Sample records for ac26-07nt42677 rpsea fe

  1. Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources

    SciTech Connect (OSTI)

    Russell E. Fray

    2007-05-31T23:59:59.000Z

    RPSEA is currently in its first year of performance under contract DE-AC26-07NT42677, Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program Administration. Significant progress has been made in establishing the program administration policies, procedures, and strategic foundation for future research awards. RPSEA has concluded an industry-wide collaborative effort to identify focus areas for research awards under this program. This effort is summarized in the RPSEA Draft Annual Plan, which is currently under review by committees established by the Secretary of Energy.

  2. Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources

    SciTech Connect (OSTI)

    Russell E. Fray

    2007-06-30T23:59:59.000Z

    RPSEA is currently in its first year of performance under contract DE-AC26-07NT42677, Ultra-Deepwater and Unconventional Natural Gas and Other Petroleum Resources Program Administration. Progress continues to be made in establishing the program administration policies, procedures, and strategic foundation for future research awards. Significant progress was made in development of the draft program solicitations. In addition, RPSEA personnel continued an aggressive program of outreach to engage the industry and ensure wide industry participation in the research award solicitation process.

  3. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produced water samples from active well sites without any pretreatment for organic removal. Both the PEE and CTA membranes displayed excellent salt rejection capabilities...

  4. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    average pressure is higher than the case when CO 2 is 34 continuously injected (red color curve), the pressure variation is generally within the pressure range of near miscible...

  5. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70COMMUNITYResponses:December562 Revision 0 HANFORD

  6. RPSEA Final Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70COMMUNITYResponses:December562 Revision 0 HANFORDRPSEA

  7. rpsea | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,, ,Development ofrluyendi AmesProgram Consortium -

  8. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    RPSEA FE Brine Chemistry SCNGO 2012; FY1236 months Gary Covatch Houston, TX Corrosion and Scale at Extreme Temperature and Pressure Theory and Practical Testing of Scale...

  9. 42677RPSEA | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruaryOctober 2, AlgeriaQ1 Q2 Q3 Q4 Q1 Q2 Q3

  10. RPSEA Final Report Small Producers Program Development Strategies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have increased the reservoir pressure and improved oil recovery. The South Kilgore Unit and the South Pilot area are two of the best producing areas in the ETOF in the last 10...

  11. RPSEA UNCONVENTIONAL GAS CONFERENCE 2012: Geology, the Environment, Hydraulic Fracturing

    E-Print Network [OSTI]

    Yener, Aylin

    Recovery and Salt Production - Jim Silva, GE Oil & Gas 9:30 a.m. Appalachian Shale and Barnett Area Water Shale Coalition 8:30 a.m. Meeting Overview & Agenda - Kent Perry, Vice President, Onshore Programs Isotope Interpretation Tools to Optimize Gas Shale Production - Yongchun Tang, PEER Institute Shale Gas

  12. Research Partnership to Secure Energy for America RPSEA | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation,Maze - Making the Path for(Colorado) |the

  13. RPSEA Final Report Small Producers Program Development Strategies for Maximizing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70COMMUNITYResponses:December562 Revision 0 HANFORDRPSEARPSEA

  14. Masses of Fe-61 and Fe-62

    E-Print Network [OSTI]

    Cossairt, J. D.; Tribble, Robert E.; Kenefick, R. A.

    1977-01-01T23:59:59.000Z

    PHYSICAL RKVIK% C VO LUMK 15, N UMBKB, 5 Masses of 'Fe and Fef MA Y 1977 J. D. Cossairt, R. E. Tribble, * and R. A. Kenefick Cyclotron Institute, Texas A AM University, College Station, Texas 77843 (Received 4 October 1976) The mass excesses... of 'Fe and Fe have been measured using the Ni(a, Be) 'Fe and Ni("B,"N) Fe reactions. The mass excesses obtained are M( 'Fe) = ?58.92 ~ 0.02 MeV and M("Fe) = ?58.85 + 0.07 MeV. The results are consistent with recent predictions from two different mass...

  15. Masses of Fe-61 and Fe-62 

    E-Print Network [OSTI]

    Cossairt, J. D.; Tribble, Robert E.; Kenefick, R. A.

    1977-01-01T23:59:59.000Z

    . 1O) 58.5+ 0.2 (Ref. 12) -58.935 + 0.050 (Ref. 11) Q-value determination using the Ni(' 0, Ne)6 Fe reaction. MASSES OF 'Fe Ago Fe 1689 of -59.41 MeV (Ref. 2) and -58.82 MeV (Ref. 4). The weighted average of the two Q-value de- terminations...PHYSICAL RKVIK% C VO LUMK 15, N UMBKB, 5 Masses of 'Fe and Fef MA Y 1977 J. D. Cossairt, R. E. Tribble, * and R. A. Kenefick Cyclotron Institute, Texas A AM University, College Station, Texas 77843 (Received 4 October 1976) The mass excesses...

  16. miniFE Benchmark

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compiling: tar xzf miniFEref1.4b.tgz cd miniFEref1.4b Edit makefile for your environment make How to Run miniFE requires three input parameters which dictate the...

  17. Organometallic Complexes that Model the Active Sites of the [FeFe]- and [Fe]-Hydrogenases 

    E-Print Network [OSTI]

    Liu, Tianbiao

    2011-02-22T23:59:59.000Z

    My research primarily focuses on biomimetics of the active sites of the [FeFe]- and [Fe]-hydrogenases (H2ase) and is classified into three parts. Part A: The one-electron oxidation of asymmetrically disubstituted FeIFeI models of the active site...

  18. Organometallic Complexes that Model the Active Sites of the [FeFe]- and [Fe]-Hydrogenases

    E-Print Network [OSTI]

    Liu, Tianbiao

    2011-02-22T23:59:59.000Z

    My research primarily focuses on biomimetics of the active sites of the [FeFe]- and [Fe]-hydrogenases (H2ase) and is classified into three parts. Part A: The one-electron oxidation of asymmetrically disubstituted FeIFeI models of the active site...

  19. FE Transition Deliverables

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdfFE DOCKET NO.OilFE

  20. Theoretical study of the interaction of Fe, Fe/sup +/, and FeCO with Ar

    SciTech Connect (OSTI)

    Braga, M.; Almeida, A.L.; Taft, C.A.; Hammond, B.L.; Lester W.A. Jr.

    1988-10-15T23:59:59.000Z

    Ab initio Hartree--Fock calculations were performed on FeAr and FeAr/sup +/ in order to determine the interaction of both neutral and singly-ionized Fe atoms trapped in Ar, and on ArFeCO and FeCOAr in order to ascertain the effect of an Ar matrix on the FeCO molecule. Quadrupole splittings and isomer shifts are computed using ab initio orbital populations and charge densities scaled by a relativistic factor. Good agreement between calculated and experimental hyperfine parameters is found in each case. The interaction energy for Fe/sup +/--Ar has been computed by ab initio Hartree--Fock and effective-core potential (ECP) methods. Both approaches yield a minimum between Fe/sup +/ and Ar at approximately 7.6 bohr.

  1. Supporting Information for "Seasonal changes in Fe species and soluble Fe concentration in the

    E-Print Network [OSTI]

    ) ferrihydrite goethite (-FeOOH) Fe(III) oxalate Fe(III) citrate Fe(III) sulfate smectite (SWy-2) illite (IMt-1 shown. #12;2 4 6 8 10o k (A -1 ) k 3 (k) pyrite (FeS2). hematite (-Fe2O3) ferrihydrite goethite (-Fe

  2. Measurements and calculations of metastable level lifetimes in Fe X, Fe XI, Fe XII, Fe XIII, and Fe XIV 

    E-Print Network [OSTI]

    Moehs, D. P.; Bhatti, M. I.; Church, David A.

    2001-01-01T23:59:59.000Z

    Lifetimes of metastable levels in the ground term of Fe ions within the 3s(2)3p(k), k=1-5, isoelectronic sequences have been measured. These measurements were performed utilizing ions that were selected by mass to charge ratio while transported from...

  3. Measurements and calculations of metastable level lifetimes in Fe X, Fe XI, Fe XII, Fe XIII, and Fe XIV

    E-Print Network [OSTI]

    Moehs, D. P.; Bhatti, M. I.; Church, David A.

    2001-01-01T23:59:59.000Z

    Lifetimes of metastable levels in the ground term of Fe ions within the 3s(2)3p(k), k=1-5, isoelectronic sequences have been measured. These measurements were performed utilizing ions that were selected by mass to charge ratio while transported from...

  4. Relative g-factor measurements in {sup 54}Fe, {sup 56}Fe, and {sup 58}Fe

    SciTech Connect (OSTI)

    East, M. C.; Stuchbery, A. E.; Chamoli, S. K.; Kibedi, T. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Pinter, J. S.; Crawford, H. L.; Mantica, P. F. [NSCL and Department of Chemistry, Michigan State University, Michigan 48824 (United States); Wilson, A. N. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Department of Physics, Australian National University, Canberra, ACT 0200 (Australia)

    2009-02-15T23:59:59.000Z

    The g factors of the 2{sub 1}{sup +} states in {sup 54}Fe and {sup 58}Fe have been measured relative to the 2{sub 1}{sup +} state g factor of {sup 56}Fe using the transient-field technique in inverse kinematics. The results are in satisfactory agreement with recent shell model calculations in the fp model space. For {sup 56}Fe and {sup 58}Fe the g factors approach Z/A and are therefore also consistent with collective interpretations of these 2{sup +} states.

  5. FinalTechnicalReport_15U5O2I-11_RPSEA.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    API RP 2INT MET (Central Gulf of Mexico) 1yr API RP 2INT MET 100yr API RP 2INT MET 1000yr API RP 2INT MET Fatigue Spectrum JONSWAP Gamma 1.0 Seastates Distribution Reference...

  6. FinalTechnicalReport_15U5O2I-11_RPSEA.docx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.New Mexico Feb.Information 91,Security ComplexULTRA-DEEPWATER

  7. Biomineralization Associated with Microbial Reduction of Fe3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Associated with Microbial Reduction of Fe3+ and Oxidation of Fe2+ in Solid Minerals . Biomineralization Associated with Microbial Reduction of Fe3+ and Oxidation of Fe2+...

  8. Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    irradiation of Fe-Fe oxide core-shell nanocluster films: Effect of interface on stability of magnetic properties. Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...

  9. Microstructure, mechanical property, biodegradation behavior, and biocompatibility of biodegradable FeFe2O3 composites

    E-Print Network [OSTI]

    Zheng, Yufeng

    behaviors, and in vitro biocompatibility of Fe­ Fe2O3 composites fabricated by spark plasma sintering were

  10. SCHOOL INFORMATION Santa Fe Indian School

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SCHOOL INFORMATION Santa Fe Indian School 1501 Cerrillos Road Santa Fe, NM 87505 P.O. Box 5340 Santa Fe, NM 87502 Main: (505) 989-6300 www.sfindianschool.org Main and only Entrance...

  11. Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fe3+, and Cr3+ Surface Sites in the Oxidation of NO on the (Fe,Cr)3O4(1 1 1) Surface Termination of an -(Fe,Cr Roles of Fe2+, Fe3+, and Cr3+ Surface Sites in the Oxidation of NO...

  12. fe0024360-paulsson | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fe0024360-paulsson Injection and Tracking of Micro-seismic emitters to Optimize Unconventional Oil and Gas (UOG) Development Last Reviewed 6302015 DE-FE0024360 Goal The goal of...

  13. Second Harmonic Generation Studies of Fe(II) Interactions with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (?-Fe2O3). Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (?-Fe2O3)....

  14. Characterization of hematite (a-Fe2O3), goethite (a-FeOOH), greigite (Fe3S4), and pyrrhotite (Fe7S8) using first-order reversal

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Characterization of hematite (a-Fe2O3), goethite (a-FeOOH), greigite (Fe3S4), and pyrrhotite (Fe7S8) synthetic aluminous hematite (a-Fe2-xAlxO3) and goethite (a-(FeAl)OOH) and natural greigite (Fe3S4) and pyrrhotite (Fe7S8) to constrain interpretation of FORC diagrams from natural samples. Hematite and goethite

  15. Process and genes for expression and overexpression of active [FeFe] hydrogenases

    DOE Patents [OSTI]

    Seibert, Michael; King, Paul W; Ghirardi, Maria Lucia; Posewitz, Matthew C; Smolinski, Sharon L

    2014-09-16T23:59:59.000Z

    A process for expression of active [FeFe]-hydrogenase in a host organism that does not contain either the structural gene(s) for [FeFe]-hydrogenases and/or homologues for the maturation genes HydE, HydF and HyG, comprising: cloning the structural hydrogenase gene(s) and/or the maturation genes HydE, HydF and HydG from an organisms that contains these genes into expression plasmids; transferring the plasmids into an organism that lacks a native [FeFe]-hydrogenase or that has a disrupted [FeFe]-hydrogenase and culturing it aerobically; and inducing anaerobiosis to provide [FeFe] hydrogenase biosynthesis and H?2#191 production.

  16. Radiation effects on interface reactions of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni)

    SciTech Connect (OSTI)

    KUn Shao; Di Chen; Chaochen Wei; Michael S. Martin; Xuemei Wang; Youngjoo Park; Ed Dein; Kevin R. Coffey; b , Yongho Sohn; Bulent H. Sencer; J. Rory Kennedy

    2014-09-01T23:59:59.000Z

    We study the effects of radiation damage on interdiffusion and intermetallic phase formation at the interfaces of U/Fe, U/(Fe + Cr), and U/(Fe + Cr + Ni) diffusion couples. Magnetron sputtering is used to deposit thin films of Fe, Fe + Cr, or Fe + Cr + Ni on U substrates to form the diffusion couples. One set of samples are thermally annealed under high vacuum at 450 C or 550 C for one hour. A second set of samples are annealed identically but with concurrent 3.5 MeV Fe++ ion irradiation. The Fe++ ion penetration depth is sufficient to reach the original interfaces. Rutherford backscattering spectrometry analysis with high fidelity spectral simulations is used to obtain interdiffusion profiles, which are used to examine differences in U diffusion and intermetallic phase formation at the buried interfaces. For all three diffusion systems, Fe++ ion irradiations enhance U diffusion. Furthermore, the irradiations accelerate the formation of intermetallic phases. In U/Fe couples, for example, the unirradiated samples show typical interdiffusion governed by Fick’s laws, while the irradiated ones show step-like profiles influenced by Gibbs phase rules.

  17. Fe-containing phases in hydrated cements

    SciTech Connect (OSTI)

    Dilnesa, B.Z., E-mail: belay.dilnesa@gmail.com [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Wieland, E. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Lothenbach, B. [Empa, Laboratory for Concrete and Construction Chemistry, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Dähn, R. [Paul Scherrer Institute, Laboratory for Waste Management, 5232 Villigen PSI (Switzerland); Scrivener, K.L. [Ecole Polytechnique Federal de Lausanne (EPFL), Laboratory for Construction Materials, 1015 Lausanne (Switzerland)

    2014-04-01T23:59:59.000Z

    In this study synchrotron X-ray absorption spectroscopy (XAS) has been applied, an element specific technique which allows Fe-containing phases to be identified in the complex mineral mixture of hydrated cements. Several Fe species contributed to the overall Fe K-edge spectra recorded on the cement samples. In the early stage of cement hydration ferrite was the dominant Fe-containing mineral. Ferrihydrite was detected during the first hours of the hydration process. After 1 day the formation of Al- and Fe-siliceous hydrogarnet was observed, while the amount of ferrihydrite decreased. The latter finding agrees with thermodynamic modeling, which predicts the formation of Fe-siliceous hydrogarnet in Portland cement systems. The presence of Al- and Fe-containing siliceous hydrogarnet was further substantiated in the residue of hydrated cement by performing a selective dissolution procedure. - Highlights: • Fe bound to ferrihydrite at early age hydration • Fe found to be stable in siliceous hydrogarnet at longer term age hydration • Fe-containing AFt and AFm phases are less stable than siliceous hydrogarnet. • The study demonstrates EXAFS used to identify amorphous or poorly crystalline phases.

  18. Interstitial Fe in MgO

    SciTech Connect (OSTI)

    Mřlholt, T. E., E-mail: tem4@hi.is; Gislason, H. P.; Ólafsson, S. [Science Institute, University of Iceland, Dunhaga 3, IS-107 Reykjavík (Iceland); Mantovan, R. [Laboratorio MDM, IMM-CNR, Via Olivetti 2, 20846 Agrate Brianza (MB) (Italy); Gunnlaugsson, H. P.; Svane, A.; Weyer, G. [Department of Physics and Astronomy, Aarhus University, DK-8000 Aarhus C (Denmark); Masenda, H.; Naidoo, D. [School of Physics, University of the Witwatersrand, WITS 2050 (South Africa); Bharuth-Ram, K. [Durban University of Technology, Durban 4001 (South Africa); Fanciulli, M. [Laboratorio MDM, IMM-CNR, Via Olivetti 2, 20846 Agrate Brianza (MB) (Italy); Dipartimento di Scienza dei Materiali, Universitŕ di Milano Bicocca, Milano (Italy); Johnston, K. [PH Department, ISOLDE/CERN, 1211 Geneva 23 (Switzerland); Langouche, G. [Instituut voor Kern-en Stralings fysika, University of Leuven, B-3001 Leuven (Belgium); Sielemann, R. [Helmholtz-Zentrum-Berlin für Materialien und Energie, D-14109 Berlin (Germany)

    2014-01-14T23:59:59.000Z

    Isolated {sup 57}Fe atoms were studied in MgO single-crystals by emission Mössbauer spectroscopy following implantation of {sup 57}Mn decaying to {sup 57}Fe. Four Mössbauer spectral components were found corresponding to different Fe lattice positions and/or charge states. Two components represent Fe atoms substituting Mg as Fe{sup 2+} and Fe{sup 3+}, respectively; a third component is due to Fe in a strongly implantation-induced disturbed region. The fourth component, which is the focus of this paper, can be assigned to Fe at an interstitial site. Comparison of its measured isomer shift with ab initio calculations suggests that the interstitial Fe is located on, or close to, the face of the rock-salt MgO structure. To harmonize such an assignment with the measured near-zero quadrupole interaction a local motion process (cage motion) of the Fe has to be stipulated. The relation of such a local motion as a starting point for long range diffusion is discussed.

  19. Transmission electron microscopy study on Co/Fe interdiffusion in SmCo5/Fe and Sm2Co7/Fe/Sm2Co7 thin films

    E-Print Network [OSTI]

    Liu, J. Ping

    Transmission electron microscopy study on Co/Fe interdiffusion in SmCo5/Fe and Sm2Co7/Fe/Sm2Co7 at the interface of an as-deposited SmCo5/Fe bilayer, while annealing results in measurable Co/Fe interdiffusion near the boundary. For the annealed SmCo5/Fe bilayer, phase separation occurs within the bcc

  20. Fe/Au Multilayers: Structure and Magnetoresistance

    SciTech Connect (OSTI)

    Singh, Surendra; Basu, Saibal; Bhattacharya, D. [Solid State Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Prajapat, C. L. [Technical Physics Division, Bhabha Atomic Research Center, Mumbai 400085 (India); Gupta, M. [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452 017 (India)

    2011-07-15T23:59:59.000Z

    We have measured the magnetoresistance (MR) in two sets of Fe/Au multilayers, with varying (1) Fe layer thickness, t{sub Fe} = 3-10 nm, and (2) Au layer thickness t{sub Au} = 5-15 nm, grown on Si substrates by sputtering. The multilayer interface structure and magnetic properties were studied by polarized neutron reflectometry (PNR). The study was undertaken to understand the correlation between structure of these multilayers and their magneto-transport properties.

  1. Identification of Highly Active Fe Sites in (Ni,Fe)OOH for Electrocata...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enhanced OER activity in Fe-doped -NiOOH, in which Fe sites have near-optimum binding energies for OER intermediates. The conversion of solar energy and water to hydrogen is a...

  2. Bimagnetic Core/Shell FePt/Fe3O4 Nanoparticles

    E-Print Network [OSTI]

    Wang, Zhong L.

    and H2S.11,12 Procedures leading to novel inorganic core/shell structures with controlled dimensions nanoparticles, FePt and Fe3O4, followed by reduc- tive annealing to remove organic surfactant around each

  3. Reductive Biotransformation of Fe in Shale-Limestone Saprolite Containing Fe(III) Oxides and Fe(II)/Fe(III) Phyllosilicates

    SciTech Connect (OSTI)

    Kukkadapu, Ravi K.; Zachara, John M.; Fredrickson, Jim K.; McKinley, James P.; Kennedy, David W.; Smith, Steven C.; Dong, Hailiang

    2006-07-15T23:59:59.000Z

    A <2.0-mm fraction of a mineralogically complex subsurface sediment containing goethite and Fe(II)/Fe(III) phyllosilicates was incubated with Shewanella putrefaciens (strain CN32) and lactate at circumneutral pH under anoxic conditions to investigate electron acceptor preference and the nature of the resulting biogenic Fe(II) fraction. Anthraquinone-2,6-disulfonate (AQDS), an electron shuttle, was included in select treatments to enhance bioreduction and subsequent biomineralization. The sediment was highly aggregated and contained two distinct clast populations: i) a highly weathered one with “sponge-like” internal porosity, large mineral crystallites, and Fe-containing micas, and ii) a dense, compact one with fine-textured Fe-containing illite and nano-sized goethite, as revealed by various forms of electron microscopic analyses. Approximately 10 to 15% of the Fe(III)TOT was bioreduced by CN32 over 60 d in media without AQDS, whereas 24% and 35% of the Fe(III)TOT was bioreduced by CN32 after 40 and 95 d in media with AQDS. Little or no Fe2+, Mn, Si, Al, and Mg were evident in aqueous filtrates after reductive incubation. Mössbauer measurements on the bioreduced sediments indicated that both goethite and phyllosilicate Fe(III) were partly reduced without bacterial preference. Goethite was more extensively reduced in the presence of AQDS whereas phyllosilicate Fe(III) reduction was not influenced by AQDS. Biogenic Fe(II) resulting from phyllosilicate Fe(III) reduction remained in a layer-silicate environment that displayed enhanced solubility in weak acid. The mineralogic nature of the goethite biotransformation product was not determined. Chemical and cryogenic Mössbauer measurements, however, indicated that the transformation product was not siderite, green rust, magnetite, Fe(OH)2, or Fe(II) adsorbed on phyllosilicate or bacterial surfaces. Several lines of evidence suggested that biogenic Fe(II) existed as surface associated phase on the residual goethite, and/or as a Fe(II)-Al coprecipitate. Sediment aggregation and mineral physical and/or chemical factors were demonstrated to play a major role on the nature and location of the biotransformation reaction and its products.

  4. Fe-V redox flow batteries

    DOE Patents [OSTI]

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

    2014-07-08T23:59:59.000Z

    A redox flow battery having a supporting solution that includes Cl.sup.- anions is characterized by an anolyte having V.sup.2+ and V.sup.3+ in the supporting solution, a catholyte having Fe.sup.2+ and Fe.sup.3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO.sub.4.sup.2- and Cl.sup.- anions.

  5. fe0024292-gti | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Resources - Field Labs Hydraulic Fracturing Test Site (HFTS) Last Reviewed 6292015 DE-FE0024292 Goal This project is to conduct a field-based hydraulic fracturing research...

  6. fe0024293-geglobal | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unconventional Resources Enhanced Oil Recovery Deepwater Tech Methane Hydrate nXis Well Integrity Inspection in Unconventional Wells Last Reviewed January 2015 DE-FE0024293...

  7. fe0013723-UTA | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development of Nanoparticle-Stabilized Foams To Improve Performance of Water-less Hydraulic Fracturing Last Reviewed 1292014 DE-FE0013723 Goal The overall objective of this...

  8. fe0024314-swri | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Novel Natural Gas Surface Process Equipment for Replacement of Water as Primary Hydraulic Fracturing Fluid Last Reviewed 1272015 DE-FE0024314 Goal The goal is to develop...

  9. Structural and magnetic properties of the ordered FePt{sub 3}, FePt and Fe{sub 3}Pt nanoparticles

    SciTech Connect (OSTI)

    Liu, Yang [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China); Jiang, Yuhong; Zhang, Xiaolong; Wang, Yaxin; Zhang, Yongjun; Liu, Huilian; Zhai, Hongju; Liu, Yanqing [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yang, Jinghai, E-mail: jhyang1@jlnu.edu.cn [Institute of Condensed State Physics, Jilin Normal University, Siping 136000 (China); Key Laboratory of Functional Materials Physics and Chemistry (Jilin Normal University), Ministry of Education, Siping 136000 (China); Yan, Yongsheng, E-mail: yanyongsheng215@126.com [Institute of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2014-01-15T23:59:59.000Z

    The Fe{sub x}Pt{sub 100?x} nanoparticles (NPs) with different nominal atomic rations (30?x?80) were synthesized at 700 °C by the sol–gel method. The structure, morphology and magnetic properties of the samples were investigated. When the Fe content in the Fe–Pt alloy NPs was 30 at%, FePt{sub 3} NPs were successfully synthesized. With the increase in Fe content up to 50 at%, it was found that the superlattice reflections (0 0 1) and (1 1 0) appeared, which indicated the formation of the L1{sub 0}-FePt phase. Meanwhile, the FePt{sub 3} fraction was reduced. When the Fe content increased to 60 at%, single-phase L1{sub 0}-FePt NPs were synthesized. The coercivity (Hc), saturation magnetization (Ms) and chemical order parameter S for Fe{sub 60}Pt{sub 40} NPs were as high as 10,200 Oe, 17.567 emu/g and 0.928, respectively. With the further increase of the Fe content to 80 at%, only Fe{sub 3}Pt phase existed and the Hc of the Fe{sub 3}Pt NPs decreased drastically to 360 Oe. - Graphical abstract: Fe{sub 3}Pt, FePt and FePt{sub 3} nanoparticles was obtained by sol–gel method. The effect of iron and platinum content on structural and magnetic properties of the FePt nanoparticles was investigated. Display Omitted - Highlights: • L1{sub 2}-FePt{sub 3}, L1{sub 0}-FePt and L1{sub 2}-Fe{sub 3}Pt NPs were synthesized by sol–gel method. • The chemical order parameter S affects the magnetic properties of the Fe–Pt alloy. • Structural and magnetic properties of the Fe–Pt alloy NPs were studied. • The synthetic route in this study will open up the possibilities of practical use.

  10. Fe(II)-catalyzed Recrystallization of Goethite Revisited. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structural Fe in Fe(III) oxides and aqueous Fe(II) with no formation of secondary minerals or change in particle size or shape. Here we derive a mass balance model to quantify...

  11. al cr fe: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    junctions with CrFe and CrFeCr barriers. Although the exact... Robinson, J. W. A.; Banerjee, N.; Blamire, M. G. 2014-03-05 15 Cavitation erosion of laser processed Fe-Cr-Mn and...

  12. Theoretical Electron Density Distributions for Fe- and Cu-Sulfide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Density Distributions for Fe- and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Theoretical Electron Density Distributions for Fe- and Cu-Sulfide...

  13. Biogeochemical Transformation of Fe Minerals in a Petroleum-Contaminat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformation of Fe Minerals in a Petroleum-Contaminated Aquifer. Biogeochemical Transformation of Fe Minerals in a Petroleum-Contaminated Aquifer. Abstract: Biogeochemical...

  14. Purification and Characterization of [NiFe]-Hydrogenase of Shewanella...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1. Purification and Characterization of NiFe-Hydrogenase of Shewanella oneidensis MR-1....

  15. Study of Fe-Co Nanocomposite Films

    SciTech Connect (OSTI)

    Lancok, A.; Klementova, M. [Institute of Inorganic Chemistry of the AS CR, v. v. i., 250 68 Husinec-Rez 1001 (Czech Republic); Kohout, J. [Faculty of Mathematics and Physics. Charles University, V Holesovickach 2, 180 00 Prague (Czech Republic); Miglierini, M. [Institute of Inorganic Chemistry of the AS CR, v. v. i., 250 68 Husinec-Rez 1001 (Czech Republic); Department of Nuclear Physics and Technology, Slovak University of Technology, Ilkovicova 3, 812 19 Bratislava (Slovakia); Fendrych, F.; Lancok, J. [Institute of Physics AS CR, v. v. i., Na Slovance 2, 182 21 Prague (Czech Republic)

    2010-07-13T23:59:59.000Z

    Moessbauer study of nanogranular ferromagnetic FeCo films is presented. Two ways of production of nanocomposite systems were employed: (i) hollow cathode plasma jet deposition process, and (ii) laser ablation from Fe-Co metallic targets by means of a KrF excimer laser and r.f. magnetron sputtering. Complementary information on the composition of the samples were obtained by nuclear magnetic resonance of {sup 57}Fe and {sup 59}Co nuclei, conversion electron Moessbauer spectroscopy, and high resolution transmission electron microscopy. The films contain crystalline nanoparticles, 5-20 nm in size, embedded in an amorphous matrix.

  16. FE0005889_UTPermian | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Case Studies of the ROZ CO2 Flood and the Combined ROZMPZ CO2 Flood at the Goldsmith Landreth Unit, Ector County, Texas Last Reviewed 12162014 DE-FE0005889 Goal The goal of this...

  17. Thermodynamics of the Magnetite-Ulvöspinel (Fe3O4-Fe2TiO4) Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Thermodynamics of the Magnetite-Ulvspinel (Fe3O4-Fe2TiO4) Solid Solution. Abstract: The thermodynamics of mixing and its...

  18. FINITENESS OF e Ass Fe (M) AND ITS

    E-Print Network [OSTI]

    Katzman, Moty

    FINITENESS OF e Ass Fe (M) AND ITS CONNECTIONS TO TIGHT CLOSURE. Mordechai Katzman Abstract. Let R the sets e Ass Fe(M) and e Ass Ge(M) where Fe() is the Peskine-Szpiro functor and Ge(M) is Fe(M) modulo and tight closure. The last section of this paper constructs an example which shows that e Ass Fe(M) may

  19. Second Harmonic Generation Studies of Fe(II) Interactions with Hematite (?-Fe2O3)

    SciTech Connect (OSTI)

    Jordan, David S.; Hull, Christopher J.; Troiano, Julianne M.; Riha, Shannon C.; Martinson, Alex B.; Rosso, Kevin M.; Geiger, Franz M.

    2013-02-28T23:59:59.000Z

    Iron oxides are a ubiquitous class of compounds that are involved in many biological, geological, and technological processes, and the Fe(III)/Fe(II) redox couple is a fundamental transformation pathway; however, the study of iron oxide surfaces in aqueous solution by powerful spectroscopic techniques has been limited due to "strong absorber problem". In this work, atomic layer deposition (ALD) thin films of polycrystalline alpha-Fe2O3 were analyzed using the Eisenthal chi((3)) technique, a variant of second harmonic generation that reports on interfacial potentials. By determining the surface charge densities at multiple pH values, the point of zero charge was found to be 5.5 +/- 0.3. The interaction of aqueous Fe(II) at pH 4 and in 1 mM NaCl with ALD-prepared hematite was found to be fully reversible and to lead to about 4 times more ferrous iron ions adsorbed per square centimeter than on fused-silica surfaces under the same conditions. The data are consistent with a recently proposed conceptual model for net Fe(II) uptake or release that is underlain by a dynamic equilibrium between Fe(II) adsorbed onto hematite, electron transfer into favorable surface sites with attendant Fe(III) deposition, and electron conduction to favorable remote sites that release and replenish aqueous Fe(II).

  20. FeMn/Fe/Co/Cu(1,1,10) films studied using the magneto-optic Kerr effect and photoemission electron microscopy

    E-Print Network [OSTI]

    Meng, Y.

    2012-01-01T23:59:59.000Z

    B 84, 064416 (2011) FeMn/Fe/Co/Cu(1,1,10) ?lms studied usingmeasurements on FeMn/ Fe(8ML)/Co/vicinal Cu(001), in whichthe FeMn(10ML)/Fe(2ML)/Co(20ML)/Cu(1,1,10) sample growth. (

  1. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27T23:59:59.000Z

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  2. Membrane separation advances in FE hydrogen program

    SciTech Connect (OSTI)

    NONE

    2007-12-31T23:59:59.000Z

    Since its inception in Fiscal Year 2003 the US Office of Fossil Energy (FE) Hydrogen from Coal Program has sponsored more than 60 projects and made advances in the science of separating out pure hydrogen from syngas produced through coal gasification. The Program is focusing on advanced hydrogen separation technologies, which include membranes, and combining the WGS reaction and hydrogen separation in a single operation known as process intensification. The article explains the technologies and describes some key FE membrane projects. More details are available from http://www.fossil.energy.gov. 1 fig.

  3. Santa Fe Community College selects new president

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearch Briefs TheSanket A. Deshmukh ArgonneSanta FeSanta Fe

  4. Regulation of brain copper homeostasis by the brain barrier systems: Effects of Fe-overload and Fe-deficiency

    SciTech Connect (OSTI)

    Monnot, Andrew D.; Behl, Mamta; Ho, Sanna; Zheng, Wei, E-mail: wzheng@purdue.edu

    2011-11-15T23:59:59.000Z

    Maintaining brain Cu homeostasis is vital for normal brain function. The role of systemic Fe deficiency (FeD) or overload (FeO) due to metabolic diseases or environmental insults in Cu homeostasis in the cerebrospinal fluid (CSF) and brain tissues remains unknown. This study was designed to investigate how blood-brain barrier (BBB) and blood-SCF barrier (BCB) regulated Cu transport and how FeO or FeD altered brain Cu homeostasis. Rats received an Fe-enriched or Fe-depleted diet for 4 weeks. FeD and FeO treatment resulted in a significant increase (+ 55%) and decrease (- 56%) in CSF Cu levels (p < 0.05), respectively; however, neither treatment had any effect on CSF Fe levels. The FeD, but not FeO, led to significant increases in Cu levels in brain parenchyma and the choroid plexus. In situ brain perfusion studies demonstrated that the rate of Cu transport into the brain parenchyma was significantly faster in FeD rats (+ 92%) and significantly slower (- 53%) in FeO rats than in controls. In vitro two chamber Transwell transepithelial transport studies using primary choroidal epithelial cells revealed a predominant efflux of Cu from the CSF to blood compartment by the BCB. Further ventriculo-cisternal perfusion studies showed that Cu clearance by the choroid plexus in FeD animals was significantly greater than control (p < 0.05). Taken together, our results demonstrate that both the BBB and BCB contribute to maintain a stable Cu homeostasis in the brain and CSF. Cu appears to enter the brain primarily via the BBB and is subsequently removed from the CSF by the BCB. FeD has a more profound effect on brain Cu levels than FeO. FeD increases Cu transport at the brain barriers and prompts Cu overload in the CNS. The BCB plays a key role in removing the excess Cu from the CSF.

  5. 90° magnetic coupling in a NiFe/FeMn/biased NiFe multilayer spin valve component investigated by polarized neutron reflectometry

    SciTech Connect (OSTI)

    Callori, S. J., E-mail: sara.callori@ansto.gov.au; Bertinshaw, J. [School of Physics, The University of New South Wales, Sydney, New South Wales 2052 (Australia); Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Cortie, D. L. [The Institute for Superconducting and Electronic Materials, The University of Wollongong, Wollongong, New South Wales 2522 (Australia); Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Cai, J. W., E-mail: jwcai@aphy.iphy.ac.cn; Zhu, T. [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Le Brun, A. P. [Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Klose, F. [Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Department of Physics and Materials Science, City University of Hong Kong (Hong Kong)

    2014-07-21T23:59:59.000Z

    We have observed 90° magnetic coupling in a NiFe/FeMn/biased NiFe multilayer system using polarized neutron reflectometry. Magnetometry results show magnetic switching for both the biased and free NiFe layers, the latter of which reverses at low applied fields. As these measurements are only capable of providing information about the total magnetization within a sample, polarized neutron reflectometry was used to investigate the reversal behavior of the NiFe layers individually. Both the non-spin-flip and spin-flip neutron reflectometry signals were tracked around the free NiFe layer hysteresis loop and were used to detail the evolution of the magnetization during reversal. At low magnetic fields near the free NiFe coercive field, a large spin-flip signal was observed, indicating magnetization aligned perpendicular to both the applied field and pinned layer.

  6. THE THICKNESS DISTORTION OF Fe 57 BACKSCATTER MOSSBAUER SPECTRA

    E-Print Network [OSTI]

    Fultz, B.

    2013-01-01T23:59:59.000Z

    F. Weise, and P. Flinn, "Mossbauer Spectrometry for AnalysisOF Fe 57 BACKSCATTER MOSSBAUER SPECTRA B. Fultz and J. W.DISTORTION OF Fe BACKSCATTER MOSSBAUER SPECTRA B. Fultz and

  7. Reductive Biotransformation of Fe in Shale-Limestone Saprolite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AQDS, whereas 24% and 35% of the Fe(III)TOT was bioreduced by CN32 after 40 and 95 d in media with AQDS. Little or no Fe2+, Mn, Si, Al, and Mg were evident in aqueous filtrates...

  8. Microbial Lithotrophic Oxidation of Structural Fe(II) in Biotite...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of weathering. Here we show that a lithotrophic Fe(II)-oxidizing, nitrate-reducing enrichment culture (Straub, 6 1996) can grow via oxidation of structural Fe(II) in biotite, a...

  9. Metallicity distribution of bulge planetary nebulae and the [O/Fe] x [Fe/H] relation

    E-Print Network [OSTI]

    W. J. Maciel

    1999-10-27T23:59:59.000Z

    The O/H metallicity distribution of different samples of planetary nebulae in the bulge of the Milky Way and M31 are compared. O/H abundances are converted into [Fe/H] metallicity by the use of theoretical [O/Fe] x [Fe/H] relationships both for the bulge and the solar neighbourhood. It is found that these relationships imply an offset of [Fe/H] abundances by a factor up to 0.5 dex for bulge nebulae. Systematic errors in the O/H abundances as suggested by some recent recombination line work, ON cycling and statistical uncertainties are unable to explain the observed offset, suggesting that the adopted relationship for the bulge probably overestimates the oxygen enhancement relative to iron.

  10. Solution-phase photochemistry of a [FeFe]hydrogenase model compound: Evidence of photoinduced isomerisation

    SciTech Connect (OSTI)

    Kania, Rafal; Hunt, Neil T. [Department of Physics, University of Strathclyde, SUPA, Glasgow G4 0NG (United Kingdom); Frederix, Pim W. J. M. [Department of Physics, University of Strathclyde, SUPA, Glasgow G4 0NG (United Kingdom); WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL (United Kingdom); Wright, Joseph A.; Pickett, Christopher J. [Energy Materials Laboratory, School of Chemistry, University of East Anglia, Norwich Research Park, Norwich NR4 7TJ (United Kingdom); Ulijn, Rein V. [WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL (United Kingdom)

    2012-01-28T23:59:59.000Z

    The solution-phase photochemistry of the [FeFe] hydrogenase subsite model ({mu}-S(CH{sub 2}){sub 3}S)Fe{sub 2}(CO){sub 4}(PMe{sub 3}){sub 2} has been studied using ultrafast time-resolved infrared spectroscopy supported by density functional theory calculations. In three different solvents, n-heptane, methanol, and acetonitrile, relaxation of the tricarbonyl intermediate formed by UV photolysis of a carbonyl ligand leads to geminate recombination with a bias towards a thermodynamically less stable isomeric form, suggesting that facile interconversion of the ligand groups at the Fe center is possible in the unsaturated species. In a polar or hydrogen bonding solvent, this process competes with solvent substitution leading to the formation of stable solvent adduct species. The data provide further insight into the effect of incorporating non-carbonyl ligands on the dynamics and photochemistry of hydrogenase-derived biomimetic compounds.

  11. Magnetism in La?O?(Fe??xMnx)?Se? tuned by Fe/Mn ratio

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lei, Hechang; Bozin, Emil S.; Llobet, A.; Ivanovski, V.; Koteski, V.; Belosevic-Cavor, J.; Cekic, B.; Petrovic, C.

    2012-09-01T23:59:59.000Z

    We report the evolution of structural and magnetic properties in La?O?(Fe??xMnx)?Se?. Heat capacity and bulk magnetization indicate an increased ferromagnetic component of the long-range magnetic order and possible increased degree of frustration. Atomic disorder on Fe(Mn) sites suppresses the temperature of the long-range order whereas intermediate alloys show a rich magnetic phase diagram.

  12. CRITICAL FLUCTUATIONS. ANOMALOUS LINE SHAPES OF Fe3+ -MOSSBAUER SPECTRA

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CRITICAL FLUCTUATIONS. ANOMALOUS LINE SHAPES OF Fe3+ -MOSSBAUER SPECTRA IN MAGNETICALLY ORDERED Mossbauer ont montre qu'un recuit incomplet des solutions solides CrzO3-Fez03 et A12 0 3-Fez03 donnelieu203-Fe203pures ou dopeespar Fe2+donnent lieu uneespkceentierementnouvelle de spectres Mossbauer

  13. Low 60Fe abundance in Semarkona and Sahara 99555

    E-Print Network [OSTI]

    Tang, Haolan

    2015-01-01T23:59:59.000Z

    Iron-60 (t1/2=2.62 Myr) is a short-lived nuclide that can help constrain the astrophysical context of solar system formation and date early solar system events. A high abundance of 60Fe (60Fe/56Fe= 4x10-7) was reported by in situ techniques in some chondrules from the LL3.00 Semarkona meteorite, which was taken as evidence that a supernova exploded in the vicinity of the birthplace of the Sun. However, our previous MC-ICPMS measurements of a wide range of meteoritic materials, including chondrules, showed that 60Fe was present in the early solar system at a much lower level (60Fe/56Fe=10-8). The reason for the discrepancy is unknown but only two Semarkona chondrules were measured by MC-ICPMS and these had Fe/Ni ratios below ~2x chondritic. Here, we show that the initial 60Fe/56Fe ratio in Semarkona chondrules with Fe/Ni ratios up to ~24x chondritic is 5.4x10-9. We also establish the initial 60Fe/56Fe ratio at the time of crystallization of the Sahara 99555 angrite, a chronological anchor, to be 1.97x10-9. The...

  14. Revised Transition Probabilities for Fe XXV Relativistic CI Calculations

    E-Print Network [OSTI]

    Johnson, Walter R.

    Revised Transition Probabilities for Fe XXV Relativistic CI Calculations W. R. Johnson1 and U are provided for transition probabilities between fine-structure components of levels with n 6 in FeXXV. Earlier published data for transitions between fine-structure levels in FeXXV is found to in error

  15. RDX degradation using an integrated Fe(0)-microbial treatment approach

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    RDX degradation using an integrated Fe(0)-microbial treatment approach M.J. Wildman and P was enhanced by anaerobic bacteria that feed on cathodic hydrogen (i.e., H2 produced during anaerobic Fe(0) corrosion by water). Apparently, the hydrogenotrophic consortium that exploits Fe(0) corrosion

  16. Multiferroicity and spiral magnetism in FeVO{sub 4} with quenched Fe orbital moments

    SciTech Connect (OSTI)

    Daoud-Aladine, A.; Chapon, L. C. [ISIS facility, Rutherford Appleton Laboratory, STFC, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Kundys, B.; Martin, C.; Simon, C. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); Radaelli, P. G. [ISIS facility, Rutherford Appleton Laboratory, STFC, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Brown, P. J. [Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, 38042 Grenoble Cedex 9 (France)

    2009-12-01T23:59:59.000Z

    FeVO{sub 4} has been studied by heat capacity, magnetic susceptibility, electric polarization and single-crystal neutron-diffraction experiments. The triclinic crystal structure is made of S-shaped clusters of six Fe{sup 3+} ions, linked by VO{sub 4}{sup 3-} groups. Two long-range magnetic ordering transitions occur at T{sub N1}=22 K and T{sub N2}=15 K. Both magnetic structures are incommensurate and below T{sub N2}, FeVO{sub 4} becomes weakly ferroelectric coincidentally with the loss of the collinearity of the magnetic structure in a very similar fashion than in the classical TbMnO{sub 3} multiferroic material. However we argue that the symmetry considerations and the mechanisms invoked to explain these properties in TbMnO{sub 3} do not straightforwardly apply to FeVO{sub 4}. First, the magnetic structures, even the collinear structure, are all acentric so that ferroelectricity in FeVO{sub 4} is not correlated with the fact magnetic ordering is breaking inversion symmetry. Regarding the mechanism, FeVO{sub 4} has quenched orbital moments that questions the exact role of the spin-orbit interactions.

  17. In vitro degradation and biocompatibility of FePd and FePt composites fabricated by spark plasma sintering

    E-Print Network [OSTI]

    Zheng, Yufeng

    rate than pure iron, Fe-5 wt.%Pd and Fe-5 wt.%Pt composites were prepared by spark plasma sinteringIn vitro degradation and biocompatibility of Fe­Pd and Fe­Pt composites fabricated by spark plasma sintering T. Huang a,b , J. Cheng c , Y.F. Zheng a,b,c, a State Key Laboratory for Turbulence and Complex

  18. In-field {sup 57}Fe Mössbauer spectroscopy below spin-flop transition in powdered troilite (FeS) mineral

    SciTech Connect (OSTI)

    Cuda, Jan, E-mail: jan.cuda@upol.cz; Tucek, Jiri; Filip, Jan; Malina, Ondrej; Krizek, Michal; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science, Palacký University in Olomouc, 17. listopadu 1192/12, 771 46 Olomouc (Czech Republic); Kohout, Tomas [Department of Physics, University of Helsinki, P.O. Box 64, 00014 Helsinki University, Finland and Institute of Geology, Academy of Sciences of the Czech Republic v.v.i., Rozvojová 269, 165 00 Prague (Czech Republic)

    2014-10-27T23:59:59.000Z

    Powdered troilite (FeS), extracted from the Cape York IIIA octahedrite meteorite, was investigated employing in-field {sup 57}Fe Mössbauer spectroscopy. The study identified a typical behavior of polycrystalline antiferromagnetic material under external magnetic fields. The in-field evolution of the {sup 57}Fe Mössbauer spectra showed that the spin-flop transition in the FeS system occurs at a field higher than 5 T.

  19. Controlled oxidation of FeCo magnetic nanoparticles to produce faceted FeCo/ferrite nanocomposites for rf heating applications

    E-Print Network [OSTI]

    Laughlin, David E.

    Controlled oxidation of FeCo magnetic nanoparticles to produce faceted FeCo/ferrite nanocomposites XRD and TEM showed MNPs to have a thin ferrite shell. Nanopowders were isochronally annealed and oxidation products in FeCo/ferrite nanocomposite materials and their influence on applications.4 We report

  20. Granular nanostructures and magnetic characteristics of FePt-TiO{sub 2}/FePt-C stacked granular films

    SciTech Connect (OSTI)

    Ono, Takuya, E-mail: ono-takuya@fujielectric.co.jp; Moriya, Tomohiro [Fuji Electric Co. Ltd., Tokyo 191-8502 (Japan); Frontier Research Institute for Interdisciplinary Sciences (FRIS), Tohoku University, Miyagi 980-8578 (Japan); Hatayama, Masatoshi [Frontier Research Institute for Interdisciplinary Sciences (FRIS), Tohoku University, Miyagi 980-8578 (Japan); Kikuchi, Nobuaki; Okamoto, Satoshi; Kitakami, Osamu [Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Miyagi 980-8577 (Japan); Shimatsu, Takehito [Frontier Research Institute for Interdisciplinary Sciences (FRIS), Tohoku University, Miyagi 980-8578 (Japan); Research institutes of Electrical Communication (RIEC), Tohoku University, Miyagi 980-8577 (Japan)

    2014-05-07T23:59:59.000Z

    To realize a granular film composed of L1{sub 0}-FePt grains with high uniaxial magnetic anisotropy energy, K{sub u}, and segregants for heat-assisted magnetic recording, the FePt-TiO{sub 2}/FePt-C stacked film was investigated. The FePt-TiO{sub 2}/FePt-C stacked film has well-isolated granular structure with average grain size of 6.7?nm because the FePt-TiO{sub 2} film follows the FePt-C template film in microstructural growth. However, the K{sub u} value is quite low for total thickness of 9?nm: 5?×?10{sup 6} erg/cm{sup 3}. Exploration of the thickness dependence of L1{sub 0}-FePt(001) peaks in XRD spectra and cross-sectional TEM images suggest that degradation of the L1{sub 0} ordering appears near the middle of the FePt-TiO{sub 2} layer. The EDX-STEM mapping reveals that Ti atoms exist within the FePt grains in addition to the grain boundary. This indicates the possibility that TiO{sub 2} tends to be incorporated into the FePt grains and that it prevents L1{sub 0}-ordering of the FePt grains along the normal-to-plane direction.

  1. Challenges in synthesizing carbon-coated LiFePO4 nanoparticles from hydrous FePO4 and their electrochemical properties

    E-Print Network [OSTI]

    Park, Byungwoo

    Challenges in synthesizing carbon-coated LiFePO4 nanoparticles from hydrous FePO4 properties A B S T R A C T Carbon-coated LiFePO4 nanoparticles are obtained from a polymer-coated hydrous Fe polymer additives which are subsequently carbonized by calcination [14­19]. Carbon-coated LiFePO4

  2. FT-ICR SWNTs Co/Fe FT-ICR Mass Spectroscopy and Initial Reaction of Co/Fe Mixed Clusters

    E-Print Network [OSTI]

    Maruyama, Shigeo

    FT-ICR SWNTs Co/Fe FT-ICR Mass Spectroscopy and Initial Reaction of Co/Fe Mixed Clusters Used, for FenCoN-n + (N ) 2 (b) (Fe : Co = 0.514 : 0.486) 3 Fe2FeCoCo2 Corbett(3) Li Na 112 116 120 Mass (amu

  3. Nitrogen addition to bcc-Fe by attrition milling

    SciTech Connect (OSTI)

    Rawers, J.; Krabbe, R.; Cook, D.

    1999-01-01T23:59:59.000Z

    To enhance the nitrogen solubility in bcc-Fe, iron powder and blends of iron and iron nitride powders were attrition-milled in nitrogen gas. X-ray diffraction and Moessbauer spectroscopy were used to characterize the milled microstructure and to characterize the nitrogen distribution. After processing for 150 hours, the infused nitrogen was determined to be interstitial (locally deforming the bcc-Fe lattice to a bct-Fe lattice) and associated with the outer layer of the bcc-Fe nanograin. Nitrogen stabilized the milled grain structure but at elevated temperatures rapidly came to thermodynamical equilibrium, transforming from bcc-Fe(N) to bcc-Fe and Fe{sub 4}N.

  4. Speciation of Fe in ambient aerosol and cloudwater

    SciTech Connect (OSTI)

    Siefert, L. [California Institute of Technology, Pasadena, CA (United States)

    1996-08-15T23:59:59.000Z

    Atmospheric iron (Fe) is thought to play an important role in cloudwater chemistry (e.g., S(IV) oxidation, oxidant production, etc.), and is also an important source of Fe to certain regions of the worlds oceans where Fe is believed to be a rate-limiting nutrient for primary productivity. This thesis focuses on understanding the chemistry, speciation and abundance of Fe in cloudwater and aerosol in the troposphere, through observations of Fe speciation in the cloudwater and aerosol samples collected over the continental United States and the Arabian Sea. Different chemical species of atmospheric Fe were measured in aerosol and cloudwater samples to help assess the role of Fe in cloudwater chemistry.

  5. Effect of nitrogen upon structural and magnetic properties of FePt in FePt/AlN multilayer structures

    SciTech Connect (OSTI)

    Gao, Tenghua, E-mail: gao.t.ab@m.titech.ac.jp; Zhang, Cong; Sannomiya, Takumi; Muraishi, Shinji; Nakamura, Yoshio; Shi, Ji [Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2-12-1 Oh-okayama, Meguro-ku, Tokyo 152-8552 (Japan)

    2014-09-01T23:59:59.000Z

    This paper investigates the effect of the addition of nitrogen in FePt layers for ultrathin FePt/AlN multilayer structures. X-ray diffraction results reveal that a compressive stress relaxation occurs after annealing owing to the release of interstitial nitrogen atoms in the FePt layers. The introduction of nitrogen also induces a large in-plane compressive strain during grain growth not seen in FePt deposited without nitrogen. This strain is considered to decrease the driving force for (111) grain growth and FePt ordering.

  6. Proteome of Geobacter sulfurreducens grown with Fe(III) oxide or Fe(III) citrate as the electron acceptor.

    SciTech Connect (OSTI)

    Ding, Y-H R.; Hixson, Kim K.; Aklujkar, Ma; Lipton, Mary S.; Smith, Richard D.; Lovley, Derek R.; Mester, Tunde

    2008-12-01T23:59:59.000Z

    e(III) oxides are the most abundant source of reducible Fe(III) by microorganisms in most soils and sediments, yet few studies on the physiology of Fe(III)-reducing microorganisms during growth on Fe(III) oxide have been conducted because of the technical difficulties in working with cell growth and harvest in the presence of Fe(III) oxides. Geobacter sulfurreducens is a representative of the Geobacter species that predominate in a variety of subsurface environments in which Fe(III) oxide is important. In order to better understand the physiology of Geobacter species during growth on Fe(III) oxide, the proteome of G. sulfurreducens grown on Fe(III) oxide was compared with the proteome of cells grown with soluble Fe(III) citrate. Two-dimensional polyacrylamide gel electrophoresis (2-D PAGE) revealed 19 proteins that were more abundant during growth on Fe(III) oxide than on soluble Fe(III). These included proteins related to protein synthesis, electron transfer and energy production, oxidative stress, protein folding, outer membrane proteins, nitrogen metabolism and hypothetical proteins. Further analysis of the proteome with the accurate mass and time (AMT) tag method revealed additional proteins associated with growth on Fe(III) oxide. These included the outer-membrane c-type cytochrome, OmcS and OmcG, which genetic studies have suggested are required for Fe(III) oxide reduction. Furthermore, several other cytochromes, as yet unstudied, were detected to be significantly up regulated during growth on Fe(III) oxide and other proteins of unknown function were more abundant during growth on Fe(III) oxide than on soluble Fe(III). PilA, the structural protein for pili, which is required for Fe(III) oxide reduction, and other pilin-associated proteins were also more abundant during growth on Fe(III) oxide. Confirmation of the differential expression of proteins known to be important in Fe(III) oxide reduction was observed, and an additional number of previously unidentified proteins were found with significant abundance in the cells grown under conditions of Fe(III) oxide reduction.

  7. Activation of the S-H Group in Fe(µ2-SH)Fe Clusters: S-H Bond Strengths and Free Radical Reactivity of the Fe(µ2-SH)Fe Cluster

    SciTech Connect (OSTI)

    Franz, James A.; Lee, Suh-Jane; Bowden, Thomas A.; Alnajjar, Mikhail S.; Appel, Aaron M.; Birnbaum, Jerome C.; Bitterwolf, Thomas E.; Dupuis, Michel

    2009-10-28T23:59:59.000Z

    Absolute rate constants were determined for the abstraction of hydrogen atom from (OC)3Fe(?-SH)2Fe(CO)3 (Fe2S2H2) and (OC)3Fe(?-SCH3)(?-SH)Fe(CO)3 (Fe2S2MeH) by benzyl radical in benzene. From the temperature dependent rate data for Fe2S2H2, ?H‡ and ?S‡ were determined to be 2.03 ? 0.56 kcal/mol and 19.3 ? 1.7 cal/mol K, respectively, giving kabs = 1.2 ? 107 M 1 s 1 at 25?C. For Fe2S2MeH, ?H‡ and ?S‡ were determined to be 1.97 ? 0.46 kcal/mol and 18.1 ? 1.5 cal/mol K, respectively, giving kabs = 2.3 ? 107 M 1 s 1 at 25?C. Temperature dependent rate data are also reported for hydrogen atom abstraction by benzyl radical from thiophenol (?H‡ = 3.62 ? 0.43 kcal/mol, ?S‡ = 21.7 ? 1.3 cal/mol K) and H2S (?H‡ = 5.13 ? 0.99 kcal/mol, ?S‡ = 24.8 ? 3.2 cal/mol K), giving kabs at 25?C of 2.5 ? 105 and 4.2 ? 103 M 1 s 1, respectively. DFT calculations predict S-H bond strengths of 73.1 and 73.2 kcal/mol for Fe2S2H2 and Fe2S2MeH, respectively. Free energy and NMR chemical shift calculations confirm the NMR assignments and populations of Fe2S2H2 and Fe2S2MeH isomers. Derived radicals Fe2S2H• and Fe2S2Me• exhibit singly occupied HOMOs with unpaired spin density distributed between the two Fe atoms, a bridging sulfur, and d?-bonding between Fe centers. The S-H solution bond dissociation free energy (SBDFE) of Fe2S2MeH was found to be 69.4 ± 1.7 kcal/mol by determination of its pKa (16.0 ± 0.4) and the potential for the oxidation of the anion, Fe2S2Me- of 0.26 ± 0.05 V vs. ferrocene in acetonitrile (corrected for dimerization of Fe2S2Me•). This SBDFE for Fe2S2MeH corresponds to a gas phase bond dissociation enthalpy (BDE) of 74.2 kcal/mol, in satisfactory agreement with the DFT value of 73.2 kcal/mol. Replacement of the Fe-Fe bond in Fe2S2MeH with bridging ?-S (Fe2S3MeH) or ?-CO (Fe2S2(CO)MeH) groups leads to (DFT) BDEs of 72.8 and 66.2 kcal/mol, the latter indicating dramatic effects of choice of bridge structure on S-H bond strengths. These results provide a model for the reactivity of hydrosulfido sites of low-valent heterogeneous FeS catalysts. This work was supported by the US Department of Energy's Office of Basic Energy Sciences, Chemical Sciences program. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  8. MAS NMR Study of the Metastable Solid Solutions Found in the LiFePO4/FePO4 System

    E-Print Network [OSTI]

    Cabana, Jordi

    2010-01-01T23:59:59.000Z

    compared to the lithium-electron interaction in x Li FeP04 (by Fermi contact interactions between the lithium ions andlithium ions in LiFePC^ suggests a modification of the Fe -O-P interaction.

  9. Overview of the development of FeAl intermetallic alloys

    SciTech Connect (OSTI)

    Maziasz, P.J.; Liu, C.T.; Goodwin, G.M.

    1995-09-01T23:59:59.000Z

    B2-phase FeAl ordered intermetallic alloys based on an Fe-36 at.% Al composition are being developed to optimize a combination of properties that includes high-temperature strength, room-temperature ductility, and weldability. Microalloying with boron and proper processing are very important for FeAl properties optimization. These alloys also have the good to outstanding resistance to oxidation, sulfidation, and corrosion in molten salts or chlorides at elevated temperatures, characteristic of FeAl with 30--40 at.% Al. Ingot- and powder-metallurgy (IM and PM, respectively) processing both produce good properties, including strength above 400 MPa up to about 750 C. Technology development to produce FeAl components for industry testing is in progress. In parallel, weld-overlay cladding and powder coating technologies are also being developed to take immediate advantage of the high-temperature corrosion/oxidation and erosion/wear resistance of FeAl.

  10. Microsoft Word - FeVI.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighandSWPA / SPRA / USACE SWPAURTeC:8CO6 Figure 1. Proposed Fe(VI)-nitrido

  11. FE Categorical Exclusions | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdf FAR27.pdfEnclosureFE

  12. FE Petroleum Reserves News | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdfFE DOCKET NO.Oil

  13. FE Clean Energy Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOEHazelPennsylvania: EnergyExolis Energy JumpFAC 04-08 Jump to:FC3 Group JumpFE

  14. FE Oil and Natural Gas News

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube|6721 FederalTexasManager FAQS Reference Guide -September 30,Clean CoalFE

  15. Isolation and microbial reduction of Fe(III) phyllosilicates...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to conditions similar to that in the pristine sediment. The extent of microbial (Geobacter sulfurreducens) reduction of Fe(III) phyllosilicates isolated by CDB extraction (ca....

  16. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    aging, etc. deer09devarakonda.pdf More Documents & Publications The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst CLEERS Aftertreatment Modeling and...

  17. Competing retention pathways of uranium upon reaction with Fe...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upon reaction with Fe(II). Abstract: Biogeochemical retention processes, including adsorption, reductive precipitation, and incorporation into host minerals, are important in...

  18. Anisotropic scattering rate in Fe-substituted Bi 2 Sr 2 Ca ( Cu 1 - x Fe x ) 2 O 8 + ?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Naamneh, M.; Lubashevsky, Y.; Lahoud, E.; Gu, G. D.; Kanigel, A.

    2015-05-01T23:59:59.000Z

    We measured the electronic structure of Fe-substituted Bi2212 using angle-resolved photoemission spectroscopy. We find that the substitution does not change the momentum dependence of the superconducting gap but induces a very anisotropic enhancement of the scattering rate. A comparison of the effect of Fe substitution to that of Zn substitution suggests that the Fe reduces Tc so effectively because it suppresses very strongly the coherence weight around the antinodes.

  19. Modified embedded-atom method interatomic potential for the Fe-Cu alloy system and cascade simulations on pure Fe and Fe-Cu alloys

    SciTech Connect (OSTI)

    Lee, Byeong-Joo [Department of Materials Science and Engineering, Pohang University of Science and Technology Pohang 790-784 (Korea, Republic of); Wirth, Brian D. [Nuclear Engineering Department, University of California, Berkeley, Berkeley, California 94720-1730 (United States); Shim, Jae-Hyeok [Nuclear Engineering Department, University of California, Berkeley, Berkeley, California 94720-1730 (United States); Nano-Materials Research Center, Korea Institute of Science and Technology Seoul 136-791 (Korea, Republic of); Kwon, Junhyun; Kwon, Sang Chul; Hong, Jun-Hwa [Nuclear Materials Technology R and D Team, Korea Atomic Energy Research Institute, Taejon 305-353 (Korea, Republic of)

    2005-05-01T23:59:59.000Z

    A modified embedded-atom method (MEAM) interatomic potential for the Fe-Cu binary system has been developed using previously developed MEAM potentials of Fe and Cu. The Fe-Cu potential was determined by fitting to data on the mixing enthalpy and the composition dependencies of the lattice parameters in terminal solid solutions. The potential gives a value of 0.65 eV for the dilute heat of solution and reproduces the increase of lattice parameter of Fe with addition of Cu in good agreement with experiments. The potential was used to investigate the primary irradiation defect formation in pure Fe and Fe-0.5 at. % Cu alloy by a molecular dynamics cascade simulation study with a PKA energy of 2 keV at 573 K. A tendency for self-interstitial atom-Cu binding, the formation of mixed (Fe-Cu) dumbbells and even Cu-Cu dumbbells was observed. Given a positive binding energy between Cu atoms and self-interstitials, Cu transport by an interstitial diffusion mechanism could be proposed to contribute to the formation of Cu-rich precipitates and irradiation-induced embrittlement in nuclear structural steels.

  20. Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition

    E-Print Network [OSTI]

    Sklenak, Stepan

    Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brřnsted

  1. Bulk FePt/Fe3Pt nanocomposite magnets prepared by spark plasma Chuan-Bing Rong, Vikas Nandwana, Narayan Poudyal, and J. Ping Liua

    E-Print Network [OSTI]

    Liu, J. Ping

    Bulk FePt/Fe3Pt nanocomposite magnets prepared by spark plasma sintering Chuan-Bing Rong, Vikas nanocomposite magnets from nano- particles remains a great challenge. Spark plasma sintering SPS is known as one; published online 27 April 2007 FePt/Fe3Pt bulk nanocomposite magnets have been prepared by the spark plasma

  2. Fe(III) Oxide Reactivity Toward Biological versus Chemical

    E-Print Network [OSTI]

    Roden, Eric E.

    amorphous materials, such as ferrihydrite, to well-crystallized minerals such as goethite and hematite (5 assemblages. Experimental Section Oxide Synthesis and Characterization.A variety of synthetic Fe(III) oxides included a series of goethites with differing crystallinity and surface area, synthesized from Fe(NO3

  3. CONTROL OF FE(III) SITE OCCUPANCY ON THE RATE AND EXTENT OF MICROBIAL...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONTROL OF FE(III) SITE OCCUPANCY ON THE RATE AND EXTENT OF MICROBIAL REDUCTION OF FE(III) IN NONTRONITE. CONTROL OF FE(III) SITE OCCUPANCY ON THE RATE AND EXTENT OF MICROBIAL...

  4. Insights into the Mechanism of Fe(II) Adsorption and Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mechanism of Fe(II) Adsorption and Oxidation at Fe-Clay Mineral Surfaces from First-Principles Calculations. Insights into the Mechanism of Fe(II) Adsorption and Oxidation at...

  5. Synthesis and Photoexcited Charge Carrier Dynamics of beta-FeOOH...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photoexcited Charge Carrier Dynamics of beta-FeOOH Nanorods. Synthesis and Photoexcited Charge Carrier Dynamics of beta-FeOOH Nanorods. Abstract: Akaganeite(B-FeOOH) nanorods of...

  6. Oxygen Plasma Activation of Cr(CO)(6) on ?-Fe2O3(0001)...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on ?-Fe2O3(0001). Abstract: The chemistry of Cr(CO)6 on the Fe3O4(111) surface termination of ?-Fe2O3(0001) was explored using temperature programmed desorption (TPD),...

  7. Water Adsorption, Desorption, and Clustering on FeO(111). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Adsorption, Desorption, and Clustering on FeO(111). Water Adsorption, Desorption, and Clustering on FeO(111). Abstract: The adsorption of water on FeO(111) is investigated using...

  8. Kinetics of Fe(II)-catalyzed transformation of 6-line ferrihydrite under anaerobic flow conditions

    E-Print Network [OSTI]

    Yang, L.

    2010-01-01T23:59:59.000Z

    transformation to goethite via the Fe(II) pathway. Am.ferrihydrite, and goethite. Geochim. Cosmochim. Acta 2001,between Aqueous Fe(II) and Goethite: An Fe Isotope Tracer

  9. Anharmonic phonons and magnons in BiFeO3

    SciTech Connect (OSTI)

    Delaire, Olivier A [ORNL; Ma, Jie [ORNL; Stone, Matthew B [ORNL; Huq, Ashfia [ORNL; Gout, Delphine J [ORNL; Brown, Craig [National Institute of Standards and Technology (NIST); Wang, Kefeng [Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing; Ren, Zhifeng [Boston College, Chestnut Hill

    2012-01-01T23:59:59.000Z

    The phonon density of states (DOS) and magnetic excitation spectrum of polycrystalline BiFeO3 were measured for temperatures 200 < T < 750K , using inelastic neutron scattering (INS). Our results indicate that the magnetic spectrum of BiFeO3 closely resembles that of similar Fe perovskites, such as LaFeO3, despite the cycloid modulation in BiFeO3. We do not find any evidence for a spin gap. A strong T-dependence of the phonon DOS was found, with a marked broadening of the whole spectrum, providing evidence of strong anharmonicity. This anharmonicity is corroborated by large amplitude motions of Bi and O ions observed with neutron diffraction. These results highlight the importance of spin-phonon coupling in this material.

  10. Microbial Reduction of Fe(III) in the Fithian and Muloorina Illites...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fe(III) in the Fithian and Muloorina Illites : Contrasting Extents and Rates of Bioreduction. Microbial Reduction of Fe(III) in the Fithian and Muloorina Illites : Contrasting...

  11. Heterogeneous Reduction of U6+ by Structural Fe2+ From Theory...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U6+ by Structural Fe2+ From Theory and Experiment. Heterogeneous Reduction of U6+ by Structural Fe2+ From Theory and Experiment. Abstract: Computational and experimental studies...

  12. Fine structure of Fe-Co-Ga and Fe-Cr-Ga alloys with low Ga content

    SciTech Connect (OSTI)

    Kleinerman, Nadezhda M., E-mail: kleinerman@imp.uran.ru; Serikov, Vadim V., E-mail: kleinerman@imp.uran.ru; Vershinin, Aleksandr V., E-mail: kleinerman@imp.uran.ru; Mushnikov, Nikolai V., E-mail: kleinerman@imp.uran.ru; Stashkova, Liudmila A., E-mail: kleinerman@imp.uran.ru [Institute of Metal Physics UB RAS, S. Kovalevskaya str. 18, 620990 Ekaterinburg (Russian Federation)

    2014-10-27T23:59:59.000Z

    Investigation of Ga influence on the structure of Fe-Cr and Fe-Co alloys was performed with the use of {sup 57}Fe Mössbauer spectroscopy and X-ray diffraction methods. In the alloys of the Fe-Cr system, doping with Ga handicaps the decomposition of solid solutions, observed in the binary alloys, and increases its stability. In the alloys with Co, Ga also favors the uniformity of solid solutions. The analysis of Mössbauer experiments gives some grounds to conclude that if, owing to liquation, clusterization, or initial stages of phase separation, there exist regions enriched in iron, some amount of Ga atoms prefer to enter the nearest surroundings of iron atoms, thus forming binary Fe-Ga regions (or phases)

  13. Epitaxial Fe3-xTixO4 films from magnetite to ulvöspinel by pulsed laser deposition

    E-Print Network [OSTI]

    Droubay, T.C.

    2012-01-01T23:59:59.000Z

    Fe O Fig. 1. Droubay et al. PRB Intensity (Counts) Fe 2 TiOdeg) Fig. 2. Droubay et al. PRB Fe 2p 3/2 Intensity Fe 2peV) Fig. 3. Droubay et al. PRB Fe 2.75 Ti 0.25 O 4 Fe 2.50

  14. Pulsed-electron-beam melting of Fe

    SciTech Connect (OSTI)

    Knapp, J.A.; Follstaedt, D.M.

    1981-01-01T23:59:59.000Z

    Pulsed (50 nsec) electron beams with deposited energies of 1.1 to 2.3 J/cm/sup 2/ have been used to rapidly melt a surface layer of Fe. Calculations show that this range of energies produces melt depths from 0.4 to 1.2 ..mu..m and melt times of 100 to 500 nsec. Optical microscopy and SEM of pulse treated polycrystalline foils show slip traces, as well as a general smoothing of surface features which shows that melting has occurred. TEM shows that the resolidified material is bcc, and that the material within a grain is epitaxial with the substrate. TEM also shows slip traces along (110) planes, as well as a high density of dislocations, both extended and loop. At the highest energy, subgrain boundaries are observed. Some samples were implanted with 1 x 10/sup 16/ Sn/cm/sup 2/ at 150 keV. After pulse treatment, the Sn depth profile was observed to have broadened, consistent with liquid phase diffusion. The Sn had the unexpected effect of suppressing slip at the sample surface.

  15. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RPSEA Sugarland, TX CSI Technologies, LLC. Possible Pad locations covered by this CX Form include Conway, Faulkner, Cleburne, Pope, White, and Van Buren counties, Arkansas...

  16. asymmetric hydraulic fracture: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the fractured shale 17 RPSEA UNCONVENTIONAL GAS CONFERENCE 2012: Geology, the Environment, Hydraulic Fracturing Engineering Websites Summary: Fracturing Experiment Overview...

  17. advanced hydraulic fracturing: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the fractured shale 18 RPSEA UNCONVENTIONAL GAS CONFERENCE 2012: Geology, the Environment, Hydraulic Fracturing Engineering Websites Summary: Fracturing Experiment Overview...

  18. Feasibility of band gap engineering of pyrite FeS?

    E-Print Network [OSTI]

    Sun, Ruoshi

    We use first-principles computations to investigate whether the band gap of pyrite FeS? can be increased by alloying in order to make it a more effective photovoltaic material. In addition to the isostructural compounds ...

  19. Hydrogen-Vacancy Interactions in Fe-C Alloys

    E-Print Network [OSTI]

    Yip, Sidney

    Energetics and concentrations of hydrogen-containing point defect clusters (PDCs) in Fe-C alloys are calculated and cast into a PDC dominance diagram. Because of the strong binding effects of iron vacancies on the stability ...

  20. Simulated magnetization reversal in Fe nanopillar S. H. Thompson

    E-Print Network [OSTI]

    Weston, Ken

    Simulated magnetization reversal in Fe nanopillar S. H. Thompson Florida State University and Center for Materials Research and Technology. 1 S. H. Thompson, G. Brown, and P. A. Rikvold, J. Appl

  1. Clean Energy- FE Dkt No. 14-54-LNG (FTA)

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application filed on March 18, 2014, by Clean Energy, requesting blanket authorization to engage in...

  2. PRECIPITATION-STRENGTHENED AUSTENITIC FE-MN-TI ALLOYS

    E-Print Network [OSTI]

    Chiang, K.-M.

    2010-01-01T23:59:59.000Z

    energy spectrums showing that precipitates are rich in titanium, andtitanium additions can reduce the austenitic stacking fault energyfault energy of the Fe-Mn austenite is lowered by titanium

  3. fe0013531-Oregon-State | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DE-FE0013531 Goal The goal of this project is to study the biogeochemical response of the gas hydrate system on the Svalbard margin to environmental change. Performer Oregon State...

  4. Fe-CYCLE BACTERIA FROM INDUSTRIAL CLAYS MINED IN GEORGIA, USA EVGENYA S. SHELOBOLINA

    E-Print Network [OSTI]

    Lovley, Derek

    Fe-CYCLE BACTERIA FROM INDUSTRIAL CLAYS MINED IN GEORGIA, USA EVGENYA S. SHELOBOLINA 1, *,{, SAM M are major discoloring impurities in mined commercial white kaolin clay. In order to evaluate the potential influence of Fe-cycle bacteria on Fe cycling during post- depositional clay-weathering alteration, Fe

  5. NITRIDATION EFFECTS ON THE OXIDATION MECHANISMS OF AN ODS FeAl INTERMETALLIC ALLOY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    NITRIDATION EFFECTS ON THE OXIDATION MECHANISMS OF AN ODS FeAl INTERMETALLIC ALLOY F. Pedraza*, J-mail: fpedraza@univ-lr.fr Abstract An ODS FeAl intermetallic alloy has been nitrided at low-energy high flux of an ODS FeAl alloy have been discussed [13], indicating the formation of AlN and again of -Fe after

  6. Demonstration of Security Benefits of Renewable Generation at FE Warren Air Force Base

    SciTech Connect (OSTI)

    Warwick, William M.; Myers, Kurt; Seifert, Gary

    2010-12-31T23:59:59.000Z

    Report detailing field demonstration of security benefits of renewable generation at FE Warren Air Force Base.

  7. Determination of the stellar (n,$\\gamma$) cross section of $^{54}Fe$ with accelerator mass spectrometry

    E-Print Network [OSTI]

    Coquard, L; Dillmann, I; Wallner, A; Knie, K; Kutschera, W

    2006-01-01T23:59:59.000Z

    Determination of the stellar (n,$\\gamma$) cross section of $^{54}Fe$ with accelerator mass spectrometry

  8. A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics

    E-Print Network [OSTI]

    Chi, Ji

    2009-05-15T23:59:59.000Z

    Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

  9. Structural and electronic properties of Fe3+ in GaN from optical and EPR experiments

    E-Print Network [OSTI]

    Nabben, Reinhard

    into GaN to compensate inherent n-type conductivity and to produce semi-insulating substrate materialStructural and electronic properties of Fe3+ and Fe2+ centers in GaN from optical and EPR, and electronic properties of Fe-doped GaN. A set of high-quality GaN crystals doped with Fe at concentrations

  10. Mössbauer investigations of hyperfine interactions features of {sup 57}Fe nuclei in BiFeO{sub 3} ferrite

    SciTech Connect (OSTI)

    Sobolev, Alexey, E-mail: salex12@rambler.ru; Presniakov, Igor, E-mail: salex12@rambler.ru; Rusakov, Vyacheslav, E-mail: salex12@rambler.ru; Matsnev, Mikhail; Gorchakov, Dmitry; Glazkova, Iana [Lomonosov Moscow State University, 119991, Moscow (Russian Federation); Belik, Alexey [International Center for Materials Nanoarchitectonics (MANA), National Institute for Material Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044 (Japan)

    2014-10-27T23:59:59.000Z

    New results of {sup 57}Fe Mössbauer studies on BiFeO{sub 3} powder sample performed at various temperatures above and below magnetic phase transitions point T{sub N} ? 640K are reported. We have performed self-consistent calculations of the lattice contributions to the EFG tensor, taking into account dipole moments of the O{sup 2?} and Bi{sup 3+} ions. Low-temperature {sup 57}Fe Mössbauer spectra recorded at T < T{sub N} were analyzed assuming an anharmonic cycloidal modulation of the Fe{sup 3+} magnetic moments. The cycloidal modulation of the iron spin was described with the elliptic Jacobi function sn[(±4K(m)/?)x,m]. The good fit of the experimental spectra was obtained for the anharmonicity m = 0.44 ± 0.04 (T = 4.9K) resulting from the easy-axis magnetic anisotropy.

  11. Heterogeneous Reduction of PuO2 with Fe(II): Importance of the Fe(III) Reaction Product

    SciTech Connect (OSTI)

    Felmy, Andrew R.; Moore, Dean A.; Rosso, Kevin M.; Qafoku, Odeta; Rai, Dhanpat; Buck, Edgar C.; Ilton, Eugene S.

    2011-05-01T23:59:59.000Z

    Abstract Heterogeneous reduction of actinides in higher and more soluble oxidation states to lower more insoluble oxidation states by reductants such as Fe(II) has been the subject of intensive study for more than two decades. However, Fe(II)-induced reduction of sparingly soluble Pu(IV) to the more soluble lower oxidation state Pu(III) has been much less studied even though such reactions can potentially increase the mobility of Pu in the subsurface. Thermodynamic calculations are presented that show how differences in the free energy of various possible solid-phase Fe(III) reaction products can greatly influence aqueous Pu(III) concentrations resulting from reduction of PuO2(am) by Fe(II). We present the first experimental evidence that reduction of PuO2(am) to Pu(III) by Fe(II) was enhanced when the Fe(III) mineral goethite was spiked into the reaction. The effect of goethite on reduction of Pu(IV) was demonstrated by measuring the time-dependence of total aqueous Pu concentration, its oxidation state, and system pe/pH. We also re-evaluated established protocols for determining Pu(III) [(Pu(III) + Pu(IV)) - Pu(IV)] by using thenoyltrifluoroacetone (TTA) in toluene extractions; the study showed that it is important to eliminate dissolved oxygen from the TTA solutions for accurate determinations. More broadly, this study highlights the importance of the Fe(III) reaction product in actinide reduction rate and extent by Fe(II).

  12. Composition-Mediated Order-Disorder Transformation in FePt Nanoparticles

    SciTech Connect (OSTI)

    Johnston-Peck, Aaron C [ORNL; Cullen, David A [ORNL; Tracy, Joseph B [North Carolina State University

    2013-01-01T23:59:59.000Z

    Thumbnail image of graphical abstract Heat-treated alloy FePt nanoparticles transform into L10 FePt and mixed L10/L12 FePt3 intermetallic phases. Enrichment in Pt in some nanoparticles, rather than intrinsic thermodynamic effects, drives phase segregation. FePt nanoparticles of uniform, equimolar composition are expected to transform into phase-pure, highly ordered L10 FePt nanoparticles.

  13. N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes 

    E-Print Network [OSTI]

    Chiang, Chao-Yi

    2006-08-16T23:59:59.000Z

    model complexes I have examined the fundamental properties of a dithiolato-Fe(NO)2 complex, bismercaptoethandiazacyclooctane iron dinitrosyl or (H+bme-daco)Fe(NO)2 as a biomimic of dicysteinate coordination of [Fe(NO)2]. This complex was prepared...

  14. PHYSICAL REVIEW B 83, 104526 (2011) Fe Mossbauer study of magnetic ordering in superconducting K0.80Fe1.76Se2.00 single crystals

    E-Print Network [OSTI]

    Ryan, Dominic

    2011-01-01T23:59:59.000Z

    PHYSICAL REVIEW B 83, 104526 (2011) 57 Fe M¨ossbauer study of magnetic ordering in superconducting 31 March 2011) The magnetic ordering of superconducting single crystals of K0.80Fe1.76Se2.00 has been studied between 10 and 550 K using 57 Fe M¨ossbauer spectroscopy. Despite being superconducting below Tsc

  15. N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes

    E-Print Network [OSTI]

    Chiang, Chao-Yi

    2006-08-16T23:59:59.000Z

    model complexes I have examined the fundamental properties of a dithiolato-Fe(NO)2 complex, bismercaptoethandiazacyclooctane iron dinitrosyl or (H+bme-daco)Fe(NO)2 as a biomimic of dicysteinate coordination of [Fe(NO)2]. This complex was prepared...

  16. Dual and Triple Ion-Beam Irradiations of Fe, Fe(Cr) and Fe(Cr)-ODS Final Report: IAEA SMoRE CRP

    SciTech Connect (OSTI)

    Fluss, M J; Hsiung, L L; Marian, J

    2011-11-20T23:59:59.000Z

    Structures of nanoparticles in Fe-16Cr-4.5Al-0.3Ti-2W-0.37Y2O3 (K3) and Fe-20Cr-4.5Al-0.34Ti-0.5Y2O3 (MA956) oxide dispersion strengthened (ODS) ferritic steels produced by mechanical alloying (MA) and followed by hot extrusion have been studied using high-resolution transmission electron microscopy (HRTEM) techniques to gain insight about the formation mechanism of nanoparticles in MA/ODS steels. The observations of Y-Al-O complex-oxide nanoparticles in both ODS steels imply that decomposition of Y2O3 in association with internal oxidation of Al occurred during mechanical alloying. While the majority of oxide nanoparticles formed in both steels is Y4Al2O9, a few oxide particles of YAlO3 are also occasionally observed. These results reveal that Ti (0.3 wt %) plays an insignificant role in forming oxide nanoparticles in the presence of Al (4.5 wt %). HRTEM observations of crystalline nanoparticles larger than {approx}2 nm and amorphous or disordered cluster domains smaller than {approx}2 nm provide an insight into the formation mechanism of oxide nanoparticle in MA/ODS steels, which we believe from our observations involves a solid-state amorphous precursor followed by recrystallization. Dual ion-beam irradiations using He{sup +} + Fe{sup +8} ions were employed to gain more detailed insight about the role of nanoparticles in suppressing radiation-induced swelling. This is elaborated through TEM examinations of cavity distributions in ion-irradiated Fe-14Cr and K3-ODS ferritic steels. HRTEM observations of helium-filled cavities (helium bubbles) preferably trapped at nanoscale oxide particles and clusters in ion-irradiated K3-ODS are presented. Finally, we describe the results from triple ion-beam irradiations using H{sup +} + He{sup +} + Fe{sup +8} ions to emulate fusion first wall radiation effects. Preliminary work is reported that confirms the existence of significant hydrogen synergistic effects described earlier by Tanaka et al., for Fe(Cr) and by Wakai et al., for F82H reduced activation ferritic martensitic (RAF/M) steel. These previous results combined with our data suggest a complex new 'catalytic' mechanism whereby H interacts with the steady state population of defects and the embryonic cavities so as to accelerated cavity (void) growth in both Fe(Cr) and under special conditions in ODS steels.

  17. Unique Properties of Lunar Impact Glass: Nanophase Metallic Fe Synthesis

    SciTech Connect (OSTI)

    Liu, Yang [University of Tennessee, Knoxville (UTK); Taylor, Lawrence A. [University of Tennessee, Knoxville (UTK); Thompson, James R [ORNL; Schnare, Darren W. [University of Tennessee, Knoxville (UTK); Park, Jae-Sung [University of Tennessee, Knoxville (UTK)

    2007-01-01T23:59:59.000Z

    Lunar regolith contains important materials that can be used for in-situ resource utilization (ISRU) on the Moon, thereby providing for substantial economic savings for development of a manned base. However, virtually all activities on the Moon will be affected by the deleterious effects of the adhering, abrasive, and pervasive nature of lunar dust (<20 {micro}m portion of regolith, which constitutes {approx}20 wt% of the soil). In addition, the major impact-produced glass in the lunar soil, especially agglutinitic glass (60-80 vol% of the dust), contains unique nanometer-sized metallic Fe (np-Fe{sup 0}), which may pose severe pulmonary problems for humans. The presence of the np-Fe0 imparts considerable magnetic susceptibility to the fine portion of the lunar soil, and dust mitigation techniques can be designed using these magnetic properties. The limited availability of Apollo lunar soils for ISRU research has made it necessary to produce materials that simulate this unique np-Fe{sup 0} property, for testing different dust mitigation methods using electromagnetic fields, and for toxicity studies of human respiratory and pulmonary systems, and for microwave treatment of lunar soil to produce paved roads, etc. A method for synthesizing np-Fe{sup 0} in an amorphous silica matrix is presented here. This type of specific simulant can be used as an additive to other existing lunar soil simulants.

  18. Fe-doped InN layers grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Wang Xinqiang; Liu Shitao; Ma Dingyu; Zheng Xiantong; Chen Guang; Xu Fujun; Tang Ning; Shen Bo [State Key Laboratory of Artificial Microstructure and Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Zhang Peng; Cao Xingzhong; Wang Baoyi [State Key Laboratory of Nuclear Analysis Techniques, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Huang Sen; Chen, Kevin J. [Department of Electronic and Computer Engineering, Hong Kong University of Science and Technology (Hong Kong); Zhou Shengqiang [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), 01314 Dresden (Germany); Yoshikawa, Akihiko [Center for SMART Green Innovation Research, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522 (Japan)

    2012-10-22T23:59:59.000Z

    Iron(Fe)-doped InN (InN:Fe) layers have been grown by molecular beam epitaxy. It is found that Fe-doping leads to drastic increase of residual electron concentration, which is different from the semi-insulating property of Fe-doped GaN. However, this heavy n-type doping cannot be fully explained by doped Fe-concentration ([Fe]). Further analysis shows that more unintentionally doped impurities such as hydrogen and oxygen are incorporated with increasing [Fe] and the surface is degraded with high density pits, which probably are the main reasons for electron generation and mobility reduction. Photoluminescence of InN is gradually quenched by Fe-doping. This work shows that Fe-doping is one of good choices to control electron density in InN.

  19. Single-crystal epitaxial thin films of SrFeO{sub 2} with FeO{sub 2} 'infinite layers'

    SciTech Connect (OSTI)

    Inoue, Satoru; Kawai, Masanori; Shimakawa, Yuichi [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Mizumaki, Masaichiro; Kawamura, Naomi [Japan Synchrotron Radiation Research Institute/SPring-8, Sayo, Hyogo 679-5198 (Japan); Watanabe, Takashi; Tsujimoto, Yoshihiro; Kageyama, Hiroshi; Yoshimura, Kazuyoshi [Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502 (Japan)

    2008-04-21T23:59:59.000Z

    Single-crystal thin films of SrFeO{sub 2}, which is an oxygen-deficient perovskite with ''infinite layers'' of Fe{sup 2+}O{sub 2}, were prepared by using CaH{sub 2} for low-temperature reduction of epitaxial SrFeO{sub 2.5} single-crystal films deposited on KTaO{sub 3} substrates. This reduction process, removing oxygen ions from the perovskite structure framework and causing rearrangements of oxygen ions, topotactically transforms the brownmillerite SrFeO{sub 2.5} to the c-axis oriented SrFeO{sub 2}.

  20. Anomalous codeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions: Experimental study and mathematical model

    SciTech Connect (OSTI)

    Ramasubramanian, M.; Popova, S.N.; Popov, B.N.; White, R.E. [Univ. of South Carolina, Columbia, SC (United States). Dept. of Chemical Engineering; Yin, K.M. [Yuan-Ze Inst. of Tech., Taoyuan (Taiwan, Province of China)

    1996-07-01T23:59:59.000Z

    A mathematical model has been developed to describe the electrodeposition of Fe-Ni alloys and Fe-Ni-SiO{sub 2} composites under potentiostatic conditions. This model can be used to predict the polarization behavior, partial current densities, and alloy composition of each of the components as a function of the applied potential. Fe-Ni-SiO{sub 2} samples were deposited on platinum rotating disk electrodes from sulfate electrolytes under potentiostatic conditions, and the results obtained were compared to the model. The model predictions were found to agree well with the experimental observations for the Fe-Ni and Fe-Ni-SiO{sub 2} systems.

  1. Structural and Electrochemical Characterization of PureLiFePO4and Nanocomposite C-LiFePO4Cathodes for Lithium Ion Rechargeable Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumar, Arun; Thomas, R.; Karan, N. K.; Saavedra-Arias, J. J.; Singh, M. K.; Majumder, S. B.; Tomar, M. S.; Katiyar, R. S.

    2009-01-01T23:59:59.000Z

    Pure lithium iron phosphate (LiFePO4) and carbon-coatedLiFePO4(C-LiFePO4) cathode materials were synthesized for Li-ion batteries. Structural and electrochemical properties of these materials were compared. X-ray diffraction revealed orthorhombic olivine structure. Micro-Raman scattering analysis indicates amorphous carbon, and TEM micrographs show carbon coating onLiFePO4particles. Ex situ Raman spectrum of C-LiFePO4at various stages of charging and discharging showed reversibility upon electrochemical cycling. The cyclic voltammograms ofLiFePO4and C-LiFePO4showed only a pair of peaks corresponding to the anodic and cathodic reactions. The first discharge capacities were 63, 43, and 13?mAh/g for C/5, C/3, and C/2, respectively forLiFePO4where as in case of C-LiFePO4that were 163, 144,more »118, and 70?mAh/g for C/5, C/3, C/2, and 1C, respectively. The capacity retention of pureLiFePO4was 69% after 25 cycles where as that of C-LiFePO4was around 97% after 50 cycles. These results indicate that the capacity and the rate capability improved significantly upon carbon coating.« less

  2. Synthesis and characterization of Fe(III)-silicate precipitation tubes

    SciTech Connect (OSTI)

    Parmar, K.; Pramanik, A.K. [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India)] [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India); Bandyopadhya, N.R. [Bengal Engineering and Science University, Shibpur, Howrah 711103 (India)] [Bengal Engineering and Science University, Shibpur, Howrah 711103 (India); Bhattacharjee, S., E-mail: santanu@nmlindia.org [National Metallurgical Laboratory, Council of Scientific and Industrial Research, Burmamines, Jamshedpur 831007 (India)

    2010-09-15T23:59:59.000Z

    Fe(III)-silicate precipitation tubes synthesized through 'silica garden' route have been characterized using a number of analytical techniques including X-ray diffraction, infrared spectroscopy, atomic force microscopy, scanning and transmission electron microscopy. These tubes are brittle and amorphous and are hierarchically built from smaller tubes of 5-10 nm diameters. They remain amorphous at least up to 650 {sup o}C. Crystobalite and hematite are the major phases present in Fe(III)-silicate tubes heated at 850 {sup o}C. Morphology and chemical compositions at the external and internal walls of these tubes are remarkably different. These tubes are porous with high BET surface area of 291.2 m{sup 2}/g. Fe(III)-silicate tubes contain significant amount of physically and chemically bound moisture. They show promise as an adsorbent for Pb(II), Zn(II), and Cr(III) in aqueous medium.

  3. Iron-phosphorus relationships in Fe chlorisis of sorghum 

    E-Print Network [OSTI]

    Morales-Vargas, Dennis A

    1979-01-01T23:59:59.000Z

    soils, depending on the species or variety of plant grown. Wallace and Lunt (52) indicated that 25 to 30% of the earth's land surface is calcareous. A survey (31) in all states west of the Mississippi River to de- termine the estimated acreage of Fe... as decrease in the yields, whereas, the same quantities of P applied to so1ls with an initial react1on ranging between 3. 5 and 5. 8 may cause stimulation of plant growth and increase of y1elds. In experiments of Fe nutrition of plants at h1gh pH, De...

  4. Room-Temperature Multiferroic Hexagonal LuFeO3

    SciTech Connect (OSTI)

    Cheng, Xuemei [Bryn Mawr College; Balke, Nina [ORNL; Chi, Miaofang [ORNL; Gai, Zheng [ORNL; Keavney, David [Argonne National Laboratory (ANL); Lee, Ho Nyung [ORNL; Shen, Jian [University of Tennessee, Knoxville (UTK); Snijders, Paul C [ORNL; Wang, Wenbin [ORNL; Ward, Thomas Z [ORNL; Xu, Xiaoshan [ORNL; Yi, Jieyu [ORNL; Zhu, Leyi [Argonne National Laboratory (ANL); Christen, Hans M [ORNL; Zhao, Jun [University of California, Berkeley

    2013-01-01T23:59:59.000Z

    We observed the coexistence of ferroelectricity and weak ferromagnetism at room temperature in the hexagonal phase of LuFeO3 stabilized by epitaxial thin film growth. While the ferroelectricity in hexagonal LuFeO3 can be understood as arising from its polar structure, the observation of weak ferromagnetism at room temperature is remarkable considering the frustrated triangular spin structure. An explanation of the room temperature weak ferromagnetism is proposed in terms of a subtle lattice distortion revealed by the structural characterization. The combination of ferroelectricity and weak ferromagnetism in epitaxial films at room temperature offers great potential for the application of this novel multiferroic material in next generation devices.

  5. Iron-phosphorus relationships in Fe chlorisis of sorghum

    E-Print Network [OSTI]

    Morales-Vargas, Dennis A

    1979-01-01T23:59:59.000Z

    IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSIS OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Submitted to the Graduate College of Texas A8M University in partial fulfillment of the requirement for the degree of MASl'ER OF SCIENCE December... 1979 Major Subject: Soil Science IRON-PHOSPHORUS RELATIONSHIPS IN FE CHLOROSI OF SORGHUM A Thesis by DENNIS A. MORALES-VARGAS Approved as to style and content by: \\ J(c'w"H~. v& 4 Cc ~. r&'4 wc' c "&"~ / ~Chairman of Committee ! ~Co-' hai...

  6. FE DOCKET NO. 11-59-LNG | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010SaltInstrumentation andFE DOCKET NO. 11-59-LNG FE DOCKET

  7. FE FY 2015 Budget Request Presentation | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010SaltInstrumentation andFE DOCKET NO. 11-59-LNG FE DOCKETFY

  8. FE Leaders Discuss African Energy Development | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011AT&T,OfficeEnd of Year 2010SaltInstrumentation andFE DOCKET NO. 11-59-LNG FE

  9. k-space spin filtering effect in the epitaxial Fe/Au/Fe/GaAs(001) spin-valve

    SciTech Connect (OSTI)

    Hervé, M.; Tricot, S.; Claveau, Y.; Delhaye, G.; Lépine, B.; Di Matteo, S.; Schieffer, P.; Turban, P., E-mail: pascal.turban@univ-rennes1.fr [Département Matériaux et Nanosciences, Institut de Physique de Rennes, UMR 6251, CNRS-Université de Rennes 1, Campus de Beaulieu, Bât 11E, 35042 Rennes cedex (France)

    2013-11-11T23:59:59.000Z

    The hot-electron magnetotransport of epitaxial Fe/Au/Fe/GaAs(001) spin-valves is investigated by ballistic-electron magnetic microscopy. A magnetocurrent amplitude larger than 500% is observed at room temperature close to the Schottky barrier energy. Remarkably, this magnetocurrent is not significantly affected by the thickness reduction of ferromagnetic films, down to 5 atomic layers of the Fe(001) top electrode. This rather suggests a dominant interfacial spin-filtering effect. Finally, the magnetocurrent is strongly reduced when the effective mass of the semiconductor collector is increased. These observations are consistent with recent theoretical prediction of k-space spin-filtering effect in epitaxial spin-valves attached to a semiconducting lead.

  10. Synthesis and crystal structure of layered chalcogenides [KCuFeS[sub 2] and KCuFeSe[sub 2

    SciTech Connect (OSTI)

    Mujica, C.; Paez, J.; Llanos, J. (Univ. Catolica del Norte, Antofagasta (Chile). Dept. de Quimica)

    1994-03-01T23:59:59.000Z

    The new layer chalcogenides KCuFeS[sub 2] and KCuFeSe[sub 2] have been prepared from the copper iron chalcogenide and potassium carbonate. Both phases crystallize with tetragonal symmetry, in the space group I4/mmm (Nr 139) with a=383.7 (1) pm, c=1338.4 (4) pm and a=397.9 (2) pm, c = 1378.7 (54) pm respectively in the ThCr[sub 2]Si[sub 2]-type structure. The chalcogen atoms form bidimensional layers of edge sharing pyramids. Copper and iron are statistically distributed in tetrahedral sites. The potassium ions are placed in cubic sites between the layers.

  11. The passivation of calcite by acid mine water. Column experiments with Fe(III)- SO4-H+ and Fe(III)-Cl-H+ solutions at pH 2

    E-Print Network [OSTI]

    Boi, Marco

    2010-01-01T23:59:59.000Z

    transformation into goethite and jarosite. Geochimica etwith respect to goethite, hematite and schwertmannite (Fe(+ solutions. Schwertmannite and goethite appeared as the Fe(

  12. Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt. No. - 15-33-LNG Bear Head LNG Corporation and Bear Head LNG (USA), LLC - FE Dkt. No. - 15-33-LNG The Office of...

  13. CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 | Department...

    Broader source: Energy.gov (indexed) [DOE]

    CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 CE FLNG, LLC - FE DKT. NO. 12-123-LNG - ORDER 3193 No reports submitted for this docket. More Documents & Publications...

  14. The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst The Effects of Hydrocarbons on NOx Reduction over Fe-based SCR Catalyst Study of effects of hydrocarbons on ammonia storage...

  15. Non-ideal liquidus curve in the Fe-S system and Mercury's snowing core

    E-Print Network [OSTI]

    Hauck II, Steven A.

    was quenched by shutting off the power to the furnace. Recovered run products were polished, carbon-coated]. Stoichiometric mixtures of Fe and FeS were dried and packed into MgO capsules. High temperature was generated

  16. Charge transport in micas: The kinetics of FeII/III electron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transport in micas: The kinetics of FeIIIII electron transfer in the octahedral sheet. Charge transport in micas: The kinetics of FeIIIII electron transfer in the octahedral...

  17. An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3) Basal Planes. An Ab Initio Model of Electron Transport in Hematite (a-Fe2O3) Basal Planes. Abstract: Transport of...

  18. Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial films. Electrical transport properties of Ti-doped Fe2O3(0001) epitaxial films. Abstract: The electrical transport...

  19. Excited Carrier Dynamics of ?-Cr2O3/?-Fe2O3 Core...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Excited Carrier Dynamics of ?-Cr2O3?-Fe2O3 Core-Shell Nanostructures. Excited Carrier Dynamics of ?-Cr2O3?-Fe2O3 Core-Shell Nanostructures. Abstract: In...

  20. Carrier Dynamics in a-Fe2O3 (0001) Thin Films and Single Crystals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carrier Dynamics in a-Fe2O3 (0001) Thin Films and Single Crystals Probed by Femtosecond Transient Absorption and Reflectivity. Carrier Dynamics in a-Fe2O3 (0001) Thin Films and...

  1. Template-directed FeCo nanoshells on AuCu. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on AuCu. Abstract: A synthetic route is reported to achieve a precise control of FeCo shell growth on AuCu cores, leading to AuCuFeCo core-shell nanoparticles, which could...

  2. Isotopic Fractionation of Mg2+(aq), Ca2+(aq), and Fe2+(aq) with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation of Mg2+(aq), Ca2+(aq), and Fe2+(aq) with Carbonate Minerals. Isotopic Fractionation of Mg2+(aq), Ca2+(aq), and Fe2+(aq) with Carbonate Minerals. Abstract: Density...

  3. Characterization of natural titanomagnetites (Fe3-xTixO4) for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as those at the Hanford nuclear reservation, Washington, USA, are rich in Fe-bearing minerals of mixed valence. These minerals are redox reactive with aqueous O2 or Fe(II), and...

  4. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser Assisted Atom Probe Tomography. Effects of Laser Energy and Wavelength on the Analysis of LiFePO4 Using Laser...

  5. Analysis of Fe Nanoparticles Using XPS Measurements Under D.C...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fe Nanoparticles Using XPS Measurements Under D.C. or Pulsed-Voltage Bias. Analysis of Fe Nanoparticles Using XPS Measurements Under D.C. or Pulsed-Voltage Bias. Abstract: The...

  6. FLORIDIAN NATURAL GAS STORAGE COMPANY, LLC - FE DKT. NO. 15-38...

    Energy Savers [EERE]

    FLORIDIAN NATURAL GAS STORAGE COMPANY, LLC - FE DKT. NO. 15-38-LNG FLORIDIAN NATURAL GAS STORAGE COMPANY, LLC - FE DKT. NO. 15-38-LNG The Office of Fossil Energy gives notice of...

  7. American LNG Marketing LLC - FE Dkt. No. 14-209-LNG | Department...

    Office of Environmental Management (EM)

    American LNG Marketing LLC - FE Dkt. No. 14-209-LNG American LNG Marketing LLC - FE Dkt. No. 14-209-LNG The Office of Fossil Energy gives notice of receipt of an application filed...

  8. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 11-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 11-161-LNG On November 15,...

  9. SEMI-ANNUAL REPORTS FOR LAKE CHARLES EXPORTS, LLC - FE DKT. NO...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LAKE CHARLES EXPORTS, LLC - FE DKT. NO. 11-59-LNG - ORDER 3324 SEMI-ANNUAL REPORTS FOR LAKE CHARLES EXPORTS, LLC - FE DKT. NO. 11-59-LNG - ORDER 3324 October 2013 April 2014...

  10. Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE...

    Office of Environmental Management (EM)

    and FLNG Liquefaction, LLC - FE Dkt. No. 10-161-LNG Freeport LNG Expansion, L.P. and FLNG Liquefaction, LLC - FE Dkt. No. 10-161-LNG On May 17, 2013, the Office of Fossil Energy...

  11. SEMI-ANNUAL REPORTS FOR GASFIN DEVELOPMENT USA, LLC - FE DKT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GASFIN DEVELOPMENT USA, LLC - FE DKT. NO. 13-06-LNG - ORDER 3253 SEMI-ANNUAL REPORTS FOR GASFIN DEVELOPMENT USA, LLC - FE DKT. NO. 13-06-LNG - ORDER 3253 April 2013 October 2013...

  12. SEMI-ANNUAL REPORTS FOR ALASKA LNG PROJECT, LLC - FE DKT NO....

    Office of Environmental Management (EM)

    ALASKA LNG PROJECT, LLC - FE DKT NO. 14-96-LNG - ORDER 3643 (NFTA) SEMI-ANNUAL REPORTS FOR ALASKA LNG PROJECT, LLC - FE DKT NO. 14-96-LNG - ORDER 3643 (NFTA) No reports submitted....

  13. UV spectra of iron-doped carbon clusters FeC_n n = 3-6

    E-Print Network [OSTI]

    Steglich, Mathias; Johnson, Anatoly; Maier, John P

    2015-01-01T23:59:59.000Z

    Electronic transitions of jet-cooled FeC$_n$ clusters ($n = 3 - 6$) were measured between 230 and 300 nm by a mass-resolved 1+1 resonant two-photon ionization technique. Rotational profiles were simulated based on previous calculations of ground state geometries and compared to experimental observations. Reasonable agreement is found for the planar fan-like structure of FeC$_3$. The FeC$_4$ data indicate a shorter distance between the Fe atom and the bent C$_4$ unit of the fan. The transitions are suggested to be $^{3}$A$_{2} \\leftarrow ^{3}$B$_{1}$ for FeC$_3$ and $^{5}$A$_{1} \\leftarrow ^{5}$A$_{1}$ for FeC$_4$. In contrast to the predicted C$_{\\infty \\text{v}}$ geometry, non-linear FeC$_5$ is apparently observed. Line width broadening prevents analysis of the FeC$_6$ spectrum.

  14. Low Temperature Oxidation of Fe2+ Surface Sites on the (2x1)...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sites on the (2x1) Reconstructed Surface of ?-Fe2O3(01(1) over-bar2). Low Temperature Oxidation of Fe2+ Surface Sites on the (2x1) Reconstructed Surface of...

  15. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    E-Print Network [OSTI]

    Nelson-Cheeseman, B. B.

    2007-01-01T23:59:59.000Z

    Magnetism of NiMn 2 O 4 –Fe 3 O 4 spinel interfaces B. B.2. Element-specific magnetism of Fe 3 O 4 /NMO interface inin these structures, 6 the magnetism near the isostructural

  16. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phasehydrodeoxy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of...

  17. A MOSSBAUER STUDY OF AUSTENITE STABILITY AND IMPACT FRACTURE IN Fe - 6 Ni STEEL

    E-Print Network [OSTI]

    Fultz, Brent

    2011-01-01T23:59:59.000Z

    IMPACT FRACTURE IN Fe-6Ni STEEL Brent Thomas Fultz Materialscommercial cryogenic alloy steel was studied with regard toThe Experiments Fe-6Ni-lMn steel plate was received from the

  18. WELDABILITY OF GRAIN-REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Morris Jr., J.W.

    2013-01-01T23:59:59.000Z

    of the Cryogenic Nickel Steels, WRC Bull, 205, May, 1975.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.E.REFINED Fe-12Ni-0.25Ti STEEL FOR CRYOGENIC APPLICATIONS D.

  19. The Utility of FeVO4 in Combination with Stabilized Titanias...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application The Utility of FeVO4 in Combination with Stabilized Titanias for Mobile SCR Application...

  20. Stability of uranium incorporated into Fe(hydr)oxides under fluctuating redox conditions

    E-Print Network [OSTI]

    Stewart, B.D.

    2009-01-01T23:59:59.000Z

    by interaction with goethite, lepidocrocite, muscovite, andM. Reduction of U(VI) in goethite (alpha-FeOOH) suspensionsmM Fe(II) k F=ferrihydrite, G=goethite, L=lepidocrocite, M=

  1. Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation

    E-Print Network [OSTI]

    Um, Wooyong

    2013-01-01T23:59:59.000Z

    of Technetium-99 by Fe(II)-goethite; PNNL- 19833; PacificTransformation of magnetite to goethite under alkaline pHisotope variation among goethite (alpha- FeOOH) and the

  2. JOURNAL DE PHYSIQUE Colloque C2, supplment au n 3, Tome 40, mars 1979, page C2-267 Fe MOSSBAUER STUDIES IN FeCoCr04 AND Fe2 Mo04 CUBIC SPINELS*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MOSSBAUER STUDIES IN FeCoCr04 AND Fe2 Mo04 CUBIC SPINELS* M.P. Guptat, S.M.Kanetkartt, S.K. Datettt, ACoCrOi, et FezMoOii, ont été déterminées ŕ l'aide de la spectroscopie Mossbauer et la diffraction des rayons spi- nels, FeCoCrOi, and FeaMoOi, have been determined using Mossbauer and X-ray diffraction

  3. Important role of the non-uniform Fe distribution for the ferromagnetism in group-IV-based ferromagnetic semiconductor GeFe

    SciTech Connect (OSTI)

    Wakabayashi, Yuki K.; Ohya, Shinobu; Ban, Yoshisuke; Tanaka, Masaaki [Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2014-11-07T23:59:59.000Z

    We investigate the growth-temperature dependence of the properties of the group-IV-based ferromagnetic semiconductor Ge{sub 1?x}Fe{sub x} films (x?=?6.5% and 10.5%), and reveal the correlation of the magnetic properties with the lattice constant, Curie temperature (T{sub C}), non-uniformity of Fe atoms, stacking-fault defects, and Fe-atom locations. While T{sub C} strongly depends on the growth temperature, we find a universal relationship between T{sub C} and the lattice constant, which does not depend on the Fe content x. By using the spatially resolved transmission-electron diffractions combined with the energy-dispersive X-ray spectroscopy, we find that the density of the stacking-fault defects and the non-uniformity of the Fe concentration are correlated with T{sub C}. Meanwhile, by using the channeling Rutherford backscattering and particle-induced X-ray emission measurements, we clarify that about 15% of the Fe atoms exist on the tetrahedral interstitial sites in the Ge{sub 0.935}Fe{sub 0.065} lattice and that the substitutional Fe concentration is not correlated with T{sub C}. Considering these results, we conclude that the non-uniformity of the Fe concentration plays an important role in determining the ferromagnetic properties of GeFe.

  4. Beta-decay of Mn-65 to Fe-65

    E-Print Network [OSTI]

    Olaizola, B; Mach, H; Aprahamian, A; Briz, J A; Cal-Gonzalez, J; Ghita, D; Koster, U; Kurcewicz, W; Lesher, S R; Pauwels, D; Picado, E; Poves, A; Radulov, D; Simpson, G S; Udias, J M

    2013-01-01T23:59:59.000Z

    The low energy structure of Fe-65 has been studied by means of gamma- and fast-timing spectroscopy. A level scheme of Fe-65 populated following the beta-decay of Mn-65 was established for the first time. It includes 41 levels and 85 transitions. The excitation energy of the beta-decaying isomer in Fe-65 has been precisely determined at 393.7(2) keV. The beta delayed neutron emission branch was measured as Pn = 7.9(12)%, which cannot be reconciled with the previously reported value of 21.0(5)%. Four gamma-rays and four excited states in Fe-64 were identified as being populated following the beta-n decay. Four lifetimes and five lifetime limits in the subnanosecond range have been measured using the Advanced Time-Delayed Method. The level scheme is compared with shell-model calculations. Tentative spin and parity assignments are proposed based on the observed transition rates, the calculations and the systematics of the region.

  5. Ligand exchange in gold-coated FePt nanoparticles

    E-Print Network [OSTI]

    de la Presa, P; Morales, M P; Hernando, A; 10.1109/TMAG.2008.2002251

    2009-01-01T23:59:59.000Z

    In this work we present the magnetic properties of gold coated FePt nanoparticles and the study of stable aqueous dispersions of FePt@Au and FePt synthesized after ligand exchange with mercaptoundecanoic acid. The particle size determined from TEM micrographs goes from 4 nm for the uncoated nanoparticles to a maximum of 10 nm for the gold coated ones indicating that the thickness of the shell ranges from 1 to 3 nm. The magnetic characterization consists in hysteresis cycles at 10 and 300 K. The results show that, at low field and room temperature, the magnetic behavior of uncoated and coated nanoparticles are surprisingly quite similar. Since the gold coated nanoparticles keep the magnetic properties of FePt and the presence of gold improves the functionalization of nanoparticles, the system is suitable for biological application. Mercaptoundecanoic ligand transfer was used to render water stable nanoparticles in a wide pH range. Transmission electron microscopy and dynamic light scattering results show the n...

  6. Vapor Phase Synthesis and Characterization of -FeSi Nanowires

    E-Print Network [OSTI]

    Heller, Eric

    HF and placed in a horizontal tube furnace, between the center and the downstream end of the alumina tube. Anhydrous FeCl3 powder (Aldrich, 99.99%) was placed in an alumina boat upstream of the substrates. An inert atmosphere was maintained with a flow rate of 100 sccm N2, and the temperature at the center

  7. Spin glass behavior in FeAl2 

    E-Print Network [OSTI]

    Lue, CS; Oner, Y.; Naugle, Donald G.; Ross, JH.

    2001-01-01T23:59:59.000Z

    Magnetic and transport measurements indicate FeAl2 to be an ordered intermetallic spin glass, with canonical behavior including a susceptibility cusp at T-f = 35 K and frequency-dependent susceptibility below T-f. The field-cooled and zero...

  8. Equation of state and phase diagram of FeO

    SciTech Connect (OSTI)

    Fischer, Rebecca A.; Campbell, Andrew J.; Shofner, Gregory A.; Lord, Oliver T.; Dera, Przemyslaw; Prakapenka, Vitali B. (Bristol); (Maryland); (UC)

    2012-04-11T23:59:59.000Z

    Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component in the core. Therefore the high pressure, high temperature behavior of FeO, including its phase diagram and equation of state, is essential knowledge for understanding the properties and evolution of Earth's deep interior. We performed X-ray diffraction measurements using a laser-heated diamond anvil cell to achieve simultaneous high pressures and temperatures. Wuestite was mixed with iron metal, which served as our pressure standard, under the assumption that negligible oxygen dissolved into the iron. Our data show a positive slope for the subsolidus phase boundary between the B1 and B8 structures, indicating that the B1 phase is stable at the P-T conditions of the lower mantle and core. We have determined the thermal equation of state of B1 FeO to 156 GPa and 3100 K, finding an isothermal bulk modulus K{sub 0} = 149.4 {+-} 1.0 GPa and its pressure derivative K'{sub 0} = 3.60 {+-} 0.4. This implies that 7.7 {+-} 1.1 wt.% oxygen is required in the outer core to match the seismologically-determined density, under the simplifying assumption of a purely Fe-O outer core.

  9. QER- Comment of Sustainable Santa Fe Programs Manager

    Broader source: Energy.gov [DOE]

    At the City of Santa Fe we have had difficulty in getting energy usage data from the investor-owned utility to be able to track progress towards energy use and greenhouse gas reduction goals. It would be helpful if that information were required to be publicly available at the Zip code level. Thanks.

  10. FE-Analysen zur Thermoermdung Test-und Feldzyklen

    E-Print Network [OSTI]

    Berlin,Technische Universität

    LIVE AG 1 -AG 2 FE-Analysen zur Thermoermüdung Test- und Feldzyklen R. Dudek, R. Döring, B #12;LIVE different SAC creep laws: Steady State Creep (after Schubert, SAC405 and Röllig/Wiese SAC xx) Creep properties of SAC 407 show much higher creep resistance than SAC xx SAC 305 bulk averaged values

  11. ELECTRON-CAPTURE SUPERNOVAE AS SOURCES OF {sup 60}Fe

    SciTech Connect (OSTI)

    Wanajo, Shinya [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Janka, Hans-Thomas; Mueller, Bernhard, E-mail: shinya.wanajo@nao.ac.jp [Max-Planck-Institut fuer Astrophysik, Karl-Schwarzschild-Str. 1, D-85748 Garching (Germany)

    2013-09-01T23:59:59.000Z

    We investigate the nucleosynthesis of the radionuclide {sup 60}Fe in electron-capture supernovae (ECSNe). The nucleosynthetic results are based on a self-consistent, two-dimensional simulation of an ECSN as well as models in which the densities are systematically increased by some factors (low-entropy models). {sup 60}Fe is found to be appreciably made in neutron-rich ejecta during the nuclear quasi-equilibrium phase with greater amounts being produced in the lower-entropy models. Our results, combining them with the yields of core-collapse supernovae in the literature, suggest that ECSNe account for at least 4%-30% of live {sup 60}Fe in the Milky Way. ECSNe co-produce neutron-rich isotopes, {sup 48}Ca, {sup 50}Ti, {sup 54}Cr, some light trans-iron elements, and possibly weak r-process elements including some radionuclides such as {sup 93}Zr, {sup 99}Tc, and {sup 107}Pd, whose association with {sup 60}Fe might have been imprinted in primitive meteorites or in the deep ocean crust on the Earth.

  12. Spin glass behavior in FeAl2

    E-Print Network [OSTI]

    Lue, CS; Oner, Y.; Naugle, Donald G.; Ross, JH.

    2001-01-01T23:59:59.000Z

    Magnetic and transport measurements indicate FeAl2 to be an ordered intermetallic spin glass, with canonical behavior including a susceptibility cusp at T-f = 35 K and frequency-dependent susceptibility below T-f. The field-cooled and zero...

  13. The Effects of Fe3+ Aluminum Silicate Phase Relations in

    E-Print Network [OSTI]

    Lee, Cin-Ty Aeolus

    The Effects of Fe3+ and Mn3+ on Aluminum Silicate Phase Relations in North-Central New Mexico, U, New Mexico 87131 (Received 28 November 1983; in revised form 2 October 1984) ABSTRACT Aluminum, then their equilibrium coexistence is invariant. However, the aluminum silicate minerals are not pure in highly oxidized

  14. High strength-high conductivity Cu--Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, John D. (Ames, IA); Spitzig, William A. (Ames, IA); Gibson, Edwin D. (Ames, IA); Anderson, Iver E. (Ames, IA)

    1991-08-27T23:59:59.000Z

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an "in-situ" Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite.

  15. Structural and Mössbauer spectroscopic study of Fe-Ni alloy nanoparticles

    SciTech Connect (OSTI)

    Kumar, Asheesh; Banerjee, S., E-mail: vsudar@barc.gov.in; Sudarsan, V., E-mail: vsudar@barc.gov.in [Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India); Meena, S. S. [Solid State Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai-400085 (India)

    2014-04-24T23:59:59.000Z

    Nano-crystalline Fe-Ni alloys have been synthesized in ethylene glycol medium. Based on XRD studies it is confirmed that, in these alloys Fe atoms are incorporated at Ni site to form Ni-Fe solid solutions. Mössbauer studies have established that for alloy particles having smaller size there is significant concentration of two different types of paramagnetic Fe species and their relative concentration decreased with increase in particle size.

  16. High strength-high conductivity Cu-Fe composites produced by powder compaction/mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, J.D.; Spitzig, W.A.; Gibson, E.D.; Anderson, I.E.

    1991-08-27T23:59:59.000Z

    A particulate mixture of Cu and Fe is compacted and mechanically reduced to form an ''in-situ'' Cu-Fe composite having high strength and high conductivity. Compaction and mechanical reduction of the particulate mixture are carried out at a temperature and time at temperature selected to avoid dissolution of Fe into the Cu matrix particulates to a harmful extent that substantially degrades the conductivity of the Cu-Fe composite. 5 figures.

  17. Adsorption and diffusion energetics of hydrogen atoms on Fe(1 1 0) from first principles

    E-Print Network [OSTI]

    Carter, Emily A.

    as a reactant in Fe-catalyzed ammonia synthesis [1], the Fischer­Tropsch reaction [2] (and many others

  18. Adsorption and dissociation of CO on Fe(110) from first principles

    E-Print Network [OSTI]

    Carter, Emily A.

    catalysis and Fischer­Tropsch synthesis. Fe is used as a catalyst in the Fischer­Tropsch process [1] due

  19. High temperature magnetic properties of SmCo5/-Fe(Co) bulk nanocomposite magnets

    E-Print Network [OSTI]

    Liu, J. Ping

    High temperature magnetic properties of SmCo5/-Fe(Co) bulk nanocomposite magnets Chuanbing Rong://apl.aip.org/about/rights_and_permissions #12;High temperature magnetic properties of SmCo5/a-Fe(Co) bulk nanocomposite magnets Chuanbing Rong,1 containing no heavy rare earths for power applications, SmCo5/Fe bulk nanocomposite magnets with enhanced

  20. SmCo5/Fe nanocomposites synthesized from reductive annealing of oxide nanoparticles

    E-Print Network [OSTI]

    Liu, J. Ping

    SmCo5/Fe nanocomposites synthesized from reductive annealing of oxide nanoparticles Yanglong Hou nanocomposites SmCo5/Fex x=0­2.9 are synthesized by a simultaneous calcium reduction of Sm­Co­O and Fe3O4 nanoparticles. The composites consist of nanostructured SmCo5 and Fe with their average grain sizes at 29 and 8

  1. Reduction of Sintering during Annealing of FePt Nanoparticles Coated with Iron Oxide

    E-Print Network [OSTI]

    Laughlin, David E.

    Reduction of Sintering during Annealing of FePt Nanoparticles Coated with Iron Oxide Chao Liu °C for 30 min at which 2.6-nm FePt nanoparticles without oxide shell coating start to sinter. LowVised Manuscript ReceiVed October 12, 2004 FePt/iron oxide core/shell nanoparticles are synthesized by a two step

  2. OXIDATION MECHANISMS OF LOW ENERGY-HIGH FLUX NITRIDED ODS FeAl INTERMETALLIC ALLOY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    OXIDATION MECHANISMS OF LOW ENERGY-HIGH FLUX NITRIDED ODS FeAl INTERMETALLIC ALLOY F. Pedraza*, J)5.46.45.72.72 Abstract Microscopy studies of low energy-high flux nitrided ODS FeAl Grade 3 intermetallic alloy reveal nitridation treatment at moderate temperature of ODS FeAl Grade 3 has been performed to modify the surface

  3. Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa

    E-Print Network [OSTI]

    Kim, Jai Sam

    Hydrogen adsorption on Pd/TiFe (110) surface S.E. Kulkovaa , S.V. Eremeeva,b,*, V.E. Egorushkinc February 2003 by E.L. Ivchenko Abstract Adsorption of hydrogen on the TiFe (110) surface covered the local density approximation. Influence of palladium coating to adsorption properties of the TiFe (110

  4. Combined Microbial-Fe(0) Treatment Systems 1 1058-8337/00/$.50

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    produces cathodic H2 when corroded by water. The preferential colonization of Fe(0) suggests- valent iron (Fe(0)) is submerged in anoxic water, hydro- gen gas is produced via cathodic depolarizationCombined Microbial-Fe(0) Treatment Systems 1 1058-8337/00/$.50 © 2000 by Battelle Memorial

  5. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    3, 1976 LBL-5401 l NICKEL-FREE Fe-12Mn-O. 2Ti ALLOY STEELowned rights. I v LBL-540l NICKEL-FREE Fe-12Mn-0.2Ti ALLOY94720 USA ABSTRACT A nickel-free Fe-12Mn-0.2Ti alloy steel

  6. High-pressure phases of FeTiO3 from first principles N. C. Wilson

    E-Print Network [OSTI]

    2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

  7. Emitting gas regions in Mrk 493: An extensive Fe II line emission region

    E-Print Network [OSTI]

    L. C. Popovic; A. Smirnova; D. Ilic; A. Moiseev; J. Kovacevic; V. Afanasiev

    2007-01-24T23:59:59.000Z

    We performed 3D spectroscopic observations of Mrk 493 in order to investigate the Fe II emitting region and their possible connection with the Hydrogen emitting region. We found that there is a strong Fe II emission in an extensive region ~ 4" x 4" around Sy 1 nucleus. The Fe II line width indicates that these lines are originated in an intermediate line region.

  8. Temperature dependence of magnetoelastic properties of Fe100?xSix (5 < x < 20)

    SciTech Connect (OSTI)

    Petculescu, G.; Lambert, P.K.; Clark, A.E.; Hathaway, K.B.; Xing, Qingfeng; Lograsso, Tom; Restorff, J.B.; Wun-Fogle, M.

    2012-02-29T23:59:59.000Z

    Tetragonal magnetostriction (??,2) and elastic constants (c?, c44, and c11) for Fe100?xSix were measured as a function of temperature (T). Compositions corresponding to the disordered A2 (x?=?5), ordered D03 (x?=?19.8), and mixed (x?=?11.6) phases, were investigated. The magnetoelastic coupling (?b1) was determined for 77 < T < 300?K and compared with those of Fe-Ga, Fe-Ge, and Fe-Al. Both ??,2(T) and ?b1(T) of Fe-Si behave similarly to those of Fe-Ge, while other notable differences exist between the measured properties of Fe-Si and those of the other three alloys. Due to the early establishment of short range order, Fe-Si exhibits a positive, although small, slope in ??,2(T) at 5 at. % Si, and a remarkable drop in ?b1 before the solubility limit. The weaker softening of the tetragonal shear modulus with the addition of Si and the lack of strong anharmonic effects in the Fe-Si lattice inferred from the weak T-dependence of all the moduli suggest that Fe-Si exhibits more structural stability than the other three alloys. The distinctive behavior is likely due to the smaller size of Si compared to the sizes of Ga, Ge and Al, and therefore to the effect of the larger size difference between Fe and Si in the Fe-Si lattice.

  9. A synthesis of LiFePO{sub 4} starting from FePO{sub 4} under reducing atmosphere

    SciTech Connect (OSTI)

    Prosini, Pier Paolo [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome, Italy and DInESto, Drive the Innovation in Energy Storage, Via Provin (Italy); Cento, Cinzia; Masci, Amedeo; Carewska, Maria; Gislon, Paola [ENEA, Italian National Agency for New Technologies, Energy and Sustainable Economic Development, Casaccia Research Centre, Via Anguillarese 301, 00123 Santa Maria di Galeria, Rome (Italy)

    2014-06-19T23:59:59.000Z

    A fast and easy way to produce LiFePO{sub 4} starting from FePO{sub 4}, used as iron and phosphorus source, is proposed. 5% hydrogen is employed as a reducing agent and various compounds containing lithium as lithiation agents. The selected lithiation agents included: LiCl, CH{sub 3}COOLi, LiOH, Li{sub 2}S, LiH, and Li{sub 2}CO{sub 3}. Solid state synthesis is used for the LiFePO{sub 4} preparation and the so obtained materials are structurally characterized by XRD. The materials are used to fabricate composite electrode and their specific capacity is evaluated by low rate galvanostatic charge/discharge cycles (C/10 rate). Among the various lithium salts, the acetate give rise to the LiFePO{sub 4} with the best electrochemical performance. The morphology of this material is further investigated by SEM microscopy and the specific capacity is evaluated as a function of the discharge rate and the cycle number.

  10. Identification of an incommensurate FeAl{sub 2} overlayer on FeAl(110) using x-ray diffraction and reflectivity

    SciTech Connect (OSTI)

    Baddorf, A.P. [Oak Ridge National Lab., TN (United States); Chandavarkar, S.S. [Tennessee Univ., Knoxville, TN (United States). Dept. of Physics and Astronomy

    1995-06-30T23:59:59.000Z

    FeAl, like NiAl, crystallizes in the CsCl structure. Consequently the (110) planes contain equal amounts of Fe and Al distributed as interlocking rectangles. Unlike the NiAI(110) surface, which retains the (1{times}l) in-plane symmetry of the bulk, FeAl(l10) reconstructs to form an ordered, incommensurate overlayer. The reconstructed layer introduces x-ray diffraction rods at half-order positions along the [1{bar 1}0] direction, and displaced {plus_minus}0.2905 from integer positions along the [001] direction. Peak widths reveal excellent long range order. Specular reflectivity measurements above and below the Fe K{alpha} edge can be reproduced using a model containing a single reconstructed overlayer with an Fe:Al ratio of 1:2, consistent with FeA{sub I}2.

  11. g factor of the first excited state in {sup 56}Fe and implications for transient-field calibration in the Fe region

    SciTech Connect (OSTI)

    East, M. C.; Stuchbery, A. E.; Chamoli, S. K.; Kibedi, T. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University Canberra, ACT 0200 (Australia); Wilson, A. N. [Department of Nuclear Physics, Research School of Physics and Engineering, Australian National University Canberra, ACT 0200 (Australia); Department of Physics, Australian National University, Canberra, ACT 0200 (Australia); Crawford, H. L.; Pinter, J. S.; Mantica, P. F. [NSCL and Department of Chemistry, Michigan State University, Michigan 48824 (United States)

    2009-02-15T23:59:59.000Z

    The transient-field technique has been used to measure the g factor of the 2{sub 1}{sup +} state in {sup 56}Fe relative to the independently determined g factor of the first 5/2{sup -} state in {sup 57}Fe. The new result for {sup 56}Fe agrees with previous measurements but is more precise. Implications for calibrating the transient field and g-factor measurements in the fp region are discussed.

  12. 0 1 2 3 4 5 Fig. S1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core

    E-Print Network [OSTI]

    Gilli, Adrian

    1. Core photograph combined with Ca, Mn, Fe counts and Mn/Fe ratio determined by XRF core scanning determined by XRF core scanning on core ZH10-19 from Lake Zurich recovered in 135 m water depth (2 m above counts and Mn/Fe ratio determined by XRF core scanning on core ZH10-21 from Lake Zurich recovered in 123

  13. Iron silicide formation at different layers of (Fe/Si){sub 3} multilayered structures determined by conversion electron Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Badía-Romano, L., E-mail: lbadia@unizar.es; Bartolomé, J. [Departamento de Física de la Materia Condensada, Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, E-50009 Zaragoza (Spain); Rubín, J. [Departamento de Ciencia y Tecnología de Materiales y Fluidos, Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza, E-50018 Zaragoza (Spain); Magén, C. [Laboratorio de Microscopías Avanzadas (LMA), Instituto de Nanociencia de Aragón (INA), Universidad de Zaragoza, E-50018 Zaragoza (Spain); Bürgler, D. E. [Peter Grünberg Institut (PGI-6), Forschungszentrum Jülich GmbH, D-52425 Jülich (Germany)

    2014-07-14T23:59:59.000Z

    The morphology and the quantitative composition of the Fe-Si interface layer forming at each Fe layer of a (Fe/Si){sub 3} multilayer have been determined by means of conversion electron Mössbauer spectroscopy (CEMS) and high-resolution transmission electron microscopy (HRTEM). For the CEMS measurements, each layer was selected by depositing the Mössbauer active {sup 57}Fe isotope with 95% enrichment. Samples with Fe layers of nominal thickness d{sub Fe}?=?2.6?nm and Si spacers of d{sub Si}?=?1.5?nm were prepared by thermal evaporation onto a GaAs(001) substrate with an intermediate Ag(001) buffer layer. HRTEM images showed that Si layers grow amorphous and the epitaxial growth of the Fe is good only for the first deposited layer. The CEMS spectra show that at all Fe/Si and Si/Fe interfaces a paramagnetic c-Fe{sub 1?x}Si phase is formed, which contains 16% of the nominal Fe deposited in the Fe layer. The bottom Fe layer, which is in contact with the Ag buffer, also contains ?-Fe and an Fe{sub 1?x}Si{sub x} alloy that cannot be attributed to a single phase. In contrast, the other two layers only comprise an Fe{sub 1?x}Si{sub x} alloy with a Si concentration of ?0.15, but no ?-Fe.

  14. Interface magnetism of Co{sub 2}FeGe Heusler alloy layers and magnetoresistance of Co{sub 2}FeGe/MgO/Fe magnetic tunnel junctions

    SciTech Connect (OSTI)

    Tanaka, M. A., E-mail: mtanaka@nitech.ac.jp; Maezaki, D.; Ishii, T.; Okubo, A.; Mibu, K. [Department of Engineering Physics, Electronics and Mechanics, Nagoya Institute of Technology, Nagoya, Aichi 466-8555 (Japan); Hiramatsu, R.; Ono, T. [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan)

    2014-10-28T23:59:59.000Z

    The interface magnetism between Co{sub 2}FeGe Heusler alloy layers and MgO layers was investigated using {sup 57}Fe Mössbauer spectroscopy. Interface-sensitive samples, where the {sup 57}Fe isotope was used only for the interfacial atomic layer of the Co{sub 2}FeGe layer on the MgO layer, were prepared using atomically controlled alternate deposition. The {sup 57}Fe Mössbauer spectra of the interface-sensitive samples at room temperature were found similar to those of the bulk-sensitive Co{sub 2}FeGe films in which the {sup 57}Fe isotope was distributed throughout the films. On the other hand, the tunnel magnetoresistance effect of magnetic tunnel junctions with Co{sub 2}FeGe layers as the ferromagnetic electrodes showed strong reduction at room temperature. These results indicate that the strong temperature dependence of the tunneling magnetoresistance of magnetic tunnel junctions using Heusler alloy electrodes cannot be attributed simply to the reduction of the magnetization at the interfaces between the Heusler alloy and insulator layers.

  15. Oxide shell reduction and magnetic property changes in core-shell Fe nanoclusters under ion irradiation

    SciTech Connect (OSTI)

    Sundararajan, Jennifer A.; Kaur, Maninder; Qiang, You, E-mail: youqiang@uidaho.edu [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States); McCloy, John S. [School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164 (United States)

    2014-05-07T23:59:59.000Z

    Ion irradiation effects are studied on the Fe-based core-shell nanocluster (NC) films with core as Fe and shell as Fe{sub 3}O{sub 4}/Fe{sub 3}N. These NC films were deposited on Si substrates to thickness of ?0.5 ?m using a NC deposition system. The films were irradiated at room temperature with 5.5?MeV Si{sup 2+} ions to ion fluences of 10{sup 15} and 10{sup 16} ions/cm{sup 2}. It is found that the irradiation induces grain growth, Fe valence reduction in the shell, and crystallization or growth of Fe{sub 3}N. The film retained its Fe-core and its ferromagnetic properties after irradiation. The nature and mechanism of oxide shell reduction and composition dependence after irradiation were studied by synthesizing additional NC films of Fe{sub 3}O{sub 4} and FeO?+?Fe{sub 3}N and irradiating them under the same conditions. The presence of nanocrystalline Fe is found to be a major factor for the oxide shell reduction. The surface morphologies of these films show dramatic changes in the microstructures due to cluster growth and agglomeration as a result of ion irradiation.

  16. Morphology and crystallographic orientation relationship in isothermally transformed Fe–N austenite

    SciTech Connect (OSTI)

    Jiao, Dongling, E-mail: dljiao@scut.edu.cn [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Luo, Chengping; Liu, Jiangwen [School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640 (China); Zhang, Guoqing [Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095 (China)

    2014-02-15T23:59:59.000Z

    The 225 °C isothermal transformation of a high-nitrogen austenite with Fe–2.71 wt.% N was investigated by means of electron microscopy. It was found that the transformation products were composed of ultrafine ?-Fe and ??-Fe{sub 4}N plus retained austenite ?, which were in two types of morphologies, namely, (i) with the retained austenite patches dispersed among the (?-Fe + ??-Fe{sub 4}N) packets and (ii) with the ultrafine ?-Fe and ?/??-Fe{sub 4}N laths interwoven with each other within a single bainitic packet. A cube–cube orientation relationship between the ? (austenite) and ??-Fe{sub 4}N, and a near Greninger–Troiano (G–T) one between the ? (austenite) and the bainitic ?-ferrite were detected. The morphology, orientation relationship and high hardness (> 1000 HV) of the transformation products indicated that the isothermal transformation of the high nitrogen austenite was analogous to a bainitic one. - Highlights: • Isothermal transformation products consisted of nano-sized ?-Fe + ?? + ? (retained). • The hardness of transformation product exceeded 1000 HV. • The ?-Fe and ?/??-Fe{sub 4}N kept a near G-T OR in the grain interior.

  17. Synthesis of Monodisperse FeCo Nanoparticles by Reductive Salt-Matrix Annealing

    SciTech Connect (OSTI)

    Poudyal, Narayan; Chaubey, Girija S.; Rong, Chuan-bing; Cui, Jun; Liu, J.Ping

    2013-08-02T23:59:59.000Z

    We report here a novel synthetic method to prepare monodisperse air-stable FeCo nanoparticles. CoFe2O4 nanoparticles with different sizes were first synthesized by a chemical solution method. The as-synthesized CoFe2O4 nanoparticles were then mixed with ball-milled NaCl powders and heated to 400–500oC in forming gas (Ar 93% + H2 7%). The salt powder worked as a separating medium that prevents the CoFe2O4 nanoparticles from agglomerating during the heat treatment while the forming gas reduces the CoFe2O4 nanoparticles to FeCo nanoparticles. Monodisperse FeCo nanoparticles were recovered by dissolving the NaCl in water and subsequently washing with ethanol and acetone. Structural analyses confirmed that FeCo nanoparticles retained the same size as their oxide precursors. The size of the FeCo nanoparticles can be well tuned by controlling the size of the CoFe2O4 nanoparticles. The saturation magnetization of FeCo nanoparticles is size dependent and increases with size.

  18. Improved gas sensing and dielectric properties of Fe doped hydroxyapatite thick films: Effect of molar concentrations

    SciTech Connect (OSTI)

    Mene, Ravindra U. [PDEA's, Annasaheb Waghire College of Science, Arts and Commerce, Otur 412409, M.S. (India); School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India); Mahabole, Megha P. [School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India); Mohite, K.C. [Haribhai. V. Desai College, Pune 411002, M.S. (India); Khairnar, Rajendra S., E-mail: rskhairnarsps@gmail.com [School of Physical Sciences, Swami Ramanand Teerth Marathwada University, Nanded 431606, M.S. (India)

    2014-02-01T23:59:59.000Z

    Highlights: • We report improved gas sensing and dielectric characteristics of Fe ion exchanged HAp films. • Fe doped HAp film shows maximum gas response at relatively lower temperature. • Response and gas uptake capacity of sensors is improved for appropriate amount of Fe ions in HAp matrix. • Fe-HAp films exhibit remarkable improvement in dielectric properties compared to pure HAp. • Fe doped HAp films show significant improvement in gas sensing as well as in dielectric properties. - Abstract: In the present work Fe doped hydroxyapatite (Fe-HAp) thick films has been successfully utilized to improve the gas sensing as well as its dielectric properties. Initially, HAp nano powder is synthesized by chemical precipitation process and later on Fe ions are doped in HAp by ion exchange process. Structural and morphological modifications are observed by means of X-ray diffraction and scanning electron microscopy analysis. The sensing parameters such as operating temperature, response/recovery time and gas uptake capacity are experimentally determined. The Fe-HAp (0.05 M) film shows improved CO and CO{sub 2} gas sensing capacity at lower operating temperature compared to pure HAp. Moreover, variation of dielectric constant and dielectric loss for pure and Fe-HAp thick films are studied as a function of frequency in the range of 10 Hz–1 MHz. The study reveals that Fe doped HAp thick films improve the sensing and dielectric characteristics as compared to pure HAp.

  19. Phase formation in Zr/Fe multilayers during Kr ion irradiation.

    SciTech Connect (OSTI)

    Motta, A. T.

    1998-01-29T23:59:59.000Z

    A detailed study has been conducted of the effect of Kr ion irradiation on phase formation in Zr-Fe metallic multilayers, using the Intermediate Voltage Electron Microscopy (IVEM) at Argonne National Laboratory. Metallic multilayers were prepared with different overall compositions (near 50-50 and Fe-rich), and with different wavelengths (repetition thicknesses). These samples were irradiated with 300 keV Kr ions at various temperatures to investigate the final products, as well as the kinetics of phase formation. For the shorter wavelength samples, the final product was in all cases an amorphous Zr-Fe phase, in combination with Fe, while specially for the larger wavelength samples, in the Fe-rich samples the intermetallic compounds ZrFe{sub 2} and Zr{sub 3}Fe were formed in addition to the amorphous phase. The dose to full reaction decreases with temperature, and with wavelength in a manner consistent with a diffusion-controlled reaction.

  20. The passivation of calcite by acid mine water. Column experiments with Fe(III)- SO4-H+ and Fe(III)-Cl-H+ solutions at pH 2

    E-Print Network [OSTI]

    Boi, Marco

    2010-01-01T23:59:59.000Z

    2 (e) (a) t / tau Fe (ppm) mg Fe / g CaCO3 Fe (ppm) (b) t /tau mg Fe / g CaCO3 SO4 or Cl (eq/kg H2O) SO4 or Cl (eq/kg

  1. Exchange bias in Fe/Cr double superlattices.

    SciTech Connect (OSTI)

    Jiang, J. S.; Felcher, G. P.; Inomata, A.; Goyette, R.; Nelson, C.; Bader, S. D.

    1999-11-30T23:59:59.000Z

    Utilizing the oscillatory interlayer exchange coupling in Fe/Cr superlattices, we have constructed ''double superlattice'' structures where a ferromagnetic (F) and an antiferromagnetic (AF) Fe/Cr superlattice are coupled through a Cr spacer. The minor hysteresis loops in the magnetization are shifted from zero field, i.e., the F superlattice is exchange biased by the AF one. The double superlattices are sputter-deposited with (211) epitaxy and possess uniaxial in-plane magnetic anisotropy. The magnitude of the bias field is satisfactorily described by the classic formula for collinear spin structures. The coherent structure and insensitivity to atomic-scale roughness makes it possible to determine the spin distribution by polarized neutron reflectivity, which confirms that the spin structure is collinear. The magnetic reversal behavior of the double superlattices suggests that a realistic model of exchange bias needs to address the process of nucleating local reverse domains.

  2. Kinetics of Fe(III)*EDTA reduction by ascorbic acid

    SciTech Connect (OSTI)

    Li, W.; Harkness, J.B.L.; Mendelsohn, M.H.

    1992-12-01T23:59:59.000Z

    The kinetics of the reduction of ferric chelate by ascorbic acid have been determined at a typical flue-gas scrubber-system operating temperature ({approximately}55{degrees}C). The ascorbic acid reaction has the same reduction rate expression as the reduction by bisulfite ions, namely, first order with respect to the concentrations of both Fe(III)*EDTA and monoionic species of ascorbic acid. The reaction rate isnegative first order with respect to Fe(II)*EDTA concentration. In the pH range of 6--8, reduction of the hydrolyzed form of the metal chelate compound was negligible. The rate constant for the ascorbic acid reduction reaction is almost 400 times larger than that for the bisulfite reduction reaction under the same reaction conditions. There was no contribution associated with the nonionized form of ascorbic acid.

  3. Kinetics of Fe(III)*EDTA reduction by ascorbic acid

    SciTech Connect (OSTI)

    Li, W.; Harkness, J.B.L.; Mendelsohn, M.H.

    1992-01-01T23:59:59.000Z

    The kinetics of the reduction of ferric chelate by ascorbic acid have been determined at a typical flue-gas scrubber-system operating temperature ([approximately]55[degrees]C). The ascorbic acid reaction has the same reduction rate expression as the reduction by bisulfite ions, namely, first order with respect to the concentrations of both Fe(III)*EDTA and monoionic species of ascorbic acid. The reaction rate isnegative first order with respect to Fe(II)*EDTA concentration. In the pH range of 6--8, reduction of the hydrolyzed form of the metal chelate compound was negligible. The rate constant for the ascorbic acid reduction reaction is almost 400 times larger than that for the bisulfite reduction reaction under the same reaction conditions. There was no contribution associated with the nonionized form of ascorbic acid.

  4. Effect of tungsten addition on the toughness and hardness of Fe{sub 2}B in wear-resistant Fe-B-C cast alloy

    SciTech Connect (OSTI)

    Huang, Zhifu, E-mail: hzf@mail.xjtu.edu.cn; Xing, Jiandong; Lv, Liangliang

    2013-01-15T23:59:59.000Z

    The effects of tungsten additions of 0%, 1.12%, 2.04%, and 3.17% (in wt.%) on the morphology, fracture toughness and micro-hardness of Fe{sub 2}B in Fe-B-C cast alloy were investigated. The results indicate that, with the increase of tungsten addition, the morphology and distribution of Fe{sub 2}B have no change and a new W-containing phase, except the (Fe, W){sub 2}B with a certain tungsten solution, does not form, and that the fracture toughness of Fe{sub 2}B increases first and then decreases, while the hardness increases first and then has a little change. Compared with the fracture toughness (3.8 MPa{center_dot}m{sup 1/2}) of Fe{sub 2}B without tungsten addition, the toughness at 2.04 wt.% tungsten can be improved by about above 80% and achieves about 6.9 MPa{center_dot}m{sup 1/2}, and variation characteristics of hardness and toughness of Fe{sub 2}B were also testified by viewing the indentation marks and cracks on the Fe{sub 2}B, respectively. - Highlights: Black-Right-Pointing-Pointer Poor toughness of Fe2B decreases obviously the wear resistance of the alloy. Black-Right-Pointing-Pointer As W content increases, Fe2B's toughness increases first and then decreases. Black-Right-Pointing-Pointer As W content increases, Fe2B's hardness first increases and then has little change. Black-Right-Pointing-Pointer The toughness at 2.04 % W can be improved by above 80% more than that at 0% W.

  5. Average Fe K-alpha emission from distant AGN

    E-Print Network [OSTI]

    A. Corral; M. J. Page; F. J. Carrera; X. Barcons; S. Mateos; J. Ebrero; M. Krumpe; A. Schwope; J. A. Tedds; M. G. Watson

    2008-10-02T23:59:59.000Z

    One of the most important parameters in the XRB (X-ray background) synthesis models is the average efficiency of accretion onto SMBH (super-massive black holes). This can be inferred from the shape of broad relativistic Fe lines seen in X-ray spectra of AGN (active galactic nuclei). Several studies have tried to measure the mean Fe emission properties of AGN at different depths with very different results. We compute the mean Fe emission from a large and representative sample of AGN X-ray spectra up to redshift ~ 3.5. We developed a method of computing the rest-frame X-ray average spectrum and applied it to a large sample (more than 600 objects) of type 1 AGN from two complementary medium sensitivity surveys based on XMM-Newton data, the AXIS and XWAS samples. This method makes use of medium-to-low quality spectra without needing to fit complex models to the individual spectra but with computing a mean spectrum for the whole sample. Extensive quality tests were performed by comparing real to simulated data, and a significance for the detection of any feature over an underlying continuum was derived. We detect with a 99.9% significance an unresolved Fe K-alpha emission line around 6.4 keV with an EW ~ 90 eV, but we find no compelling evidence of any significant broad relativistic emission line in the final average spectrum. Deviations from a power law around the narrow line are best represented by a reflection component arising from cold or low-ionization material. We estimate an upper limit for the EW of any relativistic line of 400 eV at a 3 sigma confidence level. We also marginally detect the so-called Iwasawa-Taniguchi effect on the EW for the unresolved emission line, which appears weaker for higher luminosity AGN.

  6. Santa Fe Community College offers new welding program

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearch Briefs TheSanket A. Deshmukh ArgonneSanta Fe

  7. Average Fe K-alpha emission from distant AGN

    E-Print Network [OSTI]

    Corral, A; Carrera, F J; Barcons, X; Mateos, S; Ebrero, J; Krumpe, M; Schwope, A; Tedds, J A; Watson, M G

    2008-01-01T23:59:59.000Z

    One of the most important parameters in the XRB (X-ray background) synthesis models is the average efficiency of accretion onto SMBH (super-massive black holes). This can be inferred from the shape of broad relativistic Fe lines seen in X-ray spectra of AGN (active galactic nuclei). Several studies have tried to measure the mean Fe emission properties of AGN at different depths with very different results. We compute the mean Fe emission from a large and representative sample of AGN X-ray spectra up to redshift ~ 3.5. We developed a method of computing the rest-frame X-ray average spectrum and applied it to a large sample (more than 600 objects) of type 1 AGN from two complementary medium sensitivity surveys based on XMM-Newton data, the AXIS and XWAS samples. This method makes use of medium-to-low quality spectra without needing to fit complex models to the individual spectra but with computing a mean spectrum for the whole sample. Extensive quality tests were performed by comparing real to simulated data, a...

  8. Magnetoelectric nano-Fe3O4?CoFe2O4?PbZr0.53Ti0.47O3 composite

    E-Print Network [OSTI]

    Ren, Shenqiang; Wuttig, Manfred

    2008-02-26T23:59:59.000Z

    A new magnetoelectric hybrid device composed of a nanoparticulate magnetostrictive iron oxide-cobalt ferritefilm on a piezoelectric lead zirconic titanate crystal serving as both substrate and straining medium is described. Nano-Fe3O4?CoFe2O4...

  9. Focus on superconductivity in Fe-based systems

    SciTech Connect (OSTI)

    Prozorov, Ruslan; Chubukov, Andrey; Meingast, Christoph; Putti, Marina

    2012-08-03T23:59:59.000Z

    The past four years of incredibly intense research into Fe-based superconductors have brought about many unexpected surprises. Our understanding of their behavior and physical properties is constantly evolving. Unlike any other superconductors, those containing iron span diverse groups of materials: pnictides, chalcogenides, intermetallics and oxides. Some major properties of the materials are quite similar, yet each group has its own distinct features. Significant effort has been put into identifying new superconducting compositions, modifying the existing ones with new dopants and treatments, and producing single crystals, thin films, wires and polycrystalline bulk material. A wide array of experimental techniques was applied to study Fe-based superconductors and the result is a tremendous amount of data collected over a period of less than four years. Theoretical debates are still lively, and there is an ongoing search for possible universalities and commonalities with other unconventional superconductors, like high-Tc cuprates or heavy fermion materials. The three-dimensional electronic structures of Fe-based superconductors, as well as their extreme sensitivity to disorder, present serious challenges for both theoretical analysis and the interpretation of experiments. However, some key properties emerge from multiple studies. Unconventional, multiband superconductivity originating from an electronic mechanism has found both experimental and theoretical support. There has been great progress in the understanding of various anisotropies of superconducting gap structures, including the possibility of gap nodes even if the gap symmetry is s-wave. Similar to high-Tc cuprates, the superconducting phase has a dome-like shape on T-doping or T-pressure phase diagrams. The anisotropy of the superconducting gap evolves with doping and is likely to become stronger at the dome's edge. In many Fe-based superconductors there is a range where superconductivity coexists and competes with long-range magnetic order, and magnetic fluctuations are considered by some to be of the utmost importance for the pairing mechanism. Others argue that orbital fluctuations, possibly in combination with phonons, are crucial for the pairing. Fe-based superconductors show extremely large upper critical fields and relatively low electronic anisotropy, which are crucial aspects for power applications. The expectations are high, though it remains unclear what maximal current densities can be supported by a properly designed bulk material with optimal pinning centers. This focus issue of Superconductor Science and Technology is a snapshot of some of the recent progress in materials preparation, experiments and theory. It includes articles on the search for new Fe-based superconductors and on the search for superconductivity at extreme conditions. Particular attention is devoted to: the effects of chemical substitutions; the development of thin films; the introduction of artificial defects to increase critical current density; and a general analysis of vortex physics. The articles on fundamental aspects of superconductivity include: the discussion of various experimental problems; an in-depth analysis of the nodal and nodeless pairing states; the discussion of the pairing mechanism; and the effects of pair-breaking due to disorder. Also discussed are nematic correlations and the coexistence of magnetism and superconductivity. The papers collected in this issue present a detailed review of the accomplishments of the last four years of research into Fe-based superconductors, up to and including last-minute developments. We hope that this combination will make this special section of Superconductor Science and Technology both interesting and useful to a broad spectrum of physicists and materials scientists.

  10. Isolation and microbial reduction of Fe(III) phyllosilicates from subsurface sediments

    SciTech Connect (OSTI)

    Wu, Tao; Shelobolina, Evgenya S.; Xu, Huifang; Konishi, Hiromi; Kukkadapu, Ravi K.; Roden, Eric E.

    2012-10-12T23:59:59.000Z

    Fe(III)-bearing phyllosilicates can be important sources of Fe(III) for dissimilatory microbial iron reduction in clay-rich anoxic soils and sediments. The goal of this research was to isolate Fe(III) phyllosilicate phases, and if possible, Fe(III) oxide phases, from a weathered shale saprolite sediment in order to permit experimentation with each phase in isolation. Physical partitioning by density gradient centrifugation did not adequately separate phyllosilicate and Fe(III) oxide phases (primarily nanoparticulate goethite). Hence we examined the ability of chemical extraction methods to remove Fe(III) oxides without significantly altering the properties of the phyllosilicates. XRD analysis showed that extraction with oxalate alone or oxalate in the presence of added Fe(II) altered the structure of Fe-bearing phyllosilicates in the saprolite. In contrast, citrate-bicarbonate-dithionite (CBD) extraction at room temperature and 80C led to minimal alteration of phyllosilicate structures. Reoxidation of CDB-extracted sediment with H2O2 restored phyllosilicate structure (i.e. d-spacing) and redox speciation to conditions similar to that in the pristine sediment. The extent of microbial (Geobacter sulfurreducens) reduction of Fe(III) phyllosilicates isolated by CDB extraction (ca. 16 %) was comparable to what took place in pristine sediments as determined by Mossbauer spectroscopy (ca. 18 % reduction). These results suggest that materials isolated by CDB extraction and H2O2 reoxidation are appropriate targets for detailed studies of natural soil/sediment Fe(III) phyllosilicate reduction.

  11. First principles study of Fe in diamond: A diamond-based half metallic dilute magnetic semiconductor

    SciTech Connect (OSTI)

    Benecha, E. M. [Department of Physics, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa); Lombardi, E. B., E-mail: lombaeb@unisa.ac.za [College of Graduate Studies, University of South Africa, P.O. Box 392, UNISA 0003 Pretoria (South Africa)

    2013-12-14T23:59:59.000Z

    Half-metallic ferromagnetic ordering in semiconductors, essential in the emerging field of spintronics for injection and transport of highly spin polarised currents, has up to now been considered mainly in III–V and II–VI materials. However, low Curie temperatures have limited implementation in room temperature device applications. We report ab initio Density Functional Theory calculations on the properties of Fe in diamond, considering the effects of lattice site, charge state, and Fermi level position. We show that the lattice sites and induced magnetic moments of Fe in diamond depend strongly on the Fermi level position and type of diamond co-doping, with Fe being energetically most favorable at the substitutional site in p-type and intrinsic diamond, while it is most stable at a divacancy site in n-type diamond. Fe induces spin polarized bands in the band gap, with strong hybridization between Fe-3d and C-2s,2p bands. We further consider Fe-Fe spin interactions in diamond and show that substitutional Fe{sup +1} in p-type diamond exhibits a half-metallic character, with a magnetic moment of 1.0??{sub B} per Fe atom and a large ferromagnetic stabilization energy of 33?meV, an order of magnitude larger than in other semiconductors, with correspondingly high Curie temperatures. These results, combined with diamond's unique properties, demonstrate that Fe doped p-type diamond is likely to be a highly suitable candidate material for spintronics applications.

  12. Towards tailoring the magnetocaloric response in FeRh-based ternary compounds

    SciTech Connect (OSTI)

    Barua, Radhika, E-mail: barua.r@husky.neu.edu; Jiménez-Villacorta, Félix; Lewis, L. H. [Department of Chemical Engineering, Northeastern University, Boston, Massachusetts 02115 (United States)

    2014-05-07T23:59:59.000Z

    In this work, we demonstrate that the magnetocaloric response of FeRh-based compounds may be tailored for potential magnetic refrigeration applications by chemical modification of the FeRh lattice. Alloys of composition Fe(Rh{sub 1?x}A{sub x}) or (Fe{sub 1?x}B{sub x})Rh (A?=?Cu, Pd; B?=?Ni; 0?FeRh-based systems were determined using isothermal M(H) curves measured in the vicinity of the magnetostructural temperature (T{sub t}). It is found that the FeRh working temperature range (?T{sub FWHM}) may be chemically tuned over a wide temperature range, 100?K???T???400?K. While elemental substitution consistently decreases the magnetic entropy change (?S{sub mag}) of the FeRh-based ternary alloys from that of the parent FeRh compound (?S{sub mag},{sub FeRh}???17?J/kg?K; ?S{sub mag,FeRh-ternary?=}?7–14?J/kg?K at H{sub app}?=?2?T), the net refrigeration capacity (RC), defined as the amount of heat that can be transferred during one magnetic refrigeration cycle, of the modified systems is significantly higher (RC{sub FeRh}???150?J/kg; RC{sub FeRh-ternary?=}?170–210?J/kg at H{sub app}?=?2?T). These results are attributed to stoichiometry-induced changes in the FeRh electronic band structure and beneficial broadening of the magnetostructural transition due to local chemical disorder.

  13. STORAGE RING CROSS SECTION MEASUREMENTS FOR ELECTRON IMPACT SINGLE AND DOUBLE IONIZATION OF Fe{sup 13+} AND SINGLE IONIZATION OF Fe{sup 16+} AND Fe{sup 17+}

    SciTech Connect (OSTI)

    Hahn, M.; Novotny, O.; Savin, D. W. [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)] [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States); Becker, A.; Grieser, M.; Krantz, C.; Repnow, R.; Wolf, A. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany)] [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Bernhardt, D.; Mueller, A.; Schippers, S.; Spruck, K. [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany)] [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany); Lestinsky, M. [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany)] [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany)

    2013-04-10T23:59:59.000Z

    We report measurements of electron impact ionization for Fe{sup 13+}, Fe{sup 16+}, and Fe{sup 17+} over collision energies from below threshold to above 3000 eV. The ions were recirculated using an ion storage ring. Data were collected after a sufficiently long time that essentially all the ions had relaxed radiatively to their ground state. For single ionization of Fe{sup 13+}, we find that previous single pass experiments are more than 40% larger than our results. Compared to our work, the theoretical cross section recommended by Arnaud and Raymond is more than 30% larger, while that of Dere is about 20% greater. Much of the discrepancy with Dere is due to the theory overestimating the contribution of excitation-autoionization via n = 2 excitations. Double ionization of Fe{sup 13+} is dominated by direct ionization of an inner shell electron accompanied by autoionization of a second electron. Our results for single ionization of Fe{sup 16+} and Fe{sup 17+} agree with theoretical calculations to within the experimental uncertainties.

  14. Refined model of the {Fe9} magnetic molecule from low-temperature inelastic neutron scattering studies

    SciTech Connect (OSTI)

    Engelhardt, Larry [Francis Marion University; Demmel, Franz [Rutherford Appleton Laboratory; Luban, Marshall [Ames Laboratory; Timco, Grigore A [The University of Manchester; Tuna, Floriana [The University of Manchester; Winpenny, Richard E [The University of Manchester

    2014-06-01T23:59:59.000Z

    We present a refined model of the {Fe9} tridiminished icosahedron magnetic molecule system. This molecule was originally modeled as being composed of two ({Fe3} and {Fe6}) clusters, with the Fe3+ ions within each cluster being coupled via exchange interactions, but with no coupling between the clusters. The present inelastic neutron scattering (INS) measurements were used to probe the low-lying energy spectrum of {Fe9}, and these results demonstrate that the previously published model of two uncoupled clusters is incomplete. To achieve agreement between the experiment and theory, we have augmented the model with relatively small exchange coupling between the clusters. A combination of Lanczos matrix diagonalization and quantum Monte Carlo simulations have been used to achieve good agreement between the experimental data and the improved model of the full {Fe9} system despite the complexity of this model (with Hilbert space dimension >107).

  15. Cation self-diffusion in Fe/sub 2/O/sub 3/

    SciTech Connect (OSTI)

    Hoshino, K.; Peterson, N.L.

    1984-01-01T23:59:59.000Z

    Self-diffusion of /sup 59/Fe in single crystals of Fe/sub 2/O/sub 3/ parallel to the c-axis has been measured as a function of temperature (1150 to 1340/sup 0/C) and oxygen partial pressure (2 x 10/sup -3/) less than or equal to Po/sub 2/ less than or equal to 1 atm). The oxygen partial pressure dependence of the diffusivity indicates that cation self-diffusion occurs by an interstitial-type mechanism. The simultaneous diffusion of /sup 52/Fe and /sup 59/Fe has been measured in Fe/sub 2/O/sub 3/ at 1251/sup 0/C and Po/sub 2/ = 1.91 x 10/sup -2/ atm. The small value of the isotope effect (f..delta..K = 0.067 +- 0.016) is consistent with diffusion of Fe ions by an interstitially mechanism.

  16. Development of an Fe efficiency screening procedure for sorghum based on realistic soil parameters 

    E-Print Network [OSTI]

    Hernandez, Francisco

    1987-01-01T23:59:59.000Z

    , are considered to be good indicators of Fe use efficiency in plants, and thus were the basis determining Fe-efficiency of the sorghum cultivars. Rodriguez de Cianzio et al. (1979) reported that visual chlorosis ratings weze highly correlated (r=0. 90...DEVELOPMENT OF AN FE EFFICIENCY SCREENING PROCEDURE FOR SORGHUH BASED ON REAl ISTIC SOIL PARAHETERS A Thesis by FRANCISCO HERNANDEZ Submitted to the Graduate College of Texas ASH University in partial fulfillment of the requirements...

  17. Corrosion behavior of newly developed TiAgFe dental alloys in neutral saline solution

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion behavior of newly developed Ti­Ag­Fe dental alloys in neutral saline solution B. B. Zhang, B. L. Wang, L. Li and Y. F. Zheng* The corrosion behavior of Ti­5Ag­xFe alloys (x ¼ 1, 2.5, 5 wt) Ti,Ti­ 5Ag­xFe alloys exhibited higher corrosion potentials, lower current densities, and larger

  18. The impact of alpha/Fe enhanced stellar evolutionary tracks on the ages of elliptical galaxies

    E-Print Network [OSTI]

    Daniel Thomas; Claudia Maraston

    2003-02-04T23:59:59.000Z

    We complement our study of alpha/Fe enhanced stellar population models of Lick absorption indices (Thomas et al. 2003) by comparing two sets of alpha/Fe enhanced models. In both models the impact on Lick indices due to alpha/Fe enhancement is accounted for through a modification of the stellar absorption line-strengths using the response functions of Tripicco & Bell (1995). One set of models, however, uses solar-scaled, the other alpha/Fe enhanced stellar evolutionary tracks. Since the alpha/Fe enhanced tracks are hotter than the solar-scaled ones (Salasnich et al. 2000), the correspondent stellar population models have slightly weaker metallic indices (i.e. Mgb, etc.) and stronger Balmer line indices (Hbeta) (Maraston et al 2003). Here we explore quantitatively the impact of this effect on the alpha/Fe ratios, metallicities and ages that are derived for elliptical galaxies. We find that the modest decrease of the metallic indices Mgb and balance each other, such that fully consistent alpha/Fe ratios are derived for stellar systems using alpha/Fe enhanced models with either solar-scaled or alpha/Fe enhanced stellar tracks. The decrease of the metallic indices and the increase of Hbeta conspire in a way that also consistent metallicities are obtained. The derived ages, instead, are significantly different. The inclusion of alpha/Fe enhanced stellar tracks leads to the derivation of ages as high as 30 Gyr for elliptical galaxies. For the same objects, ages not older than 15 Gyr are obtained, if alpha/Fe enhanced models using solar-scaled tracks are adopted. This may indicate that current stellar evolutionary models overestimate the bluing of stellar evolutionary tracks due to alpha/Fe enhanced chemical mixtures at super-solar metallicities.

  19. Controlling ferromagnetism of (In,Fe)As semiconductors by electron doping

    SciTech Connect (OSTI)

    Dang Vu, Nguyen; Fukushima, Tetsuya; Katayama-Yoshida, Hiroshi [Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531 (Japan); Sato, Kazunori [Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)

    2014-02-21T23:59:59.000Z

    Based on experimental results, using the Korringa-Kohn-Rostoker coherent potential approximation (KKR-CPA) method and Monte Carlo simulation, we study the mechanism of ferromagnetic behavior of (In,Fe)As. We show that with doped Be atoms occupying in interstitial sites, chemical pair interactions between atoms and magnetic exchange interactions between Fe atoms change due to electron concentration. Therefore, by controlling the doping process, magnetic behavior of (In,Fe)As is controlled and ferromagnetism is observed in this semiconductor.

  20. The reaction of Fe and Ni at intermediate energies

    E-Print Network [OSTI]

    Liddick, Sean Nicholas

    2013-02-22T23:59:59.000Z

    of the LtVrIVERSITY UNDERGRADUATE RESEARCH FEI LOtVS April 2001 Group. Physical Sciences THE REACTION OF Fe AND Vi AT IlvTFRMEDIATE ENERGIFS A Senior Honors Thesis B& SEAN NICHOLAS I. IDDICK Submitted to the Office of Honors Progran & Academic..., and the energy of the incident beam. Sean Nicholas Liddick Department of Chemistry Texas AilcM University Fellows Advisor: Dr, Sherry Yennello Department of Chemistry TABLE OF CONTFNTS ABSTRACT Page i 1 i TABI E OF CONTENTS. LIST OF FIGURES...

  1. Cu-Ni-Fe anodes having improved microstructure

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.

    2004-04-20T23:59:59.000Z

    A method of producing aluminum in a low temperature electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten electrolyte having alumina dissolved therein in an electrolytic cell containing the electrolyte. A non-consumable anode and cathode is disposed in the electrolyte, the anode comprised of Cu--Ni--Fe alloys having single metallurgical phase. Electric current is passed from the anode, through the electrolyte to the cathode thereby depositing aluminum on the cathode, and molten aluminum is collected from the cathode.

  2. Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, K.; Baxter, D.J.

    1983-07-26T23:59:59.000Z

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

  3. Oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, Ken (Naperville, IL); Baxter, David J. (Woodridge, IL)

    1984-01-01T23:59:59.000Z

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

  4. Nonlinear FE analysis of cracks in tension and shear

    E-Print Network [OSTI]

    Kesse, G.; Lees, Janet M.

    2007-05-01T23:59:59.000Z

    Carbon FRP Shear Reinforcement. PhD thesis, University of Cambridge, UK, 2003. 3. Bazant Z. P. and Planas J. Fracture and Size Effect in Con- crete and Other Quasibrittle Materials. CRC Press, Boca Raton, Florida, 1998. Nonlinear FE analysis of cracks... of plain concrete to cyclic tension. ACI Materials Journal, 1987, 84, No. 5, 365–373. 9. Paulay T. and Loeber P. J. Shear transfer by aggregate inter- lock. ACI Special Publication, SP-42, 1974, 1, 1–14. 10. Houde J. and Mirza M. S. A finite element...

  5. Inelastic scattering of fast neutrons from $^{56}$Fe

    E-Print Network [OSTI]

    Beyer, R; Hannaske, R; Junghans, A R; Massarczyk, R; Anders, M; Bemmerer, D; Ferrari, A; Kögler, T; Röder, M; Schmidt, K; Wagner, A

    2014-01-01T23:59:59.000Z

    Inelastic scattering of fast neutrons from $^{56}$Fe was studied at the photoneutron source nELBE. The neutron energies were determined on the basis of a timeof- flight measurement. Gamma-ray spectra were measured with a high-purity germanium detector. The total scattering cross sections deduced from the present experiment in an energy range from 0.8 to 9.6 MeV agree within 15% with earlier data and with predictions of the statistical-reaction code Talys.

  6. Balmer Absorption Lines in FeLoBALs

    E-Print Network [OSTI]

    K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

    2006-12-14T23:59:59.000Z

    We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

  7. Startup Funding Forum on October 18 in Santa Fe

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary900 SpecialNanoparticulate FeS asEnzyme2ResidualStartup

  8. FE FY 2016 BUDGET REQUEST PRESENTATION | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdfFE DOCKET NO. 11-59-LNGFE

  9. FE Implementation of the Recovery Act | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdfFE DOCKET NO.

  10. FE Oil and Natural Gas News | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic Plan| Department of Energy 088:EnergyFAR27.pdfFE DOCKET NO.Oil and

  11. Los Alamos National Security invests in Santa Fe Community College

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5LetLooking5invests in Santa Fe Community College

  12. AgFe Management Ltd | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-fTriWildcat 1AMEE JumpAeroWind Inc.Information AfluenteAg Fuels LtdAgFe

  13. SF 6432-FE Fixed Price Contracts Outside the US

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobs RunningSEAB ReportsFE (04/2015) SECTION II

  14. FE Leaders Discuss African Energy Development | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy Chinaof EnergyImpactOn Chapter 42.15Mechanical14, 2011 CX-006821:8,AugustFE's

  15. Santa Fe Chamber of Commerce Business Awards Gala

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiationImplementingnpitcheResearch Briefs TheSanket A. Deshmukh ArgonneSanta Fe Chamber

  16. Magnetization, magnetic susceptibility, effective magnetic moment of Fe{sup 3+} ions in Bi{sub 25}FeO{sub 39} ferrite

    SciTech Connect (OSTI)

    Zatsiupa, A.A., E-mail: zatsiupa@mail.ru [Belarussian State Technological University, 220030 Minsk (Belarus); Bashkirov, L.A. [Belarussian State Technological University, 220030 Minsk (Belarus); Troyanchuk, I.O. [Scientific and Practical Materials Research Centre of the NAS of Belarus, 220072 Minsk (Belarus); Petrov, G.S. [Belarussian State Technological University, 220030 Minsk (Belarus); Galyas, A.I.; Lobanovsky, L.S.; Truhanov, S.V. [Scientific and Practical Materials Research Centre of the NAS of Belarus, 220072 Minsk (Belarus)

    2014-04-01T23:59:59.000Z

    Magnetic susceptibility for ferrite Bi{sub 25}FeO{sub 39} is measured at 5–950 K in the magnetic field of 0.86 T. It is shown that Bi{sub 25}FeO{sub 39} is paramagnetic in the temperature range 5?950 K. The saturation magnetization is equal to 5.04?{sub B} per formula unit at 5 K in a magnetic field of 10 T. It is found that at 5?300 K the effective magnetic moment of Fe{sup 3+} ions in Bi{sub 25}FeO{sub 39} is equal to 5.82?{sub B}. - Graphical abstract: The dependence of the magnetization (n, ?{sub B}) on the magnetic field for one formula unit of Bi{sub 25}FeO{sub 39} at 5 K. - Highlights: • Magnetic susceptibility for Bi{sub 25}FeO{sub 39} is measured at 5–950 K in the magnetic field of 0.86 T. • It is shown that Bi{sub 25}FeO{sub 39} is paramagnetic in the temperature range 5?950 K. • The saturation magnetization is equal to 5.04?{sub B} per formula unit at 5 K in a magnetic field of 10 T.

  17. Effect of CoFe insertion in Co{sub 2}MnSi/CoFe/n-GaAs junctions on spin injection properties

    SciTech Connect (OSTI)

    Ebina, Yuya; Akiho, Takafumi; Liu, Hong-xi; Yamamoto, Masafumi; Uemura, Tetsuya, E-mail: uemura@ist.hokudai.ac.jp [Division of Electronics for Informatics, Graduate School of Information Science and Technology, Hokkaido University, Sapporo 060-0814 (Japan)

    2014-04-28T23:59:59.000Z

    The CoFe thickness (t{sub CoFe}) dependence of spin injection efficiency was investigated for Co{sub 2}MnSi/CoFe/n-GaAs junctions. The ?V{sub NL}/I value, which is a measure of spin injection efficiency, strongly depended on t{sub CoFe}, where ?V{sub NL} is the amplitude of a nonlocal spin-valve signal, and I is an injection current. Importantly, the maximum value of ?V{sub NL}/I for a Co{sub 2}MnSi/CoFe/n-GaAs junction was one order of magnitude higher than that for a CoFe/n-GaAs junction, indicating that a Co{sub 2}MnSi electrode works as a highly polarized spin source. No clear spin signal, on the other hand, was observed for a Co{sub 2}MnSi/n-GaAs junction due to diffusion of Mn atoms into the GaAs channel. Secondary ion mass spectrometry analysis indicated that the CoFe insertion effectively suppressed the diffusion of Mn into GaAs, resulting in improved spin injection properties compared with those for a Co{sub 2}MnSi/n-GaAs junction.

  18. Magnetic structures and interplay between rare-earth Ce and Fe magnetism in single-crystal CeFeAsO

    SciTech Connect (OSTI)

    Zhang, Qiang [Ames Laboratory; Tian, Wei [Ames Laboratory; Li, Haifeng [Ames Laboratory; Kim, Jong-Woo [Argonne Naitonal Laboratory; Yan, Jiaqiang [Ames Laboratory; McCallum, Robert William [Ames Laboratory; Lograsso, Thomas A. [Ames Laboratory; Zarestky, Jerel L. [Ames Laboratory; Budko, Sergey L. [Ames Laboratory; McQueeney, Robert J. [Ames Laboratory; Vaknin, David [Ames Laboratory

    2013-11-27T23:59:59.000Z

    Neutron and synchrotron resonant x-ray magnetic scattering (RXMS) complemented by heat capacity and resistivity measurements reveal the evolution of the magnetic structures of Fe and Ce sublattices in a CeFeAsO single crystal. The RXMS of magnetic reflections at the Ce LII edge shows a magnetic transition that is specific to the Ce antiferromagnetic long-range ordering at TCe? 4 K with short-range Ce ordering above TCe, whereas neutron diffraction measurements of a few magnetic reflections indicate a transition at T?? 12 K with an unusual order parameter. Detailed order-parameter measurements on several magnetic reflections by neutrons show a weak anomaly at 4 K that we associate with the Ce ordering. The successive transitions at TCe and T? can also be clearly identified by two anomalies in heat capacity and resistivity measurements. The higher transition temperature at T?? 12 K is mainly ascribed to Fe spin reorientation transition, below which Fe spins rotate uniformly and gradually in the ab plane. The Fe spin reorientation transition and short-range Ce ordering above TCe reflect the strong Fe-Ce couplings prior to long-range ordering of the Ce. The evolution of the intricate magnetic structures in CeFeAsO going through T? and TCe is proposed.

  19. The Role of FeS in Initial Activation and Performance Degradation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optimum level of FeS in the cathode resulted in minimum Ni particle growth and improved battery cycling performance. The results of electrochemical characterization indicated...

  20. Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

    SciTech Connect (OSTI)

    Hong, Yongchun; Zhang, He; Sun, Junming; Karim, Ayman M.; Hensley, Alyssa; Gu, Meng; Engelhard, Mark H.; McEwen, Jean-Sabin; Wang, Yong

    2014-10-31T23:59:59.000Z

    In this work, a series of Pd/Fe2O3 catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity towards the production of toluene (C-O cleavage without saturation of aromatic ring and C-C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray absorption near edge fine structure (XANES). A possible mechanism, including Pd assisted H2 dissociation and Pd facilitated stabilization of metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd-Fe catalysts. The synergic catalysis derived from Pd-Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.

  1. Mass Measurements of Proton-Rich Nuclei Fe-50 and Ni-54 

    E-Print Network [OSTI]

    Tribble, Robert E.; Cossairt, J. D.; May, D. P.; Kenefick, R. A.

    1977-01-01T23:59:59.000Z

    PHYSICAL REUIE% C VOLUME 16, N UMBER 2 AUGUST 1977 Mess measurements of' the proton-rich nuciei Fe and ~Nit R. E. Tribble, ~ J. D. Cossairt, D. P. May, and R. A. Kenefick Cyclotron Institute and Physics Department, Texas A AM University, College... Station, Texas 77843 {Received 6 December 1976) The reactions "Fe{'He,'He)' Fe and "Ni{'He,'He)"Ni have been observed at an incident a energy of 110 MeV. The reaction Q values are found to be Q{ Fe) = ?50.95 + 0.06 MeV and Q{' Ni) = ?50.19 + 0.05 Me...

  2. Electrochemical performance of Sol-Gel synthesized LiFePO4 in lithium batteries

    E-Print Network [OSTI]

    Hu, Yaoqin; Doeff, Marca M.; Kostecki, Robert; Finones, Rita

    2003-01-01T23:59:59.000Z

    LiFePO 4 in Lithium Batteries Yaoqin Hu,* Marca M. Doeff,*material in lithium ion batteries based on environmental and

  3. Nanostructure evolution in joining of Al and Fe nanoparticles with femtosecond laser irradiation

    SciTech Connect (OSTI)

    Jiao, Z. [State Key Laboratory of Advanced Welding Production Technology, Harbin Institute of Technology, Harbin 150001 (China); Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Huang, H.; Zhou, Y., E-mail: hepeng@hit.edu.cn, E-mail: nzhou@uwaterloo.ca [Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Liu, L. [Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China); Hu, A. [Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Mechanical, Aerospace, and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37916 (United States); Duley, W. [Centre for Advanced Materials Joining, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); Department of Physics and Astronomy, University of Waterloo, Waterloo, Ontario N2L 3G1 (Canada); He, P., E-mail: hepeng@hit.edu.cn, E-mail: nzhou@uwaterloo.ca [State Key Laboratory of Advanced Welding Production Technology, Harbin Institute of Technology, Harbin 150001 (China)

    2014-04-07T23:59:59.000Z

    The joining of Al-Fe nanoparticles (NPs) by femtosecond (fs) laser irradiation is reported in this paper. Fe and Al NPs were deposited on a carbon film in vacuum via fs laser ablation. Particles were then exposed to multiple fs laser pulses at fluences between 0.5 and 1.3?mJ/cm{sup 2}. Transmission Electron Microscopy (TEM) and Electron Diffraction X-ray observations indicate that Al and Fe NPs bond to each other under these conditions. For comparison, bonding of Al to Al and Fe to Fe NPs was also investigated. The nanostructure, as observed using TEM, showed that individual Al NPs were monocrystalline while individual Fe NPs were polycrystalline prior to joining and that these structures are retained after the formation of Al-Al and Fe-Fe NPs. Al-Fe NPs produced by fs laser joining exhibited a mixed amorphous and crystalline phase at the interface. Bonding is suggested to originate from intermixing within a region of high field intensity between particles.

  4. SciTech Connect: A Solution for Solution-Produced [beta]-FeSe...

    Office of Scientific and Technical Information (OSTI)

    A Solution for Solution-Produced beta-FeSe: Elucidating and Overcoming Factors that Prevent Superconductivity Citation Details In-Document Search Title: A Solution for...

  5. Origin of room temperature ferromagnetic moment in Rh-rich Rh/Fe multilayer thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    films of FeRh was done by electron beam melting on amorphous substrates3 but the low extent of ordering

  6. HIGH RESOLUTION SCANNING AUGER MICROSCOPIC INVESTIGATION OF INTERGRANULAR FRACTURE IN AS-QUENCHED Fe-12Mn

    E-Print Network [OSTI]

    Lee, H.J.

    2013-01-01T23:59:59.000Z

    contents in Fe-Mn alloys. Scanning electron fractographsTransactions HIGH RESOLUTION SCANNING AUGER MICROSCOPICof Califomia. HIGH RESOLUTION SCANNING AUGER MICROSCOPIC

  7. Connecting Observations of Hematite (a Fe2O3) Growth Catalyzed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structural Fe(III) in iron oxides and oxyhydroxides is important for understanding degradation of environmental pollutants through its apparent constitutive role underlying...

  8. Preservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with organic material from nearby flora and fauna. The collaboration suggests that the organic matrices prevent oxidation and precipitation of the Fe(II), perhaps increasing...

  9. Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Fe(II) to sequester Tc present in both deionized water and simulated off-gas scrubber waste solutions. Pertechnetate concentration in solution decreased immediately when...

  10. Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

    E-Print Network [OSTI]

    Shim, J.; Guerfi, A.; Zaghib, K.; Striebel, K.A.

    2003-01-01T23:59:59.000Z

    Effect of Conductive Additives in LiFePO 4 Cathode forcapacity on conductive additive content and specificthe amount of conductive additive increases. The addition of

  11. Phonon densities of states of face-centered-cubic Ni-Fe alloys

    SciTech Connect (OSTI)

    Lucas, Matthew [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Mauger, L [California Institute of Technology, W. M. Keck Laboratory, Pasadena] [California Institute of Technology, W. M. Keck Laboratory, Pasadena; Munoz, Jorge A. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Halevy, I [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena; Horwath, J [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Semiatin, S L [United States Air Force Research Laboratory, Wright-Patterson Air Force Base] [United States Air Force Research Laboratory, Wright-Patterson Air Force Base; Leontsev, S. O. [University of Kentucky, Lexington] [University of Kentucky, Lexington; Stone, Matthew B [ORNL] [ORNL; Abernathy, Douglas L [ORNL] [ORNL; Xiao, Yuming [Carnegie Institution of Washington] [Carnegie Institution of Washington; Chow, P [HPCAT Geophysical Lab, Argonne, IL] [HPCAT Geophysical Lab, Argonne, IL; Fultz, B. [California Institute of Technology, Pasadena] [California Institute of Technology, Pasadena

    2013-01-01T23:59:59.000Z

    Inelastic neutron scattering and nuclear resonant inelastic x-ray scattering were used to determine the phonon densities of states of face-centered-cubic Ni-Fe alloys. Increasing Fe concentration results in an average softening of the phonon modes. Chemical ordering of the Ni0.72Fe0.28 alloy results in a reduction of the partial vibrational entropy of the Fe atoms but does not significantly change the partial vibrational entropy of the Ni atoms. Changes in the phonon densities of states with composition and chemical ordering are discussed and analyzed with a cluster expansion method.

  12. Structural, thermodynamic, mechanical, and magnetic properties of FeW system

    SciTech Connect (OSTI)

    Ren, Q. Q.; Fan, J. L.; Han, Y.; Gong, H. R., E-mail: gonghr@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China)

    2014-09-07T23:59:59.000Z

    The Fe-W system is systematically investigated through a combined use of first-principles calculation, cluster expansion, special quasirandom structures, and experiments. It is revealed that the ferromagnetic state of BCC Fe-W solid solution has lower heat of formation than its nonmagnetic state within the entire composition range, and intermetallic ?-Fe{sub 2}W and ?-Fe{sub 7}W{sub 6} phases are energetically favorable with negative heats of formation. Calculations also show that the Fe-W solid solution has much lower coefficient of thermal expansion than its mechanical mixture, and that the descending sequence of temperature-dependent elastic moduli of each Fe-W solid solution is E?>?G?>?B. Moreover, magnetic state should have an important effect on mechanical properties of Fe-W phases, and electronic structures can provide a deeper understanding of various properties of Fe-W. The derived results agree well with experimental observations, and can clarify two experimental controversies regarding structural stability and magnetic property of Fe-W phases in the literature.

  13. Improvement of SOFC Electrodes through Catalyst Infiltration & Control of Cr Volatilization from FeCr Components

    SciTech Connect (OSTI)

    Visco, S.J.; Jacobson, C.; Kurokawa, H.; Sholklapper, T.; Lu, C.; De Jonghe, L.

    2005-01-28T23:59:59.000Z

    This presentation discusses the improvement of SOFC electrodes through catalyst infiltration and control of Cr volatilization from FeCr components.

  14. Search for Resonant Absorption of Solar Axions Emitted in M1 Transition in $^{57}$Fe Nuclei

    E-Print Network [OSTI]

    A. V. Derbin; A. I. Egorov; I. A. Mitropol'sky; V. N. Muratova; D. A. Semenov; E. V. Unzhakov

    2009-06-01T23:59:59.000Z

    A search for resonant absorbtion of 14.4 keV solar axions by $^{57}$Fe target was performed. The Si(Li) detector placed inside the low-background setup was used to detect the $\\gamma$-quanta appearing in the deexcitation of 14.4 keV nuclear level: $A+\\rm{^{57}Fe} \\to \\rm{^{57}Fe^{*}} \\to \\rm{^{57}Fe} + \\gamma$. The new upper limit for the hadronic axion mass have been obtained: $m_{A} \\leq 151$ eV (90% C.L.) ($S$=0.5, $z$=0.56).

  15. CONTROL OF FE(III) SITE OCCUPANCY ON THE RATE AND EXTENT OF MICROBIAL REDUCTION OF FE(III) IN NONTRONITE

    SciTech Connect (OSTI)

    Jaisi, Deb P.; Kukkadapu, Ravi K.; Eberl, Dennis D.; Dong, Hailiang

    2005-12-01T23:59:59.000Z

    A quantitative study was performed to understand how Fe(III) site occupancy controls Fe(III) bioreduction in nontronite by Shewanella putrefaciens CN32. NAu-1 and NAu-2 were nontronites and contained Fe(III) in different structure sites with 16% and 23% total iron (w/w), respectively, with almost all iron as Fe(III). Moessbauer spectroscopy showed that Fe(III) was present in the octahedral site in NAu-1 (with a small amount of goethite), but in both the tetrahedral and the octahedral sites in NAu-2. Moessbauer data further showed that the octahedral Fe(III) in NAu-2 existed in at least two environments- trans (M1) and cis (M2) sites. The microbial Fe(III) reduction in NAu-1 and NAu-2 was studied in batch cultures at a nontronite concentration of 5mg/mL in bicarbonate buffer with lactate as the electron donor. Fe(II) production in inoculated treatments was determined by extraction with 0.5 N HCl and compared to uninoculated controls to establish the extent of biological reduction. The resulting solids were characterized by X-ray diffraction (XRD), Moessbauer spectroscopy, and transmission electron microscopy (TEM). In the presence of an electron shuttle, anthraquinone-2,6-disulfonate (AQDS), the extent of bioreduction was 11-16% for NAu-1 but 28-32% for NAu-2. The extent of reduction in the absence of AQDS was only 5-7% in NAu-1 but 14-18% in NAu-2. The reduction rate was also faster in NAu-2 than that in NAu-1. Moessbauer data of the bioreduced nontronite materials indicated that the Fe(III) reduction in NAu-1 was mostly from the presence of goethite, whereas the reduction in NAu-2 was due to the presence of the tetrahedral and trans-octahedral Fe(III) in the structure. The measured aqueous Fe(II) was negligible [< 2.5% of the total biogenic Fe(II)]. As a result of bioreduction, the average nontronite particle thickness remained nearly the same (from 2.1 to 2.5 nm) for NAu-1, but decreased significantly from 6 to 3.5 nm for NAu-2 with a concomitant change in crystal size distribution. The decrease in crystal size suggests reductive dissolution of nontronite NAu-2, which was supported by aqueous solution chemistry (i.e., aqueous Si). These data suggest that the more extensive Fe(III) bioreduction in NAu-2 was due to the presence of the tetrahedral and the trans-octahedral Fe(III), which was presumed to be more reducible. The biogenic Fe(II) was not associated with biogenic solids such as siderite or green rust or in the aqueous solution. We infer that it may be either adsorbed onto surfaces of nontronite particles/bacteria and in the structure of nontronite. Furthermore, we have demonstrated that natural nontronite clays were capable of supporting cell growth even in non-growth medium, possibly due to presence of naturally existing nutrients in the nontronite clays. These results suggest that crystal chemical environment of Fe(III) is an important determinant in controlling the rate and extent of microbial reduction of Fe(III) in nontronite.

  16. Proton spectroscopy of 48Ni, 46Fe, and 44Cr

    E-Print Network [OSTI]

    M. Pomorski; M. Pfützner; W. Dominik; R. Grzywacz; A. Stolz; T. Baumann; J. S. Berryman; H. Czyrkowski; R. D?browski; A. Fija?kowska; T. Ginter; J. Johnson; G. Kami?ski; N. Larson; S. N. Liddick; M. Madurga; C. Mazzocchi; S. Mianowski; K. Miernik; D. Miller; S. Paulauskas; J. Pereira; K. P. Rykaczewski; S. Suchyta

    2014-07-06T23:59:59.000Z

    Results of decay spectroscopy on nuclei in vicinity of the doubly magic 48Ni are presented. The measurements were performed with a Time Projection Chamber with optical readout which records tracks of ions and protons in the gaseous volume. Six decays of 48Ni including four events of two-proton ground-state radioactivity were recorded. An advanced reconstruction procedure yielded the 2p decay energy for 48Ni of Q2p = 1.29(4) MeV. In addition, the energy spectra of \\b{eta}-delayed protons emitted in the decays of 44Cr and 46Fe, as well as half-lives and branching ratios were determined. The results were found to be consistent with the previous measurements made with Si detectors. A new proton line in the decay of 44Cr corresponding to the decay energy of 760 keV is reported. The first evidence for the \\b{eta}2p decay of 46 Fe, based on one clear event, is shown.

  17. Postirradiation deformation of ferritic Fe-Cr binary alloys

    SciTech Connect (OSTI)

    Hamilton, M.L.; Gelles, D.S.

    1991-06-01T23:59:59.000Z

    Six binary Fe-Cr alloys ranging from 3 to 18% chromium were irradiated in the form of miniature tensile specimens in the Fast Flux Test Facility and tested at room temperature. The irradiation conditions produced 7 to 30 dpa at 365 to 574{degrees}C. The major purpose of the experiment was to compare the behavior of these simple alloys with that of more complex commercial alloys, The tensile data obtained on these specimens at room temperature are discussed with appropriate fractographic and microstructural support. Previous studies on similar materials had revealed the presence of a feature typically exhibited in channel fractures: elongated voids were evident in shear bands of an irradiated and deformed TEM disk of a binary Fe-6Cr alloy. An additional purpose of the experiment was therefore to provide a better understanding of the potential contribution of channel fracture to deformation in ferritic alloys. No evidence for channel fracture was found, however. 14 refs., 6 figs., 2 tabs.

  18. Si and Fe depletion in Galactic star-forming regions observed by the Spitzer Space Telescope

    E-Print Network [OSTI]

    Yoko Okada; Takashi Onaka; Takashi Miyata; Yoshiko K. Okamoto; Itsuki Sakon; Hiroshi Shibai; Hidenori Takahashi

    2008-04-10T23:59:59.000Z

    We report the results of the mid-infrared spectroscopy of 14 Galactic star-forming regions with the high-resolution modules of the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. We detected [SiII] 35um, [FeII] 26um, and [FeIII] 23um as well as [SIII] 33um and H2 S(0) 28um emission lines. Using the intensity of [NII] 122um or 205um and [OI] 146um or 63um reported by previous observations in four regions, we derived the ionic abundance Si+/N+ and Fe+/N+ in the ionized gas and Si+/O0 and Fe+/O0 in the photodissociation gas. For all the targets, we derived the ionic abundance of Si+/S2+ and Fe2+/S2+ for the ionized gas. Based on photodissociation and HII region models the gas-phase Si and Fe abundance are suggested to be 3-100% and solar abundance, respectively, for the ionized gas and 16-100% and 2-22% of the solar abundance, respectively, for the photodissociation region gas. Since the [FeII] 26um and [FeIII] 23um emissions are weak, the high sensitivity of the IRS enables to derive the gas-phase Fe abundance widely in star-forming regions. The derived gas-phase Si abundance is much larger than that in cool interstellar clouds and that of Fe. The present study indicates that 3-100% of Si atoms and <22% of Fe atoms are included in dust grains which are destroyed easily in HII regions, probably by the UV radiation. We discuss possible mechanisms to account for the observed trend; mantles which are photodesorbed by UV photons, organometallic complexes, or small grains.

  19. Role of cross-shell excitations in the reaction 54Fe(d_pol,p)55Fe

    E-Print Network [OSTI]

    M. Mahgoub; R. Kruecken; Th. Faestermann; A. Bergmaier; D. Bucurescu; R. Hertenberger; Th. Kroell; H. -F. Wirth; A. F. Lisetskiy

    2009-01-13T23:59:59.000Z

    The reaction 54Fe(d_pol,p)55Fe was studied at the Munich Q3D spectrograph with a 14 MeV polarized deuteron beam. Excitation energies, angular distributions and analyzing powers were measured for 39 states up to 4.5 MeV excitation energy. Spin and parity assignments were made and spectroscopic factors deduced by comparison to DWBA calculations. The results were compared to predictions by large scale shell model calculations in the full pf-shell and it was found that reasonable agreement for energies and spectroscopic factors below 2.5 MeV could only be obtained if up to 6 particles were allowed to be excited from the f_7/2 orbital into p_3/2, f_5/2, and p_1/2 orbitals across the N=28 gap. For levels above 2.5 MeV the experimental strength distribution was found to be significantly more fragmented than predicted by the shell model calculations.

  20. Itinerant electrons, local moments, and magnetic correlations in the pnictide superconductors CeFeAsO??xFxand Sr(Fe??xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vilmercati, Paolo; Fedorov, Alexei; Bondino, Federica; Offi, Francesco; Panaccione, Giancarlo; Lacovig, Paolo; Simonelli, Laura; McGuire, Michael A.; Sefat, Athena S. M.; Mandrus, David; Sales, Brian C.; Egami, Takeshi; Ku, Wei; Mannella, Norman

    2012-06-01T23:59:59.000Z

    A direct and element-specific measurement of the local Fe spin moment has been provided by analyzing the Fe 3s core level photoemission spectra in the parent and optimally doped CeFeAsO??xFx (x = 0, 0.11) and Sr(Fe??xCox)2As2 (x = 0, 0.10) pnictides. The rapid time scales of the photoemission process allowed the detection of large local spin moments fluctuating on a 10?ą? s time scale in the paramagnetic, antiferromagnetic, and superconducting phases, indicative of the occurrence of ubiquitous strong Hund's magnetic correlations. The magnitude of the spin moment is found to vary significantly among different families, 1.3?B in CeFeAsO and 2.1?B in SrFe?As?. Surprisingly, the spin moment is found to decrease considerably in the optimally doped samples, 0.9?B in CeFeAsO?.??F?.?? and 1.3?B in Sr(Fe?.?Co?.?)?As?. The strong variation of the spin moment against doping and material type indicates that the spin moments and the motion of itinerant electrons are influenced reciprocally in a self-consistent fashion, reflecting the strong competition between the antiferromagnetic superexchange interaction among the spin moments and the kinetic energy gain of the itinerant electrons in the presence of a strong Hund's coupling. By describing the evolution of the magnetic correlations concomitant with the appearance of superconductivity, these results constitute a fundamental step toward attaining a correct description of the microscopic mechanisms shaping the electronic properties in the pnictides, including magnetism and high-temperature superconductivity.

  1. PHYSICAL REVIEW B 88, 174406 (2013) High magnetic field study of the Tm2Fe17 and Tm2Fe17D3.2 compounds

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2013-01-01T23:59:59.000Z

    of the deuteride Tm2Fe17D3.2 has been carried out in steady (14 T) and pulsed (60 T and, in one case, up to 74 T in the deuteride. In either case the magnetization increases with magnetic field undulatorily in broad steps whose the powder data for the deuteride. Thus, the mean molecular field on Tm in Tm2Fe17D3.2 is found to be 49

  2. Itinerant electrons, local moments, and magnetic correlations in the pnictide superconductors CeFeAsO??xFxand Sr(Fe??xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vilmercati, Paolo; Fedorov, Alexei; Bondino, Federica; Offi, Francesco; Panaccione, Giancarlo; Lacovig, Paolo; Simonelli, Laura; McGuire, Michael A.; Sefat, Athena S. M.; Mandrus, David; et al

    2012-06-01T23:59:59.000Z

    A direct and element-specific measurement of the local Fe spin moment has been provided by analyzing the Fe 3s core level photoemission spectra in the parent and optimally doped CeFeAsO??xFx (x = 0, 0.11) and Sr(Fe??xCox)2As2 (x = 0, 0.10) pnictides. The rapid time scales of the photoemission process allowed the detection of large local spin moments fluctuating on a 10?ą? s time scale in the paramagnetic, antiferromagnetic, and superconducting phases, indicative of the occurrence of ubiquitous strong Hund's magnetic correlations. The magnitude of the spin moment is found to vary significantly among different families, 1.3?B in CeFeAsO and 2.1?Bmore »in SrFe?As?. Surprisingly, the spin moment is found to decrease considerably in the optimally doped samples, 0.9?B in CeFeAsO?.??F?.?? and 1.3?B in Sr(Fe?.?Co?.?)?As?. The strong variation of the spin moment against doping and material type indicates that the spin moments and the motion of itinerant electrons are influenced reciprocally in a self-consistent fashion, reflecting the strong competition between the antiferromagnetic superexchange interaction among the spin moments and the kinetic energy gain of the itinerant electrons in the presence of a strong Hund's coupling. By describing the evolution of the magnetic correlations concomitant with the appearance of superconductivity, these results constitute a fundamental step toward attaining a correct description of the microscopic mechanisms shaping the electronic properties in the pnictides, including magnetism and high-temperature superconductivity.« less

  3. SCT&E LNG, LLC - FE Dkt. No. 14-98-LNG | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    FE Dkt. No. 14-98-LNG SCT&E LNG, LLC - FE Dkt. No. 14-98-LNG The Office of Fossil Energy gives notice of receipt of an Application filed July 24, 2014, by SCT&E LNG, LLC (SCT&E),...

  4. Faraday rotation enhancement of gold coated Fe2O3 nanoparticles: comparison of experiment and theory

    E-Print Network [OSTI]

    Wysin, Gary

    Faraday rotation enhancement of gold coated Fe2O3 nanoparticles: comparison of experiment to evaluate their potential for application. In this study, the Faraday rotation enhancement of gold coated Fe2O3 nanoparticles (NP) is investigated experimentally and theoretically. The experiment shows

  5. Neutron powder diffraction of carbon-coated FeCo alloy nanoparticles John Henry J. Scotta)

    E-Print Network [OSTI]

    McHenry, Michael E.

    Neutron powder diffraction of carbon-coated FeCo alloy nanoparticles John Henry J. Scotta in carbon-coated FexCo1 x nanoparticles produced using a radio frequency plasma torch. The nanoparticles roll and machine. In this work, the order­disorder trans- formation in C-coated FeCo nanoparticles

  6. Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses

    E-Print Network [OSTI]

    Osterloh, Frank

    -iodopropionic acid treated LiMo3Se3 nanowire bundles with oleic acid-stabilized Fe3O4 nanoparticles of 2.8, 5Fe3O4-LiMo3Se3 Nanoparticle Clusters as Superparamagnetic Nanocompasses Frank E. Osterloh,*, Hiroki A scaleable chemical approach to functional nanoscale analogues of the magnetic compasses in magnetotactic

  7. Building the Santa Fe Artificial Stock Market Blake LeBaron

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    Building the Santa Fe Artificial Stock Market Blake LeBaron Brandeis University June 2002 Abstract This short summary presents an insider's look at the construction of the Santa Fe artificial stock of the directions that researchers have been taking is the use of agent-based financial markets. These "bottom- up

  8. Water adsorption on alpha-Fe2O3(0001) at near ambient conditions

    E-Print Network [OSTI]

    Yamamoto, Susumu

    2010-01-01T23:59:59.000Z

    Physical Chemistry Water adsorption on at n e a r a m b i eR U N N I N G H E A D : Water adsorption on a-Fe O (0001) *hydroxylation and water adsorption on a-Fe O (0001) at water

  9. Fe(II) Sorption on a Synthetic Montmorillonite. A Combined Macroscopic and Spectroscopic Study

    E-Print Network [OSTI]

    Wehrli, Bernhard

    , and the fate of contaminants.1-3 With respect to pollutant transformation reactions, Fe(II) bound to solid the reactivity of Fe(II) associated with (hydr)oxides, green rust, and iron-containing minerals such as magnetite minerals, although a large proportion of the iron pool in soils is thought to be present as sorbed

  10. Magnetic properties of Fe3C nanograins embedded in carbon matrix Y. H. Lee,a)

    E-Print Network [OSTI]

    Huang, Jung-Chun

    Magnetic properties of Fe3C nanograins embedded in carbon matrix Y. H. Lee,a) T. C. Han, and J. C. A. Huang Physics Department, National Cheng-Kung University, Tainan 70101, Taiwan, Republic of China rods was used in manufacturing carbon films with Fe3C nanograin inclusions. Both temperature- and field

  11. Short communication Chemically abrupt interface between Ce oxide and Fe films

    E-Print Network [OSTI]

    Kim, Sehun

    layer barrier. This situation can lead to partial oxidation of the ferromagnetic metals and degradationShort communication Chemically abrupt interface between Ce oxide and Fe films H.G. Lee a,b , D. Lee online 24 May 2005 Abstract A chemically abrupt Fe/Ce oxide interface can be formed by initial oxidation

  12. First-principles study of iron oxyfluorides and lithiation of FeOF

    E-Print Network [OSTI]

    Chevrier, Vincent L.

    First-principles studies of iron oxyfluorides in the FeF[subscript 2] rutile framework (FeO[subscript x]F[subscript 2?x], 0?x?1) are performed using density functional theory (DFT) in the general gradient approximation ...

  13. LOW ENERGYHIGH FLUX NITROGEN IMPLANTATION OF AN OXIDE-DISPERSION-STRENGTHENED FeAl INTERMETALLIC ALLOY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 LOW ENERGY­HIGH FLUX NITROGEN IMPLANTATION OF AN OXIDE- DISPERSION-STRENGTHENED Fe countercurrent diffusion of nitrogen and aluminium seems to proceed. As a result, segregation of -Fe is observed alloys, the nitridation of titanium aluminides have received most of the attention concerning

  14. Induced lattice strain in epitaxial Fe-based superconducting films on CaF{sub 2} substrates: A comparative study of the microstructures of SmFeAs(O,F), Ba(Fe,Co){sub 2}As{sub 2}, and FeTe{sub 0.5}Se{sub 0.5}

    SciTech Connect (OSTI)

    Ichinose, Ataru, E-mail: ai@criepi.denken.or.jp; Tsukada, Ichiro [Central Research Institute of Electric Power Industry, 2-6-1 Nagasaka, Yokosuka 240-0195 (Japan); Nabeshima, Fuyuki; Imai, Yoshinori; Maeda, Atsutaka [Department of Basic Science, The University of Tokyo, Meguro, Tokyo 153-8902 (Japan); Kurth, Fritz; Holzapfel, Bernhard; Iida, Kazumasa [Institute for Metallic Materials, IFW Dresden, 01171 Dresden (Germany); Ueda, Shinya; Naito, Michio [Department of Applied Physics, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588 (Japan)

    2014-03-24T23:59:59.000Z

    The microstructures of SmFeAs(O,F), Ba(Fe,Co){sub 2}As{sub 2}, and FeTe{sub 0.5}Se{sub 0.5} prepared on CaF{sub 2} substrates were investigated using transmission electron microscopy. The SmFeAs(O,F)/CaF{sub 2} interface is steep, without a disordered layer. By contrast, a chemical reaction occurs at the interface in the cases of Ba(Fe,Co){sub 2}As{sub 2} and FeTe{sub 0.5}Se{sub 0.5}. The reaction layers are located on opposite sides of the interface for Ba(Fe,Co){sub 2}As{sub 2} and FeTe{sub 0.5}Se{sub 0.5}. We found that the lattice distortion of the three superconducting films on the CaF{sub 2} substrates enhances the T{sub C} values compared with films prepared on oxide substrates. The origin of this lattice deformation varies depending on the superconducting material.

  15. Thermoelastic strain in polycrystalline FePd shape memory alloy thin film Jun Hyun Han a,

    E-Print Network [OSTI]

    Thermoelastic strain in polycrystalline Fe­Pd shape memory alloy thin film Jun Hyun Han a, , Juil shape memory alloy Elastic modulus Wrinkling Thermoelastic strain in a polycrystalline Fe­Pd thin film due to shape memory effect was determined from Hooke's law using the measured residual stress

  16. Multi-bit magnetic memory using Fe8 high spin molecules

    E-Print Network [OSTI]

    Keren, Amit

    16 10 17 10 18 10 19 10 20 QTM Magnetic cores Disk file Magnetic bubble Thin film Optical disk IBM molecule behaves independently. #12;8 [Fe8O2(OH)12(C6H15N3)6]Br7(H2O)Br8H2O Fe8 Molecule Iron Carbon

  17. From: To: FERGAS Subject: FE Docket No. 14-96-LNG Date:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FE Docket No. 14-96-LNG Date: Monday, November 17, 2014 7:26:37 PM Dear DOE, I am writing in support of FE Docket No. 14-96-LNG and asking you to grant an Export License to The...

  18. Research paper The determination of labile Fe in ferrihydrite by ascorbic acid extraction

    E-Print Network [OSTI]

    Benning, Liane G.

    , grain-sizes and crystallinity. Furthermore the extraction of bioavailable Fe from potential mineral). No simple chemical extraction can replicate the diversity of these processes, nevertheless extractionsResearch paper The determination of labile Fe in ferrihydrite by ascorbic acid extraction

  19. A Twisted Ladder: Relating the Fe Superconductors to the High Tc Cuprates

    SciTech Connect (OSTI)

    Berg, E.

    2010-05-26T23:59:59.000Z

    We construct a 2-leg ladder model of an Fe-pnictide superconductor and discuss its properties and relationship with the familiar 2-leg cuprate model. Our results suggest that the underlying pairing mechanism for the Fe-pnictide superconductors is similar to that for the cuprates.

  20. Mapping magnetic fields of Fe3O4 nanosphere assemblies by electron holography

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Magnetite (Fe3O4) nanocrystals have attracted much attention due to their unique magnetic properties, and bio-separation.1­3 Fe3O4 has also been demonstrated as an excellent storage material for lithium and mesocrystals, where magnetic interactions deter- mine the morphology.3 It is of great importance to identify

  1. Switchable diode effect and ferroelectric resistive switching in epitaxial BiFeO3 thin films

    E-Print Network [OSTI]

    Tian, Weidong

    Switchable diode effect and ferroelectric resistive switching in epitaxial BiFeO3 thin films Can observed in epitaxial multiferroic BiFeO3 BFO thin films. The forward direction of the rectifying current the switchable diode effect and the ferroelectric resistive switching in epitaxially BFO thin films. BFO thin

  2. Thermal equation of state of Fe3S and implications for sulfur in Earth's core

    E-Print Network [OSTI]

    Shen, Guoyin

    anvil cell (DAC). The thermal equation of state (EOS) of Fe3S was investigated up to pressures of 80 GPa.8(3) calibrated against NaCl in the B2 structure. The room temperature data were also calibrated against the EOS in Earth's core, because of its solar abundance and the ease with which it forms compounds with Fe. Other

  3. Large pyramid shaped single crystals of BiFeO{sub 3} by solvothermal synthesis method

    SciTech Connect (OSTI)

    Sornadurai, D.; Ravindran, T. R.; Paul, V. Thomas; Sastry, V. Sankara [Condensed Matter Physics Division, Materials Science Group, Physical Metallurgy Division, Metallurgy and Materials Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamil Nadu (India); Condensed Matter Physics Division, Materials Science Group (India)

    2012-06-05T23:59:59.000Z

    Synthesis parameters are optimized in order to grow single crystals of multiferroic BiFeO{sub 3}. 2 to 3 mm size pyramid (tetrahedron) shaped single crystals were successfully obtained by solvothermal method. Scanning electron microscopy with EDAX confirmed the phase formation. Raman scattering spectra of bulk BiFeO3 single crystals have been measured which match well with reported spectra.

  4. Probe Mössbauer spectroscopy of mechanical alloying in binary Cr?{sup 57}Fe(1 at%) system

    SciTech Connect (OSTI)

    Elsukov, Evgeny P., E-mail: e-yelsukov@mail.ru; Kolodkin, Denis A., E-mail: e-yelsukov@mail.ru; Ul'yanov, Alexander L., E-mail: e-yelsukov@mail.ru; Porsev, Vitaly E., E-mail: e-yelsukov@mail.ru [Physical-Technical Institute UrB RAS, Izhevsk (Russian Federation)

    2014-10-27T23:59:59.000Z

    Solid state reactions during mechanical alloying (MA) in a binary mixture of powdered Cr and {sup 57}Fe in atomic ratio of 99:1 have been studied using {sup 57}Fe Mössbauer spectroscopy, X-ray diffraction and Auger spectrometry. The proposed model of MA includes formation of Cr(Fe){sub x}O{sub y} oxides at the contact places of Cr and Fe particles, formation of nanostructure with simultaneous dissolution of the oxides, penetration of Fe atoms along grain boundaries in close-to-boundary distorted zones of interfaces in a substitutional position, formation of the substitutional solid solution of Fe in Cr in the body of grains. It was shown that the increase in the BCC lattice parameter on increasing the milling time is due to the dissolution of oxides and formation of interstitial solid solution of O in Cr. There were established substantial differences in consumption of BCC Fe in a Mg ? Al ? Si ? Cr sequence due to the major role of chemical interaction of Mg(Al,Si,Cr) with Fe.

  5. INVESTIGATION OF THE ELECTRICAL PROPERTIES OF METAL/PYRITE (FeS2) JUNCTIONS

    E-Print Network [OSTI]

    Hall, Sharon J.

    cost was a factor and the unconventional solar cell candidates included: FeS2, CuO, and Zn3P2 (Wadia et al 2009:2702). For high volume production of solar panels, cheaper material for commercial use The nontoxic semiconductor pyrite FeS2 appeals to us as a good candidate for solar cells because it has a small

  6. Si and Fe depletion in Galactic star-forming regions observed by the Spitzer Space Telescope

    E-Print Network [OSTI]

    Okada, Yoko; Miyata, Takashi; Okamoto, Yoshiko K; Sakon, Itsuki; Shibai, Hiroshi; Takahashi, Hidenori

    2008-01-01T23:59:59.000Z

    We report the results of the mid-infrared spectroscopy of 14 Galactic star-forming regions with the high-resolution modules of the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. We detected [SiII] 35um, [FeII] 26um, and [FeIII] 23um as well as [SIII] 33um and H2 S(0) 28um emission lines. Using the intensity of [NII] 122um or 205um and [OI] 146um or 63um reported by previous observations in four regions, we derived the ionic abundance Si+/N+ and Fe+/N+ in the ionized gas and Si+/O0 and Fe+/O0 in the photodissociation gas. For all the targets, we derived the ionic abundance of Si+/S2+ and Fe2+/S2+ for the ionized gas. Based on photodissociation and HII region models the gas-phase Si and Fe abundance are suggested to be 3-100% and solar abundance, respectively, for the ionized gas and 16-100% and 2-22% of the solar abundance, respectively, for the photodissociation region gas. Since the [FeII] 26um and [FeIII] 23um emissions are weak, the high sensitivity of the IRS enables to de...

  7. NICKEL-FREE Fe-12Mn-0.2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

    E-Print Network [OSTI]

    Hwang, S.

    2010-01-01T23:59:59.000Z

    Parr, J. Gordon, J. Iron and Steel Inst. B, vol. 283,137 (Properties of Fe-12Mn-0.2Ti Steel at -196°C Yield Stress (FREE Fe-12Mn-O. 2Ti ALLOY STEEL FOR CRYOGENIC APPLICATIONS

  8. FE Electrical Report 2005-2006 By: Chris Dudasik, Tianyi Li, and Jeff Schvey

    E-Print Network [OSTI]

    Ruina, Andy L.

    , batteries, or general electrical theory, please see the Fe Electrical Team Report ­ Spring 2005 or the Fe the ground, the metal strip connected to the lever of the limit switch presses up against the case; this causes the signal wire to read +0v. When the foot is in the air, the strip is depressed and the signal

  9. Carbon-Supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol

    SciTech Connect (OSTI)

    Sun, Junming; Karim, Ayman M.; Zhang, He; Kovarik, Libor; Li, Xiaohong S.; Hensley, Alyssa; McEwen, Jean-Sabin; Wang, Yong

    2013-10-01T23:59:59.000Z

    Abstract Carbon supported metal catalysts (Cu/C, Fe/C, Pd/C, Pt/C, PdFe/C and Ru/C) have been prepared, characterized and tested for vapor-phase hydrodeoxygenation (HDO) of guaiacol (GUA) at atmospheric pressure. Phenol was the major intermediate on all catalysts. Over the noble metal catalysts saturation of the aromatic ring was the major pathway observed at low temperature (250 °C), forming predominantly cyclohexanone and cyclohexanol. Substantial ring opening reaction was observed on Pt/C and Ru/C at higher reaction temperatures (e.g., 350 °C). Base metal catalysts, especially Fe/C, were found to exhibit high HDO activity without ring-saturation or ring-opening with the main products being benzene, phenol along with small amounts of cresol, toluene and trimethylbenzene (TMB). A substantial enhancement in HDO activity was observed on the PdFe/C catalysts. Compared with Fe/C, the yield to oxygen-free aromatic products (i.e., benzene/toluene/TMB) on PdFe/C increased by a factor of four at 350 °C, and by approximately a factor of two (83.2% versus 43.3%) at 450 °C. The enhanced activity of PdFe/C is attributed to the formation of PdFe alloy as evidenced by STEM, EDS and TPR.

  10. Experimental constraints on the thermodynamics and sound velocities of hcp-Fe to core pressures

    E-Print Network [OSTI]

    Jackson, Jennifer M.

    that comprises the volume-dependent phonon density of states (DOS) of e-Fe at eleven compression points. From information about the partitioning behavior of iron isotopes in equilibrium processes involving solid e providing a new tight constraint on the density dependence of e-Fe's sound velocities to outer core

  11. Characteristics of Phosphate Adsorption-Desorption Onto Ferrihydrite: Comparison With Well-Crystalline Fe

    E-Print Network [OSTI]

    Sparks, Donald L.

    . Sparks2 Abstract: The adsorption-desorption behavior of phosphate on ferrihydrite, goethite, and hematite for ferrihydrite and goethite, yet more time for hematite; phosphate exchange with Fe-OH2 1/2+ and Fe-OH1/2j goethite (10%) 9 ferrihydrite (8.5%). The lower desorption for ferrihydrite indicates a higher percentage

  12. Exchange bias and blocking temperature distribution of Fe-film/CoO-nanoparticle hybrid bilayers

    E-Print Network [OSTI]

    Krishnan, Kannan M.

    relaxation in a Fe-film/CoO-nanoparticle hybrid system Appl. Phys. Lett. 101, 132401 (2012); 10 anisotropy energy per unit volume and V is the grain volume. Therefore, hybrid EB bilayers with the AF layer beExchange bias and blocking temperature distribution of Fe-film/CoO-nanoparticle hybrid bilayers Wei

  13. Nebular spectra and abundance tomography of the type Ia supernova SN 2011fe: a normal SN Ia with a stable Fe core

    E-Print Network [OSTI]

    Mazzali, P A; Filippenko, A V; Garnavich, P M; Clubb, K I; Maguire, K; Pan, Y -C; Shappee, R; Silverman, J M; Benetti, S; Hachinger, S; Nomoto, K; Pian, E

    2015-01-01T23:59:59.000Z

    A series of optical and one near-infrared nebular spectra covering the first year of the Type Ia supernova SN 2011fe are presented and modelled. The density profile that proved best for the early optical/ultraviolet spectra, "rho-11fe", was extended to lower velocities to include the regions that emit at nebular epochs. Model rho-11fe is intermediate between the fast deflagration model W7 and a low-energy delayed-detonation. Good fits to the nebular spectra are obtained if the innermost ejecta are dominated by neutron-rich, stable Fe-group species, which contribute to cooling but not to heating. The correct thermal balance can thus be reached for the strongest [FeII] and [FeIII] lines to be reproduced with the observed ratio. The 56Ni mass thus obtained is 0.47 +/- 0.05 Mo. The bulk of 56Ni has an outermost velocity of ~8500 km/s. The mass of stable iron is 0.23 +/- 0.03 Mo. Stable Ni has low abundance, ~10^{-2} Mo. This is sufficient to reproduce an observed emission line near 7400 A. A sub-Chandrasekhar exp...

  14. STORAGE RING CROSS-SECTION MEASUREMENTS FOR ELECTRON IMPACT SINGLE AND DOUBLE IONIZATION OF Fe{sup 9+} AND SINGLE IONIZATION OF Fe{sup 10+}

    SciTech Connect (OSTI)

    Hahn, M.; Novotny, O.; Savin, D. W. [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States); Becker, A.; Grieser, M.; Krantz, C.; Wolf, A. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Lestinsky, M.; Repnow, R. [GSI Helmholtzzentrum fuer Schwerionenforschung, Planckstr. 1, D-64291 Darmstadt (Germany); Mueller, A.; Schippers, S.; Spruck, K. [Institut fuer Atom- und Molekuelphysik, Justus-Liebig-Universitaet Giessen, Leihgesterner Weg 217, D-35392 Giessen (Germany)

    2012-11-20T23:59:59.000Z

    We have measured electron impact ionization from the ground state of Fe{sup 9+} and Fe{sup 10+} over the relative electron-ion collision energy ranges 200-1900 eV and 250-1800 eV, respectively. The ions were confined in an ion storage ring long enough for essentially all metastable levels to radiatively relax to the ground state. For single ionization, we find a number of discrepancies between the existing theoretical cross sections and our results. The calculations appear to neglect some excitation-autoionization (EA) channels, particularly from n = 3 to n' excitations, which are important near threshold, and those from n = 2 {yields} 3 excitations, which contribute at about 650 eV. Conversely, at higher energies the calculations appear to overestimate the importance of EA channels due to excitation into levels where n {>=} 4. The resulting experimental rate coefficients agree with the most recent theory for Fe{sup 9+} to within 16% and for Fe{sup 10+} to within 19% at temperatures where these ions are predicted to form in collisional ionization equilibrium. We have also measured double ionization of Fe{sup 9+} forming Fe{sup 11+} in the energy range 450-3000 eV and found that although there is an appreciable cross section for direct double ionization, the dominant mechanism appears to be through direct ionization of an inner shell electron producing an excited state that subsequently stabilizes through autoionization.

  15. Tuning exchange bias in Fe/?-Fe{sub 2}O{sub 3} core-shell nanoparticles: Impacts of interface and surface spins

    SciTech Connect (OSTI)

    Khurshid, Hafsa, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Phan, Manh-Huong, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu; Mukherjee, Pritish; Srikanth, Hariharan, E-mail: hkhurshi@usf.edu, E-mail: phanm@usf.edu, E-mail: sharihar@usf.edu [Department of Physics, University of South Florida, Tampa, Florida 33620 (United States)

    2014-02-17T23:59:59.000Z

    A comparative study has been performed of the exchange bias (EB) effect in Fe/?-Fe{sub 2}O{sub 3} core-shell nanoparticles with the same thickness of the ?-Fe{sub 2}O{sub 3} shell (?2?nm) and the diameter of the Fe core varying from 4?nm to 11?nm. Transmission electron microscopy (TEM) and high-resolution TEM confirmed the high quality of the core-shell nanostructures. A systematic analysis of magnetization versus magnetic field measurements under zero-field-cooled and field-cooled regimes using the Meiklejohn-Bean model and deconvoluting superparamagnetic and paramagnetic contribution to the total magnetic moment Langevin function shows that there exists a critical particle size (?10?nm), above which the spins at the interface between Fe and ?-Fe{sub 2}O{sub 3} contribute primarily to the EB, but below which the surface spin effect is dominant. Our finding yields deeper insight into the collective contributions of interface and surface spins to the EB in core-shell nanoparticle systems, knowledge of which is the key to manipulating EB in magnetic nanostructures for spintronics applications.

  16. Controllable synthesis, magnetic and biocompatible properties of Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3} nanocrystals

    SciTech Connect (OSTI)

    Zhou, Xi, E-mail: xizhou@xmu.edu.cn [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Shi, Yanfeng; Ren, Lei [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Bao, Shixiong [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China)] [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian 361005 (China); Han, Yu; Wu, Shichao; Zhang, Honggang; Zhong, Lubin [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China); Zhang, Qiqing, E-mail: zhangqiq@xmu.edu.cn [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)] [Research Center of Biomedical Engineering, Department of Biomaterials, College of Materials, The Key Laboratory of Biomedical Engineering of Fujian Province, Xiamen University, Xiamen, Fujian 361005 (China)

    2012-12-15T23:59:59.000Z

    Iron oxide nanocrystals (NCs) with a series of well-controlled morphologies (octahedron, rod, wire, cube and plate) and compositions (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) were synthesized via a facile hydrothermal process. The morphological and compositional control of various iron oxide NCs was based on the regulations of precursor thermolysis kinetics and surfactants. The obtained samples were characterized by XRD, SEM, TEM, SQUID and cytotoxicity test. These as-prepared iron oxide NCs showed excellent magnetic properties and good biocompatibility, paving the way for their high-efficiency bio-separation and bio-detection applications. - Graphical Abstract: Schematic illustration for the formation of iron oxide NCs (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) with different controlled morphologies and compositions. Highlights: Black-Right-Pointing-Pointer Iron oxide NCs with a series of well-controlled morphologies (octahedron, rod, wire, cube, and plate) and compositions (Fe{sub 3}O{sub 4} and {alpha}-Fe{sub 2}O{sub 3}) were synthesized via a facile hydrothermal method. Black-Right-Pointing-Pointer The mechanism of the morphological and compositional control process is directly related to precursor thermolysis kinetics and surfactants. Black-Right-Pointing-Pointer These iron oxide NCs exhibited excellent magnetic response and good biocompatibility, which should have great applications in the cell separation and biodetection.

  17. Spreading of Sn-Ag solders on FeNi alloys

    SciTech Connect (OSTI)

    Saiz, Eduardo; Hwang, C-W.; Suganuma, Katsuaki; Tomsia, Antoni P.

    2003-02-28T23:59:59.000Z

    The spreading of Sn-3Ag-xBi solders on Fe-42Ni has been studied using a drop transfer setup. Initial spreading velocities as fast as {approx}0.5 m/s have been recorded. The results are consistent with a liquid front moving on a metastable, flat, unreacted substrate and can be described by using a modified molecular-kinetic model for which the rate controlling step is the movement of one atom from the liquid to the surface of the solid substrate. Although the phase diagram predicts the formation of two Fe-Sn intermetallics at the solder/substrate interface in samples heated at temperatures lower than 513 C, after spreading at 250 C only a thin FeSn reaction layer could be observed. Two interfacial layers (FeSn and FeSn2) were found after spreading at 450 C.

  18. Effects of temperature and pressure on phonons in FeSi1–xAlx

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Delaire, O.; Al-Qasir, I. I.; Ma, J.; dos Santos, A. M.; Sales, B. C.; Mauger, L.; Stone, M. B.; Abernathy, D. L.; Xiao, Y.; Somayazulu, M.

    2013-05-01T23:59:59.000Z

    The effects of temperature and pressure on phonons in B20 compounds FeSi1–xAlx were measured using inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering. The effect of hole doping through Al substitution is compared to results of alloying with Co (electron doping) in Fe??xCoxSi. While the temperature dependence of phonons in FeSi is highly anomalous, doping with either type of carriers leads to a recovery of the normal quasiharmonic behavior. Density functional theory (DFT) computations of the electronic band structure and phonons were performed. The anomaly in the temperature dependence of the phonons in undoped FeSi was related to the narrow band gap, and its sensitivity to the effect of thermal disordering by phonons. On the other hand, the pressure dependence of phonons at room temperature in undoped FeSi follows the quasiharmonic behavior and is well reproduced by the DFT calculations.

  19. Intrinsic magnetic properties of hexagonal LuFeO{sub 3} and the effects of nonstoichiometry

    SciTech Connect (OSTI)

    Moyer, Jarrett A., E-mail: moyerja@illinois.edu, E-mail: schlom@cornell.edu; Schiffer, Peter [Department of Physics and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Misra, Rajiv [Department of Physics, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Mundy, Julia A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Brooks, Charles M.; Heron, John T. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Muller, David A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States); Schlom, Darrell G., E-mail: moyerja@illinois.edu, E-mail: schlom@cornell.edu [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

    2014-01-01T23:59:59.000Z

    We used oxide molecular-beam epitaxy in a composition-spread geometry to deposit hexagonal LuFeO{sub 3} (h-LuFeO{sub 3}) thin films with a monotonic variation in the Lu/Fe cation ratio, creating a mosaic of samples that ranged from iron rich to lutetium rich. We characterized the effects of composition variation with x-ray diffraction, atomic force microscopy, scanning transmission electron microscopy, and superconducting quantum interference device magnetometry. After identifying growth conditions leading to stoichiometric film growth, an additional sample was grown with a rotating sample stage. From this stoichiometric sample, we determined stoichiometric h-LuFeO{sub 3} to have a T{sub N} = 147 K and M{sub s} = 0.018 ?{sub B}/Fe.

  20. Growth of FePt encapsulated carbon nanotubes by thermal chemical vapor deposition

    SciTech Connect (OSTI)

    Fujiwara, Yuji, E-mail: fujiwara@phen.mie-u.ac.jp; Kaneko, Tetsuya; Hori, Kenta; Takase, Sho; Sato, Hideki; Maeda, Kohji; Kobayashi, Tadashi [Graduate School of Engineering, Mie University, Kurima-machiya-cho 1577, Tsu 514-8507 (Japan); Kato, Takeshi; Iwata, Satoshi [Department of Quantum Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8601 (Japan); Jimbo, Mutsuko [Department of Electrical and Electronic Engineering, Daido University, Takiharu-cho 10-3, Minami-ku, Nagoya 457-8530 (Japan)

    2014-03-15T23:59:59.000Z

    FePt encapsulated carbon nanotubes (CNTs) were grown by thermal chemical vapor deposition using an Fe/Pt bilayer catalyst. The CNTs were grown according to the base growth model. Selected area electron diffraction results revealed that the encapsulated particles were A1-FePt, L1{sub 0}-FePt, and Fe{sub 3}PtC. The crystal structures of particles found at the root parts of CNTs were not able to be identified, however. The layered structure of catalytic films seemed to be responsible for the difference in Pt content between particles found at tip and root parts of CNTs. Approximately 60% of CNTs grown at 800?°C had particles at their tip parts, compared to only 30% when the growth temperature was 700?°C, indicating that higher process temperatures promote particle encapsulation in CNTs.

  1. Phonon properties of BaFe?X? (X=S, Se) spin ladder compounds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Popovicq, Z. V.; Petrovic, C.; Scepanovic, M.; Lazarevic, N.; Opacic, M.; Radonjic, M. M.; Tanaskovic, D.; Lei, Hechang

    2015-02-01T23:59:59.000Z

    We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe?X? (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe?S? (BaFe?Se?) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe?S(Se)? is supported by themore »lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe?Se? below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.« less

  2. FePt-based exchange-coupled composite perpendicular recording media.

    SciTech Connect (OSTI)

    Sun, C.; Stafford, D.; Acharya, R.; X-Ray Science Division; Western Digital Media

    2010-06-01T23:59:59.000Z

    In order to demonstrate the strong and proper exchange coupling between bottom magnetic layer and capping magnetic layer in FePt-based exchange-coupled composite (ECC) perpendicular recording media, we have investigated the thermal stability, writability, degree of exchange coupling, and ECC gain factor of FePt-based ECC media as a function of the thickness of the capping FePt layer. With increasing the thickness of capping FePt layer, both thermal stability and media writability increase simultaneously as a result of the change from strong exchange coupling to proper exchange coupling. The proper exchange-coupled FePt ECC is a promising candidate for future high-density perpendicular recording.

  3. 9 T high magnetic field annealing effects on FeN bulk sample

    SciTech Connect (OSTI)

    Jiang, Yanfeng; Wang, Jian-Ping, E-mail: jpwang@umn.edu [Department of Electrical and Computer Engineering, University of Minnesota, Minneapolis, Minneota 55455 (United States); Dabade, Vivekanand; James, Richard D. [Department of Aerospace Engineering and Mechanics, University of Minnesota, Minneapolis, Minnesota 55455 (United States); Brady, Michael P.; Rios, Orlando [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831–6115 (United States)

    2014-05-07T23:59:59.000Z

    ??-Fe{sub 16}N{sub 2} has been suggested as a promising candidate for future rare-earth-free magnets. In this paper, we report to use high magnetic field (9?T) assisted post-annealing process to enhance the Fe{sub 16}N{sub 2} phase formation in FeN bulk rod samples during the ?? ? ?? phase transformation and thus improve its magnetic properties. It was found by X-ray Diffraction measurement that the volume ratio of Fe{sub 16}N{sub 2} phase was increased up to 22%, which corresponds to an increase in the amount of transformation from ?? ? ?? up to 78%. Also, the saturation magnetization (M{sub s}) of the prepared FeN rod sample was increased to 227?emu/g with its coercivity up to 376?Oe at room temperature. A working mechanism for the high field assisted post-annealing process was presented.

  4. Resolving the stellar sources of isotopically rare presolar silicate grains through Mg and Fe isotopic analyses

    SciTech Connect (OSTI)

    Nguyen, Ann N.; Messenger, Scott, E-mail: lan-anh.n.nguyen@nasa.gov [Robert M. Walker Laboratory for Space Science, Astromaterials Research and Exploration Science Directorate, NASA Johnson Space Center, Houston, TX 77058 (United States)

    2014-04-01T23:59:59.000Z

    We conducted multi-element isotopic analyses of 11 presolar silicate grains from the Acfer 094 meteorite having unusual O isotopic compositions. Eight grains are {sup 18}O-rich, one is {sup 16}O-rich, and two are extremely {sup 17}O-rich. We constrained the grains' stellar sources by measuring their Si and Mg isotopic ratios, and also the {sup 54}Fe/{sup 56}Fe and {sup 57}Fe/{sup 56}Fe ratios for five grains. The Mg and Fe isotopic measurements were conducted after surrounding matrix grains were removed for more accurate ratios. Most of the {sup 18}O-rich silicates had anomalous Mg isotopic ratios, and their combined isotopic constraints are consistent with origins in low-mass Type II supernovae (SNe II) rather than high-metallicity stars. The isotopic ratios of the {sup 16}O-rich silicate are also consistent with an SN origin. Mixing small amounts of interior stellar material with the stellar envelope replicated all measured isotopic ratios except for {sup 29}Si/{sup 28}Si and {sup 54}Fe/{sup 56}Fe in some grains. The {sup 29}Si/{sup 28}Si ratios of all SN-derived grains are matched by doubling the {sup 29}Si yield in the Ne- and Si-burning zones. The {sup 54}Fe/{sup 56}Fe ratios of the grains imply elemental fractionation in the Si/S zone, or introduction of isotopically solar Fe by secondary processing. The two highly {sup 17}O-rich silicates exhibited significant {sup 25}Mg and/or {sup 26}Mg enrichments and their isotopic ratios are best explained by strong dilution of 1.15 M {sub ?} CO nova matter. We estimate that ?12% and 1% of presolar silicates have SN and nova origins, respectively, similar to presolar SiC and oxides. This implies that asymptotic giant branch stars are the dominant dust producers in the galaxy.

  5. Postirradiation deformation behavior in ferritic Fe-Cr alloys

    SciTech Connect (OSTI)

    Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, VA (United States); Gardner, P.L. [Univ. of Missouri, Rolla (United States)

    1992-12-31T23:59:59.000Z

    It has been demonstrated that fast neutron irradiation produces significant hardening in simple Fe(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work hardening exponent. The work hardening exponent of the lower chromium alloys decreased significantly after low temperature irradiation ({le}420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

  6. Postirradiation deformation behavior in ferritic Fe-Cr alloys

    SciTech Connect (OSTI)

    Hamilton, M.L.; Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States); Gardner, P.L. [Missouri Univ., Rolla, MO (United States)

    1992-06-01T23:59:59.000Z

    It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420{degrees}C, whereas irradiation at 574{degrees}C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ({le} 420{degrees}C) but increased after irradiation at 574{degrees}C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

  7. Postirradiation deformation behavior in ferritic Fe-Cr alloys

    SciTech Connect (OSTI)

    Hamilton, M.L.; Gelles, D.S. (Pacific Northwest Lab., Richland, WA (United States)); Gardner, P.L. (Missouri Univ., Rolla, MO (United States))

    1992-06-01T23:59:59.000Z

    It has been demonstrated that fast-neutron irradiation produces significant hardening in simple Fe-(3-18)Cr binary alloys irradiated to about 35 dpa in the temperature range 365 to 420[degrees]C, whereas irradiation at 574[degrees]C produces hardening only for 15% or more chromium. The irradiation-induced changes in tensile properties are discussed in terms of changes in the power law work-hardening exponent. The work-hardening exponent of the lower chromium alloys decreased significantly after low-temperature irradiation ([le] 420[degrees]C) but increased after irradiation at 574[degrees]C. The higher chromium alloys failed either in cleavage or in a mixed ductile/brittle fashion. Deformation microstructures are presented to support the tensile behavior.

  8. Fast Neutron Damage Studies on NdFeB Materials

    E-Print Network [OSTI]

    Spencer, James; Baldwin, A; Boussoufi, Moe; Pellet, David; Volk, James T; Wolf, Zachary

    2005-01-01T23:59:59.000Z

    Many materials and electronics need to be tested for the radiation environment expected at linear colliders (LC) where the accelerator and detectors will be subjected to large fluences of hadrons, leptons and gammas over the life of the facility. Although the linacs will be superconducting, there are still many potential uses for NdFeB in the damping rings, injection and extraction lines and final focus. Our understanding of the radiation damage situation for rare earth permanent magnet materials was presented at PAC2003 and our first measurements of fast neutron, stepped doses at the UC Davis McClellan Nuclear Reactor Center (UCD MNRC) were presented at EPAC2004 where the damage appeared proportional to the distances between the effective operating points and Hc. Here we have extended those doses and included more commercial samples together with the induced radioactivities associated with their respective dopants. Hall probe data for the external induction distributions are compared with vector magnetizatio...

  9. The Wide Field Spectrograph (WiFeS)

    E-Print Network [OSTI]

    Michael Dopita; John Hart; Peter McGregor; Patrick Oates; Gabe Bloxham; Damien Jones

    2007-05-02T23:59:59.000Z

    This paper describes the Wide Field Spectrograph (WiFeS) under construction at the Research School of Astronomy and Astrophysics (RSAA) of the Australian National University (ANU) for the ANU 2.3m telescope at the Siding Spring Observatory. WiFeS is a powerful integral field, double-beam, concentric, image-slicing spectrograph designed to deliver excellent thoughput, wavelength stability, spectrophotometric performance and superb image quality along with wide spectral coverage throughout the 320-950 nm wavelength region. It provides a 25x38 arcsec. field with 0.5 arcsec. sampling along each of twenty five 38X1 arcsec slitlets. The output format is optimized to match the 4096x4096 pixel CCD detectors in each of two cameras individually optimized for the blue and the red ends of the spectrum, respectively. A process of "interleaved nod-and-shuffle" will be applied to permit quantum noise-limited sky subtraction. Using VPH gratings, spectral resolutions of 3000 and 7000 are provided. The full spectral range is covered in a single exposure at R=3000, and in two exposures in the R=7000 mode. The use of transmissive coated optics, VPH gratings and optimized mirror coatings ensures a throughput (including telescope atmosphere and detector) > 30% over a wide spectral range. The concentric image-slicer design ensures an excellent and uniform image quality across the full field. To maximize scientific return, the whole instrument is configured for remote observing, pipeline data reduction, and the accumulation of calibration image libraries.

  10. Mossbauer spectroscopic and x-ray diffraction studies of FeSiO2 nanocomposite soft magnetic materials

    E-Print Network [OSTI]

    Yang, De-Ping

    Mo¨ssbauer spectroscopic and x-ray diffraction studies of FeŐSiO2 nanocomposite soft magnetic. The compositions of the precursor and the successive heat-treated samples have been investigated by 57 Fe Mo¨ssbauer a synthesis of Fe/SiO2 nanocomposites and a study of their magnetic and structural properties using Mo¨ssbauer

  11. SPIN DENSITY OF THE CANTED MOMENT IN 03B1-Fe2O3 (1) By S. J. PICKART,

    E-Print Network [OSTI]

    Boyer, Edmond

    avec des neutrons polarisés. On trouve que cette densité diffčre de celle de l'ion Fe3+. Abstract. 2014 neutrons and found to differ from that of the Fe3+ ion. LE JOURNAL DE PHYSIQUE TOME 25, MAI 1964, as established by the original neutron diffraction measurements [3], consists of the Fe3 ~ spins in each (111

  12. Phase equilibria of an Al0.5CrFeCoNiCu High Entropy Alloy

    E-Print Network [OSTI]

    Jones, N. G.; Frezza, A.; Stone, H. J.

    2014-07-27T23:59:59.000Z

    /Co/Fe with Cr exhibit multiphase regions, the solubility of Cr in each Ni/Co/Fe binary solid solutions at elevated temperatures is always significant [22,34–36]. The Fig. 4. BSEI micrographs of Al0.5CrFeCoNiCu following 1000 h heat treatment at (a) 700 1C, (b...

  13. Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w

    E-Print Network [OSTI]

    de Lima, Oscar Ferreira

    Synthesis and magnetic properties of the double layer perovskite CeBaFe2O5+w R. L. de Almeida,1 O The synthesis, crystallographic structure, and magnetic properties of polycrystalline single-phase samples of CeBaFe results on the successful prepara- tion and characterization of polycrystalline CeBaFe2O5+w samples. Ideal

  14. Effects of Ag underlayers on the microstructure and magnetic properties of epitaxial FePt thin films

    E-Print Network [OSTI]

    Laughlin, David E.

    in the in situ ordering of the FePt thin film at reduced temperatures. The microstructural and magneticPt thin films have drawn considerable attention as a potential high-density magnetic recording material.1. Because the 111 plane is the FePt close-packed plane, the FePt thin film deposited directly onto

  15. Removal of arsenic from effluents - a comparison between the FeSO{sub 4}/Air and FeSO{sub 4}/H{sub 2}O{sub 2} systems

    SciTech Connect (OSTI)

    Teixeira, L.A.; Kohler, H.M. [Catholic Univ. of Rio de Janeiro (Brazil); [Peroxidos do Brasil Ltda, S. Paulo (Brazil); Kohler, H.M. [Catholic Univ. of Rio de Janeiro (Brazil); Monteiro, A.G. [BHP Minerals, Reno, NV (United States)

    1996-12-31T23:59:59.000Z

    This paper reports the results of kinetic studies involving the precipitation of arsenic from aqueous solutions as FeAsO{sub 4} / Fe(OH){sub 3}, using FeSO{sub 4} as source of Fe ions, and Air or H{sub 2}O{sub 2} as oxidizing agents. Both systems lead to an efficient removal of arsenic. The differences in oxidants performances are in the precipitation reaction rate - much faster using hydrogen peroxide. Mechanisms of reactions were suggested based on the following main steps: Fe(II) oxidation: 2 Fe{sup 2+} + 1/2 O{sub 2} + 2 H{sup +} 2 Fe{sup 3+} + H{sub 2}O 2 Fe{sup 2+} + H{sub 2}O{sub 2} + 2 H{sup +}= 2 Fe{sup 3+} + 2 H{sub 2}O As(III) oxidation: HAsO{sub 2} + 2 Fe {sup 3+} + 2 H{sub 2}O = 2 Fe{sup 2+} + H{sub 3}AsO{sub 4} + 2H{sup +} HAsO{sub 2} + H{sub 2}O{sub 2} = H{sub 3}ASO{sub 4} Precipitation: Fe{sup 3+} + H{sub 3}AsO{sub 4} = FeASO{sub 4} (s) + 3 H{sup +} H{sub 3}AsO{sub 4} + n Fe(OH){sub 3} (s) = H{sub 3}ASO{sub 4} (ads) [Fe(OH){sub 3}]{sub n} (s). 15 refs., 7 figs.

  16. Platinum Monolayer on IrFe Core–Shell Nanoparticle Electrocatalysts for the Oxygen Reduction Reaction

    SciTech Connect (OSTI)

    Sasaki K.; Kuttiyiel, K.A.; Su, D.; Adzic, R.R.

    2012-04-19T23:59:59.000Z

    We synthesized high activity and stability platinum monolayer on IrFe core-shell nanoparticle electrocatalysts. Carbon-supported IrFe core-shell nanoparticles were synthesized by chemical reduction and subsequent thermal annealing. The formation of Ir shells on IrFe solid-solution alloy cores has been verified by scanning transmission electron microscopy coupled with energy-loss spectroscopy (EELS) and in situ X-ray absorption spectroscopy. The Pt monolayers were deposited on IrFe core-shell nanoparticles by galvanic replacement of underpotentially deposited Cu adatoms on the Ir shell surfaces. The specific and Pt mass activities for the ORR on the Pt monolayer on IrFe core-shell nanoparticle electrocatalyst are 0.46 mA/cm{sup 2} and 1.1 A/mg{sub Pt}, which are much higher than those on a commercial Pt/C electrocatalyst. High durability of Pt{sub ML}/IrFe/C has also been demonstrated by potential cycling tests. These high activity and durability observed can be ascribed to the structural and electronic interaction between the Pt monolayer and the IrFe core-shell nanoparticles.

  17. Fe-phyllosilicate redox cycling organisms from a redox transition zone in Hanford 300 Area sediments

    SciTech Connect (OSTI)

    Benzine, Jason; Shelobolina, Evgenya S.; Xiong, Mai Yia; Kennedy, David W.; McKinley, James P.; Lin, Xueju; Roden, Eric E.

    2013-01-01T23:59:59.000Z

    Microorganisms capable of reducing or oxidizing structural iron (Fe) in Fe-bearing phyllosilicate minerals were enriched and isolated from a subsurface redox transition zone at the Hanford 300 Area site in eastern Washington, USA. Both conventional and in situ "i-chip" enrichment strategies were employed. One Fe(III)-reducing Geobacter (G. bremensis strain R1, Deltaproteobacteria) and six Fe(II) phyllosilicate-oxidizing isolates from the Alphaproteobacteria (Bradyrhizobium japonicum strains 22, is5, and in8p8), Betaproteobacteria (Cupriavidus necator strain A5-1, Dechloromonas agitata strain is5), and Actinobacteria (Nocardioides sp. strain in31) were recovered. The G. bremensis isolate grew by oxidizing acetate with the oxidized form of NAu-2 smectite as the electron acceptor. The Fe(II)-oxidizers grew by oxidation of chemically reduced smectite as the energy source with nitrate as the electron acceptor. The Bradyrhizobium isolates could also carry out aerobic oxidation of biotite. This is the first report of the recovery of a Fe(II)-oxidizing Nocardioides, and to date only one other Fe(II)-oxidizing Bradyrhizobium is known. The 16S rRNA gene sequences of the isolates were similar to ones found in clone libraries from Hanford 300 sediments and groundwater, suggesting that such organisms may be present and active in situ. Whole genome sequencing of the isolates is underway, the results of which will enable comparative genomic analysis of mechanisms of extracellular phyllosilicate Fe redox metabolism, and facilitate development of techniques to detect the presence and expression of genes associated with microbial phyllosilicate Fe redox cycling in sediments.

  18. NdBaFe{sub 2}O{sub 5+w} and steric effect of Nd on valence mixing and ordering of Fe

    SciTech Connect (OSTI)

    Linden, J. [Department of Physics, AAbo Akademi, FI-20500 Turku (Finland); Karen, P., E-mail: pavel.karen@kjemi.uio.n [Department of Chemistry, University of Oslo, P.O.Box 1033, Blindern, N-0315 Oslo (Norway)

    2010-11-15T23:59:59.000Z

    NdBaFe{sub 2}O{sub 5} above and below Verwey transition is studied by synchrotron X-ray powder diffraction and Moessbauer spectroscopy and compared with GdBaFe{sub 2}O{sub 5} that adopts a higher-symmetry charge-ordered structure typical of the Sm-Ho variants of the title phase. Differences are investigated by Moessbauer spectroscopy accounting for iron valence states at their local magnetic and ionic environments. In the charge-ordered state, the orientation of the electric-field gradient (EFG) versus the internal magnetic field (B) agrees with experiment only when contribution from charges of the ordered d{sub xz} orbitals of Fe{sup 2+} is included, proving thus the orbital ordering. The EFG magnitude indicates that only some 60% of the orbital order occurring in the Sm-Ho variants is achieved in NdBaFe{sub 2}O{sub 5}. The consequent diminishing of the orbit contribution (of opposite sign) to the field B at the Fe{sup 2+} nucleus explains why B is larger than for the Sm-Ho variants. The decreased orbital ordering in NdBaFe{sub 2}O{sub 5} causes a corresponding decrease in charge ordering, which is achieved by decreasing both the amount of the charge-ordered iron states in the sample and their fractional valence separation as seen by the Moessbauer isomer shift. The charge ordering in NdBaFe{sub 2}O{sub 5+w} is more easily suppressed by the oxygen nonstoichiometry (w) than in the Sm-Ho variants. Also the valence mixing into Fe{sup 2.5+} is destabilized by the large size of Nd. The orientation of the EFG around this valence-mixed iron can only be accounted for when the valence-mixing electron is included in the electrostatic ligand field. This proves that the valence mixing occurs between the two iron atoms facing each other across the structural plane of the rare-earth atoms. -- Graphical Abstract: Moessbauer spectrum detects ordering of d{sub xz} orbitals of Fe{sup II}O{sub 5} via the electric-field gradient (EFG) of the orbital, which makes the main component of the total EFG parallel with the magnetic moment B. Display Omitted

  19. Size dependent structural, vibrational and magnetic properties of BiFeO{sub 3} and core-shell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Chauhan, Sunil, E-mail: sunilchauhanjiit@gmail.com; Kumar, Manoj, E-mail: sunilchauhanjiit@gmail.com; Chhoker, Sandeep, E-mail: sunilchauhanjiit@gmail.com; Katyal, S. C., E-mail: sunilchauhanjiit@gmail.com [Department of Physics and Materials Science and Engineering, Jaypee Institute of Information Technology, Noida- 201307 (India)

    2014-04-24T23:59:59.000Z

    Bulk BiFeO{sub 3}, BiFeO{sub 3} nanoparticles and core-shell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles were synthesized by solid state reaction method, sol-gel and Stöber process (SiO{sub 2} shell) respectively. Transmission electron microscopy image confirmed the core-shell structure of BiFeO{sub 3}@SiO{sub 2} nanoparticles with BiFeO3 core ?50-90 nm and SiO{sub 2} shell ?16 nm. X-ray diffraction and FTIR spectroscopy results showed the presence of distorted rhombohedral structure with R3c space group in all three samples. The magnetic measurement indicated the existence of room-temperature weak ferromagnetism in core-shell BiFeO{sub 3}@SiO{sub 2} nanoparticles and BiFeO3 nanoparticles, whereas bulk BiFeO{sub 3} showed antiferromagnteic nature. Electron Spin Resonance results confirmed the enhancement in magnetic properties of coreshell structured BiFeO{sub 3}@SiO{sub 2} nanoparticles in comparison with BiFeO{sub 3} nanoparticles and bulk BiFeO{sub 3}.

  20. Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers

    SciTech Connect (OSTI)

    Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

    2014-01-28T23:59:59.000Z

    We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?°C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

  1. Studies of Charged Particle Emission in the Decay of 45Fe

    SciTech Connect (OSTI)

    Miernik, K. [University of Warsaw; Dominik, W. [University of Warsaw; Janas, Z. [University of Warsaw; Pfutzner, M. [University of Warsaw; Grigorenko, L. [Joint Institute for Nuclear Research, Dubna, Russia; Bingham, C. R. [University of Tennessee, Knoxville (UTK); Czyrkowski, H. [University of Warsaw; Cwiok, Mikolaj [Warsaw University; Darby, Iain [University of Tennessee, Knoxville (UTK); Dabrowski, Ryszard [Warsaw University; Ginter, T. N. [Michigan State University, East Lansing; Grzywacz, R. [University of Tennessee, Knoxville (UTK); Karny, M. [University of Warsaw; Korgul, A. [University of Warsaw; Kusmierz, W. [University of Warsaw; Liddick, Sean [University of Tennessee, Knoxville (UTK); Rajabali, M. M. [University of Tennessee, Knoxville (UTK); Rykaczewski, Krzysztof Piotr [ORNL; Stolz, A. [Michigan State University, East Lansing

    2008-01-01T23:59:59.000Z

    The decay of extremely neutron-deficient isotope 45Fe has been studied by using a new type of gaseous detector in which a technique of optical imaging is used to record tracks of charged particles. The two-proton radioactivity and the -decay channels accompanied by proton(s) emission were clearly identified. For the first time, the angular and energy correlations between two protons emitted from the 45Fe ground-state were measured. The obtained distributions were confronted with predictions of a three-body model. Studies of -decay channels of 45Fe provided first unambiguous evidence for the -delayed three proton emission.

  2. Screening peach rootstocks for tolerance to iron deficiency stress: mechanisms of Fe?p3+ ?sreduction 

    E-Print Network [OSTI]

    Egilla, Jonathan Nda

    1989-01-01T23:59:59.000Z

    ) GF 677 and (b) Nemaguard with and without Fe. 34 5 pH changes in nutrient solution with roots of Ff?s ha"1nrnfnn L with and without Fe. 35 6 pH depression in de-tonized water over 4 hours by roots of 'Montclar' and h emaguard peach rootstocks.... , 1987), and Romheld et al. (1984) provided evidence that the protons are excreted by an ATP- dependent pump in the plasma membrane. Ric de Vos et al. (1986), proposed that Fe- deficiency induces the production of organic acids in the roots, which...

  3. A Minimal Two-band Model for the Superconducting Fe-pnictides

    SciTech Connect (OSTI)

    Raghu, S.

    2010-03-25T23:59:59.000Z

    Following the discovery of the Fe-pnictide superconductors, LDA band structure calculations showed that the dominant contributions to the spectral weight near the Fermi energy came from the Fe 3d orbitals. The Fermi surface is characterized by two hole surfaces around the {Lambda} point and two electron surfaces around the M point of the 2 Fe/cell Brillouin zone. Here, we describe a 2-band model that reproduces the topology of the LDA Fermi surface and exhibits both ferromagnetic and q = ({pi}, 0) spin density wave (SDW) fluctuations. We argue that this minimal model contains the essential low energy physics of these materials.

  4. Chemical, electronic, and magnetic structure of LaFeCoSi alloy: Surface and bulk properties

    SciTech Connect (OSTI)

    Lollobrigida, V. [Dipartimento di Scienze, Universitŕ Roma Tre, I-00146 Rome (Italy); Dipartimento di Matematica e Fisica, Universitŕ Roma Tre, I-00146 Rome (Italy); Basso, V.; Kuepferling, M.; Coďsson, M.; Olivetti, E. S.; Celegato, F. [Istituto Nazionale di Ricerca Metrologica (INRIM), I-10135 Torino (Italy); Borgatti, F. [CNR, Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), I-40129 Bologna (Italy); Torelli, P.; Panaccione, G. [CNR, Istituto Officina dei Materiali (IOM), Lab. TASC, I-34149 Trieste (Italy); Tortora, L. [Laboratorio di Analisi di Superficie, Dipartimento di Matematica e Fisica, Universitŕ Roma Tre, I-00146 Rome (Italy); Dipartimento di Ingegneria Meccanica, Universitŕ Tor Vergata, I-00133 Rome (Italy); Stefani, G.; Offi, F. [Dipartimento di Scienze, Universitŕ Roma Tre, I-00146 Rome (Italy)

    2014-05-28T23:59:59.000Z

    We investigate the chemical, electronic, and magnetic structure of the magnetocaloric LaFeCoSi compound with bulk and surface sensitive techniques. We put in evidence that the surface retains a soft ferromagnetic behavior at temperatures higher than the Curie temperature of the bulk due to the presence of Fe clusters at the surface only. This peculiar magnetic surface effect is attributed to the exchange interaction between the ferromagnetic Fe clusters located at the surface and the bulk magnetocaloric alloy, and it is used here to monitor the magnetic properties of the alloy itself.

  5. Cyclic voltammetric study of Co-Ni-Fe alloys electrodeposition in sulfate medium

    SciTech Connect (OSTI)

    Hanafi, I.; Daud, A. R.; Radiman, S. [Material Science Program, School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)

    2013-11-27T23:59:59.000Z

    Electrochemical technique has been used to study the electrodeposition of cobalt, nickel, iron and Co-Ni-Fe alloy on indium tin oxide (ITO) coated glass substrate. To obtain the nucleation mechanism, cyclic voltammetry is used to characterize the Co-Ni-Fe system. The scanning rate effect on the deposition process was investigated. Deposition of single metal occurs at potential values more positive than that estimated stability potential. Based on the cyclic voltammetry results, the electrodeposition of cobalt, nickel, iron and Co-Ni-Fe alloy clearly show that the process of diffusion occurs is controlled by the typical nucleation mechanism.

  6. Influence of surface segregation on magnetic properties of FePt nanoparticles

    SciTech Connect (OSTI)

    Lv, Hongyan [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States) [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States); Key Laboratory of Artificial Micro- and Nano-Structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Lei, Yinkai; Datta, Aditi; Wang, Guofeng [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)] [Department of Mechanical Engineering and Materials Science, University of Pittsburgh, Pittsburgh, Pennsylvania 15261 (United States)

    2013-09-23T23:59:59.000Z

    Surface segregation leads to chemical disordering in magnetic alloy nanostructures and thus could have profound impact upon the magnetic properties of these nanostructures. In this study, we used the first-principles density functional theory calculation method to determine how Pt surface segregation (exchanging interior Pt with surface Fe atoms) would affect the magnetic properties of L1{sub 0} ordered FePt nanoparticles. For both cuboid and cuboctahedral FePt nanoparticles, we predicted that the Pt surface segregation process could cause a decrease in total magnetic moments, a change in (easy and/or hard) magnetization axes, and a reduction in magnetic anisotropy.

  7. Mechanism of coercivity enhancement by Ag addition in FePt-C granular films for heat assisted magnetic recording media

    SciTech Connect (OSTI)

    Varaprasad, B. S. D. Ch. S.; Takahashi, Y. K., E-mail: takahashi.yukiko@nims.go.jp; Wang, J.; Hono, K. [National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba 305-0047 (Japan); Ina, T.; Nakamura, T.; Ueno, W.; Nitta, K.; Uruga, T. [Japan Synchrotron Radiation Research Institute (JASRI/SPring-8), 1-1-1 Kouto, Sayo, Hyogo 679-5198 (Japan)

    2014-06-02T23:59:59.000Z

    We investigated the Ag distribution in a FePtAg-C granular film that is under consideration for a heat assisted magnetic recording medium by aberration-corrected scanning transmission electron microscope-energy dispersive X-ray spectroscopy and X-ray absorption fine structure. Ag is rejected from the core of FePt grains during the deposition, forming Ag-enriched shell surrounding L1{sub 0}-ordered FePt grains. Since Ag has no solubility in both Fe and Pt, the rejection of Ag induces atomic diffusions thereby enhancing the kinetics of the L1{sub 0}-order in the FePt grains.

  8. Structural studies of SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} by employing XRD and XANES spectroscopic techniques

    SciTech Connect (OSTI)

    Akhtar, M. Javed, E-mail: javeda@pinstech.org.pk; Khan, R. Tahir Ali

    2011-10-15T23:59:59.000Z

    The perovskite based SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} materials have been synthesized by solid state reaction methods. The structural properties are investigated using a combination of X-ray diffraction and X-ray absorption fine structure spectroscopic techniques. From the Rietveld refinement of the X-ray diffraction data it has been observed that SrFeO{sub 3} has a simple cubic perovskite structure, which is consistent with the previous literature results; whereas SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} shows a tetragonal structure within P4mm space group. X-ray absorption results demonstrate that the valence state of Fe in SrFeO{sub 3} is (IV); however, it changes to (III) when 50% Nb{sup 5+} is substituted at the Fe sites. - Highlights: {yields} Structural studies by employing XRD and XANES spectroscopic techniques. {yields} Rietveld refinement confirmed SrFeO{sub 3} has cubic structure, space group Pm-3m. {yields} It is revealed that SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} has tetragonal structure, in P4mm space group. {yields} From XANES results it is observed that Fe has valence state of (IV) in SrFeO{sub 3}. {yields} Doping of 50% Nb{sup 5+} at Fe sites, changes Fe valence to (III) in SrFe{sub 0.5}Nb{sub 0.5}O{sub 3}.

  9. Nickel recovery from electronic waste II Electrodeposition of Ni and Ni–Fe alloys from diluted sulfate solutions

    SciTech Connect (OSTI)

    Robotin, B. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Ispas, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Coman, V. [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania); Bund, A. [Fachgebiet Elektrochemie und Galvanotechnik II, Technische Universität Ilmenau, D-98693 Ilmenau (Germany); Ilea, P., E-mail: pilea@chem.ubbcluj.ro [Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos Street, RO-400028 Cluj-Napoca (Romania)

    2013-11-15T23:59:59.000Z

    Highlights: • Ni can be recovered from EG wastes as pure Ni or as Ni–Fe alloys. • The control of the experimental conditions gives a certain alloy composition. • Unusual deposits morphology shows different nucleation mechanisms for Ni vs Fe. • The nucleation mechanism was progressive for Ni and instantaneous for Fe and Ni–Fe. - Abstract: This study focuses on the electrodeposition of Ni and Ni–Fe alloys from synthetic solutions similar to those obtained by the dissolution of electron gun (an electrical component of cathode ray tubes) waste. The influence of various parameters (pH, electrolyte composition, Ni{sup 2+}/Fe{sup 2+} ratio, current density) on the electrodeposition process was investigated. Scanning electron microscopy (SEM) and X-ray fluorescence analysis (XRFA) were used to provide information about the obtained deposits’ thickness, morphology, and elemental composition. By controlling the experimental parameters, the composition of the Ni–Fe alloys can be tailored towards specific applications. Complementarily, the differences in the nucleation mechanisms for Ni, Fe and Ni–Fe deposition from sulfate solutions have been evaluated and discussed using cyclic voltammetry and potential step chronoamperometry. The obtained results suggest a progressive nucleation mechanism for Ni, while for Fe and Ni–Fe, the obtained data points are best fitted to an instantaneous nucleation model.

  10. Phase equilibria in W-Fe-Co-Ni system alloys I. Alloys containing 10% (Fe+Co+Ni) at 1400-1200/sup 0/ C

    SciTech Connect (OSTI)

    Zakharov, A.M.

    1986-04-01T23:59:59.000Z

    The authors investigate the phase composition of W-Fe-Co-Ni system alloys with a total (Fe + Co + Ni) content of 10% at 1400-1200 C and also of their solidus temperature. The alloys were prepared from powders of tungsten (not less than 99.87% ), carbonyl nickel (not less than 99.98%), type ChDA iron (not less than 99.55%), and cobalt (not less than 99.5%) with a particle size of 1.7-70 um. The phase composition of the alloys was studied by methods of metallographic, x-ray, and micro-x-ray spectral analysis and also by measurement of the microhardness of the coexisting phases. upon Completiodnof crystallization and at temperatures of 1400-1200 C alloys of the primary section with 10% (Fe + Co + Ni) have a two-(alpha + u or alpha + gamma) or three phase (alpha + u + gamma) structure.

  11. High temperature oxidation behavior of Fe-Cr-Al foils

    SciTech Connect (OSTI)

    Chang, C.S.; Jha, B. [Texas Instruments, Inc., Attleboro, MA (United States)

    1998-12-31T23:59:59.000Z

    Metallic catalytic converters for automotive emission control is becoming an important application for heat resistant alloys as more design opportunities are realized. The service conditions and design of metallic catalytic converters require the alloy to be highly oxidation resistant at gauges typically at 50 microns or less. For conventional heat resistant alloy design the goal is to form a well adherent scale on the alloy surface to protect the alloy matrix from being oxidized. However, the thin gauge results in a limited supply of alloying elements that can form the protective scale on the surface. The alloy chemistry has to be optimized to have the minimum oxidation while maintaining processing characteristics. Furthermore, the ratio of scale thickness to foil gauge is significant and the stress state between them introduces measurable permanent distortion of the foil. In this study, the effect of alloying elements on the oxidation behavior of commonly used Fe-Cr-Al alloys was quantified by the oxidation weight gain and length change measurements.

  12. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...

    Broader source: Energy.gov (indexed) [DOE]

    111-LNG - ORDER 2961 & 2961-A SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-111-LNG - ORDER 2961 & 2961-A April 2011 October 2011 April 2012 October 2012...

  13. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...

    Broader source: Energy.gov (indexed) [DOE]

    30-LNG - ORDER 3306 SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 13-30-LNG - ORDER 3306 No reports submitted. More Documents & Publications SEMI-ANNUAL...

  14. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...

    Broader source: Energy.gov (indexed) [DOE]

    42-LNG - ORDER 3307 SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 13-42-LNG - ORDER 3307 No reports submitted. More Documents & Publications SEMI-ANNUAL...

  15. SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT...

    Broader source: Energy.gov (indexed) [DOE]

    85-LNG - ORDER 2833 SEMI-ANNUAL REPORTS FOR SABINE PASS LIQUEFACTION, LLC - FE DKT. NO. 10-85-LNG - ORDER 2833 April 2011 October 2011 April 2012 October 2012 April 2013 October...

  16. Enhanced Magnetism of Fe3O4 Nanoparticles with Ga Doping

    SciTech Connect (OSTI)

    Pool, V. L.; Klem, M. T.; Chorney, C. L.; Arenholz, E.; Idzerda, Y.U.

    2010-10-22T23:59:59.000Z

    Magnetic (Ga{sub x}Fe{sub 1-x}){sub 3}O{sub 4} nanoparticles with 5%-33% gallium doping (x = 0.05-0.33) were measured using x-ray absorption spectroscopy and x-ray magnetic circular dichroism to determine that the Ga dopant is substituting for Fe{sub 3+} as Ga{sub 3+} in the tetrahedral A-site of the spinel structure, resulting in an overall increase in the total moment of the material. Frequency-dependent alternating-current magnetic susceptibility measurements showed these particles to be weakly interacting with a reduction of the cubic anisotropy energy term with Ga concentration. The element-specific dichroism spectra show that the average Fe moment is observed to increase with Ga concentration, a result consistent with the replacement of A-site Fe by Ga.

  17. Air Flow North America Corp. – FE Dkt. No. 14-53-LNG (Re-export)

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy (FE) of the Department of Energy (DOE) gives notice of receipt of an application filed on March 25, 2014, by Air Flow North America Corp. (AIR FLOW) requesting short...

  18. Bioavailability of Fe(III) in Loess Sediments: An Important Source...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fe(III) in loess as the sole electron acceptor in the presence and absence of anthraquinone-2, 6-disulfonate (AQDS) as an electron shuttle. Experiments were performed in...

  19. 2002 Blackwell Science Ltd Reduction of Fe(III) oxide by methanogens in the

    E-Print Network [OSTI]

    Lovley, Derek

    electrons to extracellular quinones such as humic acids and the humic acid analogue anthraquinone- 2 anthraquinone-2,6-disulphonate (AQDS). Two species (M. barkeri and M. voltaei) reduced significant amounts of Fe

  20. Bioreduction of Fe-bearing clay minerals and their reactivity toward pertechnetate (Tc-99)

    SciTech Connect (OSTI)

    Bishop, Michael E.; Dong, Hailiang; Kukkadapu, Ravi K.; Liu, Chongxuan; Edelmann, Richard E.

    2011-07-01T23:59:59.000Z

    99Technetium (99Tc) is a fission product of uranium-235 and plutonium-239 and poses a high environmental hazard due to its long half-life (t1/2 = 2.13 x 105 y), abundance in nuclear wastes, and environmental mobility under oxidizing conditions [i.e., Tc(VII)]. Under reducing conditions, Tc(VII) can be reduced to insoluble Tc(IV). Ferrous iron [Fe(II)], either in aqueous form or in mineral form, has been used to reduce Tc(VII) to Tc(IV). However, the reactivity of Fe(II) from clay minerals, other than nontronite, toward immobilization of Tc(VII) and its role in retention of reduced Tc(IV) have not been investigated. In this study the reactivity of a suite of clay minerals toward Tc(VII) reduction and immobilization was evaluated. The clay minerals chosen for this study included five members in the smectite-illite (S-I) series, (montmorillonite, nontronite, rectorite, mixed layered I-S, and illite), chlorite, and palygorskite. Fe-oxides were removed from these minerals with a modified dithionite-citrate-bicarbonate (DCB) procedure. The total Fe content of these clay minerals, after Fe-oxide removal, ranged from 0.7 to 30.4% by weight, and the Fe(III)/Fe(total) ratio ranged from 44.9 to 98.5%. X-ray diffraction (XRD) and Mössbauer spectroscopy results showed that after Fe oxide removal the clay minerals were free of Fe-oxides. Scanning electron microscopy (SEM) revealed that little dissolution occurred during the DCB treatment. Bioreduction experiments were performed in bicarbonate buffer (pH-7) with Fe(III) in the clay minerals as the sole electron acceptor, lactate as the sole electron donor, and Shewanella Putrifaciens CN32 cells as mediators. In select tubes, anthraquinone-2,6-disulfate (AQDS) was added as electron shuttle to facilitate electron transfer. The extent of Fe(III) bioreduction was the highest for chlorite (~43 wt%) and the lowest for palygorskite (~4.17 wt%). In the S-I series, NAu-2 was the most reducible (~31 %) and illite the least (~0.4 %). The extent and initial rate of bioreduction were positively correlated with the percent smectite in the S-I series (i.e., layer expandability). Fe(II) in the bioreduced clay minerals subsequently was used to reduce Tc(VII) to Tc(IV) in PIPES buffer. Similar to the trend of bioreduction, in the S-I series, reduced smectite showed the highest reactivity toward Tc(VII), and reduced illite exhibited the least. The initial rate of Tc(VII) reduction, after normalization to clay and Fe(II) concentrations, was positively correlated with the percent smectite in the S-I series. Fe(II) in chlorite and palygorskite was also reactive toward Tc(VII) reduction. These data demonstrate that crystal chemical parameters (layer expandability, Fe and Fe(II) contents, and surface area etc.) play important roles in controlling the extent and rate of bioreduction and the reactivity toward Tc(VII) reduction. Reduced Tc(IV) resides within clay mineral matrix, and this association could minimize any potential of reoxidation over long term.

  1. FE's Advanced Combustion R&D Seeks Innovative Ways to Lower Cost...

    Office of Environmental Management (EM)

    Combustion R&D Seeks Innovative Ways to Lower Cost of Capturing Carbon Emissions from Coal Fired Power Plants FE's Advanced Combustion R&D Seeks Innovative Ways to Lower Cost of...

  2. CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR

    E-Print Network [OSTI]

    Gordon, B.A.

    2011-01-01T23:59:59.000Z

    Potent.ials Encountered in Coal Conversion Systems", NASA TNof Illinois #6 ash and coal char. Figure 1. Cross sectionsof Fe-lOAl-Cr Alloys by Coal Char B. A. Gordon and V.

  3. Evaluation of Quasicrystal Al-Cu-Fe Alloys for Tribological Applications 

    E-Print Network [OSTI]

    Nabelsi, Nezar

    2013-07-22T23:59:59.000Z

    This research investigated the tribological performance of a composite material, formed from an ultra high molecular weight polyethylene (UHMWPE) matrix and quasicrystalline Al-Cu-Fe alloy powders. An evaluation was conducted for the microstructure...

  4. A Biophysical Approach to Investigate the Human Fe-S Cluster Assembly Pathway 

    E-Print Network [OSTI]

    Fox, Nicholas G

    2014-06-02T23:59:59.000Z

    Iron sulfur (Fe-S) clusters are essential cofactors that function in electron transport, catalyzing substrate turnover, environmental sensing, and initiating radical chemistry. Elaborate multi-component systems have evolved to protect organisms from...

  5. Impact of Fe (III) on the Performance of Viscoelastic Surfactant-Based Acids 

    E-Print Network [OSTI]

    Shu, Yi

    2013-08-02T23:59:59.000Z

    Viscoelastic surfactant (VES)-based acid systems have been used successfully in matrix and acid fracturing treatments. However, the existence of Fe (III) as a contaminant in such systems may lead to many problems, due to interactions between VES...

  6. Soil and Mold Influences on Fe and Zn Concentrations of Sorghum Grain in Mali, West Africa

    E-Print Network [OSTI]

    Verbree, Cheryl

    2012-10-19T23:59:59.000Z

    Iron (Fe) and zinc (Zn) deficiencies affect an estimated 3 billion people worldwide and are linked with cognitive and physical impairments, maternal and child mortality rates, and decreased adult work activity. To combat this "hidden" hunger, plant...

  7. Duo at Santa Fe's Monte del Sol Charter School takes top award...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Mexico Supercomputing Challenge Duo at Santa Fe's Monte del Sol Charter School takes top award in 25th New Mexico Supercomputing Challenge Meghan Hill and Katelynn James took...

  8. Characterization of Zr-Fe-Cu Alloys for an Inert Matrix Fuel for Nuclear Energy Applications 

    E-Print Network [OSTI]

    Barnhart, Brian A.

    2013-08-09T23:59:59.000Z

    distinct phase morphologies. The top half of the sample was Zr rich and contained Zr precipitates dispersed in a matrix of intermetallic compounds while the bottom half consisted solely of intermetallic compounds. The third alloy, Zr-12Fe-15Cu...

  9. Ferromagnetism and Nonmetallic Transport of Thin-Film ? - FeSi 2 : A Stabilized Metastable Material

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cao, Guixin; Singh, D.?J.; Zhang, X.-G.; Samolyuk, German; Qiao, Liang; Parish, Chad; Jin, Ke; Zhang, Yanwen; Guo, Hangwen; Tang, Siwei; Wang, Wenbin; Yi, Jieyu; Cantoni, Claudia; Siemons, Wolter; Payzant, E. Andrew; Biegalski, Michael; Ward, T.?Z.; Mandrus, David; Stocks, G.?M.; Gai, Zheng

    2015-04-01T23:59:59.000Z

    A metastable phase ?-FeSi? was epitaxially stabilized on a silicon substrate using pulsed laser deposition. Nonmetallic and ferromagnetic behaviors are tailored on ?-FeSi? (111) thin films, while the bulk material of ?-FeSi? is metallic and nonmagnetic. The transport property of the films renders two different conducting states with a strong crossover at 50 K, which is accompanied by the onset of a ferromagnetic transition as well as a substantial magnetoresistance. These experimental results are discussed in terms of the unusual electronic structure of ?-FeSi? obtained within density functional calculations and Boltzmann transport calculations with and without strain. Our finding sheds light on achieving ferromagnetic semiconductors through both their structure and doping tailoring, and provides an example of a tailored material with rich functionalities for both basic research and practical applications.

  10. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geochemical Behaviour of S, Cl and Fe in Silicate MeltsGlasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E....

  11. SEMI-ANNUAL REPORTS FOR GOLDEN PASS PRODUCTS LLC - FE DKT. NO...

    Broader source: Energy.gov (indexed) [DOE]

    October 2013 April 2014 October 2014 April 2015 More Documents & Publications GULF LNG LIQUEFACTION COMPANY, LLC - FE DKT. NO. 12-47-LNG - ORDER 3104 SEMI-ANNUAL REPORTS FOR...

  12. Strom Inc, FE Dkt. No. 14-57-LNG | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7-LNG Strom Inc, FE Dkt. No. 14-57-LNG The Office of Fossil Energy gives notice of receipt of an Application filed April 18, 2014, by Strom, Inc. (Strom), seeking a long-term...

  13. Helical spin-density wave in Fe/Cr trilayers with perfect interfaces

    SciTech Connect (OSTI)

    Fishman, R.S.

    1998-07-01T23:59:59.000Z

    Despite the presence of only collinear, commensurate (C) and incommensurate (I) spin-density waves (SDW`s) in bulk Cr, the interfacial steps in Fe/Cr multilayers are now believed to stabilize a helical (H) SDW within the Cr spacer. Yet H SDW`s were first predicted in an Fe/Cr trilayer with perfect interfaces when the orientation of the Fe moments does not favor C ordering: if the number of Cr monolayers is even (odd) and the Fe moments are pointing in the same (opposite) direction, then a C SDW does not gain any coupling energy. Under these circumstances, a simple model verifies that H ordering is indeed favored over 1 ordering provided that the Fermi surface mismatch is sufficiently small or the temperature sufficiently high.

  14. Microsoft Word - DC-#9887372-v1-API_Intervention_in_DOE-FE_Docket...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    THE DEPARTMENT OF ENERGY OFFICE OF FOSSIL ENERGY In the matter of: ) Venture Global LNG, LLC ) FE Docket No. 14-88-LNG ) MOTION TO INTERVENE OF THE AMERICAN PETROLEUM...

  15. From: Miller, Mike To: FERGAS Subject: FE Docket No. 14-96-LNG

    Broader source: Energy.gov (indexed) [DOE]

    Miller, Mike To: FERGAS Subject: FE Docket No. 14-96-LNG Date: Friday, October 24, 2014 3:39:43 PM Please consider the following when reviewing the Alaska LNG Project LLC...

  16. From: FERGAS To: "Jo A. Kuchle"; FERGAS Subject: RE: FE Docket...

    Energy Savers [EERE]

    Jo A. Kuchle"; FERGAS Subject: RE: FE Docket No. 14-96-LNG Date: Tuesday, November 18, 2014 3:45:05 PM This is receipt of your submission in the above docket. The comment period...

  17. Evaluation of Quasicrystal Al-Cu-Fe Alloys for Tribological Applications

    E-Print Network [OSTI]

    Nabelsi, Nezar

    2013-07-22T23:59:59.000Z

    This research investigated the tribological performance of a composite material, formed from an ultra high molecular weight polyethylene (UHMWPE) matrix and quasicrystalline Al-Cu-Fe alloy powders. An evaluation was conducted for the microstructure...

  18. CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR

    E-Print Network [OSTI]

    Gordon, B.A.

    2011-01-01T23:59:59.000Z

    owned rights. LBL-6946 Corrosion of Fe-lOAl-Cr Alloys byOctober, 1977 Abstract Corrosion of iron-base alloys at 982°high-temperature induced corrosion are probably sulfides and

  19. PROOF COPY 035717JAP Design of ferromagnetic shape memory alloy composite made of Fe and

    E-Print Network [OSTI]

    Taya, Minoru

    processed by spark plasma sintering with varying weight fractions of NiTi 51 at. % Ni and Fe powders. An assortment of experimental processing conditions such as temperature, pressure, duration of sintering

  20. PROCESS PARAMETERS for INFRARED PROCESSING of FePt NANOPARTICLE FILMS

    SciTech Connect (OSTI)

    Sabau, Adrian S [ORNL; Kadolkar, Puja [ORNL; Dinwiddie, Ralph Barton [ORNL; Ott, Ronald D [ORNL; Blue, Craig A [ORNL

    2007-01-01T23:59:59.000Z

    Pulse thermal processing (PTP) of FePt nanoparticle films was studied using a high density infrared (HDI) plasma arc lamp. FePt nanoparticle films on silicon substrates were processed using 0.25- second infrared (IR) pulses. The processing was aimed at reaching a peak target temperature for multiple pulses of 550 C. Numerical simulations of the heat transfer for the PTP were performed to determine the operating power levels for the plasma arc lamp. Infrared measurements were conducted to obtain experimental data for the surface temperature of the FePt nanofilm. Parameters needed for the heat-transfer model were identified based on the experimental temperature results. Following the model validation, several numerical simulations were performed to estimate the power levels. It was shown that the FePt nanoparticle films were successfully processed using the power levels provided by the heat-transfer analysis.

  1. Critical analysis on nanostructured CoFeB synthetic orthogonal ferrimagnet

    SciTech Connect (OSTI)

    Chen, Y. S.; Lin, J. G., E-mail: jglin@ntu.edu.tw [Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan (China); Cheng, Chih-Wei; Chern, G. [Department of Physics, National Chung Cheng University, Chia-Yi 621, Taiwan (China)

    2014-09-21T23:59:59.000Z

    Critical analysis on the magnetic properties of synthetic ferrimagnet (SyF), Ta/MgO/CoFeB/Ru/CoFeB/MgO/Ta, is demonstrated via both static and dynamic techniques. With the Ru thickness being 2.3?nm, the coupling between two CoFeB layers becomes orthogonal, which can be used for spin-transfer-torque nano-oscillator (STNO). The fitting of angular dependent ferromagnetic resonance (FMR) allows the precise determination of magnetic anisotropy of each CoFeB layer, the relative magnetizations and the exchange field near the frequency of STNO applications. In addition, the mechanism of resonance broadening at out-of-plane direction is identified to be magnetic inhomogeneity by fitting the angular dependent linewidth of FMR spectra, which provides indispensable information for the future design of STNO devices.

  2. Impact of Fe (III) on the Performance of Viscoelastic Surfactant-Based Acids

    E-Print Network [OSTI]

    Shu, Yi

    2013-08-02T23:59:59.000Z

    Viscoelastic surfactant (VES)-based acid systems have been used successfully in matrix and acid fracturing treatments. However, the existence of Fe (III) as a contaminant in such systems may lead to many problems, due to interactions between VES...

  3. A Biophysical Approach to Investigate the Human Fe-S Cluster Assembly Pathway

    E-Print Network [OSTI]

    Fox, Nicholas G

    2014-06-02T23:59:59.000Z

    Iron sulfur (Fe-S) clusters are essential cofactors that function in electron transport, catalyzing substrate turnover, environmental sensing, and initiating radical chemistry. Elaborate multi-component systems have evolved to protect organisms from...

  4. Charge transfer in Fe-doped GaN: The role of the donor

    SciTech Connect (OSTI)

    Sunay, Ustun; Dashdorj, J.; Zvanut, M. E.; Harrison, J. G. [Department of Physics, University of Alabama at Birmingham, 1300 University Blvd., CH 310, Birmingham, Alabama 35294-1170 (United States); Leach, J. H.; Udwary, K. [Kyma Technologies, 8829 Midway West Rd., Raleigh, North Carolina 27617 (United States)

    2014-02-21T23:59:59.000Z

    Several nitride-based device structures would benefit from the availability of high quality, large-area, freestanding semi-insulating GaN substrates. Due to the intrinsic n-type nature of GaN, however, the incorporation of compensating centers such as Fe is necessary to achieve the high resistivity required. We are using electron paramagnetic resonance (EPR) to explore charge transfer in 450 um thick GaN:Fe plates to understand the basic mechanisms related to compensation so that the material may be optimized for device applications. The results suggest that the simple model based on one shallow donor and a single Fe level is insufficient to describe compensation. Rather, the observation of the neutral donor and Fe3+ indicates that either the two species are spatially segregated or additional compensating and donor defects must be present.

  5. Reactivity of nanocolloidal particles -Fe2O3 at charged interfaces: 2-Electrochemical conversion.

    E-Print Network [OSTI]

    Boyer, Edmond

    synthesis of magnetic and conductive liquids. The reactivity of charged colloidal10 particles occurs in two by methyl viologen), nanoparticles of hematite and goethite (-FeOOH: d = 50 nm) are invo

  6. Pressure-temperature stability studies of FeOOH using x-ray diffraction

    E-Print Network [OSTI]

    Gleason, Arianna E.

    2009-01-01T23:59:59.000Z

    size effect on the reaction: goethite = hematite + water.and heat capacity of goethite (alpha-FeOOH), lepidocrocite (bonded O…O distances in goethite at high pressure. American

  7. Hydrated goethite (alpha-FeOOH) (100) interface structure: Ordered water and surface functional groups.

    E-Print Network [OSTI]

    Ghose, S.K.

    2011-01-01T23:59:59.000Z

    and the (010) surface of goethite. Geochem. Trans. 9, 1–16.Con?rmation of the surface structure of goethite (a-FeOOH. ,phosphated goethite by infrared spectroscopy. Soil Sci. Soc.

  8. Strain relaxation and enhanced perpendicular magnetic anisotropy in BiFeO{sub 3}:CoFe{sub 2}O{sub 4} vertically aligned nanocomposite thin films

    SciTech Connect (OSTI)

    Zhang, Wenrui; Jiao, Liang; Li, Leigang [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Jian, Jie; Khatkhatay, Fauzia; Chu, Frank [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States); Chen, Aiping [Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States); Center for Integrated Nanotechnologies (CINT), Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Jia, Quanxi [Center for Integrated Nanotechnologies (CINT), Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); MacManus-Driscoll, Judith L. [Department of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Wang, Haiyan, E-mail: wangh@ece.tamu.edu [Department of Materials Science and Engineering, Texas A and M University, College Station, Texas 77843 (United States); Department of Electrical and Computer Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2014-02-10T23:59:59.000Z

    Self-assembled BiFeO{sub 3}:CoFe{sub 2}O{sub 4} (BFO:CFO) vertically aligned nanocomposite thin films have been fabricated on SrTiO{sub 3} (001) substrates using pulsed laser deposition. The strain relaxation mechanism between BFO and CFO with a large lattice mismatch has been studied by X-ray diffraction and transmission electron microscopy. The as-prepared nanocomposite films exhibit enhanced perpendicular magnetic anisotropy as the BFO composition increases. Different anisotropy sources have been investigated, suggesting that spin-flop coupling between antiferromagnetic BFO and ferrimagnetic CFO plays a dominant role in enhancing the uniaxial magnetic anisotropy.

  9. ANALYSIS OF OPTICAL Fe II EMISSION IN A SAMPLE OF ACTIVE GALACTIC NUCLEUS SPECTRA

    SciTech Connect (OSTI)

    Kovacevic, Jelena; Popovic, Luka C.; Dimitrijevic, Milan S., E-mail: jkovacevic@aob.bg.ac.r [Astronomical Observatory, Volgina 7, 11060 Belgrade (Serbia)

    2010-07-15T23:59:59.000Z

    We present a study of optical Fe II emission in 302 active galactic nuclei (AGNs) selected from the Sloan Digital Sky Survey. We group the strongest Fe II multiplets into three groups according to the lower term of the transition (b{sup 4} F, a{sup 6} S, and a{sup 4} G terms). These approximately correspond to the blue, central, and red parts, respectively, of the 'iron shelf' around H{beta}. We calculate an Fe II template that takes into account transitions into these three terms and an additional group of lines, based on a reconstruction of the spectrum of I Zw 1. This Fe II template gives a more precise fit of the Fe II lines in broad-line AGNs than other templates. We extract Fe II, H{alpha}, H{beta}, [O III], and [N II] emission parameters and investigate correlations between them. We find that Fe II lines probably originate in an intermediate line region. We note that the blue, red, and central parts of the iron shelf have different relative intensities in different objects. Their ratios depend on continuum luminosity, FWHM H{beta}, the velocity shift of Fe II, and the H{alpha}/H{beta} flux ratio. We examine the dependence of the well-known anti-correlation between the equivalent widths of Fe II and [O III] on continuum luminosity. We find that there is a Baldwin effect for [O III] but an inverse Baldwin effect for the Fe II emission. The [O III]/Fe II ratio thus decreases with L {sub {lambda}5100}. Since the ratio is a major component of the Boroson and Green Eigenvector 1 (EV1), this implies a connection between the Baldwin effect and EV1 and could be connected with AGN evolution. We find that spectra are different for H{beta} FWHMs greater and less than {approx}3000 km s{sup -1}, and that there are different correlation coefficients between the parameters.

  10. Protonation Studies of the New Iron Carbonyl Cyanide trans-[Fe(CO)3(CN)2]2-: Implications with Respect to Hydrogenases

    E-Print Network [OSTI]

    Rauchfuss, Thomas B.

    , Fe-CO-CN-H species may be considered as minimalist biomimetic models of Fe-only and possibly the [NiFe] hydro- genase features two CN- ligands.8 This logic suggested that the replacement of a further CO by CN indicate extensive -back-bonding in the Fe-CO bond and the predominantly -bond character * Author to whom

  11. Doctrina breve muy provechosa de las cosas que pertenecen a la fe católica y a nuestra cristiandad en estilo llano para común inteligencia 

    E-Print Network [OSTI]

    Zumá rraga, Juan de, 1468-1548 Doctrina breve muy provechosa de las cosas que pertenecen a la fe cató lica y a nuestra cristiandad en estilo llano para comú n inteligencia  Zumá rraga, Juan de, 1468-1548; 1544 Ligand effects on bioinspired iron complexes  Mejia Rodriguez, Ma. del Rosario

    2005-11-01T23:59:59.000Z

    - phosphaadamantane, PTA, coordinates to the Fe centers forming the disubstituted complex (m-pdt)[Fe(CO)2PTA]2, which presents one PTA in each iron in a transoid arrangement. Substitution of one CO ligand in the (m-pdt)[Fe(CO)3]2 parent complex forms the asymmetric (m-pdt)[Fe...

  12. Exchange-coupled nanoscale SmCo/NdFeB hybrid magnets Dapeng Wang a

    E-Print Network [OSTI]

    Liu, J. Ping

    t Nanoscale hybrid magnets containing SmCo5 and Nd2Fe14B hard magnetic phases have been produced via a novel magnetization and energy products compared to the single-phase SmCo5 counterpart. & 2012 Elsevier B.V. All-coupled fully dense nanoscale hybrid magnets of different hard magnetic phases ``in one pot''. The SmCo5/Nd2Fe14

  13. Inferences from the vertical distribution of Fe isotopic compositions1 on pedogenetic processes in soils2

    E-Print Network [OSTI]

    Boyer, Edmond

    studied using Fe isotopes and classical soil parameters.4 In the Cambisol, Fe transfer is limited; in-situ in soils2 Z. Fekiacova1 , S. Pichat2 , S. Cornu1 and J. Balesdent1 3 4 5 1 INRA - UR1119 Géochimie des sols.geoderma.2013.06.007 #12;2 ABSTRACT1 The isotopic compositions of major elements in soils can help understand

  14. Magnetic Properties of Fe Ions in a Silicate Glass and Ceramic

    E-Print Network [OSTI]

    Mekki, Abdelkarim

    Magnetic Properties of Fe Ions in a Silicate Glass and Ceramic A. Mekki1 ) Department of Physics of sodium iron silicate glasses, namely (0.70­­x)SiO2­0.30Na2O­xFe2O3, where x ¼ 0, 0.05, 0.10, 0.15, and 0 of the present study is to compare the magnetic properties of the so- dium silicate glass and the crystallized

  15. Microstructure and Mechanical Property Studies on Neutron-Irradiated Ferritic Fe-Cr Model Alloys

    SciTech Connect (OSTI)

    Jian Gan; Maria Okuniewski; Wei-Ying Chen; Yinbin Miao; Carolyn A. Tomchik; James F. Stubbins; Y. Q. Wu; Stu A. Maloy

    2014-06-01T23:59:59.000Z

    Model Fe, Fe-10Cr and Fe-14Cr alloys were irradiated in Advanced Test Reactor at 300°C and 450°C to target doses of 0.01, 0.1 and 1 dpa. The microstructure and the mechanical property of irradiated specimens were investigated using TEM, APT and hardness measurements. The irradiation-induced hardening was consistent with the observed microstructures. For lower doses of 0.01 and 0.1 dpa, the formation of dislocation loops was the primarily contributor to the hardening; no a’ precipitates of resolvable sizes were observed. By 1 dpa, additional increase in hardening were attributed to the formation of a high density of 1-2 nm a' precipitates. In Fe, the hardness increased less as a function of irradiation dose compared to Fe-Cr alloys because of the lack of a' precipitation and differences in loop structures. Three single-parameter effects have been studied: the Cr content, the irradiation temperature and the grain size. The addition of Cr reduced the mobility of both ˝<111> and <100> dislocation loops, leading to a smaller loop size and higher loop density. Also, the Cr contents were positively correlated to the density of a' precipitates, but were less relevant to the precipitate size. Higher irradiation temperature of 450°C resulted in a preferential production of the immobile <100> loops over the mobile ˝<111> loops (ex. a ratio of 8:1 in Fe-10Cr irradiated 450°C to 0.01 dpa). At lower temperature of 300°C, heterogeneous formation of dislocation loops at the vicinity of line dislocations frequently. In Fe, the development of dislocation loops was suppressed (compared to Fe-Cr alloys) due to a combination of smaller grain size, high initial dislocation density and high defect mobility.

  16. Surface modification to improve fireside corrosion resistance of Fe-Cr ferritic steels

    DOE Patents [OSTI]

    Park, Jong-Hee (Clarendon Hills, IL); Natesan, Krishnamurti (Naperville, IL); Rink, David L. (Mokena, IL)

    2010-03-16T23:59:59.000Z

    An article of manufacture and a method for providing an Fe--Cr ferritic steel article of manufacture having a surface layer modification for corrosion resistance. Fe--Cr ferritic steels can be modified to enhance their corrosion resistance to liquid coal ash and other chemical environments, which have chlorides or sulfates containing active species. The steel is modified to form an aluminide/silicide passivating layer to reduce such corrosion.

  17. Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion

    DOE Patents [OSTI]

    Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

    1984-01-01T23:59:59.000Z

    A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

  18. Lifshitz Transition and Chemical Instabilities in Ba1 xKxFe2As2 Superconductors

    SciTech Connect (OSTI)

    Khan, Suffian N. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign; Johnson, Duane D. [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign

    2014-01-01T23:59:59.000Z

    Forsolid-solutionBa1 xKxFe2As2FermisurfaceevolutionismappedviaBlochspectralfunctionscalculatedusingdensityfunctionaltheoryimplementedinKorringa-Kohn-Rostokermultiplescatteringtheorywiththecoherent-potentialapproximation.Spectralfunctionsrevealelectronicdispersion,topology,orbitalcharacter,andbroadening(electron-lifetimeeffects)duetochemicaldisorder.Dissolutionofelectroncylindersoccursnearx 0.9withanonuniform,topological(Lifshitz)transition,reducingtheinterbandinteractions;yetthedispersionmaintainsitsdxzordyzcharacter.Formationenergiesindicatealloyingatx 0.35,asobserved,andatendencyforsegregationontheK-rich(x>0.6)side,explainingthedifficultyofcontrollingsamplequalityandtheconflictingresultsbetweencharacterizedelectronicstructures.OurresultsrevealFermisurfacetransitionsinalloyedsamplesthatinfluencestonodalsuperconductivityandsuggesttheoriginfordeviationsofcommontrendsinFe-basedsuperconductors,suchasBud ko-Ni-Canfieldscaling.

  19. Screening peach rootstocks for tolerance to iron deficiency stress: mechanisms of Fe?p3+ ?sreduction

    E-Print Network [OSTI]

    Egilla, Jonathan Nda

    1989-01-01T23:59:59.000Z

    SCREENING PEACH ROOTSTOCKS FOR TOLERANCE TO IRON DEFICIENCY STRESS: MECHANISMS OF FE REDUCTION A Thesis by JONATHAN NDA A. EGILLA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 1989 Major Subject: Horticulture SCREENING PEACH ROOTSTOCKS FOR TOLERANCE TO IRON DEFICIENCY STRESS: MECHANISMS OF FE REDUCTION A Thesis by JONATHAN NDA A. EGILLA Approved as to style and content by: . H...

  20. Development of an Fe efficiency screening procedure for sorghum based on realistic soil parameters

    E-Print Network [OSTI]

    Hernandez, Francisco

    1987-01-01T23:59:59.000Z

    DEVELOPMENT OF AN FE EFFICIENCY SCREENING PROCEDURE FOR SORGHUH BASED ON REAl ISTIC SOIL PARAHETERS A Thesis by FRANCISCO HERNANDEZ Submitted to the Graduate College of Texas ASH University in partial fulfillment of the requirements... for the degree of HASTER OF SCIENCE August 1987 Hajor Subject: Agronomy DEVELOPMENT OF AN FE EFFICIENCY SCREENING PROCEDURE FOR SORGHUM BASED ON REALISTIC SOIL PARAMETERS A Thesis by Francisco Hernandez Approved as to style and content by: (Chairman...

  1. Multiferroic BaTiO3-CoFe2O4 Nanostructures

    E-Print Network [OSTI]

    Ramesh, R.

    an additional degree of freedom in the design of actuators, transducers, and storage devices. HoweverMultiferroic BaTiO3-CoFe2O4 Nanostructures H. Zheng,1 J. Wang,1 S. E. Lofland,3 Z. Ma,1 L. Mohaddes and magnetic order param- eters in a nanostructured BaTiO3-CoFe2O4 ferroelectromagnet. This facilitates

  2. Magnetron-sputter epitaxy of {beta}-FeSi{sub 2}(220)/Si(111) and {beta}-FeSi{sub 2}(431)/Si(001) thin films at elevated temperatures

    SciTech Connect (OSTI)

    Liu Hongfei; Tan Chengcheh; Chi Dongzhi [Institute of Materials Research and Engineering (IMRE), A-STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)

    2012-07-15T23:59:59.000Z

    {beta}-FeSi{sub 2} thin films have been grown on Si(111) and Si(001) substrates by magnetron-sputter epitaxy at 700 Degree-Sign C. On Si(111), the growth is consistent with the commonly observed orientation of [001]{beta}-FeSi{sub 2}(220)//[1-10]Si(111) having three variants, in-plane rotated 120 Degree-Sign with respect to one another. However, on Si(001), under the same growth conditions, the growth is dominated by [-111]{beta}-FeSi{sub 2}(431)//[110]Si(001) with four variants, which is hitherto unknown for growing {beta}-FeSi{sub 2}. Photoelectron spectra reveal negligible differences in the valance-band and Fe2p core-level between {beta}-FeSi{sub 2} grown on Si(111) and Si(001) but an apparent increased Si-oxidization on the surface of {beta}-FeSi{sub 2}/Si(001). This phenomenon is discussed and attributed to the Si-surface termination effect, which also suggests that the Si/Fe ratio on the surface of {beta}-FeSi{sub 2}(431)/Si(001) is larger than that on the surface of {beta}-FeSi{sub 2}(220)/Si(111).

  3. Pressure driven spin crossover and isostructural phase transition in LaFeO{sub 3}

    SciTech Connect (OSTI)

    Javaid, Saqib [EMMG, Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); National Centre of Physics, Islamabad (Pakistan); Javed Akhtar, M., E-mail: javedakhtar6@gmail.com; Younas, Muhammad [EMMG, Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); Ahmad, Irfan [EMMG, Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); DMME, Pakistan Institute of Engineering and Applied Sciences, Nilore, Islamabad (Pakistan); Shah, Shafqat H. [Theoretical Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); Ahmad, Iftikhar [Department of Physics, University of Malakand, Chakdara (Pakistan)

    2013-12-28T23:59:59.000Z

    We have studied the behavior of LaFeO{sub 3} under pressure (P) using density functional theory (DFT) and atomistic simulations. Ground state structural properties of LaFeO{sub 3} are correctly described by atomistic simulations. The effect of high pressure shows that there is an isotropic compression up to 100?GPa. However, DFT calculations show that within pressure range 0?FeO{sub 3} retains its ground state electronic structure. On the other hand, at P ?32.4?GPa high to low spin magnetic phase transition is observed, which is accompanied by 6.9% volume collapse of LaFeO{sub 3} unit cell, while retaining the ground state orthorhombic crystal structure, i.e., isostructural phase transition. Furthermore, the band gap is closed leading insulator to metal transition. This differing behavior observed by the two techniques can be attributed to the omission of magnetic effects in static simulations. The simultaneous magnetic, electrical, and structural (volume collapse) phase transitions of LaFeO{sub 3} under compression as revealed by DFT calculations corroborate experimental findings. From these results, we can elaborate the mechanism of phase transition in LaFeO{sub 3}: increasing crystal field induces a high spin to low spin transition, which in turn drives the electrical transitions and volume collapse.

  4. N site ordering effect on partially ordered Fe{sub 16}N{sub 2}

    SciTech Connect (OSTI)

    Ji Nian; Wang Jianping [Department of Electrical and Computer Engineering, The Center for Micromagnetics and Information Technologies (MINT), University of Minnesota, 200 Union St SE, 4-174 EE/CSci, Minneapolis, Minnesota 55455 (United States); Allard, Lawrence F.; Lara-Curzio, Edgar [High Temperature Materials Laboratory, Materials Science and Technology Division, Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, Tennessee 37831 (United States)

    2011-02-28T23:59:59.000Z

    Partially ordered Fe{sub 16}N{sub 2} thin films have been fabricated on Fe (001)-buffered GaAs (001) single-crystal substrates by a facing target sputtering process. The saturation magnetization has been systematically investigated as a function of N site ordering in partially ordered Fe{sub 16}N{sub 2} thin films, which is found to be increased monotonically with the increase in the N site ordering parameter, reaching up to 2.68 T at high ordering case. A model discussion is provided based on the partial localization of 3d electron states in this material system, which successfully rationalizes the formation of the giant saturation magnetization in chemically ordered Fe{sub 16}N{sub 2}. We further demonstrate that the average magnetic moment of partially ordered Fe{sub 16}N{sub 2} sensitively depends on the special arrangement of Fe{sub 6}N clusters, which is the key to realize high magnetic moment in this material system.

  5. Transmission electron microscopy investigation of acicular ferrite precipitation in {gamma}'-Fe{sub 4}N nitride

    SciTech Connect (OSTI)

    Xiong, X.C., E-mail: xiaochuan.xiong@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); Redjaimia, A. [Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); Goune, M. [Institut Jean Lamour, UMR 7198 CNRS, Nancy-Universite, UPV-Metz, Ecole des Mines de Nancy, Parc de Saurupt CS 14234, F-54042 Nancy Cedex (France); ArcelorMittal SA, Voie Romaine, BP 30320, F-57283 Maizieres-les-Metz (France)

    2010-11-15T23:59:59.000Z

    Acicular-shaped crystals precipitate from {gamma}'-Fe{sub 4}N nitride in an iron-nitrogen alloy and were identified by electron microdiffraction as {alpha}-ferrite. Acicular ferrite develops both the Nishiyama-Wassermann and the Kurdjumov-Sachs orientation relationships with {gamma}'-Fe{sub 4}N nitride. These orientation relationships were discussed in terms of the symmetry theory. The driving force for acicular ferrite formation was related to the increasing nitrogen content of {gamma}'-Fe{sub 4}N, in equilibrium with {alpha}-ferrite, with decreasing temperature. The passage from lamellar to acicular structure in Fe-N system was proposed. - Research Highlights: {yields} Acicular crystals precipitate from pearlitic{gamma}'-Fe{sub 4}N nitride in an iron-nitrogen alloy and were identified by electron microdiffraction as acicular ferrite. {yields} The crystal structure, orientation relationships with the matrix and morphologies of acicular ferrite, were studied by transmission electron microscopy. {yields} The driving force for the formation of acicular ferrite is related to the temperature dependence of nitrogen content of {gamma}'-Fe{sub 4}N, in equilibrium with ferrite. {yields} The passage from the pearlitic structure to the acicular structure in the present iron-nitrogen alloy was proposed.

  6. Damage formation and recovery in Fe implanted 6H–SiC

    E-Print Network [OSTI]

    Miranda, Pedro; Catarino, Norberto; Lorenz, Katharina; Correia, Joăo Guilherme; Alves, Eduardo

    2012-01-01T23:59:59.000Z

    Silicon carbide doped with magnetic ions such as Fe, Mn, Ni or Co could make this wide band gap semiconductor part of the diluted magnetic semiconductor family. In this study, we report the implantation of 6H-SiC single crystals with magnetic $^{56}$Fe$^{+}$ ions with an energy of 150 keV. The samples were implanted with 5E14 Fe$^+$/cm$^{2}$ and 1E16 Fe$^+$/cm$^{2}$ at different temperatures to study the damage formation and lattice site location. The samples were subsequently annealed up to 1500°C in vacuum in order to remove the implantation damage. The effect of the annealing was followed by Rutherford Backscattering/Channeling (RBS/C) measurements. The results show that samples implanted above the critical amorphization temperature reveal a high fraction of Fe incorporated into regular sites along the [0001] axis. After the annealing at 1000°C, a maximum fraction of 75%, corresponding to a total of 3.8E14 Fe$^{+}$/cm$^{2}$, was measured in regular sites along the [0001] axis. A comparison is made betwee...

  7. Microbial Reductive Transformation of Phyllosilicate Fe(III) and U(VI) in Fluvial Subsurface Sediments

    SciTech Connect (OSTI)

    Lee, Ji-Hoon; Fredrickson, Jim K.; Kukkadapu, Ravi K.; Boyanov, Maxim I.; Kemner, Kenneth M.; Lin, Xueju; Kennedy, David W.; Bjornstad, Bruce N.; Konopka, Allan; Moore, Dean A.; Resch, Charles T.; Phillips, Jerry L.

    2012-04-14T23:59:59.000Z

    The microbial reduction of Fe(III) and U(VI) were investigated in shallow aquifer sediments collected from subsurface Pleistocene flood deposits near the Hanford Reach of the Columbia River in Washington State. Increases in 0.5 N HCl-extractable Fe(II) were observed in incubated sediments and 57Fe Mössbauer spectroscopy revealed that Fe(III) associated with phyllosilicates and pyroxene was reduced to Fe(II). Aqueous uranium(VI) concentrations decreased in incubated Hanford sediments with the rate and extent being greater in sediment amended with organic carbon. X-ray absorption spectroscopy of bioreduced sediments indicated that 67-77% of the U signal was U(VI), probably as an adsorbed species associated with a new or modified reactive mineral phase. Phylotypes within the Deltaproteobacteria were more common in Hanford sediments incubated with U(VI) than without and in U(VI)-free incubations, members of the Clostridiales were dominant with sulfate-reducing phylotypes more common in the sulfate-amended sediments. These results demonstrate the potential for anaerobic reduction phyllosilicate Fe(III) and sulfate in Hanford unconfined aquifer sediments and biotransformations involving reduction and adsorption leading to decreased aqueous U concentrations.

  8. Precessional magnetization induced spin current from CoFeB into Ta

    SciTech Connect (OSTI)

    Jamali, Mahdi; Klemm, Angeline; Wang, Jian-Ping, E-mail: jpwang@umn.edu [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)] [Department of Electrical and Computer Engineering, University of Minnesota, 4-174 200 Union Street SE, Minneapolis, Minnesota 55455 (United States)

    2013-12-16T23:59:59.000Z

    The spin dynamics at the interface between the CoFeB and Ta layer has been studied using spin pumping and spin wave characterizations. The spin pumping driven by the ferromagnetic resonance in the CoFeB layer injects a spin current into Ta layer which results in an electromotive force across the Ta layer due to the inverse spin Hall effect. Upon changing the polarity of the bias magnetic field, the polarity of the output voltage inverts and the output voltage increases linearly in respect to the microwave signal power which are consistent with the spin pumping characteristics. The effect of the in-plane magnetization angle on the output voltage has been studied. Furthermore, it is found that the frequency spectrum of the spin Hall voltage is modified by the annealing temperature and the full width at half maximum of the spin pumping increases by more than 40% with the increase of the annealing temperature from 200?°C to 300?°C. The spin Hall angle at the Ta-CoFeB interface is determined to be 0.014, and the damping constant of the CoFeB increases from 0.006 in pure CoFeB to 0.015 in Ta/CoFeB film.

  9. Snapshot metallicity estimate of resolved stellar systems through Lick Fe5270 diagnostic

    E-Print Network [OSTI]

    Buzzoni, Alberto; Chavez, Miguel

    2009-01-01T23:59:59.000Z

    We outline a new method to derive a "snapshot" metallicity estimate of stellar systems (providing one resolves at least the brightest part of the CMD) just on the basis of low-resolution (i.e., 6-8A FWHM) spectroscopy of a small stellar sample. Our method relies on the Fe5270 Lick index measurements and takes advantage of the special behavior of this spectral feature, that reaches its maximum strength among the ubiquitous component of K-type giants. This makes the Fe5270(max} estimate a robust and model-independent tracer of cluster [Fe/H], being particularly insensitive to the age of the stellar population. A comparison of the Fe5270(max) distribution derived from globular and open clusters, as well as from the field giant population in the Galaxy disk, confirms a tight correlation of the index maximum vs. cluster [Fe/H] allover the entire metallicity range for stellar population with [Fe/H] >~ -2.0. Relying on a theoretical calibration of the feature, we trust to effectively infer cluster metallicity within...

  10. Dopant spin states and magnetism of Sn{sub 1?x}Fe{sub x}O{sub 2} nanoparticles

    SciTech Connect (OSTI)

    Punnoose, A., E-mail: apunnoos@boisestate.edu; Dodge, Kelsey; Reddy, K. M.; Franco, Nevil; Chess, Jordan; Eixenberger, Josh [Department of Physics, Boise State University, Boise, Idaho 83725-1570 (United States); Beltrán, J. J. [Department of Physics, Boise State University, Boise, Idaho 83725-1570 (United States); Grupo de Estado Sólido, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No 52-21, Medellín (Colombia); Barrero, C. A. [Grupo de Estado Sólido, Facultad de Ciencias Exactas y Naturales, Universidad de Antioquia UdeA, Calle 70 No 52-21, Medellín (Colombia)

    2014-05-07T23:59:59.000Z

    This work reports detailed investigations of a series of ?2.6?nm sized, Sn{sub 1?x}Fe{sub x}O{sub 2} crystallites with x?=?0–0.10 using Mossbauer spectroscopy, x-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance spectroscopy (EPR), and magnetometry to determine the oxidation state of Fe dopants and their role in the observed magnetic properties. The magnetic moment per Fe ion ? was the largest ?6.48?×?10{sup ?3} ?{sub B} for the sample with the lowest (0.001%) Fe doping, and it showed a rapid downward trend with increasing Fe doping. Majority of the Fe ions are in 3+ oxidation state occupying octahedral sites. Another significant fraction of Fe dopant ions is in 4+ oxidation state and a still smaller fraction might be existing as Fe{sup 2+} ions, both occupying distorted sites, presumably in the surface regions of the nanocrystals, near oxygen vacancies. These studies also suggest that the observed magnetism is not due to exchange coupling between Fe{sup 3+} spins. A more probable role for the multi-valent Fe ions may be to act as charge reservoirs, leading to charge transfer ferromagnetism.

  11. Epitaxial growth and thermal stability of Fe{sub 4}N film on TiN buffered Si(001) substrate

    SciTech Connect (OSTI)

    Xiang, H.; Shi, F.-Y.; Voyles, P. M.; Chang, Y. A. [Department of Materials Science and Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Rzchowski, M. S. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

    2011-04-01T23:59:59.000Z

    Epitaxial Fe{sub 4}N thin films were grown on TiN buffered Si(001) substrate by dc reactive sputtering deposition at different substrate temperatures. Fe{sub 4}N films epitaxially grew on TiN within the substrate temperature range from 250 to 350 deg. C. Lower than 250 deg. C there will be some other Fe{sub x}N compounds formed and higher than 400 deg. C there will be only Fe left. Fe{sub 4}N is metastable and the postannealing process in vacuum will decompose Fe{sub 4}N film to Fe. However, introducing 30% N{sub 2} in the postannealing atmosphere can stabilize the Fe{sub 4}N up to 350 deg. C in the (Ar,N{sub 2}) gas mixture. The surface roughness of the epitaxial Fe{sub 4}N films decreases with film thickness. There is in-plane biaxial magnetic anisotropy of epitaxial Fe{sub 4}N(001) on Si(001) with the [100] easy direction.

  12. Interplay between out-of-plane anisotropic L1{sub 1}-type CoPt and in-plane anisotropic NiFe layers in CoPt/NiFe exchange springs

    SciTech Connect (OSTI)

    Saravanan, P. [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Hsu, Jen-Hwa, E-mail: jhhsu@phys.ntu.edu.tw; Tsai, C. L. [Department of Physics, National Taiwan University, Taipei 106, Taiwan (China); Tsai, C. Y.; Lin, Y. H. [Graduate Institute of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Kuo, C. Y.; Wu, J.-C. [Department of Physics, National Chang Hua University of Education, Chang Hua 50000, Taiwan (China); Lee, C.-M. [Graduate School of Materials Science, National Yunlin University of Science and Technology, Douliou 64002, Taiwan (China)

    2014-06-28T23:59:59.000Z

    Films of L1{sub 1}-type CoPt/NiFe exchange springs were grown with different NiFe (Permalloy) layer thickness (t{sub NiFe}?=?0–10?nm). X-ray diffraction analysis reveals that the characteristic peak position of NiFe(111) is not affected by the CoPt-layer—confirming the absence of any inter-diffusion between the CoPt and NiFe layers. Magnetic studies indicate that the magnetization orientation of NiFe layer can be tuned through varying t{sub NiFe} and the perpendicular magnetic anisotropy of L1{sub 1}-type CoPt/NiFe films cannot sustain for t{sub NiFe} larger than 3.0?nm due to the existence of exchange interaction at the interface of L1{sub 1}-CoPt and NiFe layers. Magnetic force microscopy analysis on the as-grown samples shows the changes in morphology from maze-like domains with good contrast to hazy domains when t{sub NiFe}???3.0?nm. The three-dimensional micro-magnetic simulation results demonstrate that the magnetization orientation in NiFe layer is not uniform, which continuously increases from the interface to the top of NiFe layer. Furthermore, the tilt angle of the topmost NiFe layers can be changed over a very wide range from a small number to about 75° by varying t{sub NiFe} from 1 to 10?nm. It is worth noting that there is an abrupt change in the magnetization direction at the interface, for all the t{sub NiFe} investigated. The results of present study demonstrate that the tunable tilted exchange springs can be realized with L1{sub 1}-type CoPt/NiFe bilayers for future applications in three-axis magnetic sensors or advanced spintronic devices demanding inclined magnetic anisotropy.

  13. Dissimilatory reduction of Fe(III) and other electron acceptors by a Thermus isolate

    SciTech Connect (OSTI)

    Kieft, T.L. [New Mexico Inst. of Mining and Technology, Socorro, NM (United States). Dept. of Biology; Fredrickson, J.K. [Pacific Northwest National Lab., Richland, WA (United States); Onstott, T.C. [Princeton Univ., NJ (United States). Dept. of Geosciences] [and others

    1999-03-01T23:59:59.000Z

    A thermophilic bacterium that can use O{sub 2}, NO{sub 3}{sup {minus}}, Fe(III), and S{sup 0} as terminal electron acceptors for growth was isolated from groundwater sampled at a 3.2-km depth in a South African gold mine. This organism, designated SA-01, clustered most closely with members of the genus Thermus, as determined by 16S rRNA gene (rDNA) sequence analysis. The 16S rDNA sequence of SA-01 was >98% similar to that of Thermus strain NMX2 A.1, which was previously isolated by other investigators from a thermal spring in New Mexico. Strain NMX2 A.1 was also able to reduce Fe(III) and other electron acceptors. Neither SA-01 nor NMX2 A.1 grew fermentatively, i.e., addition of an external electron acceptor was required for anaerobic growth. Thermus strain SA-01 reduced soluble Fe(III) complexed with citrate or nitrilotriacetic acid (NTA); however, it could reduce only relatively small quantities of hydrous ferric oxide except when the humic acid analog 2,6-anthraquinone disulfonate was added as an electron shuttle, in which case 10 mM Fe(III) was reduced. Fe(III)-NTA was reduced quantitatively to Fe(II); reduction of Fe(III)-NTA was coupled to the oxidation of lactate and supported growth through three consecutive transfers. Suspensions of Thermus strain SA-01 cells also reduced Mn(IV), Co(III)-EDTA, Cr(VI), and U(VI). Mn(IV)-oxide was reduce in the presence of either lactate or H{sub 2}. Both strains were also able to mineralize NTA to CO{sub 2} and to couple its oxidation to Fe(III) reduction and growth. The optimum temperature for growth and Fe(III) reduction by Thermus strains SA-01 and NMX2 A.1 is approximately 65 C; their optimum pH is 6.5 to 7.0. This is the first report of a Thermus sp. being able to couple the oxidation of organic compounds to the reduction of Fe, Mn, or S.

  14. Bacterial reduction of crystalline Fe{sup 3+} oxides in single phase suspensions and subsurface materials

    SciTech Connect (OSTI)

    Zachara, J.M.; Fredrickson, J.K.; Li, S.M.; Kennedy, D.W.; Smith, S.C.; Gassman, P.L. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-11-01T23:59:59.000Z

    Microbiologic reduction of synthetic and geologic Fe{sup 3+} oxides associated with four Pleistocene-age, Atlantic coastal plain sediments was investigated using a dissimilatory Fe reducing bacterium (Shewanella putrefaciens, strain CN32) in bicarbonate buffer. Experiments investigated whether phosphate and anthraquinone-2,6-disulfonate, (AQDS, a humic acid analogue) influenced the extent of crystalline Fe{sup 3+} oxide bioreduction and whether crystalline Fe{sup 3+} oxides in geologic materials are more or less reducible than comparable synthetic phases. Anaerobic incubations (10{sup 8} organisms/mL) were performed both with and without PO{sub 4} and AQDS that functions as an electron repository and shuttle. The production of Fe{sup 2+} (solid and aqueous) was followed with time, as was mineralogy by X-ray diffraction. The synthetic oxides were reduced in a qualitative trend consistent with their surface area and free energy: hydrous ferric oxide (HFO) > goethite > hematite. Bacterial reduction of the crystalline oxides was incomplete in spite of excess electron donor. Biogenic formation of vivianite [Fe{sub 3}(PO{sub 4}){sub 2}{center_dot}8H{sub 2}O] and siderite (FeCO{sub 3}) was observed; the conditions of their formation was consistent with their solubility. The geologic Fe{sup 3+} oxides showed a large range in reducibility, approaching 100% in some materials. The natural oxides were equally or more reducible than their synthetic counterparts, in spite of association with non-reducible mineral phases (e.g., kaolinite). The reducibility of the synthetic and geologic oxides was weakly effected by PO{sub 4}, but was accelerated by AQDS. CN32 produced the hydroquinone form of AQDS (AHDS), that, in turn, had thermodynamic power to reduce the Fe{sup 3+} oxides. As a chemical reductant, it could reach physical regions of the oxide not accessible by the organism. Electron microscopy showed that crystallite size was not the primary factor that caused differences in reducibility between natural and synthetic crystalline Fe{sup 3+} oxide phases. Crystalline disorder and microheterogeneities may be more important.

  15. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect (OSTI)

    Geiling, D.W. [ed.

    1993-08-01T23:59:59.000Z

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  16. A First-principles Study onA First-principles Study on Fe Substituted CrFe Substituted Cr2323CC66

    E-Print Network [OSTI]

    Cambridge, University of

    halpy of FeCr22C6. #12;Creep Resistant Steel Steam Power Plant Efficiency ~42 % Goal Efficiency 45 common power plant steels (MTDAT A, SGTE database, 565 °C) [Bhadeshia, 2001] M23C6 in Power Plant Steels % Anticipated efficiency improvements for changes in pow er plant operating conditions [Wachter and Ennis, 1995

  17. Crystal structure and magnetic properties of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' containing residual {alpha}-Fe prepared by low-temperature ammonia nitridation

    SciTech Connect (OSTI)

    Yamashita, S.; Masubuchi, Y. [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan)] [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan); Nakazawa, Y.; Okayama, T.; Tsuchiya, M. [Automobile R and D Center, Tochigi, Honda R and D Co. LTD., Shimotakanezawa 4630, Haga, Tochigi 321-3393 (Japan)] [Automobile R and D Center, Tochigi, Honda R and D Co. LTD., Shimotakanezawa 4630, Haga, Tochigi 321-3393 (Japan); Kikkawa, S., E-mail: kikkawa@eng.hokudai.ac.jp [Faculty of Engineering, Hokkaido University N13W8, Kita-ku, Sapporo 060-8628 (Japan)

    2012-10-15T23:59:59.000Z

    Slight enhancement of saturation magnetization to 219 A m{sup 2} kg{sup -1} was observed from 199 A m{sup 2} kg{sup -1} for the original {alpha}-Fe on the intermediate nitrided mixture of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' with residual {alpha}-Fe among the low temperature ammonia nitridation products under 5 T magnetic field at room temperature. The value changed not linearly against the yield as had been expected. Crystal structure refinement indicated that the phase similar to {alpha} Prime Prime -Fe{sub 16}N{sub 2} had deviations on its lattice constants and positional parameters, compared to previously reported values for {alpha} Prime Prime -Fe{sub 16}N{sub 2}. Spin-polarized total energy calculations were performed using the projector-augmented wave method as implemented in the Vienna ab-initio simulation package (VASP) to calculate magnetic moment on the refined crystal structure of the intermediate '{alpha} Prime Prime -Fe{sub 16}N{sub 2}'. The calculations supported the observed magnetization enhancement in the intermediate nitridation product. - Graphical abstract: Crystal structural parameters slightly change in the intermediate nitrided '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' from those in {alpha} Prime Prime -Fe{sub 16}N{sub 2} to show the magnetization maxima in the mixture of '{alpha} Prime Prime -Fe{sub 16}N{sub 2}' and the residual {alpha}-F. Highlights: Black-Right-Pointing-Pointer Larger magnetization was observed than the value of Fe{sub 16}N{sub 2} on its intermediate nitrided mixture with residual {alpha}-Fe. Black-Right-Pointing-Pointer The enhancement was related to the crystal structural deviation from Fe{sub 16}N{sub 2} on the intermediate nitride. Black-Right-Pointing-Pointer It was supported by spin-polarized total energy calculation using the deviated structure.

  18. Electronic structures and magnetic moments of Co{sub 3}FeN thin films grown by molecular beam epitaxy

    SciTech Connect (OSTI)

    Ito, Keita; Sanai, Tatsunori; Yasutomi, Yoko; Toko, Kaoru; Honda, Syuta; Suemasu, Takashi [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan)] [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); Zhu, Siyuan; Kimura, Akio [Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526 (Japan)] [Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526 (Japan); Ueda, Shigenori [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science (NIMS), 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Takeda, Yukiharu; Saitoh, Yuji [Condensed Matter Science Division, Japan Atomic Energy Agency (JAEA), 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Condensed Matter Science Division, Japan Atomic Energy Agency (JAEA), 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Imai, Yoji [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan) [Institute of Applied Physics, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565 (Japan)

    2013-12-02T23:59:59.000Z

    We evaluated electronic structures and magnetic moments in Co{sub 3}FeN epitaxial films on SrTiO{sub 3}(001). The experimentally obtained hard x-ray photoemission spectra of the Co{sub 3}FeN film have a good agreement with those calculated. Site averaged spin magnetic moments deduced by x-ray magnetic circular dichroism were 1.52 ?{sub B} per Co atom and 2.08 ?{sub B} per Fe atom at 100 K. They are close to those of Co{sub 4}N and Fe{sub 4}N, respectively, implying that the Co and Fe atoms randomly occupy the corner and face-centered sites in the Co{sub 3}FeN unit cell.

  19. Structural and Raman scattering study of Ni-doped CoFe{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Kumar, Ashwini, E-mail: vdinesh33@rediffmail.com; Dar, Mashkoor A., E-mail: vdinesh33@rediffmail.com; Sharma, Poorva, E-mail: vdinesh33@rediffmail.com; Varshney, Dinesh, E-mail: vdinesh33@rediffmail.com [School of Physics, Vigyan Bhawan, Devi Ahilya University, Khandwa Road Campus, Indore-452001 (India)

    2014-04-24T23:59:59.000Z

    Raman scattering measurements were made on polycrystalline CoFe{sub 2}O{sub 4} and Co{sub 0.5}Ni{sub 0.5}Fe{sub 2}O{sub 4} ferrites as prepared by solid-state reaction route. Rietveld refined X-ray diffraction pattern confirmed the formation of single-phase and both of the samples perfectly indexed in cubic spinel structure with Fd3m space group. Slight reduction in the lattice parameter of Co{sub 0.5}Ni{sub 0.5}Fe{sub 2}O{sub 4} has been observed as compared to CoFe{sub 2}O{sub 4}. From Raman scattering spectra, a shoulder like feature has been observed in both of the compounds reveals that octahedral site is occupied by Co, Ni and Fe ions and tetrahedral site is occupied by only Fe ion.

  20. Stripe-to-bubble transition of magnetic domains at the spin reorientation of (Fe/Ni)/Cu/Ni/Cu(001)

    SciTech Connect (OSTI)

    Wu, J.; Choi, J.; Won, C.; Wu, Y. Z.; Scholl, A.; Doran, A.; Hwang, Chanyong; Qiu, Z.

    2010-06-09T23:59:59.000Z

    Magnetic domain evolution at the spin reorientation transition (SRT) of (Fe/Ni)/Cu/Ni/Cu(001) is investigated using photoemission electron microscopy. While the (Fe/Ni) layer exhibits the SRT, the interlayer coupling of the perpendicularly magnetized Ni layer to the (Fe/Ni) layer serves as a virtual perpendicular magnetic field exerted on the (Fe/Ni) layer. We find that the perpendicular virtual magnetic field breaks the up-down symmetry of the (Fe/Ni) stripe domains to induce a net magnetization in the normal direction of the film. Moreover, as the virtual magnetic field increases to exceed a critical field, the stripe domain phase evolves into a bubble domain phase. Although the critical field depends on the Fe film thickness, we show that the area fraction of the minority domain exhibits a universal value that determines the stripe-to-bubble phase transition.

  1. Photo-driven oxidation of water on ?-Fe{sub 2}O{sub 3} surfaces: An ab initio study

    SciTech Connect (OSTI)

    Nguyen, Manh-Thuong, E-mail: mtnguyen@ictp.it; Seriani, Nicola [The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste (Italy)] [The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste (Italy); Piccinin, Simone [CNR-IOM DEMOCRITOS, c/o SISSA, via Bonomea 265, 34136 Trieste (Italy)] [CNR-IOM DEMOCRITOS, c/o SISSA, via Bonomea 265, 34136 Trieste (Italy); Gebauer, Ralph [The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste, Italy and CNR-IOM DEMOCRITOS Simulation Center, 34136 Trieste (Italy)] [The Abdus Salam International Centre for Theoretical Physics, Strada Costiera 11, 34151 Trieste, Italy and CNR-IOM DEMOCRITOS Simulation Center, 34136 Trieste (Italy)

    2014-02-14T23:59:59.000Z

    Adopting the theoretical scheme developed by the Nřrskov group [see, for example, Nřrskov et al., J. Phys. Chem. B 108, 17886 (2004)], we conducted a density functional theory study of photo-driven oxidation processes of water on various terminations of the clean hematite (?-Fe{sub 2}O{sub 3}) (0001) surface, explicitly taking into account the strong correlation among the 3d states of iron through the Hubbard U parameter. Six best-known terminations, namely, Fe ? Fe ?O{sub 3}? (we call S{sub 1}), O? Fe ? Fe ? (S{sub 2}), O{sub 2}? Fe ? Fe ?(S{sub 3}), O{sub 3}? Fe ? Fe ? (S{sub 4}), Fe ?O{sub 3}? Fe ? (S{sub 5}), and O? Fe ?O{sub 3}?(S{sub 6}), are first exposed to water, the stability of resulting surfaces is investigated under photoelectrochemical conditions by considering different chemical reactions (and their reaction free energies) that lead to surfaces covered by O atoms or/and OH groups. Assuming that the water splitting reaction is driven by the redox potential for photogenerated holes with respect to the normal hydrogen electrode, U{sub VB}, at voltage larger than U{sub VB}, most 3-oxygen terminated substrates are stable. These results thus suggest that the surface, hydroxylated in the dark, should release protons under illumination. Considering the surface free energy of all the possible terminations shows that O{sub 3}–S{sub 5} and O{sub 3}–S{sub 1} are the most thermodynamically stable. While water oxidation process on the former requires an overpotential of 1.22 V, only 0.84 V is needed on the latter.

  2. Reduction And Immobilization Of Hexavalent Chromium By Microbially Reduced Fe-bearing Clay Minerals

    SciTech Connect (OSTI)

    Bishop, Michael E.; Glasser, Paul; Dong, Hailiang; Arey, Bruce W.; Kovarik, Libor

    2014-05-15T23:59:59.000Z

    Hexavalent chromium (Cr6+) is a major contaminant in the environment. As a redox-sensitive element, the fate and toxicity of chromium is controlled by reduction-oxidation (redox) reactions. Previous research has shown the ability of structural Fe(II) in naturally present and chemically reduced clay minerals to reduce Cr6+ to Cr(III) as a way of immobilization and detoxification. However, it is still poorly known whether or not structural Fe(II) in biologically reduced clay minerals exhibits a similar reactivity and if so, what the kinetics and mechanisms of Cr6+ reduction are. The objective of this study was to determine the kinetics and possible mechanisms of Cr6+ reduction by structural Fe(II) in microbially reduced clay minerals and the nature of reduced Cr(III). Structural Fe(III) in nontronite (NAu-2), montmorillonite (SWy-2), chlorite (CCa-2), and clay-rich sediments from the Ringold Formation of the Hanford site of Washington State, USA was first bioreduced to Fe(II) by an iron-reducing bacterium Geobacter sulfurreducens with acetate as the sole electron donor and anthraquinone-2,6-disulfate (AQDS) as electron shuttle in synthetic groundwater (pH 7). Biogenic Fe(II) was then used to reduce aqueous Cr6+ at three different temperatures, 10°, 20°, and 30°C, in order to determine the temperature dependence of the redox reaction between Cr6+ and clay-Fe(II). The results showed that nontronite and montmorillonite were most effective in reducing aqueous Cr6+ at all three temperatures. In contrast, most Fe(II) in chlorite was not reactive towards Cr6+ reduction at 10°C, though at 30°C there was some reduction. For all the clay minerals, the ratio of total Fe(II) oxidized to Cr6+ reduced was close to the expected stoichiometric value of 3. Characterization of the Cr-clay reaction product with scanning electron microscopy with focused ion beam and transmission electron microscopy with electron energy loss spectroscopy revealed that reduced chromium was possibly in the form of sub-nanometer Cr2O3 in association with residual clay minerals as micro-aggregates. This textural association was expected to minimize the chance of Cr(III) reoxidation upon exposure to oxidants. These results are important for our understanding of how various clay minerals may be used to reductively immobilize the heavy metal contaminant Cr in the environment.

  3. Fast magnetic response in gigahertz-band for columnar-structured Fe nanoparticle assembly

    SciTech Connect (OSTI)

    Ogawa, T., E-mail: tomoyuki@ecei.tohoku.ac.jp; Tate, R. [Department of Electronic Engineering, Graduate School of Engineering, Tohoku University, 6-6-05 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Kura, H. [New Industry Creation Hatchery Center (NICHe), Tohoku University, 6-6-10 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Oikawa, T.; Hata, K. [Samsung R and D Institute Japan Co., Ltd., 2-7 Sugasawa-cho, Tsurumi-ku, Yokohama 230-0027 (Japan)

    2014-05-07T23:59:59.000Z

    High density Fe-based ferromagnetic nanoparticle (NP) assembly is expected to have unique magnetic properties, such as superferromagnetism and super-spin-glass, different from magnetically isolated NP systems due to strong dipole interactions among the NPs. A high dipole interaction field, H{sub dip}, of ?3.5 kOe can result in a high effective internal field to the magnetic moment of the NP, expecting for ultra-fast magnetic response, that is, a high magnetic resonance frequency, f{sub r}, of ?10 GHz. However, for a simply molded Fe NP assembly, a low f{sub r} was observed due to inhomogeneous distribution of the internal field, implying the necessity of a unidirectional state of H{sub dip} for higher f{sub r}. In this study, we fabricated a columnar Fe NP assembly for realizing the unidirectional state of H{sub dip} by applying our uniquely developed external field-induced agglomeration method for monodispersed Fe NPs (13 nm in average size) as a function of the field (0–30 kOe) and volume fraction of the Fe NPs (0.5%–51%) in a polymer matrix with dimensions of 4 mm × 4 mm × 0.7 mm{sup t}. A columnar-structured Fe NP assembly was successfully achieved along an in-plane direction (defined as the x-axis) under optimized conditions. From static magnetization curves, induced uniaxial magnetic anisotropy was observed according to the shape of the columnar structure of the Fe NP assembly, where easy and hard axes of magnetization were realized along the parallel (x-axis) and normal directions (in-plane y-axis and z-axis in the thickness direction) to the external field during the process, respectively. Interestingly, this fabricated columnar-structured Fe NP assembly exhibited very high f{sub r} in the range from 3 to 11 GHz judging from the complex susceptibility spectra obtained. The f{sub r} values were well-scaled by a modified Snoek's-limit-law using demagnetization factors quantitatively estimated from the static magnetization curves. Thus, shape-induced anisotropy originating from the unidirectional state of H{sub dip} in the columnar structure of the Fe NP assembly plays an important role for high frequency magnetic response in the GHz-band.

  4. Novel Laser-Based Manufacturing of nano-LiFePO4-Based Materials for High Power Li Ion Batteries

    E-Print Network [OSTI]

    Horne, Craig R.; Jaiswal, Abhishek; Chang, On; Crane, S.; Doeff, Marca M.; Wang, Emile

    2006-01-01T23:59:59.000Z

    17-18, 2007 Novel Laser-Based Manufacturing of nano-LiFePO 4laser-based process for synthesizing nanomaterials, NanoParticle Manufacturing (

  5. Understanding the solidification and microstructure evolution during CSC-MIG welding of Fe–Cr–B-based alloy

    SciTech Connect (OSTI)

    Sorour, A.A., E-mail: ahmad.sorour@mail.mcgill.ca; Chromik, R.R., E-mail: richard.chromik@mcgill.ca; Gauvin, R., E-mail: raynald.gauvin@mcgill.ca; Jung, I.-H., E-mail: in-ho.jung@mcgill.ca; Brochu, M., E-mail: mathieu.brochu@mcgill.ca

    2013-12-15T23:59:59.000Z

    The present is a study of the solidification and microstructure of Fe–28.2%Cr–3.8%B–1.5%Si–1.5%Mn (wt.%) alloy deposited onto a 1020 plain carbon steel substrate using the controlled short-circuit metal inert gas welding process. The as-solidified alloy was a metal matrix composite with a hypereutectic microstructure. Thermodynamic calculation based on the Scheil–Gulliver model showed that a primary (Cr,Fe){sub 2}B phase formed first during solidification, followed by an eutectic formation of the (Cr,Fe){sub 2}B phase and a body-centered cubic Fe-based solid solution matrix, which contained Cr, Mn and Si. Microstructure analysis confirmed the formation of these phases and showed that the shape of the (Cr,Fe){sub 2}B phase was irregular plate. As the welding heat input increased, the weld dilution increased and thus the volume fraction of the (Cr,Fe){sub 2}B plates decreased while other microstructural characteristics were similar. - Highlights: • We deposit Fe–Cr–B-based alloy onto plain carbon steel using the CSC-MIG process. • We model the solidification behavior using thermodynamic calculation. • As deposited alloy consists of (Cr,Fe){sub 2}B plates embedded in Fe-based matrix. • We study the effect of the welding heat input on the microstructure.

  6. Lattice distortion and stripelike antiferromagnetic order in Ca10(Pt3As8)(Fe2As2)5

    SciTech Connect (OSTI)

    Sapkota, Aashish [Ames Laboratory; Tucker, Gregory S [Ames Laboratory; Ramazanoglu, Mehmet [Ames Laboratory; Tian, Wei [Ames Laboratory; Ni, N [University of California; Cava, R. J.; McQueeney, Robert J [Princeton; Goldman, Alan I [Ames Laboratory; Kreyssig, Andreas [Ames Laboratory

    2014-09-01T23:59:59.000Z

    Ca10(Pt3As8)(Fe2As2)5 is the parent compound for a class of Fe-based high-temperature superconductors where superconductivity with transition temperatures up to 30 K can be introduced by partial element substitution. We present a combined high-resolution high-energy x-ray diffraction and elastic neutron scattering study on a Ca10(Pt3As8)(Fe2As2)5 single crystal. This study reveals the microscopic nature of two distinct and continuous phase transitions to be very similar to other Fe-based high-temperature superconductors: an orthorhombic distortion of the high-temperature tetragonal Fe-As lattice below TS=110(2) K followed by stripelike antiferromagnetic ordering of the Fe moments below TN=96(2) K. These findings demonstrate that major features of the Fe-based high-temperature superconductors are very robust against variations in chemical constitution as well as structural imperfection of the layers separating the Fe-As layers from each other and confirms that the Fe-As layers primarily determine the physics in this class of material.

  7. Stress-induced large Curie temperature enhancement in Fe(sub 64)Ni(sub 36) Invar alloy.

    SciTech Connect (OSTI)

    Gorria, P.; Martinez-Blanco, D.; Perez, M. J.; Blanco, J. A.; Hernando, A.; Laguna-Marco, M. A.; Haskel, D.; Souza-Neto, N. M.; Xmith, R. I.; Marshall, W. G.; Garbarino, G.; Mezouar, M.; Fernandez-Martinez, A.; Chaboy, J.; Fernandez Barquin, L.; Rodriguez Castrillon, J. A.; Moldovan, M.; Garcia Alonso, J. I.; Zhang, J.; Llobet, A.; Jiang, J. S.; Univ. de Oviedo; Inst. de Magnetismo Aplicado; ISIS Facility; ESRF; Univ.Grenoble and CNRS; CSIC-Univ. de Zaragoza; Univ. de Cantabria; LANL

    2009-01-01T23:59:59.000Z

    We have succeeded in increasing up to 150 K the Curie temperature in the Fe{sub 64}N{sub 36}6 invar alloy by means of a severe mechanical treatment followed by a heating up to 1073 K. The invar behavior is still present as revealed by the combination of magnetic measurements with neutron and x-ray techniques under extreme conditions, such as high temperature and high pressure. The proposed explanation is based in a selective induced microstrain around the Fe atoms, which causes a slight increase in the Fe-Fe interatomic distances, thus reinforcing ferromagnetic interactions due to the strong magnetoelastic coupling in these invar compounds.

  8. Synthesis of multiferroic Er-Fe-O thin films by atomic layer and chemical vapor deposition

    SciTech Connect (OSTI)

    Mantovan, R., E-mail: roberto.mantovan@mdm.imm.cnr.it; Vangelista, S.; Wiemer, C.; Lamperti, A.; Tallarida, G. [Laboratorio MDM IMM-CNR, I-20864 Agrate Brianza (MB) (Italy); Chikoidze, E.; Dumont, Y. [GEMaC, Université de Versailles St. Quentin en Yvelines-CNRS, Versailles (France); Fanciulli, M. [Laboratorio MDM IMM-CNR, I-20864 Agrate Brianza (MB) (Italy); Dipartimento di Scienza dei Materiali, Universitŕ di Milano Bicocca, Milano (Italy)

    2014-05-07T23:59:59.000Z

    R-Fe-O (R?=?rare earth) compounds have recently attracted high interest as potential new multiferroic materials. Here, we report a method based on the solid-state reaction between Er{sub 2}O{sub 3} and Fe layers, respectively grown by atomic layer deposition and chemical vapor deposition, to synthesize Er-Fe-O thin films. The reaction is induced by thermal annealing and evolution of the formed phases is followed by in situ grazing incidence X-ray diffraction. Dominant ErFeO{sub 3} and ErFe{sub 2}O{sub 4} phases develop following subsequent thermal annealing processes at 850?°C in air and N{sub 2}. Structural, chemical, and morphological characterization of the layers are conducted through X-ray diffraction and reflectivity, time-of-flight secondary ion-mass spectrometry, and atomic force microscopy. Magnetic properties are evaluated by magnetic force microscopy, conversion electron Mössbauer spectroscopy, and vibrating sample magnetometer, being consistent with the presence of the phases identified by X-ray diffraction. Our results constitute a first step toward the use of cost-effective chemical methods for the synthesis of this class of multiferroic thin films.

  9. Effects of temperature and pressure on phonons in FeSi1–xAlx

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Delaire, O.; Al-Qasir, I. I.; Ma, J.; dos Santos, A. M.; Sales, B. C.; Mauger, L.; Stone, M. B.; Abernathy, D. L.; Xiao, Y.; Somayazulu, M.

    2013-05-01T23:59:59.000Z

    The effects of temperature and pressure on phonons in B20 compounds FeSi1–xAlx were measured using inelastic neutron scattering and nuclear-resonant inelastic x-ray scattering. The effect of hole doping through Al substitution is compared to results of alloying with Co (electron doping) in Fe??xCoxSi. While the temperature dependence of phonons in FeSi is highly anomalous, doping with either type of carriers leads to a recovery of the normal quasiharmonic behavior. Density functional theory (DFT) computations of the electronic band structure and phonons were performed. The anomaly in the temperature dependence of the phonons in undoped FeSi was related to the narrowmore »band gap, and its sensitivity to the effect of thermal disordering by phonons. On the other hand, the pressure dependence of phonons at room temperature in undoped FeSi follows the quasiharmonic behavior and is well reproduced by the DFT calculations.« less

  10. Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation

    SciTech Connect (OSTI)

    Um, Wooyong; Chang, Hyun-Shik; Icenhower, Jonathan P.; Lukens, Wayne W.; Serne, R. Jeffrey; Qafoku, Nikolla; Westsik, Joseph H.; Buck, Edgar C.; Steven, Smith C.

    2011-05-04T23:59:59.000Z

    Synthesized goethite was successfully used with addition of Fe(II) to sequester Tc present in both deionized water and simulated off-gas scrubber waste solutions. Pertechnetate concentration in solution decreased immediately when the pH was raised above 7 by addition of sodium hydroxide. Removal of Tc(VII) from solution occurred most likely as a result of heterogeneous surface-catalyzed reduction to Tc(IV) and subsequent co-precipitation onto the goethite. The final Tc-bearing solid was identified as goethite-dominated Fe(III)-(oxy)hydroxide based on XRD analysis, confirming the widespread observation of its characteristic acicular habit by TEM/SEM images. Analysis of the solid precipitate by XAFS showed that the dominant oxidation state of Tc was Tc(IV) and was in octahedral coordination with Tc-O, Fe-O, and Tc-Fe bond distances that are consistent with direct substitution of Tc for Fe in the goethite structure. In some experiments the final Tc-goethite product was subsequently armored with additional layers of freshly precipitated goethite. Successful incorporation of Tc(IV) within the goethite mineral lattice and subsequent goethite armoring can limit re-oxidation of Tc(IV) and its subsequent release from Tc-goethite waste forms, even when the final product is placed in oxidizing environments that typify shallow waste burial facilities.

  11. Paramagnetism and antiferromagnetic interactions in single-phase Fe-implanted ZnO

    E-Print Network [OSTI]

    Pereira, Lino Miguel da Costa; Correia, Joăo Guilherme; Van Bael, M J; Temst, Kristiaan; Vantomme, André; Araújo, Joăo Pedro

    2013-01-01T23:59:59.000Z

    As the intrinsic origin of the high temperature ferromagnetism often observed in wide-gap dilute magnetic semiconductors becomes increasingly debated, there is a growing need for comprehensive studies on the single-phase region of the phase diagram of these materials. Here we report on the magnetic and structural properties of Fe-doped ZnO prepared by ion implantation of ZnO single crystals. A detailed structural characterization shows that the Fe impurities substitute for Zn in ZnO in a wurtzite Zn$_{1?x}$Fe$_{x}$O phase which is coherent with the ZnO host. In addition, the density of beam-induced defects is progressively decreased by thermal annealing up to 900$^ {?}$C, from highly disordered after implantation to highly crystalline upon subsequent annealing. Based on a detailed analysis of the magnetometry data, we demonstrate that isolated Fe impurities occupying Zn substitutional sites behave as localized paramagnetic moments down to 2 K, irrespective of the Fe concentration and the density of beam-i...

  12. Development of a new graded-porosity FeAl alloy by elemental reactive synthesis

    SciTech Connect (OSTI)

    Shen, P Z [State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China; He, Y H [State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China; Gao, H Y [State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China; Zou, J [School of Engineering and Centre for Microscopy and Microanalysis, The University of Queensland, QLD; Xu, N P [Membrane Science and Technology Research Center, Nanjing University of Technology, Nanjing 210009, C; Jiang, Y [State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China; Huang, B [State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China; Lui, C T [Oak Ridge National Laboratory (ORNL)

    2009-01-01T23:59:59.000Z

    A new graded-porosity FeAl alloy can be fabricated through Fe and Al elemental reactive synthesis. FeAl alloy with large connecting open pores and permeability were used as porous supports. The coating was obtained by spraying slurries consisting of mixtures of Fe powder and Al powder with 3 5 m diameter onto porous FeAl support and then sintered at 1100 C. The performances of the coating were compared in terms of thickness, pore diameter and permeability. With an increase in the coating thickness up to 200 m, the changes of maximum pore size decreased from 23.6 m to 5.9 m and the permeability decreased from 184.2 m3m 2kPa 1h 1 to 76.2 m3m 2kPa 1h 1, respectively, for a sintering temperature equal to 1100 C. The composite membranes have potential application for excellent filters in severe environments.

  13. On Deep-Ocean $^{60}Fe$ as a Fossil of a Near-Earth Supernova

    E-Print Network [OSTI]

    Fields, B D; Fields, Brian D.; Ellis, John

    1999-01-01T23:59:59.000Z

    Live $^{60}$Fe has recently been reported in a deep-ocean ferromanganese crust. Analysis of the isotopic ratios in the sample suggests that the measured $^{60}$Fe abundance exceeds the levels generated by terrestrial and cosmogenic sources, and it has been proposed that the excess of $^{60}$Fe is a signature of a supernova that exploded near the earth several Myr ago. In this paper, we consider the possible background sources, and confirm that the measured $^{60}$Fe is significantly higher than all known backgrounds, in contrast with the reported abundance of live $^{53}$Mn. We discuss scenarios in which the data are consistent with a supernova event at a distance $D \\sim 30$ pc and an epoch $t_{\\rm SN} \\sim 5$ Myr ago. We propose tests that could confirm or refute the interpretation of the $^{60}$Fe discovery, including searches for $^{10}$Be, $^{129}$I and $^{146}$Sm. Such a nearby supernova event might have had some impact on the earth's biosphere, principally by enhancing the cosmic-ray flux. This might h...

  14. On Deep-Ocean Fe-60 as a Fossil of a Near-Earth Supernova

    E-Print Network [OSTI]

    Brian D. Fields; John Ellis

    1998-11-29T23:59:59.000Z

    Live $^{60}$Fe has recently been reported in a deep-ocean ferromanganese crust. Analysis of the isotopic ratios in the sample suggests that the measured $^{60}$Fe abundance exceeds the levels generated by terrestrial and cosmogenic sources, and it has been proposed that the excess of $^{60}$Fe is a signature of a supernova that exploded near the earth several Myr ago. In this paper, we consider the possible background sources, and confirm that the measured $^{60}$Fe is significantly higher than all known backgrounds, in contrast with the reported abundance of live $^{53}$Mn. We discuss scenarios in which the data are consistent with a supernova event at a distance $D \\sim 30$ pc and an epoch $t_{\\rm SN} \\sim 5$ Myr ago. We propose tests that could confirm or refute the interpretation of the $^{60}$Fe discovery, including searches for $^{10}$Be, $^{129}$I and $^{146}$Sm. Such a nearby supernova event might have had some impact on the earth's biosphere, principally by enhancing the cosmic-ray flux. This might have damaged the earth's ozone layer, enhancing the penetration of solar ultraviolet radiation. In this connection, we comment on the Middle Miocene and Pliocene mini-extinction events. We also speculate on the possibility of a supernova-induced "cosmic-ray winter," if cosmic rays play a significant role in seeding cloud formation.

  15. Structural and Magnetic Properties of MCl2 (M = Fe, Mn, Co): Acetonitrile Solvates

    SciTech Connect (OSTI)

    Pokhodnya,K.; Bonner, M.; DiPasquale, A.; Rheingold, A.; Her, J.; Stephens, P.; Park, J.; Kennon, B.; Arif, A.; Miller, J.

    2007-01-01T23:59:59.000Z

    M{sup II}Cl{sub 2} (M = Mn, Fe, Co) as their acetonitrile solvates were isolated, and their structural, spectroscopic, and magnetic properties were studied. MCl{sub 2}(NCMe){sub 2} (M = Fe, Mn) form 1-D chains of octahedral M{sup II} ions with four bridging chlorides and two axial MeCN's. The presence of an axial distortion for MFe causes a significant magnetic anisotropy that increases significantly below 150 K; however, {chi}{sub av} [=({chi}{sub {parallel}} + 2{chi}{sub {perpendicular}})/3] almost coincides with the value obtained on a polycrystalline sample. MnCl{sub 2}(NCMe){sub 2} is a paramagnet with a weak antiferromagnetic coupling. Annealing FeCl{sub 2}(NCMe){sub 2} at 55 {sup o}C forms the monosolvate of FeCl{sub 2}(NCMe) composition in which two chains collapse into a double chain with formation of Fe-Cl bonding such that half of the {mu}-Cl's becomes {mu}{sub 3}-Cl's. This material orders magnetically below {Tc} = 4.3 K. For M = Co, paramagnetic tetrahedral [CoCl{sub 3}(NCMe)]{sup -} anions are isolated.

  16. Proceedings of the AD HOC Workshop on Ceramics for Li/FeS{sub 2} batteries

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    Representatives from industry, the U.S. Advanced Battery Consortium (USABC), DOE, national laboratories, and other govt agencies met to develop recommendations and actions for accelerating the development of ceramic components critical to the successful introduction of the Li/FeS{sub 2} bipolar battery for electric vehicles. Most of the workshop is devoted to electrode materials, bipolar designs, separators, and bipolar plates. The bulk of this document is viewographs and is divided into: ceramics, USABC overview, SAFT`s Li/FeS{sub 2} USABC program, bipolar Li/FeS{sub 2} component development, design requirements for bipolar plates, separator design requirements, compatibility of ceramic insulators with lithium, characterization of MgO for use in separators, resistivity measurements of separators, sintered AlN separators for LiMS batteries, etc.

  17. Studies of Charged Particle Emission in the Decay of 45Fe

    SciTech Connect (OSTI)

    Miernik, K. [University of Warsaw; Dominik, W. [University of Warsaw; Janas, Z. [University of Warsaw; Pfutzner, M. [University of Warsaw; Grigorenko, L. [Joint Institute for Nuclear Research, Dubna, Russia; Bingham, C. R. [University of Tennessee, Knoxville (UTK); Czyrkowski, H. [University of Warsaw; Cwiok, Mikolaj [Warsaw University; Darby, Iain [University of Tennessee, Knoxville (UTK); Dabrowski, Ryszard [Warsaw University; Ginter, T. N. [Michigan State University, East Lansing; Grzywacz, Robert [University of Tennessee, Knoxville (UTK); Karny, M. [University of Warsaw; Korgul, A. [University of Warsaw; Kusmierz, W. [University of Warsaw; Liddick, Sean [University of Tennessee, Knoxville (UTK); Rajabali, Mustafa [University of Tennessee, Knoxville (UTK); Rykaczewski, Krzysztof Piotr [ORNL; Stolz, A. [Michigan State University, East Lansing

    2008-01-01T23:59:59.000Z

    The decay of extremely neutron-deficient isotope 45Fe has been studied by using a new type of gaseous detector in which a technique of optical imaging is used to record tracks of charged particles. The two-proton radioactivity and the beta-decay channels accompanied by proton(s) emission were clearly identified. For the first time, the angular and energy correlations between two protons emitted from the 45Fe ground-state were measured. The obtained distributions were confronted with predictions of a three-body model. Studies of beta-decay channels of 45Fe provided first unambiguous evidence for the beta-delayed three proton emission.

  18. Phase transition and metallization of FeO at high pressures and temperatures

    SciTech Connect (OSTI)

    Fischer, Rebecca A.; Campbell, Andrew J.; Lord, Oliver T.; Shofner, Gregory A.; Dera, Przemyslaw; Prakapenka, Vitali B. (Maryland); (UC); (UCL)

    2012-05-10T23:59:59.000Z

    Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component of the core. Therefore its high pressure-temperature behavior, including its electronic structure, is essential to understanding the nature and evolution of Earth's deep interior. We performed X-ray diffraction and radiometric measurements on wuestite in a laser-heated diamond anvil cell, finding an insulator-metal transition at high pressures and temperatures. Our data show a negative slope for this apparently isostructural phase boundary, which is characterized by a volume decrease and emissivity increase. The metallic phase of FeO is stable at conditions of the lower mantle and core, which has implications for the high P-T character of Fe-O bonds, magnetic field propagation, and lower mantle conductivity.

  19. Surface transport properties of Fe-based superconductors: The influence of degradation and inhomogeneity

    SciTech Connect (OSTI)

    Plecenik, T.; Gregor, M.; Sobota, R.; Truchly, M.; Satrapinskyy, L.; Kus, P.; Plecenik, A. [Department of Experimental Physics, FMPI, Comenius University, 842 48 Bratislava (Slovakia)] [Department of Experimental Physics, FMPI, Comenius University, 842 48 Bratislava (Slovakia); Kurth, F.; Holzapfel, B.; Iida, K. [Institute for Metallic Materials, IFW Dresden, P. O. Box 270116, D-01171 Dresden (Germany)] [Institute for Metallic Materials, IFW Dresden, P. O. Box 270116, D-01171 Dresden (Germany)

    2013-07-29T23:59:59.000Z

    Surface properties of Co-doped BaFe{sub 2}As{sub 2} epitaxial superconducting thin films were inspected by X-ray photoelectron spectroscopy, scanning spreading resistance microscopy (SSRM), and point contact spectroscopy (PCS). It has been shown that surface of Fe-based superconductors degrades rapidly if being exposed to air, what results in suppression of gap-like structure on PCS spectra. Moreover, SSRM measurements revealed inhomogeneous surface conductivity, what is consistent with strong dependence of PCS spectra on contact position. Presented results suggest that fresh surface and small probing area should be assured for surface sensitive measurements like PCS to obtain intrinsic properties of Fe-based superconductors.

  20. Tailoring of a metastable material: alfa-FeSi2 thin film

    SciTech Connect (OSTI)

    Cao, Guixin [ORNL; Singh, David J [ORNL; Zhang, Xiaoguang [ORNL; Samolyuk, German D [ORNL; Qiao, Liang [ORNL; Parish, Chad M [ORNL; Ke, Jin [The University of Tennessee; Zhang, Yanwen [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Guo, Hangwen [ORNL; Tang, Siwei [ORNL; Wang, Wenbin [ORNL; Yi, Jieyu [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Cantoni, Claudia [ORNL; Siemons, Wolter [ORNL; Payzant, E Andrew [ORNL; Biegalski, Michael D [ORNL; Ward, Thomas Zac [ORNL; Sales, Brian C [ORNL; Mandrus, D. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Stocks, George Malcolm [ORNL; Gai, Zheng [ORNL

    2015-01-01T23:59:59.000Z

    The epitaxially stabilized metallic -FeSi2 thin films on Si(001) were grown using pulsed laser deposition. While the bulk material of -FeSi2 is a high temperature metastable phase and nonmagnetic, the thin film is stabilized at room temperature and shows unusual electronic transport and magnetic properties due to strain modification. The transport renders two different conducting states with a strong crossover at 50 K accompanied by an onset of ferromagnetism as well as a substantial magnetocaloric effect and magnetoresistance. These experimental results are discussed in terms of the unusual electronic structure of -FeSi2 obtained within density functional calculations and Boltzmann transport calculations with and without strain. Our findings provide an example of a tailored material with interesting physics properties for practical applications.

  1. Void swelling resistance in Fe-Cr alloys at 200 dpa

    SciTech Connect (OSTI)

    Gelles, D.S. [Pacific Northwest Lab., Richland, WA (United States)

    1995-09-01T23:59:59.000Z

    Microstructural examinations have been performed on a serious of binary Fe-cr alloys irradiated to 200 dpa at 425 C in a fast breeder reactor. The alloy compositions ranged from 3% to 18% Cr in 3% Cr increments, and the irradiation temperature corresponded to the peak swelling condition for this alloy class. Density measurements showed swelling levels as high as 7.4%, with the highest swelling found in the Fe-9Cr and Fe-6Cr alloys. Microstructural examinations revealed that the highest swelling conditions contained well-developed voids, often as large as 100 nm, and a dislocation network comprised of both a/2<111> and a<100> Burgers vectors. Swelling was lower in the other alloys, and the swelling reduction could be correlated with increased precipitation. These results are considered in light of the current theories for low swelling in ferritic alloys, but no theory is available to completely explain the results.

  2. The internal-nitriding behavior of Co-Fe-Al alloys

    SciTech Connect (OSTI)

    Chen, I.C. [Raytheon Systems Co., El Segundo, CA (United States). Sensors and Electronics Systems] [Raytheon Systems Co., El Segundo, CA (United States). Sensors and Electronics Systems; Douglass, D.L. [Univ. of Arizona, Tucson, AZ (United States). Arizona Materials Labs.] [Univ. of Arizona, Tucson, AZ (United States). Arizona Materials Labs.

    1999-10-01T23:59:59.000Z

    Co-10Fe, Co-20Fe, and Co-40Fe alloys containing 3 at.% Al were internally nitrided in NH{sub 3}/H{sub 2} mixtures over the range 700--1000 C. The kinetics of thickening of the internal-reaction zone followed the parabolic rate law, suggesting that solid-state diffusion was rate controlling. Nitrogen permeabilities were obtained for each alloy. AlN was the only nitride to form for all materials and at all temperatures. At high temperature, the nitride precipitates formed hexagonal plates near the surface, the precipitates becoming more blocky near the reaction front. Precipitate size increased with increasing depth in the alloy and increasing temperature, because of competition between nucleation and growth processes. Increasing iron content increased the reaction kinetics due to increased nitrogen solubility with increasing iron content.

  3. Critical Fields, Thermally Activated Transport, and Critical Current Density of Beta-FeSe Single Crystals

    SciTech Connect (OSTI)

    Petrovic, C.; Lei, H.; Hu, R.

    2011-07-27T23:59:59.000Z

    We present critical fields, thermally activated flux flow (TAFF), and critical current density of tetragonal phase {beta}-FeSe single crystals. The upper critical fields H{sub c2}(T) for H {parallel} (101) and H {perpendicular} (101) are nearly isotropic and are likely governed by the Pauli limiting process. The large Ginzburg-Landau parameter {Kappa} {approx} 72.3(2) indicates that {beta}-FeSe is a type-II superconductor with a smaller penetration depth than in Fe(Te, Se). The resistivity below T{sub c} follows Arrhenius TAFF behavior. For both field directions below 30 kOe, single-vortex pinning is dominant, whereas collective creep becomes important above 30 kOe. The critical current density J{sub c} from M-H loops for H {parallel} (101) is about five times larger than for H {perpendicular} (101), yet much smaller than in other iron-based superconductors.

  4. A Ni-Fe Layered Double Hydroxide-Carbon Nanotube Complex for Water Oxidation

    E-Print Network [OSTI]

    Gong, Ming; Wang, Hailiang; Liang, Yongye; Wu, Justin Zachary; Zhou, Jigang; Wang, Jian; Regier, Tom; Wei, Fei; Dai, Hongjie

    2013-01-01T23:59:59.000Z

    Highly active, durable and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double hydroxide nanoplates on mildly oxidized multi-walled carbon nanotubes. Incorporation of Fe into the nickel hydroxide induced the formation of NiFe-layered double hydroxide. The nanoplates were covalently attached to a network of nanotubes, affording excellent electrical wiring to the nanoplates. The ultra-thin Ni-Fe layered double hydroxide nanoplates/carbon nanotube complex was found to exhibit unusually high electro-catalytic activity and stability for oxygen evolution and outperformed commercial precious metal Ir catalysts.

  5. New EUV Fe IX emission line identifications from Hinode/EIS

    E-Print Network [OSTI]

    P. R. Young

    2008-10-28T23:59:59.000Z

    Four Fe IX transitions in the wavelength range 188--198 A are identified for the first time in spectra from the EUV Imaging Spectrometer on board the Hinode satellite. In particular the emission line at 197.86 A is unblended and close to the peak of the EIS sensitivity curve, making it a valuable diagnostic of plasma at around 800,000 K - a critical temperature for studying the interface between the corona and transition region. Theoretical ratios amongst the four lines predicted from the CHIANTI database reveal weak sensitivity to density and temperature with observed values consistent with theory. The ratio of 197.86 relative to the 171.07 resonance line of Fe IX is found to be an excellent temperature diagnostic, independent of density, and the derived temperature in the analysed data set is log T=5.95, close to the predicted temperature of maximum ionization of Fe IX.

  6. Substitution of Ni for Fe in superconducting Fe?.??Te?.?Se?.? depresses the normal-state conductivity but not the magnetic spectral weight

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Jinghui; Tranquada, J. M.; Zhong, Ruidan; Li, Shichao; Gan, Yuan; Xu, Zhijun; Zhang, Cheng; Ozaki, T.; Matsuda, M.; Zhao, Yang; et al

    2015-01-01T23:59:59.000Z

    We have performed systematic resistivity and inelastic neutron scattering measurements on Fe?.???zNizTe?.?Se?.? samples to study the impact of Ni substitution on the transport properties and the low-energy (? 12 meV) magnetic excitations. It is found that, with increasing Ni doping, both the conductivity and superconductivity are gradually suppressed; in contrast, the low-energy magnetic spectral weight changes little. Comparing with the impact of Co and Cu substitution, we find that the effects on conductivity and superconductivity for the same degree of substitution grow systematically as the atomic number of the substituent deviates from that of Fe. The impact of the substituentsmore »as scattering centers appears to be greater than any contribution to carrier concentration. The fact that low-energy magnetic spectral weight is not reduced by increased electron scattering indicates that the existence of antiferromagnetic correlations does not depend on electronic states close to the Fermi energy.« less

  7. Substitution of Ni for Fe in superconducting Fe?.??Te?.?Se?.? depresses the normal-state conductivity but not the magnetic spectral weight

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Jinghui [Nanjing Univ., Nanjing (China); Tranquada, J. M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhong, Ruidan [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States); Li, Shichao [Nanjing Univ., Nanjing (China); Gan, Yuan [Nanjing Univ., Nanjing (China); Xu, Zhijun [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zhang, Cheng [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States); Ozaki, T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Matsuda, M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Zhao, Yang [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, G. [Brookhaven National Lab. (BNL), Upton, NY (United States); Gu, Genda [Brookhaven National Lab. (BNL), Upton, NY (United States); Birgeneau, R. J. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wen, Jinsheng [Nanjing Univ., Nanjing (China)

    2015-01-01T23:59:59.000Z

    We have performed systematic resistivity and inelastic neutron scattering measurements on Fe?.???zNizTe?.?Se?.? samples to study the impact of Ni substitution on the transport properties and the low-energy (? 12 meV) magnetic excitations. It is found that, with increasing Ni doping, both the conductivity and superconductivity are gradually suppressed; in contrast, the low-energy magnetic spectral weight changes little. Comparing with the impact of Co and Cu substitution, we find that the effects on conductivity and superconductivity for the same degree of substitution grow systematically as the atomic number of the substituent deviates from that of Fe. The impact of the substituents as scattering centers appears to be greater than any contribution to carrier concentration. The fact that low-energy magnetic spectral weight is not reduced by increased electron scattering indicates that the existence of antiferromagnetic correlations does not depend on electronic states close to the Fermi energy.

  8. Substitution of Ni for Fe in superconducting Fe?.??Te?.?Se?.? depresses the normal-state conductivity but not the magnetic spectral weight

    SciTech Connect (OSTI)

    Wang, Jinghui [Nanjing Univ., Nanjing (China); Tranquada, J. M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhong, Ruidan [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States); Li, Shichao [Nanjing Univ., Nanjing (China); Gan, Yuan [Nanjing Univ., Nanjing (China); Xu, Zhijun [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zhang, Cheng [Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States); Ozaki, T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Matsuda, M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Zhao, Yang [National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States); Univ. of Maryland, College Park, MD (United States); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States); Xu, G. [Brookhaven National Lab. (BNL), Upton, NY (United States); Gu, Genda [Brookhaven National Lab. (BNL), Upton, NY (United States); Birgeneau, R. J. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wen, Jinsheng [Nanjing Univ., Nanjing (China)

    2015-01-01T23:59:59.000Z

    We have performed systematic resistivity and inelastic neutron scattering measurements on Fe?.???zNizTe?.?Se?.? samples to study the impact of Ni substitution on the transport properties and the low-energy (? 12 meV) magnetic excitations. It is found that, with increasing Ni doping, both the conductivity and superconductivity are gradually suppressed; in contrast, the low-energy magnetic spectral weight changes little. Comparing with the impact of Co and Cu substitution, we find that the effects on conductivity and superconductivity for the same degree of substitution grow systematically as the atomic number of the substituent deviates from that of Fe. The impact of the substituents as scattering centers appears to be greater than any contribution to carrier concentration. The fact that low-energy magnetic spectral weight is not reduced by increased electron scattering indicates that the existence of antiferromagnetic correlations does not depend on electronic states close to the Fermi energy.

  9. Transition from Three-Dimensional Anisotropic Spin Excitations to Two-Dimensional Spin Excitations by Electron Doping the FeAs-Based BaFe1:96Ni0:04As2 Superconductor

    E-Print Network [OSTI]

    Hu, Jiangping

    by Electron Doping the FeAs-Based BaFe1:96Ni0:04As2 Superconductor Leland W. Harriger,1 Astrid Schneidewind,2 arsenides is important because high-transition temperature (high-Tc) superconductivity arises from electron optimal superconductivity [4­6], the gapped spin wave excitations were replaced by a gapless continuum

  10. Bioavailability of Fe(III) in Loess Sediments: An Important Source of Electron Acceptors

    SciTech Connect (OSTI)

    Bishop, Michael E.; Jaisi, Deb P.; Dong, Hailiang; Kukkadapu, Ravi K.; Ji, Junfeng

    2010-08-01T23:59:59.000Z

    A quantitative study was conducted to understand if Fe (III) in loess sediments is available for microbial respiration by using a common metal reducing bacterium, Shewanella putrefaciens, CN32. The loess samples were collected from three different sites: St. Louis (Peoria), Missouri, USA; Huanxia (HX) and Yanchang (YCH), Shanxi Province of China. Wet chemical analyses indicated that the total Fe concentration for the three samples was 1.69%, 2.76%, and 3.29%, respectively, of which 0.48%, 0.67%, and 1.27% was Fe(III). All unreduced loess sediments contained iron oxides and phyllosilicates (smectite, illite, chlorite, vermiculite), in addition to common minerals such as quartz, feldspar, plagioclase, calcite, and dolomite. Bioreduction experiments were performed at a loess concentration of 20 mg/mL using lactate as the sole electron donor, Fe(III) in loess as the sole electron acceptor in the presence and absence of anthraquinone-2, 6-disulfonate (AQDS) as an electron shuttle. Experiments were performed in non-growth (bicarbonate buffer) and growth (M1) media with a cell concentration of ~2.8 x 107 and 2.1 x 107 cells/mL, respectively. The unreduced and bioreduced solids were analyzed by X-ray diffraction (XRD), Mössbauer spectroscopy, diffuse reflection spectroscopy (DRS), and scanning electron microscopy/energy dispersive spectroscopy (SEM/EDS) methods. Despite many similarities among the three loess samples, the extent and rate of Fe (III) reduction varied significantly. For example, in presence of AQDS the extent of reduction in the non-growth experiment was 25% in HX, 34% in Peoria, and 38% in YCH. The extent of reduction in the growth experiment was 72% in HX, 94% in Peoria, and 56% in YCH. The extent of bioreduction was lower in absence of AQDS. Overall, AQDS and the M1 growth medium significantly enhanced the rate and extent of bioreduction. Fe(III) in iron oxides and Fe(III)-containing phyllosilicates was bioreduced. Biogenic illite, siderite, and vivianite formed. The results of this study suggest that Fe (III) in loess sediments represents a potentially important source of electron acceptors to support microbial activity in dry environments.

  11. El monólogo como acto de fe: Estreno en Broadway de Rodolfo Usigli

    E-Print Network [OSTI]

    Layera, Ramó n

    1994-10-01T23:59:59.000Z

    FALL 1994 81 El monólogo como acto de fe: Estreno en Broadway de Rodolfo Usigli Ramón Layera El monólogo corto Estreno en Broadway de Rodolfo Usigli, como pieza inédita hasta hace pocos meses, representa un desafío a la crítica académica ya... circunstancias personales de su autor, se puede decir que se trata de un acto de fe en la capacidad sublimadora y redentora del arte dramático. Comenzando por el título, Usigli anuncia el carácter ficticio y metateatral del monólogo. Se trata de un estreno...

  12. Microstructure evolution of hot-deformed Nd-Fe-B anisotropic magnets

    SciTech Connect (OSTI)

    Liu, J., E-mail: liu.jun@nims.go.jp; Hono, K. [Elements Strategy Initiative Center for Magnetic Materials, National Institute for Materials Science, Tsukuba 305-0047 (Japan); Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8577 (Japan); Sepehri-Amin, H.; Ohkubo, T. [Elements Strategy Initiative Center for Magnetic Materials, National Institute for Materials Science, Tsukuba 305-0047 (Japan); Hioki, K.; Hattori, A. [Daido Steel Co. Ltd., Nagoya 457-8545 (Japan)

    2014-05-07T23:59:59.000Z

    The microstructural evolution of hot-deformed Nd-Fe-B magnets in each stage of hot-deformation process was studied using transmission electron microscopy and three dimensional atom probe (3DAP). The anisotropic growth of initially isotropic grains in rapidly solidified alloy occurs by annealing without pressing. 3DAP analyses showed a higher concentration of rare-earth elements in the intergranular phase parallel to the flat surface of platelet shaped Nd{sub 2}Fe{sub 14}B grains compared to that in the intergranular phase at the side of platelets.

  13. Nanolamellar magnetoelectric BaTiO3–CoFe2O4 bicrystal

    E-Print Network [OSTI]

    Ren, Shenqiang; Laver, Mark; Wuttig, Manfred

    2009-10-13T23:59:59.000Z

    Nanolamellar magnetoelectric BaTiO3–CoFe2O4 bicrystal Shenqiang Ren,1 Mark Laver,2 and Manfred Wuttig1,a#1; 1Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742-2115, USA 2NIST Center for Neutron... Research, Gaithersburg, Maryland 20899-6103, USA #1;Received 30 July 2009; accepted 9 September 2009; published online 13 October 2009#2; Here, we report a spontaneously formed nanolamellar BaTiO3–CoFe2O4 bicrystal. #1;11Ż0#2; interfaces join the BaTiO3...

  14. Structural changes in nano-crystalline mackinawite (FeS) at high - pressure.

    SciTech Connect (OSTI)

    Ehm, L.; Michael, F. M.; Antao, S. M.; Martin, C. D.; Lee, P. L.; Shastri, S. D.; Chupas, P. J.; Parise, J. B.; Stony Brook Univ.

    2009-02-01T23:59:59.000Z

    The high-pressure behavior of nanocrystalline mackinawite (FeS) with particle sizes of 6, 7 and 8 nm has been investigated by high-energy X-ray total scattering and pair distribution function analysis. An irreversible first-order structural phase transition from tetragonal mackinawite to orthorhombic FeS-II was observed at about 3 GPa. The transition is induced by the closure of the van der Waals gap in the layered mackinawite structure. A grain size effect on the transition pressure and the compressibility was observed.

  15. Room-Temperature Multiferroic Hexagonal LuFeO3 Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Wenbin; Zhao, Jun; Wang, Wenbo; Gai, Zheng; Balke, Nina; Chi, Miaofang; Lee, Ho Nyung; Tian, Wei; Zhu, Leyi; Cheng, Xuemei; Keavney, David J.; Yi, Jieyu; Ward, Thomas Z.; Snijders, Paul C.; Christen, Hans M.; Wu, Weida; Shen, Jian; Xu, Xiaoshan

    2013-06-01T23:59:59.000Z

    The crystal and magnetic structures of single-crystalline hexagonal LuFeO3 films have been studied using x-ray, electron, and neutron diffraction methods. The polar structure of these films are found to persist up to 1050 K; and the switchability of the polar behavior is observed at room temperature, indicating ferroelectricity. An antiferromagnetic order was shown to occur below 440 K, followed by a spin reorientation resulting in a weak ferromagnetic order below 130 K. This observation of coexisting multiple ferroic orders demonstrates that hexagonal LuFeO3 films are room-temperature multiferroics.

  16. Effect of ethylenediamine on the electrodeposition of Ni-Fe alloys

    SciTech Connect (OSTI)

    Harris, T.M.; Wilson, J.L.; Bleakley, M. [Univ. of Tulsa, OK (United States). Dept. of Chemistry] [Univ. of Tulsa, OK (United States). Dept. of Chemistry

    1999-04-01T23:59:59.000Z

    Ethylenediamine (EDA) greatly affects the phenomenon of anomalous codeposition observed in the nickel-iron electrodeposition system. EDA increases the Ni/Fe ratio of the deposit when the bath is chloride based and the pH is at least 5. Ion microprobe analysis indicates that EDA is incorporated in the deposit. It is hypothesized that EDA adsorbs on the deposit surface and serves as a bridge for Ni{sup 2+} deposition in preference to that for Fe{sup 2+}, which forms less stable complexes with EDA. Chloride ion in the bath is necessary for the adsorption of EDA, and thus the relative increase in the nickel deposition rate.

  17. Electrodeposition of Cu/Fe{sub 20}Ni{sub 80} magnetic multilayers

    SciTech Connect (OSTI)

    Chassaing, E.; Nallet, P.; Trichet, M.F. [CNRS, Vitry-sur-Seine (France). Centre d`Etudes de Chimie Metallurgique

    1996-05-01T23:59:59.000Z

    Electrodeposition conditions have been studied in order to prepare Cu/Fe{sub 20}Ni{sub 80} multilayers by the pulse potential method using a single electrolyte. Individual layer thicknesses ranged between 0.5 and 3 nm. Up to 40 bilayers were electrodeposited either on copper or glass plate substrates. Grazing angle X-ray diffraction showed good coherency between the layers. A magnetic coupling between FeNi layers has been observed with a magnetoresistance ratio of 2% at 2 kOe and 77 K.

  18. Symmetry-Defying Iron Pyrite (FeS2) Nanocrystals through Oriented Attachment

    E-Print Network [OSTI]

    Gong, Maogang; Kirkeminde, Alec; Ren, Shenqiang

    2013-06-28T23:59:59.000Z

    states, dislocations, twins, etc) of FeS2 nano- crystals dictate their optoelectronic and electrochemical applica- tions, therefore a strategy to achieve high quality crystalline FeS2 needs to be identified. Polycrystalline-to-monocrystalline conver- sion... in pyrite material is the limiting factor for performance of devices2,35–37. In this study, it is seen that the pyrite particles eventually reach a maximum size, and then begin to convert from poly-crystalline to mono-crystalline, which will reduce...

  19. Attempt to produce element 120 in the 244Pu + 58Fe reaction

    SciTech Connect (OSTI)

    Oganessian, Y T; Utyonkov, V K; Lobanov, Y V; Abdullin, F S; Polyakov, A N; Sagaidak, R N; Shorokovsky, I V; Tsyganov, Y S; Voinov, A A; Mezentsev, A N; Subbotin, V G; Sukhov, A M; Subotic, K; Zagrebaev, V I; Dmitriev, S N; Henderson, R A; Moody, K J; Kenneally, J M; Landrum, J H; Shaughnessy, D A; Stoyer, M A; Stoyer, N J; Wilk, P A

    2008-10-24T23:59:59.000Z

    An experiment aimed at the synthesis of isotopes of element 120 has been performed using the {sup 244}Pu({sup 58}Fe,xn){sup 302-x} 120 reaction. No decay chains consistent with fusion-evaporation reaction products were observed during an irradiation with a beam dose of 7.1 x 10{sup 18} 330-MeV {sup 58}Fe projectiles. The sensitivity of the experiment corresponds to a cross section of 0.4 pb for the detection of one decay.

  20. Evolution of level density step structures from 56,57-Fe to 96,97-Mo

    E-Print Network [OSTI]

    A. Schiller; E. Tavukcu; L. A. Bernstein; P. E. Garrett; M. Guttormsen; M. Hjorth-Jensen; C. W. Johnson; G. E. Mitchell; J. Rekstad; S. Siem; A. Voinov; W. Younes

    2003-02-24T23:59:59.000Z

    Level densities have been extracted from primary gamma spectra for 56,57-Fe and 96,97-Mo nuclei using (3-He,alpha gamma) and (3-He,3-He') reactions on 57-Fe and 97-Mo targets. The level density curves reveal step structures above the pairing gap due to the breaking of nucleon Cooper pairs. The location of the step structures in energy and their shapes arise from the interplay between single-particle energies and seniority-conserving and seniority-non-conserving interactions.

  1. Synthesis, morphology and optical properties of LaFeO{sub 3} nanospheres

    SciTech Connect (OSTI)

    Kumar, R. Dhinesh [Crystal Growth Centre, Anna University, Chennai - 600 025 (India); Jayavel, R., E-mail: rjvel@annauniv.edu [Crystal Growth Centre, Anna University, Chennai - 600 025, India and Centre for Nanoscience and Technology, Anna University, Chennai - 600 025 (India)

    2014-04-24T23:59:59.000Z

    LaFeO{sub 3} nanospheres have been successively synthesized via hydrothermal method. Structural, morphological and optical properties of the prepared nanopowder were analyzed by powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV–Vis absorption spectroscopy. The UV–Vis shows strong absorption at 475 nm which has excellent visible light absorption ability. Band gap energy of the prepared nanosphere was found to be 2.60 eV. The results indicate that the LaFeO{sub 3} nanospheres prepared by this method could be a kind of photocatalytic material.

  2. Neutron Scattering Study on spin dynamics in superconducting (TlRb)2Fe4Se5

    SciTech Connect (OSTI)

    Chi, Songxue [ORNL; Ye, Feng [ORNL; Bao, Wei [Renmin University of China; Fang, Dr. Minghu [Zhejiang University; Wang, H.D. [Zhejiang University; Dong, C.H. [Zhejiang University; Savici, Andrei T [ORNL; Granroth, Garrett E [ORNL; Stone, Matthew B [ORNL; Fishman, Randy Scott [ORNL

    2013-01-01T23:59:59.000Z

    Spin dynamics in superconducting (Tl,Rb)2Fe4Se5 was investigated using the inelastic neutron scattering technique. Spin wave branches that span an energy range from 6.5 to 209 meV are success- fully described by a Heisenberg model whose dominant interactions include only the in-plane nearest (J1 and J0 1) and next nearest neighbor (J2 and J0 2) exchange terms within and between the tetramer spin blocks, respectively. These exchange constants, experimentally determined in this work, would crucially constrain the diverse theoretical viewpoints on magnetism and superconductivity in the Fe-based materials.

  3. SEMI-ANNUAL REPORTS FOR Louisiana LNG Energy LLC - FE DKT. NO 14-19-LNG -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin ofEnergy atLLC - FE DKT. 10-160-LNG - ORDER 2913 | Department ofORDER 3324 |FE

  4. SEMI-ANNUAL REPORTS FOR MAGNOLIA LNG, LLC - FE DKT. NO. 12-183-LNG - ORDER

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin ofEnergy atLLC - FE DKT. 10-160-LNG - ORDER 2913 | Department ofORDER 3324 |FE3245 |

  5. SEMI-ANNUAL REPORTS FOR PANGEA LNG (NORTH AMERICA) HOLDINGS, LLC - FE DKT.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin ofEnergy atLLC - FE DKT. 10-160-LNG - ORDER 2913 | Department ofORDER 3324 |FE3245

  6. Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano-

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Particle-size and morphology dependence of the preferred interface orientation in LiFePO4 nano insights into the equilibrium properties and potential two-phase lithiation mechanisms in LiFePO4 nano, if experimentally-relevant nano-particles were to (de)lithiate under a thermodynamic two-phase mechanism

  7. Bulk SmCo5/a-Fe nanocomposite permanent magnets fabricated by mould-free Joule-heating compaction

    E-Print Network [OSTI]

    Liu, J. Ping

    Bulk SmCo5/a-Fe nanocomposite permanent magnets fabricated by mould-free Joule-heating compaction 2011) Bulk SmCo5/a-Fe nanocomposite magnets have been prepared using a Joule-heating compaction of 2 GPa at temperatures above 400 C. Structural analysis shows that the grain size of both the SmCo5

  8. Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode and annealing temperature are used for MPO4 nanoparticle coatings M = Al, Fe, Ce, and SrH on a LiCoO2 cathode, the extent of the coating coverage is influenced by the nanoparticle size or morphology. Nanoparticles AlPO4

  9. Effect of Elastic Stress on Phase Separation in Fe-20%Cr-6%Al-0.5%Ti ODS alloy

    E-Print Network [OSTI]

    Cambridge, University of

    Effect of Elastic Stress on Phase Separation in Fe- 20%Cr-6%Al-0.5%Ti ODS alloy C. Capdevila1, M. K Aldazabal from CEIT; and Monica Campos from Carlos III University (UC3) for their help with ODS for nuclear applications Acknowledgements Effect of Elastic Stress on Phase Separation in Fe-Cr-Al-Ti ODS alloy by C

  10. Materials Science and Engineering A 449451 (2007) 1217 Non-equilibrium solidification of concentrated FeGe alloys

    E-Print Network [OSTI]

    Srivastava, Kumar Vaibhav

    with the interface diffusive speed (VD) for diffusion-limited or speed of sound (Vs) for collision-limited growth phase change like peritectic reaction during liquid to solid transformation. The Fe-rich part of Fe-equilibrium conditions. The deviation of the chemical equilibrium at the solid­liquid interface and the kinetic

  11. The Effect of Aluminum Content on the Corrosion Behavior of Fe-Al Alloys in Reducing Environments at 700 C

    E-Print Network [OSTI]

    DuPont, John N.

    The Effect of Aluminum Content on the Corrosion Behavior of Fe-Al Alloys in Reducing Environments with the observance and/or duration of each stage directly related to the aluminum content of the alloy. The first behavior of low aluminum Fe-Al alloys in moder- tions are presently providing protection

  12. FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters

    E-Print Network [OSTI]

    Wilhelm, Steven W.

    FeCycle: Attempting an iron biogeochemical budget from a mesoscale SF6 tracer experiment to ocean physics. In summer 2003 we conducted FeCycle, a 10-day mesoscale tracer release in HNLC waters SE biogeochemical budget from a mesoscale SF6 tracer experiment in unperturbed low iron waters, Global Biogeochem

  13. Variability of Optical \\ion{Fe}{ii} Complex in Narrow-Line Seyfert 1 Galaxy NGC 4051

    E-Print Network [OSTI]

    J. Wang; J. Y. Wei; X. T. He

    2005-04-05T23:59:59.000Z

    The variability of optical FeII blends in NGC 4051 is examined from spectra extracted from the AGN Watch program.In our analysis, the FeII complex are subtracted and measured with the following results. Firstly, the FeII variations were detected in NGC 4051 during a 3-year period. The identified FeII variations followed the variations in continuum closely. Secondly, the EW of FeII is reported to increase with the rising continuum flux, which is consistent with previous claims that there is no convincing Baldwin Effect in optical FeII. Thirdly, by comparing the variations of H$\\beta$ and FeII, we find that RFe scales with continuum flux as $\\rm{R_{Fe}\\propto (5.0\\pm0.8) \\log(L/M)}$, which is significantly different from the theoretical expectations. Finally, in six selected Seyferts, four out of five Narrow-Line Seyfert 1 galaxies present positive correlation between RFe and the continuum flux. The negative correlations are identified in the remaindng two objects that have relatively broad profiles of H$\\beta$ ($\\rm{FWHM>1500 km\\ s^{-1}}$).We argue that the difference of electron density of broad line clouds and/or variability behavior of incident high-energy radiation can explain the dichotomy in variability behavior of RFe.

  14. Induction heating of FeCo nanoparticles for rapid rf curing of epoxy K. J. Miller,1,a

    E-Print Network [OSTI]

    McHenry, Michael E.

    , and cracking of the polymer. An alternative curing process involves remote, noncontact rf heating of MNP loadedInduction heating of FeCo nanoparticles for rapid rf curing of epoxy composites K. J. Miller,1,a K epoxy composites through radio-frequency rf heating. The rf response of functionalized FeCo MNPs

  15. Single-Ion Magnetic Anisotropy and Isotropic Magnetic Couplings in the Metal-Organic Framework Fe2(dobdc)

    E-Print Network [OSTI]

    are here assessed with quantum chemical calculations performed on a finite size cluster. It is shown.16 The structure of this compound consists of high-spin FeII ions arranged in a helical pattern along columns at the intersection of three hexagonal pores. As synthesized, each FeII ion is hexacoordinate; five coordination sites

  16. Magnetic properties of HITPERM ,,Fe,Co...88Zr7B4Cu1 magnets M. A. Willard,a)

    E-Print Network [OSTI]

    Laughlin, David E.

    power applications requires new bulk soft magnetic materials that 1 are capable of operating at higher magnetization that persists to the phase transformation at 980 °C. Alternating current permeability experiments nanocrystalline Fe­Si­B­Nb­Cu alloys and nanocrystalline Fe­M­B­Cu M Zr, Nb, Hf, etc. alloys have been optimized

  17. Highway Geology Symposium Santa Fe, 2008 HGS Session 5 -Paper 5.2 Page 1 of 21

    E-Print Network [OSTI]

    Haneberg, William C.

    59th Highway Geology Symposium Santa Fe, 2008 HGS Session 5 - Paper 5.2 Page 1 of 21 59 TH HIGHWAY GEOLOGY SYMPOSIUM 2008 Santa Fe, New Mexico SESSION 5 PAPER #5.2 REVISITING AN OLD PROJECT WITH NEW TECHNOLOGY-- DIGITAL TERRAIN MODELING AND MULTI-LAYERED VIRTUAL GEOLOGIC HAZARD MAPPING ALONG A PROPOSED

  18. Synthesis, structural and magnetic characterisation of nanocrystalline nickel ferrite NiFe2O4 obtained by reactive milling

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Synthesis, structural and magnetic characterisation of nanocrystalline nickel ferrite ­ NiFe2O4-Napoca, Romania Abstract Nanocrystalline nickel ferrite (NiFe2O4) has been synthesized from a stoichiometric. The particles size distribution was analyzed using a laser particle size analyser. The nickel ferrite begins

  19. Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Corrosion resistance and friction of sintered NdFeB coated with Ti/TiN multilayers Yuanyuan Cheng Polarization Fretting corrosion Ti/TiN multilayers were deposited on sintered NdFeB by radio frequency magnetron sputtering. The film grain size decreased with the number of multilayers in the stack. Corrosion

  20. DOI: 10.1002/adma.200502721 Vapor-Phase Synthesis and Characterization of e-FeSi Nanowires**

    E-Print Network [OSTI]

    Deshmukh, Mandar M.

    -dimensional inorganic nano- structures have emerged as promising materials for funda- mental studies and possibleDOI: 10.1002/adma.200502721 Vapor-Phase Synthesis and Characterization of e-FeSi Nanowires-rod or thin-film samples. Here, we report the synthesis of single-crystalline FeSi nanowires

  1. LARGE-AREA [Fe II] LINE MAPPING OF THE SUPERNOVA REMNANT IC 443 WITH THE IRSF/SIRIUS

    SciTech Connect (OSTI)

    Kokusho, Takuma; Nagayama, Takahiro; Kaneda, Hidehiro; Ishihara, Daisuke [Graduate School of Science, Nagoya University, Chikusa-ku, Nagoya 464-8602 (Japan); Lee, Ho-Gyu; Onaka, Takashi, E-mail: kokusho@u.phys.nagoya-u.ac.jp [Department of Astronomy, Graduate School of Science, University of Tokyo, Bunkyo-ku, Tokyo 113-0033 (Japan)

    2013-05-01T23:59:59.000Z

    We present the results of near-infrared (near-IR) [Fe II] line mapping of the supernova remnant IC 443 with IRSF/SIRIUS, using the two narrow-band filters tuned for the [Fe II] 1.257 {mu}m and [Fe II] 1.644 {mu}m lines. Covering a large area of 30' Multiplication-Sign 35', our observations reveal that [Fe II] filamentary structures exist all over the remnant, not only in an ionic shock shell, but also in a molecular shock shell and a central region inside the shells. With the two [Fe II] lines, we performed corrections for dust extinction to derive the intrinsic line intensities. We also obtained the intensities of thermal emission from the warm dust associated with IC 443, using the far- and mid-IR images taken with AKARI and Spitzer, respectively. As a result, we find that the [Fe II] line emission relative to the dust emission notably enhances in the inner central region. We discuss causes of the enhanced [Fe II] line emission, estimating the Fe{sup +} and dust masses.

  2. Petrologic mapping of the Moon using Fe, Mg, and Al abundances A.A. Berezhnoy a,*, N. Hasebe a

    E-Print Network [OSTI]

    Berezhnoi, Aleksei A.

    Petrologic mapping of the Moon using Fe, Mg, and Al abundances A.A. Berezhnoy a,*, N. Hasebe a , M for the presence of polar lunar hydrogen. Using Mg, Fe, and Al abundances, petrologic maps containing information: Moon; Maps of elemental abundances; Petrology; End-member rocks; Chemistry of lunar polar regions; Rock

  3. Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy), Rome, 6 au 10 juillet 2009

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy on Sustainable Fossil Fuels for Future Energy), Rome : Italy (2009)" #12;Communication : S4FE2009 (International Conference on Sustainable Fossil Fuels for Future Energy), Rome, 6 au 10 juillet 2009 2 FFiigguurree 11

  4. A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries

    E-Print Network [OSTI]

    1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

  5. Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed for battery management system (BMS) applications and comprehensive aging investigations. Based on a modified

  6. Controlled synthesis of CoFe2O4 nano-octahedra Andr Lus Lopes-Moriyamaa,b *

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Title Controlled synthesis of CoFe2O4 nano-octahedra Authors André Luís Lopes cetyltrimethylammonium bromide (CTAB) hindered the formation of goethite, which favored the production of a pure CoFe2O4" DOI : 10.1016/j.powtec.2014.01.080 #12;2 Hydrothermal synthesis; nanoparticles; cobalt ferrite; shape

  7. Sorption and transport of aqueous FeII in a goethite-coated sand column under anoxic

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Sorption and transport of aqueous FeII in a goethite-coated sand column under anoxic conditions K and dynamic flow conditions to evaluate the sorption of FeII onto three goethites (G1, G2 and G3) having batch experiments were combined with hydrodynamic parameters to simulate breakthrough curves in goethite

  8. Positive exchange bias and upward magnetic relaxation in a Fe-film/CoO-nanoparticle hybrid system

    E-Print Network [OSTI]

    Krishnan, Kannan M.

    Positive exchange bias and upward magnetic relaxation in a Fe-film/CoO- nanoparticle hybrid system exchange bias and upward magnetic relaxation in a Fe-film/CoO-nanoparticle hybrid system Wei Zhang) Heat-induced damping modification in yttrium iron garnet/platinum hetero-structures Appl. Phys. Lett

  9. Aluminum Triggers Decreased Aconitase Activity via Fe-S Cluster Disruption and the Overexpression of Isocitrate Dehydrogenase and

    E-Print Network [OSTI]

    Appanna, Vasu

    Aluminum Triggers Decreased Aconitase Activity via Fe-S Cluster Disruption and the Overexpression Research, Sudbury, Ontario P3E 6B4, Canada Although aluminum is known to be toxic to most or- ganisms, its that aluminum promotes the inhibition of aconitase (Acn) activity via the perturbation of the Fe-S cluster

  10. Thermal Expansion, Heat Capacity, and Thermal Conductivity of Nickel Ferrite (NiFe[subscript 2]O[subscript 4])

    E-Print Network [OSTI]

    Nelson, Andrew T.

    Nickel ferrite (NiFe[subscript 2]O[subscript 4]) is a major constituent of the corrosion deposits formed on the exterior of nuclear fuel cladding tubes during operation. NiFe[subscript 2]O[subscript 4] has attracted much ...

  11. The Role of FeS in Initial Activation and Performance Degradation of Na-NiCl2 Batteries

    SciTech Connect (OSTI)

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; Engelhard, Mark H.; Lemmon, John P.; Sprenkle, Vincent L.

    2014-12-25T23:59:59.000Z

    The role of iron sulfide (FeS) in initial cell activation and degradation in the Na-NiCl2 battery was investigated in this work. The research focused on identifying the effects of the FeS level on the electrochemical performance and morphological changes in the cathode. The x-ray photoelectron spectroscopy study along with battery tests revealed that FeS plays a critical role in initial battery activation by removing passivation layers on Ni particles. It was also found that the optimum level of FeS in the cathode resulted in minimum Ni particle growth and improved battery cycling performance. The results of electrochemical characterization indicated that sulfur species generated in situ during initial charging, such as polysulfide and sulfur, are responsible for removing the passivation layer. Consequently, the cells containing elemental sulfur in the cathode exhibited similar electrochemical behavior during initial charging compared to that of the cells containing FeS.

  12. Synthesis, Crystal Structure, and Magnetism of ?-Fe1.00(2)Se1.00(3) Single Crystals

    SciTech Connect (OSTI)

    Petrovic, C.; Billinge, S.

    2011-06-20T23:59:59.000Z

    Understanding iron-based superconductors requires high-quality impurity-free single crystals. So far they have been elusive for {beta}-FeSe and extraction of intrinsic materials properties has been compromised by several magnetic-impurity phases. Here, we report synchrotron-clean {beta}-FeSe superconducting single crystals grown via LiCl/CsCl flux method. Phase purity yields evidence for a defect-induced weak ferromagnetism that coexists with superconductivity below T{sub c}. In contrast to Fe{sub 1+y}Te-based superconductors, our results reveal that the interstitial Fe(2) site is not occupied and that all contribution to density of states at the Fermi level must come from in-plane Fe(1).

  13. Microstructural evolution of Fe grown on a (001) Cu film and its implication to the elastic anomaly in metallic superlattices

    SciTech Connect (OSTI)

    Koike, J.; Nastasi, M.

    1990-01-01T23:59:59.000Z

    A large softening of the shear modulus has been reported in metallic superlattices composed of insoluble bcc/fcc metals. In an attempt to understand this elastic anomaly, we have studied the microstructure of Fe/Cu bilayers as a function of the Fe thickness with transmission electron microscopy (TEM). Analysis of the moire fringes observed in plan-view TEM images revealed that the fcc Fe structure epitaxially grows on the (001) Cu up to a thickness of 2.0 nm. At 2.3 nm. At 2.3 nm, the bcc Fe structure nucleates, accompanying lattice rotation around the growth direction with respect to the underlying fcc structure. As the Fe thickness further increases, the submicron polycrystalline grains formed. Based on these results, the microstructure of the metallic superlattices and its relation to the softening of the shear modulus will be discussed. 22 refs., 2 figs

  14. Photoluminescence and photothermal effect of Fe{sub 3}O{sub 4} nanoparticles for medical imaging and therapy

    SciTech Connect (OSTI)

    Sadat, M. E.; Kaveh Baghbador, Masoud; Wagner, H. P.; Mast, David B., E-mail: mastdb@ucmail.uc.edu, E-mail: donglu.shi@uc.edu [Department of Physics, University of Cincinnati, Cincinnati, Ohio 45221 (United States); Dunn, Andrew W. [The Materials Science and Engineering Program, Department of Mechanical and Materials Engineering, College of Engineering and Applied Science, University of Cincinnati, Cincinnati, Ohio 45221 (United States); Ewing, Rodney C.; Zhang, Jiaming [Department of Geological and Environmental Sciences, Stanford University, Stanford, California 94305-2115 (United States); Xu, Hong [Med-X Institute, Shanghai Jiao Tong University, Shanghai 200030 (China); Pauletti, Giovanni M. [James L. Winkle College of Pharmacy, University of Cincinnati, Cincinnati, Ohio 45267 (United States); Shi, Donglu, E-mail: mastdb@ucmail.uc.edu, E-mail: donglu.shi@uc.edu [The Materials Science and Engineering Program, Department of Mechanical and Materials Engineering, College of Engineering and Applied Science, University of Cincinnati, Cincinnati, Ohio 45221 (United States); Shanghai East Hospital, The Institute for Biomedical Engineering and Nano Science, Tongji University School of Medicine, Shanghai 200120 (China)

    2014-09-01T23:59:59.000Z

    Photoluminescence (PL) of Fe{sub 3}O{sub 4} nanoparticle was observed from the visible to near-infrared (NIR) range by laser irradiation at 407?nm. PL spectra of ?10?nm diameter Fe{sub 3}O{sub 4} nanoparticles organized in different spatial configuration, showed characteristic emissions with a major peak near 560?nm, and two weak peaks near 690?nm and 840?nm. Different band gap energies were determined for these Fe{sub 3}O{sub 4} nanoparticle samples corresponding to, respectively, the electron band structures of the octahedral site (2.2?eV) and the tetrahedral site (0.9?eV). Photothermal effect of Fe{sub 3}O{sub 4} nanoparticles was found to be associated with the photoluminescence emissions in the NIR range. Also discussed is the mechanism responsible for the photothermal effect of Fe{sub 3}O{sub 4} nanoparticles in medical therapy.

  15. Li{sub 4}FeH{sub 6}: Iron-containing complex hydride with high gravimetric hydrogen density

    SciTech Connect (OSTI)

    Saitoh, Hiroyuki, E-mail: cyto@spring8.or.jp [Quantum Beam Science Center, Japan Atomic Energy Agency, Hyogo 679-5148 (Japan); Takagi, Shigeyuki; Matsuo, Motoaki; Aoki, Katsutoshi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Iijima, Yuki [WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Endo, Naruki [Renewable Energy Research Center, National Institute of Advanced Industrial Science and Technology, Fukushima 963-0215 (Japan); Orimo, Shin-ichi [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); WPI-Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

    2014-07-01T23:59:59.000Z

    Li{sub 4}FeH{sub 6}, which has the highest gravimetric hydrogen density of iron-containing complex hydrides reported so far, is synthesized by hydrogenation of a powder mixture of iron and LiH above 6.1 GPa at 900?°C. In situ synchrotron radiation X-ray diffraction measurements reveal that while kinetics require high temperature and thus high pressure for the synthesis, Li{sub 4}FeH{sub 6} is expected to be thermodynamically stable slightly below room temperature at ambient pressure; further synthetic studies to suppress the kinetic effects may enable us to synthesize Li{sub 4}FeH{sub 6} at moderate pressures. Li{sub 4}FeH{sub 6} can be recovered at ambient conditions where Li{sub 4}FeH{sub 6} is metastable.

  16. Time-dependent release of iron from soot particles by acid extraction and the reduction of fe3+ by elemental carbon

    E-Print Network [OSTI]

    Drake, Stephen James

    2009-05-15T23:59:59.000Z

    Elemental carbon reduces Fe3+ to Fe2+ in aqueous solutions. This process has potential implications in the adverse health effects of fine particles in air pollution, because both elemental carbon and iron are major components in atmospheric...

  17. Spin glass behavior in an interacting -Fe2O3 nanoparticle system D. Parker*1

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Spin glass behavior in an interacting -Fe2O3 nanoparticle system D. Parker*1 , V. Dupuis+2 glass behavior of a concentrated assembly of interacting maghemite nanoparticles and compare it to that of canonical atomic spin glass systems. ac versus temperature and frequency measurements show evidence

  18. Phase formation in ZrFe multilayers: Effect of irradiation A. T. Motta

    E-Print Network [OSTI]

    Motta, Arthur T.

    of the wavelength, indicating a process controlled by atomic transport. Amorphization was also achieved by 900 ke disappears first, indicating that amorphization takes place in the Zr layer by atomic transport of Fe from, likely because there was competition with formation of other phases. The reaction kinetics were

  19. Pressure-Induced Magnetization in FeO: Evidence from Elasticity and Mossbauer Spectroscopy

    E-Print Network [OSTI]

    Jacobsen, Steven D.

    Pressure-Induced Magnetization in FeO: Evidence from Elasticity and Mo¨ssbauer Spectroscopy of a magnetic ordering transition is observed by high-pressure Mo¨ssbauer spectroscopy and neutron powder that a unique combination of Mo¨ssbauer spectroscopy (MS), neutron powder diffrac- tion, and GHz

  20. MOSSBAUER SPECTROSCOPY OF57 Fe IMPLANTED TO ALUMINIUM AT LIQUID NITROGEN TEMPERATURE

    E-Print Network [OSTI]

    Boyer, Edmond

    MOSSBAUER SPECTROSCOPY OF57 Fe IMPLANTED TO ALUMINIUM AT LIQUID NITROGEN TEMPERATURE K. Sassa, Y. The ageing behavior of the specimen was examined by conversion electron Mossbauer spec- troscopy at 77 K at room temperature. Internal conversion electron Mossbauer spec- troscopy is most suitable