Sample records for absorption fine structure

  1. absorption fine structures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption fine structures First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Photon interference x-ray...

  2. absorption fine structure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption fine structure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Photon interference x-ray...

  3. Radial distribution function in x-ray-absorption fine structure

    SciTech Connect (OSTI)

    Stern, E.A.; Ma, Y.; Hanske-Petitpierre, O. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)); Bouldin, C.E. (National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States))

    1992-07-01T23:59:59.000Z

    It has been argued that, in systems that have disorder too large to be described by a Gaussian, x-ray-absorption fine-structure (XAFS) spectroscopy alone cannot define the radial distribution function (RDF) because of the lack of low-{ital k} data. We show that the low-{ital k} data can, under certain conditions, be reconstructed using cumulant expansions, which give the correct functional form. This allows XAFS to determine unbiased single-shell RDF's in cases of moderate disorder, without assuming a particular model for the RDF. Some examples are given to illustrate the technique and its limitations.

  4. Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications

    E-Print Network [OSTI]

    Sparks, Donald L.

    Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized of quick extended x-ray absorption fine structure QEXAFS and quick x-ray absorption near edge structure- tion spectroscopy XAS was developed in energy dispersive and quick extended x-ray absorption fine

  5. ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING CONFIGURATIONS OF

    E-Print Network [OSTI]

    Sparks, Donald L.

    ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING Rights Reserved #12;ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE

  6. Number of relevant independent points in x-ray-absorption fine-structure spectra

    SciTech Connect (OSTI)

    Stern, E.A. (Physics Department FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-10-01T23:59:59.000Z

    A discussion is given of the amount of information present in x-ray-absorption fine-structure spectra. It is shown that the usual formulations underestimate the degrees of freedom by at least one.

  7. Ultrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations

    E-Print Network [OSTI]

    Cao, Jianshu

    13­20 to generate ultrafast x-ray pulses, however, the prospect of ultrafast EXAFS seems encouragingUltrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations Frank L by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework

  8. absorption fine-structure spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption fine-structure spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

  9. High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials

    E-Print Network [OSTI]

    Duffy, Thomas S.

    nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

  10. Speciation of Lead in a Mixed Soil Component System Using X-ray Absorption Fine Structure Spectroscopy

    E-Print Network [OSTI]

    Sparks, Donald L.

    Speciation of Lead in a Mixed Soil Component System Using X-ray Absorption Fine Structure (XAFS). Lead concentrations of 6000, 18000, and 29000 µg Pb/g solid were reacted with soil components

  11. Solution spectroelectrochemical cell for in situ X-ray absorption fine structure

    SciTech Connect (OSTI)

    Antonio, M.R.; Soderholm, L. [Argonne National Lab., IL (United States). Chemistry Div.; Song, I. [Case Western Reserve Univ., Cleveland, OH (United States)

    1995-06-12T23:59:59.000Z

    A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L{sub 3}-edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl{sub 3}{center_dot}6H{sub 2}O in 1 M H{sub 2}SO{sub 4}. The europium L{sub 3}-edge resonances reported here for the Eu{sup III} and Eu{sup II} ions demonstrate that their 2p{sub 3/2} {yields} 5d electronic transition probabilities are not the same.

  12. Vibronic fine structure in high-resolution x-ray absorption spectra from ion-bombarded boron nitride nanotubes

    SciTech Connect (OSTI)

    Petravic, Mladen; Peter, Robert; Varasanec, Marijana [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Li Luhua; Chen Ying [Institute for Technology Research and Innovation, Deakin University, Geelong Waurn Ponds Campus, 3217 (Australia); Cowie, Bruce C. C. [Australian Synchrotron, Clayton VIC 3168 (Australia)

    2013-05-15T23:59:59.000Z

    The authors have applied high-resolution near-edge x-ray absorption fine structure measurements around the nitrogen K-edge to study the effects of ion-bombardment on near-surface properties of boron nitride nanotubes. A notable difference has been observed between surface sensitive partial electron yield (PEY) and bulk sensitive total electron yield (TEY) fine-structure measurements. The authors assign the PEY fine structure to the coupling of excited molecular vibrational modes to electronic transitions in NO molecules trapped just below the surface. Oxidation resistance of the boron nitride nanotubes is significantly reduced by low energy ion bombardment, as broken B-N bonds are replaced by N-O bonds involving oxygen present in the surface region. In contrast to the PEY spectra, the bulk sensitive TEY measurements on as-grown samples do not exhibit any fine structure while the ion-bombarded samples show a clear vibronic signature of molecular nitrogen.

  13. X-ray absorption fine structure spectroscopic study of uranium nitrides

    SciTech Connect (OSTI)

    Poineau, Frederic [University of Nevada, Las Vegas; Yeamans, Charles B. [University of California, Berkeley; Cerefice, Gary S. [University of Nevada, Las Vegas; Sattelberger, Alfred P [Argonne National Laboratory (ANL); Czerwinski, Ken R. [University of Nevada, Las Vegas

    2012-01-01T23:59:59.000Z

    Uranium mononitride (UN), sesquinitride (U2N3) and dinitride (UN2) were characterized by extended X-Ray absorption fine structure spectroscopy. Analysis on UN indicate the presence of three uranium shells at distances of 3.46(3), 4.89(5) and 6.01(6) A and a nitrogen shell at a distance of 2.46(2) A . For U2N3, two absorbing uranium atoms at different crystallographic positions are present in the structure. One of the uranium atoms is surrounded by nitrogen atoms at 2.28(2) A and by uranium atoms at 3.66(4) and 3.95(4) A . The second type of uranium atom is surrounded by nitrogen atoms at 2.33(2) and 2.64(3) A and by uranium atoms at 3.66(4), 3.95(4) and 5.31(5) A . Results on UN2 indicate two uranium shells at 3.71(4) and 5.32(5) A and two nitrogen shells at 2.28(2).

  14. Optically Detected Extended X-Ray Absorption Fine Structure Study of InGaN/GaN Single Quantum Wells

    SciTech Connect (OSTI)

    Rigopoulos, N.; Hamilton, B.; Davies, G. J.; Towlson, B. M. [School of Electrical and Electronic Engineering, University of Manchester, Manchester M60 1QD (United Kingdom); Poolton, N. R. J. [Synchrotron Radiation Department, Daresbury Laboratory, Daresbury, Warrington WA4 4AD (United Kingdom); Dawson, P.; Graham, D. M. [School of Physics and Astronomy, University of Manchester, Manchester M60 1QD (United Kingdom); Kappers, M. J.; Humphreys, C. J. [Dept. of Materials Science and Metallurgy, University of Cambridge, Pembroke Street, Cambridge CB2 3QZ (United Kingdom); Carlson, S. [MAX-lab, Lund University, P.O. Box 118, SE- 221 00 Lund (Sweden)

    2007-04-10T23:59:59.000Z

    We have investigated the local atomic environment of the Ga atoms in an InxGa1-xN single quantum well structure using Optically Detected Extended X-ray Absorption Fine Structure (OD-EXAFS). A comparison of the OD-EXAFS data with a theoretical model shows the technique to be site selective for this particular structure and reveals that the quantum well emission originates from regions with x=0.15.

  15. Ab initio curved-wave x-ray-absorption fine structure

    SciTech Connect (OSTI)

    Mustre de Leon, J.; Rehr, J.J.; Zabinsky, S.I. (Department of Physics, FM-15, University of Washington, Seattle, Washington (USA)); Albers, R.C. (Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico (USA))

    1991-09-01T23:59:59.000Z

    The most important elements of {ital ab} {ital initio} calculations of x-ray-absorption fine structure (XAFS) are studied. To obtain accurate results without {ital ad} {ital hoc} adjustable parameters, we find it essential to include (i) curved-wave effects, (ii) a complex, energy-dependent self-energy, (iii) an approximate molecular potential, and (iv) a fixed energy reference for the photoelectron wave number. Based on these findings, an automated code has been developed for {ital ab} {ital initio} calculations of single-scattering XAFS, in which curved-wave effects are treated exactly in terms of effective backscattering amplitudes, inelastic losses and self-energy shifts are incorporated with use of a Hedin-Lundqvist self-energy, an automated relativistic overlapping-atom muffin-tin potential is used, and the energy threshold is estimated from electron-gas theory. The efficiency of the code is made possible by analytic expressions for the Hedin-Lundqvist self-energy. This code replaces existing tables of XAFS phases and scattering amplitudes and yields reliable theoretical XAFS standards for arbitrary pairs of atoms throughout the Periodic Table ({ital Z}{le}94). These results are comparable to those from self-consistent calculations and are valid to within about 20 eV of the absorption edge. Comparisons with experiment are presented for Cu, Ge, Pt, Br{sub 2}, and GeCl{sub 4}. The calculated XAFS amplitudes are found to be accurate to within 15%; XAFS phases are accurate to within 0.2 rad; and nearest-neighbor distances are typically accurate to within 0.02 A.

  16. X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats environmental technology

    SciTech Connect (OSTI)

    Lezama-pacheco, Juan S [Los Alamos National Laboratory; Conradson, Steven D [Los Alamos National Laboratory; Clark, David L [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO{sub 2+x}-type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO{sub 2+x}, and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO{sub 2+x} would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

  17. Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications

    SciTech Connect (OSTI)

    Khalid, S.; Caliebe, W.; Siddons, P.; So, I.; Clay, b.; Hanson, J.; Wang, Q.; Frenkel, A.; Marinkovicl, N.; Hould, N.; ginder-Vogel, M.; Landrot, G.L.; Sparks, D.L.; Ganjoo, A.

    2010-01-19T23:59:59.000Z

    In order to learn about in situ structural changes in materials at subseconds time scale, we have further refined the techniques of quick extended x-ray absorption fine structure (QEXAFS) and quick x-ray absorption near edge structure (XANES) spectroscopies at beamline X18B at the National Synchrotron Light Source. The channel cut Si (111) monochromator oscillation is driven through a tangential arm at 5 Hz, using a cam, dc motor, pulley, and belt system. The rubber belt between the motor and the cam damps the mechanical noise. EXAFS scan taken in 100 ms is comparable to standard data. The angle and the angular range of the monochromator can be changed to collect a full EXAFS or XANES spectrum in the energy range 4.7-40.0 KeV. The data are recorded in ascending and descending order of energy, on the fly, without any loss of beam time. The QEXAFS mechanical system is outside the vacuum system, and therefore changing the mode of operation from conventional to QEXAFS takes only a few minutes. This instrument allows the acquisition of time resolved data in a variety of systems relevant to electrochemical, photochemical, catalytic, materials, and environmental sciences.

  18. Near-edge x-ray-absorption fine structure of Pb: A comparison of theory and experiment

    SciTech Connect (OSTI)

    Newville, M.; Livins, P. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States)); Yacoby, Y. (Racah Institute of Physics, Hebrew University, Jerusalem (Israel)); Rehr, J.J.; Stern, E.A. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-06-01T23:59:59.000Z

    Two independent techniques are used to obtain the background function for the x-ray-absorption fine structure (XAFS) of pure Pb at energies that are normally inaccessible because they are in the edge. The results of the two techniques are shown to give the same [chi]([ital k]) above a threshold energy in the absorption edge, where the background is 70% of the edge step. The reliability of the XAFS starting at unprecedentedly low [ital k] values (1.5 A[sup [minus]1] above the Fermi energy) allows sensitive tests of several details of theoretical XAFS calculations. Electron-hole-excitation losses in addition to the plasmon-pole loss term are shown to be important, and the Hedin-Lundqvist many-body self-energy is found to be superior to that of Dirac-Hara for pure Pb. One of the presented methods of background removal can be employed for general XAFS analysis, and is easily automated.

  19. Near-edge X-ray absorption fine-structure spectroscopy of naphthalene diimide-thiophene co-polymers

    SciTech Connect (OSTI)

    Gann, Eliot; McNeill, Christopher R., E-mail: christopher.mcneill@monash.edu [Department of Materials Engineering, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Szumilo, Monika; Sirringhaus, Henning [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom)] [Cavendish Laboratory, University of Cambridge, JJ Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Sommer, Michael [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany)] [Institute of Macromolecular Chemistry, University of Freiburg, Stefan-Meier-Str. 31, 79104 Freiburg (Germany); Maniam, Subashani; Langford, Steven J. [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia)] [School of Chemistry, Monash University, Wellington Road, Clayton, Victoria 3800 (Australia); Thomsen, Lars [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)] [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2014-04-28T23:59:59.000Z

    Near-edge X-ray absorption fine-structure (NEXAFS) spectroscopy is an important tool for probing the structure of conjugated polymer films used in organic electronic devices. High-performance conjugated polymers are often donor-acceptor co-polymers which feature a repeat unit with multiple functional groups. To facilitate better application of NEXAFS spectroscopy to the study of such materials, improved understanding of the observed NEXAFS spectral features is required. In order to examine how the NEXAFS spectrum of a donor-acceptor co-polymer relates to the properties of the sub-units, a series of naphthalene diimide-thiophene-based co-polymers have been studied where the nature and length of the donor co-monomer has been systematically varied. The spectra of these materials are compared with that of a thiophene homopolymer and naphthalene diimide monomer enabling peak assignment and the influence of inter-unit electronic coupling to be assessed. We find that while it is possible to attribute peaks within the ?* manifold as arising primarily due to the naphthalene diimide or thiophene sub-units, very similar dichroism of these peaks is observed indicating that it may not be possible to separately probe the molecular orientation of the separate sub-units with carbon K-edge NEXAFS spectroscopy.

  20. The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure

    SciTech Connect (OSTI)

    Barrera, E.V. (Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science); Heald, S.M. (Brookhaven National Lab., Upton, NY (United States))

    1991-01-01T23:59:59.000Z

    Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

  1. The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure

    SciTech Connect (OSTI)

    Barrera, E.V. [Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science; Heald, S.M. [Brookhaven National Lab., Upton, NY (United States)

    1991-12-31T23:59:59.000Z

    Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

  2. In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes

    SciTech Connect (OSTI)

    Kim, Sunghyun; Tryk, D.A.; Scherson, D. (Case Western Reserve Univ., Cleveland, OH (United States)); Antonio, M.R. (Argonne National Lab., IL (United States)); Carr, R. (Stanford Synchrotron Radiation Lab., CA (United States))

    1994-10-06T23:59:59.000Z

    Aspects of the structural and electronic properties of hydrous oxide films of composite (9:1) Ni/Co and (9:1) Ni/Fe, prepared by electrodeposition, have been examined in alkaline electrolytes using in situ X-ray absorption fine structure (XAFS). An analysis of the X-ray absorption near the edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) for the Co and Fe K-edges of these composite hydrous oxides revealed that, regardless of the oxidation state of nickel sites in the films, the guest metal ions are present as Co[sup 3+] and Fe[sup 3+] and that the cobalt-oxygen distance d(Co-O) = 1.9 [+-] 0.02 [angstrom] and d(Fe-O) = 1.92 [+-] 0.02 [angstrom]. The latter values are in excellent agreement with d(Me-O) (Me = Co or Fe) in CoOOH and [beta]- and [gamma]-FeOOH, respectively, determined by conventional X-ray diffraction. Two clearly defined Me-Ni first coordination shells could be observed in the Fourier transforms (FT) of the K-edge EXAFS of the guest metal recorded at a potential at which both Ni[sup 2+] and Ni[sup 3+] sites are expected to be present. 28 refs., 10 figs., 3 tabs.

  3. Separable-spherical-wave approximation: Application to x-ray-absorption fine-structure multiple scattering in ReO sub 3

    SciTech Connect (OSTI)

    Houser, B. (Department of Physics, MS 68, Eastern Washington University, Cheney, Washington 99004 (United States)); Ingalls, R.; Rehr, J.J. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1992-04-01T23:59:59.000Z

    Rehr and Albers have shown that the exact x-ray-absorption fine-structure (XAFS) propagator may be expanded in a separable matrix form, and that the lowest-order term in the expansion yields XAFS formulas that contain spherical-wave corrections, yet retain the simplicity of the plane-wave approximation. This separable-spherical-wave approximation was used to model the multiple-scattering contributions to the XAFS spectrum of rhenium trioxide. We report a modest improvement over the plane-wave approximation.

  4. In situ x-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes.

    SciTech Connect (OSTI)

    Hu, Y.; Bae, I. T.; Mo, Y.; Antonio, M. R.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

    1997-01-01T23:59:59.000Z

    X-ray absorption fine structure (XAFS) and optical reflectance spectroscopy (RS) have been used to examine in situ electronic and structural aspects of nickel hydrous oxide, a-Ni(OH)2(hyd), electrodes supported on gold in alkaline electrolytes as a function of their state of charge. The extended X-ray absorption fine structure (EXAFS) of a-Ni(OH)2(hyd) electrodes in the uncharged (UC, or discharged) and overcharged (OC, or fully charged) states yielded, in each case, a single set of two distinct nearest-neighbor shells, with distances, d(Ni-O)1 = 2.05 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 3.11 {+-} 0.02 {angstrom} for UC, and d(Ni-O)1 = 1.87 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 2.83 {+-} 0.02 {angstrom} for OC. The in situ EXAFS of films allowed to self-discharge following overcharge could be fit with contributions from both sets of shells, suggesting that only two types of nickel sites are sufficient to account for the redox chemistry of this material. These data, in addition to information derived both from quantitative X-ray absorption near-edge structure (XANES) and optical RS in the visible range, indicate that the excess anodic charge, i.e., beyond the one-electron oxidation of Ni2+ sites, observed during the first oxidation of freshly prepared a-Ni(OH)2(hyd) electrodes may not be related to oxidation state changes involving nickel sites in the lattice, and, therefore, do not support the existence of nickel sites with a formal oxidation state higher than three for charged or overcharged electrodes in this media.

  5. In situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated ruthenium dioxide films with relevance to supercapacitor applications.

    SciTech Connect (OSTI)

    Mo, Y.; Antonio, M. R.; Stefan, I. C.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

    2000-10-26T23:59:59.000Z

    Modifications in electronic and structural aspects of RuO{sub 2} films electroprecipitated onto Au electrodes induced by changes in the applied potential have been examined in situ in aqueous 0.50 M H{sub 2}SO{sub 4} by Ru K-edge X-ray absorption spectroscopy (XAS). The Fourier transform of the k{sup 3}-weighted extended X-ray absorption fine structure (EXAFS), k{sup 3}x(k), for the film polarized at +1.20V vs RHE is characterized by two shells attributed to Ru-O and Ru-Ru interactions with average distances of 1.94(1) and 3.12(2) {angstrom}, respectively, in agreement with results obtained ex situ for Ru{sup 4+} in hydrous RuO{sub 2} by other groups. In contrast, films in the reduced state, i.e., +0.40 V vs RHE, yielded only a single shell ascribed to a Ru-O interaction at 2.02(1) {angstrom} with no evidence for a distant Ru-Ru shell. The long Ru-O distance is in agreement with that reported earlier for the hydrous Ru{sup 3+} ion [Ru-(OH{sub 2}){sub 6}]{sup 3+} in the solid state. Moreover, the difference between the average Ru-O bond lengths for the reduced and oxidized films is consistent with the difference in the ionic radii of Ru{sup 3+} and Ru{sup 4+}. On this basis it has been suggested that films in the reduced state contain Ru{sup 3+} sites, consistent with the electrochemical results, in a phase with apparently less order beyond the Ru-O coordination sphere than for hydrous RuO{sub 2}.

  6. Versatile plug flow catalytic cell for in situ transmission/fluorescence x-ray absorption fine structure measurements

    SciTech Connect (OSTI)

    Centomo, P.; Zecca, M. [Dipartimento di Scienze Chimiche, via Marzolo 1, Universita degli Studi di Padova, 35131 Padova (Italy); Meneghini, C. [Dipartimento di Scienze, via della Vasca Navale 84, Universita di Roma TRE, 00146 Roma (Italy)

    2013-05-15T23:59:59.000Z

    A novel flow-through catalytic cell has been developed for in situ x-ray absorption spectroscopy (XAS) experiments on heterogeneous catalysts under working conditions and in the presence of a liquid and a gas phase. The apparatus allows to carry out XAS measurements in both the transmission and fluorescence modes, at moderate temperature (from RT to 50-80 Degree-Sign C) and low-medium gas pressure (up to 7-8 bars). The materials employed are compatible with several chemicals such as those involved in the direct synthesis of hydrogen peroxide (O{sub 2}, H{sub 2}, H{sub 2}O{sub 2}, methanol). The versatile design of the cell allows to fit it to different experimental setups in synchrotron radiation beamlines. It was used successfully for the first time to test nanostructured Pd catalysts during the direct synthesis of hydrogen peroxide (H{sub 2}O{sub 2}) in methanol solution from dihydrogen and dioxygen.

  7. PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL

    SciTech Connect (OSTI)

    Phelan, B.T.; Myers, D.J.; Smith, M.C.

    2009-01-01T23:59:59.000Z

    State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratory’s Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

  8. Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption Fine Structure (XAFS) Study

    E-Print Network [OSTI]

    Sparks, Donald L.

    Effect of Residence Time on Ni-Sorption Mechanisms on Clay and Oxide Minerals: An X-ray Absorption minerals is typically fast initially, then the rates gradually diminish. In the literature the decline

  9. X-ray diffraction and extended X-ray absorption fine structure study of epitaxial mixed ternary bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} (x = 0-2) films on Si (111)

    SciTech Connect (OSTI)

    Niu, G.; Zoellner, M. H.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Pouliopoulos, A. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); D'Acapito, F. [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, F. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France)

    2013-01-28T23:59:59.000Z

    Ternary single crystalline bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} films over the full stoichiometry range (x = 0-2) have been epitaxially grown on Si (111) with tailored electronic and crystallographic structure. In this work, we present a detailed study of their local atomic environment by extended X-ray absorption fine structure at both Y K and Pr L{sub III} edges, in combination with complementary high resolution x-ray diffraction measurements. The local structure exhibits systematic variations as a function of the film composition. The cation coordination in the second and third coordination shells changes with composition and is equal to the average concentration, implying that the Pr{sub x}Y{sub 2-x}O{sub 3} films are indeed fully mixed and have a local bixbyite structure with random atomic-scale ordering. A clear deviation from the virtual crystal approximation for the cation-oxygen bond lengths is detected. This demonstrates that the observed Vegard's law for the lattice variation as a function of composition is based microscopically on a more complex scheme related to local structural distortions which accommodate the different cation-oxygen bond lengths.

  10. An application of Ti-K X-ray absorption edges and fine structures to the study of substoichiometric titanium carbide TiC1-x

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of substoichiometric titanium carbide TiC1-x V. Moisy-Maurice and C. H. de Novion C.E.A./IRDI/DMECN/DTech, Laboratoire-ray absorption coefficient were made around and up to 1000 eV above the titanium K-edge of TiC1-x samples (0 of titanium deduced from the edge-shift decreases, (ii) the bottom of the titanium 4p bands (situated at 10

  11. The helium fine-structure controversy

    E-Print Network [OSTI]

    Ingvar Lindgren

    2008-10-05T23:59:59.000Z

    There is presently disagreement between theory and experiment as well as between different theoretical calculations concerning the fine-structure splitting of the lowest P state of the neutral helium atom. We believe that we have found a minor error in the formulas used by Drake et al. (Can. J. Phys. 80, 1195 (2002)) in their calculations, and we may have an explanation how the error has occurred. To what extent this might resolve (part of) the discrepancy is not known at present.

  12. Helium fine structure theory for determination of Krzysztof Pachucki

    E-Print Network [OSTI]

    Pachucki, Krzysztof

    Helium fine structure theory for determination of Krzysztof Pachucki Institute of Theoretical in the calculation of helium fine-structure splitting of the 23 PJ states, based on the quantum electrodynamic theory by comparison with all experimental results for light helium-like ions and with the known large nuclear charge

  13. Substitution behavior of x(Na{sub 0.5}K{sub 0.5})NbO{sub 3}-(1???x)BaTiO{sub 3} ceramics for multilayer ceramic capacitors by a near edge x-ray absorption fine structure analysis

    SciTech Connect (OSTI)

    Ha, Jooyeon; Ryu, Jiseung; Lee, Heesoo, E-mail: heesoo@pusan.ac.kr [School of Materials Science and Engineering, Pusan National University, Busan 609-735 (Korea, Republic of)

    2014-06-30T23:59:59.000Z

    The doping effect of (Na{sub 0.5}K{sub 0.5})NbO{sub 3} (NKN) as alternatives for rare-earth elements on the electrical properties of BaTiO{sub 3} has been investigated, in terms of their substitution behavior. The dielectric constant of a specimen with x?=?0.05 was about 79% higher than that of pure BaTiO{sub 3}, and the temperature coefficient of capacitance was satisfied by the X7R specification. The specimen with x?=?0.05 showed the lowest tetragonality among the four compositions and had a fine grain size of <2 ?m. Although the addition of NKN decreased the specimen's tetragonality, the electrical properties were enhanced by the formation of defect dipoles and conduction electrons, which resulted from an acceptor and donor substitution behavior. Through O K-edge near edge x-ray absorption fine structure spectroscopy, the practical substitution behavior was defined by the change in Ti 3d orbital states. The energy separation of the Ti 3d orbitals was more apparent with the specimen of x?=?0.05, which is related to the donor level from the donor substitution of Nb{sup 5+} ion for Ti-sites. Therefore, the simultaneous substitution of Na{sup +}/K{sup +} and Nb{sup 5+} ions into BaTiO{sub 3} can improve dielectric properties, based on the charge-transfer process.

  14. Influence of 8-Oxoguanosine on the Fine Structure of DNA Studied...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8-Oxoguanosine on the Fine Structure of DNA Studied with Biasing-Potential Replica Exchange Simulations. Influence of 8-Oxoguanosine on the Fine Structure of DNA Studied with...

  15. Effects of {pi}-stacking interactions on the near carbon K-edge x-ray absorption fine structure: A theoretical study of the ethylene pentamer and the phthalocyanine dimer

    SciTech Connect (OSTI)

    Linares, Mathieu; Stafstroem, Sven; Norman, Patrick [Department of Physics, Chemistry and Biology, Linkoeping University, SE-581 83 Linkoeping (Sweden)

    2009-03-14T23:59:59.000Z

    X-ray absorption spectra have been determined for ethylene and free base phthalocyanine at the carbon K-edge with use of the complex polarization propagator method combined with Kohn-Sham density functional theory and the Coulomb attenuated method B3LYP exchange-correlation functional. Apart from isolated molecules, the study includes {pi}-stacked systems of the phthalocyanine dimer and the ethylene dimer, trimer, tetramer, and pentamer. For ethylene, {pi}-stacking involves a reduction in transition energy of the valence {pi}*-band by some 70 meV and large spectral changes (regarding also shape and intensity) of the Rydberg bands. For phthalocyanine, there are large spectral changes in the entire valence {pi}*-part of the spectrum.

  16. Fine structure transitions of C+ in collisions with H2

    E-Print Network [OSTI]

    Chu, Shih-I; Dalgarno, A.

    1975-01-01T23:59:59.000Z

    ://scitation.aip.org/content/aip/journal/jcp/62/10?ver=pdfcov Published by the AIP Publishing Articles you may be interested in ?doublet substate specific investigation of rotational and fine structure transitions in collisions of OH with H2 and D2 J. Chem. Phys. 95, 5763 (1991); 10... for Astrophysics, Harvard College Observatory and Smithsonian Astrophysical Observatory, Cambridge, Massachusetts 02138 (Received 7 November 1974) Close-coupling calculations are described of the cross sections for the fine-structure excitation of C...

  17. Time-Varying Fine-Structure Constant Requires Cosmological Constant

    E-Print Network [OSTI]

    R. W. Kuhne

    1999-08-31T23:59:59.000Z

    Webb et al. presented preliminary evidence for a time-varying fine-structure constant. We show Teller's formula for this variation to be ruled out within the Einstein-de Sitter universe, however, it is compatible with cosmologies which require a large cosmological constant.

  18. Fine Structure Studies in Proton Emission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.New MexicoFinancing Opportunities for RenewableSeriesStructure

  19. C-C bond unsaturation degree in monosubstituted ferrocenes for molecular electronics investigated by a combined near-edge x-ray absorption fine structure, x-ray photoemission spectroscopy, and density functional theory approach

    SciTech Connect (OSTI)

    Boccia, A.; Lanzilotto, V.; Marrani, A. G.; Zanoni, R. [Dipartimento di Chimica, Universita degli Studi di Roma ''La Sapienza'', piazzale Aldo Moro 5, I-00185 Rome (Italy); Stranges, S. [Dipartimento di Chimica, Universita degli Studi di Roma ''La Sapienza'', piazzale Aldo Moro 5, I-00185 Rome (Italy); IOM-CNR, Laboratorio TASC, I-34149 Basovizza, Trieste (Italy); Alagia, M. [IOM-CNR, Laboratorio TASC, I-34149 Basovizza, Trieste (Italy); Fronzoni, G.; Decleva, P. [Dipartimento di Scienze Chimiche, Universita di Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy and IOM-CNR Democritos, Trieste (Italy)

    2012-04-07T23:59:59.000Z

    We present the results of an experimental and theoretical investigation of monosubstituted ethyl-, vinyl-, and ethynyl-ferrocene (EtFC, VFC, and EFC) free molecules, obtained by means of synchrotron-radiation based C 1s photoabsorption (NEXAFS) and photoemission (C 1s XPS) spectroscopies, and density functional theory (DFT) calculations. Such a combined study is aimed at elucidating the role played by the C-C bond unsaturation degree of the substituent on the electronic structure of the ferrocene derivatives. Such substituents are required for molecular chemical anchoring onto relevant surfaces when ferrocenes are used for molecular electronics hybrid devices. The high resolution C 1s NEXAFS spectra exhibit distinctive features that depend on the degree of unsaturation of the hydrocarbon substituent. The theoretical approach to consider the NEXAFS spectrum made of three parts allowed to disentangle the specific contribution of the substituent group to the experimental spectrum as a function of its unsaturation degree. C 1s IEs were derived from the experimental data analysis based on the DFT calculated IE values for the different carbon atoms of the substituent and cyclopentadienyl (Cp) rings. Distinctive trends of chemical shifts were observed for the substituent carbon atoms and the substituted atom of the Cp ring along the series of ferrocenes. The calculated IE pattern was rationalized in terms of initial and final state effects influencing the IE value, with special regard to the different mechanism of electron conjugation between the Cp ring and the substituent, namely the {sigma}/{pi} hyperconjugation in EtFC and the {pi}-conjugation in VFC and EFC.

  20. X-ray absorption fine structure and magnetization characterization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a measurement of the fraction of metallic Co. Any quantitative understanding of magnetism in this system needs to take account of both types of Co. Results are reported for...

  1. Global Representation of the Fine Structure Constant and its Variation

    E-Print Network [OSTI]

    Michael Edmund Tobar

    2005-02-06T23:59:59.000Z

    The fine structure constant, alpha, is shown to be proportional to the ratio of the quanta of electric and magnetic flux of force of the electron, and provides a new representation, which is global across all unit systems. Consequently, a variation in alpha was shown to manifest due to a differential change in the fraction of the quanta of electric and magnetic flux of force, while a variation in hcross.c was shown to manifest due to the common mode change. The representation is discussed with respect to the running of the fine structure constant at high energies (small distances), and a putative temporal drift. It is shown that the running of the fine structure constant is due to equal components of electric screening (polarization of vacuum) and magnetic anti-screening (magnetization of vacuum), which cause the perceived quanta of electric charge to increase at small distances, while the magnetic flux quanta decreases. This introduces the concept of the bare magnetic flux quanta as well as the bare electric charge. With regards to temporal drift, it is confirmed that it is impossible to determine which fundamental constant is varying if alpha varies.

  2. Fine structure of coupled optical modes in photonic molecules

    SciTech Connect (OSTI)

    Rakovich, Y.P.; Donegan, J.F.; Gerlach, M.; Bradley, A.L. [Semiconductor Photonics Group, Department of Physics, Trinity College, Dublin 2 (Ireland); Connolly, T.M.; Boland, J.J. [Department of Chemistry, Trinity College, Dublin 2 (Ireland); Gaponik, N. [Institute of Physical Chemistry, University of Hamburg, 20146 Hamburg (Germany); Rogach, A. [Photonics and Optoelectronics Group, Physics Department and CeNS, Ludwig-Maximilians Universitaet Muenchen, 80799 Munich (Germany)

    2004-11-01T23:59:59.000Z

    We report on the coherent coupling of whispering gallery modes (WGM) in a photonic molecule formed from two melamine-formaldehyde spherical microcavities with a thin shell of CdTe nanocrystals. Utilizing a microporous polymer structure to orient the photonic molecule, we have excited the photonic molecule both on and off axis. This controllable geometry has allowed the observation of an off-axis fine structure that consists of very sharp peaks resulting from the removal of the WGM degeneracy with respect to the azimuthal quantum number m. The mode splittings are in very good agreement with theory.

  3. Topological Quantization in Units of the Fine Structure Constant

    SciTech Connect (OSTI)

    Maciejko, Joseph; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Qi, Xiao-Liang; /Station Q, UCSB /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Drew, H.Dennis; /Maryland U.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC

    2011-11-11T23:59:59.000Z

    Fundamental topological phenomena in condensed matter physics are associated with a quantized electromagnetic response in units of fundamental constants. Recently, it has been predicted theoretically that the time-reversal invariant topological insulator in three dimensions exhibits a topological magnetoelectric effect quantized in units of the fine structure constant {alpha} = e{sup 2}/{h_bar}c. In this Letter, we propose an optical experiment to directly measure this topological quantization phenomenon, independent of material details. Our proposal also provides a way to measure the half-quantized Hall conductances on the two surfaces of the topological insulator independently of each other.

  4. Fine-structure constant constraints on Bekenstein-type models

    E-Print Network [OSTI]

    P. M. M. Leal; C. J. A. P. Martins; L. B. Ventura

    2014-07-15T23:59:59.000Z

    Astrophysical tests of the stability of dimensionless fundamental couplings, such as the fine-structure constant $\\alpha$, are an area of much increased recent activity, following some indications of possible spacetime variations at the few parts per million level. Here we obtain updated constraints on the Bekenstein-Sandvik-Barrow-Magueijo model, which is arguably the simplest model allowing for $\\alpha$ variations. Recent accurate spectroscopic measurements allow us to improve previous constraints by about an order of magnitude. We briefly comment on the dependence of the results on the data sample, as well as on the improvements expected from future facilities.

  5. Hydrogen Atom and Time Variation of Fine-Structure Constant

    E-Print Network [OSTI]

    Mu-Lin Yan

    2009-11-21T23:59:59.000Z

    In this paper, we have solved the de Sitter special relativistic ($\\mathcal{SR}_{cR}$-) Dirac equation of hydrogen in the earth-QSO(quasar) framework reference by means of the adiabatic approach. The aspects of geometry effects of de Sitter space-time described by Beltrami metric are explored and taken into account. It is found that the $\\mathcal{SR}_{cR}$-Dirac equation of hydrogen is a time dependent quantum Hamiltonian system. We provide an explicit calculation to justify the adiabatic approach in dealing with this time-dependent system. Since the radius of de Sitter sphere $R$ is cosmologically large, the evolution of the system is very slow so that the adiabatic approximation legitimately works with high accuracy. We conclude that the electromagnetic fine-structure constant, the electron mass and the Planck constant are time variations. This prediction of fine-structure constant is consistent with the presently available observation data. For confirming it further, experiments/observations are required.

  6. Solar Radio Bursts with Spectral Fine Structures in Preflares

    E-Print Network [OSTI]

    Zhang, Yin; Karlický, Marian; Mészárosová, Hana; Huang, Jing; Tan, Chengming; Simões, Paulo

    2014-01-01T23:59:59.000Z

    A good observation of preflare activities is important for us to understand the origin and triggering mechanism of solar flares, and to predict the occurrence of solar flares. This work presents the characteristics of microwave spectral fine structures as preflare activities of four solar flares observed by Ond\\v{r}ejov radio spectrograph in the frequency range of 0.8--2.0 GHz. We found that these microwave bursts which occurred 1--4 minutes before the onset of flares have spectral fine structures with relatively weak intensities and very short timescales. They include microwave quasi-periodic pulsations (QPP) with very short period of 0.1-0.3 s and dot bursts with millisecond timescales and narrow frequency bandwidths. Accompanying these microwave bursts, there are filament motions, plasma ejection or loop brightening on the EUV imaging observations and non-thermal hard X-ray emission enhancements observed by RHESSI. These facts may reveal certain independent non-thermal energy releasing processes and partic...

  7. Fine-structure constant constraints on dark energy

    E-Print Network [OSTI]

    Martins, C J A P

    2015-01-01T23:59:59.000Z

    We use astrophysical and atomic clock tests of the stability of the fine-structure constant $\\alpha$, together with Type Ia supernova and Hubble parameter data, to constrain the simplest class of dynamical dark energy models where the same degree of freedom is assumed to provide both the dark energy and (through a dimensionless coupling, $\\zeta$, to the electromagnetic sector) the $\\alpha$ variation. We show how current data tightly constrains a combination of $\\zeta$ and the dark energy equation of state $w_0$. At the $95\\%$ confidence level and marginalizing over $w_0$ we find $|\\zeta|<5\\times10^{-6}$, with the atomic clock tests dominating the constraints. The forthcoming generation of high-resolution ultra-stable spectrographs will enable significantly tighter constraints.

  8. $f(T)$ Theories and Varying Fine Structure Constant

    E-Print Network [OSTI]

    Wei, Hao; Qi, Hao-Yu

    2011-01-01T23:59:59.000Z

    In analogy to $f(R)$ theory, recently $f(T)$ theory has been proposed to drive the current accelerated expansion without invoking dark energy. In the literature, the observational constraints on $f(T)$ theories were obtained mainly by using the cosmological data, such as type Ia supernovae (SNIa), baryon acoustic oscillation (BAO), and cosmic microwave background radiation (CMB). In this work, we instead try to constrain $f(T)$ theories with the varying fine structure "constant", $\\alpha\\equiv e^2/\\hbar c$. We find that the constraints on $f(T)$ theories from the observational $\\Delta\\alpha/\\alpha$ data are very severe. In fact, they make $f(T)$ theories almost indistinguishable from $\\Lambda$CDM model.

  9. Real-time, Photo-realistic, Physically Based Rendering of Fine Scale Human Skin Structure

    E-Print Network [OSTI]

    Haro, Antonio

    structure samples, build models of fine scale structure production, and then render this detail usingReal-time, Photo-realistic, Physically Based Rendering of Fine Scale Human Skin Structure Antonio, which is clearly visible in close-up shots in a film or game. Methods that rely on simple texture

  10. Fine structure of helium and light helium-like ions Krzysztof Pachucki and Vladimir A. Yerokhin

    E-Print Network [OSTI]

    Pachucki, Krzysztof

    1 Fine structure of helium and light helium-like ions Krzysztof Pachucki and Vladimir A. Yerokhin Abstract: Calculational results are presented for the fine-structure splitting of the 23 P state of helium and helium-like ions with the nuclear charge Z up to 10. Theoretical predictions are in agreement

  11. HEP/123-qed Fine structure of alpha decay in odd nuclei

    E-Print Network [OSTI]

    M. Mirea

    2000-01-01T23:59:59.000Z

    Using an ? decay level scheme, the fine structure in odd nuclei is explained by taking into account the radial and rotational couplings between the unpaired valence nucleon and the core of the decaying system. It is shown that the experimental behavior of the ? decay fine structure phenomenon is governed by the dynamical characteristics of the system.

  12. Impact of instrumental systematic errors on fine-structure constant measurements with quasar spectra

    E-Print Network [OSTI]

    J. B. Whitmore; M. T. Murphy

    2014-11-18T23:59:59.000Z

    We present a new `supercalibration' technique for measuring systematic distortions in the wavelength scales of high resolution spectrographs. By comparing spectra of `solar twin' stars or asteroids with a reference laboratory solar spectrum, distortions in the standard thorium--argon calibration can be tracked with $\\sim$10 m s$^{-1}$ precision over the entire optical wavelength range on scales of both echelle orders ($\\sim$50--100 \\AA) and entire spectrographs arms ($\\sim$1000--3000 \\AA). Using archival spectra from the past 20 years we have probed the supercalibration history of the VLT--UVES and Keck--HIRES spectrographs. We find that systematic errors in their wavelength scales are ubiquitous and substantial, with long-range distortions varying between typically $\\pm$200 m s$^{-1}$ per 1000 \\AA. We apply a simple model of these distortions to simulated spectra that characterize the large UVES and HIRES quasar samples which previously indicated possible evidence for cosmological variations in the fine-structure constant, $\\alpha$. The spurious deviations in $\\alpha$ produced by the model closely match important aspects of the VLT--UVES quasar results at all redshifts and partially explain the HIRES results, though not self-consistently at all redshifts. That is, the apparent ubiquity, size and general characteristics of the distortions are capable of significantly weakening the evidence for variations in $\\alpha$ from quasar absorption lines.

  13. X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films

    SciTech Connect (OSTI)

    Siah, Sin Cheng, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu; Lee, Yun Seog; Buonassisi, Tonio, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Lee, Sang Woon; Gordon, Roy G. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138 (United States); Heo, Jaeyeong [Department of Materials Science and Engineering, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Shibata, Tomohiro; Segre, Carlo U. [Physics Department and CSRRI, Illinois Institute of Technology, Chicago, Illinois 606016 (United States)

    2014-06-16T23:59:59.000Z

    We investigate the correlation between the atomic structures of amorphous zinc-tin-oxide (a-ZTO) thin films grown by atomic layer deposition (ALD) and their electronic transport properties. We perform synchrotron-based X-ray absorption spectroscopy at the K-edges of Zn and Sn with varying [Zn]/[Sn] compositions in a-ZTO thin films. In extended X-ray absorption fine structure (EXAFS) measurements, signal attenuation from higher-order shells confirms the amorphous structure of a-ZTO thin films. Both quantitative EXAFS modeling and X-ray absorption near edge spectroscopy (XANES) reveal that structural disorder around Zn atoms increases with increasing [Sn]. Field- and Hall-effect mobilities are observed to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron mobility may be correlated with structural changes.

  14. Fine structures in the atmosphere above a sunspot umbra

    E-Print Network [OSTI]

    Bharti, L; Solanki, S K

    2013-01-01T23:59:59.000Z

    We present simultaneous photospheric and chromospheric observations of the trailing sunspot in NOAA 10904, obtained with the Swedish Solar Telescope (SST) La Palma, Canary Islands. Time series of high resolution \\ion{Ca}{ii}\\,$H$ images show transient jet-like structures in sunspot umbrae are elongated, which we call umbral microjets. These jets are directed roughly parallel to nearby penumbral microjets, suggesting that they are aligned with the background magnetic field. In general, first a bright dot-like structure appears, from which a jet later emerges, although some jets appear without an associated chromospheric dot. Bright photospheric umbral dots are associated with umbral microjets arising in the outer umbra. Nevertheless, a one-to-one correspondence between jet-like events and underlying umbral dots is not seen. They are typically less than 1\\arcsec ~long and less than 0\\farcs3 wide. The typical lifetime of umbral microjets is around one minute. The brightness of these structures increases from the...

  15. Fine structure, hyperfine structure, and Stark effect in the NO A 2~+ state by optical radiofrequency double resonance

    E-Print Network [OSTI]

    Zare, Richard N.

    Fine structure, hyperfine structure, and Stark effect in the NO A 2~+ state by optical radio·frequency double resonance T. Bergeman Columbia Radiation Laboratory, Columbia University, New York, New York 10027 and Department of Physics*, Fordham University, Bronx, New York 10458 R. N. Zare Columbia Radiation Laboratory

  16. Fine Structure of the Solar Wind Turbulence Inferred from Simultaneous Radio Occultation Observations at

    E-Print Network [OSTI]

    Padmanabhan, Janardhan

    Fine Structure of the Solar Wind Turbulence Inferred from Simultaneous Radio Occultation Observations at Widely-Spaced Ground Stations M.K. Bird , P. Janardhan , A.I. Efimov, L.N. Samoznaev, V extended for up to four hours, thereby allowing studies of solar wind turbulence dynamics at spatial scales

  17. Constraints on the value of the fine structure constant from gravitational thermodynamics

    E-Print Network [OSTI]

    P. C. W. Davies

    2007-09-26T23:59:59.000Z

    In this paper I show how the second law of thermodynamics, generalized to include event horizon area, places interesting constraints on the value of the fine structure constant. A simple analysis leads to the conclusion that classical Dirac and point-like magnetic monopoles could be used to violate the second law, and that GUT monopoles are inconsistent with minicharged particles.

  18. MORPHOLOGY, HISTOLOGY, AND FINE STRUCTURE Sensilla on the Antennal Flagellum of Sirex noctilio

    E-Print Network [OSTI]

    MORPHOLOGY, HISTOLOGY, AND FINE STRUCTURE Sensilla on the Antennal Flagellum of Sirex noctilio subterminal pore is seen to be associated with each sensillum. Males had signiÞcantly more uniporous sensory (Pinus taeda L.). S. noctilio has therefore been assessed as being a high risk to native pine forests

  19. THE FINE STRUCTURE OF THE WAX GLAND OF THE HONEY BEE (APIS MELLIFERA L.)

    E-Print Network [OSTI]

    Boyer, Edmond

    THE FINE STRUCTURE OF THE WAX GLAND OF THE HONEY BEE (APIS MELLIFERA L.) Malcolin T. SANFORD Alfred An electron microscopic study was initiated to elucidate the ultrastructure of the wax gland in an actively wax secreting worker honey bee. The investigation showed that the cuticle is penetrated by bundles

  20. New rest wavelength determinations for 7 mid-infrared fine structure lines by ISO-SWS

    E-Print Network [OSTI]

    H. Feuchtgruber; D. Lutz; D. A. Beintema

    2001-05-15T23:59:59.000Z

    Observations of the planetary nebulae NGC6302, NGC6543 and NGC7027 by the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO) have been used to determine rest wavelengths of spectral lines. We report on improved accuracies for wavelengths of 7 mid-infrared ionic fine structure lines.

  1. Distinct local structure of nanoparticles and nanowires of V{sub 2}O{sub 5} probed by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Joseph, B.; Maugeri, L.; Bendele, M.; Saini, N. L., E-mail: Naurang.Saini@roma1.infn.it [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy); Iadecola, A. [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy) [Dipartimento di Fisica, Universitá di Roma “La Sapienza” - P. le Aldo Moro 2, 00185 Roma (Italy); Elettra, Sincrotrone Trieste, Strada Statale 14, Km 163.5, Basovizza, Trieste (Italy); Okubo, M.; Li, H.; Zhou, H. [National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba 305-8568 (Japan)] [National Institute of Advanced Industrial Science and Technology (AIST), Umezono 1-1-1, Tsukuba 305-8568 (Japan); Mizokawa, T. [Department of Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan) [Department of Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan); Department of Complexity Science and Engineering, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan)

    2013-12-16T23:59:59.000Z

    We have used V K-edge x-ray absorption spectroscopy to study local structures of bulk, nanoparticles and nanowires of V{sub 2}O{sub 5}. The extended x-ray absorption fine structure measurements show different local displacements in the three morphologically different V{sub 2}O{sub 5} samples. It is found that the nanowires have a significantly ordered chain structure in comparison to the V{sub 2}O{sub 5} bulk. In contrast, nanoparticles have larger interlayer disorder. The x-ray absorption near-edge structure spectra show different electronic structure that appears to be related with the local atomic disorder in the three V{sub 2}O{sub 5} samples.

  2. Development of Internal Fine Structure in Stretched Rubber Vulcanizates

    SciTech Connect (OSTI)

    M Tosaka; S Toki; J Che; L Rong; B Hsiao

    2011-12-31T23:59:59.000Z

    Small-angle X-ray scattering (SAXS) pattern and tensile stress during relaxation of stretched rubber vulcanizates (synthetic polyisoprene) were measured simultaneously at room temperature and at 0 C. The samples were quickly stretched to the prefixed strain and then allowed to relax for 1 h. In every SAXS pattern, the intensity distribution was elongated along the equator, indicating the formation of structures elongated in the stretching direction. The so-called two-spots pattern corresponding to the long period of stacked lamellar crystals did not appear even when the critical strain to induce crystallization was exceeded. On the other hand, even below the critical strain, additional development of equatorial streaks was detected in the differential SAXS patterns. This result suggests the growth of the density fluctuation elongated in the stretching direction, which is not directly related to strain-induced crystallization.

  3. The Analysis of Penumbral Fine Structure Using an Advanced Inversion Technique

    E-Print Network [OSTI]

    Jan Jur?ák; Luis Bellot Rubio; Kiyoshi Ichimoto; Yukio Katsukawa; Bruce Lites; Shin'ichi Nagata; Toshifumi Shimizu; Yoshinori Suematsu; Theodore Tarbell; Alan Title; Saku Tsuneta

    2007-07-11T23:59:59.000Z

    We present a method to study the penumbral fine structure using data obtained by the spectropolarimeter onboard HINODE. For the first time, the penumbral filaments can be considered as resolved in spectropolarimetric measurements. This enables us to use inversion codes with only one-component model atmospheres, and thus assign the obtained stratifications of plasma parameters directly to the penumbral fine structure. This approach is applied to the limb-side part of the penumbra in active region NOAA 10923. The preliminary results show a clear dependence of the plasma parameters on continuum intensity in the inner penumbra, i.e. weaker and horizontal magnetic field along with increased line-of-sight velocity are found in the low layers of the bright filaments. The results in the mid penumbra are ambiguous and future analyses are necessary to unveil the magnetic field structure and other plasma parameters there.

  4. Suppression of fine-structure splitting and oscillator strength of sodium D-line in a Debye plasma

    SciTech Connect (OSTI)

    Basu, Joyee, E-mail: joyeebasu@yahoo.com; Ray, Debasis, E-mail: ray.debasis@gmail.com [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)] [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)

    2014-01-15T23:59:59.000Z

    We investigate theoretically the influence of static plasma screening on relativistic spin-orbit interaction-induced fine-structure splitting of the D-line doublet arising from the transitions 3p{sub 1/2}–3s{sub 1/2} and 3p{sub 3/2}–3s{sub 1/2} of the valence electron of a sodium atom embedded in a model plasma environment. The many-electron atomic problem is formulated first as an effective one-electron problem in which the interaction between the optically active valence electron and the atomic ion core is represented by an accurate parametric model potential including core-polarization correction, and then the plasma effect on the atomic system is simulated by the Debye-screening model for the valence-core interaction. It is observed that the magnitude of spin-orbit energy shift reduces for both the upper component 3p{sub 3/2} and the lower component 3p{sub 1/2} with increasing plasma screening strength, thereby reducing the spin-orbit energy separation between these two components as the screening becomes stronger. As a consequence, the magnitude of fine-structure splitting between the D{sub 1} and D{sub 2} line energies of sodium drops significantly with stronger plasma screening. The optical (absorption) oscillator strength for 3s ? 3p transition is seen to reduce with stronger screening and this leads to a screening-induced gradual suppression of the 3p ? 3s spontaneous decay rate.

  5. Possible variations of the fine structure constant $?$ and their metrological significance

    E-Print Network [OSTI]

    K. A. Bronnikov; S. A. Kononogov

    2006-09-03T23:59:59.000Z

    We briefly review the recent experimental results on possible variations of the fine structure constant $\\alpha$ on the cosmological time scale and its position dependence. We outline the theoretical grounds for the assumption that $\\alpha$ might be variable, mention some phenomenological models incorporating a variable $\\alpha$ into the context of modern cosmology and discuss the significance of possible $\\alpha$ variations for theoretical and practical metrology.

  6. Quantification of rapid environmental redox processes with quick-scanning x-ray absorption

    E-Print Network [OSTI]

    Sparks, Donald L.

    Quantification of rapid environmental redox processes with quick-scanning x-ray absorption. Here we apply quick-scanning x-ray absorption spectroscopy (Q-XAS), at sub-second time that can be measured using x-ray absorption spectroscopy. arsenic extended x-ray absorption fine structure

  7. Low-energy fine-structure resonances in photoionization of O ii

    SciTech Connect (OSTI)

    Nahar, Sultana N.; Pradhan, Anil K. [Department of Astronomy, Ohio State University, Columbus, Ohio 43210 (United States); Montenegro, Maximiliano [Facultad de Educaci, Pontificia Universidad Catholica de Chile, Avda Vicua Mackenna 4860, Macul, Santiago (Chile); Eissner, Werner [Institut fuer Theoretische Physik, Teilinstitut 1, D-70550 Stuttgart (Germany)

    2010-12-15T23:59:59.000Z

    Resonant features in low-energy photoionization cross sections are reported in coupled-channel calculations for O ii including relativistic fine structure. The calculations reveal extensive near-threshold resonant structures in the small energy region between the fine structure levels of the ground state 2p{sup 2}({sup 3}P{sub 0,1,2}) of the residual ion O iii. Although the resonances have not yet been observed, they are similar to other experimentally observed features. They are expected to significantly enhance the very-low-temperature dielectronic recombination rates, potentially leading to the resolution of an outstanding nebular abundances anomaly. Higher energy partial and total photoionization cross sections of the ground configuration levels 2p{sup 3}({sup 4}S{sub 3/2}{sup o},{sup 2}D{sub 3/2,5/2}{sup o},{sup 2}P{sub 1/2,3/2}{sup o}) are found to be in agreement with experimental measurements on synchrotron-based photon sources [1-3], thereby identifying the excited O iii levels present in the ion beams. These are also the first results from a recently developed version of Breit-Pauli R-matrix (BPRM) codes, with inclusion of two-body magnetic interaction terms. The improved relativistic treatment could be important for other astrophysical applications and for more precise benchmarking of experimental measurements.

  8. He I vector magnetic field maps of a sunspot and its superpenumbral fine-structure

    E-Print Network [OSTI]

    Schad, T A; Lin, H; Tritschler, A

    2015-01-01T23:59:59.000Z

    Advanced inversions of high-resolution spectropolarimetric observations of the He I triplet at 1083 nm are used to generate unique maps of the chromospheric magnetic field vector across a sunspot and its superpenumbral canopy. The observations were acquired by the Facility Infrared Spectropolarimeter (FIRS) at the Dunn Solar Telescope (DST) on 29 January 2012. Multiple atmospheric models are employed in the inversions, as superpenumbral Stokes profiles are dominated by atomic-level polarization while sunspot profiles are Zeeman-dominated but also exhibit signatures perhaps induced by symmetry breaking effects of the radiation field incident on the chromospheric material. We derive the equilibrium magnetic structure of a sunspot in the chromosphere, and further show that the superpenumbral magnetic field does not appear finely structured, unlike the observed intensity structure. This suggests fibrils are not concentrations of magnetic flux but rather distinguished by individualized thermalization. We also dire...

  9. Speciation of arsenic in pyrite by micro-X-ray absorption fine- structure spectroscopy (XAFS)

    SciTech Connect (OSTI)

    Paktunc, D. (CCM)

    2008-09-30T23:59:59.000Z

    Pyrite (FeS2) often contains variable levels of arsenic, regardless of the environment of formation. Arsenian pyrite has been reported in coals, sediments and ore deposits. Arsenian pyrite having As concentrations of up to 10 wt % in sedimentary rocks (Kolker et al. 1997), about 10 wt% in gold deposits (Fleet et al. 1993), 12 wt % in a refractory gold ore (Paktunc et al. 2006) and 20 wt % in a Carlin-type gold deposit in Nevada (Reich et al. 2005) have been reported. Arsenian pyrite is the carrier of gold in hydrothermal Carlin-type gold deposits, and gold concentrations of up to 0.9 wt % have been reported (Reich et al. 2005; Paktunc et al. 2006). In general, high Au concentrations correlate with As-rich zones in pyrite (Paktunc et al. 2006). Pyrite often ends up in mining and metallurgical wastes as an unwanted mineral and consititutes one of the primary sources of As in the wastes. Arsenic can be readily released to the environment due to rapid oxidative dissolution of host pyrite under atmospheric conditions. Pyrite is also the primary source of arsenic in emissions and dust resulting from combustion of bituminous coals. Despite the importance of arsenian pyrite as a primary source of anthropogenic arsenic in the environment and its economic significance as the primary carrier of gold in Carlin-type gold deposits, our understanding of the nature of arsenic in pyrite is limited. There are few papers dealing with the mode of occurrence of arsenic by bulk XAFS in a limited number of pyrite-bearing samples. The present study documents the analysis of pyrite particles displaying different morphologies and a range of arsenic and gold concentrations to determine the nature and speciation of arsenic.

  10. RAPID COMMUNICATION Near-Edge X-Ray Absorption Fine Structure (NEXAFS) Microscopy of a

    E-Print Network [OSTI]

    of a Polycarbonate/Poly(acrylonitrile/butadiene/styrene) Blend C. C. SLOOP,1 * H. ADE,2 R. E. FORNES,2 R. D. GILBERT; revised 11 December 2000; accepted 20 December 2000 Published online 00 Month 2001 Keywords: polycarbonate Blends of polycarbonate (PC), poly(styrene/acryloni- trile) (SAN), and polybutadiene (PB), commonly

  11. The Fine-Structure of the Net-Circular Polarization in a Sunspot Penumbra

    E-Print Network [OSTI]

    A. Tritschler; D. A. N. Mueller; R. Schlichenmaier; H. J. Hagenaar

    2007-10-24T23:59:59.000Z

    We present novel evidence for a fine structure observed in the net-circular polarization (NCP) of a sunspot penumbra based on spectropolarimetric measurements utilizing the Zeeman sensitive FeI 630.2 nm line. For the first time we detect a filamentary organized fine structure of the NCP on spatial scales that are similar to the inhomogeneities found in the penumbral flow field. We also observe an additional property of the visible NCP, a zero-crossing of the NCP in the outer parts of the center-side penumbra, which has not been recognized before. In order to interprete the observations we solve the radiative transfer equations for polarized light in a model penumbra with embedded magnetic flux tubes. We demonstrate that the observed zero-crossing of the NCP can be explained by an increased magnetic field strength inside magnetic flux tubes in the outer penumbra combined with a decreased magnetic field strength in the background field. Our results strongly support the concept of the uncombed penumbra.

  12. Fine structure of the red luminescence band in undoped GaN

    SciTech Connect (OSTI)

    Reshchikov, M. A., E-mail: mreshchi@vcu.edu [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Usikov, A. [Nitride Crystals, Inc., 181E Industry Ct., Ste. B, Deer Park, New York 11729 (United States); Saint-Petersburg National Research University of Information Technologies, Mechanics and Optics, 49 Kronverkskiy Ave., 197101 Saint Petersburg (Russian Federation); Helava, H.; Makarov, Yu. [Nitride Crystals, Inc., 181E Industry Ct., Ste. B, Deer Park, New York 11729 (United States)

    2014-01-20T23:59:59.000Z

    Many point defects in GaN responsible for broad photoluminescence (PL) bands remain unidentified. Their presence in thick GaN layers grown by hydride vapor phase epitaxy (HVPE) detrimentally affects the material quality and may hinder the use of GaN in high-power electronic devices. One of the main PL bands in HVPE-grown GaN is the red luminescence (RL) band with a maximum at 1.8?eV. We observed the fine structure of this band with a zero-phonon line (ZPL) at 2.36?eV, which may help to identify the related defect. The shift of the ZPL with excitation intensity and the temperature-related transformation of the RL band fine structure indicate that the RL band is caused by transitions from a shallow donor (at low temperature) or from the conduction band (above 50?K) to an unknown deep acceptor having an energy level 1.130?eV above the valence band.

  13. Fine and hyperfine structure of P-levels in muonic hydrogen

    E-Print Network [OSTI]

    A. P. Martynenko

    2006-10-25T23:59:59.000Z

    Corrections of orders $\\alpha^5$ and $\\alpha^6$ are calculated in the fine structure interval $\\Delta E^{fs}=E(2P_{3/2})-E(2P_{1/2})$ and in the hyperfine structure of the energy levels $2P_{1/2}$ and $2P_{3/2}$ in muonic hydrogen. The obtained numerical values $\\Delta E^{fs}= 8352.08 \\mu eV$, $\\Delta \\tilde E^{hfs}(2P_{1/2})=7964.36 \\mu eV$, $\\Delta \\tilde E^{hfs}(2P_{3/2})=3392.59 \\mu eV$ can be considered as a reliable estimate for the comparison with corresponding experimental data and for the extraction of the experimental value of the Lamb shift $(2P-2S)$ in muonic hydrogen.

  14. MHD wave modes resolved in fine-scale chromospheric magnetic structures

    E-Print Network [OSTI]

    Verth, G

    2015-01-01T23:59:59.000Z

    Within the last decade, due to significant improvements in the spatial and temporal resolution of chromospheric data, magnetohydrodynamic (MHD) wave studies in this fascinating region of the Sun's atmosphere have risen to the forefront of solar physics research. In this review we begin by reviewing the challenges and debates that have manifested in relation to MHD wave mode identification in fine-scale chromospheric magnetic structures, including spicules, fibrils and mottles. Next we go on to discuss how the process of accurately identifying MHD wave modes also has a crucial role to play in estimating their wave energy flux. This is of cardinal importance for estimating what the possible contribution of MHD waves is to solar atmospheric heating. Finally, we detail how such advances in chromospheric MHD wave studies have also allowed us, for the first time, to implement cutting-edge magnetoseismological techniques that provide new insight into the sub-resolution plasma structuring of the lower solar atmospher...

  15. Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Efficiency

    E-Print Network [OSTI]

    Park, Namkyoo

    Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Doped Fiber Amplifier. With proper adjustments on doping profiles for the reduction of pump absorption rate, it becomes possible to optimize pump evolution map inside the doped fiber to get better power

  16. Role of defects in BiFeO{sub 3} multiferroic films and their local electronic structure by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Ravalia, Ashish; Vagadia, Megha; Solanki, P. S.; Shah, N. A.; Kuberkar, D. G., E-mail: dgkuberkar@rediffmail.com [Department of Physics, Saurashtra University, Rajkot 360 005 (India); Gautam, S.; Chae, K. H. [Nano Material Analysis Centre, Korean Institute of Science and Technology, Seoul 136-79 (Korea, Republic of); Asokan, K. [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

    2014-10-21T23:59:59.000Z

    Present study reports the role of defects in the electrical transport in BiFeO{sub 3} (BFO) multiferroic films and its local electronic structure investigated by near-edge X-ray absorption fine structure. Defects created by high energy 200?MeV Ag{sup +15} ion irradiation with a fluence of ?5?×?10{sup 11} ions/cm{sup 2} results in the increase in structural strain and reduction in the mobility of charge carriers and enhancement in resistive (I-V) and polarization (P-E) switching behaviour. At higher fluence of ?5?×?10{sup 12} ions/cm{sup 2}, there is a release in the structural strain due to local annealing effect, resulting in an increase in the mobility of charge carriers, which are released from oxygen vacancies and hence suppression in resistive and polarization switching. Near-edge X-ray absorption fine structure studies at Fe L{sub 3,2}- and O K-edges show a significant change in the spectral features suggesting the modifications in the local electronic structure responsible for changes in the intrinsic magnetic moment and electrical transport properties of BFO.

  17. Fine structure of the Poynting-Robertson effect for a luminous spinning relativistic star

    E-Print Network [OSTI]

    Jae Sok Oh; Hongsu Kim; Hyung Mok Lee

    2010-11-13T23:59:59.000Z

    As a sequel to our recent works challenging toward the systematic inclusion of the effect of radiation on the trajectory of a test particle orbiting around a luminous spinning relativistic star eventually aiming at its application to the accretion flow. We explore in the present work the fine structure of the trajectory of test particle just entering the ``suspension orbit" under the purpose of a detailed investigation of test particle's trajectory in the vicinity of the ``suspension orbit". We end up with a rather puzzling behavior that, contrary to our expectation, the specific angular momentum of the test particle instantly rises instead of decreasing monotonically just before the test particle enters the ``suspension orbit".

  18. The variation of the fine structure constant: testing the dipole model with thermonuclear supernovae

    E-Print Network [OSTI]

    Kraiselburd, Lucila; Negrelli, Carolina; Berro, Enrique García

    2014-01-01T23:59:59.000Z

    The large-number hypothesis conjectures that fundamental constants may vary. Accordingly, the spacetime variation of fundamental constants has been an active subject of research for decades. Recently, using data obtained with large telescopes a phenomenological model in which the fine structure constant might vary spatially has been proposed. We test whether this hypothetical spatial variation of {\\alpha}, which follows a dipole law, is compatible with the data of distant thermonuclear supernovae. Unlike previous works, in our calculations we consider not only the variation of the luminosity distance when a varying {\\alpha} is adopted, but we also take into account the variation of the peak luminosity of Type Ia supernovae resulting from a variation of {\\alpha}. This is done using an empirical relation for the peak bolometric magnitude of thermonuclear supernovae that correctly reproduces the results of detailed numerical simulations. We find that there is no significant difference between the several phenome...

  19. Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid

    E-Print Network [OSTI]

    Dmitri K. Gramotnev; Melissa L. Mather; Timo A. Nieminen

    2005-09-05T23:59:59.000Z

    It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface.

  20. DIRECT IMAGING OF FINE STRUCTURE IN THE CHROMOSPHERE OF A SUNSPOT UMBRA

    SciTech Connect (OSTI)

    Socas-Navarro, H. [Instituto de AstrofIsica de Canarias, Avda VIa Lactea S/N, La Laguna 38200, Tenerife (Spain); McIntosh, S. W.; Centeno, R.; De Wijn, A. G.; Lites, B. W. [High Altitude Observatory, NCAR , 3080 Center Green Drive, Boulder, CO 80301 (United States)], E-mail: hsocas@iac.es

    2009-05-10T23:59:59.000Z

    High-resolution imaging observations from the Hinode spacecraft in the Ca II H line are employed to study the dynamics of the chromosphere above a sunspot. We find that umbral flashes and other brightenings produced by the oscillation are extremely rich in fine structure, even beyond the resolving limit of our observations (0.''22). The umbra is tremendously dynamic to the point that our time cadence of 20 s does not suffice to resolve the fast lateral (probably apparent) motion of the emission source. Some bright elements in our data set move with horizontal propagation speeds of 30 km s{sup -1}. We have detected filamentary structures inside the umbra (some of which have a horizontal extension of {approx}1500 km) which, to our best knowledge, had not been reported before. The power spectra of the intensity fluctuations reveal a few distinct areas with different properties within the umbra that seem to correspond with the umbral cores that form it. Inside each one of these areas the dominant frequencies of the oscillation are coherent, but they vary considerably from one core to another.

  1. Direct Imaging of Fine Structure in the Chromosphere of a Sunspot Umbra

    E-Print Network [OSTI]

    H. Socas-Navarro; S. W. McIntosh; R. Centeno; A. G. de Wijn; B. W. Lites

    2008-11-19T23:59:59.000Z

    High-resolution imaging observations from the Hinode spacecraft in the CaII H line are employed to study the dynamics of the chromosphere above a sunspot. We find that umbral flashes and other brightenings produced by the oscillation are extremely rich in fine structure, even beyond the resolving limit of our observations (0.22"). The umbra is tremendously dynamic, to the point that our time cadence of 20 s does not suffice to resolve the fast lateral (probably apparent) motion of the emission source. Some bright elements in our dataset move with horizontal propagation speeds of 30 km/s. We have detected filamentary structures inside the umbra (some of which have a horizontal extension of ~1500 km) which, to our best knowledge, had not been reported before. The power spectra of the intensity fluctuations reveals a few distinct areas with different properties within the umbra that seem to correspond with the umbral cores that form it. Inside each one of these areas the dominant frequencies of the oscillation are coherent, but they vary considerably from one core to another.

  2. Fine Structure in the Energy Region of the Isoscalar Giant Quadrupole Resonance: Characteristic Scales from a Wavelet Analysis

    E-Print Network [OSTI]

    Ponomarev, Vladimir

    of the Witwatersrand, PO Wits, Johannesburg 2050, South Africa 3 Physics Department, University of Cape Town, Rondebosch 7700, South Africa 4 iThemba LABS, PO Box 722, Somerset West 7129, South Africa 5 DepartmentFine Structure in the Energy Region of the Isoscalar Giant Quadrupole Resonance: Characteristic

  3. Quantum of optical absorption in two-dimensional semiconductors

    E-Print Network [OSTI]

    California at Irvine, University of

    Quantum of optical absorption in two-dimensional semiconductors Hui Fanga,b,c , Hans A. Bechteld semiconductor, where is the fine structure con- stant and nc is an optical local field correction factor quantitative examination of the intrinsic absorption properties of free-standing 2D semiconductor thin films

  4. Structure and Mass Absorption of Hypothetical Terrestrial Black Holes

    E-Print Network [OSTI]

    A. P. VanDevender; J. Pace VanDevender

    2011-05-02T23:59:59.000Z

    The prospect of mini black holes, either primordial or in planned experiments at the Large Hadron Collider, interacting with the earth motivate us to examine how they may be detected and the scope of their impact on the earth. We propose that the more massive of these objects may gravitationally bind matter without significant absorption. Since the wave functions of gravitationally bound atoms orbiting a black hole are analogous to those of electrons around a nucleus, we call such an object the Gravitationally Equivalent of an Atom (GEA). Mini black holes are expected to lose mass through quantum evaporation, which has become well accepted on purely theoretical grounds. Since all attempts to directly observe x-rays from an evaporating black hole have failed, we examine the possibility of the inverse test: search for extant mini black holes by looking for emissions from matter bound in a GEA. If quantum evaporation does not occur, then miniature black holes left over from the early universe may be stable, contribute to dark matter, and in principle be detectable through emissions associated with the bound matter. We show that small black holes-with masses below \\sim10^12 kg-can bind matter without readily absorbing it into the black hole but the emissions are too weak to be detected from earth.

  5. Fine-scale Horizontal Structure of Arctic Mixed-Phase Clouds.

    SciTech Connect (OSTI)

    Rambukkange,M.; Verlinde, J.; Elorante, E.; Luke, E.; Kollias, P.; Shupe, M.

    2006-07-10T23:59:59.000Z

    Recent in situ observations in stratiform clouds suggest that mixed phase regimes, here defined as limited cloud volumes containing both liquid and solid water, are constrained to narrow layers (order 100 m) separating all-liquid and fully glaciated volumes (Hallett and Viddaurre, 2005). The Department of Energy Atmospheric Radiation Measurement Program's (DOE-ARM, Ackerman and Stokes, 2003) North Slope of Alaska (NSA) ARM Climate Research Facility (ACRF) recently started collecting routine measurement of radar Doppler velocity power spectra from the Millimeter Cloud Radar (MMCR). Shupe et al. (2004) showed that Doppler spectra has potential to separate the contributions to the total reflectivity of the liquid and solid water in the radar volume, and thus to investigate further Hallett and Viddaurre's findings. The Mixed-Phase Arctic Cloud Experiment (MPACE) was conducted along the NSA to investigate the properties of Arctic mixed phase clouds (Verlinde et al., 2006). We present surface based remote sensing data from MPACE to discuss the fine-scale structure of the mixed-phase clouds observed during this experiment.

  6. Bohr - Planck quantum theory, (Tesla) magnetic monopoles and fine structure constant

    E-Print Network [OSTI]

    Vladan Pankovic; Darko V. Kapor; Stevica Djurovic; Miodrag Krmar

    2014-10-17T23:59:59.000Z

    In this work we apply Bohr-Planck (Old quantum atomic and radiation) theory, i.e. and quasi-classical methods for analysis of the magnetic monopoles and other problems. We reproduce exactly some basic elements of the Dirac magnetic monopoles theory, especially Dirac electric/magnetic charge quantization condition. Also, we suggest a new, effective, simply called Tesla model (for analogy with positions of the solenoids by Tesla inductive motor) of the magnetic monopole instead of usual effective Dirac model (half-infinite, very tinny solenoid) of the magnetic monopole. In our, i.e. Tesla model we use three equivalent tiny solenoids connected in series with a voltage source. One end of any solenoid is placed at the circumference of a circle and solenoids are directed radial toward circle center. Length of any solenoid is a bit smaller than finite circle radius so that other end of any solenoid is very close to the circle center. Angles between neighboring solenoids equal $120^{\\circ}$. All this implies that, practically, there is no magnetic field, or, magnetic pole, e.g. $S$, in the circle center, and that whole system holds only other, $N$ magnetic pole, at the ends of the solenoids at circle circumference. Finally, we reproduce relatively satisfactory value of the fine structure constant using Planck, i.e. Bose-Einstein statistics and Wien displacement law.

  7. On the variation of the fine-structure constant in Friedmann Universes

    E-Print Network [OSTI]

    William Q. Sumner

    2005-03-07T23:59:59.000Z

    The fine-structure constant alpha does not vary as Friedmann Universes evolve, a conclusion based on assessments of quantum mechanics and electrodynamics. alpha = e^2/(4pi epsilon hbar c), where e is the charge of the electron, epsilon is vacuum permittivity, c is the speed of light, and hbar is Planck's constant divided by 2pi. This inquiry was motivated by Schrodinger's (1939) prediction that all quantum wave functions coevolve with Friedmann geometry and a similar prediction by Sumner (1994) for vacuum permittivity. The functional form of variations in quantum wave functions found by Schrodinger is enough to show that alpha does not vary. Electrodynamics also predicts that alpha does not vary. Evolutionary changes in c exactly cancel those in vacuum permittivity and other factors in alpha do not change. Since alpha appears in all first-order perturbation formulas for atomic energy levels, comparisons of the atomic spectra of distant atoms with those in laboratories provide an experimental measure of this prediction. Most experiments find changes in alpha that are either statistically zero or very small. These results and estimates of the Hubble constant and deceleration parameter from precision redshift/magnitude data support a major assumption of this paper that the Friedmann solution to Einstein's theory of general relativity without cosmological constant is an adequate approximation to spacetime geometry and its long term evolution at quantum scales.

  8. Semiconductor quantum dots with light-hole exciton ground state: fabrication and fine structure

    E-Print Network [OSTI]

    Y. H. Huo; B. J. Witek; S. Kumar; R. Singh; E. Zallo; R. Grifone; D. Kriegner; R. Trotta; N. Akopian; J. Stangl; V. Zwiller; G. Bester; A. Rastelli; O. G. Schmidt

    2012-08-31T23:59:59.000Z

    Quantum dots (QDs) can act as convenient hosts of two-level quantum szstems, such as single electron spins, hole spins or excitons (bound electron-hole pairs). Due to quantum confinement, the ground state of a single hole confined in a QD usually has dominant heavy-hole (HH) character. For this reason light-hole (LH) states have been largely neglected, despite the fact that may enable the realilzation of coherent photon-to-spin converters or allow for faster spin manipulation compared to HH states. In this work, we use tensile strains larger than 0.3% to switch the ground state of excitons confined in high quality GaAs/AlGaAs QDs from the conventional HH- to LH-type. The LH-exciton fine structure is characterized by two in-plane-polarized lines and, ~400 micro-eV above them, by an additional line with pronounced out-of-plane oscillator strength, consistent with theoretical predictions based on atomistic empirical pseudopotential calculations and a simple mesoscopic model.

  9. INTENSITY MAPPING OF THE [C II] FINE STRUCTURE LINE DURING THE EPOCH OF REIONIZATION

    SciTech Connect (OSTI)

    Gong Yan; Cooray, Asantha [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Silva, Marta; Santos, Mario G. [CENTRA, Instituto Superior Tecnico, Technical University of Lisbon, Lisboa 1049-001 (Portugal); Bock, James; Bradford, C. Matt; Zemcov, Michael [California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States)

    2012-01-20T23:59:59.000Z

    The atomic C II fine-structure line is one of the brightest lines in a typical star-forming galaxy spectrum with a luminosity {approx}0.1%-1% of the bolometric luminosity. It is potentially a reliable tracer of the dense gas distribution at high redshifts and could provide an additional probe to the era of reionization. By taking into account the spontaneous, stimulated, and collisional emission of the C II line, we calculate the spin temperature and the mean intensity as a function of the redshift. When averaged over a cosmologically large volume, we find that the C II emission from ionized carbon in individual galaxies is larger than the signal generated by carbon in the intergalactic medium. Assuming that the C II luminosity is proportional to the carbon mass in dark matter halos, we also compute the power spectrum of the C II line intensity at various redshifts. In order to avoid the contamination from CO rotational lines at low redshift when targeting a C II survey at high redshifts, we propose the cross-correlation of C II and 21 cm line emission from high redshifts. To explore the detectability of the C II signal from reionization, we also evaluate the expected errors on the C II power spectrum and C II-21 cm cross power spectrum based on the design of the future millimeter surveys. We note that the C II-21 cm cross power spectrum contains interesting features that capture physics during reionization, including the ionized bubble sizes and the mean ionization fraction, which are challenging to measure from 21 cm data alone. We propose an instrumental concept for the reionization C II experiment targeting the frequency range of {approx}200-300 GHz with 1, 3, and 10 m apertures and a bolometric spectrometer array with 64 independent spectral pixels with about 20,000 bolometers.

  10. absorption near-edge structure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption near-edge structure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of Intermolecular...

  11. absorption pre-edge structures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption pre-edge structures First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Temperature dependence...

  12. Utilization of Structured Packing for Energy Savings in Distillation and Absorption Columns

    E-Print Network [OSTI]

    Berven, O. J.; Howard, W. E.

    "UTILIZATION OF STRUCTURED PACKING FOR ENERGY SAVINGS IN DISTILLATION AND ABSORPTION COLUMNS" O. Jeffrey Berven and Wendell E. Howard Koch Engineering Company, Inc. Wi chita, Kansas As the need to reduce production costs causes... manufacturers to re-evaluate process ing schemes, hi gh efficiency structured packings are increasingly recognized as an effective alternative for reducing energy consumption in heat and mass transfer operations. In distillation, the high efficiency and low...

  13. Atomic structure of machined semiconducting chips: An x-ray absorption spectroscopy study

    SciTech Connect (OSTI)

    Paesler, M.; Sayers, D.

    1988-12-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) has been used to examine the atomic structure of chips of germanium that were produced by single point diamond machining. It is demonstrated that although the local (nearest neighbor) atomic structure is experimentally quite similar to that of single crystal specimens information from more distant atoms indicates the presence of considerable stress. An outline of the technique is given and the strength of XAS in studying the machining process is demonstrated.

  14. The vibrational and rotational structure of the 2400 to 1950 A? absorption spectrum of sulfur dioxide

    E-Print Network [OSTI]

    Riggs, James Willborn

    1958-01-01T23:59:59.000Z

    -l ap pi ng Or de rs 26 Ex te rn al Op ti cs As so ci at ed wi th Ab so rp ti on Tu be 27 28 Sulfur Dioxide Gas System.-The sulfur dioxide gas system associated with the absorption tube is pictured in Figure 3... fulfillment of' %hm r*tuir??Mi*s f?r %ift ??' m m m m m m & m s t Major Sttfejoott Rupeio* THE VIBRATIONAL AND ROTATIONAL STRUCTURE OP THE 2400 TO 1950 A ABSORPTION SPECTRUM OP SULFUR DIOXIDE A Dissertation 37 James Willborn Riggs, Jr. Approved...

  15. Diffraction anomalous fine structure analysis on (Bi,Pb){sub 2}PtO{sub 4} powders

    SciTech Connect (OSTI)

    Vacinova, J. [Centre National de la Recherche Scientifique (CNRS), 38 - Grenoble (France). Lab. de Cristallographie; Hodeau, J.L.; Bordet, P. [European Synchrotron Radiation Facility, 38 - Grenoble (France)] [and others

    1995-12-31T23:59:59.000Z

    The Diffraction Anomalous Fine Structure (DAFS) method can provide site selective and chemical selective structural information. The possibilities of DAFS experimental and data analysis procedures are demonstrated for (Bi{sub 1.67},Pb{sub 0.33}) powder samples. Experiments have been performed at both L{sub III} and K Pt edges (11.56.564keV and 78keV), using several data collection set-ups (analyser crystals, 1D-detector, 2D-detector). Based on this example, a comparison between these experimental procedures and analysis is given and discussed.

  16. GEOC Sunday, March 21, 2010 47 -Speciation and release kinetics of cadmium and zinc in paddy soils: Application of X-ray absorption

    E-Print Network [OSTI]

    Sparks, Donald L.

    : Application of X-ray absorption spectroscopy (XAS) Saengdao Khaokaew, Rufus L Chaney, PhD Matt Ginder kinetics, which is the aim of this research. X-ray absorption spectroscopy (XAS) was used to investigate Cd-ray absorption fine structure (EXAFS) spectroscopic data indicates that CdCO3 and Cd-humic complexes

  17. X-ray absorption in GaGdN: A study of local structure

    SciTech Connect (OSTI)

    Martinez-Criado, G.; Sans, J. A.; Susini, J. [Experiments Division, European Synchrotron Radiation Facility, 38043-Grenoble (France); Sancho-Juan, O.; Cantarero, A. [Institut de Ciencia dels Materials, Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Garro, N. [Institut de Ciencia dels Materials, Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Fundacio General de la Universitat de Valencia, P.O. Box 22085, 46071-Valencia (Spain); Roever, M.; Mai, D.-D.; Bedoya-Pinto, A.; Malindretos, J.; Rizzi, A. [IV. Physikalisches Institut and Virtual Institute of Spin Electronics (VISel), Georg-August Universitaet Goettingen, D-37077 Goettingen (Germany)

    2008-07-14T23:59:59.000Z

    In this study, we report on the incorporation of dilute Gd amounts into GaN films grown by molecular beam epitaxy. A combination of x-ray fluorescence with x-ray absorption spectroscopic techniques enabled us to examine not only the distribution of rare earth atoms in the GaN matrix but also the short-range structural order. Our results show Gd atoms in a trivalent state with tetrahedral coordination, thus substituting Ga in the wurtzite GaN structure.

  18. Solar abundances and helioseismology: fine structure spacings and separation ratios of low-degree p modes

    E-Print Network [OSTI]

    Sarbani Basu; William J. Chaplin; Yvonne Elsworth; Roger New; Aldo M. Serenelli; Graham A. Verner

    2006-10-02T23:59:59.000Z

    We have used 4752 days of data collected by the Birmingham Solar-Oscillations Network (BiSON) to determine very precise oscillation frequencies of acoustic low-degree modes that probe the solar core. We compare the fine (small frequency) spacings and frequency separation ratios formed from these data with those of different solar models. We find that models constructed with low metallicity are incompatible with the observations. The results provide strong support for lowering the theoretical uncertainties on the neutrino fluxes. These uncertainties had recently been raised due to the controversy over the solar abundances.

  19. Strong enhancement of light absorption and highly directive thermal emission in graphene

    E-Print Network [OSTI]

    Chen, Po

    Strong enhancement of light absorption and highly directive thermal emission in graphene Mingbo Pu: Graphene is a two-dimensional material with exotic electronic, optical and thermal properties. The optical absorption in monolayer graphene is limited by the fine structure constant . Here we demonstrated the strong

  20. Distribution of Fine Roots of Ponderosa Pine and Douglas-Fir in a Central Idaho Forest

    E-Print Network [OSTI]

    Fried, Jeremy S.

    at a study site in a central Idaho forest. Concentration and content of fine roots extracted from soil cores of exotic dis- eases, heavy grazing, and timber harvest has altered forest structure, stand composition(SwezyandAgee1991,Dumm2003).Finerootsarecritical structures for water and nutrient absorption from the soil

  1. A Scenario for the Fine Structures of Solar Type IIIb Radio Bursts Based on the Electron Cyclotron Maser Emission

    E-Print Network [OSTI]

    Wang, C B

    2015-01-01T23:59:59.000Z

    A scenario based on the electron cyclotron maser emission is proposed for the fine structures of solar radio emission in the present discussion. It is suggested that under certain conditions modulation of the ratio between the plasma frequency and electron gyro-frequency by ultra low frequency waves, which is a key parameter for excitation of the electron cyclotron maser instability, may lead to the intermittent emission of radio waves. As an example, the explanation of the observed fine-structure components in the solar type IIIb burst is discussed in detail. Three primary issues of the type IIIb bursts are addressed: 1) what is the physical mechanism that results in the intermittent emission elements that form a chain in the dynamic spectrum of type IIIb bursts, 2) what causes the split pair (or double stria) and the triple stria, 3) why in the events of fundamental-harmonic pair emission there is only IIIb-III, but IIIb-IIIb or III-IIIb cases are very rarely observed.

  2. Electronic Structure of Transition Metal-Cysteine Complexes From X-Ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Leung, B.O.; Jalilehvand, F.; Szilagyi, R.K.

    2009-05-19T23:59:59.000Z

    The electronic structures of Hg{sup II}, Ni{sup II}, Cr{sup III}, and Mo{sup V} complexes with cysteine were investigated by sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy and density functional theory. The covalency in the metal-sulfur bond was determined by analyzing the intensities of the electric-dipole allowed pre-edge features appearing in the XANES spectra below the ionization threshold. Because of the well-defined structures of the selected cysteine complexes, the current work provides a reference set for further sulfur K-edge XAS studies of bioinorganic active sites with transition metal-sulfur bonds from cysteine residues as well as more complex coordination compounds with thiolate ligands.

  3. Nonlinear optical propagation in a tandem structure comprising nonlinear absorption and scattering materials

    SciTech Connect (OSTI)

    Wang, Kangpeng; Ju, Yongfeng; He, Jin; Zhang, Long, E-mail: jwang@siom.ac.cn, E-mail: lzhang@siom.ac.cn; Wang, Jun, E-mail: jwang@siom.ac.cn, E-mail: lzhang@siom.ac.cn [Key Laboratory of Materials for High-Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); Chen, Yu [Key Laboratory for Advanced Materials, Department of Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237 (China); Blau, Werner J. [Key Laboratory of Materials for High-Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); School of Physics and the Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College Dublin, Dublin 2 (Ireland)

    2014-01-13T23:59:59.000Z

    Laser propagation in a tandem structure comprising carbon nanotubes and phthalocyanines is studied by Z-scan method. Due to the different mechanisms of the two materials, the laser beam can be attenuated with different absorptivities, by changing the sequence of light passing through each material. Numerical simulations considering the effect of path length and the change of nonlinear coefficient within each material are conducted for understanding the distribution of laser intensity in the tandem system and hence, fitting of the asymmetric Z-scan curves. The results are helpful for the design of nonlinear optical devices comprising multiple nonlinear materials and mechanisms.

  4. Sum rules for polarization-dependent x-ray absorption

    SciTech Connect (OSTI)

    Ankudinov, A.; Rehr, J.J. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1995-01-01T23:59:59.000Z

    A complete set of sum rules is obtained for polarization-dependent x-ray-absorption fine structure and x-ray circular magnetic dichroism (CMD), analogous to those for CMD derived by Thole [ital et] [ital al]. These sum rules relate x-ray-absorption coefficients to the ground-state expectation values of various operators. Problems with applying these sum rules are discussed.

  5. Precision Test of Many-Body QED in the Be$^+$ $2p$ Fine Structure Doublet Using Short-Lived Isotopes

    E-Print Network [OSTI]

    Nörtershäuser, Wilfried; Krieger, Andreas; Pachucki, Krzysztof; Puchalski, Mariusz; Blaum, Klaus; Bissell, Mark L; Frömmgen, Nadja; Hammen, Michael; Kowalska, Magdalena; Krämer, Jörg; Kreim, Kim; Neugart, Rainer; Neyens, Gerda; Sánchez, Rodolfo; Yordanov, Deyan T

    2015-01-01T23:59:59.000Z

    Absolute transition frequencies of the $2s\\; ^2{\\rm S}_{1/2} \\rightarrow 2p\\;^2\\mathrm{P}_{1/2,3/2}$ transitions in Be$^+$ were measured for the isotopes $^{7,9-12}$Be. The fine structure splitting of the $2p$ state and its isotope dependence are extracted and compared to results of \\textit{ab initio} calculations using explicitly correlated basis functions, including relativistic and quantum electrodynamics effects at the order of $m \\alpha^6$ and $m \\alpha^7 \\ln \\alpha$. Accuracy has been improved in both the theory and experiment by 2 orders of magnitude, and good agreement is observed. This represents one of the most accurate tests of quantum electrodynamics for many-electron systems, being insensitive to nuclear uncertainties.

  6. On the importance of nuclear quantum motions in near edge x-ray absorption fine structure (NEXAFS) spectroscopy of molecules

    E-Print Network [OSTI]

    Schwartz, Craig P.

    2009-01-01T23:59:59.000Z

    improved spectral agreement when nuclear quantum effects areby nuclear motion), and generally improves agreement with

  7. Fine-structure calculations of energy levels, oscillator strengths, and transition probabilities for sulfur-like iron, Fe XI

    SciTech Connect (OSTI)

    Abou El-Maaref, A., E-mail: aahmh@hotmail.com [Physics Department, Faculty of Science, Al-Azhar University, Assuit (Egypt); Ahmad, Mahmoud [Physics Department, Faculty of Science, Al-Azhar University, Assuit (Egypt); Allam, S.H. [Laboratory of Lasers and New Materials, Physics Department, Faculty of Science, Cairo University, Giza (Egypt)

    2014-05-15T23:59:59.000Z

    Energy levels, oscillator strengths, and transition probabilities for transitions among the 14 LS states belonging to configurations of sulfur-like iron, Fe XI, have been calculated. These states are represented by configuration interaction wavefunctions and have configurations 3s{sup 2}3p{sup 4}, 3s3p{sup 5}, 3s{sup 2}3p{sup 3}3d, 3s{sup 2}3p{sup 3}4s, 3s{sup 2}3p{sup 3}4p, and 3s{sup 2}3p{sup 3}4d, which give rise to 123 fine-structure energy levels. Extensive configuration interaction calculations using the CIV3 code have been performed. To assess the importance of relativistic effects, the intermediate coupling scheme by means of the Breit–Pauli Hamiltonian terms, such as the one-body mass correction and Darwin term, and spin–orbit, spin–other-orbit, and spin–spin corrections, are incorporated within the code. These incorporations adjusted the energy levels, therefore the calculated values are close to the available experimental data. Comparisons between the present calculated energy levels as well as oscillator strengths and both experimental and theoretical data have been performed. Our results show good agreement with earlier works, and they might be useful in thermonuclear fusion research and astrophysical applications. -- Highlights: •Accurate atomic data of iron ions are needed for identification of solar corona. •Extensive configuration interaction wavefunctions including 123 fine-structure levels have been calculated. •The relativistic effects by means of the Breit–Pauli Hamiltonian terms are incorporated. •This incorporation adjusts the energy levels, therefore the calculated values are close to experimental values.

  8. AN INTRIGUING CHROMOSPHERIC JET OBSERVED BY HINODE: FINE STRUCTURE KINEMATICS AND EVIDENCE OF UNWINDING TWISTS

    SciTech Connect (OSTI)

    Liu Wei; Berger, Thomas E.; Title, Alan M.; Tarbell, Theodore D. [Lockheed Martin Solar and Astrophysics Laboratory, Department ADBS, Building 252, 3251 Hanover Street, Palo Alto, CA 94304 (United States)

    2009-12-10T23:59:59.000Z

    We report a chromospheric jet lasting for more than 1 hr observed by the Hinode Solar Optical Telescope in unprecedented detail. The ejection occurred in three episodes separated by 12-14 minutes, with the amount and velocity of material decreasing with time. The upward velocities range from 438 to 33 km s{sup -1}, while the downward velocities of the material falling back have smaller values (mean: -56km s{sup -1}) and a narrower distribution (standard deviation: 14km s{sup -1}). The average acceleration inferred from parabolic spacetime tracks is 141 m s{sup -2}, a fraction of the solar gravitational acceleration. The jet consists of fine threads (0.''5-2'' wide), which exhibit coherent, oscillatory transverse motions perpendicular to the jet axis and about a common equilibrium position. These motions propagate upward along the jet, with the maximum phase speed of 744+-11 km s{sup -1}at the leading front of the jet. The transverse oscillation velocities range from 151 to 26 km s{sup -1}, amplitudes from 6.0 to 1.9 Mm, and periods from 250 to 536 s. The oscillations slow down with time and cease when the material starts to fall back. The falling material travels along almost straight lines in the original direction of ascent, showing no transverse motions. These observations are consistent with the scenario that the jet involves untwisting helical threads, which rotate about the axis of a single large cylinder and shed magnetic helicity into the upper atmosphere.

  9. Fine scale structural variants distinguish the genomes of Drosophilia melanogaster and D. pseudoobscura

    E-Print Network [OSTI]

    Macdonald, Stuart J.

    2006-07-07T23:59:59.000Z

    Background: A primary objective of comparative genomics is to identify genomic elements of functional significance that contribute to phenotypic diversity. Complex changes in genome structure (insertions, duplications, rearrangements, translocations...

  10. Possible Fine Structure in the Delayed Neutron Yields in the Resonance Region for Pu-239

    SciTech Connect (OSTI)

    Ohsawa, Takaaki; Torii, Takayuki [Department of Electrical and Electronic Engineering, Kinki University, Higashi-osaka 577-8502 (Japan); Hambsch, Franz-Josef [EC-JRC-Institute for Reference Materials and Measurements, Retieseweg 111, B-2440 Geel (Belgium)

    2005-05-24T23:59:59.000Z

    A method of analysis of fluctuation in the delayed neutron yield on the basis of the multimodal fission model was applied to the low-energy resolved resonances for Pu-239. The present calculation using recent data of the fluctuation of the mode branching ratios for the resolved resonances showed both positive and negative resonance structure in the delayed neutron yield relative to the thermal neutron value. This is in contrast to the U-235 case, for which mainly negative dips of about -3.5% were predicted.

  11. Characterization of the Electronic Structure of Silicon Nanoparticles Using X-ray Absorption and Emission

    SciTech Connect (OSTI)

    Vaverka, A M

    2008-07-15T23:59:59.000Z

    Resolving open questions regarding transport in nanostructures can have a huge impact on a broad range of future technologies such as light harvesting for energy. Silicon has potential to be used in many of these applications. Understanding how the band edges of nanostructures move as a function of size, surface termination and assembly is of fundamental importance in understanding the transport properties of these materials. In this thesis work I have investigated the change in the electronic structure of silicon nanoparticle assemblies as the surface termination is changed. Nanoparticles are synthesized using a thermal evaporation technique and sizes are determined using atomic force microscopy (AFM). By passivating the particles with molecules containing alcohol groups we are able to modify the size dependent band edge shifts. Both the valence and conduction bands are measured using synchrotron based x-ray absorption spectroscopy (XAS) and soft x-ray fluorescence (SXF) techniques. Particles synthesized via recrystallization of amorphous silicon/SiO{sub 2} multilayers of thicknesses below 10 nm are also investigated using the synchrotron techniques. These samples also show quantum confinement effects but the electronic structure is different from those synthesized via evaporation methods. The total bandgap is determined for all samples measured. The origins of these differences in the electronic structures are discussed.

  12. Umbral Fine Structures in Sunspots Observed with Hinode Solar Optical Telescope

    E-Print Network [OSTI]

    Reizaburo Kitai; Hiroko Watanabe; Tahei Nakamura; Ken-ichi Otsuji; Takuma Matsumoto; Satoru UeNo; Shin-ichi Nagata; Kazunari Shibata; Richard Muller; Kiyoshi Ichimoto; Saku Tsuneta; Yoshinori Suematsu; Yukio Katsukawa; Toshifumi Shimizu; Theodore D. Tarbell; Richard A. Shine; Alan M. Title; Bruce W. Lites

    2007-11-21T23:59:59.000Z

    High resolution imaging observation of a sunspot umbra was done with Hinode Solar Optical Telescope (SOT). Filtergrams in wavelengths of blue and green continuum were taken during three consecutive days. The umbra consisted of a dark core region, several diffuse components and numerous umbral dots. We derived basic properties of umbral dots (UDs), especially their temperatures, lifetimes, proper motions, spatial distribution and morphological evolution. Brightness of UDs is confirmed to depend on the brightness of their surrounding background. Several UDs show fission and fusion. Thanks to the stable condition of space observation, we could first follow the temporal behavior of these events. The derived properties of internal structure of the umbra are discussed in viewpoint of magnetoconvection in a strong magnetic field.

  13. High-resolution spectra of solar magnetic features. I. Analysis of penumbral fine structure

    SciTech Connect (OSTI)

    Lites, B.W.; Skumanich, A.; Scharmer, G.B. (High Altitude Observatory, Boulder, CO (USA) Kungliga Svenska Vetenskapsakademien, Stockholm (Sweden))

    1990-05-01T23:59:59.000Z

    The Swedish Vacuum Telescope on La Palma was used to obtain spectra of the magnetic-sensitive Fe I 630.25 nm line under conditions of exceptional angular resolution (0.32 arcsec) and high spectral resolution (FWHM 2.5 pm). Simultaneous 0.02 s CCD exposures of both the spectrum and the slit-jaw image effectively 'freeze' the atmospheric seeing motions and permit unambiguous identification of the spectra of the various penumbral structures. These spectra reveal the magnetic field strength in penumbral filaments through an intensity fit of the Zeeman splitting of this line. The observations show that: (1) the field strength varies from about 2100 G near the umbra-penumbra boundary to about 900 G at the outer edge of the penumbra, (2) the observed fluctuation of penumbral magnetic field is much less dramatic than the fluctuation in intensity, (3) there is a suggestion of a rapid change in field inclination between some light and dark filaments near the edge of the penumbra, and (4) there is no obvious correlation between Doppler shift (in part due to the Evershed flow) and filament intensity. 43 refs.

  14. Energy levels, oscillator strengths, radiative decay rates, and fine-structure collision strengths for the Zn-like ions Nb XII and Mo XIII

    SciTech Connect (OSTI)

    Liang, Liang, E-mail: liangll501@163.com; Liu, Xu-yang; Zhou, Chao

    2014-07-15T23:59:59.000Z

    Energy levels, line strengths, oscillator strengths, radiative decay rates, and fine-structure collision strengths are presented for the Zn-like ions Nb XII and Mo XIII. The atomic data are calculated with the AUTOSTRUCTURE code, where relativistic corrections are introduced according to the Breit–Pauli distorted wave approach. We present the calculations of atomic data for 110 fine-structure levels generated from fifteen configurations (1s{sup 2}2s{sup 2}2p{sup 6}3s{sup 2}3p{sup 6}3d{sup 10})4s{sup 2}, 4s4p, 4p{sup 2}, 4s4d, 4s4f, 4s5s, 4p4d, 4s5p, 4s5d, 4p4f, 4p5s, 4d{sup 2}, 4d4f, 4f{sup 2}, and 3d{sup 9}4s{sup 2}4p. Fine-structure collision strengths for transitions from the ground and the first four excited levels are presented at six electron energies (20, 50, 80, 110, 150, and 180 Ryd). Our atomic structure data are compared with the available experimental and theoretical results.

  15. Electronic structure of liquid water from polarization-dependent two-photon absorption spectroscopy

    E-Print Network [OSTI]

    Elles, Christopher G.; Rivera, Christopher A.; Zhang, Yuyuan; Pieniazek, Piotr A.; Bradforth, Stephen E.

    2009-02-26T23:59:59.000Z

    the absorption at many wavelengths simultaneously. A preresonance enhancement of the absolute 2PA cross section is observed when the pump-photon energy increases from 4.6 to 6.2 eV. The absorption cross section also depends on the relative polarization...

  16. Nonperturbative numerical calculation of the fine and hyperfine structure of muonic hydrogen by Breit potential including the effects from the proton size

    E-Print Network [OSTI]

    Pang, Hou-Rong

    2015-01-01T23:59:59.000Z

    By solving the two-body Schordinger equation in a very high precise nonperturbative numerical (NPnum) way, we reexamine the contributions of fine, hyperfine structure splittings of muonic hydrogen based on the Breit potential. The comparison of our results with those by the first order perturbative theory ($^{1st}$PT) in the literature shows, when the structure of proton is considered, the differences between the results by the $^{1st}$PT and NPnum methods are small for the fine and hyperfine splitting of $2P$ state, while are about $-0.009$ meV and $0.08$ meV for the $F=1$ and total hyperfine splitting of $2S$ state of muonic hydrogen, respectively. These differences are larger than the current experimental precision and would be significant to be considered in the theoretical calculation.

  17. Nonperturbative numerical calculation of the fine and hyperfine structure of muonic hydrogen by Breit potential including the effects from the proton size

    E-Print Network [OSTI]

    Hou-Rong Pang; Hai-Qing Zhou

    2015-04-27T23:59:59.000Z

    By solving the two-body Schordinger equation in a very high precise nonperturbative numerical (NPnum) way, we reexamine the contributions of fine, hyperfine structure splittings of muonic hydrogen based on the Breit potential. The comparison of our results with those by the first order perturbative theory ($^{1st}$PT) in the literature shows, when the structure of proton is considered, the differences between the results by the $^{1st}$PT and NPnum methods are small for the fine and hyperfine splitting of $2P$ state, while are about $-0.009$ meV and $0.08$ meV for the $F=1$ and total hyperfine splitting of $2S$ state of muonic hydrogen, respectively. These differences are larger than the current experimental precision and would be significant to be considered in the theoretical calculation.

  18. Surface structure of CdSe Nanorods revealed by combined X-ray absorption fine structure measurements and ab-initio calculations

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    Walda, J. ; Manna, L. ; Alivisatos, A. P. Nano Letters 2002,2, 557. Li, L. S. ; Alivisatos, A. P. Advanced MaterialsB. ; Colvin, V. L. ; Alivisatos, A. P. Journal of Physical

  19. Three-dimensional mapping of nickel oxidation states using full field x-ray absorption near edge structure nanotomography

    SciTech Connect (OSTI)

    Nelson, George J.; Harris, William M.; Izzo, John R. Jr.; Grew, Kyle N.; Chiu, Wilson K. S. [HeteroFoaM Center, a DOE Energy Frontier Research Center, Department of Mechanical Engineering, University of Connecticut, 191 Auditorium Rd., Storrs, Connecticut 06269-3139 (United States); Chu, Yong S. [National Synchrotron Light Source II, Brookhaven National Laboratory, Bldg. 703 Upton, New York 11973-5000 (United States); Yi, Jaemock [Advanced Photon Source, Argonne National Laboratory, 9700 S. Cass Ave., Bldg. 438-B007 Argonne, Illinois 60439 (United States); Andrews, Joy C.; Liu Yijin; Pianetta, Piero [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Rd., MS 69 Menlo Park, California 94025 (United States)

    2011-04-25T23:59:59.000Z

    The reduction-oxidation cycling of the nickel-based oxides in composite solid oxide fuel cells and battery electrodes is directly related to cell performance. A greater understanding of nickel redox mechanisms at the microstructural level can be achieved in part using transmission x-ray microscopy (TXM) to explore material oxidation states. X-ray nanotomography combined with x-ray absorption near edge structure (XANES) spectroscopy has been applied to study samples containing distinct regions of nickel and nickel oxide (NiO) compositions. Digitally processed images obtained using TXM demonstrate the three-dimensional chemical mapping and microstructural distribution capabilities of full-field XANES nanotomography.

  20. Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Hillyard, P. W.; Kuchibhatla, S. V. N. T.; Glover, T. E.; Hertlein, M. P.; Huse, Nils; Nachimuthu, P.; Saraf, L. V.; Thevuthasan, S.; Gaffney, K. J.

    2010-05-02T23:59:59.000Z

    We have used time-resolved soft x-ray spectroscopy to investigate the electronic structure of optically excited cuprous oxide at the O K-edge and the Cu L3-edge. The 400 nm optical excitation shifts the Cu and O absorptions to lower energy, but does not change the integrated x-ray absorption significantly for either edge. The constant integrated x-ray absorption cross-section indicates that the conduction-band and valence-band edges have very similar Cu 3d and O 2p orbital contributions. The 2.1 eV optical band gap of Cu2O significantly exceeds the one eV shift in the Cu L3- and O K-edges absorption edges induced by optical excitation, demonstrating the importance of core-hole excitonic effects and valence electron screening in the x-ray absorption process.

  1. Sensitivity of absorption spectra to surface segregation in InGaN/GaN quantum well structures

    SciTech Connect (OSTI)

    Klymenko, M. V.; Shulika, O. V. [Lab. Photonics, Kharkov National University of Radio Electronics, Kharkov, 61166 (Ukraine); Sukhoivanov, I. A. [Department of Electronics, Engineering Division, University of Guanajuato, Salamanca, Guanajuato, 36885 (Mexico)

    2014-05-15T23:59:59.000Z

    We investigate the influence of the indium surface segregation on absorption spectra in InGaN/GaN quantum well structures having different indium amount. Results of the mathematical modeling show that such influence is more pronounced in quantum well structures with high indium amounts. The origin of this effect is related to the interplay between the indium surface segregation and internal electrostatic fields. Our theoretical analysis is performed using semiconductor Bloch equations within the Hartree-Fock approximation including into consideration excitonic effects. Results of the global sensitivity analysis evidence that the influence of the indium surface segregation is less than one order of magnitude in comparison with the impact of the quantum-well width and indium molar fraction. Also, the influence of the indium surface segregation is not the same for each interface of the quantum well.

  2. A microsecond time resolved x-ray absorption near edge structure synchrotron study of phase transitions in Fe undergoing ramp heating at high pressure

    SciTech Connect (OSTI)

    Marini, C.; Mathon, O.; Pascarelli, S. [European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP220, 38043 Grenoble Cedex (France); Occelli, F.; Torchio, R.; Recoules, V.; Loubeyre, P. [CEA, Bruyeres le Chatel, 91297 Arpajon Cedex (France)

    2014-03-07T23:59:59.000Z

    We report a microsecond time-resolved x-ray absorption near edge structure study using synchrotron radiation to dynamically detect structural phase transitions in Fe undergoing rapid heating along a quasi-isochoric path. Within a few ms, we observed two structural phase transitions, which transform the ambient bcc phase of Fe into the fcc phase, and then into the liquid phase. This example illustrates the opportunities offered by energy dispersive x-ray absorption spectroscopy in the study of matter under extreme dynamic conditions. Advanced simulations are compared to these data.

  3. Advanced Fine Particulate Characterization Methods

    SciTech Connect (OSTI)

    Steven Benson; Lingbu Kong; Alexander Azenkeng; Jason Laumb; Robert Jensen; Edwin Olson; Jill MacKenzie; A.M. Rokanuzzaman

    2007-01-31T23:59:59.000Z

    The characterization and control of emissions from combustion sources are of significant importance in improving local and regional air quality. Such emissions include fine particulate matter, organic carbon compounds, and NO{sub x} and SO{sub 2} gases, along with mercury and other toxic metals. This project involved four activities including Further Development of Analytical Techniques for PM{sub 10} and PM{sub 2.5} Characterization and Source Apportionment and Management, Organic Carbonaceous Particulate and Metal Speciation for Source Apportionment Studies, Quantum Modeling, and High-Potassium Carbon Production with Biomass-Coal Blending. The key accomplishments included the development of improved automated methods to characterize the inorganic and organic components particulate matter. The methods involved the use of scanning electron microscopy and x-ray microanalysis for the inorganic fraction and a combination of extractive methods combined with near-edge x-ray absorption fine structure to characterize the organic fraction. These methods have direction application for source apportionment studies of PM because they provide detailed inorganic analysis along with total organic and elemental carbon (OC/EC) quantification. Quantum modeling using density functional theory (DFT) calculations was used to further elucidate a recently developed mechanistic model for mercury speciation in coal combustion systems and interactions on activated carbon. Reaction energies, enthalpies, free energies and binding energies of Hg species to the prototype molecules were derived from the data obtained in these calculations. Bimolecular rate constants for the various elementary steps in the mechanism have been estimated using the hard-sphere collision theory approximation, and the results seem to indicate that extremely fast kinetics could be involved in these surface reactions. Activated carbon was produced from a blend of lignite coal from the Center Mine in North Dakota and sunflower hulls for the biomass material to be carbonized. The ability to remove mercury from a bituminous coal's derived flue gas was low. Removals of only 15% were attained while injecting 6 lb/Macf of activated carbon upstream of an electrostatic precipitator. Poisoning of sites on the activated carbon by SO{sub 2} and SO{sub 3} contributed to the poor mercury capture performance.

  4. X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

    1999-02-01T23:59:59.000Z

    The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

  5. Helium and Deuterium Abundances as a Test for the Time Variation of the Fine Structure Constant and the Higgs Vacuum Expectation Value

    E-Print Network [OSTI]

    Nidal Chamoun; Susana J. Landau; Mercedes E. Mosquera; Hector Vucetich

    2006-12-21T23:59:59.000Z

    We use the semi-analytic method of \\citet{Esma91} to calculate the abundances of Helium and Deuterium produced during Big Bang nucleosynthesis assuming the fine structure constant and the Higgs vacuum expectation value may vary in time. We analyze the dependence on the fundamental constants of the nucleon mass, nuclear binding energies and cross sections involved in the calculation of the abundances. Unlike previous works, we do not assume the chiral limit of QCD. Rather, we take into account the quark masses and consider the one-pion exchange potential, within perturbation theory, for the proton-neutron scattering. However, we do not consider the time variation of the strong interactions scale but attribute the changes in the quark masses to the temporal variation of the Higgs vacuum expectation value. Using the observational data of the helium and deuterium, we put constraints on the variation of the fundamental constants between the time of nucleosynthesis and the present time.

  6. 3D Imaging of Nickel Oxidation States using Full Field X-ray Absorption Near Edge Structure Nanotomography

    SciTech Connect (OSTI)

    Nelson, George; Harris, William; Izzo, John; Grew, Kyle N. (Connecticut); (USARL)

    2012-01-20T23:59:59.000Z

    Reduction-oxidation (redox) cycling of the nickel electrocatalyst phase in the solid oxide fuel cell (SOFC) anode can lead to performance degradation and cell failure. A greater understanding of nickel redox mechanisms at the microstructural level is vital to future SOFC development. Transmission x-ray microscopy (TXM) provides several key techniques for exploring oxidation states within SOFC electrode microstructure. Specifically, x-ray nanotomography and x-ray absorption near edge structure (XANES) spectroscopy have been applied to study samples of varying nickel (Ni) and nickel oxide (NiO) compositions. The imaged samples are treated as mock SOFC anodes containing distinct regions of the materials in question. XANES spectra presented for the individual materials provide a basis for the further processing and analysis of mixed samples. Images of composite samples obtained are segmented, and the distinct nickel and nickel oxide phases are uniquely identified using full field XANES spectroscopy. Applications to SOFC analysis are discussed.

  7. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2004-08-31T23:59:59.000Z

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  8. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2003-10-14T23:59:59.000Z

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  9. Electric communication signals retain their fine temporal structure as they are transmitted from signaller to receiver in

    E-Print Network [OSTI]

    Hopkins, Carl D.

    and reverberation (Hopkins, 1986b). This enables weakly electric fish to communicate useful information even with their brief electric organ discharges (EODs). EODs from different species of African mormyrid electric fish). These experiments suggested that the salient feature of the EOD is its temporal waveform structure. Mormyrid fish

  10. DIRECT IMAGING OF FINE STRUCTURES IN GIANT PLANET-FORMING REGIONS OF THE PROTOPLANETARY DISK AROUND AB AURIGAE

    SciTech Connect (OSTI)

    Hashimoto, J.; Tamura, M.; Fukue, T.; Kokubo, E. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Muto, T. [Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo 152-8551 (Japan); Kudo, T. [Subaru Telescope, 650 North A'ohoku Place, Hilo, HI 96720 (United States); Fukagawa, M. [Department of Earth and Space Science, Graduate School of Science, Osaka University, 1-1, Machikaneyama, Toyonaka, Osaka 560-0043 (Japan); Goto, M.; Henning, T. [Max Planck Institute for Astronomy, Heidelberg (Germany); Grady, C. A. [Eureka Scientific and Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Hodapp, K. [Institute for Astronomy, University of Hawaii, 640 North A'ohoku Place, Hilo, HI 96720 (United States); Honda, M. [Department of Information Sciences, Kanagawa University, 2946 Tsuchiya, Hiratsuka, Kanagawa 259-1293 (Japan); Inutsuka, S. [Department of Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8602 (Japan); Knapp, G.; McElwain, M. W.; Turner, E. L. [Department of Astrophysical Sciences, Princeton University, NJ 08544 (United States); Momose, M.; Okamoto, Y. K. [College of Science, Ibaraki University, 2-1-1 Bunkyo, Mito, Ibaraki 310-8512 (Japan); Ohashi, N.; Takami, M., E-mail: jun.hashimoto@nao.ac.jp, E-mail: motohide.tamura@nao.ac.jp [Institute of Astronomy and Astrophysics, Academia Sinica, P.O. Box 23-141, Taipei 10617, Taiwan (China)

    2011-03-10T23:59:59.000Z

    We report high-resolution 1.6 {mu}m polarized intensity (PI) images of the circumstellar disk around the Herbig Ae star AB Aur at a radial distance of 22 AU (0.''15) up to 554 AU (3.''85), which have been obtained by the high-contrast instrument HiCIAO with the dual-beam polarimetry. We revealed complicated and asymmetrical structures in the inner part ({approx}<140 AU) of the disk while confirming the previously reported outer (r {approx}> 200 AU) spiral structure. We have imaged a double ring structure at {approx}40 and {approx}100 AU and a ring-like gap between the two. We found a significant discrepancy of inclination angles between two rings, which may indicate that the disk of AB Aur is warped. Furthermore, we found seven dips (the typical size is {approx}45 AU or less) within two rings, as well as three prominent PI peaks at {approx}40 AU. The observed structures, including a bumpy double ring, a ring-like gap, and a warped disk in the innermost regions, provide essential information for understanding the formation mechanism of recently detected wide-orbit (r > 20 AU) planets.

  11. Cavity resonance absorption in ultra-high bandwidth CRT deflection structure by a resistive load

    DOE Patents [OSTI]

    Dunham, M.E.; Hudson, C.L.

    1993-05-11T23:59:59.000Z

    An improved ultra-high bandwidth helical coil deflection structure for a cathode ray tube is described comprising a first metal member having a bore therein, the metal walls of which form a first ground plane; a second metal member coaxially mounted in the bore of the first metal member and forming a second ground plane; a helical deflection coil coaxially mounted within the bore between the two ground planes; and a resistive load disposed in one end of the bore and electrically connected to the first and second ground planes, the resistive load having an impedance substantially equal to the characteristic impedance of the coaxial line formed by the two coaxial ground planes to inhibit cavity resonance in the structure within the ultra-high bandwidth of operation. Preferably, the resistive load comprises a carbon film on a surface of an end plug in one end of the bore.

  12. THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED BY MO K-EDGE X-RAY ABSORPTION

    E-Print Network [OSTI]

    Sheffield, University of

    THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED of molybdenum in model UK high level nuclear waste glasses was investigated by X-ray Absorption Spectroscopy (XAS). Molybdenum K-edge XAS data were acquired from several inactive simulant high level nuclear waste

  13. Dopant site selectivity in BaCe0.85M0.15O3-by extended x-ray absorption fine structure

    E-Print Network [OSTI]

    Haile, Sossina M.

    solid oxide fuel cells and in hydrogen sensors.1­3 Proton incorporation requires, as a first step- titioning has also been interpreted to be responsible for the unusual observation that the cell volume vacancy content. Because proton incorporation requires, as a first step, the generation of oxygen

  14. Supporting information for Kinetics of Chromium(III) Oxidation by Manganese(IV) Oxides Using Quick Scanning X-Ray Absorption Fine Structure Spectroscopy (Q-XAFS)

    E-Print Network [OSTI]

    Sparks, Donald L.

    H 2.5, 3, and 3.5 Page S-5 to S-7: Figure S5 ­ S5-S1) Effect of Cr concentration S5-S2) Effect of Mn SH 2.5, 3, and 3.5 #12;S-5 Figure S5-S1 #12;S-6 Figure S5-S2 #12;S-7 Figure S5-S3 Figure S5 ­ S5-S1) Effect of Cr concentration ­ pH 2.5; 20 g/L HMO; [Cr(III)]= 100 mM, 80 mM, and 60 mM S5-S2) Effect of Mn

  15. Fine structure of Fe-Co-Ga and Fe-Cr-Ga alloys with low Ga content

    SciTech Connect (OSTI)

    Kleinerman, Nadezhda M., E-mail: kleinerman@imp.uran.ru; Serikov, Vadim V., E-mail: kleinerman@imp.uran.ru; Vershinin, Aleksandr V., E-mail: kleinerman@imp.uran.ru; Mushnikov, Nikolai V., E-mail: kleinerman@imp.uran.ru; Stashkova, Liudmila A., E-mail: kleinerman@imp.uran.ru [Institute of Metal Physics UB RAS, S. Kovalevskaya str. 18, 620990 Ekaterinburg (Russian Federation)

    2014-10-27T23:59:59.000Z

    Investigation of Ga influence on the structure of Fe-Cr and Fe-Co alloys was performed with the use of {sup 57}Fe Mössbauer spectroscopy and X-ray diffraction methods. In the alloys of the Fe-Cr system, doping with Ga handicaps the decomposition of solid solutions, observed in the binary alloys, and increases its stability. In the alloys with Co, Ga also favors the uniformity of solid solutions. The analysis of Mössbauer experiments gives some grounds to conclude that if, owing to liquation, clusterization, or initial stages of phase separation, there exist regions enriched in iron, some amount of Ga atoms prefer to enter the nearest surroundings of iron atoms, thus forming binary Fe-Ga regions (or phases)

  16. Towards simultaneous measurements of electronic and structural properties in ultra-fast x-ray free electron laser absorption spectroscopy experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaudin, J.; Fourment, C.; Cho, B. I.; Engelhorn, K.; Galtier, E.; Harmand, M.; Leguay, P. M.; Lee, H. J.; Nagler, B.; Nakatsutsumi, M.; et al

    2014-04-17T23:59:59.000Z

    The rapidly growing ultrafast science with X-ray lasers unveils atomic scale processes with unprecedented time resolution bringing the so called “molecular movie” within reach. X-ray absorption spectroscopy is one of the most powerful x-ray techniques providing both local atomic order and electronic structure when coupled with ad-hoc theory. Collecting absorption spectra within few x-ray pulses is possible only in a dispersive setup. We demonstrate ultrafast time-resolved measurements of the LIII-edge x-ray absorption near-edge spectra of irreversibly laser excited Molybdenum using an average of only few x-ray pulses with a signal to noise ratio limited only by the saturation level ofmore »the detector. The simplicity of the experimental set-up makes this technique versatile and applicable for a wide range of pump-probe experiments, particularly in the case of non-reversible processes.« less

  17. An x-ray absorption spectroscopic study of the electronic structure and bonding of rare-earth orthoferrites

    SciTech Connect (OSTI)

    Hayes, J.R.; Grosvenor, A.P. (Saskatchewan)

    2011-11-07T23:59:59.000Z

    Rare-earth orthoferrites, REFeO{sub 3} (RE=rare earth; Y), are tremendously adaptable compounds that are being investigated for use in a wide variety of applications including gas sensors, vehicle catalytic converters, and solid-oxide fuel cells. They also exhibit interesting magnetic properties such as high-temperature antiferromagnetism, making them useful for data storage applications. The compounds adopt a distorted perovskite-type structure where the tilt angle of the octahedra increases (Fe-O-Fe bond angle decreases) as the size of the rare-earth atom decreases. Despite intensive study of the physical properties of these compounds, very few studies have investigated how the bonding and electronic structure of these systems change with substitution of the RE. X-ray absorption near-edge spectroscopy (XANES) is a technique well-suited for such a study, and, in view of this, Fe L-, Fe K- and O K-edge spectra from a series of REFeO{sub 3} compounds (RE=La, Pr, Nd, Sm, Eu, Gd, Ho, Yb, Y) have been collected, and are presented here. Fe L-edge spectra show that Fe is octahedrally coordinated and that the Fe-centered octahedra do not appear to distort with changes in the identity of the RE. The Fe K-edge spectra contain an intersite hybrid peak, which is an ill-studied feature that is attributed to non-local transitions of 1s electrons to 3d states on the next-nearest-neighbor atom that are hybridized with 4p states on the absorbing atom through O 2p states. In this study, it is shown that the intensity of this feature is strongly dependent on the Fe-O-Fe bond angle; the lower the Fe-O-Fe bond angle, the less intense the intersite hybrid peak is.

  18. X-ray absorption spectroscopy studies of electrochemically deposited thin oxide films.

    SciTech Connect (OSTI)

    Balasubramanian, M.

    1998-06-02T23:59:59.000Z

    We have utilized ''in situ'' X-ray Absorption Fine Structure Spectroscopy to investigate the structure and composition of thin oxide films of nickel and iron that have been prepared by electrodeposition on a graphite substrate from aqueous solutions. The films are generally disordered. Structural information has been obtained from the analysis of the data. We also present initial findings on the local structure of heavy metal ions, e.g. Sr and Ce, incorporated into the electrodeposited nickel oxide films. Our results are of importance in a number of technological applications, among them, batteries, fuel cells, electrochromic and ferroelectric materials, corrosion protection, as well as environmental speciation and remediation.

  19. Mid-infrared electro-luminescence and absorption from AlGaN/GaN-based multi-quantum well inter-subband structures

    SciTech Connect (OSTI)

    Hofstetter, Daniel, E-mail: Daniel.Hofstetter@unine.ch [University of Neuchâtel, Institute of Physics, 51 Avenue de Bellevaux, Neuchâtel, CH–2009 (Switzerland); Bour, David P. [Avogy, Inc., 677 River Oaks Parkway, San Jose, California 95134 (United States); Kirste, Lutz [Fraunhofer Institute for Applied Solid State Physics (IAF), Tullastrasse 72, D-79108 Freiburg i. Brsg. (Germany)

    2014-06-16T23:59:59.000Z

    We present electro-modulated absorption and electro-luminescence measurements on chirped AlGaN/GaN-based multi-quantum well inter-subband structures grown by metal-organic vapour phase epitaxy. The absorption signal is a TM-polarized, 70?meV wide feature centred at 230?meV. At medium injection current, a 58?meV wide luminescence peak corresponding to an inter-subband transition at 1450?cm{sup ?1} (180?meV) is observed. Under high injection current, we measured a 4?meV wide structure peaking at 92.5?meV in the luminescence spectrum. The energy location of this peak is exactly at the longitudinal optical phonon of GaN.

  20. Step-by-step capping and strain state of GaN/AlN quantum dots studied by grazing-incidence diffraction anomalous fine structure

    SciTech Connect (OSTI)

    Coraux, J.; Favre-Nicolin, V.; Renevier, H. [Commissariat l'Energie Atomique, Departement de Recherche Fondamentale sur la Matiere Condensee, SP2M/NRS, 17 rue des martyrs, 38054 Grenoble Cedex 9 (France); Universite Joseph Fourier, BP 53, 38041, Grenoble Cedex 9 (France); Proietti, M. G. [Departamento de Fisica de la Materia Condensada, Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza, c. Pedro Cerbuna 12, 50009 Zaragoza (Spain); Daudin, B. [Commissariat l'Energie Atomique, Departement de Recherche Fondamentale sur la Matiere Condensee, SP2M/NRS, 17 rue des martyrs, 38054 Grenoble Cedex 9 (France)

    2006-05-15T23:59:59.000Z

    The investigation of small-size embedded nanostructures, by a combination of complementary anomalous diffraction techniques, is reported. GaN quantum dots (QD's), grown by molecular beam epitaxy in a modified Stranski-Krastanow mode, are studied in terms of strain and local environment, as a function of the AlN cap layer thickness, by means of grazing-incidence anomalous diffraction. That is, the x-ray photon energy is tuned across the Ga absorption K edge which makes diffraction chemically selective. Measurement of hkl scans, close to the AlN (3030) Bragg reflection, at several energies across the Ga K edge, allows the extraction of the Ga partial structure factor, from which the in-plane strain of GaN QD's is deduced. From the fixed-Q energy-dependent diffracted intensity spectra, measured for diffraction-selected isostrain regions corresponding to the average in-plane strain state of the QD's, quantitative information regarding the composition and out-of-plane strain has been obtained. We recover the in-plane and out-of-plane strains in the dots. The comparison to the biaxial elastic strain in a pseudomorphic layer indicates a tendency to an overstrained regime.

  1. Fine Grained Robotics

    E-Print Network [OSTI]

    Flynn, Anita M.

    Fine grained robotics is the idea of solving problems utilizing multitudes of very simple machines in place of one large complex entity. Organized in the proper way, simple machines and simple behaviors can lead to emergent ...

  2. Infrared study of the absorption edge of {beta}-InN films grown on GaN/MgO structures

    SciTech Connect (OSTI)

    Perez-Caro, M.; Rodriguez, A. G.; Vidal, M. A.; Navarro-Contreras, H. [Coordinacion para la Innovacion y la Aplicacion de la Ciencia y la Tecnologia (CIACYT), Universidad Autonoma de San Luis Potosi (UASLP), Alvaro Obregon 64, San Luis Potosi, SLP 78000 (Mexico)

    2010-07-15T23:59:59.000Z

    Infrared optical studies were carried out in a group of cubic InN samples grown by gas source molecular beam epitaxy on MgO (001) substrates. Room temperature (RT) reflectance and low-temperature (LT) transmittance measurements were performed by using fast Fourier transform infrared spectrometry. Reflectance fittings allowed to establish that {beta}-InN films have large free-carrier concentrations present (>10{sup 19} cm{sup -3}), a result that is corroborated by Hall effect measurements. Each sample explored exhibited a different optical absorption edge. The Varshni parameters that describe adequately the optical absorption edge responses with temperature are obtained for the set of samples studied. The observed temperatures changes, from LT to RT, are the lowest reported for III-V semiconductor binary compounds. The temperature coefficient of the conduction band depends on the strength of the electron-phonon interaction (e-ph-i), as well as on the thermal expansion. It has been predicted that cubic InN has one of the smallest e-ph-i of all III-V compounds, which is corroborated by these results. The variation in values of absorption edges is clearly consistent with the Burstein-Moss and band renormalization effects, produced by high free electron concentrations. It is shown that the conduction band in {beta}-InN, analogous to wurtzite InN, follows a nonparabolic behavior.

  3. Investigation of Temperature Dependent Optical Modes in GexAs35-xSe65 Thin Films: Structure Specific Raman, FIR and Optical Absorption Spectroscopy

    E-Print Network [OSTI]

    Khan, Pritam; Joshy, Abin; Sathe, Vasant; Deshpande, Uday; Adarsh, K V

    2015-01-01T23:59:59.000Z

    In this article, we present a comprehensive study of temperature and composition dependent Raman spectroscopy of GexAs35-xSe65 thin films to understand different structural units responsible for optical properties. Strikingly, our experimental results uncover the ratio of GeSe4/2 tetrahedral and AsSe3/2 pyramidal units in GexAs35-xSe65 thin films and their linear scaling relationship with temperature and x. An important notable outcome of our study is the formation of Se8 rings at lower temperatures. Our experimental results further provide interesting optical features, thermally and compositionally tunable optical absorption spectra. Detailed structure specific FIR data at room temperature also present direct information on the structural units in consistent with Raman data. We foresee that our studies are useful in determining the lightinduced response of these films and also for their potential applications in optics and optoelectronics.

  4. Using in situ X-ray absorption spectroscopy to study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}}

    SciTech Connect (OSTI)

    Itoh, Takanori, E-mail: tknitoh@seimichemical.co.jp [AGC SeimiChemical Co., Ltd., 3-2-10 Chigasaki, Chigasaki City, Kanagawa 253-8585 (Japan); Nakayama, Masanobu [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya-city, Aichi 466-8555 (Japan)

    2012-08-15T23:59:59.000Z

    To study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF) as a function of the oxygen partial pressure (P(O{sub 2})), in situ the Co and Fe K-edge X-ray absorption spectroscopy (XAS) was measured at elevated temperatures of 900 and 1000 K. The reduction of the Co and Fe valence, i.e., the oxygen content (3-{delta}) in LSCF, followed the change of P(O{sub 2}) from 1 to 10{sup -4} atm during{approx}4000 s. The quantitative analysis of the X-ray absorption near edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) indicated that the Fe valence was higher than the Co valence at oxidative condition ({delta} Almost-Equal-To 0) in LSCF. Whereas the Co valence decreased more than the Fe valence after reduction of P(O{sub 2}) at both 900 and 1000 K. From the relaxation plots of the valence and the oxygen content (3-{delta}) for Co and Fe after changing P(O{sub 2}), we successfully determined D{sub chem} and E{sub a} of an oxygen ion migration around Co and Fe in LSCF. A structural model with and without oxygen vacancies and an oxygen ion conduction mechanism for LSCF are proposed based on these results. - Graphical abstract: A structural model with and without oxygen vacancies, and the oxygen ion conduction mechanism of LSCF were speculated. In other words, oxygen vacancies would form more preferentially around Co than Fe from the results of in situ XAS analysis during reduction, and oxygen ions needs to pass through at the vicinity of Fe from the results of D{sub chem} and E{sub a}. Highlights: Black-Right-Pointing-Pointer Study of the oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF). Black-Right-Pointing-Pointer Using in situ X-ray absorption for study of valence and oxygen diffusion coefficient. Black-Right-Pointing-Pointer The oxygen vacancies should be preferentially localized around Co in LSCF. Black-Right-Pointing-Pointer The values of the dynamics parameters for Co and Fe are close to each other.

  5. The calculation of differential cross sections, polarization factions, electron-impact coherence parameters and fine-structure-effect spin-polarization functions for the electron-impact excitation of neon

    SciTech Connect (OSTI)

    Cartwright, D.C.; Csanak, G.; Machado, L.E.; Meneses, G.D. [Los Alamos National Laboratory, NM (United States)

    1993-05-01T23:59:59.000Z

    First-order many-body theory (FOMBT) has been used for the calculation of cross sections (DCSs), polarization fractions, a complete set of electron-impact coherence parameters, and fine-structure-effect spin-polarizations for the 1S{sub 0}-3P{sub 0,1,2} excitation of Ne. Results will be reported for E = 20, 25, 30, 50, 80, 100 and 120 eV incident electron energies and will be compared with available experimental data.

  6. Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure

    SciTech Connect (OSTI)

    Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Moog Chow, Gan, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2014-05-07T23:59:59.000Z

    The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{sub g} orbitals decreased and the density of states above the Fermi level increased in the relaxed MnO{sub 6} octahedron, as reflected by a wider separation between two sub-peaks in the pre-edge XANES spectra.

  7. Synthesis and enhanced light absorption of alumina matrix nanocomposites containing multilayer oxide nanorods and silver nanoparticles

    SciTech Connect (OSTI)

    Gan, Yong X., E-mail: yong.gan@utoledo.edu [Department of Mechanical, Industrial and Manufacturing Engineering, College of Engineering, University of Toledo, Toledo, OH 43606 (United States); Zeng, Xianwu; Su, Lusheng; Yang, Lu [Department of Mechanical, Industrial and Manufacturing Engineering, College of Engineering, University of Toledo, Toledo, OH 43606 (United States)] [Department of Mechanical, Industrial and Manufacturing Engineering, College of Engineering, University of Toledo, Toledo, OH 43606 (United States); Gan, Bo J. [Ottawa Hills High School, 2532 Evergreen Road, Toledo, OH 43606 (United States)] [Ottawa Hills High School, 2532 Evergreen Road, Toledo, OH 43606 (United States); Zhang, Lihua [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973 (United States)] [Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY 11973 (United States)

    2011-11-15T23:59:59.000Z

    Highlights: {yields} Multilayer oxide nanorods (nanocables) were obtained via chemical processing. {yields} Ag nanoparticles were deposited between the core and shell layers of the nanorods. {yields} The structure and composition of the nanorods were analyzed by SEM and TEM. {yields} CoO nanorods and Ag nanoparticles enhance light absorption of the nanocomposites. -- Abstract: In this paper, multilayer oxide nanorods were deposited in the nanopores of anodic aluminum oxide (AAO) via solution infiltration followed by heat treatment. The nanorods have a core-shell structure. First, the shell (nanotube) with the thickness of about 40 nm was made of TiO{sub 2} through the hydrolysis of (NH{sub 4}){sub 2}TiF{sub 6}. Second, silver nanoparticles with the diameter of about 3 nm were added into the TiO{sub 2} layer through thermal decomposition of AgNO{sub 3} at elevated temperatures. Then, cylindrical cores (nanorods) of CoO and ZnO with 200 nm diameter were prepared, respectively. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize the structure and composition of the nanorods. UV-vis light absorption measurements in the wavelength range from 350 to 1000 nm were performed to study the effect of nanorod and nanoparticle addition on the light absorption property of the alumina nanocomposites. It is found that CoO nanorods increase the light absorption of the alumina matrix composite in the wavelength range from 500 nm to 800 nm, but the TiO{sub 2} shell does not increase the light absorption much. The ZnO nanorods do not change the light absorption either. However, the addition of silver nanoparticles significantly enhances light absorption of both AAO/TiO{sub 2}/Ag/CoO and AAO/TiO{sub 2}/Ag/ZnO nanocomposites. This increase in the visible light absorption reveals that there exists surface plasmon around the fine silver nanoparticles in the nanorods.

  8. Percolative superconductivity in La{sub 2}CuO{sub 4.06} by lattice granularity patterns with scanning micro x-ray absorption near edge structure

    SciTech Connect (OSTI)

    Poccia, Nicola [MESA Institute for Nanotechnology, University of Twente, P. O. Box 217, 7500AE Enschede (Netherlands); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Chorro, Matthieu [Synchrotron SOLEIL L'Orme des Merisiers, 91190 Paris S.Aubin (France); Ricci, Alessandro [Deutsches Elektronen-Synchrotron DESY, Notkestraße 85, D-22607 Hamburg (Germany); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Xu, Wei [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Marcelli, Augusto [Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Frascati, 00044 Frascati, Rome (Italy); NSRL, University of Science and Technology of China, Hefei 230026 (China); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Campi, Gaetano [Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Bianconi, Antonio [RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy)

    2014-06-02T23:59:59.000Z

    The simplest cuprate superconductor La{sub 2}CuO{sub 4+y} with mobile oxygen interstitials exhibits a clear phase separation. It is known that oxygen interstitials enter into the rocksalt La{sub 2}O{sub 2+y} spacer layers forming oxygen interstitials rich puddles and poor puddles but only recently a bulk multiscale structural phase separation has been observed by using scanning micro X-ray diffraction. Here we get further information on their spatial distribution, using scanning La L{sub 3}-edge micro X-ray absorption near edge structure. Percolating networks of oxygen rich puddles are observed in different micrometer size portions of the crystals. Moreover, the complex surface resistivity shows two jumps associated to the onset of intra-puddle and inter-puddles percolative superconductivity. The similarity of oxygen doped La{sub 2}CuO{sub 4+y}, with the well established phase separation in iron selenide superconductors is also discussed.

  9. Electromagnetic waves reflection, transmission and absorption by graphene - magnetic semiconductor - graphene sandwich-structure in magnetic field: Faraday geometry

    E-Print Network [OSTI]

    Kuzmin, Dmitry A; Shavrov, Vladimir G

    2014-01-01T23:59:59.000Z

    Electrodynamic properties of the graphene - magnetic semiconductor - graphene sandwich-structure have been investigated theoretically with taking into account the dissipation processes. Influence of graphene layers on electromagnetic waves propagation in graphene - semi-infinte magnetic semiconductor and graphene - magnetic semiconductor - graphene sandwich-structure has been analyzed. Frequency and field dependences of the reflectance, transmittance and absorbtance of electromagnetic waves by such structure have been calculated. The size effects associated with the thickness of the structure have been analyzed. The possibility of efficient control of electrodynamic properties of graphene - magnetic semiconductor - graphene sandwich structure by an external magnetic field has been shown.

  10. X-ray absorption spectroscopic studies of mononuclear non-heme iron enzymes

    SciTech Connect (OSTI)

    Westre, T.E.

    1996-01-01T23:59:59.000Z

    Fe-K-edge X-ray absorption spectroscopy (XAS) has been used to investigate the electronic and geometric structure of the iron active site in non-heme iron enzymes. A new theoretical extended X-ray absorption fine structure (EXAFS) analysis approach, called GNXAS, has been tested on data for iron model complexes to evaluate the utility and reliability of this new technique, especially with respect to the effects of multiple-scattering. In addition, a detailed analysis of the 1s{yields}3d pre-edge feature has been developed as a tool for investigating the oxidation state, spin state, and geometry of iron sites. Edge and EXAFS analyses have then been applied to the study of non-heme iron enzyme active sites.

  11. The Apollo 15 Coarse Fines

    E-Print Network [OSTI]

    Rathbun, Julie A.

    I The Apollo 15 Coarse Fines (4-10 mm) Graham Ryder Sarah Bean Sherman Lunar and Planetary. TX 77058-4399 REFERENCE copy PLEASf 00 NOtr REbOIE #12;( The Apollo 15 Coarse Fines (4-10 mm) Graham. Johnson Space Center Houstqn, Texas JSC# 24035 #12;( THE APOLLO 15 COARSE FINES (4-10 mm) Introduction

  12. Measurement of the absorption coefficient for light laterally propagating in light-emitting diode structures with In{sub 0.2}Ga{sub 0.8}N/GaN quantum wells

    SciTech Connect (OSTI)

    Lelikov, Yu. S.; Bochkareva, N. I.; Gorbunov, R. I.; Martynov, I. A.; Rebane, Yu. T.; Tarkin, D. V.; Shreter, Yu. G. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)], E-mail: YShreter@mail.ioffe.ru

    2008-11-15T23:59:59.000Z

    A procedure for measuring the absorption coefficient for light propagating parallel to the surface of a GaN-based light emitting diode chip on a sapphire substrate is suggested. The procedure implies the study of emission from one end face of the chip as the opposite end face is illuminated with a light emitting diode. The absorption coefficient is calculated from the ratio between the intensities of emission emerging from the end faces of the sapphire substrate and the epitaxial layer. From the measurements for chips based on p-GaN/In{sub 0.2}Ga{sub 0.8}N/n-GaN structures, the lateral absorption coefficient is determined at a level of (23 {+-} 3)cm{sup -1} at a wavelength of 465 nm. Possible causes for the discrepancy between the absorption coefficients determined in the study and those reported previously are analyzed.

  13. Ge L{sub 3}-edge x-ray absorption near-edge structure study of structural changes accompanying conductivity drift in the amorphous phase of Ge{sub 2}Sb{sub 2}Te{sub 5}

    SciTech Connect (OSTI)

    Mitrofanov, K. V. [Nanoelectronics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Kolobov, A. V., E-mail: a.kolobov@aist.go.jp; Fons, P. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562, Japan and Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Wang, X.; Tominaga, J. [Nanoelectronics Research Institute and Green Nanoelectronics Center, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba 305-8562 (Japan); Tamenori, Y.; Uruga, T. [Synchrotron Radiation Research Institute (JASRI), SPring-8, 1-1-1, Kouto, Sayo, Hyogo 679-5198 (Japan); Ciocchini, N.; Ielmini, D. [DEIB - Politecnico di Milano, Piazza L. Da Vinci 32, 20133 Milano (Italy)

    2014-05-07T23:59:59.000Z

    A gradual uncontrollable increase in the resistivity of the amorphous phase of phase-change alloys, such as Ge{sub 2}Sb{sub 2}Te{sub 5}, known as drift, is a serious technological issue for application of phase-change memory. While it has been proposed that drift is related to structural relaxation, no direct structural results have been reported so far. Here, we report the results of Ge L{sub 3}-edge x-ray absorption measurements that suggest that the drift in electrical conductivity is associated with the gradual conversion of tetrahedrally coordinated Ge sites into pyramidal sites, while the system still remains in the amorphous phase. Based on electronic configuration arguments, we propose that during this process, which is governed by the existence of lone-pair electrons, the concentration of free carriers in the system decreases resulting in an increase in resistance despite the structural relaxation towards the crystalline phase.

  14. Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: Vibrations and structure of its excited S{sub 1}(?,?{sup *}) electronic state

    SciTech Connect (OSTI)

    Shin, Hee Won; Ocola, Esther J.; Laane, Jaan, E-mail: laane@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States)] [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States); Kim, Sunghwan [National Center for Biotechnology Information, National Library of Medicine, National Institutes of Health, Department of Health and Human Services, 8600 Rockville Pike, Bethesda, Maryland 20894 (United States)] [National Center for Biotechnology Information, National Library of Medicine, National Institutes of Health, Department of Health and Human Services, 8600 Rockville Pike, Bethesda, Maryland 20894 (United States)

    2014-01-21T23:59:59.000Z

    The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S{sub 1}(?,?{sup *}) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S{sub 0} and S{sub 1}(?,?{sup *}) electronic states. In each case the decreased ? bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S{sub 0} and S{sub 1}(?,?{sup *}) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S{sub 1}(?,?{sup *}) excited state.

  15. Structural and dynamical properties of Bridgman-grown CdSe[subscript x]Te[subscript 1?x] (0alloys

    E-Print Network [OSTI]

    Talwar, Devki N.

    Measurements of the Raman scattering and extended x-ray-absorption fine-structure (EXAFS) spectroscopy are reported on a series of Bridgman-grown zinc-blende CdTe[subscript 1?x]Se[subscript x] (0.35 ? x > 0.05) ternary ...

  16. Synthesis and Enhanced Light Absorption of Alumina Matrix Nanocomposites Containing Multilayer Oxide Nanorods and Silver Nanoparticles

    SciTech Connect (OSTI)

    Gan, Y.X.; Zhang, L.; Zeng, X.; Su, L.; Yang, L.; Gan, B.J.

    2011-11-01T23:59:59.000Z

    In this paper, multilayer oxide nanorods were deposited in the nanopores of anodic aluminum oxide (AAO) via solution infiltration followed by heat treatment. The nanorods have a core-shell structure. First, the shell (nanotube) with the thickness of about 40 nm was made of TiO{sub 2} through the hydrolysis of (NH{sub 4}){sub 2}TiF{sub 6}. Second, silver nanoparticles with the diameter of about 3 nm were added into the TiO{sub 2} layer through thermal decomposition of AgNO{sub 3} at elevated temperatures. Then, cylindrical cores (nanorods) of CoO and ZnO with 200 nm diameter were prepared, respectively. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize the structure and composition of the nanorods. UV-vis light absorption measurements in the wavelength range from 350 to 1000 nm were performed to study the effect of nanorod and nanoparticle addition on the light absorption property of the alumina nanocomposites. It is found that CoO nanorods increase the light absorption of the alumina matrix composite in the wavelength range from 500 nm to 800 nm, but the TiO{sub 2} shell does not increase the light absorption much. The ZnO nanorods do not change the light absorption either. However, the addition of silver nanoparticles significantly enhances light absorption of both AAO/TiO{sub 2}/Ag/CoO and AAO/TiO{sub 2}/Ag/ZnO nanocomposites. This increase in the visible light absorption reveals that there exists surface plasmon around the fine silver nanoparticles in the nanorods.

  17. Mn Occupations in Ga1-xMnxN Dilute Magnetic Semiconductors Probed by X-Ray Absorption Near-Edge Structure Spectroscopy

    SciTech Connect (OSTI)

    Wei Shiqiang; Yan Wensheng; Sun Zhihu; Liu Qinghua; Zhong Wenjie [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Zhang Xinyi [Department of Physics, Surface Physics Laboratory (National Key Laboratory), Fudan University, 220 Handan Road, Shanghai 200433 (China); Synchrotron Radiation Research Center, Fudan University, 220 Handan Road, Shanghai 200433 (China); Oyanagi, H. [Photonics Research Institute, National Institute of Advanced Industrial Science and Technology 1-1-1 Umezono Tsukuba, Ibaraki 305-8568 (Japan); Wu Ziyu [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100039 (China)

    2007-02-02T23:59:59.000Z

    X-ray absorption near-edge structure (XANES) is used to study the characteristics of different sites of Mn in the Ga1-xMnxN dilute magnetic semiconductor (DMS) with zinc-blende structure. The XANES spectra of representative Mn occupation sites (substitutional MnGa, interstitial MnI, MnGa-MnI dimer and Mn cluster) in GaN lattice are theoretically calculated and compared with experimental results. The substitutional Mn in GaN is characterized by a pre-edge peak at 2.0 eV and a post-edge multiple-scattering peak at 29.1 eV. The peaks shift in position and drop in intensity dramatically for the interstitial MnI and MnGa-MnI dimmer, and disappear completely for Mn clusters. We propose that the distinct characteristics of Mn K-edge XANES spectra for different Mn sites favor to discriminate Mn occupations in GaMnN DMS.

  18. Continuous fine ash depressurization system

    DOE Patents [OSTI]

    Liu, Guohai (Birmingham, AL); Peng, Wan Wang (Birmingham, AL); Vimalchand, Pannalal (Birmingham, AL)

    2011-11-29T23:59:59.000Z

    A system for depressurizing and cooling a high pressure, high temperature fine solid particles stream having entrained gas therein. In one aspect, the system has an apparatus for cooling the high pressure, high temperature fine solid particles stream having entrained gas therein and a pressure letdown device for depressurization by separating the cooled fine solid particles from a portion of the fine solid particles stream having entrained gas therein, resulting in a lower temperature, lower pressure outlet of solid particles for disposal or handling by downstream equipment.

  19. Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions at the Soil/Water Interface

    E-Print Network [OSTI]

    Sparks, Donald L.

    Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions on the surface coordination environment of Ni sorbed onto clays and aluminum oxides using X-ray absorption fine

  20. Beer Bike Violations & Fines 2012 # Water/Balloon Violations Fine

    E-Print Network [OSTI]

    Beer Bike Violations & Fines 2012 # Water/Balloon Violations Fine 1 Consistent under the violating college) 2 Filling balloons with any substance but water $1,500 per offense 3 Hitting Beer Bike Beer Bike shirt $150 per person 12 Unauthorized Entry to Buildings $200 per offense 13 Non

  1. Manufacture of finely divided carbon

    SciTech Connect (OSTI)

    Walker, D.G.

    1980-01-22T23:59:59.000Z

    Finely divided carbon is manufactured by a process producing a gaseous stream containing carbon monoxide by reacting coal and air in a slagging ash gasifier, separating carbon monoxide from the gaseous mixture, and disproportionating the carbon monoxide to produce finely divided carbon and carbon dioxide, the latter of which is recycled to the gasifier.

  2. A wavelet analysis for the X-ray absorption spectra of molecules

    SciTech Connect (OSTI)

    Penfold, T. J. [Ecole polytechnique Federale de Lausanne, Laboratoire de spectroscopie ultrarapide, ISIC, FSB-BSP, CH-1015 Lausanne (Switzerland); Ecole polytechnique Federale de Lausanne, Laboratoire de chimie et biochimie computationnelles, ISIC, FSB-BCH, CH-1015 Lausanne (Switzerland); SwissFEL, Paul Scherrer Inst, CH-5232 Villigen (Switzerland); Tavernelli, I.; Rothlisberger, U. [Ecole polytechnique Federale de Lausanne, Laboratoire de chimie et biochimie computationnelles, ISIC, FSB-BCH, CH-1015 Lausanne (Switzerland); Milne, C. J.; Abela, R. [SwissFEL, Paul Scherrer Inst, CH-5232 Villigen (Switzerland); Reinhard, M.; Nahhas, A. El; Chergui, M. [Ecole polytechnique Federale de Lausanne, Laboratoire de spectroscopie ultrarapide, ISIC, FSB-BSP, CH-1015 Lausanne (Switzerland)

    2013-01-07T23:59:59.000Z

    We present a Wavelet transform analysis for the X-ray absorption spectra of molecules. In contrast to the traditionally used Fourier transform approach, this analysis yields a 2D correlation plot in both R- and k-space. As a consequence, it is possible to distinguish between different scattering pathways at the same distance from the absorbing atom and between the contributions of single and multiple scattering events, making an unambiguous assignment of the fine structure oscillations for complex systems possible. We apply this to two previously studied transition metal complexes, namely iron hexacyanide in both its ferric and ferrous form, and a rhenium diimine complex, [ReX(CO){sub 3}(bpy)], where X = Br, Cl, or ethyl pyridine (Etpy). Our results demonstrate the potential advantages of using this approach and they highlight the importance of multiple scattering, and specifically the focusing phenomenon to the extended X-ray absorption fine structure (EXAFS) spectra of these complexes. We also shed light on the low sensitivity of the EXAFS spectrum to the Re-X scattering pathway.

  3. Silicate absorption in heavily obscured galaxy nuclei

    E-Print Network [OSTI]

    P. F. Roche; C. Packham; D. K. Aitken; R. E. Mason

    2006-10-19T23:59:59.000Z

    Spectroscopy at 8-13 microns with T-ReCS on Gemini-S is presented for 3 galaxies with substantial silicate absorption features, NGC 3094, NGC 7172 and NGC 5506. In the galaxies with the deepest absorption bands, the silicate profile towards the nuclei is well represented by the emissivity function derived from the circumstellar emission from the red supergiant, mu Cephei which is also representative of the mid-infrared absorption in the diffuse interstellar medium in the Galaxy. There is spectral structure near 11.2 microns in NGC 3094 which may be due to a component of crystalline silicates. In NGC 5506, the depth of the silicate absorption increases from north to south across the nucleus, suggestive of a dusty structure on scales of 10s of parsecs. We discuss the profile of the silicate absorption band towards galaxy nuclei and the relationship between the 9.7 micron silicate and 3.4 micron hydrocarbon absorption bands.

  4. Vibrational fine structure in the valence ionizations of transition-metal hexacarbonyls: new experimental indication of metal-to-carbonyl. pi. bonding

    SciTech Connect (OSTI)

    Hubbard, J.L.; Lichtenberger, D.L.

    1982-04-21T23:59:59.000Z

    The first observations of metal-carbon vibrational structure in photoionization bands are reported. Attention is focused on the predominantly metal d ionizations of M(CO)/sub 6/ (M = Cr, Mo, and W), and the methods for obtaining high resolution and very high signal-to-noise He I ionization data are detailed. The /sup 2/T/sub 2g/ ionization band of Cr(CO)/sub 6/ and the spin-orbit split /sup 2/E'' and /sup 2/U' bands of W(CO)/sub 6/ show distinct vibrational progressions which correspond to the totally symmetric (a/sub 1g/) metal-carbon stretching mode in the positive ion states. The metal-carbon stretching frequencies are found to be significantly less in the positive ion states than in the ground states, indicating a reduction of metal-carbon bond order upon the loss of a t/sub 2g/ electron. Evaluation of the vibrational progressions shows that the metal-carbon bond length increases on the order of 0.10 A upon t/sub 2g/ ionization in the case of W(CO)/sub 6/ and about 0.14 A in the case of Cr(CO)/sub 6/. In addition, the beginning of a short progression in the a/sub 1g/ carbon-oxygen stretching mode is observed in the Mo(CO)/sub 6/ spectrum and is clearly seen in the W(CO)/sub 6/ spectrum. All of these observations show that removal of an electron from the predominantly metal t/sub 2g/ orbitals, which are strictly ..pi.. symmetry with respect to the carbonyls, substantially weakens the metal-to-carbonyl bond. 9 figures, 2 tables.

  5. Oral Drug Absorption

    E-Print Network [OSTI]

    Yamashita, Shinji

    2006-10-26T23:59:59.000Z

    properties ? membrane permeability ? metabolic stability ? enzyme inhibition or induction ? protein binding ? transporter affinity ?. Chemical Optimization DDS technology 4 Strategy of Drug Delivery Absorption Distribution Metabolism Excretion Improve of drug... absorption absorption enhancement controlled releasecontrolled release new administration route Drug targeting to the tissue to the cell to the organelle Dr. Shinji Yamashita (Setsunan University) Issue: Oral Drug Absorption Dr. Valentino J. Stella...

  6. Interpretation of Wild 2 Dust Fine Structure: Comparison of Stardust Aluminium Foil Craters to the Three-Dimensional Shape of Experimental Impacts by Artificial Aggregate Particles and Meteorite Powders

    SciTech Connect (OSTI)

    Kearsley, A T; Burchell, M J; Price, M C; Graham, G A; Wozniakiewicz, P J; Cole, M J; Foster, N J; Teslich, N

    2009-12-10T23:59:59.000Z

    New experimental results show that Stardust crater morphology is consistent with interpretation of many larger Wild 2 dust grains being aggregates, albeit most of low porosity and therefore relatively high density. The majority of large Stardust grains (i.e. those carrying most of the cometary dust mass) probably had density of 2.4 g cm{sup -3} (similar to soda-lime glass used in earlier calibration experiments) or greater, and porosity of 25% or less, akin to consolidated carbonaceous chondrite meteorites, and much lower than the 80% suggested for fractal dust aggregates. Although better size calibration is required for interpretation of the very smallest impacting grains, we suggest that aggregates could have dense components dominated by {micro}m-scale and smaller sub-grains. If porosity of the Wild 2 nucleus is high, with similar bulk density to other comets, much of the pore-space may be at a scale of tens of micrometers, between coarser, denser grains. Successful demonstration of aggregate projectile impacts in the laboratory now opens the possibility of experiments to further constrain the conditions for creation of bulbous (Type C) tracks in aerogel, which we have observed in recent shots. We are also using mixed mineral aggregates to document differential survival of pristine composition and crystalline structure in diverse fine-grained components of aggregate cometary dust analogues, impacted onto both foil and aerogel under Stardust encounter conditions.

  7. Trends in the Carbonyl Core (C 1S, O 1S) f *C)O Transition in the Near-Edge X-ray Absorption Fine Structure Spectra of Organic Molecules

    E-Print Network [OSTI]

    ,2 meteorites3 and interplanetary dust particles,4 eocene and recent wood,5,6 coal, coke, and other organic

  8. Influence of recycled fine aggregates on the resistance of mortars to magnesium sulfate attack

    SciTech Connect (OSTI)

    Lee, Seung-Tae [Department of Civil Engineering, Kunsan National University, 68 Miryong-dong, Kunsan, Jeonbuk 573-701 (Korea, Republic of)], E-mail: stlee@kunsan.ac.kr

    2009-08-15T23:59:59.000Z

    The influence of recycled fine aggregates, which had been reclaimed from field-demolished concretes, on the resistance of mortar specimens to magnesium sulfate attack was investigated. Mortar specimens were prepared with recycled fine aggregates at different replacement levels (0%, 25%, 50%, 75% and 100% of natural fine aggregate by mass). The mortar specimens were exposed to 4.24% magnesium sulfate solution for about 1 year at ambient temperature, and regularly monitored for visual appearance, compressive strength loss and expansion. Additionally, in order to identify products of magnesium sulfate attack, mortar samples incorporating 0%, 25% and 100% replacement levels of the recycled fine aggregates were examined by X-ray diffraction (XRD) technique. Experimental results confirmed that the use of recycled fine aggregates up to a maximum 50% replacement level is effective under severe magnesium sulfate environment, irrespective of type of recycled fine aggregates. However, the worse performance was observed in mortar specimens incorporating 100% replacement level. It was found that the water absorption of recycled fine aggregates affected deterioration of mortar specimens, especially at a higher replacement level. XRD results indicated that the main cause of deterioration of the mortar specimens was primarily due to the formation of gypsum and thaumasite by magnesium sulfate attack. In addition, it appeared that the conversion of C-S-H into M-S-H by the attack probably influenced mechanical deterioration of mortar specimens with recycled fine aggregates.

  9. Enhanced light absorption of solar cells and photodetectors by diffraction

    DOE Patents [OSTI]

    Zaidi, Saleem H.; Gee, James M.

    2005-02-22T23:59:59.000Z

    Enhanced light absorption of solar cells and photodetectors by diffraction is described. Triangular, rectangular, and blazed subwavelength periodic structures are shown to improve performance of solar cells. Surface reflection can be tailored for either broadband, or narrow-band spectral absorption. Enhanced absorption is achieved by efficient optical coupling into obliquely propagating transmitted diffraction orders. Subwavelength one-dimensional structures are designed for polarization-dependent, wavelength-selective absorption in solar cells and photodetectors, while two-dimensional structures are designed for polarization-independent, wavelength-selective absorption therein. Suitable one and two-dimensional subwavelength periodic structures can also be designed for broadband spectral absorption in solar cells and photodetectors. If reactive ion etching (RIE) processes are used to form the grating, RIE-induced surface damage in subwavelength structures can be repaired by forming junctions using ion implantation methods. RIE-induced surface damage can also be removed by post RIE wet-chemical etching treatments.

  10. X-ray absorption spectroscopic studies of the active sites of nickel- and copper-containing metalloproteins

    SciTech Connect (OSTI)

    Tan, G.O.

    1993-06-01T23:59:59.000Z

    X-ray absorption spectroscopy (XAS) is a useful tool for obtaining structural and chemical information about the active sites of metalloproteins and metalloenzymes. Information may be obtained from both the edge region and the extended X-ray absorption fine structure (EXAFS) or post-edge region of the K-edge X-ray absorption spectrum of a metal center in a compound. The edge contains information about the valence electronic structure of the atom that absorbs the X-rays. It is possible in some systems to infer the redox state of the metal atom in question, as well as the geometry and nature of ligands connected to it, from the features in the edge in a straightforward manner. The EXAFS modulations, being produced by the backscattering of the ejected photoelectron from the atoms surrounding the metal atom, provide, when analyzed, information about the number and type of neighbouring atoms, and the distances at which they occur. In this thesis, analysis of both the edge and EXAFS regions has been used to gain information about the active sites of various metalloproteins. The metalloproteins studied were plastocyanin (Pc), laccase and nickel carbon monoxide dehydrogenase (Ni CODH). Studies of Cu(I)-imidazole compounds, related to the protein hemocyanin, are also reported here.

  11. ISO-LWS observations of C+ and O lines in absorption toward SgrB2

    E-Print Network [OSTI]

    Charlotte Vastel; Edward Polehampton; Jean-Paul Baluteau; Bruce Swinyard; Emmanuel Caux; Pierre Cox

    2002-08-09T23:59:59.000Z

    High spectral resolution ISO-LWS observations of the [OI] 63.2 and 145.5 microns and [CII] 157.7 microns fine structure lines are presented for the center of the Sagittarius B2 complex (SgrB2). Both the [OI] 63.2 microns and the [CII] 157.7 microns lines are detected in absorption. Using observations of the CO isotopes and of the HI lines, absorption components can be associated with many clouds along the Sgr B2 line of sight. From these data, we were able to disentangle three different layers, as predicted by PDR models, which contain atomic oxygen. We derive lower limits for the column densities of C and O. The fact that the [CII] 157.7 microns line is detected in absorption implies that the main cooling line of the interstellar medium can be optically thick especially in the direction of large star-forming complexes or in the nuclei of galaxies. This could partially account for the deficiency in the [CII] 157.7 microns line which has been recently found toward infrared bright galaxies in ISO data.

  12. Compressive behavior of fine sand.

    SciTech Connect (OSTI)

    Martin, Bradley E. (Air Force Research Laboratory, Eglin, FL); Kabir, Md. E. (Purdue University, West Lafayette, IN); Song, Bo; Chen, Wayne (Purdue University, West Lafayette, IN)

    2010-04-01T23:59:59.000Z

    The compressive mechanical response of fine sand is experimentally investigated. The strain rate, initial density, stress state, and moisture level are systematically varied. A Kolsky bar was modified to obtain uniaxial and triaxial compressive response at high strain rates. A controlled loading pulse allows the specimen to acquire stress equilibrium and constant strain-rates. The results show that the compressive response of the fine sand is not sensitive to strain rate under the loading conditions in this study, but significantly dependent on the moisture content, initial density and lateral confinement. Partially saturated sand is more compliant than dry sand. Similar trends were reported in the quasi-static regime for experiments conducted at comparable specimen conditions. The sand becomes stiffer as initial density and/or confinement pressure increases. The sand particle size become smaller after hydrostatic pressure and further smaller after dynamic axial loading.

  13. Dense, finely, grained composite materials

    DOE Patents [OSTI]

    Dunmead, Stephen D. (Davis, CA); Holt, Joseph B. (San Jose, CA); Kingman, Donald D. (Danville, CA); Munir, Zuhair A. (Davis, CA)

    1990-01-01T23:59:59.000Z

    Dense, finely grained composite materials comprising one or more ceramic phase or phase and one or more metallic and/or intermetallic phase or phases are produced by combustion synthesis. Spherical ceramic grains are homogeneously dispersed within the matrix. Methods are provided, which include the step of applying mechanical pressure during or immediately after ignition, by which the microstructures in the resulting composites can be controllably selected.

  14. Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy

    SciTech Connect (OSTI)

    Advanced Light Source; Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; England, Alice H.; Prendergast, David; Saykally, Richard J

    2009-05-29T23:59:59.000Z

    Near edge x-ray absorption fine structure (NEXAFS) spectra have been measured at the carbon and nitrogen K-edges of the prototypical aromatic molecule, pyrrole, both in the gas phase and when solvated in water, and compared with spectra simulated using a combination of classical molecular dynamics and first principles density functional theory in the excited state core hole approximation. The excellent agreement enabled detailed assignments. Pyrrole is highly reactive, particularly in water, and reaction products formed by the auto-oligomerization of pyrrole are identified. The solvated spectra have been measured at two different temperatures, indicating that the final states remain largely unaffected by both hydration and temperature. This is somewhat unexpected, since the nitrogen in pyrrole can donate a hydrogen bond to water.

  15. Resonant Absorption of Transverse Oscillations and Associated Heating in a Solar Prominence. I- Observational aspects

    E-Print Network [OSTI]

    Okamoto, Takenori J; De Pontieu, Bart; Uitenbroek, Han; Van Doorsselaere, Tom; Yokoyama, Takaaki

    2015-01-01T23:59:59.000Z

    Transverse magnetohydrodynamic (MHD) waves have been shown to be ubiquitous in the solar atmosphere and can in principle carry sufficient energy to generate and maintain the Sun's million-degree outer atmosphere or corona. However, direct evidence of the dissipation process of these waves and subsequent heating has not yet been directly observed. Here we report on high spatial, temporal, and spectral resolution observations of a solar prominence that show a compelling signature of so-called resonant absorption, a long hypothesized mechanism to efficiently convert and dissipate transverse wave energy into heat. Aside from coherence in the transverse direction, our observations show telltale phase differences around 180 degrees between transverse motions in the plane-of-sky and line-of-sight velocities of the oscillating fine structures or threads, and also suggest significant heating from chromospheric to higher temperatures. Comparison with advanced numerical simulations support a scenario in which transverse...

  16. X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films

    E-Print Network [OSTI]

    to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron for photovoltaic applications by reducing interface recombination and improving device performance.12

  17. XAFS near-edge structure of As[sub 2]S[sub 3]: A comparison of experiment and theory

    SciTech Connect (OSTI)

    Pfeiffer, G. (Max-Planck-Institut fuer Festkoerperforschung, Postfach 800665, 70506 Stuttgart (Germany)); Rehr, J.J. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States)); Sayers, D.E. (Department of Physics, North Carolina State University, Raleigh, North Carolina 27695-8202 (United States))

    1995-01-01T23:59:59.000Z

    The experimental As [ital K]-edge x-ray-absorption fine structure of As[sub 2]S[sub 3] is analyzed in detail and compared to data calculated theoretically from a model structure. The experimental spectrum is resolved into two components, one representing a bound excited state resonance and a second due to transitions to the continuum. The bound state resonance is located 6.1 eV below the continuum threshold and is fitted by a Lorentzian. The continuum structure is constructed using theoretically calculated [chi] and absorption cross section data together with an arctangent function simulating the absorption and lifetime at the continuum edge. For the theoretical calculation, the [ital ab] [ital initio] code FEFF was applied to an atomic cluster representing the amorphous solid. The results show that multiple scattering effects give rise only to small contributions in the region of the continuum threshold. They are negligible for higher energies.

  18. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  19. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, G.

    1982-06-16T23:59:59.000Z

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  20. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, Robert C. (Knoxville, TN); Biermann, Wendell J. (Fayetteville, NY)

    1989-01-01T23:59:59.000Z

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit.

  1. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, R.C.; Biermann, W.J.

    1989-05-09T23:59:59.000Z

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

  2. Optical absorption measurement system

    DOE Patents [OSTI]

    Draggoo, Vaughn G. (Livermore, CA); Morton, Richard G. (San Diego, CA); Sawicki, Richard H. (Pleasanton, CA); Bissinger, Horst D. (Livermore, CA)

    1989-01-01T23:59:59.000Z

    The system of the present invention contemplates a non-intrusive method for measuring the temperature rise of optical elements under high laser power optical loading to determine the absorption coefficient. The method comprises irradiating the optical element with a high average power laser beam, viewing the optical element with an infrared camera to determine the temperature across the optical element and calculating the absorption of the optical element from the temperature.

  3. Suppression of thermal carrier escape and efficient photo-carrier generation by two-step photon absorption in InAs quantum dot intermediate-band solar cells using a dot-in-well structure

    SciTech Connect (OSTI)

    Asahi, S.; Teranishi, H.; Kasamatsu, N.; Kada, T.; Kaizu, T.; Kita, T. [Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 (Japan)

    2014-08-14T23:59:59.000Z

    We investigated the effects of an increase in the barrier height on the enhancement of the efficiency of two-step photo-excitation in InAs quantum dot (QD) solar cells with a dot-in-well structure. Thermal carrier escape of electrons pumped in QD states was drastically reduced by sandwiching InAs/GaAs QDs with a high potential barrier of Al{sub 0.3}Ga{sub 0.7}As. The thermal activation energy increased with the introduction of the barrier. The high potential barrier caused suppression of thermal carrier escape and helped realize a high electron density in the QD states. We observed efficient two-step photon absorption as a result of the high occupancy of the QD states at room temperature.

  4. Source Signatures of Fine Particulate Matter from Petroleum Refining and Fuel Use

    SciTech Connect (OSTI)

    Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Robert Huggins

    1999-12-31T23:59:59.000Z

    Combustion experiments were carried out on four different residual fuel oils in a 732 kW boiler. Particulate matter (PM) emission samples were separated aerodynamically by a cyclone into fractions that were nominally less than and greater than 2.5 microns in diameter. However, examination of several of the samples by computer-controlled scanning electron microscopy (CCSEM) revealed that part of the <2.5 micron fraction (PM{sub 2.5}) in fact consists of carbonaceous cenospheres and vesicular particles that range up to 10 microns in diameter. X-ray absorption fine structure (XAFS) spectroscopy data were obtained at the S, V, Ni, Fe, Cu, Zn, and As Kedges, and at the Pb L-edge. Deconvolution of the x-ray absorption near edge structure (XANES) region of the S spectra established that the dominant molecular forms of S present were sulfate (26-84% of total S) and thiophene (13-39% of total S). Sulfate was greater in the PM{sub 2.5} samples than in the >2.5 micron samples (PM{sub 2.5+}). Inorganic sulfides and elemental sulfur were present in lower percentages. The Ni XANES spectra from all of the samples agree fairly well with that of NiSO4, while most of the V spectra closely resemble that of vanadyl sulfate (VO{center_dot}SO{sub 4}{center_dot}xH{sub 2}O). The other metals investigated (Fe, Cu, Zn, and Pb) were also present predominantly as sulfates. Arsenic is present as an arsenate (As{sup +5}). X-ray diffraction patterns of the PM{sub 2.5} fraction exhibit sharp lines due to sulfate compounds (Zn, V, Ni, Ca, etc.) superimposed on broad peaks due to amorphous carbons. All of the samples contain a significant organic component, with the LOI ranging from 64 to 87 % for the PM{sub 2.5} fraction and from 88 to 97% for the PM{sub 2.5+} fraction. {sup 13}C nuclear magnetic resonance (NMR) analysis indicates that the carbon is predominantly condensed in graphitic structures. Aliphatic structure was detected in only one of seven samples examined.

  5. Roadmap: Fine Arts Interdisciplinary Painting/Sculpture Bachelor of Fine Arts

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Fine Arts ­ Interdisciplinary Painting/Sculpture ­ Bachelor of Fine Arts [CA This roadmap is a recommended semester-by-semester plan of study for this major. However, courses on page 2 Kent Core Requirement 3 #12;Roadmap: Fine Arts ­ Interdisciplinary Painting/Sculpture ­ Bachelor

  6. Roadmap: Fine Arts Interdisciplinary Drawing/Sculpture Bachelor of Fine Arts

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Fine Arts ­ Interdisciplinary Drawing/Sculpture ­ Bachelor of Fine Arts [CA This roadmap is a recommended semester-by-semester plan of study for this major. However, courses on page 2 Kent Core Requirement 3 #12;Roadmap: Fine Arts ­ Interdisciplinary Drawing/Sculpture ­ Bachelor

  7. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon (Oak Ridge, TN); Perez-Blanco, Horacio (Knoxville, TN)

    1984-01-01T23:59:59.000Z

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  8. Intrinsic AGN Absorption Lines

    E-Print Network [OSTI]

    Fred Hamann

    2000-06-12T23:59:59.000Z

    Strong absorption lines are common in rest-frame UV spectra of AGNs due to a variety of resonant transitions, for example the HI Lyman series lines (most notably Ly-alpha 1216) and high-ionization doublets like CIV 1549,1551. The lines are called ``intrinsic'' if the absorbing gas is physically related to the AGN, e.g. if the absorber resides broadly within the radius of the AGN's surrounding ``host'' galaxy. Intrinsic absorption lines are thus valuable probes of the kinematics, physical conditions and elemental abundances in the gas near AGNs. Studies of intrinsic absorbers have historically emphasized the broad absorption lines (BALs) in quasars. Today we recognize a wider variety of intrinsic lines in a wider range of objects. For example, we now know that Seyfert 1 galaxies (the less luminous cousins of quasars) have intrinsic absorption. We also realize that intrinsic lines can form in a range of AGN environments --- from the dynamic inner regions like the BALs, to the more quiescent outer host galaxies >10 kpc away. This article provides a brief introduction to current observational and theoretical work on intrinsic AGN absorbers.

  9. Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants

    E-Print Network [OSTI]

    Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

    2012-01-01T23:59:59.000Z

    The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

  10. SOUTHERN FINE PARTICULATE MONITORING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2002-04-01T23:59:59.000Z

    This quarterly report presents results and analysis of continuous onsite ambient fine particulate data at the North Birmingham sampling site during the January-March, 2002 study period. The continuous data include PM{sub 2.5} mass concentrations measured by TEOM, particle sulfate using the R&P 8400S monitor, particle size distributions measured by SMPS and APS monitors, and PM{sub 2.5} light scattering extinction coefficient as measured by nephelometer. Some instrumental issues were noted with the upgrade of the APS model 3320 are described in the report, as well as preliminary performance indications for the upgraded instrument. During the quarter preliminary data analysis and modeling studies were conducted to test the potential of the North Birmingham site data for source attribution analyses. Our initial assessment has continued to be optimistic in this regard due to the location of the site relative to several important classes of local and midrange emission sources. We anticipate that these analyses will provide good separations of the effects of major source classes and spatial source clusters, and will provide useful information relevant to PM{sub 2.5} implementation strategies.

  11. Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption

    SciTech Connect (OSTI)

    Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C. (ANU)

    2014-09-24T23:59:59.000Z

    The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

  12. Plasmon absorption modulator systems and methods

    SciTech Connect (OSTI)

    Kekatpure, Rohan Deodatta; Davids, Paul

    2014-07-15T23:59:59.000Z

    Plasmon absorption modulator systems and methods are disclosed. A plasmon absorption modulator system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and a metal layer formed on a top surface of the stack of quantum well layers. A method for modulating plasmonic current includes enabling propagation of the plasmonic current along a metal layer, and applying a voltage across the stack of quantum well layers to cause absorption of a portion of energy of the plasmonic current by the stack of quantum well layers. A metamaterial switching system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and at least one metamaterial structure formed on a top surface of the stack of quantum well layers.

  13. The Quantum Absorption Refrigerator

    E-Print Network [OSTI]

    Amikam Levy; Ronnie Kosloff

    2011-11-09T23:59:59.000Z

    A quantum absorption refrigerator driven by noise is studied with the purpose of determining the limitations of cooling to absolute zero. The model consists of a working medium coupled simultaneously to hot, cold and noise baths. Explicit expressions for the cooling power are obtained for Gaussian and Poisson white noise. The quantum model is consistent with the first and second laws of thermodynamics. The third law is quantified, the cooling power J_c vanishes as J_c proportional to T_c^{alpha}, when T_c approach 0, where alpha =d+1 for dissipation by emission and absorption of quanta described by a linear coupling to a thermal bosonic field, where d is the dimension of the bath.

  14. Immobilization of Rocky Flats Graphite Fines Residue

    SciTech Connect (OSTI)

    Rudisill, T.S.

    1999-04-06T23:59:59.000Z

    The development of the immobilization process for graphite fines has proceeded through a series of experimental programs. The experimental procedures and results from each series of experiments are discussed in this report.

  15. York University Faculty of Fine Arts

    E-Print Network [OSTI]

    , Design, Digital Media, Film, Music, Theatre and Visual Arts. performance, which explores how digital media is transforming performance practice, Dance, Music, Film and Media Studies, Digital Media, or a related Fine Arts

  16. Segmentation and Enhancement of Latent Fingerprints: A Coarse to Fine Ridge

    E-Print Network [OSTI]

    ., "Image Quality Assessment: From Error Visibility to Structural Similarity", IEEE Transaction on ImageSegmentation and Enhancement of Latent Fingerprints: A Coarse to Fine Ridge Structure Dictionary ridge Pores · Include all dimensional attributes of the ridge such as pores, edge contour, incipient

  17. Development of an Advanced Fine Coal Suspension Dewatering Process

    SciTech Connect (OSTI)

    B. K. Parekh; D. P. Patil

    2008-04-30T23:59:59.000Z

    With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

  18. Direct and quantitative photothermal absorption spectroscopy of individual particulates

    SciTech Connect (OSTI)

    Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

    2013-12-23T23:59:59.000Z

    Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

  19. Antiproton Absorption in Nuclei

    E-Print Network [OSTI]

    Yu. T. Kiselev; E. Ya. Paryev

    2006-01-24T23:59:59.000Z

    We present the analysis of experimental data on forward antiproton production on nuclei. The calculations are done in the framework of a folding model which takes properly into account both incoherent direct proton-nucleon and cascade pion-nucleon antiproton production processes as well as internal nucleon momentum distribution. The effective antiproton-nucleon cross section in nuclear matter and the imaginary part of the antiproton nuclear optical potential are estimated to be 25-45 mb and -(38-56) MeV at normal nuclear matter density, respectively. The results of the performed analysis evidence for the decreasing of antiproton absorption in the nuclear medium.

  20. Crown structure, radiation absorption, photosynthesis and transpiration 

    E-Print Network [OSTI]

    Wang, Yingping

    and photosynthetic properties of the shoots of Sitka spruce were measure in an open path gas exchange system to parameterize a biochemical photosynthesis model. It was found that co-limitation of photosynthesis plays an important role in the PAR responses of both...

  1. Americium characterization by X-ray fluorescence and absorption spectroscopy in plutonium uranium mixed oxide

    SciTech Connect (OSTI)

    Degueldre, Claude, E-mail: claude.degueldre@psi.ch; Cozzo, Cedric; Martin, Matthias; Grolimund, Daniel; Mieszczynski, Cyprian

    2013-06-01T23:59:59.000Z

    Plutonium uranium mixed oxide (MOX) fuels are currently used in nuclear reactors. The actinides in these fuels need to be analyzed after irradiation for assessing their behaviour with regard to their environment and the coolant. In this work the study of the atomic structure and next-neighbour environment of Am in the (Pu,U)O? lattice in an irradiated (60 MW d kg?¹) MOX sample was performed employing micro-X-ray fluorescence (µ-XRF) and micro-X-ray absorption fine structure (µ-XAFS) spectroscopy. The chemical bonds, valences and stoichiometry of Am (~0.66 wt%) are determined from the experimental data gained for the irradiated fuel material examined in its peripheral zone (rim) of the fuel. In the irradiated sample Am builds up as Am³? species within an [AmO?]¹³? coordination environment (e.g. >90%) and no (<10%) Am(IV) or (V) can be detected in the rim zone. The occurrence of americium dioxide is avoided by the redox buffering activity of the uranium dioxide matrix. - Graphical abstract: Americium LIII XAFS spectra recorded for the irradiated MOX sub-sample in the rim zone for a 300 ?m×300 ?m beam size area investigated over six scans of 4 h. The records remain constant during multi-scan. The analysis of the XAFS signal shows that Am is found as trivalent in the UO? matrix. This analytical work shall open the door of very challenging analysis (speciation of fission product and actinides) in irradiated nuclear fuels. - Highlights: • Americium was characterized by microX-ray absorption spectroscopy in irradiated MOX fuel. • The americium redox state as determined from XAS data of irradiated fuel material was Am(III). • In the sample, the Am³? face an AmO?¹³?coordination environment in the (Pu,U)O? matrix. • The americium dioxide is reduced by the uranium dioxide matrix.

  2. DIVISION S-5-PEDOLOGY Secondary Carbonates in Three Fine and Fine-loamy Alfisols in Michigan

    E-Print Network [OSTI]

    Schaetzl, Randall

    DIVISION S-5-PEDOLOGY Secondary Carbonates in Three Fine and Fine-loamy Alfisols in Michigan can be troublesome. We studied three Alfisol pedons in Michigan that contained secondary carbonates are young soils or those in drier climates. The Late Wisconsinan glaciated region of Michigan and nearby

  3. Cosmic Fine Tuning and the Multiverse Hypothesis

    E-Print Network [OSTI]

    Colin S. Coleman

    2012-06-28T23:59:59.000Z

    The observable universe is necessarily hospitable for life. There are indications, however, that the laws of physics and cosmological parameters need not take the form and values observed, and if they were slightly different life could not exist. A common approach to this fine tuning problem is to propose a cosmos with an ensemble of domains, mostly inhospitable for life. A Bayesian method is used to show that this hypothesis is more credible than a homogeneous fine tuned universe. This conclusion is straightforward for a finite ensemble, but can be extended to an infinite ensemble by applying a formulation of the Principle of Mediocrity.

  4. Balmer Absorption Lines in FeLoBALs

    E-Print Network [OSTI]

    K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

    2006-12-14T23:59:59.000Z

    We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

  5. LAMINAR: PRACTICAL FINE-GRAINED DECENTRALIZED INFORMATION

    E-Print Network [OSTI]

    Witchel, Emmett

    · Programming language based (PL) · Example: Jif, Flow Caml · Operating system based (OS) · Example: AsbestosLAMINAR: PRACTICAL FINE-GRAINED DECENTRALIZED INFORMATION FLOW CONTROL (DIFC) Indrajit Roy, Donald, SSN, personal calendar... But not every program you run is trusted Bugs in code, malicious plugins

  6. 700:20131001.1211 Fine Sun Sensor

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    700:20131001.1211 Fine Sun Sensor The Laboratory for Atmospheric and Space Physics (LASP) at the University of Colorado, Boulder is a world leader in space-based research including measurements of the Sun with respect to sun center. LASP has built sun position sensors for decades beginning with sensors for sub

  7. University of Florida College of Fine Arts

    E-Print Network [OSTI]

    Watson, Craig A.

    ­ pursuing the degree ­ final project and exams ­ graduation. General information for both Master's degree1 University of Florida College of Fine Arts School of Music GRADUATE STUDIES HANDBOOK Section 1 for International Student Services Graduate Music Placement Exams Graduate Listserv Graduate Advisory Group Section

  8. 7, 96359661, 2007 apportionment of fine

    E-Print Network [OSTI]

    Boyer, Edmond

    ). The air pollution generated in megacities poses a threat to human health and25 the environment; Mexico organic aerosol in Mexico City during the MILAGRO Experiment 2006 E. A. Stone1 , D. C. Snyder1 , R. J fraction of fine particulate matter (PM2.5) in Mexico City. Daily and select 12-h PM2.5 samples were

  9. System for utilizing oil shale fines

    DOE Patents [OSTI]

    Harak, Arnold E. (Laramie, WY)

    1982-01-01T23:59:59.000Z

    A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort (20) which pyrolyzes the fines in the presence of heated gaseous combustion products, the cyclone retort having a first outlet (30) through which vapors can exit that can be cooled to provide oil, and having a second outlet (32) through which spent shale fines are removed. A burner (36) connected to the spent shale outlet of the cyclone retort, burns the spent shale with air, to provide hot combustion products (24) that are carried back to the cyclone retort to supply gaseous combustion products utilized therein. The burner heats the spent shale to a temperature which forms a molten slag, and the molten slag is removed from the burner into a quencher (48) that suddenly cools the molten slag to form granules that are relatively inert and of a size that is convenient to handle for disposal in the ground or in industrial processes.

  10. ORIGINAL ARTICLE Fine Particulate Matter and Mortality

    E-Print Network [OSTI]

    Dominici, Francesca

    landmark cohort studies for estimating the chronic effects of fine particulate air pollution (PM2 that the Medicare files can be used to construct on-going cohorts for tracking the risk of air pollution over time- tory diseases, and also with increased mortality.1­6 Chronic effects of air pollution potentially

  11. CONFERENCES | EVENTS | FINE DINING TRINITY HALL

    E-Print Network [OSTI]

    Lasenby, Joan

    CONFERENCES | EVENTS | FINE DINING #12;32 WELCOME WELCOME TO TRINITY HALL CONFERENCE AND EVENTS "If and point the way to the gardens of Trinity Hall. "HENRY JAMES 1878 Trinity Hall is the fifth oldest college from the hustle and bustle of the City, Trinity Hall has a quiet, peaceful air making it perfect

  12. 7, 71717233, 2007 Aerosol absorption

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    black carbon refractive indices, new cloud radiative properties considering the effect of aerosol absorption and radiative forcing. The effect of the usage of more accurate effective medium approximations radiative properties re- sults in a small global annual-mean all-sky absorption of 0.05 W m-2 and a positive

  13. Optical absorption of silicon nanowires

    SciTech Connect (OSTI)

    Xu, T. [Key Laboratory of Advanced Display and System Application, Shanghai University, 149 Yanchang Road, Shanghai 200072 (China); Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France); Lambert, Y.; Krzeminski, C.; Grandidier, B.; Stievenard, D.; Leveque, G.; Akjouj, A.; Pennec, Y.; Djafari-Rouhani, B. [Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France)

    2012-08-01T23:59:59.000Z

    We report on simulations and measurements of the optical absorption of silicon nanowires (NWs) versus their diameter. We first address the simulation of the optical absorption based on two different theoretical methods: the first one, based on the Green function formalism, is useful to calculate the scattering and absorption properties of a single or a finite set of NWs. The second one, based on the finite difference time domain (FDTD) method, is well-adapted to deal with a periodic set of NWs. In both cases, an increase of the onset energy for the absorption is found with increasing diameter. Such effect is experimentally illustrated, when photoconductivity measurements are performed on single tapered Si nanowires connected between a set of several electrodes. An increase of the nanowire diameter reveals a spectral shift of the photocurrent intensity peak towards lower photon energies that allow to tune the absorption onset from the ultraviolet radiations to the visible light spectrum.

  14. In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}

    SciTech Connect (OSTI)

    Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

    2013-07-15T23:59:59.000Z

    The local structure of nanoscale (?10–40 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests Li–Co site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: • A new method is developed to understand capacity fade in Li-ion battery cathodes. • Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. • Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. • Full multiple scattering calculations are used to support ?? analysis.

  15. Eta absorption by mesons

    E-Print Network [OSTI]

    W. Liu; C. M. Ko; L. W. Chen

    2005-12-12T23:59:59.000Z

    Using the $[SU(3)_{\\mathrm{L}} \\times SU(3)_{\\mathrm{R}}]_{\\mathrm{global}% }\\times [SU(3)_V]_{\\mathrm{local}}$ chiral Lagrangian with hidden local symmetry, we evaluate the cross sections for the absorption of eta meson ($% \\eta$) by pion ($\\pi$), rho ($\\rho$), omega ($\\omega$), kaon ($K$), and kaon star ($K^*$) in the tree-level approximation. With empirical masses and coupling constants as well as reasonable values for the cutoff parameter in the form factors at interaction vertices, we find that most cross sections are less than 1 mb, except the reactions $\\rho\\eta\\to K\\bar K^*(\\bar KK^*)$, $\\omega\\eta\\to K\\bar K^*(\\bar KK^*)$, $K^*\\eta\\to\\rho K$, and $K^*\\eta\\to\\omega K$, which are a few mb, and the reactions $\\pi\\eta\\to K\\bar K$ and $K\\eta\\to\\pi K$, which are more than 10 mb. Including these reactions in a kinetic model based on a schematic hydrodynamic description of relativistic heavy ion collisions, we find that the abundance of eta mesons likely reaches chemical equilibrium with other hadrons in nuclear collisions at the Relativistic Heavy Ion Collider.

  16. Microwave absorptions of ultrathin conductive films and designs of frequency-independent ultrathin absorbers

    SciTech Connect (OSTI)

    Li, Sucheng; Anwar, Shahzad; Lu, Weixin; Hang, Zhi Hong; Hou, Bo, E-mail: houbo@suda.edu.cn, E-mail: phyhoubo@gmail.com; Shen, Mingrong [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China)] [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Wang, Chin-Hua [Institute of Modern Optical Technologies and Collaborative Innovation Center of Suzhou Nano Science and Technology, Jiangsu Key Lab of Advanced Optical Manufacturing Technologies, Soochow University, 1 Shizi Street, Suzhou 215006 (China)] [Institute of Modern Optical Technologies and Collaborative Innovation Center of Suzhou Nano Science and Technology, Jiangsu Key Lab of Advanced Optical Manufacturing Technologies, Soochow University, 1 Shizi Street, Suzhou 215006 (China)

    2014-01-15T23:59:59.000Z

    We study the absorption properties of ultrathin conductive films in the microwave regime, and find a moderate absorption effect which gives rise to maximal absorbance 50% if the sheet (square) resistance of the film meets an impedance matching condition. The maximal absorption exhibits a frequency-independent feature and takes place on an extremely subwavelength scale, the film thickness. As a realistic instance, ?5 nm thick Au film is predicted to achieve the optimal absorption. In addition, a methodology based on metallic mesh structure is proposed to design the frequency-independent ultrathin absorbers. We perform a design of such absorbers with 50% absorption, which is verified by numerical simulations.

  17. Mg/Ti multilayers: Structural and hydrogen absorption properties A. Baldi,1,2,* G. K. Plsson,3 M. Gonzalez-Silveira,1 H. Schreuders,2 M. Slaman,1,2 J. H. Rector,1 G. Krishnan,4

    E-Print Network [OSTI]

    Wijngaarden, Rinke J.

    of hydrogen in Mg and Ti, as shown by diffusion calculations on a model multilayered systems. Absorption strongly bonded Mg/Pd and broken Mg/Ti interfaces. DOI: 10.1103/PhysRevB.81.224203 PACS number s : 68.65.Ac I. INTRODUCTION Magnesium and titanium are immiscible. Metastable Mg-Ti alloys have nevertheless

  18. Achieving progressive fine granularity scalable coding in H.26L

    E-Print Network [OSTI]

    Shanmugampillai, Muthukumar

    2001-01-01T23:59:59.000Z

    Fine granularity scalable (FGS) coding and progressive fine granularity scalable (PFGS) coding are novel scalable video schemes which are ideally suited for streaming multimedia over networks with varying bandwidth, network conditions and receiver...

  19. How Nature Fine Tunes Protein Stability

    E-Print Network [OSTI]

    Wickstrom, Megan

    2007-07-14T23:59:59.000Z

    UNDERGRADUATE RESEARCH FELLOWS April 2007 Major: Biology ii ABSTRACT How Nature Fine Tunes Protein Stability (April 2007) Megan Wickstrom Department of Biology Texas A&M University Fellows Co-Advisors: Dr. C. Nick Pace Department of Medical Biochemistry... appreciate their loving support. Also, this thesis is dedicated to my fiancé who has been a constant source of motivation and inspiration. v ACKNOWLEDGMENTS I wish to express my sincere thanks and appreciation to my supervisor and mentor, Dr. C. Nick Pace...

  20. Process for treating moisture laden coal fines

    DOE Patents [OSTI]

    Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

    1993-01-01T23:59:59.000Z

    A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

  1. absorptivity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    confondre Absorption Adsorption Mathematics Websites Summary: Ne pas confondre Absorption Adsorption et Quand des molcules sont amenes en contact avec un'attachent...

  2. Thorium nanochemistry: the solution structure of the Th(IV)?hydroxo pentamer

    SciTech Connect (OSTI)

    Walther, Clemens; Rothe, Jörg; Schimmelpfennig, Bernd; Fuss, Markus (Karlsruher)

    2012-10-10T23:59:59.000Z

    Tetravalent thorium exhibits a strong tendency towards hydrolysis and subsequent polymerization. Polymeric species play a crucial role in understanding thorium solution chemistry, since their presence causes apparent solubility several orders of magnitude higher than predicted by thermodynamic data bases. Although electrospray mass spectrometry (ESI MS) identifies Th(IV) dimers and pentamers unequivocally as dominant species close to the solubility limit, the molecular structure of Th{sub 5}(OH){sub y} polymers was hitherto unknown. In the present study, X-ray absorption fine structure (XAFS) spectroscopy, high energy X-ray scattering (HEXS) measurements, and quantum chemical calculations are combined to solve the pentamer structure. The most favourable structure is represented by two Th(IV) dimers linked by a central Th(IV) cation through hydroxide bridges.

  3. Structure in multilayer films of zinc sulfide and copper sulfide via atomic layer deposition

    SciTech Connect (OSTI)

    Short, Andrew; Jewell, Leila; Bielecki, Anthony; Keiber, Trevor; Bridges, Frank; Carter, Sue; Alers, Glenn, E-mail: galers@ucsc.edu [Department of Physics, University of California at Santa Cruz, 1156 High Street, Santa Cruz, California 95064 (United States)

    2014-01-15T23:59:59.000Z

    Multilayer film stacks of ZnS and Cu{sub x}S (x???2) were made via atomic layer deposition. The precursors were bis(2,2,6,6-tetramethyl-3,5-heptanedionato)zinc, bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper, and H{sub 2}S generated in situ for sulfur. Samples were deposited at 200?°C, in layers ranging from approximately 2 to 20 nm thick, based on binary growth rates. The properties of the film stacks were studied with atomic force microscopy, ultraviolet–visible spectroscopy, and extended x-ray absorption fine structure. The results demonstrate that the structure of films with the thinnest layers is dominated by Cu{sub x}S, whereas in the thicker films, the structure is determined by whichever material is first deposited. This can be attributed to the crystal structure mismatch of ZnS and Cu{sub x}S.

  4. Effect of Mn Concentration on the Structural, optical and Magnetic Properties of GaMnN

    SciTech Connect (OSTI)

    Thaler, G.; Frazier, R.; Gila, B.; Stapleton, J.; Davidson, M.; Abernathy, C.R.; Pearton, S.J.; Segre, C.U. (IIT); (Florida)

    2010-11-16T23:59:59.000Z

    The room temperature magnetization of GaMnN films grown by molecular beam epitaxy on (0001) sapphire substrates with Mn concentrations varying from 0 to 9 at. % was found to depend on Mn concentration, with a maximum magnetization found at -3 at. % Mn. High-resolution x-ray diffraction measurements show that the c-plane lattice constant initially decreases with increasing Mn concentration, then increases when the Mn content increases above -3 at. %. This increase is accompanied by a decrease in the full width at half maximum of the rocking curves. Extended x-ray absorption fine structure results indicate that the nonsubstitutional Mn is not present in the form of Ga{sub x}Mn{sub y} clusters and thus is most likely present in the form of an interstitial. Optical absorption measurements show only a slight increase in the band gap for material with 3 at. % Mn, relative to undoped GaN.

  5. The fine-structure constant and wavelength calibration

    E-Print Network [OSTI]

    Whitmore, Jonathan

    2011-01-01T23:59:59.000Z

    the Calibration . . . . . . . . . . . . . . . . . . . .Convolution . . . . . . . . . . . . . . Calibration Shift3.4 Degree Polynomial Calibration Effects . . . . . . . 3.5

  6. The fine-structure constant and wavelength calibration

    E-Print Network [OSTI]

    Whitmore, Jonathan

    2011-01-01T23:59:59.000Z

    82, 888 Edl´en, B. 1966, Metrologia, 2, 71 Flambaum, V. V.82, 888 Edl´en, B. 1966, Metrologia, 2, 71 Flambaum, V. V.82, 888 Edl´en, B. 1966, Metrologia, 2, 71 Flambaum, V. V.

  7. Fine structure in the gamma-ray sky

    E-Print Network [OSTI]

    A. D. Erlykin; A. W. Wolfendale

    2006-05-17T23:59:59.000Z

    The EGRET results for gamma-ray intensities in and near the Galactic Plane have been analysed in some detail. Attention has been concentrated on energies above 1 GeV and the individual intensities in a $4^\\circ$ longitude bin have been determined and compared with the large scale mean found from a nine-degree polynomial fit. Comparison has been made of the observed standard deviation for the ratio of these intensities with that expected from variants of our model. The basic model adopts cosmic ray origin from supernova remnants, the particles then diffusing through the Galaxy with our usual 'anomalous diffusion'. The variants involve the clustering of SN, a frequency distribution for supernova explosion energies, and 'normal', rather than 'anomalous' diffusion. It is found that for supernovae of unique energy, and our usual anomalous diffusion, clustering is necessary, particularly in the Inner Galaxy. An alternative, and preferred, situation is to adopt the model with a frequency distribution of supernova energies. The results for the Outer Galaxy are such that no clustering is required.

  8. FOURIER ANALYSIS OF EXTENDED FINE STRUCTURE WITH AUTOREGRESSIVE PREDICTION

    E-Print Network [OSTI]

    Barton, J.

    2008-01-01T23:59:59.000Z

    ~ E. O. Brigham, The Fast Fourier Englewood Cliffs~ N.J. ~and sidelobe ratios for Fourier weighting functions. For aof ~k, the full width of the Fourier amplitude mainlobe for

  9. alpha fine structure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interlaced by concentrations of stronger magnetic field at the interface between the umbra and the outer field-free atmosphere. Calculated synthetic images show dark cores like...

  10. anomalous fine structure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interlaced by concentrations of stronger magnetic field at the interface between the umbra and the outer field-free atmosphere. Calculated synthetic images show dark cores like...

  11. Evidence for Fine Structure in the Chromospheric Umbral Oscillation

    E-Print Network [OSTI]

    R. Centeno; H. Socas-Navarro; M. Collados; J. Trujillo Bueno

    2005-10-26T23:59:59.000Z

    Novel spectro-polarimetric observations of the \\ion{He}{1} multiplet are used to explore the dynamics of the chromospheric oscillation above sunspot umbrae. The results presented here provide strong evidence in support of the two-component model proposed by Socas-Navarro and co-authors. According to this model, the waves propagate only inside channels of sub-arcsecond width (the ``active'' component), whereas the rest of the umbra remains nearly at rest (the ``quiet'' component). Although the observations support the fundamental elements of that model, there is one particular aspect that is not compatible with our data. We find that, contrary to the scenario as originally proposed, the active component remains through the entire oscillation cycle and harbors both the upflowing and the downflowing phase of the oscillation.

  12. New Measurement Explores Fine Details of Proton Structure | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy:Nanowire Solar541,9337, 2011R - 445 CU -Standards Began

  13. Mid-and far-infrared fine-structure-line sensitivities to hypothetical variability of the fine-structure constant

    E-Print Network [OSTI]

    Kozlov, Mikhail G

    optical observations / 10-5 , and to suppress considerably systematic errors of the radial velocity measurements caused by the Doppler noise. Moreover, the far infrared lines can be observed at redshifts z 10 shifts caused by the motion of the object and by the putative effect of the variability of con- stants

  14. Near-infrared free carrier absorption in heavily doped silicon

    SciTech Connect (OSTI)

    Baker-Finch, Simeon C., E-mail: simeon.bakerfinch@gmail.com [School of Engineering, Australian National University, Canberra, ACT 0200 (Australia); PV Lighthouse, Coledale, NSW 2515 (Australia); McIntosh, Keith R. [PV Lighthouse, Coledale, NSW 2515 (Australia); Yan, Di; Fong, Kean Chern; Kho, Teng C. [School of Engineering, Australian National University, Canberra, ACT 0200 (Australia)

    2014-08-14T23:59:59.000Z

    Free carrier absorption in heavily doped silicon can have a significant impact on devices operating in the infrared. In the near infrared, the free carrier absorption process can compete with band to band absorption processes, thereby reducing the number of available photons to optoelectronic devices such as solar cells. In this work, we fabricate 18 heavily doped regions by phosphorus and boron diffusion into planar polished silicon wafers; the simple sample structure facilitates accurate and precise measurement of the free carrier absorptance. We measure and model reflectance and transmittance dispersion to arrive at a parameterisation for the free carrier absorption coefficient that applies in the wavelength range between 1000 and 1500?nm, and the range of dopant densities between ?10{sup 18} and 3?×?10{sup 20}?cm{sup ?3}. Our measurements indicate that previously published parameterisations underestimate the free carrier absorptance in phosphorus diffusions. On the other hand, published parameterisations are generally consistent with our measurements and model for boron diffusions. Our new model is the first to be assigned uncertainty and is well-suited to routine device analysis.

  15. Transient absorption spectroscopy of laser shocked explosives

    SciTech Connect (OSTI)

    Mcgrane, Shawn D [Los Alamos National Laboratory; Dang, Nhan C [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolome, Cindy A [Los Alamos National Laboratory; Moore, D S [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

  16. Absorption-heat-pump system

    DOE Patents [OSTI]

    Grossman, G.; Perez-Blanco, H.

    1983-06-16T23:59:59.000Z

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  17. Quasistellar Objects: Intervening Absorption Lines

    E-Print Network [OSTI]

    Jane C. Charlton; Christopher W. Churchill

    2000-05-31T23:59:59.000Z

    We briefly review, at a level appropriate for graduate students and non-specialists, the field of quasar absorption lines (QALs). Emphasis is on the intervening absorbers. We present the anatomy of a quasar spectrum due to various classes of intervening absorption systems, and a brief historical review of each absorber class (Lyman-alpha forest and Lyman limit systems, and metal-line and damped Lyman-alpha absorbers). We also provide several heuristic examples on how the physical properties of both the intergalactic medium and the gaseous environments associated with earlier epoch galaxies can be inferred from QALs. The evolution of these environments from z=4 are discussed.

  18. Saturable absorption and 'slow light'

    E-Print Network [OSTI]

    Adrian C Selden

    2006-03-25T23:59:59.000Z

    Quantitative evaluation of some recent 'slow light' experiments based on coherent population oscillations (CPO) shows that they can be more simply interpreted as saturable absorption phenomena. Therefore they do not provide an unambiguous demonstration of 'slow light'. Indeed a limiting condition on the spectral bandwidth is not generally satisfied, such that the requirements for burning a narrow spectral hole in the homogeneously broadened absorption line are not met. Some definitive tests of 'slow light' phenomena are suggested, derived from analysis of phase shift and pulse delay for a saturable absorber

  19. Simulations of solar cell absorption enhancement using resonant modes of a nanosphere array

    E-Print Network [OSTI]

    Grandidier, Jonathan

    Simulations of solar cell absorption enhancement using resonant modes of a nanosphere array an approach for enhancing the absorption of thin-film amorphous silicon solar cells using periodic on the temporal coupled mode theory. Keywords: Resonant Dielectric Structures, Solar cells, Nanospheres

  20. Gyrotropic-nihility state in a composite ferrite-semiconductor structure

    E-Print Network [OSTI]

    Tuz, Vladimir R

    2014-01-01T23:59:59.000Z

    Characteristics of the gyrotropic-nihility state are studied in a finely-stratified ferrite-semiconductor structure, which is under an action of an external static magnetic field. Investigations are carried out with the assistance of the effective medium theory, according to which the studied structure is approximated as a uniform gyroelectromagnetic medium. The theory of the gyrotropic-nihility state is developed in terms of the eigenwaves propagation in such gyroelectromagnetic medium. The frequency and angular dependencies of the transmittance, reflectance and absorption coefficient are presented. It turns out that in the frequency band around the frequency of gyrotropic-nihility state the studied structure appears to be matched to free space with both the refractive index and the wave impedance which results in its high transmittance almost in the entire range of angles of the electromagnetic wave incidence.

  1. H I ABSORPTION TOWARD H II REGIONS AT SMALL GALACTIC LONGITUDES

    SciTech Connect (OSTI)

    Jones, C.; Dickey, J. M.; Dawson, J. R. [School of Mathematics and Physics, Private Bag 37, University of Tasmania, Hobart 7001 (Australia); McClure-Griffiths, N. M. [CSIRO Astronomy and Space Science, ATNF, P.O. Box 76, Epping, NSW 1710 (Australia); Anderson, L. D. [Department of Physics, West Virginia University, Morgantown, WV 26506 (United States); Bania, T. M. [Institute for Astrophysical Research, Department of Astronomy, Boston University, 725 Commonwealth Avenue, Boston, MA 02215 (United States)

    2013-09-10T23:59:59.000Z

    We make a comprehensive study of H I absorption toward H II regions located within |l| < 10 Degree-Sign . Structures in the extreme inner Galaxy are traced using the longitude-velocity space distribution of this absorption. We find significant H I absorption associated with the Near and Far 3 kpc Arms, the Connecting Arm, Bania's Clump 1, and the H I Tilted Disk. We also constrain the line-of-sight distances to H II regions, by using H I absorption spectra together with the H II region velocities measured by radio recombination lines.

  2. Symmetrical and anti-symmetrical coherent perfect absorption for acoustic waves

    SciTech Connect (OSTI)

    Wei, Pengjiang; Croënne, Charles; Tak Chu, Sai [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Li, Jensen, E-mail: j.li@bham.ac.uk [School of Physics and Astronomy, University of Birmingham, Birmingham B15 2TT (United Kingdom)

    2014-03-24T23:59:59.000Z

    We investigate tunable acoustic absorption enabled by the coherent control of input waves. It relies on coherent perfect absorption originally proposed in optics. By designing appropriate acoustic metamaterial structures with resonating effective bulk modulus or density, we show that complete absorption of incident waves impinging on the metamaterial can be achieved for either symmetrical or anti-symmetrical inputs in the forward and backward directions. By adjusting the relative phase between the two incident beams, absorption can be tuned effectively from unity to zero, making coherent control useful in applications like acoustic modulators, noise controllers, transducers, and switches.

  3. Ne pas confondre Absorption Adsorption

    E-Print Network [OSTI]

    Liège, Université de

    Ne pas confondre Absorption Adsorption et Quand des molécules sont amenées en contact avec un'attachent simplement à la surface du solide on parle d'adsorption. L'adsorption est donc le « collage » de molécules à la surface d'un solide. Quand le charbon nettoie Principes physiques de l'adsorption Cédric Gommes

  4. Ultrasonic absorption in liquid mixtures

    E-Print Network [OSTI]

    Davis, James Madison

    1954-01-01T23:59:59.000Z

    snd water and of methanol and water, Since Storey's work on ethanol and water at 0 C showed that for the three different frequencies at, which his investigation wms carried outx the ratio of ths absorption to the frequency squared increased...

  5. Interferometric tunability of the absorption

    E-Print Network [OSTI]

    Vittorio Giovannetti; Seth Lloyd; Lorenzo Maccone

    2006-03-27T23:59:59.000Z

    We propose an interferometric setup that permits to tune the quantity of radiation absorbed by an object illuminated by a fixed light source. The method can be used to selectively irradiate portions of an object based on their transmissivities or to accurately estimate the transmissivities from rough absorption measurements.

  6. Observation of scattering and absorption centers in lead fluoride crystals

    E-Print Network [OSTI]

    Patrick Achenbach

    2006-06-22T23:59:59.000Z

    For the first time, lead fluoride is used as a fast and compact material in electromagnetic calorimetry. Excellent optical and mechanical properties of the pure Cherenkov crystals are necessary for the A4 collaboration to perform a measurement of the nucleon's strange form factors. Visible scattering and absorption centers as well as surface damages have been investigated to characterize the quality of more than one thousand crystals. Besides, transmittance measurements have been performed on all crystals to reveal absorption bands produced by intrinsic or impurity related point-structure defects. As a consequence, 89 crystals had to be replaced by the Chinese manufacturer SICCAS.

  7. active fine particulates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  8. airborne fine particulate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  9. ambient fine particulate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

  10. Solving the structure of disordered mixed salts

    SciTech Connect (OSTI)

    Frenkel, A. (School of Physics and Astronomy, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978 (Israel)); Stern, E.A. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States)); Voronel, A. (School of Physics and Astronomy, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978 (Israel)); Qian, M. (Princeton Materials Institute, Princeton University, Princeton, New Jersey 08540 (United States)); Newville, M. (Department of Physics FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1994-05-01T23:59:59.000Z

    A detailed x-ray-absorption fine-structure (XAFS) investigation of two mixed alkali halides Rb[sub 0.76]K[sub 0.24]Br and RbBr[sub 0.62]Cl[sub 0.38] was performed. The concentrations of the mixtures had been chosen to produce a single homogeneous phase for each, and it was checked by XAFS that the salts were randomly mixed on the atomic level. Detailed analysis of the data including multiple-scattering contributions revealed an rms buckling angular deviation of both mixtures from the average NaCl collinear structure of 7--9[degree]. The angles are defined by three atomic positions determined through double- and triple-scattering paths. These angles are new parameters which should be added to characterize the buckled crystals. Adding to diffraction results the parameters determined from XAFS as input into a molecular-dynamics simulation the structures of the mixed salts with their fluctuations about the NaCL structure are solved and displayed.

  11. Studies of selected transuranium and lanthanide triiodides under pressure using absorption spectrophotometry

    SciTech Connect (OSTI)

    Haire, R.G.; Young, J.P.; Peterson, J.R.; Benedict, U.

    1986-01-01T23:59:59.000Z

    The anhydrous triiodides of plutonium, americium, and curium under pressure have been investigated using absorption spectrophotometry. These initial studies on plutonium and curium triiodides together with the published data for americium triiodide show that the rhombohedral (BiI/sub 3/-type structure) form of these compounds can be converted to the same orthorhombic (PuBr/sub 3/-type structure) form by applying pressure at room temperature. Absorption spectrophotometry can often differentiate between two crystallographic forms of materials and has been used in the present high pressure studies to monitor the effects of pressure on the triiodides. A complication in these studies of the triiodides is a significant shift of their absorption edges from the near uv to the visible spectral region with pressure. With curium triiodide this shift causes interference with the major f-f absorption peaks and precludes identification by absorption spectrophotometry of the high pressure phase of CmI/sub 3/. 21 refs., 2 figs.

  12. Energy Saving with Absorption Refrigeration Technologies

    E-Print Network [OSTI]

    Davis, R. C.

    1984-01-01T23:59:59.000Z

    Absorption refrigeration technology can be an economical and cost effective means of reducing energy cost and/or improving the efficiency and output of your process. We believe the potential benefits of absorption refrigeration technology have...

  13. Opacity of iron, nickel, and copper plasmas in the x-ray wavelength range: Theoretical interpretation of 2p-3d absorption spectra

    SciTech Connect (OSTI)

    Blenski, T.; Loisel, G.; Poirier, M.; Thais, F.; Arnault, P.; Caillaud, T.; Fariaut, J.; Gilleron, F.; Pain, J.-C.; Porcherot, Q.; Reverdin, C.; Silvert, V.; Villette, B.; Bastiani-Ceccotti, S.; Turck-Chieze, S.; Foelsner, W.; Gaufridy de Dortan, F. de [CEA, IRAMIS, Service 'Photons, Atomes et Molecules', Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); CEA, DAM, DIF, F-91297 Arpajon (France); LULI, UMR No. 7605 CNRS - Ecole Polytechnique, F-91128 Palaiseau Cedex (France); CEA, IRFU, Service d'Astrophysique, Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); Max-Planck-Institut fuer Quantenoptik, D-85748 Garching (Germany); Institute of Nuclear Fusion, Universidad Politecnica de Madrid, Spain and Laboratoire d'Optique Appliquee, ENSTA-Paritech-Polytechnique, Chemin de la Huniere, F-91671 Palaiseau (France)

    2011-09-15T23:59:59.000Z

    This paper deals with theoretical studies on the 2p-3d absorption in iron, nickel, and copper plasmas related to LULI2000 (Laboratoire pour l'Utilisation des Lasers Intenses, 2000J facility) measurements in which target temperatures were of the order of 20 eV and plasma densities were in the range 0.004-0.01 g/cm{sup 3}. The radiatively heated targets were close to local thermodynamic equilibrium (LTE). The structure of 2p-3d transitions has been studied with the help of the statistical superconfiguration opacity code sco and with the fine-structure atomic physics codes hullac and fac. A new mixed version of the sco code allowing one to treat part of the configurations by detailed calculation based on the Cowan's code rcg has been also used in these comparisons. Special attention was paid to comparisons between theory and experiment concerning the term features which cannot be reproduced by sco. The differences in the spin-orbit splitting and the statistical (thermal) broadening of the 2p-3d transitions have been investigated as a function of the atomic number Z. It appears that at the conditions of the experiment the role of the term and configuration broadening was different in the three analyzed elements, this broadening being sensitive to the atomic number. Some effects of the temperature gradients and possible non-LTE effects have been studied with the help of the radiative-collisional code scric. The sensitivity of the 2p-3d structures with respect to temperature and density in medium-Z plasmas may be helpful for diagnostics of LTE plasmas especially in future experiments on the {Delta}n=0 absorption in medium-Z plasmas for astrophysical applications.

  14. Absorption properties of identical atoms

    E-Print Network [OSTI]

    Pedro Sancho

    2013-07-31T23:59:59.000Z

    Emission rates and other optical properties of multiparticle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas.

  15. Thermochemical Analysis of Hydrogen Absorption in Welding

    E-Print Network [OSTI]

    Eagar, Thomas W.

    '' .' j I ~l Thermochemical Analysis of Hydrogen Absorption in Welding A new model that addresses the shortcomings of Sievert's law for predicting hydrogen absorption is proposed ABSTRACT. A systematic review of diatomic hydrogen) to calcu· late the hydrogen absorption reaction temperature in the weld pool is invalid

  16. Absorption cross section in Lifshitz black hole

    E-Print Network [OSTI]

    Taeyoon Moon; Yun Soo Myung

    2012-10-05T23:59:59.000Z

    We derive the absorption cross section of a minimally coupled scalar in the Lifshitz black hole obtained from the new massive gravity. The absorption cross section reduces to the horizon area in the low energy and massless limit of s-wave mode propagation, indicating that the Lifshitz black hole also satisfies the universality of low energy absorption cross section for black holes.

  17. Effects of self-irradiation on local crystal structure and 5flocalization in PuCoGa5

    SciTech Connect (OSTI)

    Booth, C.H.; Daniel, M.; Wilson, R.E.; Bauer, E.D.; Mitchell,J.N.; Moreno, N.O.; Morales, L.A.; Sarrao, J.L.; Allen, P.G.

    2006-10-20T23:59:59.000Z

    The 18.5 K superconductor PuCoGa{sub 5} has many unusual properties, including those due to damage induced by self-irradiation. The superconducting transition temperature decreases sharply with time, suggesting a radiation-induced Frenkel defect concentration much larger than predicted by current radiation damage theories. Extended x-ray absorption fine-structure measurements demonstrate that while the local crystal structure in fresh material is well ordered, aged material is disordered much more strongly than expected from simple defects, consistent with strong disorder throughout the damage cascade region. These data highlight the potential impact of local lattice distortions relative to defects on the properties of irradiated materials and underscore the need for more atomic-resolution structural comparisons between radiation damage experiments and theory.

  18. Calcium silicate insulation structure

    DOE Patents [OSTI]

    Kollie, Thomas G. (Oak Ridge, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01T23:59:59.000Z

    An insulative structure including a powder-filled evacuated casing utilizes a quantity of finely divided synthetic calcium silicate having a relatively high surface area. The resultant structure-provides superior thermal insulating characteristics over a broad temperature range and is particularly well-suited as a panel for a refrigerator or freezer or the insulative barrier for a cooler or a insulated bottle.

  19. Electronic structure of nitinol surfaces oxidized by low-energy ion bombardment

    SciTech Connect (OSTI)

    Petravic, M., E-mail: mpetravic@phy.uniri.hr; Varasanec, M.; Peter, R.; Kavre, I. [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Metikos-Hukovic, M. [Department of Electrochemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, 10000 Zagreb (Croatia); Yang, Y.-W. [National Synchrotron Radiation Research Center, Hsinchu 30077, Taiwan (China)

    2014-06-28T23:59:59.000Z

    We have studied the electronic structure of nitinol exposed to low-energy oxygen-ion bombardment, using x-ray photoemission spectroscopy (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy. XPS spectra reveal a gradual transformation of nitinol surfaces into TiO{sub 2} with increased dose of implanted oxygen. No oxidation of Ni atoms has been detected. NEXAFS spectra around O K-edge and Ti L{sub 2,3}-edge, reflecting the element-specific partial density of empty electronic states, exhibit features, which can be attributed to the creation of molecular orbitals, crystal field splitting, and the absence of long-range order, characteristic of the amorphous TiO{sub 2}. Based on these results, we discuss the oxidation kinetics of nitinol under low-energy oxygen-ion bombardment.

  20. Soft X-ray Spectroscopy Study of the Electronic Structure of Oxidized and Partially Oxidized Magnetite Nanoparticles

    SciTech Connect (OSTI)

    Gilbert, Benjamin; Katz, Jordan E.; Denlinger, Jonathan D.; Yin, Yadong; Falcone, Roger; Waychunas, Glenn A.

    2010-10-24T23:59:59.000Z

    The crystal structure of magnetite nanoparticles may be transformed to maghemite by complete oxidation, but under many relevant conditions the oxidation is partial, creating a mixed-valence material with structural and electronic properties that are poorly characterized. We used X-ray diffraction, Fe K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy, and soft X-ray absorption and emission spectroscopy to characterize the products of oxidizing uncoated and oleic acid-coated magnetite nanoparticles in air. The oxidization of uncoated magnetite nanoparticles creates a material that is structurally and electronically indistinguishable from maghemite. By contrast, while oxidized oleic acid-coated nanoparticles are also structurally indistinguishable from maghemite, Fe L-edge spectroscopy revealed the presence of interior reduced iron sites even after a 2-year period. We used X-ray emission spectroscopy at the O K-edge to study the valence bands (VB) of the iron oxide nanoparticles, using resonant excitation to remove the contributions from oxygen atoms in the ligands and from low-energy excitations that obscured the VB edge. The bonding in all nanoparticles was typical of maghemite, with no detectable VB states introduced by the long-lived, reduced-iron sites in the oleic acid-coated sample. However, O K-edge absorption spectroscopy observed a 0.2 eV shift in the position of the lowest unoccupied states in the coated sample, indicating an increase in the semiconductor band gap relative to bulk stoichiometric maghemite that was also observed by optical absorption spectroscopy. The results show that the ferrous iron sites within ferric iron oxide nanoparticles coated by an organic ligand can persist under ambient conditions with no evidence of a distinct interior phase and can exert an effect on the global electronic and optical properties of the material. This phenomenon resembles the band gap enlargement caused by electron accumulation in the conduction band of TiO2.

  1. Advanced regenerative absorption refrigeration cycles

    DOE Patents [OSTI]

    Dao, Kim (14 Nace Ave., Piedmont, CA 94611)

    1990-01-01T23:59:59.000Z

    Multi-effect regenerative absorption cycles which provide a high coefficient of performance (COP) at relatively high input temperatures. An absorber-coupled double-effect regenerative cycle (ADR cycle) (10) is provided having a single-effect absorption cycle (SEA cycle) (11) as a topping subcycle and a single-effect regenerative absorption cycle (1R cycle) (12) as a bottoming subcycle. The SEA cycle (11) includes a boiler (13), a condenser (21), an expansion device (28), an evaporator (31), and an absorber (40), all operatively connected together. The 1R cycle (12) includes a multistage boiler (48), a multi-stage resorber (51), a multisection regenerator (49) and also uses the condenser (21), expansion device (28) and evaporator (31) of the SEA topping subcycle (11), all operatively connected together. External heat is applied to the SEA boiler (13) for operation up to about 500 degrees F., with most of the high pressure vapor going to the condenser (21) and evaporator (31) being generated by the regenerator (49). The substantially adiabatic and isothermal functioning of the SER subcycle (12) provides a high COP. For higher input temperatures of up to 700 degrees F., another SEA cycle (111) is used as a topping subcycle, with the absorber (140) of the topping subcycle being heat coupled to the boiler (13) of an ADR cycle (10). The 1R cycle (12) itself is an improvement in that all resorber stages (50b-f) have a portion of their output pumped to boiling conduits (71a-f) through the regenerator (49), which conduits are connected to and at the same pressure as the highest pressure stage (48a) of the 1R multistage boiler (48).

  2. Improved fluid bed combustor efficiencies through fines recycle

    SciTech Connect (OSTI)

    Rickman, W.S.

    1980-04-01T23:59:59.000Z

    Carbon burnup efficiencies of 99.9% and higher have been attained on a 0.4-MW(t) atmospheric fluid bed combustor with fines recycle. A cyclone and sintered metal filter system separated the fines from the off-gas stream, returning them at 600/sup 0/C (1150/sup 0/F) to the fluid bed. The fines were metered through a unique rotary valve that also served as a pressure boundary between the fluid bed and the fines recycle hopper. Combustor operation was fully automated with a 100-channel process controller and supervisory computer. This high combustion efficiency is especially significant, since the fuel was graphite sized to less than 5 mm (1.3 in.) maximum size. More than 30% of the feed was fine enough to be quickly entrained, placing a substantial burden on the fines recycle system. Detailed modeling techniques were successfully developed to allow prediction of recycle rates and temperatures needed to maintain high combustion efficiency. This model has now been used to analyze coal combustion tests sponsored by Electric Power Research Institute. Surface reaction rate constants were first determined using combustor data taken during cold, low-flow fines recycle tests. These were then used to predict the effect of higher rates of recycle at various temperatures.

  3. DEVELOPMENT OF SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS

    E-Print Network [OSTI]

    Dao, K.

    2013-01-01T23:59:59.000Z

    DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS K. Dao, M.ABSORPTION AIR CONDITIONERS AND HEAT PUMPS* K. DAO, M.

  4. Hazards analysis for the E.O. Lawrence Berkeley National Laboratory x-ray absorption experiments to be performed at Stanford Synchrotron Radiation Laboratory

    SciTech Connect (OSTI)

    Edelstein, N.M.; Shuh, D.K.; Bucher, J.B. [Lawrence Berkeley National Lab., CA (United States). Chemical Sciences Div.

    1995-04-01T23:59:59.000Z

    The objective of this experiment is to determine the oxidation state(s) of neptunium (Np) in mouse skeleton and in soft tissue by X-ray Absorption Near Edge Structure (XANES). If Np is present in sufficient concentration, X-ray Absorption Fine Structure (XAFS) data will be obtained in order to further identify the Np species present. These data will be crucial in understanding the metabolic pathway of Np in mammals which will help in the design of reagents which can eliminate Np from mammals in the event of accidental exposure. It is proposed to run these experiments at the Standard Synchrotron Radiation Laboratory (SSRL). This laboratory is a DOE national user facility located at the Stanford Linear Accelerator Center (SLAC). The {sup 237}Np nucleus decays by the emission of an alpha particle and this particle emission is the principal hazard in handling Np samples. This hazard is mitigated by physical containment of the sample which stops the alpha particles within the containment. The total amount of Np material that will be shipped to and be at SSRL at any one time will be less than 1 gram. This limit on the amount of Np will ensure that SLAC remains a low hazard, non-nuclear facility. The Np samples will be solids or Np ions in aqueous solution. The Np samples will be shipped to SSRL/SLAC OHP. SLAC OHP will inventory the samples and swipe the containers holding the triply contained samples, and then bring them to the SSRL Actinide trailer located outside building 131. The QA counting records from the samples, as measured at LBNL, will be provided to SSRL and SLAC OHP prior to the arrival of the samples at SLAC OHP. In addition, strict monitoring of the storage and experimental areas will be performed in accordance with SLAC/OHP radiation protection procedures to ensure against the release of contamination.

  5. A Finely-Predicted Higgs Boson Mass from A Finely-Tuned Weak Scale

    E-Print Network [OSTI]

    Lawrence J. Hall; Yasunori Nomura

    2009-10-19T23:59:59.000Z

    If supersymmetry is broken directly to the Standard Model at energies not very far from the unified scale, the Higgs boson mass lies in the range 128-141 GeV. The end points of this range are tightly determined. Theories with the Higgs boson dominantly in a single supermultiplet predict a mass at the upper edge, (141 \\pm 2) GeV, with the uncertainty dominated by the experimental errors on the top quark mass and the QCD coupling. This edge prediction is remarkably insensitive to the supersymmetry breaking scale and to supersymmetric threshold corrections so that, in a wide class of theories, the theoretical uncertainties are at the level of \\pm 0.4 GeV. A reduction in the uncertainties from the top quark mass and QCD coupling to the level of \\pm 0.3 GeV may be possible at future colliders, increasing the accuracy of the confrontation with theory from 1.4% to 0.4%. Verification of this prediction would provide strong evidence for supersymmetry, broken at a very high scale of ~ 10^{14 \\pm 2} GeV, and also for a Higgs boson that is elementary up to this high scale, implying fine-tuning of the Higgs mass parameter by ~ 20-28 orders of magnitude. Currently, the only known explanation for such fine-tuning is the multiverse.

  6. Enhanced p-Mode Absorption seen near the Sunspot Umbral-Penumbral Boundary

    E-Print Network [OSTI]

    Shibu K. Mathew

    2008-06-17T23:59:59.000Z

    We investigate p-mode absorption in a sunspot using SOHO/MDI high-resolution Doppler images. The Doppler power computed from a three and a half hour data set is used for studying the absorption in a sunspot. The result shows an enhancement in absorption near the umbral-penumbral boundary of the sunspot. We attempt to relate the observed absorption with the magnetic field structure of the sunspot. The transverse component of the potential field is computed using the observed SOHO/MDI line-of-sight magnetograms. A comparison of the power map and the computed potential field shows enhanced absorption near the umbral-penumbral boundary where the computed transverse field strength is higher.

  7. Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments

    DOE Patents [OSTI]

    Kansa, Edward J. (Livermore, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

    1997-01-01T23:59:59.000Z

    The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculents and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude.

  8. Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments

    DOE Patents [OSTI]

    Kansa, E.J.; Wijesinghe, A.M.; Viani, B.E.

    1997-01-14T23:59:59.000Z

    The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculants and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude. 8 figs.

  9. HI emission and absorption in nearby, gas-rich galaxies

    E-Print Network [OSTI]

    Reeves, S N; Allison, J R; Koribalski, B S; Curran, S J; Pracy, M B

    2015-01-01T23:59:59.000Z

    We present the results of a targeted search for intervening HI absorption in six nearby, gas-rich galaxies using the Australia Telescope Compact Array (ATCA). The sightlines searched have impact parameters of 10-20 kpc. By targeting nearby galaxies we are also able to map their HI emission, allowing us to directly relate the absorption-line detection rate to the extended HI distribution. The continuum sightlines intersect the HI disk in four of the six galaxies, but no intervening absorption was detected. Of these four galaxies, we find that three of the non-detections are the result of the background source being too faint. In the fourth case we find that the ratio of the spin temperature to the covering factor ($T_{\\mathrm{S}}/f$) must be much higher than expected ($\\gtrsim$5700 K) in order to explain the non-detection. We discuss how the structure of the background continuum sources may have affected the detection rate of HI absorption in our sample, and the possible implications for future surveys. Future...

  10. Bachelor of Fine Arts Lindsey Michelle Allen, Art

    E-Print Network [OSTI]

    Gering, Jon C.

    Bachelor of Fine Arts Lindsey Michelle Allen, Art Todd Christopher Baran, Art Mindy Lynnette Bryant Emily Dian Buford, Psychology Brennen Gail Bushnell, English Andrea Jeanne Calvin, English Erica Marie

  11. AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL

    SciTech Connect (OSTI)

    K. Osseo-Asare; X. Zeng

    2002-01-01T23:59:59.000Z

    The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

  12. FINE VARIATION AND FRACTAL MEASURES G. A. Edgar

    E-Print Network [OSTI]

    Edgar, Gerald

    FINE VARIATION AND FRACTAL MEASURES G. A. Edgar The Ohio State University revised October, 1994. EDGAR density results are proved for this setting. This paper may be considered a counter­ part of [7

  13. MICROSTRUCTURE AND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE PRECIPITATES

    E-Print Network [OSTI]

    Gau, J.S.

    2014-01-01T23:59:59.000Z

    and Properties of Dual-Phase Steels, R. A. Kot and J. W.of Niobium Microalloyed Dual- Phase Steel, MetallurgicalAND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE

  14. Microsoft Word - Finely_NorthValley_CX.docx

    Broader source: Energy.gov (indexed) [DOE]

    Manager - KEWM-4 Proposed Action: Finely Creek and North Valley Creek property funding Fish and Wildlife Project No. and Contract No.: 2002-003-00, BPA-58888 Categorical Exclusion...

  15. Modified approaches for high pressure filtration of fine clean coal

    SciTech Connect (OSTI)

    Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

    1995-12-31T23:59:59.000Z

    Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

  16. Deadlock-free fine-grained thread migration

    E-Print Network [OSTI]

    Cho, Myong Hyon

    Several recent studies have proposed fine-grained, hardware-level thread migration in multicores as a solution to power, reliability, and memory coherence problems. The need for fast thread migration has been well documented, ...

  17. Combining Feedback Absorption Spectroscopy, Amplified Resonance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Compounds in Automotive Emissions Discusses a novel combination of multi-component scanning direct absorption spectroscopy, resonant cavity and low-pressure sampling to...

  18. Direct and quantitative absorptive spectroscopy of nanowires

    E-Print Network [OSTI]

    Tong, Jonathan Kien-Kwok

    2012-01-01T23:59:59.000Z

    Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

  19. Advanced Low Temperature Absorption Chiller Module Integrated...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Low Temperature Absorption Chiller Module Integrated with a CHP System at a Distributed Data Center - Presentation by Exergy Partners Corp., June 2011 Advanced Low...

  20. Effect of morphology and solvent on two-photon absorption of nano zinc oxide

    SciTech Connect (OSTI)

    Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

    2013-05-15T23:59:59.000Z

    Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

  1. Local structure underlying anomalous tetragonal distortions in BiFeO{sub 3}-PbTiO{sub 3} ferroelectrics

    SciTech Connect (OSTI)

    Levin, I.; Krayzman, V.; Woicik, J. C. [Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Tucker, M. G. [ISIS Facility, Rutherford Appleton Laboratory, Didcot (United Kingdom)

    2014-06-16T23:59:59.000Z

    The local structure of tetragonal BiFeO{sub 3}-PbTiO{sub 3} solid solutions featuring anomalous lattice distortions has been determined using simultaneous fitting of neutron total scattering and extended X-ray absorption fine structure data. On the local scale, the large tetragonal distortion, promoted by the displacements of the A-cations (Bi and Pb), is accommodated primarily by the [FeO{sub 6}] octahedra, even though both Fe and Ti acquire (5+1)-fold coordination. Bi cations exhibit considerably larger displacements than Pb. The combination of the A-cation displacements and the ability of M-cations to adopt 5-fold coordination is suggested as key for stabilizing the large tetragonality in BiMO{sub 3}-PbTiO{sub 3} systems.

  2. INCREASED LEAD ABSORPTION AND LEAD POISONING

    E-Print Network [OSTI]

    INCREASED LEAD ABSORPTION AND LEAD POISONING IN YOUNG CHILDREN A STATDIE:"IT BY THE CEJde slnt:t! the Surgeon GenerJi's Statement. "~edicJI Aspects of Childhood Lead POisoning," was issued:ld absorption Jnd lead poisoning. Such JCtivities for children will continue to be necessary until sources

  3. Broadband solar absorption enhancement via periodic

    E-Print Network [OSTI]

    Province, 230009, P. R. China. Solution processed colloidal quantum dot (CQD) solar cells have greatBroadband solar absorption enhancement via periodic nanostructuring of electrodes Michael M. Adachi demonstrate a bottom- illuminated periodic nanostructured CQD solar cell that enhances broadband absorption

  4. Lyman-alpha Absorption from Heliosheath Neutrals

    E-Print Network [OSTI]

    Brian E. Wood; Vladislav V. Izmodenov; Jeffrey L. Linsky; Yury G. Malama

    2006-11-30T23:59:59.000Z

    We assess what information HST observations of stellar Ly-alpha lines can provide on the heliosheath, the region of the heliosphere between the termination shock and heliopause. To search for evidence of heliosheath absorption, we conduct a systematic inspection of stellar Ly-alpha lines reconstructed after correcting for ISM absorption (and heliospheric/astrospheric absorption, if present). Most of the stellar lines are well centered on the stellar radial velocity, as expected, but the three lines of sight with the most downwind orientations relative to the ISM flow (Chi1 Ori, HD 28205, and HD 28568) have significantly blueshifted Ly-alpha lines. Since it is in downwind directions where heliosheath absorption should be strongest, the blueshifts are almost certainly caused by previously undetected heliosheath absorption. We make an initial comparison between the heliosheath absorption and the predictions of a pair of heliospheric models. A model with a complex multi-component treatment of plasma within the heliosphere predicts less absorption than a model with a simple single-fluid treatment, which leads to better agreement with the data. Finally, we find that nonplanetary energetic neutral atom (ENA) fluxes measured by the ASPERA-3 instrument on board Mars Express, which have been interpreted as being from the heliosheath, are probably too high to be consistent with the relative lack of heliosheath absorption seen by HST. This would argue for a local interplanetary source for these ENAs instead of a heliosheath source.

  5. absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Planning of Axiom Absorptions CiteSeer...

  6. Novel absorption detection techniques for capillary electrophoresis

    SciTech Connect (OSTI)

    Xue, Y.

    1994-07-27T23:59:59.000Z

    Capillary electrophoresis (CE) has emerged as one of the most versatile separation methods. However, efficient separation is not sufficient unless coupled to adequate detection. The narrow inner diameter (I.D.) of the capillary column raises a big challenge to detection methods. For UV-vis absorption detection, the concentration sensitivity is only at the {mu}M level. Most commercial CE instruments are equipped with incoherent UV-vis lamps. Low-brightness, instability and inefficient coupling of the light source with the capillary limit the further improvement of UV-vis absorption detection in CE. The goals of this research have been to show the utility of laser-based absorption detection. The approaches involve: on-column double-beam laser absorption detection and its application to the detection of small ions and proteins, and absorption detection with the bubble-shaped flow cell.

  7. Fine particulate chemical composition and light extinction at Meadview, AZ

    SciTech Connect (OSTI)

    Delbert J. Eatough; Wenxuan Cui; Jeffery Hull; Robert J. Farber [Brigham Young University, Provo, UT (United States). Department of Chemistry and Biochemistry

    2006-12-15T23:59:59.000Z

    The concentration of fine particulate nitrate, sulfate, and carbonaceous material was measured for 12-hr daynight samples using diffusion denuder samplers during the Project Measurement of Haze and Visibility Effects (MOHAVE) July to August 1992 Summer Intensive study at Meadview, AZ, just west of Grand Canyon National Park. Organic material was measured by several techniques. Only the diffusion denuder method measured the semivolatile organic material. Fine particulate sulfate and nitrate (using denuder technology) determined by various groups agreed. Based on the various collocated measurements obtained during the Project MOHAVE study, the precision of the major fine particulate species was {+-} 0.6 {mu}g/m{sup 3} organic material, {+-} 0.3 {mu}g/m{sup 3} ammonium sulfate, and {+-} 0.07 {mu}g/m{sup 3} ammonium nitrate. Fine particulate organic material was the principal particulate contributor to light extinction during the study period, with fine particulate sulfate as the second most important contributor. Particle light extinction was dominated by sulfate and organic material during periods of lowest light extinction. Combination of the extinction data and chemical mass balance analysis of sulfur oxides sources in the region indicate that the major anthropogenic contributors to light extinction were from the Los Angeles, CA, and Las Vegas, NV, urban areas. Mohave Power Project associated secondary sulfate was a negligible contributor to light extinction. 49 refs., 12 figs., 7 tabs.

  8. Absorption spectrum of Ca atoms attached to $^4$He nanodroplets

    E-Print Network [OSTI]

    Alberto Hernando; Manuel Barranco; Marek Kro?nicki; Ricardo Mayol; Martí Pi

    2007-11-12T23:59:59.000Z

    Within density functional theory, we have obtained the structure of $^4$He droplets doped with neutral calcium atoms. These results have been used, in conjunction with newly determined {\\it ab-initio} $^1\\Sigma$ and $^1\\Pi$ Ca-He pair potentials, to address the $4s4p$ $^1$P$_1 \\leftarrow 4s^2$ $^1$S$_0$ transition of the attached Ca atom, finding a fairly good agreement with absorption experimental data. We have studied the drop structure as a function of the position of the Ca atom with respect of the center of mass of the helium moiety. The interplay between the density oscillations arising from the helium intrinsic structure and the density oscillations produced by the impurity in its neighborhood plays a role in the determination of the equilibrium state, and hence in the solvation properties of alkaline earth atoms. In a case of study, the thermal motion of the impurity within the drop surface region has been analyzed in a semi-quantitative way. We have found that, although the atomic shift shows a sizeable dependence on the impurity location, the thermal effect is statistically small, contributing by about a 10% to the line broadening. The structure of vortices attached to the calcium atom has been also addressed, and its effect on the calcium absorption spectrum discussed. At variance with previous theoretical predictions, we conclude that spectroscopic experiments on Ca atoms attached to $^4$He drops will be likely unable to detect the presence of quantized vortices in helium nanodrops.

  9. Recycling of PET bottles as fine aggregate in concrete

    SciTech Connect (OSTI)

    Frigione, Mariaenrica, E-mail: mariaenrica.frigione@unisalento.i [Department of Engineering for Innovation, University of Salento, Via per Monteroni, 73100 Lecce (Italy)

    2010-06-15T23:59:59.000Z

    An attempt to substitute in concrete the 5% by weight of fine aggregate (natural sand) with an equal weight of PET aggregates manufactured from the waste un-washed PET bottles (WPET), is presented. The WPET particles possessed a granulometry similar to that of the substituted sand. Specimens with different cement content and water/cement ratio were manufactured. Rheological characterization on fresh concrete and mechanical tests at the ages of 28 and 365 days were performed on the WPET/concretes as well as on reference concretes containing only natural fine aggregate in order to investigate the influence of the substitution of WPET to the fine aggregate in concrete. It was found that the WPET concretes display similar workability characteristics, compressive strength and splitting tensile strength slightly lower that the reference concrete and a moderately higher ductility.

  10. Lattice complexity and fine graining of symbolic sequence

    E-Print Network [OSTI]

    Da-Guan Ke; Hong Zhang; Qin-Ye Tong

    2008-04-05T23:59:59.000Z

    A new complexity measure named as Lattice Complexity is presented for finite symbolic sequences. This measure is based on the symbolic dynamics of one-dimensional iterative maps and Lempel-Ziv Complexity. To make Lattice Complexity distinguishable from Lempel-Ziv Complexity, an approach called fine-graining process is also proposed. When the control parameter fine-graining order is small enough, the two measures are almost equal. While the order increases, the difference between the two measures becomes more and more significant. Applying Lattice Complexity to logistic map with a proper order, we find that the sequences that are regarded as complex are roughly at the edges of chaotic regions. Further derived properties of the two measures concerning the fine-graining process are also discussed.

  11. Structure and Fine Structure in Multiparticle Production Data at High Energies

    E-Print Network [OSTI]

    Wit Busza

    2004-10-22T23:59:59.000Z

    A summary is given of data on the longitudinal rapidity and pseudorapidity distributions observed in $e^+e^-$, pp, pA and AA collisions at high energies. The remarkable simplicity and universality observed in the data and its relevance to the study of the high energy density system produced in heavy ion collisions is discussed.

  12. Total absorption by degenerate critical coupling

    SciTech Connect (OSTI)

    Piper, Jessica R., E-mail: jrylan@stanford.edu; Liu, Victor; Fan, Shanhui, E-mail: shanhui@stanford.edu [Ginzton Laboratory, Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

    2014-06-23T23:59:59.000Z

    We consider a mirror-symmetric resonator with two ports. We show that, when excited from a single port, complete absorption can be achieved through critical coupling to degenerate resonances with opposite symmetry. Moreover, any time two resonances with opposite symmetry are degenerate in frequency and absorption is always significantly enhanced. In contrast, when two resonances with the same symmetry are nearly degenerate, there is no absorption enhancement. We numerically demonstrate these effects using a graphene monolayer on top of a photonic crystal slab, illuminated from a single side in the near-infrared.

  13. DEVELOPMENT OF SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS

    E-Print Network [OSTI]

    Dao, K.

    2013-01-01T23:59:59.000Z

    SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS K.Driven Absorption Air-Conditioner", K. Dao, M. Simmons, R.SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS* K.

  14. Development of fine-resolution analyses and expanded large-scale forcing properties. Part I: Methodology and evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Zhijin; Vogelmann, Andrew M.; Feng, Sha; Liu, Yangang; Lin, Wuyin; Zhang, Minghua; Toto, Tami; Endo, Satoshi

    2015-01-27T23:59:59.000Z

    We produce fine-resolution, three-dimensional fields of meteorological and other variables for the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) Southern Great Plains site. The Community Gridpoint Statistical Interpolation system is implemented in a multiscale data assimilation (MS-DA) framework that is used within the Weather Research and Forecasting model at a cloud-resolving resolution of 2 km. The MS-DA algorithm uses existing reanalysis products and constrains fine-scale atmospheric properties by assimilating high-resolution observations. A set of experiments show that the data assimilation analysis realistically reproduces the intensity, structure, and time evolution of clouds and precipitation associated with a mesoscale convective system.more »Evaluations also show that the large-scale forcing derived from the fine-resolution analysis has an overall accuracy comparable to the existing ARM operational product. For enhanced applications, the fine-resolution fields are used to characterize the contribution of subgrid variability to the large-scale forcing and to derive hydrometeor forcing, which are presented in companion papers.« less

  15. Development of fine-resolution analyses and expanded large-scale forcing properties. Part I: Methodology and evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Zhijin [California Inst. of Technology (CalTech), Pasadena, CA (United States); Univ. of California at Los Angeles, Los Angeles, CA (United States); Vogelmann, Andrew M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Feng, Sha [Univ. of California at Los Angeles, Los Angeles, CA (United States); California Inst. of Technology (CalTech), Pasadena, CA (United States); Liu, Yangang [Brookhaven National Lab. (BNL), Upton, NY (United States); Lin, Wuyin [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhang, Minghua [Stony Brook Univ., NY (United States); Toto, Tami [Brookhaven National Lab. (BNL), Upton, NY (United States); Endo, Satoshi [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-27T23:59:59.000Z

    We produce fine-resolution, three-dimensional fields of meteorological and other variables for the U.S. Department of Energy’s Atmospheric Radiation Measurement (ARM) Southern Great Plains site. The Community Gridpoint Statistical Interpolation system is implemented in a multiscale data assimilation (MS-DA) framework that is used within the Weather Research and Forecasting model at a cloud-resolving resolution of 2 km. The MS-DA algorithm uses existing reanalysis products and constrains fine-scale atmospheric properties by assimilating high-resolution observations. A set of experiments show that the data assimilation analysis realistically reproduces the intensity, structure, and time evolution of clouds and precipitation associated with a mesoscale convective system. Evaluations also show that the large-scale forcing derived from the fine-resolution analysis has an overall accuracy comparable to the existing ARM operational product. For enhanced applications, the fine-resolution fields are used to characterize the contribution of subgrid variability to the large-scale forcing and to derive hydrometeor forcing, which are presented in companion papers.

  16. Mechanical properties and energy absorption characteristics of a polyurethane foam

    SciTech Connect (OSTI)

    Goods, S.H.; Neuschwanger, C.L.; Henderson, C.; Skala, D.M.

    1997-03-01T23:59:59.000Z

    Tension, compression and impact properties of a polyurethane encapsulant foam have been measured as a function of foam density. Significant differences in the behavior of the foam were observed depending on the mode of testing. Over the range of densities examined, both the modulus and the elastic collapse stress of the foam exhibited power-law dependencies with respect to density. The power-law relationship for the modulus was the same for both tension and compression testing and is explained in terms of the elastic compliance of the cellular structure of the foam using a simple geometric model. Euler buckling is used to rationalize the density dependence of the collapse stress. Neither tension nor compression testing yielded realistic measurements of energy absorption (toughness). In the former case, the energy absorption characteristics of the foam were severely limited due to the inherent lack of tensile ductility. In the latter case, the absence of a failure mechanism led to arbitrary measures of energy absorption that were not indicative of true material properties. Only impact testing revealed an intrinsic limitation in the toughness characteristics of the material with respect to foam density. The results suggest that dynamic testing should be used when assessing the shock mitigating qualities of a foam.

  17. Absorption Heat Pumping- Have You Tried It? 

    E-Print Network [OSTI]

    Davis, R. C.

    1985-01-01T23:59:59.000Z

    The concept of a thermal powered absorption heat pump is not a new or revolutionary idea. It has been successfully demonstrated in the lab and prototypes have been installed in the field. Units have been successfully applied in a number...

  18. Variable effect desorber-resorber absorption cycle

    DOE Patents [OSTI]

    Biermann, Wendell J. (Fayetteville, NY)

    1985-01-01T23:59:59.000Z

    An absorption refrigeration system has an intermediate temperature desorber-resorber pair. A valve between the desorber-resorber pair is modulated to control the capacity for load matching.

  19. Visible spectrometer utilizing organic thin film absorption

    E-Print Network [OSTI]

    Tiefenbruck, Laura C. (Laura Christine)

    2004-01-01T23:59:59.000Z

    In this thesis, I modeled and developed a spectrometer for the visible wavelength spectrum, based on absorption characteristics of organic thin films. The device uses fundamental principles of linear algebra to reconstruct ...

  20. Absorption chillers: Part of the solution

    SciTech Connect (OSTI)

    Occhionero, A.J. (American Gas Cooling Center, Arlington, VA (United States)); Hughes, P.J. (Oak Ridge National Lab., TN (United States)); Reid, E.A. (Columbia Gas Distribution Co., Columbus, OH (United States))

    1991-01-01T23:59:59.000Z

    Acid rain, ozone depletion, global warming, and implementation economics are considered as they relate to the advisability of expanding the application of absorption chillers. Introductory and background information are provided to put the discussion in the proper context. Then all four issues are discussed separately as they relate to absorption chillers. Acid rain and ozone depletion concerns, and implementation economics, are found to support the expanded use of absorption chillers. The global warming concern is found to be more of a gray area, but the areas of benefit correspond well with the conditions of greatest economic advantage. All things considered, absorption chillers are believed to be part of the environmental and economic solution. It is further believed that integrated resource planning (IRP) processes that consider electric and gas technologies on an equal footing would come to the same conclusion for many regions of the United States. 9 refs., 3 tabs.

  1. Absorption Heat Pumping- Have You Tried It?

    E-Print Network [OSTI]

    Davis, R. C.

    The concept of a thermal powered absorption heat pump is not a new or revolutionary idea. It has been successfully demonstrated in the lab and prototypes have been installed in the field. Units have been successfully applied in a number...

  2. IHT: Tools for Computing Insolation Absorption by Particle Laden Flows

    SciTech Connect (OSTI)

    Grout, R. W.

    2013-10-01T23:59:59.000Z

    This report describes IHT, a toolkit for computing radiative heat exchange between particles. Well suited for insolation absorption computations, it is also has potential applications in combustion (sooting flames), biomass gasification processes and similar processes. The algorithm is based on the 'Photon Monte Carlo' approach and implemented in a library that can be interfaced with a variety of computational fluid dynamics codes to analyze radiative heat transfer in particle-laden flows. The emphasis in this report is on the data structures and organization of IHT for developers seeking to use the IHT toolkit to add Photon Monte Carlo capabilities to their own codes.

  3. Reduction in biomass burning aerosol light absorption upon humidificat...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in biomass burning aerosol light absorption upon humidification: Roles of inorganically-induced hygroscopicity, Reduction in biomass burning aerosol light absorption upon...

  4. absorption heat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    drive compressor heat pump; (3) absorption heat pump; (4) high temperature heat powered compressor heat pump; (5) reverse absorption heat... Erickson, D. C. 1983-01-01 26...

  5. acoustic power absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The distribution of acoustic power over sunspots shows an enhanced absorption near the umbra--penumbra boundary. Earlier studies revealed that the region of enhanced absorption...

  6. The Future of Absorption Technology in America: A Critical Look...

    Broader source: Energy.gov (indexed) [DOE]

    The Future of Absorption Technology in America: A Critical Look at the Impact of Building, Cooling, Heating, and Power (BCHP) and Innovation, June 2000 The Future of Absorption...

  7. Absorption cross section of RN black hole

    E-Print Network [OSTI]

    Sini R.; V. C. Kuriakose

    2007-08-23T23:59:59.000Z

    The behavior of a charged scalar field in the RN black hole space time is studied using WKB approximation. In the present work it is assumed that matter waves can get reflected from the event horizon. Using this effect, the Hawking temperature and the absorption cross section for RN black hole placed in a charged scalar field are calculated. The absorption cross section $\\sigma _{abs}$ is found to be inversely proportional to square of the Hawking temperature of the black hole.

  8. Fine tuning of graphene-metal adhesion by surface alloying

    E-Print Network [OSTI]

    Alfè, Dario

    Fine tuning of graphene-metal adhesion by surface alloying D. Alfe`1,2 , M. Pozzo1 , E. Miniussi3 route for governing the interaction between graphene and metal through the selective choice characterization of the properties of graphene on a model PtRu surface alloy on Ru(0001), with a concentration

  9. Science fictions: Comment on Godfrey-Smith Arthur Fine

    E-Print Network [OSTI]

    Fine, Arthur

    Science+Business Media B.V. 2008 Abstract This is a comment on Peter Godfrey-Smith's, ``ModelsScience fictions: Comment on Godfrey-Smith Arthur Fine Published online: 2 December 2008 � Springer in a naturalized and deflationary framework. Keywords Hans Vaihinger Á Models Á Fictions Á Peter Godfrey-Smith Hans

  10. MIXTURES OF FINE-GRAINED MINERALS KAOLINITE AND CARBONATE GRAINS

    E-Print Network [OSTI]

    Palomino, Angelica M.

    MIXTURES OF FINE-GRAINED MINERALS À KAOLINITE AND CARBONATE GRAINS ANGELICA M. PALOMINO 1, *, SUSAN, Georgia 30332-0355, USA Abstract--The behavior of mineral mixtures can be significantly different from properties of the individual minerals, and their ensuing effects on interparticle interactions and fabric

  11. Fine-Grained Power Management Using Process-level Profiling

    E-Print Network [OSTI]

    Shi, Weisong

    . To evaluate energy efficiency, the Green Grid group proposed the definition of power usage effectiveness (PUE between performance and energy consumption, fine-grained methods, such as process- level power management-aware decisions based on these information. In addition, we introduce a power-aware system module called Energy

  12. BFA Handbook THE RuskinSCHOOL OF DRAWING & FINE ART

    E-Print Network [OSTI]

    Oxford, University of

    , giving them a firm understanding of constructing practice and a good grounding in health and safety rulesBFA Handbook 2013-2014 THE RuskinSCHOOL OF DRAWING & FINE ART UNIVERSITY OF OXFORD A working guide to essential facts A set of rules and r An explanation of examination criteria and practice A set of health

  13. My Eyes Are Fine. Why Get an Exam?

    E-Print Network [OSTI]

    ; they might lead you to believe that all you need is new eyeglasses. You can protect your eyesight by having or ophthalmologist will ask about your current and past health, your family's medical history and if you're currentlyMy Eyes Are Fine. Why Get an Exam? By Jonna Jefferis If you're like many people, the idea

  14. Unraveling the Excess Air/Coal Fineness Enigma

    E-Print Network [OSTI]

    Laspe, C. G.

    1983-01-01T23:59:59.000Z

    In the use of powered coal as a boiler fuel, the factors involved in heat loss from unburnt carbon in the ash are but partially understood. More finely pulverized coal particles will result in lower carbon-in-ash losses. On the other hand, the finer...

  15. Self-irradiation damage to the local structure of plutonium and plutonium intermetallics

    SciTech Connect (OSTI)

    Booth, C. H.; Jiang Yu; Medling, S. A. [Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Wang, D. L. [Nuclear Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Costello, A. L.; Schwartz, D. S.; Mitchell, J. N.; Tobash, P. H. [Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bauer, E. D. [Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); McCall, S. K.; Wall, M. A.; Allen, P. G. [Condensed Matter and Materials Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2013-03-07T23:59:59.000Z

    The effect of self-irradiation damage on the local structure of {delta}-Pu, PuAl{sub 2}, PuGa{sub 3}, and other Pu intermetallics has been determined for samples stored at room temperature using the extended x-ray absorption fine-structure (EXAFS) technique. These measurements indicate that the intermetallic samples damage at a similar rate as indicated in previous studies of PuCoGa{sub 5}. In contrast, {delta}-Pu data indicate a much slower damage accumulation rate. To explore the effect of storage temperature and possible room temperature annealing effects, we also collected EXAFS data on a {delta}-Pu sample that was held at less than 32 K for a two month period. This sample damaged much more quickly. In addition, the measurable damage was annealed out at above only 135 K. Data from samples of {delta}-Pu with different Ga concentrations and results on all samples collected from different absorption edges are also reported. These results are discussed in terms of the vibrational properties of the materials and the role of Ga in {delta}-Pu as a network former.

  16. Resonant absorption and not-so-resonant absorption in short, intense laser irradiated plasma

    SciTech Connect (OSTI)

    Ge, Z. Y.; Zhuo, H. B.; Ma, Y. Y.; Yang, X. H.; Yu, T. P.; Zou, D. B.; Yin, Y.; Shao, F. Q. [College of Science, National University of Defense Technology, Changsha 410073 (China)] [College of Science, National University of Defense Technology, Changsha 410073 (China); Yu, W.; Luan, S. X. [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China)] [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); Zhou, C. T. [College of Science, National University of Defense Technology, Changsha 410073 (China) [College of Science, National University of Defense Technology, Changsha 410073 (China); Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); Peng, X. J. [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)] [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)

    2013-07-15T23:59:59.000Z

    An analytical model for laser-plasma interaction during the oblique incidence by an ultrashort ultraintense p-polarized laser on a solid-density plasma is proposed. Both the resonant absorption and not-so-resonant absorption are self-consistently included. Different from the previous theoretical works, the physics of resonant absorption is found to be valid in more general conditions as the steepening of the electron density profile is considered. Even for a relativistic intensity laser, resonant absorption can still exist under certain plasma scale length. For shorter plasma scale length or higher laser intensity, the not-so-resonant absorption tends to be dominant, since the electron density is steepened to a critical level by the ponderomotive force. The laser energy absorption rates for both mechanisms are discussed in detail, and the difference and transition between these two mechanisms are presented.

  17. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03T23:59:59.000Z

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  18. Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite C H E N H . S H E N A N D G by absorption in sulfite solution in existing scrubbers for desulfurization. Rates of NO2 absorption and sulfite absorption initiates sulfite oxidation in the presence of oxygen, and this study quantified the effect

  19. Application of chemical structure and bonding of actinide oxide materials for forensic science

    SciTech Connect (OSTI)

    Wilkerson, Marianne Perry [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    We are interested in applying our understanding of actinide chemical structure and bonding to broaden the suite of analytical tools available for nuclear forensic analyses. Uranium- and plutonium-oxide systems form under a variety of conditions, and these chemical species exhibit some of the most complex behavior of metal oxide systems known. No less intriguing is the ability of AnO{sub 2} (An: U, Pu) to form non-stoichiometric species described as AnO{sub 2+x}. Environmental studies have shown the value of utilizing the chemical signatures of these actinide oxide materials to understand transport following release into the environment. Chemical speciation of actinide-oxide samples may also provide clues as to the age, source, or process history of the material. The scientific challenge is to identify, measure and understand those aspects of speciation of actinide analytes that carry information about material origin and history most relevant to forensics. Here, we will describe our efforts in material synthesis and analytical methods development that we will use to provide the fundamental science to characterize actinide oxide molecular structures for forensic science. Structural properties and initial results to measure structural variability of uranium oxide samples using synchrotron-based X-ray Absorption Fine Structure will be discussed.

  20. Simulating a 4-effect absorption chiller

    SciTech Connect (OSTI)

    Grossman, G. [Technion-Israel Inst. of Tech., Haifa (Israel). Dept. of Mechanical Engineering; Zaltash, A.; Adcock, P.W.; DeVault, R.C. [Oak Ridge National Lab., TN (United States). Energy Div.

    1995-06-01T23:59:59.000Z

    Absorption chillers are heat-operated refrigeration machines that operate on one of the earliest known principles of refrigeration. Current absorption chillers typically use either steam or a gas-fired burner as the energy source. All current gas-fired absorption cooling systems are based on the well known single-effect or double-effect cycles. To further improve utilization of the high temperature heat available from natural gas, a variety of triple-effect cycles have been proposed and are being developed that are capable of substantial performance improvement over equivalent double-effect cycles. This article describes a study that investigated the possibility of even further improving utilization of the high temperature heat available from natural gas combustion. During the study, performance simulation was conducted for a 4-effect lithium bromide/water cycle. From an environmental perspective, absorption chillers provide several benefits. They use absorption pairs (such as lithium bromide/water) as the working fluids, rather than chlorofluorocarbons or hydrochlorofluorocarbons, which contribute to ozone depletion and global warming.

  1. Fine Tuning for Best-Value Super ESPC Deals Using the Responsibility...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fine Tuning for Best-Value Super ESPC Deals Using the Responsibility Matrix Fine Tuning for Best-Value Super ESPC Deals Using the Responsibility Matrix Fact sheet outlines the...

  2. KrF- and ArF-excimer-laser-induced absorption in silica glasses produced by melting synthetic silica powder

    SciTech Connect (OSTI)

    Kuzuu, Nobu; Sasaki, Toshiya; Kojima, Tatsuya [Department of Applied Physics, University of Fukui, 3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507 (Japan); Tanaka, Jun-ichiro; Nakamura, Takayuki; Horikoshi, Hideharu [Tosoh SGM Corp., 4555 Kaisei-cho, Shunan-shi, Yamaguchi 746-0006 (Japan)

    2013-07-07T23:59:59.000Z

    KrF- and ArF-excimer-laser-induced absorption of silica glasses produced by electric melting and flame fusion of synthetic silica powder were investigated. The growth of KrF-laser-induced absorption was more gradual than that of ArF-laser-induced absorption. Induced absorption spectra exhibited a peak at about 5.8 eV, of which the position and width differed slightly among samples and laser species. Widths of ArF-laser-induced absorption spectra were wider than those of KrF-laser-induced spectra. KrF-laser-induced absorption is reproducible by two Gaussian absorption bands peaking at 5.80 eV with full width at half maximum (FWHM) of 0.62 eV and at 6.50 eV with FWHM of 0.74 eV. For reproduction of ArF-laser-induced absorption, Gaussian bands at 5.41 eV with FWHM of 0.62 eV was necessary in addition to components used for reproducing KrF-laser-induced absorption. Based on the discussion of the change of defect structures evaluated from change of absorption components, we proposed that the precursor of the 5.8-eV band ascribed to E Prime center ({identical_to}Si{center_dot}) is {identical_to}Si-H HO-Si{identical_to} structures formed by the reaction between strained Si-O-Si bonds and interstitial H{sub 2} molecules during the irradiation.

  3. Stop on Top: SUSY Parameter Regions, Fine-Tuning Constraints

    E-Print Network [OSTI]

    Demir, Durmus Ali

    2014-01-01T23:59:59.000Z

    We analyze common supersymmetric models in order to determine in what parameter regions with what amount of fine-tuning they are capable of accomodating the LHC-allowed top-stop degeneracy window. The stops must be light enough to enable Higgs naturalness yet heavy enough to induce a 125 GeV Higgs boson mass. These two constraints require the two stops to have a large mass splitting. We find that, compared to the usual neutralino-LSP CMSSM, the NUHM and gravitino-LSP CMSSM models possess relatively wide regions in which the light stop weighs close to the top quark. The fine-tuning involved lies in 10^3-10^4 range.

  4. Limit theorems and absorption problems for one-dimensional correlated random walks

    E-Print Network [OSTI]

    Norio Konno

    2010-06-06T23:59:59.000Z

    There has recently been considerable interest in quantum walks in connection with quantum computing. The walk can be considered as a quantum version of the so-called correlated random walk. We clarify a strong structural similarity between both walks and study limit theorems and absorption problems for correlated random walks by our PQRS method, which was used in our analysis of quantum walks.

  5. Absolute absorption spectroscopy based on molecule interferometry

    E-Print Network [OSTI]

    Stefan Nimmrichter; Klaus Hornberger; Hendrik Ulbricht; Markus Arndt

    2008-11-07T23:59:59.000Z

    We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

  6. Evaluation of hyperbaric filtration for fine coal dewatering. Final report

    SciTech Connect (OSTI)

    Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Hogg, R. [Pennsylvania State Univ., University Park, PA (United States); Fonseca, A. [CONSOL Inc. (United States)

    1996-08-15T23:59:59.000Z

    The main objectives of the project were to investigate the fundamental aspects of particle-liquid interaction in fine coal dewatering, to conduct laboratory and pilot plant studies on the applicability of hyperbaric filter systems and to develop process conditions for dewatering of fine clean coal to less than 20% moisture. The program consisted of three phases, namely Phase 1 -- Model Development, Phase 2 -- Laboratory Studies, Phase 3 -- Pilot Plant Testing. The Pennsylvania State University led efforts in Phase 1, the University of Kentucky in Phase 2, and CONSOL Inc. in Phase 3 of the program. All three organizations were involved in all the three phases of the program. The Pennsylvania State University developed a theoretical model for hyperbaric filtration systems, whereas the University of Kentucky conducted experimental studies to investigate fundamental aspects of particle-liquid interaction and application of high pressure filter in fine coal dewatering. The optimum filtration conditions identified in Phase 1 and 2 were tested in two of the CONSOL Inc. coal preparation plants using an Andritz Ruthner portable hyperbaric filtration unit.

  7. Stop on Top: SUSY Parameter Regions, Fine-Tuning Constraints

    E-Print Network [OSTI]

    Durmus Ali Demir; Cem Salih Un

    2014-11-18T23:59:59.000Z

    We analyze minimal supersymmetric models in order to determine in what parameter regions with what amount of fine-tuning they are capable of accomodating the LHC-allowed top-stop degeneracy window. The stops must be light enough to enable Higgs naturalness yet heavy enough to induce a 125 GeV Higgs boson mass. These two constraints imply a large mass splitting. By an elaborate scan of the parameter space, we show that stop-on-top scenario requires at least Delta_CMSSM ~ O(10^4) fine-tuning in the CMSSM. By relaxing the CMSSM parameter space with nonuniversal Higgs masses, we find that Delta_NUHM1 ~ O(10^4). The CMSSM with gravitino LSP works slightly better than the NUHM1 model. Compared to all these, the CMSSM with mu<0 and nonuniversal gauginos yield a much smaller fine-tuning Delta_{mu,g} ~ O(100). Our results show that gaugino sector can pave the road towards a more natural stop-on-top scenario.

  8. Potassium emission absorption system. Topical report 12

    SciTech Connect (OSTI)

    Bauman, L.E.

    1995-04-01T23:59:59.000Z

    The Potassium Emission Absorption System is one of the advanced optical diagnostics developed at Mississippi State University to provide support for the demonstration of prototype-scale coal-fired combustion magnetohydrodynamic (MHD) electrical power generation. Intended for application in the upstream of an MHD flow, the system directly measures gas temperature and neutral potassium atom number density through spectroscopic emission absorption techniques. From these measurements the electron density can be inferred from a statistical equilibrium calculation and the electron conductivity in the MHD channel found by use of an electron mobility model. The instrument has been utilized for field test measurements on MHD facilities for almost a decade and has been proven to provide useful measurements as designed for MHD nozzle, channel, and diffuser test sections. The theory of the measurements, a system description, its capabilities, and field test measurement results are reported here. During the development and application of the instrument several technical issues arose which when addressed advanced the state of the art in emission absorption measurement. Studies of these issues are also reported here and include: two-wavelength measurements for particle-laden flows, potassium D-line far wing absorption coefficient, bias in emission absorption measurements arising from dirty windows and misalignments, non-coincident multiwavelength emission absorption sampling errors, and lineshape fitting for boundary layer flow profile information. Although developed for NLHD application, the instrument could be applied to any high temperature flow with a resonance line in the 300 to 800 nm range, for instance other types of flames, rocket plumes or low temperature plasmas.

  9. LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch-Based Image Retrieval

    E-Print Network [OSTI]

    Gong, Shaogang

    LI,HOSPEDALES,SONG,GONG: FINE-GRAINED SKETCH-BASED IMAGE RETRIEVAL 1 Fine-Grained Sketch.hospedales@qmul.ac.uk Yi-Zhe Song yizhe.song@qmul.ac.uk Shaogang Gong s.gong@qmul.ac.uk Queen Mary University of London. It may be distributed unchanged freely in print or electronic forms. #12;2 LI,HOSPEDALES,SONG,GONG: FINE

  10. The 4000 A absorption system of formaldehyde

    E-Print Network [OSTI]

    Henderson, James Ralph

    1957-01-01T23:59:59.000Z

    THE $000 A ABSORPTION SYSTEM OF FORMALDEHYDE JAMES RALPH HENDERSON A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May i 1957 Ma]or Subject: Physics THE 4000 A ABSORPTION SYSTEM OF FORMALDEHYDE A Thesis JAMES RALPH HENDERSON Approved as to style and content bye rlllan 0 OIllK e e ea o epar men May, l957 TABLE OF CONTENTS Page I. Introduction...

  11. Multi-plasmon absorption in graphene

    E-Print Network [OSTI]

    Marinko Jablan; Darrick E. Chang

    2015-01-21T23:59:59.000Z

    We show that graphene possesses a strong nonlinear optical response in the form of multi-plasmon absorption, with exciting implications in classical and quantum nonlinear optics. Specifically, we predict that graphene nano-ribbons can be used as saturable absorbers with low saturation intensity in the far-infrared and terahertz spectrum. Moreover, we predict that two-plasmon absorption and extreme localization of plasmon fields in graphene nano-disks can lead to a plasmon blockade effect, in which a single quantized plasmon strongly suppresses the possibility of exciting a second plasmon.

  12. Modified discrete random walk with absorption

    E-Print Network [OSTI]

    Theo van Uem

    2009-03-02T23:59:59.000Z

    We obtain expected number of arrivals, probability of arrival, absorption probabilities and expected time before absorption for a modified discrete random walk on the (sub)set of integers. In a [pqrs] random walk the particle can move one step forward or backward, stay for a moment in the same state or it can be absorbed immediately in the current state. M[pqrs] is a modified version, where probabilities on both sides of a multiple function barrier M are of different [pqrs] type.

  13. Anomalous Light Absorption by Small Particles

    E-Print Network [OSTI]

    Michael I. Tribelsky

    2009-12-18T23:59:59.000Z

    A new type of resonant light absorption by a small particle (nanocluster) is reported. The problem cannot be described within the commonly used dipole scattering approximation and should be studied with methods based upon the exact Mie solution. It is shown that the absorption cross-section has giant maxima realized at small values of the imaginary part of the complex dielectric permittivity of the particle. The maxima are situated in the vicinity of the plasmon (polariton) resonances and correspond to the regions where the dissipative damping equals the radiative one. The case is similar to the recently introduced anomalous scattering [PRL vol. 97, 263902 (2006)] and exhibits similar peculiarities.

  14. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  15. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  16. General syllabus for doctoral (third cycle) education in the arts at the University of Gothenburg Fine Arts

    E-Print Network [OSTI]

    Johannesson, Henrik

    and understanding For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine and skills For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine and approach For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine

  17. Study of light-induced vector changes in the local atomic structure of AsSe glasses by EXAFS

    E-Print Network [OSTI]

    Drabold, David

    Study of light-induced vector changes in the local atomic structure of As­Se glasses by EXAFS G changes in the local structure of As­Se glasses using extended X-ray ab- sorption fine structure (EXAFS

  18. Absorption features of high redshift galactic winds

    E-Print Network [OSTI]

    A. P. M. Fangano; A. Ferrara; P. Richter

    2007-06-11T23:59:59.000Z

    The environment of high-redshift galaxies is characterized by both wind-driven outflowing gas and gravitationally infalling streams. To investigate such galaxy-IGM interplay we have generated synthetic optical absorption line spectra piercing the volume surrounding a starbursting analog of a Lyman Break Galaxy selected in a $z \\approx 3$ output from a SPH simulation, including a detailed treatment of mechanical feedback from winds. Distributions for several observable species (HI, CIII, CIV, SiII, SiIII, SiIV, OVI, OVII, and OVIII) have been derived by post-processing the simulation outputs. The hot wind material is characterized by the presence of high-ionization species such as OVI, OVII, and OVIII (the latter two observable only in X-ray bands); the colder ($Tgas clumps. However, both line profile and Pixel Optical Depth analysis of the synthetic spectra show that the intergalactic filament in which the wind-blowing galaxy is embedded produces absorption signatures that closely mimic those of the wind environment. We conclude that may be difficult to clearly identify wind-blowing galaxies and their complex gaseous environment at high redshift in optical QSO absorption-line spectra based solely on the observed ion absorption patterns.

  19. SUPPLY-SIDE OPTIMIZATION : MAXIMIZING ABSORPTIVE RATES

    E-Print Network [OSTI]

    Jumars, Pete

    and Piglet walked home thoughtfully together in the golden evening, and for a long time they were silent The World of Pooh INTRODUCTION The complexities of feeding behavior extend far beyond the simple priorities source of the material and energy for this escalation in heterotrophs with digestive tracts is absorption

  20. Coupled dual loop absorption heat pump

    DOE Patents [OSTI]

    Sarkisian, Paul H. (Watertown, MA); Reimann, Robert C. (Lafayette, NY); Biermann, Wendell J. (Fayetteville, NY)

    1985-01-01T23:59:59.000Z

    A coupled dual loop absorption system which utilizes two separate complete loops. Each individual loop operates at three temperatures and two pressures. This low temperature loop absorber and condenser are thermally coupled to the high temperature loop evaporator, and the high temperature loop condenser and absorber are thermally coupled to the low temperature generator.

  1. Absorption machine with desorber-resorber

    DOE Patents [OSTI]

    Biermann, Wendell J. (Fayetteville, NY)

    1985-01-01T23:59:59.000Z

    An absorption refrigeration system utilizing a low temperature desorber and intermediate temperature resorber. The system operates at three temperatures and three pressures to increase the efficiency of the system and is capable of utilizing a lower generator temperature than previously used.

  2. Absorption of solar radiation by solar neutrinos

    E-Print Network [OSTI]

    G. Duplancic; P. Minkowski; J. Trampetic

    2004-03-22T23:59:59.000Z

    We calculate the absorption probability of photons radiated from the surface of the Sun by a left-handed neutrino with definite mass and a typical momentum for which we choose |p_1|=0.2 MeV, producing a heavier right-handed antineutrino. Considering two transitions the \

  3. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

    1998-09-22T23:59:59.000Z

    A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

  4. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, B.A.; Whitlow, E.P.

    1998-09-22T23:59:59.000Z

    A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

  5. Polymer microcantilevers fabricated via multiphoton absorption polymerization

    E-Print Network [OSTI]

    Teich, Malvin C.

    Polymer microcantilevers fabricated via multiphoton absorption polymerization Z. Bayindir, Y. Sun polymer cantilevers. Atomic force microscopy has been used to characterize the mechanical properties orders of magnitude smaller than would be predicted from the properties of the bulk polymer.6 If correct

  6. Approaching total absorption at near infrared in a large area monolayer graphene by critical coupling

    SciTech Connect (OSTI)

    Liu, Yonghao; Chadha, Arvinder; Zhao, Deyin; Shuai, Yichen; Menon, Laxmy; Yang, Hongjun; Zhou, Weidong, E-mail: wzhou@uta.edu [Nanophotonics Lab, Department of Electrical Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States); Piper, Jessica R.; Fan, Shanhui [Ginzton Laboratory, Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Jia, Yichen; Xia, Fengnian [Department of Electrical Engineering, Yale University, New Haven, Connecticut 06520 (United States); Ma, Zhenqiang [Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

    2014-11-03T23:59:59.000Z

    We demonstrate experimentally close to total absorption in monolayer graphene based on critical coupling with guided resonances in transfer printed photonic crystal Fano resonance filters at near infrared. Measured peak absorptions of 35% and 85% were obtained from cavity coupled monolayer graphene for the structures without and with back reflectors, respectively. These measured values agree very well with the theoretical values predicted with the coupled mode theory based critical coupling design. Such strong light-matter interactions can lead to extremely compact and high performance photonic devices based on large area monolayer graphene and other two–dimensional materials.

  7. Fatigue and Creep-Fatigue Deformation of an Ultra-Fine Precipitate Strengthened Advanced Austenitic Alloy

    SciTech Connect (OSTI)

    M.C. Carroll; L.J. Carroll

    2012-10-01T23:59:59.000Z

    An advanced austenitic alloy, HT-UPS (high-temperature ultrafine-precipitation-strengthened), has been identified as an ideal candidate material for the structural components of fast reactors and energy-conversion systems. HT-UPS alloys demonstrate improved creep resistance relative to 316 stainless steel (SS) through additions of Ti and Nb, which precipitate to form a widespread dispersion of stable nanoscale metallic carbide (MC) particles in the austenitic matrix. The low-cycle fatigue and creep-fatigue behavior of an HT-UPS alloy have been investigated at 650 °C and a 1.0% total strain, with an R-ratio of -1 and hold times at peak tensile strain as long as 150 min. The cyclic deformation response of HT-UPS is directly compared to that of standard 316 SS. The measured values for total cycles to failure are similar, despite differences in peak stress profiles and in qualitative observations of the deformed microstructures. Crack propagation is primarily transgranular in fatigue and creep-fatigue of both alloys at the investigated conditions. Internal grain boundary damage in the form of fine cracks resulting from the tensile hold is present for hold times of 60 min and longer, and substantially more internal cracks are quantifiable in 316 SS than in HT-UPS. The dislocation substructures observed in the deformed material differ significantly; an equiaxed cellular structure is observed in 316 SS, whereas in HT-UPS the microstructure takes the form of widespread and relatively homogenous tangles of dislocations pinned by the nanoscale MC precipitates. The significant effect of the fine distribution of precipitates on observed fatigue and creep-fatigue response is described in three distinct behavioral regions as it evolves with continued cycling.

  8. Development of Updated ABsorption SIMulation Software (ABSIM)

    SciTech Connect (OSTI)

    Yang, Zhiyao [Purdue University, West Lafayette, IN; Tang, Xin [Purdue University, West Lafayette, IN; Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Gluesenkamp, Kyle R [ORNL

    2014-01-01T23:59:59.000Z

    ABsorption SIMulation, ABSIM, was developed for the simulation of absorption systems by The Oak Ridge National Laboratory during 1980s and 1990s. ABSIM provides a platform for users to investigate various cycle configurations and working fluids, to calculate their operating parameters, to predict their performance, and to compare them with each other on a uniform basis. ABSIM is indeed a very useful and accurate tool for researchers to investigate various absorption systems. However, it has not been well maintained: it is incompatible with recent operating systems; the interface needs improved user-friendliness, and the system needs better parameter setting and debugging tools to help achieve convergence. Therefore, it is highly needed to update and improve ABSIM. The paper presents recent efforts to improve ABSIM s compatibility with current operating systems, user interface, and analysis capabilities. The paper details the features and functions of the newly updated ABSIM software. The new ABSIM still uses the previously validated calculation engine of the old ABSIM. The new graphic user interfaces (GUI) were developed in Qt, which is an open source license GUI software based on C++. XML was used as the database for data storage in the new ABSIM. The new ABSIM has been designed to be easily learned and used. It has enhanced editing and construction functions, plus enhanced analysis features including parametric tables, plotting, property plots, and master panels for debugging. A single effect water/LiBr absorption system is used as a case study in this paper to illustrate the features, capabilities, and functions of the new ABSIM. This case study was actually an example system available in the old ABSIM. The new version of ABSIM will be continuously developed to include additional subroutines for the components in liquid desiccant systems. The new ABSIM will be available to public for free. The ultimate goal of the new ABSIM is to allow it to become a simulation platform for both absorption heat pump and liquid desiccant systems.

  9. Effects of thermal motion on electromagnetically induced absorption

    SciTech Connect (OSTI)

    Tilchin, E.; Wilson-Gordon, A. D.; Firstenberg, O. [Department of Chemistry, Bar-Ilan University, Ramat Gan IL-52900 (Israel); Department of Physics, Technion-Israel Institute of Technology, Haifa IL-32000 (Israel)

    2011-05-15T23:59:59.000Z

    We describe the effect of thermal motion and buffer-gas collisions on a four-level closed N system interacting with strong pump(s) and a weak probe. This is the simplest system that experiences electromagnetically induced absorption (EIA) due to transfer of coherence via spontaneous emission from the excited state to the ground state. We investigate the influence of Doppler broadening, velocity-changing collisions (VCC), and phase-changing collisions (PCC) with a buffer gas on the EIA spectrum of optically active atoms. In addition to exact expressions, we present an approximate solution for the probe absorption spectrum, which provides physical insight into the behavior of the EIA peak due to VCC, PCC, and the wave-vector difference between the pump and probe beams. VCC are shown to produce a wide pedestal at the base of the EIA peak, which is scarcely affected by the pump-probe angular deviation, whereas the sharp central EIA peak becomes weaker and broader due to the residual Doppler-Dicke effect. Using diffusionlike equations for the atomic coherences and populations, we construct a spatial-frequency filter for a spatially structured probe beam and show that Ramsey narrowing of the EIA peak is obtained for beams of finite width.

  10. Effects of thermal motion on electromagnetically induced absorption

    E-Print Network [OSTI]

    E. Tilchin; O. Firstenberg; A. D. Wilson-Gordon

    2011-07-04T23:59:59.000Z

    We describe the effect of thermal motion and buffer-gas collisions on a four-level closed N system interacting with strong pump(s) and a weak probe. This is the simplest system that experiences electromagnetically induced absorption (EIA) due to transfer of coherence via spontaneous emission from the excited to ground state. We investigate the influence of Doppler broadening, velocity-changing collisions (VCC), and phase-changing collisions (PCC) with a buffer gas on the EIA spectrum of optically active atoms. In addition to exact expressions, we present an approximate solution for the probe absorption spectrum, which provides physical insight into the behavior of the EIA peak due to VCC, PCC, and wave-vector difference between the pump and probe beams. VCC are shown to produce a wide pedestal at the base of the EIA peak, which is scarcely affected by the pump-probe angular deviation, whereas the sharp central EIA peak becomes weaker and broader due to the residual Doppler-Dicke effect. Using diffusion-like equations for the atomic coherences and populations, we construct a spatial-frequency filter for a spatially structured probe beam and show that Ramsey narrowing of the EIA peak is obtained for beams of finite width.

  11. Measuring optical absorption coefficient of pure water in UV using the integrating cavity absorption meter. 

    E-Print Network [OSTI]

    Wang, Ling

    2008-10-10T23:59:59.000Z

    of the instrument is only several centimeters. The long effective total path length ensures a high sensitivity that enables the ICAM to measure liquid mediums with low absorption. Compared to the conventional transmission type of instruments that were used...

  12. Effective Absorption Enhancement in Small Molecule Organic Solar Cells by Employing Trapezoid Gratings

    E-Print Network [OSTI]

    Chun-Ping, Xiang; Yu, Jin; Bin-Zong, Xu; Wei-Min, Wang; Xin, Wei; Guo-Feng, Song; Yun, Xu

    2013-01-01T23:59:59.000Z

    We demonstrate the optical absorption has been enhanced in the small molecule organic solar cells by employing trapezoid grating structure. The enhanced absorption is mainly attributed to both waveguide modes and surface plasmon modes, which has been simulated by using finite-difference time-domain method. The simulated results show that the surface plasmon along the semitransparent metallic Ag anode is excited by introducing the periodical trapezoid gratings, which induce high intensity field increment in the donor layer. Meanwhile, the waveguide modes result a high intensity field in acceptor layer. The increment of field improves the absorption of organic solar cells, significantly, which has been demonstrated by simulating the electrical properties. The simulated results exhibiting 31 % increment of the short-circuit current has been achieved in the optimized device, which is supported by the experimental measurement. The power conversion efficiency of the grating sample obtained in experiment exhibits an...

  13. Process for preparing fine grain titanium carbide powder

    DOE Patents [OSTI]

    Janney, M.A.

    1985-03-12T23:59:59.000Z

    A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

  14. Fine, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdf Jump to:ar-80m.pdfFillmore County, Minnesota: EnergyFinanzasFine, New York:

  15. On the nature of structural disorder in calcium silicate hydrates with a calcium/silicon ratio similar to tobermorite

    SciTech Connect (OSTI)

    Grangeon, Sylvain, E-mail: S.Grangeon@brgm.fr [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Claret, Francis; Lerouge, Catherine [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Warmont, Fabienne [CRMD, UMR 6619 – CNRS, 1b rue de la férollerie, 45071 Orléans Cedex 2 (France)] [CRMD, UMR 6619 – CNRS, 1b rue de la férollerie, 45071 Orléans Cedex 2 (France); Sato, Tsutomu; Anraku, Sohtaro [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan)] [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan); Numako, Chiya [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan)] [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan); Linard, Yannick [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France)] [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France); Lanson, Bruno [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)] [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)

    2013-10-15T23:59:59.000Z

    Four calcium silicate hydrates (C-S-H) with structural calcium/silicon (Ca/Si) ratios ranging from 0.82 ± 0.02 to 0.87 ± 0.02 were synthesized at room temperature, 50, 80, and 110 °C. Their structure was elucidated by collating information from electron probe micro-analysis, transmission electron microscopy, extended X-ray absorption fine structure spectroscopy, and powder X-ray diffraction (XRD). A modeling approach specific to defective minerals was used because sample turbostratism prevented analysis using usual XRD refinement techniques (e.g. Rietveld analysis). It is shown that C-S-H with Ca/Si ratio of ? 0.8 are structurally similar to nano-crystalline turbostratic tobermorite, a naturally occurring mineral. Their structure thus consists of sheets of calcium atoms in 7-fold coordination, covered by ribbons of silicon tetrahedra with a dreierketten (wollastonite-like) organization. In these silicate ribbons, 0.42 Si per bridging tetrahedron are missing. Random stacking faults occur systematically between successive layers (turbostratic stacking). Layer-to-layer distance is equal to 11.34 Å. Crystallites have a mean size of 10 nm in the a–b plane, and a mean number of 2.6–2.9 layers stacked coherently along the c* axis.

  16. Optical hydrogen absorption consistent with a thin bow shock leading the hot Jupiter HD 189733b

    E-Print Network [OSTI]

    Cauley, P Wilson; Jensen, Adam G; Barman, Travis; Endl, Michael; Cochran, William D

    2015-01-01T23:59:59.000Z

    Bow shocks are ubiquitous astrophysical phenomena resulting from the supersonic passage of an object through a gas. Recently, pre-transit absorption in UV metal transitions of the hot Jupiter exoplanets HD 189733b and WASP12-b have been interpreted as being caused by material compressed in a planetary bow shock. Here we present a robust detection of a time-resolved pre-transit, as well as in-transit, absorption signature around the hot Jupiter exoplanet HD 189733b using high spectral resolution observations of several hydrogen Balmer lines. The line shape of the pre-transit feature and the shape of the time series absorption provide the strongest constraints on the morphology and physical characteristics of extended structures around an exoplanet. The in-transit measurements confirm the previous exospheric H-alpha detection although the absorption depth measured here is ~50% lower. The pre-transit absorption feature occurs 125 minutes before the predicted optical transit, a projected linear distance from the ...

  17. THE DISCOVERY OF HOST GALAXY H I ABSORPTION IN CTA 21

    SciTech Connect (OSTI)

    Salter, C. J.; Minchin, R.; Ghosh, T. [Arecibo Observatory, NAIC, HC3 Box 53995, Arecibo, Puerto Rico, PR 00612 (Puerto Rico); Saikia, D. J.; Chandola, Y. [National Centre for Radio Astrophysics, TIFR, Post Bag 3, Pune 411 007 (India)

    2010-06-01T23:59:59.000Z

    We report the discovery of H I 21 cm absorption toward the well-studied Gigahertz peaked spectrum source CTA 21 (4C 16.09) using the Arecibo telescope on 2009 September 20 and 21. Recently, the frequency band between 700 and 800 MHz was temporarily opened up to radio astronomy when US TV stations were mandated to switch from analog to digital transmissions, with new frequency allocations. The redshifted H I frequency for CTA 21 falls within this band. CTA 21 has a complex radio structure on a range of scales. The innermost prominent components are separated by {approx}12 mas while weak diffuse emission extends for up to {approx}300 mas. The H I absorption profile that we find has two main components, one narrow and the other wider and blueshifted. The total H I column density is 7.9 x 10{sup 20} cm{sup -2}, assuming a covering factor of unity and a spin temperature of 100 K. This H I absorption confirms the recently determined optical redshift of this faint galaxy of z {approx} 0.907. We discuss this new detection in light of H I absorption studies toward compact radio sources, and also the possibility that CTA 21 may be exhibiting multiple cycles of nuclear activity. This new detection in CTA 21 is consistent with a strong trend for detection of H I absorption in radio galaxies with evidence of episodic nuclear/jet activity.

  18. HI 21cm Absorption at $z \\sim 2.347$ towards PKS B0438-436

    E-Print Network [OSTI]

    N. Kanekar; R. Subrahmanyan; S. L. Ellison; W. M. Lane; J. N. Chengalur

    2006-05-14T23:59:59.000Z

    We report the detection of redshifted HI~21cm absorption in the $z \\sim 2.347$ damped Lyman-$\\alpha$ absorber (DLA) towards PKS B0438-436, with the Green Bank Telescope. This is the second-highest redshift at which 21cm absorption has been detected in a DLA. The absorption extends over $\\sim 60$ km/s and has two distinct components, at $z = 2.347477 (12)$ and $z = 2.347869 (20)$. A similar velocity structure is seen in optical metal lines, although the peak absorption here is offset by $\\sim 11$ km/s from the peak in the 21cm line. We obtain a high spin temperature $T_s \\sim (886 \\pm 248) \\times (f/0.58)$ K, using a covering factor estimated from 2.3 GHz VLBI data. However, the current data cannot rule out a low spin temperature. The non-detection of CO 3-2 absorption places the upper limit $N_{CO} < 3.8 \\times 10^{15} \\times (T_x/10)$ cm$^{-2}$ on the CO column density.

  19. CO2 Capture by Absorption with Potassium Carbonate

    SciTech Connect (OSTI)

    Gary T. Rochelle; Marcus Hilliard; Eric Chen; Babatunde Oyenekan; Ross Dugas; John McLees; Andrew Sexton; Daniel Ellenberger

    2005-10-26T23:59:59.000Z

    The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Modeling of stripper performance suggests that vacuum stripping may be an attractive configuration for all solvents. Flexipac 1Y structured packing performs in the absorber as expected. It provides twice as much mass transfer area as IMTP No.40 dumped packing. Independent measurements of CO{sub 2} solubility give a CO{sub 2} loading that is 20% lower than that Cullinane's values with 3.6 m PZ at 100-120 C. The effective mass transfer coefficient (K{sub G}) in the absorber with 5 m K/2.5 m PZ appears to be 0 to 30% greater than that of 30 wt% MEA.

  20. The digestive adaptation of flying vertebrates: High intestinal paracellular absorption

    E-Print Network [OSTI]

    Mladenoff, David

    The digestive adaptation of flying vertebrates: High intestinal paracellular absorption compensates analysis. Significantly greater amplification of digestive surface area by villi in small birds, also in actively flying vertebrates. digestion gut morphometrics nutrient absorption paracellular uptake Birds have

  1. absorption cycle heat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    drive compressor heat pump; (3) absorption heat pump; (4) high temperature heat powered compressor heat pump; (5) reverse absorption heat... Erickson, D. C. 1983-01-01 First Page...

  2. autonomous solar absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N; Teng, M; Cryan, M J 2012-01-01 4 WEATHER MODIFICATION BY CARBON DUST ABSORPTION OF SOLAR ENERGY Geosciences Websites Summary: WEATHER MODIFICATION BY CARBON DUST ABSORPTION...

  3. Infrared absorption spectra, radiative efficiencies, and global warming potentials

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Infrared absorption spectra, radiative efficiencies, and global warming potentials absorption spectra, radiative efficiencies, and global warming potentials of perfluorocarbons: Comparison. (1995) and combined with atmospheric lifetimes from the literature to determine global warming

  4. absorption integrals measured: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 24 25 Next Page Last Page Topic Index 1 The development of an integrating cavity absorption meter to measure optical absorption of pure waters and suspended particulates Texas...

  5. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

  6. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

  7. atomic absorption spectrophotometric: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atomic absorption spectrophotometric First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption...

  8. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22T23:59:59.000Z

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  9. Recovery of coal fines from preparation plant effluents

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1990-01-01T23:59:59.000Z

    The objectives of this project are to test and demonstrate the feasibility of recovering the coal fines which are currently disposed of with plant effluent streams in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of carbonaceous material from the effluent streams will be effected by means of Michigan Technological University's static tube flotation process in conjunction with pyrite depressants. This process has been successfully demonstrated on a number of coals to reject 85% of the pyritic sulfur and recover 90% of the Btu value. The process parameters will be modified to accept preparation plant effluents in order to produce a low-ash, low-sulfur clean coal product that at a minimum is compatible with the quality requirements of the plant clean coal. This report covers the first quarter of the project. The main activities during this period were the drafting of a project work plan and the collection of four coal preparation plant effluent samples for testing. Effluent slurry samples were collected from four operating preparation plants in Illinois and shipped to Michigan Technological University for experimental work.

  10. DEVELOPMENT OF SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS

    E-Print Network [OSTI]

    Dao, K.

    2013-01-01T23:59:59.000Z

    ROAD BERKELEY, CALIFORNIA OBJECTIVE AND APPROACH The objective of this project is the development of absorption refrigeration systems for solar

  11. Absorptive Recycle of Distillation Waste Heat

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    ABSORPTIVE RECYCLE OF DISTILLATION WASTE HEAT Donald C. Erickson and Edward J. Lutz Jr. Energy Concepts Company Annapolis, Maryland ABSTRACT When the heat source available to a distillation process is at a significantly higher temperature... which conserve 60 to 70%. Also, there are ver sions which incorporate separate low tem perature waste heat streams and thereby conserve over 90% of the required dis tillation energy. The main limitations of the R/AHP are the need for sufficient...

  12. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, Robert F. (Allentown, PA)

    1987-01-01T23:59:59.000Z

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

  13. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, R.F.

    1987-11-24T23:59:59.000Z

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs. 4 figs.

  14. Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

  15. On the Absorption and Emission Properties of Interstellar Grains

    E-Print Network [OSTI]

    Aigen Li

    2005-03-25T23:59:59.000Z

    Our current understanding of the absorption and emission properties of interstellar grains are reviewed. The constraints placed by the Kramers-Kronig relation on the wavelength-dependence and the maximum allowable quantity of the dust absorption are discussed. Comparisons of the opacities (mass absorption coefficients) derived from interstellar dust models with those directly estimated from observations are presented.

  16. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. Modeling.................................................................................................................................. 11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  17. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous.................................................................................................................................... 8 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  18. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing...................................................................................................................................11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  19. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing.................................................................................................................................. 10 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  20. Application of Quantitative Fluorescence and Absorption-Edge

    E-Print Network [OSTI]

    Sparks, Donald L.

    Application of Quantitative Fluorescence and Absorption-Edge Computed Microtomography to Image, Chicago, Illinois 60637 This paper shows that synchrotron-based fluorescence and absorption-edge computed, which had a well-correlated metal coating. Absorption-edge CMT showed the three-dimensional distribution

  1. The role of solar absorption in climate and climate change

    E-Print Network [OSTI]

    1 The role of solar absorption in climate and climate change William Collins UC Berkeley Research Boulder, Colorado, USA #12;2 Prior Research on Absorption and Climate Field Experiments: · Central · Climate with enhanced cloud absorption Synthesis of models and aerosol observations: · Development

  2. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. In Campaign.................................................................................................................................... 9 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

  3. Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall loading. The absorption rate did not follow pseudo first-order beha®ior except at ®ery low loading. All

  4. Absorption of solar radiation by the cloudy atmosphere: Further interpretations of collocated aircraft measurements

    E-Print Network [OSTI]

    1999-01-01T23:59:59.000Z

    J. Vitko Jr. , Absorption of solar radiation by the cloudyet al. , Absorption of solar radiation by clouds: Observa-1999 Absorption of solar radiation by the cloudy atmosphere:

  5. Photodetector with absorbing region having resonant periodic absorption between reflectors

    DOE Patents [OSTI]

    Bryan, R.P.; Olbright, G.R.; Brennan, T.M.; Tsao, J.Y.

    1995-02-14T23:59:59.000Z

    A photodetector is disclosed that is responsive to a wavelength or wavelengths of interest which have heretofore been unrealized. The photodetector includes a resonant cavity structure bounded by first and second reflectors, the resonant cavity structure being resonant at the wavelength or wavelengths of interest for containing a plurality of standing waves therein. The photodetector further includes a radiation absorbing region disposed within the resonant cavity structure, the radiation absorbing region including a plurality of radiation absorbing layers spaced apart from one another by a distance substantially equal to a distance between antinodes of adjacent ones of the standing waves. Each of radiation absorbing layers is spatially positioned at a location of one of the antinodes of one of the standing waves such that radiation absorption is enhanced. The radiation absorbing layers may be either bulk layers or quantum wells includes a plurality of layers, each of which is comprised of a strained layer of InGaAs. Individual ones of the InGaAs layers are spaced apart from one another by a GaAs barrier layer. 11 figs.

  6. Effects of metallic absorption and the corrugated layer on the optical extraction efficiency of organic light-emitting diodes

    E-Print Network [OSTI]

    Lee, Baek-Woon

    2011-01-01T23:59:59.000Z

    The absorption of a metallic cathode in OLEDs is analyzed by using FDTD calculation. As the light propagates parallel to the layer, the intensity of Ez polarization decreases rapidly. The intensity at 2.0 um from the dipole is less than a quarter of that at 0.5 um. The strong absorption by a cathode can be a critical factor when considering the increase of optical extraction by means of bending the optical layers. The calculation indicates that the corrugation of layers helps the guided light escape the guiding layer, but also increases the absorption into a metallic cathode. The final optical output power of the corrugated OLED can be smaller than that of the flat OLED. On the contrary, the corrugated structure with a non-absorptive cathode increases the optical extraction by nearly two times.

  7. Improvement of the Performance for an Absorption Refrigeration System with Lithium bromide-water as Refrigerant by Increasing Absorption Pressure

    E-Print Network [OSTI]

    Xie, G.; Sheng, G.; Li, G.; Pan, S.

    2006-01-01T23:59:59.000Z

    ICEBO2006, Shenzhen, China HVAC Technologies for Energy Efficiency, Vol. IV-10-4 Improvement of the Performance for an Absorption Refrigerating System with Lithium bromide-water as Refrigerant by Increasing Absorption... in order to lay a theoretical foundation of improving the performance of whole LBAC. 2. THE PRINCIPLE OF ENHANCING ABSORPTION EFFICIENCY OF THE ABSORBER It is well known that the absorption of ICEBO2006, Shenzhen, China HVAC...

  8. A strategy to stabilise the local structure of Ti{sup 4+} and Zn{sup 2+} species against aging in TiO{sub 2}/aluminium-doped ZnO bi-layers for applications in hybrid solar cells

    SciTech Connect (OSTI)

    Pellegrino, Giovanna; La Magna, Antonino; Bongiorno, Corrado; Smecca, Emanuele; Alberti, Alessandra, E-mail: alessandra.alberti@imm.cnr.it [CNR-IMM Zona Industriale VIII Strada 5, 95121 Catania (Italy); Condorelli, Guglielmo G. [Università degli studi di Catania and INSTM UdR Catania V.le A. Doria 6, Catania (Italy); Mocuta, Cristian [Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin BP 48, 91192, Gif-sur-Yvette Cedex (France)

    2014-08-07T23:59:59.000Z

    We explore a strategy to counteract aging issues in TiO{sub 2}/aluminium-doped ZnO bi-layers used in hybrid solar cells photo-anodes, mainly related to Zn diffusion in the TiO{sub 2} matrix. Different Ti{sup 4+} and Zn{sup 2+} local structures within the anatase grains and along the film thickness were found as a function of post-deposition annealing treatments in the range between 200?°C and 500?°C by synchrotron radiation extended x-ray absorption fine structure analyses. In particular, in the 500?°C-treated sample, diffusion of zinc species along the TiO{sub 2} grain-boundaries has been observed with aging (3?years). In contrast, a mild thermal budget at 200?°C favours a proper atomic arrangement of the zinc-containing anatase lattice which reduces Zn diffusion, thus guaranteeing a good stability with aging.

  9. Differential Pair Distribution Function Study of the Structure of Arsenate Adsorbed on Nanocrystalline [gamma]-Alumina

    SciTech Connect (OSTI)

    Li, Wei; Harrington, Richard; Tang, Yuanzhi; Kubicki, James D.; Aryanpour, Masoud; Reeder, Richard J.; Parise, John B.; Phillips, Brian L. (SBU); (Penn)

    2012-03-15T23:59:59.000Z

    Structural information is important for understanding surface adsorption mechanisms of contaminants on metal (hydr)oxides. In this work, a novel technique was employed to study the interfacial structure of arsenate oxyanions adsorbed on {gamma}-alumina nanoparticles, namely, differential pair distribution function (d-PDF) analysis of synchrotron X-ray total scattering. The d-PDF is the difference of properly normalized PDFs obtained for samples with and without arsenate adsorbed, otherwise identically prepared. The real space pattern contains information on atomic pair correlations between adsorbed arsenate and the atoms on {gamma}-alumina surface (Al, O, etc.). PDF results on the arsenate adsorption sample on {gamma}-alumina prepared at 1 mM As concentration and pH 5 revealed two peaks at 1.66 {angstrom} and 3.09 {angstrom}, corresponding to As-O and As-Al atomic pair correlations. This observation is consistent with those measured by extended X-ray absorption fine structure (EXAFS) spectroscopy, which suggests a first shell of As-O at 1.69 {+-} 0.01 {angstrom} with a coordination number of 4 and a second shell of As-Al at 3.13 {+-} 0.04 {angstrom} with a coordination number of 2. These results are in agreement with a bidentate binuclear coordination environment to the octahedral Al of {gamma}-alumina as predicted by density functional theory (DFT) calculation.

  10. Programmable Differential Delay Circuit With Fine Delay Adjustment

    DOE Patents [OSTI]

    DeRyckere, John F. (Eau Claire, WI); Jenkins, Philip Nord (Eau Claire, WI); Cornett, Frank Nolan (Chippewa Falls, WI)

    2002-07-09T23:59:59.000Z

    Circuitry that provides additional delay to early arriving signals such that all data signals arrive at a receiving latch with same path delay. The delay of a forwarded clock reference is also controlled such that the capturing clock edge will be optimally positioned near quadrature (depending on latch setup/hold requirements). The circuitry continuously adapts to data and clock path delay changes and digital filtering of phase measurements reduce errors brought on by jittering data edges. The circuitry utilizes only the minimum amount of delay necessary to achieve objective thereby limiting any unintended jitter. Particularly, this programmable differential delay circuit with fine delay adjustment is designed to allow the skew between ASICS to be minimized. This includes skew between data bits, between data bits and clocks as well as minimizing the overall skew in a channel between ASICS.

  11. Dilution cycle control for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01T23:59:59.000Z

    A dilution cycle control system for an absorption refrigeration system is disclosed. The control system includes a time delay relay for sensing shutdown of the absorption refrigeration system and for generating a control signal only after expiration of a preselected time period measured from the sensed shutdown of the absorption refrigeration system, during which the absorption refrigeration system is not restarted. A dilution cycle for the absorption refrigeration system is initiated in response to generation of a control signal by the time delay relay. This control system is particularly suitable for use with an absorption refrigeration system which is frequently cycled on and off since the time delay provided by the control system prevents needless dilution of the absorption refrigeration system when the system is turned off for only a short period of time and then is turned back on.

  12. Investigation of Sulfur Deactivation on Cu/Zeolite SCR Catalysts...

    Broader source: Energy.gov (indexed) [DOE]

    ZCuSO 3 or ZCuSO 2 Can we identify the species (structure) with XAFS? XAFS (X-ray absorption fine structure) XAFS XANES (X-ray absorption near-edge spectroscopy) + EXAFS...

  13. DEVELOPMENT OF A NOVEL FINE COAL CLEANING SYSTEM

    SciTech Connect (OSTI)

    Manoj K. Mohanty

    2005-06-01T23:59:59.000Z

    The goal of the proposed project was to develop a novel fine coal separator having the ability to clean 1 mm x 0 size coal in a single processing unit. The novel fine coal separator, named as EG(Enhanced Gravity) Float Cell, utilizes a centrifugal field to clean 1 mm x 250 micron size coal, whereas a flotation environment to clean minus 250 micron coal size fraction. Unlike a conventional enhanced gravity concentrator, which rotates to produce a centrifugal field requiring more energy, the EG Float Cell is fed with a tangential feed slurry to generate an enhanced gravity field without any rotating part. A prototype EG Float Cell unit having a maximum diameter of 60 cm (24 inch) was fabricated during the first-half of the project period followed by a series of exploratory tests to make suitable design modification. Test data indicated that there was a significant concentration of coarse heavy materials in the coarse tailings discharge of the EG Float Cell. The increase in weight (%) of 1 mm x 250 micron (16 x 60 mesh) size fraction from 48.9% in the feed to 72.2% in the coarse tailings discharge and the corresponding increase in the ash content from 56.9% to 87.0% is indicative of the effectiveness of the enhanced gravity section of the EG Float Cell. However, the performance of the flotation section needs to be improved. Some of the possible design modifications may include more effective air sparging system for the flotation section to produce finer bubbles and a better wash water distributor.

  14. (Recovery of coal fines from preparation plant effluents)

    SciTech Connect (OSTI)

    Choudhry, V. (Praxis Engineers, Inc., Milpitas, CA (USA)); Khan, L. (Illinois State Geological Survey, Champaign, IL (USA)); Yang, D. (Michigan Technological Univ., Houghton, MI (USA))

    1991-01-01T23:59:59.000Z

    The objectives of this project are to test and demonstrate the feasibility of recovering coal fines which are currently disposed of with plant effluent streams, in order to produce a fine clean coal product. This product can then be blended with the coarse clean coal from the preparation plant. Recovery of coal from the effluent stream samples will be effected by means of Michigan Technological University's static tube flotation process. This process has been successfully demonstrated on a number of raw coals to reject 85% of the pyritic sulfur and recover 90% of the combustible matter. The process parameters will be modified so that this technology can be applied to preparation plant effluents in order to recover a low-ash, low-sulfur clean coal that is, at a minimum, compatible with the quality of the clean coal currently produced from the preparation plant. The main activities during this period were setting up the static tube test unit to conduct the experimental work as outlined in the project work plan. The first of four effluent slurry samples collected from four operating Illinois preparation plants was tested at Michigan Technological University. The first batch of tests resulted in a clean coal containing 7.5% ash at 94.5% combustible matter recovery. Another test aimed at lowering the ash further analyzed at 3.0% ash and 0.92% total sulfur. In addition, analyses of particle size distribution and sink-float testing of the +200 mesh material were undertaken as a part of the effluent characterization work. 5 tabs.

  15. Electromagnetic scattering and absorption by aerosol agglomerates

    SciTech Connect (OSTI)

    Chen, Hsingyi.

    1989-01-01T23:59:59.000Z

    Calculation of scattering and absorption by smoke aerosols is required in many applications, including characterization of atmospheric aerosols, prediction of climatic impact of smoke, evaluation of smoke effectiveness in obscuration, calculation of heat transfer from flames, and evaluation of various scenarios of nuclear winter. In this dissertation two procedures were developed to accurately make these calculations utilizing realistic models of smoke agglomerates including oriented chains and fractal geometries. First the Iterative Extended Boundary Condition Method (IEBCM) was utilized to calculate the electromagnetic (EM) scattering and absorption of elongated aerosol particles. The computation efficiency and capability of IEBCM were improved by implementing the sectioning and the segmentation procedures. The sectioning procedure resulted in improving the computational efficiency and the segmentation method made it possible to make calculations for particles with aspect ratios as high as 250. The other procedure employed the Volume Integral Equation Formulation (VIEF) to compute the EM scattering and absorption by agglomerates of complex geometries. The validity of the procedure was checked first by comparing the obtained results with those obtained from the Mie solution for a spherical object and with the IEBCM for nonspherical objects. The comparison between results showed excellent agreement and hence validated the accuracy of the VIEF. The VIEF solution was then used to make calculations for five types of fractal agglomerates of smoke aerosol particles with fractal dimensions in the range from 1.7 to 1.9. The results obtained were compared with those based on the fractal theory recently published by Berry and Percival, and some differences were observed.

  16. Cross section for charmonium absorption by nucleons

    E-Print Network [OSTI]

    Liu, W.; Ko, Che Ming; Lin, ZW.

    2002-01-01T23:59:59.000Z

    July 2001; publishe The cross section for J/c absorption by nucleons is with empirical particle masses, which has been used previousl by pion and r meson. Including both two-body and three-bod of 1 GeV at interaction vertices involving charm hadrons... and is consistent with that extracted from J/c productio DOI: 10.1103/PhysRevC.65.015203 PAC I. INTRODUCTION Two main mechanisms for J/c suppression observed in relativistic heavy ion collisions @1# are the dissociation by the quark-gluon plasma @2...

  17. Distributed Bragg Reflectors With Reduced Optical Absorption

    DOE Patents [OSTI]

    Klem, John F. (Albuquerque, NM)

    2005-08-16T23:59:59.000Z

    A new class of distributed Bragg reflectors has been developed. These distributed Bragg reflectors comprise interlayers positioned between sets of high-index and low-index quarter-wave plates. The presence of these interlayers is to reduce photon absorption resulting from spatially indirect photon-assisted electronic transitions between the high-index and low-index quarter wave plates. The distributed Bragg reflectors have applications for use in vertical-cavity surface-emitting lasers for use at 1.55 .mu.m and at other wavelengths of interest.

  18. Absorption of the $?$ and $?$ Mesons in Nuclei

    E-Print Network [OSTI]

    M. H. Wood; R. Nasseripour; M. Paolone; C. Djalali; D. P. Weygand; the CLAS Collaboration

    2010-06-17T23:59:59.000Z

    Due to their long lifetimes, the $\\omega$ and $\\phi$ mesons are the ideal candidates for the study of possible modifications of the in-medium meson-nucleon interaction through their absorption inside the nucleus. During the E01-112 experiment at the Thomas Jefferson National Accelerator Facility, the mesons were photoproduced from $^{2}$H, C, Ti, Fe, and Pb targets. This paper reports the first measurement of the ratio of nuclear transparencies for the $e^{+}e^{-}$ channel. The ratios indicate larger in-medium widths compared with what have been reported in other reaction channels.

  19. Absorption Heat Pump Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently20,000 RussianBy:Whether you're a16-17, 201529, 2015 8:00AM EDT toTheWith693Absorption

  20. SMB, X-ray Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited ReleaseWelcome to theAbsorption Spectroscopy X-ray

  1. Intrinsic Nanoscience of ? Pu-Ga Alloys: Local Structure and Speciation, Collective Behavior, Nanoscale Heterogeneity, and Aging Mechanisms

    SciTech Connect (OSTI)

    Conradson, Steven D.; Bock, Nicolas; Castro, Julio M.; Conradson, Dylan R.; Cox, Lawrence E.; Dmowski, Wojtek; Dooley, David E.; Egami, Takeshi; Espinosa-Faller, Francisco J.; Freibert, Franz J.; Garcia-Adeva, Angel J.; Hess, Nancy J.; Holmstrom, Erik; Howell, Rafael C.; Katz, Barbara A.; Lashley, Jason C.; Martinez, Raymond J.; Moore, David P.; Morales, Luis A.; Olivas, J David; Pereyra, Ramiro A.; Ramos, Michael; Terry, Jeff H.; Villella, Phillip M.

    2014-04-24T23:59:59.000Z

    Because diffraction measurements are sensitive only to the long range average arrangement of the atoms in the coherent portion of a crystal, complementary local structure measurements are required for a complete understanding of the structure of a complex material. This is particularly an issue in solid solutions where even random distributions of a solute will result in nanometer-scale fluctuations in the local composition. The structure will be further complicated if collective and cooperative phenomena organize the solute distribution via longer range interactions between non-bonded solute sites. If the solute affects the phase stability then the question is raised of whether the atoms in domains with local compositions outside the limits of the bulk phase will rearrange into the structure stable for that composition and temperature or if the resulting stress would prevent such a local phase transition. If the former, then phase separated, heterogeneous structures at or below the diffraction limit will form. This nanometerscale competition between the phase transition and the epitaxial mismatch – exacerbated by the added strain if the transition involves a volume change – raises the potential for the formation of novel structures that do not occur in bulk material, e.g., fcc Fe. This coupling over multiple scales between inhomogeneity ordering, elastic forces, phase competition, and texture in the form of coexisting structures is a hallmark of martensites, a class of complex materials that includes ?-stabilized PuGa and that often exhibit correlated atomic and electronic properties. The enigmatic and extreme nature of Pu is consistent with its exhibiting unusual structural behavior of this type, including nanoscale heterogeneity in ?-stabilized PuGa and its enhanced homogeneity on aging that has been suggested based on earlier X-ray Absorption Fine Structure (XAFS) spectroscopy and x-ray pair distribution function (pdf) measurements. Measurements on a defined set of laboratory-prepared materials now corroborate and better describe this heterogeneity while additional aged samples demonstrate the role of heterogeneity in aging processes in Pu.

  2. Measurement of intensities of bands in the electronic absorption spectrum of chlorine dioxide

    E-Print Network [OSTI]

    Rapp, Thomas Louis

    1955-01-01T23:59:59.000Z

    energy levels are derived, Twelve bands in the electronic absorption spectrum of chlorine dioxide between the wavelengths 4250 R and 5250 R were photographed and measured. Of these twelve, the vibrational energy levels calculated for nine of them... Calculation of Vibrational Energy Levels . . . . , 35 Estimation of Errors . . . , . . . . . . . . . . . 38 CONCLUSIONS Conolusions ~ ~ ~ 47 B IBLI QGRAFEZ ~ ~ ~ ~ ~ ~ ~ ~ 48 ~INTRGDUGT10 Analysis of thc rotational structure of the chlorine dioxide...

  3. Magnetic cellulose-derivative structures

    DOE Patents [OSTI]

    Walsh, Myles A. (Falmouth, MA); Morris, Robert S. (Fairhaven, MA)

    1986-09-16T23:59:59.000Z

    Structures to serve as selective magnetic sorbents are formed by dissolving a cellulose derivative such as cellulose triacetate in a solvent containing magnetic particles. The resulting solution is sprayed as a fine mist into a chamber containing a liquid coagulant such as n-hexane in which the cellulose derivative is insoluble but in which the coagulant is soluble or miscible. On contact with the coagulant, the mist forms free-flowing porous magnetic microspheric structures. These structures act as containers for the ion-selective or organic-selective sorption agent of choice. Some sorbtion agents can be incorporated during the manufacture of the structure.

  4. Effects of mining on fine sediment quality; a comparison with regional metal background

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Effects of mining on fine sediment quality; a comparison with regional metal background University Date March 2, 2011 #12;2 Abstract The impact of an abandoned hydraulic gold mine and an open cast copper-gold mine on the quality of fine-grained sediment (

  5. Hayaku: Designing and Optimizing Finely Tuned and Portable Interactive Graphics with a Graphical Compiler

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Hayaku: Designing and Optimizing Finely Tuned and Portable Interactive Graphics with a Graphical, France stephane.conversy@enac.fr ABSTRACT Although reactive and graphically rich interfaces are now that supports de- signing finely tuned interactive graphics. With Hayaku, a designer can abstract graphics

  6. Fine-Scale Zonal Flow Suppression of Electron Temperature Gradient Turbulence

    E-Print Network [OSTI]

    Lin, Zhihong

    as an explanation for the long time build up of the zonal flow in ETG turbulence and it is shown that the generationFine-Scale Zonal Flow Suppression of Electron Temperature Gradient Turbulence S.E. Parker , J continue to grow algebraically (proportional to time). These fine-scale zonal flows have a radial wave

  7. Physically based model of downstream fining in bedrock streams with lateral input

    E-Print Network [OSTI]

    Lajeunesse, Eric

    Click Here for Full Article Physically based model of downstream fining in bedrock streams not show a clear, monotonic pattern of size reduction in the downstream direction. Both abrasion and selective sorting may play important roles in generating downstream fining. The objective of this study

  8. Structural studies of SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} by employing XRD and XANES spectroscopic techniques

    SciTech Connect (OSTI)

    Akhtar, M. Javed, E-mail: javeda@pinstech.org.pk; Khan, R. Tahir Ali

    2011-10-15T23:59:59.000Z

    The perovskite based SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} materials have been synthesized by solid state reaction methods. The structural properties are investigated using a combination of X-ray diffraction and X-ray absorption fine structure spectroscopic techniques. From the Rietveld refinement of the X-ray diffraction data it has been observed that SrFeO{sub 3} has a simple cubic perovskite structure, which is consistent with the previous literature results; whereas SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} shows a tetragonal structure within P4mm space group. X-ray absorption results demonstrate that the valence state of Fe in SrFeO{sub 3} is (IV); however, it changes to (III) when 50% Nb{sup 5+} is substituted at the Fe sites. - Highlights: {yields} Structural studies by employing XRD and XANES spectroscopic techniques. {yields} Rietveld refinement confirmed SrFeO{sub 3} has cubic structure, space group Pm-3m. {yields} It is revealed that SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} has tetragonal structure, in P4mm space group. {yields} From XANES results it is observed that Fe has valence state of (IV) in SrFeO{sub 3}. {yields} Doping of 50% Nb{sup 5+} at Fe sites, changes Fe valence to (III) in SrFe{sub 0.5}Nb{sub 0.5}O{sub 3}.

  9. Single photon absorption by a single atom: from heralded absorption to polarization state mapping

    E-Print Network [OSTI]

    Nicolas Piro; Jürgen Eschner

    2015-02-19T23:59:59.000Z

    Together with photon emission, the absorption of a single photon by a single atom is a fundamental process in matter-light interaction that manifests its quantum mechanical nature. As an experimentally controlled process, it is a key tool for the realization of quantum technologies. In particular, in an atom/photon based quantum network scenario, in which localized atomic particles are used as quantum information processing nodes while photons are used as carriers of quantum information between distant nodes, controlling both emission and absorption of single photons by single atoms is required for quantum coherent state mapping between the two entities. Most experimental efforts to date have focused on establishing the control of single photon emission by single trapped atoms, and the implementation of quantum networking protocols using this interaction. In this chapter, we describe experimental efforts to control the process of single photon absorption by single trapped ions. We describe a series of experiments in which polarization entangled photon pairs, generated by a spontaneous parametric down-conversion source, are coupled to a single ion. First the source is operated to generate heralded single photons, and coincidences between the absorption event of one photon of the pair and the detection of the heralding partner photon are observed. We then show how polarization control in the process is established, leading to the manifestation of the photonic polarization entanglement in the absorption process. Finally, we introduce protocols in which this interaction scheme is harnessed to perform tasks in a quantum network, such as entanglement distribution among distant nodes of the network, and we demonstrate a specific protocol for heralded, high-fidelity photon-to-atom quantum state transfer.

  10. UV Interstellar Absorption Lines towards the Starburst Dwarf Galaxy NGC 1705

    E-Print Network [OSTI]

    Sahu, M S

    1997-01-01T23:59:59.000Z

    Archival Goddard High Resolution Spectrograph low-resolution spectra of NGC 1705, with wavelength ranges 1170.3 to 1461.7 A and 1453.5 to 1740.1 A and a velocity resolution of about 100 km\\s, have been used to derive the velocity structure and equivalent widths of the absorption lines of Si II 1190.42, 1260.42, 1304.37 and 1526.71 A, S II 1253 , Al II 1670.79 Aand Fe II 1608.45 A in this sightline. Three relatively narrow absorption components are seen at LSR velocities --20 km/s, 260 km/sand 540 km/s. Arguments are presented to show these absorption features are interstellar rather than stellar in origin based on a comparison with the C III 1175.7 A absorption feature. We identify the --20 km/s component with Milky Way disk/halo gas and the 260 km/s component with an isolated high-velocity cloud HVC 487. This small HVC is located about 10 degrees from the H I gas which envelops the Magellanic Clouds and the Magellanic Stream (MS). The (Si/H) ratio for this HVC is > 0.6 (Si/H)solar which together with velocit...

  11. Ab initio calculation of the electronic absorption spectrum of liquid water

    SciTech Connect (OSTI)

    Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

    2014-04-28T23:59:59.000Z

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  12. APS 2003 Conferences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Conference on X-ray Absorption Fine Structure (XAFS-12). (Jun. 22-27) Malm, Sweden. First Workshop of the International Consortium on Ultra-Small-Angle Scattering...

  13. Influence of fine particles on the stability of a humid granular pile

    E-Print Network [OSTI]

    Xixi Huang; Sandrine Bec; J. Colombani

    2014-12-02T23:59:59.000Z

    We have investigated by rotating drum experiments the influence of a small amount of fine particles on the stability of a granular heap. The fine particles are shown to have a strong and ambivalent influence. For low fine particle content, the heap destabilizes by avalanches, and the fine particles tend to fluidize the heap. In contrast, for high fine particle content, they increase the cohesion of the heap, which destabilizes through stick-slip at the drum wall. We interpret and model the fluidification in the avalanching regime, which we show is independent of humidity, by granular lubrication considerations, whereas the stick-slip behavior, highly dependent on humidity, is understood by a solid friction model.

  14. Influence of fine particles on the stability of a humid granular pile

    E-Print Network [OSTI]

    Huang, Xixi; Colombani, J

    2014-01-01T23:59:59.000Z

    We have investigated by rotating drum experiments the influence of a small amount of fine particles on the stability of a granular heap. The fine particles are shown to have a strong and ambivalent influence. For low fine particle content, the heap destabilizes by avalanches, and the fine particles tend to fluidize the heap. In contrast, for high fine particle content, they increase the cohesion of the heap, which destabilizes through stick-slip at the drum wall. We interpret and model the fluidification in the avalanching regime, which we show is independent of humidity, by granular lubrication considerations, whereas the stick-slip behavior, highly dependent on humidity, is understood by a solid friction model.

  15. Enhancement of optical absorption in thin-film organic solar cells through the excitation of plasmonic modes in metallic gratings

    E-Print Network [OSTI]

    Veronis, Georgios

    .1063/1.3377791 Thin-film organic solar cells OSCs are a promising candidate for low-cost energy conversion.1­6 HoweverEnhancement of optical absorption in thin-film organic solar cells through the excitation up to 50% for such solar cell structures. © 2010 American Institute of Physics. doi:10

  16. Commercialization of Industrialized Absorption Heat Pumps in the US

    E-Print Network [OSTI]

    Pettigrew, M. G.

    COMMERCIALIZATION OF INDUSTRIAL ABSORPTION HEAT PUMPS IN THE US MALCOLM G. PETTIGREW LITWIN ENGINEERS &CONSTRUCTORS, INC. HOUSTON, ABSTRACT The recovery of waste heat through absorption heat pumping is quite appeal ing to U.S. industry.... However, although this technology has been successfully applied in Europe and Japan, a cauti ous atmosphere wi 11 continue to prevail in the U.S. until the first absorption heat pump is built and successfully demonstrates it's viability...

  17. Order and disorder in the local and long-range structure of the spin-glass pyrochlore, Tb{sub 2}Mo{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Jiang, Yu; Huq, Ashfia; Booth, Corwin H.; Ehlers, Georg; Greedan, John E.; Gardner, Jason S.

    2011-02-11T23:59:59.000Z

    To understand the origin of the spin-glass state in molybdate pyrochlores, the structure of Tb{sub 2}Mo{sub 2}O{sub 7} is investigated using two techniques: the long-range lattice structure was measured using neutron powder diffraction (NPD), and local structure information was obtained from the extended x-ray absorption fine structure (EXAFS) technique. While the long-range structure appears generally well ordered, enhanced mean-squared site displacements on the O(1) site and the lack of temperature dependence of the strongly anisotropic displacement parameters for both the Mo and O(1) sites indicate some disorder exists. Likewise, the local structure measurements indicate some Mo-Mo and Tb-O(1) nearest-neighbor disorder exists, similar to that found in the related spin-glass pyrochlore, Y{sub 2}Mo{sub 2}O{sub 7}. Although the freezing temperature in Tb{sub 2}Mo{sub 2}O{sub 7}, 25 K, is slightly higher than in Y{sub 2}Mo{sub 2}O{sub 7}, 22 K, the degree of local pair distance disorder is actually less in Tb{sub 2}Mo{sub 2}O{sub 7}. This apparent contradiction is considered in light of the interactions involved in the freezing process.

  18. Observing heme doming in myoglobin with femtosecond X-ray absorption spectroscopya)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Levantino, M.; Lemke, H. T.; Schirò, G.; Glownia, M.; Cupane, A.; Cammarata, M.

    2015-07-01T23:59:59.000Z

    We report time-resolved X-ray absorption measurements after photolysis of carbonmonoxy myoglobin performed at the LCLS X-ray free electron laser with nearly 100 fs (FWHM) time resolution. Data at the Fe K-edge reveal that the photoinduced structural changes at the heme occur in two steps, with a faster (~70 fs) relaxation preceding a slower (~400 fs) one. We tentatively attribute the first relaxation to a structural rearrangement induced by photolysis involving essentially only the heme chromophore and the second relaxation to a residual Fe motion out of the heme plane that is coupled to the displacement of myoglobin F-helix.

  19. Selecting fines recycle methods to optimize fluid bed combustor performance

    SciTech Connect (OSTI)

    Rickman, W.S.; Fields, D.E.; Brimhall, W.L.; Callahan, S.F.

    1980-05-01T23:59:59.000Z

    Testing and analysis of a number of different fines recycle methods for fluid bed combustors has led to a generalized modeling technique. This model accounts for the effect of pertinent variables in determining overall combustion efficiencies. Computer application of this model has allowed trade-off studies to be performed that show the overall process effects of changes in individual operating parameters. Verification of the model has been accomplished in processing campaigns while combusting fuels such as graphite and bituminous coal. A 0.4 MW test unit was used for the graphite experimental work. Solid fuel was typically crushed to 5 mm maximum screen size. Bed temperatures were normally controlled at 900/sup 0/C; the combustor was an atmospheric unit with maximum in-bed pressures of 0.2 atm. Expanded bed depths ranged from 1.5 to 3 meters. Additional data was taken from recycle tests sponsored by EPRI on the B and W 6 ft x 6 ft fluid bed combustor. These tests used high sulfur coal in a 1.2 meter deep, 850/sup 0/C atmospheric fluidized bed of limestone, with low recycle rates and temperatures. Close agreement between the model and test data has been noted, with combustion efficiency predictions matching experimental results within 1%.

  20. Solder flow over fine line PWB surface finishes

    SciTech Connect (OSTI)

    Hosking, F.M.; Hernandez, C.L.

    1998-08-01T23:59:59.000Z

    The rapid advancement of interconnect technology has stimulated the development of alternative printed wiring board (PWB) surface finishes to enhance the solderability of standard copper and solder-coated surfaces. These new finishes are based on either metallic or organic chemistries. As part of an ongoing solderability study, Sandia National Laboratories has investigated the solder flow behavior of two azole-based organic solderability preservations, immersion Au, immersion Ag, electroless Pd, and electroless Pd/Ni on fine line copper features. The coated substrates were solder tested in the as-fabricated and environmentally-stressed conditions. Samples were processed through an inerted reflow machine. The azole-based coatings generally provided the most effective protection after aging. Thin Pd over Cu yielded the best wetting results of the metallic coatings, with complete dissolution of the Pd overcoat and wetting of the underlying Cu by the flowing solder. Limited wetting was measured on the thicker Pd and Pd over Ni finishes, which were not completely dissolved by the molten solder. The immersion Au and Ag finishes yielded the lowest wetted lengths, respectively. These general differences in solderability were directly attributed to the type of surface finish which the solder came in contact with. The effects of circuit geometry, surface finish, stressing, and solder processing conditions are discussed.

  1. Fine Structure of Highly Charged Excitons in Semiconductor Quantum Dots B. Urbaszek,1

    E-Print Network [OSTI]

    Ludwig-Maximilians-Universität, München

    quantum dots (QDs) are artificial atoms whose properties can be individually measured in their solid, the degeneracy of the excitonic ground state is lifted by the electron-hole (EH) exchange interaction, resultingV, they can be much larger in semiconductor nanocrystals [3] or polymers [4]. In all these systems

  2. LATE EFFECTS OF HEAVY CHARGED PARTICLES ON THE FINE STRUCTURE OF THE MOUSE CORONARY ARTERY

    E-Print Network [OSTI]

    Yang, V.V.

    2012-01-01T23:59:59.000Z

    under Contract No. W-7405-ENG-48. REFERENCES 1. P. Rubin andEnergy under contract W-7405-ENG-48. Running Title: ChargedEnergy under Contract W-7405-ENG-48 DISCLAIMER This document

  3. Astron. Nachr./AN 32X (200X) X, XXXXXX Penumbral fine structure: Theoretical understanding

    E-Print Network [OSTI]

    Schlichenmaier, Rolf

    ) fluctuations in the magnetic field vector. The penumbral flow field is essentially a horizontal out- flow. The first thin flux tube model that has been proposed to explain the Evershed flow is the time & Montesinos 1990; 1991) to in- clude adiabatic flows, radiative heat exchange, standing tube shocks

  4. Fine Structure of the Gamow-Teller Resonance in 90 Nb and Level Density of 1

    E-Print Network [OSTI]

    Ponomarev, Vladimir

    Africa 5 iThemba LABS, P.O. Box 722, Somerset West 7129, South Africa 6 Department of Physics, Kyoto, Osaka 567-0047, Japan 4 School of Physics, University of the Witwatersrand, Johannesburg 2050, South analysis technique, it is possible to extract characteristic energy scales and to quantify their relative

  5. PHYSICAL REVIEW C 77, 024302 (2008) Analysis of fine structure in the nuclear continuum

    E-Print Network [OSTI]

    Ponomarev, Vladimir

    2008-01-01T23:59:59.000Z

    , Johannesburg 2050, South Africa 3 School of Earth Sciences, University of the Witwatersrand, P. O. Wits, Johannesburg 2050, South Africa 4 Department of Physics, University of Cape Town, Rondebosch 7700, South Africa, results on the isoscalar giant quadrupole resonance in 208 Pb from high-energy-resolution inelastic proton

  6. MINERAL FINE STRUCTURE OF THE AMERICAN LOBSTER CUTICLE JOSEPH G. KUNKEL,1

    E-Print Network [OSTI]

    Kunkel, Joseph G.

    . Calcite and amorphous calcium carbonate are the most abundant and most acid vulnerable of the cuticle than calcium carbonate has been diminished. But this detail in crustaceans is now yielding. Milne-Edwards, 1837, that the 3 minerals calcite, amorphous calcium carbonate (ACC), and carbonate

  7. Cosmological constant and quantum gravitational corrections to the running fine structure constant

    E-Print Network [OSTI]

    David J. Toms

    2008-09-23T23:59:59.000Z

    The quantum gravitational contribution to the renormalization group behavior of the electric charge in Einstein-Maxwell theory with a cosmological constant is considered. Quantum gravity is shown to lead to a contribution to the running charge not present when the cosmological constant vanishes. This re-opens the possibility, suggested by Robinson and Wilczek, of altering the scaling behaviour of gauge theories at high energies although our result differs. We show the possibility of an ultraviolet fixed point that is linked directly to the cosmological constant.

  8. Shape dependence of band-edge exciton fine structure in CdSe nanocrystals

    E-Print Network [OSTI]

    Zhao, Qingzhong

    2008-01-01T23:59:59.000Z

    E . ; Kadavanich A . ; Alivisatos A . P. Nature Q u L. ;H u J. ; Yang W . D . ; Alivisatos A . P. Nano Lett. 2001,Manna L. ; Scher E . ; Alivisatos A . P. J. A m . Chem. Soc.

  9. absorption spectrometry configurations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    recurrence satisfied by the Stirling numbers of the second kind. Abrams, Aaron; Hower, Valerie 2010-01-01 74 Nonlinear Coherent Perfect Absorption CERN Preprints Summary:...

  10. absorption heat pumps: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heating capacity k jet nozzle Closed Cycles: AbsorptionAdsorption heat pump thermal compressor driven by waste heat1 Industrial heat pumps in Germany - potentials,...

  11. absorption heat pump: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heating capacity k jet nozzle Closed Cycles: AbsorptionAdsorption heat pump thermal compressor driven by waste heat1 Industrial heat pumps in Germany - potentials,...

  12. Capturing All the Light: Panchromatic Visible Absorption for...

    Office of Science (SC) Website

    Capturing All the Light: Panchromatic Visible Absorption for Solar Photoconversion Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES...

  13. Geothermal: Sponsored by OSTI -- Chapter 13. Absorption Refrigeration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3. Absorption Refrigeration Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us HomeBasic Search About Publications Advanced Search New Hot Docs News...

  14. absorption solar receiver: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which exhibit a broadband absorption enhancement over 2 An Air-Based Cavity-Receiver for Solar Trough Concentrators Roman Bader Renewable Energy Websites Summary: for a heat...

  15. Absorption of Foliar-Applied Nitrogen by Cotton

    E-Print Network [OSTI]

    Oosterhuis, Derrick M

    2009-01-01T23:59:59.000Z

    on the epicuticular wax composition and ultrastructure ofleaf age, epicuticular wax, and nitrogen-15 absorption. Cropleaf cuticle and epicuticular wax as described by Oosterhuis

  16. absorption spectrometry feasibility: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption is induced by tunable laser excitation Maier, John Paul 5 FEASIBILITY OF SOLAR-FIRED, COMPRESSOR-ASSISTED Energy Storage, Conversion and Utilization Websites...

  17. Absorption Mode FT-ICR Mass Spectrometry Imaging. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass Spectrometry Imaging. Absorption Mode FT-ICR Mass Spectrometry Imaging. Abstract: Fourier transform ion cyclotron resonance mass spectrometry offers the highest mass resolving...

  18. Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry

    E-Print Network [OSTI]

    Gruner, Daniel S.

    Atomic Absorption Spectrometry · Perkin Elmer 500, Chemistry & Biochemistry · Perkin Elmer 560 AA Harvester-Luminometer scintillation counter, CBMG Centrifuges · Beckman Coulter Optima XL-I Analytical

  19. absorption leaves: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2007. ESTIMATION OF VANADIUM IN SELECTED LEAVES FROM AKURE, NIGERIA BY ATOMIC ABSORPTION SPECTROPHOTOMETRY. CiteSeer Summary: Estimation of the levels of vanadium in...

  20. absorption diffusion physical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Low Temperature Physics, Vol. 72, Nos. 56, 1988 Pressure Diffusion and Sound Absorption in Physics Websites Summary: of the usual transport coefficients (viscosity...

  1. absorption coefficient based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    22 23 24 25 Next Page Last Page Topic Index 1 Lifshitz tails for the Interband Light Absorption Coefficient Mathematics Websites Summary: Lifshitz tails for the Interband Light...

  2. Black holes and the absorption rate of cosmological scalar fields

    E-Print Network [OSTI]

    L. Arturo Urena-Lopez; Lizbeth M. Fernandez

    2011-07-15T23:59:59.000Z

    We study the absorption of a massless scalar field by a static black hole. Using the continuity equation that arises from the Klein-Gordon equation, it is possible to define a normalized absorption rate $\\Gamma(t)$ for the scalar field as it falls into the black hole. It is found that the absorption mainly depends upon the characteristics wavelengths involved in the physical system: the mean wavenumber and the width of the wave packet, but that it is insensitive to the scalar field's strength. By taking a limiting procedure, we determine the minimum absorption fraction of the scalar field's mass by the black hole, which is around 50%.

  3. Absorption Lengths in the Holographic Plasma

    E-Print Network [OSTI]

    Irene Amado; Carlos Hoyos; Karl Landsteiner; Sergio Montero

    2007-07-11T23:59:59.000Z

    We consider the effect of a periodic perturbation with frequency $\\omega$ on the holographic N=4 plasma represented by the planar AdS black hole. The response of the system is given by exponentially decaying waves. The corresponding complex wave numbers can be found by solving wave equations in the AdS black hole background with infalling boundary conditions on the horizon in an analogous way as in the calculation of quasinormal modes. The complex momentum eigenvalues have an interpretation as poles of the retarded Green's functions, where the inverse of the imaginary part gives an absorption length $\\lambda$. At zero frequency we obtain the screening length for a static field. These are directly related to the glueball masses in the dimensionally reduced theory. We also point out that the longest screening length corresponds to an operator with non-vanishing R-charge and thus does not have an interpretation as a QCD3 glueball.

  4. Performance bound for quantum absorption refrigerators

    E-Print Network [OSTI]

    Luis A. Correa; José P. Palao; Gerardo Adesso; Daniel Alonso

    2013-04-29T23:59:59.000Z

    An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modelling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

  5. Counterflow absorber for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01T23:59:59.000Z

    An air-cooled, vertical tube absorber for an absorption refrigeration system is disclosed. Strong absorbent solution is supplied to the top of the absorber and refrigerant vapor is supplied to the bottom of the absorber to create a direct counterflow of refrigerant vapor and absorbent solution in the absorber. The refrigeration system is designed so that the volume flow rate of refrigerant vapor in the tubes of the absorber is sufficient to create a substantially direct counterflow along the entire length of each tube in the absorber. This provides several advantages for the absorber such as higher efficiency and improved heat transfer characteristics, and allows improved purging of non-condensibles from the absorber.

  6. Multi-stage quantum absorption heat pumps

    E-Print Network [OSTI]

    Luis A. Correa

    2014-01-16T23:59:59.000Z

    It is well known that heat pumps, while being all limited by the same basic thermodynamic laws, may find realization on systems as "small" and "quantum" as a three-level maser. In order to quantitatively assess how the performance of these devices scales with their size, we design generalized $N$-dimensional ideal heat pumps by merging $N-2$ elementary three-level stages. We set them to operate in the absorption chiller mode between given hot and cold baths, and study their maximum achievable cooling power and the corresponding efficiency as a function of $N$. While the efficiency at maximum power is roughly size-independent, the power itself slightly increases with the dimension, quickly saturating to a constant. Thus, interestingly, scaling up autonomous quantum heat pumps does not render a significant enhancement beyond the optimal double-stage configuration.

  7. Gas separation using ultrasound and light absorption

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    2012-07-31T23:59:59.000Z

    An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

  8. J/$?$ absorption in a multicomponent hadron gas

    E-Print Network [OSTI]

    Dariusz Prorok; Ludwik Turko; David Blaschke

    2008-08-04T23:59:59.000Z

    A model for anomalous $J/\\Psi$ suppression in high energy heavy ion collisions is presented. As the additional suppression mechanism beyond standard nuclear absorption inelastic $J/\\Psi$ scattering with hadronic matter is considered. Hadronic matter is modeled as an evolving multi-component gas of point-like non-interacting particles (MCHG). Estimates for the sound velocity of the MCHG are given and the equation of state is compared with Lattice QCD data in the vicinity of the deconfinement phase transition. The approximate cooling pattern caused by longitudinal expansion is presented. It is shown that under these conditions the resulting $J/\\Psi$ suppression pattern agrees well with NA38 and NA50 data.

  9. A moving target: responding to magnetic and structural disorder in lanthanide- and actinide-based superconductors

    SciTech Connect (OSTI)

    Booth, Corwin H.; Bauer, Eric D.; Mitchel, Jeremy N.

    2010-02-10T23:59:59.000Z

    The effects of various chemical substitutions and induced lattice disorder in the Ce- and Pu-based 115 superconductors are reviewed, with particular emphasis on results from x-ray absorption fine structure (XAFS) measurements. The PuCoGa{sub 5} system offers the opportunity to follow changes in magnetic and electronic properties due to lattice disorder as a function of time in the same samples, in addition to the more traditional approach of perturbing the superconducting state through chemical substitutions. The reviewed work establishes a baseline for such future studies by determining the intrinsic lattice order in the 115 system, successfully understanding disorder as introduced through chemical substitutions in the Ce-based 115s, and beginning to explore the surprisingly large role of self-irradiation damage directly on the PuCoGa{sub 5} lattice. These studies lay the foundation for the harder future work toward measuring chemical substitutions in PuCoGa{sub 5}, correlating effects with non-Fermi liquid behavior, and obtaining a better structural picture of the distortions induced by {alpha}-decay of the plutonium nucleus.

  10. Dynamic molecular structure of plant biomass-derived black carbon (biochar)

    SciTech Connect (OSTI)

    Keiluweit, M.; Nico, P.S.; Johnson, M.G.; Kleber, M.

    2009-11-15T23:59:59.000Z

    Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases from 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.

  11. Chemical Bonding and Structural Information of Black CarbonReference Materials and Individual Carbonaceous AtmosphericAerosols

    SciTech Connect (OSTI)

    Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

    2007-04-25T23:59:59.000Z

    The carbon-to-oxygen ratios and graphitic nature of a rangeof black carbon standard reference materials (BC SRMs), high molecularmass humic-like substances (HULIS) and atmospheric particles are examinedusing scanning transmission X-ray microscopy (STXM) coupled with nearedge X-ray absorption fine structure (NEXAFS) spectroscopy. UsingSTXM/NEXAFS, individual particles with diameter>100 nm are studied,thus the diversity of atmospheric particles collected during a variety offield missions is assessed. Applying a semi-quantitative peak fittingmethod to the NEXAFS spectra enables a comparison of BC SRMs and HULIS toparticles originating from anthropogenic combustion and biomass burns,thus allowing determination of the suitability of these materials forrepresenting atmospheric particles. Anthropogenic combustion and biomassburn particles can be distinguished from one another using both chemicalbonding and structural ordering information. While anthropogeniccombustion particles are characterized by a high proportion ofaromatic-C, the presence of benzoquinone and are highly structurallyordered, biomass burn particles exhibit lower structural ordering, asmaller proportion of aromatic-C and contain a much higher proportion ofoxygenated functional groups.

  12. Geometry and continuity of fine-grained reservoir sandstones deformed within an accretionary prism - Basal Unit, West Woodbourne 

    E-Print Network [OSTI]

    Blackman, Ingrid Maria

    2004-09-30T23:59:59.000Z

    The Basal Unit of West Woodbourne Field in Barbados is a 250 m thick succession of finely-interbedded sandstones and mudstones deposited by Paleogene, fine-grained, deep-water systems off the northern South American margin ...

  13. X-RAY ABSORPTION ANALYSIS OF NGC 3516: APPEARANCE OF FAST COMPONENTS WITH INCREASED SOURCE FLUX

    SciTech Connect (OSTI)

    Holczer, Tomer; Behar, Ehud, E-mail: tomer@physics.technion.ac.il, E-mail: behar@physics.technion.ac.il [Department of Physics, Technion, Haifa 32000 (Israel)

    2012-03-01T23:59:59.000Z

    By analyzing the X-ray spectra of NGC 3516 from 2001 and 2006 obtained with the HETGS spectrometer on board the Chandra X-ray Observatory, we find that the kinematic structure of the outflow can be well represented by four outflow components intrinsic to NGC 3516: -350 {+-} 100 km s{sup -1}, -1500 {+-} 150 km s{sup -1}, -2600 {+-} 200 km s{sup -1}, and -4000 {+-} 400 km s{sup -1}. A local component at z = 0 could be confused in the spectrum with intrinsic component 3. Components 1 and 2 have a broad range of ionization manifested by absorption from 23 different charge states of Fe. Components 3 and 4 are more highly ionized and show absorption from only nine different charge states of Fe. However, we were able to reconstruct the absorption measure distribution for all four. The total column density of each component is N{sub H} = (1.8 {+-} 0.5) Multiplication-Sign 10{sup 22} cm{sup -2}, (2.5 {+-} 0.3) Multiplication-Sign 10{sup 22} cm{sup -2}, (6.9 {+-} 4.3) Multiplication-Sign 10{sup 22} cm{sup -2}, and (5.4 {+-} 1.2) Multiplication-Sign 10{sup 22} cm{sup -2}, respectively. The fast components 3 and 4 appear only in the high state of 2006 and not in 2001, while the slower components persist during both epochs. On the other hand, there is no significant absorption variability within days during 2001 or 2006. We find that the covering factor plays a minor role for the line absorption.

  14. Vitrification testing of soil fines from contaminated Hanford 100 Area and 300 Area soils

    SciTech Connect (OSTI)

    Ludowise, J.D.

    1994-05-01T23:59:59.000Z

    The suitability of Hanford soil for vitrification is well known and has been demonstrated extensively in other work. The tests reported here were carried out to confirm the applicability of vitrification to the soil fines (a subset of the Hanford soil potentially different in composition from the bulk soil) and to provide data on the performance of actual, vitrified soil fines. It was determined that the soil fines were generally similar in composition to the bulk Hanford soil, although the fraction <0.25 mm in the 100 Area soil sample appears to differ somewhat from the bulk soil composition. The soil fines are readily melted into a homogeneous glass with the simple additions of CaO and/or Na{sub 2}O. The vitrified waste (plus additives) occupies only 60% of the volume of the initial untreated waste. Leach testing has shown the glasses made from the soil fines to be very durable relative to natural and man-made glasses and has demonstrated the ability of the vitrified waste to greatly reduce the release of radionuclides to the environment. Viscosity and electrical conductivity measurements indicate that the soil fines will be readily processable, although with levels of additives slightly greater than used in the radioactive melts. These tests demonstrate the applicability of vitrification to the contaminated soil fines and the exceptional performance of the waste form resulting from the vitrification of contaminated Hanford soils.

  15. Fine density/design variable Computational Science and Engineering

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    1400 1600 FE Analysis Optimization Initialization Buildings designed to minimize seismic or wind of the topology for a lower computational cost · National Science Foundation Coarse displacement mesh meshes · Topology optimization can be used to tailor cost effective structures or microstructures

  16. Availability of the Phosphoric Acid of Finely-Divided Rock Phosphate.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach)

    1935-01-01T23:59:59.000Z

    -poor drainage, grayish brown clay, taken from 2 mi. E. of Lea by. 32650. Lake Charles Clay, 7 to 19 inches deep, Galveston County, d ayish black clay, from 2 mi. E. of League City. 33125. Moscow fine sandy loam, 3 to 7 inches, Polk County, a g imy fine sand... with numerous dark brown to black soft concretic ken 6 mi. W. of Corrigan, near the Groveton Road. 33126. Crockett Clay Loam, 0 to 7 inches, Polk County, surface ot cultivated) a dark brownish gray heavy fine sandy loam to li ~y loam, taken 2% mi. E. of Rock...

  17. LATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    LATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION AND COHERENT DECAY MODES Institut effets de correlation de paires. Abstract. -The cross-section for nuclear resonance absorption of gamma-radiation rksonnante des radiations gamma est en gBneral calculee en negligeant I'influence des phenomknes de coherence

  18. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

  19. Laser Locking with Doppler-free Saturated Absorption Spectroscopy

    E-Print Network [OSTI]

    Novikova, Irina

    - 1 - Laser Locking with Doppler-free Saturated Absorption Spectroscopy Paul L. Stubbs, Advisor the frequency of a 795 nm diode laser using a saturated absorption spectroscopy method. Laser locking in AMO physics is done to stabilize the frequency of lasers used in the laboratory in order to make results more

  20. Triple effect absorption chiller utilizing two refrigeration circuits

    DOE Patents [OSTI]

    DeVault, Robert C. (Knoxville, TN)

    1988-01-01T23:59:59.000Z

    A triple effect absorption method and apparatus having a high coefficient of performance. Two single effect absorption circuits are combined with heat exchange occurring between a condenser and absorber of a high temperature circuit, and a generator of a low temperature circuit. The evaporators of both the high and low temperature circuits provide cooling to an external heat load.

  1. Optical absorption and ionization of silicate glasses Leonid B. Glebov

    E-Print Network [OSTI]

    Glebov, Leon

    Optical absorption and ionization of silicate glasses Leonid B. Glebov School of Optics and hydroxyl), and induced (color centers) absorption of multicomponent silicate glasses in UV, visible-photon ionization was detected in alkaline-silicate glasses exposed to high-power laser radiation in nano

  2. Simulations of solar cell absorption enhancement using resonant modes

    E-Print Network [OSTI]

    Grandidier, Jonathan

    Simulations of solar cell absorption enhancement using resonant modes of a nanosphere array Jonathan Grandidier Michael G. Deceglie Dennis M. Callahan Harry A. Atwater #12;Simulations of solar cell for enhancing the absorption of thin-film amorphous silicon solar cells using periodic arrangements of resonant

  3. Infrared absorption spectra, radiative efficiencies, and global warming potentials

    E-Print Network [OSTI]

    Wirosoetisno, Djoko

    Infrared absorption spectra, radiative efficiencies, and global warming potentials of newly.mdpi.com/journal/atmosphere Article Infrared Absorption Spectra, Radiative Efficiencies, and Global Warming Potentials of Newly of 600­1730 cm-1 . These spectra are then used to calculate the radiative efficiencies and global warming

  4. absorption spectroscopy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino Absorption...

  5. atomic absorption method: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption method First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption properties of identical...

  6. absorption difference spectra: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption difference spectra First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption Spectra of...

  7. absorption spectroscopy aas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy aas First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Relic Neutrino Absorption...

  8. affect intestinal absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    affect intestinal absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Intestinal Absorption and...

  9. absorption tissue distribution: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption tissue distribution First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption and...

  10. atomic absorption flame: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption flame First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption properties of identical...

  11. absorption features dust: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption features dust First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Silicon carbide absorption...

  12. atomic absorption spectroscopic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atomic absorption spectroscopic First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption properties...

  13. absorption spectrophotometric studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectrophotometric studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Light absorption...

  14. absorption intestinal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption intestinal First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Intestinal Absorption and...

  15. acid absorption acceleration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption acceleration First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Digestion and absorption of...

  16. atomic absorption spectrometry-determination: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    atomic absorption spectrometry-determination First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption...

  17. absorption model: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption model First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Two models for absorption by coloured...

  18. atomic absorption methods: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption methods First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption properties of identical...

  19. active potassium absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    active potassium absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 CO2 Capture by Absorption...

  20. absorption spectroscopy exafs: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy exafs First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Extended Xray Absorption...

  1. anomalous light absorption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anomalous light absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Anomalous Light Absorption...

  2. absorption cross section: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption cross section First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 ? absorption cross sections...

  3. absorption line quasars: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption line quasars First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quasar Absorption Lines...

  4. absorption spectroscopy studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectroscopy studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption...

  5. atomic absorption faa: Topics by E-print Network

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    atomic absorption faa First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption properties of...

  6. atomic absorption spectrom: Topics by E-print Network

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  7. absorption lines ii: Topics by E-print Network

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    absorption lines ii First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 ABSORPTION LINE SURVEY OF H 3...

  8. absorption spectroscopic analysis: Topics by E-print Network

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  9. absorption spectra: Topics by E-print Network

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    absorption spectra First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Absorption Spectra of Astaxanthin...

  10. absorption line quasar: Topics by E-print Network

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  11. absorption process tcap: Topics by E-print Network

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  12. absorption line systems: Topics by E-print Network

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    absorption line systems First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Clustering of absorption line...

  13. absorption band substructure: Topics by E-print Network

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    absorption band substructure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 THE ABSORPTION BAND EDGE...

  14. alpha absorption systems: Topics by E-print Network

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    absorption systems First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Lyman alpha Absorption Systems and...

  15. Phonon mediated electromagnetically induced absorption in hybrid opto-electro mechanical systems

    E-Print Network [OSTI]

    Kenan Qu; G. S. Agarwal

    2013-03-15T23:59:59.000Z

    We predict the existence of the electromagnetically induced absorption (EIA) in the double cavity configurations of the hybrid opto-electro mechanical systems (OEMS). We discuss the origin of the EIA in OEMS which exhibit the existence of an absorption peak within the transparency window. We provide analytical results for the width and the height of the EIA peak. The combination of the EIT and EIA is especially useful for photon switching applications. The EIA that we discuss is different from the one originally discovered by Lezama et al in atomic systems and can be understood in terms of the dynamics of three coupled oscillators (rather than two) under different conditions on the relaxation parameters. The EIA we report can also be realized in metamaterials and plasmonic structures.

  16. Intersubband absorption in AlN/GaN/AlGaN coupled quantum wells

    SciTech Connect (OSTI)

    Driscoll, Kristina; Bhattacharyya, Anirban; Moustakas, Theodore D.; Paiella, Roberto; Zhou, Lin; Smith, David J. [Department of Electrical and Computer Engineering and Photonics Center, Boston University, 8 Saint Mary's Street, Boston, Massachusetts 02215 (United States); Department of Physics and School of Materials, Arizona State University, Tempe, Arizona 85287 (United States)

    2007-10-01T23:59:59.000Z

    AlN/GaN/AlGaN coupled quantum wells grown by molecular beam epitaxy have been developed and characterized via intersubband absorption spectroscopy. In these structures, an AlGaN layer of sufficiently low Al content is used to achieve strong interwell coupling without the need for ultrathin inner barriers. At the same time, AlN is used in the outer barriers to provide the large quantum confinement required for near-infrared intersubband transitions. The composition of the inner barriers also provides a continuously tunable parameter to control the coupling strength. Double intersubband absorption peaks are measured in each sample, at photon energies in good agreement with theoretical expectations.

  17. Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy

    SciTech Connect (OSTI)

    Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Straße 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin für Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Straße 15, 12489 Berlin (Germany)

    2014-10-15T23:59:59.000Z

    A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

  18. Theory of triplet optical absorption in oligoacenes: From naphthalene to heptacene

    SciTech Connect (OSTI)

    Chakraborty, Himanshu, E-mail: chakraborty.himanshu@gmail.com; Shukla, Alok, E-mail: shukla@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India)

    2014-10-28T23:59:59.000Z

    In this paper, we present a detailed theory of the triplet states of oligoacenes containing up to seven rings, i.e., starting from naphthalene all the way up to heptacene. In particular, we present results on the optical absorption from the first triplet excited state 1{sup 3}B{sub 2u}{sup +} of these oligomers, computed using the Pariser-Parr-Pople model Hamiltonian, and a correlated electron approach employing the configuration-interaction methodology at various levels. Excitation energies of various triplets states obtained by our calculations are in good agreement with the experimental results, where available. The computed triplet spectra of oligoacenes exhibits rich structure dominated by two absorption peaks of high intensities, which are well separated in energy, and are caused by photons polarized along the conjugation direction. This prediction of ours can be tested in future experiments performed on oriented samples of oligoacenes.

  19. On the local electronic and atomic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films on Si

    SciTech Connect (OSTI)

    Niu, Gang, E-mail: gang@ihp-microelectronics.com; Schubert, Markus Andreas; Zoellner, Marvin Hartwig [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); D'Acapito, Francesco [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, Federico [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Department of Physics and Astronomy, University of Bologna, via le C. Berti Pichat 6/2, 40127 Bologna (Italy)

    2014-09-28T23:59:59.000Z

    The local electronic and atomic structure of (111)-oriented, single crystalline mixed Ce{sub 1?x}Pr{sub x}O{sub 2??} (x?=?0, 0.1 and 0.6) epitaxial thin films on silicon substrates have been investigated in view of engineering redox properties of complex oxide films. Non-destructive X-ray absorption near edge structure reveals that Pr shows only +3 valence and Ce shows only nominal +4 valence in mixed oxides. Extended x-ray absorption fine structure (EXAFS) studies were performed at K edges of Ce and Pr using a specially designed monochromator system for high energy measurements. They demonstrate that the fluorite lattice of ceria (CeO{sub 2}) is almost not perturbed for x?=?0.1 sample, while higher Pr concentration (x?=?0.6) not only generates a higher disorder level (thus more disordered oxygen) but also causes a significant reduction of Ce–O interatomic distances. The valence states of the cations were also examined by techniques operating in highly reducing environments: scanning transmission electron microscopy-electron energy loss spectroscopy and X-ray photoemission spectroscopy; in these reducing environments, evidence for the presence of Ce{sup 3+} was clearly found for the higher Pr concentration. Thus, the introduction of Pr{sup 3+} into CeO{sub 2} strongly enhances the oxygen exchange properties of CeO{sub 2}. This improved oxygen mobility properties of CeO{sub 2} are attributed to the lattice disorder induced by Pr mixing in the CeO{sub 2} fluorite lattice, as demonstrated by EXAFS measurements. Thus, a comprehensive picture of the modifications of the atomic and electronic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films and their relation is obtained.

  20. Absorption of surface acoustic waves by topological insulator thin films

    SciTech Connect (OSTI)

    Li, L. L., E-mail: lllihfcas@foxmail.com [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Xu, W., E-mail: wenxu-issp@aliyun.com [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Department of Physics, Yunnan University, Kunming 650091 (China)

    2014-08-11T23:59:59.000Z

    We present a theoretical study on the absorption of the surface acoustic waves (SAWs) by Dirac electrons in topological insulator (TI) thin films (TITFs). We find that due to momentum and energy conservation laws, the absorption of the SAWs in TITFs can only be achieved via intra-band electronic transitions. The strong absorption can be observed up to sub-terahertz frequencies. With increasing temperature, the absorption intensity increases significantly and the cut-off frequency is blue-shifted. More interestingly, we find that the absorption of the SAWs by the TITFs can be markedly enhanced by the tunable subgap in the Dirac energy spectrum of the TI surface states. Such a subgap is absent in conventional two-dimensional electron gases (2DEGs) and in the gapless Dirac 2DEG such as graphene. This study is pertinent to the exploration of the acoustic properties of TIs and to potential application of TIs as tunable SAW devices working at hypersonic frequencies.