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We encourage you to perform a real-time search of NLEBeta
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1

absorption fine structures: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption fine structures First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Photon interference x-ray...

2

absorption fine structure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption fine structure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Photon interference x-ray...

3

Improved self-absorption correction for extended x-ray absorption fine-structure measurements  

SciTech Connect (OSTI)

Extended x-ray absorption fine-structure (EXAFS) data collected in the fluorescence mode are susceptible to an apparent amplitude reduction due to the self-absorption of the fluorescing photon by the sample before it reaches a detector. Previous treatments have made the simplifying assumption that the effect of the EXAFS on the correction term is negligible, and that the samples are in the thick limit. We present a nearly exact treatment that can be applied for any sample thickness or concentration, and retains the EXAFS oscillations in the correction term.

Booth, C.H.; Bridges, F.

2003-06-04T23:59:59.000Z

4

Accepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption  

E-Print Network [OSTI]

be only performed using synchrotron radiation. Keywords: x-ray absorption, atomic structure, xAccepted Manuscript Laboratory-based recording of holographic fine structure in x-ray absorption structure in x-ray absorption anisotropy using polycapillary optics, Nucl. Instr. and Meth. in Phys. Res. B

Korecki, Pawe³

5

Directional fine structure in absorption of white x rays: A tomographic interpretation P. Korecki,1,  

E-Print Network [OSTI]

structure in absorption of white x rays can be interpreted as real-space projections of atomic structure from neigh- boring atoms.1 A straightforward analysis of the extended x-ray absorption fine structure of the absorbing atoms. Thus, the absorption cross section is effectively modulated by the x-ray scattering

Korecki, Pawe³

6

Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized for in situ applications  

E-Print Network [OSTI]

Quick extended x-ray absorption fine structure instrument with millisecond time scale, optimized of quick extended x-ray absorption fine structure QEXAFS and quick x-ray absorption near edge structure- tion spectroscopy XAS was developed in energy dispersive and quick extended x-ray absorption fine

Sparks, Donald L.

7

ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING CONFIGURATIONS OF  

E-Print Network [OSTI]

ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE THE BONDING Rights Reserved #12;ON THE USE OF EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY TO DETERMINE

Sparks, Donald L.

8

Ultrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations  

E-Print Network [OSTI]

13­20 to generate ultrafast x-ray pulses, however, the prospect of ultrafast EXAFS seems encouragingUltrafast extended x-ray absorption fine structure ,,EXAFS...--theoretical considerations Frank L by the recent experimental demonstration of ultrafast x-ray absorption spectroscopy, we present a framework

Cao, Jianshu

9

absorption fine-structure spectroscopy: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption fine-structure spectroscopy First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of...

10

Laboratory-based recording of holographic fine structure in X-ray absorption anisotropy using polycapillary optics  

E-Print Network [OSTI]

10 April 2012 Available online 17 May 2012 Keywords: X-ray absorption Atomic structure XLaboratory-based recording of holographic fine structure in X-ray absorption anisotropy using) was characterized and used for recording two-dimensional maps of X-ray absorption anisotropy (XAA). XAA originates

Korecki, Pawe³

11

High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials  

E-Print Network [OSTI]

nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

Duffy, Thomas S.

12

Solution spectroelectrochemical cell for in situ X-ray absorption fine structure  

SciTech Connect (OSTI)

A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L{sub 3}-edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl{sub 3}{center_dot}6H{sub 2}O in 1 M H{sub 2}SO{sub 4}. The europium L{sub 3}-edge resonances reported here for the Eu{sup III} and Eu{sup II} ions demonstrate that their 2p{sub 3/2} {yields} 5d electronic transition probabilities are not the same.

Antonio, M.R.; Soderholm, L. [Argonne National Lab., IL (United States). Chemistry Div.; Song, I. [Case Western Reserve Univ., Cleveland, OH (United States)

1995-06-12T23:59:59.000Z

13

Vibronic fine structure in high-resolution x-ray absorption spectra from ion-bombarded boron nitride nanotubes  

SciTech Connect (OSTI)

The authors have applied high-resolution near-edge x-ray absorption fine structure measurements around the nitrogen K-edge to study the effects of ion-bombardment on near-surface properties of boron nitride nanotubes. A notable difference has been observed between surface sensitive partial electron yield (PEY) and bulk sensitive total electron yield (TEY) fine-structure measurements. The authors assign the PEY fine structure to the coupling of excited molecular vibrational modes to electronic transitions in NO molecules trapped just below the surface. Oxidation resistance of the boron nitride nanotubes is significantly reduced by low energy ion bombardment, as broken B-N bonds are replaced by N-O bonds involving oxygen present in the surface region. In contrast to the PEY spectra, the bulk sensitive TEY measurements on as-grown samples do not exhibit any fine structure while the ion-bombarded samples show a clear vibronic signature of molecular nitrogen.

Petravic, Mladen; Peter, Robert; Varasanec, Marijana [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Li Luhua; Chen Ying [Institute for Technology Research and Innovation, Deakin University, Geelong Waurn Ponds Campus, 3217 (Australia); Cowie, Bruce C. C. [Australian Synchrotron, Clayton VIC 3168 (Australia)

2013-05-15T23:59:59.000Z

14

Polarization of absorption lines as a diagnostics of circumstellar, interstellar and intergalactic magnetic fields: Fine structure atoms  

E-Print Network [OSTI]

The relative population of the fine structure sublevels of an atom's ground state is affected by radiative transitions induced by an anisotropic radiation flux. This causes the alignment of atomic angular momentum. In terms of observational consequences for the interstellar and intergalactic medium, this results in the polarization of the absorption lines. In the paper we consider the conditions necessary for this effect and provide calculations of polarization from a few astrophysically important atoms and ions with multiple upper and lower levels for an arbitrary orientation of magnetic fields to the a) source of optical pumping, b) direction of observation, c) absorbed source. We also consider an astrophysically important ``degenerate'' case when the source of optical pumping coincides with the source of the absorbed radiation. We present analytical expressions that relate the degree of linear polarization and the intensity of absorption to the 3D orientation of the magnetic field with respect to the pumping source, the source of the absorbed radiation, and the direction of observations. We discuss how all these parameters can be determined via simultaneous observations of several absorption lines and suggest graphical means that are helpful in practical data interpretation. We prove that studies of absorption line polarization provide a unique tool to study 3D magnetic field topology in various astrophysical conditions.

Huirong Yan; A. Lazarian

2006-11-09T23:59:59.000Z

15

Characterization of Pt/Al/sub 2/O/sub 3/ catalysts by extended X-ray absorption fine structure  

SciTech Connect (OSTI)

Three different Pt/Al/sub 2/O/sub 3/ catalysts with average crystallite sizes of 95, 26, and 8 A., as assessed by hydrogen chemisorption measurements, and reference samples of platimum foil and PtO/sub 2/ were examined by transmission X-ray absorption measurements near the Pt L/sub I//sub I//sub I/ X-ray absorption edge. The fine structure for the reduced catalysts showed that the first Pt-Pt interatomic separation distance in the crystallites did not change with crystallite size. The 95 and 26 A. catalysts had Pt crystallites with fcc crystal structure, the same as in bulk platimum. Adsorption of carbon monoxide on the 26 A. catalyst at room temperature did not disturb crystallite structure, but oxygen chemisorption on that catalyst significantly reduced the magnitude of the first Pt-Pt peak, implying a reduction in the average number of first-nearest-neighbor Pt atoms. The Fourier transform indicated coordination of Pt atoms with oxygen. All Pt-Pt bands vanished when the 8 A. catalyst was exposed to oxygen. Platimum atom electron deficiency decreased significantly after carbon monoxide or oxygen adsorption on the catalysts.

Lornston, J.M.

1980-01-01T23:59:59.000Z

16

Extended x-ray absorption fine structure studies on the iron-containing subunit of ribunucleotide reductase from Escherichia coli  

SciTech Connect (OSTI)

Iron K-edge X-ray absorption spectra were obtained on the protein B2, the small subunit of ribonucleotide reductase from Escherichia coli. Protein B2 contains a binuclear iron center with many properties in common with the iron center of oxidized hemerythrins. The extended x-ray absorption fine structure (EXAFS) measurements on protein B2 were analyzed and compared with published data for oxyhemerythrin. In protein B2 there are, in the first coordination shell around each Fe atom, five or six oxygen or nitrogen atoms that are directly coordinated ligands. In oxyhemerythrin there are six ligands to each iron. As in oxyhemerythrin, one of the ligands in the first shell of protein B2 is at a short distance, about 1.78 A, confirming the existence of a ..mu..-oxo bridge. The other atoms of the first shell are at an average distance of 2.04 A, which is about 0.1 A shorter than in oxyhemerythrin. In protein B2 the Fe-Fe distance is in the range 3.26-3.48 A, and the bridging angle falls between 130 and 150/sup 0/. On the basis of these data, there is no direct evidence for any histidine ligands in protein B2, but the noise level leaves way for the possibility of a maximum of about three histidines for each Fe pair. The x-ray absorption spectrum of a hydroxyurea-treated sample was not significantly different from that of the native protein B2, which implies that no significant alteration in the structure of the iron site occurs upon destruction of the tyrosine radical.

Bunker, G.; Petersson, L.; Sjoeberg, B.M.; Sahlin, M.; Chance, M.; Chance, B.; Ehrenberg, A.

1987-07-28T23:59:59.000Z

17

Nuclear quantum effects in the structure and lineshapes of the N{sub 2} near-edge x-ray absorption fine structure spectrum  

SciTech Connect (OSTI)

We study the relative ability of several models of x-ray absorption spectra to capture the Franck-Condon structure apparent from an experiment on gaseous nitrogen. In doing so, we adopt the Born-Oppenheimer approximation and a constrained density functional theory method for computing the energies of the x-ray-excited molecule. Starting from an otherwise classical model for the spectrum, we systematically introduce more realistic physics, first by substituting the quantum mechanical nuclear radial density in the bond separation R for the classical radial density, then by adding the effect of zero-point energy and other level shifts, and finally by including explicit rovibrational quantization of both the ground and excited states. The quantization is determined exactly, using a discrete variable representation (DVR). We show that the near-edge x-ray absorption fine structure (NEXAFS) spectrum can be predicted semiquantitatively within this framework. We also address the possibility of non-trivial temperature dependence in the spectrum. By using constrained density functional theory in combination with more accurate potentials, we demonstrate that it is possible to improve the predicted spectrum. Ultimately, we establish the predictive limits of our method with respect to vibrational fine structure in NEXAFS spectra.

Fatehi, Shervin; Schwartz, Craig P.; Saykally, Richard J. [Department of Chemistry, University of California, Berkeley, California 94720 (United States) and Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Prendergast, David [Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2010-03-07T23:59:59.000Z

18

The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure  

SciTech Connect (OSTI)

Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

Barrera, E.V. (Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science); Heald, S.M. (Brookhaven National Lab., Upton, NY (United States))

1991-01-01T23:59:59.000Z

19

The determination of interfacial structure and phase transitions in Al/Cu and Al/Ni interfaces by means of surface extended x-ray absorption fine structure  

SciTech Connect (OSTI)

Surface extended x-ray absorption fine structure (SEXAFS) was used to investigate the interfacial conditions of Al/Cu and Al/Ni shallow buried interfaces. Previous studies using glancing angle extended x-ray absorption fine structure, x-ray reflectivity, photoemission, and SEXAFS produced conflicting results as to whether or not the interfaces between Al and Cu and Al and Ni were reacted upon room temperature deposition. In this study polycrystalline bilayers of Al/Cu and Al/Ni and trilayers of Al/Cu/Al and Al/Ni/Al were deposited on tantalum foil at room temperature in ultra high vacuum and analyzed to evaluate the reactivity of these systems on a nanometer scale. It become overwhelming apparent that the interfacial phase reactions were a function of the vacuum conditions. Samples deposited with the optimum vacuum conditions showed reaction products upon deposition at room temperature which were characterized by comparisons to standards and by least squares fitting the be CuAl{sub 2} and NiAl{sub 3} respectively. The results of this study that the reacted zone thicknesses were readily dependent on the deposition parameters. For both Al on Cu and Al on Ni as well as the metal on Al conditions 10{Angstrom} reaction zones were observed. These reaction zones were smaller than that observed for bilayers of Al on Cu (30{Angstrom}) and Al on Ni (60{Angstrom}) where deposition rates were much higher and samples were much thicker. The reaction species are evident by SEXAFS, where the previous photoemission studies only indicated that changes had occurred. Improved vacuum conditions as compared to the earlier experiments is primarily the reason reactions on deposition were seen in this study as compared to the earlier SEXAFS studies.

Barrera, E.V. [Rice Univ., Houston, TX (United States). Dept. of Mechanical Engineering and Materials Science; Heald, S.M. [Brookhaven National Lab., Upton, NY (United States)

1991-12-31T23:59:59.000Z

20

In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes  

SciTech Connect (OSTI)

Aspects of the structural and electronic properties of hydrous oxide films of composite (9:1) Ni/Co and (9:1) Ni/Fe, prepared by electrodeposition, have been examined in alkaline electrolytes using in situ X-ray absorption fine structure (XAFS). An analysis of the X-ray absorption near the edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) for the Co and Fe K-edges of these composite hydrous oxides revealed that, regardless of the oxidation state of nickel sites in the films, the guest metal ions are present as Co[sup 3+] and Fe[sup 3+] and that the cobalt-oxygen distance d(Co-O) = 1.9 [+-] 0.02 [angstrom] and d(Fe-O) = 1.92 [+-] 0.02 [angstrom]. The latter values are in excellent agreement with d(Me-O) (Me = Co or Fe) in CoOOH and [beta]- and [gamma]-FeOOH, respectively, determined by conventional X-ray diffraction. Two clearly defined Me-Ni first coordination shells could be observed in the Fourier transforms (FT) of the K-edge EXAFS of the guest metal recorded at a potential at which both Ni[sup 2+] and Ni[sup 3+] sites are expected to be present. 28 refs., 10 figs., 3 tabs.

Kim, Sunghyun; Tryk, D.A.; Scherson, D. (Case Western Reserve Univ., Cleveland, OH (United States)); Antonio, M.R. (Argonne National Lab., IL (United States)); Carr, R. (Stanford Synchrotron Radiation Lab., CA (United States))

1994-10-06T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Analysis of the near-edge X-ray-absorption fine-structure of anthracene: A combined theoretical and experimental study  

SciTech Connect (OSTI)

The near-edge fine structure of the carbon K-edge absorption spectrum of anthracene was measured and theoretically analyzed by density functional theory calculations implemented in the StoBe code. It is demonstrated that the consideration of electronic relaxation of excited states around localized core holes yields a significant improvement of the calculated excitation energies and reproduces the experimentally observed fine structure well. The detailed analysis of excitation spectra calculated for each symmetry inequivalent excitation center allows in particular to examine the influence of chemical shifts and core hole effects on the excitation energies. Moreover, the visualization of final states explains the large variations in the oscillator strength of various transitions as well as the nature of Rydberg-states that exhibit a notable density of states below the ionization potentials.

Klues, Michael; Witte, Gregor, E-mail: gregor.witte@physik.uni-marburg.de [Molekulare Festkrperphysik, Philipps-Universitt Marburg (Germany)] [Molekulare Festkrperphysik, Philipps-Universitt Marburg (Germany); Hermann, Klaus, E-mail: hermann@FHI-Berlin.MPG.de [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany)] [Inorganic Chemistry Department, Fritz-Haber-Institut der Max-Planck-Gesellschaft, Berlin (Germany)

2014-01-07T23:59:59.000Z

22

In situ x-ray absorption fine structure and optical reflectance studies of electrodeposited nickel hydrous oxide films in alkaline electrolytes.  

SciTech Connect (OSTI)

X-ray absorption fine structure (XAFS) and optical reflectance spectroscopy (RS) have been used to examine in situ electronic and structural aspects of nickel hydrous oxide, a-Ni(OH)2(hyd), electrodes supported on gold in alkaline electrolytes as a function of their state of charge. The extended X-ray absorption fine structure (EXAFS) of a-Ni(OH)2(hyd) electrodes in the uncharged (UC, or discharged) and overcharged (OC, or fully charged) states yielded, in each case, a single set of two distinct nearest-neighbor shells, with distances, d(Ni-O)1 = 2.05 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 3.11 {+-} 0.02 {angstrom} for UC, and d(Ni-O)1 = 1.87 {+-} 0.02 {angstrom} and d(Ni-Ni)1 = 2.83 {+-} 0.02 {angstrom} for OC. The in situ EXAFS of films allowed to self-discharge following overcharge could be fit with contributions from both sets of shells, suggesting that only two types of nickel sites are sufficient to account for the redox chemistry of this material. These data, in addition to information derived both from quantitative X-ray absorption near-edge structure (XANES) and optical RS in the visible range, indicate that the excess anodic charge, i.e., beyond the one-electron oxidation of Ni2+ sites, observed during the first oxidation of freshly prepared a-Ni(OH)2(hyd) electrodes may not be related to oxidation state changes involving nickel sites in the lattice, and, therefore, do not support the existence of nickel sites with a formal oxidation state higher than three for charged or overcharged electrodes in this media.

Hu, Y.; Bae, I. T.; Mo, Y.; Antonio, M. R.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

1997-01-01T23:59:59.000Z

23

Particle Formation from Pulsed Laser Irradiation of SootAggregates studied with scanning mobility particle sizer, transmissionelectron microscope and near-edge x-ray absorption fine structure.  

SciTech Connect (OSTI)

We investigated the physical and chemical changes induced in soot aggregates exposed to laser radiation using a scanning mobility particle sizer, a transmission electron microscope, and a scanning transmission x-ray microscope to perform near-edge x-ray absorption fine structure spectroscopy. Laser-induced nanoparticle production was observed at fluences above 0.12 J/cm(2) at 532 nm and 0.22 J/cm(2) at 1064 nm. Our results indicate that new particle formation proceeds via (1) vaporization of small carbon clusters by thermal or photolytic mechanisms, followed by homogeneous nucleation, (2) heterogeneous nucleation of vaporized carbon clusters onto material ablated from primary particles, or (3) both processes.

Michelsen, Hope A.; Tivanski, Alexei V.; Gilles, Mary K.; vanPoppel, Laura H.; Dansson, Mark A.; Buseck, Peter R.; Buseck, Peter R.

2007-02-20T23:59:59.000Z

24

Study of hard disk and slider surfaces using X-ray photoemission electron microscopy and near-edge X-ray absorption fine structure spectroscopy  

SciTech Connect (OSTI)

X-ray Photo Emission Electron Microscopy (X-PEEM) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy were applied to study the properties of amorphous hard carbon overcoats on disks and sliders, and the properties of the lubricant. The modification of lubricants after performing thermal desorption studies was measured by NEXAFS, and the results are compared to the thermal desorption data. The study of lubricant degradation in wear tracks is described. Sliders were investigated before and after wear test, and the modification of the slider coating as well as the transfer of lubricant to the slider was studied. The studies show that the lubricant is altered chemically during the wear. Fluorine is removed and carboxyl groups are formed.

Anders, S.; Stammler, T. [Lawrence Berkeley National lab., CA (United States). Advanced Light Source Div.; Bhatia, C.S. [SSD/IBM, San Jose, CA (United States); Stoehr, J. [IBM Research Div., San Jose, CA (United States). Almaden Research Center; Fong, W.; Chen, C.Y.; Bogy, D.B. [Univ. of California, Berkeley, CA (United States)

1998-04-01T23:59:59.000Z

25

In situ Ru K-edge x-ray absorption fine structure studies of electroprecipitated ruthenium dioxide films with relevance to supercapacitor applications.  

SciTech Connect (OSTI)

Modifications in electronic and structural aspects of RuO{sub 2} films electroprecipitated onto Au electrodes induced by changes in the applied potential have been examined in situ in aqueous 0.50 M H{sub 2}SO{sub 4} by Ru K-edge X-ray absorption spectroscopy (XAS). The Fourier transform of the k{sup 3}-weighted extended X-ray absorption fine structure (EXAFS), k{sup 3}x(k), for the film polarized at +1.20V vs RHE is characterized by two shells attributed to Ru-O and Ru-Ru interactions with average distances of 1.94(1) and 3.12(2) {angstrom}, respectively, in agreement with results obtained ex situ for Ru{sup 4+} in hydrous RuO{sub 2} by other groups. In contrast, films in the reduced state, i.e., +0.40 V vs RHE, yielded only a single shell ascribed to a Ru-O interaction at 2.02(1) {angstrom} with no evidence for a distant Ru-Ru shell. The long Ru-O distance is in agreement with that reported earlier for the hydrous Ru{sup 3+} ion [Ru-(OH{sub 2}){sub 6}]{sup 3+} in the solid state. Moreover, the difference between the average Ru-O bond lengths for the reduced and oxidized films is consistent with the difference in the ionic radii of Ru{sup 3+} and Ru{sup 4+}. On this basis it has been suggested that films in the reduced state contain Ru{sup 3+} sites, consistent with the electrochemical results, in a phase with apparently less order beyond the Ru-O coordination sphere than for hydrous RuO{sub 2}.

Mo, Y.; Antonio, M. R.; Stefan, I. C.; Scherson, D. A.; Chemistry; Case Western Reserve Univ.

2000-10-26T23:59:59.000Z

26

PRELIMINARY IN-SITU X-RAY ABSORPTION FINE STRUCTURE EXAMINATION OF PT/C AND PTCO/C CATHODE CATALYSTS IN AN OPERATIONAL POLYMER ELECTROLYTE FUEL CELL  

SciTech Connect (OSTI)

State-of-the-art polymer electrolyte fuel cells require a conditioning period to reach optimized cell performance. There is insuffi cient understanding about the behavior of catalysts during this period, especially with regard to the changing environment of the cathode electrocatalyst, which is typically Pt nanoparticles supported on high surface area Vulcan XC-72 carbon (Pt/C). The purpose of this research was to record preliminary observations of the changing environment during the conditioning phase using X-Ray Absorption Fine Structure (XAFS) spectroscopy. XAFS was recorded for a Pt/C cathode at the Pt L3-edge and a PtCo/C cathode at both the Pt L3-edge and Co K-edge. Using precision machined graphite cell-blocks, both transmission and fl uorescence data were recorded at Sector 12-BM-B of Argonne National Laboratorys Advanced Photon Source. The fl uorescence and transmission edge steps allow for a working description of the changing electrocatalyst environment, especially water concentration, at the anode and cathode as functions of operating parameters. These features are discussed in the context of how future analysis may correlate with potential, current and changing apparent thickness of the membrane electrode assembly through loss of catalyst materials (anode, cathode, carbon support). Such direct knowledge of the effect of the conditioning protocol on the electrocatalyst may lead to better catalyst design. In turn, this may lead to minimizing, or even eliminating, the conditioning period.

Phelan, B.T.; Myers, D.J.; Smith, M.C.

2009-01-01T23:59:59.000Z

27

Near-Edge X-ray Absorption Fine Structure Imaging of Spherical and Flat Counterfaces of Ultrananocrystalline Diamond Tribological Contacts: A Correlation of Surface Chemistry and Friction  

SciTech Connect (OSTI)

A recently installed synchrotron radiation near-edge X-ray absorption fine structure (NEXAFS) full field imaging electron spectrometer was used to spatially resolve the chemical changes of both counterfaces from an ultra-nanocrystalline diamond (UNCD) tribological contact. A silicon flat and Si{sub 3}N{sub 4} sphere were both coated with UNCD, and employed to form two wear tracks on the flat in a linear reciprocating tribometer. The first wear track was produced using a new, unconditioned sphere whose surface was thus conditioned during this first experiment. This led to faster run-in and lower friction when producing a second wear track using the conditioned sphere. The large depth of field of the magnetically guided NEXAFS imaging detector enabled rapid, large area spectromicroscopic imaging of both the spherical and flat surfaces. Laterally resolved NEXAFS data from the tribological contact area revealed that both substrates had an as-grown surface layer that contained a higher fraction of sp{sup 2}-bonded carbon and oxygen which was mechanically removed. Unlike the flat, the film on the sphere showed evidence of having graphitic character, both before and after sliding. These results show that the graphitic character of the sphere is not solely responsible for low friction and short run-in. Rather, conditioning the sphere, likely by removing asperities and passivating dangling bonds, leads to lower friction with less chemical modification of the substrate in subsequent tests. The new NEXAFS imaging spectroscopy detector enabled a more complete understanding of the tribological phenomena by imaging, for the first time, the surface chemistry of the spherical counterface which had been in continual contact during wear track formation.

A Konicek; C Jaye; M Hamilton; W Sawyer; D Fischer; R Carpick

2011-12-31T23:59:59.000Z

28

Extended Xray Absorption Fine Structure Spectroscopy (EXAFS) Provides details on how x rays are absorbed by an atom at energies near X18A,B,X19A Provides details on how xrays are absorbed by an atom at energies near  

E-Print Network [OSTI]

's xray absorption probability due to the chemical and physical state of the atom · Especially sensitiveExtended Xray Absorption Fine Structure Spectroscopy (EXAFS) · Provides details on how x rays are absorbed by an atom at energies near X18A,B,X19A· Provides details on how xrays are absorbed by an atom

Ohta, Shigemi

29

X-ray diffraction and extended X-ray absorption fine structure study of epitaxial mixed ternary bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} (x = 0-2) films on Si (111)  

SciTech Connect (OSTI)

Ternary single crystalline bixbyite Pr{sub x}Y{sub 2-x}O{sub 3} films over the full stoichiometry range (x = 0-2) have been epitaxially grown on Si (111) with tailored electronic and crystallographic structure. In this work, we present a detailed study of their local atomic environment by extended X-ray absorption fine structure at both Y K and Pr L{sub III} edges, in combination with complementary high resolution x-ray diffraction measurements. The local structure exhibits systematic variations as a function of the film composition. The cation coordination in the second and third coordination shells changes with composition and is equal to the average concentration, implying that the Pr{sub x}Y{sub 2-x}O{sub 3} films are indeed fully mixed and have a local bixbyite structure with random atomic-scale ordering. A clear deviation from the virtual crystal approximation for the cation-oxygen bond lengths is detected. This demonstrates that the observed Vegard's law for the lattice variation as a function of composition is based microscopically on a more complex scheme related to local structural distortions which accommodate the different cation-oxygen bond lengths.

Niu, G.; Zoellner, M. H.; Zaumseil, P. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); Pouliopoulos, A. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); D'Acapito, F. [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, F. [Department of Physics and Astronomy, University of Bologna, viale C. BertiPichat 6/2, 40127 Bologna (Italy); Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France)

2013-01-28T23:59:59.000Z

30

Limits on the temporal variation of the fine structure constant, quark masses and strong interaction from quasar absorption spectra and atomic clock experiments  

E-Print Network [OSTI]

We perform calculations of the dependence of nuclear magnetic moments on quark masses and obtain limits on the variation of $(m_q/\\Lambda_{QCD})$ from recent measurements of hydrogen hyperfine (21 cm) and molecular rotational transitions in quasar absorption systems, atomic clock experiments with hyperfine transitions in H, Rb, Cs, Yb$^+$, Hg$^+$ and optical transition in Hg$^+$. Experiments with Cd$^+$, deuterium/hydrogen, molecular SF$_6$ and Zeeman transitions in $^3$He/Xe are also discussed.

V. V. Flambaum; D. B. Leinweber; A. W. Thomas; R. D. Young

2004-02-10T23:59:59.000Z

31

Dopant site selectivity in BaCe0.85M0.15O3-by extended x-ray absorption fine structure  

E-Print Network [OSTI]

Material Science, California Institute of Technology, Pasadena, California 91125 S. M. Webb and S. Brennan, California Institute of Technology, Pasadena, California 91125 Received 17 February 2004; accepted 12, and thereby introduce oxygen vacancies into the perovskite structure. Recent studies indicate the possibility

Haile, Sossina M.

32

On the Detectability of the Hydrogen 3-cm Fine Structure Line from the EoR  

E-Print Network [OSTI]

A soft ultraviolet radiation field, 10.2 eV EoR) excites the 2p (directly) and 2s (indirectly) states of atomic hydrogen. Because the 2s state is metastable, the lifetime of atoms in this level is relatively long, which may cause the 2s state to be overpopulated relative to the 2p state. It has recently been proposed that for this reason, neutral intergalactic atomic hydrogen gas may be detected in absorption in its 3-cm fine-structure line (2s_1/2 -> 2p_3/2) against the Cosmic Microwave Background out to very high redshifts. In particular, the optical depth in the fine-structure line through neutral intergalactic gas surrounding bright quasars during the EoR may reach tau~1e-5. The resulting surface brightness temperature of tens of micro K (in absorption) may be detectable with existing radio telescopes. Motivated by this exciting proposal, we perform a detailed analysis of the transfer of Lyman beta,gamma,delta,... radiation, and re-analyze the detectability of the fine-structure line in neutral intergalactic gas surrounding high-redshift quasars. We find that proper radiative transfer modeling causes the fine-structure absorption signature to be reduced tremendously to tauEoR cannot reveal its presence in the 3-cm fine-structure line to existing radio telescopes.

Mark Dijkstra; Adam Lidz; Jonathan R. Pritchard; Lincoln J. Greenhill; D. A. Mitchell; S. M. Ord; Randal B. Wayth

2009-02-25T23:59:59.000Z

33

Crown structure, radiation absorption, photosynthesis and transpiration  

E-Print Network [OSTI]

. Among the four different structural properties studied, crown shape is least important for PAR absorption, photosynthesis and transpiration. For the Sitka spruce stand studied, transpiration was most sensitive to the total area of leaves within the tree...

Wang, Yingping

34

X-ray Absorption Spectroscopy  

E-Print Network [OSTI]

type: Review X-ray Absorption Spectroscopy Junko Yano andPhotosystem II; XAS, X-ray absorption spectroscopy; EXAFS,X-ray absorption fine structure; EPR, electron paramagnetic

Yano, Junko

2010-01-01T23:59:59.000Z

35

AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS  

E-Print Network [OSTI]

II. Extended X-ray Absorption Fine Structure (EXAFS) TheoryIII. X-ray Absorption Spectroscopy (XAS) ExperimentIII. EXTENDED X-RAY ABSORPTION FINE STRUCTURE (EXAFS) DATA

Kirby, Jon Allan

2012-01-01T23:59:59.000Z

36

Fine structure transitions of C+ in collisions with H2  

E-Print Network [OSTI]

://scitation.aip.org/content/aip/journal/jcp/62/10?ver=pdfcov Published by the AIP Publishing Articles you may be interested in ?doublet substate specific investigation of rotational and fine structure transitions in collisions of OH with H2 and D2 J. Chem. Phys. 95, 5763 (1991); 10... for Astrophysics, Harvard College Observatory and Smithsonian Astrophysical Observatory, Cambridge, Massachusetts 02138 (Received 7 November 1974) Close-coupling calculations are described of the cross sections for the fine-structure excitation of C...

Chu, Shih-I; Dalgarno, A.

1975-01-01T23:59:59.000Z

37

Fine structure in nitromethane/acetone detonations  

SciTech Connect (OSTI)

Dark waves in the detonation front of nitromethane/acetone mixtures, known for 30 years, have been photographed using pairs of image intensifier cameras, triggered at slightly different times. The photographs show the motions and changes of the complex wave structure. Intriguing results are that the average brightness doesn't change as much from center to edge as simple theory would predict, and brightness goes down rather than up when a reflected shock from a glass plate enters the explosive products. The structure remains visible in the products stagnated against a glass plate, showing that the bright regions are high temperature regions, not just areas where less absorbing material is present ahead of the emitting layer.

Davis, W.C.

1981-01-01T23:59:59.000Z

38

X-ray absorption fine structure and magnetization characterization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a measurement of the fraction of metallic Co. Any quantitative understanding of magnetism in this system needs to take account of both types of Co. Results are reported for...

39

Global Representation of the Fine Structure Constant and its Variation  

E-Print Network [OSTI]

The fine structure constant, alpha, is shown to be proportional to the ratio of the quanta of electric and magnetic flux of force of the electron, and provides a new representation, which is global across all unit systems. Consequently, a variation in alpha was shown to manifest due to a differential change in the fraction of the quanta of electric and magnetic flux of force, while a variation in hcross.c was shown to manifest due to the common mode change. The representation is discussed with respect to the running of the fine structure constant at high energies (small distances), and a putative temporal drift. It is shown that the running of the fine structure constant is due to equal components of electric screening (polarization of vacuum) and magnetic anti-screening (magnetization of vacuum), which cause the perceived quanta of electric charge to increase at small distances, while the magnetic flux quanta decreases. This introduces the concept of the bare magnetic flux quanta as well as the bare electric charge. With regards to temporal drift, it is confirmed that it is impossible to determine which fundamental constant is varying if alpha varies.

Michael Edmund Tobar

2005-02-06T23:59:59.000Z

40

Topological Quantization in Units of the Fine Structure Constant  

SciTech Connect (OSTI)

Fundamental topological phenomena in condensed matter physics are associated with a quantized electromagnetic response in units of fundamental constants. Recently, it has been predicted theoretically that the time-reversal invariant topological insulator in three dimensions exhibits a topological magnetoelectric effect quantized in units of the fine structure constant {alpha} = e{sup 2}/{h_bar}c. In this Letter, we propose an optical experiment to directly measure this topological quantization phenomenon, independent of material details. Our proposal also provides a way to measure the half-quantized Hall conductances on the two surfaces of the topological insulator independently of each other.

Maciejko, Joseph; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Qi, Xiao-Liang; /Station Q, UCSB /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC; Drew, H.Dennis; /Maryland U.; Zhang, Shou-Cheng; /Stanford U., Phys. Dept. /Stanford U., Materials Sci. Dept. /SLAC

2011-11-11T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Solar Radio Bursts with Spectral Fine Structures in Preflares  

E-Print Network [OSTI]

A good observation of preflare activities is important for us to understand the origin and triggering mechanism of solar flares, and to predict the occurrence of solar flares. This work presents the characteristics of microwave spectral fine structures as preflare activities of four solar flares observed by Ond\\v{r}ejov radio spectrograph in the frequency range of 0.8--2.0 GHz. We found that these microwave bursts which occurred 1--4 minutes before the onset of flares have spectral fine structures with relatively weak intensities and very short timescales. They include microwave quasi-periodic pulsations (QPP) with very short period of 0.1-0.3 s and dot bursts with millisecond timescales and narrow frequency bandwidths. Accompanying these microwave bursts, there are filament motions, plasma ejection or loop brightening on the EUV imaging observations and non-thermal hard X-ray emission enhancements observed by RHESSI. These facts may reveal certain independent non-thermal energy releasing processes and partic...

Zhang, Yin; Karlick, Marian; Mszrosov, Hana; Huang, Jing; Tan, Chengming; Simes, Paulo

2014-01-01T23:59:59.000Z

42

Hydrogen Atom and Time Variation of Fine-Structure Constant  

E-Print Network [OSTI]

In this paper, we have solved the de Sitter special relativistic ($\\mathcal{SR}_{cR}$-) Dirac equation of hydrogen in the earth-QSO(quasar) framework reference by means of the adiabatic approach. The aspects of geometry effects of de Sitter space-time described by Beltrami metric are explored and taken into account. It is found that the $\\mathcal{SR}_{cR}$-Dirac equation of hydrogen is a time dependent quantum Hamiltonian system. We provide an explicit calculation to justify the adiabatic approach in dealing with this time-dependent system. Since the radius of de Sitter sphere $R$ is cosmologically large, the evolution of the system is very slow so that the adiabatic approximation legitimately works with high accuracy. We conclude that the electromagnetic fine-structure constant, the electron mass and the Planck constant are time variations. This prediction of fine-structure constant is consistent with the presently available observation data. For confirming it further, experiments/observations are required.

Mu-Lin Yan

2009-11-21T23:59:59.000Z

43

$f(T)$ Theories and Varying Fine Structure Constant  

E-Print Network [OSTI]

In analogy to $f(R)$ theory, recently $f(T)$ theory has been proposed to drive the current accelerated expansion without invoking dark energy. In the literature, the observational constraints on $f(T)$ theories were obtained mainly by using the cosmological data, such as type Ia supernovae (SNIa), baryon acoustic oscillation (BAO), and cosmic microwave background radiation (CMB). In this work, we instead try to constrain $f(T)$ theories with the varying fine structure "constant", $\\alpha\\equiv e^2/\\hbar c$. We find that the constraints on $f(T)$ theories from the observational $\\Delta\\alpha/\\alpha$ data are very severe. In fact, they make $f(T)$ theories almost indistinguishable from $\\Lambda$CDM model.

Wei, Hao; Qi, Hao-Yu

2011-01-01T23:59:59.000Z

44

Gravitation, the 'Dark Matter' Effect and the Fine Structure Constant  

E-Print Network [OSTI]

Gravitational anomalies such as the mine/borehole g anomaly, the near-flatness of the spiral galaxy rotation-velocity curves, currently interpreted as a `dark matter' effect, the absence of that effect in ordinary elliptical galaxies, and the ongoing problems in accurately determining Newton's gravitational constant G_N are explained by a generalisation of the Newtonian theory of gravity to a fluid-flow formalism with one new dimensionless constant. By analysing the borehole data this constant is shown to be the fine structure constant alpha=1/137. The spiral galaxy `dark matter' effect and the globular cluster `black hole' masses are then correctly predicted. This formalism also explains the cause of the long-standing uncertainties in G_N and leads to the introduction of a fundamental gravitational constant G not = G_N with value G=(6.6526 +/- 0.013)x 10^-11 m^3s^{-2}kg^{-1}. The occurrence of alpha implies that space has a quantum structure, and we have the first evidence of quantum gravity effects.

Reginald T. Cahill

2005-04-07T23:59:59.000Z

45

HEP/123-qed Fine structure of alpha decay in odd nuclei  

E-Print Network [OSTI]

Using an ? decay level scheme, the fine structure in odd nuclei is explained by taking into account the radial and rotational couplings between the unpaired valence nucleon and the core of the decaying system. It is shown that the experimental behavior of the ? decay fine structure phenomenon is governed by the dynamical characteristics of the system.

M. Mirea

2000-01-01T23:59:59.000Z

46

AN ATLAS-BASED DEEP BRAIN STRUCTURE SEGMENTATION METHOD: FROM COARSE POSITIONING TO FINE SHAPING  

E-Print Network [OSTI]

AN ATLAS-BASED DEEP BRAIN STRUCTURE SEGMENTATION METHOD: FROM COARSE POSITIONING TO FINE SHAPING Segmentation of deep brain structures is a challenging task for MRI images due to blurry structure boundaries brain structures and determine an optimal sequence for the structure- by-structure segmentation. After

Chung, Albert C. S.

47

An in-situ cell for characterization of solids by soft X-ray absorption  

E-Print Network [OSTI]

Scientific Instruments a Absorption (a.u. ) b d 0.01 abs cJ. Lynch, in X-ray Absorption Fine Structure for Catalysts18, pp. 431-512. X-ray Absorption: Principles, Applications,

2007-01-01T23:59:59.000Z

48

X-ray Absorption Spectroscopy Study of Prototype Chemical Systems: Theory vs. Experiment  

E-Print Network [OSTI]

acids by Near Edge X-ray Absorption Fine Structure (NEXAFS)X-ray Absorption Spectroscopy Study of Prototype ChemicalGlaeser Spring 2010 X-ray Absorption Spectroscopy Study of

Schwartz, Craig Philip

2010-01-01T23:59:59.000Z

49

New Measurement Explores Fine Details of Proton Structure | Jefferson Lab  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the Contributions andDataNational Library of1,DepartmentMeasurement Explores Fine Details

50

Optical Absorption, Stability and Structure of NpO2+ Complexes with Dicarboxylic Acids  

E-Print Network [OSTI]

Np(V)/IDA complex, the absorption band still shows, but theOptical Absorption, Stability and Structure of NpO 2+and the intensity of the absorption band of NpO 2+ at 980 nm

Guoxin Tian; Linfeng Rao

2006-01-01T23:59:59.000Z

51

X-ray absorption study of the electronic structure of Mn-doped amorphous Si  

E-Print Network [OSTI]

X-ray absorption study of the electronic structure of Mn-?x ) is studied by X-ray absorption spectroscopy at the Mn Land featureless L 3,2 absorption peaks, corresponding to an

Zeng, Li

2008-01-01T23:59:59.000Z

52

Fine scale structural variants distinguish the genomes of Drosophilia melanogaster and D. pseudoobscura  

E-Print Network [OSTI]

RESEARCH Open Access Fine scale structural variants distinguish the genomes of Drosophila melanogaster and D. pseudoobscura Stuart J Macdonald* and Anthony D Long Abstract Background: A primary objective of comparative genomics is to identify... genomic elements of functional significance that contribute to phenotypic diversity. Complex changes in genome structure (insertions, duplications, rearrangements, translocations) may be widespread, and have important effects on organismal diversity. Any...

Macdonald, Stuart J.

2006-07-07T23:59:59.000Z

53

Fine structures in the atmosphere above a sunspot umbra  

E-Print Network [OSTI]

We present simultaneous photospheric and chromospheric observations of the trailing sunspot in NOAA 10904, obtained with the Swedish Solar Telescope (SST) La Palma, Canary Islands. Time series of high resolution \\ion{Ca}{ii}\\,$H$ images show transient jet-like structures in sunspot umbrae are elongated, which we call umbral microjets. These jets are directed roughly parallel to nearby penumbral microjets, suggesting that they are aligned with the background magnetic field. In general, first a bright dot-like structure appears, from which a jet later emerges, although some jets appear without an associated chromospheric dot. Bright photospheric umbral dots are associated with umbral microjets arising in the outer umbra. Nevertheless, a one-to-one correspondence between jet-like events and underlying umbral dots is not seen. They are typically less than 1\\arcsec ~long and less than 0\\farcs3 wide. The typical lifetime of umbral microjets is around one minute. The brightness of these structures increases from the...

Bharti, L; Solanki, S K

2013-01-01T23:59:59.000Z

54

E-Print Network 3.0 - absorption difference spectra Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: these spectra show a large difference of the fine structure near the absorption edges of the inner atomic shells... . One of the specific feature of the...

55

New rest wavelength determinations for 7 mid-infrared fine structure lines by ISO-SWS  

E-Print Network [OSTI]

Observations of the planetary nebulae NGC6302, NGC6543 and NGC7027 by the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO) have been used to determine rest wavelengths of spectral lines. We report on improved accuracies for wavelengths of 7 mid-infrared ionic fine structure lines.

H. Feuchtgruber; D. Lutz; D. A. Beintema

2001-05-15T23:59:59.000Z

56

Fine Structure of the Solar Wind Turbulence Inferred from Simultaneous Radio Occultation Observations at  

E-Print Network [OSTI]

Fine Structure of the Solar Wind Turbulence Inferred from Simultaneous Radio Occultation Observations at Widely-Spaced Ground Stations M.K. Bird , P. Janardhan , A.I. Efimov, L.N. Samoznaev, V extended for up to four hours, thereby allowing studies of solar wind turbulence dynamics at spatial scales

Padmanabhan, Janardhan

57

X-ray absorption spectroscopy elucidates the impact of structural disorder on electron mobility in amorphous zinc-tin-oxide thin films  

SciTech Connect (OSTI)

We investigate the correlation between the atomic structures of amorphous zinc-tin-oxide (a-ZTO) thin films grown by atomic layer deposition (ALD) and their electronic transport properties. We perform synchrotron-based X-ray absorption spectroscopy at the K-edges of Zn and Sn with varying [Zn]/[Sn] compositions in a-ZTO thin films. In extended X-ray absorption fine structure (EXAFS) measurements, signal attenuation from higher-order shells confirms the amorphous structure of a-ZTO thin films. Both quantitative EXAFS modeling and X-ray absorption near edge spectroscopy (XANES) reveal that structural disorder around Zn atoms increases with increasing [Sn]. Field- and Hall-effect mobilities are observed to decrease with increasing structural disorder around Zn atoms, suggesting that the degradation in electron mobility may be correlated with structural changes.

Siah, Sin Cheng, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu; Lee, Yun Seog; Buonassisi, Tonio, E-mail: siahsincheng@gmail.com, E-mail: buonassisi@mit.edu [Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Lee, Sang Woon; Gordon, Roy G. [Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138 (United States); Heo, Jaeyeong [Department of Materials Science and Engineering, Chonnam National University, Gwangju 500-757 (Korea, Republic of); Shibata, Tomohiro; Segre, Carlo U. [Physics Department and CSRRI, Illinois Institute of Technology, Chicago, Illinois 606016 (United States)

2014-06-16T23:59:59.000Z

58

Fine structure of the isovector giant dipole resonance in 208Pb: Characteristic scales and level densities  

E-Print Network [OSTI]

The IVGDR in 208Pb has been measured with high energy resolution with the (p,p') reaction under extreme forward angles and shows considerable fine structure. Characteristic scales are extracted from the spectra with a wavelet analysis based on continuous wavelet transforms. Comparison with corresponding analyses of B(E1) strength distributions from microscopic model calculations in the framework of the QPM and relativistic RPA allow to identify giant resonance decay mechanisms responsible for the fine structure. The level density of 1- states can be related to local fluctuations of the cross sections in the energy region of the IVGDR. The magnitude of the fluctuations is determined by the autocorrelation function. Scales in the fine structure of the IVGDR in 208Pb are found at 80, 130, 220, 430, 640, 960 keV, and at 1.75 MeV. The values of the most prominent scales can be reasonably well reproduced by the microscopic calculations although they generally yield a smaller number of scales. In both models the major scales are already present at the one-particle one-hole level indicating Landau damping as a dominant mechanism responsible for the fine structure of the IVGDR in contrast to the isoscalar giant quadrupole resonance, where fine structure arises from the coupling to low-lying surface vibrations. The inclusion of complex configurations in the calculations changes the E1 strength distributions but the impact on the wavelet power spectra and characteristic scales is limited. The level density of 1- states is extracted in the excitation energy range 9-12.5 MeV and compared to a variety of phenomenological and microscopic models. The back-shifted Fermi gas model parameterization of Rauscher et al., Phys. Rev. C 56, 1613 (1997) describes the level-density data well, while other phenomeological and microscopic approaches fail to reproduce absolute values or the energy dependence or both.

I. Poltoratska; R. W. Fearick; A. M. Krumbholz; E. Litvinova; H. Matsubara; P. von Neumann-Cosel; V. Yu. Ponomarev; A. Richter; A. Tamii

2014-05-19T23:59:59.000Z

59

Possible variations of the fine structure constant $?$ and their metrological significance  

E-Print Network [OSTI]

We briefly review the recent experimental results on possible variations of the fine structure constant $\\alpha$ on the cosmological time scale and its position dependence. We outline the theoretical grounds for the assumption that $\\alpha$ might be variable, mention some phenomenological models incorporating a variable $\\alpha$ into the context of modern cosmology and discuss the significance of possible $\\alpha$ variations for theoretical and practical metrology.

K. A. Bronnikov; S. A. Kononogov

2006-09-03T23:59:59.000Z

60

Suppression of fine-structure splitting and oscillator strength of sodium D-line in a Debye plasma  

SciTech Connect (OSTI)

We investigate theoretically the influence of static plasma screening on relativistic spin-orbit interaction-induced fine-structure splitting of the D-line doublet arising from the transitions 3p{sub 1/2}3s{sub 1/2} and 3p{sub 3/2}3s{sub 1/2} of the valence electron of a sodium atom embedded in a model plasma environment. The many-electron atomic problem is formulated first as an effective one-electron problem in which the interaction between the optically active valence electron and the atomic ion core is represented by an accurate parametric model potential including core-polarization correction, and then the plasma effect on the atomic system is simulated by the Debye-screening model for the valence-core interaction. It is observed that the magnitude of spin-orbit energy shift reduces for both the upper component 3p{sub 3/2} and the lower component 3p{sub 1/2} with increasing plasma screening strength, thereby reducing the spin-orbit energy separation between these two components as the screening becomes stronger. As a consequence, the magnitude of fine-structure splitting between the D{sub 1} and D{sub 2} line energies of sodium drops significantly with stronger plasma screening. The optical (absorption) oscillator strength for 3s ? 3p transition is seen to reduce with stronger screening and this leads to a screening-induced gradual suppression of the 3p ? 3s spontaneous decay rate.

Basu, Joyee, E-mail: joyeebasu@yahoo.com; Ray, Debasis, E-mail: ray.debasis@gmail.com [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)] [Department of Physics, Bengal Engineering and Science University, Shibpur, Howrah, West Bengal 711 103 (India)

2014-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Band structures Optical absorption Summary Key concepts in Density Functional Theory (II)  

E-Print Network [OSTI]

Band structures Optical absorption Summary Key concepts in Density Functional Theory (II) Kohn, Belfast Key concepts in Density Functional Theory (II) Silvana Botti #12;Band structures Optical in Density Functional Theory (II) Silvana Botti #12;Band structures Optical absorption Summary Outline 1 From

Botti, Silvana

62

Low-energy fine-structure resonances in photoionization of O ii  

SciTech Connect (OSTI)

Resonant features in low-energy photoionization cross sections are reported in coupled-channel calculations for O ii including relativistic fine structure. The calculations reveal extensive near-threshold resonant structures in the small energy region between the fine structure levels of the ground state 2p{sup 2}({sup 3}P{sub 0,1,2}) of the residual ion O iii. Although the resonances have not yet been observed, they are similar to other experimentally observed features. They are expected to significantly enhance the very-low-temperature dielectronic recombination rates, potentially leading to the resolution of an outstanding nebular abundances anomaly. Higher energy partial and total photoionization cross sections of the ground configuration levels 2p{sup 3}({sup 4}S{sub 3/2}{sup o},{sup 2}D{sub 3/2,5/2}{sup o},{sup 2}P{sub 1/2,3/2}{sup o}) are found to be in agreement with experimental measurements on synchrotron-based photon sources [1-3], thereby identifying the excited O iii levels present in the ion beams. These are also the first results from a recently developed version of Breit-Pauli R-matrix (BPRM) codes, with inclusion of two-body magnetic interaction terms. The improved relativistic treatment could be important for other astrophysical applications and for more precise benchmarking of experimental measurements.

Nahar, Sultana N.; Pradhan, Anil K. [Department of Astronomy, Ohio State University, Columbus, Ohio 43210 (United States); Montenegro, Maximiliano [Facultad de Educaci, Pontificia Universidad Catholica de Chile, Avda Vicua Mackenna 4860, Macul, Santiago (Chile); Eissner, Werner [Institut fuer Theoretische Physik, Teilinstitut 1, D-70550 Stuttgart (Germany)

2010-12-15T23:59:59.000Z

63

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption  

E-Print Network [OSTI]

Quantification of rapid environmental redox processes with quick-scanning x-ray absorption. Here we apply quick-scanning x-ray absorption spectroscopy (Q-XAS), at sub-second time that can be measured using x-ray absorption spectroscopy. arsenic extended x-ray absorption fine structure

Sparks, Donald L.

64

The Fine-Structure of the Net-Circular Polarization in a Sunspot Penumbra  

E-Print Network [OSTI]

We present novel evidence for a fine structure observed in the net-circular polarization (NCP) of a sunspot penumbra based on spectropolarimetric measurements utilizing the Zeeman sensitive FeI 630.2 nm line. For the first time we detect a filamentary organized fine structure of the NCP on spatial scales that are similar to the inhomogeneities found in the penumbral flow field. We also observe an additional property of the visible NCP, a zero-crossing of the NCP in the outer parts of the center-side penumbra, which has not been recognized before. In order to interprete the observations we solve the radiative transfer equations for polarized light in a model penumbra with embedded magnetic flux tubes. We demonstrate that the observed zero-crossing of the NCP can be explained by an increased magnetic field strength inside magnetic flux tubes in the outer penumbra combined with a decreased magnetic field strength in the background field. Our results strongly support the concept of the uncombed penumbra.

A. Tritschler; D. A. N. Mueller; R. Schlichenmaier; H. J. Hagenaar

2007-10-24T23:59:59.000Z

65

Photoluminescence and Extended X-ray Absorption Fine Structure Studies on CdTe Material.  

E-Print Network [OSTI]

??The direct-band-gap semiconductor CdTe is an important material for fabricating high efficiency, polycrystalline thin-film solar cells in a heterojunction configuration. The outstanding physical properties of (more)

Liu, Xiangxin

2006-01-01T23:59:59.000Z

66

Speciation of arsenic in pyrite by micro-X-ray absorption fine- structure spectroscopy (XAFS)  

SciTech Connect (OSTI)

Pyrite (FeS2) often contains variable levels of arsenic, regardless of the environment of formation. Arsenian pyrite has been reported in coals, sediments and ore deposits. Arsenian pyrite having As concentrations of up to 10 wt % in sedimentary rocks (Kolker et al. 1997), about 10 wt% in gold deposits (Fleet et al. 1993), 12 wt % in a refractory gold ore (Paktunc et al. 2006) and 20 wt % in a Carlin-type gold deposit in Nevada (Reich et al. 2005) have been reported. Arsenian pyrite is the carrier of gold in hydrothermal Carlin-type gold deposits, and gold concentrations of up to 0.9 wt % have been reported (Reich et al. 2005; Paktunc et al. 2006). In general, high Au concentrations correlate with As-rich zones in pyrite (Paktunc et al. 2006). Pyrite often ends up in mining and metallurgical wastes as an unwanted mineral and consititutes one of the primary sources of As in the wastes. Arsenic can be readily released to the environment due to rapid oxidative dissolution of host pyrite under atmospheric conditions. Pyrite is also the primary source of arsenic in emissions and dust resulting from combustion of bituminous coals. Despite the importance of arsenian pyrite as a primary source of anthropogenic arsenic in the environment and its economic significance as the primary carrier of gold in Carlin-type gold deposits, our understanding of the nature of arsenic in pyrite is limited. There are few papers dealing with the mode of occurrence of arsenic by bulk XAFS in a limited number of pyrite-bearing samples. The present study documents the analysis of pyrite particles displaying different morphologies and a range of arsenic and gold concentrations to determine the nature and speciation of arsenic.

Paktunc, D. (CCM)

2008-09-30T23:59:59.000Z

67

X-ray absorption fine structure and magnetization characterization of the  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1of EnergyX-rayNew Materials formetallic

68

Fine and hyperfine structure of P-levels in muonic hydrogen  

E-Print Network [OSTI]

Corrections of orders $\\alpha^5$ and $\\alpha^6$ are calculated in the fine structure interval $\\Delta E^{fs}=E(2P_{3/2})-E(2P_{1/2})$ and in the hyperfine structure of the energy levels $2P_{1/2}$ and $2P_{3/2}$ in muonic hydrogen. The obtained numerical values $\\Delta E^{fs}= 8352.08 \\mu eV$, $\\Delta \\tilde E^{hfs}(2P_{1/2})=7964.36 \\mu eV$, $\\Delta \\tilde E^{hfs}(2P_{3/2})=3392.59 \\mu eV$ can be considered as a reliable estimate for the comparison with corresponding experimental data and for the extraction of the experimental value of the Lamb shift $(2P-2S)$ in muonic hydrogen.

A. P. Martynenko

2006-10-25T23:59:59.000Z

69

E-Print Network 3.0 - atomic scale structure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic scale structure Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

70

Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Efficiency  

E-Print Network [OSTI]

Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Doped Fiber Amplifier. With proper adjustments on doping profiles for the reduction of pump absorption rate, it becomes possible to optimize pump evolution map inside the doped fiber to get better power

Park, Namkyoo

71

Highly charged ions for atomic clocks and search for variation of the fine structure constant  

E-Print Network [OSTI]

We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons, the Ir$^{17+}$ ion, which has a hole in almost filled $4f$ subshell, the Ho$^{14+}$, Cf$^{15+}$, Es$^{17+}$ and Es$^{16+}$ ions. Clock transitions in most of these ions are sensitive to variation of the fine structure constant, $\\alpha$ ($\\alpha = e^2/\\hbar c$). E.g., californium and einsteinium ions have largest known sensitivity to $\\alpha$-variation while holmium ion looks as the most suitable ion for experimental study. We study the spectra of the ions and their features relevant to the use as frequency standards.

Dzuba, V A

2015-01-01T23:59:59.000Z

72

The variation of the fine structure constant: testing the dipole model with thermonuclear supernovae  

E-Print Network [OSTI]

The large-number hypothesis conjectures that fundamental constants may vary. Accordingly, the spacetime variation of fundamental constants has been an active subject of research for decades. Recently, using data obtained with large telescopes a phenomenological model in which the fine structure constant might vary spatially has been proposed. We test whether this hypothetical spatial variation of {\\alpha}, which follows a dipole law, is compatible with the data of distant thermonuclear supernovae. Unlike previous works, in our calculations we consider not only the variation of the luminosity distance when a varying {\\alpha} is adopted, but we also take into account the variation of the peak luminosity of Type Ia supernovae resulting from a variation of {\\alpha}. This is done using an empirical relation for the peak bolometric magnitude of thermonuclear supernovae that correctly reproduces the results of detailed numerical simulations. We find that there is no significant difference between the several phenome...

Kraiselburd, Lucila; Negrelli, Carolina; Berro, Enrique Garca

2014-01-01T23:59:59.000Z

73

Role of defects in BiFeO{sub 3} multiferroic films and their local electronic structure by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Present study reports the role of defects in the electrical transport in BiFeO{sub 3} (BFO) multiferroic films and its local electronic structure investigated by near-edge X-ray absorption fine structure. Defects created by high energy 200?MeV Ag{sup +15} ion irradiation with a fluence of ?5??10{sup 11} ions/cm{sup 2} results in the increase in structural strain and reduction in the mobility of charge carriers and enhancement in resistive (I-V) and polarization (P-E) switching behaviour. At higher fluence of ?5??10{sup 12} ions/cm{sup 2}, there is a release in the structural strain due to local annealing effect, resulting in an increase in the mobility of charge carriers, which are released from oxygen vacancies and hence suppression in resistive and polarization switching. Near-edge X-ray absorption fine structure studies at Fe L{sub 3,2}- and O K-edges show a significant change in the spectral features suggesting the modifications in the local electronic structure responsible for changes in the intrinsic magnetic moment and electrical transport properties of BFO.

Ravalia, Ashish; Vagadia, Megha; Solanki, P. S.; Shah, N. A.; Kuberkar, D. G., E-mail: dgkuberkar@rediffmail.com [Department of Physics, Saurashtra University, Rajkot 360 005 (India); Gautam, S.; Chae, K. H. [Nano Material Analysis Centre, Korean Institute of Science and Technology, Seoul 136-79 (Korea, Republic of); Asokan, K. [Inter University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

2014-10-21T23:59:59.000Z

74

DIRECT IMAGING OF FINE STRUCTURE IN THE CHROMOSPHERE OF A SUNSPOT UMBRA  

SciTech Connect (OSTI)

High-resolution imaging observations from the Hinode spacecraft in the Ca II H line are employed to study the dynamics of the chromosphere above a sunspot. We find that umbral flashes and other brightenings produced by the oscillation are extremely rich in fine structure, even beyond the resolving limit of our observations (0.''22). The umbra is tremendously dynamic to the point that our time cadence of 20 s does not suffice to resolve the fast lateral (probably apparent) motion of the emission source. Some bright elements in our data set move with horizontal propagation speeds of 30 km s{sup -1}. We have detected filamentary structures inside the umbra (some of which have a horizontal extension of {approx}1500 km) which, to our best knowledge, had not been reported before. The power spectra of the intensity fluctuations reveal a few distinct areas with different properties within the umbra that seem to correspond with the umbral cores that form it. Inside each one of these areas the dominant frequencies of the oscillation are coherent, but they vary considerably from one core to another.

Socas-Navarro, H. [Instituto de AstrofIsica de Canarias, Avda VIa Lactea S/N, La Laguna 38200, Tenerife (Spain); McIntosh, S. W.; Centeno, R.; De Wijn, A. G.; Lites, B. W. [High Altitude Observatory, NCAR , 3080 Center Green Drive, Boulder, CO 80301 (United States)], E-mail: hsocas@iac.es

2009-05-10T23:59:59.000Z

75

Direct Imaging of Fine Structure in the Chromosphere of a Sunspot Umbra  

E-Print Network [OSTI]

High-resolution imaging observations from the Hinode spacecraft in the CaII H line are employed to study the dynamics of the chromosphere above a sunspot. We find that umbral flashes and other brightenings produced by the oscillation are extremely rich in fine structure, even beyond the resolving limit of our observations (0.22"). The umbra is tremendously dynamic, to the point that our time cadence of 20 s does not suffice to resolve the fast lateral (probably apparent) motion of the emission source. Some bright elements in our dataset move with horizontal propagation speeds of 30 km/s. We have detected filamentary structures inside the umbra (some of which have a horizontal extension of ~1500 km) which, to our best knowledge, had not been reported before. The power spectra of the intensity fluctuations reveals a few distinct areas with different properties within the umbra that seem to correspond with the umbral cores that form it. Inside each one of these areas the dominant frequencies of the oscillation are coherent, but they vary considerably from one core to another.

H. Socas-Navarro; S. W. McIntosh; R. Centeno; A. G. de Wijn; B. W. Lites

2008-11-19T23:59:59.000Z

76

Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid  

E-Print Network [OSTI]

It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface.

Dmitri K. Gramotnev; Melissa L. Mather; Timo A. Nieminen

2005-09-05T23:59:59.000Z

77

Solving the structure of reaction intermediates by time-resolved synchrotron x-ray absorption spectroscopy  

E-Print Network [OSTI]

metal oxides CuO,1 Cu-ceria,2 Au-ceria,3 and Cu­MoO2 Ref. 4 in water-gas- shift reactions. Another area catalysts where we detected reaction intermediates and measured fine details of the reaction kinetics and 12 have been also applied to study intermediate state structure and deter- mine reaction kinetic

Frenkel, Anatoly

78

Bohr - Planck quantum theory, (Tesla) magnetic monopoles and fine structure constant  

E-Print Network [OSTI]

In this work we apply Bohr-Planck (Old quantum atomic and radiation) theory, i.e. and quasi-classical methods for analysis of the magnetic monopoles and other problems. We reproduce exactly some basic elements of the Dirac magnetic monopoles theory, especially Dirac electric/magnetic charge quantization condition. Also, we suggest a new, effective, simply called Tesla model (for analogy with positions of the solenoids by Tesla inductive motor) of the magnetic monopole instead of usual effective Dirac model (half-infinite, very tinny solenoid) of the magnetic monopole. In our, i.e. Tesla model we use three equivalent tiny solenoids connected in series with a voltage source. One end of any solenoid is placed at the circumference of a circle and solenoids are directed radial toward circle center. Length of any solenoid is a bit smaller than finite circle radius so that other end of any solenoid is very close to the circle center. Angles between neighboring solenoids equal $120^{\\circ}$. All this implies that, practically, there is no magnetic field, or, magnetic pole, e.g. $S$, in the circle center, and that whole system holds only other, $N$ magnetic pole, at the ends of the solenoids at circle circumference. Finally, we reproduce relatively satisfactory value of the fine structure constant using Planck, i.e. Bose-Einstein statistics and Wien displacement law.

Vladan Pankovic; Darko V. Kapor; Stevica Djurovic; Miodrag Krmar

2014-10-17T23:59:59.000Z

79

Fine-scale Horizontal Structure of Arctic Mixed-Phase Clouds.  

SciTech Connect (OSTI)

Recent in situ observations in stratiform clouds suggest that mixed phase regimes, here defined as limited cloud volumes containing both liquid and solid water, are constrained to narrow layers (order 100 m) separating all-liquid and fully glaciated volumes (Hallett and Viddaurre, 2005). The Department of Energy Atmospheric Radiation Measurement Program's (DOE-ARM, Ackerman and Stokes, 2003) North Slope of Alaska (NSA) ARM Climate Research Facility (ACRF) recently started collecting routine measurement of radar Doppler velocity power spectra from the Millimeter Cloud Radar (MMCR). Shupe et al. (2004) showed that Doppler spectra has potential to separate the contributions to the total reflectivity of the liquid and solid water in the radar volume, and thus to investigate further Hallett and Viddaurre's findings. The Mixed-Phase Arctic Cloud Experiment (MPACE) was conducted along the NSA to investigate the properties of Arctic mixed phase clouds (Verlinde et al., 2006). We present surface based remote sensing data from MPACE to discuss the fine-scale structure of the mixed-phase clouds observed during this experiment.

Rambukkange,M.; Verlinde, J.; Elorante, E.; Luke, E.; Kollias, P.; Shupe, M.

2006-07-10T23:59:59.000Z

80

Semiconductor quantum dots with light-hole exciton ground state: fabrication and fine structure  

E-Print Network [OSTI]

Quantum dots (QDs) can act as convenient hosts of two-level quantum szstems, such as single electron spins, hole spins or excitons (bound electron-hole pairs). Due to quantum confinement, the ground state of a single hole confined in a QD usually has dominant heavy-hole (HH) character. For this reason light-hole (LH) states have been largely neglected, despite the fact that may enable the realilzation of coherent photon-to-spin converters or allow for faster spin manipulation compared to HH states. In this work, we use tensile strains larger than 0.3% to switch the ground state of excitons confined in high quality GaAs/AlGaAs QDs from the conventional HH- to LH-type. The LH-exciton fine structure is characterized by two in-plane-polarized lines and, ~400 micro-eV above them, by an additional line with pronounced out-of-plane oscillator strength, consistent with theoretical predictions based on atomistic empirical pseudopotential calculations and a simple mesoscopic model.

Y. H. Huo; B. J. Witek; S. Kumar; R. Singh; E. Zallo; R. Grifone; D. Kriegner; R. Trotta; N. Akopian; J. Stangl; V. Zwiller; G. Bester; A. Rastelli; O. G. Schmidt

2012-08-31T23:59:59.000Z

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81

X-ray absorption anisotropy for polychromatic illumination--Crystal views from inside  

E-Print Network [OSTI]

X-ray absorption anisotropy for polychromatic illumination--Crystal views from inside P. Korecki a Keywords: X-ray absorption Real-space imaging X-ray holography Electron channeling Electron backscatter of the fine structure in X-ray absorption anisotropy, which results from incident beam diffraction

Korecki, Pawe³

82

Structure and Mass Absorption of Hypothetical Terrestrial Black Holes  

E-Print Network [OSTI]

The prospect of mini black holes, either primordial or in planned experiments at the Large Hadron Collider, interacting with the earth motivate us to examine how they may be detected and the scope of their impact on the earth. We propose that the more massive of these objects may gravitationally bind matter without significant absorption. Since the wave functions of gravitationally bound atoms orbiting a black hole are analogous to those of electrons around a nucleus, we call such an object the Gravitationally Equivalent of an Atom (GEA). Mini black holes are expected to lose mass through quantum evaporation, which has become well accepted on purely theoretical grounds. Since all attempts to directly observe x-rays from an evaporating black hole have failed, we examine the possibility of the inverse test: search for extant mini black holes by looking for emissions from matter bound in a GEA. If quantum evaporation does not occur, then miniature black holes left over from the early universe may be stable, contribute to dark matter, and in principle be detectable through emissions associated with the bound matter. We show that small black holes-with masses below \\sim10^12 kg-can bind matter without readily absorbing it into the black hole but the emissions are too weak to be detected from earth.

A. P. VanDevender; J. Pace VanDevender

2011-05-02T23:59:59.000Z

83

X-ray absorption studies of the local structure and f-level occupancy in CeIr(1-x)Rh(x)In(5)  

SciTech Connect (OSTI)

The CeIr{sub 1-x}Rh{sub x}In{sub 5} series exhibits a range of interesting phenomena, including heavy-fermion superconductivity, non-Fermi liquid behavior, and concomitant antiferromagnetism (AF) and superconductivity (SC). In the low-Rh concentration range (0.1 {ge} x {ge} 0.5), specific heat measurements show a broad anomaly, suggestive of gross phase separation. We have performed x-ray absorption experiments at the Ce L{sub III}, Ir L{sub III}, and Rh K-edges as a function of Rh concentration and temperature. X-ray absorption near-edge structure (XANES) measurements indicate that cerium is close to trivalent in this system, with no measurable change with temperature from 20-300 K, consistent with a heavy-fermion material. Extended x-ray absorption fine structure (EXAFS) measurements as a function of temperature from all measured edges indicate the local crystal structure of all samples is well ordered, with no gross phase separation observed, even for samples with x = 0.125 and x = 0.25. These results therefore suggest that the anomalous specific heat behavior in the 0.1 {ge} x {ge} 0.5 range have some other explanation, and some possibilities are discussed.

Daniel, M.; Han, S.-W.; Booth, C.H.; Cornelius, A.L.; Pagliuso, P.G.; Sarrao, J.L.; Thompson, J.D.

2004-04-15T23:59:59.000Z

84

absorption near-edge structure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption near-edge structure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Effect of Intermolecular...

85

absorption pre-edge structures: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption pre-edge structures First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Temperature dependence...

86

FAR-INFRARED FINE-STRUCTURE LINE DIAGNOSTICS OF ULTRALUMINOUS INFRARED GALAXIES  

SciTech Connect (OSTI)

We present Herschel observations of 6 fine-structure lines in 25 ultraluminous infrared galaxies at z < 0.27. The lines, [O III]52 ?m, [N III]57 ?m, [O I]63 ?m, [N II]122 ?m, [O I]145 ?m, and [C II]158 ?m, are mostly single Gaussians with widths <600 km s{sup 1} and luminosities of 10{sup 7}-10{sup 9} L{sub ?}. There are deficits in the [O I]63/L{sub IR}, [N II]/L{sub IR}, [O I]145/L{sub IR}, and [C II]/L{sub IR} ratios compared to lower luminosity systems. The majority of the line deficits are consistent with dustier H II regions, but part of the [C II] deficit may arise from an additional mechanism, plausibly charged dust grains. This is consistent with some of the [C II] originating from photodissociation regions or the interstellar medium (ISM). We derive relations between far-IR line luminosities and both the IR luminosity and star formation rate. We find that [N II] and both [O I] lines are good tracers of the IR luminosity and star formation rate. In contrast, [C II] is a poor tracer of the IR luminosity and star formation rate, and does not improve as a tracer of either quantity if the [C II] deficit is accounted for. The continuum luminosity densities also correlate with the IR luminosity and star formation rate. We derive ranges for the gas density and ultraviolet radiation intensity of 10{sup 1} < n < 10{sup 2.5} and 10{sup 2.2} < G{sub 0} < 10{sup 3.6}, respectively. These ranges depend on optical type, the importance of star formation, and merger stage. We do not find relationships between far-IR line properties and several other parameters: active galactic nucleus (AGN) activity, merger stage, mid-IR excitation, and SMBH mass. We conclude that these far-IR lines arise from gas heated by starlight, and that they are not strongly influenced by AGN activity.

Farrah, D.; Petty, S. M.; Harris, K. [Department of Physics, Virginia Tech, Blacksburg, VA 24061 (United States); Lebouteiller, V.; Spoon, H. W. W. [Cornell University, CRSR, Space Sciences Building, Ithaca, NY 14853 (United States); Bernard-Salas, J.; Pearson, C. [Department of Physics and Astronomy, The Open University, Milton Keynes MK7 6AA (United Kingdom); Rigopoulou, D. [RAL Space, Rutherford Appleton Laboratory, Harwell, Oxford OX11 0QX (United Kingdom); Smith, H. A. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Gonzlez-Alfonso, E. [Universidad de Alcal, Departamento de Fsica y Matemticas, Campus Universitario, E-28871 Alcal de Henares, Madrid (Spain); Clements, D. L. [Physics Department, Imperial College London, Prince Consort Road, London SW7 2AZ (United Kingdom); Efstathiou, A. [School of Sciences, European University Cyprus, Diogenes Street, Engomi, 1516 Nicosia (Cyprus); Cormier, D. [Institut fr theoretische Astrophysik, Zentrum fr Astronomie der Universitt Heidelberg, Albert-Ueberle Str. 2, D-69120 Heidelberg (Germany); Afonso, J. [Centro de Astronomia e Astrofsica da Universidade de Lisboa, Observatrio Astronmico de Lisboa, Tapada da Ajuda, 1349-018 Lisbon (Portugal); Hurley, P. [Department of Physics and Astronomy, University of Sussex, Falmer, Brighton BN1 9QH (United Kingdom); Borys, C. [Infrared Processing and Analysis Center, MS220-6, California Institute of Technology, Pasadena, CA 91125 (United States); Verma, A. [Oxford Astrophysics, Denys Wilkinson Building, University of Oxford, Keble Rd, Oxford OX1 3RH (United Kingdom); Cooray, A.; Salvatelli, V. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States)

2013-10-10T23:59:59.000Z

87

Atomic structure of machined semiconducting chips: An x-ray absorption spectroscopy study  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) has been used to examine the atomic structure of chips of germanium that were produced by single point diamond machining. It is demonstrated that although the local (nearest neighbor) atomic structure is experimentally quite similar to that of single crystal specimens information from more distant atoms indicates the presence of considerable stress. An outline of the technique is given and the strength of XAS in studying the machining process is demonstrated.

Paesler, M.; Sayers, D.

1988-12-01T23:59:59.000Z

88

Diffraction anomalous fine structure analysis on (Bi,Pb){sub 2}PtO{sub 4} powders  

SciTech Connect (OSTI)

The Diffraction Anomalous Fine Structure (DAFS) method can provide site selective and chemical selective structural information. The possibilities of DAFS experimental and data analysis procedures are demonstrated for (Bi{sub 1.67},Pb{sub 0.33}) powder samples. Experiments have been performed at both L{sub III} and K Pt edges (11.56.564keV and 78keV), using several data collection set-ups (analyser crystals, 1D-detector, 2D-detector). Based on this example, a comparison between these experimental procedures and analysis is given and discussed.

Vacinova, J. [Centre National de la Recherche Scientifique (CNRS), 38 - Grenoble (France). Lab. de Cristallographie; Hodeau, J.L.; Bordet, P. [European Synchrotron Radiation Facility, 38 - Grenoble (France)] [and others

1995-12-31T23:59:59.000Z

89

Solar abundances and helioseismology: fine structure spacings and separation ratios of low-degree p modes  

E-Print Network [OSTI]

We have used 4752 days of data collected by the Birmingham Solar-Oscillations Network (BiSON) to determine very precise oscillation frequencies of acoustic low-degree modes that probe the solar core. We compare the fine (small frequency) spacings and frequency separation ratios formed from these data with those of different solar models. We find that models constructed with low metallicity are incompatible with the observations. The results provide strong support for lowering the theoretical uncertainties on the neutrino fluxes. These uncertainties had recently been raised due to the controversy over the solar abundances.

Sarbani Basu; William J. Chaplin; Yvonne Elsworth; Roger New; Aldo M. Serenelli; Graham A. Verner

2006-10-02T23:59:59.000Z

90

GEOC Sunday, March 21, 2010 47 -Speciation and release kinetics of cadmium and zinc in paddy soils: Application of X-ray absorption  

E-Print Network [OSTI]

: Application of X-ray absorption spectroscopy (XAS) Saengdao Khaokaew, Rufus L Chaney, PhD Matt Ginder kinetics, which is the aim of this research. X-ray absorption spectroscopy (XAS) was used to investigate Cd-ray absorption fine structure (EXAFS) spectroscopic data indicates that CdCO3 and Cd-humic complexes

Sparks, Donald L.

91

Strong enhancement of light absorption and highly directive thermal emission in graphene  

E-Print Network [OSTI]

Strong enhancement of light absorption and highly directive thermal emission in graphene Mingbo Pu: Graphene is a two-dimensional material with exotic electronic, optical and thermal properties. The optical absorption in monolayer graphene is limited by the fine structure constant . Here we demonstrated the strong

Chen, Po

92

E-Print Network 3.0 - anomalous fine structure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure derives micr PDF f elementary cell (with... 2005 Understanding anomalous transport intermittent maps: From ... Source: Klages, Rainer - School of Mathematical...

93

Electronic Structure of Transition Metal-Cysteine Complexes From X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The electronic structures of Hg{sup II}, Ni{sup II}, Cr{sup III}, and Mo{sup V} complexes with cysteine were investigated by sulfur K-edge X-ray absorption near-edge structure (XANES) spectroscopy and density functional theory. The covalency in the metal-sulfur bond was determined by analyzing the intensities of the electric-dipole allowed pre-edge features appearing in the XANES spectra below the ionization threshold. Because of the well-defined structures of the selected cysteine complexes, the current work provides a reference set for further sulfur K-edge XAS studies of bioinorganic active sites with transition metal-sulfur bonds from cysteine residues as well as more complex coordination compounds with thiolate ligands.

Leung, B.O.; Jalilehvand, F.; Szilagyi, R.K.

2009-05-19T23:59:59.000Z

94

The vibrational and rotational structure of the 2400 to 1950 A? absorption spectrum of sulfur dioxide  

E-Print Network [OSTI]

0. $ ? Vs TBE YiaUSXOKtf U ? m sm U M A L M W of thb 2400 to 1950 2 Ammwim mmmm m s u m m m a m A. BisMrtatiim % James Willbom Biggs, Jfe. Submitted to the Gra4taata Sdtotd tdt HA* Agricultural and Maofcudoal Qtlltc* %ff I'M* 3*i partial... fulfillment of' %hm r*tuir??Mi*s f?r %ift ??' m m m m m m & m s t Major Sttfejoott Rupeio* THE VIBRATIONAL AND ROTATIONAL STRUCTURE OP THE 2400 TO 1950 A ABSORPTION SPECTRUM OP SULFUR DIOXIDE A Dissertation 37 James Willborn Riggs, Jr. Approved...

Riggs, James Willborn

1958-01-01T23:59:59.000Z

95

AN INTRIGUING CHROMOSPHERIC JET OBSERVED BY HINODE: FINE STRUCTURE KINEMATICS AND EVIDENCE OF UNWINDING TWISTS  

SciTech Connect (OSTI)

We report a chromospheric jet lasting for more than 1 hr observed by the Hinode Solar Optical Telescope in unprecedented detail. The ejection occurred in three episodes separated by 12-14 minutes, with the amount and velocity of material decreasing with time. The upward velocities range from 438 to 33 km s{sup -1}, while the downward velocities of the material falling back have smaller values (mean: -56km s{sup -1}) and a narrower distribution (standard deviation: 14km s{sup -1}). The average acceleration inferred from parabolic spacetime tracks is 141 m s{sup -2}, a fraction of the solar gravitational acceleration. The jet consists of fine threads (0.''5-2'' wide), which exhibit coherent, oscillatory transverse motions perpendicular to the jet axis and about a common equilibrium position. These motions propagate upward along the jet, with the maximum phase speed of 744+-11 km s{sup -1}at the leading front of the jet. The transverse oscillation velocities range from 151 to 26 km s{sup -1}, amplitudes from 6.0 to 1.9 Mm, and periods from 250 to 536 s. The oscillations slow down with time and cease when the material starts to fall back. The falling material travels along almost straight lines in the original direction of ascent, showing no transverse motions. These observations are consistent with the scenario that the jet involves untwisting helical threads, which rotate about the axis of a single large cylinder and shed magnetic helicity into the upper atmosphere.

Liu Wei; Berger, Thomas E.; Title, Alan M.; Tarbell, Theodore D. [Lockheed Martin Solar and Astrophysics Laboratory, Department ADBS, Building 252, 3251 Hanover Street, Palo Alto, CA 94304 (United States)

2009-12-10T23:59:59.000Z

96

Fine-structure calculations of energy levels, oscillator strengths, and transition probabilities for sulfur-like iron, Fe XI  

SciTech Connect (OSTI)

Energy levels, oscillator strengths, and transition probabilities for transitions among the 14 LS states belonging to configurations of sulfur-like iron, Fe XI, have been calculated. These states are represented by configuration interaction wavefunctions and have configurations 3s{sup 2}3p{sup 4}, 3s3p{sup 5}, 3s{sup 2}3p{sup 3}3d, 3s{sup 2}3p{sup 3}4s, 3s{sup 2}3p{sup 3}4p, and 3s{sup 2}3p{sup 3}4d, which give rise to 123 fine-structure energy levels. Extensive configuration interaction calculations using the CIV3 code have been performed. To assess the importance of relativistic effects, the intermediate coupling scheme by means of the BreitPauli Hamiltonian terms, such as the one-body mass correction and Darwin term, and spinorbit, spinother-orbit, and spinspin corrections, are incorporated within the code. These incorporations adjusted the energy levels, therefore the calculated values are close to the available experimental data. Comparisons between the present calculated energy levels as well as oscillator strengths and both experimental and theoretical data have been performed. Our results show good agreement with earlier works, and they might be useful in thermonuclear fusion research and astrophysical applications. -- Highlights: Accurate atomic data of iron ions are needed for identification of solar corona. Extensive configuration interaction wavefunctions including 123 fine-structure levels have been calculated. The relativistic effects by means of the BreitPauli Hamiltonian terms are incorporated. This incorporation adjusts the energy levels, therefore the calculated values are close to experimental values.

Abou El-Maaref, A., E-mail: aahmh@hotmail.com [Physics Department, Faculty of Science, Al-Azhar University, Assuit (Egypt); Ahmad, Mahmoud [Physics Department, Faculty of Science, Al-Azhar University, Assuit (Egypt); Allam, S.H. [Laboratory of Lasers and New Materials, Physics Department, Faculty of Science, Cairo University, Giza (Egypt)

2014-05-15T23:59:59.000Z

97

On the importance of nuclear quantum motions in near edge x-ray absorption fine structure (NEXAFS) spectroscopy of molecules  

SciTech Connect (OSTI)

We report the effects of sampling nuclear quantum motion with path integral molecular dynamics (PIMD) on calculations of the nitrogen K-edge spectra of two isolated organic molecules. S-triazine, a prototypical aromatic molecule occupying primarily its vibrational ground state at room temperature, exhibits substantially improved spectral agreement when nuclear quantum effects are included via PIMD, as compared to the spectra obtained from either a single fixed-nuclei based calculation or from a series of configurations extracted from a classical molecular dynamics trajectory. Nuclear quantum dynamics can accurately explain the intrinsic broadening of certain features. Glycine, the simplest amino acid, is problematic due to large spectral variations associated with multiple energetically accessible conformations at the experimental temperature. This work highlights the sensitivity of NEXAFS to quantum nuclear motions in molecules, and the necessity of accurately sampling such quantum motion when simulating their NEXAFS spectra.

Schwartz, Craig P.; Uejio, Janel S.; Saykally, Richard J.; Prendergast, David

2009-02-26T23:59:59.000Z

98

In Situ X-ray Absorption Fine Structure Studies on the Effect of pH on Pt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348 270 300Aptamers and GraphenePhase EvolutionIn

99

Fine-scale structures and material flows of quiescent filaments observed by New Vacuum Solar Telescope  

E-Print Network [OSTI]

Study on the small-scale structures and material flows of solar quiescent filaments is very important for understanding the formation and equilibrium of solar filaments. Using the high resolution H{\\alpha} data observed by the New Vacuum Solar Telescope (NVST), we present the structures of the barbs and the material flows along the threads across the spine in two quiescent filaments on 2013 September 29 and on 2012 November 2, respectively. During the evolution of the filament barb, several parallel tube-shaped structures formed and the width of the structures ranges from about 2.3 Mm to 3.3 Mm. The parallel tube-shaped structures merged together accompanied with the material flows from the spine to the barb. Moreover, the boundary between the barb and surrounding atmosphere is very neat. The counter-streaming flows were not found to appear alternately in the adjacent threads of the filament. However, the large-scale patchy counter-streaming flows are detected in the filament. The flows in one patch of the fi...

Yan, X L; Xiang, Y Y; Yang, L H

2015-01-01T23:59:59.000Z

100

Possible Fine Structure in the Delayed Neutron Yields in the Resonance Region for Pu-239  

SciTech Connect (OSTI)

A method of analysis of fluctuation in the delayed neutron yield on the basis of the multimodal fission model was applied to the low-energy resolved resonances for Pu-239. The present calculation using recent data of the fluctuation of the mode branching ratios for the resolved resonances showed both positive and negative resonance structure in the delayed neutron yield relative to the thermal neutron value. This is in contrast to the U-235 case, for which mainly negative dips of about -3.5% were predicted.

Ohsawa, Takaaki; Torii, Takayuki [Department of Electrical and Electronic Engineering, Kinki University, Higashi-osaka 577-8502 (Japan); Hambsch, Franz-Josef [EC-JRC-Institute for Reference Materials and Measurements, Retieseweg 111, B-2440 Geel (Belgium)

2005-05-24T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
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101

High-resolution spectra of solar magnetic features. I. Analysis of penumbral fine structure  

SciTech Connect (OSTI)

The Swedish Vacuum Telescope on La Palma was used to obtain spectra of the magnetic-sensitive Fe I 630.25 nm line under conditions of exceptional angular resolution (0.32 arcsec) and high spectral resolution (FWHM 2.5 pm). Simultaneous 0.02 s CCD exposures of both the spectrum and the slit-jaw image effectively 'freeze' the atmospheric seeing motions and permit unambiguous identification of the spectra of the various penumbral structures. These spectra reveal the magnetic field strength in penumbral filaments through an intensity fit of the Zeeman splitting of this line. The observations show that: (1) the field strength varies from about 2100 G near the umbra-penumbra boundary to about 900 G at the outer edge of the penumbra, (2) the observed fluctuation of penumbral magnetic field is much less dramatic than the fluctuation in intensity, (3) there is a suggestion of a rapid change in field inclination between some light and dark filaments near the edge of the penumbra, and (4) there is no obvious correlation between Doppler shift (in part due to the Evershed flow) and filament intensity. 43 refs.

Lites, B.W.; Skumanich, A.; Scharmer, G.B. (High Altitude Observatory, Boulder, CO (USA) Kungliga Svenska Vetenskapsakademien, Stockholm (Sweden))

1990-05-01T23:59:59.000Z

102

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P. Korecki,1,* D. V. Novikov,2 and M. Tolkiehn2  

E-Print Network [OSTI]

Projections of local atomic structure revealed by wavelet analysis of x-ray absorption anisotropy P x-ray field amplitude at the sites of absorbing atoms and effectively changes the atomic absorption in an experiment a wavelet transform approach for analysis of x-ray absorption anisotropy XAA patterns recorded

Korecki, Pawe³

103

Energy levels, oscillator strengths, radiative decay rates, and fine-structure collision strengths for the Zn-like ions Nb XII and Mo XIII  

SciTech Connect (OSTI)

Energy levels, line strengths, oscillator strengths, radiative decay rates, and fine-structure collision strengths are presented for the Zn-like ions Nb XII and Mo XIII. The atomic data are calculated with the AUTOSTRUCTURE code, where relativistic corrections are introduced according to the BreitPauli distorted wave approach. We present the calculations of atomic data for 110 fine-structure levels generated from fifteen configurations (1s{sup 2}2s{sup 2}2p{sup 6}3s{sup 2}3p{sup 6}3d{sup 10})4s{sup 2}, 4s4p, 4p{sup 2}, 4s4d, 4s4f, 4s5s, 4p4d, 4s5p, 4s5d, 4p4f, 4p5s, 4d{sup 2}, 4d4f, 4f{sup 2}, and 3d{sup 9}4s{sup 2}4p. Fine-structure collision strengths for transitions from the ground and the first four excited levels are presented at six electron energies (20, 50, 80, 110, 150, and 180Ryd). Our atomic structure data are compared with the available experimental and theoretical results.

Liang, Liang, E-mail: liangll501@163.com; Liu, Xu-yang; Zhou, Chao

2014-07-15T23:59:59.000Z

104

X-ray absorption spectroscopy  

E-Print Network [OSTI]

009-9473-8 REVIEW X-ray absorption spectroscopy Junko Yano and application of X-ray absorption spectroscopy, bothX-ray absorption near-edge structure (XANES) and extended X-

Yano, Junko; Yachandra, Vittal K.

2009-01-01T23:59:59.000Z

105

Does complex absorption behavior leading to conditioning and damage in KDP/DKDP reflect the electronic structure of initiators?  

SciTech Connect (OSTI)

Currently, most of our thinking about the defects responsible for initiating laser damage considers them as featureless absorbers. However, an increasing body of evidence, particularly involving multi-wavelength irradiation, suggests electronic structure of damage initiators is important in determining both initiation and conditioning behaviors in KDP. The effective absorption coefficient of energy under multi-wavelength irradiation cannot be accounted for by a structureless absorber, but is consistent with an initiator with a multi-level structure. We outline the evidence and assess the ability of such a simple multi-level model to explain these and other experimentally observed behaviors.

Feit, M D; DeMange, P P; Negres, R A; Rubenchik, A M; Demos, S G

2007-10-24T23:59:59.000Z

106

E-Print Network 3.0 - atomic absorption determination Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption determination Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine...

107

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation  

E-Print Network [OSTI]

Light-induced polarization effects in atoms with partially resolved hyperfine structure and applications to absorption, fluorescence, and nonlinear magneto-optical rotation M. Auzinsh* Department 9 November 2009 The creation and detection of atomic polarization is examined theoretically through

Auzinsh, Marcis

108

Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy  

SciTech Connect (OSTI)

We have used time-resolved soft x-ray spectroscopy to investigate the electronic structure of optically excited cuprous oxide at the O K-edge and the Cu L3-edge. The 400 nm optical excitation shifts the Cu and O absorptions to lower energy, but does not change the integrated x-ray absorption significantly for either edge. The constant integrated x-ray absorption cross-section indicates that the conduction-band and valence-band edges have very similar Cu 3d and O 2p orbital contributions. The 2.1 eV optical band gap of Cu2O significantly exceeds the one eV shift in the Cu L3- and O K-edges absorption edges induced by optical excitation, demonstrating the importance of core-hole excitonic effects and valence electron screening in the x-ray absorption process.

Hillyard, P. W.; Kuchibhatla, S. V. N. T.; Glover, T. E.; Hertlein, M. P.; Huse, Nils; Nachimuthu, P.; Saraf, L. V.; Thevuthasan, S.; Gaffney, K. J.

2010-05-02T23:59:59.000Z

109

Sensitivity of absorption spectra to surface segregation in InGaN/GaN quantum well structures  

SciTech Connect (OSTI)

We investigate the influence of the indium surface segregation on absorption spectra in InGaN/GaN quantum well structures having different indium amount. Results of the mathematical modeling show that such influence is more pronounced in quantum well structures with high indium amounts. The origin of this effect is related to the interplay between the indium surface segregation and internal electrostatic fields. Our theoretical analysis is performed using semiconductor Bloch equations within the Hartree-Fock approximation including into consideration excitonic effects. Results of the global sensitivity analysis evidence that the influence of the indium surface segregation is less than one order of magnitude in comparison with the impact of the quantum-well width and indium molar fraction. Also, the influence of the indium surface segregation is not the same for each interface of the quantum well.

Klymenko, M. V.; Shulika, O. V. [Lab. Photonics, Kharkov National University of Radio Electronics, Kharkov, 61166 (Ukraine); Sukhoivanov, I. A. [Department of Electronics, Engineering Division, University of Guanajuato, Salamanca, Guanajuato, 36885 (Mexico)

2014-05-15T23:59:59.000Z

110

Utilization of Structured Packing for Energy Savings in Distillation and Absorption Columns  

E-Print Network [OSTI]

structured packings are the product of choice in such diverse applications as petroluem refining, gas processing, ethylene plants, and styrene fractionation trains....

Berven, O. J.; Howard, W. E.

111

Fine Structure of Optical Energy Levels Scheme for Ni{sup 2+} Doped in Inverted Perovskite BaLiF{sub 3}  

SciTech Connect (OSTI)

The aim of this paper is to calculate the fine structure of the optical energy levels scheme of BaLiF{sub 3}:Ni{sup 2+} taken into account besides the spin-orbit interaction, also the spin-spin, orbit-orbit and spin-other-orbit interactions. The numerical theoretical crystal field parameters were computed using the model exchange charge calculations of crystal field, taking into account the effects of the covalent bond formation between the Ni{sup 2+} and F{sup -} ions. The Hamiltonian of the BaLiF{sub 3}:Ni{sup 2+} system has been diagonalized in a complete basis set spanned by all wave functions of the 3d{sup 8} electron configuration. The comparison of the calculated energy levels with experimental data gives a satisfactory agreement, which confirms the model and used method.

Andreici, Emiliana-Laura [Department of Physics, West University of Timisoara, Bd. V. Parvan No. 4, 300223, Timisoara (Romania); Avram, N. M. [Department of Physics, West University of Timisoara, Bd. V. Parvan No. 4, 300223, Timisoara (Romania); Academy of Romanian Scientists, Independentei 54, 050094-Bucharest (Romania)

2011-10-03T23:59:59.000Z

112

A microsecond time resolved x-ray absorption near edge structure synchrotron study of phase transitions in Fe undergoing ramp heating at high pressure  

SciTech Connect (OSTI)

We report a microsecond time-resolved x-ray absorption near edge structure study using synchrotron radiation to dynamically detect structural phase transitions in Fe undergoing rapid heating along a quasi-isochoric path. Within a few ms, we observed two structural phase transitions, which transform the ambient bcc phase of Fe into the fcc phase, and then into the liquid phase. This example illustrates the opportunities offered by energy dispersive x-ray absorption spectroscopy in the study of matter under extreme dynamic conditions. Advanced simulations are compared to these data.

Marini, C.; Mathon, O.; Pascarelli, S. [European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP220, 38043 Grenoble Cedex (France); Occelli, F.; Torchio, R.; Recoules, V.; Loubeyre, P. [CEA, Bruyeres le Chatel, 91297 Arpajon Cedex (France)

2014-03-07T23:59:59.000Z

113

X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films  

SciTech Connect (OSTI)

The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

1999-02-01T23:59:59.000Z

114

FINE-SCALE STRUCTURE OF THE QUASAR 3C 279 MEASURED WITH 1.3 mm VERY LONG BASELINE INTERFEROMETRY  

SciTech Connect (OSTI)

We report results from five day very long baseline interferometry observations of the well-known quasar 3C 279 at 1.3 mm (230 GHz) in 2011. The measured nonzero closure phases on triangles including stations in Arizona, California, and Hawaii indicate that the source structure is spatially resolved. We find an unusual inner jet direction at scales of {approx}1 pc extending along the northwest-southeast direction (P.A. = 127 Degree-Sign {+-} 3 Degree-Sign ), as opposed to other (previously) reported measurements on scales of a few parsecs showing inner jet direction extending to the southwest. The 1.3 mm structure corresponds closely with that observed in the central region of quasi-simultaneous super-resolution Very Long Baseline Array images at 7 mm. The closure phase changed significantly on the last day when compared with the rest of observations, indicating that the inner jet structure may be variable on daily timescales. The observed new direction of the inner jet shows inconsistency with the prediction of a class of jet precession models. Our observations indicate a brightness temperature of {approx}8 Multiplication-Sign 10{sup 10} K in the 1.3 mm core, much lower than that at centimeter wavelengths. Observations with better uv coverage and sensitivity in the coming years will allow the discrimination between different structure models and will provide direct images of the inner regions of the jet with 20-30 {mu}as (5-7 light months) resolution.

Lu Rusen; Fish, Vincent L.; Doeleman, Sheperd S.; Crew, Geoffrey; Cappallo, Roger J. [Massachusetts Institute of Technology, Haystack Observatory, Route 40, Westford, MA 01886 (United States); Akiyama, Kazunori; Honma, Mareki [National Astronomical Observatory of Japan, Osawa 2-21-1, Mitaka, Tokyo 181-8588 (Japan); Algaba, Juan C.; Ho, Paul T. P.; Inoue, Makoto [Institute of Astronomy and Astrophysics, Academia Sinica, P.O. Box 23-141, Taipei 10617, Taiwan, R.O.C. (China); Bower, Geoffrey C.; Dexter, Matt [Department of Astronomy, Radio Astronomy Laboratory, University of California Berkeley, 601 Campbell, Berkeley, CA 94720-3411 (United States); Brinkerink, Christiaan [Department of Astrophysics, IMAPP, Radboud University Nijmegen, P.O. Box 9010, 6500-GL Nijmegen (Netherlands); Chamberlin, Richard [Caltech Submillimeter Observatory, 111 Nowelo Street, Hilo, HI 96720 (United States); Freund, Robert [Arizona Radio Observatory, Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721-0065 (United States); Friberg, Per [James Clerk Maxwell Telescope, Joint Astronomy Centre, 660 North A'ohoku Place, University Park, Hilo, HI 96720 (United States); Gurwell, Mark A. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Jorstad, Svetlana G. [Institute for Astrophysical Research, Boston University, Boston, MA 02215 (United States); Krichbaum, Thomas P. [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, D-53121 Bonn (Germany); Loinard, Laurent, E-mail: rslu@haystack.mit.edu [Centro de Radiostronomia y Astrofisica, Universidad Nacional Autonoma de Mexico, 58089 Morelia, Michoacan (Mexico); and others

2013-07-20T23:59:59.000Z

115

Cavity resonance absorption in ultra-high bandwidth CRT deflection structure by a resistive load  

DOE Patents [OSTI]

An improved ultra-high bandwidth helical coil deflection structure for a cathode ray tube is described comprising a first metal member having a bore therein, the metal walls of which form a first ground plane; a second metal member coaxially mounted in the bore of the first metal member and forming a second ground plane; a helical deflection coil coaxially mounted within the bore between the two ground planes; and a resistive load disposed in one end of the bore and electrically connected to the first and second ground planes, the resistive load having an impedance substantially equal to the characteristic impedance of the coaxial line formed by the two coaxial ground planes to inhibit cavity resonance in the structure within the ultra-high bandwidth of operation. Preferably, the resistive load comprises a carbon film on a surface of an end plug in one end of the bore.

Dunham, M.E.; Hudson, C.L.

1993-05-11T23:59:59.000Z

116

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2003-10-14T23:59:59.000Z

117

Solar selective absorption coatings  

DOE Patents [OSTI]

A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

2004-08-31T23:59:59.000Z

118

An application of Ti-K X-ray absorption edges and fine structures to the study of substoichiometric titanium carbide TiC1-x  

E-Print Network [OSTI]

remarkable physical proper- ties, cubic rocksalt transition metal carbides present a large domain of substoichiometric titanium carbide TiC1-x V. Moisy-Maurice and C. H. de Novion C.E.A./IRDI/DMECN/DTech, Laboratoire concentration on the bulk physical properties of the carbides has been extensively studied [2] ; but a detailed

Paris-Sud XI, Université de

119

THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED BY MO K-EDGE X-RAY ABSORPTION  

E-Print Network [OSTI]

THE STRUCTURAL CHEMISTRY OF MOLYBDENUM IN MODEL HIGH LEVEL NUCLEAR WASTE GLASSES, INVESTIGATED of molybdenum in model UK high level nuclear waste glasses was investigated by X-ray Absorption Spectroscopy (XAS). Molybdenum K-edge XAS data were acquired from several inactive simulant high level nuclear waste

Sheffield, University of

120

The synthesis, single-crystal structure, optical absorption, and resistivity of Th{sub 2}GeSe{sub 5}  

SciTech Connect (OSTI)

The compound Th{sub 2}GeSe{sub 5} has been synthesized by the reaction of the elements at 1273 K. From a single-crystal study Th{sub 2}GeSe{sub 5} crystallizes in the Ba{sub 5}Si{sub 3} structure type with four formula units in the space group D{sup 8}{sub 4h}?P4/ncc of the tetragonal system in a cell with dimensions a=7.4968(4) and c=13.6302(9) at 100(2) K. From optical absorption measurements Th{sub 2}GeSe{sub 5} is found to have an optical band gap of 1.92 eV (indirect) or 1.98 eV (direct), consistent with its red color. Th{sub 2}GeSe{sub 5} is a wide gap semiconductor, as indicated by its electrical resistivity at 298 K of 4.37(2)10{sup 9} ? cm measured on a single crystal. - Graphical abstract: The structure of Th{sub 2}GeSe{sub 5}. Display Omitted - Highlights: The new compound Th{sub 2}GeSe{sub 5} was synthesized from the elements and recrystallized from Sb{sub 2}Se{sub 3}. Th{sub 2}GeSe{sub 5} crystallizes in the Ba{sub 5}Si{sub 3} structure type. The band gap of Th{sub 2}GeSe{sub 5} is1.92 eV and its resistivity shows it to be a wide gap semiconductor.

Koscielski, Lukasz A.; Malliakas, Christos D.; Sarjeant, Amy A.; Ibers, James A., E-mail: ibers@chem.northwestern.edu

2013-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

MID-INFRARED ATOMIC FINE-STRUCTURE EMISSION-LINE SPECTRA OF LUMINOUS INFRARED GALAXIES: SPITZER/IRS SPECTRA OF THE GOALS SAMPLE  

SciTech Connect (OSTI)

We present the data and our analysis of mid-infrared atomic fine-structure emission lines detected in Spitzer/Infrared Spectrograph high-resolution spectra of 202 local Luminous Infrared Galaxies (LIRGs) observed as part of the Great Observatories All-sky LIRG Survey (GOALS). We readily detect emission lines of [S IV], [Ne II], [Ne V], [Ne III], [S III]{sub 18.7{sub ?m}}, [O IV], [Fe II], [S III]{sub 33.5{sub ?m}}, and [Si II]. More than 75% of these galaxies are classified as starburst-dominated sources in the mid-infrared, based on the [Ne V]/[Ne II] line flux ratios and equivalent width of the 6.2 ?m polycyclic aromatic hydrocarbon feature. We compare ratios of the emission-line fluxes to those predicted from stellar photo-ionization and shock-ionization models to constrain the physical and chemical properties of the gas in the starburst LIRG nuclei. Comparing the [S IV]/[Ne II] and [Ne III]/[Ne II] line ratios to the Starburst99-Mappings III models with an instantaneous burst history, the emission-line ratios suggest that the nuclear starbursts in our LIRGs have ages of 1-4.5 Myr, metallicities of 1-2 Z{sub ?}, and ionization parameters of 2-8 10{sup 7} cm s{sup 1}. Based on the [S III]{sub 33.5{sub ?m}}/[S III]{sub 18.7{sub ?m}} ratios, the electron density in LIRG nuclei is typically one to a few hundred cm{sup 3}, with a median electron density of ?300 cm{sup 3}, for those sources above the low density limit for these lines. We also find that strong shocks are likely present in 10 starburst-dominated sources of our sample. A significant fraction of the GOALS sources (80) have resolved neon emission-line profiles (FWHM ?600 km s{sup 1}) and five show clear differences in the velocities of the [Ne III] or [Ne V] emission lines, relative to [Ne II], of more than 200 km s{sup 1}. Furthermore, six starburst and five active galactic nucleus dominated LIRGs show a clear trend of increasing line width with ionization potential, suggesting the possibility of a compact energy source and stratified interstellar medium in their nuclei. We confirm a strong correlation between the sum of the [Ne II]{sub 12.8{sub ?m}} and [Ne III]{sub 15.5{sub ?m}} emission, as well as [S III]{sub 33.5{sub ?m}}, with both the infrared luminosity and the 24 ?m warm dust emission measured from the spectra, consistent with all three lines tracing ongoing star formation. Finally, we find no correlation between the hardness of the radiation field or the emission-line width and the ratio of the total infrared to 8 ?m emission (IR8), a measure of the strength of the starburst and the distance of the LIRGs from the star-forming main sequence. This may be a function of the fact that the infrared luminosity and the mid-infrared fine-structure lines are sensitive to different timescales over the starburst, or that IR8 is more sensitive to the geometry of the region emitting the warm dust than the radiation field producing the H II region emission.

Inami, H. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Armus, L.; Stierwalt, S.; Daz-Santos, T.; Surace, J.; Howell, J.; Marshall, J. [Spitzer Science Center, California Institute of Technology, CA 91125 (United States); Charmandaris, V. [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003 Heraklion (Greece); Groves, B. [Max Planck Institute for Astronomy, Knigstuhl 17, D-69117 Heidelberg (Germany); Kewley, L. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia); Petric, A. [Department of Astronomy, California Institute of Technology, MS 320-47, Pasadena, CA 91125 (United States); Rich, J. [The Observatories, Carnegie Institute of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Haan, S. [CSIRO Astronomy and Space Science, Marsfield, NSW 2122 (Australia); Evans, A. S. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Mazzarella, J.; Lord, S. [Infrared Processing and Analysis Center, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Appleton, P. [NASA Herschel Science Center, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Spoon, H. [Astronomy Department, Cornell University, Ithaca, NY 14853 (United States); Frayer, D. [National Radio Astronomy Observatory, P.O. Box 2, Green Bank, WV 24944 (United States); Matsuhara, H., E-mail: inami@noao.edu [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (Japan); and others

2013-11-10T23:59:59.000Z

122

X-ray absorption spectroscopy studies of electrochemically deposited thin oxide films.  

SciTech Connect (OSTI)

We have utilized ''in situ'' X-ray Absorption Fine Structure Spectroscopy to investigate the structure and composition of thin oxide films of nickel and iron that have been prepared by electrodeposition on a graphite substrate from aqueous solutions. The films are generally disordered. Structural information has been obtained from the analysis of the data. We also present initial findings on the local structure of heavy metal ions, e.g. Sr and Ce, incorporated into the electrodeposited nickel oxide films. Our results are of importance in a number of technological applications, among them, batteries, fuel cells, electrochromic and ferroelectric materials, corrosion protection, as well as environmental speciation and remediation.

Balasubramanian, M.

1998-06-02T23:59:59.000Z

123

Femtosecond laser-induced modification of potassium-magnesium silicate glasses: An analysis of structural changes by near edge x-ray absorption spectroscopy  

SciTech Connect (OSTI)

The effects of femtosecond laser pulse irradiation on the glass structure of alkaline silicate glasses were investigated by x-ray absorption near edge structure spectroscopy using the beamline of the Physikalisch-Technische Bundesanstalt at the electron synchrotron BESSY II in Berlin (Germany) by analyzing the magnesium K-edge absorption peak for different laser fluences. The application of fluences above the material modification threshold (2.1 J/cm{sup 2}) leads to a characteristic shift of {approx}1.0 eV in the K-edge revealing a reduced ({approx}3%) mean magnesium bond length to the ligated oxygen ions (Mg-O) along with a reduced average coordination number of the Mg ions.

Seuthe, T.; Eberstein, M. [Fraunhofer-Institut fuer Keramische Technologien und Systeme (IKTS), Winterbergstrasse 28, 01277 Dresden (Germany); Hoefner, M.; Eichler, H. J.; Grehn, M. [Technische Universitaet Berlin, Institut fuer Optik und Atomare Physik, Strasse des 17. Juni 135, 10623 Berlin (Germany); Reinhardt, F. [Physikalisch-Technische Bundesanstalt (PTB), Abbestr. 2-12, 10587 Berlin (Germany); Tsai, W. J. [ITRI South, Industrial Technology Research Institute, 8 Gongyan Rd., Liu-jia District, Tainan City 73445, Taiwan (China); Bonse, J. [BAM Bundesanstalt fuer Materialforschung und - pruefung, Unter den Eichen 87, 12205 Berlin (Germany)

2012-05-28T23:59:59.000Z

124

Mid-infrared electro-luminescence and absorption from AlGaN/GaN-based multi-quantum well inter-subband structures  

SciTech Connect (OSTI)

We present electro-modulated absorption and electro-luminescence measurements on chirped AlGaN/GaN-based multi-quantum well inter-subband structures grown by metal-organic vapour phase epitaxy. The absorption signal is a TM-polarized, 70?meV wide feature centred at 230?meV. At medium injection current, a 58?meV wide luminescence peak corresponding to an inter-subband transition at 1450?cm{sup ?1} (180?meV) is observed. Under high injection current, we measured a 4?meV wide structure peaking at 92.5?meV in the luminescence spectrum. The energy location of this peak is exactly at the longitudinal optical phonon of GaN.

Hofstetter, Daniel, E-mail: Daniel.Hofstetter@unine.ch [University of Neuchtel, Institute of Physics, 51 Avenue de Bellevaux, Neuchtel, CH2009 (Switzerland); Bour, David P. [Avogy, Inc., 677 River Oaks Parkway, San Jose, California 95134 (United States); Kirste, Lutz [Fraunhofer Institute for Applied Solid State Physics (IAF), Tullastrasse 72, D-79108 Freiburg i. Brsg. (Germany)

2014-06-16T23:59:59.000Z

125

X-Ray Tomographic Imaging of Crystal Structure at the Atomic Level P. Korecki,1,* M. Tolkiehn,2  

E-Print Network [OSTI]

X-Ray Tomographic Imaging of Crystal Structure at the Atomic Level P. Korecki,1,* M. Tolkiehn,2 D of the crystal structure from real-space projections obtained by illuminating the sample with white x rays. This approach was applied to the pattern of the directional fine structure in absorption of white x rays

Korecki, Pawe³

126

Fine Grained Robotics  

E-Print Network [OSTI]

Fine grained robotics is the idea of solving problems utilizing multitudes of very simple machines in place of one large complex entity. Organized in the proper way, simple machines and simple behaviors can lead to emergent ...

Flynn, Anita M.

127

X-ray Absorption and Emission Spectroscopy Study of the Effect of Doping on the Low Energy Electronic Structure of PrFeAsO1-[delta  

E-Print Network [OSTI]

X-ray Absorption and Emission Spectroscopy Study of theusing soft X-ray absorption and emission spectroscopy. The2. (a) Oxygen 1s x-ray absorption spectra of PrFeAsO 1-? (?

Freelon, Byron

2010-01-01T23:59:59.000Z

128

Investigation of Temperature Dependent Optical Modes in GexAs35-xSe65 Thin Films: Structure Specific Raman, FIR and Optical Absorption Spectroscopy  

E-Print Network [OSTI]

In this article, we present a comprehensive study of temperature and composition dependent Raman spectroscopy of GexAs35-xSe65 thin films to understand different structural units responsible for optical properties. Strikingly, our experimental results uncover the ratio of GeSe4/2 tetrahedral and AsSe3/2 pyramidal units in GexAs35-xSe65 thin films and their linear scaling relationship with temperature and x. An important notable outcome of our study is the formation of Se8 rings at lower temperatures. Our experimental results further provide interesting optical features, thermally and compositionally tunable optical absorption spectra. Detailed structure specific FIR data at room temperature also present direct information on the structural units in consistent with Raman data. We foresee that our studies are useful in determining the lightinduced response of these films and also for their potential applications in optics and optoelectronics.

Khan, Pritam; Joshy, Abin; Sathe, Vasant; Deshpande, Uday; Adarsh, K V

2015-01-01T23:59:59.000Z

129

The calculation of differential cross sections, polarization factions, electron-impact coherence parameters and fine-structure-effect spin-polarization functions for the electron-impact excitation of neon  

SciTech Connect (OSTI)

First-order many-body theory (FOMBT) has been used for the calculation of cross sections (DCSs), polarization fractions, a complete set of electron-impact coherence parameters, and fine-structure-effect spin-polarizations for the 1S{sub 0}-3P{sub 0,1,2} excitation of Ne. Results will be reported for E = 20, 25, 30, 50, 80, 100 and 120 eV incident electron energies and will be compared with available experimental data.

Cartwright, D.C.; Csanak, G.; Machado, L.E.; Meneses, G.D. [Los Alamos National Laboratory, NM (United States)

1993-05-01T23:59:59.000Z

130

Using in situ X-ray absorption spectroscopy to study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}}  

SciTech Connect (OSTI)

To study the local structure and oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF) as a function of the oxygen partial pressure (P(O{sub 2})), in situ the Co and Fe K-edge X-ray absorption spectroscopy (XAS) was measured at elevated temperatures of 900 and 1000 K. The reduction of the Co and Fe valence, i.e., the oxygen content (3-{delta}) in LSCF, followed the change of P(O{sub 2}) from 1 to 10{sup -4} atm during{approx}4000 s. The quantitative analysis of the X-ray absorption near edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) indicated that the Fe valence was higher than the Co valence at oxidative condition ({delta} Almost-Equal-To 0) in LSCF. Whereas the Co valence decreased more than the Fe valence after reduction of P(O{sub 2}) at both 900 and 1000 K. From the relaxation plots of the valence and the oxygen content (3-{delta}) for Co and Fe after changing P(O{sub 2}), we successfully determined D{sub chem} and E{sub a} of an oxygen ion migration around Co and Fe in LSCF. A structural model with and without oxygen vacancies and an oxygen ion conduction mechanism for LSCF are proposed based on these results. - Graphical abstract: A structural model with and without oxygen vacancies, and the oxygen ion conduction mechanism of LSCF were speculated. In other words, oxygen vacancies would form more preferentially around Co than Fe from the results of in situ XAS analysis during reduction, and oxygen ions needs to pass through at the vicinity of Fe from the results of D{sub chem} and E{sub a}. Highlights: Black-Right-Pointing-Pointer Study of the oxygen ion conduction mechanism in (La{sub 0.6}Sr{sub 0.4})(Co{sub 0.2}Fe{sub 0.8})O{sub 3-{delta}} (LSCF). Black-Right-Pointing-Pointer Using in situ X-ray absorption for study of valence and oxygen diffusion coefficient. Black-Right-Pointing-Pointer The oxygen vacancies should be preferentially localized around Co in LSCF. Black-Right-Pointing-Pointer The values of the dynamics parameters for Co and Fe are close to each other.

Itoh, Takanori, E-mail: tknitoh@seimichemical.co.jp [AGC SeimiChemical Co., Ltd., 3-2-10 Chigasaki, Chigasaki City, Kanagawa 253-8585 (Japan); Nakayama, Masanobu [Department of Materials Science and Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya-city, Aichi 466-8555 (Japan)

2012-08-15T23:59:59.000Z

131

Temperature dependent electronic structure of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film probed by X-ray absorption near edge structure  

SciTech Connect (OSTI)

The Mn K edge X-ray absorption near edge structures (XANES) of Pr{sub 0.67}Sr{sub 0.33}MnO{sub 3} film (100 nm) on (001) LaAlO{sub 3} substrate was measured at different temperatures to probe the MnO{sub 6} octahedron distortion and corresponding electronic structure. The absorption of high temperature paramagnetic-insulator phase differed from that of the low temperature ferromagnetic-metal phase. The temperature-dependent absorption intensity of Mn K edge XANES was correlated with the relaxation of distorted MnO{sub 6} octahedron, which changed the crystal field acting on the Mn site and the related electronic structure and properties. At low temperature, the splitting of Mn majority e{sub g} orbitals decreased and the density of states above the Fermi level increased in the relaxed MnO{sub 6} octahedron, as reflected by a wider separation between two sub-peaks in the pre-edge XANES spectra.

Zhang, Bangmin [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Sun, Cheng-Jun, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg; Heald, Steve M. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Chen, Jing-Sheng; Moog Chow, Gan, E-mail: cjsun@aps.anl.gov, E-mail: msecgm@nus.edu.sg [Department of Materials Science and Engineering, National University of Singapore, Singapore 117576 (Singapore); Venkatesan, T. [NUSNNI-Nanocore, National University of Singapore, Singapore 117411 (Singapore); Department of Physics, National University of Singapore, Singapore 117542 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

2014-05-07T23:59:59.000Z

132

Percolative superconductivity in La{sub 2}CuO{sub 4.06} by lattice granularity patterns with scanning micro x-ray absorption near edge structure  

SciTech Connect (OSTI)

The simplest cuprate superconductor La{sub 2}CuO{sub 4+y} with mobile oxygen interstitials exhibits a clear phase separation. It is known that oxygen interstitials enter into the rocksalt La{sub 2}O{sub 2+y} spacer layers forming oxygen interstitials rich puddles and poor puddles but only recently a bulk multiscale structural phase separation has been observed by using scanning micro X-ray diffraction. Here we get further information on their spatial distribution, using scanning La L{sub 3}-edge micro X-ray absorption near edge structure. Percolating networks of oxygen rich puddles are observed in different micrometer size portions of the crystals. Moreover, the complex surface resistivity shows two jumps associated to the onset of intra-puddle and inter-puddles percolative superconductivity. The similarity of oxygen doped La{sub 2}CuO{sub 4+y}, with the well established phase separation in iron selenide superconductors is also discussed.

Poccia, Nicola [MESA Institute for Nanotechnology, University of Twente, P. O. Box 217, 7500AE Enschede (Netherlands); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Chorro, Matthieu [Synchrotron SOLEIL L'Orme des Merisiers, 91190 Paris S.Aubin (France); Ricci, Alessandro [Deutsches Elektronen-Synchrotron DESY, Notkestrae 85, D-22607 Hamburg (Germany); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Xu, Wei [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China); Marcelli, Augusto [Istituto Nazionale di Fisica Nucleare - Laboratori Nazionali di Frascati, 00044 Frascati, Rome (Italy); NSRL, University of Science and Technology of China, Hefei 230026 (China); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Campi, Gaetano [Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy); RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Bianconi, Antonio [RICMASS Rome International Center for Materials Science Superstripes, via dei Sabelli 119A, 00185 Roma (Italy); Institute of Crystallography, CNR, via Salaria Km 29.300, Monterotondo, 00015 Rome (Italy)

2014-06-02T23:59:59.000Z

133

Efficient optical absorption enhancement in organic solar cells by using a 2-dimensional periodic light trapping structure  

SciTech Connect (OSTI)

We have investigated the effects induced by periodic nanosphere arrays on the performance of organic solar cells (OSCs). Two-dimensional periodic arrays of polystyrene nanospheres were formed by using a colloidal lithography method together with plasma etching to trim down the size to various degrees on the substrates of OSCs. It is found that the devices prepared on such substrates can have improved light harvesting, resulting in as high as 35% enhancement in power conversion efficiency over that of the reference devices. The measured external quantum efficiency and finite-difference time-domain simulation reveal that the controlled periodic morphology of the substrate can efficiently increase light scattering in the device and thus enhance the absorption of incident light.

Zu, Feng-Shuo [Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China); Shi, Xiao-Bo; Liang, Jian; Xu, Mei-Feng; Wang, Zhao-Kui, E-mail: lsliao@suda.edu.cn, E-mail: zkwang@suda.edu.cn, E-mail: apcslee@cityu.edu.hk; Liao, Liang-Sheng, E-mail: lsliao@suda.edu.cn, E-mail: zkwang@suda.edu.cn, E-mail: apcslee@cityu.edu.hk [Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Institute of Functional Nano and Soft Materials (FUNSOM), Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, Jiangsu 215123 (China); Lee, Chun-Sing, E-mail: lsliao@suda.edu.cn, E-mail: zkwang@suda.edu.cn, E-mail: apcslee@cityu.edu.hk [Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR (China)

2014-06-16T23:59:59.000Z

134

Electronic and atomic structures of Ti{sub 1-x}Al{sub x}N thin films related to their damage behavior  

SciTech Connect (OSTI)

Ti and Al K-edge x-ray absorption spectroscopy is used to investigate the electronic structure of Ti{sub 1-x}Al{sub x}N thin films deposited by reactive magnetron sputtering. The experimental near edge spectra of TiN and AlN are interpreted in the light of unoccupied density of state band structure calculations. The comparison of the structural parameters derived from x-ray absorption fine structure and x-ray diffraction reveals segregation between Al-rich and Ti-rich domains within the Ti{sub 1-x}Al{sub x}N films. Whereas x-ray diffraction probes only the crystallized domains, the structural information derived from extended x-ray absorption fine structure analysis turns on both crystalline and grain boundaries. The results are discussed by considering the damage behavior of the films depending on the composition.

Tuilier, M.-H.; Pac, M.-J.; Girleanu, M.; Covarel, G.; Arnold, G.; Louis, P. [Laboratoire de Mecanique, Materiaux et Procedes de Fabrication, Universite de Haute Alsace, 61 rue Albert Camus, F-68093 Mulhouse cedex (France); Rousselot, C. [Institut FEMTO-ST (UMR CNRS 6174), Universite de Franche-Comte, BP 71427, F-25211 Montbeliard cedex (France); Flank, A.-M. [CNRS--UR1 SOLEIL, F-91192 Gif sur Yvette cedex (France)

2008-04-15T23:59:59.000Z

135

Electronic structures and bonding properties of chlorine-treated nitrogenated carbon nanotubes: X-ray absorption and scanning photoelectron microscopy studies  

SciTech Connect (OSTI)

The electronic and bonding properties of nitrogenated carbon nanotubes (N-CNTs) exposed to chlorine plasma were investigated using C and N K-edge x-ray absorption near-edge structure (XANES) and scanning photoelectron microscopy (SPEM). The C and N K-edge XANES spectra of chlorine-treated N-CNTs consistently reveal the formation of pyridinelike N-CNTs by the observation of 1s{yields}{pi}*(e{sub 2u}) antibonding and 1s{yields}{pi}*(b{sub 2g}) bonding states. The valence-band photoemission spectra obtained from SPEM images indicate that chlorination of the nanotubes enhances the C-N bonding. First-principles calculations of the partial densities of states in conjunction with C K-edge XANES data identify the presence of C-Cl bonding in chlorine treated N-CNTs.

Ray, S. C.; Pao, C. W.; Tsai, H. M.; Chiou, J. W.; Pong, W. F.; Chen, C. W.; Tsai, M.-H.; Papakonstantinou, P.; Chen, L. C.; Chen, K. H.; Graham, W. G. [Department of Physics, Tamkang University, Tamsui 251, Taiwan (China); Department of Materials Science and Engineering, National Taiwan University, Taipei 106, Taiwan (China); Department of Physics, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); NRI, School of Electrical and Mechanical Engineering, University of Ulster at Jordanstown, Newtownabbey, County Antrim BT37OQB, Northern Ireland (United Kingdom); Center for Condensed Matter Sciences, National Taiwan University, Taipei 106, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan (China); Department of Physics and Astronomy, Queens University of Belfast, Belfast, Antrim BT71NN, Northern Ireland (United Kingdom)

2007-05-07T23:59:59.000Z

136

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

2/9/07 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 9, 07] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

137

X-Ray Absorption Spectroscopy of Metallobiomolecules  

E-Print Network [OSTI]

9/6/09 1 X-Ray Absorption Spectroscopy of Metallobiomolecules The Outskirts of Structural Biology 6, 09] This is a tutorial about the use of X-ray Absorption Spectroscopy (XAS) in biology, RG; Eisenberger, P; Kincaid, BM "X-ray Absorption Spectroscopy of Biological Molecules" Annu. Rev

Scott, Robert A.

138

Chemical evolution STRUCTURE OF GALAXIES  

E-Print Network [OSTI]

Outline Absorption Chemical evolution STRUCTURE OF GALAXIES 8. Absorption; chemical evolution Piet Piet van der Kruit, Kapteyn Astronomical Institute Absorption; chemical evolution #12;Outline Absorption Chemical evolution Outline Absorption Holmberg's analysis Analysis of Disney et al. Edge

Kruit, Piet van der

139

X-ray absorption spectroscopic studies of mononuclear non-heme iron enzymes  

SciTech Connect (OSTI)

Fe-K-edge X-ray absorption spectroscopy (XAS) has been used to investigate the electronic and geometric structure of the iron active site in non-heme iron enzymes. A new theoretical extended X-ray absorption fine structure (EXAFS) analysis approach, called GNXAS, has been tested on data for iron model complexes to evaluate the utility and reliability of this new technique, especially with respect to the effects of multiple-scattering. In addition, a detailed analysis of the 1s{yields}3d pre-edge feature has been developed as a tool for investigating the oxidation state, spin state, and geometry of iron sites. Edge and EXAFS analyses have then been applied to the study of non-heme iron enzyme active sites.

Westre, T.E.

1996-01-01T23:59:59.000Z

140

Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: Vibrations and structure of its excited S{sub 1}(?,?{sup *}) electronic state  

SciTech Connect (OSTI)

The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S{sub 1}(?,?{sup *}) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S{sub 0} and S{sub 1}(?,?{sup *}) electronic states. In each case the decreased ? bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S{sub 0} and S{sub 1}(?,?{sup *}) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S{sub 1}(?,?{sup *}) excited state.

Shin, Hee Won; Ocola, Esther J.; Laane, Jaan, E-mail: laane@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States)] [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States); Kim, Sunghwan [National Center for Biotechnology Information, National Library of Medicine, National Institutes of Health, Department of Health and Human Services, 8600 Rockville Pike, Bethesda, Maryland 20894 (United States)] [National Center for Biotechnology Information, National Library of Medicine, National Institutes of Health, Department of Health and Human Services, 8600 Rockville Pike, Bethesda, Maryland 20894 (United States)

2014-01-21T23:59:59.000Z

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141

Measurement of the absorption coefficient for light laterally propagating in light-emitting diode structures with In{sub 0.2}Ga{sub 0.8}N/GaN quantum wells  

SciTech Connect (OSTI)

A procedure for measuring the absorption coefficient for light propagating parallel to the surface of a GaN-based light emitting diode chip on a sapphire substrate is suggested. The procedure implies the study of emission from one end face of the chip as the opposite end face is illuminated with a light emitting diode. The absorption coefficient is calculated from the ratio between the intensities of emission emerging from the end faces of the sapphire substrate and the epitaxial layer. From the measurements for chips based on p-GaN/In{sub 0.2}Ga{sub 0.8}N/n-GaN structures, the lateral absorption coefficient is determined at a level of (23 {+-} 3)cm{sup -1} at a wavelength of 465 nm. Possible causes for the discrepancy between the absorption coefficients determined in the study and those reported previously are analyzed.

Lelikov, Yu. S.; Bochkareva, N. I.; Gorbunov, R. I.; Martynov, I. A.; Rebane, Yu. T.; Tarkin, D. V.; Shreter, Yu. G. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)], E-mail: YShreter@mail.ioffe.ru

2008-11-15T23:59:59.000Z

142

The {ital b} Distribution and the Velocity Structure of Absorption Peaks in the Ly{alpha} Forest  

SciTech Connect (OSTI)

A theory is developed that relates the observed {ital b} parameter of a Ly{alpha} absorption line to the velocity curvature of the corresponding peak in the optical depth fluctuation. Its relation to the traditional interpretation of {ital b} as the thermal broadening width is discussed. It is demonstrated that, independent of the details of the cosmological model, the differential {ital b} distribution has a high-{ital b} asymptote of dN/db{proportional_to}b{sup {minus}m}, where m{ge}5, when we make the reasonable assumption that low-curvature fluctuations are statistically favored over high-curvature ones. There in general always exist lines much broader than the thermal width. We develop a linear perturbative analysis of the optical depth fluctuation, which yields a single-parameter prediction for the full {ital b} distribution. In addition to exhibiting the high-velocity tail, it qualitatively explains the observed sharp low-{ital b} cutoff{emdash}a simple reflection of the fact that high-curvature fluctuations are relatively rare. Although the existence of the high-{ital b} asymptote, which is independent of the validity of the linear expansion, is consistent with the observed {ital b} distribution, a detailed comparison of the linear prediction with six observational data sets indicates that higher order corrections are not negligible. The perturbative analysis nonetheless offers valuable insights into the dependence of the {ital b} distribution on cosmological parameters such as {Omega} and the power spectrum. A key parameter is the effective smoothing scale of the optical depth fluctuation, which is in turn determined by three scales: the thermal broadening width, the baryon smoothing scale (approximately the Jeans scale), and the observation/simulation resolution. The first two are determined by reionization history, but are comparable in general, whereas the third varies by about an order of magnitude in current hydrodynamic simulations. Studies with non{endash}resolution-dominated {ital b} distributions can be used to probe the reionization history of the universe. {copyright} {ital {copyright} 1999.} {ital The American Astronomical Society}

Hui, L. [NASA/Fermilab Astrophysics Center, Fermi National Accelerator Laboratory, Batavia, IL 60510 (United States)] [NASA/Fermilab Astrophysics Center, Fermi National Accelerator Laboratory, Batavia, IL 60510 (United States); Rutledge, R.E. [Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1603, D-85740 Garching (Germany)] [Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1603, D-85740 Garching (Germany)

1999-06-01T23:59:59.000Z

143

The [ital b] Distribution and the Velocity Structure of Absorption Peaks in the Ly[alpha] Forest  

SciTech Connect (OSTI)

A theory is developed that relates the observed [ital b] parameter of a Ly[alpha] absorption line to the velocity curvature of the corresponding peak in the optical depth fluctuation. Its relation to the traditional interpretation of [ital b] as the thermal broadening width is discussed. It is demonstrated that, independent of the details of the cosmological model, the differential [ital b] distribution has a high-[ital b] asymptote of dN/db[proportional to]b[sup [minus]m], where m[ge]5, when we make the reasonable assumption that low-curvature fluctuations are statistically favored over high-curvature ones. There in general always exist lines much broader than the thermal width. We develop a linear perturbative analysis of the optical depth fluctuation, which yields a single-parameter prediction for the full [ital b] distribution. In addition to exhibiting the high-velocity tail, it qualitatively explains the observed sharp low-[ital b] cutoff[emdash]a simple reflection of the fact that high-curvature fluctuations are relatively rare. Although the existence of the high-[ital b] asymptote, which is independent of the validity of the linear expansion, is consistent with the observed [ital b] distribution, a detailed comparison of the linear prediction with six observational data sets indicates that higher order corrections are not negligible. The perturbative analysis nonetheless offers valuable insights into the dependence of the [ital b] distribution on cosmological parameters such as [Omega] and the power spectrum. A key parameter is the effective smoothing scale of the optical depth fluctuation, which is in turn determined by three scales: the thermal broadening width, the baryon smoothing scale (approximately the Jeans scale), and the observation/simulation resolution. The first two are determined by reionization history, but are comparable in general, whereas the third varies by about an order of magnitude in current hydrodynamic simulations. Studies with non[endash]resolution-dominated [ital b] distributions can be used to probe the reionization history of the universe. [copyright] [ital [copyright] 1999.] [ital The American Astronomical Society

Hui, L. (NASA/Fermilab Astrophysics Center, Fermi National Accelerator Laboratory, Batavia, IL 60510 (United States)); Rutledge, R.E. (Max-Planck-Institut fuer extraterrestrische Physik, Postfach 1603, D-85740 Garching (Germany))

1999-06-01T23:59:59.000Z

144

Continuous fine ash depressurization system  

DOE Patents [OSTI]

A system for depressurizing and cooling a high pressure, high temperature fine solid particles stream having entrained gas therein. In one aspect, the system has an apparatus for cooling the high pressure, high temperature fine solid particles stream having entrained gas therein and a pressure letdown device for depressurization by separating the cooled fine solid particles from a portion of the fine solid particles stream having entrained gas therein, resulting in a lower temperature, lower pressure outlet of solid particles for disposal or handling by downstream equipment.

Liu, Guohai (Birmingham, AL); Peng, Wan Wang (Birmingham, AL); Vimalchand, Pannalal (Birmingham, AL)

2011-11-29T23:59:59.000Z

145

Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions at the Soil/Water Interface  

E-Print Network [OSTI]

Use of X-Ray Absorption Spectroscopy to Monitor the Kinetics of Metal Sorption Reactions on the surface coordination environment of Ni sorbed onto clays and aluminum oxides using X-ray absorption fine

Sparks, Donald L.

146

Moments of Absorption.  

E-Print Network [OSTI]

??Moments of Absorption explores the conceptual and visual themes that are presented in my MFA thesis exhibition. The research looks into the absorption of the (more)

Kaufman, Sarah K.

2008-01-01T23:59:59.000Z

147

Hot Gas Filtration of Fine and Ultra fine Particles with Liquid...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC Ceramic DPF Hot Gas Filtration of Fine and Ultra fine Particles with Liquid Phase Sintered SiC...

148

Interpretation of Wild 2 Dust Fine Structure: Comparison of Stardust Aluminium Foil Craters to the Three-Dimensional Shape of Experimental Impacts by Artificial Aggregate Particles and Meteorite Powders  

SciTech Connect (OSTI)

New experimental results show that Stardust crater morphology is consistent with interpretation of many larger Wild 2 dust grains being aggregates, albeit most of low porosity and therefore relatively high density. The majority of large Stardust grains (i.e. those carrying most of the cometary dust mass) probably had density of 2.4 g cm{sup -3} (similar to soda-lime glass used in earlier calibration experiments) or greater, and porosity of 25% or less, akin to consolidated carbonaceous chondrite meteorites, and much lower than the 80% suggested for fractal dust aggregates. Although better size calibration is required for interpretation of the very smallest impacting grains, we suggest that aggregates could have dense components dominated by {micro}m-scale and smaller sub-grains. If porosity of the Wild 2 nucleus is high, with similar bulk density to other comets, much of the pore-space may be at a scale of tens of micrometers, between coarser, denser grains. Successful demonstration of aggregate projectile impacts in the laboratory now opens the possibility of experiments to further constrain the conditions for creation of bulbous (Type C) tracks in aerogel, which we have observed in recent shots. We are also using mixed mineral aggregates to document differential survival of pristine composition and crystalline structure in diverse fine-grained components of aggregate cometary dust analogues, impacted onto both foil and aerogel under Stardust encounter conditions.

Kearsley, A T; Burchell, M J; Price, M C; Graham, G A; Wozniakiewicz, P J; Cole, M J; Foster, N J; Teslich, N

2009-12-10T23:59:59.000Z

149

Structural and dynamical properties of Bridgman-grown CdSe[subscript x]Te[subscript 1?x] (0  

E-Print Network [OSTI]

Measurements of the Raman scattering and extended x-ray-absorption fine-structure (EXAFS) spectroscopy are reported on a series of Bridgman-grown zinc-blende CdTe[subscript 1?x]Se[subscript x] (0.35 ? x > 0.05) ternary ...

Talwar, Devki N.

150

Silicate absorption in heavily obscured galaxy nuclei  

E-Print Network [OSTI]

Spectroscopy at 8-13 microns with T-ReCS on Gemini-S is presented for 3 galaxies with substantial silicate absorption features, NGC 3094, NGC 7172 and NGC 5506. In the galaxies with the deepest absorption bands, the silicate profile towards the nuclei is well represented by the emissivity function derived from the circumstellar emission from the red supergiant, mu Cephei which is also representative of the mid-infrared absorption in the diffuse interstellar medium in the Galaxy. There is spectral structure near 11.2 microns in NGC 3094 which may be due to a component of crystalline silicates. In NGC 5506, the depth of the silicate absorption increases from north to south across the nucleus, suggestive of a dusty structure on scales of 10s of parsecs. We discuss the profile of the silicate absorption band towards galaxy nuclei and the relationship between the 9.7 micron silicate and 3.4 micron hydrocarbon absorption bands.

P. F. Roche; C. Packham; D. K. Aitken; R. E. Mason

2006-10-19T23:59:59.000Z

151

Oral Drug Absorption  

E-Print Network [OSTI]

properties ? membrane permeability ? metabolic stability ? enzyme inhibition or induction ? protein binding ? transporter affinity ?. Chemical Optimization DDS technology 4 Strategy of Drug Delivery Absorption Distribution Metabolism Excretion Improve of drug... absorption absorption enhancement controlled releasecontrolled release new administration route Drug targeting to the tissue to the cell to the organelle Dr. Shinji Yamashita (Setsunan University) Issue: Oral Drug Absorption Dr. Valentino J. Stella...

Yamashita, Shinji

2006-10-26T23:59:59.000Z

152

Fine Structure Studies in Proton Emission  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityField Office FinalFinancing

153

Trends in the Carbonyl Core (C 1S, O 1S) f *C)O Transition in the Near-Edge X-ray Absorption Fine Structure Spectra of Organic Molecules  

E-Print Network [OSTI]

,2 meteorites3 and interplanetary dust particles,4 eocene and recent wood,5,6 coal, coke, and other organic

154

X-ray absorption spectroscopy at the Ni-K edge in Stackhousia tryonii Bailey hyperaccumulator  

E-Print Network [OSTI]

X-ray absorption spectroscopy at the NiK edge inin vivo by micro x-ray absorption spectroscopy (XAS) at theNiK edge. Both x-ray absorption near edge structure and

Kachenko, A.

2009-01-01T23:59:59.000Z

155

HII Absorption Bill Erickson  

E-Print Network [OSTI]

HII Absorption Bill Erickson November 10, 2006 It would make all of the drift curve simulations.8 dB above the data. One reason for this might be HII absorption which is not modeled in simulations. There are a number of ways that one might try to estimate the absorption. One might use optical maps of HII

Ellingson, Steven W.

156

Transient Absorption Spectroscopy with Isolated Attosecond Pulses  

E-Print Network [OSTI]

viii Attosecond transient absorption instrument. . . . . .5.2.2 AbsorptionTransient absorption spectroscopy . . . . . . . . . . . .

Bell, Marie Justine

2013-01-01T23:59:59.000Z

157

Influence of recycled fine aggregates on the resistance of mortars to magnesium sulfate attack  

SciTech Connect (OSTI)

The influence of recycled fine aggregates, which had been reclaimed from field-demolished concretes, on the resistance of mortar specimens to magnesium sulfate attack was investigated. Mortar specimens were prepared with recycled fine aggregates at different replacement levels (0%, 25%, 50%, 75% and 100% of natural fine aggregate by mass). The mortar specimens were exposed to 4.24% magnesium sulfate solution for about 1 year at ambient temperature, and regularly monitored for visual appearance, compressive strength loss and expansion. Additionally, in order to identify products of magnesium sulfate attack, mortar samples incorporating 0%, 25% and 100% replacement levels of the recycled fine aggregates were examined by X-ray diffraction (XRD) technique. Experimental results confirmed that the use of recycled fine aggregates up to a maximum 50% replacement level is effective under severe magnesium sulfate environment, irrespective of type of recycled fine aggregates. However, the worse performance was observed in mortar specimens incorporating 100% replacement level. It was found that the water absorption of recycled fine aggregates affected deterioration of mortar specimens, especially at a higher replacement level. XRD results indicated that the main cause of deterioration of the mortar specimens was primarily due to the formation of gypsum and thaumasite by magnesium sulfate attack. In addition, it appeared that the conversion of C-S-H into M-S-H by the attack probably influenced mechanical deterioration of mortar specimens with recycled fine aggregates.

Lee, Seung-Tae [Department of Civil Engineering, Kunsan National University, 68 Miryong-dong, Kunsan, Jeonbuk 573-701 (Korea, Republic of)], E-mail: stlee@kunsan.ac.kr

2009-08-15T23:59:59.000Z

158

Chapter 1 - The Impacts of X-Ray Absorption Spectroscopy on Understanding Soil Processes and Reaction Mechanisms  

SciTech Connect (OSTI)

During the last two decades, X-ray absorption spectroscopy (XAS) has developed into a mature technique for obtaining the speciation (e.g., oxidation state) and short-range structure of elements present in soils and sediments. XAS encompasses both X-ray absorption near-edge structure (XANES) spectroscopy and extended X-ray absorption fine structure (EXAFS) spectroscopy. XAS has a number of advantageous qualities for studying soils and sediments, which include elemental specificity, sensitivity to the local chemical and structural state of an element, and the ability to analyze materials in situ. This information allows accurate determination of oxidation state, type of nearest neighbors, coordination number, bond distance, and orbital symmetries of the X-ray absorbing element. In this review, we examine the application of a wide variety of synchrotron X-ray techniques to fundamental issues in environmental soil chemistry. Additionally, we examine the application of microfocused and time-resolved XAS to determine speciation (e.g., oxidation state and/or local coordination environment) and transformation kinetics of contaminants in heterogeneous environmental systems. During the last three decades, XAS has a played a critical role in furthering our understanding of a myriad of environmental systems and will continue to do so into the foreseeable future.

Ginder-Vogel, Matthew; Sparks, Donald L. (Delaware)

2011-11-17T23:59:59.000Z

159

Structure of Palladium Nanoclusters for Hydrogen Gas Sensors  

SciTech Connect (OSTI)

Palladium nanoclusters produced by inert gas aggregation/magnetron sputtering are used as building blocks for the construction of nano electronic devices with large surface to volume ratios that can be used as sensitive hydrogen gas sensors in fuel cells and in petrochemical plants. X-ray diffraction (XRD), extended X-ray absorption fine structure (EXAFS), and high resolution transmission electron microscopy (HRTEM) have been used to characterize the structure, lattice constant, particle diameter and oxide thickness of the palladium nanoclusters in order to understand the operation of these sensors. Grazing incidence XRD (GIXRD) of heat treated Pd clusters has shown that the palladanite structure forms at elevated temperatures.

Stevens, K.J.; Ingham, B.; Toney, M.F.; Brown, S.A.; Lassesson, A.; /SLAC, SSRL /Canterbury U.

2009-05-11T23:59:59.000Z

160

Enhanced light absorption of solar cells and photodetectors by diffraction  

DOE Patents [OSTI]

Enhanced light absorption of solar cells and photodetectors by diffraction is described. Triangular, rectangular, and blazed subwavelength periodic structures are shown to improve performance of solar cells. Surface reflection can be tailored for either broadband, or narrow-band spectral absorption. Enhanced absorption is achieved by efficient optical coupling into obliquely propagating transmitted diffraction orders. Subwavelength one-dimensional structures are designed for polarization-dependent, wavelength-selective absorption in solar cells and photodetectors, while two-dimensional structures are designed for polarization-independent, wavelength-selective absorption therein. Suitable one and two-dimensional subwavelength periodic structures can also be designed for broadband spectral absorption in solar cells and photodetectors. If reactive ion etching (RIE) processes are used to form the grating, RIE-induced surface damage in subwavelength structures can be repaired by forming junctions using ion implantation methods. RIE-induced surface damage can also be removed by post RIE wet-chemical etching treatments.

Zaidi, Saleem H.; Gee, James M.

2005-02-22T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Dense, finely, grained composite materials  

DOE Patents [OSTI]

Dense, finely grained composite materials comprising one or more ceramic phase or phase and one or more metallic and/or intermetallic phase or phases are produced by combustion synthesis. Spherical ceramic grains are homogeneously dispersed within the matrix. Methods are provided, which include the step of applying mechanical pressure during or immediately after ignition, by which the microstructures in the resulting composites can be controllably selected.

Dunmead, Stephen D. (Davis, CA); Holt, Joseph B. (San Jose, CA); Kingman, Donald D. (Danville, CA); Munir, Zuhair A. (Davis, CA)

1990-01-01T23:59:59.000Z

162

X-ray absorption spectroscopic studies of the active sites of nickel- and copper-containing metalloproteins  

SciTech Connect (OSTI)

X-ray absorption spectroscopy (XAS) is a useful tool for obtaining structural and chemical information about the active sites of metalloproteins and metalloenzymes. Information may be obtained from both the edge region and the extended X-ray absorption fine structure (EXAFS) or post-edge region of the K-edge X-ray absorption spectrum of a metal center in a compound. The edge contains information about the valence electronic structure of the atom that absorbs the X-rays. It is possible in some systems to infer the redox state of the metal atom in question, as well as the geometry and nature of ligands connected to it, from the features in the edge in a straightforward manner. The EXAFS modulations, being produced by the backscattering of the ejected photoelectron from the atoms surrounding the metal atom, provide, when analyzed, information about the number and type of neighbouring atoms, and the distances at which they occur. In this thesis, analysis of both the edge and EXAFS regions has been used to gain information about the active sites of various metalloproteins. The metalloproteins studied were plastocyanin (Pc), laccase and nickel carbon monoxide dehydrogenase (Ni CODH). Studies of Cu(I)-imidazole compounds, related to the protein hemocyanin, are also reported here.

Tan, G.O.

1993-06-01T23:59:59.000Z

163

ISO-LWS observations of C+ and O lines in absorption toward SgrB2  

E-Print Network [OSTI]

High spectral resolution ISO-LWS observations of the [OI] 63.2 and 145.5 microns and [CII] 157.7 microns fine structure lines are presented for the center of the Sagittarius B2 complex (SgrB2). Both the [OI] 63.2 microns and the [CII] 157.7 microns lines are detected in absorption. Using observations of the CO isotopes and of the HI lines, absorption components can be associated with many clouds along the Sgr B2 line of sight. From these data, we were able to disentangle three different layers, as predicted by PDR models, which contain atomic oxygen. We derive lower limits for the column densities of C and O. The fact that the [CII] 157.7 microns line is detected in absorption implies that the main cooling line of the interstellar medium can be optically thick especially in the direction of large star-forming complexes or in the nuclei of galaxies. This could partially account for the deficiency in the [CII] 157.7 microns line which has been recently found toward infrared bright galaxies in ISO data.

Charlotte Vastel; Edward Polehampton; Jean-Paul Baluteau; Bruce Swinyard; Emmanuel Caux; Pierre Cox

2002-08-09T23:59:59.000Z

164

X-ray absorption spectroscopy and EPR studies of oriented spinach thylakoid preparations  

SciTech Connect (OSTI)

In this study, oriented Photosystem II (PS II) particles from spinach chloroplasts are studied with electron paramagnetic resonance (EPR) and x-ray absorption spectroscopy (XAS) to determine more details of the structure of the oxygen evolving complex (OEC). The nature of halide binding to Mn is also studied with Cl K-edge and Mn EXAFS (extended x-ray absorption fine structure) of Mn-Cl model compounds, and with Mn EXAFS of oriented PS II in which Br has replaced Cl. Attention is focused on the following: photosynthesis and the oxygen evolving complex; determination of mosaic spread in oriented photosystem II particles from signal II EPR measurement; oriented EXAFS--studies of PS II in the S{sub 2} state; structural changes in PS II as a result of treatment with ammonia: EPR and XAS studies; studies of halide binding to Mn: Cl K-edge and Mn EXAFS of Mn-Cl model compounds and Mn EXAFS of oriented Br-treated photosystem II.

Andrews, J.C. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States). Structural Biology Div.

1995-08-01T23:59:59.000Z

165

Auto-oligomerization and hydration of pyrrole revealed by x-ray absorption spectroscopy  

SciTech Connect (OSTI)

Near edge x-ray absorption fine structure (NEXAFS) spectra have been measured at the carbon and nitrogen K-edges of the prototypical aromatic molecule, pyrrole, both in the gas phase and when solvated in water, and compared with spectra simulated using a combination of classical molecular dynamics and first principles density functional theory in the excited state core hole approximation. The excellent agreement enabled detailed assignments. Pyrrole is highly reactive, particularly in water, and reaction products formed by the auto-oligomerization of pyrrole are identified. The solvated spectra have been measured at two different temperatures, indicating that the final states remain largely unaffected by both hydration and temperature. This is somewhat unexpected, since the nitrogen in pyrrole can donate a hydrogen bond to water.

Advanced Light Source; Schwartz, Craig P.; Uejio, Janel S.; Duffin, Andrew M.; England, Alice H.; Prendergast, David; Saykally, Richard J

2009-05-29T23:59:59.000Z

166

Liquefaction characteristics of a fine sand  

E-Print Network [OSTI]

LIQUEFACTION CHARACTERISTICS OF A FINE SAND A Thesis by DONALD TIMOTHY BRANDON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1974 Major Subject...: Civil Engineering LIQUEFACTION CHARACTERISTICS OF A FINE SAND A Thesis by DONALD TIMOTHY BRANDON Approved as to style and content by: airman o Commi ee) ead of Depar ent) (Member) ( ber) ABSTRACT LIQUEFACTION CEARACTERISTICS OF A FINE SAND...

Brandon, Donald Timothy

2012-06-07T23:59:59.000Z

167

Absorption heat pump system  

DOE Patents [OSTI]

The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

Grossman, G.

1982-06-16T23:59:59.000Z

168

Absorption heat pump system  

DOE Patents [OSTI]

The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

Grossman, Gershon (Oak Ridge, TN)

1984-01-01T23:59:59.000Z

169

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

DeVault, R.C.; Biermann, W.J.

1989-05-09T23:59:59.000Z

170

Seven-effect absorption refrigeration  

DOE Patents [OSTI]

A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit.

DeVault, Robert C. (Knoxville, TN); Biermann, Wendell J. (Fayetteville, NY)

1989-01-01T23:59:59.000Z

171

Suppression of thermal carrier escape and efficient photo-carrier generation by two-step photon absorption in InAs quantum dot intermediate-band solar cells using a dot-in-well structure  

SciTech Connect (OSTI)

We investigated the effects of an increase in the barrier height on the enhancement of the efficiency of two-step photo-excitation in InAs quantum dot (QD) solar cells with a dot-in-well structure. Thermal carrier escape of electrons pumped in QD states was drastically reduced by sandwiching InAs/GaAs QDs with a high potential barrier of Al{sub 0.3}Ga{sub 0.7}As. The thermal activation energy increased with the introduction of the barrier. The high potential barrier caused suppression of thermal carrier escape and helped realize a high electron density in the QD states. We observed efficient two-step photon absorption as a result of the high occupancy of the QD states at room temperature.

Asahi, S.; Teranishi, H.; Kasamatsu, N.; Kada, T.; Kaizu, T.; Kita, T. [Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodai, Nada, Kobe 657-8501 (Japan)

2014-08-14T23:59:59.000Z

172

Synthesis, single-crystal structure, and optical absorption of Rb{sub 2}Th{sub 7}Se{sub 15}  

SciTech Connect (OSTI)

The compound Rb{sub 2}Th{sub 7}Se{sub 15} has been synthesized by the solid-state reaction at 1273 K of Th, Rb{sub 2}Se{sub 3}, Se, and Ge, and its structure has been determined by single-crystal X-ray diffraction methods. Red crystals of Rb{sub 2}Th{sub 7}Se{sub 15} crystallize at 100(2) K with four formula units in a new structure type in the monoclinic space group C{sub 2h}{sup 5}?P2{sub 1}/c. The structure is three-dimensional and comprises Rb and Th atoms coordinated by Se atoms to form nine-, eight-, and seven-coordinate polyhedra. Infinite channels that contain Rb atoms are present. Crystals of Rb{sub 2}Th{sub 7}Se{sub 15} are red in color; an indirect band gap of 1.83 eV was derived from single-crystal optical measurements. - Graphical abstract: Structure of Rb{sub 2}Th{sub 7}Se{sub 15} viewed down the b-axis. Display Omitted - Highlights: The new compound Rb{sub 2}Th{sub 7}Se{sub 15} was synthesized at 1273 K from the elements in the presence of Ge. The structures of the two known Rb/Th/Se compounds, RbTh{sub 2}Se{sub 6} and Rb{sub 2}Th{sub 7}Se{sub 15}, differ markedly. Optical measurements establish the band gap of Rb{sub 2}Th{sub 7}Se{sub 15} to be indirect with a value of 1.83 eV.

Koscielski, Lukasz A.; Pozzi, Eric A.; Van Duyne, Richard P.; Ibers, James A., E-mail: ibers@chem.northwestern.edu

2013-09-15T23:59:59.000Z

173

Roadmap: Fine Arts Interdisciplinary Painting/Sculpture Bachelor of Fine Arts  

E-Print Network [OSTI]

Roadmap: Fine Arts ­ Interdisciplinary Painting/Sculpture ­ Bachelor of Fine Arts [CA This roadmap is a recommended semester-by-semester plan of study for this major. However, courses on page 2 Kent Core Requirement 3 #12;Roadmap: Fine Arts ­ Interdisciplinary Painting/Sculpture ­ Bachelor

Sheridan, Scott

174

Roadmap: Fine Arts Interdisciplinary Drawing/Sculpture Bachelor of Fine Arts  

E-Print Network [OSTI]

Roadmap: Fine Arts ­ Interdisciplinary Drawing/Sculpture ­ Bachelor of Fine Arts [CA This roadmap is a recommended semester-by-semester plan of study for this major. However, courses on page 2 Kent Core Requirement 3 #12;Roadmap: Fine Arts ­ Interdisciplinary Drawing/Sculpture ­ Bachelor

Sheridan, Scott

175

Source Signatures of Fine Particulate Matter from Petroleum Refining and Fuel Use  

SciTech Connect (OSTI)

Combustion experiments were carried out on four different residual fuel oils in a 732 kW boiler. Particulate matter (PM) emission samples were separated aerodynamically by a cyclone into fractions that were nominally less than and greater than 2.5 microns in diameter. However, examination of several of the samples by computer-controlled scanning electron microscopy (CCSEM) revealed that part of the <2.5 micron fraction (PM{sub 2.5}) in fact consists of carbonaceous cenospheres and vesicular particles that range up to 10 microns in diameter. X-ray absorption fine structure (XAFS) spectroscopy data were obtained at the S, V, Ni, Fe, Cu, Zn, and As Kedges, and at the Pb L-edge. Deconvolution of the x-ray absorption near edge structure (XANES) region of the S spectra established that the dominant molecular forms of S present were sulfate (26-84% of total S) and thiophene (13-39% of total S). Sulfate was greater in the PM{sub 2.5} samples than in the >2.5 micron samples (PM{sub 2.5+}). Inorganic sulfides and elemental sulfur were present in lower percentages. The Ni XANES spectra from all of the samples agree fairly well with that of NiSO4, while most of the V spectra closely resemble that of vanadyl sulfate (VO{center_dot}SO{sub 4}{center_dot}xH{sub 2}O). The other metals investigated (Fe, Cu, Zn, and Pb) were also present predominantly as sulfates. Arsenic is present as an arsenate (As{sup +5}). X-ray diffraction patterns of the PM{sub 2.5} fraction exhibit sharp lines due to sulfate compounds (Zn, V, Ni, Ca, etc.) superimposed on broad peaks due to amorphous carbons. All of the samples contain a significant organic component, with the LOI ranging from 64 to 87 % for the PM{sub 2.5} fraction and from 88 to 97% for the PM{sub 2.5+} fraction. {sup 13}C nuclear magnetic resonance (NMR) analysis indicates that the carbon is predominantly condensed in graphitic structures. Aliphatic structure was detected in only one of seven samples examined.

Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Robert Huggins

1999-12-31T23:59:59.000Z

176

SOUTHERN FINE PARTICULATE MONITORING PROJECT  

SciTech Connect (OSTI)

This quarterly report presents results and analysis of continuous onsite ambient fine particulate data at the North Birmingham sampling site during the January-March, 2002 study period. The continuous data include PM{sub 2.5} mass concentrations measured by TEOM, particle sulfate using the R&P 8400S monitor, particle size distributions measured by SMPS and APS monitors, and PM{sub 2.5} light scattering extinction coefficient as measured by nephelometer. Some instrumental issues were noted with the upgrade of the APS model 3320 are described in the report, as well as preliminary performance indications for the upgraded instrument. During the quarter preliminary data analysis and modeling studies were conducted to test the potential of the North Birmingham site data for source attribution analyses. Our initial assessment has continued to be optimistic in this regard due to the location of the site relative to several important classes of local and midrange emission sources. We anticipate that these analyses will provide good separations of the effects of major source classes and spatial source clusters, and will provide useful information relevant to PM{sub 2.5} implementation strategies.

Unknown

2002-04-01T23:59:59.000Z

177

Absorption heat pump system  

DOE Patents [OSTI]

An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

Grossman, Gershon (Oak Ridge, TN); Perez-Blanco, Horacio (Knoxville, TN)

1984-01-01T23:59:59.000Z

178

Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants  

E-Print Network [OSTI]

The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

179

Absorption-Line Spectroscopy of Planetary Nebulae with FUSE: Probing the Molecular, Atomic, and Ionized Gas  

E-Print Network [OSTI]

The central stars of planetary nebulae (PNe) are natural targets for FUSE due to their UV brightness. The FUSE spectra of many PNe show absorption features due to circumstellar material in species ranging from H_2 and neutrals in the photodissociation region (PDR) to ions resident in the H II region. We report results from a program designed to search for nebular components in the H_2 Lyman and Werner resonance lines that are responsible for the fluorescent excitation of H_2 in strong FUV radiation fields. Our failure to detect H_2 in absorption in several PNe with strong near-infrared H_2 emission indicates that the molecular material has an asymmetrical or clumpy distribution. We also detect enrichments in the s-process product Ge, find that Fe is not depleted into dust along at least one line of sight through a PN, and show that starlight fluorescence can affect the populations of the excited fine-structure levels of O I.

Harriet L. Dinerstein; N. C. Sterling; Charles W. Bowers

2004-10-25T23:59:59.000Z

180

The Radio to Infrared Emission of Very High Redshift Gamma-Ray Bursts: Probing Early Star Formation through Molecular and Atomic Absorption Lines  

E-Print Network [OSTI]

We evaluate the broadband afterglow emission of very high redshift gamma-ray bursts (GRBs) using standard relativistic blastwave models with both forward and reverse shock components. For a broad range of parameters, a generic property for GRBs at redshifts $z \\sim$ 5--30 is that the emission peaks in the millimeter to far-infrared bands with milli-Jansky flux levels, first at a few hours after the burst due to the reverse shock, and then again for several days afterwards with somewhat lower flux due to the forward shock. The radio, submillimeter and infrared continuum emission should be readily detectable out to $z \\ga 30$ by the Atacama Large Millimeter Array (ALMA), Extended Very Large Array (EVLA), Square Kilometer Array (SKA) and other facilities. For relatively bright bursts, spectroscopic measurements of molecular and atomic absorption lines due to ambient protostellar gas may be possible. Utilizing models of primordial protostellar clouds, we show that under certain conditions, appreciable absorption may be caused by HD rotational transitions even in metal-free environments. After sufficient metal enrichment, absorption from CO rotational transitions and [OI] fine-structure transitions can also become strong. With appropriate observing strategies in combination with optical telescopes, ALMA and/or SKA may be able to detect such lines, offering a unique probe of physical conditions in individual Pop III and early Pop II star forming regions. We also remark on potential near-infrared absorption features due to electronic transitions of H$_2$.

Susumu Inoue; Kazuyuki Omukai; Benedetta Ciardi

2007-07-14T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Intrinsic AGN Absorption Lines  

E-Print Network [OSTI]

Strong absorption lines are common in rest-frame UV spectra of AGNs due to a variety of resonant transitions, for example the HI Lyman series lines (most notably Ly-alpha 1216) and high-ionization doublets like CIV 1549,1551. The lines are called ``intrinsic'' if the absorbing gas is physically related to the AGN, e.g. if the absorber resides broadly within the radius of the AGN's surrounding ``host'' galaxy. Intrinsic absorption lines are thus valuable probes of the kinematics, physical conditions and elemental abundances in the gas near AGNs. Studies of intrinsic absorbers have historically emphasized the broad absorption lines (BALs) in quasars. Today we recognize a wider variety of intrinsic lines in a wider range of objects. For example, we now know that Seyfert 1 galaxies (the less luminous cousins of quasars) have intrinsic absorption. We also realize that intrinsic lines can form in a range of AGN environments --- from the dynamic inner regions like the BALs, to the more quiescent outer host galaxies >10 kpc away. This article provides a brief introduction to current observational and theoretical work on intrinsic AGN absorbers.

Fred Hamann

2000-06-12T23:59:59.000Z

182

Formaldehyde Absorption toward W51  

SciTech Connect (OSTI)

We have measured formaldehyde (H{sub 2}CO) absorption toward the HII region complex W51A (G49.5-0.4) in the 6 cm and 2 cm wavelength rotational transitions with angular resolution of approximately 4 inch. The continuum HII region shows a large, previously undetected shell structure 5.5 pc along the major axis. We observe no H{sub 2}CO emission in regions of low continuum intensity. The absorption, converted to optical depth, shows a higher degree of clumping than previous maps at lower resolution. The good S/N of the maps allows accurate estimation of the complicated line profiles, showing some of the absorbing clouds to be quite patchy. We list the properties of the opacity spectra for a number of positions both in the clumps and in the more diffuse regions of the absorbing clouds, and derive column densities for the 1{sub 11} and 2{sub 12} rotational levels of ortho-formaldehyde.

Kogut, A.; Smoot, G.F.; Bennett, C.L.; Petuchowski, S.J.

1988-04-01T23:59:59.000Z

183

York University Faculty of Fine Arts  

E-Print Network [OSTI]

, Design, Digital Media, Film, Music, Theatre and Visual Arts. performance, which explores how digital media is transforming performance practice, Dance, Music, Film and Media Studies, Digital Media, or a related Fine Arts

184

Immobilization of Rocky Flats Graphite Fines Residue  

SciTech Connect (OSTI)

The development of the immobilization process for graphite fines has proceeded through a series of experimental programs. The experimental procedures and results from each series of experiments are discussed in this report.

Rudisill, T.S.

1999-04-06T23:59:59.000Z

185

Plasmon absorption modulator systems and methods  

SciTech Connect (OSTI)

Plasmon absorption modulator systems and methods are disclosed. A plasmon absorption modulator system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and a metal layer formed on a top surface of the stack of quantum well layers. A method for modulating plasmonic current includes enabling propagation of the plasmonic current along a metal layer, and applying a voltage across the stack of quantum well layers to cause absorption of a portion of energy of the plasmonic current by the stack of quantum well layers. A metamaterial switching system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and at least one metamaterial structure formed on a top surface of the stack of quantum well layers.

Kekatpure, Rohan Deodatta; Davids, Paul

2014-07-15T23:59:59.000Z

186

Pelletization of fine coals. Final report  

SciTech Connect (OSTI)

Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

Sastry, K.V.S.

1995-12-31T23:59:59.000Z

187

The Quantum Absorption Refrigerator  

E-Print Network [OSTI]

A quantum absorption refrigerator driven by noise is studied with the purpose of determining the limitations of cooling to absolute zero. The model consists of a working medium coupled simultaneously to hot, cold and noise baths. Explicit expressions for the cooling power are obtained for Gaussian and Poisson white noise. The quantum model is consistent with the first and second laws of thermodynamics. The third law is quantified, the cooling power J_c vanishes as J_c proportional to T_c^{alpha}, when T_c approach 0, where alpha =d+1 for dissipation by emission and absorption of quanta described by a linear coupling to a thermal bosonic field, where d is the dimension of the bath.

Amikam Levy; Ronnie Kosloff

2011-11-09T23:59:59.000Z

188

Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption  

SciTech Connect (OSTI)

The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C. (ANU)

2014-09-24T23:59:59.000Z

189

Development of an Advanced Fine Coal Suspension Dewatering Process  

SciTech Connect (OSTI)

With the advancement in fine coal cleaning technology, recovery of fine coal (minus 28 mesh) has become an attractive route for the U.S. coal industry. The clean coal recovered using the advanced flotation technology i.e. column flotation, contains on average 20% solids and 80% water, with an average particle size of 35 microns. Fine coal slurry is usually dewatered using a vacuum dewatering technique, providing a material with about 25 to 30 percent moisture. The process developed in this project will improve dewatering of fine (0.6mm) coal slurry to less than 20 percent moisture. Thus, thermal drying of dewatered wet coal will be eliminated. This will provide significant energy savings for the coal industry along with some environmental benefits. A 1% increase in recovery of coal and producing a filter cake material of less than 20 % moisture will amount to energy savings of 1900 trillion Btu/yr/unit. In terms of the amount of coal it will be about 0.8% of the total coal being used in the USA for electric power generation. It is difficult to dewater the fine clean coal slurry to about 20% moisture level using the conventional dewatering techniques. The finer the particle, the larger the surface area and thus, it retains large amounts of moisture on the surface. The coal industry has shown some reluctance in using the advanced coal recovery techniques, because of unavailability of an economical dewatering technique which can provide a product containing less than 20% moisture. The U.S.DOE and Industry has identified the dewatering of coal fines as a high priority problem. The goal of the proposed program is to develop and evaluate a novel two stage dewatering process developed at the University of Kentucky, which involves utilization of two forces, namely, vacuum and pressure for dewatering of fine coal slurries. It has been observed that a fine coal filter cake formed under vacuum has a porous structure with water trapped in the capillaries. When this porous cake is subjected to pressure for a short time, the free water present is released from the filter cake. Laboratory studies have shown that depending on the coal type a filter cake containing about 15% moisture could be obtained using the two-stage filtration technique. It was also noted that applying intermittent breaks in vacuum force during cake formation, which disturbed the cake structure, helped in removing moisture from the filter cakes. In this project a novel approach of cleaning coal using column flotation was also developed. With this approach the feed capacity of the column is increased significantly, and the column was also able to recover coarser size coal which usually gets lost in the process. The outcome of the research benefits the coal industry, utility industry, and indirectly the general public. The benefits can be counted in terms of clean energy, cleaner environment, and lower cost power.

B. K. Parekh; D. P. Patil

2008-04-30T23:59:59.000Z

190

VARIOUS APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY  

E-Print Network [OSTI]

APPLICATIONS OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPYthe Zeeman effect to atomic absorption spectroscopy has beenthe Zeeman effect on atomic absorption spectrometry has been

Koizumi, Hideaki

2011-01-01T23:59:59.000Z

191

Moisture absorption modeling using design of experiments  

E-Print Network [OSTI]

Moisture Absorption Modeling Using Design of Experimentssurface pro?les of moisture absorption for the two laminatetheir amounts of moisture absorption are different. The

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

192

Antiproton Absorption in Nuclei  

E-Print Network [OSTI]

We present the analysis of experimental data on forward antiproton production on nuclei. The calculations are done in the framework of a folding model which takes properly into account both incoherent direct proton-nucleon and cascade pion-nucleon antiproton production processes as well as internal nucleon momentum distribution. The effective antiproton-nucleon cross section in nuclear matter and the imaginary part of the antiproton nuclear optical potential are estimated to be 25-45 mb and -(38-56) MeV at normal nuclear matter density, respectively. The results of the performed analysis evidence for the decreasing of antiproton absorption in the nuclear medium.

Yu. T. Kiselev; E. Ya. Paryev

2006-01-24T23:59:59.000Z

193

X-ray Absorption Spectroscopy: a powerful tool for the investigation  

E-Print Network [OSTI]

X-ray Absorption Spectroscopy: a powerful tool for the investigation of the role of metals is to illustrate the potentialities of X-ray Absorption Spectroscopy (XAS) to investigate structural properties Protein and Zinc ions 2 Introduction to the X-ray Absorption Spec- troscopy XAS uses Synchrotron Radiation

Morante, Silvia

194

Electrical Conductivity, Near-Infrared Absorption, and Thermal Lens Spectroscopic Studies of Percolation of Microemulsions  

E-Print Network [OSTI]

Electrical Conductivity, Near-Infrared Absorption, and Thermal Lens Spectroscopic Studies studied below and above the percolation thresholds by electrical conductivity, near-infrared absorption. In this work the structure of microemulsions was investigated by using the near-IR absorption and thermal lens

Reid, Scott A.

195

Direct and quantitative photothermal absorption spectroscopy of individual particulates  

SciTech Connect (OSTI)

Photonic structures can exhibit significant absorption enhancement when an object's length scale is comparable to or smaller than the wavelength of light. This property has enabled photonic structures to be an integral component in many applications such as solar cells, light emitting diodes, and photothermal therapy. To characterize this enhancement at the single particulate level, conventional methods have consisted of indirect or qualitative approaches which are often limited to certain sample types. To overcome these limitations, we used a bilayer cantilever to directly and quantitatively measure the spectral absorption efficiency of a single silicon microwire in the visible wavelength range. We demonstrate an absorption enhancement on a per unit volume basis compared to a thin film, which shows good agreement with Mie theory calculations. This approach offers a quantitative approach for broadband absorption measurements on a wide range of photonic structures of different geometric and material compositions.

Tong, Jonathan K.; Hsu, Wei-Chun; Eon Han, Sang; Burg, Brian R.; Chen, Gang, E-mail: gchen2@mit.edu [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Zheng, Ruiting [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China)] [Key Laboratory of Radiation Beam Technology and Materials Modification of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875 (China); Shen, Sheng [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)] [Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213 (United States)

2013-12-23T23:59:59.000Z

196

ORIGINAL ARTICLE Fine Particulate Matter and Mortality  

E-Print Network [OSTI]

landmark cohort studies for estimating the chronic effects of fine particulate air pollution (PM2 that the Medicare files can be used to construct on-going cohorts for tracking the risk of air pollution over time- tory diseases, and also with increased mortality.1­6 Chronic effects of air pollution potentially

Dominici, Francesca

197

University of Florida College of Fine Arts  

E-Print Network [OSTI]

­ pursuing the degree ­ final project and exams ­ graduation. General information for both Master's degree1 University of Florida College of Fine Arts School of Music GRADUATE STUDIES HANDBOOK Section 1 for International Student Services Graduate Music Placement Exams Graduate Listserv Graduate Advisory Group Section

Watson, Craig A.

198

7, 96359661, 2007 apportionment of fine  

E-Print Network [OSTI]

). The air pollution generated in megacities poses a threat to human health and25 the environment; Mexico organic aerosol in Mexico City during the MILAGRO Experiment 2006 E. A. Stone1 , D. C. Snyder1 , R. J fraction of fine particulate matter (PM2.5) in Mexico City. Daily and select 12-h PM2.5 samples were

Boyer, Edmond

199

Arthur Fine Bohrs Response to EPR: Criticism  

E-Print Network [OSTI]

Arthur Fine Bohrs Response to EPR: Criticism and Defense If a specific question has meaning of focus that Niels Bohr makes in responding to EPR.1 EPR appeal to measurement as sometimes sufficient ("elements of reality"). In his response, Bohr, while paraphrasing thewordsofEPR

Fine, Arthur

200

System for utilizing oil shale fines  

DOE Patents [OSTI]

A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort (20) which pyrolyzes the fines in the presence of heated gaseous combustion products, the cyclone retort having a first outlet (30) through which vapors can exit that can be cooled to provide oil, and having a second outlet (32) through which spent shale fines are removed. A burner (36) connected to the spent shale outlet of the cyclone retort, burns the spent shale with air, to provide hot combustion products (24) that are carried back to the cyclone retort to supply gaseous combustion products utilized therein. The burner heats the spent shale to a temperature which forms a molten slag, and the molten slag is removed from the burner into a quencher (48) that suddenly cools the molten slag to form granules that are relatively inert and of a size that is convenient to handle for disposal in the ground or in industrial processes.

Harak, Arnold E. (Laramie, WY)

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

700:20131001.1211 Fine Sun Sensor  

E-Print Network [OSTI]

700:20131001.1211 Fine Sun Sensor The Laboratory for Atmospheric and Space Physics (LASP) at the University of Colorado, Boulder is a world leader in space-based research including measurements of the Sun with respect to sun center. LASP has built sun position sensors for decades beginning with sensors for sub

Mojzsis, Stephen J.

202

Ultrasonic absorption in liquid mixtures  

E-Print Network [OSTI]

, It is obvious that much moxe experimental dates both absorption snd thermalv is needed before this theory can be substantiated Purpose of the Investigation Ths present research was undertaken to investigate thoroughly ths absorption in mixtuxws of ethanol... Agricultural and lheohaaioal College of %nas ia partial fulfi&went of tbs aequtreaante for the daggse of ~t %53 ~or Sub)eot Pllgedss Table of Contents Ii Beokgxeund snd Theory Absorption in Pure Liqu1ds 8, Absorpt1on in Idquid Bixtures XI Purpose...

Davis, James Madison

2012-06-07T23:59:59.000Z

203

Balmer Absorption Lines in FeLoBALs  

E-Print Network [OSTI]

We discovered non-stellar Balmer absorption lines in two many-narrow-trough FeLoBALs (mntBALs) by the near-infrared spectroscopy with Subaru/CISCO. Presence of the non-stellar Balmer absorption lines is known to date only in the Seyfert galaxy NGC 4151, thus our discovery is the first cases for quasars. Since all known active galactic nuclei with Balmer absorption lines share characteristics, it is suggested that there is a population of BAL quasars which have unique structures at their nuclei or unique evolutionary phase.

K. Aoki; I. Iwata; K. Ohta; N. Tamura; M. Ando; M. Akiyama; G. Kiuchi; K. Nakanishi

2006-12-14T23:59:59.000Z

204

EMERGING INFRARED LASER ABSORPTION SPECTROSCOPIC  

E-Print Network [OSTI]

CHAPTER 4 EMERGING INFRARED LASER ABSORPTION SPECTROSCOPIC TECHNIQUES FOR GAS ANALYSIS Frank K detection and monitoring of molecular trace gas species in the mid-infrared spectral region be- cause many of the infrared laser source. Well established detection methods include several types of multipass gas absorption

205

TECHNIQUES FOR THE STUDY OF THE STRUCTURAL PROPERTIES.  

SciTech Connect (OSTI)

The evolution of our understanding of the behavior of oxide nanostructures depends heavily on the structural information obtained from a wide range of physical methods traditionally used in solid state physics, surface science and inorganic chemistry. In this chapter, we describe several techniques that are useful for the characterization of the structural properties of oxide nanostructures: X-ray diffraction (XRD) and scattering, X-ray absorption fine structure (XAFS), Raman spectroscopy, transmission electron microscopy (TEM), scanning tunneling microscopy (STM) and atomic force microscopy (AFM). The ultimate goal is to obtain information about the spatial arrangement of atoms in the nanostructures with precise interatomic distances and bond angles. This may not be possible for complex systems and one may get only partial information about the local geometry or morphology.

FERNANDEZ-GARCIA, M.; RODRIGUEZ, J.A.; MARTINEZ-ARIAS, A.; HANSON, J.C.

2006-06-30T23:59:59.000Z

206

Eta absorption by mesons  

E-Print Network [OSTI]

Using the $[SU(3)_{\\mathrm{L}} \\times SU(3)_{\\mathrm{R}}]_{\\mathrm{global}% }\\times [SU(3)_V]_{\\mathrm{local}}$ chiral Lagrangian with hidden local symmetry, we evaluate the cross sections for the absorption of eta meson ($% \\eta$) by pion ($\\pi$), rho ($\\rho$), omega ($\\omega$), kaon ($K$), and kaon star ($K^*$) in the tree-level approximation. With empirical masses and coupling constants as well as reasonable values for the cutoff parameter in the form factors at interaction vertices, we find that most cross sections are less than 1 mb, except the reactions $\\rho\\eta\\to K\\bar K^*(\\bar KK^*)$, $\\omega\\eta\\to K\\bar K^*(\\bar KK^*)$, $K^*\\eta\\to\\rho K$, and $K^*\\eta\\to\\omega K$, which are a few mb, and the reactions $\\pi\\eta\\to K\\bar K$ and $K\\eta\\to\\pi K$, which are more than 10 mb. Including these reactions in a kinetic model based on a schematic hydrodynamic description of relativistic heavy ion collisions, we find that the abundance of eta mesons likely reaches chemical equilibrium with other hadrons in nuclear collisions at the Relativistic Heavy Ion Collider.

W. Liu; C. M. Ko; L. W. Chen

2005-12-12T23:59:59.000Z

207

Achieving progressive fine granularity scalable coding in H.26L  

E-Print Network [OSTI]

Fine granularity scalable (FGS) coding and progressive fine granularity scalable (PFGS) coding are novel scalable video schemes which are ideally suited for streaming multimedia over networks with varying bandwidth, network conditions and receiver...

Shanmugampillai, Muthukumar

2001-01-01T23:59:59.000Z

208

Process for treating moisture laden coal fines  

DOE Patents [OSTI]

A process is provided for making a free flowing granular product from moisture laden caked coal fines, such as wet cake, by mixing a water immiscible substance, such as oil, with the caked coal, preferably under low shear forces for a period of time sufficient to produce a plurality of free flowing granules. Each granule is preferably comprised of a dry appearing admixture of one or more coal particle, 2-50% by weight water and the water immiscible substance.

Davis, Burl E. (New Kensington, PA); Henry, Raymond M. (Gibsonia, PA); Trivett, Gordon S. (South Surrey, CA); Albaugh, Edgar W. (Birmingham, AL)

1993-01-01T23:59:59.000Z

209

In-situ X-ray absorption spectroscopy analysis of capacity fade in nanoscale-LiCoO{sub 2}  

SciTech Connect (OSTI)

The local structure of nanoscale (?1040 nm) LiCoO{sub 2} is monitored during electrochemical cycling utilizing in-situ X-ray absorption spectroscopy (XAS). The high surface area of the LiCoO{sub 2} nanoparticles not only enhances capacity fade, but also provides a large signal from the particle surface relative to the bulk. Changes in the nanoscale LiCoO{sub 2} metal-oxide bond lengths, structural disorder, and chemical state are tracked during cycling by adapting the delta mu (??) technique in complement with comprehensive extended X-ray absorption fine structure (EXAFS) modeling. For the first time, we use a ?? EXAFS method, and by comparison of the difference EXAFS spectra, extrapolate significant coordination changes and reduction of cobalt species with cycling. This combined approach suggests LiCo site exchange at the surface of the nanoscale LiCoO{sub 2} as a likely factor in the capacity fade and irreversible losses in practical, microscale LiCoO{sub 2}. - Graphical abstract: Electrochemical cycling of Li-ion batteries has strong impact on the structure and integrity of the cathode active material particularly near the surface/electrolyte interface. In developing a new method, we have used in-situ X-ray absorption spectroscopy during electrochemical cycling of nanoscale LiCoO{sub 2} to track changes during charge and discharge and between subsequent cycles. Using difference spectra, several small changes in Co-O bond length, Co-O and Co-Co coordination, and site exchange between Co and Li sites can be tracked. These methods show promise as a new technique to better understand processes which lead to capacity fade and loss in Li-ion batteries. - Highlights: A new method is developed to understand capacity fade in Li-ion battery cathodes. Structural changes are tracked during Li intercalation/deintercalation of LiCoO{sub 2}. Surface structural changes are emphasized using nanoscale-LiCoO{sub 2} and difference spectra. Full multiple scattering calculations are used to support ?? analysis.

Patridge, Christopher J. [NRC/NRL Cooperative Research Associate, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Love, Corey T., E-mail: corey.love@nrl.navy.mil [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Swider-Lyons, Karen E. [Chemistry Division, Code 6113, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Twigg, Mark E. [Electronics Science and Technology Division, Code 6812, U.S. Naval Research Laboratory, Washington, DC 20375 (United States); Ramaker, David E. [Chemistry Division, Code 6189, U.S. Naval Research laboratory, Washington, DC 20375 (United States)

2013-07-15T23:59:59.000Z

210

Mg/Ti multilayers: Structural and hydrogen absorption properties A. Baldi,1,2,* G. K. Plsson,3 M. Gonzalez-Silveira,1 H. Schreuders,2 M. Slaman,1,2 J. H. Rector,1 G. Krishnan,4  

E-Print Network [OSTI]

of hydrogen in Mg and Ti, as shown by diffusion calculations on a model multilayered systems. Absorption strongly bonded Mg/Pd and broken Mg/Ti interfaces. DOI: 10.1103/PhysRevB.81.224203 PACS number s : 68.65.Ac I. INTRODUCTION Magnesium and titanium are immiscible. Metastable Mg-Ti alloys have nevertheless

Wijngaarden, Rinke J.

211

alpha fine structure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interlaced by concentrations of stronger magnetic field at the interface between the umbra and the outer field-free atmosphere. Calculated synthetic images show dark cores like...

212

The fine-structure constant and wavelength calibration  

E-Print Network [OSTI]

82, 888 Edlen, B. 1966, Metrologia, 2, 71 Flambaum, V. V.82, 888 Edlen, B. 1966, Metrologia, 2, 71 Flambaum, V. V.82, 888 Edlen, B. 1966, Metrologia, 2, 71 Flambaum, V. V.

Whitmore, Jonathan

2011-01-01T23:59:59.000Z

213

Microwave absorptions of ultrathin conductive films and designs of frequency-independent ultrathin absorbers  

SciTech Connect (OSTI)

We study the absorption properties of ultrathin conductive films in the microwave regime, and find a moderate absorption effect which gives rise to maximal absorbance 50% if the sheet (square) resistance of the film meets an impedance matching condition. The maximal absorption exhibits a frequency-independent feature and takes place on an extremely subwavelength scale, the film thickness. As a realistic instance, ?5 nm thick Au film is predicted to achieve the optimal absorption. In addition, a methodology based on metallic mesh structure is proposed to design the frequency-independent ultrathin absorbers. We perform a design of such absorbers with 50% absorption, which is verified by numerical simulations.

Li, Sucheng; Anwar, Shahzad; Lu, Weixin; Hang, Zhi Hong; Hou, Bo, E-mail: houbo@suda.edu.cn, E-mail: phyhoubo@gmail.com; Shen, Mingrong [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China)] [School of Physical Science and Technology, Soochow University, 1 Shizi Street, Suzhou 215006 (China); Wang, Chin-Hua [Institute of Modern Optical Technologies and Collaborative Innovation Center of Suzhou Nano Science and Technology, Jiangsu Key Lab of Advanced Optical Manufacturing Technologies, Soochow University, 1 Shizi Street, Suzhou 215006 (China)] [Institute of Modern Optical Technologies and Collaborative Innovation Center of Suzhou Nano Science and Technology, Jiangsu Key Lab of Advanced Optical Manufacturing Technologies, Soochow University, 1 Shizi Street, Suzhou 215006 (China)

2014-01-15T23:59:59.000Z

214

Absorption properties of identical atoms  

SciTech Connect (OSTI)

Emission rates and other optical properties of multi-particle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas. -- Highlights: The absorption rates of a pair of identical atoms in product and (anti)symmetrized states are different. The modifications of the optical properties are essentially determined by the overlapping between the atoms. The absorption properties differ, in some cases, for bosons and fermions.

Sancho, Pedro, E-mail: psanchos@aemet.es

2013-09-15T23:59:59.000Z

215

The determination of the moisture absorption characteristics of lightweight concrete aggregates  

E-Print Network [OSTI]

'. ! on A & p&. d Me I I l. A New Me&h'd nf les& Kesul ts nf Test s &v the New Method t ''n&. !us& Appendix A Exp. ::m n? ! Data . u ne &di x, t&. Standard Me&bud of Test for Specific. Grav& tv and Absorption of Coarse Aggregate Appendix ( S...&sndsrd Method of Test for Specific Grsvitv nd Abso& pt &un of Fine Aggregate Appe &dix D Standard Definitions of Terms Relating tn Specific Gravity Appendi x E A D! rec t Method of Determining Absorption and Specific Gravitv of Aggregates hy Edwi~ L. Saxer...

Bryant, Julian Stephen

1959-01-01T23:59:59.000Z

216

Collision--induced absorption in dense atmospheres of cool stars  

SciTech Connect (OSTI)

In the atmosphere of the Sun the major interaction between the matter and the radiation is through light absorption by ions (predominantly the negative ion of hydrogen atoms), neutral atoms and a small amount of polar molecules. The majority of stars in the universe are, however, cooler and denser than our Sun, and for a large fraction of these, the above absorption processes are very weak. Here, collision-induced absorption (CIA) becomes the dominant opacity source. The radiation is absorbed during very short mutual passages ('collisions') of two non-polar molecules (and/or atoms), while their electric charge distributions are temporarily distorted which gives rise to a transient dipole moment. We present here a review of the present-day knowledge about the impact of collision-induced absorption processes on the structure and the spectrum of such stars.

Borysow, Aleksandra; Joergensen, Uffe Graae [Niels Bohr Institute, for Astronomy, Physics and Geophysics, University Observatory, Juliane Maries vej 30, DK-2100 Copenhagen (Denmark)

1999-04-01T23:59:59.000Z

217

Thorium nanochemistry: the solution structure of the Th(IV)?hydroxo pentamer  

SciTech Connect (OSTI)

Tetravalent thorium exhibits a strong tendency towards hydrolysis and subsequent polymerization. Polymeric species play a crucial role in understanding thorium solution chemistry, since their presence causes apparent solubility several orders of magnitude higher than predicted by thermodynamic data bases. Although electrospray mass spectrometry (ESI MS) identifies Th(IV) dimers and pentamers unequivocally as dominant species close to the solubility limit, the molecular structure of Th{sub 5}(OH){sub y} polymers was hitherto unknown. In the present study, X-ray absorption fine structure (XAFS) spectroscopy, high energy X-ray scattering (HEXS) measurements, and quantum chemical calculations are combined to solve the pentamer structure. The most favourable structure is represented by two Th(IV) dimers linked by a central Th(IV) cation through hydroxide bridges.

Walther, Clemens; Rothe, Jrg; Schimmelpfennig, Bernd; Fuss, Markus (Karlsruher)

2012-10-10T23:59:59.000Z

218

Photon interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T. Ishikawa  

E-Print Network [OSTI]

. Therefore the atomic absorption coeffi- cient a is given by a a PI a ES a Incoh , 1 where a PI , a ESPhoton interference effect in x-ray absorption spectra over a wide energy range Y. Nishino and T Received 3 July 2002; published 12 September 2002 We consider fundamental structures in x-ray absorption

Korecki, Pawe³

219

Transient absorption spectroscopy of laser shocked explosives  

SciTech Connect (OSTI)

Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

Mcgrane, Shawn D [Los Alamos National Laboratory; Dang, Nhan C [Los Alamos National Laboratory; Whitley, Von H [Los Alamos National Laboratory; Bolome, Cindy A [Los Alamos National Laboratory; Moore, D S [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

220

Near-infrared free carrier absorption in heavily doped silicon  

SciTech Connect (OSTI)

Free carrier absorption in heavily doped silicon can have a significant impact on devices operating in the infrared. In the near infrared, the free carrier absorption process can compete with band to band absorption processes, thereby reducing the number of available photons to optoelectronic devices such as solar cells. In this work, we fabricate 18 heavily doped regions by phosphorus and boron diffusion into planar polished silicon wafers; the simple sample structure facilitates accurate and precise measurement of the free carrier absorptance. We measure and model reflectance and transmittance dispersion to arrive at a parameterisation for the free carrier absorption coefficient that applies in the wavelength range between 1000 and 1500?nm, and the range of dopant densities between ?10{sup 18} and 3??10{sup 20}?cm{sup ?3}. Our measurements indicate that previously published parameterisations underestimate the free carrier absorptance in phosphorus diffusions. On the other hand, published parameterisations are generally consistent with our measurements and model for boron diffusions. Our new model is the first to be assigned uncertainty and is well-suited to routine device analysis.

Baker-Finch, Simeon C., E-mail: simeon.bakerfinch@gmail.com [School of Engineering, Australian National University, Canberra, ACT 0200 (Australia); PV Lighthouse, Coledale, NSW 2515 (Australia); McIntosh, Keith R. [PV Lighthouse, Coledale, NSW 2515 (Australia); Yan, Di; Fong, Kean Chern; Kho, Teng C. [School of Engineering, Australian National University, Canberra, ACT 0200 (Australia)

2014-08-14T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Quasistellar Objects: Intervening Absorption Lines  

E-Print Network [OSTI]

We briefly review, at a level appropriate for graduate students and non-specialists, the field of quasar absorption lines (QALs). Emphasis is on the intervening absorbers. We present the anatomy of a quasar spectrum due to various classes of intervening absorption systems, and a brief historical review of each absorber class (Lyman-alpha forest and Lyman limit systems, and metal-line and damped Lyman-alpha absorbers). We also provide several heuristic examples on how the physical properties of both the intergalactic medium and the gaseous environments associated with earlier epoch galaxies can be inferred from QALs. The evolution of these environments from z=4 are discussed.

Jane C. Charlton; Christopher W. Churchill

2000-05-31T23:59:59.000Z

222

Absorption-heat-pump system  

DOE Patents [OSTI]

An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

Grossman, G.; Perez-Blanco, H.

1983-06-16T23:59:59.000Z

223

Saturable absorption and 'slow light'  

E-Print Network [OSTI]

Quantitative evaluation of some recent 'slow light' experiments based on coherent population oscillations (CPO) shows that they can be more simply interpreted as saturable absorption phenomena. Therefore they do not provide an unambiguous demonstration of 'slow light'. Indeed a limiting condition on the spectral bandwidth is not generally satisfied, such that the requirements for burning a narrow spectral hole in the homogeneously broadened absorption line are not met. Some definitive tests of 'slow light' phenomena are suggested, derived from analysis of phase shift and pulse delay for a saturable absorber

Adrian C Selden

2006-03-25T23:59:59.000Z

224

Transient Xray absorption features in GRBs 1 Transient XRay Absorption in GRBs  

E-Print Network [OSTI]

due to photoelectric absorption or other atomic processes.) The transient nature of the absorptionTransient X­ray absorption features in GRBs 1 Transient X­Ray Absorption in GRBs and its Abstract The recent detection of a transient absorption feature in the prompt emission of GRB 990705 has

Boettcher, Markus

225

active fine particulates: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences and Ecology Websites Summary: Effects of Sampling Conditions on the Size Distribution of Fine Particulate Matter Emitted from complex because the dilution...

226

Self-consistent QM/MM methodologies for structural refinement of photosystem II and other macromolecules of biological interest  

SciTech Connect (OSTI)

The combination of quantum mechanics and molecular mechanics (QM/MM) is one of the most promising approaches to study the structure, function, and properties of proteins and nucleic acids. However, there some instances in which the limitations of either the MM (lack of a proper electronic description) or QM (limited to a few number of atoms) methods prevent a proper description of the system. To address this issue, we review here our approach to fine-tune the structure of biological systems using post-QM/MM refinements. These protocols are based on spectroscopy data, and/or partitioning of the system to extend the QM description to a larger region of a protein. We illustrate these methodologies through applications to several biomolecules, which were pre-optimized at the QM/MM level and then further refined using postQM/MM refinement methodologies: mod(QM/MM), which refines the atomic charges of the residues included in the MM region accounting for polarization effects; mod(QM/MM)-opt that partition the MM region in smaller parts and optimizes each part in an iterative. self-consistent way, and the Polarized-Extended X-Ray Absorption Fine Structure (P-EXAFS) fitting procedure, which fine-tune the atomic coordinates to reproduce experimental polarized EXAFS spectra. The first two techniques were applied to the guanine quadruplex. while the P-EXAFS refinement was applied to the oxygen evolving complex of photosystem II.

Batista, Enrique R [Los Alamos National Laboratory; Sproviero, Eduardo M [YALE UNIV; Newcomer, Michael [YALE UNIV; Gascon, Jose A [YALE UNIV; Batista, Victor S [YALE UNIV

2008-01-01T23:59:59.000Z

227

Interferometric tunability of the absorption  

E-Print Network [OSTI]

We propose an interferometric setup that permits to tune the quantity of radiation absorbed by an object illuminated by a fixed light source. The method can be used to selectively irradiate portions of an object based on their transmissivities or to accurately estimate the transmissivities from rough absorption measurements.

Vittorio Giovannetti; Seth Lloyd; Lorenzo Maccone

2006-03-27T23:59:59.000Z

228

Gyrotropic-nihility state in a composite ferrite-semiconductor structure  

E-Print Network [OSTI]

Characteristics of the gyrotropic-nihility state are studied in a finely-stratified ferrite-semiconductor structure, which is under an action of an external static magnetic field. Investigations are carried out with the assistance of the effective medium theory, according to which the studied structure is approximated as a uniform gyroelectromagnetic medium. The theory of the gyrotropic-nihility state is developed in terms of the eigenwaves propagation in such gyroelectromagnetic medium. The frequency and angular dependencies of the transmittance, reflectance and absorption coefficient are presented. It turns out that in the frequency band around the frequency of gyrotropic-nihility state the studied structure appears to be matched to free space with both the refractive index and the wave impedance which results in its high transmittance almost in the entire range of angles of the electromagnetic wave incidence.

Tuz, Vladimir R

2014-01-01T23:59:59.000Z

229

Nonlinear absorption in silicon nanocrystals  

SciTech Connect (OSTI)

The nonlinear absorption of light in silicon nanocrystals suspended in glycerol is studied by the Z-scan method. The experimental data are used for calculating the nonlinear absorption coefficient {beta}{sub Si-gl} for silicon nanocrystals in glycerol (with a volume filling factor f=2x10{sup -4}), and the coefficient {beta}{sub Si} for pure silicon with a hypothetical volume filling factor f{approx}1. For the laser radiation wavelength {lambda}=497 nm and the pulse duration {tau}=0.5 ns, these coefficients are {beta}{sub Si-gl}=1.2x10{sup -8} cm W{sup -1} and {beta}{sub Si} =7.36x10{sup -5} cm W{sup -1}, while the corresponding values for {lambda}=532 nm and {tau}=10 ns are {beta}{sub Si-gl}=5.36x10{sup -5} cm W{sup -1} and {beta}{sub Si} =0.25 cm W{sup -1}. Experiments with 540-nm, 20-ps laser pulses performed for two different filling factors equal to 2x10{sup -4} and 3x10{sup -3} gave nonlinear absorption coefficients {beta}{sub Si-gl}=2x10{sup -7} and 3.6x10{sup -6} cm W{sup -1}, respectively. Optical absorption and Raman scattering spectra of silicon nanocrystals are also studied. A theoretical analysis of the experimental results shows that optical absorption can be related to the localisation of photoexcited carriers in the conduction band. The localisation is caused by the action of strong static electric fields on an electron in a nanoparticle. (nonlinear optical phenomena)

Korovin, S B; Orlov, A N; Prokhorov, A M; Pustovoi, V I [Natural Science Center, A.M. Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Konstantaki, M; Couris, S; Koudoumas, E [Foundation for Research and Technology-Hellas (IESL-FORTH), Institute of Electronic Structure and Lasers, Crete (Greece)

2001-09-30T23:59:59.000Z

230

H I ABSORPTION TOWARD H II REGIONS AT SMALL GALACTIC LONGITUDES  

SciTech Connect (OSTI)

We make a comprehensive study of H I absorption toward H II regions located within |l| < 10 Degree-Sign . Structures in the extreme inner Galaxy are traced using the longitude-velocity space distribution of this absorption. We find significant H I absorption associated with the Near and Far 3 kpc Arms, the Connecting Arm, Bania's Clump 1, and the H I Tilted Disk. We also constrain the line-of-sight distances to H II regions, by using H I absorption spectra together with the H II region velocities measured by radio recombination lines.

Jones, C.; Dickey, J. M.; Dawson, J. R. [School of Mathematics and Physics, Private Bag 37, University of Tasmania, Hobart 7001 (Australia); McClure-Griffiths, N. M. [CSIRO Astronomy and Space Science, ATNF, P.O. Box 76, Epping, NSW 1710 (Australia); Anderson, L. D. [Department of Physics, West Virginia University, Morgantown, WV 26506 (United States); Bania, T. M. [Institute for Astrophysical Research, Department of Astronomy, Boston University, 725 Commonwealth Avenue, Boston, MA 02215 (United States)

2013-09-10T23:59:59.000Z

231

Symmetrical and anti-symmetrical coherent perfect absorption for acoustic waves  

SciTech Connect (OSTI)

We investigate tunable acoustic absorption enabled by the coherent control of input waves. It relies on coherent perfect absorption originally proposed in optics. By designing appropriate acoustic metamaterial structures with resonating effective bulk modulus or density, we show that complete absorption of incident waves impinging on the metamaterial can be achieved for either symmetrical or anti-symmetrical inputs in the forward and backward directions. By adjusting the relative phase between the two incident beams, absorption can be tuned effectively from unity to zero, making coherent control useful in applications like acoustic modulators, noise controllers, transducers, and switches.

Wei, Pengjiang; Cronne, Charles; Tak Chu, Sai [Department of Physics and Materials Science, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Li, Jensen, E-mail: j.li@bham.ac.uk [School of Physics and Astronomy, University of Birmingham, Birmingham B15 2TT (United Kingdom)

2014-03-24T23:59:59.000Z

232

DNA Concentration By UV Spectrophotometry Measure Absorption  

E-Print Network [OSTI]

DNA Concentration By UV Spectrophotometry Measure Absorption: 1. Dilute DNA to 0.5 to 50 µg 2. Measure absorption at 260 nm (A260). Start by zeroing instrument with TE buffer or dH2O alone

Aris, John P.

233

Energy Saving with Absorption Refrigeration Technologies  

E-Print Network [OSTI]

Absorption refrigeration technology can be an economical and cost effective means of reducing energy cost and/or improving the efficiency and output of your process. We believe the potential benefits of absorption refrigeration technology have...

Davis, R. C.

1984-01-01T23:59:59.000Z

234

Absorption properties of identical atoms  

E-Print Network [OSTI]

Emission rates and other optical properties of multiparticle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas.

Pedro Sancho

2013-07-31T23:59:59.000Z

235

Photodetector with enhanced light absorption  

DOE Patents [OSTI]

A photodetector including a light transmissive electrically conducting layer having a textured surface with a semiconductor body thereon. This layer traps incident light thereby enhancing the absorption of light by the semiconductor body. A photodetector comprising a textured light transmissive electrically conducting layer of SnO.sub.2 and a body of hydrogenated amorphous silicon has a conversion efficiency about fifty percent greater than that of comparative cells. The invention also includes a method of fabricating the photodetector of the invention.

Kane, James (Lawrenceville, NJ)

1985-01-01T23:59:59.000Z

236

Inorganic composition of fine particles in mixed mineral dustpollution plumes observed from airborne measurements during ACE-Asia  

E-Print Network [OSTI]

of the atmosphere (2419, 2427); 0345 Atmospheric Composition and Structure: Pollution--urban and regional (0305Inorganic composition of fine particles in mixed mineral dust­pollution plumes observed from of Earth and Atmospheric Science, Georgia Institute of Technology, Atlanta, Georgia, USA G. R. Carmichael

Weber, Rodney

237

Opacity of iron, nickel, and copper plasmas in the x-ray wavelength range: Theoretical interpretation of 2p-3d absorption spectra  

SciTech Connect (OSTI)

This paper deals with theoretical studies on the 2p-3d absorption in iron, nickel, and copper plasmas related to LULI2000 (Laboratoire pour l'Utilisation des Lasers Intenses, 2000J facility) measurements in which target temperatures were of the order of 20 eV and plasma densities were in the range 0.004-0.01 g/cm{sup 3}. The radiatively heated targets were close to local thermodynamic equilibrium (LTE). The structure of 2p-3d transitions has been studied with the help of the statistical superconfiguration opacity code sco and with the fine-structure atomic physics codes hullac and fac. A new mixed version of the sco code allowing one to treat part of the configurations by detailed calculation based on the Cowan's code rcg has been also used in these comparisons. Special attention was paid to comparisons between theory and experiment concerning the term features which cannot be reproduced by sco. The differences in the spin-orbit splitting and the statistical (thermal) broadening of the 2p-3d transitions have been investigated as a function of the atomic number Z. It appears that at the conditions of the experiment the role of the term and configuration broadening was different in the three analyzed elements, this broadening being sensitive to the atomic number. Some effects of the temperature gradients and possible non-LTE effects have been studied with the help of the radiative-collisional code scric. The sensitivity of the 2p-3d structures with respect to temperature and density in medium-Z plasmas may be helpful for diagnostics of LTE plasmas especially in future experiments on the {Delta}n=0 absorption in medium-Z plasmas for astrophysical applications.

Blenski, T.; Loisel, G.; Poirier, M.; Thais, F.; Arnault, P.; Caillaud, T.; Fariaut, J.; Gilleron, F.; Pain, J.-C.; Porcherot, Q.; Reverdin, C.; Silvert, V.; Villette, B.; Bastiani-Ceccotti, S.; Turck-Chieze, S.; Foelsner, W.; Gaufridy de Dortan, F. de [CEA, IRAMIS, Service 'Photons, Atomes et Molecules', Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); CEA, DAM, DIF, F-91297 Arpajon (France); LULI, UMR No. 7605 CNRS - Ecole Polytechnique, F-91128 Palaiseau Cedex (France); CEA, IRFU, Service d'Astrophysique, Centre d'Etudes de Saclay, F-91191 Gif-sur-Yvette Cedex (France); Max-Planck-Institut fuer Quantenoptik, D-85748 Garching (Germany); Institute of Nuclear Fusion, Universidad Politecnica de Madrid, Spain and Laboratoire d'Optique Appliquee, ENSTA-Paritech-Polytechnique, Chemin de la Huniere, F-91671 Palaiseau (France)

2011-09-15T23:59:59.000Z

238

Polymer microcantilevers fabricated via multiphoton absorption polymerization  

E-Print Network [OSTI]

Polymer microcantilevers fabricated via multiphoton absorption polymerization Z. Bayindir, Y. Sun February 2005 We have used multiphoton absorption polymerization to fabricate a series of microscale.1063/1.1863414 Multiphoton absorption polymerization MAP 1­4 offers the unparalleled ability to create arbitrarily complex 3D

Teich, Malvin C.

239

ENCAPSULATION EFFECTS ON CARBONACEOUS AEROSOL LIGHT ABSORPTION  

E-Print Network [OSTI]

ENCAPSULATION EFFECTS ON CARBONACEOUS AEROSOL LIGHT ABSORPTION Arthur Sedlacek, Brookhaven National of aerosol absorption on direct radiative forcing is still an active area of research, in part, because. This poster presents data on black carbon (BC) light absorption measured by Photothermal Interferometry

240

ALGEBRAIC ASPECTS OF EMISSION TOMOGRAPHY WITH ABSORPTION  

E-Print Network [OSTI]

ALGEBRAIC ASPECTS OF EMISSION TOMOGRAPHY WITH ABSORPTION L. Hajdu and R. Tijdeman Abstract of emission tomography with absorption, con- sider a ray (such as light or X-ray) transmitting through #1; e #22;x ; where #22; #21; 0 denotes the absorption coe?cient of the material, and x is the length

Tijdeman, Robert

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Visual Absorption Capability1 Lee Anderson  

E-Print Network [OSTI]

Visual Absorption Capability1 Lee Anderson 2a/ Jerry Mosier 2b/ Geoffrey Chandler 2c/ 1/ Submitted, Lassen National Forest, Susanville, California. Abstract: Visual absorption capability (VAC) is a tool development which is in harmony with the visual resource vis- ual absorption capability (VAC) is a tool which

Standiford, Richard B.

242

Absorption Coefficients and Impedance Daniel A. Russell  

E-Print Network [OSTI]

1 Absorption Coefficients and Impedance Daniel A. Russell Science and Mathematics Department will measure the absorption coefficients and acoustic impedance of samples of acoustic absorbing materials material is responsible for almost 50% of sound absorption inside an automobile). The reverberation time

Russell, Daniel A.

243

Discriminant Absorption Feature Learning for Material Classification  

E-Print Network [OSTI]

1 Discriminant Absorption Feature Learning for Material Classification Zhouyu Fu, Antonio Robles in spectral imaging by combining the use of invariant spectral absorption features and statistical machine learning techniques. Our method hinges in the relevance of spectral absorption features for material

Robles-Kelly, Antonio

244

Enhanced Absorption Induced by a Metallic Nanoshell  

E-Print Network [OSTI]

Enhanced Absorption Induced by a Metallic Nanoshell Roi Baer* Department of Physical Chemistry ABSTRACT Nanoshells have been previously shown to have tunable absorption frequencies that are dependent on the ratio of their inner and outer radii. Inspired by this, we ask: can a nanoshell increase the absorption

Baer, Roi

245

LIMITING ABSORPTION PRINCIPLE FOR SINGULARLY PERTURBED OPERATORS  

E-Print Network [OSTI]

LIMITING ABSORPTION PRINCIPLE FOR SINGULARLY PERTURBED OPERATORS WALTER RENGER Abstract. Given an operator H 1 for which a limiting absorption principle holds, we study operators H 2 which are produced that (except for possibly a discrete set of eigenvalues) a limiting absorption principle holds for H 2 . We

246

Original article Improvement of zinc intestinal absorption  

E-Print Network [OSTI]

Original article Improvement of zinc intestinal absorption and reduction of zinc/iron interaction of caseins, improves its absorption and could prevent inhibition by other nutrients such as iron (Fe). The absorption of Zn (100 Ilmol/L) bound to the 1-25 CN ((3-CN(1-25)) of (3-casein, or as ZnS04 was studied using

Boyer, Edmond

247

Absorption cross section in Lifshitz black hole  

E-Print Network [OSTI]

We derive the absorption cross section of a minimally coupled scalar in the Lifshitz black hole obtained from the new massive gravity. The absorption cross section reduces to the horizon area in the low energy and massless limit of s-wave mode propagation, indicating that the Lifshitz black hole also satisfies the universality of low energy absorption cross section for black holes.

Taeyoon Moon; Yun Soo Myung

2012-10-05T23:59:59.000Z

248

Salicylate Toxicity from Ingestion and Continued Dermal Absorption  

E-Print Network [OSTI]

of salicylate dermal absorption and toxicity. REFERENCESand Continued Dermal Absorption Rachel L. Chin, MD*, Kent R.bases in the percutaneous absorption of salicylates II. J

Chin, Rachel L; Olson, Kent R; Dempsey, Delia

2007-01-01T23:59:59.000Z

249

SENSITIVE OPTOACOUSTIC DETECTION OF CARBON MONOXIDE BY RESONANCE ABSORPTION  

E-Print Network [OSTI]

Monoxide by Resonance Absorption Robert Gerlach and Nabil M.MONOXIDE BY RESONANCE ABSORPTION Robert Gerlach and Nabil M.the context of atmospheric absorption. The carbon monoxide

Gerlach, R.

2011-01-01T23:59:59.000Z

250

Absorption of Foliar-Applied Nitrogen by Cotton  

E-Print Network [OSTI]

wax, and nitrogen-15 absorption. Crop Science 37:807-811.water- deficit stress, and the absorption of foliar-appliedgrowth favorable for N absorption and translocation. Four

Oosterhuis, Derrick M

2009-01-01T23:59:59.000Z

251

Energy absorption behaviors of nanoporous materials functionalized (NMF) liquids  

E-Print Network [OSTI]

of a nanoporous energy absorption system by using chemicalSurani, and Y. Qiao, "Energy absorption of nanoporous silicaSAN DIEGO Energy Absorption Behaviors of Nanoporous

Kim, Tae Wan

2011-01-01T23:59:59.000Z

252

High Energy Astrophysics: Emission and Absorption 1/114 Emission and Absorption  

E-Print Network [OSTI]

High Energy Astrophysics: Emission and Absorption 1/114 Emission and Absorption 1 Motivation and the jet. #12;High Energy Astrophysics: Emission and Absorption 2/114 HST optical image of 3C273 Note: Emission and Absorption 3/114 Set of 3 images of the jet of 3C273. Left: HST Middle: Chandra X-ray Right

Bicknell, Geoff

253

X-ray Absorption Spectroscopy Identifies Calcium-Uranyl-Carbonate Complexes at Environmental Concentrations  

SciTech Connect (OSTI)

Current research on bioremediation of uranium-contaminated groundwater focuses on supplying indigenous metal-reducing bacteria with the appropriate metabolic requirements to induce microbiological reduction of soluble uranium(VI) to poorly soluble uranium(IV). Recent studies of uranium(VI) bioreduction in the presence of environmentally relevant levels of calcium revealed limited and slowed uranium(VI) reduction and the formation of a Ca-UO2-CO3 complex. However, the stoichiometry of the complex is poorly defined and may be complicated by the presence of a Na-UO2-CO3 complex. Such a complex might exist even at high calcium concentrations, as some UO2-CO3 complexes will still be present. The number of calcium and/or sodium atoms coordinated to a uranyl carbonate complex will determine the net charge of the complex. Such a change in aqueous speciation of uranium(VI) in calcareous groundwater may affect the fate and transport properties of uranium. In this paper, we present the results from X-ray absorption fine structure (XAFS) measurements of a series of solutions containing 50 lM uranium(VI) and 30 mM sodium bicarbonate, with various calcium concentrations of 0-5 mM. Use of the data series reduces the uncertainty in the number of calcium atoms bound to the UO2-CO3 complex to approximately 0.6 and enables spectroscopic identification of the Na-UO2-CO3 complex. At nearly neutral pH values, the numbers of sodium and calcium atoms bound to the uranyl triscarbonate species are found to depend on the calcium concentration, as predicted by speciation calculations.

Kelly, Shelly D [Argonne National Laboratory (ANL); Kemner, Kenneth M [Argonne National Laboratory (ANL); Brooks, Scott C [ORNL

2007-01-01T23:59:59.000Z

254

A Finely-Predicted Higgs Boson Mass from A Finely-Tuned Weak Scale  

E-Print Network [OSTI]

If supersymmetry is broken directly to the Standard Model at energies not very far from the unified scale, the Higgs boson mass lies in the range 128-141 GeV. The end points of this range are tightly determined. Theories with the Higgs boson dominantly in a single supermultiplet predict a mass at the upper edge, (141 \\pm 2) GeV, with the uncertainty dominated by the experimental errors on the top quark mass and the QCD coupling. This edge prediction is remarkably insensitive to the supersymmetry breaking scale and to supersymmetric threshold corrections so that, in a wide class of theories, the theoretical uncertainties are at the level of \\pm 0.4 GeV. A reduction in the uncertainties from the top quark mass and QCD coupling to the level of \\pm 0.3 GeV may be possible at future colliders, increasing the accuracy of the confrontation with theory from 1.4% to 0.4%. Verification of this prediction would provide strong evidence for supersymmetry, broken at a very high scale of ~ 10^{14 \\pm 2} GeV, and also for a Higgs boson that is elementary up to this high scale, implying fine-tuning of the Higgs mass parameter by ~ 20-28 orders of magnitude. Currently, the only known explanation for such fine-tuning is the multiverse.

Lawrence J. Hall; Yasunori Nomura

2009-10-19T23:59:59.000Z

255

Calcium silicate insulation structure  

DOE Patents [OSTI]

An insulative structure including a powder-filled evacuated casing utilizes a quantity of finely divided synthetic calcium silicate having a relatively high surface area. The resultant structure-provides superior thermal insulating characteristics over a broad temperature range and is particularly well-suited as a panel for a refrigerator or freezer or the insulative barrier for a cooler or a insulated bottle.

Kollie, Thomas G. (Oak Ridge, TN); Lauf, Robert J. (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

256

THE SOCIAL UNDERPINNINGS OF ABSORPTIVE CAPACITY: EXTERNAL KNOWLEDGE, SOCIAL NETWORKS, AND INDIVIDUAL  

E-Print Network [OSTI]

-FOUNDATIONS OF ABSORPTIVE CAPACITY 3.1 The Social Structure of Innovation 3.2 External knowledge 3.2.1 Scientific vs. Industrial External Knowledge 3.3 Internal Social Structure 3.3.1 Is brokerage always good for innovation? 3.4 A new framework for social structure and innovativeness 3.5 Local vs. Global Informational Advantages

Sadeh, Norman M.

257

Advanced regenerative absorption refrigeration cycles  

DOE Patents [OSTI]

Multi-effect regenerative absorption cycles which provide a high coefficient of performance (COP) at relatively high input temperatures. An absorber-coupled double-effect regenerative cycle (ADR cycle) (10) is provided having a single-effect absorption cycle (SEA cycle) (11) as a topping subcycle and a single-effect regenerative absorption cycle (1R cycle) (12) as a bottoming subcycle. The SEA cycle (11) includes a boiler (13), a condenser (21), an expansion device (28), an evaporator (31), and an absorber (40), all operatively connected together. The 1R cycle (12) includes a multistage boiler (48), a multi-stage resorber (51), a multisection regenerator (49) and also uses the condenser (21), expansion device (28) and evaporator (31) of the SEA topping subcycle (11), all operatively connected together. External heat is applied to the SEA boiler (13) for operation up to about 500 degrees F., with most of the high pressure vapor going to the condenser (21) and evaporator (31) being generated by the regenerator (49). The substantially adiabatic and isothermal functioning of the SER subcycle (12) provides a high COP. For higher input temperatures of up to 700 degrees F., another SEA cycle (111) is used as a topping subcycle, with the absorber (140) of the topping subcycle being heat coupled to the boiler (13) of an ADR cycle (10). The 1R cycle (12) itself is an improvement in that all resorber stages (50b-f) have a portion of their output pumped to boiling conduits (71a-f) through the regenerator (49), which conduits are connected to and at the same pressure as the highest pressure stage (48a) of the 1R multistage boiler (48).

Dao, Kim (14 Nace Ave., Piedmont, CA 94611)

1990-01-01T23:59:59.000Z

258

Electronic structure of nitinol surfaces oxidized by low-energy ion bombardment  

SciTech Connect (OSTI)

We have studied the electronic structure of nitinol exposed to low-energy oxygen-ion bombardment, using x-ray photoemission spectroscopy (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy. XPS spectra reveal a gradual transformation of nitinol surfaces into TiO{sub 2} with increased dose of implanted oxygen. No oxidation of Ni atoms has been detected. NEXAFS spectra around O K-edge and Ti L{sub 2,3}-edge, reflecting the element-specific partial density of empty electronic states, exhibit features, which can be attributed to the creation of molecular orbitals, crystal field splitting, and the absence of long-range order, characteristic of the amorphous TiO{sub 2}. Based on these results, we discuss the oxidation kinetics of nitinol under low-energy oxygen-ion bombardment.

Petravic, M., E-mail: mpetravic@phy.uniri.hr; Varasanec, M.; Peter, R.; Kavre, I. [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Metikos-Hukovic, M. [Department of Electrochemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, 10000 Zagreb (Croatia); Yang, Y.-W. [National Synchrotron Radiation Research Center, Hsinchu 30077, Taiwan (China)

2014-06-28T23:59:59.000Z

259

Microsoft Word - Finely_NorthValley_CX.docx  

Broader source: Energy.gov (indexed) [DOE]

Manager - KEWM-4 Proposed Action: Finely Creek and North Valley Creek property funding Fish and Wildlife Project No. and Contract No.: 2002-003-00, BPA-58888 Categorical Exclusion...

260

AQUEOUS BIPHASE EXTRACTION FOR PROCESSING OF FINE COAL  

SciTech Connect (OSTI)

The objective of this research project is to develop an aqueous biphase extraction process for the treatment of fine coals. Aqueous biphase extraction is an advanced separation technology that relies on the ability of an aqueous system consisting of a water-soluble polymer and another component, e.g., another polymer, an inorganic salt, or a nonionic surfactant, to separate into two immiscible aqueous phases. The principle behind the partition of solid particles in aqueous biphase systems is the physicochemical interaction between the solid surface and the surrounding liquid solution. In order to remove sulfur and mineral matter from fine coal with aqueous biphasic extraction, it is necessary to know the partitioning behavior of coal, as well as the inorganic mineral components. Therefore, in this research emphasis was placed on the partitioning behavior of fine coal particles as well as model fine inorganic particles in aqueous biphase systems.

K. Osseo-Asare; X. Zeng

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Modified approaches for high pressure filtration of fine clean coal  

SciTech Connect (OSTI)

Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

1995-12-31T23:59:59.000Z

262

Deadlock-free fine-grained thread migration  

E-Print Network [OSTI]

Several recent studies have proposed fine-grained, hardware-level thread migration in multicores as a solution to power, reliability, and memory coherence problems. The need for fast thread migration has been well documented, ...

Cho, Myong Hyon

263

MICROSTRUCTURE AND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE PRECIPITATES  

E-Print Network [OSTI]

and Properties of Dual-Phase Steels, R. A. Kot and J. W.of Niobium Microalloyed Dual- Phase Steel, MetallurgicalAND PROPERTIES OF DUAL PHASE STEELS CONTAINING FINE

Gau, J.S.

2014-01-01T23:59:59.000Z

264

Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments  

DOE Patents [OSTI]

The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculants and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude. 8 figs.

Kansa, E.J.; Wijesinghe, A.M.; Viani, B.E.

1997-01-14T23:59:59.000Z

265

Nontoxic chemical process for in situ permeability enhancement and accelerated decontamination of fine-grain subsurface sediments  

DOE Patents [OSTI]

The remediation of heterogeneous subsurfaces is extremely time consuming and expensive with current and developing technologies. Although such technologies can adequately remove contaminants in the high hydraulic conductivity, coarse-grained sediments, they cannot access the contaminated low hydraulic conductivity fine-grained sediments. The slow bleed of contaminants from the fine-grained sediments is the primary reason why subsurface remediation is so time-consuming and expensive. This invention addresses the problem of remediating contaminated fine-grained sediments. It is intended that, in the future, a heterogeneous site be treated by a hybrid process that first remediates the high hydraulic conductivity, coarse-grained sediments, to be followed by the process, described in this invention, to treat the contaminated low hydraulic conductivity fine-grained sediments. The invention uses cationic flocculents and organic solvents to collapse the swelling negative double layer surrounding water saturated clay particles, causing a flocculated, cracked clay structure. The modification of the clay fabric in fine-grained sediments dramatically increases the hydraulic conductivity of previously very tight clays many orders of magnitude.

Kansa, Edward J. (Livermore, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1997-01-01T23:59:59.000Z

266

DEVELOPMENT OF SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS  

E-Print Network [OSTI]

DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS K. Dao, M.ABSORPTION AIR CONDITIONERS AND HEAT PUMPS* K. DAO, M.

Dao, K.

2013-01-01T23:59:59.000Z

267

Enhanced p-Mode Absorption seen near the Sunspot Umbral-Penumbral Boundary  

E-Print Network [OSTI]

We investigate p-mode absorption in a sunspot using SOHO/MDI high-resolution Doppler images. The Doppler power computed from a three and a half hour data set is used for studying the absorption in a sunspot. The result shows an enhancement in absorption near the umbral-penumbral boundary of the sunspot. We attempt to relate the observed absorption with the magnetic field structure of the sunspot. The transverse component of the potential field is computed using the observed SOHO/MDI line-of-sight magnetograms. A comparison of the power map and the computed potential field shows enhanced absorption near the umbral-penumbral boundary where the computed transverse field strength is higher.

Shibu K. Mathew

2008-06-17T23:59:59.000Z

268

HI emission and absorption in nearby, gas-rich galaxies  

E-Print Network [OSTI]

We present the results of a targeted search for intervening HI absorption in six nearby, gas-rich galaxies using the Australia Telescope Compact Array (ATCA). The sightlines searched have impact parameters of 10-20 kpc. By targeting nearby galaxies we are also able to map their HI emission, allowing us to directly relate the absorption-line detection rate to the extended HI distribution. The continuum sightlines intersect the HI disk in four of the six galaxies, but no intervening absorption was detected. Of these four galaxies, we find that three of the non-detections are the result of the background source being too faint. In the fourth case we find that the ratio of the spin temperature to the covering factor ($T_{\\mathrm{S}}/f$) must be much higher than expected ($\\gtrsim$5700 K) in order to explain the non-detection. We discuss how the structure of the background continuum sources may have affected the detection rate of HI absorption in our sample, and the possible implications for future surveys. Future...

Reeves, S N; Allison, J R; Koribalski, B S; Curran, S J; Pracy, M B

2015-01-01T23:59:59.000Z

269

Olefin recovery via chemical absorption  

SciTech Connect (OSTI)

The recovery of fight olefins in petrochemical plants has generally been accomplished through cryogenic distillation, a process which is very capital and energy intensive. In an effort to simplify the recovery process and reduce its cost, BP Chemicals has developed a chemical absorption technology based on an aqueous silver nitrate solution. Stone & Webster is now marketing, licensing, and engineering the technology. The process is commercially ready for recovering olefins from olefin derivative plant vent gases, such as vents from polyethylene, polypropylene, ethylene oxide, and synthetic ethanol units. The process can also be used to debottleneck C{sub 2} or C{sub 3} splinters, or to improve olefin product purity. This paper presents the olefin recovery imp technology, discusses its applications, and presents economics for the recovery of ethylene and propylene.

Barchas, R. [Stone & Webster Engineering Corporation, Houston, TX (United States)

1998-06-01T23:59:59.000Z

270

Direct and quantitative absorptive spectroscopy of nanowires  

E-Print Network [OSTI]

Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

Tong, Jonathan Kien-Kwok

2012-01-01T23:59:59.000Z

271

Combining Feedback Absorption Spectroscopy, Amplified Resonance...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling Cummins...

272

Advanced Low Temperature Absorption Chiller Module Integrated...  

Broader source: Energy.gov (indexed) [DOE]

Advanced Low Temperature Absorption Chiller Module Integrated with a CHP System at a Distributed Data Center - Presentation by Exergy Partners Corp., June 2011 Advanced Low...

273

Pseudopotential calculations and photothermal lensing measurements of two-photon absorption in solids  

SciTech Connect (OSTI)

We have studied two-photon absorption in solids theoretically and experimentally. We have shown that it is possible to use accurate band structure techniques to compute two-photon absorption spectra within 15% of measured values in a wide band-gap material, ZnS. The empirical pseudopotential technique that we used is significantly more accurate than previous models of two-photon absorption in zinc blende materials, including present tunneling theories (which are essentially parabolic-band results in disguise) and the nonparabolic-band formalism of Pidgeon et al. and Weiler. The agreement between our predictions and previous measurements allowed us to use ZnS as a reference material in order to validate a technique for measuring two-photon absorption that was previously untried in solids, pulsed dual-beam thermal lensing. With the validated technique, we examined nonlinear absorption in one other crystal (rutile) and in several glasses, including silicates, borosilicates, and one phosphate glass. Initially, we believed that the absorption edges of all the materials were comparable; however, subsequent evidence suggested that the effective band-gap energies of the glasses were above the energy of two photons in our measurement. Therefore, we attribute the nonlinear absorption that we observed in glasses to impurities or defects. The measured nonlinear absorption coefficients were of the order of a few cm/TW in the glasses and of the order of 10 cm/GW in the crystals, four orders of magnitude higher than in glasses. 292 refs.

White, W.T. III

1985-11-04T23:59:59.000Z

274

Effect of morphology and solvent on two-photon absorption of nano zinc oxide  

SciTech Connect (OSTI)

Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

2013-05-15T23:59:59.000Z

275

Fine particulate chemical composition and light extinction at Meadview, AZ  

SciTech Connect (OSTI)

The concentration of fine particulate nitrate, sulfate, and carbonaceous material was measured for 12-hr daynight samples using diffusion denuder samplers during the Project Measurement of Haze and Visibility Effects (MOHAVE) July to August 1992 Summer Intensive study at Meadview, AZ, just west of Grand Canyon National Park. Organic material was measured by several techniques. Only the diffusion denuder method measured the semivolatile organic material. Fine particulate sulfate and nitrate (using denuder technology) determined by various groups agreed. Based on the various collocated measurements obtained during the Project MOHAVE study, the precision of the major fine particulate species was {+-} 0.6 {mu}g/m{sup 3} organic material, {+-} 0.3 {mu}g/m{sup 3} ammonium sulfate, and {+-} 0.07 {mu}g/m{sup 3} ammonium nitrate. Fine particulate organic material was the principal particulate contributor to light extinction during the study period, with fine particulate sulfate as the second most important contributor. Particle light extinction was dominated by sulfate and organic material during periods of lowest light extinction. Combination of the extinction data and chemical mass balance analysis of sulfur oxides sources in the region indicate that the major anthropogenic contributors to light extinction were from the Los Angeles, CA, and Las Vegas, NV, urban areas. Mohave Power Project associated secondary sulfate was a negligible contributor to light extinction. 49 refs., 12 figs., 7 tabs.

Delbert J. Eatough; Wenxuan Cui; Jeffery Hull; Robert J. Farber [Brigham Young University, Provo, UT (United States). Department of Chemistry and Biochemistry

2006-12-15T23:59:59.000Z

276

Recycling of PET bottles as fine aggregate in concrete  

SciTech Connect (OSTI)

An attempt to substitute in concrete the 5% by weight of fine aggregate (natural sand) with an equal weight of PET aggregates manufactured from the waste un-washed PET bottles (WPET), is presented. The WPET particles possessed a granulometry similar to that of the substituted sand. Specimens with different cement content and water/cement ratio were manufactured. Rheological characterization on fresh concrete and mechanical tests at the ages of 28 and 365 days were performed on the WPET/concretes as well as on reference concretes containing only natural fine aggregate in order to investigate the influence of the substitution of WPET to the fine aggregate in concrete. It was found that the WPET concretes display similar workability characteristics, compressive strength and splitting tensile strength slightly lower that the reference concrete and a moderately higher ductility.

Frigione, Mariaenrica, E-mail: mariaenrica.frigione@unisalento.i [Department of Engineering for Innovation, University of Salento, Via per Monteroni, 73100 Lecce (Italy)

2010-06-15T23:59:59.000Z

277

Local structure underlying anomalous tetragonal distortions in BiFeO{sub 3}-PbTiO{sub 3} ferroelectrics  

SciTech Connect (OSTI)

The local structure of tetragonal BiFeO{sub 3}-PbTiO{sub 3} solid solutions featuring anomalous lattice distortions has been determined using simultaneous fitting of neutron total scattering and extended X-ray absorption fine structure data. On the local scale, the large tetragonal distortion, promoted by the displacements of the A-cations (Bi and Pb), is accommodated primarily by the [FeO{sub 6}] octahedra, even though both Fe and Ti acquire (5+1)-fold coordination. Bi cations exhibit considerably larger displacements than Pb. The combination of the A-cation displacements and the ability of M-cations to adopt 5-fold coordination is suggested as key for stabilizing the large tetragonality in BiMO{sub 3}-PbTiO{sub 3} systems.

Levin, I.; Krayzman, V.; Woicik, J. C. [Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Tucker, M. G. [ISIS Facility, Rutherford Appleton Laboratory, Didcot (United Kingdom)

2014-06-16T23:59:59.000Z

278

Broadband solar absorption enhancement via periodic  

E-Print Network [OSTI]

Province, 230009, P. R. China. Solution processed colloidal quantum dot (CQD) solar cells have greatBroadband solar absorption enhancement via periodic nanostructuring of electrodes Michael M. Adachi demonstrate a bottom- illuminated periodic nanostructured CQD solar cell that enhances broadband absorption

279

Lyman-alpha Absorption from Heliosheath Neutrals  

E-Print Network [OSTI]

We assess what information HST observations of stellar Ly-alpha lines can provide on the heliosheath, the region of the heliosphere between the termination shock and heliopause. To search for evidence of heliosheath absorption, we conduct a systematic inspection of stellar Ly-alpha lines reconstructed after correcting for ISM absorption (and heliospheric/astrospheric absorption, if present). Most of the stellar lines are well centered on the stellar radial velocity, as expected, but the three lines of sight with the most downwind orientations relative to the ISM flow (Chi1 Ori, HD 28205, and HD 28568) have significantly blueshifted Ly-alpha lines. Since it is in downwind directions where heliosheath absorption should be strongest, the blueshifts are almost certainly caused by previously undetected heliosheath absorption. We make an initial comparison between the heliosheath absorption and the predictions of a pair of heliospheric models. A model with a complex multi-component treatment of plasma within the heliosphere predicts less absorption than a model with a simple single-fluid treatment, which leads to better agreement with the data. Finally, we find that nonplanetary energetic neutral atom (ENA) fluxes measured by the ASPERA-3 instrument on board Mars Express, which have been interpreted as being from the heliosheath, are probably too high to be consistent with the relative lack of heliosheath absorption seen by HST. This would argue for a local interplanetary source for these ENAs instead of a heliosheath source.

Brian E. Wood; Vladislav V. Izmodenov; Jeffrey L. Linsky; Yury G. Malama

2006-11-30T23:59:59.000Z

280

Absorption spectrum of Ca atoms attached to $^4$He nanodroplets  

E-Print Network [OSTI]

Within density functional theory, we have obtained the structure of $^4$He droplets doped with neutral calcium atoms. These results have been used, in conjunction with newly determined {\\it ab-initio} $^1\\Sigma$ and $^1\\Pi$ Ca-He pair potentials, to address the $4s4p$ $^1$P$_1 \\leftarrow 4s^2$ $^1$S$_0$ transition of the attached Ca atom, finding a fairly good agreement with absorption experimental data. We have studied the drop structure as a function of the position of the Ca atom with respect of the center of mass of the helium moiety. The interplay between the density oscillations arising from the helium intrinsic structure and the density oscillations produced by the impurity in its neighborhood plays a role in the determination of the equilibrium state, and hence in the solvation properties of alkaline earth atoms. In a case of study, the thermal motion of the impurity within the drop surface region has been analyzed in a semi-quantitative way. We have found that, although the atomic shift shows a sizeable dependence on the impurity location, the thermal effect is statistically small, contributing by about a 10% to the line broadening. The structure of vortices attached to the calcium atom has been also addressed, and its effect on the calcium absorption spectrum discussed. At variance with previous theoretical predictions, we conclude that spectroscopic experiments on Ca atoms attached to $^4$He drops will be likely unable to detect the presence of quantized vortices in helium nanodrops.

Alberto Hernando; Manuel Barranco; Marek Kro?nicki; Ricardo Mayol; Mart Pi

2007-11-12T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Unraveling the Excess Air/Coal Fineness Enigma  

E-Print Network [OSTI]

In the use of powered coal as a boiler fuel, the factors involved in heat loss from unburnt carbon in the ash are but partially understood. More finely pulverized coal particles will result in lower carbon-in-ash losses. On the other hand, the finer...

Laspe, C. G.

1983-01-01T23:59:59.000Z

282

WASHLOAD AND FINE SEDIMENT LOAD By Hyoseop S. Woo,1  

E-Print Network [OSTI]

WASHLOAD AND FINE SEDIMENT LOAD By Hyoseop S. Woo,1 Pierre Y. Julien,2 M. ASCE, and Everett V describes it very distinctly. He stated that if the sediment is added to the upstream end of a concrete channel and the channel is swept clean, and the sediment has not left any trace in the channel, its rate

Julien, Pierre Y.

283

Fine-Grained Power Management Using Process-level Profiling  

E-Print Network [OSTI]

. To evaluate energy efficiency, the Green Grid group proposed the definition of power usage effectiveness (PUE between performance and energy consumption, fine-grained methods, such as process- level power management-aware decisions based on these information. In addition, we introduce a power-aware system module called Energy

Shi, Weisong

284

My Eyes Are Fine. Why Get an Exam?  

E-Print Network [OSTI]

; they might lead you to believe that all you need is new eyeglasses. You can protect your eyesight by having or ophthalmologist will ask about your current and past health, your family's medical history and if you're currentlyMy Eyes Are Fine. Why Get an Exam? By Jonna Jefferis If you're like many people, the idea

285

Fine tuning of graphene-metal adhesion by surface alloying  

E-Print Network [OSTI]

Fine tuning of graphene-metal adhesion by surface alloying D. Alfe`1,2 , M. Pozzo1 , E. Miniussi3 route for governing the interaction between graphene and metal through the selective choice characterization of the properties of graphene on a model PtRu surface alloy on Ru(0001), with a concentration

Alfè, Dario

286

Science fictions: Comment on Godfrey-Smith Arthur Fine  

E-Print Network [OSTI]

Science+Business Media B.V. 2008 Abstract This is a comment on Peter Godfrey-Smith's, ``ModelsScience fictions: Comment on Godfrey-Smith Arthur Fine Published online: 2 December 2008 ? Springer in a naturalized and deflationary framework. Keywords Hans Vaihinger Á Models Á Fictions Á Peter Godfrey-Smith Hans

Fine, Arthur

287

09-10 Catalog Date ________________________ FINE ARTS: STUDIO  

E-Print Network [OSTI]

include 12 hours of social sciences [at least 2 different areas; 6 hours above freshman level]) 3000 2650 2750 ("C" or better necessary to move to next level of studio work in a given area.) 9 Fine Arts Option (one area) __________ __________ __________ __________* *Senior project in area of concentration

Kulp, Mark

288

Fine and coarse components in surface sediments from Bikini Lagoon  

SciTech Connect (OSTI)

In 1979, 21 years after the moratorium on nuclear testing in the Marshall Islands, surface sediment samples (to depths of 2 and 4 cm) were collected from 87 locations in the lagoon of Bikini Atoll, one of the two sites in the Marshall Islands used by the United States to test nuclear devices from 1946 through 1958. The main purpose for the collections was to map the distribution of long-lived man-made radionuclides associated with the bottom material. In addition the samples were processed to estimate the fraction of fine and coarse components to show, by comparison, what modifications occurred in the composition since the sediments were first described in samples collected before testing in 1946. Nuclear testing produced more finely divided material that is now found in the surface sediment layer over large areas of the lagoon and especially in regions of the lagoon and reef adjacent to test sites. The 5 cratering events alone at Bikini Atoll redistributed sufficient material to account for the higher inventory of fine material found over the surface 4 cm of the sediment of the lagoon. Although the fraction of fine material in the bottom sediments was altered by the nuclear events, the combined processes of formation, transport and deposition were not sufficiently dynamic to greatly change the general geographical features of the major sedimentary components over most of the lagoon floor.

Noshkin, V. E., LLNL

1997-01-01T23:59:59.000Z

289

Absorption and Scattering When we have both variations in both absorption and scattering, the solution to the  

E-Print Network [OSTI]

Chapter 6 Absorption and Scattering When we have both variations in both absorption and scattering of absorption and scatttering. 6.1 Simulation Results For the following simulationsthe forward data were of the simulation. #12;Absorption and Scattering 107 We have reconstructed images of scattering and absorption

290

Total absorption by degenerate critical coupling  

SciTech Connect (OSTI)

We consider a mirror-symmetric resonator with two ports. We show that, when excited from a single port, complete absorption can be achieved through critical coupling to degenerate resonances with opposite symmetry. Moreover, any time two resonances with opposite symmetry are degenerate in frequency and absorption is always significantly enhanced. In contrast, when two resonances with the same symmetry are nearly degenerate, there is no absorption enhancement. We numerically demonstrate these effects using a graphene monolayer on top of a photonic crystal slab, illuminated from a single side in the near-infrared.

Piper, Jessica R., E-mail: jrylan@stanford.edu; Liu, Victor; Fan, Shanhui, E-mail: shanhui@stanford.edu [Ginzton Laboratory, Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States)

2014-06-23T23:59:59.000Z

291

Electronic Structure of CeFeAsO1-xFx (x=0, 0.11/x=0.12) compounds  

SciTech Connect (OSTI)

We report an extensive study on the intrinsic bulk electronic structure of the high-temperature superconductor CeFeAsO{sub 0.89}F{sub 0.11} and its parent compound CeFeAsO by soft and hard x-ray photoemission, x-ray absorption and soft-x-ray emission spectroscopies. The complementary surface/bulk probing depth, and the elemental and chemical sensitivity of these techniques allows resolving the intrinsic electronic structure of each element and correlating it with the local structure, which has been probed by extended-x-ray absorption fine structure spectroscopy. The measurements indicate a predominant 4f{sup 1} (i.e. Ce{sup 3+}) initial state configuration for Cerium and an effective valence-band-to-4f charge-transfer screening of the core hole. The spectra also reveal the presence of a small Ce f{sup 0} initial state configuration, which we assign to the occurrence of an intermediate valence state. The data reveal a reasonably good agreement with the partial density of states as obtained in standard density functional calculations over a large energy range. Implications for the electronic structure of these materials are discussed.

Bondino, F.; Magnano, E.; Booth, C. H.; Offi, F.; Panaccione, G.; Malvestuto, M.; Paolicelli, G.; Simonelli, L.; Parmigiani, F.; McGuire, M. A.; Sefat, A. S.; Sales, B. C.; Jin, R.; Vilmercati, P.; Mandrus, D.; Singh, D. J.; Mannella, N.

2011-01-25T23:59:59.000Z

292

Hyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

the frequency of a laser with respect to an atomic spectral feature.[20] As such, saturated absorptionHyperfine Studies of Lithium Vapor using Saturated Absorption Spectroscopy? . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14 3.3 Broadening Mechanisms . . . . . . . . . . . . . . . . . . . . . 15 3.4 Saturated Absorption

Cronin, Alex D.

293

X-ray Absorption Spectroscopy of Biologically Relevant Systems  

E-Print Network [OSTI]

308, Messer, B. M. X-ray Absorption Spectroscopy of AqueousSarcosine via X-ray Absorption Spectroscopy 5.1 Introductionwith Carboxylate by X-Ray Absorption Spectroscopy of Liquid

Uejio, Janel Sunayo

2010-01-01T23:59:59.000Z

294

THE RELATION OF BACKSCATTERING TO SELF-ABSORPTION  

E-Print Network [OSTI]

of backscattering upon salf-absorption correction data, somemg/cm I Figure 1. Self-absorption Correction Curves forof backsc3ttering upon self-absorption correction curves are

Yankwich, Peter E.

2010-01-01T23:59:59.000Z

295

Solar absorption by Mie resonances in cloud droplets  

E-Print Network [OSTI]

on the enhancement factor for absorption of light by carbonKlett JD. Black carbon and absorption of solar radiation bySize parameter; Particle absorption; Water clouds; Aerosols

Zender, Charles S; Talamantes, Jorge

2006-01-01T23:59:59.000Z

296

DEVELOPMENT OF SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS  

E-Print Network [OSTI]

SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS K.Driven Absorption Air-Conditioner", K. Dao, M. Simmons, R.SOLAR DRIVEN ABSORPTION AIR CONDITIONERS AND HEAT PUMPS* K.

Dao, K.

2013-01-01T23:59:59.000Z

297

DAFS study of site-specific local structure of Mn in manganese ferrite films.  

SciTech Connect (OSTI)

Manganese ferrite (MnFe{sub 2}O{sub 4}) is a well-known magnetic material widely used in electronics for many years. It is well established that its magnetic behavior is strongly influenced by local structural properties of Mn ions, which are distributed between crystallographically inequivalent tetrahedral and octahedral sites in the unit cell. In order to understand and be able to tune properties of these structures, it is necessary to have detailed site-specific structural information on the system. Here we report on the application of diffraction-anomalous fine structure (DAFS) spectroscopy to resolve site-specific Mn local structures in manganese ferrite films. The DAFS measurements were done at undulator beamline 4-ID-D of the Advanced Photon Source at Argonne National Laboratory. The DAFS spectra (Fig. 1) were measured at several Bragg reflections in the vicinity of the Mn absorption K-edge, having probed separately contributions from tetrahedrally and octahedrally coordinated Mn sites. The DAFS data analysis done with an iterative Kramers-Kroenig algorithm made it possible to solve separately the local structure around different inequivalent Mn sites in the unit cell. The reliability of the data treatment was checked carefully, and it was showed that the site-specific structural parameters obtained with DAFS allow us to describe fluorescence EXAFS spectrum measured independently. Fig. 2 shows individual site contributions to the imaginary part of the resonant scattering amplitude obtained from the treatment of the data of Fig. 1. The analysis of the refined site-specific absorption spectra was done using EXAFS methods based on theoretical standards. We provided direct evidence for the tetrahedral Mn-O bond distance being increased relative to the corresponding Fe-O distance in bulk manganese ferrites. The first coordination shell number was found to be reduced significantly for Mn atoms at these sites. This finding is consistent with the well-known tendency of Mn to be tetrahedrally coordinated in these compounds.

Kravtsov, E.; Haskel, D.; Cady, A.; Yang, A.; Vittoria, C.; Zuo, X.; Harris, V. G.; X-Ray Science Division; Inst. of Metal Physics; Northeastern Univ.; Nankai Univ.

2006-01-01T23:59:59.000Z

298

Mechanical properties and energy absorption characteristics of a polyurethane foam  

SciTech Connect (OSTI)

Tension, compression and impact properties of a polyurethane encapsulant foam have been measured as a function of foam density. Significant differences in the behavior of the foam were observed depending on the mode of testing. Over the range of densities examined, both the modulus and the elastic collapse stress of the foam exhibited power-law dependencies with respect to density. The power-law relationship for the modulus was the same for both tension and compression testing and is explained in terms of the elastic compliance of the cellular structure of the foam using a simple geometric model. Euler buckling is used to rationalize the density dependence of the collapse stress. Neither tension nor compression testing yielded realistic measurements of energy absorption (toughness). In the former case, the energy absorption characteristics of the foam were severely limited due to the inherent lack of tensile ductility. In the latter case, the absence of a failure mechanism led to arbitrary measures of energy absorption that were not indicative of true material properties. Only impact testing revealed an intrinsic limitation in the toughness characteristics of the material with respect to foam density. The results suggest that dynamic testing should be used when assessing the shock mitigating qualities of a foam.

Goods, S.H.; Neuschwanger, C.L.; Henderson, C.; Skala, D.M.

1997-03-01T23:59:59.000Z

299

Stability of Bulk Metallic Glass Structure. Final Report  

SciTech Connect (OSTI)

The fundamental origins of the stability of the (Pd-Ni){sub 80}P{sub 20} bulk metallic glasses (BMGs), a prototype for a whole class of BMG formers, were explored. While much of the properties of their BMGs have been characterized, their glass-stability have not been explained in terms of the atomic and electronic structure. The local structure around all three constituent atoms was obtained, in a complementary way, using extended X-ray absorption fine structure (EXAFS), to probe the nearest neighbor environment of the metals, and extended energy loss fine structure (EXELFS), to investigate the environment around P. The occupied electronic structure was investigated using X-ray photoelectron spectroscopy (XPS). The (Pd-Ni){sub 80}P{sub 20} BMGs receive their stability from cumulative, and interrelated, effects of both atomic and electronic origin. The stability of the (Pd-Ni){sub 80}P{sub 20} BMGs can be explained in terms of the stability of Pd{sub 60}Ni{sub 20}P{sub 20} and Pd{sub 30}Ni{sub 50}P{sub 20}, glasses at the end of BMG formation. The atomic structure in these alloys is very similar to those of the binary phosphide crystals near x=0 and x=80, which are trigonal prisms of Pd or Ni atoms surrounding P atoms. Such structures are known to exist in dense, randomly-packed systems. The structure of the best glass former in this series, Pd{sub 40}Ni{sub 40}P{sub 20} is further described by a weighted average of those of Pd{sub 30}Ni{sub 50}P{sub 20} and Pd{sub 60}Ni{sub 20}P{sub 20}. Bonding states present only in the ternary alloys were found and point to a further stabilization of the system through a negative heat of mixing between Pd and Ni atoms. The Nagel and Tauc criterion, correlating a decrease in the density of states at the Fermi level with an increase in the glass stability, was consistent with greater stability of the Pd{sub x}Ni{sub 80-x}P{sub 20} glasses with respect to the binary alloys of P. A valence electron concentration of 1.8 e/a, which ensures the superpositioning of the first peak in the structure factor with twice the Fermi momentum, was used to calculate the interatomic potential of these alloys. The importance of Pd to the stability of the alloys is evidenced by the fact that replacing Ni and Pd places the nearest neighbor distances at more attractive positions in this potential.

Jain, H.; Williams, D. B.

2003-06-01T23:59:59.000Z

300

Absorption Heat Pumping- Have You Tried It?  

E-Print Network [OSTI]

The concept of a thermal powered absorption heat pump is not a new or revolutionary idea. It has been successfully demonstrated in the lab and prototypes have been installed in the field. Units have been successfully applied in a number...

Davis, R. C.

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Visible spectrometer utilizing organic thin film absorption  

E-Print Network [OSTI]

In this thesis, I modeled and developed a spectrometer for the visible wavelength spectrum, based on absorption characteristics of organic thin films. The device uses fundamental principles of linear algebra to reconstruct ...

Tiefenbruck, Laura C. (Laura Christine)

2004-01-01T23:59:59.000Z

302

Absorptive Recycle of Distillation Waste Heat  

E-Print Network [OSTI]

condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

Erickson, D. C.; Lutz, E. J., Jr.

1982-01-01T23:59:59.000Z

303

On the mechanism of electromagnetic microwave absorption in superfluid helium  

SciTech Connect (OSTI)

In experiments on electromagnetic (EM) wave absorption in the microwave range in superfluid (SF) helium [1-3], a narrow EM field absorption line with a width on the order of (20-200) kHz was observed against the background of a wide absorption band with a width of 30-40 GHz at frequencies f{sub 0} Almost-Equal-To 110-180 GHz corresponding to the roton gap energy {Delta}{sub r}(T) in the temperature range 1.4-2.2 K. Using the so-called flexoelectric mechanism of polarization of helium atoms ({sup 4}He) in the presence of density gradients in SF helium (HeII), we show that nonresonance microwave absorption in the frequency range 170-200 GHz can be due to the existence of time-varying local density gradients produced by roton excitations in the bulk HeII. The absorption bandwidth is determined by the roton-roton scattering time in an equilibrium Boltzmann gas of rotons, which is t{sub r-r} Almost-Equal-To 3.4 Multiplication-Sign 10{sup -11} s at T = 1.4 K and decreases upon heating. We propose that the anomalously narrow microwave resonance absorption line in HeII at the roton frequency f{sub 0}(T) = {Delta}r(T)/2{pi}h appears due to the following two factors: (i) the discrete structure of the spectrum of the surface EM resonator modes in the form of a periodic sequence of narrow peaks and (ii) the presence of a stationary dipole layer in HeII near the resonator surface, which forms due to polarization of {sup 4}He atoms under the action of the density gradient associated with the vanishing of the density of the SF component at the solid wall. For this reason, the relaxation of nonequilibrium rotons generated in such a surface dipole layer is strongly suppressed, and the shape and width of the microwave resonance absorption line are determined by the roton density of states, which has a sharp peak at the edge of the roton gap in the case of weak dissipation. The effective dipole moments of rotons in the dipole layer can be directed either along or across the normal to the resonator surface, which explains the experimentally observed symmetric doublet splitting of the resonance absorption line in an external dc electric field perpendicular to the resonator surface. We show that negative absorption (induced emission) of EM field quanta observed after triggering a Kapitza 'heat gun' occurs when the occupation numbers for roton states due to 'pumping' of rotons exceed the occupation numbers of EM field photons in the resonator.

Pashitskii, E. A., E-mail: pashitsk@iop.kiev.ua; Pentegov, V. I. [National Academy of Sciences of Ukraine, Institute of Physics (Ukraine)

2012-08-15T23:59:59.000Z

304

Absorption cross section of RN black hole  

E-Print Network [OSTI]

The behavior of a charged scalar field in the RN black hole space time is studied using WKB approximation. In the present work it is assumed that matter waves can get reflected from the event horizon. Using this effect, the Hawking temperature and the absorption cross section for RN black hole placed in a charged scalar field are calculated. The absorption cross section $\\sigma _{abs}$ is found to be inversely proportional to square of the Hawking temperature of the black hole.

Sini R.; V. C. Kuriakose

2007-08-23T23:59:59.000Z

305

IHT: Tools for Computing Insolation Absorption by Particle Laden Flows  

SciTech Connect (OSTI)

This report describes IHT, a toolkit for computing radiative heat exchange between particles. Well suited for insolation absorption computations, it is also has potential applications in combustion (sooting flames), biomass gasification processes and similar processes. The algorithm is based on the 'Photon Monte Carlo' approach and implemented in a library that can be interfaced with a variety of computational fluid dynamics codes to analyze radiative heat transfer in particle-laden flows. The emphasis in this report is on the data structures and organization of IHT for developers seeking to use the IHT toolkit to add Photon Monte Carlo capabilities to their own codes.

Grout, R. W.

2013-10-01T23:59:59.000Z

306

Reduction in biomass burning aerosol light absorption upon humidificat...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in biomass burning aerosol light absorption upon humidification: Roles of inorganically-induced hygroscopicity, Reduction in biomass burning aerosol light absorption upon...

307

acoustic power absorption: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The distribution of acoustic power over sunspots shows an enhanced absorption near the umbra--penumbra boundary. Earlier studies revealed that the region of enhanced absorption...

308

E-Print Network 3.0 - absorption spectrometry configurations...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

309

Self-corrected Sensors Based On Atomic Absorption Spectroscopy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy. Self-corrected Sensors Based On Atomic Absorption Spectroscopy For...

310

E-Print Network 3.0 - absorption spectrometry analyticalmethod...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Trace Elements in Biological Tissues by Summary: Block Digestion and Spike-Height Flame Atomic Absorption Spectrometry ,.. U. TINGGI AND W. MAHER School... absorption...

311

The Future of Absorption Technology in America: A Critical Look...  

Broader source: Energy.gov (indexed) [DOE]

The Future of Absorption Technology in America: A Critical Look at the Impact of Building, Cooling, Heating, and Power (BCHP) and Innovation, June 2000 The Future of Absorption...

312

Charge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers  

E-Print Network [OSTI]

to the formalism of Fano's treatment for atomic absorption line shapes associated with autoionization (Fano, UCharge Resonance Effects on Electronic Absorption Line Shapes: Application to the Heterodimer Absorption of Bacterial Photosynthetic Reaction Centers Huilin Zhou and Steven G. Boxer* Department

Boxer, Steven G.

313

Resonant absorption and not-so-resonant absorption in short, intense laser irradiated plasma  

SciTech Connect (OSTI)

An analytical model for laser-plasma interaction during the oblique incidence by an ultrashort ultraintense p-polarized laser on a solid-density plasma is proposed. Both the resonant absorption and not-so-resonant absorption are self-consistently included. Different from the previous theoretical works, the physics of resonant absorption is found to be valid in more general conditions as the steepening of the electron density profile is considered. Even for a relativistic intensity laser, resonant absorption can still exist under certain plasma scale length. For shorter plasma scale length or higher laser intensity, the not-so-resonant absorption tends to be dominant, since the electron density is steepened to a critical level by the ponderomotive force. The laser energy absorption rates for both mechanisms are discussed in detail, and the difference and transition between these two mechanisms are presented.

Ge, Z. Y.; Zhuo, H. B.; Ma, Y. Y.; Yang, X. H.; Yu, T. P.; Zou, D. B.; Yin, Y.; Shao, F. Q. [College of Science, National University of Defense Technology, Changsha 410073 (China)] [College of Science, National University of Defense Technology, Changsha 410073 (China); Yu, W.; Luan, S. X. [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China)] [Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); Zhou, C. T. [College of Science, National University of Defense Technology, Changsha 410073 (China) [College of Science, National University of Defense Technology, Changsha 410073 (China); Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China); Peng, X. J. [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)] [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)

2013-07-15T23:59:59.000Z

314

On the variations of optical property and electronic structure in heavily Al-doped ZnO films during double-step growth process  

SciTech Connect (OSTI)

We have investigated the variations of optical property and electronic structure in heavily Al-doped ZnO (AZO) films during the growth process, which were formed by first creating Zn vacancies in O{sub 2}-rich atmosphere and second filling the vacancies with Zn atoms in Zn-vapor atmosphere. After the first step, the high-resistance AZO films have the same optical bandgap with nominally undoped ZnO, indicating that negligible variations in the fundamental bandgap happened to the AZO films although Al atom was incorporated into the ZnO lattice. After the second step, once free electrons were brought into the lattice by Zn-filling, the optical transition energy blueshifts due to the band-filling effect. X-ray absorption fine structure measurements suggest that Zn-filling process decreased the unoccupied states of the conduction band, but not raised the conduction band minimum.

Hu, Q. C.; Ding, K., E-mail: kding@fjirsm.ac.cn; Zhang, J. Y.; Yan, F. P.; Pan, D. M.; Huang, F., E-mail: fhuang@fjirsm.ac.cn [Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Chiou, J. W., E-mail: jwchiou@nuk.edu.tw [Department of Applied Physics, National University of Kaohsiung, Kaohsiung 811, Taiwan (China)

2014-01-13T23:59:59.000Z

315

Quantifying the Magnitude of Anomalous Solar Absorption  

SciTech Connect (OSTI)

The data set from ARESE II, sponsored by the Atmospheric Radiation Measurement Program, provides a unique opportunity to understand solar absorption in the atmosphere because of the combination of three sets of broadband solar radiometers mounted on the Twin Otter aircraft and the ground based instruments at the ARM Southern Great Plains facility. In this study, we analyze the measurements taken on two clear sky days and three cloudy days and model the solar radiative transfer in each case with two different models. On the two clear days, the calculated and measured column absorptions agree to better than 10 Wm-2, which is about 10% of the total column absorption. Because both the model fluxes and the individual radiometer measurements are accurate to no better than 10 Wm-2, we conclude that the models and measurements are essentially in agreement. For the three cloudy days, the model calculations agree very well with each other and on two of the three days agree with the measurements to 20 Wm-2 or less out of a total column absorption of more than 200 Wm-2, which is again agreement at better than 10%. On the third day, the model and measurements agree to either 8% or 14% depending on which value of surface albedo is used. Differences exceeding 10% represent a significant absorption difference between model and observations. In addition to the uncertainty in absorption due to surface albedo, we show that including aerosol with an optical depth similar to that found on clear days can reduce the difference between model and measurement by 5% or more. Thus, we conclude that the ARESE II results are incompatible with previous studies reporting extreme anomalous absorption and can be modeled with our current understanding of radiative transfer.

Ackerman, Thomas P.; Flynn, Donna M.; Marchand, Roger T.

2003-05-16T23:59:59.000Z

316

Estimate of fine sediment deposit dynamics on a gravel bar using photography analysis  

E-Print Network [OSTI]

Estimate of fine sediment deposit dynamics on a gravel bar using photography analysis B. CAMENEN1 , M. JODEAU2 , and M. JABALLAH3 Abstract Three different methods to analyse fine sediment deposits the ground. These methods were used to estimate the surface of fine sediment deposits before and after

Paris-Sud XI, Université de

317

Simulating a 4-effect absorption chiller  

SciTech Connect (OSTI)

Absorption chillers are heat-operated refrigeration machines that operate on one of the earliest known principles of refrigeration. Current absorption chillers typically use either steam or a gas-fired burner as the energy source. All current gas-fired absorption cooling systems are based on the well known single-effect or double-effect cycles. To further improve utilization of the high temperature heat available from natural gas, a variety of triple-effect cycles have been proposed and are being developed that are capable of substantial performance improvement over equivalent double-effect cycles. This article describes a study that investigated the possibility of even further improving utilization of the high temperature heat available from natural gas combustion. During the study, performance simulation was conducted for a 4-effect lithium bromide/water cycle. From an environmental perspective, absorption chillers provide several benefits. They use absorption pairs (such as lithium bromide/water) as the working fluids, rather than chlorofluorocarbons or hydrochlorofluorocarbons, which contribute to ozone depletion and global warming.

Grossman, G. [Technion-Israel Inst. of Tech., Haifa (Israel). Dept. of Mechanical Engineering; Zaltash, A.; Adcock, P.W.; DeVault, R.C. [Oak Ridge National Lab., TN (United States). Energy Div.

1995-06-01T23:59:59.000Z

318

High redshift star-forming galaxies in absorption and emission  

E-Print Network [OSTI]

-forming galaxies in the redshift range 1 emission filling of absorption lines which has implications...

Quider, Anna Marie

2011-07-12T23:59:59.000Z

319

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite  

E-Print Network [OSTI]

Nitrogen Dioxide Absorption and Sulfite Oxidation in Aqueous Sulfite C H E N H . S H E N A N D G by absorption in sulfite solution in existing scrubbers for desulfurization. Rates of NO2 absorption and sulfite absorption initiates sulfite oxidation in the presence of oxygen, and this study quantified the effect

Rochelle, Gary T.

320

X-ray bandwidth: Determination by on-edge absorption and effect on various absorption experiments  

E-Print Network [OSTI]

X-ray bandwidth: Determination by on-edge absorption and effect on various absorption experiments of an x-ray source is increasingly important in fundamental experi- ments and critical applications. The bandwidth of an x-ray beam, selected from a synchrotron radiation spectrum for example, ultimately defines

Chantler, Christopher T.

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Crystal Structure and Characterization of Particulate Methane Monooxygenase from Methylocystis species Strain M  

SciTech Connect (OSTI)

Particulate methane monooxygenase (pMMO) is an integral membrane metalloenzyme that oxidizes methane to methanol in methanotrophic bacteria. Previous biochemical and structural studies of pMMO have focused on preparations from Methylococcus capsulatus (Bath) and Methylosinus trichosporium OB3b. A pMMO from a third organism, Methylocystis species strain M, has been isolated and characterized. Both membrane-bound and solubilized Methylocystis sp. strain M pMMO contain {approx}2 copper ions per 100 kDa protomer and exhibit copper-dependent propylene epoxidation activity. Spectroscopic data indicate that Methylocystis sp. strain M pMMO contains a mixture of Cu{sup I} and Cu{sup II}, of which the latter exhibits two distinct type 2 Cu{sup II} electron paramagnetic resonance (EPR) signals. Extended X-ray absorption fine structure (EXAFS) data are best fit with a mixture of Cu-O/N and Cu-Cu ligand environments with a Cu-Cu interaction at 2.52-2.64 {angstrom}. The crystal structure of Methylocystis sp. strain M pMMO was determined to 2.68 {angstrom} resolution and is the best quality pMMO structure obtained to date. It provides a revised model for the pmoA and pmoC subunits and has led to an improved model of M. capsulatus (Bath) pMMO. In these new structures, the intramembrane zinc/copper binding site has a different coordination environment from that in previous models.

Smith, Stephen M.; Rawat, Swati; Telser, Joshua; Hoffman, Brian M.; Stemmler, Timothy L.; Rosenzweig, Amy C. (WSU-MED); (NWU)

2012-02-08T23:59:59.000Z

322

Atomic and Molecular Absorption at High Redshift  

E-Print Network [OSTI]

Strong constraints on possible variations in fundamental constants can be derived from HI 21-cm and molecular rotational absorption lines observed towards quasars. With the aim of forming a statistical sample of constraints we have begun a program of systematic searches for such absorption systems. Here we describe molecular rotational searches in 25 damped Lyman-alpha systems where, in many cases, we set optical depth limits an order of magnitude better than that required to detect the 4 known redshifted millimeter-wave absorbers. We also discuss the contributory factors in the detectability of HI 21-cm absorption, focusing on possible biases (e.g.low covering factors) in the currently known sample of absorbers and non-detections.

S. J. Curran; J. K. Webb; M. T. Murphy; Y. M. Pihlstrm

2004-05-14T23:59:59.000Z

323

Absolute absorption spectroscopy based on molecule interferometry  

E-Print Network [OSTI]

We propose a new method to measure the absolute photon absorption cross section of neutral molecules in a molecular beam. It is independent of our knowledge of the particle beam density, nor does it rely on photo-induced fragmentation or ionization. The method is based on resolving the recoil resulting from photon absorption by means of near-field matter-wave interference, and it thus applies even to very dilute beams with low optical densities. Our discussion includes the possibility of internal state conversion as well as fluorescence. We assess the influence of various experimental uncertainties and show that the measurement of absolute absorption cross sections is conceivable with high precision and using existing technologies.

Stefan Nimmrichter; Klaus Hornberger; Hendrik Ulbricht; Markus Arndt

2008-11-07T23:59:59.000Z

324

General syllabus for doctoral (third cycle) education in the arts at the University of Gothenburg Fine Arts  

E-Print Network [OSTI]

and understanding For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine and skills For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine and approach For the degree of Licentiate of the Arts in Fine Arts and the degree of Doctor of the Arts in Fine

Johannesson, Henrik

325

Potassium emission absorption system. Topical report 12  

SciTech Connect (OSTI)

The Potassium Emission Absorption System is one of the advanced optical diagnostics developed at Mississippi State University to provide support for the demonstration of prototype-scale coal-fired combustion magnetohydrodynamic (MHD) electrical power generation. Intended for application in the upstream of an MHD flow, the system directly measures gas temperature and neutral potassium atom number density through spectroscopic emission absorption techniques. From these measurements the electron density can be inferred from a statistical equilibrium calculation and the electron conductivity in the MHD channel found by use of an electron mobility model. The instrument has been utilized for field test measurements on MHD facilities for almost a decade and has been proven to provide useful measurements as designed for MHD nozzle, channel, and diffuser test sections. The theory of the measurements, a system description, its capabilities, and field test measurement results are reported here. During the development and application of the instrument several technical issues arose which when addressed advanced the state of the art in emission absorption measurement. Studies of these issues are also reported here and include: two-wavelength measurements for particle-laden flows, potassium D-line far wing absorption coefficient, bias in emission absorption measurements arising from dirty windows and misalignments, non-coincident multiwavelength emission absorption sampling errors, and lineshape fitting for boundary layer flow profile information. Although developed for NLHD application, the instrument could be applied to any high temperature flow with a resonance line in the 300 to 800 nm range, for instance other types of flames, rocket plumes or low temperature plasmas.

Bauman, L.E.

1995-04-01T23:59:59.000Z

326

ON THE DIVERSITY AND COMPLEXITY OF ABSORPTION LINE PROFILES PRODUCED BY OUTFLOWS IN ACTIVE GALACTIC NUCLEI  

SciTech Connect (OSTI)

Understanding the origin of active galactic nucleus (AGN) absorption line profiles and their diversity could help to explain the physical structure of the accretion flow, and also to assess the impact of accretion on the evolution of the AGN host galaxies. Here, we present our first attempt to systematically address the issue of the origin of the complexities observed in absorption profiles. Using a simple method, we compute absorption line profiles against a continuum point source for several simulations of accretion disk winds. We investigate the geometrical, ionization, and dynamical effects on the absorption line shapes. We find that significant complexity and diversity of the absorption line profile shapes can be produced by the non-monotonic distribution of the wind velocity, density, and ionization state. Non-monotonic distributions of such quantities are present even in steady-state, smooth disk winds, and naturally lead to the formation of multiple and detached absorption troughs. These results demonstrate that the part of a wind where an absorption line is formed is not representative of the entire wind. Thus, the information contained in the absorption line is incomplete if not even insufficient to well estimate gross properties of the wind such as the total mass and energy fluxes. In addition, the highly dynamical nature of certain portions of disk winds can have important effects on the estimates of the wind properties. For example, the mass outflow rates can be off by up to two orders of magnitude with respect to estimates based on a spherically symmetric, homogeneous, constant velocity wind.

Giustini, Margherita [INAF-Istituto di Astrofisica Spaziale e Fisica cosmica di Bologna, via Gobetti 101, I-40129 Bologna (Italy); Proga, Daniel [Department of Physics and Astronomy, University of Nevada Las Vegas, 4505 Maryland Pkwy, Las Vegas, NV 891541-4002 (United States)

2012-10-10T23:59:59.000Z

327

KrF- and ArF-excimer-laser-induced absorption in silica glasses produced by melting synthetic silica powder  

SciTech Connect (OSTI)

KrF- and ArF-excimer-laser-induced absorption of silica glasses produced by electric melting and flame fusion of synthetic silica powder were investigated. The growth of KrF-laser-induced absorption was more gradual than that of ArF-laser-induced absorption. Induced absorption spectra exhibited a peak at about 5.8 eV, of which the position and width differed slightly among samples and laser species. Widths of ArF-laser-induced absorption spectra were wider than those of KrF-laser-induced spectra. KrF-laser-induced absorption is reproducible by two Gaussian absorption bands peaking at 5.80 eV with full width at half maximum (FWHM) of 0.62 eV and at 6.50 eV with FWHM of 0.74 eV. For reproduction of ArF-laser-induced absorption, Gaussian bands at 5.41 eV with FWHM of 0.62 eV was necessary in addition to components used for reproducing KrF-laser-induced absorption. Based on the discussion of the change of defect structures evaluated from change of absorption components, we proposed that the precursor of the 5.8-eV band ascribed to E Prime center ({identical_to}Si{center_dot}) is {identical_to}Si-H HO-Si{identical_to} structures formed by the reaction between strained Si-O-Si bonds and interstitial H{sub 2} molecules during the irradiation.

Kuzuu, Nobu; Sasaki, Toshiya; Kojima, Tatsuya [Department of Applied Physics, University of Fukui, 3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507 (Japan); Tanaka, Jun-ichiro; Nakamura, Takayuki; Horikoshi, Hideharu [Tosoh SGM Corp., 4555 Kaisei-cho, Shunan-shi, Yamaguchi 746-0006 (Japan)

2013-07-07T23:59:59.000Z

328

Laser isotope separation by multiple photon absorption  

DOE Patents [OSTI]

Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

1987-04-07T23:59:59.000Z

329

Laser isotope separation by multiple photon absorption  

DOE Patents [OSTI]

Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

1987-01-01T23:59:59.000Z

330

The 4000 A absorption system of formaldehyde  

E-Print Network [OSTI]

THE $000 A ABSORPTION SYSTEM OF FORMALDEHYDE JAMES RALPH HENDERSON A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May i 1957 Ma]or Subject: Physics THE 4000 A ABSORPTION SYSTEM OF FORMALDEHYDE A Thesis JAMES RALPH HENDERSON Approved as to style and content bye rlllan 0 OIllK e e ea o epar men May, l957 TABLE OF CONTENTS Page I. Introduction...

Henderson, James Ralph

1957-01-01T23:59:59.000Z

331

Multi-plasmon absorption in graphene  

E-Print Network [OSTI]

We show that graphene possesses a strong nonlinear optical response in the form of multi-plasmon absorption, with exciting implications in classical and quantum nonlinear optics. Specifically, we predict that graphene nano-ribbons can be used as saturable absorbers with low saturation intensity in the far-infrared and terahertz spectrum. Moreover, we predict that two-plasmon absorption and extreme localization of plasmon fields in graphene nano-disks can lead to a plasmon blockade effect, in which a single quantized plasmon strongly suppresses the possibility of exciting a second plasmon.

Marinko Jablan; Darrick E. Chang

2015-01-21T23:59:59.000Z

332

Modified discrete random walk with absorption  

E-Print Network [OSTI]

We obtain expected number of arrivals, probability of arrival, absorption probabilities and expected time before absorption for a modified discrete random walk on the (sub)set of integers. In a [pqrs] random walk the particle can move one step forward or backward, stay for a moment in the same state or it can be absorbed immediately in the current state. M[pqrs] is a modified version, where probabilities on both sides of a multiple function barrier M are of different [pqrs] type.

Theo van Uem

2009-03-02T23:59:59.000Z

333

Anomalous Light Absorption by Small Particles  

E-Print Network [OSTI]

A new type of resonant light absorption by a small particle (nanocluster) is reported. The problem cannot be described within the commonly used dipole scattering approximation and should be studied with methods based upon the exact Mie solution. It is shown that the absorption cross-section has giant maxima realized at small values of the imaginary part of the complex dielectric permittivity of the particle. The maxima are situated in the vicinity of the plasmon (polariton) resonances and correspond to the regions where the dissipative damping equals the radiative one. The case is similar to the recently introduced anomalous scattering [PRL vol. 97, 263902 (2006)] and exhibits similar peculiarities.

Michael I. Tribelsky

2009-12-18T23:59:59.000Z

334

Limit theorems and absorption problems for one-dimensional correlated random walks  

E-Print Network [OSTI]

There has recently been considerable interest in quantum walks in connection with quantum computing. The walk can be considered as a quantum version of the so-called correlated random walk. We clarify a strong structural similarity between both walks and study limit theorems and absorption problems for correlated random walks by our PQRS method, which was used in our analysis of quantum walks.

Norio Konno

2010-06-06T23:59:59.000Z

335

Ultra Large Castings for Lightweight Vehicle Structures ?AMD...  

Broader source: Energy.gov (indexed) [DOE]

for reduced investment cost in tooling and dies - Demonstrate improved energy absorption. USAMP AMD 406 Ultra Large Castings for Lightweight Vehicle Structures...

336

Fatigue and Creep-Fatigue Deformation of an Ultra-Fine Precipitate Strengthened Advanced Austenitic Alloy  

SciTech Connect (OSTI)

An advanced austenitic alloy, HT-UPS (high-temperature ultrafine-precipitation-strengthened), has been identified as an ideal candidate material for the structural components of fast reactors and energy-conversion systems. HT-UPS alloys demonstrate improved creep resistance relative to 316 stainless steel (SS) through additions of Ti and Nb, which precipitate to form a widespread dispersion of stable nanoscale metallic carbide (MC) particles in the austenitic matrix. The low-cycle fatigue and creep-fatigue behavior of an HT-UPS alloy have been investigated at 650 C and a 1.0% total strain, with an R-ratio of -1 and hold times at peak tensile strain as long as 150 min. The cyclic deformation response of HT-UPS is directly compared to that of standard 316 SS. The measured values for total cycles to failure are similar, despite differences in peak stress profiles and in qualitative observations of the deformed microstructures. Crack propagation is primarily transgranular in fatigue and creep-fatigue of both alloys at the investigated conditions. Internal grain boundary damage in the form of fine cracks resulting from the tensile hold is present for hold times of 60 min and longer, and substantially more internal cracks are quantifiable in 316 SS than in HT-UPS. The dislocation substructures observed in the deformed material differ significantly; an equiaxed cellular structure is observed in 316 SS, whereas in HT-UPS the microstructure takes the form of widespread and relatively homogenous tangles of dislocations pinned by the nanoscale MC precipitates. The significant effect of the fine distribution of precipitates on observed fatigue and creep-fatigue response is described in three distinct behavioral regions as it evolves with continued cycling.

M.C. Carroll; L.J. Carroll

2012-10-01T23:59:59.000Z

337

Harmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals  

E-Print Network [OSTI]

of the direct absorption characteristics of atomic or molecular absorption lines. This is accomplishedHarmonic wavelet analysis of modulated tunable diode laser absorption spectroscopy signals Hong analyses of tunable diode laser absorption spectroscopy signals were performed. The absorption spectroscopy

Cheng, Harry H.

338

Process for preparing fine grain titanium carbide powder  

DOE Patents [OSTI]

A method for preparing finely divided titanium carbide powder in which an organotitanate is reacted with a carbon precursor polymer to provide an admixture of the titanium and the polymer at a molecular-level due to a crosslinking reaction between the organotitanate and the polymer. The resulting gel is dried, pyrolyzed to drive off volatile components and provide carbon. The resulting solids are then heated at an elevated temperature to convert the titanium and carbon to high-purity titanium carbide powder in a submicron size range.

Janey, Mark A. (Concord, TN)

1986-01-01T23:59:59.000Z

339

Fine, New York: Energy Resources | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublicIDAPowerPlantSitingConstruction.pdfNotify98.pdf Jump to:Siting.pdf Jump to:NoticeFinanzas CarbonoFine, New

340

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents [OSTI]

A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

1998-09-22T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Corrosion inhibitor for aqueous ammonia absorption system  

DOE Patents [OSTI]

A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

Phillips, B.A.; Whitlow, E.P.

1998-09-22T23:59:59.000Z

342

SUPPLY-SIDE OPTIMIZATION : MAXIMIZING ABSORPTIVE RATES  

E-Print Network [OSTI]

and Piglet walked home thoughtfully together in the golden evening, and for a long time they were silent The World of Pooh INTRODUCTION The complexities of feeding behavior extend far beyond the simple priorities source of the material and energy for this escalation in heterotrophs with digestive tracts is absorption

Jumars, Pete

343

Direct fired absorption machine flue gas recuperator  

DOE Patents [OSTI]

A recuperator which recovers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine. The recuperator includes a housing with liquid flowing therethrough, the liquid being in direct contact with the combustion gas for increasing the effectiveness of the heat transfer between the gas and the liquid.

Reimann, Robert C. (Lafayette, NY); Root, Richard A. (Spokane, WA)

1985-01-01T23:59:59.000Z

344

Coupled dual loop absorption heat pump  

DOE Patents [OSTI]

A coupled dual loop absorption system which utilizes two separate complete loops. Each individual loop operates at three temperatures and two pressures. This low temperature loop absorber and condenser are thermally coupled to the high temperature loop evaporator, and the high temperature loop condenser and absorber are thermally coupled to the low temperature generator.

Sarkisian, Paul H. (Watertown, MA); Reimann, Robert C. (Lafayette, NY); Biermann, Wendell J. (Fayetteville, NY)

1985-01-01T23:59:59.000Z

345

Absorption on horizon-wrapped branes  

E-Print Network [OSTI]

We compute the absorption cross section of space-time scalars on a static D2 rane, in global coordinates, wrapped on the S^2 of an AdS_2 X S^2 X CY_3 geometry. We discuss its relevance for the construction of the dual quantum mechanics of Calabi-Yau black holes.

S. Ansari; G. Panotopoulos; I. Sachs

2009-01-09T23:59:59.000Z

346

Absorption of solar radiation by solar neutrinos  

E-Print Network [OSTI]

We calculate the absorption probability of photons radiated from the surface of the Sun by a left-handed neutrino with definite mass and a typical momentum for which we choose |p_1|=0.2 MeV, producing a heavier right-handed antineutrino. Considering two transitions the \

G. Duplancic; P. Minkowski; J. Trampetic

2004-03-22T23:59:59.000Z

347

Absorption features of high redshift galactic winds  

E-Print Network [OSTI]

The environment of high-redshift galaxies is characterized by both wind-driven outflowing gas and gravitationally infalling streams. To investigate such galaxy-IGM interplay we have generated synthetic optical absorption line spectra piercing the volume surrounding a starbursting analog of a Lyman Break Galaxy selected in a $z \\approx 3$ output from a SPH simulation, including a detailed treatment of mechanical feedback from winds. Distributions for several observable species (HI, CIII, CIV, SiII, SiIII, SiIV, OVI, OVII, and OVIII) have been derived by post-processing the simulation outputs. The hot wind material is characterized by the presence of high-ionization species such as OVI, OVII, and OVIII (the latter two observable only in X-ray bands); the colder ($Tgas clumps. However, both line profile and Pixel Optical Depth analysis of the synthetic spectra show that the intergalactic filament in which the wind-blowing galaxy is embedded produces absorption signatures that closely mimic those of the wind environment. We conclude that may be difficult to clearly identify wind-blowing galaxies and their complex gaseous environment at high redshift in optical QSO absorption-line spectra based solely on the observed ion absorption patterns.

A. P. M. Fangano; A. Ferrara; P. Richter

2007-06-11T23:59:59.000Z

348

High Shear Deformation to Produce High Strength and Energy Absorption in Mg Alloys  

SciTech Connect (OSTI)

Magnesium alloys have the potential to reduce the mass of transportation systems however to fully realize the benefits it must be usable in more applications including those that require higher strength and ductility. It has been known that fine grain size in Mg alloys leads to high strength and ductility. However, the challenge is how to achieve this optimal microstructure in a cost effective way. This work has shown that by using optimized high shear deformation and second phase particles of Mg2Si and MgxZnZry the energy absorption of the extrusions can exceed that of AA6061. The extrusion process under development described in this presentation appears to be scalable and cost effective. In addition to process development a novel modeling approach to understand the roles of strain and state-of-strain on particle fracture and grain size control has been developed

Joshi, Vineet V.; Jana, Saumyadeep; Li, Dongsheng; Garmestani, Hamid; Nyberg, Eric A.; Lavender, Curt A.

2014-02-01T23:59:59.000Z

349

Development of Updated ABsorption SIMulation Software (ABSIM)  

SciTech Connect (OSTI)

ABsorption SIMulation, ABSIM, was developed for the simulation of absorption systems by The Oak Ridge National Laboratory during 1980s and 1990s. ABSIM provides a platform for users to investigate various cycle configurations and working fluids, to calculate their operating parameters, to predict their performance, and to compare them with each other on a uniform basis. ABSIM is indeed a very useful and accurate tool for researchers to investigate various absorption systems. However, it has not been well maintained: it is incompatible with recent operating systems; the interface needs improved user-friendliness, and the system needs better parameter setting and debugging tools to help achieve convergence. Therefore, it is highly needed to update and improve ABSIM. The paper presents recent efforts to improve ABSIM s compatibility with current operating systems, user interface, and analysis capabilities. The paper details the features and functions of the newly updated ABSIM software. The new ABSIM still uses the previously validated calculation engine of the old ABSIM. The new graphic user interfaces (GUI) were developed in Qt, which is an open source license GUI software based on C++. XML was used as the database for data storage in the new ABSIM. The new ABSIM has been designed to be easily learned and used. It has enhanced editing and construction functions, plus enhanced analysis features including parametric tables, plotting, property plots, and master panels for debugging. A single effect water/LiBr absorption system is used as a case study in this paper to illustrate the features, capabilities, and functions of the new ABSIM. This case study was actually an example system available in the old ABSIM. The new version of ABSIM will be continuously developed to include additional subroutines for the components in liquid desiccant systems. The new ABSIM will be available to public for free. The ultimate goal of the new ABSIM is to allow it to become a simulation platform for both absorption heat pump and liquid desiccant systems.

Yang, Zhiyao [Purdue University, West Lafayette, IN; Tang, Xin [Purdue University, West Lafayette, IN; Qu, Ming [Purdue University, West Lafayette, IN; Abdelaziz, Omar [ORNL; Gluesenkamp, Kyle R [ORNL

2014-01-01T23:59:59.000Z

350

Approaching total absorption at near infrared in a large area monolayer graphene by critical coupling  

SciTech Connect (OSTI)

We demonstrate experimentally close to total absorption in monolayer graphene based on critical coupling with guided resonances in transfer printed photonic crystal Fano resonance filters at near infrared. Measured peak absorptions of 35% and 85% were obtained from cavity coupled monolayer graphene for the structures without and with back reflectors, respectively. These measured values agree very well with the theoretical values predicted with the coupled mode theory based critical coupling design. Such strong light-matter interactions can lead to extremely compact and high performance photonic devices based on large area monolayer graphene and other twodimensional materials.

Liu, Yonghao; Chadha, Arvinder; Zhao, Deyin; Shuai, Yichen; Menon, Laxmy; Yang, Hongjun; Zhou, Weidong, E-mail: wzhou@uta.edu [Nanophotonics Lab, Department of Electrical Engineering, University of Texas at Arlington, Arlington, Texas 76019 (United States); Piper, Jessica R.; Fan, Shanhui [Ginzton Laboratory, Department of Electrical Engineering, Stanford University, Stanford, California 94305 (United States); Jia, Yichen; Xia, Fengnian [Department of Electrical Engineering, Yale University, New Haven, Connecticut 06520 (United States); Ma, Zhenqiang [Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)

2014-11-03T23:59:59.000Z

351

Replication of Two-Photon-Polymerized Structures with Extremely High Aspect Ratios and Large Overhangs  

E-Print Network [OSTI]

Replication of Two-Photon-Polymerized Structures with Extremely High Aspect Ratios and Large created with an acrylic polymer using multiphoton absorption polymerization. Microtransfer molding be expected from the diffraction limit. Multiphoton absorption polymerization (MAP) with 800-nm light

Teich, Malvin C.

352

Effects of thermal motion on electromagnetically induced absorption  

E-Print Network [OSTI]

We describe the effect of thermal motion and buffer-gas collisions on a four-level closed N system interacting with strong pump(s) and a weak probe. This is the simplest system that experiences electromagnetically induced absorption (EIA) due to transfer of coherence via spontaneous emission from the excited to ground state. We investigate the influence of Doppler broadening, velocity-changing collisions (VCC), and phase-changing collisions (PCC) with a buffer gas on the EIA spectrum of optically active atoms. In addition to exact expressions, we present an approximate solution for the probe absorption spectrum, which provides physical insight into the behavior of the EIA peak due to VCC, PCC, and wave-vector difference between the pump and probe beams. VCC are shown to produce a wide pedestal at the base of the EIA peak, which is scarcely affected by the pump-probe angular deviation, whereas the sharp central EIA peak becomes weaker and broader due to the residual Doppler-Dicke effect. Using diffusion-like equations for the atomic coherences and populations, we construct a spatial-frequency filter for a spatially structured probe beam and show that Ramsey narrowing of the EIA peak is obtained for beams of finite width.

E. Tilchin; O. Firstenberg; A. D. Wilson-Gordon

2011-07-04T23:59:59.000Z

353

Effective Absorption Enhancement in Small Molecule Organic Solar Cells by Employing Trapezoid Gratings  

E-Print Network [OSTI]

We demonstrate the optical absorption has been enhanced in the small molecule organic solar cells by employing trapezoid grating structure. The enhanced absorption is mainly attributed to both waveguide modes and surface plasmon modes, which has been simulated by using finite-difference time-domain method. The simulated results show that the surface plasmon along the semitransparent metallic Ag anode is excited by introducing the periodical trapezoid gratings, which induce high intensity field increment in the donor layer. Meanwhile, the waveguide modes result a high intensity field in acceptor layer. The increment of field improves the absorption of organic solar cells, significantly, which has been demonstrated by simulating the electrical properties. The simulated results exhibiting 31 % increment of the short-circuit current has been achieved in the optimized device, which is supported by the experimental measurement. The power conversion efficiency of the grating sample obtained in experiment exhibits an...

Chun-Ping, Xiang; Yu, Jin; Bin-Zong, Xu; Wei-Min, Wang; Xin, Wei; Guo-Feng, Song; Yun, Xu

2013-01-01T23:59:59.000Z

354

Integrated vacuum absorption steam cycle gas separation  

DOE Patents [OSTI]

Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

2011-11-22T23:59:59.000Z

355

CO2 Capture by Absorption with Potassium Carbonate  

SciTech Connect (OSTI)

The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Modeling of stripper performance suggests that vacuum stripping may be an attractive configuration for all solvents. Flexipac 1Y structured packing performs in the absorber as expected. It provides twice as much mass transfer area as IMTP No.40 dumped packing. Independent measurements of CO{sub 2} solubility give a CO{sub 2} loading that is 20% lower than that Cullinane's values with 3.6 m PZ at 100-120 C. The effective mass transfer coefficient (K{sub G}) in the absorber with 5 m K/2.5 m PZ appears to be 0 to 30% greater than that of 30 wt% MEA.

Gary T. Rochelle; Marcus Hilliard; Eric Chen; Babatunde Oyenekan; Ross Dugas; John McLees; Andrew Sexton; Daniel Ellenberger

2005-10-26T23:59:59.000Z

356

Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry  

E-Print Network [OSTI]

Atomic Absorption Spectrometry · Perkin Elmer 500, Chemistry & Biochemistry · Perkin Elmer 560 AA-star stopped flow with absorption, fluorescence and circular dichroism detection · KinTek quench flow apparatus

Gruner, Daniel S.

357

Multiband Optical Absorption Controlled by Lattice Strain in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Multiband Optical Absorption Controlled by Lattice Strain in Thin-Film LaCrO3. Multiband Optical Absorption Controlled by Lattice Strain in Thin-Film LaCrO3. Abstract: Experimental...

358

Infrared absorption spectra, radiative efficiencies, and global warming potentials  

E-Print Network [OSTI]

Infrared absorption spectra, radiative efficiencies, and global warming potentials absorption spectra, radiative efficiencies, and global warming potentials of perfluorocarbons: Comparison. (1995) and combined with atmospheric lifetimes from the literature to determine global warming

Wirosoetisno, Djoko

359

The digestive adaptation of flying vertebrates: High intestinal paracellular absorption  

E-Print Network [OSTI]

The digestive adaptation of flying vertebrates: High intestinal paracellular absorption compensates analysis. Significantly greater amplification of digestive surface area by villi in small birds, also in actively flying vertebrates. digestion gut morphometrics nutrient absorption paracellular uptake Birds have

Mladenoff, David

360

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

Rochelle, Gary T.

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

Rochelle, Gary T.

362

Optical absorption at its onset in sputter deposited hafnia-titania nanolaminates  

SciTech Connect (OSTI)

The onset of the fundamental optical absorption edge in sputter deposited HfO{sub 2}-TiO{sub 2} nanolaminate films grown on unheated substrates was investigated. Three bilayer architectures were examined, representing overall film chemistry from 0.51 to 0.72 atom fraction Hf. The goal was to determine the absorption coefficient, {alpha}(E), versus incident photon energy, E, and to model this dependence in terms of the absorption behavior of specific functional units within the nanolaminate. Persistence and amalgamation models were applied, representing the extremes of segregated cation and mixed cation structures, respectively, and both were found to be unsatisfactory. Consideration of physiochemical data for the nanolaminates led to the development of a modified persistence model for absorption. {alpha}(E) was decomposed into contributions from (I) broad (9 nm-thick) interfacial regions that were chiefly o-HfTiO{sub 4}, and (II) regions remote from interfaces that contained material based on a highly defective m-HfO{sub 2} lattice. The absorption edge at its onset in all nanolaminates was determined by short-range atomic order characteristic of o-HfTiO{sub 4}. An indirect band gap of E{sub G}=3.25{+-}0.02 eV was determined for this compound.

Cisneros-Morales, Massiel Cristina; Aita, Carolyn Rubin [Department of Chemistry and Biochemistry, University of Wisconsin-Milwaukee, P.O. Box 413, Milwaukee, Wisconsin 53201 (United States)

2010-12-15T23:59:59.000Z

363

HI 21cm Absorption at $z \\sim 2.347$ towards PKS B0438-436  

E-Print Network [OSTI]

We report the detection of redshifted HI~21cm absorption in the $z \\sim 2.347$ damped Lyman-$\\alpha$ absorber (DLA) towards PKS B0438-436, with the Green Bank Telescope. This is the second-highest redshift at which 21cm absorption has been detected in a DLA. The absorption extends over $\\sim 60$ km/s and has two distinct components, at $z = 2.347477 (12)$ and $z = 2.347869 (20)$. A similar velocity structure is seen in optical metal lines, although the peak absorption here is offset by $\\sim 11$ km/s from the peak in the 21cm line. We obtain a high spin temperature $T_s \\sim (886 \\pm 248) \\times (f/0.58)$ K, using a covering factor estimated from 2.3 GHz VLBI data. However, the current data cannot rule out a low spin temperature. The non-detection of CO 3-2 absorption places the upper limit $N_{CO} < 3.8 \\times 10^{15} \\times (T_x/10)$ cm$^{-2}$ on the CO column density.

N. Kanekar; R. Subrahmanyan; S. L. Ellison; W. M. Lane; J. N. Chengalur

2006-05-14T23:59:59.000Z

364

On the nature of structural disorder in calcium silicate hydrates with a calcium/silicon ratio similar to tobermorite  

SciTech Connect (OSTI)

Four calcium silicate hydrates (C-S-H) with structural calcium/silicon (Ca/Si) ratios ranging from 0.82 0.02 to 0.87 0.02 were synthesized at room temperature, 50, 80, and 110 C. Their structure was elucidated by collating information from electron probe micro-analysis, transmission electron microscopy, extended X-ray absorption fine structure spectroscopy, and powder X-ray diffraction (XRD). A modeling approach specific to defective minerals was used because sample turbostratism prevented analysis using usual XRD refinement techniques (e.g. Rietveld analysis). It is shown that C-S-H with Ca/Si ratio of ? 0.8 are structurally similar to nano-crystalline turbostratic tobermorite, a naturally occurring mineral. Their structure thus consists of sheets of calcium atoms in 7-fold coordination, covered by ribbons of silicon tetrahedra with a dreierketten (wollastonite-like) organization. In these silicate ribbons, 0.42 Si per bridging tetrahedron are missing. Random stacking faults occur systematically between successive layers (turbostratic stacking). Layer-to-layer distance is equal to 11.34 . Crystallites have a mean size of 10 nm in the ab plane, and a mean number of 2.62.9 layers stacked coherently along the c* axis.

Grangeon, Sylvain, E-mail: S.Grangeon@brgm.fr [BRGM, 3, Avenue Claude Guillemin, 45060 Orlans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orlans Cedex 2 (France); Claret, Francis; Lerouge, Catherine [BRGM, 3, Avenue Claude Guillemin, 45060 Orlans Cedex 2 (France)] [BRGM, 3, Avenue Claude Guillemin, 45060 Orlans Cedex 2 (France); Warmont, Fabienne [CRMD, UMR 6619 CNRS, 1b rue de la frollerie, 45071 Orlans Cedex 2 (France)] [CRMD, UMR 6619 CNRS, 1b rue de la frollerie, 45071 Orlans Cedex 2 (France); Sato, Tsutomu; Anraku, Sohtaro [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan)] [Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste, Resources and Geoenvironmental/Engineering Graduate School of Engineering, Hokkaido University, Kita 13 Nishi 8, Sapporo 060-8628 (Japan); Numako, Chiya [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan)] [Faculty of Integrated Arts and Sciences, The University of Tokushima, 1-1, Minami-Josanjima, Tokushima, 770-8502 (Japan); Linard, Yannick [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France)] [ANDRA, Centre de Meuse/Haute Marne, 55290 Bure (France); Lanson, Bruno [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)] [ISTerre, Grenoble University, CNRS, F-38041 Grenoble (France)

2013-10-15T23:59:59.000Z

365

Radiation absorption properties of different plaster samples  

SciTech Connect (OSTI)

Although the plaster is one of the oldest known synthetic building materials, nowadays, it is used as interior coating of walls and ceilings of buildings. Thus measuring its radiation shielding properties is vital. For this purpose, radiation absorption properties of different plaster samples in this study. The measurements have been performed using gamma spectrometer system which connected to 3'' Multiplication-Sign 3''NaI (TI) detector.

Akkurt, Iskender; Guenoglu, Kadir; Mavi, Betuel; K Latin-Small-Letter-Dotless-I l Latin-Small-Letter-Dotless-I ncarslan, Semsettin; Seven, Aysun [Suleyman Demirel University, Faculty of Arts and Sciences, Department of Physics, Isparta (Turkey); Amasya University, Faculty of Arts and Sciences, Department of Physics, Amasya (Turkey); Suleyman Demirel University, Faculty of Technical Education, Department of Construction Education, Isparta (Turkey)

2012-09-06T23:59:59.000Z

366

The absorption of ultrasonic waves in liquids  

E-Print Network [OSTI]

Vee ~ ~ ~ ~ a ~ ~ ~ ~ ~ ~ a ~ e ~ ~ ~ ~ a ~ ~ ea ~ ~ ~ eee ~ ~ ~ ~ ~ ~ ea ~ ~ ~ ~ 2 ~ ?easursasnt of ths Prop-:. ties of:asss and Liquids by Ultrasonicseae ~ ~ ~ ~ ~ e ~ ~ ~ ~ ~ ~ ~ ~ e ~ ~ dies Borne erscsnt Theories ConcsrrrinS the Oisorsparrcy 3e tween... ~ ~ ~ ~ ~ ~ ~ o 3Q VI, Plot of' Los A /A vs~ Sound Path Length Ital ZthoI' 1Mox' Ppoalul'oe ~ ~ a ~ y ~ ~ s ~ ~ ~ ~ ~ ~ e ~ ~ ~ e s ~ ~ ~ ~ e ~ ~ a ~ ~ 3) xxeasuraaents oa the absorption of high frequency souad. waves ia liquids axe useful ia studying...

Hudson, Paul A

2012-06-07T23:59:59.000Z

367

Oral absorption of apramycin in newborn calves  

E-Print Network [OSTI]

as a model is the Journal of Veterinary Pharmacology and Therapeutics. animals in other species may also have a larger extent of absorption than older animals. Apramycin is an aminoglycoside antibiotic which is active against some gram... to healthy newborn (less than 24 hours old) veal calves than calves that are 3 weeks old. If the drug is absorbed, it indicates that neonatal calves have a greater capacity to absorb a poorly absorbed drug, thereby potentiating possible problems...

Buck, Joan Marjorie

2012-06-07T23:59:59.000Z

368

Programmable Differential Delay Circuit With Fine Delay Adjustment  

DOE Patents [OSTI]

Circuitry that provides additional delay to early arriving signals such that all data signals arrive at a receiving latch with same path delay. The delay of a forwarded clock reference is also controlled such that the capturing clock edge will be optimally positioned near quadrature (depending on latch setup/hold requirements). The circuitry continuously adapts to data and clock path delay changes and digital filtering of phase measurements reduce errors brought on by jittering data edges. The circuitry utilizes only the minimum amount of delay necessary to achieve objective thereby limiting any unintended jitter. Particularly, this programmable differential delay circuit with fine delay adjustment is designed to allow the skew between ASICS to be minimized. This includes skew between data bits, between data bits and clocks as well as minimizing the overall skew in a channel between ASICS.

DeRyckere, John F. (Eau Claire, WI); Jenkins, Philip Nord (Eau Claire, WI); Cornett, Frank Nolan (Chippewa Falls, WI)

2002-07-09T23:59:59.000Z

369

DEVELOPMENT OF A NOVEL FINE COAL CLEANING SYSTEM  

SciTech Connect (OSTI)

The goal of the proposed project was to develop a novel fine coal separator having the ability to clean 1 mm x 0 size coal in a single processing unit. The novel fine coal separator, named as EG(Enhanced Gravity) Float Cell, utilizes a centrifugal field to clean 1 mm x 250 micron size coal, whereas a flotation environment to clean minus 250 micron coal size fraction. Unlike a conventional enhanced gravity concentrator, which rotates to produce a centrifugal field requiring more energy, the EG Float Cell is fed with a tangential feed slurry to generate an enhanced gravity field without any rotating part. A prototype EG Float Cell unit having a maximum diameter of 60 cm (24 inch) was fabricated during the first-half of the project period followed by a series of exploratory tests to make suitable design modification. Test data indicated that there was a significant concentration of coarse heavy materials in the coarse tailings discharge of the EG Float Cell. The increase in weight (%) of 1 mm x 250 micron (16 x 60 mesh) size fraction from 48.9% in the feed to 72.2% in the coarse tailings discharge and the corresponding increase in the ash content from 56.9% to 87.0% is indicative of the effectiveness of the enhanced gravity section of the EG Float Cell. However, the performance of the flotation section needs to be improved. Some of the possible design modifications may include more effective air sparging system for the flotation section to produce finer bubbles and a better wash water distributor.

Manoj K. Mohanty

2005-06-01T23:59:59.000Z

370

Split-flow regeneration in absorptive air separation  

DOE Patents [OSTI]

A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs. 4 figs.

Weimer, R.F.

1987-11-24T23:59:59.000Z

371

Split-flow regeneration in absorptive air separation  

DOE Patents [OSTI]

A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

Weimer, Robert F. (Allentown, PA)

1987-01-01T23:59:59.000Z

372

Atomic Absorption Method Guide Zn in Copper Alloys  

E-Print Network [OSTI]

Atomic Absorption Method Guide Zn in Copper Alloys Principle The sample is digested in nitric/hydrochloric acid, and zinc is determined by flame atomic absorption spectrometry using an air-acetylene flame · Copper Alloys · Zinc · Flame · Atomic Absorption Method Guide: 40158 #12;©2008 Thermo Fisher Scientific

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

373

Laser Locking with Doppler-free Saturated Absorption Spectroscopy  

E-Print Network [OSTI]

there are many ways to stabilize the frequency of a laser, atomic absorption lines are particularly accurate are made, it becomes possible to resolve the saturated absorption lines that correspond to specific atomic absorption spectroscopy. This affects the number of atoms in the ground state and excited state

Novikova, Irina

374

LATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION  

E-Print Network [OSTI]

crystalline domains are taken. Absorption studies of the dynamics of atomic motions in condensed matterLATTICE DYNAMICS NUCLEAR RESONANCE ABSORPTION OF GAMMA-RADIATION AND COHERENT DECAY MODES Institut Max von Laue-Paul Langevin, Grenoble, France R6sumb. -La section efficace pour l'absorption nucleaire

Paris-Sud XI, Université de

375

Colossal Absorption of Molecules Inside Single Terahertz Nanoantennas  

E-Print Network [OSTI]

Colossal Absorption of Molecules Inside Single Terahertz Nanoantennas Hyeong-Ryeol Park, Kwang Jun: Molecules have extremely small absorption cross sections in the terahertz range even under resonant to be enhanced by >103 accompanied by a colossal absorption coefficient of 170 000 cm-1 . Tens of nanograms

Park, Namkyoo

376

Woodhead Publishing Limited, 2013 Tunable mid-infrared laser absorption  

E-Print Network [OSTI]

absorption spectroscopy F. K. TITTEL and R. LEWICKI, Rice University, USA DOI: 10 absorption spectroscopy (LAS) and recent examples of their use in field deployable optical instruments detection methods that include several types of multipass gas absorption cells with the option to apply

377

HHFW absorption in Neutral-Beam heated NSTX plasmas  

E-Print Network [OSTI]

HHFW absorption in Neutral-Beam heated NSTX plasmas B. LeBlanc, M. Podestà, W. Heidbrink XP -1012 ions Need to characterize RF absorption as a function of RF phasing, L vs. H-mode plasmas, outer gap, optimized for FIDA measurements · Similar to 2008 FIDA experiment on RF absorption by fast ions · NB sources

Princeton Plasma Physics Laboratory

378

QSO Metal Absorption Systems at High Redshift Toru Misawa1  

E-Print Network [OSTI]

QSO Metal Absorption Systems at High Redshift Toru Misawa1 , Nobunari Kashikawa2 , Youichi Ohyama2 Abstract. Quasar absorption systems give us useful information about very faint objects that we cannot detect directly. For example, metal absorption systems are generally provided by star formation

Iye, Masanori

379

Optical absorption spectra and geometric e ects in higher fullerenes  

E-Print Network [OSTI]

Optical absorption spectra and geometric e ects in higher fullerenes (Running head: Optical absorption in higher fullerenes) Kikuo Harigaya and Shuji Abe Physical Science Division, Electrotechnical of their amplitudes at the pentagons. The oscillator strengths of projected absorption almost accord with those

Harigaya, Kikuo

380

Does the photon-diffusion coefficient depend on absorption?  

E-Print Network [OSTI]

Does the photon-diffusion coefficient depend on absorption? T. Durduran and A. G. Yodh Department independent of absorption, i.e., D0 v/3 s . After presentation of the general theoretical arguments underlying this assertion, Monte Carlo simulations are performed and explicitly reveal that the absorption- independent

Boas, David

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

SPECTRA OF CRITICAL EXPONENTS IN NONLINEAR HEAT EQUATIONS WITH ABSORPTION  

E-Print Network [OSTI]

SPECTRA OF CRITICAL EXPONENTS IN NONLINEAR HEAT EQUATIONS WITH ABSORPTION V.A. GALAKTIONOV AND P of the classical porous medium equation with absorption u t = #1;u m u p in R N #2; R+ change their large-time behaviour at the critical absorption exponent p 0 = m+2=N . We show that, actually, there exists an in#12

Bath, University of

382

Assertion Absorption in Object Queries over Knowledge Bases  

E-Print Network [OSTI]

Assertion Absorption in Object Queries over Knowledge Bases Jiewen Wu, Alexander Hudek, David Toman contribute to this development by introducing a novel adaptation of bi- nary absorption for DL knowledge satisfaction problems in which consistency is assumed, and then revisit absorption in this new setting. To date

Waterloo, University of

383

Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in  

E-Print Network [OSTI]

Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

Rochelle, Gary T.

384

On the Absorption and Emission Properties of Interstellar Grains  

E-Print Network [OSTI]

Our current understanding of the absorption and emission properties of interstellar grains are reviewed. The constraints placed by the Kramers-Kronig relation on the wavelength-dependence and the maximum allowable quantity of the dust absorption are discussed. Comparisons of the opacities (mass absorption coefficients) derived from interstellar dust models with those directly estimated from observations are presented.

Aigen Li

2005-03-25T23:59:59.000Z

385

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. Modeling.................................................................................................................................. 11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

386

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous.................................................................................................................................... 8 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

387

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing...................................................................................................................................11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

388

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing.................................................................................................................................. 10 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

389

Application of Quantitative Fluorescence and Absorption-Edge  

E-Print Network [OSTI]

Application of Quantitative Fluorescence and Absorption-Edge Computed Microtomography to Image, Chicago, Illinois 60637 This paper shows that synchrotron-based fluorescence and absorption-edge computed, which had a well-correlated metal coating. Absorption-edge CMT showed the three-dimensional distribution

Sparks, Donald L.

390

The role of solar absorption in climate and climate change  

E-Print Network [OSTI]

1 The role of solar absorption in climate and climate change William Collins UC Berkeley Research Boulder, Colorado, USA #12;2 Prior Research on Absorption and Climate Field Experiments: · Central · Climate with enhanced cloud absorption Synthesis of models and aerosol observations: · Development

391

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. In Campaign.................................................................................................................................... 9 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

392

Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine  

E-Print Network [OSTI]

Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall loading. The absorption rate did not follow pseudo first-order beha®ior except at ®ery low loading. All

Rochelle, Gary T.

393

Waste Coal Fines Reburn for NOx and Mercury Emission Reduction  

SciTech Connect (OSTI)

Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury capture. During July, August, and September 2007, BES designed, procured, installed, and tested the slurry injection system at Beaver Valley. Slurry production was performed by Penn State University using equipment that was moved from campus to the Beaver Valley site. Waste coal fines were procured from Headwaters Inc. and transported to the site in Super Sacks. In addition, bituminous coal was pulverized at Penn State and trucked to the site in 55-gallon drums. This system was operated for three weeks during August and September 2007. NO{sub x} emission data were obtained using the plant CEM system. Hg measurements were taken using EPA Method 30B (Sorbent Trap method) both downstream of the electrostatic precipitator and in the stack. Ohio Lumex Company was on site to provide rapid Hg analysis on the sorbent traps during the tests. Key results from these tests are: (1) Coal Fines reburn alone reduced NO{sub x} emissions by 0-10% with up to 4% heat input from the CWS. However, the NO{sub x} reduction was accompanied by higher CO emissions. The higher CO limited our ability to try higher reburn rates for further NO{sub x} reduction. (2) Coal Fines reburn with Urea (Carbon enhanced SNCR) decreased NO{sub x} emissions by an additional 30% compared to Urea injection only. (3) Coal slurry injection did not change Hg capture across the ESP at full load with an inlet temperature of 400-430 F. The Hg capture in the ESP averaged 40%, with or without slurry injection; low mercury particulate capture is normally expected across a higher temperature ESP because any oxidized mercury is thought to desorb from the particulate at ESP temperatures above 250 F. (4) Coal slurry injection with halogen salts added to the mixing tank increased the Hg capture in the ESP to 60%. This significant incremental mercury reduction is important to improved mercury capture with hot-side ESP operation and wherever hindrance from sulfur oxides limit mercury reduction, because the higher temperature is above sulfur oxide dew point interference.

Stephen Johnson; Chetan Chothani; Bernard Breen

2008-04-30T23:59:59.000Z

394

E-Print Network 3.0 - ambient fine particulate Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

about Clean Transportation projects at the North Carolina Solar Center Summary: or maintenance areas for national ambient air quality standards (NAAQS) for ozone andor fine...

395

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network [OSTI]

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

396

POC-SCALE TESTING OF OIL AGGLOMERATION TECHNIQUES AND EQUIPMENT FOR FINE COAL PROCESSING  

SciTech Connect (OSTI)

This report covers the technical progress achieved from July 01, 1997 to September 30, 1997 on the POC-Scale Testing Agglomeration Techniques and Equipment for Fine Coal Processing project. Experimental procedures and test data for recovery of fine coal from coal fines streams generated at a commercial coal preparation plant are described. Two coal fines streams, namely Sieve Bend Effluent and Cyclone Overflow were investigated. The test results showed that ash was reduced by more than 50% at combustible matter recovery levels exceeding 95%.

NONE

1998-01-01T23:59:59.000Z

397

Photodetector with absorbing region having resonant periodic absorption between reflectors  

DOE Patents [OSTI]

A photodetector is disclosed that is responsive to a wavelength or wavelengths of interest which have heretofore been unrealized. The photodetector includes a resonant cavity structure bounded by first and second reflectors, the resonant cavity structure being resonant at the wavelength or wavelengths of interest for containing a plurality of standing waves therein. The photodetector further includes a radiation absorbing region disposed within the resonant cavity structure, the radiation absorbing region including a plurality of radiation absorbing layers spaced apart from one another by a distance substantially equal to a distance between antinodes of adjacent ones of the standing waves. Each of radiation absorbing layers is spatially positioned at a location of one of the antinodes of one of the standing waves such that radiation absorption is enhanced. The radiation absorbing layers may be either bulk layers or quantum wells includes a plurality of layers, each of which is comprised of a strained layer of InGaAs. Individual ones of the InGaAs layers are spaced apart from one another by a GaAs barrier layer. 11 figs.

Bryan, R.P.; Olbright, G.R.; Brennan, T.M.; Tsao, J.Y.

1995-02-14T23:59:59.000Z

398

E-Print Network 3.0 - absorption heat exchange Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Center MOTIVATION ABSORPTION HEAT PUMP COMBINED CARNOT CYCLES... HEAT-DRIVEN HEAT PUMPS EXERGY DESTRUCTION IN ABSORPTION CYCLE PROCESSES ZERO-ORDER ABSORPTION...

399

SPECIES DETERMINATION OF ORGANOMETALLIC COMPOUNDS USING ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY WITH LIQUID CHROMATOGRAPHY  

E-Print Network [OSTI]

Compounds Using Zeeman Atomic Absorption Spectroscopy WithCompounds Using Zeeman ,Atomic Absorption Spectroscopy withcapabilities of Zeeman atomic absorption spectroscopy (ZAA)

Koizumi, H.

2011-01-01T23:59:59.000Z

400

X-RAY ABSORPTION SPECTROSCOPY FOR THE CHEMICAL CHARACTERIZATION OF ATMOSPHERIC AEROSOLS  

E-Print Network [OSTI]

November 11-16 9 1979 X-RAY ABSORPTION SPECTROSCOPY FOR THEUniversity of California. ABSORPTION SPECTROSCOPY FOR THEand x-ray emission and absorption spectroscopy. The first

Jaklevic, J. M.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Absorption and scattering by long and randomly oriented linear chains of spheres  

E-Print Network [OSTI]

experimental measurements absorption and scattering cross-C. Bohren and D. Huffman, Absorption and Scattering of LightScattering and absorption of light by nonspherical

Lee, Euntaek; Pilon, Laurent

2013-01-01T23:59:59.000Z

402

INFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON NICKEL FILMS: A LOW TEMPERATURE THERMAL DETECTION TECHNIQUE  

E-Print Network [OSTI]

A. B. Optical System Absorption Signal C. Small SignalNoise . Sensitivity of Absorption Spectroscopy EXPERIMENTSINFRARED ABSORPTION SPECTROSCOPY OF CARBON MONOXIDE ON

Bailey, Robert Brian

2011-01-01T23:59:59.000Z

403

Absorption of solar radiation by the cloudy atmosphere: Further interpretations of collocated aircraft measurements  

E-Print Network [OSTI]

J. Vitko Jr. , Absorption of solar radiation by the cloudyet al. , Absorption of solar radiation by clouds: Observa-1999 Absorption of solar radiation by the cloudy atmosphere:

1999-01-01T23:59:59.000Z

404

Improvement of the Performance for an Absorption Refrigeration System with Lithium bromide-water as Refrigerant by Increasing Absorption Pressure  

E-Print Network [OSTI]

ICEBO2006, Shenzhen, China HVAC Technologies for Energy Efficiency, Vol. IV-10-4 Improvement of the Performance for an Absorption Refrigerating System with Lithium bromide-water as Refrigerant by Increasing Absorption... in order to lay a theoretical foundation of improving the performance of whole LBAC. 2. THE PRINCIPLE OF ENHANCING ABSORPTION EFFICIENCY OF THE ABSORBER It is well known that the absorption of ICEBO2006, Shenzhen, China HVAC...

Xie, G.; Sheng, G.; Li, G.; Pan, S.

2006-01-01T23:59:59.000Z

405

Effects of metallic absorption and the corrugated layer on the optical extraction efficiency of organic light-emitting diodes  

E-Print Network [OSTI]

The absorption of a metallic cathode in OLEDs is analyzed by using FDTD calculation. As the light propagates parallel to the layer, the intensity of Ez polarization decreases rapidly. The intensity at 2.0 um from the dipole is less than a quarter of that at 0.5 um. The strong absorption by a cathode can be a critical factor when considering the increase of optical extraction by means of bending the optical layers. The calculation indicates that the corrugation of layers helps the guided light escape the guiding layer, but also increases the absorption into a metallic cathode. The final optical output power of the corrugated OLED can be smaller than that of the flat OLED. On the contrary, the corrugated structure with a non-absorptive cathode increases the optical extraction by nearly two times.

Lee, Baek-Woon

2011-01-01T23:59:59.000Z

406

Tunable subwavelength strong absorption by graphene wrapped dielectric particles  

E-Print Network [OSTI]

The optical absorption properties of graphene wrapped dielectric particles have been investigated by using Mie scattering theory and exact multi-scattering method. It is shown that subwavelength strong absorption in infrared spectra can take place in such systems due to the excitation of plasmon resonance in graphene. The absorption characteristics and efficiency are tunable by varying Fermi level and damping constant of graphene, or by changing size and dielectric constant of small particles. For a cluster of these particles, the absorption characteristics are also affected by the separation distance between them. These extreme light resonances and absorptions in graphene wrapped nanostructures have great potential for opto-electronic devices.

Yang, Bing; Yang, Yue; Zhang, Xiangdong

2015-01-01T23:59:59.000Z

407

A strategy to stabilise the local structure of Ti{sup 4+} and Zn{sup 2+} species against aging in TiO{sub 2}/aluminium-doped ZnO bi-layers for applications in hybrid solar cells  

SciTech Connect (OSTI)

We explore a strategy to counteract aging issues in TiO{sub 2}/aluminium-doped ZnO bi-layers used in hybrid solar cells photo-anodes, mainly related to Zn diffusion in the TiO{sub 2} matrix. Different Ti{sup 4+} and Zn{sup 2+} local structures within the anatase grains and along the film thickness were found as a function of post-deposition annealing treatments in the range between 200?C and 500?C by synchrotron radiation extended x-ray absorption fine structure analyses. In particular, in the 500?C-treated sample, diffusion of zinc species along the TiO{sub 2} grain-boundaries has been observed with aging (3?years). In contrast, a mild thermal budget at 200?C favours a proper atomic arrangement of the zinc-containing anatase lattice which reduces Zn diffusion, thus guaranteeing a good stability with aging.

Pellegrino, Giovanna; La Magna, Antonino; Bongiorno, Corrado; Smecca, Emanuele; Alberti, Alessandra, E-mail: alessandra.alberti@imm.cnr.it [CNR-IMM Zona Industriale VIII Strada 5, 95121 Catania (Italy); Condorelli, Guglielmo G. [Universit degli studi di Catania and INSTM UdR Catania V.le A. Doria 6, Catania (Italy); Mocuta, Cristian [Synchrotron SOLEIL, L'Orme des Merisiers, Saint-Aubin BP 48, 91192, Gif-sur-Yvette Cedex (France)

2014-08-07T23:59:59.000Z

408

Differential Pair Distribution Function Study of the Structure of Arsenate Adsorbed on Nanocrystalline [gamma]-Alumina  

SciTech Connect (OSTI)

Structural information is important for understanding surface adsorption mechanisms of contaminants on metal (hydr)oxides. In this work, a novel technique was employed to study the interfacial structure of arsenate oxyanions adsorbed on {gamma}-alumina nanoparticles, namely, differential pair distribution function (d-PDF) analysis of synchrotron X-ray total scattering. The d-PDF is the difference of properly normalized PDFs obtained for samples with and without arsenate adsorbed, otherwise identically prepared. The real space pattern contains information on atomic pair correlations between adsorbed arsenate and the atoms on {gamma}-alumina surface (Al, O, etc.). PDF results on the arsenate adsorption sample on {gamma}-alumina prepared at 1 mM As concentration and pH 5 revealed two peaks at 1.66 {angstrom} and 3.09 {angstrom}, corresponding to As-O and As-Al atomic pair correlations. This observation is consistent with those measured by extended X-ray absorption fine structure (EXAFS) spectroscopy, which suggests a first shell of As-O at 1.69 {+-} 0.01 {angstrom} with a coordination number of 4 and a second shell of As-Al at 3.13 {+-} 0.04 {angstrom} with a coordination number of 2. These results are in agreement with a bidentate binuclear coordination environment to the octahedral Al of {gamma}-alumina as predicted by density functional theory (DFT) calculation.

Li, Wei; Harrington, Richard; Tang, Yuanzhi; Kubicki, James D.; Aryanpour, Masoud; Reeder, Richard J.; Parise, John B.; Phillips, Brian L. (SBU); (Penn)

2012-03-15T23:59:59.000Z

409

Dilution cycle control for an absorption refrigeration system  

DOE Patents [OSTI]

A dilution cycle control system for an absorption refrigeration system is disclosed. The control system includes a time delay relay for sensing shutdown of the absorption refrigeration system and for generating a control signal only after expiration of a preselected time period measured from the sensed shutdown of the absorption refrigeration system, during which the absorption refrigeration system is not restarted. A dilution cycle for the absorption refrigeration system is initiated in response to generation of a control signal by the time delay relay. This control system is particularly suitable for use with an absorption refrigeration system which is frequently cycled on and off since the time delay provided by the control system prevents needless dilution of the absorption refrigeration system when the system is turned off for only a short period of time and then is turned back on.

Reimann, Robert C. (Lafayette, NY)

1984-01-01T23:59:59.000Z

410

Atomic Resolution Mapping of the Excited-State Electronic Structure...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mapping of the Excited-State Electronic Structure of Cu2O with Time-Resolved X-Ray Absorption Spectroscopy. Atomic Resolution Mapping of the Excited-State Electronic Structure of...

411

Cross section for charmonium absorption by nucleons  

E-Print Network [OSTI]

July 2001; publishe The cross section for J/c absorption by nucleons is with empirical particle masses, which has been used previousl by pion and r meson. Including both two-body and three-bod of 1 GeV at interaction vertices involving charm hadrons... and is consistent with that extracted from J/c productio DOI: 10.1103/PhysRevC.65.015203 PAC I. INTRODUCTION Two main mechanisms for J/c suppression observed in relativistic heavy ion collisions @1# are the dissociation by the quark-gluon plasma @2...

Liu, W.; Ko, Che Ming; Lin, ZW.

2002-01-01T23:59:59.000Z

412

Absorption Heat Pumps | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects ofAbout ScienceAbout Oak RidgeAbouttheAbsorption

413

Distributed Bragg Reflectors With Reduced Optical Absorption  

DOE Patents [OSTI]

A new class of distributed Bragg reflectors has been developed. These distributed Bragg reflectors comprise interlayers positioned between sets of high-index and low-index quarter-wave plates. The presence of these interlayers is to reduce photon absorption resulting from spatially indirect photon-assisted electronic transitions between the high-index and low-index quarter wave plates. The distributed Bragg reflectors have applications for use in vertical-cavity surface-emitting lasers for use at 1.55 .mu.m and at other wavelengths of interest.

Klem, John F. (Albuquerque, NM)

2005-08-16T23:59:59.000Z

414

Absorption of the $?$ and $?$ Mesons in Nuclei  

E-Print Network [OSTI]

Due to their long lifetimes, the $\\omega$ and $\\phi$ mesons are the ideal candidates for the study of possible modifications of the in-medium meson-nucleon interaction through their absorption inside the nucleus. During the E01-112 experiment at the Thomas Jefferson National Accelerator Facility, the mesons were photoproduced from $^{2}$H, C, Ti, Fe, and Pb targets. This paper reports the first measurement of the ratio of nuclear transparencies for the $e^{+}e^{-}$ channel. The ratios indicate larger in-medium widths compared with what have been reported in other reaction channels.

M. H. Wood; R. Nasseripour; M. Paolone; C. Djalali; D. P. Weygand; the CLAS Collaboration

2010-06-17T23:59:59.000Z

415

Physically based model of downstream fining in bedrock streams with lateral input  

E-Print Network [OSTI]

Click Here for Full Article Physically based model of downstream fining in bedrock streams not show a clear, monotonic pattern of size reduction in the downstream direction. Both abrasion and selective sorting may play important roles in generating downstream fining. The objective of this study

Lajeunesse, Eric

416

Fine root growth in a sweet chestnut (Castanea sativa Mill.) coppice  

E-Print Network [OSTI]

Fine root growth in a sweet chestnut (Castanea sativa Mill.) coppice P. Montpied Laboratoire d of a sweet chestnut (Castanea sativa Mill.) coppice. The aim of this study was to examine fine root phenology of a chestnut coppice with an emphasis on the influence of coppicing. Materials and Methods This study took

Paris-Sud XI, Université de

417

Hayaku: Designing and Optimizing Finely Tuned and Portable Interactive Graphics with a Graphical Compiler  

E-Print Network [OSTI]

Hayaku: Designing and Optimizing Finely Tuned and Portable Interactive Graphics with a Graphical, France stephane.conversy@enac.fr ABSTRACT Although reactive and graphically rich interfaces are now that supports de- signing finely tuned interactive graphics. With Hayaku, a designer can abstract graphics

Paris-Sud XI, Université de

418

Synthesis of zinc oxide particles coated multiwalled carbon nanotubes: Dielectric properties, electromagnetic interference shielding and microwave absorption  

SciTech Connect (OSTI)

Graphical abstract: A resistorcapacitor model could well describe the relationships between the structure and the dielectric properties, electromagnetic interference shielding and microwave-absorption of the composites in the frequency range of 218 GHz. The resonant behavior associated with the multiwalled carbon nanotubes/zinc oxide (MWCNTs/ZnO) interface greatly broadens the absorption band. Highlights: ? ZnO-immobilized on multiwalled carbon nanotubes (MWCNTs/ZnO) have resonant behavior. ? A resistorcapacitor model describes the relation between the structure and properties. ? The composite with 40 wt% MWCNTs/ZnO has good electromagnetic interference shielding. ? Two different types of absorption peaks are found in the MWCNTs/ZnO composites. ? The existence of MWCNTs/ZnO interface broadens the absorption band. -- Abstract: Zinc oxide (ZnO) nanoparticles were coated on the surfaces of multiwalled carbon nanotubes (MWCNTs). High resolution transmission electron microscopy images show that the wurtzite ZnO immobilized on the MWCNTs is single-crystalline with a preferential [0 0 0 2] growth direction. A capacitor was generated by the interface of ZnO and MWCNTs, and a resistorcapacitor model could well describe the relationships between the structure and the dielectric properties, electromagnetic interference shielding and microwave-absorption of the composites in the frequency range of 218 GHz. The network built by ZnO-immobilized MWCNTs could contribute to the improvement of electrical properties. Resonant peaks associated with the capacitor formed by the interface were observed in the microwave absorption spectra, which suggest that reflectionloss peaks greatly broadens the absorption bandwidth.

Song, Wei-Li [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Cao, Mao-Sheng, E-mail: caomaosheng@bit.edu.cn [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Wen, Bo; Hou, Zhi-Ling; Cheng, Jin [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China)] [School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081 (China); Yuan, Jie, E-mail: yuanjie4000@sina.com [School of Information Engineering, Central University for Nationality, Beijing 100081 (China)] [School of Information Engineering, Central University for Nationality, Beijing 100081 (China)

2012-07-15T23:59:59.000Z

419

Loss of Fine Particle Ammonium from Denuded Nylon Filters  

SciTech Connect (OSTI)

Ammonium is an important constituent of fine particulate mass in the atmosphere, but can be difficult to quantify due to possible sampling artifacts. Losses of semivolatile species such as NH4NO3 can be particularly problematic. In order to evaluate ammonium losses from aerosol particles collected on filters, a series of field experiments was conducted using denuded nylon and Teflon filters at Bondville, Illinois (February 2003), San Gorgonio, California (April 2003 and July 2004), Grand Canyon National Park, Arizona (May, 2003), Brigantine, New Jersey (November 2003), and Great Smoky Mountains National Park (NP), Tennessee (JulyAugust 2004). Samples were collected over 24-hr periods. Losses from denuded nylon filters ranged from 10% (monthly average) in Bondville, Illinois to 28% in San Gorgonio, California in summer. Losses on individual sample days ranged from 1% to 65%. Losses tended to increase with increasing diurnal temperature and relative humidity changes and with the fraction of ambient total N(--III) (particulate NH4+ plus gaseous NH3) present as gaseous NH3. The amount of ammonium lost at most sites could be explained by the amount of NH4NO3 present in the sampled aerosol. Ammonium losses at Great Smoky Mountains NP, however, significantly exceeded the amount of NH4NO3 collected. Ammoniated organic salts are suggested as additional important contributors to observed ammonium loss at this location.

Yu, Xiao-Ying; Lee, Taehyoung; Ayres, Benjamin; Kreidenweis, Sonia M.; Malm, William C.; Collett, Jeffrey L.

2006-08-01T23:59:59.000Z

420

Solder flow over fine line PWB surface finishes  

SciTech Connect (OSTI)

The rapid advancement of interconnect technology has stimulated the development of alternative printed wiring board (PWB) surface finishes to enhance the solderability of standard copper and solder-coated surfaces. These new finishes are based on either metallic or organic chemistries. As part of an ongoing solderability study, Sandia National Laboratories has investigated the solder flow behavior of two azole-based organic solderability preservations, immersion Au, immersion Ag, electroless Pd, and electroless Pd/Ni on fine line copper features. The coated substrates were solder tested in the as-fabricated and environmentally-stressed conditions. Samples were processed through an inerted reflow machine. The azole-based coatings generally provided the most effective protection after aging. Thin Pd over Cu yielded the best wetting results of the metallic coatings, with complete dissolution of the Pd overcoat and wetting of the underlying Cu by the flowing solder. Limited wetting was measured on the thicker Pd and Pd over Ni finishes, which were not completely dissolved by the molten solder. The immersion Au and Ag finishes yielded the lowest wetted lengths, respectively. These general differences in solderability were directly attributed to the type of surface finish which the solder came in contact with. The effects of circuit geometry, surface finish, stressing, and solder processing conditions are discussed.

Hosking, F.M.; Hernandez, C.L.

1998-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Evidence of novel fine-scale structural variation at autism spectrum disorder candidate loci  

E-Print Network [OSTI]

control locus in future experiments. To identify potential outlier samples (with respect to sample quality) total

2012-01-01T23:59:59.000Z

422

Fine Structure of the Radial Breathing Mode in Double-Wall Carbon Nanotubes  

E-Print Network [OSTI]

The analysis of the Raman scattering cross section of the radial breathing modes of double-wall carbon nanotubes allowed to determine the optical transitions of the inner tubes. The Raman lines are found to cluster into species with similar resonance behavior. The lowest components of the clusters correspond well to SDS wrapped HiPco tubes. Each cluster represents one particular inner tube inside different outer tubes and each member of the clusters represents one well defined pair of inner and outer tubes. The number of components in one cluster increases with decreasing of the inner tube diameter and can be as high as 14.

R. Pfeiffer; F. Simon; H. Kuzmany; V. N. Popov

2005-08-09T23:59:59.000Z

423

Fine Structure of Highly Charged Excitons in Semiconductor Quantum Dots B. Urbaszek,1  

E-Print Network [OSTI]

quantum dots (QDs) are artificial atoms whose properties can be individually measured in their solid, the degeneracy of the excitonic ground state is lifted by the electron-hole (EH) exchange interaction, resultingV, they can be much larger in semiconductor nanocrystals [3] or polymers [4]. In all these systems

Ludwig-Maximilians-Universität, München

424

Pseudospherical Junctions or Josephson Effect, Backlund Transformations, and Fine Structure Coupling  

E-Print Network [OSTI]

, that the geometric phase evolution within M circularly and toroidally arranged virtual Josephson junctions (coupled by a special arrangement of Josephson junctions. In this con- text "virtual junction" means simply a scalar impedance will represent in this paper a "virtual Josephson junction". The Josephson junctions

Binder, Bernd

425

Influence of 8-Oxoguanosine on the Fine Structure of DNA Studied with  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348ASSEMBLY [ICO]Industry

426

Measurement of intensities of bands in the electronic absorption spectrum of chlorine dioxide  

E-Print Network [OSTI]

energy levels are derived, Twelve bands in the electronic absorption spectrum of chlorine dioxide between the wavelengths 4250 R and 5250 R were photographed and measured. Of these twelve, the vibrational energy levels calculated for nine of them... Calculation of Vibrational Energy Levels . . . . , 35 Estimation of Errors . . . , . . . . . . . . . . . 38 CONCLUSIONS Conolusions ~ ~ ~ 47 B IBLI QGRAFEZ ~ ~ ~ ~ ~ ~ ~ ~ 48 ~INTRGDUGT10 Analysis of thc rotational structure of the chlorine dioxide...

Rapp, Thomas Louis

1955-01-01T23:59:59.000Z

427

E-Print Network 3.0 - absorption spectroscopy measurements Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A partial sampling of these techniques includes: Absorption spectroscopy Atomic absorption... spectroscopy Auger electron ... Source: Yucca Mountain Project, US...

428

E-Print Network 3.0 - absorption spectrometry etaas Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

With Confirmation of Accuracy by Inductively Coupled Plasma Mass Spectrometry and Atomic Absorption Spectrometry... -LEAFS uses absorption; graphite furnace; inductively...

429

Intrinsic nature of visible-light absorption in amorphous semiconducting oxides  

SciTech Connect (OSTI)

To enlighten microscopic origin of visible-light absorption in transparent amorphous semiconducting oxides, the intrinsic optical property of amorphous InGaZnO{sub 4} is investigated by considering dipole transitions within the quasiparticle band structure. In comparison with the crystalline InGaZnO{sub 4} with the optical gap of 3.6 eV, the amorphous InGaZnO{sub 4} has two distinct features developed in the band structure that contribute to significant visible-light absorption. First, the conduction bands are down-shifted by 0.55 eV mainly due to the undercoordinated In atoms, reducing the optical gap between extended states to 2.8 eV. Second, tail states formed by localized oxygen p orbitals are distributed over ?0.5 eV near the valence edge, which give rise to substantial subgap absorption. The fundamental understanding on the optical property of amorphous semiconducting oxides based on underlying electronic structure will pave the way for resolving instability issues in recent display devices incorporating the semiconducting oxides.

Kang, Youngho; Song, Hochul; Han, Seungwu, E-mail: hansw@snu.ac.kr [Department of Materials Science and Engineering, Seoul National University, Seoul 151-755 (Korea, Republic of); Nahm, Ho-Hyun [Center for Correlated Electron Systems, Institute for Basic Science (IBS), Seoul 151-747 (Korea, Republic of); Department of Physics and Astronomy, Seoul National University, Seoul 151-747 (Korea, Republic of); Jeon, Sang Ho; Cho, Youngmi [CAE Team, Samsung Display Co., Ltd, 95 Samsung 2-ro, Giheung-gu, Youngin-City, Gyeonggi-Do 446-711 (Korea, Republic of)

2014-03-01T23:59:59.000Z

430

Elimination of self-absorption in fluorescence hard-x-ray absorption spectra P. Pfalzer, J.-P. Urbach, M. Klemm, and S. Horn  

E-Print Network [OSTI]

Elimination of self-absorption in fluorescence hard-x-ray absorption spectra P. Pfalzer, J-ray absorption spectra in situations where samples cannot be made in the required configuration. However, self-absorption-ray absorption coefficients. This procedure is used to obtain the vanadium K-edge spectrum of single crystal V2O3

Frenkel, Anatoly

431

Single photon absorption by a single atom: from heralded absorption to polarization state mapping  

E-Print Network [OSTI]

Together with photon emission, the absorption of a single photon by a single atom is a fundamental process in matter-light interaction that manifests its quantum mechanical nature. As an experimentally controlled process, it is a key tool for the realization of quantum technologies. In particular, in an atom/photon based quantum network scenario, in which localized atomic particles are used as quantum information processing nodes while photons are used as carriers of quantum information between distant nodes, controlling both emission and absorption of single photons by single atoms is required for quantum coherent state mapping between the two entities. Most experimental efforts to date have focused on establishing the control of single photon emission by single trapped atoms, and the implementation of quantum networking protocols using this interaction. In this chapter, we describe experimental efforts to control the process of single photon absorption by single trapped ions. We describe a series of experiments in which polarization entangled photon pairs, generated by a spontaneous parametric down-conversion source, are coupled to a single ion. First the source is operated to generate heralded single photons, and coincidences between the absorption event of one photon of the pair and the detection of the heralding partner photon are observed. We then show how polarization control in the process is established, leading to the manifestation of the photonic polarization entanglement in the absorption process. Finally, we introduce protocols in which this interaction scheme is harnessed to perform tasks in a quantum network, such as entanglement distribution among distant nodes of the network, and we demonstrate a specific protocol for heralded, high-fidelity photon-to-atom quantum state transfer.

Nicolas Piro; Jrgen Eschner

2015-02-19T23:59:59.000Z

432

Ab initio calculation of the electronic absorption spectrum of liquid water  

SciTech Connect (OSTI)

The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the OH stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Qumica e Bioqumica, Faculdade de Cincias, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Fsica da Universidade de So Paulo, CP 66318, 05314-970 So Paulo, SP (Brazil)

2014-04-28T23:59:59.000Z

433

Commercialization of Industrialized Absorption Heat Pumps in the US  

E-Print Network [OSTI]

COMMERCIALIZATION OF INDUSTRIAL ABSORPTION HEAT PUMPS IN THE US MALCOLM G. PETTIGREW LITWIN ENGINEERS &CONSTRUCTORS, INC. HOUSTON, ABSTRACT The recovery of waste heat through absorption heat pumping is quite appeal ing to U.S. industry.... However, although this technology has been successfully applied in Europe and Japan, a cauti ous atmosphere wi 11 continue to prevail in the U.S. until the first absorption heat pump is built and successfully demonstrates it's viability...

Pettigrew, M. G.

434

Multi-stage quantum absorption heat pumps  

E-Print Network [OSTI]

It is well known that heat pumps, while being all limited by the same basic thermodynamic laws, may find realization on systems as "small" and "quantum" as a three-level maser. In order to quantitatively assess how the performance of these devices scales with their size, we design generalized $N$-dimensional ideal heat pumps by merging $N-2$ elementary three-level stages. We set them to operate in the absorption chiller mode between given hot and cold baths, and study their maximum achievable cooling power and the corresponding efficiency as a function of $N$. While the efficiency at maximum power is roughly size-independent, the power itself slightly increases with the dimension, quickly saturating to a constant. Thus, interestingly, scaling up autonomous quantum heat pumps does not render a significant enhancement beyond the optimal double-stage configuration.

Luis A. Correa

2014-01-16T23:59:59.000Z

435

Performance bound for quantum absorption refrigerators  

E-Print Network [OSTI]

An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modelling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

Luis A. Correa; Jos P. Palao; Gerardo Adesso; Daniel Alonso

2013-04-29T23:59:59.000Z

436

Absorption Lengths in the Holographic Plasma  

E-Print Network [OSTI]

We consider the effect of a periodic perturbation with frequency $\\omega$ on the holographic N=4 plasma represented by the planar AdS black hole. The response of the system is given by exponentially decaying waves. The corresponding complex wave numbers can be found by solving wave equations in the AdS black hole background with infalling boundary conditions on the horizon in an analogous way as in the calculation of quasinormal modes. The complex momentum eigenvalues have an interpretation as poles of the retarded Green's functions, where the inverse of the imaginary part gives an absorption length $\\lambda$. At zero frequency we obtain the screening length for a static field. These are directly related to the glueball masses in the dimensionally reduced theory. We also point out that the longest screening length corresponds to an operator with non-vanishing R-charge and thus does not have an interpretation as a QCD3 glueball.

Irene Amado; Carlos Hoyos; Karl Landsteiner; Sergio Montero

2007-07-11T23:59:59.000Z

437

Gas separation using ultrasound and light absorption  

DOE Patents [OSTI]

An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

Sinha, Dipen N. (Los Alamos, NM)

2012-07-31T23:59:59.000Z

438

J/$?$ absorption in a multicomponent hadron gas  

E-Print Network [OSTI]

A model for anomalous $J/\\Psi$ suppression in high energy heavy ion collisions is presented. As the additional suppression mechanism beyond standard nuclear absorption inelastic $J/\\Psi$ scattering with hadronic matter is considered. Hadronic matter is modeled as an evolving multi-component gas of point-like non-interacting particles (MCHG). Estimates for the sound velocity of the MCHG are given and the equation of state is compared with Lattice QCD data in the vicinity of the deconfinement phase transition. The approximate cooling pattern caused by longitudinal expansion is presented. It is shown that under these conditions the resulting $J/\\Psi$ suppression pattern agrees well with NA38 and NA50 data.

Dariusz Prorok; Ludwik Turko; David Blaschke

2008-08-04T23:59:59.000Z

439

Vitrification testing of soil fines from contaminated Hanford 100 Area and 300 Area soils  

SciTech Connect (OSTI)

The suitability of Hanford soil for vitrification is well known and has been demonstrated extensively in other work. The tests reported here were carried out to confirm the applicability of vitrification to the soil fines (a subset of the Hanford soil potentially different in composition from the bulk soil) and to provide data on the performance of actual, vitrified soil fines. It was determined that the soil fines were generally similar in composition to the bulk Hanford soil, although the fraction <0.25 mm in the 100 Area soil sample appears to differ somewhat from the bulk soil composition. The soil fines are readily melted into a homogeneous glass with the simple additions of CaO and/or Na{sub 2}O. The vitrified waste (plus additives) occupies only 60% of the volume of the initial untreated waste. Leach testing has shown the glasses made from the soil fines to be very durable relative to natural and man-made glasses and has demonstrated the ability of the vitrified waste to greatly reduce the release of radionuclides to the environment. Viscosity and electrical conductivity measurements indicate that the soil fines will be readily processable, although with levels of additives slightly greater than used in the radioactive melts. These tests demonstrate the applicability of vitrification to the contaminated soil fines and the exceptional performance of the waste form resulting from the vitrification of contaminated Hanford soils.

Ludowise, J.D.

1994-05-01T23:59:59.000Z

440

Infrared absorption of hydrogen-related defects in strontium titanate M. C. Tarun and M. D. McCluskeya)  

E-Print Network [OSTI]

in perovskite oxides, an important issue in fuel cells.16 In as- grown SrTiO3, isolated hydrogen forms a bondInfrared absorption of hydrogen-related defects in strontium titanate M. C. Tarun and M. D. Mc 2011) Hydrogen has a significant impact on the structural and electronic properties of metals

McCluskey, Matthew

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

absorption spectrometry feasibility: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption is induced by tunable laser excitation Maier, John Paul 5 FEASIBILITY OF SOLAR-FIRED, COMPRESSOR-ASSISTED Energy Storage, Conversion and Utilization Websites...

442

absorption heat pump: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heating capacity k jet nozzle Closed Cycles: AbsorptionAdsorption heat pump thermal compressor driven by waste heat1 Industrial heat pumps in Germany - potentials,...

443

E-Print Network 3.0 - absorption spectroscopy characterization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Restoration Technologies 87 Terahertz Time-Domain Spectroscopy Study of Silica Aerogels and Adsorbed Molecular Jiangquan Zhang and D. Grischkowsky* Summary: absorption...

444

Solar absorption by Mie resonances in cloud droplets  

E-Print Network [OSTI]

and narrower. These sensors measure solar backscattered andsensor channels where atmospheric absorption is particle dominated. The canonical resolution produces broadband solar

Zender, Charles S; Talamantes, Jorge

2006-01-01T23:59:59.000Z

445

Which Absorption Model Should Be Used for Supercooled  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Absorption Model Should Be Used for Supercooled Liquid Water in the Microwave? For original submission and image(s), see ARM Research Highlights http:www.arm.govscience...

446

Black holes and the absorption rate of cosmological scalar fields  

E-Print Network [OSTI]

We study the absorption of a massless scalar field by a static black hole. Using the continuity equation that arises from the Klein-Gordon equation, it is possible to define a normalized absorption rate $\\Gamma(t)$ for the scalar field as it falls into the black hole. It is found that the absorption mainly depends upon the characteristics wavelengths involved in the physical system: the mean wavenumber and the width of the wave packet, but that it is insensitive to the scalar field's strength. By taking a limiting procedure, we determine the minimum absorption fraction of the scalar field's mass by the black hole, which is around 50%.

L. Arturo Urena-Lopez; Lizbeth M. Fernandez

2011-07-15T23:59:59.000Z

447

E-Print Network 3.0 - atomic binding energy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energy Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic binding energy Page: << < 1 2 3 4 5 > >> 1 Extended Xray Absorption Fine Structure...

448

Order and disorder in the local and long-range structure of the spin-glass pyrochlore, Tb{sub 2}Mo{sub 2}O{sub 7}  

SciTech Connect (OSTI)

To understand the origin of the spin-glass state in molybdate pyrochlores, the structure of Tb{sub 2}Mo{sub 2}O{sub 7} is investigated using two techniques: the long-range lattice structure was measured using neutron powder diffraction (NPD), and local structure information was obtained from the extended x-ray absorption fine structure (EXAFS) technique. While the long-range structure appears generally well ordered, enhanced mean-squared site displacements on the O(1) site and the lack of temperature dependence of the strongly anisotropic displacement parameters for both the Mo and O(1) sites indicate some disorder exists. Likewise, the local structure measurements indicate some Mo-Mo and Tb-O(1) nearest-neighbor disorder exists, similar to that found in the related spin-glass pyrochlore, Y{sub 2}Mo{sub 2}O{sub 7}. Although the freezing temperature in Tb{sub 2}Mo{sub 2}O{sub 7}, 25 K, is slightly higher than in Y{sub 2}Mo{sub 2}O{sub 7}, 22 K, the degree of local pair distance disorder is actually less in Tb{sub 2}Mo{sub 2}O{sub 7}. This apparent contradiction is considered in light of the interactions involved in the freezing process.

Jiang, Yu; Huq, Ashfia; Booth, Corwin H.; Ehlers, Georg; Greedan, John E.; Gardner, Jason S.

2011-02-11T23:59:59.000Z

449

Electronic structure, molecular orientation, charge transfer dynamics and solar cells performance in donor/acceptor copolymers and fullerene: Experimental and theoretical approaches  

SciTech Connect (OSTI)

By combining experimental and theoretical approaches, the electronic structure, molecular orientation, charge transfer dynamics and solar cell performance in donor/acceptor copolymer poly[2,7-(9,9-bis(2-ethylhexyl)-dibenzosilole)-alt-4,7-bis(thiophen-2-yl) benzo-2,1,3-thiadiazole] (PSiF-DBT) films and blended with 6,6.-phenyl-C 61-butyric acid methyl ester (PSiF-DBT:PCBM) were investigated. Good agreement between experimental and theoretical PSiF-DBT UV-Vis absorption spectrum is observed and the main molecular orbitals contributing to the spectrum were determined using DFT single point calculations. Non-coplanar configuration was determined by geometric optimization calculation in isolated PSiF-DBT pentamer and corroborated by angular variation of the sulphur 1s near-edge X-ray absorption fine structure (NEXAFS) spectra. Edge-on and plane-on molecular orientations were obtained for thiophene and benzothiadiazole units, respectively. A power conversion efficiency up to 1.58%, open circuit voltage of 0.51 V, short circuit current of 8.71 mA/cm{sup 2} and a fill factor of 35% was obtained using blended PSiF-DBT:PCBM as active layer in a bulk heterojunction solar cell. Ultrafast electron dynamics in the low-femtosecond regime was evaluated by resonant Auger spectroscopy using the core-hole clock methodology around sulphur 1s absorption edge. Electron delocalization times for PSiF-DBT and PSiF-DBT:PCBM polymeric films were derived for selected excitation energies corresponding to the main transitions in the sulphur 1s NEXAFS spectra. The mixture of PSiF-DBT with PCBM improves the charge transfer process involving the ?* molecular orbital of the thiophene units.

Garcia-Basabe, Y.; Borges, B. G. A. L.; Rocco, M. L. M., E-mail: lsroman@fisica.ufpr.br, E-mail: luiza@iq.ufrj.br [Institute of Chemistry, Federal University of Rio de Janeiro, Rio de Janeiro 21941-909 (Brazil); Marchiori, C. F. N.; Yamamoto, N. A. D.; Koehler, M.; Roman, L. S., E-mail: lsroman@fisica.ufpr.br, E-mail: luiza@iq.ufrj.br [Departament of Physics, Federal University of Paran, Curitiba 81531-990 (Brazil); Macedo, A. G. [Departament of Physics, Technological Federal University of Paran, Curitiba 80230-901 (Brazil)

2014-04-07T23:59:59.000Z

450

Dynamic molecular structure of plant biomass-derived black carbon (biochar)  

SciTech Connect (OSTI)

Char black carbon (BC), the solid residue of incomplete combustion, is continuously being added to soils and sediments due to natural vegetation fires, anthropogenic pollution, and new strategies for carbon sequestration ('biochar'). Here we present a molecular-level assessment of the physical organization and chemical complexity of biomass-derived chars and, specifically, that of aromatic carbon in char structures. BET-N{sub 2} surface area, X-ray diffraction (XRD), synchrotron-based Near-edge X-ray Absorption Fine Structure (NEXAFS), and Fourier transform infrared (FT-IR) spectroscopy are used to show how two plant materials (wood and grass) undergo analogous, but quantitatively different physical-chemical transitions as charring temperature increases from 100 to 700 C. These changes suggest the existence of four distinct categories of char consisting of a unique mixture of chemical phases and physical states: (i) in transition chars the crystalline character of the precursor materials is preserved, (ii) in amorphous chars the heat-altered molecules and incipient aromatic polycondensates are randomly mixed, (iii) composite chars consist of poorly ordered graphene stacks embedded in amorphous phases, and (iv) turbostratic chars are dominated by disordered graphitic crystallites. The molecular variations among the different char categories translate into differences in their ability to persist in the environment and function as environmental sorbents.

Keiluweit, M.; Nico, P.S.; Johnson, M.G.; Kleber, M.

2009-11-15T23:59:59.000Z

451

Chemical Bonding and Structural Information of Black CarbonReference Materials and Individual Carbonaceous AtmosphericAerosols  

SciTech Connect (OSTI)

The carbon-to-oxygen ratios and graphitic nature of a rangeof black carbon standard reference materials (BC SRMs), high molecularmass humic-like substances (HULIS) and atmospheric particles are examinedusing scanning transmission X-ray microscopy (STXM) coupled with nearedge X-ray absorption fine structure (NEXAFS) spectroscopy. UsingSTXM/NEXAFS, individual particles with diameter>100 nm are studied,thus the diversity of atmospheric particles collected during a variety offield missions is assessed. Applying a semi-quantitative peak fittingmethod to the NEXAFS spectra enables a comparison of BC SRMs and HULIS toparticles originating from anthropogenic combustion and biomass burns,thus allowing determination of the suitability of these materials forrepresenting atmospheric particles. Anthropogenic combustion and biomassburn particles can be distinguished from one another using both chemicalbonding and structural ordering information. While anthropogeniccombustion particles are characterized by a high proportion ofaromatic-C, the presence of benzoquinone and are highly structurallyordered, biomass burn particles exhibit lower structural ordering, asmaller proportion of aromatic-C and contain a much higher proportion ofoxygenated functional groups.

Hopkins, Rebecca J.; Tivanski, Alexei V.; Marten, Bryan D.; Gilles, Mary K.

2007-04-25T23:59:59.000Z

452

High-strain-rate nanoindentation behavior of fine-grained magnesium alloys  

E-Print Network [OSTI]

The effects of temperature and alloying elements on deformation in the high-strain-rate regime were investigated by testing fine-grained magnesium alloys with an average grain size of 2 ? 3 ?m by a nanoindentation technique. ...

Somekawa, Hidetoshi

453

Low-Cycle Fatigue of Ultra-Fine-Grained Cryomilled 5083 Aluminum Alloy  

E-Print Network [OSTI]

of an Ultra-Fine Grained Aluminum Alloy, Poster Session,Grained Cryomilled 5083 Aluminum Alloy J.L. WALLEY, E.J.consistent with other MA aluminum alloys and is attributed

Walley, J. L.; Lavernia, E. J.; Gibeling, J. C.

2009-01-01T23:59:59.000Z

454

Optical absorption intensity of semiconductor single-wall carbon nanotubes  

E-Print Network [OSTI]

Optical absorption intensity of semiconductor single-wall carbon nanotubes Y. Oyama1 , R. Saito1. The optical absorption intensity is inversely proportional to the diameter in the unit of per carbon atom of single-wall carbon nanotubes (SWNT) synthesized by alcohol CCVD (ACCVD) method and HiPco method [1

Maruyama, Shigeo

455

Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study  

E-Print Network [OSTI]

1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

456

Infrared absorption spectra, radiative efficiencies, and global warming potentials  

E-Print Network [OSTI]

Infrared absorption spectra, radiative efficiencies, and global warming potentials of newly.mdpi.com/journal/atmosphere Article Infrared Absorption Spectra, Radiative Efficiencies, and Global Warming Potentials of Newly of 600­1730 cm-1 . These spectra are then used to calculate the radiative efficiencies and global warming

Wirosoetisno, Djoko

457

Optical absorption and ionization of silicate glasses Leonid B. Glebov  

E-Print Network [OSTI]

Optical absorption and ionization of silicate glasses Leonid B. Glebov School of Optics and hydroxyl), and induced (color centers) absorption of multicomponent silicate glasses in UV, visible-photon ionization was detected in alkaline-silicate glasses exposed to high-power laser radiation in nano

Glebov, Leon

458

affect intestinal absorption: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

affect intestinal absorption First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Intestinal Absorption and...

459

absorption features dust: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption features dust First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Silicon carbide absorption...

460

absorption spectrophotometric studies: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption spectrophotometric studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Light absorption...

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

absorption model: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption model First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Two models for absorption by coloured...

462

absorption cross section: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption cross section First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 ? absorption cross sections...

463

absorption line quasars: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption line quasars First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quasar Absorption Lines...

464

absorption spectroscopy studies: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption spectroscopy studies First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 On Automatic Absorption...

465

Triple effect absorption chiller utilizing two refrigeration circuits  

DOE Patents [OSTI]

A triple effect absorption method and apparatus having a high coefficient of performance. Two single effect absorption circuits are combined with heat exchange occurring between a condenser and absorber of a high temperature circuit, and a generator of a low temperature circuit. The evaporators of both the high and low temperature circuits provide cooling to an external heat load.

DeVault, Robert C. (Knoxville, TN)

1988-01-01T23:59:59.000Z

466

absorption spectroscopic analysis: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption spectroscopic analysis First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 X-ray Absorption...

467

absorption line quasar: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption line quasar First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Quasar Absorption Lines...

468

absorption process tcap: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption process tcap First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Two-photon Absorption Process...

469

absorption band substructure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption band substructure First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 THE ABSORPTION BAND EDGE...

470

alpha absorption systems: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

absorption systems First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Lyman alpha Absorption Systems and...

471

Effect of sediment concentration on artificial well recharge in a fine sand aquifer  

E-Print Network [OSTI]

EFFECT OF SEDIMENT CONCENTRATION ON ARTIFICIAL WELL RECHARGE IN A FINE SAND AQUIFER A Thesis By MD. ATAUR RAHMAN Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1968 Major Subject: Agricultural Engineering EFFECT OF SEDIMENT CONCENTRATION ON ARTIFICIAL WELL RECHARGE IN A FINE SAND AqUIFER A Thesis By MD. ATAUR RAHMAN Approved as to style and content by: (Chairman of ommitt ) ( a o...

Rahman, Mohammed Ataur

1968-01-01T23:59:59.000Z

472

Chemical measurements of phosphorus avialability in some medium to fine textured soils  

E-Print Network [OSTI]

L]BRARY A A M COLLEGE OF TEXAS CHEMICAL MEASKKMEETS OF PHOSPHORUS AVAIIAHILITY IH SOME MEDIUM TO FINE TEXTURED SOILS HUGO A. VELASCO N. A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas... in Partial fulfillment of the requirements for the degree oi' MASTER OF SCIEECE MAJOR SUBJECT: AGRONOMY Nay, 1956 CHEMICAL MEASUREMENTS OF PHOSPHORUS AVAILABILITY IN SOME MEDIUM TO FINE TEXTURED SOILS A Thesis Hugo A. Velasco M. Approved as to style...

Velasco Molina, Hugo Alejo

1956-01-01T23:59:59.000Z

473

Application of the Modified Methylene Blue Test to Detect Clay Minerals in Coarse Aggregate Fines  

E-Print Network [OSTI]

APPLICATION OF THE MODIFIED METHYLENE BLUE TEST TO DETECT CLAY MINERALS IN COARSE AGGREGATE FINES A Thesis by BRANDON THOMAS PITRE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...: Civil Engineering Copyright 2012 Brandon Thomas Pitre ii ABSTRACT The purpose of this study was to implement a new, rapid field method to effectively and accurately detect harmful clay minerals in aggregate fines by using the modified...

Pitre, Brandon

2012-12-04T23:59:59.000Z

474

Effect of Fluorogestone Acetate (cronolone) on the performance of fine-wool ewes  

E-Print Network [OSTI]

EFFECT OF FLUOROGESTONE ACETATE (CRONOLONE) ON THE PERFORMANCE OF FINE-WOOL EWES A Thesis By SALAH AYACHI Submitted to the Graduate College of the Texas ARM University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1967 Major Subject: Physiology of Reproduction EFFECT OF FLUOROGESTONE ACETATE (CRONOLONE I ON THE PERFORMANCE OF FINE-WOOL EWES A Thesis SALAH AYACHI Approved as to style and content by: (Chairman of Committ e) d of Departmen...

Ayachi, Salah

1967-01-01T23:59:59.000Z

475

Structure and dielectric properties of La{sub x}Hf{sub (1?x)}O{sub y} thin films: The dependence of components  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: La{sub x}Hf{sub (1?x)}O{sub y} thin films were grown by pulse laser deposition method. The thin film with 10% La/(La + Hf) atom ratio forms a cubic HfO{sub 2} phase. The amorphous thin films due to more La introduced have almost same local structure. The main infrared phonon modes move to lower frequency for the amorphous thin films. The static dielectric constants of the amorphous thin films increase with La content. - Abstract: La{sub x}Hf{sub (1?x)}O{sub y} (x = 0, 0.1, 0.3, 0.5, 0.7, y=2?(1/2)x) thin films were grown by pulsed laser deposition (PLD) method. The component dependence of the structure and vibration properties of these thin films is studied by combining X-ray diffraction, X-ray absorption fine structure (XAFS) and infrared spectroscopy. The thin film with 10% La/(La + Hf) atom ratio forms a cubic HfO{sub 2} phase and it has the largest static dielectric constant. More La atoms introduced cause amorphous phase formed and the static dielectric constants increase with the La content. Although XAFS indicates that these amorphous thin films have almost same local structures, the infrared phonon modes with most contribution to the static dielectric constant move to lower frequency, which results in the component dependence of the dielectric constant.

Qi, Zeming, E-mail: zmqi@ustc.edu.cn [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029 (China); Cheng, Xuerui [Department of Technology and Physics, Zhengzhou University of Light Industry, Zhengzhou, Henan 450002 (China); Zhang, Guobin [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029 (China); Li, Tingting [Institute of Microelectronics of Chinese Academy of Science, Beijing 100029 (China); Wang, Yuyin; Shao, Tao; Li, Chengxiang; He, Bo [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029 (China)

2013-07-15T23:59:59.000Z

476

Two-photon absorption and emission by Rydberg atoms in coupled cavities  

E-Print Network [OSTI]

We study the dynamics of a system composed of two coupled cavities, each containing a single Rydberg atom. The interplay between Rydberg-Rydberg interaction and photon hopping enables the transition of the atoms from the collective ground state to the double Rydberg excitation state by individually interacting with the hybrid cavity modes and suppressing the up conversion process between them. The atomic transition is accompanied by the two-photon absorption and emission of the hybrid modes. Since the energy level structure of the atom-cavity system is photon number dependent, there is only a pair of states being in the two-photon resonance. Therefore, the system can act as a quantum nonlinear absorption filter through the nonclassical quantum process, converting coherent light field into a non-classical state. Meanwhile, the vacuum field in the cavity inspires the Rydberg atoms to simultaneously emit two photons into the hybrid mode, resulting in obvious emission enhancement of the mode.

Huaizhi Wu; Zhen-Biao Yang; Shi-Biao Zheng

2013-10-10T23:59:59.000Z

477

Electrochemical flowcell for in-situ investigations by soft x-ray absorption and emission spectroscopy  

SciTech Connect (OSTI)

A new liquid flow-cell designed for electronic structure investigations at the liquid-solid interface by soft X-ray absorption and emission spectroscopy is presented. A thin membrane serves simultaneously as a substrate for the working electrode and solid state samples as well as for separating the liquid from the surrounding vacuum conditions. In combination with counter and reference electrodes this approach allows in-situ studies of electrochemical deposition processes and catalytic reactions at the liquid-solid interface in combination with potentiostatic measurements. As model system in-situ monitoring of the deposition process of Co metal from a 10 mM CoCl{sub 2} aqueous solution by X-ray absorption and emission spectroscopy is presented.

Schwanke, C.; Lange, K. M., E-mail: Kathrin.lange@helmholtz-berlin.de [Helmholtz-Zentrum Berlin fr Materialien und Energie, Institute of Solar Fuels, Albert-Einstein-Strae 15, 12489 Berlin (Germany); Golnak, R.; Xiao, J. [Helmholtz-Zentrum Berlin fr Materialien und Energie, Institute of Methods for Material Development, Albert-Einstein-Strae 15, 12489 Berlin (Germany)

2014-10-15T23:59:59.000Z

478

Theory of triplet optical absorption in oligoacenes: From naphthalene to heptacene  

SciTech Connect (OSTI)

In this paper, we present a detailed theory of the triplet states of oligoacenes containing up to seven rings, i.e., starting from naphthalene all the way up to heptacene. In particular, we present results on the optical absorption from the first triplet excited state 1{sup 3}B{sub 2u}{sup +} of these oligomers, computed using the Pariser-Parr-Pople model Hamiltonian, and a correlated electron approach employing the configuration-interaction methodology at various levels. Excitation energies of various triplets states obtained by our calculations are in good agreement with the experimental results, where available. The computed triplet spectra of oligoacenes exhibits rich structure dominated by two absorption peaks of high intensities, which are well separated in energy, and are caused by photons polarized along the conjugation direction. This prediction of ours can be tested in future experiments performed on oriented samples of oligoacenes.

Chakraborty, Himanshu, E-mail: chakraborty.himanshu@gmail.com; Shukla, Alok, E-mail: shukla@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Powai, Mumbai 400076 (India)

2014-10-28T23:59:59.000Z

479

Absorption of surface acoustic waves by topological insulator thin films  

SciTech Connect (OSTI)

We present a theoretical study on the absorption of the surface acoustic waves (SAWs) by Dirac electrons in topological insulator (TI) thin films (TITFs). We find that due to momentum and energy conservation laws, the absorption of the SAWs in TITFs can only be achieved via intra-band electronic transitions. The strong absorption can be observed up to sub-terahertz frequencies. With increasing temperature, the absorption intensity increases significantly and the cut-off frequency is blue-shifted. More interestingly, we find that the absorption of the SAWs by the TITFs can be markedly enhanced by the tunable subgap in the Dirac energy spectrum of the TI surface states. Such a subgap is absent in conventional two-dimensional electron gases (2DEGs) and in the gapless Dirac 2DEG such as graphene. This study is pertinent to the exploration of the acoustic properties of TIs and to potential application of TIs as tunable SAW devices working at hypersonic frequencies.

Li, L. L., E-mail: lllihfcas@foxmail.com [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Xu, W., E-mail: wenxu-issp@aliyun.com [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031 (China); Department of Physics, Yunnan University, Kunming 650091 (China)

2014-08-11T23:59:59.000Z

480

POC-scale testing of an advanced fine coal dewatering equipment/technique  

SciTech Connect (OSTI)

Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74 {mu}m) clean coal. Economical dewatering of an ultra-fine clean coal product to a 20 percent level moisture will be an important step in successful implementation of the advanced cleaning processes. This project is a step in the Department of Energy`s program to show that ultra-clean coal could be effectively dewatered to 20 percent or lower moisture using either conventional or advanced dewatering techniques. As the contract title suggests, the main focus of the program is on proof-of-concept testing of a dewatering technique for a fine clean coal product. The coal industry is reluctant to use the advanced fine coal recovery technology due to the non-availability of an economical dewatering process. in fact, in a recent survey conducted by U.S. DOE and Battelle, dewatering of fine clean coal was identified as the number one priority for the coal industry. This project will attempt to demonstrate an efficient and economic fine clean coal slurry dewatering process.

Groppo, J.G.; Parekh, B.K. [Univ. of Kentucky, Lexington, KY (United States); Rawls, P. [Department of Energy, Pittsburgh, PA (United States)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "absorption fine structure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Absorption media for irreversibly gettering thionyl chloride  

DOE Patents [OSTI]

Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

2002-01-01T23:59:59.000Z

482

On the local electronic and atomic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films on Si  

SciTech Connect (OSTI)

The local electronic and atomic structure of (111)-oriented, single crystalline mixed Ce{sub 1?x}Pr{sub x}O{sub 2??} (x?=?0, 0.1 and 0.6) epitaxial thin films on silicon substrates have been investigated in view of engineering redox properties of complex oxide films. Non-destructive X-ray absorption near edge structure reveals that Pr shows only +3 valence and Ce shows only nominal +4 valence in mixed oxides. Extended x-ray absorption fine structure (EXAFS) studies were performed at K edges of Ce and Pr using a specially designed monochromator system for high energy measurements. They demonstrate that the fluorite lattice of ceria (CeO{sub 2}) is almost not perturbed for x?=?0.1 sample, while higher Pr concentration (x?=?0.6) not only generates a higher disorder level (thus more disordered oxygen) but also causes a significant reduction of CeO interatomic distances. The valence states of the cations were also examined by techniques operating in highly reducing environments: scanning transmission electron microscopy-electron energy loss spectroscopy and X-ray photoemission spectroscopy; in these reducing environments, evidence for the presence of Ce{sup 3+} was clearly found for the higher Pr concentration. Thus, the introduction of Pr{sup 3+} into CeO{sub 2} strongly enhances the oxygen exchange properties of CeO{sub 2}. This improved oxygen mobility properties of CeO{sub 2} are attributed to the lattice disorder induced by Pr mixing in the CeO{sub 2} fluorite lattice, as demonstrated by EXAFS measurements. Thus, a comprehensive picture of the modifications of the atomic and electronic structure of Ce{sub 1?x}Pr{sub x}O{sub 2??} epitaxial films and their relation is obtained.

Niu, Gang, E-mail: gang@ihp-microelectronics.com; Schubert, Markus Andreas; Zoellner, Marvin Hartwig [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); D'Acapito, Francesco [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Schroeder, Thomas [IHP, Im Technologiepark 25, 15236 Frankfurt (Oder) (Germany); BTU Cottbus-Senftenberg, Konrad-Zuse-Str. 1, 03046 Cottbus (Germany); Boscherini, Federico [Consiglio Nazionale delle Ricerche, Istituto Officina dei Materiali, Operative Group in Grenoble, c/o European Synchrotron Radiation Facility, B.P. 220, 38043 Grenoble (France); Department of Physics and Astronomy, University of Bologna, via le C. Berti Pichat 6/2, 40127 Bologna (Italy)

2014-09-28T23:59:59.000Z

483

Space Science: Atmosphere Thermal Structure  

E-Print Network [OSTI]

Space Science: Atmosphere Part -2 Thermal Structure Review tropospheres Absorption of Radiation Adiabatic Lapse Rate ~ 9 K/km Slightly smaller than our estimate Pressure ~3000ft under ocean surface thickness (positive up) is the solar zenith angle Fs is the solar energy flux at frequency (when

Johnson, Robert E.

484

SOURCE SIGNATURES OF FINE PARTICULATE MATTER FROM PETROLEUM REFINING AND FUEL USE  

SciTech Connect (OSTI)

The molecular structure and microstructure of a suite of fine particulate matter (PM) samples produced by the combustion of residual fuel oil and diesel fuel were investigated by an array of analytical techniques. Some of the more important results are summarized below. Diesel PM (DPM): A small diesel engine test facility was used to generate a suite of diesel PM samples from different fuels under engine load and idle conditions. C XANES, {sup 13}C NMR, XRD, and TGA were in accord that the samples produced under engine load conditions contained more graphitic material than those produced under idle conditions, which contained a larger amount of unburned diesel fuel and lubricating oil. The difference was enhanced by the addition of 5% of oxygenated compounds to the reference fuel. Scanning transmission x-ray micro-spectroscopy (STXM) was able to distinguish particulate regions rich in C=C bonds from regions rich in C-H bonds with a resolution of {approx}50 nm. The former are representative of more graphitic regions and the latter of regions rich in unburned fuel and oil. The dominant microstructure observed by SEM and TEM consisted of complex chain-like structures of PM globules {approx}20-100 nm in mean diameter, with a high fractal dimension. High resolution TEM revealed that the graphitic part of the diesel soot consisted of onion-like structures made up of graphene layers. Typically 3-10 graphene layers make up the ''onion rings'', with the layer spacing decreasing as the number of layers increases. ROFA PM: Residual oil fly ash (ROFA) PM has been analyzed by a new approach that combines XAFS spectroscopy with selective leaching procedures. ROFA PM{sub 2.5} and PM{sub 2.5+} produced in combustion facilities at the U.S. EPA National Risk Management Research Laboratory (NRML) were analyzed by XAFS before and after leaching with water, acid (1N HCl), and pentane. Both water and acid leaching removed most of the metal sulfates, which were the dominant phase present for most metals (V, Ni, Zn, etc.). This allowed conclusive identification in the leaching residue of important secondary sulfide and oxide phases, including Ni sulfide, a toxic and carcinogenic phase observed in the leached PM{sub 2.5+} samples. Other significant secondary phases identified included V{sub 2}O{sub 4}, V sulfide, and NiFe{sub 2}O{sub 4}.

Gerald P. Huffman; Frank E. Huggins; Naresh Shah; Artur Braun; Yuanzhi Chen; J. David Robertson; Joseph Kyger; Adel F. Sarofim; Ronald J. Pugmire; Henk L.C. Meuzelaar; JoAnn Lighty

2003-07-31T23:59:59.000Z