of hitherto unrecoverable natural gas that could help defray the cost of CO2...

Nogueira de Mago, Marjorie Carolina

2005-11-01T23:59:59.000Z

96

Activated carbon from grass – A green alternative catalyst support for water electrolysis  

Science Journals Connector (OSTI)

Abstract Grass blades (turf grass) have been selected as a cheap biomass source of producing activated carbon for supporting Pt particles for utilizing as electrocatalyst for H2 generation through electrolysis of water. Activation is done using ZnCl2 followed by thermal processing at 250 °C. 1% Pt was supported over the grass derived activated biomass carbon (G-ABC) powder to result in Pt@G-ABC. After physical characterization, Pt@G-ABC sample has been tested for its catalytic activity in 1 M sulfuric acid solution for H2 gas generation through Linear Sweep & Cyclic Voltammetry. Cost factor involved in the production of G-ABC has also been compared with the traditional commercially available carbon support. The studies suggest that grass may be considered not only as a potential alternative source for producing carbon supported catalyst for H2 generation but also highlight the production of low-cost carbon for further applications like electrode materials, adsorbent for color, odor and hazardous pollutants.

Palanichamy Kalyani; Ariharaputhiran Anitha; Andre Darchen

2013-01-01T23:59:59.000Z

97

Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sorbents for Removal of Carbon Dioxide from Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures Opportunity The Department of Energy's National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 6,908,497 entitled "Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures." Disclosed in this patent is a new low-cost carbon dioxide (CO 2 ) sorbent that can be used in large-scale gas-solid processes. Researchers have developed a new method to prepare these sorbents by treating substrates with an amine and/or an ether in a way that either one comprises at least 50 weight percent of the sorbent. The sorbent captures compounds contained in gaseous fluids through chemisorptions and/or

98

REMOVAL OF ORGANIC POLLUTANTS FROM SUBCRITICAL WATER WITH ACTIVATED CARBON  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) has demonstrated that controlling the temperature (and to a lesser extent, the pressure) of water can dramatically change its ability to extract organics and inorganics from matrices ranging from soils and sediments to waste sludges and coal. The dielectric constant of water can be changed from about 80 (a very polar solvent) to <5 (similar to a nonpolar organic solvent) by controlling the temperature (from ambient to about 400 C) and pressure (from about 5 to 350 bar). The EERC has shown that hazardous organic pollutants such as pesticides, PACS (polycyclic aromatic hydrocarbons), and PCBs (polychlorinated biphenyls) can be completely removed from soils, sludges, and sediments at temperatures (250 C) and pressures (<50 atm) that are much milder than typically used for supercritical water processes (temperature >374 C, pressure >221 atm). In addition, the process has been demonstrated to be particularly effective for samples containing very high levels of contaminants (e.g., part per thousand). Current projects include demonstrating the subcritical water remediation process at the pilot scale using an 8-liter system constructed under separate funding during 1997. To date, subcritical water has been shown to be an effective extraction fluid for removing a variety of organic pollutants from soils and sludges contaminated with fossil fuel products and waste products, including PACS from soil (e.g., town gas sites), refining catalysts, and petroleum tank bottom sludges; PCBs from soil and sediments; toxic gasoline components (e.g., benzene) from soil and waste sludge; and phenols from petroleum refinery sludges. The obvious need to clean the wastewater from subcritical water processes led to preliminary experiments with activated carbon placed in line after the extractor. Initial experiments were performed before and after cooling the extractant water (e.g., with water at 200 C and with water cooled to 25 C). Surprisingly, the ability of activated carbon to remove organics from the water is better at a high temperature than at room temperature. These initial results are opposite to those expected from chromatographic theory, since the solubility of the organics is about 100,000-fold higher in the hot water than in ambient water. At present, the physicochemical mechanism accounting for these results is unknown; however, it is possible that the lower surface tension and lower viscosity of subcritical water (compared to water at ambient conditions) greatly increases the available area of the carbon by several orders of magnitude. Regardless of the mechanism involved, the optimal use of activated carbon to clean the wastewater generated from subcritical water remediation will depend on obtaining a better understanding of the controlling parameters. While these investigations focused on the cleanup of wastewater generated from subcritical water remediation, the results also apply to cleanup of any wastewater contaminated with nonpolar and moderately polar organics such as wastewaters from coal and petroleum processing.

Steven B. Hawthorne; Arnaud J. Lagadec

1999-08-01T23:59:59.000Z

99

Chemical and biological systems for regenerating activated carbon contaminated with high explosives  

SciTech Connect (OSTI)

Activated carbon has been used as a substrate for efficiently removing high explosives (HEs) from aqueous and gaseous waste streams. Carbon that is saturated with HEs, however, constitutes a solid waste and is currently being stored because appropriate technologies for its treatment are not available. Because conventional treatment strategies (i.e., incineration, open burning) are not safe or will not be in compliance with future regulations, new and cost-effective methods are required for the elimination of this solid waste. Furthermore, because the purchase of activated carbon and its disposal after loading with HEs will be expensive, an ideal treatment method would result in the regeneration of the carbon thereby permitting its reuse. Coupling chemical and biological treatment systems, such as those described below, will effectively meet these technical requirements. The successful completion of this project will result in the creation of engineered commercial systems that will present safe and efficient methods for reducing the quantities of HE-laden activated carbon wastes that are currently in storage or are generated as a result of demilitarization activities. Biological treatment of hazardous wastes is desirable because the biodegradation process ultimately leads to the mineralization (e.g., conversion to carbon dioxide, nitrogen gas, and water) of parent compounds and has favorable public acceptance. These methods will also be cost- effective because they will not require large expenditures of energy and will permit the reuse of the activated carbon. Accordingly, this technology will have broad applications in the private sector and will be a prime candidate for technology transfer.

Knezovich, J.P.; Daniels, J.I. [Lawrence Livermore National Lab., CA (United States); Stenstrom, M.K.; Heilmann, H.M. [Univ. of California, Los Angeles, CA (United States). Civil and Engineering Dept.

1994-12-01T23:59:59.000Z

100

Detection of low concentration oxygen containing functional groups on activated carbon fiber surfaces through fluorescent labeling  

E-Print Network [OSTI]

Detection of low concentration oxygen containing functional groups on activated carbon fiber of surface functional groups (OH, COOH and CHO) on activated carbon fiber surfaces. The chromophores were rights reserved. Keywords: Carbon fibers; X-ray photoelectron spectroscopy; Infrared spectroscopy

Borguet, Eric

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Copper nanocrystal modified activated carbon for supercapacitors with enhanced volumetric energy and power density  

E-Print Network [OSTI]

Copper nanocrystal modified activated carbon for supercapacitors with enhanced volumetric energy of copper nanocrystals in AC has little effect on the surface area and porosity of activated carbon. copper nanocrystals improves the electrical conductivity of the carbon network.

Cao, Guozhong

102

Carbon dioxide recovery from an integrated coal gasifier, combined cycle plant using membrane separation and a CO2 gas turbine  

Science Journals Connector (OSTI)

A scheme is described for electricity production based on coal gasification with recovery of carbon dioxide. In this scheme, coal is gasified into a coal gas, consisting mainly of hydrogen and carbon monoxide. A ...

Chris Hendriks

1994-01-01T23:59:59.000Z

103

Bioindication Potential of Carbonic Anhydrase Activity in Anemones  

E-Print Network [OSTI]

bioindication. While oysters and many other bivalves are predisposed to accumulate heavy metal pollutants from polluted vs pristine ®eld sites. CA activity was found to be de- creased with increase in metal. Keywords: carbonic anhydrase; metal pollution; anemo- nes; coral reefs; Panama. The activity of the zinc

Bermingham, Eldredge

104

E-Print Network 3.0 - activated carbon fiber Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

fiber Search Powered by Explorit Topic List Advanced Search Sample search results for: activated carbon fiber...

105

Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction  

DOE Patents [OSTI]

A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Westmont, IL); Wang, Xiaoping (Naperville, IL)

2010-08-03T23:59:59.000Z

106

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts  

Science Journals Connector (OSTI)

Impact of the Presence of Carbon Monoxide and Carbon Dioxide on Gas Oil Hydrotreatment: Investigation on Liquids from Biomass Cotreatment with Petroleum Cuts ... A potential way of utilizing these bioliquids as fuels could be the direct hydrotreatment(6) or the cohydrotreatment with petroleum fractions,(7) such as atmospheric gas oils, to achieve the technical and environmental fuel standards, especially in terms of sulfur content. ...

Ana Pinheiro; Nathalie Dupassieux; Damien Hudebine; Christophe Geantet

2011-01-18T23:59:59.000Z

107

Preparation and evaluation of hydrotreating catalysts based on activated carbon derived from oil sand petroleum coke  

Science Journals Connector (OSTI)

Novel Ni–Mo/activated carbon (AC) hydrotreating catalysts were prepared and evaluated for upgrading heavy vacuum gas oil (HVGO). The AC supports were derived from Alberta oil sand petroleum coke, i.e. fluid coke and/or delayed coke, hereafter referred to as OSP coke, through a chemical process. The BET surface area was as high as 2194 m2/g for the fluid coke derived AC and 2357 m2/g for the delayed coke derived AC. Both \\{ACs\\} contained a large number of micropores with pore volume as high as 1.2 cm3/g. Ni and Mo based active component precursors could be easily loaded on the activated carbon supports by chemical impregnation of nickel nitrate and ammonium molybdate followed by calcination in nitrogen at 773 K without further modification or oxidation treatment to the activated carbons. Scanning electron microscopy (SEM) observation showed highly porous surface structure of the bare activated carbon supports and well dispersed metal (oxide) precursor nanoparticles of 30–50 nm loaded on the AC supports. For comparison, two reference catalysts were also prepared by the same procedure but using commercial activated carbon and porous alumina as supports. After catalyst activation by sulfiding, the hydrotreating performance of the prepared catalysts was evaluated in a magnetically stirred autoclave with a HVGO feedstock to examine their hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) activities. Two commercial hydrotreating catalysts were also tested and compared under similar conditions with the same feed. The results showed that the catalysts based on the activated carbon supports prepared from OSP coke had better hydrotreating performance than the other catalysts. Scanning transmission electron microscopy (STEM) characterization of the catalysts after activation showed that small particles of nanostructure (2–5 nm in size) were evenly embedded in the carbon matrix except for some bigger particles that were located on the catalyst surface. Energy dispersive X-ray (EDX) spectroscopy revealed that these particles were composed of Ni, Mo and S elements. The dispersed nanoparticles formed the active sites and were responsible for the observed high HDS and HDN activity. Elemental analysis and surface characterization of the spent catalysts showed that the formation of coke precursors was favored on the alumina supported catalyst, which resulted in catalyst deactivation.

Yu Shi; Jinwen Chen; Jian Chen; Robb A. Macleod; Marek Malac

2012-01-01T23:59:59.000Z

108

An Electrochemically-mediated Gas Separation Process for Carbon Abatement  

E-Print Network [OSTI]

This work describes a promising alternative to conventional thermal processes for absorber/desorber processing of for removal of CO[subscript 2] from flue gas streams at fossil fuel fired power plants. Our electrochemica ...

Stern, Michael C.

109

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal  

Open Energy Info (EERE)

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal System- A Case Study Of The Geysers Geothermal Field, Usa Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal System- A Case Study Of The Geysers Geothermal Field, Usa Details Activities (1) Areas (1) Regions (0) Abstract: Hydrothermal alteration and the active vapor-dominated geothermal system at The Geysers, CA are related to a composite hypabyssal granitic pluton emplaced beneath the field 1.1 to 1.2 million years ago. Deep drill holes provide a complete transect across the thermal system and samples of the modern-day steam. The hydrothermal system was liquid-dominated prior to formation of the modern vapor-dominated regime at 0.25 to 0.28 Ma. Maximum

110

Argonne CNM Highlight: New Gas Sensor Based on Multiwalled Carbon Nanotubes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

New Gas Sensor Based on Multiwalled Carbon Nanotubes A new gas sensor based on multiwalled carbon nanotubes Hybrid sensor fabrication process: (top) SEM image of a few MWCNTs spanning across two neighboring Au fingers of the interdigitated electrode; (bottom) HRTEM image of a MWCNT uniformly coated with SnO nanocrystals. Argonne Center for Nanoscale Materials staff in the Nanofabrication & Devices Group together with collaborative users from the University of Wisconsin-Milwaukee have fabricated a miniaturized gas sensor using hybrid nanostructures consisting of SnO2 nanocrystals supported on multiwalled carbon nanotubes (MWCNTs). In contrast to the high-temperature operation required for SnO2 nanocrystals alone, and to the insensitivity towards H2

111

Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

112

Petroleum contaminated ground-water: Remediation using activated carbon  

Science Journals Connector (OSTI)

Ground-water contamination resulting from the leakage of crude oil and refined petroleum products during extraction and processing operations is a serious and a growing environmental problem in Nigeria. Consequently, a study of the use of activated carbon (AC) in the clean up was undertaken with the aim of reducing the water contamination to a more acceptable level. In the experiments described, crude-oil contamination of ground water was simulated under laboratory conditions using ground-water samples collected from existing hand-dug wells at Eagle Island, Port Harcourt, Nigeria. Different masses of the absorbent (i.e., activated carbon) were then added to the samples of ground water. The so treated water samples were left to equilibrate for 7 days, after which the total petroleum hydrocarbon (TPH) contents of the samples were measured. Adsorption isotherms were derived for the two forms of activated carbon used, namely granular activated-carbon (GAC) and powdered activated-carbon (PAC). Results of the TPH analyses showed that activated carbon is an excellent means for the stripping-off of the contaminant: there were decreases in contaminant concentration from an initial concentration of 9304.70 mg/l to average final concentrations of 361.00 and 12.37 mg/l, that is, 96% and 99.9% resulting from the same amounts of GAC and PAC applications respectively. The results of this study revealed that the powdered form of AC would be very effective in the remediation of petroleum-hydrocarbon contaminated ground water and its use is therefore recommended.

M.J. Ayotamuno; R.B. Kogbara; S.O.T. Ogaji; S.D. Probert

2006-01-01T23:59:59.000Z

113

Directed evolution of an ultrastable carbonic anhydrase for highly efficient carbon capture from flue gas  

Science Journals Connector (OSTI)

...library generation, and high-throughput...year, coal-fired power plants are...natural-gas–fired power...1. Flue gas from a coal-fired power plant is piped...depleted flue gas is released into...strategy for the generation of very large...

Oscar Alvizo; Luan J. Nguyen; Christopher K. Savile; Jamie A. Bresson; Satish L. Lakhapatri; Earl O. P. Solis; Richard J. Fox; James M. Broering; Michael R. Benoit; Sabrina A. Zimmerman; Scott J. Novick; Jack Liang; James J. Lalonde

2014-01-01T23:59:59.000Z

114

CO2 Sequestration by Direct Gas?Solid Carbonation of Air Pollution Control (APC) Residues  

Science Journals Connector (OSTI)

CO2 Sequestration by Direct Gas?Solid Carbonation of Air Pollution Control (APC) Residues ... Furthermore, because fossil fuels are projected to be a dominant energy resource in the 21st century,1 technologies for sequestering emissions from fossil fuel combustion in a safe and definitive manner are being developed and implemented. ... According to these authors, the solution containing free calcium could then be used in a carbonation process for capturing CO2 directly from air. ...

Renato Baciocchi; Alessandra Polettini; Raffaella Pomi; Valentina Prigiobbe; Viktoria Nikulshina Von Zedwitz; Aldo Steinfeld

2006-07-07T23:59:59.000Z

115

Hydrogen and elemental carbon production from natural gas and other hydrocarbons  

DOE Patents [OSTI]

Diatomic hydrogen and unsaturated hydrocarbons are produced as reactor gases in a fast quench reactor. During the fast quench, the unsaturated hydrocarbons are further decomposed by reheating the reactor gases. More diatomic hydrogen is produced, along with elemental carbon. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The product is a substantially clean-burning hydrogen fuel that leaves no greenhouse gas emissions, and elemental carbon that may be used in powder form as a commodity for several processes.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

116

E-Print Network 3.0 - activated carbons produced Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

United States Department of Summary: as qualifying carbon offset activities in existing markets and regis- tries. Forest carbon projects... straightforward way to sequester...

117

E-Print Network 3.0 - activated carbon produced Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

United States Department of Summary: as qualifying carbon offset activities in existing markets and regis- tries. Forest carbon projects... straightforward way to sequester...

118

E-Print Network 3.0 - active carbon process Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI... in the composites is typically that ... Source: Chung, Deborah D.L....

119

E-Print Network 3.0 - activated carbon chemically Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI... in the composites is typically that ... Source: Chung, Deborah D.L....

120

E-Print Network 3.0 - activated carbon treatment Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI... in the composites is typically that ... Source: Chung, Deborah D.L....

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

E-Print Network 3.0 - activated carbon particles Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI... in the composites is typically that ... Source: Chung, Deborah D.L....

122

E-Print Network 3.0 - activated carbon process Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI... in the composites is typically that ... Source: Chung, Deborah D.L....

123

Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report  

SciTech Connect (OSTI)

The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

124

Production Scale-Up or Activated Carbons for Ultracapacitors  

SciTech Connect (OSTI)

Transportation use accounts for 67% of the petroleum consumption in the US. Electric and hybrid vehicles are promising technologies for decreasing our dependence on petroleum, and this is the objective of the FreedomCAR & Vehicle Technologies Program. Inexpensive and efficient energy storage devices are needed for electric and hybrid vehicle to be economically viable, and ultracapacitors are a leading energy storage technology being investigated by the FreedomCAR program. The most important parameter in determining the power and energy density of a carbon-based ultracapacitor is the amount of surface area accessible to the electrolyte, which is primarily determined by the pore size distribution. The major problems with current carbons are that their pore size distribution is not optimized for liquid electrolytes and the best carbons are very expensive. TDA Research, Inc. (TDA) has developed methods to prepare porous carbons with tunable pore size distributions from inexpensive carbohydrate based precursors. The use of low-cost feedstocks and processing steps greatly lowers the production costs. During this project with the assistance of Maxwell Technologies, we found that an impurity was limiting the performance of our carbon and the major impurity found was sulfur. A new carbon with low sulfur content was made and found that the performance of the carbon was greatly improved. We also scaled-up the process to pre-production levels and we are currently able to produce 0.25 tons/year of activated carbon. We could easily double this amount by purchasing a second rotary kiln. More importantly, we are working with MeadWestvaco on a Joint Development Agreement to scale-up the process to produce hundreds of tons of high quality, inexpensive carbon per year based on our processes.

Dr. Steven D. Dietz

2007-01-10T23:59:59.000Z

125

Quantifying Greenhouse Gas Emissions from Human Activities: Toward  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Quantifying Greenhouse Gas Emissions from Human Activities: Toward Quantifying Greenhouse Gas Emissions from Human Activities: Toward Verification of Emissions Control Compliance Speaker(s): Marc Fischer Date: April 29, 2010 - 12:00pm Location: 90-3122 Local to international control of anthropogenic greenhouse gas (GHG) emissions will require systematic estimation of emissions and independent verification. California, the only state in the US with legislated controls on GHG emissions, is conducting research to enable emissions verification of the mandated emissions reductions (AB-32). The California Energy Commission supports the California Greenhouse Gas Emissions Measurement (CALGEM) project at LBNL. In collaboration with NOAA, CALGEM measures mixing ratios of all significant GHGs at two tall-towers and on aircraft in

126

Natural catalytic activity in a marine shale for generating natural gas  

Science Journals Connector (OSTI)

...natural catalytic activity in marine shales. Gas is generated at ambient temperatures...differences are in degree. Mowry shale generates gas compositions that are quite different...probably a major source of natural gas. Mowry shale generates gas at thermodynamic...

2010-01-01T23:59:59.000Z

127

Experimental investigation of factors controlling the calcium carbonate ion activity product of shallow water carbonate-rich sediments  

E-Print Network [OSTI]

EXPERIMENTAL INVESTIGATION OF FACTORS CONTROLLING THE CALCIUM CARBONATE ION ACTIVITY PRODUCT OF SHALLOW WATER CARBONATE-RICH SEDIMENTS A Thesis by LAWRENCE DOUGLAS BERNSTEIN Submitted to the Graduate College of Texas A&M University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1983 Major Subject: Oceanography EXPERIMENTAL INVESTIGATION OF FACTORS CONTROLLING THE CALCIUM CARBONATE ION ACTIVITY PRODUCT OF SHALLOW WATER CARBONATE...

Bernstein, Lawrence Douglas

1983-01-01T23:59:59.000Z

128

Field Testing of Activated Carbon Injection Options for Mercury Control at TXU's Big Brown Station  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Field TesTing oF AcTivATed cArbon Field TesTing oF AcTivATed cArbon injecTion opTions For Mercury conTrol AT TXu's big brown sTATion Background The 2005 Clean Air Mercury Rule will require significant reductions in mercury emissions from coal-fired power plants. Lignite coal is unique because of its highly variable ash content (rich in alkali and alkaline-earth elements), high moisture levels, low chlorine content, and high calcium content. Unique to Texas lignite coals are relatively high iron and selenium concentrations. When combusting Texas lignite coals, up to 80 percent of the mercury in the flue gas is present as elemental mercury, which is not readily captured by downstream pollution control devices. To better understand the factors that influence mercury control at units firing

129

Activated carbon injection - a mercury control success story  

SciTech Connect (OSTI)

Almost 100 full-scale activated carbon injection (ACI) systems have been ordered by US electric utilities. These systems have the potential to remove over 90% of the mercury in flue, at a cost below $10,000 per pound of mercury removal. Field trials of ACI systems arm outlined. 1 fig.

NONE

2008-07-01T23:59:59.000Z

130

Using Carbon Dioxide to Enhance Recovery of Methane from Gas Hydrate Reservoirs: Final Summary Report  

SciTech Connect (OSTI)

Carbon dioxide sequestration coupled with hydrocarbon resource recovery is often economically attractive. Use of CO2 for enhanced recovery of oil, conventional natural gas, and coal-bed methane are in various stages of common practice. In this report, we discuss a new technique utilizing CO2 for enhanced recovery of an unconventional but potentially very important source of natural gas, gas hydrate. We have focused our attention on the Alaska North Slope where approximately 640 Tcf of natural gas reserves in the form of gas hydrate have been identified. Alaska is also unique in that potential future CO2 sources are nearby, and petroleum infrastructure exists or is being planned that could bring the produced gas to market or for use locally. The EGHR (Enhanced Gas Hydrate Recovery) concept takes advantage of the physical and thermodynamic properties of mixtures in the H2O-CO2 system combined with controlled multiphase flow, heat, and mass transport processes in hydrate-bearing porous media. A chemical-free method is used to deliver a LCO2-Lw microemulsion into the gas hydrate bearing porous medium. The microemulsion is injected at a temperature higher than the stability point of methane hydrate, which upon contacting the methane hydrate decomposes its crystalline lattice and releases the enclathrated gas. Small scale column experiments show injection of the emulsion into a CH4 hydrate rich sand results in the release of CH4 gas and the formation of CO2 hydrate

McGrail, B. Peter; Schaef, Herbert T.; White, Mark D.; Zhu, Tao; Kulkarni, Abhijeet S.; Hunter, Robert B.; Patil, Shirish L.; Owen, Antionette T.; Martin, P F.

2007-09-01T23:59:59.000Z

131

Preparation of activated carbon from date pits: Effect of the activation agent and liquid phase oxidation  

Science Journals Connector (OSTI)

Two series of activated carbons have been prepared from date pits; series C, using carbon dioxide as activating agent, and series S, prepared by activation with steam under the same experimental conditions. The obtained samples were oxidized with nitric acid in order to introduce more oxygen surface groups. The surface area and porosity of the parent and oxidized activated carbons were studied by N2 adsorption at 77 K and CO2 adsorption at 273 K. The oxygen surface complexes were characterized by temperature-programmed decomposition (TPD). The results show that carbon dioxide and steam activations produce microporous carbons with an increasing amount of CO evolving groups when increasing the burn-off. On the other hand, oxidation with nitric acid increases the amount of CO and CO2 evolved by the decomposition of surface oxygen groups, this increase being related to the development of porosity in the carbon with the degree of activation and to the activating agent used (CO2 versus steam).

Meriem Belhachemi; Rachel V.R.A. Rios; Fatima Addoun; Joaquín Silvestre-Albero; Antonio Sepúlveda-Escribano; Francisco Rodríguez-Reinoso

2009-01-01T23:59:59.000Z

132

A Carbon Dioxide Gas Turbine Direct Cycle with Partial Condensation for Nuclear Reactors  

SciTech Connect (OSTI)

A carbon dioxide gas turbine power generation system with a partial condensation cycle has been proposed for thermal and fast nuclear reactors, in which compression is done partly in the liquid phase and partly in the gas phase. This cycle achieves higher cycle efficiency than a He direct cycle mainly due to reduced compressor work of the liquid phase and of the carbon dioxide real gas effect, especially in the vicinity of the critical point. If this cycle is applied to a thermal reactor, efficiency of this cycle is about 55% at a reactor outlet temperature of 900 deg. C and pressure of 12.5 MPa, which is higher by about 10% than a typical helium direct gas turbine cycle plant (PBMR) at 900 deg. C and 8.4 MPa; this cycle also provides comparable cycle efficiency at the moderate core outlet temperature of 600 deg. C with that of the helium cycle at 900 deg. C. If this cycle is applied to a fast reactor, it is anticipated to be an alternative to liquid metal cooled fast reactors that can provide slightly higher cycle efficiency at the same core outlet temperature; it would eliminate safety problems, simplify the heat transport system and simplify plant maintenance. A passive decay heat removal system is realized by connecting a liquid carbon dioxide storage tank with the reactor vessel and by supplying carbon dioxide gasified from the tank to the core in case of depressurization event. (authors)

Yasuyoshi Kato; Takeshi Nitawaki; Yoshio Yoshizawa [Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, 152-8550 (Japan)

2002-07-01T23:59:59.000Z

133

Possibility of buffer-gas cooling of paramagnetic carbon to ultracold temperatures R. V. Krems,1,  

E-Print Network [OSTI]

. The temperature of the buffer-gas varies between tens of mK and 1 K. The atoms cooled can be trapped ground state 3 P0 atoms cannot be magnetically trapped. The trapping of carbon atoms at ultra- cold

Krems, Roman

134

Seven Data Sets Released from LBA Carbon Dynamics and Trace Gas Teams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Data Sets Released from LBA Carbon Dynamics and Trace Gas Teams Data Sets Released from LBA Carbon Dynamics and Trace Gas Teams The ORNL DAAC and the LBA DIS announce the release of four data sets from the Carbon Dynamics teams and three data sets from the Trace Gas and Aerosol Fluxes science teams, components of the LBA-ECO Large Scale Biosphere-Atmosphere Experiment in Amazonia (LBA). LBA-ECO CD-02 C and N Isotopes in Leaves and Atmospheric CO2, Amazonas, Brazil . Data set prepared by A.C. de Araujo, J.P.H.B. Ometto, A.J. Dolman, B. Kruijt, M.J. Waterloo and J.R. Ehleringer. This data set reports delta 13C/12C results for leaf tissues and atmospheric carbon dioxide (CO2), delta 15N/14N ratios for leaf tissue, and leaf carbon and nitrogen concentrations along a topographical gradient in old-growth forests near Manaus, Amazonas, Brazil. Also included are coincident

135

Forest Bioenergy or Forest Carbon? Assessing Trade-Offs in Greenhouse Gas Mitigation with Wood-Based Fuels  

Science Journals Connector (OSTI)

Forest Bioenergy or Forest Carbon? ... Forest carbon consequences of biomass harvest for bioenergy production can significantly delay and reduce GHG mitigation and should be included in life cycle studies. ... The potential of forest-based bioenergy to reduce greenhouse gas (GHG) emissions when displacing fossil-based energy must be balanced with forest carbon implications related to biomass harvest. ...

Jon McKechnie; Steve Colombo; Jiaxin Chen; Warren Mabee; Heather L. MacLean

2010-12-10T23:59:59.000Z

136

Catalytic activation of carbon monoxide on metal surfaces  

SciTech Connect (OSTI)

In discussing the important basic aspects of carbon monoxide chemistry, this review covers the adsorption and reaction of CO with H/sub 2/O and H/sub 2/ on reduced metal surfaces. Carbon monoxide adsorption of the Group VIII metals exhibits certain patterns. Typically, as coverages exceed one-half, compression occurs in the monolayer and the molecules lose registry with the surface metal atoms. Particular sites associated with rough surfaces facilitate CO dissociation to the surface carbon; these sites may have a significant effect on selectivity in the CO hydrogenation reaction. The support used and the metal crystallite size both affect the catalyst activity and product selectivity. Indications are strong that a better knowledge of metal-support interactions combined with a more complete understanding of the surface chemistry involved will lead to improved catalyst systems in the future.

Vannice, M.A.

1982-01-01T23:59:59.000Z

137

Sorption of uranium from nitric acid solution using TBP-impregnated activated carbons  

SciTech Connect (OSTI)

The concept of extraction chromatography has been used to study the sorption of uranium from nitric acid solutions using tri-n-butyl phosphate (TBP) impregnated activated carbons. Batch equilibrium data and kinetic and breakthrough column behavior of uranium are reported. Wood based activated carbon has shown better capacity and breakthrough characteristics than shell based activated carbon. Sorption rate on impregnated carbons was relatively slow indicating that diffusion is the rate controlling step within the pore structure of the activated carbon. Uranium distribution on impregnated activated carbons is compared with equivalent bulk liquid extraction and a mechanism of uranium sorption is discussed.

Abbasi, W.A. [Pakistan Atomic Energy Commission, Islamabad (Pakistan). Pakistan Inst. of Nuclear Science and Technology; Streat, M. [Loughborough Univ. (United Kingdom). Dept. of Chemical Engineering

1998-08-01T23:59:59.000Z

138

ENVIRONMENTAL EFFECTS IN GALAXIES: MOLECULAR GAS AND NUCLEAR ACTIVITY  

E-Print Network [OSTI]

ENVIRONMENTAL EFFECTS IN GALAXIES: MOLECULAR GAS AND NUCLEAR ACTIVITY DUILIA DE MELLO and TOMMY;ENVIRONMENTAL EFFECTS IN GALAXIES 69 a. log(MH2 /LB) versus Morphology b. Kolmogorov-Smirnov Statistic Figure 2 in dense envir- onments and in the field and to study whether there is any correlation between nuclear

Maia, Marcio Antonio Geimba

139

On the Radio-activity of Natural Gas  

Science Journals Connector (OSTI)

... Physical Science Series, an account is given of some experiments with a highly radio-active gas obtained from crude petroleum. In this investigation it was found that air drawn through ... emanation from radium. The present writer has extended this investigation to an examination of the natural ...

J. C. MCLENNAN

1904-06-16T23:59:59.000Z

140

Innovative Carbon Dioxide Sequestration from Flue Gas Using an In-Duct Scrubber Coupled with Alkaline Clay Mineralization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Innovative Carbon Dioxide Sequestration Innovative Carbon Dioxide Sequestration from Flue Gas Using an In-Duct Scrubber Coupled with Alkaline Clay Mineralization Background The United States Department of Energy (DOE) is leading an effort to find novel approaches to reduce carbon dioxide (CO 2 ) emissions from industrial sources. The Industrial Carbon Capture and Sequestration (ICCS) program is funded by the American Recovery and Reinvestment Act (ARRA) to encourage development of processes that

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Assessment of Hydrogen Production Systems based on Natural Gas Conversion with Carbon Capture and Storage  

Science Journals Connector (OSTI)

Abstract Introduction of hydrogen in the energy system, as a new energy carrier complementary to electricity, is exciting much interest not only for heat and power generation applications, but also for transport and petro-chemical sectors. In transition to a low carbon economy, Carbon Capture and Storage (CCS) technologies represent another way to reduce CO2 emissions. Hydrogen can be produced from various feedstocks, the most important being based on fossil fuels (natural gas and coal). This paper investigates the techno-economic and environmental aspects of hydrogen production based on natural gas reforming conversion with and without carbon capture. As CO2 capture options, gas - liquid absorption and chemical looping were evaluated. The evaluated plant concepts generate 300 MWth hydrogen (based on hydrogen LHV) with purity higher than 99.95 % (vol.), suitable to be used both in petro-chemical applications as well as for Proton Exchange Membrane (PEM) fuel cells for mobile applications. For the designs with CCS, the carbon capture rate is about 70 % for absorption-based scheme while for chemical looping-based system is >99 %. Special emphasis is put in the paper on the assessment of various plant configurations and process integration issues using CAPE techniques. The mass and energy balances have been used furthermore for techno-economic and environmental impact assessments.

Calin-Cristian Cormos; Letitia Petrescu; Ana-Maria Cormos

2014-01-01T23:59:59.000Z

142

Quantification of undersea gas leaks from carbon capture and storage facilities, from pipelines and from methane seeps, by their acoustic emissions  

Science Journals Connector (OSTI)

...Quantification of undersea gas leaks from carbon capture and storage facilities, from...importance of leak detection from carbon capture and storage facilities and the...pipelines or leaks from facilities for carbon capture and storage) have the advantage...

2012-01-01T23:59:59.000Z

143

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase  

E-Print Network [OSTI]

Sulfur Impregnation on Activated Carbon Fibers through H2S Oxidation for Vapor Phase Mercury: Sulfur was impregnated onto activated carbon fibers ACFs through H2S oxidation catalyzed by the sorbent CE Database subject headings: Activated carbon; Sulfur; Mercury; Hydrogen sulfides; Oxidation

Borguet, Eric

144

Nitrogen in aramid-based activated carbon fibers by TPD, XPS and XANES  

E-Print Network [OSTI]

1 Nitrogen in aramid-based activated carbon fibers by TPD, XPS and XANES J.P. Boudou a,* , Ph, 33080 Oviedo, Spain Abstract Activated carbon fibers were prepared from Nomex@ [poly to a great extent in the derived carbonized and activated fibers, it is of interest to gain knowledge about

145

An active carbon catalyst prevents coke formation from asphaltenes during the hydrocracking of vacuum residue  

SciTech Connect (OSTI)

Active carbons were prepared by the steam activation of a brown coal char. The active carbon with mesopores showed greater adsorption selectivity for asphaltenes. The active carbon was effective at suppressing coke formation, even with the high hydrocracking conversion of vacuum residue. The analysis of the change in the composition of saturates, aromatics, resins, and asphaltenes in the cracked residue with conversion demonstrated the ability of active carbon to restrict the transformation of asphaltenes to coke. The active carbon that was richer in mesopores was presumably more effective at providing adsorption sites for the hydrocarbon free-radicals generated initially during thermal cracking to prevent them from coupling and polycondensing.

Fukuyama, H.; Terai, S. [Toyo Engineering Corp., Chiba (Japan). Technological Research Center

2007-07-01T23:59:59.000Z

146

Preparation of activated carbon aerogel and its application to electrode material for electric double layer capacitor in organic electrolyte: Effect of activation temperature  

Science Journals Connector (OSTI)

Carbon aerogel was chemically activated with KOH at various activation temperatures with the aim of improving the electrochemical performance of carbon aerogel for EDLC electrode. Electrochemical performance o...

Soon Hyung Kwon; Eunji Lee; Bum-Soo Kim…

2014-11-01T23:59:59.000Z

147

Comparison of Numerical Simulators for Greenhouse Gas Storage in Coalbeds, Part I: Pure Carbon Dioxide Injection  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comparison of Numerical Simulators for Greenhouse Gas Storage Comparison of Numerical Simulators for Greenhouse Gas Storage in Coalbeds, Part I: Pure Carbon Dioxide Injection David H.-S. Law (law@arc.ab.ca; 780-450-5034) Alberta Research Council (ARC) Inc. 250 Karl Clark Road, Edmonton, Alberta, Canada T6N 1E4 L.H.G. (Bert) van der Meer (l.vandermeer@nitg.tno.nl; +31-30-256-4635) Netherlands Institute of Applied Geoscience TNO P.O. Box 80015, 3508 TA Utrecht, The Netherlands W.D. (Bill) Gunter (gunter@arc.ab.ca; 780-450-5467) Alberta Research Council (ARC) Inc. 250 Karl Clark Road, Edmonton, Alberta, Canada T6N 1E4 Abstract The injection of carbon dioxide (CO 2 ) in deep, unmineable coalbeds is a very attractive option for geologic CO 2 storage: the CO 2 is stored and at the same time the recovery of

148

Small-scale Facilities for Gas Clean Up and Carbon Capture Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Henry W. Pennline Henry W. Pennline Chemical Engineer National Energy Technology Laboratory 626 Cochrans Mill Road P.O. Box 10940 Pittsburgh, PA 15236-0940 412-386-6013 henry.pennline@netl.doe.gov Diane (DeeDee) Newlon Technology Transfer Manager National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507 304-285-4086 r.diane.newlon@netl.doe.gov Small-Scale FacilitieS For GaS clean Up and carbon captUre reSearch Capabilities The Department of Energy's (DOE) National Energy Technology Laboratory (NETL) is conducting research on the cleanup of gas produced either by the combustion or gasification of fossil fuels. This effort directly supports the goal of various DOE technology programs (i.e., Carbon Sequestration, Gasification, etc.) to ensure the continued utilization of coal in an environmentally and economically

149

A Case Study from Norway on Gas-Fired Power Plants, Carbon Sequestration, and Politics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Case Study from Norway on Case Study from Norway on Gas-Fired Power Plants, Carbon Sequestration, and Politics Guillaume Quiviger and Howard Herzog (hjherzog@mit.edu; +1-617-253-0688) Massachusetts Institute of Technology (MIT) Room E40-471 1 Amherst Street Cambridge, MA 02139 INTRODUCTION On Thursday March 9, 2000, Norwegian Prime Minister Kjell Magne Bondevik's minority government resigned over a disagreement with the opposition about a controversial proposal to build two gas-fired power plants. The government had been rejecting the building of the proposed plants for months. Bondevik and his coalition government wanted to hold off construction until new technology, such as carbon sequestration, allowed building more environmentally friendly plants. They argued that their position was supported by European

150

Landfill gas cleanup for carbonate fuel cell power generation. Final report  

SciTech Connect (OSTI)

To utilize landfill gas for power generation using carbonate fuel cells, the LFG must be cleaned up to remove sulfur and chlorine compounds. This not only benefits the operation of the fuel cell, but also benefits the environment by preventing the emission of these contaminants to the atmosphere. Commercial technologies for gas processing are generally economical in relatively large sizes (3 MMSCFD or larger), and may not achieve the low levels of contaminants required. To address the issue of LFG clean-up for fuel cell application, a process was developed utilizing commercially available technology. A pilot-scale test facility utilizing this process was built at a landfill site in Anoka, Minnesota using the EPRI fuel cell test facility used for coal gas testing. The pilot plant was tested for 1000 hours, processing 970,000 SCF (27,500 Nm{sup 3}) of landfill gas. Testing indicated that the process could achieve the following concentrations of contaminants in the clean gas: Less than 80 ppbv hydrogen sulfide; less than 1 ppm (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv if any individual chlorinated hydrocarbon; and 1.5 ppm (average) Sulfur Dioxide. The paper describes the LFG composition for bulk and trace compounds; evaluation of various methods to clean landfill gas; design of a LFG cleanup system; field test of pilot-scale gas cleanup process; fuel cell testing on simulated landfill gas; single cell testing on landfill gas contaminants and post test analysis; and design and economic analyses of a full scale gas cleanup system.

Steinfeld, G.; Sanderson, R.

1998-02-01T23:59:59.000Z

151

Diameters of Single-Wall Carbon Nanotubes Depending on Helium Gas Pressure in an Arc Discharge  

Science Journals Connector (OSTI)

Diameters of Single-Wall Carbon Nanotubes Depending on Helium Gas Pressure in an Arc Discharge ... So far, relatively large quantities of SWNTs have been produced by using Y?Ni and Fe?Ni catalysts for the electric arc discharge method28-30 and by using a Co?Ni catalyst for the pulsed laser ablation method. ... The electric current of the arc discharge also affected the yield of SWNTs though its effect was not as serious as the helium pressure. ...

Yahachi Saito; Yoshihiko Tani; Atsuo Kasuya

2000-02-26T23:59:59.000Z

152

Pt loaded carbon aerogel catalyst for catalytic exchange reactions between water and hydrogen gas  

Science Journals Connector (OSTI)

We report development and characterization of platinum doped carbon aerogel catalyst for catalytic exchange reactions between water and hydrogen gas. The carbon aerogel with uniformly dispersed platinum nanoparticles was prepared by adding platinum precursor during the sol-gel process. Thereafter colloidal PTFE was mixed with the platinum doped carbon aerogel powder and coated on Dixon rings to obtain hydrophobic catalyst with required mechanical strength. Detailed studies have been carried out to observe the effect of physical characteristics of the catalyst powder (surface area and pore size of aerogels Pt cluster size and its valence state etc) and the different coating parameters (PTFE to Pt-CA ratio and Pt loading on Dixon ring) on volume transfer rate (Ky.a) for H/D reaction. Ky.a values of ?0.8 m3 (STP).s?1. m?3 were obtained for Pt loading of 7% and Pt cluster size of 3 nm at atmospheric pressure.

P. K. Gupta

2013-01-01T23:59:59.000Z

153

The landfill gas activity of the IEA bioenergy agreement  

Science Journals Connector (OSTI)

Landfill gas (LFG) is a renewable source of useful energy. Its world wide annual energy potential is in the range of a few hundred TWh. Today it is only marginally exploited. LFG is also an important contributor to the atmospheres CH4-content, it can be estimated to contribute about 25% of the methane coming from anthropogenic sources. In comparison to many other sources of methane emissions such as peat bogs, rice paddies, termites and sheep, landfills can be considered to be point sources, i.e. they are stationary and of limited extension. For this reason landfill gas (LFG) utilisation is one of the most cost effective ways to combat the greenhouse effect. The aim of the IEA activity on LFG is to promote information exchange and co-operation between national programmes in order to promote the proliferation of landfill gas utilisation. During the period 1992–1994 the LFG activity has had six participating countries: Canada, Denmark, Norway, The Netherlands, Sweden, UK and USA. In the past three-year period, the activity has been mainly directed towards establishing networks and obtaining an over-view of data related to LFG in the member countries. Numerous contacts have been established and perhaps of most importance for the future of the activity are the links towards organisations involved in the development of landfill technology, such as ISWA and SWANA. The gathering and evaluation of data within the LFG area from the member countries has resulted in a number of documents that are to be published within the near future. These documents cover information on LFG utilisation, landfill research, landfill gas potentials, landfill emission assessment and also non-technical barriers to LFG utilisation.

A Lagerkvist

1995-01-01T23:59:59.000Z

154

Carbon capture with low energy penalty: Supplementary fired natural gas combined cycles  

Science Journals Connector (OSTI)

Enhancing CO2 concentration in exhaust gas has been considered as a potentially effective method to reduce the penalty of electrical efficiency caused by CO2 chemical absorption in post-combustion carbon capture systems. Supplementary firing is an option that inherently has an increased CO2 concentration in the exhaust gas, albeit a relatively low electrical efficiency due to its increased mass flow of exhaust gas to treat and large temperature difference in heat recovery steam generator. This paper focuses on the methods that can improve the electrical efficiency of the supplementary fired combined cycles (SFCs) integrated with MEA-based CO2 capture. Three modifications have been evaluated: (I) integration of exhaust gas reheating, (II) integration of exhaust gas recirculation, and (III) integration of supercritical bottoming cycle. It is further showed that combining all three modifications results in a significant increase in electrical efficiency which is raised from 43.3% to 54.1% based on Lower Heating Value (LHV) of natural gas when compared to the original SFC. Compared with a conventional combined cycle with a subcritical bottoming cycle and without CO2 capture (56.7% of LHV), the efficiency penalty caused by CO2 capture is only 2.6% of LHV.

Hailong Li; Mario Ditaranto; Jinyue Yan

2012-01-01T23:59:59.000Z

155

Relevance of underground natural gas storage to geologic sequestration of carbon dioxide  

SciTech Connect (OSTI)

The practice of underground natural gas storage (UNGS), which started in the USA in 1916, provides useful insight into the geologic sequestration of carbon dioxide--the dominant anthropogenic greenhouse gas released into the atmosphere. In many ways, UNGS is directly relevant to geologic CO{sub 2} storage because, like CO{sub 2}, natural gas (essentially methane) is less dense than water. Consequently, it will tend to rise to the top of any subsurface storage structure located below the groundwater table. By the end of 2001 in the USA, about 142 million metric tons of natural gas were stored underground in depleted oil and gas reservoirs and brine aquifers. Based on their performance, UNGS projects have shown that there is a safe and effective way of storing large volumes of gases in the subsurface. In the small number of cases where failures did occur (i.e., leakage of the stored gas into neighboring permeable layers), they were mainly related to improper well design, construction, maintenance, and/or incorrect project operation. In spite of differences in the chemical and physical properties of the gases, the risk-assessment, risk-management, and risk-mitigation issues relevant to UNGS projects are also pertinent to geologic CO{sub 2} sequestration.

Lippmann, Marcelo J.; Benson, Sally M.

2002-07-01T23:59:59.000Z

156

Carbon Geography: The Political Economy of Congressional Support for Legislation Intended to Mitigate Greenhouse Gas Production  

SciTech Connect (OSTI)

Over the last five years, the U.S Congress has voted on several pieces of legislation intended to sharply reduce the nation’s greenhouse gas emissions. Given that climate change is a world public bad, standard economic logic would predict that the United States would ?free ride? and wait for other nations to reduce their emissions. Within the Congress, there are clear patterns to who votes in favor of mitigating greenhouse gas emissions. This paper presents a political economy analysis of the determinants of ?pro-green? votes on such legislation. Conservatives consistently vote against such legislation. Controlling for a Representative’s ideology, representatives from richer districts and districts with a lower per-capita carbon dioxide footprint are more likely to vote in favor of climate change mitigation legislation. Representatives from districts where industrial emissions represent a larger share of greenhouse gas emissions are more likely to vote no.

Cragg, Michael; Zhou, Yuyu; Gurney, Kevin R.; Kahn, Matthew

2013-04-01T23:59:59.000Z

157

Adsorption of methane and carbon dioxide on gas shale and pure mineral samples  

Science Journals Connector (OSTI)

Abstract We have measured methane and carbon dioxide adsorption isotherms at 40 °C on gas shale samples from the Barnett, Eagle Ford, Marcellus and Montney reservoirs. Carbon dioxide isotherms were included to assess its potential for preferential adsorption, with implications for its use as a fracturing fluid and/or storage in depleted shale reservoirs. To better understand how the individual mineral constituents that comprise shales contribute to adsorption, measurements were made on samples of pure carbon, illite and kaolinite as well. We were able to successfully fit all adsorption data for both gases in accordance with a Langmuir isotherm model. Our results show carbon dioxide to have approximately 2–3 times the adsorptive capacity of methane in both the pure mineral constituents and actual shale samples. In addition to obvious microstructural and compositional differences between real rocks and pure minerals, we hypothesize that water adsorption plays an important role in regulating surface area availability for other molecules to adsorb. The resultant volumetric swelling strain was also measured as a function of pressure/adsorption. We observe both clay and pure carbon to swell an amount that is approximately linearly proportional to the amount of adsorption.

Robert Heller; Mark Zoback

2014-01-01T23:59:59.000Z

158

HYDROTHERMAL ACTIVITY AND CARBON-DIOXIDE DISCHARGE AT SHRUB AND UPPER KLAWASI MUD VOLCANOES,  

E-Print Network [OSTI]

HYDROTHERMAL ACTIVITY AND CARBON-DIOXIDE DISCHARGE AT SHRUB AND UPPER KLAWASI MUD VOLCANOES and July 1973 at Shrub and Upper Klawasi mud volcanoes 8 ii #12;HYDROTHERMAL ACTIVITY AND CARBON. Map of diffuse carbon dioxide flow from soils near the summit of Shrub mud volcano 9 TABLES 1

159

Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry  

E-Print Network [OSTI]

Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas: Coal gasification Carbon gasification Detailed chemistry Heterogeneous surface reactions Radiation Multi-physics numerical modeling a b s t r a c t Fuel synthesis through coal and biomass gasification

Qiao, Li

160

Carbon Isotope Fractionation in the System CO2(gas)—CO2(aqueous)—HCO3?(aqueous)  

Science Journals Connector (OSTI)

... three-neck distilling flasks of 300 ml. capacity were used as reaction vessels. A gas sample tube, a liquid-sampling pipette which consisted of two stopcocks in series with ... a minimum of silicone grease in order to avoid contact between solution and grease. The gas sample tube was filled with the desired amount of carbon dioxide and the pipette and ...

W. G. DEUSER; E. T. DEGENS

1967-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Carbon capture by sorption-enhanced water-gas shift reaction process using hydrotalcite-based material  

SciTech Connect (OSTI)

A novel route for precombustion decarbonization is the sorption-enhanced water-gas shift (SEWGS) process. In this process carbon dioxide is removed from a synthesis gas at elevated temperature by adsorption. Simultaneously, carbon monoxide is converted to carbon dioxide by the water-gas shift reaction. The periodic adsorption and desorption of carbon dioxide is induced by a pressure swing cycle, and the cyclic capacity can be amplified by purging with steam. From previous studies is it known that for SEWGS applications, hydrotalcite-based materials are particularly attractive as sorbent, and commercial high-temperature shift catalysts can be used for the conversion of carbon monoxide. Tablets of a potassium promoted hydrotalcite-based material are characterized in both breakthrough and cyclic experiments in a 2 m tall fixed-bed reactor. When exposed to a mixture of carbon dioxide, steam, and nitrogen at 400{sup o}C, the material shows a breakthrough capacity of 1.4 mmol/g. In subsequent experiments the material was mixed with tablets of promoted iron-chromium shift catalyst and exposed to a mixture of carbon dioxide, carbon monoxide, steam, hydrogen, and nitrogen. It is demonstrated that carbon monoxide conversion can be enhanced to 100% in the presence of a carbon dioxide sorbent. At breakthrough, carbon monoxide and carbon dioxide simultaneously appear at the end of the bed. During more than 300 cycles of adsorption/reaction and desorption, the capture rate, and carbon monoxide conversion are confirmed to be stable. Two different cycle types are investigated: one cycle with a CO{sub 2} rinse step and one cycle with a steam rinse step. The performance of both SEWGS cycles are discussed.

van Selow, E.R.; Cobden, P.D.; Verbraeken, P.A.; Hufton, J.R.; van den Brink, R.W. [Energy research Center of the Netherlands, Petten (Netherlands)

2009-05-15T23:59:59.000Z

162

Remote Functionalization of Carbon-Hydrogen and Carbon-Carbon Bonds by Bare Transition Metal Ions in the Gas Phase  

Science Journals Connector (OSTI)

The selective functionaIization of C-H bonds remains one of the major focuses of catalytic and organic chemistry. High selectivity is often achieved by the presence of activating groups which induce the reacti...

Gregor Czekay; Thomas Drewello; Karsten Eller…

1989-01-01T23:59:59.000Z

163

Post-combustion Carbon Capture with a Gas Separation Membrane: Parametric Study, Capture Cost, and Exergy Analysis  

Science Journals Connector (OSTI)

Post-combustion Carbon Capture with a Gas Separation Membrane: Parametric Study, Capture Cost, and Exergy Analysis ... (5) In a post-combustion CO2 capture process, the purity of the captured CO2 in the permeate stream mainly depends upon the selectivity of CO2 over the other gas species, such as N2 and O2. ... Capturing CO2 from flue gases in a power plant is not like traditional gas processing or purification, there are no strict requirements on the decarbonized sweet gas, which means no strict requirement on the CO2 concentration in the sweet gas or CO2 capture ratio. ...

Xiangping Zhang; Xuezhong He; Truls Gundersen

2013-03-04T23:59:59.000Z

164

NETL: Carbon Storage - Reference Shelf  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Storage > Reference Shelf Carbon Storage > Reference Shelf Carbon Storage Reference Shelf Below are links to Carbon Storage Program documents and reference materials. Each of the 10 categories has a variety of documents posted for easy access to current information - just click on the category link to view all related materials. RSS Icon Subscribe to the Carbon Storage RSS Feed. Carbon Storage Collage 2012 Carbon Utilization and Storage Atlas IV Carbon Sequestration Project Portfolio DOE/NETL Carbon Dioxide Capture and Storage RD&D Roadmap Public Outreach and Education for Carbon Storage Projects Carbon Storage Technology Program Plan Carbon Storage Newsletter Archive Impact of the Marcellus Shale Gas Play on Current and Future CCS Activities Site Screening, Selection, and Initial Characterization for Storage of CO2 in Deep Geologic Formations Carbon Storage Systems and Well Management Activities Monitoring, Verification, and Accounting of CO2 Stored in Deep Geologic Formations

165

Windowed Carbon Nanotubes for Efficient CO2 Removal from Natural Gas  

E-Print Network [OSTI]

We demonstrate from molecular dynamics simulations that windowed carbon nanotubes can efficiently separate CO2 from the CO2/CH4 mixture, resembling polymeric hollow fibers for gas separation. Three CO2/CH4 mixtures with 30%, 50% and 80% CO2 are investigated as a function of applied pressure from 80 to 180 bar. In all simulated conditions, only CO2 permeation is observed; CH4 is completely rejected by the nitrogen-functionalized windows or pores on the nanotube wall in the accessible timescale, while maintaining a fast diffusion rate along the tube. The estimated time-dependent CO2 permeance ranges from 107 to 105 GPU (gas permeation unit), compared with ~100 GPU for typical polymeric membranes. CO2/CH4 selectivity is estimated to be ~108 from the difference in free-energy barriers of permeation. This work suggests that a windowed carbon nanotube can be used as a highly efficient medium, configurable in hollow-fiber-like modules, for removing CO2 from natural gas.

Liu, Hongjun; Dai, Sheng; Jiang, De-en; 10.1021/jz301576s

2012-01-01T23:59:59.000Z

166

Method and system for capturing carbon dioxide and/or sulfur dioxide from gas stream  

DOE Patents [OSTI]

The present invention provides a system for capturing CO.sub.2 and/or SO.sub.2, comprising: (a) a CO.sub.2 and/or SO.sub.2 absorber comprising an amine and/or amino acid salt capable of absorbing the CO.sub.2 and/or SO.sub.2 to produce a CO.sub.2- and/or SO.sub.2-containing solution; (b) an amine regenerator to regenerate the amine and/or amino acid salt; and, when the system captures CO.sub.2, (c) an alkali metal carbonate regenerator comprising an ammonium catalyst capable catalyzing the aqueous alkali metal bicarbonate into the alkali metal carbonate and CO.sub.2 gas. The present invention also provides for a system for capturing SO.sub.2, comprising: (a) a SO.sub.2 absorber comprising aqueous alkali metal carbonate, wherein the alkali metal carbonate is capable of absorbing the SO.sub.2 to produce an alkali metal sulfite/sulfate precipitate and CO.sub.2.

Chang, Shih-Ger; Li, Yang; Zhao, Xinglei

2014-07-08T23:59:59.000Z

167

Activated carbon aerogel as electrode material for coin-type EDLC cell in organic electrolyte  

Science Journals Connector (OSTI)

Abstract Carbon aerogel (CA) was prepared by a carbonization of resorcinol–formaldehyde (RF) polymer gels, and it was chemically activated with KOH to obtain activated carbon aerogel (ACA) for electrode material for EDLC in organic electrolyte. Coin-type EDLC cells with two symmetrical carbon electrode were assembled using the prepared carbon materials. Electrochemical performance of the carbon electrodes was measured by galvanostatic charge/discharge and cyclic voltammetry methods. Activated carbon aerogel (20.9 F/g) showed much higher specific capacitance than carbon aerogel (7.9 F/g) and commercial activated carbon (8.5 F/g) at a scan rate of 100 mV/s. This indicates that chemical activation with KOH served as an efficient method to improve electrochemical performance of carbon aerogel for EDLC electrode in organic electrolyte. The enhanced electrochemical performance of activated carbon aerogel was attributed to the high effective surface area and the well-developed pore structure with appropriate pore size obtained from activation with KOH.

Soon Hyung Kwon; Eunji Lee; Bum-Soo Kim; Sang-Gil Kim; Byung-Jun Lee; Myung-Soo Kim; Ji Chul Jung

2014-01-01T23:59:59.000Z

168

International oil and gas exploration and development activities  

SciTech Connect (OSTI)

This report is part of an ongoing series of quarterly publications that monitors discoveries of oil and natural gas in foreign countries and provides an analysis of the reserve additions that result. The report is prepared by the Energy Information Administration (EIA) of the US Department of Energy (DOE) under the Foreign Energy Supply Assessment Program (FESAP). It presents a summary of discoveries and reserve additions that result from recent international exploration and development activities. It is intended for use by petroleum industry analysts, various government agencies, and political leaders in the development, implementation, and evaluation of energy plans, policy, and legislation. 25 refs., 8 figs., 4 tabs.

Not Available

1990-10-29T23:59:59.000Z

169

Ab Initio Study of Topological Defects in Single Walled Carbon Nanotubes and their Effect on Gas Sensing Mechanism  

SciTech Connect (OSTI)

We have studied the energetics and charge tranfer of the (10,0) and (6,6) single walled carbon nanotubes with various defects such as monovacancy and Stone-Wales defect and their interaction with the Hydrogen Sulphide gas molecule using Ab Initio based computational method to design Single Walled Carbon Nanotube based gas sensor . We have also investigated the effect of Gold doping in Carbon Nanotubes on the adsorption of Hydrogen Sulphide gas molecule. We demonstrate that the adsorption energy as well as charge transfer is affected by the introduction of defects at the surface of the CNTs resulting in improved sensitivity for the Hydrogen Sulphide gas molecules compared to the pristine CNT.

Srirangarajan, Aarti [Nanoelectronics Lab, MIMOS BHD., KL, 57000 (Malaysia); Kahaly, Mousumi Upadhyay [DSM/IRAMIS/SPCSI, CEA Saclay, 91191 (France)

2011-05-25T23:59:59.000Z

170

Oxidative Degradation of Trichloroethylene Adsorbed on Active Carbons: Use of Microwave Energy  

E-Print Network [OSTI]

OXIDATIVE DEGRADATION OF TRICHLOROETHYLENE ADSORBED ON ACTIVE CARBONS: USE OF MICROWAVE ENERGY R. VARMA, S. P. NANDI, D. CLEAVELAND, K. M. MYLES, D. R. VISSERS, AND P. A. NELSON Chemist Chemical Technology Division Argonne National... Laboratory Argonne, Illinois ABSTRACT Trichloroethylene (TCE) adsorbed on different types of active carbons was exposed to a dry and moist air stream in the presence of 2.45 GHz micro wave radiation. Active carbon beds were used becauae they absorb...

Varma, R.; Nandi, S. P.; Cleaveland, D.; Myles, K. M.; Vissers, D. R.; Nelson, P. A.

171

Carbon Dioxide Information Analysis Center: FY 1992 activities  

SciTech Connect (OSTI)

During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIACs staff also provides technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC during the period October 1, 1991 to September 30, 1992. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. As analysis and description of the preparation and distribution of numeric data packages, computer model packages, technical reports, newsletters, fact sheets, specialty publications, and reprints is provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also described.

Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center

1993-03-01T23:59:59.000Z

172

Mercury sorbent delivery system for flue gas  

DOE Patents [OSTI]

The invention presents a device for the removal of elemental mercury from flue gas streams utilizing a layer of activated carbon particles contained within the filter fabric of a filter bag for use in a flue gas scrubbing system.

Klunder; ,Edgar B. (Bethel Park, PA)

2009-02-24T23:59:59.000Z

173

Carbon Nanotubes Inhibit the Hemolytic Activity of the Pore-Forming Toxin Pyolysin  

E-Print Network [OSTI]

Carbon Nanotubes Inhibit the Hemolytic Activity of the Pore-Forming Toxin Pyolysin Apraku David Article Address correspondence to tangxw@uwaterloo.ca ABSTRACT Functionalized carbon nanotubes have oxidized and non-covalently PEGlyated single-walled carbon nanotubes (SWNTs), which were previously

Le Roy, Robert J.

174

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5  

E-Print Network [OSTI]

Single Pd atoms in activated carbon fibers and their contribution to hydrogen storage 5 Cristian I surface area carbon materials for hydrogen storage continues to attract interest because predicted high potential for hydrogen storage on metal-decorated carbon supports, the experimental

Pennycook, Steve

175

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas  

SciTech Connect (OSTI)

The objective of this project is to demonstrate an innovative process to mineralize CO2 from flue gas directly to reactive carbonates and maximize the value and versatility of its beneficial use products. The program scope includes the design, construction, and testing of a CO2 Conversion to Material Products (CCMP) Pilot Demonstration Plant utilizing CO2 from the flue gas of a power production facility in Moss Landing, CA. This topical report covers Subphase 2a which is the design phase of pilot demonstration subsystems. Materials of construction have been selected and proven in both lab scale and prototype testing to be acceptable for the reagent conditions of interest. The target application for the reactive carbonate material has been selected based upon small-scale feasibility studies and the design of a continuous fiber board production line has been completed. The electrochemical cell architecture and components have been selected based upon both lab scale and prototype testing. The appropriate quality control and diagnostic techniques have been developed and tested along with the required instrumentation and controls. Finally the demonstrate site infrastructure, NEPA categorical exclusion, and permitting is all ready for the construction and installation of the new units and upgrades.

Devenney, Martin; Gilliam, Ryan; Seeker, Randy

2013-08-01T23:59:59.000Z

176

Study of Gas-steam Combined Cycle Power Plants Integrated with MCFC for Carbon Dioxide Capture  

Science Journals Connector (OSTI)

Abstract In the field of fossil-fuel based technologies, natural gas combined cycle (NGCC) power plants are currently the best option for electricity generation, having an efficiency close to 60%. However, they produce significant CO2 emissions, amounting to around 0.4 tonne/MWh for new installations. Among the carbon capture and sequestration (CCS) technologies, the process based on chemical absorption is a well-established technology, but markedly reduces the NGCC performances. On the other side, the integration of molten carbonate fuel cells (MCFCs) is recognized as an attractive option to overcome the main drawbacks of traditional CCS technologies. If the cathode side is fed by NGCC exhaust gases, the MCFC operates as a CO2 concentrator, beside providing an additional generating capacity. In this paper the integration of MCFC into a two pressure levels combined cycle is investigated through an energy analysis. To improve the efficiency of MCFC and its integration within the NGCC, plant configurations based on two different gas recirculation options are analyzed. The first is a traditional recirculation of exhaust gases at the compressor inlet; the second, mainly involving the MCFC stack, is based on recirculating a fraction of anode exhaust gases at the cathode inlet. Effects of MCFC operating conditions on energy and environmental performances of the integrated system are evaluated.

Roberto Carapellucci; Roberto Saia; Lorena Giordano

2014-01-01T23:59:59.000Z

177

Optimal electrochemical performances of CO2 activated carbon aerogels for supercapacitors  

Science Journals Connector (OSTI)

Activated carbon aerogels(ACAs) derived from sol-gel polycondensation of resorcinol (R) and formaldehyde (F) were pyrolyzed under Ar flow and activated in CO2 atmosphere. The morphology of ACAs was characterized ...

Lijuan Chang ???; Zhibing Fu; Miao Liu…

2014-04-01T23:59:59.000Z

178

Studies of adsorption characteristics of activated carbons down to 4.5 K for the development of cryosorption pumps for fusion systems  

SciTech Connect (OSTI)

Cryosorption pump is the only possible device to pump helium, hydrogen and its isotopes in fusion environment, such as high magnetic field and high plasma temperatures. Activated carbons are known to be the most suitable adsorbent in the development of cryosorption pumps. For this purpose, the data of adsorption characteristics of activated carbons in the temperature range 4.5 K to 77 K are needed, but are not available in the literature. For obtaining the above data, a commercial micro pore analyzer operating at 77 K has been integrated with a two stage GM cryocooler, which enables the cooling of the sample temperature down to 4.5 K. A heat switch mounted between the second stage cold head and the sample chamber helps to raise the sample chamber temperature to 77 K without affecting the performance of the cryocooler. The detailed description of this system is presented elsewhere. This paper presents the results of experimental studies of adsorption isotherms measured on different types of activated carbons in the form of granules, globules, flake knitted and non-woven types in the temperature range 4.5 K to 10 K using Helium gas as the adsorbate. The above results are analyzed to obtain the pore size distributions and surface areas of the activated carbons. The effect of adhesive used for bonding the activated carbons to the panels is also studied. These results will be useful to arrive at the right choice of activated carbon to be used for the development of cryosorption pumps.

Kasthurirengan, S.; Behera, U.; Vivek, G. A. [Centre for Cryogenic Technology, Indian institute of Science, Bangalore 560012 (India); Krishnamoorthy, V.; Gangradey, R. [Cryopump Group, Institute for Plasma Research, Gandhinagar, Gujarat 382428 (India); Udgata, S. S.; Tripati, V. S. [I-Design Engineering Solutions Ltd., Ubale Nagar, Wagholi, Pune 412207 (India)

2014-01-29T23:59:59.000Z

179

IMPROVEMENT OF METHANE STORAGE IN ACTIVATED CARBON USING METHANE HYDRATE  

E-Print Network [OSTI]

and particles. As the natural gas resources are enormous, it represents a good alternative to oil in term natural gas distribution network. Secondly, at low pressure, the tank geometry can adopt various shapes, gas storage INTRODUCTION. With the massive increase of the urban traffic, coupled with its large

Paris-Sud XI, Université de

180

Molten carbonate fuel cell and gas turbine hybrid systems as distributed energy resources  

Science Journals Connector (OSTI)

Molten carbonate fuel cell (MCFC)/gas turbine (GT) hybrid system has attracted a great deal of research effort due to its higher electricity efficiency. However, its technology has remained at the conceptual level due to incomplete examination of the related issues, challenges and variables. To contribute to the development of system technology, the MCFC/GT hybrid system is analyzed and discussed herein. A qualitative comparison of the two kinds of MCFC/GT hybrid system, indirect and direct, is hindered by the many variables involved. However, the indirect system may be preferred for relatively small-scale systems with the micro-GT. The direct system can be more competitive in terms of system efficiency and GT selection due to the optionality of system layouts as well as even higher GT inlet temperature. System layout is an important factor influencing the system efficiency. The other issues such as GT selection, system pressurization and part-load operation are also significant.

Jung-Ho Wee

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Study of Adsorption of Methanol in an Activated Carbon and Carbon Nanotube Matrix for Use in a Solar Based Refrigeration Cycle  

E-Print Network [OSTI]

energy. Various adsorbent/adsorbate pairs have been tested in literature. The present work focuses on carbon nanotubes because theoretically, nanotubes should be able to adsorb better than activated carbon due to their high surface to volume ratios...

Sambath, Srivaths

2012-07-16T23:59:59.000Z

182

Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity  

SciTech Connect (OSTI)

The objectives of this project are to augment the National Reservoir Database (TORIS database) and to increase our understanding of geologic heterogeneities that affect the recoveries of oil and gas from carbonate reservoirs in the State of Alabama and to identify those resources that are producible at moderate cost. These objectives will be achieved through detailed geological, engineering, and geostatistical characterization of typical Jurassic Smackover Formation hydrocarbon reservoirs in selected productive fields in the State of Alabama. The results of these studies will be used to develop and test mathematical models for prediction of the effects of reservoir heterogeneities in hydrocarbon production. Work to date has focused on the completion of Subtasks 1, 2, and 3. Subtask 1 included the survey and tabulation of available reservoir engineering and geological data relevant to the Smackover reservoir in southwestern Alabama. Subtask 2 comprises the geological and engineering characterization of Smackover reservoir lithofacies. This has been accomplished through detailed examination and analysis of geophysical well logs, core material, well cuttings, and well-test data from wells penetrating Smackover reservoirs in southwestern Alabama. From these data, reservoir heterogeneities, such as lateral and vertical changes in lithology, porosity, permeability, and diagenetic overprint, have been recognized and used to produce maps, cross sections, graphs, and other graphic representations to aid in interpretation of the geologic parameters that affect these reservoirs. Subtask 3 includes the geologic modeling of reservoir heterogeneities for Smackover reservoirs. This research has been based primarily on the evaluation of key geologic and engineering data from selected Smackover fields. 1 fig.

Mancini, E.A.

1990-01-01T23:59:59.000Z

183

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

184

Activated carbon system cuts foaming and amine losses  

SciTech Connect (OSTI)

Alkanolamines have been successfully used to treat sour gas for removal of H/sub 2/S and CO/sub 2/ for over 30 years. More recently, alkanolamines have also been used to purify flue gas, liquid hydrocarbon streams and process gas streams. Acid gas must be scrubbed because of the lack of heating value of CO/sub 2/, the toxicity of H/sub 2/S and the corrosiveness of CO/sub 2/ and H/sub 2/S in wet gas. During the scrubbing process, other compounds which form degradation products are absorbed by the amine; these degradation products cause fouling of the amine, corrosion and foaming. Southwestern Refining Co., Inc., in Corpus Christi, Texas, installed a diethanolamine (DEA) treatment system to purify sour gas and liquid hydrocarbon streams in 1975. The amine unit was not used until May, 1982, however, because the sulfur content of the gas stream was low until then.

Keaton, M.M.; Bourke, M.J.

1983-08-01T23:59:59.000Z

185

Response to “Comment on ‘Experimental observation of carbon dioxide reduction in exhaust gas from hydrocarbon fuel burning’ ” [Phys. Plasmas17, 014701 (2010)  

Science Journals Connector (OSTI)

A high-voltage cathode initiates an electron emission resulting in a reduction in the carbon dioxide concentration in exhaust gas from the burning of hydrocarbon fuel. Assuming that the observed carbon dioxide reduction is originated from the molecular decomposition the energy needed for the endothermic reaction of this carbon dioxide reduction may stem primarily from the internal energy reduction in the exhaust gas in accordance of the first law of the thermodynamics. An oxygen increase due to the reduction in carbon dioxide in a discharge gas was observed in real time.

Han S. Uhm; Chul H. Kim

2010-01-01T23:59:59.000Z

186

Carbon dioxide capture process with regenerable sorbents  

DOE Patents [OSTI]

A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

Pennline, Henry W. (Bethel Park, PA); Hoffman, James S. (Library, PA)

2002-05-14T23:59:59.000Z

187

Active constraint regions for a natural gas liquefaction process Magnus G. Jacobsena  

E-Print Network [OSTI]

Active constraint regions for a natural gas liquefaction process Magnus G. Jacobsena , Sigurd little attention. this paper addresses optimal operation of a simple natural gas liquefaction process at all times. Keywords: Self-optimizing control, liquefied natural gas, LNG, PRICO, disturbances, optimal

Skogestad, Sigurd

188

Analysis and removal of assimilable organic carbon (AOC) from treated drinking water using a biological activated carbon filter system  

Science Journals Connector (OSTI)

Abstract This study is focused on reducing the concentration of assimilable organic carbon (AOC) in treated drinking water. Experiments were conducted to evaluate the efficiency of AOC removal by biological activated carbon filters (BACF) in a pilot-scale system. The results show that BACF reduces the total concentration of AOC. The concentration of AOC primarily indicates microorganism growth in a water supply network, and the amount of AOC in water is significantly reduced after BACF treatment. The predicted and measured values of AOC in output water treated by the BACF system show linear relationships, and their correlation coefficients are high. An AOC empirical equation was established by determining the relationship between water quality parameters such as total organic carbon, dissolved organic carbon, UV254, ammonia nitrogen, and total phosphorous. These findings may be relevant to conventional water treatment plants or to water distribution systems to provide treated drinking water with a high level of biological stability.

Jie-Chung Lou; Chih-Yuan Yang; Che-Jung Chang; Wei-Hsiang Chen; Wei-Bin Tseng; Jia-Yun Han

2014-01-01T23:59:59.000Z

189

Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

An apparatus and a method are disclosed for converting hydrocarbon fuel or an alcohol into hydrogen gas and carbon dioxide. The apparatus includes a first vessel having a partial oxidation reaction zone and a separate steam reforming reaction zone that is distinct from the partial oxidation reaction zone. The first vessel has a first vessel inlet at the partial oxidation reaction zone and a first vessel outlet at the steam reforming zone. The reformer also includes a helical tube extending about the first vessel. The helical tube has a first end connected to an oxygen-containing source and a second end connected to the first vessel at the partial oxidation reaction zone. Oxygen gas from an oxygen-containing source can be directed through the helical tube to the first vessel. A second vessel having a second vessel inlet and second vessel outlet is annularly disposed about the first vessel. The helical tube is disposed between the first vessel and the second vessel and gases from the first vessel can be directed through second vessel.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H.J. (Cambridge, MA)

2000-01-01T23:59:59.000Z

190

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal-Organic Framework mmen-Mg2(dobpdc)  

E-Print Network [OSTI]

Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine- Appended Metal-Organic Framework, stationary sources like coal-fired power plants, carbon capture and sequestration (CCS) has been proposed.4 viable absorbents for carbon capture under the aforementioned conditions, and they are presently used

191

Metal-modified and vertically aligned carbon nanotube sensors array for landfill gas  

Science Journals Connector (OSTI)

Vertically aligned carbon nanotube (CNT) layers were synthesized on Fe-coated low-cost alumina substrates using radio-frequency plasma enhanced chemical vapour deposition (RF-PECVD) technology. A miniaturized CNT-based gas sensor array was developed for monitoring landfill gas (LFG) at a temperature of 150??C. The sensor array was composed of 4 sensing elements with unmodified CNT, and CNT loaded with 5?nm nominally thick sputtered nanoclusters of platinum (Pt), ruthenium (Ru) and silver (Ag). Chemical analysis of multicomponent gas mixtures constituted of CO2, CH4, H2, NH3, CO and NO2 has been performed by the array sensor responses and pattern recognition based on principal component analysis (PCA). The PCA results demonstrate that the metal-decorated and vertically aligned CNT sensor array is able to discriminate the NO2 presence in the multicomponent mixture LFG. The NO2 gas detection in the mixture LFG was proved to be very sensitive, e.g.: the CNT:Ru sensor shows a relative change in the resistance of 1.50% and 0.55% for NO2 concentrations of 3.3?ppm and 330?ppb dispersed in the LFG, respectively, with a wide NO2 gas concentration range measured from 0.33 to 3.3?ppm, at the sensor temperature of 150??C. The morphology and structure of the CNT networks have been characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Raman spectroscopy. A forest-like nanostructure of vertically aligned CNT bundles in the multi-walled form appeared with a height of about 10 ?m and a single-tube diameter varying in the range of 5?35?nm. The intensity ratio of the Raman spectroscopy D-peak and G-peak indicates the presence of disorder and defects in the CNT networks. The size of the metal (Pt, Ru, Ag) nanoclusters decorating the CNT top surface varies in the range of 5?50?nm. Functional characterization based on electrical charge transfer sensing mechanisms in the metal-modified CNT-chemoresistor array demonstrates high sensitivity by providing minimal sub-ppm level detection, e.g., download up to 100?ppb NO2, at the sensor temperature of 150??C. The gas sensitivity of the CNT sensor array depends on operating temperature, showing a lower optimal temperature of maximum sensitivity for the metal-decorated CNT sensors compared to unmodified CNT sensors. Results indicate that the recovery mechanisms in the CNT chemiresistors can be altered by a rapid heating pulse from room temperature to about 110??C. A comparison of the NO2 gas sensitivity for the chemiresistors based on disorderly networked CNTs and vertically aligned CNTs is also reported. Cross-sensitivity towards relative humidity of the CNT sensors array is investigated. Finally, the sensing properties of the metal-decorated and vertically aligned CNT sensor arrays are promising to monitor gas events in the LFG for practical applications with low power consumption and moderate sensor temperature.

M Penza; R Rossi; M Alvisi; E Serra

2010-01-01T23:59:59.000Z

192

A mathematical model for countercurrent moving-bed activated carbon adsorption  

E-Print Network [OSTI]

the carbon column was divided into ten sections and the activated carbon flow rate was such that its detention time was fifty hours. Also, during this fifty hours one thousand gallons of water were treated. Thus the water volume of each section would... be one thou- sand gallons divided by ten sections or 100 gallons. One practical difficulty with the model is that an acti- vated carbon volume must be assumed, tests made, and calculations performed to determine if the effluent quality...

Anderson, Douglas Harold

1976-01-01T23:59:59.000Z

193

A dsorption of H2 S or SO2 on an activated carbon cloth modified by ammonia treatment  

E-Print Network [OSTI]

Recent studies have reported that activated carbon fibers, such as PAN-ACF [1] or Nomex-ACF [2], have for the recovery of sulfuric acid compared to granular activated carbon because the diffusion of sulfuric acid rarely been investigated to improve the performance of activated carbon fibers for the removal of SO2

Paris-Sud XI, Université de

194

S urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia and steam  

E-Print Network [OSTI]

-based activated carbon fibers (ACF) to optimize the oxidative retention of up to 5000 ppmv of SO2 in moist air suitable for the recovery of sulfuric acid at room temperature than granular activated carbon becauseS urface chemistry of a viscose-based activated carbon cloth modified by treatment with ammonia

Paris-Sud XI, Université de

195

Natural Gas_v2 (9764 - Activated, Traditional).xps  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

natural gas usage for this service address between September 2008 and April 2010. Billing Period Enter End Date for each billing period MMDDYY Amount used was: AActual...

196

Enhanced carbon monoxide utilization in methanation process  

DOE Patents [OSTI]

Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

Elek, Louis F. (Peekskill, NY); Frost, Albert C. (Congers, NY)

1984-01-01T23:59:59.000Z

197

Active microuidic mixer and gas bubble lter driven by thermal bubble micropump$  

E-Print Network [OSTI]

Active micro¯uidic mixer and gas bubble ®lter driven by thermal bubble micropump$ Jr-Hung Tsaia Abstract A micro¯uidic mixer with a gas bubble ®lter activated by a thermal bubble actuated nozzle/min. The optimal mixing result is found when the actuating frequency of thermal bubble reaches 200 Hz. Normalized

Lin, Liwei

198

Electric Pulse Discharge Activated Carbon Supercapacitors for Transportation Application  

Science Journals Connector (OSTI)

Carbon aerogels are good electrical conductors and, hence, can be used in supercapacitors. Capacitance increases as the distance between conductor decreases and the surface area of the conductor increases. Bec...

Subhadarshi Nayak; Jyoti Agrawal

2012-03-01T23:59:59.000Z

199

Energy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A. Sidheswaran a  

E-Print Network [OSTI]

carbon fiber (ACF) filters for air cleaning in HVAC systems. The parallel aims for the air cleaningEnergy efficient indoor VOC air cleaning with activated carbon fiber (ACF) filters Meera A. Velocities through the ACF media were typical of those in normal particle filter systems (w0.5 m sÃ?1

200

Gas-solid carbonation of Ca(OH)2 and CaO particles under non-isothermal and isothermal conditions by using a thermogravimetric analyzer  

E-Print Network [OSTI]

limiting the transfer of CO2. Finally, an alternative reaction mechanism is proposed for the gas in the CO2 molecule. Keywords: Gas-solid carbonation; nanosized Ca(OH)2 particles; non-isothermal; isothermal; CO2 capture. insu-00730652,version1-10Sep2012 #12;4 1. Introduction Gas-solid reactions

Boyer, Edmond

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Micro gas preconcentrator made of a film of single-walled carbon nanotubes Shuji Takada*Takashi Nakai*Theerapol Thurakitseree*  

E-Print Network [OSTI]

Micro gas preconcentrator made of a film of single-walled carbon nanotubes Shuji Takada-Jacques Delaunay*, *** and Ichiro Yamada*, *** The development of a micro gas preconcentrator is crucial for the realization of miniaturized gas chromatography (micro-GC) systems which are expected to open up new

Maruyama, Shigeo

202

Study on a gas-steam combined cycle system with CO2 capture by integrating molten carbonate fuel cell  

Science Journals Connector (OSTI)

Abstract This paper studies a gas-steam combined cycle system with CO2 capture by integrating the MCFC (molten carbonate fuel cell). With the Aspen plus software, this paper builds the model of the overall MCFC-GT hybrid system with CO2 capture and analyzes the effects of the key parameters on the performances of the overall system. The result shows that compared with the gas-steam combined cycle system without CO2 capture, the efficiency of the new system with CO2 capture does not decrease obviously and keeps the same efficiency with the original gas steam combined cycle system when the carbon capture percentage is 45%. When the carbon capture percentage reaches up to 85%, the efficiency of the new system is about 54.96%, only 0.67 percent points lower than that of the original gas-steam combined cycle system. The results show that the new system has an obvious superiority of thermal performance. However, its technical economic performance needs be improved with the technical development of MCFC and ITM (oxygen ion transfer membrane). Achievements from this paper will provide the useful reference for CO2 capture with lower energy consumption from the traditional power generation system.

Liqiang Duan; Jingnan Zhu; Long Yue; Yongping Yang

2014-01-01T23:59:59.000Z

203

Degassing Measurement Studies Carried out for Various Forms of Activated Carbon  

Science Journals Connector (OSTI)

Abstract Activated carbon with its large surface area has extraordinary adsorptive capabilities through physical adsorption. Using this property a project on development of cryoadsorption Cryopump is ongoing at Institute for Plasma Research (IPR), India. Under the project, to study the desorption characteristics of various sorbents; a DeGassing Measurement System (DGMS) was set up. The DGMS facility works under vacuum environment with additional feature of baking to higher temperatures. DGMS provides accurate and sensitive measurements of weight change, with one microgram sensitivity, for a various samples (Activated carbon granules of different mesh sizes, Activated carbon spheres, Activated carbon pellets and fabrics i.e. Non-woven and Flat Knitted) exposed to controlled environmental conditions over an extended period of time. This paper reports degassing measurement results obtained for various samples studied to show quantitative evolution of the gases during vacuum and heating.

Samiran Mukherjee; Ranjana Gangradey; Sapana Guru; Pratik Nayak; Jyoti Agrawal; V.S. Tripathi

2014-01-01T23:59:59.000Z

204

Adsorption capacity of hydrophobic SiO2 aerogel/activated carbon composite materials for TNT  

Science Journals Connector (OSTI)

The adsorption properties of TNT from wastewater by hydrophobic silica aerogel/activated carbon composite materials were investigated. The effects of adsorption time, pH value, adsorption temperature, and the ...

XiaoFang Zhou; Sheng Cui; Yu Liu; XueYong Liu…

2013-07-01T23:59:59.000Z

205

Optimizing Cr(VI) adsorption on activated carbon produced from heavy oil fly ash  

Science Journals Connector (OSTI)

In order to explore the beneficial utilization of heavy oil fly ash (HOFA) generated in the power plants, the present study is intended to optimize the chromium(VI) [Cr(VI)] adsorption on activated carbon prod...

Abdullah Mofarrah; Tahir Husain; Bing Chen

2014-07-01T23:59:59.000Z

206

E-Print Network 3.0 - activities carbonic anhydrase Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inc. All rights reserved. PII S1095-6433(97)00439-X Summary: .C.; Ruzicka, C.A.; Sly, W.S. Pul-carbonic anhydrase activity. J. Appl. Physiol. 55:75-83; 1983. monary... H: A...

207

Modeling Polychlorinated Biphenyl Mass Transfer after Amendment of Contaminated Sediment with Activated Carbon  

Science Journals Connector (OSTI)

The sorption kinetics and concentration of polychlorinated biphenyls (PCBs) in historically polluted sediment is modeled to assess a remediation strategy based on in situ PCB sequestration by mixing with activated carbon (AC). We extend our evaluation of ...

David Werner; Upal Ghosh; Richard G. Luthy

2006-05-24T23:59:59.000Z

208

Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of  

E-Print Network [OSTI]

. These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

Borguet, Eric

209

Neutron Scattering Methodology for Absolute Measurement of Room-Temperature Hydrogen Storage Capacity and Evidence for Spillover Effect in a Pt-Doped Activated Carbon  

Science Journals Connector (OSTI)

Neutron Scattering Methodology for Absolute Measurement of Room-Temperature Hydrogen Storage Capacity and Evidence for Spillover Effect in a Pt-Doped Activated Carbon ... A neutron scattering methodology is proposed to simultaneously determine the total hydrogen adsorption, the excess hydrogen adsorption, and hydrogen gas confined in the porous sample. ... It can be combined with an in situ small-angle neutron scattering to study the hydrogen spillover effect in the kinetic adsorption process. ...

Cheng-Si Tsao; Yun Liu; Mingda Li; Yang Zhang; Juscelino B. Leao; Hua-Wen Chang; Ming-Sheng Yu; Sow-Hsin Chen

2010-04-29T23:59:59.000Z

210

Chemically modified carbonic anhydrases useful in carbon capture systems  

SciTech Connect (OSTI)

The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

Novick, Scott; Alvizo, Oscar

2013-01-15T23:59:59.000Z

211

Chemically modified carbonic anhydrases useful in carbon capture systems  

DOE Patents [OSTI]

The present disclosure relates to chemically modified carbonic anhydrase polypeptides and soluble compositions, homogenous liquid formulations comprising them. The chemically modified carbonic anhydrase polypeptides have improved properties relative to the same carbonic anhydrase polypeptide that is not chemically modified including the improved properties of increased activity and/or stability in the presence of amine compounds, ammonia, or carbonate ion. The present disclosure also provides methods of preparing the chemically modified polypeptides and methods of using the chemically modified polypeptides for accelerating the absorption of carbon dioxide from a gas stream into a solution as well as for the release of the absorbed carbon dioxide for further treatment and/or sequestering.

Novick, Scott J; Alvizo, Oscar

2013-10-29T23:59:59.000Z

212

Low Carbon Fuel Standards  

E-Print Network [OSTI]

gas, or even coal with carbon capture and sequestration. Afuels that facilitate carbon capture and sequestration. Forenergy and could capture and sequester carbon emissions.

Sperling, Dan; Yeh, Sonia

2009-01-01T23:59:59.000Z

213

Simulated coal-gas fueled carbonate fuel cell power plant system verification. Final report, September 1990--June 1995  

SciTech Connect (OSTI)

This report summarizes work performed under U.S. Department of Energy, Morgantown Energy Technology Center (DOE/METC) Contract DE-AC-90MC27168 for September 1990 through March 1995. Energy Research Corporation (ERC), with support from DOE, EPRI, and utilities, has been developing a carbonate fuel cell technology. ERC`s design is a unique direct fuel cell (DFC) which does not need an external fuel reformer. An alliance was formed with a representative group of utilities and, with their input, a commercial entry product was chosen. The first 2 MW demonstration unit was planned and construction begun at Santa Clara, CA. A conceptual design of a 10OMW-Class dual fuel power plant was developed; economics of natural gas versus coal gas use were analyzed. A facility was set up to manufacture 2 MW/yr of carbonate fuel cell stacks. A 100kW-Class subscale power plant was built and several stacks were tested. This power plant has achieved an efficiency of {approximately}50% (LHV) from pipeline natural gas to direct current electricity conversion. Over 6,000 hours of operation including 5,000 cumulative hours of stack operation were demonstrated. One stack was operated on natural gas at 130 kW, which is the highest carbonate fuel cell power produced to date, at 74% fuel utilization, with excellent performance distribution across the stack. In parallel, carbonate fuel cell performance has been improved, component materials have been proven stable with lifetimes projected to 40,000 hours. Matrix strength, electrolyte distribution, and cell decay rate have been improved. Major progress has been achieved in lowering stack cost.

NONE

1995-03-01T23:59:59.000Z

214

Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes for air-cathode microbial fuel cells{  

E-Print Network [OSTI]

Development and evaluation of carbon and binder loading in low-cost activated carbon cathodes materials in order to optimize and extend the lifetime of AC cathodes in MFCs. 1. Introduction A microbial, with the cathode typically limiting power production.5,6 Catalysts can be used to reduce the activation energy

215

Technology Solutions for Mitigating Environmental Impacts of Oil and Gas E&P Activity  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technology Solutions for Mitigating Technology Solutions for Mitigating Environmental Impacts of Oil and Gas E&P Activity The mission of the Environmental Program is to promote a reliable, affordable, and secure supply of domestic oil and clean-burning natural gas, by providing cost-effective environmental regulatory compliance technologies, enhancing environmental protections during oil and gas E&P operations, and facilitating the development and use of scientific, risk-based environmental regulatory frameworks.

216

Gas dynamic effects on formation of carbon dimers in laser-produced plasmas  

E-Print Network [OSTI]

production, carbon laser-produced plasma (LPP) research was a main focus over the last several years.1

Harilal, S. S.

217

Experimental study of active magnetic bearing on a 150M3 turbo oxygen gas expander  

Science Journals Connector (OSTI)

This paper is concerned with the investigation, experiment and design analyses on the application of active magnetic bearings for a 150M3 turbo oxygen gas expander having 1.16 kg weight and 30...

Wang Xiping Ph. D; Zhang Zhiming; Yu Liang…

1998-12-01T23:59:59.000Z

218

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks  

SciTech Connect (OSTI)

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant progress toward the current DOE post-combustion research targets, as defined in a recent FOA issued by NETL: 90% CO{sub 2} removal with no more than a 35% increase in COE. The team discovered that favorable CO{sub 2} adsorption at more realistic flue gas conditions is dominated by one particular MOF structure type, M/DOBDC, where M designates Zn, Co, Ni, or Mg and DOBDC refers to the form of the organic linker in the resultant MOF structure, dioxybenzenedicarboxylate. The structure of the M/DOBDC MOFs consists of infinite-rod secondary building units bound by DOBDC resulting in 1D hexagonal pores about 11 angstroms in diameter. Surface areas range from 800 to 1500 sq m/g for the different MOFs. Mg/DOBDC outperformed all MOF and zeolite materials evaluated to date, with about 25 wt% CO{sub 2} captured by this MOF at flue gas conditions ({approx}0.13 atm CO{sub 2} pressure, 311K). In simulated flue gas without oxygen, the zero-length (ZLC) system was very useful in quickly simulating the effect of long term exposure to impurities on the MOFs. Detailed adsorption studies on MOF pellets have shown that water does not inhibit CO{sub 2} adsorption for MOFs as much as it does for typical zeolites. Moreover, some MOFs retain a substantial CO{sub 2} capacity even with a modest water loading at room temperature. Molecular modeling was a key activity in three areas of our earlier DOE/NETL-sponsored MOF-based research on CC. First, the team was able to effectively simulate CO{sub 2} and other gas adsorption isotherms for more than 20 MOFs, and the knowledge obtained was used to help predict new MOF structures that should be effective for CO{sub 2} adsorption at low pressure. The team also showed that molecular modeling could be utilized to predict the hydrothermal stability of a given MOF. Finally, the team showed that low moisture level exposure actually enhanced the CO{sub 2} adsorption performance of a particular MOF, HKUST-1.

David A Lesch

2010-06-30T23:59:59.000Z

219

Tracing coalbed natural gas-coproduced water using stable isotopes of carbon  

SciTech Connect (OSTI)

Recovery of hydrocarbons commonly is associated with coproduction of water. This water may be put to beneficial use or may be reinjected into subsurface aquifers. In either case, it would be helpful to establish a fingerprint for that coproduced water so that it may be tracked following discharge on the surface or reintroduction to geologic reservoirs. This study explores the potential of using {delta}{sup 13}C of dissolved inorganic carbon (DIC) of coalbed natural gas (CBNG) - coproduced water as a fingerprint of its origin and to trace its fate once it is disposed on the surface. Our initial results for water samples coproduced with CBNG from the Powder River Basin show that this water has strongly positive {delta}{sup 13}C(DIC) (12 parts per thousand to 22 parts per thousand) that is readily distinguished from the negative {delta}{sup 13}C of most surface and ground water (-8 parts per thousand to -11 parts per thousand). Furthermore, the DIC concentrations in coproduced water samples are also high (more than 100 mg C/L) compared to the 20 to 50 mg C/L in ambient surface and ground water of the region. The distinctively high {delta}{sup 13}C and DIC concentrations allow us to identify surface and ground water that have incorporated CBNG-coproduced water. Accordingly, we suggest that the {delta}{sup 13}C(DIC) and DIC concentrations of water can be used for long-term monitoring of infiltration of CBNG-coproduced water into ground water and streams. Our results also show that the {delta} {sup 13}C (DIC) of CBNG-coproduced water from two different coal zones are distinct leading to the possibility of using {delta}{sup 13}C(DIC) to distinguish water produced from different coal zones.

Sharma, S.; Frost, C.D. [University of Wyoming, Laramie, WY (United States). Dept. for Renewable Resources

2008-03-15T23:59:59.000Z

220

Ni(NiO)/single-walled carbon nanotubes composite: Synthesis of electro-deposition, gas sensing property for NO gas and density functional theory calculation  

SciTech Connect (OSTI)

Graphical abstract: The Ni(NiO)/semiconducting single-walled carbon nanotubes composite collected from the cathode after electro-deposition shows a high sensitivity to low-concentration NO gas at room temperature (18 °C). Display Omitted Highlights: ? Ni(NiO) nanoparticles were deposited on semiconducting SWCNTs by electro-deposition. ? Ni(NiO)/semiconducting SWCNTs film shows a high sensitivity to NO gas at 18 °C. ?Theoretical calculation reveals electron transfer from SWCNTs to NO via Ni. -- Abstract: Single-walled carbon nanotubes which contains metallic SWCNTs (m-SWCNTs) and semiconducting SWCNTs (s-SWCNTs) have been obtained under electric arc discharge. Their separation can be effectively achieved by the electro-deposition method. The Ni(NiO)/s-SWCNTs composite was found on cathode where Ni was partially oxidized to NiO at ambient condition with Ni(NiO) nanoparticles deposited uniformly on the bundles of SWCNTs. These results were confirmed by Raman spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV–vis–NIR and TG characterizations. Furthermore, investigation of the gas sensing property of Ni(NiO)/s-SWCNTs composite film to NO gas at 18 °C demonstrated the sensitivity was approximately 5% at the concentration of 97 ppb. Moreover, density functional theory (DFT) calculations were performed to explore the sensing mechanism which suggested the adsorption of NO molecules onto the composite through N–Ni interaction as well as the proposition of electron transfer mechanisms from SWCNTs to NO via the Ni medium.

Li, Li; Zhang, Guo; Chen, Lei [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Chemical Engineering Process and Technology for High-efficiency Conversion, College of Heilongjiang Province, Heilongjiang University, Harbin 150080 (China); Bi, Hong-Mei [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China); Shi, Ke-Ying, E-mail: shikeying2008@yahoo.cn [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)] [Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080 (China)

2013-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

PERGAMON Carbon 38 (2000) 17571765 High temperature hydrogen sulfide adsorption on activated  

E-Print Network [OSTI]

directly, as in a traditional H , 23.1% CO, 5.8% CO , 6.6% H O, 0.5% H S, and2 2 2 2 coal-fired power plant types of activated carbon sorbents were evaluated for their ability to remove H S from a simulated coal temperature was examined as a2 function of carbon surface chemistry (oxidation, thermal desorption, and metal

Cal, Mark P.

222

Structural insight into activity enhancement and inhibition of H64A carbonic anhydrase II by imidazoles  

Science Journals Connector (OSTI)

Human carbonic anhydrases are zinc metalloenzymes that catalyze the hydration and dehydration of CO2 and HCO3-, respectively. X-ray crystal structures of a variant of human carbonic anhydrase II in complex with four imidazole derivatives (imidazole, 1-methylimidazole, 2-methylimidazole and 4-methylimidazole) have been determined in order to identify the binding sites for such compounds, and a mechanism to explain the effects on catalytic activity is proposed.

Aggarwal, M.

2014-02-28T23:59:59.000Z

223

Synthesis, adsorption and regeneration of nanoporous silica aerogel and silica aerogel-activated carbon composites  

Science Journals Connector (OSTI)

Abstract Usage of aerogels as an adsorbent has become more widespread because of its specifications such as high porosity and specific surface. Nanometer silica aerogel and silica aerogel-activated carbon composites were synthesized using a water glass precursor by ambient pressure drying method. Then, the adsorption capacity of synthesized adsorbents was studied in terms of benzene and ethyl benzene adsorption by chromatography method for continuous and batch testing. Results showed that silica aerogel and silica aerogel-activated carbon composites had high tendency for benzene and ethyl benzene adsorption. Silica aerogel showed maximum adsorption capacity of 2.3 g g?1 and 0.7 g g?1 in static adsorption of benzene and ethyl benzene respectively. Also, in dynamic adsorption of benzene and ethyl benzene, silica aerogel had maximum equilibrium adsorption capacity of 0.954 g g?1 and 0.219 g g?1 respectively. Minimum equilibrium adsorption capacity in benzene and ethyl benzene static adsorption was related to activated carbon with 0.7 g g?1 and silica aerogel–2 wt% activated carbon with 0.25 g g?1 respectively. After adsorption process, silica aerogel and silica aerogel–0.5 wt% activated carbon composite were regenerated by solvent extraction–thermal treatment method and, after at least 15 adsorption/desorption cycles, their adsorption capacity became fixed.

Akbar Mohammadi; Jafarsadegh Moghaddas

2014-01-01T23:59:59.000Z

224

Inorganic Carbon Turnover caused by Digestion of Carbonate Sands and Metabolic Activity of Holothurians  

SciTech Connect (OSTI)

Recent measurements have shown that holothurians (sea cucumbers) play an important role in the cycling of CaCO3 in tropical coral reef systems through ingestion and processing of carbonate sediment. In this study inorganic additional aspects of carbon turnover were determined in laboratory incubations of Holothuria atra, H. leucospilota and Stichopus herrmanni from One Tree Reef, Great Barrier Reef. The pH values of the gut lumen ranged from 6.1 to 6.7 in animals with empty digestive tracts as opposed to 7.0 to 7.6 when digestive tracts were filled with sediment. Empty gut volume estimates for H. atra and S. herrmanni were 36 ± 4 mL and 151 ± 14 mL, respectively. Based on these measurements it is estimated that these species process 19 ± 2kg and 80 ± 7kg CaCO3 sand yr-1 per individual, respectively. The annual dissolution rates of H. atra and S. herrmanni of 6.5±1.9g and 9.6±1.4g, respectively, suggest that 0.05±0.02% and 0.1±0.02% of the CaCO3 processed through their gut annually is dissolved. During the incubations the CaCO3 dissolution was 0.07±0.01%, 0.04±0.01% and 0.21±0.05% of the fecal casts for H. atra, H. leucospilota and S. herrmanni, respectively. The CaCO3 saturation state for both aragonite and calcite minerals during laboratory incubations decreased markedly due to a greater increase in dissolved inorganic carbon (DIC) relative to total alkalinity (AT) as a result of respiration by the animals. Our results support the hypothesis that deposit feeders such as sea cucumbers play an important ecological role in the coral reef CaCO3 cycle.

Schneider, Kenneth; Silverman, Jacob; Kravitz, Benjamin S.; Rivlin, Tanya; Schneider-Mor, Aya; Barbosa, Sergio; Byrne, Maria; Caldeira, Ken

2013-11-20T23:59:59.000Z

225

Modelling and development of carbon molecular sieve membrane for gas separation.  

E-Print Network [OSTI]

??The objective of the research project was to investigate the feasibility of preparing carbon molecular sieve membranes from Kapton® polyimide film. The effects of carbonisation… (more)

Su, Jincai.

2008-01-01T23:59:59.000Z

226

Preparation of Activated Carbon and Silica Particles from Rice Straw  

Science Journals Connector (OSTI)

Lignocellulosic biomass, such as agricultural crop residues, forestry byproducts, and municipal waste, is a rich source of renewable energy and materials. ... The LH powders were dried in oven at 60 °C for 12 h, placed in a quartz tube (2 cm inner diameter), and then dried in a furnace (Mini-Mite, Lindberg/Blue) at 10 °C/min to 105 °C and held for 0.5 h. ... TEM samples were prepared by dispersing a small amount of AC and silica particles in water (?0.01 g/L) and sonicated (2510, Branson) for 60 min first, and then a drop of the sonicated suspension was placed onto a carbon grid and dried in air. ...

Sixiao Hu; You-Lo Hsieh

2014-02-21T23:59:59.000Z

227

Selective adsorption of tert-butylmercaptan and tetrahydrothiophene on modified activated carbons for fuel processing in fuel cell applications  

Science Journals Connector (OSTI)

Abstract The effects of surface oxidation and KOH impregnation on activated carbon for the selective adsorption of tert-butylmercaptan (TBM) and tetrahydrothiophene (THT) present in natural fuel gas were studied. Physicochemical properties of the adsorbents were characterized by N2 adsorption, X-ray diffraction (XRD), temperature programmed desorption (TPD), scanning electron microscopy (SEM), and surface pH measurements. Oxidation treatments by HNO3 or H2O2 gave rise to considerable increases in both TBM and THT adsorption capacity, about a threefold enhancement from those on pristine activated carbon. Notably, it was found that the oxidative modifications led to an enhancement in THT adsorption selectivity, whereas KOH impregnation led to a marked increase in TBM adsorption selectivity. The properties of the adsorption sites and the adsorption strength of TBM and THT on the sites were characterized. These results agree well with the experimental sulfur adsorption capacities of the samples and can be explained by an adsorption model proposed in this work.

Phuoc Hoang Ho; So-Yun Lee; Doohwan Lee; Hee-Chul Woo

2014-01-01T23:59:59.000Z

228

Adsorption and decomposition of triclosan by activated carbons, manganese oxides, and their composite materials from aqueous solution.  

E-Print Network [OSTI]

??This research investigates the use of activated carbon (AC) and manganese oxides as adsorbents and oxidizing agents to adsorb and oxidize triclosan, a compound which… (more)

Fang, Sheng

2010-01-01T23:59:59.000Z

229

Fluid Inclusion Gas Compositions From An Active Magmatic-Hydrothermal...  

Open Energy Info (EERE)

and the active vapor-dominated geothermal system at The Geysers, CA are related to a composite hypabyssal granitic pluton emplaced beneath the field 1.1 to 1.2 million years ago....

230

Carbon credits earned from a double slope active solar still under forced circulation mode  

Science Journals Connector (OSTI)

Human life on land is vitally dependent on fresh water along with food and air. Many areas in the world do not have access to fresh water. Growing demands of freshwater resources are creating an urgent need to develop self sustained system to meet the demand. At present, many distillation methods are available like reverse osmosis, thin film distillation multi-effect fresh evaporation but they are energy intensive or contribute to environmental degradation. Distillation is one technique used for treating available brackish water into fresh water. However, solar energy can be used as an alternative source of energy for water distillation. In this paper, carbon dioxide emission, mitigation and carbon credit earned from a double slope active solar still under forced circulation mode has been carried out. It has been observed that carbon dioxide emission and carbon credit earned over the life time of 15 years are 2.55 tons and ?220 respectively.

A.K. Sethi; Vijay Kumar Dwivedi

2014-01-01T23:59:59.000Z

231

NiFe2O4/activated carbon nanocomposite as magnetic material from petcoke  

Science Journals Connector (OSTI)

Abstract Nickel ferrite (NiFe2O4) was supported on activated carbon (AC) from petroleum coke (petcoke). Potassium hydroxide (KOH) was employed with petcoke to produce activated carbon. NiFe2O4 were synthesized using PEG-Oleic acid assisted hydrothermal method. The structural and magnetic properties were determined using thermogravimetric and differential thermal analysis (TGA–DTA), X-ray diffraction (XRD), Fourier Transform Infrared (IR-FT), surface area (BET), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and vibrating sample magnetometry (VSM). XRD analysis revealed the cubic spinel structure and ferrite phase with high crystallinity. IR-FT studies showed that chemical modification promoted the formation of surface oxygen functionalities. Morphological investigation by SEM showed conglomerates of spherical nanoparticles with an average particle size of 72 nm and TEM showed the formation of NiFe2O4/carbon nanofibers. Chemical modification and activation temperature of 800 °C prior to activation dramatically increased the BET surface area of the resulting activated carbon to 842.4 m2/g while the sulfur content was reduced from 6 to 1%. Magnetic properties of nanoparticles show strong dependence on the particle size.

Sarah Briceño; W. Brämer-Escamilla; P. Silva; J. García; H. Del Castillo; M. Villarroel; J.P. Rodriguez; M.A. Ramos; R. Morales; Y. Diaz

2014-01-01T23:59:59.000Z

232

Electrochemical formation of hydroxide for enhancing carbon dioxide and acid gas uptake by a solution  

DOE Patents [OSTI]

A system for forming metal hydroxide from a metal carbonate utilizes a water electrolysis cell having an acid-producing anode and a hydroxyl-producing cathode immersed in a water solution of sufficient ionic content to allow an electric current to pass between the hydroxyl-producing cathode and the acid-producing anode. A metal carbonate is placed in close proximity to the acid-producing anode. A direct current electrical voltage is provided across the acid-producing anode and the hydroxyl-producing cathode sufficient to generate acid at the acid-producing anode and hydroxyl ions at the hydroxyl-producing cathode. The acid dissolves at least part of the metal carbonate into metal and carbonate ions allowing the metal ions to travel toward the hydroxyl-producing cathode and to combine with the hydroxyl ions to form the metal hydroxide. The carbonate ions travel toward the acid-producing anode and form carbonic acid and/or water and carbon dioxide.

Rau, Gregory Hudson

2014-07-01T23:59:59.000Z

233

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-01-28T23:59:59.000Z

234

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-04-26T23:59:59.000Z

235

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-07-29T23:59:59.000Z

236

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-01-01T23:59:59.000Z

237

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2003-10-29T23:59:59.000Z

238

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 percent (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-04-01T23:59:59.000Z

239

Gas speciation, and [sup 13]C and [sup 18]O content of gases produced by laser sampling of carbonate  

SciTech Connect (OSTI)

To determine the concentration of gaseous carbon- and oxygen-bearing species produced by laser ablation, an Ion Trap mass spectrometer (ITD) was added to a standard Nd-YAG laser microprobe system. Ultra-pure He carrier gas, flowing through a stainless steel flanged reaction chamber, sweeps laser-generated gases from the chamber during ablation. The gas is split prior to introduction in the ITD, allowing a small percentage of the effluent to enter the ITD while the majority is passed through two liquid nitrogen cold traps for collection of CO[sub 2] for standard stable isotope ratio analysis. Gas speciation is determined from multiple mass/charge spectral scans of the gas using the ITD. When lasing is performed at 30A in cw mode, the delta C-13 of laser-generated CO[sub 2] co-varies positively as a function of the CO[sub 2]/(CO+CO[sub 2]) ratio with values increasingly by 2% from 35 to 90% CO[sub 2]. As a general rule, the delta C-13 of CO[sub 2] is closest to that of the carbonate when CO[sub 2] ratios and yields are small. The delta O-18 of CO[sub 2] remains nearly constant throughout the range of CO[sub 2] ratios or yields investigated. When lasing is performed at 35A in Q-switch mode (5kHZ), the delta C-13 of CO[sub 2] decreases by 4% as the CO[sub 2] ratio increases from 40 to 60%. The delta C-13 of laser-generated CO[sub 2] approaches that of the carbonate as CO[sub 2] ratio increases and yield decreases. The delta O-18 of CO[sub 2] remains nearly constant throughout the range of CO[sub 2] ratios or yields investigated despite the fact that O[sub 2] comprises 10 to 21% of the laser-generated gas.

Romanek, C.S.; Gibson, E.K. Jr. (Planetary Science Branch/SN2, Houston, TX (United States)); Socki, R.A. (NASA/Johnson Space Center, Houston, TX (United States))

1992-01-01T23:59:59.000Z

240

Oxygen Reduction Activity of PtxNi1-x Alloy Nanoparticles on Multiwall Carbon Nanotubes  

E-Print Network [OSTI]

PtxNi1 - x nanoparticles (Pt:Ni; 1:0, 4:1, 3:1 and 0.7:1) of ~5 nm, were synthesized on carboxylic acid-functionalized multiwall carbon nanotubes (PtxNi1 - x NPs/MWNT). The oxygen reduction reaction (ORR) activity measurements ...

Kim, Junhyung

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241

Chapter Nine - Carbon Capture with Simultaneous Activation and Its Subsequent Transformation  

Science Journals Connector (OSTI)

Abstract Carbon capture and storage/sequestration (CCS) is now being considered as a potential option to mitigate global warming associated with carbon accumulation. The chemical absorption technique employing efficient amino-containing absorbents has been widely developed. Nevertheless, extensive energy consumption in desorption–compression process would be a crucial barrier to realize practical CCS. On the other hand, CO2 is very attractive as a typical renewable feedstock for manufacturing commodity chemicals and fuels. However, the reactions involving CO2 are commonly carried out at high pressure, which may not be economically suitable and also pose safety concerns. Consequently, we have proposed a carbon capture and utilization (CCU) strategy as an alternative approach to addressing energy issue in CCS. This crucial point of CCU could be simultaneous activation of CO2 upon its capture (e.g., formation of carbamate/alkyl carbonate) and thus in situ catalytic transformation into value-added chemicals under mild conditions, avoiding additional desorption step. This chapter is intended to discuss carbon capture and in situ transformation of CO2 to oxazolidinones, carbonates, quinazolines, urea derivatives, isocyanates, and carbamates via the formation of CO and CN bond.

Yu-Nong Li; Liang-Nian He; Zhen-Feng Diao; Zhen-Zhen Yang

2014-01-01T23:59:59.000Z

242

EOS7C Version 1.0: TOUGH2 Module for Carbon Dioxide or Nitrogen inNatural Gas (Methane) Reservoirs  

SciTech Connect (OSTI)

EOS7C is a TOUGH2 module for multicomponent gas mixtures in the systems methane carbon dioxide (CH4-CO2) or methane-nitrogen (CH4-N2) with or without an aqueous phase and H2O vapor. EOS7C uses a cubic equation of state and an accurate solubility formulation along with a multiphase Darcy s Law to model flow and transport of gas and aqueous phase mixtures over a wide range of pressures and temperatures appropriate to subsurface geologic carbon sequestration sites and natural gas reservoirs. EOS7C models supercritical CO2 and subcritical CO2 as a non-condensible gas, hence EOS7C does not model the transition to liquid or solid CO2 conditions. The components modeled in EOS7C are water, brine, non-condensible gas, gas tracer, methane, and optional heat. The non-condensible gas (NCG) can be selected by the user to be CO2 or N2. The real gas properties module has options for Peng-Robinson, Redlich-Kwong, or Soave-Redlich-Kwong equations of state to calculate gas mixture density, enthalpy departure, and viscosity. Partitioning of the NCG and CH4 between the aqueous and gas phases is calculated using a very accurate chemical equilibrium approach. Transport of the gaseous and dissolved components is by advection and Fickian molecular diffusion. We present instructions for use and example problems to demonstrate the accuracy and practical application of EOS7C.

Oldenburg, Curtis M.; Moridis,George J.; Spycher, Nicholas; Pruess, Karsten

2004-06-29T23:59:59.000Z

243

Electroreduction of Oxygen in Polymer Electrolyte Fuel Cells by Activated Carbon Coated Cobalt Nanocrystallites Produced by Electric Arc Discharge  

Science Journals Connector (OSTI)

Electroreduction of Oxygen in Polymer Electrolyte Fuel Cells by Activated Carbon Coated Cobalt Nanocrystallites Produced by Electric Arc Discharge ... A recent review of the encapsulation of rare earth and iron group metals (Fe, Co, Ni) using electric arc discharge has been published by Saito. ... Nanotubes have been observed after activation of catalytically inactive carbon-coated Co nanocrystallites generated by electric arc discharge. ...

G. Lalande; D. Guay; J. P. Dodelet; S. A. Majetich; M. E. McHenry

1997-03-18T23:59:59.000Z

244

Development of a dynamic simulator for a natural gas combined cycle (NGCC) power plant with post-combustion carbon capture  

SciTech Connect (OSTI)

The AVESTAR Center located at the U.S. Department of Energy’s National Energy Technology Laboratory and West Virginia University is a world-class research and training environment dedicated to using dynamic process simulation as a tool for advancing the safe, efficient and reliable operation of clean energy plants with CO{sub 2} capture. The AVESTAR Center was launched with a high-fidelity dynamic simulator for an Integrated Gasification Combined Cycle (IGCC) power plant with pre-combustion carbon capture. The IGCC dynamic simulator offers full-scope Operator Training Simulator (OTS) Human Machine Interface (HMI) graphics for realistic, real-time control room operation and is integrated with a 3D virtual Immersive Training Simulator (ITS), thus allowing joint control room and field operator training. The IGCC OTS/ITS solution combines a “gasification with CO{sub 2} capture” process simulator with a “combined cycle” power simulator into a single high-performance dynamic simulation framework. This presentation will describe progress on the development of a natural gas combined cycle (NGCC) dynamic simulator based on the syngas-fired combined cycle portion of AVESTAR’s IGCC dynamic simulator. The 574 MW gross NGCC power plant design consisting of two advanced F-class gas turbines, two heat recovery steam generators (HRSGs), and a steam turbine in a multi-shaft 2x2x1 configuration will be reviewed. Plans for integrating a post-combustion carbon capture system will also be discussed.

Liese, E.; Zitney, S.

2012-01-01T23:59:59.000Z

245

Manufacture of Carbon Materials of Aerogel Type from Carbon Blacks of Various Origins  

Science Journals Connector (OSTI)

The influence exerted by the structure and origin of samples of technical grade carbon, conditions of their thermal treatment (temperature, nature of a gas medium) and preliminary impregnation with activating ...

S. S. Stavitskaya; V. E. Goba; A. N. Tomashevskaya…

246

Modeling and Measuring Greenhouse Gas Reduction from Low Carbon Airport Access Modes  

E-Print Network [OSTI]

domestic  greenhouse gas (GHG) emissions in 2003.  Within proportion of aviation system GHG emissions; due to their for aviation  system GHG reduction.  Discrete choice models 

Smirti, Megan

2008-01-01T23:59:59.000Z

247

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-02-10T23:59:59.000Z

248

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-04-28T23:59:59.000Z

249

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

Brandon C. Nuttall

2003-02-11T23:59:59.000Z

250

Recoil carbon-11 atom reactions with 1,3-butadiene in the gas phase  

E-Print Network [OSTI]

. . 2. Reactions of Recoil Carbon-11 Atoms with 1, 3- Butadiene as a Function of Pressure. 3. Reactions of Recoil Carbon-11 Atoms with 1, 3- Butadiene as a Function of Oxygen. 4. The Addition of Silane (SiH4) to the 1, 3-8utadiene System. CHAPTER.... III-13 Ratio as a Function of 02. Plot of the Yield of C-labeled Vinyl Aliene as a 11 Function of 02. Plot of the Yield of C-labeled Vinyl Cyclopropane 11 as a Function of 02 Variation in the C-labeled Product Spectra with 11 Increasing Silane...

Baltuskonis, Dennis Alan Anthony

2012-06-07T23:59:59.000Z

251

Carbon Sequestration  

Science Journals Connector (OSTI)

Carbon sequestration” refers to a portfolio of activities for ... capture, separation and storage or reuse of carbon or CO2. Carbon sequestration technologies encompass both the prevention of CO2 emissions into ...

Robert L. Kane MS; Daniel E. Klein MBA

2005-01-01T23:59:59.000Z

252

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2003-07-28T23:59:59.000Z

253

Active hurricane season expected to shut-in higher amount of oil and natural gas production  

U.S. Energy Information Administration (EIA) Indexed Site

Active hurricane season expected to shut-in higher amount of Active hurricane season expected to shut-in higher amount of oil and natural gas production An above-normal 2013 hurricane season is expected to cause a median production loss of about 19 million barrels of U.S. crude oil and 46 billion cubic feet of natural gas production in the Gulf of Mexico, according to the new forecast from the U.S. Energy Information Administration. That's about one-third more than the amount of oil and gas production knocked offline during last year's hurricane season. Government weather forecasts predict 13 to 20 named storms will form between June and the end of November, with 7 to 11 of those turning into hurricanes. Production outages in previous hurricane seasons were as high as 107 million barrels of crude oil

254

Solute-Solvent Interactions From Gas Chromatographic Activity Coefficients and the Solvation Parameter Model for Nitrogen-Containing Stationary Phases  

Science Journals Connector (OSTI)

......analyte injected into a gas chromatographic...Interactions From Gas Chromatographic Activity...Parameter Model for Nitrogen-Containing Stationary...mol), R is the gas con- stant (taken...pressure of saturated water vapor at ambient...the Ost- wald solubility coefficient (or......

José M. Santiuste

2003-04-01T23:59:59.000Z

255

Carbon dioxide absorber and regeneration assemblies useful for power plant flue gas  

DOE Patents [OSTI]

Disclosed are apparatus and method to treat large amounts of flue gas from a pulverized coal combustion power plant. The flue gas is contacted with solid sorbents to selectively absorb CO.sub.2, which is then released as a nearly pure CO.sub.2 gas stream upon regeneration at higher temperature. The method is capable of handling the necessary sorbent circulation rates of tens of millions of lbs/hr to separate CO.sub.2 from a power plant's flue gas stream. Because pressurizing large amounts of flue gas is cost prohibitive, the method of this invention minimizes the overall pressure drop in the absorption section to less than 25 inches of water column. The internal circulation of sorbent within the absorber assembly in the proposed method not only minimizes temperature increases in the absorber to less than 25.degree. F., but also increases the CO.sub.2 concentration in the sorbent to near saturation levels. Saturating the sorbent with CO.sub.2 in the absorber section minimizes the heat energy needed for sorbent regeneration. The commercial embodiments of the proposed method can be optimized for sorbents with slower or faster absorption kinetics, low or high heat release rates, low or high saturation capacities and slower or faster regeneration kinetics.

Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

2012-11-06T23:59:59.000Z

256

Atlantic update, July 1986--June 1990: Outer Continental Shelf oil and gas activities  

SciTech Connect (OSTI)

This report describes outer continental shelf oil and gas activities in the Atlantic Region. This edition of the Atlantic Update includes an overview of the Mid-Atlantic Planning Area and a summary of the Manteo Prospect off-shore North Carolina. 6 figs., 8 tabs.

Karpas, R.M.; Gould, G.J.

1990-10-01T23:59:59.000Z

257

The Cost of Carbon Capture and Storage for Natural Gas Combined Cycle Power Plants  

Science Journals Connector (OSTI)

Historically, natural gas has been used to provide peak-load power at a relatively high cost per kilowatt-hour during the daytime intervals when electricity demands peak and cannot be supplied wholly by baseload generators. ... (1) This share is projected to grow to 47% by 2035, with natural gas accounting for 60% of new generating capacity additions between 2010 and 2035 in the Department of Energy’s reference case scenario. ... To answer this question we use the LCOE results above to generate a probabilistic difference in cost, recognizing that some parameters should have the same value for plants with and without CCS, such as the power block capital cost, natural gas price, and the plant labor rate. ...

Edward S. Rubin; Haibo Zhai

2012-02-14T23:59:59.000Z

258

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents [OSTI]

A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-03-27T23:59:59.000Z

259

Application of Crunch-Flow Routines to Constrain Present and Past Carbon Fluxes at Gas-Hydrate Bearing Sites  

SciTech Connect (OSTI)

In November 2012, Oregon State University initiated the project entitled: Application of Crunch-Flow routines to constrain present and past carbon fluxes at gas-hydrate bearing sites. Within this project we developed Crunch-Flow based modeling modules that include important biogeochemical processes that need to be considered in gas hydrate environments. Our modules were applied to quantify carbon cycling in present and past systems, using data collected during several DOE-supported drilling expeditions, which include the Cascadia margin in US, Ulleung Basin in South Korea, and several sites drilled offshore India on the Bay of Bengal and Andaman Sea. Specifically, we completed modeling efforts that: 1) Reproduce the compositional and isotopic profiles observed at the eight drilled sites in the Ulleung Basin that constrain and contrast the carbon cycling pathways at chimney (high methane flux) and non-chimney sites (low methane, advective systems); 2) Simulate the Ba record in the sediments to quantify the past dynamics of methane flux in the southern Hydrate Ridge, Cascadia margin; and 3) Provide quantitative estimates of the thickness of individual mass transport deposits (MTDs), time elapsed after the MTD event, rate of sulfate reduction in the MTD, and time required to reach a new steady state at several sites drilled in the Krishna-Godavari (K-G) Basin off India. In addition we developed a hybrid model scheme by coupling a home-made MATLAB code with CrunchFlow to address the methane transport and chloride enrichment at the Ulleung Basins chimney sites, and contributed the modeling component to a study focusing on pore-scale controls on gas hydrate distribution in sediments from the Andaman Sea. These efforts resulted in two manuscripts currently under review, and contributed the modeling component of another pare, also under review. Lessons learned from these efforts are the basis of a mini-workshop to be held at Oregon State University (Feb 2014) to instruct graduate students (OSU and UW) as well as DOE staff from the NETL lab in Albany on the use of Crunch Flow for geochemical applications.

Torres, Marta

2014-01-31T23:59:59.000Z

260

Carbon and Hydrogen Analyses of the Components of a Mixture Utilizing Separation-Combustion Gas Chromatography  

Science Journals Connector (OSTI)

......Utilizing Separation-Combustion Gas Chromatography...temperature copper oxide combustion tube which feeds...solution of brominated hydrocarbons (1% v/v) in...was passed into a combustion tube. Following...Wisconsin) was used to heat the combustion tube...indi- cated by the data of Table II. The......

Sam N. Pennington; Harry D. Brown

1968-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Inner-shell excitation of gas phase carbonates and a,c-dicarbonyl compounds  

E-Print Network [OSTI]

correlation of the C 1s ! p� C@O transition energy and the relative oxidation at the carbonyl car- bon and dimethyldicarbonate ­ have been recorded in the gas phase with inner shell electron energy loss spectroscopy in the scattering regime dominated by electric dipole transitions. All spectra are presented on absolute oscillator

Hitchcock, Adam P.

262

A Resource Assessment Of Geothermal Energy Resources For Converting Deep Gas Wells In Carbonate Strata Into Geothermal Extraction Wells: A Permian Basin Evaluation  

SciTech Connect (OSTI)

Previously conducted preliminary investigations within the deep Delaware and Val Verde sub-basins of the Permian Basin complex documented bottom hole temperatures from oil and gas wells that reach the 120-180C temperature range, and occasionally beyond. With large abundances of subsurface brine water, and known porosity and permeability, the deep carbonate strata of the region possess a good potential for future geothermal power development. This work was designed as a 3-year project to investigate a new, undeveloped geographic region for establishing geothermal energy production focused on electric power generation. Identifying optimum geologic and geographic sites for converting depleted deep gas wells and fields within a carbonate environment into geothermal energy extraction wells was part of the project goals. The importance of this work was to affect the three factors limiting the expansion of geothermal development: distribution, field size and accompanying resource availability, and cost. Historically, power production from geothermal energy has been relegated to shallow heat plumes near active volcanic or geyser activity, or in areas where volcanic rocks still retain heat from their formation. Thus geothermal development is spatially variable and site specific. Additionally, existing geothermal fields are only a few 10’s of square km in size, controlled by the extent of the heat plume and the availability of water for heat movement. This plume radiates heat both vertically as well as laterally into the enclosing country rock. Heat withdrawal at too rapid a rate eventually results in a decrease in electrical power generation as the thermal energy is “mined”. The depletion rate of subsurface heat directly controls the lifetime of geothermal energy production. Finally, the cost of developing deep (greater than 4 km) reservoirs of geothermal energy is perceived as being too costly to justify corporate investment. Thus further development opportunities for geothermal resources have been hindered. To increase the effective regional implementation of geothermal resources as an energy source for power production requires meeting several objectives. These include: 1) Expand (oil and gas as well as geothermal) industry awareness of an untapped source of geothermal energy within deep permeable strata of sedimentary basins; 2) Identify and target specific geographic areas within sedimentary basins where deeper heat sources can be developed; 3) Increase future geothermal field size from 10 km2 to many 100’s km2 or greater; and 4) Increase the productive depth range for economic geothermal energy extraction below the current 4 km limit by converting deep depleted and abandoned gas wells and fields into geothermal energy extraction wells. The first year of the proposed 3-year resource assessment covered an eight county region within the Delaware and Val Verde Basins of West Texas. This project has developed databases in Excel spreadsheet form that list over 8,000 temperature-depth recordings. These recordings come from header information listed on electric well logs recordings from various shallow to deep wells that were drilled for oil and gas exploration and production. The temperature-depth data is uncorrected and thus provides the lower temperature that is be expected to be encountered within the formation associated with the temperature-depth recording. Numerous graphs were developed from the data, all of which suggest that a log-normal solution for the thermal gradient is more descriptive of the data than a linear solution. A discussion of these plots and equations are presented within the narrative. Data was acquired that enable the determination of brine salinity versus brine density with the Permian Basin. A discussion on possible limestone and dolostone thermal conductivity parameters is presented with the purpose of assisting in determining heat flow and reservoir heat content for energy extraction. Subsurface maps of temperature either at a constant depth or within a target geothermal reservoir are discusse

Erdlac, Richard J., Jr.

2006-10-12T23:59:59.000Z

263

Raman Spectroscopy—An Innovative and Versatile Tool To Follow the Respirational Activity and Carbonate Biomineralization of Important Cave Bacteria  

Science Journals Connector (OSTI)

Raman Spectroscopy—An Innovative and Versatile Tool To Follow the Respirational Activity and Carbonate Biomineralization of Important Cave Bacteria ... (11) Bacterial calcium carbonate formation is applied in contaminated soil and groundwater remediation,(12) the protection and repair of concrete and cement structures,(13) and the conservation of building stone and statuary. ...

Robert Keiner; Torsten Frosch; Stefan Hanf; Anna Rusznyak; Denise M. Akob; Kirsten Küsel; Jürgen Popp

2013-08-23T23:59:59.000Z

264

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.

Clawson, Lawrence G. (7 Rocky Brook Rd., Dover, MA 02030); Mitchell, William L. (111 Oakley Rd., Belmont, MA 02178); Bentley, Jeffrey M. (20 Landmark Rd., Westford, MA 01886); Thijssen, Johannes H. J. (1 Richdale Ave.#2, Cambridge, MA 02140)

2002-01-01T23:59:59.000Z

265

Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide  

DOE Patents [OSTI]

A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2001-01-01T23:59:59.000Z

266

Preparation of Activated Carbon from Oil Sands Coke by Chemical and Physical Activation Techniques.  

E-Print Network [OSTI]

??Oil sands coke is a by-product resulting from the upgrading of heavy crude bitumen to light synthetic oil. This research investigates the preparation of activated… (more)

Morshed, Golam

2012-01-01T23:59:59.000Z

267

Method And Apparatus For Converting Hydrocarbon Fuel Into Hydrogen Gas And Carbon Dioxide  

DOE Patents [OSTI]

A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.

Clawson, Lawrence G. (Dover, MA); Mitchell, William L. (Belmont, MA); Bentley, Jeffrey M. (Westford, MA); Thijssen, Johannes H. J. (Cambridge, MA)

2000-09-26T23:59:59.000Z

268

Building new power plants in a CO2 constrained world: A Case Study from Norway on Gas-Fired Power Plants, Carbon Sequestration, and  

E-Print Network [OSTI]

including technologies for carbon sequestration. Norway's primary energy production is dominated by oilBuilding new power plants in a CO2 constrained world: A Case Study from Norway on Gas-Fired Power director. Most of the material used in this work are either courtesy of the persons I talked to in Norway

269

How the Carbon Emissions Were Estimated  

U.S. Energy Information Administration (EIA) Indexed Site

How the Carbon Emissions Were Estimated How the Carbon Emissions Were Estimated How the Carbon Emissions Were Estimated Carbon dioxide emissions are the main component of greenhouse gas emissions caused by human activity. Carbon dioxide is emitted mostly as a byproduct of the combustion of fossil fuels for energy, although certain industrial processes (e.g., cement manufacture) also emit carbon dioxide. The estimates of energy-related carbon emissions require both data on the energy use and carbon emissions coefficients relating energy use to the amount of carbon emitted. The Energy Information Administration (EIA) is the main source of data on U.S. energy use. Emissions of Greenhouse Gases in the United States 1998 used annual data provided by energy suppliers. However, to obtain more detail on how different sectors use energy, the emissions estimates in Energy and GHG Analysis rely data from on surveys of energy users, such as manufacturing establishments and commercial buildings.

270

,"U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2012 Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5460us2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5460us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:31 PM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" "Sourcekey","N5460US2" "Date","U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" 34515,-19376 34880,5419 35246,-12622 35611,6367

271

,"U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5460us2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5460us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:31 PM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" "Sourcekey","N5460US2" "Date","U.S. Natural Gas Salt Underground Storage Activity-Net (MMcf)" 34349,10392 34380,8240 34408,-5388

272

,"U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5440us2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5440us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:30 PM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" "Sourcekey","N5440US2" "Date","U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" 34349,10956 34380,12444

273

,"U.S. Natural Gas Salt Underground Storage Activity-Withdraw (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5450us2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5450us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:30 PM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Withdraw (MMcf)" "Sourcekey","N5450US2" "Date","U.S. Natural Gas Salt Underground Storage Activity-Withdraw (MMcf)" 34349,21349 34380,20684

274

,"U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2012 Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5440us2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5440us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:29 PM" "Back to Contents","Data 1: U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" "Sourcekey","N5440US2" "Date","U.S. Natural Gas Salt Underground Storage Activity-Injects (MMcf)" 34515,142243 34880,194185 35246,258468

275

Carbon Additionality: Discussion Paper  

E-Print Network [OSTI]

ahead, and identifying the carbon pools and other green house gas emissions sources and savings coveredCarbon Additionality: A review Discussion Paper Gregory Valatin November 2009 Forest Research. Voluntary Carbon Standards American Carbon Registry Forest Carbon Project Standard (ACRFCPS) 27 Carbon

276

Structure and Oxidation Activity Correlations for Carbon Blacks and Diesel Soot  

Science Journals Connector (OSTI)

This work focuses on a comprehensive investigation of structure–activity relationships for a diesel engine soot sample (Corning) and 10 commercially available carbon black samples. ... Su and colleagues used high-resolution transmission electron microscopy (HRTEM) and thermogravimetric analysis (TGA) to study the relation between the microstructure and oxidation behavior of soot from exhausts of different heavy-duty diesel engines and discovered the microstructure-controlled oxidation behavior of diesel soot. ... FE-SEM images (see Figure S1 of the Supporting Information) of some carbon blacks (Monarch 1400, Monarch 280, and Printex-U) and diesel soot-1 show the agglomerates, which are composed of their fundamental units called primary particles. ...

Lakshitha Pahalagedara; Hom Sharma; Chung-Hao Kuo; Saminda Dharmarathna; Ameya Joshi; Steven L. Suib; Ashish B. Mhadeshwar

2012-10-11T23:59:59.000Z

277

PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR  

SciTech Connect (OSTI)

Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

Colon-Mercado, H.

2011-11-10T23:59:59.000Z

278

Liquid Natural Gas  

Science Journals Connector (OSTI)

Liquid Natural Gas ... IN A new technique for storing natural gas at the East Ohio Gas Co. plant, Cleveland, Ohio, the gas is liquefied before passing to the gas holders. ... Natural gas contains moisture and carbon dioxide, both of which liquefy before the natural gas and are somewhat of a nuisance because upon solidification they clog the pipes. ...

W. F. SCHAPHORST

1941-04-25T23:59:59.000Z

279

Novel Carbon Nanotube-Based Nanostructures for High-Temperature Gas Sensing  

SciTech Connect (OSTI)

The primary objective of this research is to examine the feasibility of using vertically aligned multi-wall carbon nanotubes (MWCNTs) as a high temperature sensor material for fossil energy systems where reducing atmospheres are present. In the initial period of research, we fabricated capacitive sensors for hydrogen sensing using vertically aligned MWCNTs. We found that CNT itself is not sensitive to hydrogen. Moreover, with the help of Pd electrodes, hydrogen sensors based on CNTs are very sensitive and fast responsive. However, the Pd-based sensors can not withstand high temperature (T<200 C). In the last year, we successfully fabricated a hydrogen sensor based on an ultra-thin nanoporous titanium oxide (TiO{sub 2}) film supported by an AAO substrate, which can operate at 500 C with hydrogen concentrations in a range from 50 to 500 ppm.

Zhi Chen; Kozo Saito

2008-08-31T23:59:59.000Z

280

if it is a gas leak, do not activate building alarms, use mobile phones, hand held radios, electronic equipment or light flammable material!  

E-Print Network [OSTI]

gas leak gas leak if it is a gas leak, do not activate building alarms, use mobile phones, hand held radios, electronic equipment or light flammable material! 1. If you discover a Gas Leak, shout and check that the nearest gas isolator switch is off. 4. Evacuate the building immediately, avoiding

Hickman, Mark

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Microsoft Word - Evaluation of Alternate Water Gas Shift for Carbon Capture Final Final Report .doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Evaluation of Alternate Water Evaluation of Alternate Water Gas Shift Configurations for IGCC Systems August 5, 2009 DOE/NETL-401/080509 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States

282

Simulated coal-gas-fueled molten carbonate fuel cell development program  

SciTech Connect (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

283

Simulated coal-gas-fueled molten carbonate fuel cell development program. Topical report: Cathode compatibility tests  

SciTech Connect (OSTI)

In previous work, International Fuel Cells Corporation (EFC) found interactions between molten carbonate fuel cell cathode materials being considered as replacements for the presently used nickel oxide and matrix materials. Consequently, this work was conducted to screen additional new materials for mutual compatibility. As part of this program, experiments were performed to examine the compatibility of several candidate, alternative cathode materials with the standard lithium aluminate matrix material in the presence of electrolyte at cell potentials. Initial cathode candidates were materials lithium ferrite, yttrium iron garnet, lithium manganite and doped ceria which were developed by universities, national laboratories, or contractors to DOE, EPRI, or GRI. These investigations were conducted in laboratory scale experiments. None of the materials tested can directly replace nickel oxide or indicate greater stability of cell performance than afforded by nickel oxide. Specifically: (1) no further work on niobium doped ceria is warranted; (2) cobalt migration was found in the lithium ferrite cathode tested. This could possibly lead to shorting problems similiar to those encountered with nickel oxide; (3) Possible shorting problems may also exist with the proprietary dopant in YIG; (4) lithium ferrite and YIG cathode were not single phase materials. Assessment of the chemical stability, i.e., dopant loss, was severely impeded by dissolution of these second phases in the electrolyte; and (5) Magnesium doped lithium manganite warrants further work. Electrolytes should contain Mg ions to suppress dopant loss.

Johnson, W.H.

1992-07-01T23:59:59.000Z

284

Uptake of Reactive Black 5 by pumice and walnut activated carbon: Chemistry and adsorption mechanisms  

Science Journals Connector (OSTI)

Abstract The potential of using pumice and walnut wood activated carbon as low-cost adsorbents for the removal of the diazo dye Reactive Black 5 (RB5) from aqueous solutions was investigated. The Langmuir isotherm fit to the data specified the presence of two different natures of adsorption sites with different binding energies on the AC-W surface. Kinetic modelling showed that the adsorption behaviour and mechanism of RB5 for both adsorbents is believed to happen via surface adsorption followed by diffusion into the pores of the AC-W and pumice. The main adsorption mechanisms are hydrogen bonding, electrostatic bonding and n–? interactions.

Behzad Heibati; Susana Rodriguez-Couto; Abdeltif Amrane; Mohd. Rafatullah; Alaa Hawari; Mohammad A. Al-Ghouti

2014-01-01T23:59:59.000Z

285

Economic comparison between coal-fired and liquefied natural gas combined cycle power plants considering carbon tax: Korean case  

Science Journals Connector (OSTI)

Economic growth is main cause of environmental pollution and has been identified as a big threat to sustainable development. Considering the enormous role of electricity in the national economy, it is essential to study the effect of environmental regulations on the electricity sector. This paper aims at making an economic analysis of Korea's power plant utilities by comparing electricity generation costs from coal-fired power plants and liquefied natural gas (LNG) combined cycle power plants with environmental consideration. In this study, the levelized generation cost method (LGCM) is used for comparing economic analysis of power plant utilities. Among the many pollutants discharged during electricity generation, this study principally deals with control costs related only to CO2 and NO2, since the control costs of SO2 and total suspended particulates (TSP) are already included in the construction cost of utilities. The cost of generating electricity in a coal-fired power plant is compared with such cost in a LNG combined cycle power plant. Moreover, a sensitivity analysis with computer simulation is performed according to fuel price, interest rates and carbon tax. In each case, these results can help in deciding which utility is economically justified in the circumstances of environmental regulations.

Suk-Jae Jeong; Kyung-Sup Kim; Jin-Won Park; Dong-soon Lim; Seung-moon Lee

2008-01-01T23:59:59.000Z

286

INVESTIGATION OF FLY ASH AND ACTIVATED CARBON OBTAINED FROM PULVERIZED COAL BOILERS  

SciTech Connect (OSTI)

One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addresses the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addresses the possible connection between SCR reactors, fly ash properties and Hg capture. The project is determining the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed are also being determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control, are being analyzed to determine the effect of SCR on the ash.

Edward K. Levy; Christopher Kiely

2005-11-01T23:59:59.000Z

287

Physicochemical aspects of the adsorption of sulfur dioxide by carbon adsorbents  

Science Journals Connector (OSTI)

Literature data on the chemistry of the adsorption of sulfur dioxide on carbon adsorbents are surveyed and described systematically. The influence of various factors (the nature of the carbon matrix, the activation method, the chemistry of the adsorbent surfaces, temperature, the composition of the gas stream, etc.) on the sorption of SO2 by activated carbons and semicokes is examined. The possible ways in which sulfur dioxide interacts with the carbon surface are discussed. The bibliography includes 128 references.

Sergey A Anurov

1996-01-01T23:59:59.000Z

288

Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity. [Jurassic Smackover Formation  

SciTech Connect (OSTI)

This volume contains maps, well logging correlated to porosity and permeability, structural cross section, graph of production history, porosity vs. natural log permeability plot, detailed core log, paragenetic sequence and reservoir characterization sheet of the following fields in southwest Alabama: Appleton oil field; Barnett oil field; Barrytown oil field; Big Escambia Creek gas and condensate field; Blacksher oil field; Broken Leg Creed oil field; Bucatunna Creed oil field; Chappell Hill oil field; Chatom gas and condensate field; Choctaw Ridge oil field; Chunchula gas and condensate field; Cold Creek oil field; Copeland gas and condensate field; Crosbys Creed gas and condensate field; and East Barnett oil field. (AT)

Kopaska-Merkel, D.C.; Moore, H.E. Jr.; Mann, S.D.; Hall, D.R.

1992-06-01T23:59:59.000Z

289

Establishment of an oil and gas database for increased recovery and characterization of oil and gas carbonate reservoir heterogeneity. Appendix 1, Volume 1  

SciTech Connect (OSTI)

This volume contains maps, well logging correlated to porosity and permeability, structural cross section, graph of production history, porosity vs. natural log permeability plot, detailed core log, paragenetic sequence and reservoir characterization sheet of the following fields in southwest Alabama: Appleton oil field; Barnett oil field; Barrytown oil field; Big Escambia Creek gas and condensate field; Blacksher oil field; Broken Leg Creed oil field; Bucatunna Creed oil field; Chappell Hill oil field; Chatom gas and condensate field; Choctaw Ridge oil field; Chunchula gas and condensate field; Cold Creek oil field; Copeland gas and condensate field; Crosbys Creed gas and condensate field; and East Barnett oil field. (AT)

Kopaska-Merkel, D.C.; Moore, H.E. Jr.; Mann, S.D.; Hall, D.R.

1992-06-01T23:59:59.000Z

290

Carbon Sequestered, Carbon Displaced and the Kyoto Context  

SciTech Connect (OSTI)

The integrated system that embraces forest management, forest products, and land-use change impacts the global carbon cycle - and hence the net emission of the greenhouse gas carbon dioxide - in four fundamental ways. Carbon is stored in living and dead biomass, carbon is stored in wood products and landfills, forest products substitute in the market place for products made from other materials, and forest harvests can be used wholly or partially to displace fossil fuels in the energy sector. Implementation of the Kyoto Protocol to the United Nations Framework Convention on Climate Change would result in the creation of international markets for carbon dioxide emissions credits, but the current Kyoto text does not treat all carbon identically. We have developed a carbon accounting model, GORCAM, to examine a variety of scenarios for land management and the production of forest products. In this paper we explore, for two simple scenarios of forest management, the carbon flows that occur and how these might be accounted for under the Kyoto text. The Kyoto protocol raises questions about what activities can result in emissions credits, which carbon reservoirs will be counted, who will receive the credits, and how much credit will be available? The Kyoto Protocol would sometimes give credits for carbon sequestered, but it would always give credits when fossil-fuel carbon dioxide emissions are displaced.

Marland, G.; Schlamadinger, B.

1999-04-18T23:59:59.000Z

291

Innovative high pressure gas MEM's based neutron detector for ICF and active SNM detection.  

SciTech Connect (OSTI)

An innovative helium3 high pressure gas detection system, made possible by utilizing Sandia's expertise in Micro-electrical Mechanical fluidic systems, is proposed which appears to have many beneficial performance characteristics with regards to making these neutron measurements in the high bremsstrahlung and electrical noise environments found in High Energy Density Physics experiments and especially on the very high noise environment generated on the fast pulsed power experiments performed here at Sandia. This same system may dramatically improve active WMD and contraband detection as well when employed with ultrafast (10-50 ns) pulsed neutron sources.

Martin, Shawn Bryan; Derzon, Mark Steven; Renzi, Ronald F.; Chandler, Gordon Andrew

2007-12-01T23:59:59.000Z

292

Renewable Energy Plants in Your Gas Tank: From Photosynthesis to Ethanol (4 Activities)  

Broader source: Energy.gov [DOE]

With ethanol becoming more prevalent in the media and in gas tanks, it is important for students to know where it comes from. This module uses a series of four activities to show how energy and mass are converted from one form to another. It focuses on the conversion of light energy into chemical energy via photosynthesis, then goes on to show how the chemical energy in plant sugars can be fermented to produce ethanol. Finally, the reasons for using ethanol as a fuel are discussed.

293

Synthesis and reactivity of sterically congested metallacyclobutenes and metal-mediated carbon-sulfur bond activation  

E-Print Network [OSTI]

methods for this conversion typically involve the production of byproducts like carbon monoxide and hydrogen

Vélez, Carmen L.

2011-01-01T23:59:59.000Z

294

Carbon Smackdown: Carbon Capture  

SciTech Connect (OSTI)

In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

Jeffrey Long

2010-07-12T23:59:59.000Z

295

Hanford Low-Activity Waste Processing: Demonstration of the Off-Gas Recycle Flowsheet - 13443  

SciTech Connect (OSTI)

Vitrification of Hanford Low-Activity Waste (LAW) is nominally the thermal conversion and incorporation of sodium salts and radionuclides into borosilicate glass. One key radionuclide present in LAW is technetium-99. Technetium-99 is a low energy, long-lived beta emitting radionuclide present in the waste feed in concentrations on the order of 1-10 ppm. The long half-life combined with a high solubility in groundwater results in technetium-99 having considerable impact on performance modeling (as potential release to the environment) of both the waste glass and associated secondary waste products. The current Hanford Tank Waste Treatment and Immobilization Plant (WTP) process flowsheet calls for the recycle of vitrification process off-gas condensates to maximize the portion of technetium ultimately immobilized in the waste glass. This is required as technetium acts as a semi-volatile specie, i.e. considerable loss of the radionuclide to the process off-gas stream can occur during the vitrification process. To test the process flowsheet assumptions, a prototypic off-gas system with recycle capability was added to a laboratory melter (on the order of 1/200 scale) and testing performed. Key test goals included determination of the process mass balance for technetium, a non-radioactive surrogate (rhenium), and other soluble species (sulfate, halides, etc.) which are concentrated by recycling off-gas condensates. The studies performed are the initial demonstrations of process recycle for this type of liquid-fed melter system. This paper describes the process recycle system, the waste feeds processed, and experimental results. Comparisons between data gathered using process recycle and previous single pass melter testing as well as mathematical modeling simulations are also provided. (authors)

Ramsey, William G.; Esparza, Brian P. [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)] [Washington River Protection Solutions, LLC, Richland, WA 99532 (United States)

2013-07-01T23:59:59.000Z

296

Detailed compositional analysis of gas seepage at the National Carbon Storage Test Site, Teapot Dome, Wyoming, USA  

Science Journals Connector (OSTI)

A baseline determination of CO2 and CH4 fluxes and soil gas concentrations of CO2 and CH4 was made over the Teapot Dome oil field in the Naval Petroleum Reserve No. 3 (NPR-3) in Wyoming, USA. This was done in anticipation of experimentation with CO2 sequestration in the Pennsylvanian Tensleep Sandstone underlying the field at a depth of 1680 m. The baseline data were collected during the winter, 2004 in order to minimize near-surface biological activity in the soil profile. The baseline data were used to select anomalous locations that may be the result of seeping thermogenic gas, along with background locations. Five 10-m holes were drilled, 3 of which had anomalous gas microseepage, and 2 were characterized as “background.” These were equipped for nested gas sampling at depths of 10-, 5-, 3-, 2-, and 1-m depths. Methane concentrations as high as 170,000 ppmv (17%) were found, along with high concentrations of C2H6, C3H8, n-C4H10, and i-C4H10. Much smaller concentrations of C2H4 and C3H6 were observed indicating the beginning of hydrocarbon oxidation in the anomalous holes. The anomalous 10-m holes also had high concentrations of isotopically enriched CO2, indicating the oxidation of hydrocarbons. Concentrations of the gases decreased upward, as expected, indicating oxidation and transport into the atmosphere. The ancient source of the gases was confirmed by 14C determinations on CO2, with radiocarbon ages approaching 38 ka within 5 m of the surface. Modeling was used to analyze the distribution of hydrocarbons in the anomalous and background 10-m holes. Diffusion alone was not sufficient to account for the hydrocarbon concentration distributions, however the data could be fit with the addition of a consumptive reaction. First-order rate constants for methanotrophic oxidation were obtained by inverse modeling. High rates of oxidation were found, particularly near the surface in the anomalous 10-m holes, demonstrating the effectiveness of the process in the attenuation of CH4 microseepage. The results also demonstrate the importance of CH4 measurements in the planning of a monitoring and verification program for geological CO2 sequestration in sites with significant remaining hydrocarbons (i.e. spent oil reservoirs).

Ronald W. Klusman

2006-01-01T23:59:59.000Z

297

Magnesium oxide nanoparticles on green activated carbon as efficient CO{sub 2} adsorbent  

SciTech Connect (OSTI)

This study was focused on carbon dioxide (CO{sub 2}) adsorption ability using Magnesium oxide (MgO) nanoparticles and MgO nanoparticles supported activated carbon based bamboo (BAC). The suitability of MgO as a good CO{sub 2} adsorbent was clarified using Thermodynamic considerations (Gibbs-Helmholtz relationship). The ?H and ?G of this reaction were ? 117.5 kJ?mol{sup ?1} and ? 65.4 kJ?mol{sup ?1}, respectively, at standard condition (298 K and 1 atm). The complete characterization of these adsorbent were conducted by using BET, XRD, FTIR, TEM and TPD?CO{sub 2}. The surface areas for MgO nanoparticles and MgO nanoparticles supported BAC were 297.1 m{sup 2}/g and 702.5 m{sup 2}/g, respectively. The MgO nanoparticles supported BAC shown better physical and chemical adsorption ability with 39.8 cm{sup 3}/g and 6.5 mmol/g, respectively. The combination of MgO nanoparticle and BAC which previously prepared by chemical method can reduce CO{sub 2} emissions as well as better CO{sub 2} adsorption behavior. Overall, our results indicate that nanoparticles of MgO on BAC posses unique surface chemistry and their high surface reactivity coupled with high surface area allowed them to approach the goal as an efficient CO{sub 2} adsorbent.

Wan Isahak, Wan Nor Roslam; Ramli, Zatil Amali Che; Mohamed Hisham, Mohamed Wahab; Yarmo, Mohd Ambar [Low Carbon Economy (LCE) Research Group, School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

298

Modelling and simulation of CO2 (carbon dioxide) bottoming cycles for offshore oil and gas installations at design and off-design conditions  

Science Journals Connector (OSTI)

Abstract Improved energy efficiency is an issue of increasing importance in offshore oil and gas installations. The power on offshore installations is generated by gas turbines operating in a simple cycle. There is an obvious possibility for heat recovery for further power generation from the exhaust heat. However, the limited space and weight available makes the inclusion of bottoming cycles challenging. Due to its high working pressure and thereby compact components CO2 (carbon dioxide) could be a viable solution, combining compactness and efficiency. An in-house simulation tool is used to evaluate the performance of CO2 bottoming cycles at design and off-design conditions. Both a simple recuperated single stage cycle and a more advanced dual stage system are modelled. Results from simulations show a potential for 10–11%-points increase in net plant efficiency at 100% gas turbine load. Also off-design simulations taking the variation in heat exchanger performance into account are performed showing that the bottoming cycle improves the off-design performance compared to the standard gas turbine solution. Even at 60% GT (gas turbine) load, the combined cycle with CO2 bottoming cycle can achieve up to 45% net plant efficiency, compared to 31% for only the gas turbine.

Harald Taxt Walnum; Petter Nekså; Lars O. Nord; Trond Andresen

2013-01-01T23:59:59.000Z

299

The US department of Energy's R&D program to reduce greenhouse gas emissions through beneficial uses of carbon dioxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Published in 2011 by John Wiley & Sons, Ltd | Greenhouse Gas Sci Technol. (2011); DOI: 10.1002/ghg Published in 2011 by John Wiley & Sons, Ltd | Greenhouse Gas Sci Technol. (2011); DOI: 10.1002/ghg Perspective Correspondence to: Darin Damiani, National Energy Technology Laboratory, US Department of Energy, 3610 Collins Ferry Road, Morgantown, WV 26507, USA. E-mail: darin.damiani@netl.doe.gov † This article is a US Government work and is in the public domain in the USA. Received June 24, 2011; revised July 26, 2011; accepted July 27, 2011 Published online at Wiley Online Library (wileyonlinelibrary.com) DOI: 10.1002/ghg.35 The US Department of Energy's R&D program to reduce greenhouse gas emissions through benefi cial uses of carbon dioxide † Darin Damiani and John T. Litynski, National Energy Technology Laboratory, US Department of

300

A highly active and stable Co4N/?-Al2O3 catalyst for CO and CO2 methanation to produce synthetic natural gas (SNG)  

Science Journals Connector (OSTI)

Abstract Co4N/?-Al2O3 and Co/?-Al2O3 catalysts with different metal loadings were prepared by NH3 and H2-temperature programmed reaction method for the co-methanation of carbon oxides (CO and CO2). The catalysts were characterized by N2 adsorption–desorption, XRD, XPS, TEM-SAED, H2, CO, and CO2-TPD techniques. Results showed that the Co4N catalysts had higher activity than Co metal-supported catalysts due to their enhanced adsorption capacity, uniform metal dispersion, and superior metal-support interaction. Among the catalysts studied, 20Co4N/?-Al2O3 catalyst with 20 wt% metal loading showed the best performance. This catalyst achieved higher activity for CH4 formation between 200 and 300 °C and maintained high product selectivity (?98%). A 250 h stability test for 20Co4N/?-Al2O3 was also conducted at 350 °C and increased gas hourly space velocity (GHSV; 10,000 h?1). The spent catalyst was further characterized using XRD, TEM, and TGA analysis. Results revealed that the catalyst was highly resistant to metal sintering and carbon deposition, whereas high CO and CO2 conversion and CH4 selectivity were maintained even at a higher GHSV.

Rauf Razzaq; Chunshan Li; Muhammad Usman; Kenzi Suzuki; Suojiang Zhang

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Measurement of gas/water uptake coefficients for trace gases active in the marine environment  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean's surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry's law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. (Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry); Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. (Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics)

1992-02-01T23:59:59.000Z

302

Surface free-carrier screening effect on the output of a ZnO nanowire nanogenerator and its potential as a self-powered active gas sensor  

E-Print Network [OSTI]

potential as a self-powered active gas sensor This article has been downloaded from IOPscience. Please on the output of a ZnO nanowire nanogenerator and its potential as a self-powered active gas sensor Xinyu Xue1 as a power source, but also as a response signal to the gas, demonstrating a possible approach as a self-powered

Wang, Zhong L.

303

E-Print Network 3.0 - active gas handling Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

geopolitics of gas working paper series THE BELARUS CONNECTION: EXPORTING RUSSIAN GAS TO GERMANY... AND POLAND david victor and nadejda makarova victor 12;The Belarus Connection:...

304

The use of activated charcoal for the removal of oxygen from gas ...  

Science Journals Connector (OSTI)

May 1, 1970 ... being analyzed by gas-solid chromatography. ... chosen for gas separations will not separate ... two or three stations had been processed to.

1999-12-27T23:59:59.000Z

305

Structural basis of the oxidative activation of the carboxysomal [gamma]-carbonic anhydrase, CcmM  

SciTech Connect (OSTI)

Cyanobacterial RuBisCO is sequestered in large, icosahedral, protein-bounded microcompartments called carboxysomes. Bicarbonate is pumped into the cytosol, diffuses into the carboxysome through small pores in its shell, and is then converted to CO{sub 2} by carbonic anhydrase (CA) prior to fixation. Paradoxically, many {beta}-cyanobacteria, including Thermosynechococcus elongatus BP-1, lack the conventional carboxysomal {beta}-CA, ccaA. The N-terminal domain of the carboxysomal protein CcmM is homologous to {gamma}-CA from Methanosarcina thermophila (Cam) but recombinant CcmM derived from ccaA-containing cyanobacteria show no CA activity. We demonstrate here that either full length CcmM from T. elongatus, or a construct truncated after 209 residues (CcmM209), is active as a CA - the first catalytically active bacterial {gamma}-CA reported. The 2.0 {angstrom} structure of CcmM209 reveals a trimeric, left-handed {beta}-helix structure that closely resembles Cam, except that residues 198-207 form a third {alpha}-helix stabilized by an essential Cys194-Cys200 disulfide bond. Deleting residues 194-209 (CcmM193) results in an inactive protein whose 1.1 {angstrom} structure shows disordering of the N- and C-termini, and reorganization of the trimeric interface and active site. Under reducing conditions, CcmM209 is similarly partially disordered and inactive as a CA. CcmM protein in fresh E. coli cell extracts is inactive, implying that the cellular reducing machinery can reduce and inactivate CcmM, while diamide, a thiol oxidizing agent, activates the enzyme. Thus, like membrane-bound eukaryotic cellular compartments, the {beta}-carboxysome appears to be able to maintain an oxidizing interior by precluding the entry of thioredoxin and other endogenous reducing agents.

Peña, Kerry L.; Castel, Stephane E.; de Araujo, Charlotte; Espie, George S.; Kimber, Matthew S. (Guelph); (Toronto)

2010-04-26T23:59:59.000Z

306

Intention to change activities that reduce carbon dioxide emissions related to worry about global climate change consequences  

Science Journals Connector (OSTI)

Introduction Mitigating the global climate change requires actions at different levels including that lay people change their consumption patterns, which cause emissions of greenhouse gases. Recent research suggests that inducing affects such as fear and worry may have positive effects. Objective To investigate whether worry in addition to personalized information about emissions of carbon dioxide would influence lay people's intentions to change consumption-related personal activities causing carbon-dioxide emissions. Method A municipality-provided tool to calculate their annual carbon dioxide emissions was used by 135 university students who after being informed about negative consequences of global climate change stated their intentions to change a number of personal activities to reduce carbon dioxide emissions during the following 12 months. They also rated how worried they were about eight global climate change consequences. Results Intentions to change travel, energy use at home, food consumption, involvement in environmental organizations, and support of environmental policies increased with worry. An interaction was also observed such that high-emitters’ intentions to invest in energy-efficient infrastructure increased more with worry than did low- and medium-emitters’ intentions. Conclusions In line with recent research positing that affect increases preventive actions, the hypothesis was supported that intentions to change personal activities to reduce carbon dioxide emissions increased with participants’ worry about the consequences of global climate change.

E.-L. Sundblad; A. Biel; T. Gärling

2014-01-01T23:59:59.000Z

307

Meeting State Carbon Emission Requirements through Industrial Energy Efficiency: The Southern California Gas Company’s Industrial End User Program  

Broader source: Energy.gov [DOE]

This case study describes the Southern California Gas Company’s Industrial End User program, which helps large industrial customers increase energy efficiency and reduce energy use and greenhouse gas emissions.

308

Characterizing Natural Gas Hydrates in the Deep Water Gulf of Mexico: Applications for Safe Exploration and Production Activities  

SciTech Connect (OSTI)

In 2000 Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deep water portion of the Gulf of Mexico (GOM). Chevron is an active explorer and operator in the Gulf of Mexico and is aware that natural gas hydrates need to be understood to operate safely in deep water. In August 2000 Chevron worked closely with the National Energy Technology Laboratory (NETL) of the United States Department of Energy (DOE) and held a workshop in Houston, Texas to define issues concerning the characterization of natural gas hydrate deposits. Specifically, the workshop was meant to clearly show where research, the development of new technologies, and new information sources would be of benefit to the DOE and to the oil and gas industry in defining issues and solving gas hydrate problems in deep water.

Bent, Jimmy

2014-05-31T23:59:59.000Z

309

E-Print Network 3.0 - activated carbon fluidized-bed Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technologies 16 PRODUCTION OF MULTI-WALL CARBON NANOTUBES BY MEANS OF FLUIDIZED BED PYROLYSIS OF VIRGIN OR RECYCLED POLYMERS Summary: PRODUCTION OF MULTI-WALL CARBON NANOTUBES BY...

310

Natural catalytic activity in a marine shale for generating natural gas  

Science Journals Connector (OSTI)

...in a marine shale for generating natural gas Frank D. Mango 1 * Daniel M...be the source of equilibrium in natural gas habitats and in marine shales...palaeoactivity|low-temperature gas|natural gas| 1. Introduction It is broadly...

2010-01-01T23:59:59.000Z

311

Influence of Chemical and Physical Properties of Activated Carbon Powders on Oxygen Reduction and Microbial Fuel Cell Performance  

E-Print Network [OSTI]

resource. Cathode materials can account for 47-75% of the MFC capital costs,5 and therefore it is important to choose less expensive materials as the cathode catalyst. Several catalysts have been considered for useInfluence of Chemical and Physical Properties of Activated Carbon Powders on Oxygen Reduction

312

Negative refraction with tunable absorption in an active dense gas of atoms  

E-Print Network [OSTI]

Applications of negative index materials (NIM) presently are severely limited by absorption. Next to improvements of metamaterial designs, it has been suggested that dense gases of atoms could form a NIM with negligible losses. In such gases, the low absorption is facilitated by quantum interference. Here, we show that additional gain mechanisms can be used to tune and effectively remove absorption in a dense gas NIM. In our setup, the atoms are coherently prepared by control laser fields, and further driven by a weak incoherent pump field to induce gain. We employ nonlinear optical Bloch equations to analyze the optical response. Metastable Neon is identified as a suitable experimental candidate at infrared frequencies to implement a lossless active negative index material.

P. P. Orth; R. Hennig; C. H. Keitel; J. Evers

2012-10-17T23:59:59.000Z

313

Microfluidic sieve using intertwined, free-standing carbon nanotube mesh as active medium  

DOE Patents [OSTI]

A microfluidic sieve having a substrate with a microfluidic channel, and a carbon nanotube mesh. The carbon nanotube mesh is formed from a plurality of intertwined free-standing carbon nanotubes which are fixedly attached within the channel for separating, concentrating, and/or filtering molecules flowed through the channel. In one embodiment, the microfluidic sieve is fabricated by providing a substrate having a microfluidic channel, and growing the intertwined free-standing carbon nanotubes from within the channel to produce the carbon nanotube mesh attached within the channel.

Bakajin, Olgica (San Leandro, CA); Noy, Aleksandr (Belmont, CA)

2007-11-06T23:59:59.000Z

314

How carbon-based sorbents will impact fly ash utilization and disposal  

SciTech Connect (OSTI)

The injection of activated carbon flue gas to control mercury emissions will result in a fly ash and activated carbon mixture. The potential impact of this on coal combustion product disposal and utilization is discussed. The full paper (and references) are available at www.acaa-usa.org. 1 tab., 2 photos.

Pflughoeft-Hassett, D.F.; Hassett, D.J.; Buckley, T.D.; Heebink, L.V.; Pavlish, J.H. [Energy and Environmental Research Center (United States)

2008-07-01T23:59:59.000Z

315

Iodine Adsorption on Ion-Exchange Resins and Activated Carbons– Batch Testing  

SciTech Connect (OSTI)

Iodine sorption onto seven resins and six carbon materials was evaluated using water from well 299-W19-36 on the Hanford Site. These materials were tested using a range of solution-to-solid ratios. The test results are as follows: • The efficacy of the resin and granular activated carbon materials was less than predicted based on manufacturers’ performance data. It is hypothesized that this is due to the differences in speciation previously determined for Hanford groundwater. • The sorption of iodine is affected by the iodine species in the source water. Iodine loading on resins using source water ranged from 1.47 to 1.70 µg/g with the corresponding Kd values from 189.9 to 227.0 mL/g. The sorption values when the iodine is converted to iodide ranged from 2.75 to 5.90 µg/g with the corresponding Kd values from 536.3 to 2979.6 mL/g. It is recommended that methods to convert iodine to iodide be investigated in fiscal year (FY) 2015. • The chemicals used to convert iodine to iodate adversely affected the sorption of iodine onto the carbon materials. Using as-received source water, loading and Kd values ranged from 1.47 to 1.70 µg/g and 189.8 to 226.3 mL/g respectively. After treatment, loading and Kd values could not be calculated because there was little change between the initial and final iodine concentration. It is recommended the cause of the decrease in iodine sorption be investigated in FY15. • In direct support of CH2M HILL Plateau Remediation Company, Pacific Northwest National Laboratory has evaluated samples from within the 200W pump and treat bioreactors. As part of this analysis, pictures taken within the bioreactor reveal a precipitate that, based on physical properties and known aqueous chemistry, is hypothesized to be iron pyrite or chalcopyrite, which could affect iodine adsorption. It is recommended these materials be tested at different solution-to-solid ratios in FY15 to determine their effect on iodine sorption.

Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

2014-09-30T23:59:59.000Z

316

A Comparison of Oxygen-vacancy Effect on Activity Behaviors of Carbon Dioxide and Steam Reforming of Methane over Supported Nickel Catalysts  

Science Journals Connector (OSTI)

A comparison of the activity behaviors of the mechanistically similar reactions of carbon dioxide reforming and steam reforming of methane was carried out at 400?550 °C ... show that the activity behaviors of car...

Ta-Jen Huang; Han-Jun Lin; Tien-Chun Yu

2005-12-01T23:59:59.000Z

317

Kinetic and equilibrium adsorption of methylene blue and remazol dyes onto steam-activated carbons developed from date pits  

Science Journals Connector (OSTI)

Steam-activated carbons DS2 and DS5 were prepared by gasifying 600 °C-date pits carbonization products with steam at 950 °C to burn-off = 20 and 50%, respectively. The textural properties of these carbons were determined from the nitrogen adsorption at ?196 °C. The chemistry of the carbon surface was determined from the surface pH and from neutralization of the surface carbon–oxygen groups of basic and acidic type. The kinetic and equilibrium adsorption of MB and RY on DS2 and DS5 was determined at 27 and 37 °C and at initial sorption solution pH 3–7. DS2 and DS5 have expanded surface area, large total pore volume and contain both micro and mesoporosity. They have on their surface basic and acidic groups of different strength and functionality. This enhanced the sorption of the cationic dye (MB) and of the anionic dye (RY). The adsorption of MB and RY on DS2 and DS5 involves intraparticle diffusion and followed pseudo-second order kinetics. The adsorption isotherms were applicable to the Langmuir isotherm and high monolayer capacities for MB and RY dyes were evaluated indicating the high efficiencies of the carbons for dye adsorption.

Sheikha S. Ashour

2010-01-01T23:59:59.000Z

318

Carbon Sequestration Project Portfolio  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Home > Technologies > Carbon Storage > Reference Shelf > Project Portfolio Carbon Storage 2011 Carbon Storage Project Portfolio Table of Contents CARBON STORAGE OVERVIEW Carbon Storage Program Contacts [PDF-26KB] Carbon Storage Projects National Map [PDF-169KB] State Projects Summary Table [PDF-39KB] Carbon Storage Program Structure [PDF-181KB] Selected Carbon Sequestration Program Papers and Publications The U.S. Department of Energy's R&D Program to Reduce Greenhouse Gas Emissions Through Beneficial Uses of Carbon Dioxide (2011) [PDF-3.3MB] Greenhouse Gas Science and Technology Carbon Capture and Sequestration: The U.S. Department of Energy's R&D Efforts to Characterize Opportunities for Deep Geologic Storage of Carbon Dioxide in Offshore Resources (2011) [PDF-445KB]

319

Field Trip Guide to Serpentinite, Silica-Carbonate Alteration, and Related Hydrothermal Activity in the Clear Lake Region, California  

SciTech Connect (OSTI)

This guide is designed to familiarize scientists with the geology, structure, alteration, and fluids typical of California serpentinites for purposes of carbon dioxide sequestration (Lackner et al., 1995). Goff et al. (1997) and Goff and Lackner (1998) describe the geology and geochemistry of some of the serpentinites from this area. Mechanisms of silica-carbonate alteration were outlined by Barnes et al. (1973). Donnelly-Nolan et al. (1993) most recently reviewed relations between regional hydrothermal alteration and Quarternary volcanic activity. Stanley et al. (1998) summarized geophysical characteristics of the region.

Fraser Goff; George Guthrie

1999-06-01T23:59:59.000Z

320

C/H{sub 2}O reaction under supercritical conditions and their repercussions in the preparation of activated carbon  

SciTech Connect (OSTI)

Two chars prepared by carbonization of oak wood and anthracite were used to perform a comparative study of the gasification with supercritical water (SCW) and with steam. This work reports the effects of the type of char, the activating agent, temperature, flow rate, and particle size employed on the kinetics, mechanism of reaction, and the characteristics of the activated carbons obtained. The results show that the reactivity of the two chars is much higher with SCW than with steam. Although this increase can be explained in terms of the greater penetration of SCW and diffusional effects in the pore structure of the chars, some aspects suggest a possible change in the mechanism of reaction favored by the formation of clusters in SCW. The evolution of porosity was also found to differ when the char was gasified with SCW and with steam, being governed strongly by the starting material. When the oak char was activated with SCW, the smallest microporosity was broadened from the very first moments due to its very open pore structure, providing carbons with larger micropores and some mesoporosity. In contrast, in the case of the anthracite char, with a narrower pore structure, the evolution of the porosity was slower and less uniform, favoring external gasification of the particle. Accordingly, the carbons had a broader distribution of micropores, and mesoporosity was scarce.

Salvador, F.; Senchez-Montero, M.J.; Izquierdo, C. [University of Salamanca, Salamanca (Spain)

2007-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

EPA releases list of potential endocrine disrupters | Consensus reached on prenatal exposures | Rewarding fertilizer pollution with crop subsidies | Order matters in pesticide exposures | News Briefs: Nano needs oversight ` Congress and carbon sequestration ` Low-cost greenhouse-gas controls ` Sowing carbon credits ` Cities for sustainability | Unleashing a dioxin legacy | Florida gators battle pesticides | Lead levels high in Canadian tap water  

Science Journals Connector (OSTI)

EPA releases list of potential endocrine disrupters | Consensus reached on prenatal exposures | Rewarding fertilizer pollution with crop subsidies | Order matters in pesticide exposures | News Briefs: Nano needs oversight ` Congress and carbon sequestration ` Low-cost greenhouse-gas controls ` Sowing carbon credits ` Cities for sustainability | Unleashing a dioxin legacy | Florida gators battle pesticides | Lead levels high in Canadian tap water ...

NAOMI LUBICK; ROBERT WEINHOLD; KRIS CHRISTEN; RHITU CHATTERJEE; REBECCA RENNER

2007-08-01T23:59:59.000Z

322

Assessing the Effect of Timing of Availability for Carbon Dioxide Storage in the Largest Oil and Gas Pools in the Alberta Basin: Description of Data and Methodology  

SciTech Connect (OSTI)

Carbon dioxide capture from large stationary sources and storage in geological media is a technologically-feasible mitigation measure for the reduction of anthropogenic emissions of CO2 to the atmosphere in response to climate change. Carbon dioxide (CO2) can be sequestered underground in oil and gas reservoirs, in deep saline aquifers, in uneconomic coal beds and in salt caverns. The Alberta Basin provides a very large capacity for CO2 storage in oil and gas reservoirs, along with significant capacity in deep saline formations and possible unmineable coal beds. Regional assessments of potential geological CO2 storage capacity have largely focused so far on estimating the total capacity that might be available within each type of reservoir. While deep saline formations are effectively able to accept CO2 immediately, the storage potential of other classes of candidate storage reservoirs, primarily oil and gas fields, is not fully available at present time. Capacity estimates to date have largely overlooked rates of depletion in these types of storage reservoirs and typically report the total estimated storage capacity that will be available upon depletion. However, CO2 storage will not (and cannot economically) begin until the recoverable oil and gas have been produced via traditional means. This report describes a reevaluation of the CO2 storage capacity and an assessment of the timing of availability of the oil and gas pools in the Alberta Basin with very large storage capacity (>5 MtCO2 each) that are being looked at as likely targets for early implementation of CO2 storage in the region. Over 36,000 non-commingled (i.e., single) oil and gas pools were examined with effective CO2 storage capacities being individually estimated. For each pool, the life expectancy was estimated based on a combination of production decline analysis constrained by the remaining recoverable reserves and an assessment of economic viability, yielding an estimated depletion date, or year that it will be available for CO2 storage. The modeling framework and assumptions used to assess the impact of the timing of CO2 storage resource availability on the region’s deployment of CCS technologies is also described. The purpose of this report is to describe the data and methodology for examining the carbon dioxide (CO2) storage capacity resource of a major hydrocarbon province incorporating estimated depletion dates for its oil and gas fields with the largest CO2 storage capacity. This allows the development of a projected timeline for CO2 storage availability across the basin and enables a more realistic examination of potential oil and gas field CO2 storage utilization by the region’s large CO2 point sources. The Alberta Basin of western Canada was selected for this initial examination as a representative mature basin, and the development of capacity and depletion date estimates for the 227 largest oil and gas pools (with a total storage capacity of 4.7 GtCO2) is described, along with the impact on source-reservoir pairing and resulting CO2 transport and storage economics. The analysis indicates that timing of storage resource availability has a significant impact on the mix of storage reservoirs selected for utilization at a given time, and further confirms the value that all available reservoir types offer, providing important insights regarding CO2 storage implementation to this and other major oil and gas basins throughout North America and the rest of the world. For CCS technologies to deploy successfully and offer a meaningful contribution to climate change mitigation, CO2 storage reservoirs must be available not only where needed (preferably co-located with or near large concentrations of CO2 sources or emissions centers) but also when needed. The timing of CO2 storage resource availability is therefore an important factor to consider when assessing the real opportunities for CCS deployment in a given region.

Dahowski, Robert T.; Bachu, Stefan

2007-03-05T23:59:59.000Z

323

Total oxidation of carbon monoxide and methane over transition metal-fluorite oxide composite catalysts. I. Catalyst composition and activity  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the total oxidation of carbon monoxide and methane was prepared by combining fluorite oxides with active transition metals. The fluorite oxides, such as ceria and zirconia, are oxygen-ion-conducting materials having catalytic properties usually at high temperatures. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of these oxides. The contact of the two types of materials gave rise to a high active oxidation catalyst. At a space velocity of about 42,000 h{sup {minus}1}, complete carbon monoxide oxidation in air occurred at room temperature on the Au{sub 0.05}[Ce(La)]{sub 0.95}L{sub x} catalyst and at ca. 100{degrees}C on Cu-Ce-O composite catalysts. At the same space velocity, total oxidation of methane on the Cu-Ce-O catalyst doped with La{sub 2}O{sub 3} or SrO took place at ca. 550{degrees}C. The specific carbon monoxide oxidation activity of the Cu-Ce-O catalyst was several orders of magnitude higher than that of conventional copper-based catalysts and comparable or superior to platinum catalysts. This type of composite catalyst also showed excellent resistance to water vapor poisoning. The enhanced catalyst activity and stability resulted from strong interaction of the transition metal and fluorite oxide materials. 44 refs., 14 figs., 5 tabs.

Liu, W.; Flytzani-Stephanopoulos, F. [Tufts Univ., Medford, MA (United States)] [Tufts Univ., Medford, MA (United States)

1995-05-01T23:59:59.000Z

324

CHARACTERIZING NATURAL GAS HYDRATES IN THE DEEP WATER GULF OF MEXICO: APPLICATIONS FOR SAFE EXPLORATION AND PRODUCTION ACTIVITIES  

SciTech Connect (OSTI)

In 2000, Chevron began a project to learn how to characterize the natural gas hydrate deposits in the deepwater portions of the Gulf of Mexico. A Joint Industry Participation (JIP) group was formed in 2001, and a project partially funded by the U.S. Department of Energy (DOE) began in October 2001. The primary objective of this project is to develop technology and data to assist in the characterization of naturally occurring gas hydrates in the deep water Gulf of Mexico (GOM). These naturally occurring gas hydrates can cause problems relating to drilling and production of oil and gas, as well as building and operating pipelines. Other objectives of this project are to better understand how natural gas hydrates can affect seafloor stability, to gather data that can be used to study climate change, and to determine how the results of this project can be used to assess if and how gas hydrates act as a trapping mechanism for shallow oil or gas reservoirs. During the first six months of operation, the primary activities of the JIP were to conduct and plan Workshops, which were as follows: (1) Data Collection Workshop--March 2002 (2) Drilling, Coring and Core Analyses Workshop--May 2002 (3) Modeling, Measurement and Sensors Workshop--May 2002.

Steve Holditch; Emrys Jones

2003-01-01T23:59:59.000Z

325

Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter (chloride, fluoride, sulfur), will have high ammonia, and will contain carryover particulates of glass-former chemicals. These species have potential to cause corrosion of tanks and equipment, precipitation of solids, release of ammonia gas vapors, and scale in the tank farm evaporator. Routing this stream to the tank farms does not permanently divert it from recycling into the WTP, only temporarily stores it prior to reprocessing. Testing is normally performed to demonstrate acceptable conditions and limits for these compounds in wastes sent to the tank farms. The primary parameter of this phase of the test program was measuring the formation of solids during evaporation in order to assess the compatibility of the stream with the evaporator and transfer and storage equipment. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW facility melter offgas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet, and, thus, the composition will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. This report discusses results of evaporation testing of the simulant. Two conditions were tested, one with the simulant at near neutral pH, and a second at alkaline pH. The neutral pH test is comparable to the conditions in the Hanford Effluent Treatment Facility (ETF) evaporator, although that evaporator operates at near atmospheric pressure and tests were done under vacuum. For the alkaline test, the target pH was based on the tank farm corrosion control program requirements, and the test protocol and equipment was comparable to that used for routine evaluation of feed compatibility studies for the 242-A evaporator. One of the

Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

2014-01-27T23:59:59.000Z

326

Natural gas cleanup: Evaluation of a molecular sieve carbon as a pressure swing adsorbent for the separation of methane/nitrogen mixtures  

SciTech Connect (OSTI)

This report describes the results of a preliminary evaluation to determine the technical feasibility of using a molecular sieve carbon manufactured by the Takeda Chemical Company of Japan in a pressure owing adsorption cycle for upgrading natural gas (methane) contaminated with nitrogen. Adsorption tests were conducted using this adsorbent in two, four, and five-step adsorption cycles. Separation performance was evaluated in terms of product purity, product recovery, and sorbent productivity for all tests. The tests were conducted in a small, single-column adsorption apparatus that held 120 grams of the adsorbent. Test variables included adsorption pressure, pressurization rate, purge rate and volume, feed rate, and flow direction in the steps from which the product was collected. Sorbent regeneration was accomplished by purging the column with the feed gas mixture for all but one test series where a pure methane purge was used. The ratio between the volumes of the pressurization gas and the purge gas streams was found to be an important factor in determining separation performance. Flow rates in the various cycle steps had no significant effect. Countercurrent flow in the blow-down and purge steps improved separation performance. Separation performance appears to improve with increasing adsorption pressure, but because there are a number of interrelated variables that are also effected by pressure, further testing will be needed to verify this. The work demonstrates that a molecular sieve carbon can be used to separate a mixture of methane and nitrogen when used in a pressure swing cycle with regeneration by purge. Further work is needed to increase product purity and product recovery.

Grimes, R.W.

1994-06-01T23:59:59.000Z

327

Ammonia synthesis gas purification  

SciTech Connect (OSTI)

This patent describes the purification of a reformed gas mixture following water gas shift conversion to produce a purified ammonia synthesis gas stream. The improved processing sequence consisting essentially of: (A) Selectively catalytically oxidizing the residual carbon monoxide content of the gas mixture to carbon dioxide so as to reduce the carbon monoxide content of the gas mixture to less than about 20 ppm, the selective catalytic oxidation being carried out with an excess of air, with the excess oxygen being catalytically reacted with a small amount of hydrogen so that the residual oxygen level is reduced to less than about 3 ppm; (B) removing the bulk of the carbon dioxide content of the gas mixture by liquid absorption; (C) Removing residual amounts of carbon monoxide, carbon dioxide and water by selective adsorption on the fixed beds of a thermal swing adsorption system, a dry, purified ammonia ammonia synthesis gas stream containing less than a total of 10 ppm of carbon monoxide and carbon dioxide being recovered from the thermal swing adsorption system; (D) Passing the resulting dry, purified ammonia synthesis gas stream having a low content of methane to an ammonia production operation without intermediate passage of the ammonia synthesis gas stream to a methanation unit or to a cryogenic unit for removal of carbon monoxide and carbon dioxide therefrom; whereby the efficiency of the overall purification operation and the effective utilization of hydrogen are enhanced.

Fuderer, A.

1986-02-25T23:59:59.000Z

328

Low-temperature catalyst activator: mechanism of dense carbon nanotube forest growth studied using synchrotron radiation  

Science Journals Connector (OSTI)

The mechanism of dense vertically aligned carbon nanotube growth achieved by a recently developed thermal chemical vapor deposition method was studied using synchrotron radiation spectroscopic techniques.

Takashima, A.

2014-05-22T23:59:59.000Z

329

Petrographic, Mineralogic, and Geochemical Studies of Hydrocarbon-derived Authigenic Carbonate Rock from Gas Venting, Seepage, Free Gas, and Gas Hydrate Sites in the Gulf of Mexico and offshore India  

E-Print Network [OSTI]

. ACR collected from the seafloor in the Gulf of Mexico (GOM) and ACR recovered from drilled cores in the Krishna-Godawari (KG) basin offshore India were used. All study sites are associated with hydrocarbon gas venting, seepage, free gas, or gas hydrate...

Jung, Woodong

2012-02-14T23:59:59.000Z

330

The Woodland Carbon Code  

E-Print Network [OSTI]

The Woodland Carbon Code While society must continue to make every effort to reduce greenhouse gas a role by removing carbon dioxide from the atmosphere. The potential of woodlands to soak up carbon to help compensate for their carbon emissions. But before investing in such projects, people want to know

331

Enhanced photocatalytic activity of nano titanium dioxide coated on ethanol-soluble carbon nanotubes  

SciTech Connect (OSTI)

Graphical abstract: Homogenous and dense spreading of TiO{sub 2} on surface modified CNTs and improved photocatalytic performance of TiO{sub 2} was achieved by coupling TiO{sub 2} with ethanol-soluble CNTs. Display Omitted Highlights: ? Ethanol-soluble CNTs were acquired by surface modification. ? Enhanced photoactivity of TiO{sub 2} coated on modified CNTs was obtained. ? Improved activity of TiO{sub 2} is attributed to the intimate contact between TiO{sub 2} and CNTs. ? Dense heterojunctions through Ti–O–CNTs at the interface is proposed. -- Abstract: Surface functionalized carbon nanotubes (CNTs) with ethanol solubility were synthesized and the CNTs–TiO{sub 2} nanocomposites were prepared by coupling of TiO{sub 2} with modified CNTs through a sol–gel method. The as-prepared CNTs and composites were characterized and the composite samples were evaluated for their photocatalytic activity toward the degradation of aqueous methyl orange. It is showed that the acid oxidation of CNTs leads to the embedding of oxygenated functional groups, and as a result, the acid-treated CNTs in turn may serve as chemical reactors for subsequent covalent grafting of octadecylamine. Improved photocatalytic performance of CNTs–TiO{sub 2} composites was obtained, which is mainly attributed to the high dispersion of TiO{sub 2} on ethanol-soluble CNTs and the intimate contact between TiO{sub 2} and CNTs resulted from the dense heterojunctions through the Ti-O-C structure at the interface between TiO{sub 2} and CNTs.

Fu, Xiaofei [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China)] [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China); Yang, Hanpei, E-mail: yanghanpei@hhu.edu.cn [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China)] [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China); He, Kuanyan; Zhang, Yingchao; Wu, Junming [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China)] [Key Laboratory of Integrated Regulation and Resource Development on Shallow Lakes, Ministry of Education, College of Environment, Hohai University, Nanjing 210098 (China)

2013-02-15T23:59:59.000Z

332

GALLIUM NITRIDE INTEGRATED GAS/TEMPERATURE SENSORS FOR FUEL CELL SYSTEM MONITORING FOR HYDROGEN AND CARBON MONOXIDE  

E-Print Network [OSTI]

on field effect devices using catalytic metal gates on silicon carbide substrates has been reviewed (Spetz-10%) of transition metals such as copper, silver, and chromium (Feinstein et al 1997 and Pyke 1993). High temperature. Introduction Gas sensing and analysis based on gas adsorption on a catalytic metal surface has been extensively

333

Chemical-Looping Gasification of Biomass for Hydrogen-Enriched Gas Production with In-Process Carbon Dioxide Capture  

Science Journals Connector (OSTI)

This may help to increase the carbon dioxide capture on one hand but, on other hand, also increases the size of the gasifier and regenerator and the heat requirement of the regenerator. ... Steam was used as the fluidizing medium. ...

Bishnu Acharya; Animesh Dutta; Prabir Basu

2009-09-03T23:59:59.000Z

334

Techno-economic analysis of sour gas oxy-fuel combustion power cycles for carbon capture and sequestration  

E-Print Network [OSTI]

The world's growing energy demand coupled with the problem of global warming have led us to investigate new energy sources that can be utilized in a way to reduce carbon dioxide emissions than traditional fossil fuel power ...

Chakroun, Nadim Walid

2014-01-01T23:59:59.000Z

335

Carbon Monoxide Safety Tips  

E-Print Network [OSTI]

Protect yourself and your family from the deadly effects of carbon monoxide--a colorless, odorless poisonous gas. This publication describes the warning signs of carbon monoxide exposure and includes a home safety checklist....

Shaw, Bryan W.; Garcia, Monica L.

1999-07-26T23:59:59.000Z

336

Table 2. 2011 State energy-related carbon dioxide emisssions...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

2011 State energy-related carbon dioxide emissions by fuel million metric tons of carbon dioxide shares State Coal Petroleum Natural Gas Total Coal Petroleum Natural Gas Alabama...

337

Letters to the editor / Carbon 40 (2002) 445467 447 using continuous carbon-fiber carbon-matrix and polymeruntreated fibers are used. The activation treatment does not  

E-Print Network [OSTI]

on the electrical additive is added to the electrochemically active species in resistivity of the MnO cathode-matrix and polymer­untreated fibers are used. The activation treatment does not matrix composites. Comp Part B: Eng X, Chung DDL. Submicron diameter nickel filaments[1] Chung DDL. Materials for electromagnetic

Chung, Deborah D.L.

338

Diversity and activity of methanotrophs in landfill cover soils with and without landfill gas recovery systems  

Science Journals Connector (OSTI)

Abstract Aerobic CH4 oxidation plays an important role in mitigating CH4 release from landfills to the atmosphere. Therefore, in this study, oxidation activity and community of methanotrophs were investigated in a subtropical landfill. Among the three sites investigated, the highest CH4 concentration was detected in the landfill cover soil of the site (A) without a landfill gas (LFG) recovery system, although the refuse in the site had been deposited for a longer time (?14–15 years) compared to the other two sites (?6–11 years) where a LFG recovery system was applied. In April and September, the higher CH4 flux was detected in site A with 72.4 and 51.7 g m?2 d?1, respectively, compared to the other sites. The abundance of methanotrophs assessed by quantification of pmoA varied with location and season. A linear relationship was observed between the abundance of methanotrophs and CH4 concentrations in the landfill cover soils (R = 0.827, P < 0.001). The key factors influencing the methanotrophic diversity in the landfill cover soils were pH, the water content and the CH4 concentration in the soil, of which pH was the most important factor. Type I methanotrophs, including Methylococcus, Methylosarcina, Methylomicrobium and Methylobacter, and type II methanotrophs (Methylocystis) were all detected in the landfill cover soils, with Methylocystis and Methylosarcina being the dominant genera. Methylocystis was abundant in the slightly acidic landfill cover soil, especially in September, and represented more than 89% of the total terminal-restriction fragment abundance. These findings indicated that the LFG recovery system, as well as physical and chemical parameters, affected the diversity and activity of methanotrophs in landfill cover soils.

Yao Su; Xuan Zhang; Fang-Fang Xia; Qi-Qi Zhang; Jiao-Yan Kong; Jing Wang; Ruo He

2014-01-01T23:59:59.000Z

339

Molecular gas and nuclear activity in early-type galaxies: any link with radio-loudness?  

E-Print Network [OSTI]

Aims. We want to study the amount of molecular gas in a sample of nearby early-type galaxies (ETGs) which host low-luminosity Active Galactic Nuclei (AGN). We look for possible differences between the radio-loud (RL) and radio-quiet (RQ) AGN. Methods. We observed the CO(1-0) and CO(2-1) spectral lines with the IRAM 30m and NRO 45m telescopes for eight galaxies. They belong to a large sample of 37 local ETGs which host both RQ and RL AGN. We gather data from the literature for the entire sample. Results. We report the new detection of CO(1-0) emission in four galaxies (UGC0968, UGC5617, UGC6946, and UGC8355) and CO(2-1) emission in two of them (UGC0968 and UGC5617). The CO(2-1)/CO(1-0) ratio in these sources is $\\sim0.7\\pm0.2$. Considering both the new observations and the literature, the detection rate of CO in our sample is 55 $\\pm$ 9%, with no statistically significant difference between the hosts of RL and RQ AGNs. For all the detected galaxies we converted the CO luminosities into the molecular masses, $M...

Baldi, Ranieri D; Capetti, Alessandro; Giovannini, Gabriele; Casasola, Viviana; Perez-Torres, Miguel A; Kuno, Nario

2014-01-01T23:59:59.000Z

340

Reversible Acid Gas Capture  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2009-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Reversible Acid Gas Capture  

ScienceCinema (OSTI)

Pacific Northwest National Laboratory scientist David Heldebrant demonstrates how a new process called reversible acid gas capture works to pull carbon dioxide out of power plant emissions.

Dave Heldebrant

2012-12-31T23:59:59.000Z

342

Large scale production of carbon nanotube arrays on the sphere surface from liquefied petroleum gas at low cost  

Science Journals Connector (OSTI)

Liquefied petroleum gas (LPG), a cheap industrial material, ... and good mobility, leading to the mass production of CNT arrays continuously. The arrays obtained ... easily be produced on large scale at low cost.

Qiang Zhang; JiaQi Huang; Fei Wei; GuangHui Xu; Yao Wang…

2007-11-01T23:59:59.000Z

343

Modeling polychlorinated biphenyl mass transfer after amendment of contaminated sediment with activated carbon  

SciTech Connect (OSTI)

The sorption kinetics and concentration of polychlorinated biphenyls (PCBs) in historically polluted sediment is modeled to assess a remediation strategy based on in situ PCB sequestration by mixing with activated carbon (AC). The authors extend their evaluation of a model based on intraparticle diffusion by including a biomimetic semipermeable membrane device (SPMD) and a first-order degradation rate for the aqueous phase. The model predictions are compared with the previously reported experimental PCB concentrations in the bulk water phase and in SPMDs. The simulated scenarios comprise a marine and a freshwater sediment, four PCB congeners, two AC grain sizes, four doses of AC, and comparison with laboratory experiments. The modeling approach distinguishes between two different sediment particles types: a light-density fraction representing carbonaceous particles such as charcoal, coal, coke, cenospheres, or wood, and a heavy-density fraction representing the mineral phase with coatings of organic matter. A third particle type in the numerical model is AC. The model qualitatively reproduces the observed shifts in the PCB distribution during repartitioning after AC amendment but overestimates the overall effect of the treatment in reducing aqueous and SPMD concentrations of PCBs by a factor of 2-6. For the AC application in sediment, competitive sorption of the various solutes apparently requires a reduction by a factor of 16 of the literature values for the AC-water partitioning coefficient measured in pure aqueous systems. With this correction, model results and measurements agree within a factor of 3. After AC amendment is homogeneously mixed into the sediment and then left undisturbed, aqueous PCB concentrations tend toward the same reduction after 5 years. 19 refs., 5 figs., 4 tabs.

David Werner; Upal Ghosh; Richard G. Luthy [University of Newcastle upon Tyne, Newcastle (United Kingdom)

2006-07-01T23:59:59.000Z

344

Modification of Y Zeolite with Alkaline Treatment: Textural Properties and Catalytic Activity for Diethyl Carbonate Synthesis  

Science Journals Connector (OSTI)

(1) Compared to dimethyl carbonate (DMC) and ethanol, DEC has been proposed as a potential fuel oxygenate additive to replace methyl tert-butyl ether (MTBE) because of its high oxygen content (40.6 wt %) and favorable fuel/water partition coefficient. ... For CuY using untreated zeolite as a support, there were only two H2-comsumption peaks at 473 and 681 K, ascribed to the Cu+ located on sites III? and II. ... Dunn, B. C.; Guenneau, C.; Hilton, S. A.; Pahnke, J.; Eyring, E. M.Production of diethyl carbonate from ethanol and carbon monoxide over a heterogeneous catalyst Energy Fuels 2002, 16, 177– 181 ...

Shouying Huang; Pengzhen Chen; Bing Yan; Shengping Wang; Yongli Shen; Xinbin Ma

2013-04-20T23:59:59.000Z

345

E-Print Network 3.0 - activated carbon hollow Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

titania Summary: : A general, one-step and template-free route to rattle-type hollow carbon spheres and their application... . Zhang: A simple template-free approach to TiO2...

346

Cryogenic treatment of gas  

DOE Patents [OSTI]

Systems and methods of treating a gas stream are described. A method of treating a gas stream includes cryogenically separating a first gas stream to form a second gas stream and a third stream. The third stream is cryogenically contacted with a carbon dioxide stream to form a fourth and fifth stream. A majority of the second gas stream includes methane and/or molecular hydrogen. A majority of the third stream includes one or more carbon oxides, hydrocarbons having a carbon number of at least 2, one or more sulfur compounds, or mixtures thereof. A majority of the fourth stream includes one or more of the carbon oxides and hydrocarbons having a carbon number of at least 2. A majority of the fifth stream includes hydrocarbons having a carbon number of at least 3 and one or more of the sulfur compounds.

Bravo, Jose Luis (Houston, TX); Harvey, III, Albert Destrehan (Kingwood, TX); Vinegar, Harold J. (Bellaire, TX)

2012-04-03T23:59:59.000Z

347

A statistical analysis of well production rates from UK oil and gas fields – Implications for carbon capture and storage  

Science Journals Connector (OSTI)

Abstract The number of wells required to dispose of global CO2 emissions by injection into geological formations is of interest as a key indicator of feasible deployment rate, scale and cost. Estimates have largely been driven by forecasts of sustainable injection rate from mathematical modelling of the CO2 injection process. Recorded fluid production rates from oil and gas fields can be considered an observable analogue in this respect. The article presents statistics concerning Cumulative average Bulk fluid Production (CBP) rates per well for 104 oil and gas fields from the UK offshore region. The term bulk fluid production is used here to describe the composite volume of oil, gas and water produced at reservoir conditions. Overall, the following key findings are asserted: (1) CBP statistics for UK offshore oil and gas fields are similar to those observed for CO2 injection projects worldwide. (2) 50% probability of non-exceedance (PNE) for CBP for oil and gas fields without water flood is around 0.35 Mt/yr/well of CO2 equivalent. (3) There is negligible correlation between reservoir transmissivity and CBP. (4) Study of net and gross CBP for water flood fields suggest a 50% PNE that brine co-production during CO2 injection could lead to a 20% reduction in the number of wells required.

Simon A. Mathias; Jon G. Gluyas; Eric J. Mackay; Ward H. Goldthorpe

2013-01-01T23:59:59.000Z

348

Thermocatalytic process for CO.sub.2-free production of hydrogen and carbon from hydrocarbons  

DOE Patents [OSTI]

A novel process and apparatus are disclosed for sustainable CO.sub.2-free production of hydrogen and carbon by thermocatalytic decomposition (dissociation, pyrolysis, cracking) of hydrocarbon fuels over carbon-based catalysts in the absence of air and/or water. The apparatus and thermocatalytic process improve the activity and stability of carbon catalysts during the thermocatalytic process and produce both high purity hydrogen (at least, 99.0 volume %) and carbon, from any hydrocarbon fuel, including sulfurous fuels. In a preferred embodiment, production of hydrogen and carbon is achieved by both internal and external activation of carbon catalysts. Internal activation of carbon catalyst is accomplished by recycling of hydrogen-depleted gas containing unsaturated and aromatic hydrocarbons back to the reactor. External activation of the catalyst can be achieved via surface gasification with hot combustion gases during catalyst heating. The process and apparatus can be conveniently integrated with any type of fuel cell to generate electricity.

Muradov, Nazim Z. (Melbourne, FL)

2011-08-23T23:59:59.000Z

349

ENHANCEMENT OF ADSORPTION CAPACITY BY USE OF PHASE CHANGE MATERIAL (PCM) AS ADDITIVE IN AN ACTIVATED CARBON (AC) FIXED BED ADSORBER  

Science Journals Connector (OSTI)

To avoid emission of volatile hydrocarbons from automotive tank systems, canisters filled with activated carbon (AC) are placed as a buffer to the environment. During the loading of the filter the heat of adsorpt...

W. ZIMMERMANN; J.U. KELLER

2006-01-01T23:59:59.000Z

350

Survey of state regulatory activities on least cost planning for gas utilities  

SciTech Connect (OSTI)

Integrated resource planning involves the creation of a process in which supply-side and demand-side options are integrated to create a resource mix that reliably satisfies customers' short-term and long-term energy service needs at the lowest cost. Incorporating the concept of meeting customer energy service needs entails a recognition that customers' costs must be considered along with the utility's costs in the economic analysis of energy options. As applied to gas utilities, an integrated resource plan seeks to balance cost and reliability, and should not be interpreted simply as the search for lowest commodity costs. All state commissions were surveyed to assess the current status of gas planning and demand-side management and to identify significant regulatory issues faced by commissions during the next several years. The survey was to determine the extent to which they have undertaken least-cost planning for gas utilities. The survey included the following topics: (1) status of state PUC least-cost planning regulations and practices for gas utilities; (2) type and scope ofnatural gas DSM programs in effect, includeing fuel substitution; (3) economic tests and analysis methods used to evaluate DSM programs; (4) relationship between prudence reviews of gas utility purchasing practices and integrated resource planning; and (5) key regulatory issues facing gas utilities during the next five years. 34 refs., 6 figs., 10 tabs.

Goldman, C.A. (Lawrence Berkeley Lab., CA (United States) National Association of Regulatory Utility Commissioners, Washington, DC (United States)); Hopkins, M.E. (Fleming Group, Washington, DC (United States))

1991-04-01T23:59:59.000Z

351

Carbon Dioxide Capture by Absorption with Potassium Carbonate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carbon Dioxide Capture by Absorption Carbon Dioxide Capture by Absorption with Potassium Carbonate Background Although alkanolamine solvents, such as monoethanolamine (MEA), and solvent blends have been developed as commercially-viable options for the absorption of carbon dioxide (CO 2 ) from waste gases, natural gas, and hydrogen streams, further process improvements are required to cost-effectively capture CO 2 from power plant flue gas. The promotion of potassium carbonate (K

352

The 1994 Sefidabeh (eastern Iran) earthquakes revisited: new evidence from satellite radar interferometry and carbonate dating about the growth of an active fold above a blind thrust fault  

Science Journals Connector (OSTI)

......in those places where active folds do not necessarily...was done using a cold cathode Technosyn instrument...structural development of active fault and fold systems...14C ages for carbonate materials from Lakes Lahontan and...Dinklage W.S., 1998. Active tectonics at Wheeler......

B. Parsons; T. Wright; P. Rowe; J. Andrews; J. Jackson; R. Walker; M. Khatib; M. Talebian; E. Bergman; E. R. Engdahl

2006-01-01T23:59:59.000Z

353

,"U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5560us2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5560us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:35 PM" "Back to Contents","Data 1: U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)" "Sourcekey","N5560US2" "Date","U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)" 34349,747322 34380,509144

354

,"U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly","9/2013" Monthly","9/2013" ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5550us2m.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5550us2m.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:34 PM" "Back to Contents","Data 1: U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)" "Sourcekey","N5550US2" "Date","U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)" 34349,770932

355

,"U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2012 Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5550us2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5550us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:34 PM" "Back to Contents","Data 1: U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)" "Sourcekey","N5550US2" "Date","U.S. Natural Gas Non-Salt Underground Storage Activity-Withdraw (MMcf)" 34515,2385284 34880,2774498

356

,"U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Annual",2012 Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","n5560us2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/n5560us2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov" ,,"(202) 586-8800",,,"12/12/2013 5:30:34 PM" "Back to Contents","Data 1: U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)" "Sourcekey","N5560US2" "Date","U.S. Natural Gas Non-Salt Underground Storage Activity-Net (MMcf)" 34515,-268751 34880,402800 35246,18357

357

Landfill Gas Fueled HCCI Demonstration System  

E-Print Network [OSTI]

Natural Gas Nitric Oxide/Nitrogen Dioxide Neal Road LandfillThe methane, nitrogen and carbon dioxide concentrations ofmethane, 30% nitrogen and 30% carbon dioxide. The recorded

Blizman, Brandon J.; Makel, Darby B.; Mack, John Hunter; Dibble, Robert W.

2006-01-01T23:59:59.000Z

358

CO2 gas exchange and phosphoenolpyruvate carboxylase activity in leaves of Zea mays L.  

Science Journals Connector (OSTI)

Important gas exchange characteristics of C4 plants depend on ... , the enzyme catalysing the primary fixation of CO2 during C4 photosynthesis. In this study, the relationship between intracellular resistance for...

Michael Pfeffer; Martin Peisker

1998-12-01T23:59:59.000Z

359

Fluoride enhances transfection activity of carbonate apatite by increasing cytoplasmic stability of plasmid DNA  

SciTech Connect (OSTI)

Highlights: {yields} Cytoplasmic stability of plasmid DNA is enhanced by fluoride incorporation into carbonate apatite carrier. {yields} Fluoridated carbonate apatite promotes a robust increase in transgene expression. {yields} Controlled dissolution of fluoridated carbonate apatite in endosomal acidic environment might buffer the endosomes and prevent degradation of the released DNA. -- Abstract: Intracellular delivery of a functional gene or a nucleic acid sequence to specifically knockdown a harmful gene is a potential approach to precisely treat a critical human disease. The intensive efforts in the last few decades led to the development of a number of viral and non-viral synthetic vectors. However, an ideal delivery tool in terms of the safety and efficacy has yet to be established. Recently, we have developed pH-sensing inorganic nanocrystals of carbonate apatite for efficient and cell-targeted delivery of gene and gene-silencing RNA. Here we show that addition of very low level of fluoride to the particle-forming medium facilitates a robust increase in transgene expression following post-incubation of the particles with HeLa cells. Confocal microscopic observation and Southern blotting prove the cytoplasmic existence of plasmid DNA delivered by likely formed fluoridated carbonate apatite particles while degradation of plasmid DNA presumably by cytoplasmic nucleases was noticed following delivery with apatite particles alone. The beneficial role of fluoride in enhancing carbonate apatite-mediated gene expression might be due to the buffering potential of generated fluoridated apatite in endosomal acidic environment, thereby increasing the half-life of delivered plasmid DNA.

Chowdhury, E.H., E-mail: md.ezharul.hoque@med.monash.edu.my [Jeffrey Cheah School of Medicine and Health Sciences, Monash University Sunway Campus, Jalan Lagoon Selatan, Bandar Sunway, Selangor Darul Ehsan (Malaysia)

2011-06-17T23:59:59.000Z

360

A large carbon sink in the woody biomass of Northern forests  

E-Print Network [OSTI]

A large carbon sink in the woody biomass of Northern forests R. B. Myneni* , J. Dong* , C. J fossil fuels and industrial activities. Some of the missing carbon is sequestered in vegetation biomass, industrialized nations can use certain forest biomass sinks to meet their green- house gas emissions reduction

Goldberg, Bennett

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Resources on Greenhouse Gas | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Program Areas » Greenhouse Gases » Resources on Greenhouse Gas Program Areas » Greenhouse Gases » Resources on Greenhouse Gas Resources on Greenhouse Gas October 7, 2013 - 2:30pm Addthis Many helpful resources about greenhouse gases (GHG) are available. Also see Contacts. GHG Reporting and Accounting Tools Annual GHG and Sustainability Data Report: Lists resources for reporting annual greenhouse gas activities. FedCenter Greenhouse Gas Inventory Reporting Website: Features additional information, training, and tools to assist agencies with completing comprehensive GHG inventory reporting requirements under Executive Order (E.O.) 13514. General Services Administration (GSA) Carbon Footprint and Green Procurement Tool: Voluntary tool developed by GSA to assist agencies in managing GHGs as required by E.O. 13514. Also see Greenhouse Gas Mitigation Planning Data and Tools.

362

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2005-01-01T23:59:59.000Z

363

ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION  

SciTech Connect (OSTI)

Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library are being sampled to collect CO{sub 2} adsorption isotherms. Sidewall core samples have been acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log has been acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 4.62 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 19 scf/ton in less organic-rich zones to more than 86 scf/ton in the Lower Huron Member of the shale. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

Brandon C. Nuttall

2004-08-01T23:59:59.000Z

364

Pore Size Analysis of Activated Carbons from Argon and Nitrogen Porosimetry Using Density Functional Theory  

E-Print Network [OSTI]

Form: December 28, 1999 We present isotherms calculated from density functional theory. A similar set of density functional theory isotherms, previously reported for nitrogen adsorption on carbon Functional Theory Robert J. Dombrowski, Daniel R. Hyduke, and Christian M. Lastoskie* Department of Chemical

Lastoskie, Christian M.

365

Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction  

Science Journals Connector (OSTI)

...Institute for the Development and Commercialization...ORR) at the cathode of fuel cells...carbon as an electrocatalyst for the four-electron...led to the development of new ORR electrocatalysts...Nanotechnology: Recent Developments in Chemistry...reduction at the cathode in a direct...poisoning the ORR electrocatalyst by CO-like...

Kuanping Gong; Feng Du; Zhenhai Xia; Michael Durstock; Liming Dai

2009-02-06T23:59:59.000Z

366

Heat Integration of the Water-Gas Shift Reaction System for Carbon Sequestration Ready IGCC Process with Chemical Looping  

SciTech Connect (OSTI)

Integrated gasification combined cycle (IGCC) technology has been considered as an important alternative for efficient power systems that can reduce fuel consumption and CO2 emissions. One of the technological schemes combines water-gas shift reaction and chemical-looping combustion as post gasification techniques in order to produce sequestration-ready CO2 and potentially reduce the size of the gas turbine. However, these schemes have not been energetically integrated and process synthesis techniques can be applied to obtain an optimal flowsheet. This work studies the heat exchange network synthesis (HENS) for the water-gas shift reaction train employing a set of alternative designs provided by Aspen energy analyzer (AEA) and combined in a process superstructure that was simulated in Aspen Plus (AP). This approach allows a rigorous evaluation of the alternative designs and their combinations avoiding all the AEA simplifications (linearized models of heat exchangers). A CAPE-OPEN compliant capability which makes use of a MINLP algorithm for sequential modular simulators was employed to obtain a heat exchange network that provided a cost of energy that was 27% lower than the base case. Highly influential parameters for the pos gasification technologies (i.e. CO/steam ratio, gasifier temperature and pressure) were calculated to obtain the minimum cost of energy while chemical looping parameters (oxidation and reduction temperature) were ensured to be satisfied.

Juan M. Salazara; Stephen E. Zitney; Urmila M. Diwekara

2010-01-01T23:59:59.000Z

367

NETL: The Carbon Sequestration Newsletter: July 2001  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

July 2001 July 2001 This newsletter is produced by the National Energy Technology Laboratory and presents summaries of significant events related to carbon sequestration that have taken place over the past month. TABLE OF CONTENTS Sequestration in the News Events / Announcements from NETL's Carbon Sequestration Program Publications Legislative Activity Related to Carbon Sequestration Sequestration in the News New York Times The June 17 edition of the New York Times contains an article on carbon sequestration in geologic formations, Strategy has a Greenhouse Gas Bottled Up Under Land and Sea. The article mentions President Bush's support of carbon sequestration technologies, the $15 million Southern Saskatchewan project in Weyburn oil fields, and the reactions from environmental groups. Go to the New York Times to find the article by entering "Weyburn" on the web site's search feature.

368

Kinetics Of Carbon Gasification  

Science Journals Connector (OSTI)

Kinetics Of Carbon Gasification ... The steam–carbon reaction, which is the essential reaction of the gasification processes of carbon-based feed stocks (e.g., coal and biomass), produces synthesis gas (H2 + CO), a synthetically flexible, environmentally benign energy source. ... Coal Gasification in CO2 and Steam:? Development of a Steam Injection Facility for High-Pressure Wire-Mesh Reactors ...

C. W. Zielke; Everett. Gorin

1957-03-01T23:59:59.000Z

369

Intro to Carbon Sequestration  

ScienceCinema (OSTI)

NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

None

2010-01-08T23:59:59.000Z

370

Estimation of point of zero charge for activated carbon treated with atmospheric pressure non-thermal oxygen plasmas  

Science Journals Connector (OSTI)

Commercial activated carbon was treated with a non-thermal oxygen plasma under atmospheric pressure using three types of reactors: a dielectric barrier discharge (DBD) parallel-plate reactor; an atmospheric pressure glow discharge plasma jet reactor and a DBD coaxial type reactor. The samples treated with the plasma were characterized by the pH value at the point of zero charge. An estimation of the adsorption properties of samples for copper ions in aqueous solution was also carried out in order to explain the effect of pH value on the adsorption results.

Satoshi Kodama; Hidetoshi Sekiguchi

2006-01-01T23:59:59.000Z

371

Natural Gas Monthly  

Reports and Publications (EIA)

Highlights activities, events, and analyses associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer related activities and underground storage data are also reported.

2014-01-01T23:59:59.000Z

372

Greenhouse gas emissions in biogas production systems  

E-Print Network [OSTI]

Augustin J et al. Automated gas chromatographic system forof the atmospheric trace gases methane, carbon dioxide, andfuel consumption and of greenhouse gas (GHG) emissions from

Dittert, Klaus; Senbayram, Mehmet; Wienforth, Babette; Kage, Henning; Muehling, Karl H

2009-01-01T23:59:59.000Z

373

Inversion versus Retention of Configuration for Nucleophilic Substitution at Vinylic Carbon  

E-Print Network [OSTI]

of Glukhovtsev, Pross, and Radom that the SN2 reaction of Cl- with unactivated vinyl chloride in the gas phase. However, moderately activated dihaloethylenes such as 1-chloro-1-fluoroethylene undergo gas-phase SN2. It is generally assumed that bimolecular SN2 nucleophilic substitution at saturated carbon (sp3) proceeds

Schlegel, H. Bernhard

374

Haverford Researchers Create Carbon Dioxide-Separating Polymer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Haverford College Haverford College Researchers Create Carbon Dioxide-Separating Polymer Haverford College Researchers Create Carbon Dioxide-Separating Polymer August 1, 2012 | Tags: Basic Energy Sciences (BES), Chemistry, Hopper Rebecca Raber, rraber@haverford.edu, +1 610 896 1038 gtoc.jpg Carbon dioxide gas separation is important for many environmental and energy applications. Molecular dynamics simulations are used to characterize a two-dimensional hydrocarbon polymer, PG-ES1, that uses a combination of surface adsorption and narrow pores to separate carbon dioxide from nitrogen, oxygen, and methane gases. Image by Joshua Schrier, Haverford College. Carbon dioxide is the primary greenhouse gas emitted through human activities, such as the combustion of fossil fuels for energy and

375

Activated carbon from grass -a green alternative catalyst support for water electrolysis Kalyani Palanichamy1,  

E-Print Network [OSTI]

cleanly producing water as the only product. Invariably it is stored in nature as water and hydrocarbons methods including water electrolysis, steam reformation of natural gas, and coal gasification are the foci of widespread production research; but water electrolysis is one of the renowned technologies which provide

Paris-Sud XI, Université de

376

Hydrogen storage in multilayer carbon nanotubes  

Science Journals Connector (OSTI)

Multilayer carbon nanotubes obtained by pyrolysis and mechanical activation of plant-derived amorphous carbon are excellent sorbents for hydrogen.

D. V. Onishchenko; V. P. Reva; V. G. Kuryavyi

2013-05-01T23:59:59.000Z

377

Magmatic Gas Composition Reveals the Source Depth of Slug-Driven Strombolian Explosive Activity  

Science Journals Connector (OSTI)

...hydrothermal meteoric steam during shallow...closed- to open-system conditions...entrainment of meteoric steam from the shallow hydrothermal system. (ii) The gas slugs...prevented quantitative assessment of the slug source...is a powerful tool in such studies...

Mike Burton; Patrick Allard; Filippo Muré; Alessandro La Spina

2007-07-13T23:59:59.000Z

378

Outer continental shelf oil and gas activities. Pacific update: August 1987 - November 1989  

SciTech Connect (OSTI)

This Pacific Update focuses on the geology and petroleum potential of the Central California and Washington-Oregon OCS Planning Areas. This report discusses the following topics: offshore oil and gas resources of the Pacific region; project-specific developments and status; and magnitude and timing of offshore developments. (CBS)

Slitor, Douglas L.; Wiese, Jeffrey D.; Karpas, Robert M.

1990-01-01T23:59:59.000Z

379

Resilience of gas-phase anharmonicity in the vibrational response of adsorbed carbon monoxide and breakdown under electrical conditions  

E-Print Network [OSTI]

In surface catalysis, the adsorption of carbon monoxide on transition-metal electrodes represents the prototype of strong chemisorption. Notwithstanding significant changes in the molecular orbitals of adsorbed CO, spectroscopic experiments highlight a close correlation between the adsorbate stretching frequency and equilibrium bond length for a wide range of adsorption geometries and substrate compositions. In this work, we study the origins of this correlation, commonly known as Badger's rule, by deconvoluting and examining contributions from the adsorption environment to the intramolecular potential using first-principles calculations. Noting that intramolecular anharmonicity is preserved upon CO chemisorption, we show that Badger's rule for adsorbed CO can be expressed solely in terms of the tabulated Herzberg spectroscopic constants of isolated CO. Moreover, although it had been previously established using finite-cluster models that Badger's rule is not affected by electrical conditions, we find here th...

Dabo, Ismaila

2012-01-01T23:59:59.000Z

380

Remarkable catalytic activity of cobalt tetraphenylporphyrin modified on a titania for the oxidation of carbon monoxide below room temperature  

SciTech Connect (OSTI)

CoTPP on TiO/sub 2/-120s modified at 250 /sup 0/C under vacuum catalytically oxidized carbon monoxide rapidly with oxygen even at -79/sup 0/C. Its catalytic activity was incomparably higher than that of commercial Hopcalite. Comparison of its catalytic performance with those of the same catalyst or different TiO/sub 2/ supporting catalyst both evacuated at 200 /sup 0/C revealed unique features of the present catalyst in terms of its oxygen adsorption, the poisoning of adsorbed oxygen, and the insolubility of the complex in benzene. Both significant structural modification of the complex and its strong interaction with properly dehydrated TiO/sub 2/-120s brought about by evacuation at 250 /sup 0/C may induce such extraordinary activity. 14 references, 4 figures, 5 tables.

Mochida, I.; Iwai, Y.; Kamo, T.; Fujitsu, H.

1985-12-05T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

The effect of water temperature on the adsorption equilibrium of dissolved organic matter and atrazine on granular activated carbon  

SciTech Connect (OSTI)

The influence of water temperature on the adsorption of natural dissolved organic matter (DOM) on activated carbon has not been investigated intensively yet. In this study, batch experiments with granular activated carbon (GAC) F300, from bituminous coal, have been carried out at three temperatures (5, 20, 35{sup o} C) using a humic acid model water and different types of surface water (lake, river, canal). Furthermore, the adsorption of an anthropogenic contaminant, atrazine, was quantified in the absence and presence of DOM. The results indicate a significant influence of water temperature on the adsorption equilibrium of DOM and atrazine. Contrary to expectations, DOM and atrazine adsorption in surface water tends to be increased with increasing water temperature, whereas the extent of this effect is dependent on the type and concentration of DOM. Furthermore, the temperature effect on atrazine adsorption is controlled by competition of DOM and atrazine on adsorption sites. Some assumptions are proposed and discussed for explaining the temperature effects observed in the batch studies. 39 refs., 4 figs., 2 tabs.

Bernd Schreiber; Viktor Schmalz; Thomas Brinkmann; Eckhard Worch [Dresden University of Technology, Dresden (Germany). Institute of Water Chemistry

2007-09-15T23:59:59.000Z

382

Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC: Part I. Physico-chemical and electronic interaction between Pt and carbon support, and activity enhancement of Pt/C catalyst  

Science Journals Connector (OSTI)

Carbon-supported platinum or platinum alloys are generally used as the cathodic electrocatalysts in polymer electrolyte membrane fuel cells (PEMFC) to enhance the oxygen reduction reaction (ORR). Main challenges to be addressed in this area are the high electrochemical activity and high stability maintenance for low-Pt-loading catalysts toward the feasibility for fuel cell operation and the reduction of the system cost. The interaction of Pt with carbon support, as well as the interaction of Pt precursor with carbon during the supported catalyst formation, are considered to be beneficial to the improvement of catalytic activity and durability of the electrocatalysts. This paper provides a review of recent advances related to the physico-chemical and electronic interactions at the catalyst–support interface and the catalyst activity enhancement through improved Pt–C interaction, especially focusing on the surface modification of the carbon support to form proper functional groups and chemical links at the Pt/C interface.

Xingwen Yu; Siyu Ye

2007-01-01T23:59:59.000Z

383

Thief carbon catalyst for oxidation of mercury in effluent stream  

DOE Patents [OSTI]

A catalyst for the oxidation of heavy metal contaminants, especially mercury (Hg), in an effluent stream is presented. The catalyst facilitates removal of mercury through the oxidation of elemental Hg into mercury (II) moieties. The active component of the catalyst is partially combusted coal, or "Thief" carbon, which can be pre-treated with a halogen. An untreated Thief carbon catalyst can be self-promoting in the presence of an effluent gas streams entrained with a halogen.

Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

2011-12-06T23:59:59.000Z

384

Gas inflows towards the nucleus of the active galaxy NGC7213  

E-Print Network [OSTI]

We present two-dimensional stellar and gaseous kinematics of the inner 0.8x1.1kpc^2 of the LINER/Seyfert 1 galaxy NGC7213, from optical spectra obtained with the GMOS integral field spectrograph on the Gemini South telescope at a spatial resolution of 60pc. The stellar kinematics shows an average velocity dispersion of 177km/s, circular rotation with a projected velocity amplitude of 50km/s and a kinematic major axis at a position angle of -4degrees (west of north). From the average velocity dispersion we estimate a black hole mass of M_BH=8_{-6}^{+16}x10^7 M_sun. The gas kinematics is dominated by non-circular motions, mainly along two spiral arms extending from the nucleus out to 4arcsec (280pc) to the NW and SE, that are cospatial with a nuclear dusty spiral seen in a structure map of the nuclear region of the galaxy. The projected gas velocities along the spiral arms show blueshifts in the far side and redshifts in the near side, with values of up to 200km/s. This kinematics can be interpreted as gas infl...

Schnorr-Müller, Allan; Nagar, Neil M; Ferrari, Fabricio

2014-01-01T23:59:59.000Z

385

Carbon dioxide storage professor Martin Blunt  

E-Print Network [OSTI]

Carbon dioxide storage professor Martin Blunt executive summary Carbon Capture and Storage (CCS) referS to the Set of technologies developed to capture carbon dioxide (Co2) gas from the exhausts of technologies developed to capture carbon dioxide (Co2) gas from the exhausts of power stations and from other

386

Energetics of Homogeneous Intermolecular Vinyl and Allyl Carbon-Hydrogen Bond Activation by the  

E-Print Network [OSTI]

of alkanes for both industrial and synthetic applications. While the goal of catalytic activation-H bonds,4 few have allowed for quantification of activated products crucial to the assessment of a C-H bond to a coordinatively unsaturated late-metal center (d8 Rh and Ir), generating a relatively

Jones, William D.

387

Carbon nanotubes for organic electronics.  

E-Print Network [OSTI]

??This thesis investigated the use of carbon nanotubes as active components in solution processible organic semiconductor devices. We investigated the use of functionalized carbon nanotubes… (more)

Goh, Roland Ghim Siong

2008-01-01T23:59:59.000Z

388

Well blowout rates and consequences in California Oil and Gas District 4 from 1991 to 2005: Implications for geological storage of carbon dioxide  

SciTech Connect (OSTI)

Well blowout rates in oil fields undergoing thermally enhanced recovery (via steam injection) in California Oil and Gas District 4 from 1991 to 2005 were on the order of 1 per 1,000 well construction operations, 1 per 10,000 active wells per year, and 1 per 100,000 shut-in/idle and plugged/abandoned wells per year. This allows some initial inferences about leakage of CO2 via wells, which is considered perhaps the greatest leakage risk for geological storage of CO2. During the study period, 9% of the oil produced in the United States was from District 4, and 59% of this production was via thermally enhanced recovery. There was only one possible blowout from an unknown or poorly located well, despite over a century of well drilling and production activities in the district. The blowout rate declined dramatically during the study period, most likely as a result of increasing experience, improved technology, and/or changes in safety culture. If so, this decline indicates the blowout rate in CO2-storage fields can be significantly minimized both initially and with increasing experience over time. Comparable studies should be conducted in other areas. These studies would be particularly valuable in regions with CO2-enhanced oil recovery (EOR) and natural gas storage.

Jordan, Preston; Jordan, Preston D.; Benson, Sally M.

2008-05-15T23:59:59.000Z

389

LABORATORY OPTIMIZATION TESTS OF TECHNETIUM DECONTAMINATION OF HANFORD WASTE TREATMENT PLANT LOW ACTIVITY WASTE OFF-GAS CONDENSATE SIMULANT  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in greatest abundance in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are low but are also expected to be in measurable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, {sup 241}Pu, and {sup 241}Am. These are present due to their partial volatility and some entrainment in the off-gas system. This report discusses results of optimized {sup 99}Tc decontamination testing of the simulant. Testing examined use of inorganic reducing agents for {sup 99}Tc. Testing focused on minimizing the quantity of sorbents/reactants added, and minimizing mixing time to reach the decontamination targets in this simulant formulation. Stannous chloride and ferrous sulfate were tested as reducing agents to determine the minimum needed to convert soluble pertechnetate to the insoluble technetium dioxide. The reducing agents were tried with and without sorbents.

Taylor-Pashow, K.; Nash, C.; McCabe, D.

2014-09-29T23:59:59.000Z

390

Greenhouse Gas Mitigation Options in ISEEM Global Energy Model: 2010-2050 Scenario Analysis for Least-Cost Carbon Reduction in Iron and Steel Sector  

E-Print Network [OSTI]

grows. EAF-DRI (Gas based) production cost continues toproduction costs from EAF-DRI (Gas based) and EAF productionCost of Steel from EAF-DRI (Gas based) Figure 11. Process Based Production

Karali, Nihan

2014-01-01T23:59:59.000Z

391

Well blowout rates and consequences in California Oil and Gas District 4 from 1991 to 2005: Implications for geological storage of carbon dioxide  

E-Print Network [OSTI]

pub/oil/ Data_Catalog/Oil_and_Gas/Oil_?elds/CA_oil?elds.DAT.1993) A history of oil- and gas-well blowouts in California,Health Administration (2007), Oil and gas well drilling and

Jordan, Preston D.

2008-01-01T23:59:59.000Z

392

On carbon footprints and growing energy use  

SciTech Connect (OSTI)

Could fractional reductions in the carbon footprint of a growing organization lead to a corresponding real reduction in atmospheric CO{sub 2} emissions in the next ten years? Curtis M. Oldenburg, head of the Geologic Carbon Sequestration Program of LBNL’s Earth Sciences Division, considers his own organization's carbon footprint and answers this critical question? In addressing the problem of energy-related greenhouse gas (GHG) emissions and climate change, it is essential that we understand which activities are producing GHGs and the scale of emission for each activity, so that reduction efforts can be efficiently targeted. The GHG emissions to the atmosphere of an individual or group are referred to as the ‘carbon footprint’. This terminology is entirely appropriate, because 85% of the global marketed energy supply comes from carbon-rich fossil fuel sources whose combustion produces CO{sub 2}, the main GHG causing global climate change. Furthermore, the direct relation between CO2 emissions and fossil fuels as they are used today makes energy consumption a useful proxy for carbon footprint. It would seem to be a simple matter to reduce energy consumption across the board, both individually and collectively, to help reduce our carbon footprints and therefore solve the energyclimate crisis. But just how much can we reduce carbon footprints when broader forces, such as growth in energy use, cause the total footprint to simultaneously expand? In this feature, I present a calculation of the carbon footprint of the Earth Sciences Division (ESD), the division in which I work at Lawrence Berkeley National Laboratory (LBNL), and discuss the potential for reducing this carbon footprint. It will be apparent that in terms of potential future carbon footprint reductions under projections of expected growth, ESD may be thought of as a microcosm of the situation of the world as a whole, in which alternatives to the business-as-usual use of fossil fuels are needed if absolute GHG emission reductions are to be achieved.

Oldenburg, C.M.

2011-06-01T23:59:59.000Z

393

NETL: Carbon Dioxide 101 FAQs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is carbon dioxide? is carbon dioxide? CO2 Dipole Carbon Dioxide Carbon dioxide (chemical name CO2) is a clear gas composed of one atom of carbon (C) and two atoms of oxygen (O). Carbon dioxide is one of many chemical forms of carbon on the Earth. It does not burn, and in standard temperature and pressure conditions it is stable, inert, and non-toxic. Carbon dioxide occurs naturally in small amounts (about 0.04%) in the Earth's atmosphere. The volume of CO2 in the atmosphere is equivalent to one individual in a crowd of 2,500. Carbon dioxide is produced naturally by processes deep within the Earth. This CO2 can be released at the surface by volcanoes or might be trapped in natural underground geologic CO2 deposits, similar to underground deposits of oil and natural gas. As a major greenhouse gas, CO2 helps create and

394

Preparation of water soluble carbon nanotubes and assessment of their biological activity in embryonic zebrafish  

Science Journals Connector (OSTI)

Carbon nanotubes (CNTs) are currently one of the most important classes of nanomaterials with unique properties sparking off numerous applications in many fields, including electronics, material science and medicine. However, applications of CNTs in medicine and other biological fields are hampered by their insolubility in aqueous media and concerns regarding toxicity. In this study, seven types of CNTs, including two single-walled, one double-walled, and four multi-walled, were evaluated for possible toxicological effects. Soluble CNTs were prepared by treatment with a mixture of acids (D2SO4 and DNO3), washed with Milli-Q water and oven dried. Transmission electron microscopy, thermal gravimetric analysis, and other techniques were used to characterise the prepared CNTs. CNT toxicity was assessed using the embryonic zebrafish. Results showed that none of the CNTs studied caused significant adverse developmental effects. These results support the potential safe use of CNTs as components of indwelling medical devices and drug delivery tools.

Adeniyi A. Adenuga; Lisa Truong; Robert L. Tanguay; Vincent T. Remcho

2013-01-01T23:59:59.000Z

395

Carbon Sequestration Atlas IV Video  

SciTech Connect (OSTI)

The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

Rodosta, Traci

2013-04-19T23:59:59.000Z

396

Gas chromatographic determination of polycyclic aromatic hydrocarbons in water and smoked rice samples after solid-phase microextraction using multiwalled carbon nanotube loaded hollow fiber  

Science Journals Connector (OSTI)

Abstract A novel solid-phase microextraction fiber was prepared based on multiwalled carbon nanotubes (MWCNTs) loaded on hollow fiber membrane pores. Stainless steel wire was used as unbreakable support. The major advantages of the proposed fiber are its (a) high reproducibility due to the uniform structure of the hollow fiber membranes, (b) high extraction capacity related to the porous structure of the hollow fiber and outstanding adsorptive characteristics of MWCNTs. The proposed fiber was applied for the microextraction of five representative polycyclic aromatic hydrocarbons (PAHs) from aqueous media (river and hubble–bubble water) and smoked rice samples followed by gas chromatographic determination. Analytical merits of the method, including high correlation coefficients [(0.9963–0.9992) and (0.9982–0.9999)] and low detection limits [(9.0–13.0 ng L?1) and (40.0–150.0 ng kg?1)] for water and rice samples, respectively, made the proposed method suitable for the ultra-trace determination of PAHs.

Amir Abbas Matin; Pourya Biparva; Mohammad Gheshlaghi

2014-01-01T23:59:59.000Z

397

Carbon Sequestration - Public Meeting  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Public Meeting Programmatic Environmental Impact Statement Public Meeting May 18, 2004 National Energy Technology Laboratory Office of Fossil Energy Scott Klara Carbon Sequestration Technology Manager Carbon Sequestration Program Overview * What is Carbon Sequestration * The Fossil Energy Situation * Greenhouse Gas Implications * Pathways to Greenhouse Gas Stabilization * Sequestration Program Overview * Program Requirements & Structure * Regional Partnerships * FutureGen * Sources of Information What is Carbon Sequestration? Capture can occur: * at the point of emission * when absorbed from air Storage locations include: * underground reservoirs * dissolved in deep oceans * converted to solid materials * trees, grasses, soils, or algae Capture and storage of CO 2 and other Greenhouse Gases that

398

Measurement of gas/water uptake coefficients for trace gases active in the marine environment. [Annual report  

SciTech Connect (OSTI)

Ocean produced reduced sulfur compounds including dimethylsulfide (DMS), hydrogen sulfide (H{sub 2}S), carbon disulfide (CS{sub 2}), methyl mercaptan (CH{sub 3}CH) and carbonyl sulfide (OCS) deliver a sulfur burden to the atmosphere which is roughly equal to sulfur oxides produced by fossil fuel combustion. These species and their oxidation products dimethyl sulfoxide (DMSO), dimethyl sulfone (DMSO{sub 2}) and methane sulfonic acid (MSA) dominate aerosol and CCN production in clean marine air. Furthermore, oxidation of reduced sulfur species will be strongly influenced by NO{sub x}/O{sub 3} chemistry in marine atmospheres. The multiphase chemical processes for these species must be understood in order to study the evolving role of combustion produced sulfur oxides over the oceans. We have measured the chemical and physical parameters affecting the uptake of reduced sulfur compounds, their oxidation products, ozone, and nitrogen oxides by the ocean`s surface, and marine clouds, fogs, and aerosols. These parameters include: gas/surface mass accommodation coefficients; physical and chemically modified (effective) Henry`s law constants; and surface and liquid phase reaction constants. These parameters are critical to understanding both the interaction of gaseous trace species with cloud and fog droplets and the deposition of trace gaseous species to dew covered, fresh water and marine surfaces.

Davidovits, P. [Boston Coll., Chestnut Hill, MA (United States). Dept. of Chemistry; Worsnop, D.W.; Zahniser, M.S.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States). Center for Chemical and Environmental Physics

1992-02-01T23:59:59.000Z

399

Dense gas-compatible enzymes  

DOE Patents [OSTI]

An enzymatic reaction system including a modified enzyme, and a dense gas system; modified enzymes; and methods of reacting modified enzymes in a dense gas system or liquid carbon dioxide.

Kao, Fu-jung (Dracut, MA); Laintz, Kenneth E. (Los Alamos, NM); Sawan, Samuel P. (Tyngsborough, MA); Sivils, L. Dale (Jupiter, FL); Spall, W. Dale (Los Alamos, NM)

1998-07-21T23:59:59.000Z

400

CARBON BED MERCURY EMISSIONS CONTROL FOR MIXED WASTE TREATMENT  

SciTech Connect (OSTI)

Mercury has had various uses in nuclear fuel reprocessing and other nuclear processes, and so is often present in radioactive and mixed (both radioactive and hazardous according tohe Resource Conservation and Recovery Act) wastes. Depending on regulatory requirements, the mercury in the off-gas must be controlled with sometimes very high efficiencies. Compliance to the Hazardous Waste Combustor (HWC) Maximum Achievable Control Technology (MACT) standards can require off-gas mercury removal efficiencies up to 99.999% for thermally treating some mixed waste streams. Several test programs have demonstrated this level of off-gas mercury control using fixed beds of granular sulfur-impregnated activated carbon. Other results of these tests include: (a) The depth of the mercury control mass transfer zone was less than 15-30 cm for the operating conditions of these tests, (b) MERSORB® carbon can sorb Hg up to 19 wt% of the carbon mass, and (c) the spent carbon retained almost all (98 – 99.99%) of the Hg; but when even a small fraction of the total Hg dissolves, the spent carbon can fail the TCLP test when the spent carbon contains high Hg concentrations. Localized areas in a carbon bed that become heated through heat of adsorption, to temperatures where oxidation occurs, are referred to as “bed hot spots.” Carbon bed hot spots must be avoided in processes that treat radioactive and mixed waste. Key to carbon bed hot spot mitigation are (a) designing for sufficient gas velocity, for avoiding gas flow maldistribution, and for sufficient but not excessive bed depth, (b) monitoring and control of inlet gas flowrate, temperature, and composition, (c) monitoring and control of in-bed and bed outlet gas temperatures, and (d) most important, monitoring of bed outlet CO concentrations. An increase of CO levels in the off-gas downstream of the carbon bed to levels about 50-100 ppm higher than the inlet CO concentration indicate CO formation in the bed, caused by carbon bed hot spots. Corrective actions must be implemented quickly if bed hot spots are detected, using a graded approach and sequence starting with corrective actions that are simple, quick, cause the least impact to the process, and are easiest to recover from. Multiple high and high-high alarm levels should be used, with appropriate corrective actions for each level.

Nick Soelberg; Joe Enneking

2010-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Investigating of electrons bunching in a Penning trap and accelerating process for CO2 gas mixture active medium  

E-Print Network [OSTI]

In the presence of an active medium incorporated in a Penning trap, the moving electrons can become bunched, as they get enough energy, they escape the trap forming an optical injector. These bunched electrons can enter next PASER section filled with the same active medium to be accelerated. In this paper, electron dynamics in the presence of gas mixture active medium incorporated in a penning trap is analyzed by developing an idealized 1D model. We further evaluate the energy exchange occurring as the train of electrons traversing the next PASER section. The results show that the oscillating electrons can be bunched at the resonant frequency of the active medium. The influence of the trapped time and the population inversion are analyzed, which shows that the longer the electrons are trapped, the more energy from the medium the accelerated electrons get, and with the increase of the population inversion, the decelerated electrons virtually unchanged but the accelerated electrons more than double their peak e...

Tian, Xiu-fang; Jia, Qika

2014-01-01T23:59:59.000Z

402

Modeling of UF{sub 6} enrichment with gas centrifuges for nuclear safeguards activities  

SciTech Connect (OSTI)

The physical modeling of uranium isotopes ({sup 235}U, {sup 238}U) separation process by centrifugation of is a key aspect for predicting the nuclear fuel enrichment plant performances under surveillance by the Nuclear Safeguards Authorities. In this paper are illustrated some aspects of the modeling of fast centrifuges for UF{sub 6} gas enrichment and of a typical cascade enrichment plant with the Theoretical Centrifuge and Cascade Simulator (TCCS). The background theory for reproducing the flow field characteristics of a centrifuge is derived from the work of Cohen where the separation parameters are calculated using the solution of a differential enrichment equation. In our case we chose to solve the hydrodynamic equations for the motion of a compressible fluid in a centrifugal field using the Berman - Olander vertical velocity radial distribution and the solution was obtained using the Matlab software tool. The importance of a correct estimation of the centrifuge separation parameters at different flow regimes, lies in the possibility to estimate in a reliable way the U enrichment plant performances, once the separation external parameters are set (feed flow rate and feed, product and tails assays). Using the separation parameters of a single centrifuge allow to determine the performances of an entire cascade and, for this purpose; the software Simulink was used. The outputs of the calculation are the concentrations (assays) and the flow rates of the enriched (product) and depleted (tails) gas mixture. These models represent a valid additional tool, in order to verify the compliance of the U enrichment plant operator declarations with the 'on site' inspectors' measurements.

Mercurio, G.; Peerani, P.; Richir, P.; Janssens, W.; Eklund, G. [European Commission, Joint Research Centre, Institute for Transuranium Elements Via Fermi, 2749-TP181,20127 Ispra (Italy)

2012-09-26T23:59:59.000Z

403

Investigations on emission characteristics of the pongamia biodiesel–diesel blend fuelled twin cylinder compression ignition direct injection engine using exhaust gas recirculation methodology and dimethyl carbonate as additive  

Science Journals Connector (OSTI)

Experiments were carried out on a twin cylinder direct injection compression ignition engine using pongamia biodiesel–diesel blend as fuel with exhaust gas recirculation (EGR) and dimethyl carbonate (DMC) as additive. The experimental results showed that pongamia biodiesel–diesel blend fuelled engine with EGR and DMC can simultaneously reduce smoke and nitric oxide ( NO x ) emission. The NO x emission was reduced by about 17.68% for 10% of EGR introduction and about 13.55% increase in smoke emission. When dimethyl carbonate was added with EGR the engine emits lower smoke with lesser NO x emission and it showed that the smoke reduction rate had a linear relationship with DMC percentage. The carbon monoxide (CO) and hydrocarbon (HC) emissions also decreased when DMC was added. However the addition of DMC with EGR caused an increase in both BSEC and BTE.

M. Pandian; S. P. Sivapirakasam; M. Udayakumar

2010-01-01T23:59:59.000Z

404

Cumulative Carbon and Just Allocation of the Global Carbon Commons  

E-Print Network [OSTI]

Cumulative Carbon and Just Allocation of the Global Carbon Commons R.T. Pierrehumbert1 on climate can be characterized by a single statistic, called Cumulative Carbon. This is the aggregate amount of carbon emitted in the form of carbon dioxide by activities such as fossil fuel burning and deforestation

Pierrehumbert, Raymond

405

Natural Gas | Open Energy Information  

Open Energy Info (EERE)

Gas Gas Jump to: navigation, search Click to return to AEO2011 page AEO2011 Data From AEO2011 report Full figure data for Figure 86. Reference Case Tables Table 1. Total Energy Supply, Disposition, and Price Summary Table 13. Natural Gas Supply, Disposition, and Prices Table 14. Oil and Gas Supply Table 21. Carbon Dioxide Emissions by Sector and Source - New England Table 22. Carbon Dioxide Emissions by Sector and Source- Middle Atlantic Table 23. Carbon Dioxide Emissions by Sector and Source - East North Central Table 24. Carbon Dioxide Emissions by Sector and Source - West North Central Table 25. Carbon Dioxide Emissions by Sector and Source - South Atlantic Table 26. Carbon Dioxide Emissions by Sector and Source - East South Central Table 27. Carbon Dioxide Emissions by Sector and Source - West South

406

EIA - Greenhouse Gas Emissions Overview  

Gasoline and Diesel Fuel Update (EIA)

Greenhouse Gas Tables (1990-2009) Greenhouse Gas Tables (1990-2009) Table Title Formats Overview 1 U.S. emissions of greenhouse gases, based on global warming potential 2 U.S. greenhouse gas intensity and related factors 3 Distribution of total U.S. greenhouse gas emissions by end-use sector 4 World energy-related carbon dioxide emissions by region 5 Greenhouse gases and 100-year net global warming potentials Carbon dioxide emissions 6 U.S. carbon dioxide emissions from energy and industry 7 U.S. energy-related carbon dioxide emissions by end-use sector 8 U.S. carbon dioxide emission from residential sector energy consumption 9 U.S. carbon dioxide emissions from commercial sector energy consumption 10 U.S. carbon dioxide emissions from industrial sector energy consumption

407

Carbon Capture (Carbon Cycle 2.0)  

ScienceCinema (OSTI)

Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

Smit, Berend

2011-06-08T23:59:59.000Z

408

Large Scale U.S. Unconventional Fuels Production and the Role of Carbon Dioxide Capture and Storage Technologies in Reducing Their Greenhouse Gas Emissions  

SciTech Connect (OSTI)

This paper examines the role that carbon dioxide capture and storage technologies could play in reducing greenhouse gas emissions if a significant unconventional fuels industry were to develop within the United States. Specifically, the paper examines the potential emergence of a large scale domestic unconventional fuels industry based on oil shale and coal-to-liquids (CTL) technologies. For both of these domestic heavy hydrocarbon resources, this paper models the growth of domestic production to a capacity of 3 MMB/d by 2050. For the oil shale production case, we model large scale deployment of an in-situ retorting process applied to the Eocene Green River formation of Colorado, Utah, and Wyoming where approximately 75% of the high grade oil shale resources within the United States lies. For the CTL case, we examine a more geographically dispersed coal-based unconventional fuel industry. This paper examines the performance of these industries under two hypothetical climate policies and concludes that even with the wide scale availability of cost effective carbon dioxide capture and storage technologies, these unconventional fuels production industries would be responsible for significant increases in CO2 emissions to the atmosphere. The oil shale production facilities required to produce 3MMB/d would result in net emissions to the atmosphere of between 3000-7000 MtCO2 in addition to storing potentially 1000 to 5000 MtCO2 in regional deep geologic formations in the period up to 2050. A similarly sized domestic CTL industry could result in 4000 to 5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000 to 22,000 MtCO2 stored in regional deep geologic formations over the same period up to 2050. Preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. However, additional analyses plus detailed regional and site characterization is needed, along with a closer examination of competing storage demands.

Dooley, James J.; Dahowski, Robert T.

2008-11-18T23:59:59.000Z

409

Carbon Capture and Storage  

Science Journals Connector (OSTI)

The main object of the carbon capture and storage (CCS) technologies is the...2...emissions produced in the combustion of fossil fuels such as coal, oil, or natural gas. CCS involves first the capture of the emit...

Ricardo Guerrero-Lemus; José Manuel Martínez-Duart

2013-01-01T23:59:59.000Z

410

Wetland (peat) Carbon Cycle  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Wetland (peat) Carbon Cycle Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2, but atmospheric concentrations of CH4 under future climate change are...

411

Pt/ZnO nanoarray nanogenerator as self-powered active gas sensor with linear ethanol sensing at room temperature  

Science Journals Connector (OSTI)

A self-powered gas sensor that can actively detect ethanol at room temperature has been realized from a Pt/ZnO nanoarray nanogenerator. Pt nanoparticles are uniformly distributed on the whole surface of ZnO nanowires. The piezoelectric output of Pt/ZnO nanoarrays can act not only as a power source, but also as a response signal to ethanol at room temperature. Upon exposure to dry air and 1500 ppm ethanol at room temperature, the piezoelectric output of the device under the same compressive strain is 0.672 and 0.419 V, respectively. Moreover, a linear dependence of the sensitivity on the ethanol concentration is observed. Such a linear ethanol sensing at room temperature can be attributed to the atmosphere-dependent variety of the screen effect on the piezoelectric output of ZnO nanowires, the catalytic properties of Pt nanoparticles, and the Schottky barriers at Pt/ZnO interfaces. The present results can stimulate research in the direction of designing new material systems for self-powered room-temperature gas sensing.

Yayu Zhao; Xuan Lai; Ping Deng; Yuxin Nie; Yan Zhang; Lili Xing; Xinyu Xue

2014-01-01T23:59:59.000Z

412

Lattice-gas model for active vesicle transport by molecular motors with opposite polarities  

E-Print Network [OSTI]

We introduce a multi-species lattice gas model for motor protein driven collective cargo transport on cellular filaments. We use this model to describe and analyze the collective motion of interacting vesicle cargoes being carried by oppositely directed molecular motors, moving on a single biofilament. Building on a totally asymmetric exclusion process (TASEP) to characterize the motion of the interacting cargoes, we allow for mass exchange with the environment, input and output at filament boundaries and focus on the role of interconversion rates and how they affect the directionality of the net cargo transport. We quantify the effect of the various different competing processes in terms of non-equilibrium phase diagrams. The interplay of interconversion rates, which allow for flux reversal and evaporation/deposition processes introduce qualitatively new features in the phase diagrams. We observe regimes of three-phase coexistence, the possibility of phase re-entrance and a significant flexibility in how the different phase boundaries shift in response to changes in control parameters. The moving steady state solutions of this model allows for different possibilities for the spatial distribution of cargo vesicles, ranging from homogeneous distribution of vesicles to polarized distributions, characterized by inhomogeneities or {\\it shocks}. Current reversals due to internal regulation emerge naturally within the framework of this model. We believe this minimal model will clarify the understanding of many features of collective vesicle transport, apart from serving as the basis for building more exact quantitative models for vesicle transport relevant to various {\\it in-vivo} situations.

Sudipto Muhuri; Ignacio Pagonabarraga

2010-09-09T23:59:59.000Z

413

In Situ Studies of the Active Sites for the Water Gas Shift Reaction over Cu-CeO2 Catalysts: Complex Interaction Between Metallic Copper and Oxygen Vacancies of Ceria  

SciTech Connect (OSTI)

New information about the active sites for the water gas shift (WGS) reaction over Cu-CeO{sub 2} systems was obtained using in-situ, time-resolved X-ray diffraction (TR-XRD), X-ray absorption spectroscopy (TR-XAS, Cu K and Ce L3 edges), and infrared spectroscopy (DRIFTS). Cu-CeO{sub 2} nanoparticles prepared by a novel reversed microemulsion method (doped Ce1-xCuxO2 sample) and an impregnation method (impregnated CuO{sub x}/CeO{sub 2} sample) were studied. The results from all of the samples indicate that both metallic copper and oxygen vacancies in ceria were involved in the generation of active sites for the WGS reaction. Evidence was found for a synergistic Cu-O vacancy interaction. This interaction enhances the chemical activity of Cu, and the presence of Cu facilitates the formation of O vacancies in ceria under reaction conditions. Water dissociation occurred on the O vacancy sites or the Cu-O vacancy interface. No significant amounts of formate were formed on the catalysts during the WGS reaction. The presence of strongly bound carbonates is an important factor for the deactivation of the catalysts at high temperatures. This work identifies for the first time the active sites for the WGS reaction on Cu-CeO{sub 2} catalysts and illustrates the importance of in situ structural studies for heterogeneous catalytic reactions.

Wang,X.; Rodriguez, J.; Hanson, J.; Gamarra, D.; Martinez-Arias, A.; Fernandez-Garcia, M.

2006-01-01T23:59:59.000Z

414

Improving the equilibrium performance of active carbons for separation processes by co-adsorption with low pressure solvent: application to carbon capture  

Science Journals Connector (OSTI)

The equilibrium performance of a novel gas separation process described quite recently (Sweatman in Chem. Eng. Sci. 65:3907, 2010...) called ‘pressure-swing wetting layer absorption’ here is investigated by means...

Martin B. Sweatman

2011-08-01T23:59:59.000Z

415

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Site of Myoglobin: Picosecond  

E-Print Network [OSTI]

J. Phys. Chem. 1994, 98, 11213-11219 11213 Vibrational Dynamics of Carbon Monoxide at the Active Physics Laboratory, Stanford University, Stanford, Califomia 94305 Received: April 27, 1994: In Final Form at Urbana-Champaign. Deparlment of Chemistry, Sfanford University. Hansen ExperimentaJ Physics Laboratory

Fayer, Michael D.

416

Fuel saving, carbon dioxide emission avoidance, and syngas production by tri-reforming of flue gases from coal- and gas-fired power stations, and by the carbothermic reduction of iron oxide  

Science Journals Connector (OSTI)

Flue gases from coal, gas, or oil-fired power stations, as well as from several heavy industries, such as the production of iron, lime and cement, are major anthropogenic sources of global CO2 emissions. The newly proposed process for syngas production based on the tri-reforming of such flue gases with natural gas could be an important route for CO2 emission avoidance. In addition, by combining the carbothermic reduction of iron oxide with the partial oxidation of the carbon source, an overall thermoneutral process can be designed for the co-production of iron and syngas rich in CO. Water-gas shift (WGS) of CO to H2 enables the production of useful syngas. The reaction process heat, or the conditions for thermoneutrality, are derived by thermochemical equilibrium calculations. The thermodynamic constraints are determined for the production of syngas suitable for methanol, hydrogen, or ammonia synthesis. The environmental and economic consequences are assessed for large-scale commercial production of these chemical commodities. Preliminary evaluations with natural gas, coke, or coal as carbon source indicate that such combined processes should be economically competitive, as well as promising significant fuel saving and CO2 emission avoidance. The production of ammonia in the above processes seems particularly attractive, as it consumes the nitrogen in the flue gases.

M. Halmann; A. Steinfeld

2006-01-01T23:59:59.000Z

417

Carbon formation and metal dusting in advanced coal gasification processes  

SciTech Connect (OSTI)

The product gases generated by coal gasification systems contain high concentrations of CO and, characteristically, have relatively high carbon activities. Accordingly, carbon deposition and metal dusting can potentially degrade the operation of such gasifier systems. Therefore, the product gas compositions of eight representative gasifier systems were examined with respect to the carbon activity of the gases at temperatures ranging from 480 to 1,090 C. Phase stability calculations indicated that Fe{sub 3}C is stable only under very limited thermodynamic conditions and with certain kinetic assumptions and that FeO and Fe{sub 0.877}S tend to form instead of the carbide. As formation of Fe{sub 3}C is a necessary step in the metal dusting of steels, there are numerous gasifier environments where this type of carbon-related degradation will not occur, particularly under conditions associated with higher oxygen and sulfur activities. These calculations also indicated that the removal of H{sub 2}S by a hot-gas cleanup system may have less effect on the formation of Fe{sub 3}C in air-blown gasifier environments, where the iron oxide phase can exist and is unaffected by the removal of sulfur, than in oxygen-blown systems, where iron sulfide provides the only potential barrier to Fe{sub 3}C formation. Use of carbon- and/or low-alloy steels dictates that the process gas composition be such that Fe{sub 3}C cannot form if the potential for metal dusting is to be eliminated. Alternatively, process modifications could include the reintroduction of hydrogen sulfide, cooling the gas to perhaps as low as 400 C and/or steam injection. If higher-alloy steels are used, a hydrogen sulfide-free gas may be processed without concern about carbon deposition and metal dusting.

DeVan, J.H.; Tortorelli, P.F.; Judkins, R.R.; Wright, I.G.

1997-02-01T23:59:59.000Z

418

Alternations of Structure and Functional Activity of Below Ground Microbial Communities at Elevated Atmospheric Carbon Dioxide  

SciTech Connect (OSTI)

The global atmospheric concentration of CO2 has increased by more than 30percent since the industrial revolution. Although the stimulating effects of elevated CO2 (eCO2) on plant growth and primary productivity have been well studied, its influences on belowground microbial communities are poorly understood and controversial. In this study, we showed a significant change in the structure and functional potential of soil microbial communities at eCO2 in a grassland ecosystem, the BioCON (Biodiversity, CO2 and Nitrogen) experimental site (http://www.biocon.umn.edu/) using a comprehensive functional gene array, GeoChip 3.0, which contains about 28,0000 probes and covers approximately 57,000 gene variants from 292 functional gene families involved in carbon, nitrogen, phosphorus and sulfur cycles as well as other functional processes. GeoChip data indicated that the functional structure of microbial communities was markedly different between ambient CO2 (aCO2) and eCO2 by detrended correspondence analysis (DCA) of all 5001 detected functional gene probes although no significant differences were detected in the overall microbial diversity. A further analysis of 1503 detected functional genes involved in C, N, P, and S cycles showed that a considerable portion (39percent) of them were only detected under either aCO2 (14percent) or eCO2 (25percent), indicating that the functional characteristics of the microbial community were significantly altered by eCO2. Also, for those shared genes (61percent) detected, some significantly (p<0.05) changed their abundance at eCO2. Especially, genes involved in labile C degradation, such as amyA, egl, and ara for starch, cellulose, and hemicelluloses, respectively, C fixation (e.g., rbcL, pcc/acc), N fixation (nifH), and phosphorus utilization (ppx) were significantly increased under eCO2, while those involved in decomposing recalcitrant C, such as glx, lip, and mnp for lignin degradation remained unchanged. This study provides insights into our understanding of belowground microbial communities and their feedbacks to terrestrial ecosystems at eCO2.

He, Zhili; Xu, Meiying; Deng, Ye; Kang, Sanghoon; Wu, Liyou; Van Nostrand, Joy D.; Hobbie, Sarah E.; Reich, Peter B.; Zhou, Jizhong

2010-05-17T23:59:59.000Z

419

Evaluation of Activated Carbon Adsorbents for CO2 Capture in Gasification  

Science Journals Connector (OSTI)

A linear relationship is also observed for the pore volume of the adsorbents (Figure 8b) when Vp and an estimation of the micropore volume (Vp ? Vmeso) of the adsorbents are plotted against the volume of adsorbed CO2 at 4.1 MPa. ... Modified HMS materials demonstrated to be reversibly adsorb substantially more CO2 than previously obsd. ... The anthracite with the highest CO2 adsorption capacity is the sample activated at 800 °C for 2 h, whose surface area was only 540 m2/g, and the adsorbed amt. of CO2 was 65.7 mg-CO2/g-adsorbent. ...

Trevor C. Drage; James M. Blackman; Cova Pevida; Colin E. Snape

2009-04-10T23:59:59.000Z

420

Proposed EPA Rules Will Cut Carbon Pollution While Maintaining...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

to choose from a broad set of low-carbon options (including natural gas, coal with carbon capture and sequestration, nuclear energy, renewable energy or energy efficiency)....

Note: This page contains sample records for the topic "active gas carbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Carbon Emissions: Chemicals Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Chemicals Industry Chemicals Industry Carbon Emissions in the Chemicals Industry The Industry at a Glance, 1994 (SIC Code: 28) Total Energy-Related Emissions: 78.3 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 21.1% -- Nonfuel Emissions: 12.0 MMTC Total First Use of Energy: 5,328 trillion Btu -- Pct. of All Manufacturers: 24.6% Energy Sources Used As Feedstocks: 2,297 trillion Btu -- LPG: 1,365 trillion Btu -- Natural Gas: 674 trillion Btu Carbon Intensity: 14.70 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 78.3 Natural Gas 32.1

422

Acidic gas capture by diamines  

DOE Patents [OSTI]

Compositions and methods related to the removal of acidic gas. In particular, the present disclosure relates to a composition and method for the removal of acidic gas from a gas mixture using a solvent comprising a diamine (e.g., piperazine) and carbon dioxide. One example of a method may involve a method for removing acidic gas comprising contacting a gas mixture having an acidic gas with a solvent, wherein the solvent comprises piperazine in an amount of from about 4 to about 20 moles/kg of water, and carbon dioxide in an amount of from about 0.3 to about 0.9 moles per mole of piperazine.

Rochelle, Gary (Austin, TX); Hilliard, Marcus (Missouri City, TX)

2011-05-10T23:59:59.000Z

423

A Guidebook for Low-Carbon Development at the Local Level  

E-Print Network [OSTI]

level. Percentage of landfill gas (methane) that is capturedenergy and reducing carbon emissions: landfill gas capture.Landfill gas is primarily methane; thus it can be captured

Zhou, Nan

2012-01-01T23:59:59.000Z

424

Dynamics of nitrogen and greenhouse gas emission under elevated carbon dioxide in semi-arid cropping systems in Australia and China.  

E-Print Network [OSTI]

??Within less than 50 years, atmospheric carbon dioxide concentration [CO2] will likely be double that observed in 1950. In this higher [CO2] world the sustainability… (more)

Lam, Shu Kee

2012-01-01T23:59:59.000Z

425

Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333  

SciTech Connect (OSTI)

The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

2014-01-07T23:59:59.000Z

426

Adsorption behavior of direct red 80 and congo red onto activated carbon/surfactant: Process optimization, kinetics and equilibrium  

Science Journals Connector (OSTI)

Abstract Adsorptions of congo red and direct red 80 onto activated carbon/surfactant from aqueous solution were optimized. The Box–Behnken design (BBD) has been employed to analyze the effects of concentration of surfactant, temperature, pH, and initial concentration of the dye in the adsorption capacity. Their corresponding experimental data could be evaluated excellently by second order polynomial regression models and the two models were also examined based on the analysis of variance and t test statistics, respectively. The optimum conditions were obtained as follows: Cs = 34.10 ?M, T = 50 °C, pH = 3.5, and CCR = 160 mg/L for the congo red system, and Cs = 34.10 ?M, T = 50 °C, pH = 6.1, and CDR80 = 110 mg/L for the direct red 80 system. And in these conditions, the measured experimental maximum adsorption capacities for the congo red and direct red 80 removals were 769.48 mg/g and 519.90 mg/g, which were consistent with their corresponding predicted values, with small relative errors of ?2.81% and ?0.67%, respectively. The adsorption equilibrium and kinetics for the two dye adsorptions onto AC/DDAC were also investigated. The experimental data were fitted by four isotherm models, and Langmuir model presented the best fit. The kinetic studies indicated that the kinetic data followed the pseudo-second-order model.

Zhengjun Cheng; Lei Zhang; Xiao Guo; Xiaohui Jiang; Tian Li

2015-01-01T23:59:59.000Z

427

IEP - Carbon Dioxide: Regulatory Drivers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IEP - Carbon Dioxide (CO2) Regulatory Drivers In July 7, 2009 testimony before the U.S. Senate Committee on Environment and Public Works, Secretary of Energy Steven Chu made the following statements:1 "...Overwhelming scientific evidence shows that carbon dioxide from human activity has increased the atmospheric level of CO2 by roughly 40 percent, a level one- third higher than any time in the last 800,000 years. There is also a consensus that CO2 and other greenhouse gas emissions have caused our planet to change. Already, we have seen the loss of about half of the summer arctic polar ice cap since the 1950s, a dramatically accelerating rise in sea level, and the loss of over two thousand cubic miles of glacial ice, not on geological time scales but over a mere hundred years.

428

Laboratory Scoping Tests Of Decontamination Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant  

SciTech Connect (OSTI)

The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream (LAW Off-Gas Condensate) from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of glass waste. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to acceptable concentrations in the LAW glass, and diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task seeks to examine the potential treatment of this stream to remove radionuclides and subsequently disposition the decontaminated stream elsewhere, such as the Effluent Treatment Facility (ETF), for example. The treatment process envisioned is very similar to that used for the Actinide Removal Process (ARP) that has been operating for years at the Savannah River Site (SRS), and focuses on using mature radionuclide removal technologies that are also compatible with longterm tank storage and immobilization methods. For this new application, testing is needed to demonstrate acceptable treatment sorbents and precipitating agents and measure decontamination factors for additional radionuclides in this unique waste stream. The origin of this LAW Off-Gas Condensate stream will be the liquids from the Submerged Bed Scrubber (SBS) and the Wet Electrostatic Precipitator (WESP) from the LAW melter off-gas system. The stream is expected to be a dilute salt solution with near neutral pH, and will likely contain some insoluble solids from melter carryover. The soluble components are expected to be mostly sodium and ammonium salts of nitrate, chloride, and fluoride. This stream has not been generated yet and will not be available until the WTP begins operation, but a simulant has been produced based on models, calculations, and comparison with pilot-scale tests. One of the radionuclides that is volatile and expected to be in high concentration in this LAW Off-Gas Condensate stream is Technetium-99 ({sup 99}Tc). Technetium will not be removed from the aqueous waste in the Hanford WTP, and will primarily end up immobilized in the LAW glass by repeated recycle of the off-gas condensate into the LAW melter. Other radionuclides that are also expected to be in appreciable concentration in the LAW Off-Gas Condensate are {sup 129}I, {sup 90}Sr, {sup 137}Cs, and {sup 241}Am. This report discusses results of preliminary radionuclide decontamination testing of the simulant. Testing examined use of Monosodium Titanate (MST) to remove {sup 90}Sr and actinides, inorganic reducing agents for {sup 99}Tc, and zeolites for {sup 137}Cs. Test results indicate that excellent removal of {sup 99}Tc was achieved using Sn(II)Cl{sub 2} as a reductant, coupled with sorption onto hydroxyapatite, even in the presence of air and at room temperature. This process was very effective at neutral pH, with a Decontamination Factor (DF) >577 in two hours. It was less effective at alkaline pH. Conversely, removal of the cesium was more effective at alka

Taylor-Pashow, Kathryn M.; Nash, Charles A.; Crawford, Charles L.; McCabe, Daniel J.; Wilmarth, William R.

2014-01-21T23:59:59.000Z

429

REMEDIAT1NG AT MANUFACTURED GAS  

E-Print Network [OSTI]

, comhusti- hle gas manufactured Pfrom coke, coal, and oil 1 served as the major gas- eous fuel for urban for the three primary gas production meth- ods: coal carbonization, carbureted water gas production, and oil gas, and metals. Tar resid- uals were produced from the vola- tiIe component of bituminous coals in coal

Peters, Catherine A.

430

E-Print Network 3.0 - alcohol gas additives Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

alcohol. In addition, you will not want to use... , methyl gas, hydrogen, carbon dioxide, carbon monoxide, wood alcohol, carbon, water, and a lot of other... if gas storage tanks...

431

Carbon 40 (2002) 445467 Letters to the editor  

E-Print Network [OSTI]

Carbon 40 (2002) 445­467 Letters to the editor Increasing the electromagnetic interference; Activated carbon; Carbon fibers; D. Electrical (electronic) properties Electromagnetic interference (EMI

Chung, Deborah D.L.

432

Carbon Sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

andrea Mcnemar andrea Mcnemar National Energy Technology Laboratory 3610 Collins Ferry Road P.O. Box 880 Morgantown, WV 26507-0880 304-285-2024 andrea.mcnemar@netl.doe.gov Gregory J. Elbring Principal Investigator Sandia National Laboratory P.O. Box 5800 Albuquerque, NM 87185 505-844-4904 gjelbri@sandia.gov GeoloGic SequeStration of carbon DioxiDe in a DepleteD oil reServoir: a comprehenSive moDelinG anD Site monitorinG project Background The use of carbon dioxide (CO 2 ) to enhance oil recovery (EOR) is a familiar and frequently used technique in the United States. The oil and gas industry has significant experience with well drilling and injecting CO 2 into oil-bearing formations to enhance production. While using similar techniques as in oil production, this sequestration field

433

Carbon Sequestration 101  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Perspectives on Carbon Capture and Storage Perspectives on Carbon Capture and Storage - Directions, Challenges, and Opportunities Thomas J. Feeley, III National Energy Technology Laboratory Carbon Capture and Storage November 13-15, 2007 Austin, Texas C Capture & Storage, Austin, TX Nov. 13-15, 2007 U.S. Fossil Fuel Reserves / Production Ratio 250+ Year Supply at Current Demand Levels ! 258 11.7 9.7 0 100 200 300 Coal Oil Natural Gas Anthracite & Bituminous Sub- Bituminous & Lignite Sources: BP Statistical Review, June 2004, - for coal reserves data - World Energy Council; EIA, Advance Summary U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Reserves, 2003 Annual Report, September 22, 2004 - for oil and gas reserves data. C Capture & Storage, Austin, TX Nov. 13-15, 2007 80 120 160 200 240 1970 1975 1980

434

The Greenness of Cities: Carbon Dioxide Emissions and Urban Development  

E-Print Network [OSTI]

carbon dioxide emissions per 1,000 cubic feet of natural gas. In this case, there is much less energy

Glaeser, Edward L.; Kahn, Matthew E.

2008-01-01T23:59:59.000Z

435

Oil and Gas Exploration  

E-Print Network [OSTI]

Metals Industrial Minerals Oil and Gas Geothermal Exploration Development Mining Processing Nevada, oil and gas, and geothermal activities and accomplishments in Nevada: production statistics, exploration and development including drilling for petroleum and geothermal resources, discoveries of ore

Tingley, Joseph V.

436

Some observations on the kinetics of the hydrogenation of carbon monoxide  

SciTech Connect (OSTI)

For the hydrogenation of CO a positive order of hydrogen and a slightly negative or a zero order in carbon monoxide are generally reported. The negative (or zero) order in carbon monoxide is often explained by assuming a strong adsorption of carbon monoxide on the same sites as used by the hydrogen. It is then assumed that the surface is ''almost totally'' covered by carbon monoxide. From experiments in which the surface products on an unsupported cobalt catalyst after the reaction were stripped off by a hydrogen treatment it was concluded that more than 95% of the surface (as determined from the adsorption of carbon monoxide at room temperature) was covered by carbon-containing species. This paper illustrates that ''zero order in carbon monoxide'' can be obtained with much lower coverage of carbon-containing species in equilibrium with gas-phase carbon monoxide than indicated above. Equations for reaction rates are presented, and data is calculated on the fraction of the catalyst surface covered by active carbon-containing species when the reaction is zero order in CO. The results suggest that only a small fraction of the catalyst surface is actively engaged in the hydrogenation of CO. This further suggests that the low turnover frequencies found for the Fischer-Tropsch synthesis could be caused by a small number of sites which are active in the rate-determining step. (MWF)

Rautavuoma, A.O.I.; van der Baan, H.S.

1981-10-01T23:59:59.000Z

437

Chapter 10 - Natural Gas Sweetening  

Science Journals Connector (OSTI)

Abstract Acid gas constituents present in most natural gas streams are mainly hydrogen sulfide (H2S) and carbon dioxide (CO2). Many gas streams, however, particularly those in a refinery or manufactured gases, may contain mercaptans, carbon sulfide, or carbonyl sulfide. The level of acid gas concentration in the sour gas is an important consideration for selecting the proper sweetening process. Some processes are applicable for removal of large quantities of acid gas, and other processes have the capacity for removing acid gas constituents to ppm range. This chapter covers the minimum process requirements, criteria, and features for accomplishment of process design of gas sweetening units. The basic principles for process design of main equipment, piping, and instrumentation together with guidelines on present developments and process selection in the gas sweetening process are the main objectives throughout this chapter.

Alireza Bahadori

2014-01-01T23:59:59.000Z

438

POWDERED ACTIVATED CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION FOR DISINFECTION BY-PRODUCT CONTROL IN WATER TREATMENT PLANTS  

SciTech Connect (OSTI)

New federal drinking water regulations have been promulgated to restrict the levels of disinfection by-products (DBPs) in finished public water supplies. DBPs are suspected carcinogens and are formed when organic material is partially oxidized by disinfectants commonly used in the water treatment industry. Additional federal mandates are expected in the near future that will further affect public water suppliers with respect to DBPs. Powdered activated carbon (PAC) has traditionally been used by the water treatment industry for the removal of compounds contributing to taste and odor problems. PAC also has the potential to remove naturally occurring organic matter (NOM) from raw waters prior to disinfection, thus controlling the formation of regulated DBPs. Many small water systems are currently using PAC for taste and odor control and have the potential to use PAC for controlling DBPs. This project, a cooperative effort between the Energy & Environmental Research Center (EERC), the Grand Forks Water Treatment Plant, and the University of North Dakota Department of Civil Engineering, consists of several interrelated tasks. The objective of the research was to evaluate a cost-effective PAC produced from North Dakota lignite for removing NOM from water and reducing trihalomethane formation potential. The research approach was to develop a statistically valid testing protocol that can be used to compare dose-response relationships between North Dakota lignite-derived PAC and commercially available PAC products. A statistical analysis was performed to determine whether significant correlations exist between operating conditions, water properties, PAC properties, and dose-response behavior. Pertinent physical and chemical properties were also measured for each of the waters and each of the PACs.

Daniel J. Stepan; Thomas A. Moe; Melanie D. Hetland; Margaret L. Laumb

2001-06-01T23:59:59.000Z

439

Carbon Sequestration and the Restoration of Land Health  

Science Journals Connector (OSTI)

Carbon sequestration, the conversion of greenhouse gas CO2...toorganic matter, offers a powerful tool with which to combat climate change. The enlargement of carbon sinks stored in soil and biota is...2. Carbon sequestration

Andres Arnalds

2004-08-01T23:59:59.000Z

440

Discussion by Matthew J. Kotchen (Yale University and NBER) of "Carbon Prices and Automobile Greenhouse Gas Emissions: The Extensive and Intensive Margins," by  

E-Print Network [OSTI]

1 Discussion by Matthew J. Kotchen (Yale University and NBER) of "Carbon Prices and Automobile about automobile use. In particular, KS consider how the price of gasoline affects decisions about when

Kotchen, Matthew J.

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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

High-temperature gasification of carbon-containing raw materials with the use of electric-arc energy and calorific capacity of the gas fuel  

Science Journals Connector (OSTI)

Disposal of carbon-containing wastes in a plasma furnace is studied. The influence of the plasma generator power on gasifier efficiency is found for different waste humidities; dependences of specific energy c...

A. V. Pinaev; V. A. Faleev; A. E. Urbakh

2011-03-01T23:59:59.000Z

442

Synthesis, Activity and Durability of Pt Nanoparticles Supported on Multi-walled Carbon Nanotubes for Oxygen Reduction  

E-Print Network [OSTI]

Carbon nanotube supported metal nanoparticles (NPs) have attracted considerable attention due to their great potential for heterogeneous catalysis. In this paper, surfactant-free and well dispersed platinum (Pt) NPs supported ...

Massachusetts Institute of Technology. Department of Chemistry; Massachusetts Institute of Technology. Department of Mechanical Engineering; Massachusetts Institute of Technology. Department of Materials Science and Engineering; Sheng, Wenchao; Lee, Seung Woo; Crumlin, Ethan J.; Chen, Shuo; Shao-Horn, Yang

443

Investigation into the Mechanism of Interaction of Calcium and Magnesium Silicates with Carbon Dioxide in the Course of Mechanical Activation  

Science Journals Connector (OSTI)

A prolonged grinding of diopside, akermanite, sphene, wollastonite, and enstatite is accompanied...2 from the environment (carbonation) along with amorphization and hydration. The IR spectra of ground minerals co...

A. M. Kalinkin; V. V. Boldyrev; A. A. Politov…

2003-07-01T23:59:59.000Z

444

Synthesis and Oxygen Reduction Reaction Activity of Atomic and Nanoparticle Gold on Thiol-Functionalized Multiwall Carbon Nanotubes  

E-Print Network [OSTI]

We demonstrated the self-assembly of atomic Au on thiol-functionalized multiwall carbon nanotubes through covalent bonding and the formation of Au nanoparticles (NPs) upon a subsequent thermal treatment. Au NPs of 3.4 nm ...

Kim, Junhyung

445

Sulfur tolerant molten carbonate fuel cell anode and process  

DOE Patents [OSTI]

Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

Remick, Robert J. (Naperville, IL)

1990-01-01T23:59:59.000Z

446

Investigation and Demonstration of Dry Carbon-Based Sorbent Injection for Mercury Control  

SciTech Connect (OSTI)

Public Service Company of Colorado and ADA Technologies, Inc. have performed a study of the injection of activated carbon for the removal of vapor-phase mercury from coal-fired flue gas streams. The project was completed under contract to the US Department of Energy's National Energy Technology Laboratory, with contributions from EPRI and Public Service Company. The prime contractor for the project was Public Service Company, with ADA Technologies as the major subcontractor providing technical support to all aspects of the project. The research and development effort was conducted in two phases. In Phase I a pilot facility was fabricated and tests were performed using dry carbon-based sorbent injection for mercury control on a coal-fired flue gas slipstream extracted from an operating power plant. Phase II was designed to move carbon injection technology towards commercial application on coal-fired power plants by addressing key reliability and operability concerns. Phase II field work included further development work with the Phase I pilot and mercury measurements on several of PSCo's coal-fired generating units. In addition, tests were run on collected sorbent plus fly ash to evaluate the impact of the activated carbon sorbent on the disposal of fly ash. An economic analysis was performed where pilot plant test data was used to develop a model to predict estimated costs of mercury removal from plants burning western coals. Testing in the pilot plant was undertaken to quantify the effects of plant configuration, flue gas temperature, and activated carbon injection rate on mercury removal. All three variables were found to significantly impact the mercury removal efficiency in the pilot. The trends were clear: mercury removal rates increased with decreasing flue gas temperature and with increasing carbon injection rates. Mercury removal was much more efficient with reverse-gas and pulse-jet baghouse configurations than with an ESP as the particulate control device. The native fly ash of the host unit provided significant mercury removal capacity, so that the activated carbon sorbent served as an incremental mercury removal mechanism. Tests run to characterize the waste product, a combination of fly ash and activated carbon on which mercury was present, showed that mercury and other RCRA metals of interest were all below Toxic Characteristic Leaching Procedure (TCLP) regulatory limits in the leachate. The presence of activated carbon in the fly ash was shown to have an effect on the use of fly ash as an additive in the manufacture of concrete, which could limit the salability of fly ash from a plant where activated carbon was used for mercury control.

Jim Butz; Terry Hunt

2005-11-01T23:59:59.000Z

447

Membrane-based systems for carbon capture and hydrogen purification  

SciTech Connect (OSTI)

This presentation describes the activities being conducted at Los Alamos National Laboratory to develop carbon capture technologies for power systems. This work is aimed at continued development and demonstration of a membrane based pre- and post-combustion carbon capture technology and separation schemes. Our primary work entails the development and demonstration of an innovative membrane technology for pre-combustion capture of carbon dioxide that operates over a broad range of conditions relevant to the power industry while meeting the US DOE's Carbon Sequestration Program goals of 90% CO{sub 2} capture at less than a 10% increase in the cost of energy services. Separating and capturing carbon dioxide from mixed gas streams is a first and critical step in carbon sequestration. To be technically and economically viable, a successful separation method must be applicable to industrially relevant gas streams at realistic temperatures and pressures as well as be compatible with large gas volumes. Our project team is developing polymer membranes based on polybenzimidazole (PBI) chemistries that can purify hydrogen and capture CO{sub 2} at industrially relevant temperatures. Our primary objectives are to develop and demonstrate polymer-based membrane chemistries, structures, deployment platforms, and sealing technologies that achieve the critical combination of high selectivity, high permeability, chemical stability, and mechanical stability all at elevated temperatures (> 150 C) and packaged in a scalable, economically viable, high area density system amenable to incorporation into an advanced Integrated Gasification Combined-Cycle (IGCC) plant for pre-combustion CO{sub 2} capture. Stability requirements are focused on tolerance to the primary synthesis gas components and impurities at various locations in the IGCC process. Since the process stream compositions and conditions (temperature and pressure) vary throughout the IGCC process, the project is focused on the optimization of a technology that could be positioned upstream or downstream of one or more of the water-gas-shift reactors (WGSRs) or integrated with a WGSR.

Berchtold, Kathryn A [Los Alamos National Laboratory

2010-11-24T23:59:59.000Z

448

Gas separation process  

SciTech Connect (OSTI)

The method for production of high purity hydrogen and high purity carbon monoxide from a mixed gas stream comprising these components together with carbon dioxide and a zero to a minor amount of one or more other gaseous contaminants is described comprising the steps of: (a) passing the mixed gas stream into and through a first bed of solid adsorbent capable of selectively adsorbing carbon dioxide and water while discharging from the bed a dry CO/sub 2/-freed effluent; (b) introducing the dry CO/sub 2/-freed effluent into a cryogenic environment for cooling the same therein under conditions effective for condensation of at least the major part of the carbon monoxide present in the dry CO/sub 2/-freed effluent; (c) withdrawing from the cryogenic environment carbon monoxide of high purity; (d) separately withdrawing from the cryogenic environment an uncondensed first gas stream product comprised of crude hydrogen and subjecting the first gas stream product to selective adsorption of non-hydrogen components therefrom in a second bed of solid absorbent, while recovering from the second bed the non-sorbed fraction as a product stream of essentially pure hydrogen; (e) purging the second solid adsorbent bed to desorb non-hydrogen components sorbed therein in step (d), and withdrawing from the bed a gas stream comprising the desorbed non-hydrogen components.

Nicholas, D.M.; Hopkins, J.A.; Roden, T.M.; Bushinsky, J.P.

1988-03-22T23:59:59.000Z

449

Carbon Emissions: Food Industry  

U.S. Energy Information Administration (EIA) Indexed Site

Food Industry Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct. of All Manufacturers: 6.6% Total First Use of Energy: 1,193 trillion Btu -- Pct. of All Manufacturers: 5.5% Carbon Intensity: 20.44 MMTC per quadrillion Btu Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998 Energy-Related Carbon Emissions, 1994 Source of Carbon Carbon Emissions (million metric tons) All Energy Sources 24.4 Net Electricity 9.8 Natural Gas 9.1 Coal 4.2 All Other Sources 1.3 Energy Information Administration, "1994 Manufacturing Energy Consumption Survey" and Emissions of Greenhouse Gases in the United States 1998

450

ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2003.04.02 - 2003.09.02 Lead Scientist : Marc Fischer For data sets, see below. Description Ecosystem-atmosphere exchange of carbon, water, and energy varies with climate, soil, and land management, in ways 1) that influence the CO2 flux and planetary boundary layer CO2 concentration in ARM CART and 2) that we can model and predict. This activity repeated portable flux system measurements that we performed in spring 2002, by continuing measurements of the spatial heterogeneity of carbon, water, and energy fluxes in fields surrounding the ARM SGP Central Facility (CF).

451

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite  

E-Print Network [OSTI]

CARBON-CARBON COMPOSITE ALLCOMP Carbon-Carbon Composite · C-C supplied in two forms · T300: C-C composite containing continuous PAN T300 fibers · SWB: Chopped Fiber Composite containing SWB fibers Crush strength 4340 steel, carbon-carbon composite, and Carbon-Silicon Carbide composite were tested to examine

Rollins, Andrew M.

452

Measurement of carbon capture efficiency and stored carbon leakage  

DOE Patents [OSTI]

Data representative of a measured carbon dioxide (CO.sub.2) concentration and of a measured oxygen (O.sub.2) concentration at a measurement location can be used to determine whether the measured carbon dioxide concentration at the measurement location is elevated relative to a baseline carbon dioxide concentration due to escape of carbon dioxide from a source associated with a carbon