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Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Transport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt-Binding Receptor  

E-Print Network [OSTI]

in the solid state as contact ion pairs. Transport experiments, using a supported liquid membrane and high saltTransport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt and anion receptors. All transport systems exhibit the same qualitative order of ion selectivity; that is

Smith, Bradley D.

2

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

Cassano, Anthony A. (Allentown, PA)

1985-01-01T23:59:59.000Z

3

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

Cassano, A.A.

1985-07-02T23:59:59.000Z

4

Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

1995-01-01T23:59:59.000Z

5

Influence of Salt Purity on Na+ and Palmitic Acid Interactions  

E-Print Network [OSTI]

frequency generation (VSFG) spectroscopy. Ultrapure (UP) and ACS grade NaCl salts are used for aqueous the interfacial water structure. These results suggest that the alkali salt grade even after pretreatment to many chemical, biochemical, and atmospheric processes.1-8 Particularly, Na+ and K+ , as the two most

6

Synthesis of acid addition salt of delta-aminolevulinic acid from 5-bromo levulinic acid esters  

DOE Patents [OSTI]

A process of preparing an acid addition salt of delta-aminolevulinc acid comprising: a) dissolving a lower alkyl 5-bromolevulinate and hexamethylenetetramine in a solvent selected from the group consisting of water, ethyl acetate, chloroform, acetone, ethanol, tetrahydrofuran and acetonitrile, to form a quaternary ammonium salt of the lower alkyl 5-bromolevulinate; and b) hydrolyzing the quaternary ammonium salt with an inorganic acid to form an acid addition salt of delta-aminolevulinic acid.

Moens, Luc (Lakewood, CO)

2003-06-24T23:59:59.000Z

7

Production of carboxylic acid and salt co-products  

DOE Patents [OSTI]

This invention provide processes for producing carboxylic acid product, along with useful salts. The carboxylic acid product that is produced according to this invention is preferably a C.sub.2-C.sub.12 carboxylic acid. Among the salts produced in the process of the invention are ammonium salts.

Hanchar, Robert J.; Kleff, Susanne; Guettler, Michael V.

2014-09-09T23:59:59.000Z

8

Production of Benzene Polycarboxylic Acids from Lignite by Alkali-Oxygen Oxidation  

Science Journals Connector (OSTI)

Production of Benzene Polycarboxylic Acids from Lignite by Alkali-Oxygen Oxidation ... The oxidation of coal to produce high-valued benzene polycarboxylic acids (BPCAs), which are obtained currently from diminishing petroleum reserves, is a promising industrial process of the future. ...

Wenhua Wang; Yucui Hou; Weize Wu; Muge Niu; Weina Liu

2012-10-22T23:59:59.000Z

9

In situ formation of coal gasification catalysts from low cost alkali metal salts  

DOE Patents [OSTI]

A carbonaceous material, such as crushed coal, is admixed or impregnated with an inexpensive alkali metal compound, such as sodium chloride, and then pretreated with a stream containing steam at a temperature of 350.degree. to 650.degree. C. to enhance the catalytic activity of the mixture in a subsequent gasification of the mixture. The treatment may result in the transformation of the alkali metal compound into another, more catalytically active, form.

Wood, Bernard J. (Santa Clara, CA); Brittain, Robert D. (Cupertino, CA); Sancier, Kenneth M. (Menlo Park, CA)

1985-01-01T23:59:59.000Z

10

Methanol synthesis using a catalyst combination of alkali or alkaline earth salts and reduced copper chromite for methanol synthesis  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, John W. (Pittsburgh, PA); Wender, Irving (Pittsburgh, PA); Palekar, Vishwesh M. (Pittsburgh, PA)

1993-01-01T23:59:59.000Z

11

Conversion of carboxylate salts to carboxylic acids via reactive distillation.  

E-Print Network [OSTI]

??The purpose of this study is to convert carboxylate salts (e.g. calcium acetate, propionate, and butyrate) into carboxylic acids (e.g., acetic, propionic, and butyric acids).… (more)

Williamson, Shelly Ann

2012-01-01T23:59:59.000Z

12

Microbial reverse-electrodialysis chemical-production cell for acid and alkali production  

E-Print Network [OSTI]

Microbial reverse-electrodialysis chemical-production cell for acid and alkali production Xiuping Accepted 7 March 2013 Available online 15 March 2013 Keywords: Microbial fuel cell Reverse electrodialysis Bioenergy A new type of bioelectrochemical system, called a microbial reverse-electrodialysis chemical

13

Waste to energy by industrially integrated supercritical water gasification – Effects of alkali salts in residual by-products from the pulp and paper industry  

Science Journals Connector (OSTI)

Supercritical water gasification (SCWG) is a method by which biomass can be converted into a hydrogen-rich gas product. Wet industrial waste streams, which contain both organic and inorganic material, are well suited for treatment by SCWG. In this study, the gasification of two streams of biomass resulting from the pulp and paper industry, black liquor and paper sludge, has been investigated. The purpose is to convert these to useful products, both gaseous and solids, which can be used either in the papermaking process or in external applications. Simple compounds, such as glucose, have been fully gasified in SCWG, but gasification of more complex compounds, such as biomass and waste, have not reached as high conversions. The investigated paper sludge was not easily gasified. Improving gasification results with catalysts is an option and the use of alkali salts for this purpose was studied. The relationship between alkali concentration, temperature, and gasification yields was studied with the addition of KOH, K2CO3, NaOH and black liquor to the paper sludge. Addition of black liquor to the paper sludge resulted in similarly enhancing effects as when the alkali salts were added, which made it possible to raise the dry matter content and gasification yield without expensive additives.

I. Rönnlund; L. Myréen; K. Lundqvist; J. Ahlbeck; T. Westerlund

2011-01-01T23:59:59.000Z

14

E-Print Network 3.0 - acids lead salts Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ammonium...

15

E-Print Network 3.0 - acid ammonium salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

-Partial list Chemical Incompatibilities Summary: hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ammonium...

16

New method to minimize high-temperature corrosion resulting from alkali sulfate and chloride deposition in combustion systems. II. molybdenum salts  

SciTech Connect (OSTI)

The use of fuels other than natural gas in gas turbine generators still is fraught with blade corrosion problems that result from the formation of sodium sulfate or potassium sulfate, in the presence of chlorine. The present work illustrates that the addition of molybdenum salts to synthetic fuels (synfuels) modifies this deposition process and benign protective coatings of alkali polymolybdates are produced instead. This study is a follow-up to research published earlier in this journal that showed closely similar behavior with tungsten salt additives. In the case of molybdenum, a new preferential ranking of product formation on the surface is established that is closely related to the thermodynamic stabilities, namely, Na{sub 2}Mo{sub 2}O{sub 7} {gt} Na{sub 2}SO{sub 4} {gt} Na{sub 2}MoO{sub 4} {gt} NaCl and K{sub 2}Mo{sub 4}O{sub 13} {gt} K{sub 2}Mo{sub 3}O{sub 10} {gt} K{sub 2}Mo{sub 2}O{sub 7} {gt} K{sub 2}SO{sub 4} {gt} K{sub 2}MoO{sub 4} {gt} KCl. This chemistry exists under fuel-lean conditions and is otherwise not sensitive to the fuel, combustion conditions, surface temperature, or material. The required additive trace levels of molybdenum salt are on the order of twice that of the gaseous alkali, on an atomic basis. Consequently, when used as a final pre-gas turbine polishing technique and following other fuel precleaning methods, the approach offers a very practical and inexpensive solution. 63 refs., 6 figs., 1 tab.

Keith Schofield [University of California, Santa Barbara, CA (United States). Materials Research Laboratory

2005-10-01T23:59:59.000Z

17

Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator  

DOE Patents [OSTI]

Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

Joshi, Ashok V. (Salt Lake City, UT); Balagopal, Shekar (Sandy, UT); Pendelton, Justin (Salt Lake City, UT)

2011-12-13T23:59:59.000Z

18

Improved thermoelectric performance in polycrystalline p -type Bi 2 Te 3 via an alkali metal salt hydrothermal nanocoating treatment approach  

Science Journals Connector (OSTI)

We report herein a proof-of-principle study of grain boundary engineering in the polycrystalline p -type Bi 2 Te 3 system. Utilizing the recently developed hydrothermal nanocoating treatment technique we fabricated an alkali-metal(s)-containing surface layer on the p -Bi 2 Te 3 bulk grain which in turn became part of the grain boundary upon hot pressing densification. Compared to the untreated bulk reference the dimensionless figure of merit Z T has been improved by ? 30 % in the Na-treated sample chiefly due to the reduced thermal conductivity and ? 38 % in the Rb-treated sample mainly owing to the improved power factor. The grain boundary phase provides a new avenue by which one can potentially decouple the otherwise inter-related electrical resistivity Seebeck coefficient and thermal conductivity within one thermoelectric material.

Xiaohua Ji; Jian He; Zhe Su; Nick Gothard; Terry M. Tritt

2008-01-01T23:59:59.000Z

19

Effect of Acid, Alkali, and Steam Explosion Pretreatments on Characteristics of Bio-Oil Produced from Pinewood  

SciTech Connect (OSTI)

Bio-oil produced from pinewood by fast pyrolysis has the potential to be a valuable substitute for fossil fuels. Pretreatment prior to the fast pyrolysis process has been shown to alter the structure and chemical composition of biomass. To determine the influence of biomass pretreatments on bio-oil produced during fast pyrolysis, we tested three pretreatment methods: dilute acid, dilute alkali, and steam explosion. Bio-oils were produced from untreated and pretreated pinewood feedstocks in an auger reactor at 450 C. The bio-oils�¢���� physical properties including pH, water content, acid value, density, viscosity, and heating value were measured. Chemical characteristics of the bio-oils were determined by gas chromatographymass spectrometry. Results showed that bio-oil yield and composition were influenced by biomass pretreatment. Of the three pretreatment methods, 1%H2SO4 pretreatment resulted in the highest bio-oil yield and best bio-oil quality.

Wang, Hui; Srinivasan, Radhakrishnan; Yu, Fei; Steele, Philip; Li, Qi; Mitchell, Brian

2011-06-21T23:59:59.000Z

20

Salt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Salt Salt Nature Bulletin No. 340-A April 12, 1969 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation SALT It is fortunate that Salt -- common salt, known to chemists as sodium chloride and to mineralogists as Halite -- is one of the most abundant substances on earth, because most of us crave it and must have it. Eskimos get along without salt because they live mostly on the uncooked flesh of fish and mammals. A few nomad tribes never eat it and do not need it because their diet contains so much milk cheese, and meat eaten raw or roasted. We people who eat boiled meat and many vegetables must have salt. Of the millions of tons produced commercially each year, only about three percent is used as table salt. Large quantities are required for refrigeration meat packing, curing and preserving fish, pickles, sauerkraut, and for other foods prepared in brine. A lot of it is needed for livestock. Salt is spread on sidewalks, streets and highways to melt ice in winter. It is used to glaze pottery, sewer pipe and other ceramics. It is required in many metallurgical processes, chemical industries, and the manufacture of such products as leather, glass, soap, bleaching powder and photographic supplies. It has about 14,000 uses.

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals  

SciTech Connect (OSTI)

The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

2009-07-01T23:59:59.000Z

22

A comparison of the products of the hydrolysis of cottonseed meats with acid and alkali  

E-Print Network [OSTI]

?siege that it aer bo qaaatitaiivelr re assed fan% tho brdr?I+esto ae beri~ self?tee Res?Tery hpdreehierfo acid aep bo roasted br or?per?ties aa4?2 redwood pros?are? Sera sob?tea?os ~ pret?iso ~ sa4 golsti& ero totally hrdrelpaed with? oat tho foeaatioa ef...&relrsato was ~ nalyned eoeer4ing te Ae Vea glyhIP nsthod exospt for soreral changes whish will bo ?nplaiaod ia the outline ef the prooednrw whish fnllewsi Ths hydreohlerie acid was reeeed frwa ihe hydrelyeaie nader redwood pressers, the residne was tohon wp with wares...

Schoch, Henry Bernard

2012-06-07T23:59:59.000Z

23

Conversion of carboxylate salts to carboxylic acids via reactive distillation  

E-Print Network [OSTI]

biomass used in this study . . . 1-2 Approxitnate annual production and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1 Concentration... fermentation broth derived trom various wastes. Table 1-4 describes the studies performed for each fermentation broth, as well as reagent-grade chemicals. Table 1-3. Names used for biomass feedstocks. Sample Name MSW1 MSW2 MSW3 MSW4 MSWS PF/Biol PF...

Williamson, Shelly Ann

2012-06-07T23:59:59.000Z

24

Two-dimensional hydrogen-bonded polymers in the crystal structures of the ammonium salts of phen­oxy­acetic acid, (4-fluoro­phen­oxy)acetic acid and (4-chloro-2-methyl­phen­oxy)acetic acid  

Science Journals Connector (OSTI)

The crystal of the isomorphous anhydrous ammonium salts of phen­oxy­acetic acid and (4-fluoro­phen­oxy)acetic acid and that of the hemihydrate ammonium salt of 4-chloro-2-methyl­phen­oxy)acetic acid show two-dimensional layered structures based on conjoined cyclic hydrogen-bonded motifs.

Smith, G.

2014-11-19T23:59:59.000Z

25

Ruthenium(VI) catalyzed oxidation of sodium salts of lactic, tartaric and glycolic acid by alkaline hexacyanoferrate(III)  

Science Journals Connector (OSTI)

The kinetics of ruthenium(VI) catalyzed oxidation of sodium salts of lactic, tartaric and glycolic acid by hexacyanoferrate(III) in aqueous alkaline medium have been studied at constant ionic strength. The rea...

P. Kumar; K. C. Gupta; K. Vehari

1985-01-01T23:59:59.000Z

26

Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 (12-MC-4) Structural Type  

E-Print Network [OSTI]

of crystalline salts (LiCl2)[12-MCMn(III)N(shi)-4]- ([(LiCl2),1]-), (Li(trifluoro- acetate))[12-MCMn(III)N(shi)-4:1 metal:metallacrown adducts with lithium and 2:1 metal:metallacrown complexes with sodium and potassium

Gibney, Brian R.

27

Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy  

E-Print Network [OSTI]

chloride salt eutectics for solar thermal-energy storage applications Donghyun Shin, Debjyoti Banerjee for the anoma- lous enhancement of thermal conductivity over that of the neat solvent. Eastman et al. [5] reported thermal conductivity enhance- ment of 30% and 60% for water based nanofluids of Al2O3 and Cu

Banerjee, Debjyoti

28

Conversion of glucose into 5-hydroxymethylfurfural with boric acid in molten mixtures of choline salts and carboxylic acids  

Science Journals Connector (OSTI)

Abstract The conversion of glucose into a potential platform chemical for fuels and plastics, 5-hydroxymethylfurfural (HMF), has been studied using B(OH)3 as a promoter in different solvents, namely molten mixtures made of choline salts and carboxylic acids, with the aim of developing an inexpensive and less harmful alternative to Cr/ionic liquid systems. Choline chloride-based molten mixtures afforded poor yields of HMF, whereas the yields were improved by replacing choline chloride with choline dihydrogen citrate. The combination of choline dihydrogen citrate and glycolic acid was the best choice, providing an HMF yield of ?60% at 140 °C within 4 h by adding a small volume of water as a co-solvent.

Hiroaki Matsumiya; Takeyoshi Hara

2014-01-01T23:59:59.000Z

29

Influence of admixtures of free naphthenic acids in zinc and cadmium salts on their activity in catalytic oxidation of isopropylbenzene  

SciTech Connect (OSTI)

It is confirmed that free naphthenic acids have a weak promoting effect on compounds of constant-valence metals. Free naphthenic acids have an activating effect only when present in 1.5-fold excess relative to the concentration of zinc or cadmium salt. The difference in catalytic activity of the naphthenates studied is due to the difference in the complex-forming properties of their cations.

Kozlov, S.K.; Potekhin, V.M.

1986-02-10T23:59:59.000Z

30

Crystal structures and hydrogen bonding in the proton-transfer salts of nicotine with 3,5-di­nitro­salicylic acid and 5-sulfosalicylic acid  

Science Journals Connector (OSTI)

The crystal structures of the 1:1 salts of nicotine with 3,5-di­nitro­salicylic acid and with 5-sulfosalicylic acid both show polymeric hydrogen-bonded and --bonded structures but these differ in that in the first example, cations and anions form separate cation chains or anion columns which are unassociated through formal hydrogen bonds while in the second, hydrogen-bonded cation-anion chains are found.

Smith, G.

2014-10-29T23:59:59.000Z

31

Characterization of Selective Binding of Alkali Cations with Carboxylate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of Selective Characterization of Selective Binding of Alkali Cations with Carboxylate Characterization of Selective Binding of Alkali Cations with Carboxylate Print Wednesday, 24 September 2008 00:00 During its lifetime, a cell spends a considerable fraction of its energy pumping sodium and calcium out and potassium in. This balancing process is similar to that found in the coils of the DNA double helix, where specific ions nestle and help stabilize this macromolecule. These are only two examples of selective ion interactions in biology; there are many others also vital to life. The existence of these interactions has been known since the early 20th century, when Franz Hofmeister observed that some salts (ionic compounds) aided the solution of proteins in egg, some caused proteins to destabilize and precipitate, and others ranged in activity between the two extremes. Hofmeister then ranked "salt-out" (destabilizing) ions versus "salt-in" (stabilizing) ions according to the magnitude of their effects (the "Hofmeister effects"). However, despite enormous effort, why certain interactions are preferred over others is not completely understood. Recently, a team of researchers from UC Berkeley used the model systems of acetate and formate (two simple carboxylic acids) with a series of cations to test predictions made in the literature for preferential interactions. Near-edge x-ray absorption fine structure (NEXAFS) spectroscopy was used as this technique is highly sensitive to the chemical environments around a molecule. Experiments at ALS Beamline 8.0.1 confirmed strengthening of the interaction between the cations and the carboxylate group in the following order: potassium, sodium, and lithium.

32

The results of HLW processing using zirconium salt of dibutyl phosphoric acid  

SciTech Connect (OSTI)

Available in abstract form only. Full text of publication follows: Zirconium salt of dibutyl-phosphoric acid (ZS HDBP) dissolved in a diluent, is a promising solvent for liquid HLW processing. The investigations carried out earlier showed that ZS HDBP can recover a series of radionuclides (TPE, RE, U, Pu, Np, Sr) and some other elements (Mo, Ca, Fe) from aqueous solutions. The possibility of TPE and RE effective recovery and separation into appropriate fractions with high purification from each other was demonstrated as well. The results of extraction tests in the mixer-settlers in the course of liquid HLW treatment in hot cells, using ZS HDBP (0.4 M HDBP and 0.044 M Zr) dissolved in 30% TBP are presented. 30 liters of the feed solution containing TPE, RE, Sr and Cs with the total specific activity of 520 MBq/L and acidity of 2 M HNO{sub 3} were processed using the two-cycle flowsheet. TPE and RE recovery with subsequent stripping was realized in the first cycle, while Sr was recovered and concentrated in the second cycle. Raffinate of the latter contained almost all Cs. The degree of TPE and RE recovery was 104, and that of Sr was {approx}10. Decontamination factor of TPE and RE from Cs and Sr was 104, and that of Sr from TPE and Cs was 103. So, ZS HDBP can be used for separation of long-lived radionuclides from HLW with respect to radio-toxic category of the process products. (authors)

Fedorov, Yury; Zilberman, Boris; Shmidt, Olga; Saprikin, Vladimir; Ryasantsev, Valery [V. G. Khlopin Radium Institute, 194021, 28, 2nd Murinsky pr., Saint-Petersburg (Russian Federation)

2007-07-01T23:59:59.000Z

33

Concentrating aqueous volatile fatty acid salt solutions using a tertiary amine mixture  

E-Print Network [OSTI]

, and that reaction is difficult to reverse (Streitwieser and Heathcock, 1976; King and Poole, 1994). Tertiary amines (R, N) do not form amides but generally give lower K, values than secondary amines. For the extraction of undissociated carboxylic acids, aliphatic... by acidifying with carbon dioxide under pressure in the presence of a suitable solvent (Busche, 1988). Gregor has used electrodialysis to recover acetic acid from dilute (1-5 wt%) acetate solutions. With newer membranes, acid concentrations up to 30% were...

Gaskin, David J

1997-01-01T23:59:59.000Z

34

Steel--Project Fact Sheet: Recycling Acid and Metal Salts from Pickling Liquors  

SciTech Connect (OSTI)

Regenerating hydrochloric acids from metal finishing pickling baths reduces costs, wastes, and produces a valuable by-product--ferrous sulfate. Order your copy of this OIT project fact sheet and learn more about how your company can benefit.

Poole, L.; Recca, L.

1999-01-14T23:59:59.000Z

35

Controlled in-situ dissolution of an alkali metal  

DOE Patents [OSTI]

A method for the controllable dissolution of one or more alkali metals from a vessel containing a one or more alkali metals and/or one or more partially passivated alkali metals. The vessel preferably comprising a sodium, NaK or other alkali metal-cooled nuclear reactor that has been used. The alkali metal, preferably sodium, potassium or a combination thereof, in the vessel is exposed to a treatment liquid, preferably an acidic liquid, more preferably citric acid. Preferably, the treatment liquid is maintained in continuous motion relative to any surface of unreacted alkali metal with which the treatment liquid is in contact. The treatment liquid is preferably pumped into the vessel containing the one or more alkali metals and the resulting fluid is extracted and optionally further processed. Preferably, the resulting off-gases are processed by an off-gas treatment system and the resulting liquids are processed by a liquid disposal system. In one preferred embodiment, an inert gas is pumped into the vessel along with the treatment liquid.

Jones, Jeffrey Donald; Dooley, Kirk John; Tolman, David Donald

2012-09-11T23:59:59.000Z

36

Oligoacetic Acid Characterization by Isocratic and Linear Salt Gradient Anion-Exchange Chromatography  

Science Journals Connector (OSTI)

......ion-exchange Gibbs free energy (Gexchange) was calcu...constant increment in the energy of exchange for the addition...as the increment per car- boxylic acid group...oligomers provided an alternative and convenient method...calculation of the Gibbs free energy of adsorption for biomolecules......

Hong Li; Costas S. Patrickios

2001-03-01T23:59:59.000Z

37

Direct Sulfonation of Methane to Methanesulfonic Acid with SO2 Using Ca Salts as Promoters  

E-Print Network [OSTI]

that CaCl2 can be employed as an initiator for the carbonylation of methane in trifluoroacetic acid minimally effective in promoting the formation of MSA, as compared to CaCl2 (Table 1, entries 1 is completely inactive, and CaBr2 and CaI2 are significantly less effective than CaCl2. Ca(OCl)2 and Ca(CF3COO)2

Bell, Alexis T.

38

Direct conversion of carboxylate salts to carboxylic acids via reactive extraction  

E-Print Network [OSTI]

of Petroleum Processing, P. R. China Chair of Advisory Committee: Dr. Mark T. Holtzapple The MixAlco process, a proprietary technology owned by Texas A&M University, converts biomass (e.g., municipal solid waste, sewage sludge, paper, agricultural... residues, and energy crops) into usable chemicals (e.g., acetic acid) and fuels (e.g., ethanol). Historically, calcium carbonate has been used as the buffer. Recently, it was found that using ammonium bicarbonate as the buffering agent enhances...

Xu, Xin

2008-10-10T23:59:59.000Z

39

Hydrothermal alkali metal recovery process  

DOE Patents [OSTI]

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered from the particles by treating them with a calcium or magnesium-containing compound in the presence of water at a temperature between about 250.degree. F. and about 700.degree. F. and in the presence of an added base to establish a pH during the treatment step that is higher than would otherwise be possible without the addition of the base. During the treating process the relatively high pH facilitates the conversion of water-insoluble alkali metal compounds in the alkali metal residues into water-soluble alkali metal constituents. The resultant aqueous solution containing water-soluble alkali metal constituents is then separated from the residue solids, which consist of the treated particles and any insoluble materials formed during the treatment step, and recycled to the gasification process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preferably, the base that is added during the treatment step is an alkali metal hydroxide obtained by water washing the residue solids produced during the treatment step.

Wolfs, Denise Y. (Houston, TX); Clavenna, Le Roy R. (Baytown, TX); Eakman, James M. (Houston, TX); Kalina, Theodore (Morris Plains, NJ)

1980-01-01T23:59:59.000Z

40

Selective Solid-Liquid Extraction of Lithium Halide Salts Using a Ditopic Macrobicyclic Receptor  

E-Print Network [OSTI]

pairs. The receptor can transport these salts from an aqueous phase through a liquid organic membrane and membrane transport, almost all reported efforts have focused on the transfer of lithium salts from this by binding the salts as contact ion pairs. Receptor 1 can also transport alkali metal halide salts out

Smith, Bradley D.

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

The three-dimensional hydrogen-bonded structures in the ammonium and sodium salt hydrates of 4-amino­phenyl­arsonic acid  

Science Journals Connector (OSTI)

In the hydrated ammonium salt of 4-amino­phenyl­arsonic acid (p-arsanilic acid), the ammonium cations, arsonate anions and water mol­ecules inter­act through inter-species N-HO hydrogen bonds to arsonate and water, and water O-HO hydrogen bonds, giving the common two-dimensional layers lying parallel to (010), which are expanded into three-dimensions through the amine group. The sodium salt is a one-dimensional coordination polymer with water bridges generating chains extending along c and extensive inter-chain O-HO and N-HO hydrogen-bonding inter­actions linking these chains, giving an overall three-dimensional structure.

Smith, G.

2014-07-04T23:59:59.000Z

42

Salt Effect Model for Aqueous Solubility of TBP in a 5 to 100% TBP/n-Dodecane-Nitric Acid-Water Biphasic System at 298.2 K  

SciTech Connect (OSTI)

The solubilities of nonelectrolytes in aqueous electrolyte solutions have traditionally been modeled by using the Setschenow equation for salt effect. The aqueous solubility of tri-n-butyl phosphate (TBP) during operating conditions of the Purex process is an important parameter for safety considerations. Use of the Setschenow equation for aqueous solubility of TBP under limited conditions has been reported in the literature. However, there is no general model available to account for the presence of the diluent and for the case of multicomponent electrolyte solutions in which only some electrolytes are solvated and extracted by TBP. An extended salt effect model is proposed for predicting the aqueous solubility of TBP in a 5 to 100% TBP/n-dodecane-nitric acid-water biphasic system at 298.2 K. The literature data on TBP solubility were correlated to aqueous acid concentration, diluent concentration in the solvents, and an interaction parameter for electrolytic solutes (extracted or not extracted by TBP)

Kumar, Shekhar; Koganti, Sudhir Babu [Indira Gandhi Centre for Atomic Research (India)

2000-02-15T23:59:59.000Z

43

Purification of alkali metal nitrates  

DOE Patents [OSTI]

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

44

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tropospheric Chemistry of Internally Mixed Sea Salt and Organic Particles: Surprising Reactivity of NaCl with Weak Organic Acids Tropospheric Chemistry of Internally Mixed Sea Salt...

45

Upgrading platform using alkali metals  

DOE Patents [OSTI]

A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

Gordon, John Howard

2014-09-09T23:59:59.000Z

46

Chemical Name Container size Cabinet Level # of containers (Ethylenedinitrilo) tetraacetic acid, disodium salt 500g 2 B 1  

E-Print Network [OSTI]

Acetaldehyde 250g 6 A 2 Acetyl acetone 4 fl. Oz 6 A 5 Acid oxalic, crystal 1lbs 2 E 1 Acrolein 25ml 6 A 1

Capecchi, Mario R.

47

Tungsten-188/carrier-free rhenium-188 perrhenic acid generator system  

DOE Patents [OSTI]

A generator system for providing a carrier-free radioisotope in the form of an acid comprises a chromatography column in tandem fluid connection with an ion exchange column, the chromatography column containing a charge of a radioactive parent isotope. The chromatography column, charged with a parent isotope, is eluted with an alkali metal salt solution to generate the radioisotope in the form of an intermediate solution, which is passed through the ion-exchange column to convert the radioisotope to a carrier-free acid form.

Knapp, F.F. Jr.; Lisic, E.C.; Mirzadeh, S.; Callahan, A.P.

1993-02-16T23:59:59.000Z

48

Tungsten-188/carrier-free rhenium-188 perrhenic acid generator system  

DOE Patents [OSTI]

A generator system has been invented for providing a carrier-free radioisotope in the form of an acid comprises a chromatography column in tandem fluid connection with an ion exchange column, the chromatography column containing a charge of a radioactive parent isotope. The chromatography column, charged with a parent isotope, is eluted with an alkali metal salt solution to generate the radioisotope in the form of an intermediate solution, which is passed through the ion-exchange column to convert the radioisotope to a carrier-free acid form. 1 figure.

Knapp, F.F. Jr.; Lisic, E.C.; Mirzadeh, S.; Callahan, A.P.

1994-01-04T23:59:59.000Z

49

Determination of Single-Ion Activities of H+ and Cl– in Aqueous Hydrochloric Acid Solutions by Use of an Ionic Liquid Salt Bridge  

Science Journals Connector (OSTI)

Many of the problems inherent to KCl-type salt bridges can be circumvented by use of a salt bridge made of a moderately hydrophobic ionic liquid, that is, an ionic liquid salt bridge (ILSB). ... A newly emerged salt bridge based on moderately hydrophobic ionic liqs. is promising to solve many of the problems that KCl-type salt bridges are unable to, possibly making the future of electroanal. ... The new salt bridge is free from most of the problems inherent to KCl-based salt bridges. ...

Hideaki Sakaida; Takashi Kakiuchi

2011-09-20T23:59:59.000Z

50

Raman Analysis of Perrhenate and Pertechnetate in Alkali Salts...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at high additions of the source chemical, since Na is more prevalent in the glass and ion exchange takes place. These results have significance to immobilization of nuclear...

51

E-Print Network 3.0 - alkali metal nitrate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

METAL-ALKALI HALIDE Summary: CONDUCTIVITY OF ALKALI METAL-ALKALI HALIDE SOLUTIONS R. GILBERT and G. J. MORGAN The Physics Department... to liquid alkali metals electrons are...

52

Diversity of Dissimilatory Sulfite Reductase Genes (dsrAB) in a Salt Marsh Impacted by Long-Term Acid Mine Drainage  

Science Journals Connector (OSTI)

...523-536. 42 Howarth, R. W. 1993. Microbial processes in salt-marsh sediments, p. 239-259...in a New England salt marsh. Limnol. Oceanogr. 24: 999-1013. 44 Howarth, R. W., and A. Giblin...reduction in the salt marshes at Sapelo Island, Georgia...

John W. Moreau; Robert A. Zierenberg; Jillian F. Banfield

2010-05-14T23:59:59.000Z

53

Regenerable activated bauxite adsorbent alkali monitor probe  

DOE Patents [OSTI]

A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

Lee, S.H.D.

1992-12-22T23:59:59.000Z

54

Elemental and isotopic analysis of inorganic salts by laser desorption ionization mass spectrometry  

SciTech Connect (OSTI)

Laser desorption ionization mass spectrometry is applied for the analysis of elements as well as their isotopic composition in different inorganic salts. At very low laser energies the inorganic ions are desorbed and ionized from the thin layer of the sample surface. The naturally occurring isotopes of alkali and silver ions are resolved using time of flight mass spectrometer. Further increase in laser energy shows the appearance of Al, Cr, and Fe ions in the mass spectra. This indicates the penetration laser beam beyond the sample surface leading to the ablation of sample target at higher energies. The simultaneous appearance of atomic ions from the sample target at relatively higher laser energies hampers the unambiguous identification of amino acid residues from the biomolecular ions in MALDI-MS.

Jayasekharan, T.; Sahoo, N. K. [Applied Spectroscopy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

2013-02-05T23:59:59.000Z

55

Alternative Waste Forms for Electro-Chemical Salt Waste  

SciTech Connect (OSTI)

This study was undertaken to examine alternate crystalline (ceramic/mineral) and glass waste forms for immobilizing spent salt from the Advanced Fuel Cycle Initiative (AFCI) electrochemical separations process. The AFCI is a program sponsored by U.S. Department of Energy (DOE) to develop and demonstrate a process for recycling spent nuclear fuel (SNF). The electrochemical process is a molten salt process for the reprocessing of spent nuclear fuel in an electrorefiner and generates spent salt that is contaminated with alkali, alkaline earths, and lanthanide fission products (FP) that must either be cleaned of fission products or eventually replaced with new salt to maintain separations efficiency. Currently, these spent salts are mixed with zeolite to form sodalite in a glass-bonded waste form. The focus of this study was to investigate alternate waste forms to immobilize spent salt. On a mole basis, the spent salt is dominated by alkali and Cl with minor amounts of alkaline earth and lanthanides. In the study reported here, we made an effort to explore glass systems that are more compatible with Cl and have not been previously considered for use as waste forms. In addition, alternate methods were explored with the hope of finding a way to produce a sodalite that is more accepting of as many FP present in the spent salt as possible. This study was done to investigate two different options: (1) alternate glass families that incorporate increased concentrations of Cl; and (2) alternate methods to produce a mineral waste form.

Crum, Jarrod V.; Sundaram, S. K.; Riley, Brian J.; Matyas, Josef; Arreguin, Shelly A.; Vienna, John D.

2009-10-28T23:59:59.000Z

56

Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al., 2008...  

Open Energy Info (EERE)

Alkali Flat Area (Kratt, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Gabbs Alkali Flat Area (Kratt, Et Al.,...

57

Iodized Salt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iodized Salt Iodized Salt Name: Theresa Location: N/A Country: N/A Date: N/A Question: Why do they put iodine in salt? Replies: Iodine was introduced into salt at earlier this century when it was discovered that certain areas of the US had a mark deficiency in iodine in the diet of people, and people developed a neck swelling (goiter). The Great Lakes region is one of these areas where the soil is lacking iodine. Goiter can be caused when the thyroid gland swells because of a lack of iodine in the diet. Most medical advise now states that iodine in salt is no longer necessary due to our food sources arising from all over the world. Steve Sample Hi Theresa...see, there are a variety of elements and compounds that are necessary for the proper maintenance of our life. One of these is iodine, since a small quantity of iodine is needed for the adequate functioning of the thyroid gland. A deficiency of iodine produces dire effects, as goiter, where the thyroid gland swollens due to the lack of iodine traces in the diet. The iodine affects directly the tyrhoid gland secretions, which themselves, to a great extent, control heart action, nerve response to stimuli, rate of body growth and metabolism.

58

Diode pumped alkali vapor fiber laser  

DOE Patents [OSTI]

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2006-07-26T23:59:59.000Z

59

Diode pumped alkali vapor fiber laser  

DOE Patents [OSTI]

A method and apparatus is provided for producing near-diffraction-limited laser light, or amplifying near-diffraction-limited light, in diode pumped alkali vapor photonic-band-gap fiber lasers or amplifiers. Laser light is both substantially generated and propagated in an alkali gas instead of a solid, allowing the nonlinear and damage limitations of conventional solid core fibers to be circumvented. Alkali vapor is introduced into the center hole of a photonic-band-gap fiber, which can then be pumped with light from a pump laser and operated as an oscillator with a seed beam, or can be configured as an amplifier.

Payne, Stephen A. (Castro Valley, CA); Beach, Raymond J. (Livermore, CA); Dawson, Jay W. (Livermore, CA); Krupke, William F. (Pleasanton, CA)

2007-10-23T23:59:59.000Z

60

Fate of alkalis in coal combustion  

SciTech Connect (OSTI)

The results of these measurements and experiments provide a plausible way to begin an explanation for the distribution of alkali in the ash particulates. To summarize: (1) under typical coal combustion conditions in an atmosphere rich in CO/sub 2/ and/or SO/sub 2/, the alkalis in the organic fraction do not vaporize but remain bound in the ash as stable carbonates or sulfates; (2) the alkalis in the inorganic fraction diffuse to the surface producing enrichment by a factor of about 13 to a depth of about 100A. The results, however, do not provide conclusive evidence about the fate of the alkalis. The effect of water vapor in the combustion stream has not yet been studied. Clearly, water could have an important effect on the vaporization process. Furthermore, the reasoning we have followed to explain the absence of alkali enrichment in the submicron particles requires that the volatilization of the alkalis in both the organic and inorganic fraction not be significant (say less than 20%).

Stewart, G.W. (Aerodyne Research, Inc., Bedford, MA); Stinespring, C.D.; Davidovits, P.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Alteration of alkali reactive aggregates autoclaved in different alkali solutions and application to alkali-aggregate reaction in concrete  

SciTech Connect (OSTI)

Surface alteration of typical aggregates with alkali-silica reactivity and alkali-carbonate reactivity, i.e. Spratt limestone (SL) and Pittsburg dolomitic limestone (PL), were studied by XRD and SEM/EDS after autoclaving in KOH, NaOH and LiOH solutions at 150 deg. C for 150 h. The results indicate that: (1) NaOH shows the strongest attack on both ASR and ACR aggregates, the weakest attack is with LiOH. For both aggregates autoclaved in different alkali media, the crystalline degree, morphology and distribution of products are quite different. More crystalline products are formed on rock surfaces in KOH than that in NaOH solution, while almost no amorphous product is formed in LiOH solution; (2) in addition to dedolomitization of PL in KOH, NaOH and LiOH solutions, cryptocrystalline quartz in PL involves in reaction with alkaline solution and forms typical alkali-silica product in NaOH and KOH solutions, but forms lithium silicate (Li{sub 2}SiO{sub 3}) in LiOH solution; (3) in addition to massive alkali-silica product formed in SL autoclaved in different alkaline solutions, a small amount of dolomite existing in SL may simultaneously dedolomitize and possibly contribute to expansion; (4) it is promising to use the duplex effect of LiOH on ASR and ACR to distinguish the alkali-silica reactivity and alkali-carbonate reactivity of aggregate when both ASR and ACR might coexist.

Lu Duyou [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China) and ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)]. E-mail: duyoulu@njut.edu.cn; Mei Laibao [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Xu Zhongzi [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Tang Mingshu [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, Jiangsu, 210009 (China); Fournier, Benoit [ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)

2006-06-15T23:59:59.000Z

62

Molybdenum/alkali metal/ethylene glycol complexes useful as epoxidation catalysts  

SciTech Connect (OSTI)

This patent describes a clear, storage stable solution of a molybdenum/alkali metal/ethylene glycol complex in ethylene glycol made by the process comprising: reacting at an elevated temperature between about 25/sup 0/ and 150/sup 0/C a solid ammonium molybdate or a hydrate thereof and a solid alkali metal molybdate or a hydrate thereof with ethylene glycol, such that the ratio of moles of ethylene glycol to total gram atoms of molybdenum in the molybdates ranges from about 7:10 to 10:1, and the ratio of gram atoms of molybdenum in the ammonium molybdate or hydrate thereof to gram atoms of molybdenum in the alkali metal molybdate is from about 1:1 to about 20:1 to thereby provide a reaction product composed of a solution of an alkali metal-containing complex of molybdenum, alkali metal and ethylene glycol and by-products, including water, in the ethylene glycol and subsequently stripping the solution at a reduced pressure to remove from about 5 to about 25% of the reaction product, as distillate, to thereby provide a storage stable solution of the complex in the ethylene glycol having a molybdenum content of about 6 wt. % to about 20 wt. %, a water concentration of about 0.1 wt. % to about 6 wt. % and an acid number of more than about 60.

Marquis, E.T.; Sanderson, J.R.; Keating, K.P.

1987-10-27T23:59:59.000Z

63

Estimation of Bacterial Cell Numbers in Humic Acid-Rich Salt Marsh Sediments with Probes Directed to 16S Ribosomal DNA  

Science Journals Connector (OSTI)

...involved in collection of marsh samples-Dan Wood, Alison...Khalequzzaman, who performed all marsh coring. REFERENCES Amann R. I. Ludwig W. Schleifer...bacteria in a Delaware salt marsh. . Farrelly V. Rainey...species. . Hahn D. Amann R. I. Ludwig W. Akkermans...

Virginia P. Edgcomb; John H. McDonald; Richard Devereux; David W. Smith

1999-04-01T23:59:59.000Z

64

Diversity of Dissimilatory Sulfite Reductase Genes (dsrAB) in a Salt Marsh Impacted by Long-Term Acid Mine Drainage  

Science Journals Connector (OSTI)

...primary drinking water standards. EPA 816-F-03-016...cycling of sulfur in mining-impacted freshwater...sulfate-reducing bacteria: critical review and research needs...Conceptual remedial action plan, marsh portion of subunit...Salt marsh processes: a review. Environ. Toxicol...

John W. Moreau; Robert A. Zierenberg; Jillian F. Banfield

2010-05-14T23:59:59.000Z

65

acid  

Office of Legacy Management (LM)

Acid/Pueblo Canyon, New Mexico, Site is Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south of the former waste treatment plant. The plant was situated on a mesa that forms the south rim of Acid Canyon. Acid Canyon is a small tributary near the head

66

Hydrogen Release Studies of Alkali Metal Amidoboranes. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Release Studies of Alkali Metal Amidoboranes. Hydrogen Release Studies of Alkali Metal Amidoboranes. Abstract: A series of metal amido boranes LiNH2BH3 (LAB), NaNH2BH3 (SAB),...

67

Selection of non-adsorbing alkali components  

SciTech Connect (OSTI)

This project consists of three phases of laboratory experimental study. In phase I (screening), eight candidate materials, 304SS (serves as a base material for comparison), Hastelloy C-276, Hastelloy X, Haynes No. 188, Allonized 304SS, Pt-coated 304SS, and ceramic-coated 304SS, will be subjected to atmospheric TGA study under the simulated PFBC (oxidizing) environment with and without alkali vapor doping. Each candidate material will be evaluated for its resistance toward alkali-vapor capture. In addition, a post-test metallographic characterization of the sample will be performed to obtain a better understanding of the alkali capture mechanism and material behavior. The material(s) with little or no alkali-vapor adsorption will be selected as the promising material(s) for the Phase II study. In Phase II, the promising material(s) will be further tested in the TGA under elevated pressure to simulate the PFBC environment (in terms of temperature, pressure, and gas composition). The effect of pressure on the extent of alkali-vapor adsorption will be evaluated, and the test samples will be metallographically characterized. The most promising candidate material(s) will be identified and recommended for further tesfing in the actual PFBC environment. In Phase III, four materials will be selected from the eight candidate materials screened in the PFBC environment and will be evaluated for their alkali-vapor capture by atmospheric TGA under the coal gasification fuel gas (reducing) environment. The tested samples will also be metallographically characterized. The most promising material(s) will be identified and recommended for further testing in the actual coal gasification environment.

Lee, S.H.D.; Natesan, K.; Swift, W.M.

1992-11-01T23:59:59.000Z

68

acid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acid/Pueblo Canyon, New Mexico, Site. Acid/Pueblo Canyon, New Mexico, Site. This site is managed by the U.S. Department of Energy Office of Legacy Management. Site Description and History The Acid/Pueblo Canyon, New Mexico, Site is located near the town of Los Alamos, New Mexico, approximately 25 miles northwest of Santa Fe and 60 miles north-northeast of Albuquerque. The site is accessible from Canyon Road, which runs just south

69

Alkali resistant optical coatings for alkali lasers and methods of production thereof  

DOE Patents [OSTI]

In one embodiment, a multilayer dielectric coating for use in an alkali laser includes two or more alternating layers of high and low refractive index materials, wherein an innermost layer includes a thicker, >500 nm, and dense, >97% of theoretical, layer of at least one of: alumina, zirconia, and hafnia for protecting subsequent layers of the two or more alternating layers of high and low index dielectric materials from alkali attack. In another embodiment, a method for forming an alkali resistant coating includes forming a first oxide material above a substrate and forming a second oxide material above the first oxide material to form a multilayer dielectric coating, wherein the second oxide material is on a side of the multilayer dielectric coating for contacting an alkali.

Soules, Thomas F; Beach, Raymond J; Mitchell, Scott C

2014-11-18T23:59:59.000Z

70

128 CEREAL CHEMISTRY Effects of Alkali Debranning, Roller Mill Cracking and Gap Setting, and Alkali  

E-Print Network [OSTI]

was obtained when steeping corn in 0.5% NaOH for 1 hr at 45�C. Alkali corn wet-milling has been studied Steeping Conditions on Milling Yields from a Dent Corn Hybrid P. Yang,1 L. Du,1,2 D. L. Wang,1 B. H. Li,1 K was significantly affected by all three main unit oper- ations in alkali wet-milling (debranning, roller milling

71

Diversity of Dissimilatory Sulfite Reductase Genes (dsrAB) in a Salt Marsh Impacted by Long-Term Acid Mine Drainage  

Science Journals Connector (OSTI)

...Cluster OTU a Most related dsrAB sequence...Energys Basic Energy Sciences program...characterization of sulfate-reducing bacteria in a...Stahl. 2003. Related assemblages of...acid analysis to measure impact of acid...sediments above gas hydrate (Cascadia...acidophilic sulfate-reducing bacteria. J...

John W. Moreau; Robert A. Zierenberg; Jillian F. Banfield

2010-05-14T23:59:59.000Z

72

A Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres,  

Open Energy Info (EERE)

Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres, Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres, Northwestern Spitsbergen- Volcanology And Tectonic Significance Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A Primitive Alkali Basaltic Stratovolcano And Associated Eruptive Centres, Northwestern Spitsbergen- Volcanology And Tectonic Significance Details Activities (0) Areas (0) Regions (0) Abstract: Three Quaternary volcanic centres (Sverrefjell, Sigurdfjell and Halvdanpiggen) in northwestern Spitsbergen formed by off-ridge alkali basaltic volcanism associated with nearby ocean-floor spreading and subsequent tectonism. The Sverrefjell volcano is a unique stratovolcano constructed of primitive alkali basaltic pyroclastics with subordinate lavas. About 15-20 vol.% of this volcanic (and the other centres) comprises

73

Alkali metal recovery from carbonaceous material conversion process  

DOE Patents [OSTI]

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced in the gasifier or similar reaction zone, alkali metal constitutents are recovered from the particles by withdrawing and passing the particles from the reaction zone to an alkali metal recovery zone in the substantial absence of molecular oxygen and treating the particles in the recovery zone with water or an aqueous solution in the substantial absence of molecular oxygen. The solution formed by treating the particles in the recovery zone will contain water-soluble alkali metal constituents and is recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst. Preventing contact of the particles with oxygen as they are withdrawn from the reaction zone and during treatment in the recovery zone avoids the formation of undesirable alkali metal constituents in the aqueous solution produced in the recovery zone and insures maximum recovery of water-soluble alkali metal constituents from the alkali metal residues.

Sharp, David W. (Seabrook, TX); Clavenna, LeRoy R. (Baytown, TX); Gorbaty, Martin L. (Fanwood, NJ); Tsou, Joe M. (Galveston, TX)

1980-01-01T23:59:59.000Z

74

Studies on rejuvenation of spent residue hydroprocessing catalysts by leaching of foulant metals: influence of inorganic salt additives on the leaching efficiency of organic acids  

Science Journals Connector (OSTI)

A comparative study has been made on the efficiency of oxalic, malonic and acetic acids for selective removal of metal foulants (e.g. vanadium) from spent residue hydrotreating catalysts in the presence and ab...

M. Marafi; A. Stanislaus; C. J. Mumford

1993-01-01T23:59:59.000Z

75

On the Chemla effect in molten alkali nitrates  

Science Journals Connector (OSTI)

The Chemla effect concerns the strong composition dependence of the internal ionic mobilities of cations in mixtures of two molten salts with a common anion in which the mobility of the large cation can be higher than the small one at low concentrations of the latter. Molecular dynamics simulations of molten ( Li Cs)NO 3 ( Li K)NO 3 ( Li Na)NO 3 ( Na Cs)NO 3 each at two different compositions at a given temperature and also pure LiNO 3 and pure KNO 3 have been performed with the aim of reproducing the Chemla effect. The key role played by anion polarization on the Chemla effect in molten alkali nitrates is demonstrated by comparing the calculated mobilities using nonpolarizable and polarizable models. Polarization effects were included in the simulations by using a previously proposed fluctuating charge model (FCM) for the NO 3 ? anion. It is shown that a single potential model for a ( M 1 M 2 ) NO 3 mixture gives the correct composition dependence of the M 1 and the M 2 mobilities provided that polarization effects are included in the model. The FCM is thus transferable between different systems but not its nonpolarizable counterpart. Structure and dynamics of the simulated systems are discussed in light of proposed models for the Chemla effect.

Mauro C. C. Ribeiro

2002-01-01T23:59:59.000Z

76

Sorption of carboxylic acid from carboxylic salt solutions at pHs close to or above the pK[sub a] of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH[sub a] into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. The acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carboxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia. 8 figs.

King, C.J.; Tung, L.A.

1992-07-21T23:59:59.000Z

77

Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine  

DOE Patents [OSTI]

Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.

King, C. Judson (Kensington, CA); Tung, Lisa A. (El Cerrito, CA)

1992-01-01T23:59:59.000Z

78

Salt transport extraction of transuranium elements from LWR fuel  

DOE Patents [OSTI]

A process is described for separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl[sub 2] and a Cu--Mg alloy containing not less than about 25% by weight Mg at a temperature in the range of from about 750 C to about 850 C to precipitate uranium metal and some of the noble metal fission products leaving the Cu--Mg alloy having transuranium actinide metals and rare earth fission product metals and some of the noble metal fission products dissolved therein. The CaCl[sub 2] having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO[sub 2]. The Ca metal and CaCl[sub 2] is recycled to reduce additional oxide fuel. The Cu--Mg alloy having transuranium metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with a transport salt including MgCl[sub 2] to transfer Mg values from the transport salt to the Cu--Mg alloy while transuranium actinide and rare earth fission product metals transfer from the Cu--Mg alloy to the transport salt. Then the transport salt is mixed with a Mg--Zn alloy to transfer Mg values from the alloy to the transport salt while the transuranium actinide and rare earth fission product values dissolved in the salt are reduced and transferred to the Mg--Zn alloy. 2 figs.

Pierce, R.D.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Miller, W.E.

1992-11-03T23:59:59.000Z

79

Chemistry control and corrosion mitigation of heat transfer salts for the fluoride salt reactor (FHR)  

SciTech Connect (OSTI)

The Molten Salt Reactor Experiment (MSRE) was a prototype nuclear reactor which operated from 1965 to 1969 at Oak Ridge National Laboratory. The MSRE used liquid fluoride salts as a heat transfer fluid and solvent for fluoride based {sup 235}U and {sup 233}U fuel. Extensive research was performed in order to optimize the removal of oxide and metal impurities from the reactor's heat transfer salt, 2LiF-BeF{sub 2} (FLiBe). This was done by sparging a mixture of anhydrous hydrofluoric acid and hydrogen gas through the FLiBe at elevated temperatures. The hydrofluoric acid reacted with oxides and hydroxides, fluorinating them while simultaneously releasing water vapor. Metal impurities such as iron and chromium were reduced by hydrogen gas and filtered out of the salt. By removing these impurities, the corrosion of reactor components was minimized. The Univ. of Wisconsin - Madison is currently researching a new chemical purification process for fluoride salts that make use of a less dangerous cleaning gas, nitrogen trifluoride. Nitrogen trifluoride has been predicted as a superior fluorinating agent for fluoride salts. These purified salts will subsequently be used for static and loop corrosion tests on a variety of reactor materials to ensure materials compatibility for the new FHR designs. Demonstration of chemistry control methodologies along with potential reduction in corrosion is essential for the use of a fluoride salts in a next generator nuclear reactor system. (authors)

Kelleher, B. C.; Sellers, S. R.; Anderson, M. H.; Sridharan, K.; Scheele, R. D. [Dept. of Engineering Physics, Univ.of Wisconsin - Madison, 1500 Engineering Drive, Madison, WI 53706 (United States)

2012-07-01T23:59:59.000Z

80

Alteration of alkali reactive aggregates autoclaved in different alkali solutions and application to alkali-aggregate reaction in concrete (II) expansion and microstructure of concrete microbar  

SciTech Connect (OSTI)

The effect of the type of alkalis on the expansion behavior of concrete microbars containing typical aggregate with alkali-silica reactivity and alkali-carbonate reactivity was studied. The results verified that: (1) at the same molar concentration, sodium has the strongest contribution to expansion due to both ASR and ACR, followed by potassium and lithium; (2) sufficient LiOH can completely suppress expansion due to ASR whereas it can induce expansion due to ACR. It is possible to use the duplex effect of LiOH on ASR and ACR to clarify the ACR contribution when ASR and ACR may coexist. It has been shown that a small amount of dolomite in the fine-grained siliceous Spratt limestone, which has always been used as a reference aggregate for high alkali-silica reactivity, might dedolomitize in alkaline environment and contribute to the expansion. That is to say, Spratt limestone may exhibit both alkali-silica and alkali-carbonate reactivity, although alkali-silica reactivity is predominant. Microstructural study suggested that the mechanism in which lithium controls ASR expansion is mainly due to the favorable formation of lithium-containing less-expansive product around aggregate particles and the protection of the reactive aggregate from further attack by alkalis by the lithium-containing product layer.

Lu Duyou [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China)]. E-mail: duyoulu@njut.edu.cn; Mei Laibao [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Xu Zhongzi [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Tang Mingshu [College of Materials Science and Engineering, Nanjing University of Technology, 5 New Model Road, Nanjing, 210009 (China); Mo Xiangyin [Analysis and Test Central, Nanjing Normal University, 122 Ninghai Road, Nanjing, 210097 (China); Fournier, Benoit [ICON/CANMET, Natural Resources Canada, 405 Rochester Street, Ottawa, ON, K1A 0G1 (Canada)

2006-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Retrospective salt tectonics  

SciTech Connect (OSTI)

The conceptual breakthroughs in understanding salt tectonics can be recognized by reviewing the history of salt tectonics, which divides naturally into three parts: the pioneering era, the fluid era, and the brittle era. The pioneering era (1856-1933) featured the search for a general hypothesis of salt diapirism, initially dominated by bizarre, erroneous notions of igneous activity, residual islands, in situ crystallization, osmotic pressures, and expansive crystallization. Gradually data from oil exploration constrained speculation. The effects of buoyancy versus orogeny were debated, contact relations were characterized, salt glaciers were discovered, and the concepts of downbuilding and differential loading were proposed as diapiric mechanisms. The fluid era (1933-{approximately}1989) was dominated by the view that salt tectonics resulted from Rayleigh-Taylor instabilities in which a dense fluid overburden having negligible yield strength sinks into a less dense fluid salt layer, displacing it upward. Density contrasts, viscosity contrasts, and dominant wavelengths were emphasized, whereas strength and faulting of the overburden were ignored. During this era, palinspastic reconstructions were attempted; salt upwelling below thin overburdens was recognized; internal structures of mined diapirs were discovered; peripheral sinks, turtle structures, and diapir families were comprehended; flow laws for dry salt were formulated; and contractional belts on divergent margins and allochthonous salt sheets were recognized. The 1970s revealed the basic driving force of salt allochthons, intrasalt minibasins, finite strains in diapirs, the possibility of thermal convection in salt, direct measurement of salt glacial flow stimulated by rainfall, and the internal structure of convecting evaporites and salt glaciers. The 1980`s revealed salt rollers, subtle traps, flow laws for damp salt, salt canopies, and mushroom diapirs.

Jackson, M.P.A. [Univ. of Texas, Austin, TX (United States)

1996-12-31T23:59:59.000Z

82

Molecular basis for defective secretion of the Z variant of human alpha-1-proteinase inhibitor: secretion of variants having altered potential for salt bridge formation between amino acids 290 and 342.  

Science Journals Connector (OSTI)

...the 290-342 salt bridge, is the critical...S. Gov't, P.H.S. | R01 HL 37128-01...culture medium 72 h posttransfection...Potential for salt bridge formation between...transfected with the salt bridge-competent Z-type...was collected at 72 h posttransfection...

A A McCracken; K B Kruse; J L Brown

1989-04-01T23:59:59.000Z

83

Post-Harvest Processing Methods for Reduction of Silica and Alkali Metals in Wheat Straw  

SciTech Connect (OSTI)

Silica and alkali metals in wheat straw limit its use for bioenergy and gasification. Slag deposits occur via the eutectic melting of SiO2 with K2O, trapping chlorides at surfaces and causing corrosion. A minimum melting point of 950°C is desirable, corresponding to SiO2:K2O of about 3:1. Mild chemical treatments were used to reduce Si, K, and Cl, while varying temperature, concentration, %-solids, and time. Dilute acid was more effective at removing K and Cl, while dilute alkali was more effective for Si. Reduction of minerals in this manner may prove economical for increasing utilization of the straw for combustion or gasification.

Thompson, David Neal; Lacey, Jeffrey Alan; Shaw, Peter Gordon

2002-04-01T23:59:59.000Z

84

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, zirconia, and fireclay glass. The study consists of identification of the alkali reaction products (phase equilibria) and the kinetics of the alkali reactions as a function of temperature and time.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-05-27T23:59:59.000Z

85

Effect of alkalis and sulfates on Portland cement systems.  

E-Print Network [OSTI]

??The effect of the sulfates and alkalis on the durability of Portland cement systems was investigated through a series of cube and prism mixes. Durability… (more)

Halaweh, Mahmoud

2006-01-01T23:59:59.000Z

86

ALKALI AGGREGATE REACTION AND DELAYED ETTRINGITE FORMATION: COMMON FEATURES AND DIFFERENCES  

E-Print Network [OSTI]

ALKALI AGGREGATE REACTION AND DELAYED ETTRINGITE FORMATION: COMMON FEATURES AND DIFFERENCES Renaud Department, Paris, France Abstract Alkali-Aggregate Reaction (AAR) and Delayed Ettringite Formation (DEF effects 1 INTRODUCTION Alkali Aggregate Reaction (AAR) and Delayed Ettringite Formation (DEF) are internal

Paris-Sud XI, Université de

87

Superatoms and their assemblies based on alkali and super-alkali motifs  

Science Journals Connector (OSTI)

It is shown that chosen stable clusters can mimic the chemical behavior of atoms in the periodic table and hence can be regarded as superatoms forming a third dimension of the periodic table. The review discusses the developments leading to the superatom ... Keywords: Superatoms, super-alkali clusters, superhalogens

P. Clayborne; N. O. Jones; A. C. Reber; J. U. Reveles; M. C. Qian; S. N. Khanna

2007-12-01T23:59:59.000Z

88

E-Print Network 3.0 - alkali metal picrates Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

layers of alkali metals. 1. Introduction Optical... and Cu 6 by Chen et al. The adsorption of alkali atoms on transition metals is of great importance... . Secondharmonic...

89

E-Print Network 3.0 - alkali-aggregate reactions strengthening...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Durability Issues K.W. Neale1 Summary: conducted on the FRP rehabilitation of concrete beams suffering from alkali aggregate reaction damage... to alkali aggregate reactions. FRP...

90

Studies of non-proportionality in alkali halide and strontium iodide scintillators using SLYNCI  

E-Print Network [OSTI]

in Alkali Halide and Strontium Iodide Scintillators Usingof europium doping level in strontium iodide. Directions offor several alkali halides, strontium iodide, and lanthanum

Ahle, Larry

2011-01-01T23:59:59.000Z

91

E-Print Network 3.0 - alkali halide crystals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

STUDIES IN ALKALI HALIDES Summary: of the alkali halides (KC1) the introduction of vacancies by thermal quenching of unirra- diated crystals has... ANNIHILATION STUDIES IN...

92

E-Print Network 3.0 - alkali metal hydrides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hf for selected alkali metal hydrides, alkaline earth metal hydrides, transition metal hydrides... of binary hydrides based on alkali metals, alkaline earth ... Source:...

93

Tuning of the Metal-Insulator Transition via Alkali Adsorption  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel, surprising way to continuously transform a layered metallic transition-metal compound, TaS2, into an insulator. Using angle-resolved photoemission spectroscopy (ARPES), they have demonstrated that adsorption of alkali atoms onto this material's surface gradually makes it more insulating, although in general, alkali adsorption should lead to more metallic behavior, as alkali atoms easily give away their loosely bound outermost electron.

94

Amphiphilic Maleic Acid-Containing Alternating Copolymers--2. Dilute Solution Characterization by Light  

E-Print Network [OSTI]

polyelectrolyte. The copolymer of maleic acid­sodium salt and di-isobutylene (DIBMA-Na) has a similar salting

Colby, Ralph H.

95

Treatment of a severe alkali burn  

Science Journals Connector (OSTI)

The case history of a 20-year-old male patient who sustained an 85 per cent total body surface area alkali burn to his skin, after falling into a caustic lime pit, is reported. Considerable problems regarding the correct estimate of burn wound depth, predominant location of the deepest burn on the posterior half of the body, appropriate wound coverage, and lack of sufficient skin graft donor sites required a complex treatment plan. Excisions to fascia and intradermal debridement were required to achieve an appropriate bed for wound closure. Five per cent mafenide acetate solution (Sulfamylon) was applied to prevent burn wound sepsis. Human allografts and Biobrane were used extensively to achieve temporary wound closure, to provide mechanical protection of freshly autografted wounds, and to prevent desiccation following application of cultured epidermal autografts on to debrided wounds and split thickness skin grafted donor sites. The case illustrates a number of problems associated with the evaluation and treatment of patients suffering severe alkali burns, and demonstrates the implementation of both established and evolving technologies in the management of these injuries.

D. Erdmann; J. Hussmann; J.O. Kucan

1996-01-01T23:59:59.000Z

96

E-Print Network 3.0 - asymmetric salt ion Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in multilayers of weak polyelectrolytes: A neutron reflectometry study Summary: of salt ions and water in thin poly acrylic acid and poly allylamine hydrochloride...

97

Vitrification of IFR and MSBR halide salt reprocessing wastes  

SciTech Connect (OSTI)

Both of the genuinely sustainable (breeder) nuclear fuel cycles (IFR - Integral Fast Reactor - and MSBR - Molten Salt Breeder Reactor -) studied by the USA's national laboratories would generate high level reprocessing waste (HLRW) streams consisting of a relatively small amount ( about 4 mole %) of fission product halide (chloride or fluoride) salts in a matrix comprised primarily (about 95 mole %) of non radioactive alkali metal halide salts. Because leach resistant glasses cannot accommodate much of any of the halides, most of the treatment scenarios previously envisioned for such HLRW have assumed a monolithic waste form comprised of a synthetic analog of an insoluble crystalline halide mineral. In practice, this translates to making a 'substituted' sodalite ('Ceramic Waste Form') of the IFR's chloride salt-based wastes and fluoroapatite of the MSBR's fluoride salt-based wastes. This paper discusses my experimental studies of an alternative waste management scenario for both fuel cycles that would separate/recycle the waste's halide and immobilize everything else in iron phosphate (Fe-P) glass. It will describe both how the work was done and what its results indicate about how a treatment process for both of those wastes should be implemented (fluoride and chloride behave differently). In either case, this scenario's primary advantages include much higher waste loadings, much lower overall cost, and the generation of a product (glass) that is more consistent with current waste management practices. (author)

Siemer, D.D. [Idaho National Laboratory, 12N 3167E, Idaho Falls, ID 83402 (United States)

2013-07-01T23:59:59.000Z

98

Application of inorganic aluminum salts to intensification of the clarification of cinder and oil-containing waste water  

SciTech Connect (OSTI)

The effects of inorganic coagulants together with polyacrylamide (PAA) were tested in waste water containing oil and finely dispersed cinder. It has been established that concentrated solutions of aluminum salts have the maximal clarification efficiency (82%). It has been shown that the residual alkali content of water is higher when concentrated (20%) solutions of aluminum salts are used than in the case of the use of dilute (1%) solutions. The expediency of the use of aluminum salts for the treatment of waste water with a low initial alkalinity (below 1.0 meq/liter) has been established. It has been established that aluminum sulfate is maximally effective when the alkali content of the water being purified is less than 1.8 or greater than 4.5 meq/liter.

Shub, V.B.; Khukhryanskaya, I.A.

1987-10-10T23:59:59.000Z

99

Ancient Salt Beds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

North Carolina School of Medicine. In examining fluid inclusions in the salt and solid halite crystals, scientists found abundant cellulose microfibers, estimated to be 250 million...

100

Inside Sea Salt | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sea salt particles are emitted into the atmosphere by the action of ocean waves and bubble bursting at the ocean surface. They are ubiquitous in the atmospheric environment....

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ethanol fermentation of cassava starch pretreated with alkali  

SciTech Connect (OSTI)

In view of the current industrial process for the conventional ethanol fermentation, in which raw starch materials are heated at 120 degrees C for 2 h, conditions for an alternative process were set: an overall time from saccharification to ethanol fermentation of within 3-4 days, an operation temperature of below 60 degrees C, an ethanol yield of over 93%, and a ratio of raw material to fermentation volume of within 1:4. To meet these conditions, previously a steeping method of starch materials in 0.5N HCl solution at 60 degrees C for 12 h were used, followed by combined actions of ..cap alpha..-amylase and glucoamylase. The ethanol yield from uncooked cassava starch treated under the conditions described was 95% after fermentation for 3 days with Saccharomyces cerevisiae. However, the use of a relatively higher concentration of acid for steeping is still a problem and gelatinization of starch materials is insufficient. This communication, therefore, describes effects of alkali steeping and structural change of starch granules on the ethanol fermentation. 8 references.

Shin, Y.C.; Lee, S.Y.; Choe, Y.K.; Kim, H.S.; Byun, S.M.

1986-04-01T23:59:59.000Z

102

Crystallization of rhenium salts in a simulated low-activity waste borosilicate glass  

SciTech Connect (OSTI)

This study presents a new method for looking at the solubility of volatile species in simulated low-activity waste glass. The present study looking at rhenium salts is also applicable to real applications involving radioactive technetium salts. In this synthesis method, oxide glass powder is mixed with the volatiles species, vacuum-sealed in a fused quartz ampoule, and then heat-treated under vacuum in a furnace. This technique restricts the volatile species to the headspace above the melt but still within the sealed ampoule, thus maximizing the volatile concentration in contact with the glass. Various techniques were used to measure the solubility of rhenium in glass and include energy dispersive spectroscopy, wavelength dispersive spectroscopy, laser ablation inductively-coupled plasma mass spectroscopy, and inductively-coupled plasma optical emission spectroscopy. The Re-solubility in this glass was determined to be ~3004 parts per million Re atoms. Above this concentration, the salts separated out of the melt as inclusions and as a low viscosity molten salt phase on top of the melt observed during and after cooling. This salt phase was analyzed with X-ray diffraction, scanning electron microscopy as well as some of the other aforementioned techniques and identified to be composed of alkali perrhenate and alkali sulfate.

Riley, Brian J.; McCloy, John S.; Goel, Ashutosh; Liezers, Martin; Schweiger, Michael J.; Liu, Juan; Rodriguez, Carmen P.; Kim, Dong-Sang

2013-04-01T23:59:59.000Z

103

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

The high temperature alkali corrosion kinetics of SiC have been systematically investigated from 950 to 1100[degrees]C at 0.63 vol % alkali vapor concentration. The corrosion rate in the presence of alkaliis approximately 10[sup 4] to 10[sup 5] times faster than the oxidation rate of SiC in air. The activation energy associated with the alkali corrosion is 406 kJ/mol, indicating a highly temperature-dependent reaction rate. The rate-controlling step of the overall reaction is likely to be the dissolution of silica in the sodium silicate liquid, based on the oxygen diffusivity data.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-02-24T23:59:59.000Z

104

Electrodialysis-based separation process for salt recovery and recycling from waste water  

SciTech Connect (OSTI)

A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants-containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid. 6 figs.

Tsai, S.P.

1997-07-08T23:59:59.000Z

105

Electrodialysis-based separation process for salt recovery and recycling from waste water  

DOE Patents [OSTI]

A method for recovering salt from a process stream containing organic contaminants is provided, comprising directing the waste stream to a desalting electrodialysis unit so as to create a concentrated and purified salt permeate and an organic contaminants containing stream, and contacting said concentrated salt permeate to a water-splitting electrodialysis unit so as to convert the salt to its corresponding base and acid.

Tsai, Shih-Perng (Naperville, IL)

1997-01-01T23:59:59.000Z

106

Method for removal of heavy metal from molten salt in IFR fuel pyroprocessing  

SciTech Connect (OSTI)

This report details the pyrometallurgical process for recycling spent metal fuels from the Integral Fast Reactor (IFR) which involves electrorefining spent fuel in a molten salt electrolyte (LiCl-KCI-U/PuCl{sub 3}) at 500{degree}C. The total heavy metal chloride concentration in the salt will be about 2 mol %. At some point, the concentrations of alkali, alkaline earth, and rare earth fission products in the salt must be reduced to lower the amount of heat generated in the electrorefiner. The heavy metal concentration in the salt must be reduced before removing the fission products from the salt. The operation uses a lithium-cadmium alloy anode that is solid at 500{degree}C, a solid mandrel cathode with a ceramic catch crucible below to collect heavy metal that falls off it, and a liquid cadmium cathode. The design criteria that had to be met by this equipment included the following: (1) control of the reduction rate by lithium, (2) good separation between heavy metal and rare earths, and (3) the capability to collect heavy metal and rare earths over a wide range of salt compositions. In tests conducted in an engineering-scale electrorefiner (10 kg uranium per cathode), good separation was achieved while removing uranium and rare earths from the salt. Only 13% of the rare earths was removed, while 99.9% of the uranium in the salt was removed; subsequently, the rare earths were also reduced to low concentrations. The uranium concentration in the salt was reduced to 0.05 ppm after uranium and rare earths were transferred from the salt to a solid mandrel cathode with a catch crucible. Rare earth concentrations in the salt were reduced to less than 0.01 wt % in these operations. Similar tests are planned to remove plutonium from the salt in a laboratory-scale (100--300 g heavy metal) electrorefiner.

Gay, E.C.; Miller, W.E.; Laidler, J.J.

1994-02-01T23:59:59.000Z

107

Gabbs Alkali Flat Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Gabbs Alkali Flat Geothermal Area Gabbs Alkali Flat Geothermal Area (Redirected from Gabbs Alkali Flat Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Gabbs Alkali Flat Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (2) 10 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0

108

The 4843 Alkali Metal Storage Facility Closure Plan  

SciTech Connect (OSTI)

The 4843 AMSF has been used primarily to provide a centralized building to receive and store dangerous and mixed alkali metal waste, including sodium and lithium, which has been generated at the Fast Flux Test Facility and at various other Hanford Site operations that used alkali metals. Most of the dangerous and mixed alkali metal waste received consists of retired equipment from liquid sodium processes. The unit continues to store material. In general, only solid alkali metal waste that is water reactive is stored at the 4843 AMSF. The 4843 AMSF will be closed in a manner consistent with Ecology guidelines and regulations (WAC 173-303-610). The general closure procedure is detailed as follows.

Not Available

1991-06-01T23:59:59.000Z

109

E-Print Network 3.0 - alkali vaporisation titandioxidadditiv...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

PARTICULATES 4.2.2004 5-1 Chapter 5 Particulates Summary: hundred degrees lower than for coal in order to avoid loss of alkali by vaporisation. Typical values... , aluminum and...

110

CHARGE TRANSFER BETWEEN POSITIVE ALKALI IONS AND ATOMS  

E-Print Network [OSTI]

average velocity of atoms , ::. : . . :. . in the oven. Thisfor a potassium ", . atom beam operating under conditionsPOSITIVE ALKALI IONS AND ATOMS I W. R. Gentry, Yuan-tseh L e

Gentry, W.R.; Lee, Yuan-tseh; Mahan, Bruce H.

2008-01-01T23:59:59.000Z

111

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

Calcia-stabilized cubic zirconia was mixed with soda, then fired at 840-1100 C. SiC was also reacted with alkali-containing atmosphere at 1000 C.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-11-24T23:59:59.000Z

112

Salt Waste Processing Initiatives  

Broader source: Energy.gov (indexed) [DOE]

Patricia Suggs Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives 2 Overview * Current SRS Liquid Waste System status * Opportunity to accelerate salt processing - transformational technologies - Rotary Microfiltration (RMF) and Small Column Ion Exchange (SCIX) - Actinide Removal Process/Modular Caustic Side Solvent Extraction (ARP/MCU) extension with next generation extractant - Salt Waste Processing Facility (SWPF) performance enhancement - Saltstone enhancements * Life-cycle impacts and benefits 3 SRS Liquid Waste Total Volume >37 Million Gallons (Mgal) Total Curies 183 MCi (51% ) 175 MCi (49% ) >358 Million Curies (MCi) Sludge 34.3 Mgal (92% ) 3.0 Mgal (8%)

113

Amine salts of nitroazoles  

DOE Patents [OSTI]

Compositions of matter, a method of providing chemical energy by burning said compositions, and methods of making said compositions are described. These compositions are amine salts of nitroazoles. 1 figure.

Kienyin Lee; Stinecipher, M.M.

1993-10-26T23:59:59.000Z

114

Salt Selected (FINAL)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

WHY SALT WAS SELECTED AS A DISPOSAL MEDIUM WHY SALT WAS SELECTED AS A DISPOSAL MEDIUM Waste Isolation Pilot Plant U.S. Department Of Energy Government officials and scientists chose the Waste Isolation Pilot Plant (WIPP) site through a selection process that started in the 1950s. At that time, the National Academy of Sciences conducted a nationwide search for geological formations stable enough to contain radioactive wastes for thousands of years. In 1955, after extensive

115

A Dash of Salt  

E-Print Network [OSTI]

tx H2O | pg. 18 A Texas A&M researcher is assessing the impact of using moderately saline water for irrigating urban landscapes in West Texas and southern New Mexico. A DASH OF SALT Researcher assesses salinity impacts on grasses, trees... and shrubs A Dash of Salt Story by Danielle Supercinski { } tx H2O | pg. 19 ?The primary purpose of using moderately saline water for irrigation, including reclaimed water, is to conserve potable [drinkable] water,? said Dr. Seiichi Miyamoto, a...

Supercinski, Danielle

2006-01-01T23:59:59.000Z

116

Metal-insulator transition in expanded alkali-metal fluids and alkali-metal—rare-gas films  

Science Journals Connector (OSTI)

We have developed a theoretical model for expanded alkali metals and alkali-metal—rare-gas films that is based on a physically realistic picture of the atomic-scale structure of these materials. It emphasizes the disorder in the systems, in particular the random atomic coordination number. Using this model we have calculated the density- and the energy-dependent conductivity as a function of the mean alkali-metal atomic coordination number. Although the theory contains only two parameters, both of which are fixed by the properties of pure materials at normal temperatures, we have been able to explain results measured over a temprature range from 4.2 to >2000 K in a variety of different alkali-metal systems. Conductivity and magnetic-susceptibility measurements, in particular, have been considered in some detail. In addition, the theory provides insight into the nature and location of the metal-insulator transition, the nature of the critical point for the alkali metals, and the thermal instability of the alkali-metal—rare-gas films.

Judy R. Franz

1984-02-15T23:59:59.000Z

117

The reaction dynamics of alkali dimer molecules and electronically excited alkali atoms with simple molecules  

SciTech Connect (OSTI)

This dissertation presents the results from the crossed molecular beam studies on the dynamics of bimolecular collisions in the gas phase. The primary subjects include the interactions of alkali dimer molecules with simple molecules, and the inelastic scattering of electronically excited alkali atoms with O{sub 2}. The reaction of the sodium dimers with oxygen molecules is described in Chapter 2. Two reaction pathways were observed for this four-center molecule-molecule reaction, i.e. the formations of NaO{sub 2} + Na and NaO + NaO. NaO{sub 2} products exhibit a very anisotropic angular distribution, indicating a direct spectator stripping mechanism for this reaction channel. The NaO formation follows the bond breaking of O{sub 2}, which is likely a result of a charge transfer from Na{sub 2} to the excited state orbital of O{sub 2}{sup {minus}}. The scattering of sodium dimers from ammonium and methanol produced novel molecules, NaNH{sub 3} and Na(CH{sub 3}OH), respectively. These experimental observations, as well as the discussions on the reaction dynamics and the chemical bonding within these molecules, will be presented in Chapter 3. The lower limits for the bond dissociation energies of these molecules are also obtained. Finally, Chapter 4 describes the energy transfer between oxygen molecules and electronically excited sodium atoms.

Hou, H. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry]|[Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

1995-12-01T23:59:59.000Z

118

Process and apparatus for obtaining silicon from fluosilicic acid  

DOE Patents [OSTI]

Process for producing low cost, high purity solar grade Si wherein a reduction reaction, preferably the reduction of SiF.sub.4, by an alkali metal (Na preferred) is carried out inside a reaction chamber. The chamber wall and bottom surfaces are configured so as to facilitate the continuous separation of the products of reaction (Si and NaF) and removal of the molten salt by discharging the salt through one or more ports at the bottom of the reaction chamber. Such process is especially useful where it is desirable to discharge the reaction salt products from the reactor and retain silicon within the chamber for later removal.

Nanis, Leonard (Palo Alto, CA); Sanjurjo, Angel (San Jose, CA)

1988-05-31T23:59:59.000Z

119

Fundamental Properties of Salts  

SciTech Connect (OSTI)

Thermal properties of molten salt systems are of interest to electrorefining operations, pertaining to both the Fuel Cycle Research & Development Program (FCR&D) and Spent Fuel Treatment Mission, currently being pursued by the Department of Energy (DOE). The phase stability of molten salts in an electrorefiner may be adversely impacted by the build-up of fission products in the electrolyte. Potential situations that need to be avoided, during electrorefining operations, include (i) fissile elements build up in the salt that might approach the criticality limits specified for the vessel, (ii) electrolyte freezing at the operating temperature of the electrorefiner due to changes in the liquidus temperature, and (iii) phase separation (non-homogenous solution). The stability (and homogeneity) of the phases can be monitored by studying the thermal characteristics of the molten salts as a function of impurity concentration. Simulated salt compositions consisting of the selected rare earth and alkaline earth chlorides, with a eutectic mixture of LiCl-KCl as the carrier electrolyte, were studied to determine the melting points (thermal characteristics) using a Differential Scanning Calorimeter (DSC). The experimental data were used to model the liquidus temperature. On the basis of the this data, it became possible to predict a spent fuel treatment processing scenario under which electrorefining could no longer be performed as a result of increasing liquidus temperatures of the electrolyte.

Toni Y Gutknecht; Guy L Fredrickson

2012-11-01T23:59:59.000Z

120

Tuning of the Metal-Insulator Transition via Alkali Adsorption  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tuning of the Metal-Insulator Tuning of the Metal-Insulator Transition via Alkali Adsorption Tuning of the Metal-Insulator Transition via Alkali Adsorption Print Wednesday, 29 March 2006 00:00 Turning a material from an insulator to a metal, or vice versa, by light irradiation, exposure to electric or magnetic fields, or applying small changes in temperature, pressure, or doping-such intriguing control of a material's electronic properties is possible by exploiting strongly interacting or "correlated" electrons. Now a team of researchers from the University of Kiel in Germany and the ALS has found a novel, surprising way to continuously transform a layered metallic transition-metal compound, TaS2, into an insulator. Using angle-resolved photoemission spectroscopy (ARPES), they have demonstrated that adsorption of alkali atoms onto this material's surface gradually makes it more insulating, although in general, alkali adsorption should lead to more metallic behavior, as alkali atoms easily give away their loosely bound outermost electron.

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Dual effectiveness of lithium salt in controlling both delayed ettringite formation and ASR in concretes  

Science Journals Connector (OSTI)

The influence of lithium nitrate on expansions due to delayed ettringite formation (DEF) and alkali-silica reaction (ASR) has been investigated. Effects of the lithium salt were examined in heat-cured mortars and concretes containing one or both damage mechanisms. The mortars and concretes made using reactive and/or non-reactive aggregates were subjected to heat treatment consisting of a hydration delay period of 4 h at 23 °C followed by steam-curing at 95 °C and then stored in limewater. Results showed that the lithium salt admixture was able to reduce the occurrence of deleterious expansion due to delayed ettringite formation in addition to controlling alkali-silica reaction in cementitious systems containing one or both mechanisms. In concretes made using non-reactive limestone aggregates, incorporation of lithium nitrate in a proportion of 0.74 M ratio of Li to (Na + K) was found to control delayed ettringite formation during the one-year period of this study. By analyzing the leaching properties of lithium and other alkalis from mortars during storage, it was found that a substantial amount of lithium was retained in the cementitious system in a slightly soluble form, and is expected to be responsible for reducing DEF.

S.O. Ekolu; M.D.A. Thomas; R.D. Hooton

2007-01-01T23:59:59.000Z

122

Salt Creek Student Homepage  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Salt Creek Investigation Salt Creek Investigation</2> "Whales Dying in the Pacific Ocean" "Fish Dying in Lake Michigan" Recent headlines remind us of environmental problems near and far away. Scientists have been wondering if these problems could be due to the warmer temperatures this past spring and summer or could there be other reasons? Lack of rain and near drought conditions have forced many areas to restrict water use. We know from past history that pollution affects our drinking water and marine life. Remember what we read about Lake Erie and from reading A River Ran Wild by Lynne Cherry. There are many factors affecting the environment around us . . . even in Salt Creek which runs through our area. We may not be able to investigate the Pacific Ocean and Lake Michigan

123

E-Print Network 3.0 - acid ammonium glycyrrhizate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids, chlorates, nitrites, sulfur, finely... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... Ammonium...

124

E-Print Network 3.0 - acid oxidation held Sample Search Results  

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Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

125

E-Print Network 3.0 - acid oxidation defects-remaining Sample...  

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Calcium oxide Water Carbon (activated) Calcium... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... ,...

126

E-Print Network 3.0 - acidic transition metals Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids, chlorates, nitrites, sulfur, finely... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... , copper,...

127

C-CAMP, A closed cycle alkali metal power system  

SciTech Connect (OSTI)

A concept is presented for a Closed-Cycle Alkali Metal (C-CAMP) power systems which utilizes the heat of reaction of an alkali metal and halogen compound to vaporize an alkali metal turbine fluid for a Rankine cycle. Unique features of the concept are (1) direct contact (heat exchange) between the reaction products and turbine fluid, and (2) a flow-through chemical reactor/boiler. The principal feasibility issues of the concept relate to the degree of cross-mixing of product and turbine fluid streams within the reactor-boiler. If proven feasible, the concept may be adapted to a range of fuel and turbine fluids and ultimately lead to thermal efficiencies in excess of 35%.

Wichner, R.P.; Hoffman, H.W.

1988-01-01T23:59:59.000Z

128

Alkali-metal-halogen charge-exchange collisions  

Science Journals Connector (OSTI)

An approximate quasiclassical treatment is presented for calculating the cross sections for charge transfer from a neutral alkali-metal atom colliding with a halogen atom (chlorine or fluorine). The electron is treated by the time-dependent perturbation in the two-state approximation. The two states are the ground (or the first-excited) state of alkali-metal atom and the ground state of the halogen negative ion. Charge-transfer cross sections are calculated as a function of relative velocity (v) of collision between v=0.01 and 5 a.u. Qualitative features of these cross sections are compared with an earlier work on alkali-metal-oxygen collisions. An asymptotic formula at low velocities of collision v?0 is obtained, which compares with the earlier formula obtained by Bates. At higher velocities cross sections are found to vary as 1v2, as in the Born approximation.

D. Arora; J. E. Turner; P. G. Khubchandani

1976-12-01T23:59:59.000Z

129

Gabbs Alkali Flat Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Gabbs Alkali Flat Geothermal Area Gabbs Alkali Flat Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Gabbs Alkali Flat Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (2) 10 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed.

130

E-Print Network 3.0 - alkali metal intercalates Sample Search...  

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<< < 1 2 3 4 5 > >> 1 Work functions of pristine and alkali-metal intercalated carbon nanotubes and bundles Jijun Zhao,1, Summary: Work functions of pristine and alkali-metal...

131

E-Print Network 3.0 - alkalies Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: the results of a laboratory investigation for the use of high-volume clean-coal ash on mitigating alkali... alkali-silica reaction of the blends was determined...

132

E-Print Network 3.0 - alkali substitutes technical Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on Fly Ash... the results of a laboratory investigation for the use of high-volume clean-coal ash on mitigating alkali... alkali-silica reaction of the blends was determined...

133

E-Print Network 3.0 - alkali Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: the results of a laboratory investigation for the use of high-volume clean-coal ash on mitigating alkali... alkali-silica reaction of the blends was determined...

134

E-Print Network 3.0 - alkalis tuhkan muuntuminen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: the results of a laboratory investigation for the use of high-volume clean-coal ash on mitigating alkali... alkali-silica reaction of the blends was determined...

135

E-Print Network 3.0 - alkali pre-treatments producao Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: the results of a laboratory investigation for the use of high-volume clean-coal ash on mitigating alkali... alkali-silica reaction of the blends was determined...

136

E-Print Network 3.0 - alkali metal iodogallates Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

137

E-Print Network 3.0 - alkali metal astatides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

138

E-Print Network 3.0 - alkali metals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

139

E-Print Network 3.0 - alkali metal 2-aminonicotinates Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

140

E-Print Network 3.0 - alkali metal thermal-to-electric Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

E-Print Network 3.0 - alkali metal perrhenate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

142

E-Print Network 3.0 - alkali metal diphenylamide Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

143

E-Print Network 3.0 - alkali metals analiz Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

144

E-Print Network 3.0 - alkali metal isotopes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

145

E-Print Network 3.0 - alkali metals sintez Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to the usual case of an alkali metal reservoir... to the vacuum pumps or due to adsorption of the alkali atoms onto ... Source: Jin, Deborah - JILA, University of Colorado at...

146

E-Print Network 3.0 - alkali metal alkaline Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with alkali-metals 9, loi, alkaline earth metals l,18 and some of other rare-earth elements 19, 20 have... alkali metals were doped into C60 solids 9 and...

147

Radiolysis of Salts and Long-Term Storage Issues for Both Pure and Impure PuO{sub 2} Materials in Plutonium Storage Containers  

SciTech Connect (OSTI)

The Material Identification and Surveillance (MIS) project sponsored a literature search on the effects of radiation on salts, with focus on alkali chlorides. The goal of the survey was to provide a basis for estimating the magnitude of {alpha} radiation effects on alkali chlorides that can accompany plutonium oxide (PuO{sub 2}) into storage. Chloride radiolysis can yield potentially corrosive gases in plutonium storage containers that can adversely affect long-term stability. This literature search was primarily done to provide a tutorial on this topic, especially for personnel with nonradiation chemistry backgrounds.

Lav Tandon

2000-05-01T23:59:59.000Z

148

Ammoniated salt heat pump  

SciTech Connect (OSTI)

A thermochemical heat pump/energy storage system using liquid ammoniate salts is described. The system, which can be used for space heating or cooling, provides energy storage for both functions. The bulk of the energy is stored as chemical energy and thus can be stored indefinitely. The system is well suited to use with a solar energy source or industrial waste heat.

Haas, W.R.; Jaeger, F.J.; Giordano, T.J.

1981-01-01T23:59:59.000Z

149

Magnetic polarizations of electrons at dislocations in alkali halides  

E-Print Network [OSTI]

interval. 25 NAGNETIC POLARIZATIONS OF ELECTRONS AT DISLOCATIONS IN ALKALI HALIDES 1. INTRODUCTION. The new magnetic effects observed in our laboratory on a number of single crystals of alkali halides are thought to be caused by electrons trapped... on d1slocations. The magnet1c properties are perhaps more interesting as a bas1c contribution to the sc1ence of magnetism than to a knowledge of d. islocations 1n these very pure, optically clear, s1ngle crystals of alkal1 halides. The gross magnet...

McClurg, Gene Roark

2012-06-07T23:59:59.000Z

150

Spin polarizations of photoelectrons emitted by alkali atoms  

E-Print Network [OSTI]

~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ o 55 LXS f OF %BURRS 1 Tso-photon ionization of an ~ atom. ~ . ~ ~ . . ~ ~, ~ 2 ihe photoelectron and the incident radiation. . . . . . ~ 3. ')he transitions fram the ground state substates of an alkali sterne...O and Qe2e ~ ~ ~ Ground state substate populations oi' the alkali atoms f' or &"/& -5o. I"p'- 0'4 ~ Ip? - 'fo ~ X" -0. 0~ 0. 2. . e. ee ~ e ~ e ~ ~ ~ . ~ e ~ e. eee ~ e ~ ~ ~ ~ ~ t Spin polaris. zations of the photoelectrons forX. /X. 50e (p? ~10 Vo t 7...

Stuart, Kenneth Charles

2012-06-07T23:59:59.000Z

151

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

152

X-ray-edge problem in metals. II. Alkali-metal atoms adsorbed on alkali and other metal surfaces  

Science Journals Connector (OSTI)

Outer-core spectra are reported for Cs and Rb adsorbed on clean surfaces of the alkali metals and Mg. In most cases the spectrum at threshold resembles a broadened resonance line close to the energy of the atomic transition, with additional structure on the high-energy side. With increasing electron density of the substrate, the line broadens and disappears into a profile which increases approximately linearly from zero at a red-shifted threshold. In no case does the adsorbate spectrum resemble the sharp edge and overshoot observed for the bulk metal. Above about one monolayer in many cases, a discrete feature occurs on the red wing of the threshold line and grows systematically with coverage into the dominant spectrum of the pure bulk adsorbate at about 5 monolayers. The general behavior is qualitatively consistent with the behavior of alkali-alkali alloys, reported in the paper which immediately precedes this one.

Doon Gibbs; T.-H. Chiu; J. E. Cunningham; C. P. Flynn

1985-07-15T23:59:59.000Z

153

96 CEREAL CHEMISTRY Comparison Between Alkali and Conventional Corn Wet-Milling: 100-g Procedures  

E-Print Network [OSTI]

96 CEREAL CHEMISTRY Comparison Between Alkali and Conventional Corn Wet-Milling: 100-g Procedures S ABSTRACT Cereal Chem. 76(1):96-99 A corn wet-milling process in which alkali was used was studied as an alternative to the conventional corn wet-milling procedure. In the alkali wet-milling process, corn was soaked

154

E-Print Network 3.0 - acids electronic resource Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Dicarboxylic Acid Clusters with Water Molecules Summary: Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters... -phase...

155

E-Print Network 3.0 - acid electronic resource Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Dicarboxylic Acid Clusters with Water Molecules Summary: Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters... -phase...

156

TRANSMISSION ELECTRON MICROSCOPY OF WEAKLY DEFORMED ALKALI HALIDE CRYSTALS  

E-Print Network [OSTI]

377 TRANSMISSION ELECTRON MICROSCOPY OF WEAKLY DEFORMED ALKALI HALIDE CRYSTALS H. STRUNK Max'importance croissante du durcissement de la solution solide. Abstract. 2014 Transmission electron microscopy (TEM Abstracts 7j66 - 7 I' 1. Introduction. - It is only some years ago that transmission electron microscopy

Boyer, Edmond

157

Core repulsion e ects in alkali trimers R. Gu erout  

E-Print Network [OSTI]

.e. molecules exhibiting a permanent electric dipole moment). Elementary chemical reactions at very low separation, involved when the potential energy surfaces of alkali trimers are calculated with a quantum-parity violation [10, 11, 12], and the time-independence of the electron- to-nuclear and nuclear-to-nuclear mass

Recanati, Catherine

158

Salt Creek Scenario  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Scenario Scenario HELP Index Summary Scenario References Student Pages Two branches of Salt Creek run through the city of Rolling Meadows, Illinois, not far from our school. Five members of our team of eighth grade teachers from different subject areas (science, language arts, bilingual education and special education), decided to develop an interdisciplinary study of Salt Creek as a way of giving our students authentic experiences in environmental studies. The unit begins when students enter school in August, running through the third week of September, and resuming for three weeks in October. Extension activities based on using the data gathered at the creek continue throughout the school year, culminating in a presentation at a city council meeting in the spring.

159

Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue  

DOE Patents [OSTI]

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

Sharp, David W. (Seabrook, TX)

1980-01-01T23:59:59.000Z

160

Electrodialysis-ion exchange for the separation of dissolved salts  

SciTech Connect (OSTI)

The Department of Energy generates and stores a significant quantity of low level, high level, and mixed wastes. As some of the DOE facilities are decontaminated and decommissioned, additional and possibly different forms of wastes will be generated. A significant portion of these wastes are aqueous streams containing acids, bases, and salts, or are wet solids containing inorganic salts. Some of these wastes are quite dilute solutions, whereas others contain large quantities of nitrates either in the form of dissolved salts or acids. Many of the wastes are also contaminated with heavy metals, radioactive products, or organics. Some of these wastes are in storage because a satisfactory treatment and disposal processes have not been developed. This report describes the process of electrodialysis-ion exchange (EDIX) for treating aqueous wastes streams consisting of nitrates, sodium, organics, heavy metals, and radioactive species.

Baroch, C.J.; Grant, P.J.

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

salt lake city.cdr  

Office of Legacy Management (LM)

Locations of the Salt Lake City Processing and Disposal Sites Locations of the Salt Lake City Processing and Disposal Sites This fact sheet provides information about the Uranium Mill Tailings Radiation Control Act of 1978 Title I processing site and disposal site at Salt Lake City, Utah. These sites are managed by the U.S. Department of Energy Office of Legacy Management. Salt Lake City, Utah, Processing and Disposal Sites Site Descriptions and History Regulatory Setting The former Salt Lake City processing site is located about 4 miles south-southwest of the center of Salt Lake City, Utah, at 3300 South and Interstate 15. The Vitro Chemical Company processed uranium and vanadium ore at the site from 1951 until 1968. Milling operations conducted at the processing site created radioactive tailings, a predominantly sandy material.

162

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

Raistrick, I.D.; Poris, J.; Huggins, R.A.

1980-07-18T23:59:59.000Z

163

Molten salt lithium cells  

DOE Patents [OSTI]

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1982-02-09T23:59:59.000Z

164

Electrochromic Salts, Solutions, and Devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-10-14T23:59:59.000Z

165

Electrochromic Salts, Solutions, and Devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky, T. Mark (Los Alamos, NM)

2008-11-11T23:59:59.000Z

166

Electrochromic salts, solutions, and devices  

DOE Patents [OSTI]

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Burrell, Anthony K. (Los Alamos, NM); Warner, Benjamin P. (Los Alamos, NM); McClesky,7,064,212 T. Mark (Los Alamos, NM)

2006-06-20T23:59:59.000Z

167

Batteries using molten salt electrolyte  

DOE Patents [OSTI]

An electrolyte system suitable for a molten salt electrolyte battery is described where the electrolyte system is a molten nitrate compound, an organic compound containing dissolved lithium salts, or a 1-ethyl-3-methlyimidazolium salt with a melting temperature between approximately room temperature and approximately 250.degree. C. With a compatible anode and cathode, the electrolyte system is utilized in a battery as a power source suitable for oil/gas borehole applications and in heat sensors.

Guidotti, Ronald A. (Albuquerque, NM)

2003-04-08T23:59:59.000Z

168

Acemetacin cocrystals and salts: structure solution from powder X-ray data and form selection of the piperazine salt  

Science Journals Connector (OSTI)

Multi-component crystals of the anti-inflammatory drug acemetacin were prepared by melt crystallization and their X-ray crystal structures solved using single-crystal and high-resolution powder X-ray diffraction (PXRD) data. The acemetacin-para-aminobenzoic acid adduct and the acemetacin piperazine salt are stable to hydration in the aqueous medium (up to 24 h).

Sanphui, P.

2014-02-28T23:59:59.000Z

169

Metal-insulator transition in dilute alkali-metal systems  

Science Journals Connector (OSTI)

The metal-insulator transition is studied for dilute systems of alkali metals. Using a spin-split self-consistent band-structure approach, we find the transition density, a strikingly enhanced magnetic susceptibility, and the electron effective mass. The critical density nc is found to be given by the simple relation rsc=r0+2.8. Here rsc=[3(4?nc)]13 and r0 is the model potential radius which is roughly the radius of the neutral atom. The Mott criterion of nc13aB?0.25 (where aB is the appropriate Bohr orbit) is found to be inadequate for describing these systems. The predicted effective mass and magnetic susceptibility enhancements are largest for Li and become systematically smaller for the heavier alkalis. We compare our results for the transition density with two sets of experiments, namely the gas-liquid critical density and the metal-insulator transition for codeposited thick films of alkali-metal and rare-gas atoms. Good agreement is found in both cases.

J. H. Rose

1981-01-15T23:59:59.000Z

170

Chemistry and mechanism of molten-salt catalysts in coal-gasification processes. Final report, January 1984-January 1985  

SciTech Connect (OSTI)

Alkali metal salts have been recognized as effective catalysts in coal gasification. However, the presence of reducing gases, in particular carbon monoxide, has recently been shown to have serious inhibitory effects on the catalyst performance. This program has addressed the question of the chemical interactions between carbon monoxide gas containing mixtures and the salt catalysts in liquid form by probing the solution chemistry by dynamic electrochemical techniques. The results of this study show that oxalate ions are formed by the reaction between carbonate ions and carbon monoxide gas. At temperatures above 700/sup 0/C, sulfate ions are directly attacked by carbon monoxide. The oxalate ions are electroactive and their electrochemistry has been studied and found to involve adsorption of oxalate and formation of reactive intermediates. The pathway likely involves an ECE sequence. The formation of active adsorbed species such as oxalate or sulfides at high temperature may be the means by which catalytic function of the salts is inhibited.

White, S.H.; Twardoch, U.M.

1985-02-01T23:59:59.000Z

171

Molten Metal Treatment by Salt Fluxing with Low Environmental Emissions  

SciTech Connect (OSTI)

Abstract: Chlorine gas is traditionally used for fluxing of aluminum melt for removal of alkali and alkaline earth elements. However this results in undesirable emissions of particulate matter and gases such as HCl and chlorine, which are often at unacceptable levels. Additionally, chlorine gas is highly toxic and its handling, storage, and use pose risks to employees and the local community. Holding of even minimal amounts of chlorine necessitates extensive training for all plant employees. Fugitive emissions from chlorine usage within the plant cause accelerated corrosion of plant equipment. The Secondary Aluminum Maximum Achievable Control Technology (MACT) under the Clean Air Act, finalized in March 2000 has set very tough new limits on particulate matter (PM) and total hydrogen chloride emissions from aluminum melting and holding furnaces. These limits are 0.4 and 0.1 lbs per ton of aluminum for hydrogen chloride and particulate emissions, respectively. Assuming new technologies for meeting these limits can be found, additional requirements under the Clean Air Act (Prevention of Significant Deterioration and New Source Review) trigger Best Available Control Technology (BACT) for new sources with annual emissions (net emissions not expressed per ton of production) over specified amounts. BACT currently is lime coated bag-houses for control of particulate and HCl emissions. These controls are expensive, difficult to operate and maintain, and result in reduced American competitiveness in the global economy. Solid salt fluxing is emerging as a viable option for the replacement of chlorine gas fluxing, provided emissions can be consistently maintained below the required levels. This project was a cooperative effort between the Ohio State University and Alcoa to investigate and optimize the effects of solid chloride flux addition in molten metal for alkali impurity and non-metallic inclusion removal minimizing dust and toxic emissions and maximizing energy conservation. In this program, the salt metal interactions were studies and the emissions at laboratory scale at OSU were monitored. The goal of the project was to obtain a fundamental understanding, based on first principles, of the pollutant formation that occurs when the salts are used in furnaces. This information will be used to control process parameters so that emissions are consistently below the required levels. The information obtained in these experiments will be used in industrial furnaces at aluminum plants and which will help in optimizing the process.

Yogeshwar Sahai

2007-07-31T23:59:59.000Z

172

Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Consuming Chlor-Alkali Cell Oxygen-Consuming Chlor-Alkali Cell Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide Formation Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. Available for thumbnail of Feynman Center (505) 665-9090 Email Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide Formation Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth.

173

Plant salt-tolerance mechanisms  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

2014-06-01T23:59:59.000Z

174

E-Print Network 3.0 - alkali feldspars ii Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leaching is spatially heterogeneous on some altered alkali Z .feldspar surfaces Gout et al., 1997 . Similar... weathering: II. Observation of feldspars from soils. Geochim....

175

E-Print Network 3.0 - alkali-metal vapor cells Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dispenser source Timothy M. Roach and Dwayne Henclewood Summary: pressurized storage tank, or by laser ablation, or, most typically for rubidium and other alkali metals......

176

E-Print Network 3.0 - alkali metal rhenium Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

square as a solution-phase sensing assembly (uorescent assembly) for alkali metal ions. 2... fragments as corners. Despite the fact that rhenium is a ... Source: Hupp, Joseph...

177

E-Print Network 3.0 - alkali modified sbn Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

adsorbate is ionised on the surface and that the alkali core is not modified by the adsorption. We... Review Excited states in the alkalinoble ... Source: Bauer, Michael -...

178

E-Print Network 3.0 - alkali ion scattering Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 Floppy modes and the Boson peak in crystalline and amorphous silicates: an inelastic neutron scattering study Summary: ion from Li+ to K+ in the alkali disilicate glasses,...

179

E-Print Network 3.0 - alkali alkaline earth Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Waterloo Collection: Chemistry 2 GEOL 305 Lecture 5 Felsic MaficIntermediate Summary: rare rhyolite Calc-alkaline and tholeiite basalts common, with less alkali basalt Mafic...

180

E-Print Network 3.0 - alkali carbonate reactions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

de mathmatiques Collection: Mathematics 14 REFRACTORIES FOR HAZARDOUS WASTE INCINERATION AN OVERVIEW Summary: to be upgraded. How ever, alkali reactions may still occur....

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Evaluation of concrete structures affected by alkali-silica reaction and delayed ettringite formation.  

E-Print Network [OSTI]

??Alkali-silica reaction (ASR) and delayed ettringite formation (DEF) are expansive reactions that can lead to the premature deterioration of concrete structures. Both have been implicated… (more)

Giannini, Eric Richard

2012-01-01T23:59:59.000Z

182

Nondestructive evaluation of reinforced concrete structures affected by alkali-silica reaction and delayed ettringite formation.  

E-Print Network [OSTI]

??Alkali-silica reaction (ASR) and delayed ettringite formation (DEF) deterioration have been a problem for the concrete infrastructure in the state of Texas and around the… (more)

Kreitman, Kerry Lynn

2011-01-01T23:59:59.000Z

183

Accelerated test methods for evaluating alkali-silica reactivity of recycled concrete aggregates.  

E-Print Network [OSTI]

??This thesis reports the findings of a study carried out to determine the effectiveness of Accelerated Tests in evaluating the Alkali-Silica Reactivity of Recycled Concrete… (more)

Johnson, Robert C (Author)

2011-01-01T23:59:59.000Z

184

E-Print Network 3.0 - alkali sulfate aerosol Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aerosol Formation during... " and "Mechanism of Alkali Sulfate Aerosols Formation during Biomass Combustion" describe the development... the ... Source: Ris National Laboratory...

185

E-Print Network 3.0 - alkali halides irradiated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

U ET ASSOCIATIONS DE CENTRES COLORES ATOMIC HYDROGEN CENTRES IN IONIC CRYSTALS Summary: . Abstract. - Experimental and theoretical work on atomic hydrogen centres in alkali halides...

186

Independent Oversight Assessment, Salt Waste Processing Facility...  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department of Energy...

187

The reaction of cesium hydroxide with 4-phenylvaleric acid  

E-Print Network [OSTI]

Alkali Metal Hycroxide Solutions Used in Potentio- metric and Spectrophotometric Titrations with 4-Phenylvaleric Acid 17 Samples for Nuclear Magnetic Resonance Spectra 18 Concentration of 4-Phenylvaleric Acid in Carbon Tetrachloride for Infrared.... Similarly, nuclear magnetic resonance techniques may be used to determine whether any TT-bonding involving the phenyl ring of 4- phenylvaleric acid occurs during its reaction with cesium hydroxide. If any such bonding to the n-electrons of the ring occurs...

Caughfield, Arvie Jeane

2012-06-07T23:59:59.000Z

188

E-Print Network 3.0 - acids reduce body Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

that is causing thialkalosis. Thus, the Pa... Bio390 ACID-BASE thanks to Dr. J.F. Anderson, Dept Zoology Univ of Florida, Gainesville... " "acid" ) log( "salt" "acid"...

189

1 INTRODUCTION Delayed Ettringite Formation (DEF) and Alkali-Aggregate Reaction (AAR) are both internal  

E-Print Network [OSTI]

1 INTRODUCTION Delayed Ettringite Formation (DEF) and Alkali-Aggregate Reaction (AAR) are both to produce potentially expansive ettringite in the set concrete. AAR may affect concretes cast with aggregate combined delayed ettringite formation and alkali aggregate reaction R.-P. Martin, J.-C. Renaud & F

Paris-Sud XI, Université de

190

Thermodynamic Properties Of Alkali Species In Coal Based Combined Cycle Power Systems  

SciTech Connect (OSTI)

The aim of this project is to support the development of a concept for a successful alkali removal. Two strategies are possible: optimizing the alkali retention potential of the coal ash slag in the combustion chamber and the liquid slag separators and separate alkali removal with solid sorbents (getters) at temperatures below 1450 C. Therefore in a first step the alkali partial pressure over coal ash slag should be determined in order to get information about the retention potential of the slag. The influence of additives on the retention potential of the slag should be investigated. The measurements should show if the alkali partial pressure over the slag is generally low enough in case of thermodynamic equilibrium. In case of too high alkali partial pressures a separate alkali removal is needed. Therefore in a second step commercial sorbent materials should be investigated concerning their sorption potential for alkalis. To get information about the influence of getter components on the sorption potential some mixtures of pure components, predicted by thermodynamic modeling to be most effective, should be investigated.

Willenborg, W.; Wolf, K.J.; Fricke, C.; Moeller, M.; Prikhodovsky, A.; Hilpert, K.; Singheiser, L.

2002-09-20T23:59:59.000Z

191

A Study of Novel Hexavalent Phosphazene Salts as Draw Solutes in Forward Osmosis  

SciTech Connect (OSTI)

Two novel multi-valent salts based on phosphazene chemistry have been synthesized and characterized as forward osmosis (FO) draw solutes. Commercially obtained hexachlorocyclotriphosphazene was reacted with the sodium salt of 4-ethylhydroxybenzoate to yield hexa(4-ethylcarboxylatophenoxy)phosphazene. Hydrolysis, followed by and neutralization with NaOH or LiOH, of the resulting acidic moieties yielded water soluble sodium and lithium phosphazene salts, respectively. Degrees of dissociation were determined through osmometry over the range of 0.05-0.5 m, giving degrees of 3.08-4.95 per mole, suggesting a high osmotic potential. The Li salt was found to be more ionized in solution than the sodium salt, and this was reflected in FO experiments where the Li salt gave higher initial fluxes (~ 7 L/m2h) as compared to the sodium salt (~6 L/m2h) at identical 0.07 m draw solution concentrations at 30 °C. Longer term experiments revealed no detectable degradation of the salts; however some hydrolysis of the cellulose acetate membrane was observed, presumably due to the pH of the phosphazene salt draw solution (pH = ~8).

Mark L. Stone; Aaron D. Wilson; Mason K. Harrup; Frederick F. Stewart

2013-03-01T23:59:59.000Z

192

Alkali-metal-atom chemisorption onto a metal surface  

Science Journals Connector (OSTI)

Recent theoretical and experimental work implies that an alkali-metal atom chemisorbed onto a metal surface can be viewed within a ‘‘dressed-atom’’ picture, i.e., as an atom whose wave functions are perturbed due to its interaction with the surrounding host lattice. This picture is similar to that used for a noble-gas atom physisorbed onto a metal surface. Such an approach utilizes the calculational method of the coupled–Hartree-Fock theory, and it is applied in the present work to the chemisorption of a potassium atom onto a semi-infinite Na(001) substrate. Results for the Hartree-Fock ground state of the chemisorbed K atom, its induced dipole moment, and induced splitting of its p-orbital states are calculated at various substrate-adatom separations. It has been found that the induced dipole moment exhibits a maximum in its absolute value as the metal-adatom separation changes; most of the contribution to the dipole moment is due to the 3s- and 4s-electron states, while the pz states have been found to be counterpolarized, i.e., they polarize toward the vacuum side. On the other hand, the calculated dipole moments of the adatom were found to be too small to account for the observed work-function changes during alkali-metal chemisorption on a mteal surface.

A. N. Andriotis

1990-11-15T23:59:59.000Z

193

Freshwater fish in salt water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freshwater fish in salt water Freshwater fish in salt water Name: Shannon Location: N/A Country: N/A Date: N/A Question: What would actually happen if a fresh water fish had to live in salt water? Replies: For most fish, they would die. But some, like eels and salmon, can move freely between the two at certain stages of their lives. To do this they have special mechanisms of excretion and absorption of salt and water. --ProfBill If you put a freshwater fish into saltwater, most fish would lose weight (from losing water from its body) and eventually die. Approximately 2% of all 21000 species of fish actually move from freshwater to saltwater or from salt to fresh at some point in their lives, the move would kill any other fish. But even with these special varieties of fish, the move must be gradual so their bodies can adjust, or they too, will die from the change. If you want to learn more about why the freshwater fish will lose water, (or why a saltwater fish in freshwater would gain water), look up the words "diffusion" and "osmosis"

194

Fracture and Healing of Rock Salt Related to Salt Caverns  

SciTech Connect (OSTI)

In recent years, serious investigations of potential extension of the useful life of older caverns or of the use of abandoned caverns for waste disposal have been of interest to the technical community. All of the potential applications depend upon understanding the reamer in which older caverns and sealing systems can fail. Such an understanding will require a more detailed knowledge of the fracture of salt than has been necessary to date. Fortunately, the knowledge of the fracture and healing of salt has made significant advances in the last decade, and is in a position to yield meaningful insights to older cavern behavior. In particular, micromechanical mechanisms of fracture and the concept of a fracture mechanism map have been essential guides, as has the utilization of continuum damage mechanics. The Multimechanism Deformation Coupled Fracture (MDCF) model, which is summarized extensively in this work was developed specifically to treat both the creep and fracture of salt, and was later extended to incorporate the fracture healing process known to occur in rock salt. Fracture in salt is based on the formation and evolution of microfractures, which may take the form of wing tip cracks, either in the body or the boundary of the grain. This type of crack deforms under shear to produce a strain, and furthermore, the opening of the wing cracks produce volume strain or dilatancy. In the presence of a confining pressure, microcrack formation may be suppressed, as is often the case for triaxial compression tests or natural underground stress situations. However, if the confining pressure is insufficient to suppress fracture, then the fractures will evolve with time to give the characteristic tertiary creep response. Two first order kinetics processes, closure of cracks and healing of cracks, control the healing process. Significantly, volume strain produced by microfractures may lead to changes in the permeability of the salt, which can become a major concern in cavern sealing and operation. The MDCF model is used in three simulations of field experiments in which indirect measures were obtained of the generation of damage. The results of the simulations help to verify the model and suggest that the model captures the correct fracture behavior of rock salt. The model is used in this work to estimate the generation and location of damage around a cylindrical storage cavern. The results are interesting because stress conditions around the cylindrical cavern do not lead to large amounts of damage. Moreover, the damage is such that general failure can not readily occur, nor does the extent of the damage suggest possible increased permeation when the surrounding salt is impermeable.

Chan, K.S.; Fossum, A.F.; Munson, D.E.

1999-03-01T23:59:59.000Z

195

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect (OSTI)

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

196

Why Sequence Great Salt Lake?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Great Salt Lake? Great Salt Lake? On average, the Great Salt Lake is four times saltier than the ocean and also has heavy metals, high concentrations of sulfur and petroleum seeps. In spite of all this, the lake is the saltiest body of water to support life. The lake hosts brine shrimp, algae and a diverse array of microbes, not to mention the roughly 5 million birds that migrate there annually. The secret to these microbes' ability to survive under such harsh conditions might be revealed in their genes. Researchers expect the genetic data will provide insight into how the microorganisms tolerate pollutants such as sulfur and detoxify pollutants such as sulfur and heavy metals like mercury. The information could then be used to develop bioremediation techniques. Researchers also expect that sequencing microorganisms sampled

197

Fabrication of alkali halide UV photocathodes by pulsed laser deposition  

SciTech Connect (OSTI)

A technique has been proposed for the fabrication of atmospheric corrosion resistant alkali halide UV photocathodes by pulsed laser deposition. We produced photocathodes with a highly homogeneous photoemissive layer well-adherent to the substrate. The photocathodes were mounted in a vacuum photodiode, and a tungsten grid was used as an anode. Using pulsed UV lasers, we carried out experiments aimed at evaluating the quantum efficiency of the photocathodes. With a dc voltage applied between the photocathode and anode grid, we measured a shunt signal proportional to the total charge emitted by the cathode exposed to UV laser light. The proposed deposition technique enables one to produce photocathodes with photoemissive layers highly uniform in quantum efficiency, which is its main advantage over thin film growth by resistive evaporation. (laser technologies)

Brendel', V M; Bukin, V V; Garnov, Sergei V; Bagdasarov, V Kh; Denisov, N N; Garanin, Sergey G; Terekhin, V A; Trutnev, Yurii A

2012-12-31T23:59:59.000Z

198

Comparison of the morphology of alkali–silica gel formed in limestones in concrete affected by the so-called alkali–carbonate reaction (ACR) and alkali–silica reaction (ASR)  

SciTech Connect (OSTI)

The morphology of alkali–silica gel formed in dolomitic limestone affected by the so-called alkali–carbonate reaction (ACR) is compared to that formed in a siliceous limestone affected by alkali–silica reaction (ASR). The particle of dolomitic limestone was extracted from the experimental sidewalk in Kingston, Ontario, Canada that was badly cracked due to ACR. The siliceous limestone particle was extracted from a core taken from a highway structure in Quebec, affected by ASR. Both cores exhibited marked reaction rims around limestone particles. The aggregate particles were polished and given a light gold coating in preparation for examination in a scanning electron microscope. The gel in the ACR aggregate formed stringers between the calcite crystals in the matrix of the rock, whereas gel in ASR concrete formed a thick layer on top of the calcite crystals, that are of the same size as in the ACR aggregate.

Grattan-Bellew, P.E., E-mail: p.grattan-bellew@sympatico.ca [Materials and Petrographic Research G-B Inc., 472 Edison Avenue, Ottawa, ON, Canada K2A 1T9 (Canada); Chan, Gordon [NRC Construction, Bldg., M20, 1200 Montreal Road, Ottawa, ON, Canada K1A 0R6 (Canada)] [NRC Construction, Bldg., M20, 1200 Montreal Road, Ottawa, ON, Canada K1A 0R6 (Canada)

2013-05-15T23:59:59.000Z

199

E-Print Network 3.0 - acid molecules interacting Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University (Kingston) Collection: Biology and Medicine 35 Cluster Phase Chemistry: Gas-Phase Reactions of Anionic Sodium Salts of Dicarboxylic Acid Clusters with Water...

200

E-Print Network 3.0 - acid soluble pepsin Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

protein solubility. Conversely, the acid sensitivity of LP suggests that its salt- bridge arrangement must... H, trypsin is quite stable, whereas pepsin is destabilized. The...

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Process and apparatus for obtaining silicon from fluosilicic acid  

DOE Patents [OSTI]

An apparatus for producing low cost, high purity solar grade Si wherein a reduction reaction, preferably the reduction of SiF.sub.4, by an alkali metal (Na preferred) is carried out inside a reaction chamber. The chamber wall and bottom surfaces are formed of graphite and configured with drainage channels so as to facilitate the continuous separation of the products of reaction (Si and NaF) and removal of the molten salt by discharging the salt through one or more ports at the bottom of the reaction chamber. Such process is especially useful where it is desirable to discharge the reaction salt products from the reactor and retain silicon within the chamber for later removal.

Nanis, Leonard (Palo Alto, CA); Sanjurjo, Angel (San Jose, CA)

1986-04-22T23:59:59.000Z

202

Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry  

SciTech Connect (OSTI)

This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

Baxter, Larry L.

2008-06-09T23:59:59.000Z

203

Salt Lake Community College | .EDUconnections  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

SLCC Partners with DOE's Rocky Mountain Solar Training Program This program is a joint partnership between DOE's Solar Energy Technogies Program, Salt Lake Community College, Solar Energy International, and the Utah Solar Energy Association that works to accelerate use of solar electric technologies, training and facilities at community and technical college solar training programs within a 15 western United States region. DOE Solar Instructor Training Network Salt Lake City, Utah DOE Applauds SLCC's Science and Technical Programs Architectural Technology Biology Biotechnology Biomanufacturing Chemistry Computer Science Electric Sector Training Energy Management Engineering Geographic Information Sciences Geosciences InnovaBio Manufacturing & Mechanical Engineering Technology

204

Salt dome discoveries mounting in Mississippi  

SciTech Connect (OSTI)

Exploratory drilling around piercement salt domes in Mississippi has met with a string of successes in recent months. Exploration of these salt features is reported to have been initiated through the review of non-proprietary, 2D seismic data and subsurface control. This preliminary data and work were then selectively upgraded by the acquisition of additional, generally higher quality, conventional 2D seismic lines. This current flurry of successful exploration and ensuing development drilling by Amerada Hess Corp. on the flanks of salt domes in Mississippi has resulted in a number of significant Hosston discoveries/producers at: Carson salt dome in Jefferson Davis County; Dry Creek salt dome in Covington County, Midway salt dome in lamar County, Monticello salt dome in Lawrence County, and Prentiss salt dome in Jefferson Davis County. The resulting production from these fields is gas and condensate, with wells being completed on 640 acre production units.

Ericksen, R.L. [Mississippi Office of Geology, Jackson, MS (United States)

1996-06-17T23:59:59.000Z

205

Laboratory studies of the sensitivity of tropospheric ozone to the chemistry of sea salt aerosol. Final report, September 15, 1993--September 14, 1994  

SciTech Connect (OSTI)

Ozone plays a critical role in both the chemistry and radiation balance of the troposphere. Understanding the factors controlling tropospheric ozone levels is critical to our understanding of a variety of issues in global chemistry and climate change. Chlorine atoms have the potential to contribute significantly to the ozone balance in the free troposphere. They can react directly with ozone or alternately, with organics and may actually lead to the formation of ozone in the presence of sufficient NO. Reactions of alkali halides in sea salt particles are a potential source of atomic chlorine, hence reactions of these alkali halides, especially those producing precursors to atomic chlorine, are of great interest. Finally, the mechanisms, intermediates and products of the Cl-biogenic reactions are unknown; these could serve as unique markers of chlorine atom chemistry in the troposphere, and hence are important to define.

Finlayson-Pitts, B.J.

1994-11-15T23:59:59.000Z

206

2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) | Open Energy  

Open Energy Info (EERE)

2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Gabbs Alkali Flat Area (Kratt, Et Al., 2008) Exploration Activity Details Location Gabbs Alkali Flat Area Exploration Technique 2-M Probe Activity Date Usefulness useful DOE-funding Unknown Notes More than 100 2-meter-deep temperature measurements were made during two separate surveys that took place in December 2007 and April 2008 (Figure 5). The area covered was 16 km in length parallel to the range front and a maximum of nearly 5 km out into the valley. The highest recorded temperature of 37°C was obtained approximately 100 m upslope from Rawhide hot springs. Near these springs, temperatures rapidly cool towards the

207

E-Print Network 3.0 - alkali clusters formed Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In recent years there have been a number of studies of gas-phase alkali halide cluster ions... reports which found only ions of the ... Source: Lineberger, W. Carl - JILA &...

208

Review of alkali metal and refractory alloy compatibility for Rankine cycle applications  

Science Journals Connector (OSTI)

The principal corrosion mechanisms in refractory metal-alkali systems are dissolution, mass transfer, and impurity reactions. In general, niobium, tantalum, molybdenum, and tungsten have low solubilities in th...

James R. DiStefano

1989-12-01T23:59:59.000Z

209

Catalytic Activity of Alkali Metals on the Thermochemical Conversion of Biomass Materials  

Science Journals Connector (OSTI)

The first reaction in the thermal decomposition of cellulose is very sensitive to the existence of mineral impurities such as alkali metals and iron at concentrations as low as 0.5%. The catalytic reaction app...

Mahmood M. Barbooti

1986-01-01T23:59:59.000Z

210

Photoconductivity of CdS films, undoped and doped with alkali-metal impurity ions  

Science Journals Connector (OSTI)

The nonequilibrium electron processes that occur during photoconductivity increase and relaxation in pyrolytic CdS films, both nominally undoped and doped with alkali metals, are studied. The...S...-shaped or exh...

T. L. Mayorova; V. G. Klyuev; J. S. Bezdetko

2014-07-01T23:59:59.000Z

211

Study on Recycling Alkali from the Wastewater of Textile Mercerization Process by Nanofiltration  

Science Journals Connector (OSTI)

Abstract This study has researched the treatment ability of nanofiltration technology in printing and dyeing mercerization process alkali wastewater and investigated the effect of different pressures and alkalinities on membrane flux. The effect of different operating conditions on COD removal rate and alkali penetration rate has been also investigated in this study. The experimental results show that nanofiltration technology can remove the COD in printing and dyeing mercerization process wastewater effectively and the removal rate is above 80%. We conclude that the membrane flux tends to increase as the operating pressure increases, and decrease as the concentration of alkali in feed liquor and COD increases. The infiltration liquor through membrane can be satisfactorily reused by the method of concentration, and the final recovery efficiency of alkali by nanofiltration membrane treatment is above 90%.

Yun Zhang; Shuai Shao; Weicheng Yu; Fenglin Yang; Xiaochen Xu

2014-01-01T23:59:59.000Z

212

E-Print Network 3.0 - alkali-metal vapor density Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Physics 65 nature physics | VOL 3 | APRIL 2007 | www.nature.comnaturephysics 227 REVIEW ARTICLE Summary: in a high-density alkali-metal vapor in low magnetic fields. Phys....

213

E-Print Network 3.0 - alkali mineral complex Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

complex Page: << < 1 2 3 4 5 > >> 1 Technical Report Documentation Page 1. Report No. Summary: the potential of HVFA concrete in mitigating the effects of alkali-silica...

214

Effects from Alkali-Silica Reacton and Delayed Ettringite Formation on Reinforced Concrete Column Lap Splices  

E-Print Network [OSTI]

Reinforced concrete bridge columns can deteriorate prematurely due to the alkali-silica reaction (ASR) and/or delayed ettringite formation (DEF), causing internal expansion and cracking on the surface of the concrete. The performance...

Eck, Mary

2012-07-16T23:59:59.000Z

215

E-Print Network 3.0 - alkali ion beams Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beams Search Powered by Explorit Topic List Advanced Search Sample search results for: alkali ion beams Page: << < 1 2 3 4 5 > >> 1 METHOD FOR EFFICIENCY AND TIME RESPONSE...

216

Effects from Alkali-Silica Reacton and Delayed Ettringite Formation on Reinforced Concrete Column Lap Splices.  

E-Print Network [OSTI]

??Reinforced concrete bridge columns can deteriorate prematurely due to the alkali-silica reaction (ASR) and/or delayed ettringite formation (DEF), causing internal expansion and cracking on the… (more)

Eck, Mary

2012-01-01T23:59:59.000Z

217

Marine residual fuel sorption and desorption kinetics by alkali treated rice husks  

Science Journals Connector (OSTI)

An oil absorbent material has been produced from waste biomass with an alkali treatment process. The simple yet effective process is carried out on the agricultural biowaste at 90 °C and ambient pressure. The pre...

Alireza Bazargan; Chi Wai Hui; Gordon Mckay

2014-06-01T23:59:59.000Z

218

Laboratory Measurements of Alkali Metal Containing Vapors Released during Biomass Combustion  

Science Journals Connector (OSTI)

Alkali metals, in particular potassium. have been implicated as key ingredients for enhancing fouling and slagging of heat transfer surfaces in power generating facilities that convert biomass to electricity. Whe...

David C. Dayton; Thomas A. Milne

1996-01-01T23:59:59.000Z

219

E-Print Network 3.0 - alkali-silicate glass exposed Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

silicate glass exposed Search Powered by Explorit Topic List Advanced Search Sample search results for: alkali-silicate glass exposed Page: << < 1 2 3 4 5 > >> 1 An 17O NMR...

220

Arylsulfatase Activity in Salt Marsh Soils  

Science Journals Connector (OSTI)

...Arylsulfatase Activity in Salt Marsh Soils R. L. Oshrain W. J. Wiebe...Arylsulfatase Activity in Salt Marsh Soilst R. L. OSHRAIN: AND W...Gallagher, J. L., R. J. Reimold, and D...Remote sensing and salt marsh productivity, p. 338-348...

R. L. Oshrain; W. J. Wiebe

1979-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

The economics of salt cake recycling  

SciTech Connect (OSTI)

The Process Evaluation Section at Argonne National Laboratory (ANL) has a major program aimed at developing cost-effective technologies for salt cake recycling. This paper addresses the economic feasibility of technologies for the recovery of aluminum, salt, and residue-oxide fractions from salt cake. Four processes were assessed for salt recovery from salt cake: (1) base case: leaching in water at 25{degree}C, with evaporation to crystallize salts; (2) high-temperature case: leaching in water at 250{degree}C, with flash crystallization to precipitate salts; (3) solventlantisolvent case: leaching in water at 25{degree}C, concentrating by evaporation, and reacting with acetone to precipitate salts; and (4) electrodialysis: leaching in water at 25{degree}C, with concentration and recovery of salts by electrodialysis. All test cases for salt recovery had a negative present value, given current pricing structure and 20% return on investment. Although manufacturing costs (variable plus fixed) could reasonably be recovered in the sales price of the salt product, capital costs cannot. The economics for the recycling processes are improved, however, if the residueoxide can be sold instead of landfilled. For example, the base case process would be profitable at a wet oxide value of $220/metric ton. The economics of alternative scenarios were also considered, including aluminum recovery with landfilling of salts and oxides.

Graziano, D.; Hryn, J.N.; Daniels, E.J.

1996-03-01T23:59:59.000Z

222

Simple Method for Killing Halophilic Bacteria in Contaminated Solar Salt  

Science Journals Connector (OSTI)

...growth and also to sterilize solar salt. Two samples of solar salt, contaminated with red...it had a much lower buffering capacity than the used salt, presumably...economical method of freeing solar salt from halophilic bacteria...

D. J. Kushner; G. Masson; N. E. Gibbons

1965-03-01T23:59:59.000Z

223

Detection of alkali-silica reaction swelling in concrete by staining  

DOE Patents [OSTI]

A method using concentrated aqueous solutions of sodium cobalt nitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na-K-Ca-Si gels are identified by yellow staining, and alkali-poor, Ca-Si gels are identified by pink staining.

Guthrie, G.D. Jr.; Carey, J.W.

1998-04-14T23:59:59.000Z

224

Detection of alkali-silica reaction swelling in concrete by staining  

DOE Patents [OSTI]

A method using concentrated aqueous solutions of sodium cobaltinitrite and rhodamine B is described which can be used to identify concrete that contains gels formed by the alkali-silica reaction (ASR). These solutions present little health or environmental risk, are readily applied, and rapidly discriminate between two chemically distinct gels; K-rich, Na--K--Ca--Si gels are identified by yellow staining, and alkali-poor, Ca--Si gels are identified by pink staining.

Guthrie, Jr., George D. (Santa Fe, NM); Carey, J. William (Santa Fe, NM)

1998-01-01T23:59:59.000Z

225

Radar investigation of the Hockley salt dome  

E-Print Network [OSTI]

: Geophysics RADAR INVESTIGATION OF THE HOCKLEY SALT DOME A Thesis by UAMES ANDREW HLUCHANEK A'pproved as to style and content by: (Head of Departme t ? Member) May 1. 973 ABSTRACT Radar investigation of the Hockley Salt Dome. . (Nay, 1973) James... Andrew Hluchanek, B. S. , Texas A&M University Directed by: Dr. Robert R. Unterberger Radar probing through salt was accomplished at 17 radar stations established in the United Salt Company mine at Hockley, Texas. The top of the salt dom is mapped...

Hluchanek, James Andrew

2012-06-07T23:59:59.000Z

226

Alkali monolayers on transition metal surfaces: electronic promotion in catalysis  

SciTech Connect (OSTI)

Potassium monolayers on the platinum (111) crystal surface were studied most extensively. Ultraviolet photoelectron spectroscopy showed a large decrease in the work function of the surface when potassium was adsorbed. The heat of desorption of potassium decreased with increasing coverage. Low energy electron diffraction (LEED) showed that potassium forms hexagonal (close packed) overlayer structures. The effects of potassium on the chemisorption of various small molecules on Pt(111) were studied. Oxygen and nitric oxide were readily adsorbed and dissociated by potassium, forming stable potassium-oxide complexes on the surface. Adsorption heat of carbon monoxide on Pt(111) increased with potassium coadsorption. High resolution electron energy loss spectroscopy showed that the carbon-oxygen bond of adsorbed carbon monoxide was weakened by potassium. Adsorption heat of benzene, however, was decreased by coadsorbed potassium. A molecular orbital explanation was given to explain the effects of potassium. CO hydrogenation reactions performed on metal foils showed that the addition of alkali adlayers tends to decrease the overall rate of reaction. Changes in selectivity were noted, shifting the product distribution in favor of higher molecular weight species and from alkanes to alkenes.

Garfunkel, E.

1983-08-01T23:59:59.000Z

227

Chromatographic Enrichment of Acidic Compounds from Organic Solvents Using Alkali Metal Silicates  

Science Journals Connector (OSTI)

......Fox, D.S. Farrier, and R.E. Paulson. Chemical char- acterization and analytical considerations for an in situ oil shale process water. U.S. Department of Energy, LETC/RI-78/7. Laramie Energy Technology Center, Lara- mie, Wyoming......

D.L. Stalling; J.D. Petty; L.M. Smith

1981-01-01T23:59:59.000Z

228

E-Print Network 3.0 - acid based alkali-free Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carboxylic ... Source: Glaser, Rainer - Department of Chemistry, University of Missouri-Columbia Collection: Chemistry 7 GTQ, Chemistry 212, Dr. Glaser, FS96 --1 --GTQ on...

229

High temperature alkali corrosion of ceramics in coal gas. Quarterly progress report No. 3, March 1, 1992--May 31, 1992  

SciTech Connect (OSTI)

High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, zirconia, and fireclay glass. The study consists of identification of the alkali reaction products (phase equilibria) and the kinetics of the alkali reactions as a function of temperature and time.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-05-27T23:59:59.000Z

230

Theory of the alkali-metal chemisorption on metal surfaces  

Science Journals Connector (OSTI)

The electronic structure of the alkali-metal adatom on metal surfaces is studied by a first-principles method as a function of adatom coverage (?). We employ ‘‘jellium’’ as a high-density metal substrate to make a continuous change of ? possible. Although the characteristic variation of the work function with ? is reproduced well by the present calculation, its mechanism is different from a widely accepted mechanism in which the adatom electronic structure is assumed to change from ionic to neutral with increasing ? by the depolarization shift. The charge redistribution ??(r,?) that lowers the work function deviates far from the point-charge-transfer model, and the electrostatic potential change at adatom sites due to ??(r,?) depends very little on ?. Accordingly, the adatom valence density of states shows no downward shift with increasing ?. The adatom region is essentially neutral, even at low ?. The bonding-antibonding boundary in the bond-order density of the adatom-substrate bond coincides well with the Fermi level at low ?, indicating a formation of a metallic bond by the maximum use of bonding states even at low ?. The close similarity between the calculated bond-order and dipole densities as a function of the one-electron energy implies that the adatom polarization due to the hybridization of adatom and substrate orbitals plays an important role for the adatom dipole and its ? dependence even at low ?. The decrease of the adatom dipole is explained by a weakening of the adatom-substrate bonding as well as a significant decrease in the dipole matrix elements with increasing ?.

H. Ishida

1988-10-15T23:59:59.000Z

231

Pyrolysis-Gas Chromatography of Long Chain Fatty Acid Salts  

Science Journals Connector (OSTI)

......points and elemental analysis values of alkyl methyl...in a stainless steel reactor and was heated at 600...After the reaction, the reactor was cooled, and the...order to confirm the reliability of this method. The...Qualitative and quantitative analysis of lipo- phylic groups......

Terumichi Nakagawa; Koichiro Miyajima; Toyozo Uno

1970-05-01T23:59:59.000Z

232

The direct observation of alkali vapor species in biomass combustion and gasification  

SciTech Connect (OSTI)

This report summarizes new data from screening various feedstocks for alkali vapor release under combustion conditions. The successful development of a laboratory flow reactor and molecular beam, mass spectrometer interface is detailed. Its application to several herbaceous and woody feedstocks, as well as a fast-pyrolysis oil, under 800 and 1,100{degrees}C batch combustion, is documented. Chlorine seems to play a large role in the facile mobilization of potassium. Included in the report is a discussion of relevant literature on the alkali problem in combustors and turbines. Highlighted are the phenomena identified in studies on coal and methods that have been applied to alkali speciation. The nature of binding of alkali in coal versus biomass is discussed, together with the implications for the ease of release. Herbaceous species and many agricultural residues appear to pose significant problems in release of alkali species to the vapor at typical combustor temperatures. These problems could be especially acute in direct combustion fired turbines, but may be ameliorated in integrated gasification combined cycles.

French, R.J.; Dayton, D.C.; Milne, T.A.

1994-01-01T23:59:59.000Z

233

The Salt Defense Disposal Investigations (SDDI)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Salt Defense Disposal Investigations (SDDI) Salt Defense Disposal Investigations (SDDI) will utilize a newly mined Underground Research Lab (URL) in WIPP to perform a cost effective, proof-of-principle field test of the emplacement of heat-generating radioactive waste and validate modeling efforts. The goals of the SDDI Thermal Test are to: * Demonstrate a proof-of-principle concept for in-drift disposal in salt. * Investigate, in a specific emplacement concept, the response of the salt to heat. * Develop a full-scale response for run-of- mine (ROM) salt. * Develop a validated coupled process model for disposal of heat-generating wastes in salt. * Evaluate the environmental conditions of the

234

Multiphase Flow and Cavern Abandonment in Salt  

SciTech Connect (OSTI)

This report will explore the hypothesis that an underground cavity in gassy salt will eventually be gas filled as is observed on a small scale in some naturally occurring salt inclusions. First, a summary is presented on what is known about gas occurrences, flow mechanisms, and cavern behavior after abandonment. Then, background information is synthesized into theory on how gas can fill a cavern and simultaneously displace cavern fluids into the surrounding salt. Lastly, two-phase (gas and brine) flow visualization experiments are presented that demonstrate some of the associated flow mechanisms and support the theory and hypothesis that a cavity in salt can become gas filled after plugging and abandonment

Ehgartner, Brian; Tidwell, Vince

2001-02-13T23:59:59.000Z

235

Workplace Charging Challenge Partner: Salt River Project  

Broader source: Energy.gov [DOE]

The mission of Salt River Project's (SRP) Electric Vehicle Initiative is to encourage greater use of clean energy transportation. Under this program, SRP's headquarters received two Level 2...

236

Sandia National Laboratories: molten salt test loop  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Partnership, Renewable Energy, Research & Capabilities, Solar, Solar Newsletter, SunShot, Systems Engineering AREVA and Sandia began operations of their molten salt...

237

Granular Salt Summary: Reconsolidation Principles and Applications  

SciTech Connect (OSTI)

The purposes of this paper are to review the vast amount of knowledge concerning crushed salt reconsolidation and its attendant hydraulic properties (i.e., its capability for fluid or gas transport) and to provide a sufficient basis to understand reconsolidation and healing rates under repository conditions. Topics covered include: deformation mechanisms and hydro-mechanical interactions during reconsolidation; the experimental data base pertaining to crushed salt reconsolidation; transport properties of consolidating granulated salt and provides quantitative substantiation of its evolution to characteristics emulating undisturbed rock salt; and extension of microscopic and laboratory observations and data to the applicable field scale.

Frank Hansen; Till Popp; Klaus Wieczorek; Dieter Stührenberg

2014-07-01T23:59:59.000Z

238

Drilling Waste Management Fact Sheet: Disposal in Salt Caverns  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Salt Caverns Salt Caverns Fact Sheet - Disposal in Salt Caverns Introduction to Salt Caverns Underground salt deposits are found in the continental United States and worldwide. Salt domes are large, fingerlike projections of nearly pure salt that have risen to near the surface. Bedded salt formations typically contain multiple layers of salt separated by layers of other rocks. Salt beds occur at depths of 500 to more than 6,000 feet below the surface. Schematic Drawing click to view larger image Schematic Drawing of a Cavern in Domal Salt Schematic Drawing click to view larger image Schematic Drawing of a Cavern in Bedded Salt Salt caverns used for oil field waste disposal are created by a process called solution mining. Well drilling equipment is used to drill a hole

239

Alkali-silica reaction products: Comparison between samples from concrete structures and laboratory test specimens  

SciTech Connect (OSTI)

Alkali-silica gels (ASG) were investigated in concrete from bridge structures (constructed from the 1920s to 2000), as well as in experimental specimens; employing optical microscopy, petrographic image analysis, and scanning electron microscopy combined with energy dispersive spectroscopy (SEM/EDS). The main differences were found in the chemical composition and morphology of the ASGs. ASGs which had formed in older concrete samples (50-80 years old) show a partly crystalline structure and higher Ca{sup 2+} content, indicating their aging and maturation. Younger concrete samples and experimental test specimens exhibit the presence of amorphous ASG. The chemistry of ASG from experimental specimens reflects the chemical composition of accelerating solutions. - Research Highlights: {yields} Quantitative analysis of alkali-silica gels {yields} Comparison of ASR in experimental conditions with ASR in bridge structures {yields} Investigation of factors affecting alkali-silica reaction {yields} Investigation of ASR of different types of aggregates.

Sachlova, Sarka, E-mail: lukschova@seznam.cz; Prikryl, Richard; Pertold, Zdenek

2010-12-15T23:59:59.000Z

240

Disparities in Salt Lake County and Salt Lake City Mortgage Outcomes and  

E-Print Network [OSTI]

who applied for Salt Lake County properties selected West Valley. · As the overall application volume). · Over 54 percent of all Salt Lake County mortgage applications from 2006 to 2011 were for homes in West Valley, unincorporated areas, West Jordan, and Salt Lake City. For Hispanic/Latino applicants

Feschotte, Cedric

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Synergistic capture mechanisms for alkali and sulfur species from combustion. Final report  

SciTech Connect (OSTI)

Experimental work was carried out on a 17 kW, 600 cm long, gas laboratory combustor, to investigate the post flame reactive capture of alkali species by kaolinite. Emphasis was on alkali/sorbent interactions occurring in flue gas at temperatures above the alkali dewpoint and on the formation of water insoluble reaction products. Time-temperature studies were carried out by injecting kaolinite at different axial points along the combustor. The effect of chlorine and sulfur on alkali capture was investigated by doping the flame with SO{sub 2} and Cl{sub 2} gases to simulate coal flame environments. Particle time and temperature history was kept as close as possible to that which would ordinarily be found in a practical boiler. Experiments designed to extract apparent initial reaction rates were carried using a narrow range, 1-2 {mu}m modal size sorbent, while, a coarse, multi size sorbent was used to investigate the governing transport mechanisms. The capture reaction has been proposed to be between alkali hydroxide and activated kaolinite, and remains so in the presence of sulfur and chlorine. The presence of sulfur reduces sodium capture by under 10% at 1300{degree}C. Larger reductions at lower temperatures are attributed to the elevated dewpoint of sodium ({approximately}850{degree}C) with subsequent reduction in sorbent residence time in the alkali gas phase domain. Chlorine reduces sodium capture by 30% across the temperature range covered by the present experiments. This result has been linked to thermodynamic equilibria between sodium hydroxide, sodium chloride and water.

Peterson, T.W.; Shadman, F.; Wendt, J.O.L.; Mwabe, P.O.

1994-02-01T23:59:59.000Z

242

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network [OSTI]

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined and a Strontium ion are discussed, as well as the formation of stable molecular ions. PACS numbers: 31.15.AR,31

243

The ground state of the polar alkali-Strontium molecules: potential energy curve and permanent dipole moment  

E-Print Network [OSTI]

The ground state of the polar alkali-Strontium molecules: potential energy curve and permanent In this study, we investigate the structure of the polar alkali-Strontium diatomic molecules as possible already been reported, while quantum degeneracy in Ytterbium [22, 23], Calcium [24], and Strontium [25, 26

Paris-Sud XI, Université de

244

Exciplex pumped alkali laser (XPAL) modeling and theory Andrew D. Palla, Joseph T. Verdeyen, and David L. Carroll  

E-Print Network [OSTI]

Exciplex pumped alkali laser (XPAL) modeling and theory Andrew D. Palla, Joseph T. Verdeyen pumped alkali laser (XPAL) system has been demonstrated in mixtures of Cs vapor, Ar, with and without ethane, by pumping Cs-Ar atomic collision pairs and subsequent dissociation of diatomic, electronically

Carroll, David L.

245

Absorption profiles of alkali-metal D lines in the presence of a static magnetic field  

Science Journals Connector (OSTI)

When atoms are placed in a static magnetic field, they undergo shifts of their energy levels and changes in their transition probabilities. These two effects must be taken into account when considering absorption profiles of alkali-metal D lines, which result from the contribution of many transitions influenced by the laser spectrum and Doppler broadening. The model presented here gives the D-line absorption coefficients of alkali-metal vapors in the presence of an arbitrary static magneitc field. They are evaluated considering various laser polarizations. Experimental measurements of D-line absorption profiles for Rb85, Rb87, and Cs133 isotopes show excellent agreement with theoretical predictions.

P. Tremblay; A. Michaud; M. Levesque; S. Thériault; M. Breton; J. Beaubien; N. Cyr

1990-09-01T23:59:59.000Z

246

Effect of alkali metals on the interaction of O/sub 2/ and CO with some transition-metal surfaces  

SciTech Connect (OSTI)

The interactions of O/sub 2/ and CO with alkali covered Ni, Ru, and Pt are reviewed with emphasis on the author's own studies. It is shown that the presence of alkalis changes the coadsorbates adsorption rates, heats of adsorption, and dissociative propensity, the strength of the effect depending on the alkali nature and coverage. The differences for the three substrates are interpreted comparing the properties of the clean surface. A detailed analysis of the coadsorbate--modifier interactions suggests that they depend on the adsorption state of the alkali species and the coadsorbate--substrate bond strength. Evidence of the formation of patches of ''surface complexes'' coexisting with the unperturbed surface is given and discussed in terms of strong direct alkali--coadsorbate interactions.

Kiskinova, M.

1987-07-01T23:59:59.000Z

247

Molten Salt Oxidation of mixed wastes  

SciTech Connect (OSTI)

Molten Salt Oxidation (MSO) can be characterized as a simple noncombustion process; the basic concept is to introduce air and wastes into a bed of molten salt, oxidize the organic wastes in the molten salt, use the heat of oxidation to keep the salt molten and remove the salt for disposal or processing and recycling. The process has been developed through bench-scale and pilot-scale testing, with successful destruction demonstration of a wide variety of hazardous and mixed (radioactive and hazardous) wastes including chemical warfare agents, combustible solids, halogenated solvents, polychlorinated biphenyls, plutonium-contaminated solids, uranium-contaminated solvents and fission product-contaminated oil. The MSO destruction efficiency of the hazardous organic constituents in the wastes exceeds 99.9999%. Radioactive species, such as actinides and rare earth fission products, are retained in the salt bath. These elements can be recovered from the spent salt using conventional chemical processes, such as ion exchange, to render the salt as nonradioactive and nonhazardous. This paper reviews the principles and capabilities of MSO, previous mixed waste studies, and a new US Department of Energy program to demonstrate the process for the treatment of mixed wastes.

Gay, R.L.; Navratil, J.D.; Newman, C. [Rockwell International Corp., Canoga Park, CA (United States). Rocketdyne Div.

1993-12-31T23:59:59.000Z

248

Metal salt catalysts for enhancing hydrogen spillover  

SciTech Connect (OSTI)

A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.

Yang, Ralph T; Wang, Yuhe

2013-04-23T23:59:59.000Z

249

Relative reactivities of solid benzoic acids  

E-Print Network [OSTI]

was always the acid salt, (RBZA) HK. For the reaction, RBZAH + Z R'BZAK, where R g R', the products were those predicted from Hammett o-constants for R and R'. Observations on the mode of reaction and free energy changes are given. The desirability... reaction series chosen was that. one most directly related to the Hammett substituent constants; namely, the reactions of various m- or p- monosubstituted benzoic acids with m- or p-monosubstituted potas- sium benzoate salts. CHAPTER Il RES ULTS...

Warwas, Edwin James

2012-06-07T23:59:59.000Z

250

Salt Wells Geothermal Exploratory Drilling Program EA  

Open Energy Info (EERE)

Salt Wells Geothermal Exploratory Drilling Program EA Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Abstract No abstract available. Author Bureau of Land Management Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 09/14/2009 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) Citation Bureau of Land Management. Salt Wells Geothermal Exploratory Drilling Program EA (DOI-BLM-NV-C010-2009-0006-EA) [Internet]. 09/14/2009. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management,

251

Solar Policy Environment: Salt Lake  

Broader source: Energy.gov [DOE]

The overall objective of the “Solar Salt Lake” (SSL) team is to develop a fully-scoped city and county-level implementation plan that will facilitate at least an additional ten megawatts of solar photovoltaic (PV) installations in the government, commercial, industrial, and residential sectors by 2015. To achieve this aggressive goal, the program strategy includes a combination of barrier identification, research, and policy analysis that utilizes the input of various stakeholders. Coupled with these activities will be the development and implementation of pilot installations in the government and residential sectors, and broad outreach to builders and potential practitioners of solar energy products in the process. In this way, while creating mechanisms to enable a demand for solar, SSL will also facilitate capacity building for suppliers, thereby helping to ensure long-term sustainability for the regional market.

252

Underground Salt Haul Truck Fire at the Waste Isolation Pilot...  

Office of Environmental Management (EM)

Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant February 5, 2014 March 2014 Salt Haul Truck Fire at the Waste Isolation Pilot Plant Salt Haul Truck Fire at the...

253

Sandia National Laboratories: Molten Nitrate Salt Initial Flow...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

David Gill, ddgill@sandia.gov, (505)-844-1524. Tagged with: Concentrating Solar Power * CSP * Molten Salt * molten salt test loop * National Solar Thermal Test Facility * NSTTF *...

254

Sandia National Laboratories: molten salt energy storage demonstration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

molten salt energy storage demonstration Sandia-AREVA Commission Solar ThermalMolten Salt Energy-Storage Demonstration On May 21, 2014, in Capabilities, Concentrating Solar Power,...

255

New lithium-based ionic liquid electrolytes that resist salt...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New lithium-based ionic liquid electrolytes that resist salt concentration polarization New lithium-based ionic liquid electrolytes that resist salt concentration polarization...

256

Development of Molten-Salt Heat Trasfer Fluid Technology for...  

Broader source: Energy.gov (indexed) [DOE]

Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar Power Plants Development of Molten-Salt Heat Trasfer Fluid Technology for Parabolic Trough Solar...

257

DOE - Office of Legacy Management -- Tatum Salt Dome Test Site...  

Office of Legacy Management (LM)

Tatum Salt Dome Test Site - MS 01 FUSRAP Considered Sites Site: Tatum Salt Dome Test Site (MS.01) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site...

258

Project Profile: Modular and Scalable Baseload Molten Salt Plant...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

salt receiver A distributed molten salt transport system Hybridization with natural gas or biofuels. Publications, Patents, and Awards J. E. Pacheco, C. Moursund, D. Rogers;...

259

Project Profile: Novel Molten Salts Thermal Energy Storage for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation Project Profile: Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power...

260

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot...  

Office of Environmental Management (EM)

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes...

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Project Profile: Deep Eutectic Salt Formulations Suitable as...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Halotechnics...

262

Method for inhibiting alkali metal corrosion of nickel-containing alloys  

DOE Patents [OSTI]

Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

DeVan, Jackson H. (Oak Ridge, TN); Selle, James E. (Westminster, CO)

1983-01-01T23:59:59.000Z

263

The alkali soils of the middle Niger Valley Origins, formation and present evolution  

E-Print Network [OSTI]

1 The alkali soils of the middle Niger Valley Origins, formation and present evolution Laurent area of the middle Niger valley (Niger Republic), irrigation techniques had been developed to respond, 1994). The contact between the two soil types is always so abrupt that in the all West-Africa surveys

Paris-Sud XI, Université de

264

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

DOE Patents [OSTI]

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

Doeff, Marca M. (Hayward, CA); Peng, Marcus Y. (Cupertino, CA); Ma, Yanping (Albany, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

1996-01-01T23:59:59.000Z

265

Gas phase spectroscopy of alkali carbides: The pure rotational spectrum of KC ,,X 4  

E-Print Network [OSTI]

observation of potassium carbide, and of any alkali metal carbide species. The molecule was produced under d, and possible ways to better activate C­C and C­H bonds.1 Investigating metal carbide species also can lead- faces. Finally, it has recently been suggested that adding metal carbides to H2 may provide high energy

Ziurys, Lucy M.

266

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material  

DOE Patents [OSTI]

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

1996-09-24T23:59:59.000Z

267

The role of alumina on performance of alkali-activated slag paste exposed to 50 °C  

SciTech Connect (OSTI)

The strength and microstructural evolution of two alkali-activated slags, with distinct alumina content, exposed to 50 °C have been investigated. These two slags are ground-granulated blast furnace slag (containing 13% (wt.) alumina) and phosphorous slag (containing 3% (wt.) alumina). They were hydrated in the presence of a combination of sodium hydroxide and sodium silicate solution at different ratios. The microstructure of the resultant slag pastes was assessed by X-ray diffraction, differential thermogravimetric analysis, and scanning electron microscopy. The results obtained from these techniques reveal the presence of hexagonal hydrates: CAH{sub 10} and C{sub 4}AH{sub 13} in all alkali-activated ground-granulated blast-furnace slag pastes (AAGBS). These hydrates are not observed in pastes formed by alkali-activated ground phosphorous slag (AAGPS). Upon exposure to 50 °C, the aforementioned hydration products of AAGBS pastes convert to C{sub 3}AH{sub 6}, leading to a rapid deterioration in the strength of the paste. In contrast, no strength loss was detected in AAGPS pastes following exposure to 50 °C. -- Highlights: •Strength of alkali-activated slag (AAS) pastes after exposure to 50 °C is studied. •AAS pastes with high alumina content lose strength after the exposure. •C{sub 4}AH{sub 13} and CAH{sub 10} form in these AAS pastes. •Conversion of these calcium alumina hydrates is associated with the strength loss. •AAS pastes with low alumina content maintain its strength after the exposure.

Jambunathan, N. [Department of Civil Engineering, Monash University, Clayton, Victoria 3800 (Australia)] [Department of Civil Engineering, Monash University, Clayton, Victoria 3800 (Australia); Sanjayan, J.G. [Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, Hawthorn, Victoria (Australia)] [Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, Hawthorn, Victoria (Australia); Pan, Z., E-mail: zhu.pan@monash.edu [Department of Civil Engineering, Monash University, Clayton, Victoria 3800 (Australia); Li, G. [School of Mechanical and Chemical Engineering, The University of Western Australia, Crawley, WA 6009 (Australia)] [School of Mechanical and Chemical Engineering, The University of Western Australia, Crawley, WA 6009 (Australia); Liu, Y. [School of Geosciences and Info-Physics, Central South University, Changsha 410083 (China)] [School of Geosciences and Info-Physics, Central South University, Changsha 410083 (China); Korayem, A.H.; Duan, W.H.; Collins, F. [Department of Civil Engineering, Monash University, Clayton, Victoria 3800 (Australia)] [Department of Civil Engineering, Monash University, Clayton, Victoria 3800 (Australia)

2013-12-15T23:59:59.000Z

268

Alignment of molecules in gaseous transport: Alkali dimers in supersonic nozzle beams  

E-Print Network [OSTI]

Alignment of molecules in gaseous transport: Alkali dimers in supersonic nozzle beams M. P. SinhaO) + a.P lcosO), where 0 is the angle between the angular momentum vector J of the molecule and the beam direction. This method is applied to determine the alignment of Na2 molecules in a supersonic nozzle beam

Zare, Richard N.

269

He polarization-dependent EPR frequency shifts of alkali-metal3 Earl Babcock,1  

E-Print Network [OSTI]

3 He polarization-dependent EPR frequency shifts of alkali-metal­3 He pairs Earl Babcock,1 Ian A-dependent measurements of the EPR frequency shifts for Na, K, and Rb interacting with polarized 3 He. K and Na frequency also allowed us to extend the measured temperature dependence of the Rb EPR frequency shifts up to 350

Walker, Thad G.

270

Salt Tolerance of Desorption Electrospray Ionization (DESI)  

SciTech Connect (OSTI)

Suppression of ion intensity in the presence of high salt matrices is common in most mass spectrometry ionization techniques. Desorption electrospray ionization (DESI) is an ionization method that exhibits salt tolerance, and this is investigated. DESI analysis was performed on three different drug mixtures in the presence of 0, 0.2, 2, 5, 10, and 20% NaCl:KCl weight by volume from seven different surfaces. At physiological concentrations individual drugs in each mixture were observed with each surface. Collision-induced dissociation (CID) was used to provide additional confirmation for select compounds. Multiple stage experiments, to MS5, were performed for select compounds. Even in the absence of added salt, the benzodiazepine containing mixture yielded sodium and potassium adducts of carbamazepine which masked the ions of interest. These adducts were eliminated by adding 0.1% 7M ammonium acetate to the standard methanol:water (1:1) spray solvent. Comparison of the salt tolerance of DESI with that of electrospray ionization (ESI) demonstrated much better signal/noise characteristics for DESI in this study. The salt tolerance of DESI was also studied by performing limit of detection and dynamic range experiments. Even at a salt concentration significantly above physiological concentrations, select surfaces were effective in providing spectra that allowed the ready identification of the compounds of interest. The already high salt tolerance of DESI can be optimized further by appropriate choices of surface and spray solution.

Jackson, Ayanna U. [Purdue University; Talaty, Nari [Purdue University; Cooks, R G [Purdue University; Van Berkel, Gary J [ORNL

2007-01-01T23:59:59.000Z

271

Category:Salt Lake City, UT | Open Energy Information  

Open Energy Info (EERE)

UT UT Jump to: navigation, search Go Back to PV Economics By Location Media in category "Salt Lake City, UT" The following 16 files are in this category, out of 16 total. SVFullServiceRestaurant Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVFullServiceRestauran... 57 KB SVHospital Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVHospital Salt Lake C... 57 KB SVLargeHotel Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVLargeHotel Salt Lake... 55 KB SVLargeOffice Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVLargeOffice Salt Lak... 57 KB SVMediumOffice Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png SVMediumOffice Salt La... 62 KB SVMidriseApartment Salt Lake City UT Moon Lake Electric Assn Inc (Utah).png

272

Examination of Liquid Fluoride Salt Heat Transfer  

SciTech Connect (OSTI)

The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

Yoder Jr, Graydon L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

273

Acoustic probing of salt using sonar  

E-Print Network [OSTI]

ACOUSTIC PROBING OF SALT USING SONAR A Thesis by KENNETH BRYAN BUTLER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE Oecember 1977 Major Subject...: Geophysics ACOUSTIC PROBING OF SALT USING SONAR A Thesis by KENNETH BRYAN BUTLER Approved as to style and content by: C airman of Com ttee ea of e r nt em er ember December 1977 ABSTRACT Acoustic Probing of Salt Using Sonar. (December 1977...

Butler, Kenneth Bryan

2012-06-07T23:59:59.000Z

274

High temperature alkali corrosion of ceramics in coal gas. Quarterly progress report No. 6, December 1, 1992--February 28, 1993  

SciTech Connect (OSTI)

The high temperature alkali corrosion kinetics of SiC have been systematically investigated from 950 to 1100{degrees}C at 0.63 vol % alkali vapor concentration. The corrosion rate in the presence of alkaliis approximately 10{sup 4} to 10{sup 5} times faster than the oxidation rate of SiC in air. The activation energy associated with the alkali corrosion is 406 kJ/mol, indicating a highly temperature-dependent reaction rate. The rate-controlling step of the overall reaction is likely to be the dissolution of silica in the sodium silicate liquid, based on the oxygen diffusivity data.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-02-24T23:59:59.000Z

275

E-Print Network 3.0 - alkali sodic soil Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Renewable Energy 29 ECOSYSTEM ECOLOGY The effects of tree establishment on water and salt dynamics Summary: of sodic soils in the Caspian region and India (Mishra and...

276

Salt Wells Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Area Salt Wells Geothermal Area (Redirected from Salt Wells Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Future Plans 5 Exploration History 6 Well Field Description 7 Research and Development Activities 8 Technical Problems and Solutions 9 Geology of the Area 9.1 Regional Setting 9.2 Stratigraphy 9.3 Structure 10 Hydrothermal System 11 Heat Source 12 Geofluid Geochemistry 13 NEPA-Related Analyses (9) 14 Exploration Activities (28) 15 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Northwest Basin and Range Geothermal Region GEA Development Phase: Operational"Operational" is not in the list of possible values (Phase I - Resource Procurement and Identification, Phase II - Resource Exploration and Confirmation, Phase III - Permitting and Initial Development, Phase IV - Resource Production and Power Plant Construction) for this property.

277

Molten Salt Batteries and Fuel Cells  

Science Journals Connector (OSTI)

This chapter describes recent work on batteries and fuel cells using molten salt electrolytes. This entails a comparison with other batteries and fuel cells utilizing aqueous and organic electrolytes; for...(1,2)

D. A. J. Swinkels

1971-01-01T23:59:59.000Z

278

Determining Salt Tolerance Among Sunflower Genotypes  

E-Print Network [OSTI]

Crop lands around the world are becoming more salt-affected due to natural processes and agricultural practices. Due to this increase of salinization, acquisition of saline tolerant germplasm for breeding purposes is becoming a priority. Although...

Masor, Laura Lee

2012-02-14T23:59:59.000Z

279

The Effect of Salt Water on Rice.  

E-Print Network [OSTI]

ERIME .-- - --- - -- BULLETIN NO. izz. June, 1909. THE EFFECT OF SALT WATE ON RICE, LAPS, Che Postoffice College Station, 1 --- Texas. TEXAS AGRICULTURAL EXPERIMENT S I'ATIONS. OFFICERS. GOVERNING BOARD. (Board of Directors A. and M... is Col- lege Station, Texas. Reports and bulletins are sent upon application to the Director. The Effect of Salt Water on Rice. . ...... By G. S. FRAPS. At some of the rice farms located near the coast, the amount of water lxml~etl is sometimes...

Fraps, G. S. (George Stronach)

1909-01-01T23:59:59.000Z

280

Ethylenediamine salt of 5-nitrotetrazole and preparation  

DOE Patents [OSTI]

Ethylenediamine salt of 5-nitrotetrazole and preparation. This salt has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol % of ammonium nitrate, is close to the CO.sub.2 -balanced composition of 90 mol %, and has a relatively low melting point of 110.5 C. making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C. and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

Lee, Kien-yin (Los Alamos, NM); Coburn, Michael D. (Los Alamos, NM)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Ammonia Solubility in High Concentration Salt Solutions  

SciTech Connect (OSTI)

Solubility data for ammonia in water and various dilute solutions are abundant in the literature. However, there is a noticeable lack of ammonia solubility data for high salt, basic solutions of various mixtures of salts including those found in many of the Hanford Washington underground waste tanks. As a result, models based on solubility data for dilute salt solutions have been used to extrapolate to high salt solutions. These significant extrapolations need to be checked against actual laboratory data. Some indirect vapor measurements have been made. A more direct approach is to determine the ratio of solubility of ammonia in water to its solubility in high salt solutions. In various experiments, pairs of solutions, one of which is water and the other a high salt solution, are allowed to come to equilibrium with a common ammonia vapor pressure. The ratio of concentrations of ammonia in the two solutions is equal to the ratio of the respective ammonia solubilities (Henry's Law constants) at a given temperature. This information can then be used to refine the models that predict vapor space compositions of ammonia. Ammonia at Hanford is of concern because of its toxicity in the environment and its contribution to the flammability of vapor space gas mixtures in waste tanks.

HEDENGREN, D.C.

2000-02-01T23:59:59.000Z

282

Method of extracting coal from a coal refuse pile  

DOE Patents [OSTI]

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Yavorsky, Paul M. (Monongahela, PA)

1991-01-01T23:59:59.000Z

283

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports  

Broader source: Energy.gov (indexed) [DOE]

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives November 14, 2013 - 12:00pm Addthis Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. The crushed salt is used as a supplement in cattle feed. Since the salt from WIPP has been mined from the middle of a large salt formation, its quality is high, according to Magnum Minerals.

284

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports  

Broader source: Energy.gov (indexed) [DOE]

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives Waste Isolation Pilot Plant's Excavated Salt Agreement Supports Conservation Education, Other Public Initiatives November 14, 2013 - 12:00pm Addthis Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Approximately 1.8 million tons of salt have been mined out of the underground at WIPP. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. Proceeds from the WIPP salt allowed hundreds of southeast New Mexico students to learn about resource conservation. The crushed salt is used as a supplement in cattle feed. Since the salt from WIPP has been mined from the middle of a large salt formation, its quality is high, according to Magnum Minerals.

285

High temperature alkali corrosion of ceramics in coal gas. Quarterly progress report No. 5, September 1, 1992--December 1, 1992  

SciTech Connect (OSTI)

Calcia-stabilized cubic zirconia was mixed with soda, then fired at 840-1100 C. SiC was also reacted with alkali-containing atmosphere at 1000 C.

Pickrell, G.R.; Sun, T.; Brown, J.J

1992-11-24T23:59:59.000Z

286

Role of dopant counter-anion functionality in polyaniline salts/blends and implications to morphology  

SciTech Connect (OSTI)

Polyanilines are of particular current interest primarily due to their relative ease of synthesis, low cost and stable conductivity in air. The insulating, polyaniline emeraldine base (PANI-EB) form becomes electrically conducting by preferential protonation or doping the imine nitrogen sites to yield an electrically conducting polyaniline emeraldine salt (PANI-ES). In this paper, wide and small angle X-ray scattering techniques (i.e., WAXS and SAXS) and light microscopy are used to characterize the influence of the dopant`s structure on the morphology of both polyaniline salt and blend. In an attempt to modify the morphology of the PANI-ES, the authors have evaluated a number of doping acids (i.e., methane sulfonic acid (HMSA), butane sulfonic acid (HBSA), dodecyl benzene sulfonic acid (HDBSA) and camphor sulfonic acid (HCSA)) that vary in size and polarity to better understanding the role of the acid in PANI-ES`s morphology and the resulting electrical conductivity. The other goal was to investigate the effect of the counter-anion structure on the nature of the phase separated PANI-ES network. The shape of the PANI-ES network in the host polycaprolactam has important implications on the nature of conduction behavior and the final electrical conductivity of the blend.

Hopkins, A.R.; Rasmussen, P.G. [Univ. of Michigan, Ann Arbor, MI (United States); Basheer, R.A. [General Motors Research and Development Center, Warren, MI (United States). Polymers Dept.; Annis, B.K.; Wignall, G.D. [Oak Ridge National Lab., TN (United States)

1997-04-01T23:59:59.000Z

287

Role of dopant counter-anion functionality in polyaniline salts/blends and implications to morphology  

SciTech Connect (OSTI)

In this paper, wide and small angle X-ray scattering techniques (i.e., WAXS and SAXS) and light microscopy are used to characterize the influence of the dopant`s structure on the morphology of both polyaniline salt and blend. In an attempt to modify the morphology of the PANI-ES, the authors have evaluated a number of doping acids (i.e., methane sulfonic acid (HMSA), butane sulfonic acid (HBSA), dodecyl benzene sulfonic acid (HDBSA) and camphor sulfonic acid (HCSA)) that vary in size and polarity to better understand the role of the acid in PANI-ES`s morphology and the resulting electrical conductivity. These salts were solution blended with polycaprolactam using hexafluoro-2-propanol (HFIP) as a solvent. The other goal was to investigate the effect of the counter-anion structure on the nature of the phase separated PANI-ES network. The shape of the PANI-ES network in the host polycaprolactam has important implications on the nature of conduction behavior and the final electrical conductivity of the blend.

Hopkins, A.R.; Rasmussen, P.G. [Univ. of Michigan, Ann Arbor, MI (United States); Basheer, R.A. [General Motors Research and Development Center, Warren, MI (United States). Polymers Dept.; Annis, B.K.; Wignall, G.D. [Oak Ridge National Lab., TN (United States)

1997-03-01T23:59:59.000Z

288

SALTS AND RADIATION PRODUCTS ON THE SURFACE OF EUROPA  

SciTech Connect (OSTI)

The surface of Europa could contain the compositional imprint of an underlying interior ocean, but competing hypotheses differ over whether spectral observations from the Galileo spacecraft show the signature of ocean evaporates or simply surface radiation products unrelated to the interior. Using adaptive optics at the W. M. Keck Observatory, we have obtained spatially resolved spectra of most of the disk of Europa at a spectral resolution {approx}40 times higher than seen by the Galileo spacecraft. These spectra show a previously undetected distinct signature of magnesium sulfate salts on Europa, but the magnesium sulfate is confined to the trailing hemisphere and spatially correlated with the presence of radiation products like sulfuric acid and SO{sub 2}. On the leading, less irradiated, hemisphere, our observations rule out the presence of many of the proposed sulfate salts, but do show the presence of distorted water ice bands. Based on the association of the potential MgSO{sub 4} detection on the trailing side with other radiation products, we conclude that MgSO{sub 4} is also a radiation product, rather than a constituent of a Europa ocean brine. Based on ocean chemistry models, we hypothesize that, prior to irradiation, magnesium is primarily in the form of MgCl{sub 2}, and we predict that NaCl and KCl are even more abundant, and, in fact, dominate the non-ice component of the leading hemisphere. We propose observational tests of this new hypothesis.

Brown, M. E. [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States); Hand, K. P., E-mail: mbrown@caltech.edu [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

2013-04-15T23:59:59.000Z

289

Note: An ion source for alkali metal implantation beneath graphene and hexagonal boron nitride monolayers on transition metals  

SciTech Connect (OSTI)

The construction of an alkali-metal ion source is presented. It allows the acceleration of rubidium ions to an energy that enables the penetration through monolayers of graphene and hexagonal boron nitride. Rb atoms are sublimated from an alkali-metal dispenser. The ionization is obtained by surface ionization and desorption from a hot high work function surface. The ion current is easily controlled by the temperature of ionizer. Scanning Tunneling Microscopy measurements confirm ion implantation.

Lima, L. H. de [Instituto de Física “Gleb Wataghin”, Universidade Estadual de Campinas, 13083-859, Campinas, SP (Brazil)] [Instituto de Física “Gleb Wataghin”, Universidade Estadual de Campinas, 13083-859, Campinas, SP (Brazil); Cun, H. Y.; Hemmi, A.; Kälin, T.; Greber, T. [Physik-Institut, Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich (Switzerland)] [Physik-Institut, Universität Zürich, Winterthurerstrasse 190, CH-8057 Zürich (Switzerland)

2013-12-15T23:59:59.000Z

290

Effect of the TBP and Water on the Complexation of Uranyl Nitrate and the Dissolution of Nitric Acid into Supercritical CO2. A Theoretical Study  

E-Print Network [OSTI]

started from "random" mixtures of water, TBP, nitric acid, and uranyl nitrate, complexation of uranyl to dissolve nitric acid in the supercritical phase. Indeed, without TBP, nitric acid alone self aggregates via containing the acid and uranyl salts. The simulations show that a high TBP/nitric acid ratio is needed

Boyer, Edmond

291

Electron-gas model for molecular crystals. Application to the alkali and alkaline-earth hydroxides  

Science Journals Connector (OSTI)

A theoretical model for calculating the structure and energy of molecular crystals is presented. The model, which requires no empirical parameters, is based on the Gordon-Kim electron-gas model. Many-body effects are incorporated through the mutual overlap of the electronic distributions of all molecules or ions in the neighborhood of a given point in the crystal. Effects of the crystal environment on the molecular properties are approximated by inclusion of an electrostatic potential that mimics the crystal potential in ab initio calculations on the individual component molecules or ions in the crystal. Application is made to a number of alkali and alkaline-earth hydroxide crystals in which the components are taken to be hydroxide ions, and alkali or alkaline-earth cations. The agreement with experiment is good (within 2.5% in lattice constants and 1.1% in lattice dissociation energy). The calculated changes in molecular dipole moment are between 20 and 40%.

R. LeSar and R. G. Gordon

1982-06-15T23:59:59.000Z

292

Technical report for the alkali lake ecological assessment, phase 1 reconnaissance (FY 91 and FY 92)  

SciTech Connect (OSTI)

The report summarizes the results of three field survey trips (June and September 1991, May 1992) taken to investigate the ecological effects associated with the release of over a million gallons of hazardous waste from herbicide production on the Alkali Lake playa. Sampling of soil, sediment, groundwater, soil-dwelling invertebrates and vegetation confirmed that hazardous materials from the waste disposal area are migrating westerly within the shallow aquifer to West Alkali Lake. Two areas of dead vegetation were identified and permanently marked to determine if these areas are changing in size and location. Preliminary calculations using a linear food-chain model suggested that small mammalian herbivores would probably not display adverse effects due to dietary exposures to the contaminants. However, nestling shorebirds may be exposed to concentrations potentially associated with adverse biological effects.

Linder, G.

1993-03-01T23:59:59.000Z

293

The 3-Dimensional q-Deformed Harmonic Oscillator and Magic Numbers of Alkali Metal Clusters  

E-Print Network [OSTI]

Magic numbers predicted by a 3-dimensional q-deformed harmonic oscillator with Uq(3) > SOq(3) symmetry are compared to experimental data for alkali metal clusters, as well as to theoretical predictions of jellium models, Woods--Saxon and wine bottle potentials, and to the classification scheme using the 3n+l pseudo quantum number. The 3-dimensional q-deformed harmonic oscillator correctly predicts all experimentally observed magic numbers up to 1500 (which is the expected limit of validity for theories based on the filling of electronic shells), thus indicating that Uq(3), which is a nonlinear extension of the U(3) symmetry of the spherical (3-dimensional isotropic) harmonic oscillator, is a good candidate for being the symmetry of systems of alkali metal clusters.

Bonatsos, Dennis; Raychev, P P; Roussev, R P; Terziev, P A; Bonatsos, Dennis

1999-01-01T23:59:59.000Z

294

Alkali Metal Control over N–N Cleavage in Iron Complexes  

Science Journals Connector (OSTI)

We propose that the reaction of 1-Na with benzene is slower because the mechanism is different; after all, there are not enough Fe sites to accept the six electrons from two N3– to reform N2 in the mechanism followed by 1-K and 1-Rb. ... Therefore, extreme care must be taken when synthesizing and handling these alkali graphite reductants! ... This work was supported by the National Institutes of Health (GM065313) and Yale University. ...

Katarzyna Grubel; William W. Brennessel; Brandon Q. Mercado; Patrick L. Holland

2014-11-20T23:59:59.000Z

295

Electrochemical cell with negative active material based on an alkali or alkaline earth metal  

SciTech Connect (OSTI)

In an electrochemical cell the negative active material is an alkali or alkaline earth metal, such as lithium, and the electrolyte comprises a solute and at least one solvent selected from the liquid oxyhalides and which serves also as the positive active material. The electrolyte further comprises a mineral substance the effect of which is to significantly reduce the voltage rise delay of the cell.

Vallin, D.; Chenebault, P.; Grassien, J.-V.; Kerouanton, A.

1985-10-15T23:59:59.000Z

296

Alkali or alkaline earth metal promoted catalyst and a process for methanol synthesis using alkali or alkaline earth metals as promoters  

DOE Patents [OSTI]

The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a heterogeneous catalyst comprising reduced copper chromite impregnated with an alkali or alkaline earth metal. There is thus no need to add a separate alkali or alkaline earth compound. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100--160 C and the pressure range of 40--65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H[sub 2]/CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.

Tierney, J.W.; Wender, I.; Palekar, V.M.

1995-01-31T23:59:59.000Z

297

Single Molecule Force Spectroscopy of Salt-dependent Bacteriophage T7 Gene 2.5 Protein Binding to  

E-Print Network [OSTI]

Single Molecule Force Spectroscopy of Salt-dependent Bacteriophage T7 Gene 2.5 Protein Binding by single molecule force spectroscopy. T7 gp2.5- 26C, lacking 26 acidic C-terminal residues, also reduces of single DNA molecules by stretch- ing the molecules and measuring the required force for a given extension

Richardson, Charles C.

298

Ethylenediamine salt of 5-nitrotetrazole and preparation  

DOE Patents [OSTI]

The ethylenediamine salt of 5-nitrotetrazole has been found to be useful as an explosive alone and in eutectic mixtures with ammonium nitrate and/or other explosive compounds. Its eutectic with ammonium nitrate has been demonstrated to behave in a similar manner to a monomolecular explosive such as TNT, and is less sensitive than the pure salt. Moreover, this eutectic mixture, which contains 87.8 mol% of ammonium nitrate, is close to the CO/sub 2/-balanced composition of 90 mol%, and has a relatively low melting point of 110.5 C making it readily castable. The ternary eutectic system containing the ethylenediamine salt of 5-nitrotetrazole, ammonium nitrate and ethylenediamine dinitrate has a eutectic temperature of 89.5 C and gives a measured detonation pressure of 24.8 GPa, which is 97.6% of the calculated value. Both the pure ethylenediamine salt and its known eutectic compounds behave in substantially ideal manner. Methods for the preparation of the salt are described.

Lee, K.; Coburn, M.D.

1984-05-17T23:59:59.000Z

299

Salt Wells Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Area Salt Wells Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Salt Wells Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Future Plans 5 Exploration History 6 Well Field Description 7 Research and Development Activities 8 Technical Problems and Solutions 9 Geology of the Area 9.1 Regional Setting 9.2 Stratigraphy 9.3 Structure 10 Hydrothermal System 11 Heat Source 12 Geofluid Geochemistry 13 NEPA-Related Analyses (9) 14 Exploration Activities (28) 15 References Area Overview Geothermal Area Profile Location: Nevada Exploration Region: Northwest Basin and Range Geothermal Region GEA Development Phase: Operational"Operational" is not in the list of possible values (Phase I - Resource Procurement and Identification, Phase II - Resource Exploration and Confirmation, Phase III - Permitting and Initial Development, Phase IV - Resource Production and Power Plant Construction) for this property.

300

Salt Wells Geothermal Project | Open Energy Information  

Open Energy Info (EERE)

Salt Wells Geothermal Project Salt Wells Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Salt Wells Geothermal Project Project Location Information Coordinates 39.580833333333°, -118.33444444444° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.580833333333,"lon":-118.33444444444,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
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301

Brine flow in heated geologic salt.  

SciTech Connect (OSTI)

This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

Kuhlman, Kristopher L.; Malama, Bwalya

2013-03-01T23:59:59.000Z

302

Geology of Damon Mound Salt Dome, Texas  

SciTech Connect (OSTI)

Geological investigation of the stratigraphy, cap-rock characteristics, deformation and growth history, and growth rate of a shallow coastal diapir. Damon Mound salt dome, located in Brazoria County, has salt less than 600 feet and cap rock less than 100 feet below the surface; a quarry over the dome provides excellent exposures of cap rock as well as overlying Oligocene to Pleistocene strata. These conditions make it ideal as a case study for other coastal diapirs that lack bedrock exposures. Such investigations are important because salt domes are currently being considered by chemical waste disposal companies as possible storage and disposal sites. In this book, the author reviews previous research, presents additional data on the subsurface and surface geology at Damon Mound, and evaluates Oligocene to post-Pleistocene diapir growth.

Collins, E.W.

1989-01-01T23:59:59.000Z

303

Molten nitrate salt technology development status report  

SciTech Connect (OSTI)

Recognizing thermal energy storage as potentially critical to the successful commercialization of solar thermal power systems, the Department of Energy (DOE) has established a comprehensive and aggressive thermal energy storage technology development program. Of the fluids proposed for heat transfer and energy storage molten nitrate salts offer significant economic advantages. The nitrate salt of most interest is a binary mixture of NaNO/sub 3/ and KNO/sub 3/. Although nitrate/nitrite mixtures have been used for decades as heat transfer and heat treatment fluids the use has been at temperatures of about 450/sup 0/C and lower. In solar thermal power systems the salts will experience a temperature range of 350 to 600/sup 0/C. Because central receiver applications place more rigorous demands and higher temperatures on nitrate salts a comprehensive experimental program has been developed to examine what effects, if any, the new demands and temperatures have on the salts. The experiments include corrosion testing, environmental cracking of containment materials, and determinations of physical properties and decomposition mechanisms. This report details the work done at Sandia National Laboratories in each area listed. In addition, summaries of the experimental programs at Oak Ridge National Laboratory, the University of New York, EIC Laboratories, Inc., and the Norwegian Institute of Technology on molten nitrate salts are given. Also discussed is how the experimental programs will influence the near-term central receiver programs such as utility repowering/industrial retrofit and cogeneration. The report is designed to provide easy access to the latest information and data on molten NaNO/sub 3//KNO/sub 3/ for the designers and engineers of future central receiver projects.

Carling, R.W.; Kramer, C.M.; Bradshaw, R.W.; Nissen, D.A.; Goods, S.H.; Mar, R.W.; Munford, J.W.; Karnowsky, M.M.; Biefeld, R.N.; Norem, N.J.

1981-03-01T23:59:59.000Z

304

Fast Spectrum Molten Salt Reactor Options  

SciTech Connect (OSTI)

During 2010, fast-spectrum molten-salt reactors (FS-MSRs) were selected as a transformational reactor concept for light-water reactor (LWR)-derived heavy actinide disposition by the Department of Energy-Nuclear Energy Advanced Reactor Concepts (ARC) program and were the subject of a preliminary scoping investigation. Much of the reactor description information presented in this report derives from the preliminary studies performed for the ARC project. This report, however, has a somewhat broader scope-providing a conceptual overview of the characteristics and design options for FS-MSRs. It does not present in-depth evaluation of any FS-MSR particular characteristic, but instead provides an overview of all of the major reactor system technologies and characteristics, including the technology developments since the end of major molten salt reactor (MSR) development efforts in the 1970s. This report first presents a historical overview of the FS-MSR technology and describes the innovative characteristics of an FS-MSR. Next, it provides an overview of possible reactor configurations. The following design features/options and performance considerations are described including: (1) reactor salt options-both chloride and fluoride salts; (2) the impact of changing the carrier salt and actinide concentration on conversion ratio; (3) the conversion ratio; (4) an overview of the fuel salt chemical processing; (5) potential power cycles and hydrogen production options; and (6) overview of the performance characteristics of FS-MSRs, including general comparative metrics with LWRs. The conceptual-level evaluation includes resource sustainability, proliferation resistance, economics, and safety. The report concludes with a description of the work necessary to begin more detailed evaluation of FS-MSRs as a realistic reactor and fuel cycle option.

Gehin, Jess C [ORNL; Holcomb, David Eugene [ORNL; Flanagan, George F [ORNL; Patton, Bruce W [ORNL; Howard, Rob L [ORNL; Harrison, Thomas J [ORNL

2011-07-01T23:59:59.000Z

305

Silicotungstic acid for cytochemical localization of water soluble substance(s) of cholinergic motor nerve terminal  

Science Journals Connector (OSTI)

Silicotungstic acid (STA), an electron dense substance and a powerful precipitating agent of quaternary ammonium salts such as choline and acetylcholine, was employed on the frog motor end-plate in order to pr...

S. Tsuji; H. S. Alameddine

1981-01-01T23:59:59.000Z

306

Control of Soluble Salts in Farming and Gardening.  

E-Print Network [OSTI]

of Soluble Salts in Farming and Gardening This publication on soluble salts is dedicated to Dr. Paul Lyerl!. Resident Director of Texas A&M University Agricultural Research Center at El Paso. From his arrival at the Center in 1942 until his... 23 23 26 27 28 28 29 29 29 29 30 30 31 31 7- :.- 31 32 33 33 34 SUMMARY INTRODUCTION SOLUBLE SALTS IN WATERS AND SOILS Where Salts Come From Kinds and Amounts of Salt How Salt Problems Develop Definition of Terms...

Longenecker, D. E.; Lyerly, P. J.

1974-01-01T23:59:59.000Z

307

The Salt Industry at Sterling, Kansas  

E-Print Network [OSTI]

. Exhaust stean of the engine plant is ad- mitted to the first evaporator and warms the "brine, then passes to the second and warns it lesD and condenses, causing a partial vacuum in the first where the brine then boils violent- ly. The vapor thus... and is condensed by a jet condenser, whereupon the third boils. Each evaporator has its own electric prop- eller stirrers and its own electric elevator to remove the salt. Nearly all the handling is done by electric conveyors until the salt is discharged...

Horner, Robert Messenger

1914-01-01T23:59:59.000Z

308

The Effect of Salt Water on Rice.  

E-Print Network [OSTI]

mq A QTF *'. ' . - - . 1 bC1 r*. .. r * - .=.-ksl-, G v $. THE EFFECT OF SALT WATER ON RICE AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President \\ STATION ,,,bfINISTRATION: *B. YOUNGBLOOD, M. S., Ph. D.,, Director A B CONNER... of Agriculture. ****In cooperation with the School of Agriculture. SYNOPSIS Rice farmers sometimes have trouble with salt in the water used for irrigation. Varying conditions, such as character of soil, amount of water already on the land, stage of growth...

Fraps, G. S. (George Stronach)

1927-01-01T23:59:59.000Z

309

Incompatible Chemicals The following list is to be used only as a general guideline. Please refer to your Material Safety  

E-Print Network [OSTI]

and sulfuric acid mixtures Alkali and alkaline earth metals Water, carbon tetrachloride or other chlorinated (white) Air, oxygen, alkalis, reducing agents Potassium Carbon tetrachloride, carbon dioxide, water tetrachloride, carbon dioxide, water Sodium nitrite Ammonium nitrate and other ammonium salts Sodium peroxide

Slatton, Clint

310

Role of relative humidity in concrete expansion due to alkali-silica reaction and delayed ettringite formation: relative humidity thresholds, measurement methods, and coatings to mitigate expansion.  

E-Print Network [OSTI]

??Premature concrete deterioration due to alkali-silica reaction (ASR) and delayed ettringite formation (DEF) is a significant problem all over the world. In cases where these… (more)

Rust, Charles Karissa

2009-01-01T23:59:59.000Z

311

Accelerators for Subcritical Molten-Salt Reactors  

SciTech Connect (OSTI)

Accelerator parameters for subcritical reactors have usually been based on using solid nuclear fuel much like that used in all operating critical reactors as well as the thorium burning accelerator-driven energy amplifier proposed by Rubbia et al. An attractive alternative reactor design that used molten salt fuel was experimentally studied at ORNL in the 1960s, where a critical molten salt reactor was successfully operated using enriched U235 or U233 tetrafluoride fuels. These experiments give confidence that an accelerator-driven subcritical molten salt reactor will work better than conventional reactors, having better efficiency due to their higher operating temperature, having the inherent safety of subcritical operation, and having constant purging of volatile radioactive elements to eliminate their accumulation and potential accidental release in dangerous amounts. Moreover, the requirements to drive a molten salt reactor can be considerably relaxed compared to a solid fuel reactor, especially regarding accelerator reliability and spallation neutron targetry, to the point that much of the required technology exists today. It is proposed that Project-X be developed into a prototype commercial machine to produce energy for the world by, for example, burning thorium in India and nuclear waste from conventional reactors in the USA.

Johnson, Roland (Muons, Inc.) [Muons, Inc.

2011-08-03T23:59:59.000Z

312

Mineral Salt: A Source of Costly Energy?  

Science Journals Connector (OSTI)

...required to pump salt water into a solution cavity...the flow of cooling water of a conventional or...con-siderable preliminary treatment. Os-motic flow through...process of in-verse electrodialysis, only the ions pass...nor extensive pre-treatment of the fluids (1...

W. GARY WILLIAMS

1979-01-26T23:59:59.000Z

313

Salt caverns for oil field waste disposal.  

SciTech Connect (OSTI)

Salt caverns used for oil field waste disposal are created in salt formations by solution mining. When created, caverns are filled with brine. Wastes are introduced into the cavern by pumping them under low pressure. Each barrel of waste injected to the cavern displaces a barrel of brine to the surface. The brine is either used for drilling mud or is disposed of in an injection well. Figure 8 shows an injection pump used at disposal cavern facilities in west Texas. Several types of oil field waste may be pumped into caverns for disposal. These include drilling muds, drill cuttings, produced sands, tank bottoms, contaminated soil, and completion and stimulation wastes. Waste blending facilities are constructed at the site of cavern disposal to mix the waste into a brine solution prior to injection. Overall advantages of salt cavern disposal include a medium price range for disposal cost, large capacity and availability of salt caverns, limited surface land requirement, increased safety, and ease of establishment of individual state regulations.

Veil, J.; Ford, J.; Rawn-Schatzinger, V.; Environmental Assessment; RMC, Consultants, Inc.

2000-07-01T23:59:59.000Z

314

STANDARD OPERATING PROCEDURE HEAVY METAL SALTS (selected)  

E-Print Network [OSTI]

MSDS ___Special training provided by the department/supervisor ___Review of the OSHA Lab Standard ___Review of the departmental safety manual ___Review of the Chemical Hygiene Plan ___Safety meetings12.1 STANDARD OPERATING PROCEDURE for HEAVY METAL SALTS (selected) Location

Pawlowski, Wojtek

315

Solar with a Grain of Salt  

Science Journals Connector (OSTI)

...zone, and a bot-tom storage zone. The upper zone...electricity. Hot water is pumped out of the bottom zone...sequentially on the top of the storage zone. Howard C. Bryant...leached salts to the storage zone. One way to do...says French, but the seawater itself is turbid and...

THOMAS H. MAUGH II

1982-06-11T23:59:59.000Z

316

NOVEL GRAPHITE SALTS OF HIGH OXIDIZING POTENTIAL  

E-Print Network [OSTI]

hr volatiles none AsFS AsFS > CF4 AsFS AsFS AsFS C13.l AsF 6C16.l AsF 6 C24.3AsF6·l/2 F2 > CF4> CF4 > CF4 Table VI-7. Graphite hexafluoroarsenate salts +

McCarron III, Eugene Michael

2010-01-01T23:59:59.000Z

317

Salt repository project closeout status report  

SciTech Connect (OSTI)

This report provides an overview of the scope and status of the US Department of Energy (DOE`s) Salt Repository Project (SRP) at the time when the project was terminated by the Nuclear Waste Policy Amendments Act of 1987. The report reviews the 10-year program of siting a geologic repository for high-level nuclear waste in rock salt formations. Its purpose is to aid persons interested in the information developed during the course of this effort. Each area is briefly described and the major items of information are noted. This report, the three salt Environmental Assessments, and the Site Characterization Plan are the suggested starting points for any search of the literature and information developed by the program participants. Prior to termination, DOE was preparing to characterize three candidate sites for the first mined geologic repository for the permanent disposal of high-level nuclear waste. The sites were in Nevada, a site in volcanic tuff; Texas, a site in bedded salt (halite); and Washington, a site in basalt. These sites, identified by the screening process described in Chapter 3, were selected from the nine potentially acceptable sites shown on Figure I-1. These sites were identified in accordance with provisions of the Nuclear Waste Policy Act of 1982. 196 refs., 21 figs., 11 tabs.

NONE

1988-06-01T23:59:59.000Z

318

Salt Wells, Eight Mile Flat | Open Energy Information  

Open Energy Info (EERE)

Salt Wells, Eight Mile Flat Salt Wells, Eight Mile Flat Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells, Eight Mile Flat Abstract Abstract unavailable. Author Nevada Bureau of Mines and Geology Published Online Nevada Encyclopedia, 2009 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells, Eight Mile Flat Citation Nevada Bureau of Mines and Geology. Salt Wells, Eight Mile Flat [Internet]. 2009. Online Nevada Encyclopedia. [updated 2009/03/24;cited 2013/08/07]. Available from: http://www.onlinenevada.org/articles/salt-wells-eight-mile-flat Related Geothermal Exploration Activities Activities (1) Areas (1) Regions (0) Development Wells At Salt Wells Area (Nevada Bureau of Mines and Geology, 2009) Salt Wells Geothermal Area

319

Brine Migration Experimental Studies for Salt Repositories | Department of  

Broader source: Energy.gov (indexed) [DOE]

Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Experiments were used to examine water content in Permian salt samples (Salado Formation) collected from the WIPP site. The profile of water release and movement is recognized as a function of temperature from 30 to 275 oC using classical gravimetric methods to measure weight loss as a result of heating. The amount of water released from heating the salt was found to be correlated with the salts accessory mineral content (clay, other secondary minerals lost up to 3 wt % while pure halite salt lost less than 0.5 wt % water). Water released from salt at lower temperature was reversible and is attributed to clay hydration and dehydration processes. The analysis

320

Brine Migration Experimental Studies for Salt Repositories | Department of  

Broader source: Energy.gov (indexed) [DOE]

Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Brine Migration Experimental Studies for Salt Repositories Experiments were used to examine water content in Permian salt samples (Salado Formation) collected from the WIPP site. The profile of water release and movement is recognized as a function of temperature from 30 to 275 oC using classical gravimetric methods to measure weight loss as a result of heating. The amount of water released from heating the salt was found to be correlated with the salts accessory mineral content (clay, other secondary minerals lost up to 3 wt % while pure halite salt lost less than 0.5 wt % water). Water released from salt at lower temperature was reversible and is attributed to clay hydration and dehydration processes. The analysis

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Sandia National Laboratories: New Liquid Salt Electrolytes Could...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ClimateECEnergyNew Liquid Salt Electrolytes Could Lead to Cost-Effective Flow Batteries New Liquid Salt Electrolytes Could Lead to Cost-Effective Flow Batteries Sandia Tool...

322

Corrosion Studies in High-Temperature Molten Salt Systems for...  

Broader source: Energy.gov (indexed) [DOE]

Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1 Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1...

323

Ketone Production from the Thermal Decomposition of Carboxylate Salts  

E-Print Network [OSTI]

The MixAlco process uses an anaerobic, mixed-culture fermentation to convert lignocellulosic biomass to carboxylate salts. The fermentation broth must be clarified so that only carboxylate salts, water, and minimal impurities remain. Carboxylate...

Landoll, Michael 1984-

2012-08-15T23:59:59.000Z

324

Energy Efficient Buildings, Salt Lake County, Utah  

SciTech Connect (OSTI)

Executive Summary Salt Lake County's Solar Photovoltaic Project - an unprecedented public/private partnership Salt Lake County is pleased to announce the completion of its unprecedented solar photovoltaic (PV) installation on the Calvin R. Rampton Salt Palace Convention Center. This 1.65 MW installation will be one the largest solar roof top installations in the country and will more than double the current installed solar capacity in the state of Utah. Construction is complete and the system will be operational in May 2012. The County has accomplished this project using a Power Purchase Agreement (PPA) financing model. In a PPA model a third-party solar developer will finance, develop, own, operate, and maintain the solar array. Salt Lake County will lease its roof, and purchase the power from this third-party under a long-term Power Purchase Agreement contract. In fact, this will be one of the first projects in the state of Utah to take advantage of the recent (March 2010) legislation which makes PPA models possible for projects of this type. In addition to utilizing a PPA, this solar project will employ public and private capital, Energy Efficiency and Conservation Block Grants (EECBG), and public/private subsidized bonds that are able to work together efficiently because of the recent stimulus bill. The project also makes use of recent changes to federal tax rules, and the recent re-awakening of private capital markets that make a significant public-private partnership possible. This is an extremely innovative project, and will mark the first time that all of these incentives (EECBG grants, Qualified Energy Conservation Bonds, New Markets tax credits, investment tax credits, public and private funds) have been packaged into one project. All of Salt Lake County's research documents and studies, agreements, and technical information is available to the public. In addition, the County has already shared a variety of information with the public through webinars, site tours, presentations, and written correspondence.

Barnett, Kimberly

2012-04-30T23:59:59.000Z

325

The Salt or Sodium Chloride Content of Feeds  

E-Print Network [OSTI]

1 EXAS AGRICULTURAL EXPERIMENT STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE.... ............... Salt content of feecls.. ......... Salt content of mixed feeds.. ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed...

Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

1920-01-01T23:59:59.000Z

326

Interactions among Plant Species and Microorganisms in Salt Marsh Sediments  

Science Journals Connector (OSTI)

...a New England salt marsh. Ecology 72: 138-148...L. Melville, and R. L. Peterson. 1994...Broome, and S. R. Shafer. 1993...mycorrhizae in salt marshes in North Carolina...a New England salt marsh. J. Ecol. 86: 285-292. 30 Linderman, R. G. 1988. Mycorrhizal...

David J. Burke; Erik P. Hamerlynck; Dittmar Hahn

2002-03-01T23:59:59.000Z

327

Self-potential monitoring of a salt plume  

Science Journals Connector (OSTI)

...salt-migration process. By this we...salt-migration process needs to be much...salt migration process is relatively...written as a MATLAB routine. The...The numerical simulation was used to compute...gradient in the chemical potential of...digitaledition.pdf .. Fournier...

P. Martínez-Pagán; A. Jardani; A. Revil; A. Haas

328

Occurrence of gypsum in Gulf coast salt domes  

Science Journals Connector (OSTI)

...Occurrence of gypsum in Gulf coast salt domes Barton Donald Clinton...OF GYPSUM IN THE GULF COAST SALT DOMES. Sir: On accountof thepaucityof...concerningtheoccurrenceof gypsumandanhydriteon the salt domes. The followingremarksmay...5o-footsill of saltat 3,350feetat Palangana,possiblyalsoStrattonRidge...

Donald Clinton Barton

329

Structural restoration of Louann Salt and overlying sediments, De Soto Canyon Salt Basin, northeastern Gulf of Mexico  

E-Print Network [OSTI]

The continental margin of the northeastern Gulf of Mexico is suited for seismic stratigraphic analysis and salt tectonism analysis. Jurassic strata include the Louann Salt on the continental shelf and upper slope of the Destin Dome OCS area...

Guo, Mengdong

2012-06-07T23:59:59.000Z

330

Flow, Salts, and Trace Elements in the Rio Grande: A Review  

E-Print Network [OSTI]

must then focus on either in- creasing salt removal, minimizing salt inflow into the Rio Grande, or reducing evaporative losses of water, which concentrate salts. Although techniques to remove salts such as reverse os- mosis and electrodialysis exist...

Miyamoto, S.; Fenn, L. B.; Swietlik, D.

1995-01-01T23:59:59.000Z

331

Seismic stratigraphy and salt tectonics of the Alaminos Canyon area, Gulf of Mexico.  

E-Print Network [OSTI]

morphology, salt structure, and suprasalt sediments indicate the majority of the slope is covered by a shallow salt canopy. The salt structure map indicates that the Alaminos Canyon study area represents a transition from a semi-continuous salt sheet...

Mechler, Suzanne Marie

2012-06-07T23:59:59.000Z

332

An investigation of the transfer of alkali metal chlorides from dimethyl sulfoxide to water  

E-Print Network [OSTI]

-to-back' with water as the solvent in one cell and a non- aqueous solvent in the other. The two cells used in this investigation were each composed of silver-silver chloride electrodes in the same solution with dropping alkali metal amalgam electrodes. The solute.... The dropping amalgam electrodes are written only once since they were connected by a common amalgam reservoir. When the external circuit between the two silver-silver chloride electrodes was closed a current flowed and the net result oi the electrode...

Williams, Roger

1966-01-01T23:59:59.000Z

333

Positron binding to alkali-metal hydrides: The role of molecular vibrations  

SciTech Connect (OSTI)

The bound vibrational levels for J=0 have been computed for the series of alkali-metal hydride molecules from LiH to RbH, including NaH and KH. For all four molecules the corresponding potential-energy curves have been obtained for each isolated species and for its positron-bound complex (e{sup +}XH). It is found that the calculated positron affinity values strongly depend on the molecular vibrational state for which they are obtained and invariably increase as the molecular vibrational energy content increases. The consequences of our findings on the likelihood of possibly detecting such weakly bound species are briefly discussed.

Gianturco, Franco A.; Franz, Jan; Buenker, Robert J.; Liebermann, Heinz-Peter; Pichl, Lukas; Rost, Jan-Michael; Tachikawa, Masanori; Kimura, Mineo [Department of Chemistry and INFM, University of Rome La Sapienza, Piazzale A. Moro 5, 00185 Rome (Italy); Fachbereich C-Mathematik und Naturwissenschaften, Bergische Universitaet Wuppertal, Gaussstrasse 20, D-42119 Wuppertal (Germany); Max Planck Institute for the Physics of Complex Systems, Noethnitzer St. 38, D-01187 Dresden (Germany); Graduate School of Science, Yokohama-city University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan); Graduate School of Sciences, Kyushu University, Fukuoka 812-8581 (Japan)

2006-02-15T23:59:59.000Z

334

THE JOURNAL OF CHEMICAL PHYSICS VOLUME 58, NUMBER 2 15 JANUARY 1973 Internal state distribution of alkali dimers in supersonic nozzle beams*  

E-Print Network [OSTI]

of alkali dimers in supersonic nozzle beams* M. P. Sinha, A. Schultzt, and R. N. Zare Department o the white light and laser-induced fluorescence excited in a nozzle beam of Na2 molecules, we have measured beams with various stagnation pressures (50-240 torr) of alkali metal and with nozzles of different

Zare, Richard N.

335

Enrichment and Association of Bacteria and Particulates in Salt Marsh Surface Water  

Science Journals Connector (OSTI)

...Sippewissett salt marsh, Falmouth, Massachusetts, and Palo Alto salt marsh...Sippewissett salt marsh, Falmouth, Massachusetts, and Palo Alto salt marsh...Sippewissett salt marsh, Falmouth, Massachusetts, and Palo Alto salt marsh...largely attributed to intense solar radiation. There have been...

R. W. Harvey; L. Y. Young

1980-04-01T23:59:59.000Z

336

Salt River Electric - Residential Energy Efficiency Rebate Program |  

Broader source: Energy.gov (indexed) [DOE]

Salt River Electric - Residential Energy Efficiency Rebate Program Salt River Electric - Residential Energy Efficiency Rebate Program Salt River Electric - Residential Energy Efficiency Rebate Program < Back Eligibility Residential Savings Category Home Weatherization Commercial Weatherization Sealing Your Home Heating & Cooling Construction Commercial Heating & Cooling Design & Remodeling Other Ventilation Heat Pumps Program Info State Kentucky Program Type Utility Rebate Program Rebate Amount Varies by technology Provider Salt River Electric Cooperative Salt River Electric serves as the rural electric provider in Kentucky's Bullitt, Nelson, Spencer, and Washington counties. Residential customers are eligible for a variety of cash incentives for energy efficiency. The Touchstone Energy Home Program provides a rebate of up to $250 to customers

337

Electron beam driven alkali metal atom source for loading a magneto-optical trap in a cryogenic environment  

E-Print Network [OSTI]

We present a versatile and compact electron beam driven source for alkali metal atoms, which can be implemented in cryostats. With a heat load of less than 10mW, the heat dissipation normalized to the atoms loaded into the magneto-optical Trap (MOT), is about a factor 1000 smaller than for a typical alkali metal dispenser. The measured linear scaling of the MOT loading rate with electron current observed in the experiments, indicates that electron stimulated desorption is the corresponding mechanism to release the atoms.

S. Haslinger; R. Amsuess; Ch. Koller; C. Hufnagel; N. Lippok; J. Majer; J. Verdu; S. Schneider; J. Schmiedmayer

2010-03-26T23:59:59.000Z

338

Salt River Project | Open Energy Information  

Open Energy Info (EERE)

Project Project Jump to: navigation, search Name Salt River Project Place Tempe, Arizona Utility Id 16572 Utility Location Yes Ownership P NERC Location WECC NERC WECC Yes Operates Generating Plant Yes Activity Generation Yes Activity Transmission Yes Activity Buying Transmission Yes Activity Distribution Yes Activity Wholesale Marketing Yes Activity Bundled Services Yes Alt Fuel Vehicle Yes Alt Fuel Vehicle2 Yes References EIA Form EIA-861 Final Data File for 2010 - File1_a[1] SGIC[2] Energy Information Administration Form 826[3] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Salt River Project Smart Grid Project was awarded $56,859,359 Recovery Act Funding with a total project value of $114,003,719.

339

Planning and Implementation of an Alkali-Surfactant-Polymer (ASP) Field Project  

SciTech Connect (OSTI)

The Warden ASP project has progressed from the initial planning stage to construction of an injection plant. An ASP chemical system was designed based on laboratory evaluations that included interfacial tension, mobility requirements, rock-alkali interaction, fluid capabilities, and core tests. Field cores were obtained from the Permian No. 5 and No. 6 sands on the Warden lease in Sho-Vel-Tum oil field. A separate tank battery for the pilot pattern area was installed, and a field tracer test is currently being evaluated. Tracer test results to date indicate that there is no major fracturing in the No. 5 sand. There is indication, however, of some channeling through high permeability sand. The field injection plant was designed, and construction is in progress. Several variations of injection plant design have been evaluated. Some plant design details, such as alkali storage, were found to be dependent on the availability of use equipment and project budget. The surfactant storage facility design was shown to be dependent on surfactant rheology.

French, T.

1999-03-05T23:59:59.000Z

340

3718-F Alkali Metal Treatment and Storage Facility Closure Plan. Revision 1  

SciTech Connect (OSTI)

The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, as well as for activities associated with nuclear energy development. The 300 Area of the Hanford Site contains reactor fuel manufacturing facilities and several research and development laboratories. The 3718-F Alkali Metal Treatment and Storage Facility (3718-F Facility), located in the 300 Area, was used to store and treat alkali metal wastes. Therefore, it is subject to the regulatory requirements for the storage and treatment of dangerous wastes. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610 (Ecology 1989) and 40 CFR 270.1. Closure also will satisfy the thermal treatment facility closure requirements of 40 CFR 265.381. This closure plan presents a description of the 3718-F Facility, the history of wastes managed, and the approach that will be followed to close the facility. Only hazardous constituents derived from 3718-F Facility operations will be addressed.

none,

1992-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Electrical Resistance and Thermo-Electric Power of the Alkali Metals  

Science Journals Connector (OSTI)

Electrical resistance and thermo-electric power of the five alkali metals, -183°C to 250°C.—Pure samples of the metals were fused into glass or quartz tubes, and measurements were made by means of thermo-junctions sealed into each end. Enough points were secured in each case to determine the slopes and the breaks in the curves. In both the resistance and thermo-electric power lines, changes of slope are observed beginning gradually 100 degrees or more below the melting point. These are taken to indicate transformations in each case from an ? to a ? form. These transformations occur at approximately the temperatures, 50°C for Li, -20°C to +20°C for Na, -120°C for K, -35°C for Rb, and -80°C for Cs. In all cases a sharp rise in thermo-electric power and resistance occurs as the melting point is approached. The temperature coefficients of resistance decrease smoothly with increasing atomic weight for all forms.Atomic heat of electrons in the alkali metals.—The atomic heat of electricity as computed from thermo-electric data is approximately 0.24 cal. for Na and K, and 0.58 cal. for Rb and Cs. The values are too small to account for the observed excess of the atomic heats for these metals above the equipartition value.

Charles C. Bidwell

1924-03-01T23:59:59.000Z

342

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Broader source: Energy.gov (indexed) [DOE]

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

343

Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The  

Open Energy Info (EERE)

Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Aksaray And Ecemis Faults - Diapiric Salt Relationships- Relevance To The Hydrocarbon Exploration In The Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey Details Activities (0) Areas (0) Regions (0) Abstract: Due to activitiy of the Aksaray and Ecemis Faults, volcanic intrusion and westward movement of the Anatolian plate, diapiric salt structures were occurred in the Tuz Golu (Salt Lake) basin in central Anatolia, Turkey. With the collisions of the Arabian and Anatolian plates during the late Cretaceous and Miocene times, prominent ophiolitic

344

WIPP Shares Expertise with Salt Club Members | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Shares Expertise with Salt Club Members Shares Expertise with Salt Club Members WIPP Shares Expertise with Salt Club Members November 26, 2013 - 12:00pm Addthis Carlsbad Field Office’s Abe Van Luik, third from right, examines rock salt taken from the Morsleben mine in Germany. Carlsbad Field Office's Abe Van Luik, third from right, examines rock salt taken from the Morsleben mine in Germany. CARLSBAD, N.M. - EM's Carlsbad Field Office (CBFO) participated in the second meeting of the Nuclear Energy Agency's (NEA) Salt Club and the 4th U.S.-German Workshop on Salt Repository Research, Design & Operation in Berlin. CBFO, which has responsibility for the Waste Isolation Pilot Plant (WIPP) and the National Transuranic (TRU) Program, was represented by International Programs and Policy Advisor Dr. Abe Van Luik.

345

Salt Waste Contractor Reaches Contract Milestone | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Contractor Reaches Contract Milestone Salt Waste Contractor Reaches Contract Milestone Salt Waste Contractor Reaches Contract Milestone April 29, 2013 - 12:00pm Addthis Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued successful operations. Robert Brown, SRR tank farm operator, performs daily inspections of a salt disposition process facility. The inspections and improvement upgrades have resulted in continued successful operations. AIKEN, S.C. - The liquid waste cleanup contractor for the EM program at the Savannah River Site (SRS) recently surpassed a 2013 contract milestone by processing more than 600,000 gallons of salt waste. Savannah River Remediation (SRR) salt disposition process facilities

346

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular  

Broader source: Energy.gov (indexed) [DOE]

Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics Coupled Thermal-Hydrological-Mechanical Processes in Salt, Hot Granular Salt Consolidation, Constitutive Model and Micromechanics The report addresses granular salt reconsolidation from three vantage points: laboratory testing, modeling, and petrofabrics. The experimental data 1) provide greater insight and understanding into the role of elevated temperature and pressure regimes on physical properties of reconsolidated crushed salt, 2) can supplement an existing database used to develop a reconsolidation constitutive model and 3) provide data for model evaluation. The constitutive model accounts for the effects of moisture through pressure solution and dislocation creep, with both terms dependent

347

Molten Salt Heat Transfer Fluid (HTF)  

Energy Innovation Portal (Marketing Summaries) [EERE]

Sandia has developed a heat transfer fluid (HTF) for use at elevated temperatures that has a lower freezing point than any molten salt mixture available commercially. This allows the HTF to be used in applications in which the expensive parasitic energy costs necessary for freeze protection can be significantly reduced. The higher operating temperature limit significantly increases power cycle efficiency and overall power plan sun-to-net electric efficiency....

2013-03-12T23:59:59.000Z

348

Unravelling the Structure of Magnus’ Pink Salt  

Science Journals Connector (OSTI)

Two classic examples of colorful Pt complexes featuring metallophilic interactions are Magnus’ salts, which have a long history of eluding structural characterization. ... The complete 14N WURST-CPMG and BRAIN-CP/WURST-CPMG NMR spectra were generated by mirroring the low-frequency (right) portion of the powder pattern about ? = 0 ppm, as described previously. ... The microscope was equipped with a 32× Schwarzschild objective and a liquid nitrogen cooled mercury cadmium telluride detector. ...

Bryan E. G. Lucier; Karen E. Johnston; Wenqian Xu; Jonathan C. Hanson; Sanjaya D. Senanayake; Siyu Yao; Megan W. Bourassa; Monika Srebro; Jochen Autschbach; Robert W. Schurko

2013-12-13T23:59:59.000Z

349

Stationary phase deposition based on onium salts  

DOE Patents [OSTI]

Onium salt chemistry can be used to deposit very uniform thickness stationary phases on the wall of a gas chromatography column. In particular, the stationary phase can be bonded to non-silicon based columns, especially microfabricated metal columns. Non-silicon microfabricated columns may be manufactured and processed at a fraction of the cost of silicon-based columns. In addition, the method can be used to phase-coat conventional capillary columns or silicon-based microfabricated columns.

Wheeler, David R. (Albuquerque, NM); Lewis, Patrick R. (Albuquerque, NM); Dirk, Shawn M. (Albuquerque, NM); Trudell, Daniel E. (Albuquerque, NM)

2008-01-01T23:59:59.000Z

350

Salt Lake County Residential Solar Financing Study  

Broader source: Energy.gov [DOE]

As part of our engagement with the National Renewable Energy Laboratories conducting the Salt Lake County Solar America Residential Finance Study, we have drafted this report summarizing the tools and mechanisms available for residential solar projects. These include the financial incentives available, possible financing models that could be used in the County, and a review of the community-scale solar project in St. George, Utah. We have also provided cost estimates for each system.

351

New public information resources on salt caverns.  

SciTech Connect (OSTI)

For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has funded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

Tomasko, D.; Veil, J. A.

1999-08-25T23:59:59.000Z

352

New public information resources on salt caverns.  

SciTech Connect (OSTI)

For the past decade, interest has been growing in using underground salt caverns for disposing of wastes. The Railroad Commission of Texas has permitted a few caverns for disposal of nonhazardous oil field waste (NOW) and one cavern for disposal of naturally occurring radioactive materials (NORM) from oil field activities. Several salt caverns in Canada have also been permitted for disposal of NOW. In addition, oil and gas agencies in Louisiana and New Mexico are developing cavern disposal regulations. The US Department of Energy (DOE) has funded several studies to evaluate the technical feasibility, legality, economic viability, and risk of disposing of NOW and NORM in caverns. The results of these studies have been disseminated to the scientific and regulatory communities. However, as use of caverns for waste disposal increases, more government and industry representatives and members of the public will become aware of this practice and will need adequate information about how disposal caverns operate and the risks they pose. In anticipation of this need, DOE has fi.mded Argonne National Laboratory to develop a salt cavern public outreach program. Key components of this program are an informational brochure designed for nontechnical persons and a website that provides greater detail on cavern operations and allows downloadable access to the reports on the topic funded by DOE. This paper provides an overview of the public outreach program.

Tomasko, D.; Veil, J. A.

1999-08-25T23:59:59.000Z

353

High thermal energy storage density molten salts for parabolic trough solar power generation.  

E-Print Network [OSTI]

??New alkali nitrate-nitrite systems were developed by using thermodynamic modeling and the eutectic points were predicted based on the change of Gibbs energy of fusion.… (more)

Wang, Tao

2011-01-01T23:59:59.000Z

354

The effects of combined catalysis of oxalic acid and seawater on the kinetics of xylose and arabinose dehydration to furfural  

Science Journals Connector (OSTI)

It is known that both acids and salts have a positive catalytic effect on the dehydration of pentoses to form furfural, a potentially attractive platform chemical. In this study the effects of the combined usa...

Wijittra Hongsiri; Bart Danon…

2014-11-01T23:59:59.000Z

355

The conversion of corn stover and pig manure to carboxylic acids with the MixAlco process  

E-Print Network [OSTI]

The MixAlco process, developed by Dr. Mark T. Holtzapple, uses anaerobic fermentation to convert waste biomass into carboxylate salts which can then be manipulated into carboxylic acids, ketones and alcohols. This project focuses on the application...

Black, Amanda Spring

2013-02-22T23:59:59.000Z

356

A hypothesis concerning the distribution of salt and salt structures in the Gulf of Mexico  

E-Print Network [OSTI]

A IIYPO'rklESIS CO/iCI, RI~ IG TktE DISTRIIoUTIO l OE SALT I'D cAET STRU TURES Rci TIIE GU:I 0= VEXICO A Thesis by JOIIN 'O'OODYJ ORTII A ?TOINE Subrnitte. ' to th, Graouate CoU~ Se Texas A i~. '4 University in partial fv~t'Ub~s "u o I... the reouirernent 'or th ~ cl . . gree o', ' i%I A S T E R 0 E S C IF. U C E ivla y 1 9 I 6 Mr jo? Subject: Geolnsical Oceanography A HYPOTHESIS CONCERNING THE DISTRIBUTION OF SALT AND SALT STRUCTURES IN THE GULF OF MEXICO A Thesis by JOHN WOODWORTH ANTOINE...

Antoine, John Woodworth

2012-06-07T23:59:59.000Z

357

Salt disposal of heat-generating nuclear waste.  

SciTech Connect (OSTI)

This report summarizes the state of salt repository science, reviews many of the technical issues pertaining to disposal of heat-generating nuclear waste in salt, and proposes several avenues for future science-based activities to further the technical basis for disposal in salt. There are extensive salt formations in the forty-eight contiguous states, and many of them may be worthy of consideration for nuclear waste disposal. The United States has extensive experience in salt repository sciences, including an operating facility for disposal of transuranic wastes. The scientific background for salt disposal including laboratory and field tests at ambient and elevated temperature, principles of salt behavior, potential for fracture damage and its mitigation, seal systems, chemical conditions, advanced modeling capabilities and near-future developments, performance assessment processes, and international collaboration are all discussed. The discussion of salt disposal issues is brought current, including a summary of recent international workshops dedicated to high-level waste disposal in salt. Lessons learned from Sandia National Laboratories' experience on the Waste Isolation Pilot Plant and the Yucca Mountain Project as well as related salt experience with the Strategic Petroleum Reserve are applied in this assessment. Disposal of heat-generating nuclear waste in a suitable salt formation is attractive because the material is essentially impermeable, self-sealing, and thermally conductive. Conditions are chemically beneficial, and a significant experience base exists in understanding this environment. Within the period of institutional control, overburden pressure will seal fractures and provide a repository setting that limits radionuclide movement. A salt repository could potentially achieve total containment, with no releases to the environment in undisturbed scenarios for as long as the region is geologically stable. Much of the experience gained from United States repository development, such as seal system design, coupled process simulation, and application of performance assessment methodology, helps define a clear strategy for a heat-generating nuclear waste repository in salt.

Leigh, Christi D. (Sandia National Laboratories, Carlsbad, NM); Hansen, Francis D.

2011-01-01T23:59:59.000Z

358

The influence of high quantity of fly ash on reducing the expansion due to ASR in the presence of alkalis  

E-Print Network [OSTI]

A testing program was devised to study the role of high volume fly ash (HVFA) in reducing the expansion caused by alkali-silica reaction (ASR). A series of modified ASTM C 1260 tests were performed, where the replacement of cement by Class F fly ash...

Mohidekar, Saleel D.

2000-01-01T23:59:59.000Z

359

Rheological properties of water-coal slurries based on brown coal in the presence of sodium lignosulfonates and alkali  

SciTech Connect (OSTI)

The effect of the oxidized surface of brown coal on the structural and rheological properties of water-coal slurries was found. The kinetics of structure formation processes in water-coal slurries based on as-received and oxidized brown coal was studied. The effect of lignosulfonate and alkali additives on the samples of brown coal was considered.

D.P. Savitskii; A.S. Makarov; V.A. Zavgorodnii [National Academy of Sciences of Ukraine, Kiev (Ukraine). Dumanskii Institute of Colloid and Water Chemistry

2009-07-01T23:59:59.000Z

360

DOI: 10.1002/chem.200702012 Properties of Alkali Metal Atoms Deposited on a MgO Surface: A  

E-Print Network [OSTI]

, such as in tungsten bronzes, this may turn a wide-gap insulating oxide into a material with metallic conductivity, Na, K, Rb, and Cs) on the surface of MgO powders and thin films has been stud- ied by means of EPR. These reductions in the hfccs are due to polarization effects and are not connected to ionization of the alkali

Gao, Hongjun

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Heating rates in collisionally opaque alkali-metal atom traps: Role of secondary collisions  

Science Journals Connector (OSTI)

Grazing collisions with background gas are the major cause of trap loss and trap heating in atom traps. To first order, these effects do not depend on the trap density. In collisionally opaque trapped atom clouds, however, scattered atoms with an energy E larger than the effective trap depth Eeff, which are destined to escape from the atom cloud, will have a finite probability for a secondary collision. This results in a contribution to the heating rate that depends on the column density ?nl? of the trapped atoms, i.e., the product of density and characteristic size of the trap. For alkali-metal atom traps, secondary collisions are quite important due to the strong long-range interaction with like atoms. We derive a simple analytical expression for the secondary heating rate, showing a dependency proportional to ?nl??Eeff1/2. When extrapolating to a vanishing column density, only primary collisions with the background gas will contribute to the heating rate. This contribution is rather small, due to the weak long-range interaction of the usual background gas species in an ultrahigh-vacuum system—He, Ne, or Ar—with the trapped alkali-metal atoms. We conclude that the transition between trap-loss collisions and heating collisions is determined by a cutoff energy 200??K<~Eeff<~400??K, much smaller than the actual trap depth E in most magnetic traps. Atoms with an energy Eeffalkali-metal atoms Li through Cs as a function of the effective trap depth, the column density of the trap, and the species in the background gas. The predictions of our model are in good agreement with the experimental data of Myatt for heating rates in high-density 87Rb-atom magnetic traps at JILA, including the effect of the rf shield and the composition of the background gas. It is shown that collisions with atoms from the Oort cloud also contribute to the heating rate. For 85Rb the calculated heating rate is below the experimentally observed value at JILA, supporting the idea that inelastic collisions in the trap are the major source of heating.

H. C. W. Beijerinck

2000-11-15T23:59:59.000Z

362

DEGRADED TBP SOLVENT REGENERATION TECHNOLOGY USING BUTYLAMINE AS A SOLVENT WASHING TO REDUCE SOLID SALT WASTE  

SciTech Connect (OSTI)

Normal butylamine compounds are studied as salt-free wash reagents for degraded solvent used in PUREX process in spent fuel reprocessing. The solvent wash tests were carried out with two types of butylamine compounds, n-butylamine oxalate and n-butylamine bicarbonate, by counter-current mode using a small size mixer-settler composed of two 4-stage wash steps. Di-n-butyl phosphoric acid (HDBP), the main degradation product from TBP, was removed from real degraded solvent with decontamination factor of 2.5 {approx} 7.9. The study on electrolytic decomposition of butylamine compounds was also conducted for waste treatment.

Asakura, T.; Itoh, Y.; Hotoku, S.; Morita, Y.; Uchiyama, G.

2003-02-27T23:59:59.000Z

363

Independent Oversight Assessment, Salt Waste Processing Facility Project -  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Processing Facility Salt Waste Processing Facility Project - January 2013 Independent Oversight Assessment, Salt Waste Processing Facility Project - January 2013 January 2013 Assessment of Nuclear Safety Culture at the Salt Waste Processing Facility Project The U.S. Department of Energy (DOE) Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent assessment of nuclear safety culture at the Salt Waste Processing Facility (SWPF) Project. The primary objective of the evaluation was to provide information regarding the status of the safety culture at the SWPF Project. The data collection phase of the assessment occurred during August - September 2012. Independent Oversight Assessment, Salt Waste Processing Facility Project -

364

Disposing of nuclear waste in a salt bed  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Disposing of nuclear waste in a salt bed Disposing of nuclear waste in a salt bed 1663 Los Alamos science and technology magazine Latest Issue:November 2013 All Issues » submit Disposing of nuclear waste in a salt bed Decades' worth of transuranic waste from Los Alamos is being laid to rest at the Waste Isolation Pilot Plant in southeastern New Mexico March 25, 2013 Disposing of nuclear waste in a salt bed Depending on the impurities embedded within it, the salt from WIPP can be anything from a reddish, relatively opaque rock to a clear crystal like the one shown here. Ordinary salt effectively seals transuranic waste in a long-term repository Transuranic waste, made of items such as lab coats and equipment that have been contaminated by radioactive elements heavier than uranium, is being shipped from the Los Alamos National Laboratory to a long-term storage

365

Salt tectonics, patterns of basin fill, and reservoir distribution  

SciTech Connect (OSTI)

Salt structures, which develop due to sediment loading, gravity creep, and/or buoyance, include boundary-fault grabens and half grabens, rollers, anticlines, domes and walls, diapirs, sills, massifs, and compressional toe structure. Associated features include fault systems and turtle structures. Of these, six directly relate to basin fill and all directly influence the distribution of reservoir facies. Salt structuring is initiated by sedimentation, which in turn is localized by salt withdrawal. Withdrawal produces individual salt structures, migrating sills, dissected massifs, and regional depocenters bordered by salt walls. Composite withdrawals dictate the patterns of basin fill. Relative rates of structural growth and sedimentation control the distribution of reservoir facies. When growth dominates, sands are channeled into lows. When sedimentation dominates and maintains flat surfaces, facies distribution is not impacted except where faulting develops. This paper presents techniques for using seismic data to determine the controls on salt structural growth and sedimentation and the patterns of basin fill and reservoir distribution.

Yorston, H.J.; Miles, A.E.

1988-01-01T23:59:59.000Z

366

Supai salt karst features: Holbrook Basin, Arizona  

SciTech Connect (OSTI)

More than 300 sinkholes, fissures, depressions, and other collapse features occur along a 70 km (45 mi) dissolution front of the Permian Supai Formation, dipping northward into the Holbrook Basin, also called the Supai Salt Basin. The dissolution front is essentially coincident with the so-called Holbrook Anticline showing local dip reversal; rather than being of tectonic origin, this feature is likely a subsidence-induced monoclinal flexure caused by the northward migrating dissolution front. Three major areas are identified with distinctive attributes: (1) The Sinks, 10 km WNW of Snowflake, containing some 200 sinkholes up to 200 m diameter and 50 m depth, and joint controlled fissures and fissure-sinks; (2) Dry Lake Valley and contiguous areas containing large collapse fissures and sinkholes in jointed Coconino sandstone, some of which drained more than 50 acre-feet ({approximately}6 {times} 10{sup 4} m{sup 3}) of water overnight; and (3) the McCauley Sinks, a localized group of about 40 sinkholes 15 km SE of Winslow along Chevelon Creek, some showing essentially rectangular jointing in the surficial Coconino Formation. Similar salt karst features also occur between these three major areas. The range of features in Supai salt are distinctive, yet similar to those in other evaporate basins. The wide variety of dissolution/collapse features range in development from incipient surface expression to mature and old age. The features began forming at least by Pliocene time and continue to the present, with recent changes reportedly observed and verified on airphotos with 20 year repetition. The evaporate sequence along interstate transportation routes creates a strategic location for underground LPG storage in leached caverns. The existing 11 cavern field at Adamana is safely located about 25 miles away from the dissolution front, but further expansion initiatives will require thorough engineering evaluation.

Neal, J.T.

1994-12-31T23:59:59.000Z

367

Consolidation and permeability of salt in brine  

SciTech Connect (OSTI)

The consolidation and loss of permeability of salt crystal aggregates, important in assessing the effects of water in salt repositories, has been studied as a function of several variables. The kinetic behavior was similar to that often observed in sintering and suggested the following expression for the time dependence of the void fraction: phi(t) = phi(0) - (A/B)ln(1 + Bt/z(0)/sup 3/), where A and B are rate constants and z(0) is initial average particle size. With brine present, A and phi(0) varied linearly with stress. The initial void fraction was also dependent to some extent on the particle size distribution. The rate of consolidation was most rapid in brine and least rapid in the presence of only air as the fluid. A brine containing 5 m MgCl/sub 2/ showed an intermediate rate, presumably because of the greatly reduced solubility of NaCl. A substantial wall effect was indicated by an observed increase in the void fraction of consolidated columns with distance from the top where the stress was applied and by a dependence of consolidation rate on the column height and radius. The distance through which the stress fell by a factor of phi was estimated to change inversely as the fourth power of the column diameter. With increasing temperature (to 85/sup 0/C), consolidation proceeded somewhat more rapidly and the wall effect was reduced. The permeability of the columns dropped rapidly with consolidation, decreasing with about the sixth power of the void fraction. In general, extrapolation of the results to repository conditions confirms the self-sealing properties of bedded salt as a storage medium for radioactive waste.

Shor, A.J.; Baes, C.F. Jr.; Canonico, C.M.

1981-07-01T23:59:59.000Z

368

Carrier-wave Rabi flopping signatures in high-order harmonic generation for alkali atoms  

E-Print Network [OSTI]

We present the first theoretical investigation of carrier-wave Rabi flopping in real atoms by employing numerical simulations of high-order harmonic generation (HHG) in alkali species. Given the short HHG cutoff, related to the low saturation intensity, we concentrate on the features of the third harmonic of sodium (Na) and potassium (K) atoms. For pulse areas of 2$\\pi$ and Na atoms, a characteristic unique peak appears, which, after analyzing the ground state population, we correlate with the conventional Rabi flopping. On the other hand, for larger pulse areas, carrier-wave Rabi flopping occurs, and is associated with a more complex structure in the third harmonic. These new characteristics observed in K atoms indicate the breakdown of the area theorem, as was already demonstrated under similar circumstances in narrow band gap semiconductors.

Ciappina, M F; Landsman, A S; Zimmermann, T; Lewenstein, M; Roso, L; Krausz, F

2015-01-01T23:59:59.000Z

369

Alkali-metal stoichiometry and structure of K4C60 and Rb4C60  

Science Journals Connector (OSTI)

Alkali-metal fulleride samples KxC60 and RbxC60 with stoichiometries close to x=4 were examined with x-ray powder-diffraction measurements at room temperature. We have shown through Rietveld refinements that A4C60 is a line phase with charge per lattice site that is closer to integer than in any other fulleride. The C60 molecules are disordered between two possible orientations within the body-centered-tetragonal lattice with the three orthogonal twofold rotation axes aligned with the unit-cell translation vectors in space group I4/mmm. The x-ray diffraction results exclude any quadrupole distortion of the fullerene molecule beyond about 0.04 ?. These results suggest that K4C60 and Rb4C60 may be Mott insulators.

Christine A. Kuntscher; Götz M. Bendele; Peter W. Stephens

1997-02-01T23:59:59.000Z

370

Energy conservation in the primary aluminum and chlor-alkali industries  

SciTech Connect (OSTI)

The primary aluminum and chlor-alkali industries together use nearly 13% of the electrical energy consumed by US industry. As part of its mission to promote energy conservation in basic US industries, the DOE surveys the present technological status of the major electrochemical industries and evaluates promising technological innovations that may lead to reduced energy requirements. This study provides technical and economic analyses in support of a government program of research and development in advanced electrolytic technology. This program is intended to supplement the development efforts directed toward energy savings by private industry. Sections II and III of this report cover aluminum and chlorine production processes only, since these two industries represent over 90% of the electrical energy requirements of all electrolytic industries in the United States. Section IV examines barriers to accelerated research and development by the electrolytic industries, and makes suggestions for government actions to overcome these barriers.

Not Available

1980-10-01T23:59:59.000Z

371

Atomic polar tensors and acid-base properties of metal-oxide building blocks  

SciTech Connect (OSTI)

The sensitivity of the atomic polar tensor to compositional substituents is reported for the alkali silicate series. Rotational invariants, effective atomic charge (GAPT) and charge normalized anisotropy and dipole ({alpha}{sub n} and {gamma}{sub n}) are used to characterize the charge distribution and chemical environment of the atomic sites. Comparison of {alpha}{sub n} and {gamma}{sub n} with a series of known Bronsted and Lewis acids and bases suggests that these rotational invariants may act as indicators for metal-oxide site acidities. Basis set and electron correlation particularly affect the determined effective charge, but show minimal effect on {alpha} and {gamma} quantities.

Ferris, K.F.

1993-02-01T23:59:59.000Z

372

Atomic polar tensors and acid-base properties of metal-oxide building blocks  

SciTech Connect (OSTI)

The sensitivity of the atomic polar tensor to compositional substituents is reported for the alkali silicate series. Rotational invariants, effective atomic charge (GAPT) and charge normalized anisotropy and dipole ([alpha][sub n] and [gamma][sub n]) are used to characterize the charge distribution and chemical environment of the atomic sites. Comparison of [alpha][sub n] and [gamma][sub n] with a series of known Bronsted and Lewis acids and bases suggests that these rotational invariants may act as indicators for metal-oxide site acidities. Basis set and electron correlation particularly affect the determined effective charge, but show minimal effect on [alpha] and [gamma] quantities.

Ferris, K.F.

1993-02-01T23:59:59.000Z

373

Experimental studies of actinides in molten salts  

SciTech Connect (OSTI)

This review stresses techniques used in studies of molten salts containing multigram amounts of actinides exhibiting intense alpha activity but little or no penetrating gamma radiation. The preponderance of studies have used halides because oxygen-containing actinide compounds (other than oxides) are generally unstable at high temperatures. Topics discussed here include special enclosures, materials problems, preparation and purification of actinide elements and compounds, and measurements of various properties of the molten volts. Property measurements discussed are phase relationships, vapor pressure, density, viscosity, absorption spectra, electromotive force, and conductance. 188 refs., 17 figs., 6 tabs.

Reavis, J.G.

1985-06-01T23:59:59.000Z

374

Salt River Project electric vehicle program  

SciTech Connect (OSTI)

Electric vehicles (EV) promise to be a driving force in the future of America. The quest for cleaner air and efforts to trim the nation's appetite for foreign oil are among the reasons why. America's EV future is rapidly approaching, with major automakers targeting EV mass production and sales before the end of the decade. This article describes the Salt River Project (SRP), a leader among electric utilities involved in EV research and development (R and D). R and D efforts are underway to plan and prepare for a significant number of EVs in SRP's service territory and to understand the associated recharging requirements for EVs.

Morrow, K.P.

1994-11-01T23:59:59.000Z

375

Delivery system for molten salt oxidation of solid waste  

DOE Patents [OSTI]

The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

376

Integrated demonstration of molten salt oxidation with salt recycle for mixed waste treatment  

SciTech Connect (OSTI)

Molten Salt Oxidation (MSO) is a thermal, nonflame process that has the inherent capability of completely destroying organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. Lawrence Livermore National Laboratory (LLNL) has prepared a facility and constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are performed under carefully controlled (experimental) conditions. The system consists of a MSO processor with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. This integrated system was designed and engineered based on laboratory experience with a smaller engineering-scale reactor unit and extensive laboratory development on salt recycle and final forms preparation. In this paper we present design and engineering details of the system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is identification of the most suitable waste streams and waste types for MSO treatment.

Hsu, P.C.

1997-11-01T23:59:59.000Z

377

Columbus Salt Marsh Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Columbus Salt Marsh Geothermal Area Columbus Salt Marsh Geothermal Area (Redirected from Columbus Salt Marsh Area) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Columbus Salt Marsh Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (3) 10 References Area Overview Geothermal Area Profile Location: California Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure

378

salt-water pumped-storage hydroelectric plant  

Science Journals Connector (OSTI)

salt-water pumped-storage hydroelectric plant, saltwater pumped-storage hydroelectric station, seawater pumped-storage hydroelectric plant, seawater pumped-storage hydroelectric station ? Salzwasser-...

2014-08-01T23:59:59.000Z

379

Independent Oversight Review, Savannah River Site Salt Waste...  

Energy Savers [EERE]

Waste Treatment and Immobilization Plant - May 2013 Voluntary Protection Program Onsite Review, Salt Waste Processing Facility Construction Project - February 2013 CRAD,...

380

Sedimentation and resuspension in a New England salt marsh  

Science Journals Connector (OSTI)

Particulate matter in a salt marsh can undergo repeated sedimentation and resuspension. Sedimentation measured with sediment traps, increases ... suggests that sedimentation is more than offset by resuspension. Resuspension

Thomas E. Jordan; Ivan Valiela

1983-01-23T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Method for the production of uranium chloride salt  

DOE Patents [OSTI]

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

382

Project Profile: Molten Salt-Carbon Nanotube Thermal Storage  

Broader source: Energy.gov [DOE]

Texas Engineering Experiment Station (TEES), under the Thermal Storage FOA, created a composite thermal energy storage material by embedding nanoparticles in a molten salt base material.

383

Notice of Availability of Section 3116 Determination for Salt...  

Office of Environmental Management (EM)

in the SPA SEIS, short- term impacts are incurred during operation of the salt waste processing facilities, and long-term impacts are those resulting from release of...

384

Fundamental Corrosion Studies in High-Temperature Molten Salt...  

Broader source: Energy.gov (indexed) [DOE]

Studies in High-Temperature Molten Salt Systems for CSP Applications Savannah River National Laboratory April 15, 2013 | Garcia-Diaz * The overall project approach will combine...

385

Corrosion Studies in High-Temperature Molten Salt Systems for...  

Broader source: Energy.gov (indexed) [DOE]

Studies in High-Temperature Molten Salt Systems for CSP Applications Savannah River National Laboratory Garcia-Diaz A 1152013:Garcia-Diaz * The overall project approach will...

386

Multispectral Imaging At Columbus Salt Marsh Area (Shevenell...  

Open Energy Info (EERE)

Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Columbus Salt Marsh Area Exploration Technique Multispectral Imaging Activity Date Usefulness useful...

387

Fundamental Corrosion Studies in High-Temperature Molten Salt...  

Broader source: Energy.gov (indexed) [DOE]

Molten Salt Systems for CSP Applications - FY13 Q1 Advanced Ceramic Materials and Packaging Technologies for Realizing Sensors for Concentrating Solar Power Systems...

388

Molten salt bath circulation design for an electrolytic cell  

DOE Patents [OSTI]

An electrolytic cell for reduction of a metal oxide to a metal and oxygen has an inert anode and an upwardly angled roof covering the inert mode. The angled roof diverts oxygen bubbles into an upcomer channel, thereby agitating a molten salt bath in the upcomer channel and improving dissolution of a metal oxide in the molten salt bath. The molten salt bath has a lower velocity adjacent the inert anode in order to minimize corrosion by substances in the bath. A particularly preferred cell produces aluminum by electrolysis of alumina in a molten salt bath containing aluminum fluoride and sodium fluoride. 4 figs.

Dawless, R.K.; LaCamera, A.F.; Troup, R.L.; Ray, S.P.; Hosler, R.B.

1999-08-17T23:59:59.000Z

389

THE PARTIAL EQUIVALENT VOLUMES OF SALTS IN SEAWATER  

Science Journals Connector (OSTI)

of the major salts in seawater have been mcasurcd over the salinity ... model of seawater by considering seawater .... mained essentially constant during storage.

390

Waste Isolation Pilot Plant's Excavated Salt Agreement Supports...  

Broader source: Energy.gov (indexed) [DOE]

result in large volumes of excavated salt. Seeking an innovative alternative to landfill disposal, EM's Carlsbad Field Office (CBFO) reached an agreement with Magnum...

391

Sustainable Energy Source for Water Pumping at Puttalam Salt Limited.  

E-Print Network [OSTI]

?? The cost of grid based electrical and diesel sea water pumping to salt fields is one of the major cost components out of the… (more)

Kamaldeen, Mohammed Rizwan

2014-01-01T23:59:59.000Z

392

Hybrid Molten Salt Reactor (HMSR): Method and System to fully...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hybrid Molten Salt Reactor (HMSR): Method and System to fully fission actinides for electric power production without fuel enrichment, fabrication, or reprocessing A method for...

393

Improved volatile fatty acid and biomethane production from lipid removed microalgal residue (LR?AR) through pretreatment  

Science Journals Connector (OSTI)

Abstract Renewable energy from lipid removed microalgal residues (LR?ARs) serves as a promising tool for sustainable development of the microalgal biodiesel industry. Hence, in this study, LR?AR from Ettlia sp. was characterized for its physico-biochemical parameters, and applied to various pretreatment to increase the biodegradability and used in batch experiments for the production of volatile fatty acids (VFA) and biomethane. After various pretreatments, the soluble organic matters were increased at a maximum of 82% in total organic matters in alkali-autoclaved sample. In addition, VFA and methane production was enhanced by 30% and 40% in alkali-sonicated and alkali-autoclaved samples, respectively. Methane heating value was recovered at maximum of 6.6 MJ kg?1 VS in alkali-autoclaved conditions with comparison to non-pretreated samples. The pretreatment remarkably improved LR?AR solubilization and enhanced VFA and biomethane production, which holds immense potential to eventually reduce the cost of algal biodiesel.

Arumuganainar Suresh; Charles Seo; Ho Nam Chang; Yeu-Chun Kim

2013-01-01T23:59:59.000Z

394

Excavation Damaged Zones In Rock Salt Formations  

SciTech Connect (OSTI)

Salt formations have long been proposed as potential host rocks for nuclear waste disposal. After the operational phase of a repository the openings, e.g., boreholes, galleries, and chambers, have to be sealed in order to avoid the release of radionuclides into the biosphere. For optimising the sealing techniques knowledge about the excavation damaged zones (EDZ) around these openings is essential. In the frame of a project performed between 2004 and 2007, investigations of the EDZ evolution were performed in the Stassfurt halite of the Asse salt mine in northern Germany. Three test locations were prepared in the floor of an almost 20 year old gallery on the 800-m level of the Asse mine: (1) the drift floor as existing, (2) the new drift floor shortly after removing of a layer of about 1 m thickness of the floor with a continuous miner, (3) the new drift floor 2 years after cutting off the 1-m layer. Subject of investigation were the diffusive and advective gas transport and the advective brine transport very close to the opening. Spreading of the brine was tracked by geo-electric monitoring in order to gain information about permeability anisotropy. Results obtained showed that EDZ cut-off is a useful method to improve sealing effectiveness when constructing technical barriers. (authors)

Jockwer, N.; Wieczorek, K. [Gesellschaft fur Anlagen- und Reaktorsicherheit (GRS) mbH, Braunschweig (Germany)

2008-07-01T23:59:59.000Z

395

E-Print Network 3.0 - alkali metals phase Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , calcium hypochlorite, hydrogen fluoride (HF) Ammonium Nitrate acids, metal powders, flammable liquids... , sodium carbide, turpentine, finely divided metals...

396

E-Print Network 3.0 - alkali metal dimers Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: , calcium hypochlorite, hydrogen fluoride (HF) Ammonium Nitrate acids, metal powders, flammable liquids... , sodium carbide, turpentine, finely divided metals...

397

Savannah River Site- Salt Waste Processing Facility: Briefing on the Salt Waste Processing Facility Independent Technical Review  

Broader source: Energy.gov [DOE]

This is a presentation outlining the Salt Waste Processing Facility process, major risks, approach for conducting reviews, discussion of the findings, and conclusions.

398

From pre-salt sources to post-salt traps: A specific petroleum system in Congo coastal basin  

SciTech Connect (OSTI)

The Bas Congo basin extends from Gabon to Angola and is a prolific oil province where both pre-salt and post salt sources and reservoirs have been found. In the northern part of the basin referred to as the Congo coastal basin, the proven petroleum system is more specific: mature source rocks are found only in pre-salt series whereas by contrast 99 % proven hydrocarbon reserves am located in post-salt traps. Such a system is controlled by the following factors: Source rocks are mostly organic rich shales deposited in a restricted environment developed in a rift prior to the Atlantic Ocean opening; Migration from pre-salt sources to post-salt traps is finalized by local discontinuities of the regional salt layer acting otherwise as a tight seal; Post-salt reservoirs are either carbonates or sands desposited in the evolutive shelf margin developped during Upper Cretaceous; Geometric traps are linked to salt tectonics (mostly turtle-shaped structures); Regional shaly seals are related to transgressive shales best developped during high rise sea level time interval. Stratigraphically, the age of hydrocarbon fields trends are younger and younger from West to East: lower Albian in Nkossa, Upper Albian and lower Cenomanian in Likouala, Yanga, Sendji, Upper Cenomanian in Tchibouela, Turonian in Tchendo, Turanian and Senonian in Emeraude.

Vernet, R.

1995-08-01T23:59:59.000Z

399

Modeling of flowing gas diode pumped alkali lasers: dependence of the operation on the gas velocity and on the nature of the buffer gas  

Science Journals Connector (OSTI)

A simple, semi-analytical model of flowing gas diode pumped alkali lasers (DPALs) is presented. The model takes into account the rise of temperature in the lasing medium with...

Barmashenko, B D; Rosenwaks, S

2012-01-01T23:59:59.000Z

400

Populations of Methanogenic Bacteria in a Georgia Salt Marsh  

Science Journals Connector (OSTI)

...28. Oremland, R. S., L. M. Marsh, and S. Polcin...reduction in anoxic, salt marsh sediments. Nature...29. Oremland, R. S., and S. Polcin...Pomeroy, L. R., and R. G. Wiegert. 1981. The ecology of a salt marsh. Springer-Verlag...

Michael J. Franklin; William J. Wiebe; William B. Whitman

1988-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

SALT DAMAGE CRITERION PROOF-OF-CONCEPT RESEARCH  

SciTech Connect (OSTI)

The purpose of this study was to conduct a field-scale application demonstrating the use of continuum damage mechanics to determine the minimum allowable operating pressure of compressed natural gas storage caverns in salt formations. A geomechanical study was performed of two natural gas storage caverns (one existing and one planned) utilizing state-of-the-art salt mechanics to assess the potential for cavern instability and collapse. The geomechanical study consisted primarily of laboratory testing, theoretical development, and analytical/numerical tasks. A total of 50 laboratory tests was performed on salt specimens to aid in the development and definition of the material model used to predict the behavior of rock salt. Material model refinement was performed that improved the predictive capability of modeling salt during damage healing, recovery of work-hardened salt, and the behavior of salt at stress states other than triaxial compression. Results of this study showed that the working gas capacity of the existing cavern could be increased by 18 percent and the planned cavern could be increased by 8 percent using the proposed method compared to a conventional stress-based method. Further refinement of the continuum damage model is recommended to account for known behavior of salt at stress conditions other than triaxial compression that is not characterized accurately by the existing model.

Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan

2002-11-01T23:59:59.000Z

402

Molten salts and nuclear energy production Christian Le Bruna*  

E-Print Network [OSTI]

Molten salts and nuclear energy production Christian Le Bruna* a Laboratoire de Physique or chlorides) have been taken in consideration very soon in nuclear energy production researches with solid fuels, liquid fuel in molten salt reactor, solvents for spent nuclear solid fuel in the case

Boyer, Edmond

403

Detection and removal of molten salts from molten aluminum alloys  

SciTech Connect (OSTI)

Molten salts are one source of inclusions and defects in aluminum ingots and cast shapes. A selective adsorption media was used to remove these inclusions and a device for detection of molten salts was tested. This set of experiments is described and the results are presented and analyzed.

K. Butcher; D. Smith; C. L. Lin; L. Aubrey

1999-08-02T23:59:59.000Z

404

Brachybacterium squillarum sp. nov., isolated from salt-fermented seafood  

E-Print Network [OSTI]

Brachybacterium squillarum sp. nov., isolated from salt-fermented seafood Seong-Kyu Park, Min salt-fermented seafood in Korea. The organism grew in 0­10 % (w/v) NaCl and at 25­37 6C, with optimal

Bae, Jin-Woo

405

Kocuria salsicia sp. nov., isolated from salt-fermented seafood  

E-Print Network [OSTI]

Kocuria salsicia sp. nov., isolated from salt- fermented seafood Ji-Hyun Yun,1 Seong Woon Roh,1 salt-fermented seafood in Korea. It was a Gram- positive, non-motile, coccus-shaped bacterium-fermented seafood (`gajami-sikhae') from Korea. Following isolation on marine agar 2216 (MA, BBL) at 30 uC, a pure

Bae, Jin-Woo

406

Salt tectonics, patterns of basin fill, and reservoir distribution  

SciTech Connect (OSTI)

Salt structures, which develop due to sediment loading, gravity creep, and/or buoyancy, include boundary-fault grabens and half grabens, rollers, anticlines, domes and walls, diapirs, sills, massifs, and compressional toe structures. Associated features include fault systems and turtle structures. Of these, six directly relate to basin fill and all directly influence the distribution of reservoir facies. Salt structuring is initiated by sedimentation, which in turn is localized by salt withdrawal. Withdrawal produces individual salt structures, migrating sills, dissected massifs, and regional depocenters bordered by salt walls. Composite withdrawals dictate the patterns of basin fill. Relative rates of structural growth and sedimentation control the distribution of reservoir facies. When growth dominates, sands are channeled into lows. When sedimentation dominates and maintains flat surfaces, facies distribution is not impacted except where faulting develops. Turtle structures, developed by the inversion of peripheral synclines, can move sands into favorable structural position and/or serve as platforms for carbonate reservoir development. Salt growth varies with type structure, stage of development, and rate of sedimentation. Sedimentation at a specific location depends on basin position, sediment transport system, sea level stand, and rate of salt withdrawal. This paper presents techniques for using seismic data to determine the controls on salt structural growth and sedimentation and the patterns of basin fill and reservoir distribution.

Yorston, H.J.; Miles, A.E.

1988-02-01T23:59:59.000Z

407

Independent Oversight Review, Savannah River Site Salt Waste Processing  

Broader source: Energy.gov (indexed) [DOE]

Savannah River Site Salt Waste Savannah River Site Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and design development for the Salt Waste Processing Facility (SWPF) at the U.S. Department of Energy (DOE) Savannah River Site. The review was performed February 12-14, 2013 by DOE's Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security. The purpose of the review was to evaluate the safety basis, design, and the associated technical documents developed for

408

BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project |  

Open Energy Info (EERE)

BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Abstract No abstract available. Author Bureau of Land Management Organization Bureau of Land Management, Carson City Field Office, Nevada Published U.S. Department of the Interior, 2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project Citation Bureau of Land Management (Bureau of Land Management, Carson City Field Office, Nevada). 2011. BLM Fact Sheet- Ormat Technologies Salt Wells Geothermal Energy Project. Carson City, Nevada: U.S. Department of the

409

Independent Oversight Review, Savannah River Site Salt Waste Processing  

Broader source: Energy.gov (indexed) [DOE]

Savannah River Site Salt Waste Savannah River Site Salt Waste Processing Facility - August 2013 Independent Oversight Review, Savannah River Site Salt Waste Processing Facility - August 2013 August 2013 Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development. This report documents the results of an independent oversight review of the safety basis and design development for the Salt Waste Processing Facility (SWPF) at the U.S. Department of Energy (DOE) Savannah River Site. The review was performed February 12-14, 2013 by DOE's Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security. The purpose of the review was to evaluate the safety basis, design, and the associated technical documents developed for

410

ENEL Salt Wells Geothermal Facility | Open Energy Information  

Open Energy Info (EERE)

ENEL Salt Wells Geothermal Facility ENEL Salt Wells Geothermal Facility Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home ENEL Salt Wells Geothermal Facility General Information Name ENEL Salt Wells Geothermal Facility Facility Salt Wells Geothermal Facility Sector Geothermal energy Location Information Location Churchill, NV Coordinates 39.651603422063°, -118.49778413773° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":39.651603422063,"lon":-118.49778413773,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

411

Controlled Source Frequency-Domain Magnetics At Salt Wells Area  

Open Energy Info (EERE)

Controlled Source Frequency-Domain Magnetics At Salt Wells Area Controlled Source Frequency-Domain Magnetics At Salt Wells Area (Montgomery, Et Al., 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Frequency-Domain Magnetics At Salt Wells Area (Montgomery, Et Al., 2005) Exploration Activity Details Location Salt Wells Area Exploration Technique Controlled Source Frequency-Domain Magnetics Activity Date 2004 - 2004 Usefulness useful DOE-funding Unknown Exploration Basis AMP Resource contracted Willowstick Technologies, LLC to conduct a Controlled Source-Frequency Domain Magnetics (CS-FDM) geophysical investigation at Salt Wells in order to characterize and delineate areas showing the greatest concentrations and highest temperatures of geothermal groundwater. The investigation also sought to map blind faults beneath the

412

Salt River Project SRP | Open Energy Information  

Open Energy Info (EERE)

SRP SRP Jump to: navigation, search Name Salt River Project (SRP) Place Tempe, Arizona Zip 85281-1298 Sector Biomass, Solar Product US utility which sources a percentage of its electricity from biomass plants. It is also involved in the solar power industry. Coordinates 33.42551°, -111.937419° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":33.42551,"lon":-111.937419,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

413

In situ NMR spectroscopy: Inulin biomass conversion in ZnCl2 molten salt hydrate medium—SnCl4 addition controls product distribution  

Science Journals Connector (OSTI)

Abstract The dehydration of inulin biomass to the platform chemicals, 5-hydroxymethylfurfural (5-HMF) and levulinic acid (LA), in ZnCl2 molten salt hydrate medium was investigated. The influence of the Lewis acid catalyst, SnCl4, on the product distribution was examined. An in situ 1H NMR technique was employed to follow the reaction at the molecular level. The experimental results revealed that only 5-HMF was obtained from degradation of inulin biomass in ZnCl2 molten salt hydrate medium, while the LA was gradually becoming the main product when the reaction temperature was increased in the presence of the Lewis acid catalyst SnCl4. In situ NMR spectroscopy could monitor the reaction and give valuable insight.

Yingxiong Wang; Christian Marcus Pedersen; Yan Qiao; Tiansheng Deng; Jing Shi; Xianglin Hou

2015-01-01T23:59:59.000Z

414

Ground state of the polar alkali-metal-atom-strontium molecules: Potential energy curve and permanent dipole moment  

SciTech Connect (OSTI)

In this study, we investigate the structure of the polar alkali-metal-atom-strontium diatomic molecules as possible candidates for the realization of samples of ultracold polar molecular species not yet investigated experimentally. Using a quantum chemistry approach based on effective core potentials and core polarization potentials, we model these systems as effective three-valence-electron systems, allowing for calculation of electronic properties with full configuration interaction. The potential curve and the permanent dipole moment of the {sup 2}{Sigma}{sup +} ground state are determined as functions of the internuclear distance for LiSr, NaSr, KSr, RbSr, and CsSr molecules. These molecules are found to exhibit a significant permanent dipole moment, though smaller than those of the alkali-metal-atom-Rb molecules.

Guerout, R. [Laboratoire Kastler-Brossel, CNRS, ENS, Univ Pierre et Marie Curie case 74, Campus Jussieu, F-75252 Paris Cedex 05 (France); Aymar, M.; Dulieu, O. [Laboratoire Aime Cotton, CNRS, UPR3321, Bat. 505, Univ Paris-Sud, F-91405 Orsay Cedex (France)

2010-10-15T23:59:59.000Z

415

The ground state of the polar alkali-Strontium molecules: potential energy curve and permanent dipole moment  

E-Print Network [OSTI]

In this study, we investigate the structure of the polar alkali-Strontium diatomic molecules as possible candidates for the realization of samples of new species of ultracold polar molecules. Using a quantum chemistry approach based on Effective Core Potentials and Core Polarization Potentials, we model these systems as effective three valence electron systems, allowing for calculation of electronic properties with Full Configuration Interaction. The potential curve and the permanent dipole moment of the $^2\\Sigma^+$ ground state are determined as functions of the internuclear distances for LiSr, NaSr, KSr, RbSr, and CsSr molecules. These molecules are found to exhibit a significant permanent dipole moment, though smaller than those of the alkali-Rb molecules.

Romain Guérout; Mireille Aymar; Olivier Dulieu

2010-07-12T23:59:59.000Z

416

Testing of low-temperature stabilization alternatives for salt containing mixed wastes -- Approach and results to date  

SciTech Connect (OSTI)

Through its annual process of identifying technology deficiencies associated with waste treatment, the Department of Energy`s (DOE) Mixed Waste Focus Area (MWFA) determined that the former DOE weapons complex lacks efficient mixed waste stabilization technologies for salt containing wastes. These wastes were generated as sludge and solid effluents from various primary nuclear processes involving acids and metal finishing; and well over 10,000 cubic meters exist at 6 sites. In addition, future volumes of these problematic wastes will be produced as other mixed waste treatment methods such as incineration and melting are deployed. The current method used to stabilize salt waste for compliant disposal is grouting with Portland cement. This method is inefficient since the highly soluble and reactive chloride, nitrate, and sulfate salts interfere with the hydration and setting processes associated with grouting. The inefficiency results from having to use low waste loadings to ensure a durable and leach resistant final waste form. The following five alternatives were selected for MWFA development funding in FY97 and FY98: phosphate bonded ceramics; sol-gel process; polysiloxane; polyester resin; and enhanced concrete. Comparable evaluations were planned for the stabilization development efforts. Under these evaluations each technology stabilized the same type of salt waste surrogates. Final waste form performance data such as compressive strength, waste loading, and leachability could then be equally compared. Selected preliminary test results are provided in this paper.

Maio, V.; Loomis, G. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States); Spence, R.D. [Oak Ridge National Lab., TN (United States); Smith, G. [Pacific Northwest National Lab., Richland, WA (United States); Biyani, R.K. [SGN Eurisys Services Corp., Richland, WA (United States); Wagh, A. [Argonne National Lab., IL (United States)

1998-05-01T23:59:59.000Z

417

The Ionization of Neon and Argon by Positive Alkali Ions of Energies from 650 to 2000 Volts  

Science Journals Connector (OSTI)

With an apparatus of new design the study of the ionization of neon and argon by positive alkali ions has been extended to accelerating potentials as high as 2000 volts. The results obtained are in good quantitative agreement with the previous work at the low potentials. In a number of cases the efficiency of ionization reaches a maximum at accelerating potentials less than 2000 volts.

J. Carlisle Mouzon

1932-09-01T23:59:59.000Z

418

A computational analysis of the evaporator/artery of an alkali metal thermal to electric conversion (AMTEC) PX series cell  

E-Print Network [OSTI]

, while minimizing mass. Current technology, such as Radioisotope Thermoelectric Generators (RTG's) are reliable, but do not supply the power conversion efficiencies desired for future space missions. That leads to Alkali Metal Thermal to Electric...-series cells to generate electricity for the deep space vehicle. The higher efficiency of AMTEC compared to other conversion technologies, such as Radioisotope Thermoelectric Generators (RTG's), results in less energy source material being launched...

Pyrtle, Frank

1999-01-01T23:59:59.000Z

419

E-Print Network 3.0 - australian sea salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Early salt tectonic processes and depositional systems in the Summary: -Permian Salt Basin, Southern North Sea Supervisors: Jrgen Adam (RHUL), Chris Elders (RHUL) Project...

420

Evolution in salt: Genomic and structural approaches to halophilic archaea and their viruses.  

E-Print Network [OSTI]

??Extremely saline environments include salt lakes, evaporation ponds, and terrestrial environments, such as salt deserts and underground halite deposits. They are inhabited by halophilic microbes… (more)

Jaakkola, Salla

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

E-Print Network 3.0 - avoid salt induced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with Salt Ions: An Electrostatic Theory for the Hofmeister Effect Summary: , an image charge is induced and a repulsive interaction between the salt ion and its image...

422

Elucidation of Mechanisms of Salinity Tolerance in Zoysia matrella Cultivars: A Study of Structure and Function of Salt Glands  

E-Print Network [OSTI]

Salt glands are important structural adaptations in some plant and animal species that are involved in the excretion of excess salts. Zoysia matrella is a highly salt tolerant turf grass that has salt glands. Two cultivars of Z. matrella, ‘Diamond...

Rao, Sheetal

2012-07-16T23:59:59.000Z

423

Kinetic studies for elucidation of the promoter effect of alkali in Fischer-Tropsch iron catalysts  

SciTech Connect (OSTI)

The kinetics of the formation of hydrocarbons in Fischer-Tropsch synthesis and of consecutive reactions, i.e., hydrogenation and double bond isomerization of primarily formed 1-alkenes, were studied in a slurry-phase reactor using alkalized and nonalkalized precipitated iron catalysts. Both consecutive reactions have an order of about -2 with respect to carbon monoxide and an order of about 1 with respect to 1-alkenes. The order with respect to hydrogen is 1 for the hydrocarbon formation and also 1 for the consecutive hydrogenation, but 0 for the consecutive isomerization. The reaction orders are not changed by addition of K{sub 2}CO{sub 3} to the catalyst. The kinetics of consecutive reactions can be interpreted by competitive adsorption of 1-alkene and carbon monoxide. Alkali addition causes an increase in the strength of carbon monoxide adsorption and consequently a decrease in 1-alkene adsorption so that the rates of the consecutive reactions are reduced. This hypothesis could be proved by studies of 1-hexene hydrogenation in the presence and absence of carbon monoxide for alkalized and nonalkalized iron catalysts. The kinetics were studied in the ranges 1.3 < P{sub CO}(10{sup 5} Pa) < 7, 1.6 < P{sub H{sub 2}}(10{sup 5} Pa) < 9, and 490 K < T < 530 K.

Herzog, K.; Gaube, J. (Institut fuer Chemische Technologie der Technischen Hochschule Darmstadt, Darmstadt (West Germany))

1989-02-01T23:59:59.000Z

424

Durability and microstructure characteristics of alkali activated coal bottom ash geopolymer cement  

Science Journals Connector (OSTI)

Abstract Many studies have focused on the production of mortar and concrete without cement. This is referred to as geopolymer mortar or concrete. This paper discusses the effect of alkali oxides (Na2O = 8, 12, 16 wt.% and SiO2 = 0, 4, 8, 12 wt.%) on compressive strength, microstructure and durability of circulating fluidized bed combustion coal bottom ash (CBA) geopolymer cements (GC). Durability and morphology tests were carried out through heating and freezing tests. The highest compressive strength (25.83 MPa) was achieved at Na2O wt.% = 12, SiO2 wt.% = 8. The optimum atomic ratios for a compact microstructure were obtained for Si/Al between 3.5 and 4 and Si/Na close to 0.5. Following the sintering, the main reaction products (N-A-S-H gel) became more amorphous at 800 °C, attaining Si/Al and Si/Na atomic ratios of 4.54 and 0.98. Sodium carbonate formation was observed at 800 °C. Also, the strength loss of GC was only 6.77% after 30 freeze-thaw cycles. The results show that durable geopolymer concrete without cement can be produced by using waste bottom coal ash. Therefore, the production of geopolymer concrete has a high environmental impact, decreasing waste material in addition to global warming.

?lker Bekir Topçu; Mehmet U?ur Toprak; Tayfun Uyguno?lu

2014-01-01T23:59:59.000Z

425

Theory of the alkali-metal chemisorption on metal surfaces. II.  

Science Journals Connector (OSTI)

The electronic structure of alkali-metal adlayers on metal surfaces is studied by first-principles calculations within the local-density-functional theory as a function of coverage (?). Hexagonal Na layers with varying lattice constants are used as adlayers, and the substrate is modeled by the semi-infinite jellium with rs=2, 3, and 4. The results obtained refine upon those in a previous work where the substrate was approximated by a jellium slab [Phys. Rev. B 38, 8006 (1988)]. In spite of the large potential lowering in the vacuum, the density of states in a Na sphere is rather insensitive to ?, except that the atomiclike resonances at low ? are broadened with increasing ? because of the formation of adlayer bands. For all the substrates, the bonding-antibonding boundary with regard to the Na-jellium bonding coincides with the Fermi level at the lowest ?, which implies that the covalency in the Na-jellium bond and the interatomic polarization term in the Na-induced dipole moment become the largest at the lowest ?. The rapid decrease of the dipole moment at higher ? is caused mainly by the direct Na-Na interaction due to the orbital overlap, which leads to a stronger Na-Na bond and simultaneously to a weaker Na-jellium bond, rather than by the indirect dipole-dipole interaction.

H. Ishida

1990-12-15T23:59:59.000Z

426

Laboratory simulation of salt dissolution during waste removal  

SciTech Connect (OSTI)

Laboratory experiments were performed to support the field demonstration of improved techniques for salt dissolution in waste tanks at the Savannah River Site. The tests were designed to investigate three density driven techniques for salt dissolution: (1) Drain-Add-Sit-Remove, (2) Modified Density Gradient, and (3) Continuous Salt Mining. Salt dissolution was observed to be a very rapid process as salt solutions with densities between 1.38-1.4 were frequently removed. Slower addition and removal rates and locating the outlet line at deeper levels below the top of the saltcake provided the best contact between the dissolution water and the saltcake. It was observed that dissolution with 1 M sodium hydroxide solution resulted in salt solutions that were within the current inhibitor requirements for the prevention of stress corrosion cracking. This result was independent of the density driven technique. However, if inhibited water (0.01 M sodium hydroxide and 0.011 M sodium nitrite) was utilized, the salt solutions were frequently outside the inhibitor requirements. Corrosion testing at conditions similar to the environments expected during waste removal was recommended.

Wiersma, B.J.; Parish, W.R.

1997-01-01T23:59:59.000Z

427

Mixed Waste Salt Encapsulation Using Polysiloxane - Final Report  

SciTech Connect (OSTI)

A proof-of-concept experimental study was performed to investigate the use of Orbit Technologies polysiloxane grouting material for encapsulation of U.S. Department of Energy mixed waste salts leading to a final waste form for disposal. Evaporator pond salt residues and other salt-like material contaminated with both radioactive isotopes and hazardous components are ubiquitous in the DOE complex and may exceed 250,000,000 kg of material. Current treatment involves mixing low waste percentages (less than 10% by mass salt) with cement or costly thermal treatment followed by cementation to the ash residue. The proposed technology involves simple mixing of the granular salt material (with relatively high waste loadings-greater than 50%) in a polysiloxane-based system that polymerizes to form a silicon-based polymer material. This study involved a mixing study to determine optimum waste loadings and compressive strengths of the resultant monoliths. Following the mixing study, durability testing was performed on promising waste forms. Leaching studies including the accelerated leach test and the toxicity characteristic leaching procedure were also performed on a high nitrate salt waste form. In addition to this testing, the waste form was examined by scanning electron microscope. Preliminary cost estimates for applying this technology to the DOE complex mixed waste salt problem is also given.

Miller, C.M.; Loomis, G.G.; Prewett, S.W.

1997-11-01T23:59:59.000Z

428

Application of lithium in molten-salt reduction processes.  

SciTech Connect (OSTI)

Metallothermic reductions have been extensively studied in the field of extractive metallurgy. At Argonne National Laboratory (ANL), we have developed a molten-salt based reduction process using lithium. This process was originally developed to reduce actinide oxides present in spent nuclear fuel. Preliminary thermodynamic considerations indicate that this process has the potential to be adapted for the extraction of other metals. The reduction is carried out at 650 C in a molten-salt (LiCl) medium. Lithium oxide (Li{sub 2}O), produced during the reduction of the actinide oxides, dissolves in the molten salt. At the end of the reduction step, the lithium is regenerated from the salt by an electrowinning process. The lithium and the salt from the electrowinning are then reused for reduction of the next batch of oxide fuel. The process cycle has been successfully demonstrated on an engineering scale in a specially designed pyroprocessing facility. This paper discusses the applicability of lithium in molten-salt reduction processes with specific reference to our process. Results are presented from our work on actinide oxides to highlight the role of lithium and its effect on process variables in these molten-salt based reduction processes.

Gourishankar, K. V.

1998-11-11T23:59:59.000Z

429

Using Encapsulated Phase Change Salts for Concentrated Solar Power Plant  

Science Journals Connector (OSTI)

Abstract Storing thermal energy as latent heat of fusion in phase change material (PCM), such as inorganic salt mixtures, can improve the energy density by as much as 50% while reducing the cost by over 40%. However, to discharge stored energy from PCMs, which has low thermal conductivity, requires a large heat transfer area which drives up the cost. Fortunately, salts encapsulated into small capsules can provide high specific surface area thus alleviating this problem. However, a technical barrier with encapsulating salts is that when it is produced, a void must be created inside the shell to allow for expansion of salt when it is heated above its melting point to 550 °C. Terrafore's method to economically create this void consists of using a sacrificial polymer which is coated as the middle layer between the salt prill and the shell material. The polymer is selected such that it decomposes much below the melting point of salt to gas leaving a void in the capsule. Salts with different melting points are encapsulated using the same recipe and contained in a packed bed consisting of salts with progressively higher melting points from bottom to top of the tank. This container serves as a cascaded energy storage medium to store heat transferred from the sensible heat energy collected in solar collectors. Mathematical models indicate that over 90% of salt in the capsules undergo phase change improving energy density by over 50% from a sensible-only thermal storage. Another advantage of this method is that it requires only a single tank as opposed to the two-tanks used in a sensible heat storage, thereby reducing the cost from a nominal $27 per kWht to $16 per kWht and coming close to the SunShot goal for thermal storage of $15 per kWht.

A. Mathur; R. Kasetty; J Oxley; J Mendez; K. Nithyanandam

2014-01-01T23:59:59.000Z

430

Evaluation of synthetic salt water desalination by using a functionalized polysulfone based bipolar membrane electrodialysis cell  

Science Journals Connector (OSTI)

Abstract The work reported herein describes the study of desalination of synthetic salt water at laboratory scale in five different feed concentrations using a lab-made functionalized high molecular weight polysulfone (PSu) polymer based monopolar (cation exchange and anion exchange) and bipolar ion exchange membranes (with PVA as the intermediate layer) using bipolar membrane electrodialysis cell. Various parameters such as conductivity, solution pH, feed concentration, current efficiency, energy consumption, transport number, fluxes and water dissociation efficiency were determined. During the 8 h treatment under optimal conditions (i.e. time, current, higher acid and base concentrations), for the various initial feed concentrations (from 10 g/L to 50 g/L), the current efficiencies obtained ranged from 27% to 75%. And for the highest feed concentration, the highest current efficiency (? max. of about 75% for \\{PSu\\} and 63% for polystyrene divinylbenzene (PSDVB)) with lowest energy consumption (? max. of about 1.2 Wh/mol for \\{PSu\\} and 2.6 Wh/mol for PSDVB) in addition to acid-base production (? max. of about 0.018 N acid: 0.016 N base for \\{PSu\\} and 0.012 N acid: 0.013 N base for PSDVB) was observed. The results of the study demonstrated the promising potential of functionalized polysulfone based ion exchange membranes for greater water dissociation efficiency in desalination of water.

Krishnaveni Venugopal; Sangeetha Dharmalingam

2014-01-01T23:59:59.000Z

431

Electrolyte materials containing highly dissociated metal ion salts  

DOE Patents [OSTI]

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity.

Lee, Hung-Sui (East Setauket, NY); Geng, Lin (Coram, NY); Skotheim, Terje A. (Shoreham, NY)

1996-07-23T23:59:59.000Z

432

Electrolyte materials containing highly dissociated metal ion salts  

DOE Patents [OSTI]

The present invention relates to metal ion salts which can be used in electrolytes for producing electrochemical devices, including both primary and secondary batteries, photoelectrochemical cells and electrochromic displays. The salts have a low energy of dissociation and may be dissolved in a suitable polymer to produce a polymer solid electrolyte or in a polar aprotic liquid solvent to produce a liquid electrolyte. The anion of the salts may be covalently attached to polymer backbones to produce polymer solid electrolytes with exclusive cation conductivity. 2 figs.

Lee, H.S.; Geng, L.; Skotheim, T.A.

1996-07-23T23:59:59.000Z

433

Fracturing around excavations in salt at the WIPP  

SciTech Connect (OSTI)

Salt is a plastic material when subjected to high confining pressures. However, salt can behave in a brittle manner with the development of fracturing when subject to deviatoric stresses and low confining pressures. Field data demonstrating brittle behavior have been collected and evaluated at the Waste Isolation Pilot Plant (WIPP), in Carlsbad, New Mexico. This facility is being developed to prove technology for the safe emplacement and storage of transuranic nuclear wastes in deep excavations in salt. Studies using visual, instrumentation and geophysical techniques have been carried out in the underground facility to identify and characterize the types of fractures that develop around openings. 11 refs., 7 figs.

Cook, R.F. (Westinghouse Electric Corp., Carlsbad, NM (USA). Waste Isolation Div.); Roggenthen, W.M. (South Dakota School of Mines and Technology, Rapid City, SD (USA). Dept. of Geology and Geological Engineering)

1991-01-01T23:59:59.000Z

434

Molten salts in nuclear science and technology: a scientometric perspective  

Science Journals Connector (OSTI)

This paper attempts to highlight quantitatively and qualitatively the growth and development of world literature on molten salts in terms of publication output as per INIS database (1972-2011). The objective of the study was to perform a scientometric analysis of all research publications on molten salts in the world. The parameters studied include year-wise growth of publications, country-wise distribution of publications, activity index of top countries, highly productive institutes, language-wise distribution of publications, distribution of publications as per document type, highly preferred journals and identification of highly cited publications on molten salts.

Ganesh Surwase; Lalit Mohan; B. S. Kademani; K. Bhanumurthy

2014-01-01T23:59:59.000Z

435

Effect of simultaneous electrical and thermal treatment on the performance of bulk heterojunction organic solar cell blended with organic salt  

SciTech Connect (OSTI)

This work presents the influence of simultaneous electrical and thermal treatment on the performance of organic solar cell blended with organic salt. The organic solar cells were composed of indium tin oxide as anode, poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]: (6,6)-phenyl-C61 butyric acid methyl ester: tetrabutylammonium hexafluorophosphate blend as organic active layer and aluminium as cathode. The devices underwent a simultaneous fixed-voltage electrical and thermal treatment at different temperatures of 25, 50 and 75 °C. It was found that photovoltaic performance improved with the thermal treatment temperature. Accumulation of more organic salt ions in the active layer leads to broadening of p-n doped regions and hence higher built-in electric field across thin intrinsic layer. The simultaneous electrical and thermal treatment has been shown to be able to reduce the electrical treatment voltage.

Sabri, Nasehah Syamin; Yap, Chi Chin; Yahaya, Muhammad [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Salleh, Muhamad Mat [Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

436

Energy Department Completes Salt Coolant Material Transfer to Czech  

Broader source: Energy.gov (indexed) [DOE]

Completes Salt Coolant Material Transfer to Czech Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research Energy Department Completes Salt Coolant Material Transfer to Czech Republic for Advanced Reactor Research May 20, 2013 - 12:52pm Addthis News Media Contact (202) 586-4940 PRAGUE, CZECH REPUBLIC - The U.S. Department of Energy recently joined with the U.S. Embassy in Prague and the Czech Republic's Ministry of Industry and Trade to complete the transfer of 75 kilograms of fluoride salt from the Department's Oak Ridge National Laboratory (ORNL) to the Czech Nuclear Research Institute Řež for experiments at Řež's critical test facility. This partnership builds on a strong history of U.S.-Czech energy collaboration and follows President Obama's speech in Prague in April 2009, where he laid out the importance of international

437

Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA,  

Open Energy Info (EERE)

Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Surface Indicators of Geothermal Activity at Salt Wells, Nevada, USA, Including Warm Ground, Borate Deposits, and Siliceous Alteration Abstract Surface indicators of geothermal activity are often present above blind or concealed geothermal systems in the Great Basin, but their expressions are sometimes subtle. When mapped in detail, these indicators yield valuable information on the location, structural controls, and potential subsurface reservoir temperatures of geothermal fluids. An example is provided by the Salt Wells geothermal system in Churchill County, Nevada, USA, where

438

BLM Approves Salt Wells Geothermal Energy Projects | Open Energy  

Open Energy Info (EERE)

Energy Projects Energy Projects Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: BLM Approves Salt Wells Geothermal Energy Projects Abstract Abstract unavailable. Author Colleen Sievers Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 09/28/2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for BLM Approves Salt Wells Geothermal Energy Projects Citation Colleen Sievers. BLM Approves Salt Wells Geothermal Energy Projects [Internet]. 09/28/2011. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada. [updated 2011/09/28;cited 2013/08/21]. Available from: http://www.blm.gov/nv/st/en/fo/carson_city_field/blm_information/newsroom/2011/september/blm_approves_salt.html

439

Magnetotellurics At Salt Wells Area (Bureau of Land Management, 2009) |  

Open Energy Info (EERE)

Salt Wells Area (Bureau of Land Management, 2009) Salt Wells Area (Bureau of Land Management, 2009) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Salt Wells Area (Bureau of Land Management, 2009) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique Magnetotellurics Activity Date 2008 - 2008 Usefulness not indicated DOE-funding Unknown Exploration Basis Vulcan increased exploration efforts in the summer and fall of 2008, during which time the company drilled two temperature gradient holes (86-15 O on Pad 1 and 17-16 O on Pad 3); conducted seismic, gravity and magnetotelluric surveys; and drilled deep exploration wells at Pads 6 and 8 and binary wells at Pads 1, 2, 4, and 7. Notes Data from these wells is proprietary, and so were unavailable for inclusion

440

Salt Wells Geothermal Energy Projects Environmental Impact Statement | Open  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Salt Wells Geothermal Energy Projects Environmental Impact Statement Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Salt Wells Geothermal Energy Projects Environmental Impact Statement Abstract Abstract unavailable. Author Bureau of Land Management Published U.S. Department of the Interior- Bureau of Land Management, Carson City Field Office, Nevada, 07/22/2011 DOI Not Provided Check for DOI availability: http://crossref.org Online Internet link for Salt Wells Geothermal Energy Projects Environmental Impact Statement Citation Bureau of Land Management. Salt Wells Geothermal Energy Projects Environmental Impact Statement [Internet]. 07/22/2011. Carson City, NV. U.S. Department of the Interior- Bureau of Land Management, Carson City

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

DOE Issues Salt Waste Determination for the Savannah River Site |  

Broader source: Energy.gov (indexed) [DOE]

Issues Salt Waste Determination for the Savannah River Site Issues Salt Waste Determination for the Savannah River Site DOE Issues Salt Waste Determination for the Savannah River Site January 18, 2006 - 10:49am Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today issued the waste determination for the treatment and stabilization of low activity salt-waste at the Savannah River Site allowing for significant reductions in environmental and health risks posed by the material. Stored in forty-nine underground tanks, approximately 36 million gallons of radioactive waste is left over from plutonium production during the Cold War. In addition, the department issued an amended Record of Decision and Implementation Plan to the Defense Nuclear Facilities Safety Board. "Today's announcement clears the way for the removal and treatment of this

442

Salt River Project Smart Grid Project | Open Energy Information  

Open Energy Info (EERE)

Salt River Project Smart Grid Project Salt River Project Smart Grid Project Jump to: navigation, search Project Lead Salt River Project Country United States Headquarters Location Tempe, Arizona Recovery Act Funding $56,859,359.00 Total Project Value $114,003,719.00 Coverage Area Coverage Map: Salt River Project Smart Grid Project Coordinates 33.414768°, -111.9093095° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

443

DOE - Office of Legacy Management -- Penn Salt Manufacturing Co Whitemarsh  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Penn Salt Manufacturing Co Penn Salt Manufacturing Co Whitemarsh Research Laboratories - PA 20 FUSRAP Considered Sites Site: PENN SALT MANUFACTURING CO., WHITEMARSH RESEARCH LABORATORIES (PA.20) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Penn Salt Company PA.20-1 Location: Philiadelphia , Pennsylvania PA.20-1 Evaluation Year: 1987 PA.20-1 Site Operations: Conducted process studies for recovery of uranium from fluoride scrap. PA.20-1 Site Disposition: Eliminated - AEC licensed operation. Potential for residual radioactive contamination considered remote due to limited quantities and scope of operations. PA.20-2 PA.20-1 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled: Uranium PA.20-1 Radiological Survey(s): None Indicated

444

Project Profile: Advanced Nitrate Salt Central Receiver Power Plant  

Broader source: Energy.gov [DOE]

Abengoa, under the Baseload CSP FOA, will demonstrate a 100-megawatt electrical (MWe) central receiver plant using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator.

445

Supramolecular structures and physicochemical properties of norfloxacin salts  

Science Journals Connector (OSTI)

Seven new molecular salts of norfloxacin were synthesized and structurally elucidated by single-crystal structure analysis. Physical and chemical properties were evaluated by a variety of analytical techniques.

Xu, Y.

2014-07-31T23:59:59.000Z

446

Development of Molten-Salt Heat Trasfer Fluid Technology for...  

Office of Environmental Management (EM)

- ranged from 450C to 585C M easurement frequency: salt chemistry - 200 hours off-gas composition - 12 hours Innovat ive Technology Solut ions f or Sustainability ABENGOA...

447

Salt Tolerance of Landscape Plants Common to the Southwest  

E-Print Network [OSTI]

With sharply increasing costs of providing potable water, many communities in the Southwest are attempting to utilize non-potable saline water for irrigating large landscapes. This publication provides the information related to salt effects...

Miyamoto, S.

448

Project Profile: Long-Shafted Molten Salt Pump | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CSP R&D FOA, is validating the manufacturability of a large-scale molten salt receiver panel and then confirming its operation in prototypic solar flux. This work is an...

449

Liquid Salt Heat Exchanger Technology for VHTR Based Applications  

SciTech Connect (OSTI)

The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

Mark Anderson; Kumar Sridhara; Todd Allen; Per Peterson

2012-10-11T23:59:59.000Z

450

Vertebrate survey of a dredge spoil salt marsh  

E-Print Network [OSTI]

]ect: Wildlife and Fisheries Science VERTEBRATE SURVEY OF A DREDGE SPOIL SALT MARSH A Thesis by BETTY JO LEE Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) December 1976 ABSTRACT Vertebrate Survey... of this ecotone are salinity, amount of fresh water, agitation by tides and currents, temperatut'e, wind, and industrial pollutants (Odum 1971). Clark (1974) points out the environmental importance of salt marshes to the waters of estuaries and bays by acting...

Lee, Betty Jo

1976-01-01T23:59:59.000Z

451

Analysis of salt concentrations in the Brazos River Basin, Texas  

E-Print Network [OSTI]

ANALYSIS OF SALT CONCENTRATIONS IN THE BRAZOS RIVER BASIN, TEXAS A Thesis by CHARLES KEITH GANZE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1990 Major Subject: Civil Engineering Analysis of Salt Concentrations in the Brazos River Basin, Texas A Thesis by CHARLES KEITH GANZE Approved as to style and content by: Ralph A. Wurbs (Chair of Committee) James S. Bonner...

Ganze, Charles Keith

2012-06-07T23:59:59.000Z

452

Comparison of linear and nonlinear acoustic probing of rock salt  

E-Print Network [OSTI]

COMPARISON OF LINEAR AND NONLINEAR ACOUSTIC PROBING OF ROCK SALT A Thesis by ALBERT MIN-HAO WANG Submitted to the Graduate College of Texas AIIM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August... 1980 Major Subject: Geophysics COMPARISON OF LINEAR AND NONLINEAR ACOUSTIC PROBING OF ROCK SALT A Thesis by ALBERT MIN-HAO 'RANG Approved as to style and content by: l('-/c~k~&(. Chairman o Comm ' ee Member) Member / I Member Head...

Wang, Albert Min-Hao

2012-06-07T23:59:59.000Z

453

A procedure to screen cucumber for salt tolerance  

E-Print Network [OSTI]

A PROCEDURE TO SCREEN CUCUMBER FOR SALT TOLERANCE A Thesis by LEONARD FRANK YOURMAN Submitted to the Graduate College of Texas A1IM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1979 Major... Subject: Horticulture A PROCEDURE TO SCREEN CUCUMBER FOR SALT TOLERANCE A Thesis by LEONARD FRANK VOURMAN Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) 0ugust 1979 ABSTRACT A Procedure...

Yourman, Leonard Frank

2012-06-07T23:59:59.000Z

454

A screening technique for salt tolerance in onion  

E-Print Network [OSTI]

A SCREENING TECHNIQUE FOR SALT TOLERANCE IN ONION A Thesis by MARY JORDAN WANNAMAKER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1985 Major... Subject: Horticulture A SCREENING TECHNIQUE FOR SALT TOLERANCE IN ONION A Thesis by NARY JORDAN WANNAMAKER Approved as to style and content by: Leonard M. Pike (Chairma f Cp 'ttee) 'eg C. Cobb (Member) Ron Newton (Member) . Grant Vest (Head...

Wannamaker, Mary Jordon

2012-06-07T23:59:59.000Z

455

The Estimation of Salt and Molasses in Mixed Feeds  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR COLLEGE STATION, BRAZOS COUNTY, TEXAS BULLETIN NO. 425 MAY, 1931 DIVISION OF CHEMISTRY The Estimation of Salt and Molasses in Mixed Feeds AGRICULTURAL AND MECHANICAL COLLEGE....: ~gricultural Engineering J. IT. KNOX, M. S., Animal IIushandry A. K. MACKEY, M. S., Animnl Hrrshondry *Dean School of Veterinary Medicine. ?As of May 1. 1931. **In cooperation with U. S. Department of Agriculture. A statement of the percentage of salt...

Fraps, G. S. (George Stronach)

1931-01-01T23:59:59.000Z

456

Synthesis and analysis of streamflow and salt loads  

E-Print Network [OSTI]

SYNTHESIS AND ANALYSIS OF STREAMFLOW AND SALT LOADS A Thesis ISHTIAQUE SALEH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August ] 993... Major Subject: Civil Engineering SYNTHESIS AND ANALYSIS OF STREAMFLOW AND SALT LOADS A Thesis by ISHTIAQUE SALEH Approved as to style and content by: Ralph A. Wurbs (Chair of Committee) 'Og Juan B. Valdes (Member) Tep Sastri (Member) ames T...

Saleh, Ishtiaque

2012-06-07T23:59:59.000Z

457

Poly(arylene ether sulfone) Statistical Copolymers Bearing Perfluoroalkylsulfonic Acid Moieties  

Science Journals Connector (OSTI)

Number-average molecular weight (Mn) and polydispersity index (PDI) of the polymeric materials were measured using a gel permeation chromatography (GPC) system consisting of a Waters Alliance 2695 separation module, an online multiangle laser light scattering (MALLS) detector fitted with a gallium arsenide laser (power: 20 mW) operating at 690 nm (MiniDAWN, Wyatt Technology Inc.), an interferometric refractometer (Optilab DSP, Wyatt Technology Inc.), and two Polymer Laboratories mixed D columns (5 ?m bead size) connected in series. ... (23) After experimentation with several alternative neutralizing agents including pyridine and alkali metal hydroxides and carbonates, we determined that the aliphatic tertiary amine, N,N-diisopropylethylamine, produces a salt with favorable solubility and crystallization behavior. ... It is sparingly soluble in water, which facilitates isolation, and as will be shown, it may be used directly in polymerization, and under these conditions, the free amine is released and volatilized out of the polymer product. ...

Haibo Li; Andrew B. Jackson; Nathan J. Kirk; Kenneth A. Mauritz; Robson F. Storey

2011-01-19T23:59:59.000Z

458

Independent Oversight Review, Savannah River Site Salt Waste Processing Facility- August 2013  

Broader source: Energy.gov [DOE]

Review of the Savannah River Site Salt Waste Processing Facility Safety Basis and Design Development.

459

Independent Oversight Review, Savannah River Site Salt Waste Processing Facility- April 2014  

Broader source: Energy.gov [DOE]

Review of the Savannah River Site Salt Waste Processing Facility Construction Quality and Fire Protection Systems

460

Paleoarchaic Surface Assemblages in the Great Salt Lake Desert, Northwestern Utah  

E-Print Network [OSTI]

desert scrubs, such as sagebrush, shadscale, horsebrush, snake- PALEOARCHAIC ASSEMBLAGES IN THE GREAT SALT

Arkush, Brooke S; Pitblado, Bonnie L

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Transformation of alkali metals during pyrolysis and gasification of a lignite  

SciTech Connect (OSTI)

Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2008-05-15T23:59:59.000Z

462

Quantum magnetism in ultracold alkali and alkaline-earth fermion systems with symplectic symmetry  

Science Journals Connector (OSTI)

We numerically study the quantum magnetism of ultracold alkali and alkaline-earth fermion systems with large hyperfine spin F=32, which are characterized by a generic Sp(N) symmetry with N=4. The methods of exact diagonalization (ED) and density matrix renormalization group are employed for the large size one-dimensional (1D) systems, and the ED method is applied to a two-dimensional (2D) square lattice on small sizes. We focus on the magnetic exchange models in the Mott-insulating state at quarter-filling. Both 1D and 2D systems exhibit rich phase diagrams depending on the ratio between the spin exchanges J0 and J2 in the bond spin singlet and quintet channels, respectively. In one dimension, the ground states exhibit a long-range-ordered dimerization with a finite spin gap at J0/J2>1 and a gapless spin-liquid state at J0/J2?1, respectively. In the former and latter cases, the correlation functions exhibit the two-site and four-site periodicities, respectively. In two-dimensions, various spin-correlation functions are calculated up to the size of 4×4. The Néel-type spin correlation dominates at large values of J0/J2, while a 2×2 plaquette correlation is prominent at small values of this ratio. Between them, a columnar spin-Peierls dimerization correlation peaks. We infer the competition among the plaquette ordering, the dimer ordering, and the Néel ordering in the 2D system.

Hsiang-Hsuan Hung; Yupeng Wang; Congjun Wu

2011-08-02T23:59:59.000Z

463

Study of alkali- and sulfur-enhanced corrosion of advanced energy systems. Final report  

SciTech Connect (OSTI)

The initial stage of MHD anode corrosion process appears to be dominated by out-diffusion of metallic species into the powder deposit. In addition, K and S appear to diffuse into the native oxide and underlying metal substrate. The out-diffusion process clearly leads to a loss of metal species from either the native oxide or metal substrate, while in-diffusion leads to the formation of sulfides and possibly to the accumulation of K containing compounds which may ultimately flux the protective oxide scale. The results for MHD anodes may be compared with those from previous studies of alkali-sulfur enhanced corrosion of turbine alloys. Although the specific details of these studies differ, both agree that rapid or catastrophic corrosion is preceded by a variable length induction period. During this period, relatively small changes in weight are observed. However, the protective metal oxide scale is breached which establishes the condition for rapid direct attack by condensed corrosive deposits. Thus, the mechanisms and kinetics of processes associated with the induction period are of great interest in understanding the survivability of various alloys. In the corrosion modeling effort, it was found that a simple model which considered only the diffusion-limited corrosion of iron did not correctly predict the iron corrosion product species for iron-based alloys. This lack of agreement was due to the absence of the treatment of other metal constituents in the alloy which form corrosion products. A more detailed model which includes equilibrium and diffusion relations for all metal species is required for accurate modeling of the corrosion product composition. 14 refs.

Stinespring, C.; Annen, K.; Stewart, G.

1984-01-01T23:59:59.000Z

464

CAVERN ROOF STABILITY FOR NATURAL GAS STORAGE IN BEDDED SALT  

SciTech Connect (OSTI)

This report documents research performed to develop a new stress-based criterion for predicting the onset of damage in salt formations surrounding natural gas storage caverns. Laboratory tests were conducted to investigate the effects of shear stress, mean stress, pore pressure, temperature, and Lode angle on the strength and creep characteristics of salt. The laboratory test data were used in the development of the new criterion. The laboratory results indicate that the strength of salt strongly depends on the mean stress and Lode angle. The strength of the salt does not appear to be sensitive to temperature. Pore pressure effects were not readily apparent until a significant level of damage was induced and the permeability was increased to allow penetration of the liquid permeant. Utilizing the new criterion, numerical simulations were used to estimate the minimum allowable gas pressure for hypothetical storage caverns located in a bedded salt formation. The simulations performed illustrate the influence that cavern roof span, depth, roof salt thickness, shale thickness, and shale stiffness have on the allowable operating pressure range. Interestingly, comparison of predictions using the new criterion with that of a commonly used criterion indicate that lower minimum gas pressures may be allowed for caverns at shallow depths. However, as cavern depth is increased, less conservative estimates for minimum gas pressure were determined by the new criterion.

Kerry L. DeVries; Kirby D. Mellegard; Gary D. Callahan; William M. Goodman

2005-06-01T23:59:59.000Z

465

Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report  

Broader source: Energy.gov (indexed) [DOE]

Salt Waste Processing Facility Salt Waste Processing Facility Technology Readiness Assessment Report Kurt D. Gerdes Harry D. Harmon Herbert G. Sutter Major C. Thompson John R. Shultz Sahid C. Smith July 13, 2009 Prepared by the U.S. Department of Energy Washington, D.C. SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 ii This page intentionally left blank SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iii SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iii Signatures SRS Salt Waste Processing Facility Technology Readiness Assessment July 13, 2009 iv This page intentionally left blank SRS Salt Waste Processing Facility

466

Small Ubiquitin-Like Modifier Proteases OVERLY TOLERANT TO SALT1 and -2 Regulate Salt Stress Responses in Arabidopsis  

Science Journals Connector (OSTI)

...Salt Stress Responses in Arabidopsis [W] Lucio Conti Gillian Price Elizabeth ODonnell Benjamin Schwessinger 1 Peter Dominy Ari...reveals a requirement for RUB modification for control of ethylene biosynthesis and proper induction of basic chitinase and PDF1...

Lucio Conti; Gillian Price; Elizabeth O'Donnell; Benjamin Schwessinger; Peter Dominy; Ari Sadanandom

2008-10-10T23:59:59.000Z

467

EIS-0099: Remedial Actions at the Former Vitro Chemical Company Site, South Salt Lake, Salt Lake County, Utah  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy developed this statement to evaluate the environmental impacts of various scenarios associated with the cleanup of those residues remaining at the abandoned uranium mill tailings site located in South Salt Lake, Utah.

468

Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

Salt Lake City Fuels Salt Lake City Fuels Vehicles With Natural Gas to someone by E-mail Share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Facebook Tweet about Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Twitter Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Google Bookmark Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Delicious Rank Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on Digg Find More places to share Alternative Fuels Data Center: Salt Lake City Fuels Vehicles With Natural Gas on AddThis.com... May 14, 2011 Salt Lake City Fuels Vehicles With Natural Gas W atch how Salt Lake City fuels vehicles with liquefied and compressed

469

LIFE Materails: Molten-Salt Fuels Volume 8  

SciTech Connect (OSTI)

The goals of the Laser Inertial Fusion Fission Energy (LIFE) is to use fusion neutrons to fission materials with no enrichment and minimum processing and have greatly reduced wastes that are not of interest to making weapons. Fusion yields expected to be achieved in NIF a few times per day are called for with a high reliable shot rate of about 15 per second. We have found that the version of LIFE using TRISO fuel discussed in other volumes of this series can be modified by replacing the molten-flibe-cooled TRISO fuel zone with a molten salt in which the same actinides present in the TRISO particles are dissolved in the molten salt. Molten salts have the advantage that they are not subject to radiation damage, and hence overcome the radiation damage effects that may limit the lifetime of solid fuels such as TRISO-containing pebbles. This molten salt is pumped through the LIFE blanket, out to a heat exchanger and back into the blanket. To mitigate corrosion, steel structures in contact with the molten salt would be plated with tungsten or nickel. The salt will be processed during operation to remove certain fission products (volatile and noble and semi-noble fission products), impurities and corrosion products. In this way neutron absorbers (fission products) are removed and neutronics performance of the molten salt is somewhat better than that of the TRISO fuel case owing to the reduced parasitic absorption. In addition, the production of Pu and rare-earth elements (REE) causes these elements to build up in the salt, and leads to a requirement for a process to remove the REE during operation to insure that the solubility of a mixed (Pu,REE)F3 solid solution is not exceeded anywhere in the molten salt system. Removal of the REE will further enhance the neutronics performance. With molten salt fuels, the plant would need to be safeguarded because materials of interest for weapons are produced and could potentially be removed.

Moir, R; Brown, N; Caro, A; Farmer, J; Halsey, W; Kaufman, L; Kramer, K; Latkowski, J; Powers, J; Shaw, H; Turchi, P

2008-12-11T23:59:59.000Z

470

Assessment of the Use of Nitrogen Trifluoride for Purifying Coolant and Heat Transfer Salts in the Fluoride Salt-Cooled High-Temperature Reactor  

SciTech Connect (OSTI)

This report provides an assessment of the use of nitrogen trifluoride for removing oxide and water-caused contaminants in the fluoride salts that will be used as coolants in a molten salt cooled reactor.

Scheele, Randall D.; Casella, Andrew M.

2010-09-28T23:59:59.000Z

471

Prevention of Salt Damage inPrevention of Salt Damage in LimestoneLimestone  

E-Print Network [OSTI]

with a solution of polyacrylic acid (PAA) will reduce the crystallization pressure. #12;Warping Experiment Experiment Sample Size ~ 10 x 2.5 x 1.0 cm 1. Polyacrylic acid (PAA) treatment 2. Dried at 105�C 3 Crystal cP L Ld #12;Warping Sample Sets PAA treatments No PAA 0.75% PAA solution 1.5% PAA solution 3

Petta, Jason

472

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network [OSTI]

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Mireille Aymar; Romain Guérout; Olivier Dulieu

2011-02-24T23:59:59.000Z

473

Structure of the alkali-metal-atom + strontium molecular ions: Towards photoassociation and formation of cold molecular ions  

SciTech Connect (OSTI)

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold lithium or rubidium atom and a strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, M.; Dulieu, O. [Laboratoire Aime Cotton, CNRS, UPR3321, Ba circumflex t. 505, Univ Paris-Sud, 91405 Orsay Cedex (France); Guerout, R. [Laboratoire Kastler-Brossel, CNRS, ENS, Univ Pierre et Marie Curie case 74, Campus Jussieu, F-75252 Paris Cedex 05 (France)

2011-08-14T23:59:59.000Z

474

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network [OSTI]

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, Mireille; Dulieu, Olivier

2011-01-01T23:59:59.000Z

475

Physical origin of chemical trends in glass formation in alkali tellurites: Reconciliation of constraint theory with experiments  

Science Journals Connector (OSTI)

A chemical trend in glass formation with alkali atom (Li, Na, K) in tellurite glasses is recognized, whose physical origin is revealed by a recently formulated approach to the constraint theory of glasses [Phys. Rev. B 60, 11 859 (1999)]. In this work, the parameters appearing in the constraint theory are directly related to quantities derived from atomic structure studies, which facilitates the understanding of glass formation in ionic glasses. As a corollary, the issue of coordination number that has to be considered in the theory, and which has been debated in the literature, is clarified.

R. Aravinda Narayanan

2001-09-11T23:59:59.000Z

476

Effect of Alkali and Alkaline Earth Metallic Species on Biochar Reactivity and Syngas Compositions during Steam Gasification  

Science Journals Connector (OSTI)

Effect of Alkali and Alkaline Earth Metallic Species on Biochar Reactivity and Syngas Compositions during Steam Gasification† ... Briefly, a biomass or biochar sample, held in a platinum (Pt) crucible, was ashed in air following a specially designed ashing program that raised the temperature to a final temperature of 600 °C at a very slow heating rate in order to prevent the ignition of the biomass/biochar hence to avoid the loss of AAEM species from the sample during oxidation. ... Therefore, wood may be a good fuel based on the consideration that this would potentially reduce the ash-related operation problems in a gasifier. ...

Kongvui Yip; Fujun Tian; Jun-ichiro Hayashi; Hongwei Wu

2009-07-24T23:59:59.000Z

477

DOE Joint Genome Institute: Salt-loving Microbe Provides New Enzymes for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

June 30, 2011 June 30, 2011 Salt-loving Microbe Provides New Enzymes for the Production of Next Gen Biofuels WALNUT CREEK, Calif.-In order to realize the full potential of advanced biofuels that are derived from non-food sources of lignocellulosic biomass-e.g., agricultural, forestry, and municipal waste, and crops such as poplar, switchgrass and miscanthus-new technologies that can efficiently and cost-effectively break down this biomass into simple sugars are required. Existing biomass pretreatment technologies are typically derived from the pulp and paper industry and rely on dilute acids and bases to break down the biomass. The treated biomass product is then exposed to biological catalysts, or enzymes, to liberate the sugars. Eddy Rubin and Tao Zhang Photo:Tao Zhang (left), and Eddy Rubin (right).

478

In-Drift Precipitates/Salts Model  

SciTech Connect (OSTI)

As directed by ''Technical Work Plan For: Engineered Barrier System Department Modeling and Testing FY03 Work Activities'' (BSC 2003 [165601]), the In-Drift Precipitates/Salts (IDPS) model is developed and refined to predict the aqueous geochemical effects of evaporation in the proposed repository. The purpose of this work is to provide a model for describing and predicting the postclosure effects of evaporation and deliquescence on the chemical composition of water within the proposed Engineered Barrier System (EBS). Application of this model is to be documented elsewhere for the Total System Performance Assessment License Application (TSPA-LA). The principal application of this model is to be documented in REV 02 of ''Engineered Barrier System: Physical and Chemical Environment Model'' (BSC 2003 [165601]). The scope of this document is to develop, describe, and validate the IDPS model. This model is a quasi-equilibrium model. All reactions proceed to equilibrium except for several suppressed minerals in the thermodynamic database not expected to form under the proposed repository conditions within the modeling timeframe. In this revision, upgrades to the EQ3/6 code (Version 8.0) and Pitzer thermodynamic database improve the applicable range of the model. These new additions allow equilibrium and reaction-path modeling of evaporation to highly concentrated brines for potential water compositions of the system Na-K-H-Mg-Ca-Al-Cl-F-NO{sub 3}-SO{sub 4}-Br-CO{sub 3}-SiO{sub 2}-CO{sub 2}-O{sub 2}-H{sub 2}O at temperatures in the range of 0 C to 125 C, pressures in the atmospheric range, and relative humidity in the range of 0 to 100 percent. This system applies to oxidizing conditions only, and therefore limits the model to applications involving oxidizing conditions. A number of thermodynamic parameters in the Pitzer database have values that have not been determined or verified for the entire temperature range. In these cases, the known values are used to approximate the values for the rest of the temperature range. Although such treatment contributes to uncertainty in model outputs, the model validation test cases indicate that the model, with its associated uncertainty, is valid for its intended use. The intended use of this model is to estimate and tabulate, within an appropriate level of confidence, the effects of evaporation, deliquescence, and potential environmental conditions on the pH, ionic strength, and chemical compositions of water and minerals on the drip shield or other location within the drift during the postclosure period.

P. Mariner

2003-10-21T23:59:59.000Z

479

Molten Salts for High Temperature Reactors: University of Wisconsin Molten Salt Corrosion and Flow Loop Experiments -- Issues Identified and Path Forward  

SciTech Connect (OSTI)

Considerable amount of work is going on regarding the development of high temperature liquid salts technology to meet future process needs of Next Generation Nuclear Plant. This report identifies the important characteristics and concerns of high temperature molten salts (with lesson learned at University of Wisconsin-Madison, Molten Salt Program) and provides some possible recommendation for future work

Piyush Sabharwall; Matt Ebner; Manohar Sohal; Phil Sharpe; Thermal Hydraulics Group

2010-03-01T23:59:59.000Z

480

Search for an in-line nitric acid analyzer  

SciTech Connect (OSTI)

A literature search was conducted to identify possible techniques for measuring mineral acid normality in the presence of heavy metal salts, undissolved solids, and high radiation fields. Of the techniques noted, eight were identified that could be applicable to the objective. The possibilities were reduced to two methods, which warrant further investigation. These two are refractometry and a modified coulometric-polarographic method. All methods are discussed in detail followed by rationale for including or rejecting each for further investigation.

Gallagher, K. Y.; Johnson, C. M.

1980-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "acids alkalies salts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Soranakom, C., Bakhshi M. , and Mobasher, B. " Role of Alkali Resistant Glass Fibers in Suppression of Restrained Shrinkage Cracking of Concrete Materials," 15th International Glass Fibre Reinforced Concrete Association  

E-Print Network [OSTI]

Soranakom, C., Bakhshi M. , and Mobasher, B. " Role of Alkali Resistant Glass Fibers in Suppression of Restrained Shrinkage Cracking of Concrete Materials," 15th International Glass Fibre Reinforced Concrete Association Congress, GRC 2008, CD-Proceedings, Prague, April 20-23, 2008. 1 Role of Alkali Resistant Glass

Mobasher, Barzin

482

Monte Carlo simulations of electron thermalization in alkali iodide and alkaline-earth fluoride scintillators  

SciTech Connect (OSTI)

A Monte Carlo model of electron thermalization in inorganic scintillators, which was developed and applied to CsI in a previous publication [Wang et al., J. Appl. Phys. 110, 064903 (2011)], is extended to another material of the alkali halide class, NaI, and to two materials from the alkaline-earth halide class, CaF{sub 2} and BaF{sub 2}. This model includes electron scattering with both longitudinal optical (LO) and acoustic phonons as well as the effects of internal electric fields. For the four pure materials, a significant fraction of the electrons recombine with self-trapped holes and the thermalization distance distributions of the electrons that do not recombine peak between approximately 25 and 50 nm and extend up to a few hundreds of nanometers. The thermalization time distributions of CaF{sub 2}, BaF{sub 2}, NaI, and CsI extend to approximately 0.5, 1, 2, and 7 ps, respectively. The simulations show that the LO phonon energy is a key factor that affects the electron thermalization process. Indeed, the higher the LO phonon energy is, the shorter the thermalization time and distance are. The thermalization time and distance distributions show no dependence on the incident {gamma}-ray energy. The four materials also show different extents of electron-hole pair recombination due mostly to differences in their electron mean free paths (MFPs), LO phonon energies, initial densities of electron-hole pairs, and static dielectric constants. The effect of thallium doping is also investigated for CsI and NaI as these materials are often doped with activators. Comparison between CsI and NaI shows that both the larger size of Cs{sup +} relative to Na{sup +}, i.e., the greater atomic density of NaI, and the longer electron mean free path in NaI compared to CsI contribute to an increased probability for electron trapping at Tl sites in NaI versus CsI.

Wang Zhiguo; Gao Fei; Kerisit, Sebastien [Fundamental and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Xie Yulong [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Campbell, Luke W. [National Security Directorate, Pacific Northwest National Laboratory, Richland, Washington 99352 (United States)

2012-07-01T23:59:59.000Z

483

Monte Carlo simulations of electron thermalization in alkali iodide and alkaline-earth fluoride scintillators  

SciTech Connect (OSTI)

A Monte Carlo model of electron thermalization in inorganic scintillators, which was developed and applied to CsI in a previous publication [Wang et al., J. Appl. Phys. 110, 064903 (2011)], is extended to another material of the alkali halide class, NaI, and to two materials from the alkaline-earth halide class, CaF2 and BaF2. This model includes electron scattering with both longitudinal optical (LO) and acoustic phonons as well as the effects of internal electric fields. For the four pure materials, a significant fraction of the electrons recombine with self-trapped holes and the thermalization distance distributions of the electrons that do not recombine peak between approximately 25 and 50 {per_thousand}nm and extend up to a few hundreds of nanometers. The thermalization time distributions of CaF2, BaF2, NaI, and CsI extend to approximately 0.5, 1, 2, and 7 ps, respectively. The simulations show that the LO phonon energy is a key factor that affects the electron thermalization process. Indeed, the higher the LO phonon energy is, the shorter the thermalization time and distance are. The thermalization time and distance distributions show no dependence on the incident {gamma}-ray energy. The four materials also show different extents of electron-hole pair recombination due mostly to differences in their electron mean free paths (MFPs), LO phonon energies, initial densities of electron-hole pairs, and static dielectric constants. The effect of thallium doping is also investigated for CsI and NaI as these materials are often doped with activators. Comparison between CsI and NaI shows that both the larger size of Cs+ relative to Na+, i.e., the greater atomic density of NaI, and the longer electron mean free path in NaI compared to CsI contribute to an increased probability for electron trapping at Tl sites in NaI versus CsI.

Wang, Zhiguo; Xie, YuLong; Campbell, Luke W.; Gao, Fei; Kerisit, Sebastien N.

2012-07-01T23:59:59.000Z

484

3-D physical modeling of a complex salt canopy  

SciTech Connect (OSTI)

Recent drilling has confirmed both significant reservoir potential and the presence of commercial hydrocarbons below salt structures in the Gulf of Mexico. Obtaining definitive seismic images with standard processing schemes beneath these salt structures is very difficult if not impossible. Because of the complicated seismic behavior of these structures, full volume 3-D prestack depth migration is required. Unfortunately, carrying out the multitude of calculations needed to create a proper image requires the largest and fastest supercomputers and rather complex numerical algorithms. Furthermore, developing and testing the imaging algorithms is quite involved and requires appropriate test data sets. To better understand the problems and issues of subsalt imaging, Marathon Oil Company and Louisiana Land and Exploration Company contracted with the University of Houston`s Allied Geophysical Laboratories (AGL) to construct a salt canopy physical model. The model is patterned after the SEG/EAEG Salt Model and is made from synthetic materials. It is a full three-dimensional model with an irregularly shaped, lateral salt structure embedded in five distinct sedimentary layers. The model was used to acquire a multi-offset 3-D marine-style survey. These data are being used to address problems of subsalt imaging. In addition to standard processing techniques, the authors investigate algorithms for multiple removal and prestack depth migration.

Wiley, R.W. [Marathon Oil Co., Littleton, CO (United States); Sekharan, K.K. [Univ. of Houston, TX (United States). Allied Geophysical Labs.

1996-12-31T23:59:59.000Z

485

Disposal of soluble salt waste from coal gasification  

SciTech Connect (OSTI)

This paper addresses pollutants in the form of soluble salts and resource recovery in the form of water and land. A design for disposal of soluble salts has been produced. The interactions of its parameters have been shown by a process design study. The design will enable harmonious compliance with United States Public Laws 92-500 and 94-580, relating to water pollution and resource recovery. In the disposal of waste salt solutions, natural water resources need not be contaminated, because an encapsulation technique is available which will immobilize the salts. At the same time it will make useful landforms available, and water as a resource can be recovered. There is a cost minimum when electrodialysis and evaporation are combined, which is not realizable with evaporation alone, unless very low-cost thermal energy is available or unless very high-cost pretreatment for electrodialysis is required. All the processes making up the proposed disposal process are commercially available, although they are nowhere operating commercially as one process. Because of the commercial availability of the processes, the proposed process may be a candidate 'best commercially available treatment' for soluble salt disposal.

McKnight, C.E.

1980-06-01T23:59:59.000Z

486

Oil field waste disposal in salt caverns: An information website  

SciTech Connect (OSTI)

Argonne National Laboratory has completed the construction of a Website for the US Department of Energy (DOE) that provides detailed information on salt caverns and their use for disposing of nonhazardous oil field wastes (NOW) and naturally occurring radioactive materials (NORM). Specific topics in the Website include the following: descriptions of salt deposits and salt caverns within the US, salt cavern construction methods, potential types of wastes, waste emplacement, regulatory issues, costs, carcinogenic and noncarcinogenic human health risks associated with postulated cavern release scenarios, new information on cavern disposal (e.g., upcoming meetings, regulatory issues, etc.), other studies supported by the National Petroleum Technology Office (NPTO) (e.g., considerations of site location, cavern stability, development issues, and bedded salt characterization in the Midland Basin), and links to other associated Web sites. In addition, the Website allows downloadable access to reports prepared on the topic that were funded by DOE. Because of the large quantities of NOW and NORM wastes generated annually by the oil industry, information presented on this Website is particularly interesting and valuable to project managers, regulators, and concerned citizens.

Tomasko, D.; Veil, J. A.

1999-12-10T23:59:59.000Z

487

Method for making a uranium chloride salt product  

DOE Patents [OSTI]

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

488

Effect of water in salt repositories. Final report  

SciTech Connect (OSTI)

Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

1983-09-01T23:59:59.000Z

489

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility  

SciTech Connect (OSTI)

An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

2011-03-01T23:59:59.000Z

490

Swellings due to alkali-silica reaction and delayed ettringite formation: Characterisation of expansion isotropy and effect of moisture conditions  

Science Journals Connector (OSTI)

This paper investigates the effect of different conditions on the development of concrete expansions due to alkali-silica reaction (ASR), delayed ettringite formation (DEF) and their combination. The presence of products of the two reactions has been observed during structure diagnosis. The aim of this research is to study the two reactions in concretes with close mix designs but with various types of aggregate and moisture conditions. Measurements performed in the three directions of stress-free specimens showed that DEF expansions could be considered as isotropic for stress-free material. DEF expansions were largely influenced by the storage conditions (immersed in water or in sealed conditions). The volume of storage water modified the kinetics. Under sealed conditions, no expansions were measured for mortar containing non-reactive aggregate, while small positive strains were obtained for mortar containing reactive aggregate. In all cases, new water supply caused fast, large expansions. The different effects of alkali leaching and moisture conditions on DEF and ASR expansions are discussed.

Hassina Bouzabata; Stéphane Multon; Alain Sellier; Hacène Houari

2012-01-01T23:59:59.000Z

491

Theoretical simulations of protective thin film Fabry-Pérot filters for integrated optical elements of diode pumped alkali lasers (DPAL)  

SciTech Connect (OSTI)

The lifetime of Diode-Pumped Alkali Lasers (DPALs) is limited by damage initiated by reaction of the glass envelope of its gain medium with rubidium vapor. Rubidium is absorbed into the glass and the rubidium cations diffuse through the glass structure, breaking bridging Si-O bonds. A damage-resistant thin film was developed enhancing high-optical transmission at natural rubidium resonance input and output laser beam wavelengths of 780 nm and 795 nm, while protecting the optical windows of the gain cell in a DPAL. The methodology developed here can be readily modified for simulation of expected transmission performance at input pump and output laser wavelengths using different combination of thin film materials in a DPAL. High coupling efficiency of the light through the gas cell was accomplished by matching the air-glass and glass-gas interfaces at the appropriate wavelengths using a dielectric stack of high and low index of refraction materials selected to work at the laser energies and protected from the alkali metal vapor in the gain cell. Thin films as oxides of aluminum, zirconium, tantalum, and silicon were selected allowing the creation of Fabry-Perot optical filters on the optical windows achieving close to 100% laser transmission in a solid optic combination of window and highly reflective mirror. This approach allows for the development of a new whole solid optic laser.

Quarrie, L., E-mail: Lindsay.Quarrie@l-3com.com, E-mail: lindsay.o.quarrie@gmail.com [New Mexico Institute of Mining and Technology, Department of Materials Engineering, 801 LeRoy Place, Socorro, NM 87801 (United States); Air Force Research Laboratory, AFRL/RDLC Laser CoE, 3550 Aberdeen Avenue SE, Kirtland AFB, NM 87117-5776 (United States)

2014-09-15T23:59:59.000Z

492

Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing  

SciTech Connect (OSTI)

The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk [Korea Atomic Energy Research Institute, 1045 Daedeok-daaro, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

493

Salt Waste Processing Facility Fact Sheet | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Services » Waste Management » Tank Waste and Waste Processing » Services » Waste Management » Tank Waste and Waste Processing » Salt Waste Processing Facility Fact Sheet Salt Waste Processing Facility Fact Sheet Nuclear material production operations at SRS resulted in the generation of liquid radioactive waste that is being stored, on an interim basis, in 49 underground waste storage tanks in the F- and H-Area Tank Farms. SWPF Fact Sheet More Documents & Publications EIS-0082-S2: Amended Record of Decision Savannah River Site Salt Waste Processing Facility Technology Readiness Assessment Report EIS-0082-S2: Record of Decision Waste Management Nuclear Materials & Waste Tank Waste and Waste Processing Waste Disposition Packaging and Transportation Site & Facility Restoration Deactivation & Decommissioning (D&D)

494

Savannah River Site - Salt Waste Processing Facility Independent Technical Review  

Broader source: Energy.gov (indexed) [DOE]

SALT WASTE PROCESSING FACILITY SALT WASTE PROCESSING FACILITY INDEPENDENT TECHNICAL REVIEW November 22, 2006 Conducted by: Harry Harmon, Team Lead Civil/Structural Sub Team Facility Safety Sub Team Engineering Sub Team Peter Lowry, Lead James Langsted, Lead George Krauter, Lead Robert Kennedy Chuck Negin Art Etchells Les Youd Jerry Evatt Oliver Block Loring Wyllie Richard Stark Tim Adams Tom Anderson Todd LaPointe Stephen Gosselin Carl Costantino Norman Moreau Patrick Corcoran John Christian Ken Cooper Kari McDaniel _____________________________ Harry D. Harmon ITR Team Leader SPD-SWPF-217 SPD-SWPF-217: Salt Waste Processing Facility Independent Technical Review 11/22/2006 ACKNOWLEDGEMENT The ITR Team wishes to thank Shari Clifford of Pacific Northwest National Laboratory for

495

Injector nozzle for molten salt destruction of energetic waste materials  

DOE Patents [OSTI]

An injector nozzle has been designed for safely injecting energetic waste materials, such as high explosives, propellants, and rocket fuels, into a molten salt reactor in a molten salt destruction process without premature detonation or back burn in the injection system. The energetic waste material is typically diluted to form a fluid fuel mixture that is injected rapidly into the reactor. A carrier gas used in the nozzle serves as a carrier for the fuel mixture, and further dilutes the energetic material and increases its injection velocity into the reactor. The injector nozzle is cooled to keep the fuel mixture below the decomposition temperature to prevent spontaneous detonation of the explosive materials before contact with the high-temperature molten salt bath.

Brummond, William A. (Livermore, CA); Upadhye, Ravindra S. (Pleasanton, CA)

1996-01-01T23:59:59.000Z

496

Stress measurements in rock salt using hydraulic fracturing  

SciTech Connect (OSTI)

Hydraulic fracturing was applied in horizontal drillholes in the Salado salt formation near Carlsbad, New Mexico. Testing took place approximately 650 m below surface in order to support the design of a Waste Isolation Pilot Plant (WIPP) for the disposal of radioactive waste from defense activities of the United States. Hydraulic fracturing was performed primarily to determine whether the virgin in situ stress state at the WIPP site is isotropic and whether the magnitudes of the the virgin in situ stresses correspond to the weight of the overburden. Beyond these limited objectives, measurements are being analyzed to evaluate the usefulness of hydraulic fracturing in salt formations in general. Such measurements are desirable to determine stresses induced by mining and to monitor time-dependent stress changes around underground excavations in salt masses. Hydraulic fracturing measurements are also relevant to the evaluation of allowable pressures before fracturing is induced in pressurized boreholes and storage caverns.

Wawersik, W.R.; Stone, C.M.

1986-01-01T23:59:59.000Z

497

Analytical methods for determining the reactivity of pyrochemical salts  

SciTech Connect (OSTI)

Pyrochemical processes used for the purification of plutonium have generated quantities of residue that contain varying amounts of reactive metals such as potassium, sodium, calcium, and magnesium. These residues are currently considered hazardous and are being managed under RCRA because of the reactivity characteristic. This designation is based solely on process knowledge. Currently there is no approved procedure for determining the reactivity of a solid with water. A method is being developed to rapidly evaluate the reactivity of pyrochemical salts with water by measuring the rate of hydrogen generation. The method was initially tested with a magnesium containing pyrochemical salt. A detection limit of approximately 0.004 g of magnesium was established. A surrogate molten salt extraction residue was also tested. Extrapolation of test data resulted in a hydrogen generation rate of 4.4 mg/(g min).

Phillips, A.G.; Stakebake, J.L.

1994-05-01T23:59:59.000Z

498

Columbus Salt Marsh Geothermal Area | Open Energy Information  

Open Energy Info (EERE)

Columbus Salt Marsh Geothermal Area Columbus Salt Marsh Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermal Resource Area: Columbus Salt Marsh Geothermal Area Contents 1 Area Overview 2 History and Infrastructure 3 Regulatory and Environmental Issues 4 Exploration History 5 Well Field Description 6 Geology of the Area 7 Geofluid Geochemistry 8 NEPA-Related Analyses (0) 9 Exploration Activities (3) 10 References Area Overview Geothermal Area Profile Location: California Exploration Region: Walker-Lane Transition Zone Geothermal Region GEA Development Phase: 2008 USGS Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure Operating Power Plants: 0 No geothermal plants listed.

499

E-Print Network 3.0 - acid monosodium salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Medicine 4 Browne, CB, Research Proposal, March 2009 Activation of the Inflammasome in Gout Summary: is an auto-inflammatory arthritis that can be triggered by the sedimentation...

500

E-Print Network 3.0 - acid trisodium salt Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tri-sodium citrate dihydrate 0.1 M MembFac02 zinc acetate dihydrate 0... .1 M MembFac14 iso-propanol (IPA) 10% vv MembFac02 sodium acetate trihydrate 0.1 M MembFac14...