National Library of Energy BETA

Sample records for aa bond rate

  1. FITCH RATES ENERGY NORTHWEST, WA'S ELECTRIC REV RFDG BONDS 'AA...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FITCH RATES ENERGY NORTHWEST, WA'S ELECTRIC REV RFDG BONDS 'AA'; OUTLOOK STABLE Fitch Ratings-Austin-22 September 2015: Fitch Ratings assigns its 'AA' rating to the following bonds...

  2. AA

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table 1.10 CoolingNotes &* jRealglobalAa AA In

  3. Effect of nuclear ownership on utility bond ratings and yields

    SciTech Connect (OSTI)

    Nesse, R.J.

    1982-02-01

    The major objective of this study was to test the hypothesis that investors have required an additional interest rate premium before purchasing bonds of utilities with large investments in nuclear facilities. The study required several tasks. First, the literature relating to firm bankruptcy and default was reviewed. Second, the failing financial health of the electric utility industry was assessed in terms of construction problems, the impact of federal and state regulations, and the impact of Three Mile Island. Finally, data were collected on 63 electric utilities. This allowed statistical estimation of the magnitude of the risk premium associated with utility involvement in nuclear power. The effect of this involvement on a utility's bond ratings was also examined. Multiple regression was the statistical tool used for the statistical testing and estimation.

  4. FITCH RATES ENERGY NORTHWEST, WA'S ELECTRIC REV RFDG BONDS 'AA'; OUTLOOK STABLE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HABFES OctoberEvan Racah Evan-5InformationValues61 Used4Top panel:FITCH

  5. Rate Effects for Mixed-Mode Fracture of Plastically Deforming, Adhesively-Bonded Structures

    E-Print Network [OSTI]

    Thouless, Michael

    from a commercial adhesive and a dual-phase steel has been studied under different rates. Since mixed- mode fracture occurs along the interface between the steel and adhesive, the cohesive- parameters

  6. Constitutive response of two plastic-bonded explosive binder materials as a function of temperature and strain-rate

    SciTech Connect (OSTI)

    Cady, C. M.; Blumenthal, W. R.; Gray, G. T. , III; Idar, D. J.

    2004-01-01

    Recently, interest has been shown concerning the mechanical response of plastic-bonded explosives (PBX) and propellants to enable the development of predictive materials models describing the mechanical behavior of these composites. Accordingly, detailed information about the constitutive response is crucial. Compression measurements were conducted on two explosive formulation binders, extruded Estane{trademark} 5703 (hereafter referred to as Estane) and plasticized Estane as a function of temperature from -60 C to +23 C using a specially-designed split Hopkinson pressure bar (strain rate of {approx} 2800 s{sup -1}) and quasi-stattically (strain rates from {approx} 0.001 to 1 s{sup -1}) using a hydraulic load frame. The mechanical response of the Estane was found to exhibit a stronger dependency on strain rate and temperature and higher flow strength for similar test conditions of the materials tested. Plasticized Estane was less sensitively dependent on strain rate and temperature. The visco-elastic recovery of both binders is seen to dominate the mechanical behavior at temperatures above the glass transition temperature (T{sub g}). The binders exhibited increasing elastic loading moduli, E, with increasing strain rate or decreasing temperature, which is similar to other polymeric materials. There is a pronounced shift in the apparent T{sub g} to higher temperatures as the strain rate is increased. At low strain rates the binders exhibit a yield behavior followed by a drop in the flow stress which may or may not recover. At high strain rates the load drop does not occur and the flow stresses level out. A discussion of the Hopkinson bar technique as applied to polymeric or low impedance materials is described in detail.

  7. The University of Rochester Revenue Bonds, Series 2003B (the "Series 2003B Bonds") were issued on November 6, 2003 as auction rate securities and are subject to mandatory tender for purchase and remarketing on September 3, 2008 (the "Conversion Date") in

    E-Print Network [OSTI]

    Portman, Douglas

    on November 6, 2003 as auction rate securities and are subject to mandatory tender for purchase Fund and any Bond Purchase Fund) established under the Authority's University of Rochester Revenue Bond has no taxing power. Description: The Series 2003B Bonds will be reoffered on their Conversion Date

  8. New Issue: Moody's assigns Aa1 ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nov 2014 Approximately 200 million of debt affected BONNEVILLE POWER ADMINISTRATION, OR Electric Generation OR Moody's Rating ISSUE RATING Transmission Facilities Revenue Bonds...

  9. New Issue: Moody's assigns Aa1 ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    billion of debt securities affected BONNEVILLE POWER ADMINISTRATION, OR Electric Generation OR Moody's Rating ISSUE RATING Project 1 Electric Revenue Refunding Bonds, Series...

  10. 10/2/2014 AA Advertising Information http://uwpress.wisc.edu/journals/journals/aa_ads.html 1/2

    E-Print Network [OSTI]

    Sprott, Julien Clinton

    10/2/2014 AA Advertising Information http://uwpress.wisc.edu/journals/journals/aa_ads.html 1 Arctic Anthropology Advertising Rates and Deadlines (Click here to download a pdf of this page) Print Ad Rates Cost Width Height Full page (B&W) $510 7" 91/2" Half page (B&W) $410 7" 43/4" Online Ad Rates

  11. Combined valence bond-molecular mechanics potential-energy surface and direct dynamics study of rate constants and kinetic isotope

    E-Print Network [OSTI]

    Truhlar, Donald G

    Combined valence bond-molecular mechanics potential-energy surface and direct dynamics study of the MPW54 potential-energy surface are then used to parametrize a new kind of analytical potential-energy of molecular mechanics to treat a reactive potential-energy surface or a new kind of combined quantum

  12. An Investigation of Enhanced Formability in AA5182-O Al During High-Rate Fre-Forming at Room-Temperature: Quantification of Deformation History

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Soulami, Ayoub; Stephens, Elizabeth V.; Davies, Richard W.; Smith, Mark T.

    2014-03-01

    Following the two prior publication of PNNL Pulse-Pressure research in the Journal of Materials Processing Technology, this manuscript continues to describe PNNL’s advances in getting a better understanding of sheet metal formability under high strain-rate conditions. Specifically, using a combination of numerical modeling and novel experiments, we quantitatively demonstrate the deformation history associated with enhanced formability (~2.5X) in Al under room temperature forming.

  13. RATES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and PACI Final FRN for Rate Order No. WAPA-139 - Notice of Order Temporarily Extending Formula Rates for Power, Transmission and Ancillary Services (PDF - 49K) Final FRN for Rate...

  14. RATES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - 392K) Final FRN for Rate Order No. WAPA-139 - Notice of Order Temporarily Extending Formula Rates for Power, Transmission and Ancillary Services (PDF - 49K) Final FRN for Rate...

  15. RATES

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Washoe Project, Stampede Division FERC Order Approving Extension of Non-Firm Power Formula Rate - Rate Order No. WAPA-160 (Sept. 5, 2013) (PDF - 22K) Notice of Extension of...

  16. Surface Modification by Atmospheric Pressure Plasma for Improved Bonding

    E-Print Network [OSTI]

    Williams, Thomas Scott

    2013-01-01

    of hydrogen- bonded hydroxyl groups. Acknowledgements Thisonto the exposed surface hydroxyl groups. The rate offraction of hydrogen-bonded hydroxyl groups increased from

  17. Qualifying Energy Conservation Bonds 

    E-Print Network [OSTI]

    Briggs, J.

    2013-01-01

    Bonds (QECB’s) CATEE Conference December 18, 2013 ESL-KT-13-12-39 CATEE 2013: Clean Air Through Energy Efficiency Conference, San Antonio, Texas Dec. 16-18 • Originally authorized by the Energy Improvement & Extension Act of 2008 • American Recovery... ) of the interest cost associated with the transaction • Typical effective interest rates anywhere from 0%-2% depending on credit strength • Bond issuance or private placement is acceptable 2 What are QECB’s ESL-KT-13-12-39 CATEE 2013: Clean Air Through Energy...

  18. BUILDING NAMES AA Architecture Building

    E-Print Network [OSTI]

    Dawson, Jeff W.

    P18$ P16 BUILDING NAMES AA Architecture Building AC Recreation and Athletics Centre AH Alumni Hall AP Azrieli Pavillion AT Azrieli Theatre CB Canal Building CO Residence Commons DT Dunton Tower FH Interaction Building (HCI) HP Herzberg Laboratories IH Ice House LA Loeb Building LE Leeds House LH Lanark

  19. AA Architecture Building AC Athletics

    E-Print Network [OSTI]

    Kranakis, Evangelos

    $ AA Architecture Building AC Athletics AH Alumni Hall AP Azrieli Pavilion AT Azrieli Theatre CB Canal Building CC Colonel By Child Care Centre CO Residence Commons (Fenn Lounge) DH Dundas House DT Dunton Tower Interaction Building HP Herzberg Laboratories IH Ice House LA Loeb Building LE Leeds House LH Lanark House LS

  20. Investing in Bonds 

    E-Print Network [OSTI]

    Johnson, Jason; Polk, Wade

    2002-08-12

    bonds Corporate bonds are generally the riskiest of all fixed-income securities because companies? even large, stable ones?are much more susceptible than govern- ments to economic problems, mis- management and competition. However, corporate bonds can...

  1. AA...

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VANaval Ordnance,:n5.5.8GE 1A L L Uit

  2. Multilayer roll bonded aluminium foil: processing, microstructure and flow stress

    SciTech Connect (OSTI)

    Barlow, C.Y.; Nielsen, P.; Hansen, N

    2004-08-02

    Bulk aluminium has been produced by warm-rolling followed by cold-rolling of commercial purity (99% purity) aluminium foil. The bonding appeared perfect from observation with the naked eye, light and transmission electron microscopy. By comparison with bulk aluminium of similar purity (AA1200) rolled to a similar strain (90%RA), the roll-bonded metal showed a much higher density of high-angle grain boundaries, similar strength and improved thermal stability. This study has implications for a number of applications in relation to the processing of aluminium. Roll bonding is of interest as a method for grain size refinement; oxide-containing materials have increased strength, enhanced work-hardening behaviour, and exhibit alterations in recrystallisation behaviour. The behaviour of the hard oxide film is of interest in aluminium processing, and has been investigated by characterising the size and distribution of oxide particles in the roll-bonded samples.

  3. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of...

  4. Essays on corporate bonds

    E-Print Network [OSTI]

    Bao, Jack (Jack C.)

    2009-01-01

    This thesis consists of three empirical essays on corporate bonds, examining the role of both credit risk and liquidity. In the first chapter, I test the ability of structural models of default to price corporate bonds in ...

  5. Bonding thermoplastic polymers

    DOE Patents [OSTI]

    Wallow, Thomas I. (Fremont, CA); Hunter, Marion C. (Livermore, CA); Krafcik, Karen Lee (Livermore, CA); Morales, Alfredo M. (Livermore, CA); Simmons, Blake A. (San Francisco, CA); Domeier, Linda A. (Danville, CA)

    2008-06-24

    We demonstrate a new method for joining patterned thermoplastic parts into layered structures. The method takes advantage of case-II permeant diffusion to generate dimensionally controlled, activated bonding layers at the surfaces being joined. It is capable of producing bonds characterized by cohesive failure while preserving the fidelity of patterned features in the bonding surfaces. This approach is uniquely suited to production of microfluidic multilayer structures, as it allows the bond-forming interface between plastic parts to be precisely manipulated at micrometer length scales. The bond enhancing procedure is easily integrated in standard process flows and requires no specialized equipment.

  6. Bonded semiconductor substrate

    DOE Patents [OSTI]

    Atwater, Jr.; Harry A. (South Pasadena, CA), Zahler; James M. (Pasadena, CA)

    2010-07-13

    Ge/Si and other nonsilicon film heterostructures are formed by hydrogen-induced exfoliation of the Ge film which is wafer bonded to a cheaper substrate, such as Si. A thin, single-crystal layer of Ge is transferred to Si substrate. The bond at the interface of the Ge/Si heterostructures is covalent to ensure good thermal contact, mechanical strength, and to enable the formation of an ohmic contact between the Si substrate and Ge layers. To accomplish this type of bond, hydrophobic wafer bonding is used, because as the invention demonstrates the hydrogen-surface-terminating species that facilitate van der Waals bonding evolves at temperatures above 600.degree. C. into covalent bonding in hydrophobically bound Ge/Si layer transferred systems.

  7. Computational Investigation of Hardness Evolution During Friction-Stir Welding of AA5083 and AA2139

    E-Print Network [OSTI]

    Grujicic, Mica

    Computational Investigation of Hardness Evolution During Friction-Stir Welding of AA5083 and AA2139 coupled thermo-mechanical finite-element analysis of the friction-stir welding (FSW) process developed, finite-element analysis, friction- stir welding, hardness prediction 1. Introduction Having a more mobile

  8. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Chaplin, Martin

    2007-01-01

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperature...

  9. Low Temperature Material Bonding Technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2000-10-10

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  10. Low temperature material bonding technique

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-02-12

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  11. Qualified Energy Conservation Bonds

    Broader source: Energy.gov [DOE]

    Provides an in-depth description of qualified energy conservation bonds, including process and mechanics, case studies, utilization trends, barriers, and regulatory and legal issues. Author: Energy Programs Consortium

  12. Characterization of anodic bonding

    E-Print Network [OSTI]

    Tudryn, Carissa Debra, 1978-

    2004-01-01

    Anodic bonding is a common process used in MicroElectroMechanical Systems (MEMS) device fabrication and packaging. Polycrystalline chemical vapor deposited (CVD) silicon carbide (SiC) is emerging as a new MEMS device and ...

  13. Bonding aerogels with polyurethanes

    SciTech Connect (OSTI)

    Matthews, F.M.; Hoffman, D.M.

    1989-11-01

    Aerogels, porous silica glasses with ultra-fine cell size (30nm), are made by a solution gelation (sol-gel) process. The resulting gel is critical point dried to densities from 0.15--0.60 g/cc. This material is machinable, homogeneous, transparent, coatable and bondable. To bond aerogel an adhesive should have long cure time, no attack on the aerogel structure, and high strength. Several epoxies and urethanes were examined to determine if they satisfied these conditions. Bond strengths above 13 psi were found with double bubble and DP-110 epoxies and XI-208/ODA-1000 and Castall U-2630 urethanes. Hardman Kalex Tough Stuff'' A-85 hardness urethane gave 18 psi bond strength. Hardman A-85, Tuff-Stuff'' was selected for further evaluation because it produced bond strengths comparable to the adherend cohesive strength. 5 refs., 2 figs.

  14. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  15. AAS-DDA, Philadelphia April 28-May 1 2014

    E-Print Network [OSTI]

    Malhotra, Renu

    AAS-DDA, Philadelphia April 28-May 1 2014 A few points on the dynamical evolution of the young solar system Renu Malhotra The University of Arizona #12;AAS-DDA, Philadelphia April 28-May 1 2014 A few - planetesimal-driven migration Renu Malhotra The University of Arizona #12;AAS-DDA, Philadelphia April 28-May 1

  16. Program termination discussed by BOT AA

    E-Print Network [OSTI]

    Almor, Amit

    Program termination discussed by BOT AA and BOT Full (termination of concentrations does Education (CHE) Approval Process Timeline Program Terminations 2014-2015 NOTE: These dates reflect the shortest amount of time it takes to process a program termination through the approval cycle

  17. Reti di Calcolatori AA 2011/2012

    E-Print Network [OSTI]

    Lo Cigno, Renato Antonio

    Reti di Calcolatori AA 2011/2012 http://disi.unitn.it/locigno/index.php/teaching locigno@disi.unitn.it 3 #12;1 - Fisico Livello Rete Livelli di applicazione (utente) Livelli di rete2 - Collegamento dati Fisico 3 - Rete 4 - Trasporto 5 - Sessione 6 - Presentazione 7 - Applicazione Collegamento

  18. Reti di Calcolatori AA 2013/2014

    E-Print Network [OSTI]

    Lo Cigno, Renato Antonio

    Reti di Calcolatori AA 2013/2014 http://disi.unitn.it/locigno/index.php/teaching / esercitazione n Informazioni varie, contatti, la bacheca del corso, le date di esame, ... #12;locigno rete (IP) n Livello Data Link (Ethernet) n Livello Fisico (mezzi trasmissivi e trasmissione di segnali

  19. Reti di Calcolatori AA 2012/2013

    E-Print Network [OSTI]

    Lo Cigno, Renato Antonio

    1 Reti di Calcolatori AA 2012/2013 http://disi.unitn.it/locigno/index.php/teaching Informazioni varie, contatti, la bacheca del corso, le date di esame, ... #12;2 locigno@disi.unitn.it 4 (IP) n Livello Data Link (Ethernet) n Livello Fisico (mezzi trasmissivi e trasmissione di segnali

  20. Reti di Calcolatori AA 2011/2012

    E-Print Network [OSTI]

    Lo Cigno, Renato Antonio

    1 Reti di Calcolatori AA 2011/2012 http://disi.unitn.it/locigno/index.php/teaching Consegna dei pacchetti Instradamento e Routing locigno@disi.unitn.it 3 #12;2 1 - Fisico Livello Rete Livelli di applicazione (utente) Livelli di rete2 - Collegamento dati Fisico 3 - Rete 4 - Trasporto 5

  1. Reti di Calcolatori AA 2010/2011

    E-Print Network [OSTI]

    Lo Cigno, Renato Antonio

    Reti di Calcolatori AA 2010/2011 http://disi.unitn.it/locigno/index.php/teaching dettaglio delle lezioni svolte Lucidi Giorni di lezione / esercitazione Informazioni varie, contatti, la) Livello Fisico (mezzi trasmissivi e trasmissione di segnali digitali e analogici) #12;locigno

  2. Photochemical tissue bonding

    DOE Patents [OSTI]

    Redmond, Robert W. (Brookline, MA); Kochevar, Irene E. (Charlestown, MA)

    2012-01-10

    Photochemical tissue bonding methods include the application of a photosensitizer to a tissue and/or tissue graft, followed by irradiation with electromagnetic energy to produce a tissue seal. The methods are useful for tissue adhesion, such as in wound closure, tissue grafting, skin grafting, musculoskeletal tissue repair, ligament or tendon repair and corneal repair.

  3. Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

  4. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2003-08-01

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that ...

  5. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2004-11-30

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that stock market prices are correlated ...

  6. Pauling bond strength, bond length and electron density distribution

    SciTech Connect (OSTI)

    Gibbs, Gerald V.; Ross, Nancy L.; Cox, David F.; Rosso, Kevin M.; Iversen, Bo B.; Spackman, M. A.

    2014-01-18

    A power law regression equation, = 1.46(/r)-0.19, connecting the average experimental bond lengths, , with the average accumulation of the electron density at the bond critical point, , between bonded metal M and oxygen atoms, determined at ambient conditions for oxide crystals, where r is the row number of the M atom, is similar to the regression equation R(M-O) = 1.39(?(rc)/r)-0.21 determined for three perovskite crystals for pressures as high as 80 GPa. The two equations are also comparable with those, = 1.43(/r)-0.21, determined for a large number of oxide crystals at ambient conditions and = 1.39(/r)-0.22, determined for geometry optimized hydroxyacid molecules, that connect the bond lengths to the average Pauling electrostatic bond strength, , for the M-O bonded interactions. On the basis of the correspondence between the two sets of equations connecting ?(rc) and the Pauling bond strength s with bond length, it appears that Pauling’s simple definition of bond strength closely mimics the accumulation of the electron density between bonded pairs of atoms. The similarity of the expressions for the crystals and molecules is compelling evidence that the M-O bonded interactions for the crystals and molecules 2 containing the same bonded interactions are comparable. Similar expressions, connecting bond lengths and bond strength, have also been found to hold for fluoride, nitride and sulfide molecules and crystals. The Brown-Shannon bond valence, ?, power law expression ? = [R1/(R(M-O)]N that has found wide use in crystal chemistry, is shown to be connected to a more universal expression determined for oxides and the perovskites, = r[(1.41)/]4.76, demonstrating that the bond valence for a bonded interaction is likewise closely connected to the accumulation of the electron density between the bonded atoms. Unlike the Brown-Shannon expression, it is universal in that it holds for the M-O bonded interactions for a relatively wide range of M atoms of the periodic table. The power law equation determined for the oxide crystals at ambient conditions is similar to the power law expression = r[1.46/]5.26 determined for the perovskites at pressures as high as 80 GPa, indicating that the intrinsic connection between R(M-O) and ?(rc) that holds at ambient conditions also holds, to a first approximation, at high pressures.

  7. New Issue: Moody's assigns Aa1 ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    securities affected BONNEVILLE POWER ADMINISTRATION, OR Electric Distribution and Generation OR Moody's Rating ISSUE RATING Columbia Generating Station Electric Revenue...

  8. Low temperature reactive bonding

    DOE Patents [OSTI]

    Makowiecki, D.M.; Bionta, R.M.

    1995-01-17

    The joining technique is disclosed that requires no external heat source and generates very little heat during joining. It involves the reaction of thin multilayered films deposited on faying surfaces to create a stable compound that functions as an intermediate or braze material in order to create a high strength bond. While high temperatures are reached in the reaction of the multilayer film, very little heat is generated because the films are very thin. It is essentially a room temperature joining process. 5 figures.

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.WeekProducts >TransportationEHSSTrending: Metal Oxo Bonds

  10. Transfer Guide for Major AAS in Early Childhood Education at Clackamas Community College

    E-Print Network [OSTI]

    Caughman, John

    Table A Transfer Guide for Major AAS in Early Childhood Education at Clackamas Community College #12;Early Childhood Education Specialization: Required for CFS major: Completed in AAS* Left Transfer Guide - AAS Early Childhood Education Edit: 12-08-09 #12;

  11. a.a. 2014/2015 1 Studiare alla Facolt

    E-Print Network [OSTI]

    Di Pillo, Gianni

    a.a. 2014/2015 1 Studiare alla Facoltŕ Ingegneria dell'informazione, Informatica e Statistica #12;Facoltŕ di Ingegneria dell'Informazione, Informatica e Statistica 2 a.a. 2014/2015 3 Facoltŕ di Ingegneria dell'informazione, Informatica e Statistica La Facoltŕ di Ingegneria dell'Informazione, Informatica e

  12. Roadmap: Radiologic Imaging Sciences -Nuclear Medicine (with AAS Radiologic Technology) -

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Radiologic Imaging Sciences - Nuclear Medicine (with AAS Radiologic Technology) - Bachelor Safety 3 C #12;Roadmap: Radiologic Imaging Sciences - Nuclear Medicine (with AAS Radiologic Technology of Radiologic and Imaging Sciences Technology [RE-BRIT-RIS-NMRT] Regional College Catalog Year: 2013-2014 Page 1

  13. Roadmap: Radiologic Imaging Sciences -Nuclear Medicine (with AAS Radiologic Technology) -

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Radiologic Imaging Sciences - Nuclear Medicine (with AAS Radiologic Technology) - Bachelor Imaging Sciences - Nuclear Medicine (with AAS Radiologic Technology) - Bachelor of Radiologic and Imaging of Radiologic and Imaging Sciences Technology [RE-BRIT-RIS-NMRT] Regional College Catalog Year: 2012-2013 Page 1

  14. Better Bonded Ethernet Load Balancing

    SciTech Connect (OSTI)

    Gabler, Jason

    2006-09-29

    When a High Performance Storage System's mover shuttles large amounts of data to storage over a single Ethernet device that single channel can rapidly become saturated. Using Linux Ethernet channel bonding to address this and similar situations was not, until now, a viable solution. The various modes in which channel bonding could be configured always offered some benefit but only under strict conditions or at a system resource cost that was greater than the benefit gained by using channel bonding. Newer bonding modes designed by various networking hardware companies, helpful in such networking scenarios, were already present in their own switches. However, Linux-based systems were unable to take advantage of those new modes as they had not yet been implemented in the Linux kernel bonding driver. So, except for basic fault tolerance, Linux channel bonding could not positively combine separate Ethernet devices to provide the necessary bandwidth.

  15. Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury, Junrong Zheng, and M. D. Fayer*

    E-Print Network [OSTI]

    Fayer, Michael D.

    Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Tobias Steinel, John B. Asbury of picoseconds, observe hydrogen bond breaking and monitor the equilibration of the hydrogen bond network in water. In addition, the vibrational lifetime, the time constant for hydrogen bond breaking, and the rate

  16. Quantum Confinement in Hydrogen Bond

    E-Print Network [OSTI]

    Carlos da Silva dos Santos; Elso Drigo Filho; Regina Maria Ricotta

    2015-02-09

    In this work, the quantum confinement effect is proposed as the cause of the displacement of the vibrational spectrum of molecular groups that involve hydrogen bonds. In this approach the hydrogen bond imposes a space barrier to hydrogen and constrains its oscillatory motion. We studied the vibrational transitions through the Morse potential, for the NH and OH molecular groups inside macromolecules in situation of confinement (when hydrogen bonding is formed) and non-confinement (when there is no hydrogen bonding). The energies were obtained through the variational method with the trial wave functions obtained from Supersymmetric Quantum Mechanics (SQM) formalism. The results indicate that it is possible to distinguish the emission peaks related to the existence of the hydrogen bonds. These analytical results were satisfactorily compared with experimental results obtained from infrared spectroscopy.

  17. The A&A Experience With Impact Factors

    E-Print Network [OSTI]

    Aa. Sandqvist

    2004-03-08

    There is a widespread impression that the scientific journal "Astronomy & Astrophysics" (A&A) has a smaller impact, as measured by citations to articles, than some of the other major astronomy journals. This impression was apparently supported - and probably created - by the Journal Citation Report (JCR), which is prepared annually by the Institute of Scientific Information (ISI) Web of Knowledge. The published poor impact factor of A&A was in fact wrong and was due to a serious flaw in the method used by ISI Web of Knowledge to determine it. The resulting damage inflicted upon A&A by the JCR is incalculable.

  18. Finance & Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview FY 2010 Financial Overview FY 2009 Financial Overview Budget Submission to Congress Debt Management Power Prepayment Program Lease Financing Program Bond Information...

  19. Physical Nature of Hydrogen Bond

    E-Print Network [OSTI]

    Zhyganiuk, I V

    2015-01-01

    The physical nature and the correct definition of hydrogen bond (H-bond) are considered.\\,\\,The influence of H-bonds on the thermodynamic, kinetic, and spectroscopic properties of water is analyzed.\\,\\,The conventional model of H-bonds as sharply directed and saturated bridges between water molecules is incompatible with the behavior of the specific volume, evaporation heat, and self-diffusion and kinematic shear viscosity coefficients of water. On the other hand, it is shown that the variation of the dipole moment of a water molecule and the frequency shift of valence vibrations of a hydroxyl group can be totally explained in the framework of the electrostatic model of H-bond.\\,\\,At the same time, the temperature dependences of the heat capacity of water in the liquid and vapor states clearly testify to the existence of weak H-bonds.\\,\\,The analysis of a water dimer shows that the contribution of weak H-bonds to its ground state energy is approximately 4--5 times lower in comparison with the energy of electr...

  20. Roadmap: Enology -Associate of Applied Science [RE-AAS-ENOL

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Enology - Associate of Applied Science [RE-AAS-ENOL] Regional College Catalog Year: 2013-2014 Page 1 of 1 | Last Updated: 11-Apr-13/LNHD This roadmap is a recommended semester-by-semester plan

  1. Roadmap: Enology -Associate of Applied Science [RE-AAS-ENOL

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Enology - Associate of Applied Science [RE-AAS-ENOL] Regional College Catalog Year: 2012-2013 Page 1 of 1 | Last Updated: 9-Mar-12/LNHD This roadmap is a recommended semester-by-semester plan

  2. Roadmap: Viticulture -Associate of Applied Science [RE-AAS-VITI

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Viticulture - Associate of Applied Science [RE-AAS-VITI] Regional College Catalog Year: 2012-2013 Page 1 of 1 | Last Updated: 12-Mar-12/LNHD This roadmap is a recommended semester

  3. Roadmap: Viticulture -Associate of Applied Science [RE-AAS-VITI

    E-Print Network [OSTI]

    Sheridan, Scott

    Roadmap: Viticulture - Associate of Applied Science [RE-AAS-VITI] Regional College Catalog Year: 2013-2014 Page 1 of 1 | Last Updated: 11-Apr-13/LNHD This roadmap is a recommended semester

  4. 18-1165-29AA selectingHollow Fiber

    E-Print Network [OSTI]

    Lebendiker, Mario

    18-1165-29AA selectingHollow Fiber Cartridges and Systems #12;#12;introduction About this guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 chapter 1 - Selecting a hollow fiber cross flow membrane cartridge Introduction . . . . . . . . . . . . . 12 Cartridge selection illustrated with process examples

  5. Fusion bonding and alignment fixture

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2000-01-01

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all the components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  6. Method for vacuum fusion bonding

    DOE Patents [OSTI]

    Ackler, Harold D. (Sunnyvale, CA); Swierkowski, Stefan P. (Livermore, CA); Tarte, Lisa A. (Livermore, CA); Hicks, Randall K. (Stockton, CA)

    2001-01-01

    An improved vacuum fusion bonding structure and process for aligned bonding of large area glass plates, patterned with microchannels and access holes and slots, for elevated glass fusion temperatures. Vacuum pumpout of all components is through the bottom platform which yields an untouched, defect free top surface which greatly improves optical access through this smooth surface. Also, a completely non-adherent interlayer, such as graphite, with alignment and location features is located between the main steel platform and the glass plate pair, which makes large improvements in quality, yield, and ease of use, and enables aligned bonding of very large glass structures.

  7. Method of bonding

    DOE Patents [OSTI]

    Saller, deceased, Henry A. (late of Columbus, OH); Hodge, Edwin S. (Columbus, OH); Paprocki, Stanley J. (Columbus, OH); Dayton, Russell W. (Columbus, OH)

    1987-12-01

    1. A method of making a fuel-containing structure for nuclear reactors, comprising providing an assembly comprising a plurality of fuel units; each fuel unit consisting of a core plate containing thermal-neutron-fissionable material, sheets of cladding metal on its bottom and top surfaces, said cladding sheets being of greater width and length than said core plates whereby recesses are formed at the ends and sides of said core plate, and end pieces and first side pieces of cladding metal of the same thickness as the core plate positioned in said recesses, the assembly further comprising a plurality of second side pieces of cladding metal engaging the cladding sheets so as to space the fuel units from one another, and a plurality of filler plates of an acid-dissolvable nonresilient material whose melting point is above 2000.degree. F., each filler plate being arranged between a pair of said second side pieces and the cladding plates of two adjacent fuel units, the filler plates having the same thickness as the second side pieces; the method further comprising enclosing the entire assembly in an envelope; evacuating the interior of the entire assembly through said envelope; applying inert gas under a pressure of about 10,000 psi to the outside of said envelope while at the same time heating the assembly to a temperature above the flow point of the cladding metal but below the melting point of any material of the assembly, whereby the envelope is pressed against the assembly and integral bonds are formed between plates, sheets, first side pieces, and end pieces and between the sheets and the second side pieces; slowly cooling the assembly to room temperature; removing the envelope; and dissolving the filler plates without attacking the cladding metal.

  8. Low Temperature Material Bonding Techniq Ue

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Foote, Robert S. (Oak Ridge, TN)

    2002-08-06

    A method of performing a lower temperature bonding technique to bond together two mating pieces of glass includes applying a sodium silicate aqueous solution between the two pieces.

  9. Hydrogen Bond Shaping of Membrane Protein Structure

    E-Print Network [OSTI]

    Cao, Zheng

    2013-01-01

    2 1.3. HYDROGEN BOND STRENGTHAND EQUILIBRIUM HYDROGEN / DEUTERIUM FRACTIONATION4 1.4. MEASUING HYDROGEN BOND STRENGTH IN A MEMBRANE PROTEIN

  10. Sandia Energy - Diffusion Bonding Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bond surface is poor or only the region near this corner. Diffusion 7-8-9 "Diffusion Welding and Brazing," in Welding Handbook, 7th ed., American Welding Society, 1980, p 311-335...

  11. Deflagration Rates and Molecular Bonding Trends of Statically...

    Office of Scientific and Technical Information (OSTI)

    of increasingly more rapid combustion reactions. Authors: Zaug, J M ; Foltz, M F ; Hart, E Publication Date: 2010-03-09 OSTI Identifier: 978415 Report Number(s):...

  12. Deflagration Rates and Molecular Bonding Trends of Statically Compressed

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing BacteriaConnect CollidertransferMetal/Radionuclide-reducingStudiesIdahoSecondary

  13. Deflagration Rates and Molecular Bonding Trends of Statically Compressed

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing BacteriaConnect

  14. Transient liquid phase ceramic bonding

    DOE Patents [OSTI]

    Glaeser, Andreas M. (Berkeley, CA)

    1994-01-01

    Ceramics are joined to themselves or to metals using a transient liquid phase method employing three layers, one of which is a refractory metal, ceramic or alloy. The refractory layer is placed between two metal layers, each of which has a lower melting point than the refractory layer. The three layers are pressed between the two articles to be bonded to form an assembly. The assembly is heated to a bonding temperature at which the refractory layer remains solid, but the two metal layers melt to form a liquid. The refractory layer reacts with the surrounding liquid and a single solid bonding layer is eventually formed. The layers may be designed to react completely with each other and form refractory intermetallic bonding layers. Impurities incorporated into the refractory metal may react with the metal layers to form refractory compounds. Another method for joining ceramic articles employs a ceramic interlayer sandwiched between two metal layers. In alternative embodiments, the metal layers may include sublayers. A method is also provided for joining two ceramic articles using a single interlayer. An alternate bonding method provides a refractory-metal oxide interlayer placed adjacent to a strong oxide former. Aluminum or aluminum alloys are joined together using metal interlayers.

  15. aa-tRNA competition is crucial for the effective translation efficiency

    E-Print Network [OSTI]

    Wenjun Xia; Jinzhi Lei

    2015-03-31

    Translation is a central biological process by which proteins are synthesized from genetic information contained within mRNAs. Here we study the kinetics of translation at molecular level through a stochastic simulation model. The model explicitly include RNA sequences, ribosome dynamics, tRNA pool and biochemical reactions in the translation elongation. The results show that the translation efficiency is mainly limited by the available ribosome number, translation initiation and the translation elongation time. The elongation time is log-normal distribution with mean and variance determined by both the codon saturation and the process of aa-tRNA selection at each codon binding. Moreover, our simulations show that the translation accuracy exponentially decreases with the sequence length. These results suggest that aa-tRNA competition is crucial for both translation elongation, translation efficiency and the accuracy, which in turn determined the effective protein production rate of correct proteins. Our results improve the dynamical equation of protein production with a delay differential equation which is dependent on sequence informations through both the effective production rate and the distribution of elongation time.

  16. Bond percolation on multiplex networks

    E-Print Network [OSTI]

    Hackett, A; Gómez, S; Arenas, A; Gleeson, J P

    2015-01-01

    We present an analytical approach for bond percolation on multiplex networks and use it to determine the expected size of the giant connected component and the value of the critical bond occupation probability in these networks. We advocate the relevance of these tools to the modeling of multilayer robustness and contribute to the debate on whether any benefit is to be yielded from studying a full multiplex structure as opposed to its monoplex projection, especially in the seemingly irrelevant case of a bond occupation probability that does not depend on the layer. Although we find that in many cases the predictions of our theory for multiplex networks coincide with previously derived results for monoplex networks, we also uncover the remarkable result that for a certain class of multiplex networks, well described by our theory, new critical phenomena occur as multiple percolation phase transitions are present. We provide an instance of this phenomenon in a multipex network constructed from London rail and Eu...

  17. A Hidden Markov Chain Model for the Term Structure of Bond Credit Risk Spreads 

    E-Print Network [OSTI]

    Thomas, L; Allen, David E; Morkel-Kingsbury, N

    1998-01-01

    This paper provides a Markov chain model for the term structure and credit risk spreads of bond processes. It allows dependency between the stochastic process modeling the interest rate and the Markov chain process describing ...

  18. Stress and Fracture Analysis of a Class of Bonded Joints in Wind Turbine Blades 

    E-Print Network [OSTI]

    Chen, Chang

    2013-05-08

    A simplified model is proposed to investigate the stress fields and the strain energy release rate (SERR) associated with cracks in bonded joints in wind turbine blades. The proposed two-dimensional model consists of nonparallel upper and lower...

  19. Bond Underwriter Costs: Texas School Districts and the Hidden Cost of Issuing Bonds 

    E-Print Network [OSTI]

    Stasny, Mary Knetsar

    2011-02-22

    The purpose of this study was to investigate possible relationships between school district characteristics and bond underwriter costs for Texas independent school districts. Bond data for all school districts issuing bonds in the five-year period...

  20. Non-bonded ultrasonic transducer

    DOE Patents [OSTI]

    Eoff, J.M.

    1984-07-06

    A mechanically assembled non-bonded ultrasonic transducer includes a substrate, a piezoelectric film, a wetting agent, a thin metal electrode, and a lens held in intimate contact by a mechanical clamp. No epoxy or glue is used in the assembly of this device.

  1. Enhanced rigid-bond restraints

    SciTech Connect (OSTI)

    Thorn, Andrea; Dittrich, Birger; Sheldrick, George M., E-mail: gsheldr@shelx.uni-ac.gwdg.de [Department of Structural Chemistry, University of Göttingen, Tammannstrasse 4, D-37077 Göttingen (Germany)

    2012-07-01

    An extension is proposed to the rigid-bond description of atomic thermal motion in crystals. The rigid-bond model [Hirshfeld (1976 ?). Acta Cryst. A32, 239–244] states that the mean-square displacements of two atoms are equal in the direction of the bond joining them. This criterion is widely used for verification (as intended by Hirshfeld) and also as a restraint in structure refinement as suggested by Rollett [Crystallographic Computing (1970 ?), edited by F. R. Ahmed et al., pp. 167–181. Copenhagen: Munksgaard]. By reformulating this condition, so that the relative motion of the two atoms is required to be perpendicular to the bond, the number of restraints that can be applied per anisotropic atom is increased from about one to about three. Application of this condition to 1,3-distances in addition to the 1,2-distances means that on average just over six restraints can be applied to the six anisotropic displacement parameters of each atom. This concept is tested against very high resolution data of a small peptide and employed as a restraint for protein refinement at more modest resolution (e.g. 1.7 Ĺ)

  2. Bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2010-06-08

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  3. Advising Guide for Early Childhood Education A.A.S. Articulation Agreement

    E-Print Network [OSTI]

    Advising Guide for Early Childhood Education A.A.S. Articulation Agreement Transferring to Portland State University (PSU) with the A.A.S. in Early Childhood Education from Clackamas Community College According to this articulation agreement, students completing the Early Childhood Education A.A.S. at CCC

  4. Introduction to k'yu ts'udalaas aa

    E-Print Network [OSTI]

    'udalaas aa Wood: cháan is ii Shell Gill Siphon & Pallets WoodCaecum Margo Haygood adapted from Ruth TurnerValve Gill Siphon Anus #12;Where do shipworms live? · Shipworms have been found in every ocean of the world, but also feed on plankton that they suck in through their siphons. 4 #12;Shipworm Anatomy Siphons extend

  5. Perceiving light versus material Frederick A.A. Kingdom

    E-Print Network [OSTI]

    Kingdom, Frederick A. A.

    Perceiving light versus material Frederick A.A. Kingdom McGill Vision Research, 687 Pine Av. W. Rm s t r a c t Humans rarely confuse variations in light intensity, such as shadows, shading, light sources to discriminate light from material. These cues include luminance relations, figural relations, 3D-shape, depth

  6. Social Science AA, 2015-2016 Name ID# Date

    E-Print Network [OSTI]

    Barrash, Warren

    Social Science AA, 2015-2016 Name ID# Date Course Number and Title Credits Completed In, & Applied Sciences course with lab 4 DLN Natural, Physical, and Applied Sciences course 3-4 DLV Visual and Performing Arts 3 DLL Literature and Humanities 3-4 DLS COMM 101 or COMM 112 3 DLS Social Sciences course

  7. Hydrogen Bond Shaping of Membrane Protein Structure

    E-Print Network [OSTI]

    Cao, Zheng

    2013-01-01

    Energy of Amide Hydrogen Bond Formation in Vacuum, in Water, andEnergy of Amide Hydrogen Bond Formation in Vacuum, in Water, andto water is dependent on the zero-point energies, i.e. the

  8. The Market for Borrowing Corporate Bonds

    E-Print Network [OSTI]

    Asquith, Paul

    This paper describes the market for borrowing corporate bonds using a comprehensive data set from a major lender. The cost of borrowing corporate bonds is comparable to the cost of borrowing stock, between 10 and 20 basis ...

  9. APPLIED PHYSICS REVIEWSFOCUSED REVIEW Adhesive wafer bonding

    E-Print Network [OSTI]

    Lü, James Jian-Qiang

    APPLIED PHYSICS REVIEWS­FOCUSED REVIEW Adhesive wafer bonding F. Niklausa Microsystem Technology 9 February 2006 Wafer bonding with intermediate polymer adhesives is an important fabrication-dimensional integrated circuits, advanced packaging, and microfluidics. In adhesive wafer bonding, the polymer adhesive

  10. Clean Energy and Bond Finance Initiative

    Broader source: Energy.gov [DOE]

    Provides information on Clean Energy and Bond Finance Initiative (CE+BFI). CE+BFI brings together public infrastructure finance agencies, clean energy public fund managers and institutional investors across the country to explore how to raise capital at scale for clean energy development through bond financing. Author: Clean Energy and Bond Finance Initiative

  11. Current Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in ActinideRail betweenProtectionCurrentJobPower-Rates

  12. Bonding, antibonding and tunable optical forces in asymmetric membranes

    E-Print Network [OSTI]

    Hui, Pui-Chuen

    We demonstrate that tunable attractive (bonding) and repulsive (anti-bonding) forces can arise in highly asymmetric structures coupled to external radiation, a consequence of the bonding/anti-bonding level repulsion of ...

  13. Fragmentation and depolymerization of non-covalently bonded filaments

    E-Print Network [OSTI]

    A. Zaccone; I. Terentjev; L. DiMichele; E. M. Terentjev

    2015-03-22

    Protein molecules often self-assemble by means of non-covalent physical bonds to form extended filaments, such as amyloids, F-actin, intermediate filaments, and many others. The kinetics of filament growth is limited by the disassembly rate, at which inter-protein bonds break due to the thermal motion. Existing models often assume that the thermal dissociation of subunits occurs uniformly along the filament, or even preferentially in the middle, while the well-known propensity of F-actin to depolymerize from one end is mediated by biochemical factors. Here, we show for a very general (and generic) model, using Brownian dynamics simulations and theory, that the breakup location along the filament is strongly controlled by the asymmetry of the binding force about the minimum, as well as by the bending stiffness of the filament. We provide the basic connection between the features of the interaction potential between subunits and the breakup topology. With central-force (that is, fully flexible) bonds, the breakup rate is always maximum in the middle of the chain, whereas for semiflexible or stiff filaments this rate is either a minimum in the middle or flat. The emerging framework provides a unifying understanding of biopolymer fragmentation and depolymerization and recovers earlier results in its different limits.

  14. Interface Evolution of Au-Au Thermocompression Bonding and Nanotwins

    E-Print Network [OSTI]

    Beekley, Brett

    2015-01-01

    bonds. Journal of Microelectromechanical Systems, 2004. 13(bonds. Journal of Microelectromechanical Systems, 2002. 11(packaging. Journal of Microelectromechanical Systems, 2000.

  15. Rate Schedules

    Broader source: Energy.gov [DOE]

    One of the major responsibilities of Southeastern is to design, formulate, and justify rate schedules. Repayment studies prepared by the agency determine revenue requirements and appropriate rate...

  16. Low-mass dilepton production in $pp$ and $AA$ collisions

    E-Print Network [OSTI]

    Zhong-Bo Kang; Jian-Wei Qiu; Werner Vogelsang

    2009-09-23

    We adopt a factorized QCD formalism to describe the transverse momentum distribution of low-mass lepton pairs produced in $pp$ collisions, when the pair transverse momentum $Q_T \\gg Q$, with the pair's invariant mass $Q$ as low as $Q \\sim \\Lambda_{\\mathrm{QCD}}$. We extend this formalism to dilepton production in $AA$ collisions by including the nuclear-dependent power correction due to parton multiple scattering.

  17. Bond Programs | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois:Energy Authority JumpBond Programs Jump to:

  18. Bonding Tools | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment|Marketing, LLC |Energycurrently provides technicalBonds are one of

  19. 2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene

    E-Print Network [OSTI]

    Ellison, Barney

    2590 J. Am. Chem. SOC.1995,117, 2590-2599 The C-H Bond Energy of Benzene Gustavo E. Davico ion with benzene and phenide ion with ammonia: c&6 +NH2- C6H5- +NH3. The ratio of these rate constants for derived. The enthalpy of deprotonationof benzene, the C-H bond dissociationenergy, and the electron

  20. Hydrogen-bond equilibria and life times in a supercooled monohydroxy alcohol

    E-Print Network [OSTI]

    C. Gainaru; S. Kastner; F. Mayr; P. Lunkenheimer; S. Schildmann; H. J. Weber; W. Hiller; A. Loidl; R. Böhmer

    2011-06-29

    Dielectric loss spectra covering 13 decades in frequency were collected for 2-ethyl-1-hexanol, a monohydroxy alcohol that exhibits a prominent Debye-like relaxation, typical for several classes of hydrogen-bonded liquids. The thermal variation of the dielectric absorption amplitude agrees well with that of the hydrogen-bond equilibrium population, experimentally mapped out using near infrared (NIR) and nuclear magnetic resonance (NMR) measurements. Despite this agreement, temperature-jump NIR spectroscopy reveals that the hydrogen-bond switching rate does not define the frequency position of the prominent absorption peak. This contrasts with widespread notions and models based thereon, but is consistent with a recent approach.

  1. Hydrogen Adsorption Induces Interlayer Carbon Bond Formation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Adsorption Induces Interlayer Carbon Bond Formation in Supported Few-Layer Graphene Friday, February 28, 2014 Among the allotropes of carbon, diamond has some of the most...

  2. Nuclear reactor multiphysics via bond graph formalism

    E-Print Network [OSTI]

    Sosnovsky, Eugeny

    2014-01-01

    This work proposes a simple and effective approach to modeling nuclear reactor multiphysics problems using bond graphs. Conventional multiphysics simulation paradigms normally use operator splitting, which treats the ...

  3. Bond Strength Measurements from an Australian Standard Bond Wrench in Comparison to the Unbalanced ASTM C 1072 Bond Wrench to the Balanced and Unbalanced Wrenches 

    E-Print Network [OSTI]

    Suresh, Sri Vishnu Chaitanya Guptha

    2014-08-14

    in 1980s in the Australian laboratories. Former TAMU students had built a lightweight Indian unbalanced and balanced bond wrench. An Australian bond wrench was manufactured in 2011 and subsequently in 2012 an ASTM C 1072 Bond Wrench was developed...

  4. Valence Bond States: Link models

    E-Print Network [OSTI]

    E. Rico; R. Hübener; S. Montangero; N. Moran; B. Pirvu; J. Vala; H. J. Briegel

    2009-08-07

    An isotropic anti-ferromagnetic quantum state on a square lattice is characterized by symmetry arguments only. By construction, this quantum state is the result of an underlying valence bond structure without breaking any symmetry in the lattice or spin spaces. A detailed analysis of the correlations of the quantum state is given (using a mapping to a 2D classical statistical model and methods in field theory like mapping to the non-linear sigma model or bosonization techniques) as well as the results of numerical treatments (regarding exact diagonalization and variational methods). Finally, the physical relevance of the model is motivated. A comparison of the model to known anti-ferromagnetic Mott-Hubbard insulators is given by means of the two-point equal-time correlation function obtained i) numerically from the suggested state and ii) experimentally from neutron scattering on cuprates in the anti-ferromagnetic insulator phase.

  5. A&A manuscript no. (will be inserted by hand later)

    E-Print Network [OSTI]

    , Traverse du Siphon, Les Trois Lucs, F­13120 Marseille, France Received aa/bb/95, accepted xx/yy/95 Abstract

  6. Experimental Observation of Bonding Electrons in Proteins*

    E-Print Network [OSTI]

    Experimental Observation of Bonding Electrons in Proteins* (Received for publication, April 15 enables bonding details of electron distributions in proteins to be revealed experimentally for the first time. We move one step closer to imaging directly the fine details of the electronic structure on which

  7. Identification of products containing {single_bond}COOH, {single_bond}OH, and {single_bond}C{double_bond}O in atmospheric oxidation of hydrocarbons

    SciTech Connect (OSTI)

    Yu, J.; Flagan, R.C.; Seinfeld, J.H.

    1998-08-15

    Atmospheric oxidation of hydrocarbons by hydroxyl radicals and ozone leads to products containing {single_bond}COOH, {single_bond}OH, and {single_bond}C{double_bond}O functional groups. The high polarity of such compounds precludes direct GC-MS analysis. In addition, many such compounds often exist in a single sample at trace levels. An analytical method has been developed to identify compounds containing one or more functional groups of carbonyl, carboxy, and hydroxy in atmospheric samples. In the method, {single_bond}C{double_bond}O groups are derivatized using O-(2,3,4,5,6-pentafluorobenzyl) hydroxy amine(PFBHA), and {single_bond}COOH and {single_bond}OH groups are derivatized using a silylation reagent N,O-bis(trimethylsilyl)-trifluoroacetamide (BSTFA). The derivatives are easily resolved by a GC column. The chemical ionization mass spectra of these derivatives exhibit several pseudomolecular ions, allowing unambiguous determination of molecular weights. Functional group identification is accomplished by monitoring the ions in the electron ionization mass spectra that are characteristic of each functional group derivative: m/z 181 for carbonyl and m/z 73 and 75 for carboxyl and hydroxy groups. The method is used to identify products in laboratory studies of ozone oxidation of {alpha}-pinene and {Delta}{sup 3}-carene.

  8. 1 mil gold bond wire study.

    SciTech Connect (OSTI)

    Huff, Johnathon; McLean, Michael B.; Jenkins, Mark W.; Rutherford, Brian Milne

    2013-05-01

    In microcircuit fabrication, the diameter and length of a bond wire have been shown to both affect the current versus fusing time ratio of a bond wire as well as the gap length of the fused wire. This study investigated the impact of current level on the time-to-open and gap length of 1 mil by 60 mil gold bond wires. During the experiments, constant current was provided for a control set of bond wires for 250ms, 410ms and until the wire fused; non-destructively pull-tested wires for 250ms; and notched wires. The key findings were that as the current increases, the gap length increases and 73% of the bond wires will fuse at 1.8A, and 100% of the wires fuse at 1.9A within 60ms. Due to the limited scope of experiments and limited data analyzed, further investigation is encouraged to confirm these observations.

  9. Modifications in the AA5083 Johnson-Cook Material Model for Use in Friction Stir Welding

    E-Print Network [OSTI]

    Grujicic, Mica

    Modifications in the AA5083 Johnson-Cook Material Model for Use in Friction Stir Welding, material microstructure and properties in friction stir welding welds of AA5083 (a non welding, Johnson-Cook material model 1. Introduction In this study, an attempt is made to modify

  10. Corso di Laurea in Informatica -a.a. 2003/04 Primo parziale di Elementi

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2003/04 Primo parziale di Elementi 6 novembre 2003 Compito- nenza e anno di corso. #12;Corso di Laurea in Informatica - a.a. 2003/04 Primo parziale di Elementi 6, cognome, numero di matricola, canale di apparte- nenza e anno di corso. #12;Corso di Laurea in Informatica

  11. The PortevinLe Chatelier (PLC) effect and shear band formation in an AA5754 alloy

    E-Print Network [OSTI]

    Niewczas, Marek

    The Portevin­Le Chatelier (PLC) effect and shear band formation in an AA5754 alloy Herdawandi Halim in order to observe Portevin­Le Chatelier (PLC) band behaviour during tensile deformation of AA5754 sheet and subsequently to measure the level of incre- mental plastic strain carried within the bands. In addition, PLC

  12. PCFG based on quantitative representation of AA properties proved to be successful for PS00219

    E-Print Network [OSTI]

    Nebel, Jean-Christophe

    alphabet, we use quantitative properties of amino acids to reduce the number of symbols. Our techniqueConclusion § PCFG based on quantitative representation of AA properties proved to be successful relationships between amino acids (AA) § Probabilistic Context-Free Grammar (PCFG) is a more powerful language

  13. Low Barrier Hydrogen Bonds in Acyclic Tertiary Diamines

    E-Print Network [OSTI]

    Khodagholian, Sevana

    2010-01-01

    9. S. Yaghmaei, In Search of a Low Barrier Hydrogen Bond inP.A. Frey, and J.A. Gerlt, “The Low Barrier Hydrogen Bond inConsiderations Show That Low-Barrier Hydrogen Bonds do not

  14. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Hydrogen bonds are found everywhere in chemistry and biology and are critical in DNA and RNA. A hydrogen bond...

  15. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Surprising Path for Proton Transfer Without Hydrogen Bonds A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Wednesday, 25 July 2012 00:00 Hydrogen bonds are...

  16. Laurea Triennale in Informatica a.a. 2006/07 Prova intermedia di Analisi Matematica I 15 febbraio 2007

    E-Print Network [OSTI]

    Amadori, Debora

    Laurea Triennale in Informatica ­ a.a. 2006/07 Prova intermedia di Analisi Matematica I ­ 15 dimostrazione. #12;Laurea Triennale in Informatica ­ a.a. 2006/07 Prova intermedia di Analisi Matematica I ­ 15

  17. Corso di Laurea in Informatica -a.a. 2004/05 Prova di recupero di Elementi di Matematica

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2004/05 Prova di recupero di Elementi di Matematica 6 su tutti i fogli nome, cognome, numero di matricola. #12;Corso di Laurea in Informatica - a.a. 2004

  18. Corso di Laurea in Informatica -a.a. 2003/04 Prova di recupero di Elementi di Matematica

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2003/04 Prova di recupero di Elementi di Matematica 2, numero di matricola. #12;Corso di Laurea in Informatica - a.a. 2003/04 Prova di recupero di Elementi di

  19. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO); Davis, John W. (Ballwin, MO)

    2000-07-18

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by sintering a stack of individual copper and tungsten powder blend layers having progressively higher copper content/tungsten content, by volume, ratio values in successive powder blend layers in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  20. Atomically Bonded Transparent Superhydrophobic Coatings

    SciTech Connect (OSTI)

    Aytug, Tolga

    2015-08-01

    Maintaining clarity and avoiding the accumulation of water and dirt on optically transparent surfaces such as US military vehicle windshields, viewports, periscope optical head windows, and electronic equipment cover glasses are critical to providing a high level of visibility, improved survivability, and much-needed safety for warfighters in the field. Through a combination of physical vapor deposition techniques and the exploitation of metastable phase separation in low-alkali borosilicate, a novel technology was developed for the fabrication of optically transparent, porous nanostructured silica thin film coatings that are strongly bonded to glass platforms. The nanotextured films, initially structurally superhydrophilic, exhibit superior superhydrophobicity, hence antisoiling ability, following a simple but robust modification in surface chemistry. The surfaces yield water droplet contact angles as high as 172°. Moreover, the nanostructured nature of these coatings provides increased light scattering in the UV regime and reduced reflectivity (i.e., enhanced transmission) over a broad range of the visible spectrum. In addition to these functionalities, the coatings exhibit superior mechanical resistance to abrasion and are thermally stable to temperatures approaching 500°C. The overall process technology relies on industry standard equipment and inherently scalable manufacturing processes and demands only nontoxic, naturally abundant, and inexpensive base materials. Such coatings, applied to the optical components of current and future combat equipment and military vehicles will provide a significant strategic advantage for warfighters. The inherent self-cleaning properties of such superhydrophobic coatings will also mitigate biofouling of optical windows exposed to high-humidity conditions and can help decrease repair/replacement costs, reduce maintenance, and increase readiness by limiting equipment downtime.

  1. New Bond Helps Toledo, Ohio, Expand Financing Pool | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Bond Helps Toledo, Ohio, Expand Financing Pool New Bond Helps Toledo, Ohio, Expand Financing Pool The logo for Better Buildings Northwest Ohio, Toleco Lucas County Port...

  2. Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conservation bond and new clean renewable energy bonds, including characteristics, mechanics, allocated volume, and other information. Author: U.S. Department of Energy...

  3. Using Qualified Energy Conservation Bonds for Public Building...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bonds for Public Building Upgrades: Reducing Energy Bills in the City of Philadelphia Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing...

  4. Review of Direct Metal Bonding for Microelectronic Interconnections

    E-Print Network [OSTI]

    Zhang, G.G.

    Microelectronic interconnections require advanced joining techniques. Direct metal bonding methods, which include thercomsonic and thermocompression bonding, offer remarkable advantages over soldering and adhesives joining. ...

  5. Corso di Laurea in Informatica -a.a. 2003/04 Prova finale di Elementi di Matematica

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2003/04 Prova finale di Elementi di Matematica 12 dicembre in Informatica - a.a. 2003/04 Prova finale di Elementi di Matematica 12 dicembre 2003 Compito B Parte II ­ durata tutti i fogli nome, cognome, numero di matricola. #12;Corso di Laurea in Informatica - a.a. 2003

  6. REITs: Stocks, Bonds, or Real Estate?

    E-Print Network [OSTI]

    Rosen, Kenneth T.

    1995-01-01

    Berkeley FISHER CENTER FOR REAL ESTATE AND URBAN ECONOMICS244 RElTs: Stocks, Bonds or Real Estate? By KENNETH T. ROSENBUSINESS FISHER CENTER FOR REAL ESTATE AND URBAN ECONOMICS

  7. Mechanics aspects of water thermocompression bonding

    E-Print Network [OSTI]

    Stamoulis, Konstantinos, 1970-

    2005-01-01

    Wafer-level, thermocompression bonding is a promising technique for microelectromechanical systems (MEMS) packaging. The process is a form of solid-state joining and requires the simultaneous application of temperature and ...

  8. Ultrafast Infrared Studies of Bond Activation in

    E-Print Network [OSTI]

    Harris, Charles B.

    a few. Predominate in the field are UV-pump visible-probe techniques, a fact which derives largely from industry. Si-H bond activation by certain transition-metal-containing com- pounds was discovered by Jetz

  9. Corporate bond repurchases and earnings management

    E-Print Network [OSTI]

    Lemayian, Zawadi Rehema

    2013-01-01

    This paper investigates whether earnings management incentives are associated with gains/losses recognized when firms repurchase bonds. The research question is motivated by the inclusion of these gains/losses in firms' ...

  10. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, V.A.

    1991-04-23

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof is disclosed. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, Au and alloys thereof. 3 figures.

  11. Method of bonding metals to ceramics

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL)

    1991-01-01

    A ceramic or glass having a thin layer of silver, gold or alloys thereof at the surface thereof. A first metal is bonded to the thin layer and a second metal is bonded to the first metal. The first metal is selected from the class consisting of In, Ga, Sn, Bi, Zn, Cd, Pb, Tl and alloys thereof, and the second metal is selected from the class consisting of Cu, Al, Pb, An and alloys thereof.

  12. Predicting Tensile Stretchability of Trimmed AA6111-T4 Sheets

    SciTech Connect (OSTI)

    Hu, Xiaohua; Sun, Xin; Golovashchenko, Sergey F.

    2014-02-15

    An integrated manufacturing process simulation framework has been developed to predict the trimmed edge tensile stretchability of AA6111-T4 sheets by incorporating the burr geometry, damage, and plastic strain from trimming simulations into subsequent tensile stretchability simulations. The influence of the trimming die clearances on the predicted tensile stretching ductility (stretchability) is studied and quantitatively compared with experimental measurements. Stretchability is found to decrease with increasing cutting clearances, and simulation results have successfully captured experimentally observed edge crack initiation and failure mode variations for different trimming clearances. Subsequent computational sensitivity studies reveal that while deburring of previously trimmed edges has little influence on tensile stretchability, removal of trimmed edge initial plastic strain may significantly enhance the subsequent trimmed edge stretchability.

  13. AA Dor - An Eclipsing sdOB - Brown Dwarf Binary

    E-Print Network [OSTI]

    Thomas Rauch

    2003-11-25

    AA Dor is an eclipsing, close, post common-envelope binary consisting of a sdOB primary star and an unseen secondary with an extraordinary small mass - formally a brown dwarf. The brown dwarf may have been a former planet which survived a common envelope phase and has even gained mass. A recent determination of the components' masses from results of NLTE spectral analysis and subsequent comparison to evolutionary tracks shows a discrepancy to masses derived from radial-velocity and the eclipse curves. Phase-resolved high-resolution and high-SN spectroscopy was carried out in order to investigate on this problem. We present results of a NLTE spectral analysis of the primary, an analysis of its orbital parameters, and discuss possible evolutionary scenarios.

  14. Soluble Hydrogen-bonding Interpolymer Complexes in Water: A Small-Angle Neutron Scattering Study

    E-Print Network [OSTI]

    Maria Sotiropoulou; Julian Oberdisse; Georgios Staikos

    2006-04-03

    The hydrogen-bonding interpolymer complexation between poly(acrylic acid) (PAA) and the poly(N,N-dimethylacrylamide) (PDMAM) side chains of the negatively charged graft copolymer poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid)-graft-poly(N, N dimethylacrylamide) (P(AA-co-AMPSA)-g-PDMAM), containing 48 wt % of PDMAM, and shortly designated as G48, has been studied by small-angle neutron scattering in aqueous solution. Complexation occurs at low pH (pH < 3.75), resulting in the formation of negatively charged colloidal particles, consisting of PAA/PDMAM hydrogen-bonding interpolymer complexes, whose radius is estimated to be around 165 A. As these particles involve more than five graft copolymer chains, they act as stickers between the anionic chains of the graft copolymer backbone. This can explain the characteristic thickening observed in past rheological measurements with these mixtures in the semidilute solution, with decreasing pH. We have also examined the influence of pH and PAA molecular weight on the formation of these nanoparticles.

  15. Qualified Energy Conservation Bond State-by-State Summary Tables

    Broader source: Energy.gov [DOE]

    Provides a list of qualified energy conservation bond state summary tables. Author: Energy Programs Consortium

  16. Hydrogen Bonding DOI: 10.1002/anie.200501349

    E-Print Network [OSTI]

    Simons, Jack

    Hydrogen Bonding DOI: 10.1002/anie.200501349 Observation of Weak C�H···O Hydrogen Bonding to Unactivated Alkanes** Xue-Bin Wang, Hin-Koon Woo, Boggavarapu Kiran, and Lai-Sheng Wang* The hydrogen bond carbon can also behave as a proton donor to form C�H···O-type hydrogen bonds has been the subject

  17. Managing Value-at-Risk for a bond using bond put options

    E-Print Network [OSTI]

    Vanmaele, Michčle

    Managing Value-at-Risk for a bond using bond put options Griselda Deelstra1 , Ahmed Ezzine1 , Dries. Furthermore, at a suffi- ciently low confidence level the VaR measure explicitly focuses risk managersR-based risk management. The starting point of our analysis is the classical hedging example, where

  18. Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, Tobias Steinel, and M. D. Fayer*

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Networks: Structure and Evolution after Hydrogen Bond Breaking John B. Asbury, TobiasVed: September 1, 2003; In Final Form: December 18, 2003 The nature of hydrogen bonding networks following hydrogen bond breaking is investigated using vibrational echo correlation spectroscopy of the hydroxyl

  19. Epoxy bond and stop etch fabrication method

    DOE Patents [OSTI]

    Simmons, Jerry A. (Sandia Park, NM); Weckwerth, Mark V. (Pleasanton, CA); Baca, Wes E. (Albuquerque, NM)

    2000-01-01

    A class of epoxy bond and stop etch (EBASE) microelectronic fabrication techniques is disclosed. The essence of such techniques is to grow circuit components on top of a stop etch layer grown on a first substrate. The first substrate and a host substrate are then bonded together so that the circuit components are attached to the host substrate by the bonding agent. The first substrate is then removed, e.g., by a chemical or physical etching process to which the stop etch layer is resistant. EBASE fabrication methods allow access to regions of a device structure which are usually blocked by the presence of a substrate, and are of particular utility in the fabrication of ultrafast electronic and optoelectronic devices and circuits.

  20. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, R.D.; Roe, L.H.; Migliori, A.

    1995-11-14

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements. 12 figs.

  1. Process Of Bonding Copper And Tungsten

    DOE Patents [OSTI]

    Slattery, Kevin T. (St. Charles, MO); Driemeyer, Daniel E. (Manchester, MO)

    1999-11-23

    Process for bonding a copper substrate to a tungsten substrate by providing a thin metallic adhesion promoting film bonded to a tungsten substrate and a functionally graded material (FGM) interlayer bonding the thin metallic adhesion promoting film to the copper substrate. The FGM interlayer is formed by thermal plasma spraying mixtures of copper powder and tungsten powder in a varied blending ratio such that the blending ratio of the copper powder and the tungsten powder that is fed to a plasma torch is intermittently adjusted to provide progressively higher copper content/tungsten content, by volume, ratio values in the interlayer in a lineal direction extending from the tungsten substrate towards the copper substrate. The resulting copper to tungsten joint well accommodates the difference in the coefficient of thermal expansion of the materials.

  2. Bonded ultrasonic transducer and method for making

    DOE Patents [OSTI]

    Dixon, Raymond D. (Los Alamos, NM); Roe, Lawrence H. (Los Alamos, NM); Migliori, Albert (Santa Fe, NM)

    1995-01-01

    An ultrasonic transducer is formed as a diffusion bonded assembly of piezoelectric crystal, backing material, and, optionally, a ceramic wear surface. The mating surfaces of each component are silver films that are diffusion bonded together under the application of pressure and heat. Each mating surface may also be coated with a reactive metal, such as hafnium, to increase the adhesion of the silver films to the component surfaces. Only thin silver films are deposited, e.g., a thickness of about 0.00635 mm, to form a substantially non-compliant bond between surfaces. The resulting transducer assembly is substantially free of self-resonances over normal operating ranges for taking resonant ultrasound measurements.

  3. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-11-01

    The thermal performance and reliability of sintered-silver is being evaluated for power electronics packaging applications. This will be experimentally accomplished by the synthesis of large-area bonded interfaces between metalized substrates that will be subsequently subjected to thermal cycles. A finite element model of crack initiation and propagation in these bonded interfaces will allow for the interpretation of degradation rates by a crack-velocity (V)-stress intensity factor (K) analysis. The experiment is outlined, and the modeling approach is discussed.

  4. T.A.; Coomer, C.L.; Campbell, S.L.; Wereszczak, A.A.; Cunningham...

    Office of Scientific and Technical Information (OSTI)

    S.L.; Wereszczak, A.A.; Cunningham, J.P.; Marlino, L.D.; Seiber, L.E.; Lin, H.T. 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ECONOMICS; EVALUATION; FEEDBACK;...

  5. Corso di Laurea in Informatica -a.a. 2004/05 Prova di Elementi di Matematica

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2004/05 Prova di Elementi di Matematica 21 marzo 2005 Compito: Scrivere su tutti i fogli nome, cognome, numero di matricola. #12;Corso di Laurea in Informatica - a

  6. Astronomy & Astrophysics manuscript no. aa1213 May 3, 2004 (DOI: will be inserted by hand later)

    E-Print Network [OSTI]

    Tokovinin, Andrei A.

    9: The Ninth Catalogue of Spectroscopic Binary Orbits D. Pourbaix1,2, , A.A. Tokovinin3, A.H. Batten- ation of astrometric satellites such as Gaia (Pourbaix & Jancart 2003) or SIM (Marr 2003). A catalogue

  7. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1993-01-01

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120.degree. C. to about 300.degree. C. to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate.

  8. Phosphate-bonded calcium aluminate cements

    DOE Patents [OSTI]

    Sugama, T.

    1993-09-21

    A method is described for making a rapid-setting phosphate-bonded cementitious material. A powdered aluminous cement is mixed with an aqueous solution of ammonium phosphate. The mixture is allowed to set to form an amorphous cementitious material which also may be hydrothermally treated at a temperature of from about 120 C to about 300 C to form a crystal-containing phosphate-bonded material. Also described are the cementitious products of this method and the cement composition which includes aluminous cement and ammonium polyphosphate. 10 figures.

  9. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-08-25

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  10. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, R.J.; McMillan, A.D.; Paulauskas, F.L.; Fathi, Z.; Wei, J.

    1998-09-08

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy. 26 figs.

  11. Adhesive bonding using variable frequency microwave energy

    DOE Patents [OSTI]

    Lauf, Robert J. (Oak Ridge, TN); McMillan, April D. (Knoxville, TN); Paulauskas, Felix L. (Oak Ridge, TN); Fathi, Zakaryae (Cary, NC); Wei, Jianghua (Raleigh, NC)

    1998-01-01

    Methods of facilitating the adhesive bonding of various components with variable frequency microwave energy are disclosed. The time required to cure a polymeric adhesive is decreased by placing components to be bonded via the adhesive in a microwave heating apparatus having a multimode cavity and irradiated with microwaves of varying frequencies. Methods of uniformly heating various articles having conductive fibers disposed therein are provided. Microwave energy may be selectively oriented to enter an edge portion of an article having conductive fibers therein. An edge portion of an article having conductive fibers therein may be selectively shielded from microwave energy.

  12. IMPACT OF CAPILLARY AND BOND NUMBERS ON RELATIVE PERMEABILITY

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2002-09-30

    Recovery and recovery rate of oil, gas and condensates depend crucially on their relative permeability. Relative permeability in turn depends on the pore structure, wettability and flooding conditions, which can be represented by a set of dimensionless groups including capillary and bond numbers. The effect of flooding conditions on drainage relative permeabilities is not well understood and is the overall goal of this project. This project has three specific objectives: to improve the centrifuge relative permeability method, to measure capillary and bond number effects experimentally, and to develop a pore network model for multiphase flows. A centrifuge has been built that can accommodate high pressure core holders and x-ray saturation monitoring. The centrifuge core holders can operate at a pore pressure of 6.9 MPa (1000 psi) and an overburden pressure of 17 MPa (2500 psi). The effect of capillary number on residual saturation and relative permeability in drainage flow has been measured. A pore network model has been developed to study the effect of capillary numbers and viscosity ratio on drainage relative permeability. Capillary and Reynolds number dependence of gas-condensate flow has been studied during well testing. A method has been developed to estimate relative permeability parameters from gas-condensate well test data.

  13. Fluorinated diamond bonded in fluorocarbon resin

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM)

    1982-01-01

    By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

  14. Sacrificial bonds and hidden length in biomaterials -- a kinetic, constitutive description of strength and toughness in bone

    E-Print Network [OSTI]

    Lieou, Charles K C; Carlson, Jean M

    2013-01-01

    Sacrificial bonds and hidden length in structural molecules account for the greatly increased fracture toughness of biological materials compared to synthetic materials without such structural features, by providing a molecular-scale mechanism for energy dissipation. One example is in the polymeric glue connection between collagen fibrils in animal bone. In this paper, we propose a simple kinetic model that describes the breakage of sacrificial bonds and the release of hidden length, based on Bell's theory. We postulate a master equation governing the rates of bond breakage and formation. This enables us to predict the mechanical behavior of a quasi-one-dimensional ensemble of polymers at different stretching rates. We find that both the rupture peak heights and maximum stretching distance increase with the stretching rate. In addition, our theory naturally permits the possibility of self-healing in such biological structures.

  15. Sacrificial bonds and hidden length in biomaterials -- a kinetic, constitutive description of strength and toughness in bone

    E-Print Network [OSTI]

    Charles K. C. Lieou; Ahmed E. Elbanna; Jean M. Carlson

    2013-01-25

    Sacrificial bonds and hidden length in structural molecules account for the greatly increased fracture toughness of biological materials compared to synthetic materials without such structural features, by providing a molecular-scale mechanism for energy dissipation. One example is in the polymeric glue connection between collagen fibrils in animal bone. In this paper, we propose a simple kinetic model that describes the breakage of sacrificial bonds and the release of hidden length, based on Bell's theory. We postulate a master equation governing the rates of bond breakage and formation. This enables us to predict the mechanical behavior of a quasi-one-dimensional ensemble of polymers at different stretching rates. We find that both the rupture peak heights and maximum stretching distance increase with the stretching rate. In addition, our theory naturally permits the possibility of self-healing in such biological structures.

  16. Various Carbon to Carbon Bond Lengths Inter-related via the Golden Ratio, and their Linear Dependence on Bond Energies

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-09-11

    This work presents the relations between the carbon to carbon bond lengths in the single, double and triple bonds and in graphite, butadiene and benzene. The Golden ratio, which was shown to divide the Bohr radius into two parts pertaining to the charged particles, the electron and proton, and to divide inter-atomic distances into their cationic and anionic radii, also plays a role in the carbon-carbon bonds and in the ionic/polar character of those in graphite, butadiene and benzene. Further, the bond energies of the various CC bonds are shown to vary linearly with the bond lengths.

  17. Laurea Triennale in Informatica a.a. 2004/05 Prova intermedia di Analisi Matematica I 18 febbraio 2005

    E-Print Network [OSTI]

    Amadori, Debora

    Laurea Triennale in Informatica ­ a.a. 2004/05 Prova intermedia di Analisi Matematica I ­ 18 in Informatica ­ a.a. 2004/05 Prova intermedia di Analisi Matematica I ­ 18 febbraio 2005 Compito B Esercizio 1 lim n+ 2n + 1 1 - n = -2 . #12;Laurea Triennale in Informatica ­ a.a. 2004/05 Prova intermedia di

  18. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time-Resolved Study of Bonding in Liquid Carbon Time-Resolved Study of Bonding in Liquid Carbon Print Wednesday, 28 September 2005 00:00 We are accustomed to observing carbon in...

  19. FUNDAMENTALS OF WETTING AND BONDING BETWEEN CERAMICS AND METALS

    E-Print Network [OSTI]

    Pask, J.A.

    2010-01-01

    WETTING AND BONDING BETWEEN CERAMICS AND METALS Jo s eph A.OF WETTING AND BONDING BETWEEN CERAMICS AND METALS Joseph A.and glass-to-metal or ceramic-to-metal seals. Both physical

  20. Nanoscale metals and semiconductors for the storage of solar energy in chemical bonds

    E-Print Network [OSTI]

    Manthiram, Karthish

    2015-01-01

    for the storage of solar energy in chemical bonds Byfor the storage of solar energy in chemical bonds Copyrightfor the storage of solar energy in chemical bonds By

  1. A Corpuscular Picture of Electrons in Chemical Bond

    E-Print Network [OSTI]

    Ando, Koji

    2015-01-01

    We introduce a theory of chemical bond with a corpuscular picture of electrons. It employs a minimal set of localized electron wave packets with 'floating and breathing' degrees of freedom and the spin-coupling of non-orthogonal valence-bond theory. It accurately describes chemical bonds in ground and excited states of spin singlet and triplet, in a distinct manner from conventional theories, indicating potential for establishing a dynamical theory of electrons in chemical bonds.

  2. Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang*

    E-Print Network [OSTI]

    Caflisch, Amedeo

    Hydrogen Bonding Penalty upon Ligand Binding Hongtao Zhao, Danzhi Huang* Department of Biochemistry, University of Zurich, Zurich, Switzerland Abstract Ligand binding involves breakage of hydrogen bonds with water molecules and formation of new hydrogen bonds between protein and ligand. In this work, the change

  3. Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and

    E-Print Network [OSTI]

    Hydrogen Bond Networks in Graphene Oxide Composite Paper: Structure and Mechanical Properties of hydrogen bonds mediated by oxygen-containing functional groups and water molecules. A quantitative analysis of the formation of hydrogen bond networks further shows that they play a central role in *Address correspondence

  4. Hydrogen bonds in liquid water are broken only fleetingly

    E-Print Network [OSTI]

    Geissler, Phillip

    Hydrogen bonds in liquid water are broken only fleetingly J. D. Eaves* , J. J. Loparo* , C. J that the local structure of liquid water has tetrahedral arrangements of molecules ordered by hydrogen bonds, the mechanism by which water molecules switch hydrogen-bonded partners remains unclear. In this mechanism

  5. Hydrogen bonding in benzonitrilewater complexes Eugene S. Kryachkoa)

    E-Print Network [OSTI]

    Nguyen, Minh Tho

    Hydrogen bonding in benzonitrile­water complexes Eugene S. Kryachkoa) and Minh Tho Nguyenb January 2001; accepted 23 March 2001 The hydrogen bonding between benzonitrile and one and two water,p and aug-cc-pVDZ basis sets. The strength of such hydrogen bonding is analyzed in terms of a magnitude

  6. Analysis of C H...O hydrogen bonds

    E-Print Network [OSTI]

    Babu, M. Madan

    1 Analysis of C H...O hydrogen bonds in high resolution protein crystal structures from the PDB 1.4 Identification of C-H...O hydrogen bonds............................................. 1.4.1 The definition of a C-H...O hydrogen bond.................................... 1.4.2 Fixing the hydrogen and measuring the parameters

  7. Oil prices and government bond risk premiums Herv Alexandre*

    E-Print Network [OSTI]

    Boyer, Edmond

    Oil prices and government bond risk premiums By Hervé Alexandre*º Antonin de Benoist * Abstract : This article analyses the impact of oil price on bond risk premiums issued by emerging economies. No empirical study has yet focussed on the effects of the oil price on government bond risk premiums. We develop

  8. Article coated with flash bonded superhydrophobic particles

    DOE Patents [OSTI]

    Simpson, John T (Clinton, TN) [Clinton, TN; Blue, Craig A (Knoxville, TN) [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

    2010-07-13

    A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

  9. Public Bonding Options | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011 | DepartmentFunds for Renewables andBonding

  10. Microchannel cooling of face down bonded chips

    DOE Patents [OSTI]

    Bernhardt, A.F.

    1993-06-08

    Microchannel cooling is applied to flip-chip bonded integrated circuits, in a manner which maintains the advantages of flip-chip bonds, while overcoming the difficulties encountered in cooling the chips. The technique is suited to either multi chip integrated circuit boards in a plane, or to stacks of circuit boards in a three dimensional interconnect structure. Integrated circuit chips are mounted on a circuit board using flip-chip or control collapse bonds. A microchannel structure is essentially permanently coupled with the back of the chip. A coolant delivery manifold delivers coolant to the microchannel structure, and a seal consisting of a compressible elastomer is provided between the coolant delivery manifold and the microchannel structure. The integrated circuit chip and microchannel structure are connected together to form a replaceable integrated circuit module which can be easily decoupled from the coolant delivery manifold and the circuit board. The coolant supply manifolds may be disposed between the circuit boards in a stack and coupled to supplies of coolant through a side of the stack.

  11. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  12. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2000-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  13. Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

  14. Method for bonding a transmission line to a downhole tool

    DOE Patents [OSTI]

    Hall, David R. (Provo, UT); Fox, Joe (Spanish Fork, UT)

    2007-11-06

    An apparatus for bonding a transmission line to the central bore of a downhole tool includes a pre-formed interface for bonding a transmission line to the inside diameter of a downhole tool. The pre-formed interface includes a first surface that substantially conforms to the outside contour of a transmission line and a second surface that substantially conforms to the inside diameter of a downhole tool. In another aspect of the invention, a method for bonding a transmission line to the inside diameter of a downhole tool includes positioning a transmission line near the inside wall of a downhole tool and placing a mold near the transmission line and the inside wall. The method further includes injecting a bonding material into the mold and curing the bonding material such that the bonding material bonds the transmission line to the inside wall.

  15. Corso di Laurea in Informatica -a.a. 2003/04 Prova di recupero di Elementi di Matematica

    E-Print Network [OSTI]

    Amadori, Debora

    Corso di Laurea in Informatica - a.a. 2003/04 Prova di recupero di Elementi di Matematica 12 luglio: Scrivere su tutti i fogli nome, cognome, numero di matricola. #12;Corso di Laurea in Informatica - a matricola. #12;Corso di Laurea in Informatica - a.a. 2003/04 Prova di recupero di Elementi di Matematica 12

  16. Bond selective chemistry beyond the adiabatic approximation

    SciTech Connect (OSTI)

    Butler, L.J. [Univ. of Chicago, IL (United States)

    1993-12-01

    One of the most important challenges in chemistry is to develop predictive ability for the branching between energetically allowed chemical reaction pathways. Such predictive capability, coupled with a fundamental understanding of the important molecular interactions, is essential to the development and utilization of new fuels and the design of efficient combustion processes. Existing transition state and exact quantum theories successfully predict the branching between available product channels for systems in which each reaction coordinate can be adequately described by different paths along a single adiabatic potential energy surface. In particular, unimolecular dissociation following thermal, infrared multiphoton, or overtone excitation in the ground state yields a branching between energetically allowed product channels which can be successfully predicted by the application of statistical theories, i.e. the weakest bond breaks. (The predictions are particularly good for competing reactions in which when there is no saddle point along the reaction coordinates, as in simple bond fission reactions.) The predicted lack of bond selectivity results from the assumption of rapid internal vibrational energy redistribution and the implicit use of a single adiabatic Born-Oppenheimer potential energy surface for the reaction. However, the adiabatic approximation is not valid for the reaction of a wide variety of energetic materials and organic fuels; coupling between the electronic states of the reacting species play a a key role in determining the selectivity of the chemical reactions induced. The work described below investigated the central role played by coupling between electronic states in polyatomic molecules in determining the selective branching between energetically allowed fragmentation pathways in two key systems.

  17. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, Anthony F. (Berkeley, CA); Contolini, Robert J. (Livermore, CA); Malba, Vincent (Livermore, CA); Riddle, Robert A. (Tracy, CA)

    1997-01-01

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder.

  18. Repairable chip bonding/interconnect process

    DOE Patents [OSTI]

    Bernhardt, A.F.; Contolini, R.J.; Malba, V.; Riddle, R.A.

    1997-08-05

    A repairable, chip-to-board interconnect process which addresses cost and testability issues in the multi-chip modules is disclosed. This process can be carried out using a chip-on-sacrificial-substrate technique, involving laser processing. This process avoids the curing/solvent evolution problems encountered in prior approaches, as well is resolving prior plating problems and the requirements for fillets. For repairable high speed chip-to-board connection, transmission lines can be formed on the sides of the chip from chip bond pads, ending in a gull wing at the bottom of the chip for subsequent solder. 10 figs.

  19. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in Actinide Sandwich Molecules Print Glenn Seaborg was one

  20. Covalent Bonding in Actinide Sandwich Molecules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in Actinide Sandwich Molecules Print Glenn Seaborg was

  1. Bonded Compliant Seal (BCS) - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|BilayerBiomimetic DyeBlue Gene/Q Download52015 |Bonded

  2. State Bond Program | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbHSoloPage EditStamford,Energy CenterStateState Bond

  3. Cement Bond Log | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank,CammackFLIR Jump to:RAPIDCavallo Energy JumpCeiling Fan JumpCement Bond Log

  4. Hydrogen-bond driven loop-closure kinetics in unfolded polypeptide chains

    SciTech Connect (OSTI)

    Daidone, Isabella [University of Heidelberg; Neuweiler, H [University of Heidelberg; Doose, S [University of Heidelberg; Sauer, M [University of Heidelberg; Smith, Jeremy C [ORNL

    2010-12-01

    Characterization of the length dependence of end-to-end loop-closure kinetics in unfolded polypeptide chains provides an understanding of early steps in protein folding. Here, loop-closure in poly-glycine-serine peptides is investigated by combining single-molecule fluorescence spectroscopy with molecular dynamics simulation. For chains containing more than 10 peptide bonds loop-closing rate constants on the 20-100 nanosecond time range exhibit a power-law length dependence. However, this scaling breaks down for shorter peptides, which exhibit slower kinetics arising from a perturbation induced by the dye reporter system used in the experimental setup. The loop-closure kinetics in the longer peptides is found to be determined by the formation of intra-peptide hydrogen bonds and transient beta-sheet structure, that accelerate the search for contacts among residues distant in sequence relative to the case of a polypeptide chain in which hydrogen bonds cannot form. Hydrogen-bond-driven polypeptide-chain collapse in unfolded peptides under physiological conditions found here is not only consistent with hierarchical models of protein folding, that highlights the importance of secondary structure formation early in the folding process, but is also shown to speed up the search for productive folding events.

  5. AlAA 89-1833 An Experimental Investigation of the Parallel

    E-Print Network [OSTI]

    Texas at Arlington, University of

    high Reynolds number, tran- sonic, Ludwieg-tube wind tunnel facility. The vortex- airfoil interactionAlAA 89-1833 An Experimental Investigation of the Parallel Vortex-AirfoiI Interaction at Transonic.W., Washington, D.C. 20024 #12;AN I~:XI'I!RIMf~NTAI.INVESTIGATION OF TfHE PARALLEI. VORTEX-AIRFOIL INTERACTION

  6. Modeling of AA5083 Material-Microstructure Evolution During Butt Friction-Stir Welding

    E-Print Network [OSTI]

    Grujicic, Mica

    Modeling of AA5083 Material-Microstructure Evolution During Butt Friction-Stir Welding M. Grujicic yet a fairly comprehensive overview of the friction stir welding (FSW) process is provided-element procedure developed in our prior study. Particular attention is given to proper modeling of the welding work

  7. Computational Analysis of Material Flow During Friction Stir Welding of AA5059 Aluminum Alloys

    E-Print Network [OSTI]

    Grujicic, Mica

    Computational Analysis of Material Flow During Friction Stir Welding of AA5059 Aluminum Alloys M welding (FSW) process are investigated computationally. Within the numerical model of the FSW process component. The employed coupled Eulerian/Lagrangian computational analysis of the welding process

  8. Correction to Electron Plasma Mode Frequency Formula A.A. Kabantsev and C.F. Driscoll

    E-Print Network [OSTI]

    California at San Diego, University of

    Correction to Electron Plasma Mode Frequency Formula A.A. Kabantsev and C.F. Driscoll Department [submitted]) Abstract A correction to the Prasad-O'Neil formula for non-axisymmetric Trivelpiece-Gould plasma zeros jm /jm-1 . 1 #12;The simple Prasad-O'Neil formula1 for Trivelpiece-Gould plasma wave frequencies

  9. AlAA 95-2580 Experimental Investigation of Pulse Detonation

    E-Print Network [OSTI]

    Texas at Arlington, University of

    DETONATION WAVE PHENOMENON AS RELATED TO PROPULSION APPLICATION* Steven B. Stanley?, Karl R. Burgef. Unfortunately, this tqpe of propulsion is generally not powerful enough to meet today`s propulsion requirementsAlAA 95-2580 Experimental Investigation of Pulse Detonation Wave Phenomenon as Related

  10. A&A 526, A85 (2011) DOI: 10.1051/0004-6361/201015851

    E-Print Network [OSTI]

    Montes-Hernandez, German

    2011-01-01

    A&A 526, A85 (2011) DOI: 10.1051/0004-6361/201015851 c ESO 2010 Astronomy & Astrophysics Goethite spectra that we measure for synthesized goethite are consistent with published transmission spectra. The 3-µm band in goethite has a minimum around 3.10 µm, similar to observations of 24-Themis. Its overall

  11. A&A Wood Shop 1248A 1248B 1248C

    E-Print Network [OSTI]

    Papalambros, Panos

    Building Technology Lab 1203 Student Research Room 1209 1107 Storage 1106 1223 1223A 1223B 1225 1219 3D Printing 1210 1205 1205A 1205B 1205C1205D 1105 Dock 1102 Slusser Gallery 2104 A&A Auditorium Bonisteel Blvd

  12. The effect of atmospheric corona treatment on AA1050 aluminium M. Jariyaboon a,1

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    , 5, and 15 min) in atmospheric air. A 200 nm oxide layer was generated on AA1050 after the 15 min air of a thin oxide layer on alumin- ium alloy surfaces similar to conversion coatings. A significant reduction. The thickness of oxide layer was found to be around 150­300 nm after 20 min of the treatment. However

  13. A&A 464, 761 (2007) DOI: 10.1051/0004-6361:20053201e

    E-Print Network [OSTI]

    Berdyugina, Svetlana

    2007-01-01

    unit), PO Box 3000, 90014 University of Oulu, Finland e-mail: ilya.usoskin@oulu.fi 2 Institut fĂĽr, Finland 4 Astronomy Division, PO Box 3000, 90014 University of Oulu, Finland (1) A&A, 405, 1121-1128 (2003

  14. Nonlocal Problems in MEMS Device Control J.A. Pelesko* and A.A. Triolo**

    E-Print Network [OSTI]

    Pelesko, John

    Nonlocal Problems in MEMS Device Control J.A. Pelesko* and A.A. Triolo** *Georgia Institute associated with electrostaticallyactuated MEMS devices is the pull- in" voltage instability electrostatically actuated MEMS device is constructed for the purpose of analyzingvarious schemes proposed

  15. ALGEBRA e LOGICA CdL in Ingegneria Informatica --a.a. 2012/2013

    E-Print Network [OSTI]

    Gavarini, Fabio

    ALGEBRA e LOGICA CdL in Ingegneria Informatica -- a.a. 2012/2013 prof. Fabio GAVARINI Sessione possibile, se ne spieghi il perch´e. (c) Stabilire, motivando le conclusioni, se D315 e/o D165 sia un'algebra di Boole. [4] Determinare tutte le soluzioni del sistema di equazioni congruenziali 195 x 292

  16. AA DiscretizationDiscretization ProcedureProcedure forfor EvolutionaryEvolutionary VariationalVariational

    E-Print Network [OSTI]

    Nagurney, Anna

    Variational InequalitiesInequalities andand ApplicationsApplications toto aa FinancialFinancial ModelModel Patrizia Daniele VariationalD Variational InequalitiesInequalities EE QuasiQuasi--VariationalVariational InequalitiesInequalitiesVariational InequalitiesInequalities"",, Comm.Comm. PurePure ApplAppl.. MathMath..,, 2222, 493, 493--519.519. 2.2. Brezis

  17. Title Format and Order Type AAS History Series Print; Serial Standing Order

    E-Print Network [OSTI]

    Clayton, Dale H.

    Title Format and Order Type AAS History Series Print; Serial Standing Order Advanced Series in Astrophysics and Cosmology Continuation/Print Monograph Standing Order Akzente Print, Serial Alexander Lectures Continuation/Print Monograph Standing Order, Discontinued? Annales de démographie historique Print, Serial

  18. SSooiill--SSttrruuccttuurree IInntteerraaccttiioonn RReesseeaarrcchh PPrroojjeecctt ""AA PPrraaccttiiccaall SSuubbggrraaddee MMooddeell ffoorr

    E-Print Network [OSTI]

    Horvath, John S.

    YYoorrkk,, UU..SS..AA.. JJaannuuaarryy 22001111 #12;ii Soil-Structure Interaction Research Project "A Practical Subgrade Model for Improved Soil-Structure Interaction Analysis: Parameter Assessment" Manhattan. Horvath. All rights reserved. Prof. John S. Horvath, Ph.D., P.E., M.ASCE Manhattan College Civil

  19. A&A 403, 93103 (2003) DOI: 10.1051/0004-6361:20030282

    E-Print Network [OSTI]

    Kerschbaum, Franz

    2003-01-01

    A&A 403, 93­103 (2003) DOI: 10.1051/0004-6361:20030282 c ESO 2003 Astronomy & Astrophysics A census://cdsweb.u-strabg.fr/cgi-bin/qcat?J/A+A/403/93 stars in old stellar populations. They contribute

  20. Chemically bonded phospho-silicate ceramics

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Jeong, Seung Y. (Westmont, IL); Lohan, Dirk (Chicago, IL); Elizabeth, Anne (Chicago, IL)

    2003-01-01

    A chemically bonded phospho-silicate ceramic formed by chemically reacting a monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and a sparsely soluble oxide, with a sparsely soluble silicate in an aqueous solution. The monovalent alkali metal phosphate (or ammonium hydrogen phosphate) and sparsely soluble oxide are both in powder form and combined in a stochiometric molar ratio range of (0.5-1.5):1 to form a binder powder. Similarly, the sparsely soluble silicate is also in powder form and mixed with the binder powder to form a mixture. Water is added to the mixture to form a slurry. The water comprises 50% by weight of the powder mixture in said slurry. The slurry is allowed to harden. The resulting chemically bonded phospho-silicate ceramic exhibits high flexural strength, high compression strength, low porosity and permeability to water, has a definable and bio-compatible chemical composition, and is readily and easily colored to almost any desired shade or hue.

  1. SOCO-4-E Wholesale Power Rate Schedule | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterestedReplacement-2-AA-1 SECTION J APPENDIX ADepartmentSOCO-4-E Wholesale Power Rate

  2. FRN and Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Doing Business Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-16 Rate Case OS-14 Rate Case FRN...

  3. FRN & Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Doing Business Skip navigation links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases BP-16 Rate Case OS-14 Rate Case FRN...

  4. Municipal Bond - Power Purchase Agreement Model Continues to...

    Broader source: Energy.gov (indexed) [DOE]

    power purchase agreement model to provide low-cost solar energy. Author: National Renewable Energy Laboratory Municipal Bond - Power Purchase Agreement Model Continues to Provide...

  5. Qualified Energy Conservation Bond (QECB) Update: New Guidance...

    Office of Environmental Management (EM)

    clarification of what constitutes a qualified project for potential issuers of qualified energy conservation bond capacity. Author: Lawrence Berkeley National Laboratory Qualified...

  6. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  7. Qualified Energy Conservation Bonds (ŤQECBs?) & New Clean Renewable...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conservation Bonds (QECBs) may be issued by state, local and tribal governments to finance qualified energy conservation projects. A minimum of 70% of a state's allocation must...

  8. Douglas County School District (Nevada) Bonds Case Study | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bonds Case Study Douglas County School District faced a challenging combination of aging equipment and buildings (most over 37 years old), rising energy costs, and limited...

  9. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    2013-07-01

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  10. Chlorite Dissolution Rates

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Carroll, Susan

    Spreadsheets provides measured chlorite rate data from 100 to 300C at elevated CO2. Spreadsheet includes derived rate equation.

  11. Method of bonding single crystal quartz by field-assisted bonding

    DOE Patents [OSTI]

    Curlee, R.M.; Tuthill, C.D.; Watkins, R.D.

    1991-04-23

    The method of producing a hermetic stable structural bond between quartz crystals includes providing first and second quartz crystals and depositing thin films of borosilicate glass and silicon on portions of the first and second crystals, respectively. The portions of the first and second crystals are then juxtaposed in a surface contact relationship and heated to a temperature for a period sufficient to cause the glass and silicon films to become electrically conductive. An electrical potential is then applied across the first and second crystals for creating an electrostatic field between the adjoining surfaces and causing the juxtaposed portions to be attracted into an intimate contact and form a bond for joining the adjoining surfaces of the crystals. 2 figures.

  12. Flip chip electrical interconnection by selective electroplating and bonding

    E-Print Network [OSTI]

    Lin, Liwei

    Flip chip electrical interconnection by selective electroplating and bonding L.-W. Pan, P. Yuen, L resistance of the electroplating bond is 12 W. This process has potential applications in replacing-step approach for high-density electrical in- terconnection by using flip chip selective electroplating

  13. Proton Transfer and Hydrogen Bonding in Chemical and Biological

    E-Print Network [OSTI]

    Amrhein, Valentin

    Proton Transfer and Hydrogen Bonding in Chemical and Biological Systems: A Force Field Approach and support. i #12;ii #12;Abstract Proton transfer and hydrogen bonds are fundamental for the function be regarded as incipient proton transfer reactions, so theoretically they can be de- scribed in unitary way

  14. Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options

    E-Print Network [OSTI]

    Chaudhuri, Sanjay

    Quantum Finance Hamiltonian for Coupon Bond European and Barrier Options Belal E. Baaquie RMI are financial derivatives that can be analyzed in the Hamiltonian formulation of quantum finance. Forward-2963 Fax: (65) 6777-6126 Email: phybeb@nus.edu.sg #12;Quantum Finance Hamiltonian for Coupon Bond European

  15. Material Properties of Chemically Bonded Phosphate Ceramic/Wood Interfaces

    E-Print Network [OSTI]

    Collins, Gary S.

    Material Properties of Chemically Bonded Phosphate Ceramic/Wood Interfaces M.J. Benjamin, K Chemically bonded phosphate ceramics (CBPCs) are man made inorganic solids that lie in between hydraulic cements and ceramics . Normally, ceramics are sintered at temperatures ranging from 700-2000C

  16. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, Jr., Thomas M. (P.O. Box 4231, Clearwater, FL 33518); Wells, Barbara J. (865 N. Village Dr., Apt. 101B, St. Petersburg, FL 33702)

    1987-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40.degree. to 365.degree. C. to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  17. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, T.M. Jr.; Wells, B.J.

    1985-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  18. TBR 260-096-11 2.5 M ETSU is an AA/EEO employer.

    E-Print Network [OSTI]

    Karsai, Istvan

    TBR 260-096-11 2.5 M ETSU is an AA/EEO employer. FAFSA Tips Lottery Information File the FAFSA Hall, Room 105 P.O. Box 70722 Johnson City, TN 37614-1710 423.439.4300 1.800.704.ETSU (3878) Fax: 423.439.5855 ETSU School Code: 003487 www.etsu.edu/finaid finaid@etsu.edu Managing Your Money Don't live

  19. A&A 462, 7380 (2007) DOI: 10.1051/0004-6361:20065173

    E-Print Network [OSTI]

    Zhang, Bing

    2007-01-01

    A&A 462, 73­80 (2007) DOI: 10.1051/0004-6361:20065173 c ESO 2007 Astronomy & Astrophysics Swift. Mason12, F. Marshal6, P. Mészáros5,13, J. A. Nousek5, J. P. Osborne8, D. M. Palmer4, P. W. A. Roming5, A / Accepted 5 October 2006 ABSTRACT Context. Swift discovered the high redshift (z = 6.29) GRB 050904

  20. A&A 468, 571579 (2007) DOI: 10.1051/0004-6361:20054160

    E-Print Network [OSTI]

    Zhang, Bing

    2007-01-01

    A&A 468, 571­579 (2007) DOI: 10.1051/0004-6361:20054160 c ESO 2007 Astronomy & Astrophysics Swift-Raymont8, D. N. Burrows4, G. Chincarini6, A. J. Dean9, N. Gehrels10, H. Krimm10, F. Marshall10, A. M of 41 Swift observations which led to the detection of all these 23 blazars in the 0.3­10 keV band. We

  1. ALGEBRA e LOGICA CdL in Ingegneria Informatica --a.a. 2012/2013

    E-Print Network [OSTI]

    Gavarini, Fabio

    invece non fosse possibile, se ne spieghi il perch´e. (c) D315 `e un'algebra di Boole? D165 `e un'algebraALGEBRA e LOGICA CdL in Ingegneria Informatica -- a.a. 2012/2013 prof. Fabio GAVARINI Sessione di Boole? (N.B.: spiegare!) [2] Per xR0 sia x:=max { nN nx } l'"arrotondamento inferiore" di x . Sia

  2. Theoretical Electron Density Distributions for Fe-and Cu-Sulfide Earth Materials: A Connection between Bond Length, Bond Critical Point Properties, Local Energy Densities,

    E-Print Network [OSTI]

    Downs, Robert T.

    between Bond Length, Bond Critical Point Properties, Local Energy Densities, and Bonded Interactions G. V; In Final Form: December 6, 2006 Bond critical point and local energy density properties together with netTheoretical Electron Density Distributions for Fe- and Cu-Sulfide Earth Materials: A Connection

  3. Toward an understanding of the $R_{AA}$ and $v_2$ puzzle for heavy quarks

    E-Print Network [OSTI]

    Francesco Scardina; Santosh K Das; Salvatore Plumari; Jessica I. Bellone; Vincenzo Greco

    2015-09-04

    One of the primary aims of the ongoing nuclear collisions at Relativistic Heavy Ion Collider (RHIC) and Large Hadron Collider (LHC) energies is to create a Quark Gluon Plasma (QGP). The heavy quarks constitutes a unique probe of the QGP properties. Both at RHIC and LHC energies a puzzling relation between the nuclear modification factor $R_{AA}(p_T)$ and the elliptic flow $v_2(p_T)$ related to heavy quark has been observed which challenged all the existing models.\\\\ We discuss how the temperature dependence of the heavy quark drag coefficient can address for a large part of such a puzzle. We have considered four different models to evaluate the temperature dependence of drag and diffusion coefficients propagating through a quark gluon plasma (QGP). All the four different models are set to reproduce the same $R_{AA}(p_T)$ experimentally observed at RHIC energy. We have found that for the same $R_{AA}(p_T)$ one can generate $2-3$ times more $v_{2}$ depending on the temperature dependence of the heavy quark drag coefficient.

  4. Toward an understanding of the $R_{AA}$ and $v_2$ puzzle for heavy quarks

    E-Print Network [OSTI]

    Scardina, Francesco; Plumari, Salvatore; Bellone, Jessica I; Greco, Vincenzo

    2015-01-01

    One of the primary aims of the ongoing nuclear collisions at Relativistic Heavy Ion Collider (RHIC) and Large Hadron Collider (LHC) energies is to create a Quark Gluon Plasma (QGP). The heavy quarks constitutes a unique probe of the QGP properties. Both at RHIC and LHC energies a puzzling relation between the nuclear modification factor $R_{AA}(p_T)$ and the elliptic flow $v_2(p_T)$ related to heavy quark has been observed which challenged all the existing models.\\\\ We discuss how the temperature dependence of the heavy quark drag coefficient can address for a large part of such a puzzle. We have considered four different models to evaluate the temperature dependence of drag and diffusion coefficients propagating through a quark gluon plasma (QGP). All the four different models are set to reproduce the same $R_{AA}(p_T)$ experimentally observed at RHIC energy. We have found that for the same $R_{AA}(p_T)$ one can generate $2-3$ times more $v_{2}$ depending on the temperature dependence of the heavy quark drag...

  5. Vacuum pull down method for an enhanced bonding process

    DOE Patents [OSTI]

    Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    1999-01-01

    A process for effectively bonding arbitrary size or shape substrates. The process incorporates vacuum pull down techniques to ensure uniform surface contact during the bonding process. The essence of the process for bonding substrates, such as glass, plastic, or alloys, etc., which have a moderate melting point with a gradual softening point curve, involves the application of an active vacuum source to evacuate interstices between the substrates while at the same time providing a positive force to hold the parts to be bonded in contact. This enables increasing the temperature of the bonding process to ensure that the softening point has been reached and small void areas are filled and come in contact with the opposing substrate. The process is most effective where at least one of the two plates or substrates contain channels or grooves that can be used to apply vacuum between the plates or substrates during the thermal bonding cycle. Also, it is beneficial to provide a vacuum groove or channel near the perimeter of the plates or substrates to ensure bonding of the perimeter of the plates or substrates and reduce the unbonded regions inside the interior region of the plates or substrates.

  6. Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional Vibrational Stimulated Echoes

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dynamics Probed with Ultrafast Infrared Heterodyne-Detected Multidimensional, USA (Received 24 February 2003; published 3 December 2003) Hydrogen bond dynamics are explicated hydrogen bonded network are measured with ultrashort (

  7. 2004 Rate Adjustments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Transmission and Ancillary Services Federal Register Notice -- Rate Order WAPA-141: Notice of Extension of Formula Rates for Transmission and Ancillary Services If you have any...

  8. Rate Schedule CPP-2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    points established by contract, in accordance with approved policies and procedures. Formula Rate: The formula rate for CPP includes three components: Component 1: The customer...

  9. Wire bond vibration of forward pixel tracking detector of CMS

    SciTech Connect (OSTI)

    Atac, M.; /Fermilab; Gobbi, B.; /Northwestern U.; Kwan, S.; Pischalnikov, Y.; /Fermilab; Spencer, E.; /Northwestern U.; Sellberg, G.; Pavlicek, V.; /Fermilab

    2006-10-01

    Wire bonds of the Forward Pixel (FPix) tracking detectors are oriented in the direction that maximizes Lorentz Forces relative to the 4 Tesla field of the Compact Muon Solenoid (CMS) Detector's magnet. The CMS Experiment is under construction at the Large Hadron Collider at CERN, Geneva, Switzerland. We were concerned about Lorentz Force oscillating the wires at their fundamental frequencies and possibly fracturing or breaking them at their heels, as happened with the CDF wire bonds. This paper reports a study to understand what conditions break such bonds.

  10. Hydrogen-Bond Networks: Strengths of Different Types of Hydrogen Bonds and An Alternative to the Low Barrier Hydrogen-Bond Proposal

    SciTech Connect (OSTI)

    Shokri, Alireza; Wang, Yanping; O'Doherty, George A.; Wang, Xue B.; Kass, Steven R.

    2013-11-27

    We report quantifying the strengths of different types of hydrogen bonds in hydrogen bond networks (HBNs) via measurement of the adiabatic electron detachment energy of the conjugate base of a small covalent polyol model compound (i.e., (HOCH2CH2CH(OH)CH2)2CHOH) in the gas phase and the pKa of the corresponding acid in DMSO. The latter result reveals that the hydrogen bonds to the charged center and those that are one solvation shell further away (i.e., primary and secondary) provide 5.3 and 2.5 pKa units of stabilization per hydrogen bond in DMSO. Computations indicate that these energies increase to 8.4 and 3.9 pKa units in benzene and that the total stabilizations are 16 (DMSO) and 25 (benzene) pKa units. Calculations on a larger linear heptaol (i.e., (HOCH2CH2CH(OH)CH2CH(OH)CH2)2CHOH) reveal that the terminal hydroxyl groups each contribute 0.6 pKa units of stabilization in DMSO and 1.1 pKa units in benzene. All of these results taken together indicate that the presence of a charged center can provide a powerful energetic driving force for enzyme catalysis and conformational changes such as in protein folding due to multiple hydrogen bonds in a HBN.

  11. Low temperature transient liquid phase bonding of copper

    E-Print Network [OSTI]

    Williams, Joel C. (Joel Carlton)

    2005-01-01

    This thesis describes a Pb-free solder alternative that is capable of fluxless bonding. The main advantage of this process is that it offers the benefits of low fabrication temperature (125?C) while producing a joint capable ...

  12. MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD

    E-Print Network [OSTI]

    Nairn, John A.

    MODE II FRACTURE BEHAVIOR OF BONDED VISCOELASTIC THERMAL COMPRESSED WOOD Andreja Kutnar* Graduate Student Department of Wood Science and Technology Biotechnical Faculty University of Ljubljana 1000 Ljubljana, Slovenia Frederick A. Kamke Professor John A. Nairn Professor Department of Wood Science

  13. Mpemba paradox: Hydrogen bond memory and water-skin supersolidity

    E-Print Network [OSTI]

    Chang Q Sun

    2015-01-05

    Numerical reproduction of measurements, experimental evidence for skin super-solidity and hydrogen-bond memory clarified that Mpemba paradox integrates the heat emission-conduction-dissipation dynamics in the source-path-drain cycle system.

  14. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  15. Application of Social Impact Bonds in Built Infrastructure Sustainability Projects 

    E-Print Network [OSTI]

    White, Robert Joseph

    2014-05-01

    This study examines a first look at the implementation of Social Impact Bonds (SIB) for sustainability projects by comparing two cases. The cases are described using System Dynamic (SD) modeling to portray the feedback structures and characteristics...

  16. Bond graph models of electromechanical systems. The AC generator case

    E-Print Network [OSTI]

    Batlle, Carles

    Bond graph models of electromechanical systems. The AC generator case Carles Batlle Department. After reviewing electromechanical energy conversion and torque gener- ation, the core element present in any electromechanical system is introduced, and the corresponding electrical and mechanical ports

  17. Reply to comment on "Quantum Confinement in Hydrogen Bond"

    E-Print Network [OSTI]

    Santos, Carlos da Silva dos; Ricotta, Regina Maria

    2015-01-01

    We reply to the comments on our paper "Quantum Confinement in Hydrogen Bond" (Int. J. Quantum Chem. 115 (2015) 765 DOI: 10.1002/qua.24894) made by Matthias Heger and Martin A. Suhm.

  18. Influence of receptor flexibility on intramolecular H-bonding interactions

    E-Print Network [OSTI]

    Sun, Hongmei; Guo, Kai; Gan, Haifeng; Li, Xin; Hunter, Christopher A.

    2015-01-01

    Atropisomers of a series of zinc tetraphenyl porphyrins were synthesized and used as supramolecular receptors. Rotation around the porphyrin-meso phenyl bonds is restricted by installing ortho-chlorine substituents on the phenyl groups. The chlorine...

  19. IRS Announces New Tribal Economic Development Bond Allocation Guidance

    Broader source: Energy.gov [DOE]

    Treasury and the IRS published new guidance today allocating Tribal Economic Development Bonds (TEDBs) for Tribes that have projects that are in the final stages of going to the market to receive financing.

  20. Low-Cost Financing with Clean Renewable Energy Bonds

    Broader source: Energy.gov [DOE]

    Contains information from the TAP Webcast on June 24, 2009 on clean renewable energy bonds from Claire Kreycik on feed-in tariffs, an economic resource for developing renewable energy.

  1. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Time-Resolved Study of Bonding in Liquid Carbon Print We are accustomed to observing carbon in its elemental form as a solid, ranging from the soft "lead" in pencils to the...

  2. The Geography of European Convertible Bonds: Why Firms Issue Convertibles?

    E-Print Network [OSTI]

    Saskatchewan, University of

    1 The Geography of European Convertible Bonds: Why Firms Issue Convertibles? Franck Bancel Usha R at the geography of CB issuance. The size and development of the CB market varies widely across countries and over

  3. Understanding mechanisms for C-H bond activation 

    E-Print Network [OSTI]

    Vastine, Benjamin Alan

    2009-05-15

    The results from density functional theory (DFT) studies into C–H bond activation, hydrogen transfer, and alkyne–to–vinylidene isomerization are presented in this work. The reaction mechanism for the reductive elimination ...

  4. Session 30.02, AAS San Diego, 10 Jan 2005Gelbord et al.: The Unique Quasar Jet of PKS 1421-490 The Unique, Optically-Dominated

    E-Print Network [OSTI]

    Gelbord, Jonathan

    Session 30.02, AAS San Diego, 10 Jan 2005Gelbord et al.: The Unique Quasar Jet of PKS 1421 (SAO) E.S. Perlman & M. Georganopoulos (UMBC) D.W. Murphy (JPL) #12;Session 30.02, AAS San Diego, 10 poster 144.03 for deeper Chandra and HST follow-up. #12;Session 30.02, AAS San Diego, 10 Jan 2005Gelbord

  5. Method of making sintered ductile intermetallic-bonded ceramic composites

    DOE Patents [OSTI]

    Plucknett, K.; Tiegs, T.N.; Becher, P.F.

    1999-05-18

    A method of making an intermetallic-bonded ceramic composite involves combining a particulate brittle intermetallic precursor with a particulate reactant metal and a particulate ceramic to form a mixture and heating the mixture in a non-oxidizing atmosphere at a sufficient temperature and for a sufficient time to react the brittle intermetallic precursor and the reactant metal to form a ductile intermetallic and sinter the mixture to form a ductile intermetallic-bonded ceramic composite. 2 figs.

  6. Bonded Bracket Assmebly for Frameless Solar Panels

    SciTech Connect (OSTI)

    Murray, Todd

    2013-01-30

    In February 2011 the US Department of Energy announced their new Sunshot Initiative. The Sunshot goal is to reduce the total cost of solar energy systems by about 75 percent before the end of the decade. The DOE estimated that a total installed cost of $1 per watt for photovoltaic systems would be equivalent to 6���¢/kilowatt hour (kWh) for energy available from the grid. The DOE also estimated that to meet the $1 per watt goal, PV module costs would need to be reduced to $.50 per watt, balance of systems costs would need to be reduced to $.40 per watt, and power electronic costs would need to reach $.10 per watt. To address the BOS balance of systems cost component of the $1 per watt goal, the DOE announced a funding opportunity called (BOS-X) Extreme Balance of System Hardware Cost Reductions. The DOE identified eight areas within the total BOS costs: 1) installation labor, 2) installation materials, 3) installation overhead and profit, 4) tracker, 5) permitting and commissioning, 6) site preparation, 7) land acquisition, 8) sales tax. The BOS-X funding announcement requested applications in four specific topics: Topic 1: Transformational Building Integrated Photovoltaic (BIPV) Modules Topic 2: Roof and Ground Mount Innovations Topic 3: Transformational Photovoltaic System Designs Topic 4: Development of New Wind Load Codes for PV Systems The application submitted by ARaymond Tinnerman reflected the requirements listed in Topic #2, Roof and Ground Mount Innovations. The goal of topic #2 was to develop technologies that would result in the extreme reduction of material and labor costs associated with applications that require physical connections and attachments to roof and ground mount structures. The topics researched in this project included component cost reduction, labor reduction, weight reduction, wiring innovations, and alternative material utilization. The project objectives included: 1) The development of an innovative quick snap bracket assembly that would be bonded to frameless PV modules for commercial rooftop installations. 2) The development of a composite pultruded rail to replace traditional racking materials. 3) In partnership with a roofing company, pilot the certification of a commercial roof to be solar panel compliant, eliminating the need for structural analysis and government oversight resulting in significantly decreased permitting costs. 4) Reduce the sum of all cost impacts in topic #2 from a baseline total of $2.05/watt to $.34/watt.

  7. The Breathing Orbital Valence Bond Method in Diffusion Monte Carlo: C-H Bond Dissociation of Acetylene

    E-Print Network [OSTI]

    Braida, Benoit

    2009-01-01

    Quantum Chem. 2005, (19) Barnett, R. N. ; Sun, Z. ; Lester,In a systematic DMC study, Barnett et al. 19 explored thefor the C-H bond distance. Barnett et al. reported 1-CSF DMC

  8. Monte-Carlo study of the phase transition in the AA-stacked bilayer graphene

    E-Print Network [OSTI]

    A. A. Nikolaev; M. V. Ulybyshev

    2014-12-04

    Tight-binding model of the AA-stacked bilayer graphene with screened electron-electron interactions has been studied using the Hybrid Monte Carlo simulations on the original double-layer hexagonal lattice. Instantaneous screened Coulomb potential is taken into account using Hubbard-Stratonovich transformation. G-type antiferromagnetic ordering has been studied and the phase transition with spontaneous generation of the mass gap has been observed. Dependence of the antiferromagnetic condensate on the on-site electron-electron interaction is examined.

  9. Bond-valence methods for pKa prediction. II. Bond-valence, electrostatic, molecular geometry, and solvation effects

    SciTech Connect (OSTI)

    Bickmore, Barry R.; Rosso, Kevin M.; Tadanier, Christopher J.; Bylaska, Eric J.; Doud, Darrin

    2006-08-15

    In a previous contribution, we outlined a method for predicting (hydr)oxy-acid and oxide surface acidity constants based on three main factors: bond valence, Me?O bond ionicity, and molecular shape. Here electrostatics calculations and ab initio molecular dynamics simulations are used to qualitatively show that Me?O bond ionicity controls the extent to which the electrostatic work of proton removal departs from ideality, bond valence controls the extent of solvation of individual functional groups, and bond valence and molecular shape controls local dielectric response. These results are consistent with our model of acidity, but completely at odds with other methods of predicting acidity constants for use in multisite complexation models. In particular, our ab initio molecular dynamics simulations of solvated monomers clearly indicate that hydrogen bonding between (hydr)oxo-groups and water molecules adjusts to obey the valence sum rule, rather than maintaining a fixed valence based on the coordination of the oxygen atom as predicted by the standard MUSIC model.

  10. On the competition between hydrogen abstraction versus C-O bond fission in initiating dimethyl ether combustion

    SciTech Connect (OSTI)

    Francisco, J.

    1999-07-01

    There has been a growing interest in the potential use of dimethyl ether (DME) as a diesel fuel in compression ignition engines. There are two initiation steps involved in the combustion of DME, one involving C-O bond fission and the other involving hydrogen abstraction by molecular oxygen. The kinetics and thermodynamics of C-O bond fission were explored computationally in a previous paper. The present paper addresses the competing process--hydrogen abstraction by molecular oxygen. Ab initio molecular orbital calculations are used to study the structures and energetics of the reactants, products, and the transition state for the CH{sub 3}OCH{sub 3} + O{sub 2} reaction. The calculations predict a barrier for hydrogen abstraction from CH{sub 3}OCH{sub 3} by O{sub 2} of 47.4 kcal/mol. This is lower than the barrier height for C-O bond fission previously calculated to be 81.1 kcal/mol. The results support values used in current models for the combustion of DME. Moreover, an examination of rates for C-O bond fission versus hydrogen abstraction by O{sub 2} suggests that the bimolecular process is the dominant pathway.

  11. Lesson 22 Related Rates

    E-Print Network [OSTI]

    2013-10-11

    Oct 11, 2013 ... A spherical weather balloon is being inflated with helium at a rate of 82 cubic meters per minute. Find the rate at which its radius is increasing.

  12. Naughton's related rates problems

    E-Print Network [OSTI]

    dominic

    2013-02-25

    Related rates (1). (1) Oil spills from a rupture container in a circular pattern whose radius increases at a rate of 2 ft/s. How fast is the area of the oil spill increasing ...

  13. The C OH O hydrogen bond: A determinant of stability and specificity

    E-Print Network [OSTI]

    Senes, Alessandro

    recovered by hydro- gen bond formation, so hydrogen bonds provide a small or even unfavorable net energy hydro- gen bond has been unclear and its interaction energy has been believed to be small. Recently that apparent carbon hydro- gen bonds cluster frequently at glycine-, serine-, and threonine-rich packing

  14. Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

  15. Hydrogen bonding between neon and hydrogen fluoride M. Losonczy and J. W. Moskowitz*

    E-Print Network [OSTI]

    Stillinger, Frank

    Hydrogen bonding between neon and hydrogen fluoride M. Losonczy and J. W. Moskowitz* Chemistry of hydrogen fluoride. The results exhibit formation of a linear hydrogen bond. Although this bond is weak (0.234 kcal!mole), its strength exceeds that found earlier for the neon-water hydrogen bond. I. INTRODUCTION

  16. A new hydrogen-bonding potential for the design of proteinRNA interactions predicts specific

    E-Print Network [OSTI]

    Baker, David

    A new hydrogen-bonding potential for the design of protein­RNA interactions predicts specific-dependent hydrogen-bonding potential based on the statistical analysis of hydrogen-bonding geometries of hydrogen-bonding atom pairs at protein­ nucleic acid interfaces. A scoring function based on the hydrogen

  17. Thermal Performance and Reliability of Bonded Interfaces for Power Electronics Packaging Applications (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2013-07-01

    This presentation discusses the thermal performance and reliability of bonded interfaces for power electronics packaging applications.

  18. Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke

    E-Print Network [OSTI]

    Snoke, David

    Comparison of bond character in hydrocarbons and fullerenes D. W. Snoke Department of Physics a comparison of the bond polarizabilities for carbon-carbon bonds in hydrocarbons and fullerenes, using two and ethylene. We find that the polarizabilities for single bonds in fullerenes and hydrocarbons compare well

  19. CITY, Aa.

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbins and Myers Co -VANaval ,, *' ; .BETHLEHEM$f 2c I..:..

  20. Effect of hydrogen bond on coal extraction by in-situ vacuum FTIR

    SciTech Connect (OSTI)

    Li, J.; Feng, J.; Li, W.Y.; Chang, H.Z.; Xie, K.C. [Taiyuan University of Technol, Taiyuan (China)

    2009-07-01

    Coal chemical formation environment might result in different properties of hydrogen bonds in coal structure. The thermo stability, amount and types of hydrogen bond in six typical Chinese coal macerals were investigated by in situ vacuum Fourier transform infrared spectroscopy (FTIR). It was found that three types of hydrogen bond were involved in coal structure, which were OH-N, OH self associated, and OH tetrapolymer hydrogen bond. There was no correlation between the amount of three types of hydrogen bonds and extraction yield. The thermo stability of hydrogen bond in inertinite was stronger than that of vitrinite, especially the thermo stability of hydrogen bond in Pingshuo inertinite.

  1. A_+/A_-, alpha, nu, and f_s xi^3 from 3D Ising Energy and Specific Heat

    E-Print Network [OSTI]

    M. Hasenbusch; K. Pinn

    1997-05-31

    We analyse Monte Carlo data for the energy and specific heat at and close to the critical point of the 3D cubic Ising model. From the finite size scaling of the energy E and the specific heat C at criticality we obtain the estimate nu = 0.6308(10). Furthermore, one obtains precise estimates for the ``backgrounds'' (nonsingular parts) E_ns and C_ns. Fitting solely off critical energy estimates to a scaling law, we find depending on the choice of the reduced temperature, either A_+/A_- = 0.550(12) and alpha=0.1115(37), or A_+/A_- = 0.567(16) and alpha=0.1047(48). Including information from the data at T_c, we obtain the estimate A_+/A_- = 0.560(10). We also determine the universal combination f_s xi^3 in both phases.

  2. Current Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding in ActinideRailCurrent Research Portfolio Sign

  3. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA New SolarA PresentFilm Alloys -AA

  4. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.TheoryTuesday, August 10, 20102016 News BelowAsked toUSC-Aiken,A NewAA Surprising

  5. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  6. BBIIOOLLOOGGYY SSEEMMIINNAARR AAFF FF II LL II AA TT EE AAPP PP OO II NN TT MM EE NN TT LLEE CC TT UU RR EE

    E-Print Network [OSTI]

    Brown, Sally

    BBIIOOLLOOGGYY SSEEMMIINNAARR AAFF FF II LL II AA TT EE AAPP PP OO II NN TT MM EE NN TT LLEE CC TT UU RR EE 44::0000 PPMM SSEE MM II NNAA RR PPHH YY SSII CCSS //AASS TTRR OONN OO MM YY AAUU DD .. AA

  7. "Gondwana Dispersion and Asian Accretion (Metcalfe, I., Ren Jishun, Chalvet, J. & Hada, S. eds.)", A.A. Balkema Publishers, Rotterdam & Brookfield, pp.361, 1999.

    E-Print Network [OSTI]

    Banbara, Mutsunori

    .)", A.A. Balkema Publishers, Rotterdam & Brookfield, pp.361, 1999. "Rift-drift history and Asian Accretion: 67-87. Rotterdam, A.A. Balkema Publ., 1999. "Catastrophic Loess, mass mortality". Journal of the Geological Society of Thailand, No.1, 1-17, 1999. "Asian accretion of Gondwanaland

  8. UW AA Account Setup and Lab-Use Primer Aero/Astro Account Primer 10/10/14 Page 1 of 7

    E-Print Network [OSTI]

    Doty, Sharon Lafferty

    UW AA Account Setup and Lab-Use Primer Aero/Astro Account Primer 10/10/14 Page 1 of 7 You are provided with access to UW Aero/Astro departmental computing resources on entering the department as an option for long-term storage and #12;UW AA Account Setup and Lab-Use Primer Aero/Astro Account Primer 10

  9. Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation

    SciTech Connect (OSTI)

    Colby, Denise; Bergman, Robert; Ellman, Jonathan

    2010-05-13

    Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

  10. On the Use of a Driven Wedge Test to Acquire Dynamic Fracture Energies of Bonded Beam Specimens

    SciTech Connect (OSTI)

    Dillard, David A. [Virginia Polytechnic Institute and State University (Virginia Tech); Pohilt, David [Engineering Science and Mechanics Department, Virginia Tech, Blacksburg, VA, USA; Jacob, George Chennakattu [ORNL; Starbuck, Michael [Materials Science and Engineering Department, University of Tennessee, Knoxville, TN, USA; Rakesh, Kapania [Aerospace and Ocean Engineering Department, Virginia Tech, Blacksburg, VA, USA

    2011-01-01

    A driven wedge test is used to characterize the mode I fracture resistance of adhesively bonded composite beam specimens over a range of crosshead rates up to 1 m/s. The shorter moment arms (between wedge contact and crack tip) significantly reduce inertial effects and stored energy in the debonded adherends, when compared with conventional means of testing double cantilever beam (DCB) specimens. This permitted collecting an order of magnitude more crack initiation events per specimen than could be obtained with end-loaded DCB specimens bonded with an epoxy exhibiting significant stick-slip behavior. The localized contact of the wedge with the adherends limits the amount of both elastic and kinetic energy, significantly reduces crack advance during slip events, and facilitates higher resolution imaging of the fracture zone with high speed imaging. The method appears to work well under both quasi-static and high rate loading, consistently providing substantially more discrete fracture events for specimens exhibiting pronounced stick-slip failures. Deflections associated with beam transverse shear and root rotation for the shorter beams were not negligible, so simple beam theory was inadequate for obtaining qualitative fracture energies. Finite element analysis of the specimens, however, showed that fracture energies were in good agreement with values obtained from traditional DCB tests. The method holds promise for use in dynamic testing and for characterizing bonded or laminated materials exhibiting significant stick slip behavior, reducing the number of specimens required to characterize a sufficient number of fracture events.

  11. Female chacma baboons form strong, equitable, and enduring social bonds

    E-Print Network [OSTI]

    2010-01-01

    continuous response variables (CSI, conflict rate, proportioncontinuous response variables (CSI, extent of grooming equality, rate of conflict, proportion

  12. COMPARISON OF AIR AND DEUTERIUM ON PINCH WELD BOND APPEARANCE

    SciTech Connect (OSTI)

    Korinko, P

    2005-10-11

    The effect that air and deuterium internal atmospheres have on the pinch weld bond quality was evaluated by conducting a scoping study using type 304L stainless steel LF-7 test stems that were fabricated for an associated study. Welds were made under cool, yet nominal conditions to exacerbate the influence of the atmosphere. The bond quality of the welds was directly related to the internal atmosphere with the air atmosphere welds being of lower quality than the deuterium atmosphere welds for nominally identical welding conditions.

  13. Resonant thermonuclear reaction rate

    SciTech Connect (OSTI)

    Haubold, H.J.; Mathai, A.M.

    1986-08-01

    Basic physical principles for the resonant and nonresonant thermonuclear reaction rates are applied to find their standard representations for nuclear astrophysics. Closed-form representations for the resonant reaction rate are derived in terms of Meijer's G-italic-function. Analytic representations of the resonant and nonresonant nuclear reaction rates are compared and the appearance of Meijer's G-italic-function is discussed in physical terms.

  14. Using Qualified Energy Conservation Bonds for Public Building Upgrades. Reducing Energy Bills in the City of Philadelphia

    SciTech Connect (OSTI)

    Zimring, Mark

    2012-07-18

    Qualified Energy Conservation Bonds (QECBs) are federally-subsidized bonds that enable state, tribal, and local government issuers to borrow money to fund a range of energy conservation projects, including public building upgrades that reduce energy use by at least 20 percent, at very attractive borrowing rates and long terms. As part of the American Recovery and Reinvestment Act (ARRA), the City of Philadelphia received a $15 million QECB award from the U.S. Department of the Treasury (Treasury). The city leveraged $6.25 million of its QECB allocation to finance half of a $12.6 million initiative to upgrade the energy efficiency of City buildings. The upgrades to four city facilities are expected to deliver over $10 million of net savings, and are a major step towards achieving the city’s goal of reducing government energy consumption by 30 percent by 2015.

  15. LCC Guidance Rates

    Office of Energy Efficiency and Renewable Energy (EERE)

    Notepad text file provides the LCC guidance rates in a numbered format for the various regions throughout the U.S.

  16. A.A. 2014/2015 L_SNT3 Tecniche di radiologia medica, per immagini e

    E-Print Network [OSTI]

    Bella, Giampaolo

    A.A. 2014/2015 L_SNT3 Tecniche di radiologia medica, per immagini e radioterapia (abilitante alla professione sanitaria di Tecnico di radiologia medica) Info Generali Presentazione del Corso INFO Generali;Presentazione del corso Il Corso di Studio in breve Il Corso di Studio in Tecniche di radiologia medica per

  17. Studying the Retina and Other Neurosystems A.A. Grillo Studying the Retina andStudying the Retina and

    E-Print Network [OSTI]

    Deutsch, Josh

    technologies to conduct such studies is often an important part of Experimental Particle Physics. (See previous and Super Symmetry #12;7-Nov-2006 6 Studying the Retina and Other Neurosystems A.A. Grillo SCIPP-UCSC Some of the ChallengesSome of the Challenges · Each interaction of the colliding beams of protons (occurring 40 million

  18. PUBLICATIONS 2001 * Amode M., S. Pawson, A.A. Scaife, W. Lahoz, U. Langematz, Ding Min Li, and P.

    E-Print Network [OSTI]

    Ribes, Aurélien

    PUBLICATIONS 2001 * Amodeď M., S. Pawson, A.A. Scaife, W. Lahoz, U. Langematz, Ding Min Li, and P. Simon, 2001 : SAO and Kelvin waves in the EuroGRIPS GCMSs and the UK Meteorological Office analyses, Annales Geophysicae, vol 19, n°1. * Bechtold, P. and E. Bazile, 2001: The 12-13 november flush flood

  19. Directed aerial robot explorers for planetary exploration A.A. Pankine a,*, K.M. Aaron a

    E-Print Network [OSTI]

    Lorenz, Ralph D.

    Directed aerial robot explorers for planetary exploration A.A. Pankine a,*, K.M. Aaron a , M architecture relies upon the use of Directed Aerial Robot Explorers (DAREs), which essentially are long. Published by Elsevier Ltd. All rights reserved. Keywords: Scientific ballooning; Direct Aerial Robot

  20. A Virtual DSP System for Design Instruction of Power Converters AA.. KKeeyyhhaannii aanndd MM.. NN.. MMaarrwwaallii GGeerraalldd BBaauummggaarrttnneerr

    E-Print Network [OSTI]

    Baumgartner, Gerald

    1 A Virtual DSP System for Design Instruction of Power Converters AA.. KKeeyyhhaannii aanndd MM the development of an object oriented DSP based for design and control of power converters. The testbed `hard' switching power converters, a resonant converter utilizes a controlled series or parallel LC

  1. Mild Catalytic methods for Alkyl-Alkyl Bond Formation

    SciTech Connect (OSTI)

    Vicic, David A

    2009-08-10

    Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

  2. Enantioselective nickel catalysis : exploiting activated C-H bonds

    E-Print Network [OSTI]

    Bencivenga, Nicholas Ernest

    2012-01-01

    A method for the nickel-catalyzed cross-coupling between benzoxazole and secondary halides was explored. This method was to make use of the activated C-H bond found in benzoxazole at the 2-position to generate the nucleophilic ...

  3. Water inertial reorientation: Hydrogen bond strength and the angular potential

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

  4. FULL ARTICLE Bond-selective imaging of deep tissue

    E-Print Network [OSTI]

    Cheng, Ji-Xin

    FULL ARTICLE Bond-selective imaging of deep tissue through the optical window between 1600 and 1850 of Biomedical Engineering, Purdue University, West Lafayette, IN 47907, USA 2 Department of Cellular 2011, accepted 12 November 2011 Published online 29 November 2011 Key words: optical window, deep

  5. Actuated Transitory Metal-Ligand Bond As Tunable Electromechanical Switch

    E-Print Network [OSTI]

    Ortega, Enrique

    a copper atom and coordinating organic molecules adsorbed on a metal surface acts as variable frequency of STM is the on-demand forma- tion and breaking of chemical bonds with atomic precision. Furthermore-vinyl)] benzoic acid (hereafter referred to as PVBA) with copper adatoms on the Cu (111) surface.26

  6. WHAT'S GRAPHENE? Mono or few layers of sp2 bonded

    E-Print Network [OSTI]

    Mellor-Crummey, John

    WHAT'S GRAPHENE? · Mono or few layers of sp2 bonded carbon atoms in a honeycomb lattice 105cm2/Vs at RT. 1 Due to its unique transport properties, graphene is suitable for implementation sampling (EOS) timeresolved spectroscopy to optically pump and THz probe exfoliated graphene ribbons (GR

  7. Process for protecting bonded components from plating shorts

    DOE Patents [OSTI]

    Tarte, Lisa A. (Livermore, CA); Bonde, Wayne L. (Pleasanton, CA); Carey, Paul G. (Mountain View, CA); Contolini, Robert J. (Pleasanton, CA); McCarthy, Anthony M. (Menlo Park, CA)

    2000-01-01

    A method which protects the region between a component and the substrate onto which the components is bonded using an electrically insulating fillet of photoresist. The fillet protects the regions from subsequent plating with metal and therefore shorting the plated conductors which run down the sides of the component and onto the substrate.

  8. July 18, 2012 Using Qualified Energy Conservation Bonds for Public

    E-Print Network [OSTI]

    energy use by 4.9 percent and saved approximately $4 million, primarily through reduced vehicle fuel use) as a tool that had potential to reduce the barriers to further energy savings in city- owned facilities.4July 18, 2012 Using Qualified Energy Conservation Bonds for Public Building Upgrades: Reducing

  9. A Pact with the Devil Mike Bond and George Danezis

    E-Print Network [OSTI]

    Danezis, George

    be damned." The Tragicall History of D. Faustus -- Christopher Marlowe Computer viruses and their payloads computer), through user education, to sophisticated anti-virus software, which today include full virtualA Pact with the Devil Mike Bond and George Danezis Computer Laboratory, University of Cambridge, 15

  10. Hydrogen Bonding Increases Packing Density in the Protein Interior

    E-Print Network [OSTI]

    Hydrogen Bonding Increases Packing Density in the Protein Interior David Schell,1,2 Jerry Tsai,1 J System Health Science Center, College Station, Texas 77843-1114 ABSTRACT The contribution of hydrogen to the stability, but experimental studies show that bury- ing polar groups, especially those that are hydrogen

  11. Method of preparation of bonded polyimide fuel cell package

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Jankowski, Alan (Livermore, CA); Graff, Robert T. (Modesto, CA); Bettencourt, Kerry (Dublin, CA)

    2011-04-26

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  12. Chemical Shielding Tensors for a Silicon-Carbon Double Bond

    E-Print Network [OSTI]

    Apeloig, Yitzhak

    Chemical Shielding Tensors for a Silicon-Carbon Double Bond Jarrod J. Buffy, Robert West,*, Michael of NMR chemical shielding tensors (CST) have been important in aiding the understanding of the nature shielding tensors have been reported and interpreted for compounds containing SidSi,1 PdP,2 SndSn,3 Cd

  13. Bonded polyimide fuel cell package and method thereof

    SciTech Connect (OSTI)

    Morse, Jeffrey D.; Jankowski, Alan; Graff, Robert T.; Bettencourt, Kerry

    2005-11-01

    Described herein are processes for fabricating microfluidic fuel cell systems with embedded components in which micron-scale features are formed by bonding layers of DuPont Kapton.TM. polyimide laminate. A microfluidic fuel cell system fabricated using this process is also described.

  14. Power Rate Cases (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgram Guidelines This document w w w.pv - te ch.orgPower PlantRates >

  15. Power Rates Announcements (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeedingProgram Guidelines This document w w w.pv - te ch.orgPower PlantRates >

  16. Rates Meetings and Workshops (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on GlobalRachel2RateCaseElements Sign In About | FY

  17. Previous Power Rates (rates/current)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-Rich Matrices in Hydrothermal PlumesPress1,Previous EventsRates

  18. Polyurethane spray coating of aluminum wire bonds to prevent corrosion and suppress resonant oscillations

    E-Print Network [OSTI]

    Izen, Joseph; The ATLAS collaboration; Kurth, Matthew Glenn

    2015-01-01

    Unencapsulated aluminum wedge wire bonds are common in particle-physics pixel and strip detectors. Industry-favored bulk encapsulation is eschewed due to the range of operating temperatures and radiation. Wire bond failures are a persistent, source of tracking detector failure Unencapsulated bonds are vulnerable to condensation-induced corrosion, particularly when halides are present. Oscillations from periodic Lorenz forces are documented as another source of wire bond failure. Spray application of polyurethane coatings, performance of polyurethane-coated wire bonds after climate chamber exposure, and resonant properties of PU-coated wire bonds and their resistance to periodic Lorenz forces will be described.

  19. IMAGING THE DISK AND JET OF THE CLASSICAL T TAURI STAR AA TAU

    SciTech Connect (OSTI)

    Cox, Andrew W.; Grady, Carol A.; Hammel, Heidi B.; Hornbeck, Jeremy; Russell, Ray W.; Sitko, Michael L.; Woodgate, Bruce E.

    2013-01-01

    Previous studies of the classical T Tauri star AA Tau have interpreted the UX-Orionis-like photo-polarimetric variability as being due to a warp in the inner disk caused by an inclined stellar magnetic dipole field. We test that these effects are macroscopically observable in the inclination and alignment of the disk. We use Hubble Space Telescope (HST)/STIS coronagraphic imagery to measure the V magnitude of the star for both STIS coronagraphic observations, compare these data with optical photometry in the literature, and find that, unlike other classical T Tauri stars observed in the same HST program, the disk is most robustly detected in scattered light at stellar optical minimum light. We measure the outer disk radius, 1.''15 {+-} 0.''10, major-axis position angle, and disk inclination and find that the inner disk, as reported in the literature, is both misinclined and misaligned with respect to the outer disk. AA Tau drives a faint jet, detected in both STIS observations and in follow-on Goddard Fabry-Perot imagery, which is also misaligned with respect to the projection of the outer disk minor axis and is poorly collimated near the star, but which can be traced 21'' from the star in data from 2005. The measured outer disk inclination, 71 Degree-Sign {+-} 1 Degree-Sign , is out of the range of inclinations suggested for stars with UX-Orionis-like variability when no grain growth has occurred in the disk. The faintness of the disk, small disk size, and detection of the star despite the high inclination all indicate that the dust disk must have experienced grain growth and settling toward the disk midplane, which we verify by comparing the observed disk with model imagery from the literature.

  20. Method for producing chemically bonded phosphate ceramics and for stabilizing contaminants encapsulated therein utilizing reducing agents

    DOE Patents [OSTI]

    Singh, Dileep (Naperville, IL); Wagh, Arun S. (Orland Park, IL); Jeong, Seung-Young (Westmont, IL)

    2000-01-01

    Known phosphate ceramic formulations are improved and the ability to produce iron-based phosphate ceramic systems is enabled by the addition of an oxidizing or reducing step during the acid-base reactions that form the phosphate ceramic products. The additives allow control of the rate of the acid-base reactions and concomitant heat generation. In an alternate embodiment, waste containing metal anions are stabilized in phosphate ceramic products by the addition of a reducing agent to the phosphate ceramic mixture. The reduced metal ions are more stable and/or reactive with the phosphate ions, resulting in the formation of insoluble metal species within the phosphate ceramic matrix, such that the resulting chemically bonded phosphate ceramic product has greater leach resistance.

  1. Processing and Protection of Rare Earth Permanent Magnet Particulate for Bonded Magnet Applications

    SciTech Connect (OSTI)

    Peter Kelly Sokolowski

    2007-12-01

    Rapid solidification of novel mixed rare earth-iron-boron, MRE{sub 2}Fe{sub 14}B (MRE = Nd, Y, Dy; currently), magnet alloys via high pressure gas atomization (HPGA) have produced similar properties and structures as closely related alloys produced by melt spinning (MS) at low wheel speeds. Recent additions of titanium carbide and zirconium to the permanent magnet (PM) alloy design in HPGA powder (using He atomization gas) have made it possible to achieve highly refined microstructures with magnetic properties approaching melt spun particulate at cooling rates of 10{sup 5}-10{sup 6}K/s. By producing HPGA powders with the desirable qualities of melt spun ribbon, the need for crushing ribbon was eliminated in bonded magnet fabrication. The spherical geometry of HPGA powders is more ideal for processing of bonded permanent magnets since higher loading fractions can be obtained during compression and injection molding. This increased volume loading of spherical PM powder can be predicted to yield a higher maximum energy product (BH){sub max} for bonded magnets in high performance applications. Passivation of RE-containing powder is warranted for the large-scale manufacturing of bonded magnets in applications with increased temperature and exposure to humidity. Irreversible magnetic losses due to oxidation and corrosion of particulates is a known drawback of RE-Fe-B based alloys during further processing, e.g. injection molding, as well as during use as a bonded magnet. To counteract these effects, a modified gas atomization chamber allowed for a novel approach to in situ passivation of solidified particle surfaces through injection of a reactive gas, nitrogen trifluoride (NF{sub 3}). The ability to control surface chemistry during atomization processing of fine spherical RE-Fe-B powders produced advantages over current processing methodologies. In particular, the capability to coat particles while 'in flight' may eliminate the need for post atomization treatment, otherwise a necessary step for oxidation and corrosion resistance. Stability of these thin films was attributed to the reduction of each RE's respective oxide during processing; recognizing that fluoride compounds exhibit a slightly higher (negative) free energy driving force for formation. Formation of RE-type fluorides on the surface was evidenced through x-ray photoelectron spectroscopy (XPS). Concurrent research with auger electron spectroscopy has been attempted to accurately quantify the depth of fluoride formation in order to grasp the extent of fluorination reactions with spherical and flake particulate. Gas fusion analysis on coated powders (dia. <45 {micro}m) from an optimized experiment indicated an as-atomized oxygen concentration of 343ppm, where typical, nonpassivated RE atomized alloys exhibit an average of 1800ppm oxygen. Thermogravimetric analysis (TGA) on the same powder revealed a decreased rate of oxidation at elevated temperatures up to 300 C, compared to similar uncoated powder.

  2. Effective Rate Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Regulation and Frequency Response DollarsKW-month 4.56 CV-RFS4 Spinning Reserve The formula rate for spinning reserve service is the price consistent with the California...

  3. Effective Rate Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Frequency Response DollarsKW-month 3.98 4.17 CV-RFS4 Spinning Reserve The formula rate for spinning reserve service is the price consistent with the California...

  4. Effective Rate Period

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Frequency Response DollarsKW-month 4.17 4.56 CV-RFS4 Spinning Reserve The formula rate for spinning reserve service is the price consistent with the California...

  5. 2012 Transmission Rate Schedules

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for HLH and LLH. 2. OTHER RATE PROVISIONS a. BPA Incremental Cost BPA's incremental cost will be based on an hourly energy index in the Pacific Northwest. If no adequate...

  6. On Thermonuclear Reaction Rates

    E-Print Network [OSTI]

    H. J. Haubold; A. M. Mathai

    1996-12-02

    Nuclear reactions govern major aspects of the chemical evolution od galaxies and stars. Analytic study of the reaction rates and reaction probability integrals is attempted here. Exact expressions for the reaction rates and reaction probability integrals for nuclear reactions in the case of nonresonant, modified nonresonant, screened nonresonant and resonant cases are given. These are expressed in terms of H-functions, G-functions and in computable series forms. Computational aspects are also discussed.

  7. Effect of Wafer Bow and Etch Patterns in Direct Wafer Bonding

    E-Print Network [OSTI]

    Spearing, S. Mark

    Direct wafer bonding has been identified as an en-abling technology for microelectromechanical systems (MEMS). As the complexity of devices increase and the bonding of multiple patterned wafers is required, there is a need ...

  8. Cu-Cu direct bonding achieved by surface method at room temperature

    SciTech Connect (OSTI)

    Utsumi, Jun [Advanced Technology Research Center, Mitsubishi Heavy Industries, Ltd., 1-8-1 Sachiura, Kanazawa-ku, Yokohama 236-8515 (Japan); Ichiyanagi, Yuko, E-mail: yuko@ynu.ac.jp [Department of Physics, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya, Yokohama 240-8501 (Japan)

    2014-02-20

    The metal bonding is a key technology in the processes for the microelectromechanical systems (MEMS) devices and the semiconductor devices to improve functionality and higher density integration. Strong adhesion between surfaces at the atomic level is crucial; however, it is difficult to achieve close bonding in such a system. Cu films were deposited on Si substrates by vacuum deposition, and then, two Cu films were bonded directly by means of surface activated bonding (SAB) at room temperature. The two Cu films, with the surface roughness Ra about 1.3nm, were bonded by using SAB at room temperature, however, the bonding strength was very weak in this method. In order to improve the bonding strength between the Cu films, samples were annealed at low temperatures, between 323 and 473 K, in air. As the result, the Cu-Cu bonding strength was 10 times higher than that of the original samples without annealing.

  9. Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inspection of Adhesive Bonds in Metal-Metal Joints Non-Destructive Inspection of Adhesive Bonds in Metal-Metal Joints 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  10. Plasticity of hydrogen bond networks regulates mechanochemistry of cell adhesion complexes

    E-Print Network [OSTI]

    Chakrabarti, Shaon; Thirumalai, D

    2014-01-01

    Mechanical forces acting on cell adhesion receptor proteins regulate a range of cellular functions by formation and rupture of non-covalent interactions with ligands. Typically, force decreases the lifetimes of intact complexes (slip-bonds), making the discovery that these lifetimes can also be prolonged ("catch-bonds"), a surprise. We created a microscopic analytic theory by incorporating the structures of selectin and integrin receptors into a conceptual framework based on the theory of stochastic equations, which quantitatively explains a wide range of experimental data (including catch-bonds at low forces and slip-bonds at high forces). Catch-bonds arise due to force-induced remodeling of hydrogen bond networks, a finding that also accounts for unbinding in structurally unrelated integrin-fibronectin and actomyosin complexes. For the selectin family, remodeling of hydrogen bond networks drives an allosteric transition resulting in the formation of maximum number of hydrogen bonds determined only by the st...

  11. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...

    Office of Scientific and Technical Information (OSTI)

    Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study Citation Details In-Document Search Title: Chemical Bonding In Amorphous Si...

  12. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-06-01

    This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

  13. The Optimal Payment Reduction Ratios for a Catastrophe Bond Xiaoli Zhang

    E-Print Network [OSTI]

    Brennand, Tracy

    and the future bond payments are reduced. This projects first presents a general pricing formula for a CAT bond losses. Last, it shows how strike price, maturity, parameters of the catastrophe loss process List of Tables ix List of Figures x 1 Introduction 1 1.1 Introduction to catastrophe bond

  14. Bonding is carried out by building up Quartz Wax on the sample holder to

    E-Print Network [OSTI]

    Smith, Tanya M.

    Bonding is carried out by building up Quartz Wax on the sample holder to support and bond the tooth that the Quartz Wax should cover as much of the sample face as possible to ensure a strong bond. Application Note Tooth Wax layer Figure 1 Sample holder Tooth Thin Section #12;B. Cutting - SIngle Selection Figure 2

  15. PlasticPDMS bonding for high pressure hydrolytically stable active microfluidics

    E-Print Network [OSTI]

    Ram, Rajeev J.

    to plastics. Plastics can be manufactured using mass fabrication technologies such as injection molding with established plastic mass fabri- cation technologies. Bonding technologies Bonding between PDMS and plasticsPlastic­PDMS bonding for high pressure hydrolytically stable active microfluidics Kevin S. Lee

  16. The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis

    E-Print Network [OSTI]

    Williams, Loren

    The Hydrogen Bonding of Cytosinewith Guanine:Calorimetric and`H-NMR Analysis of the Molecular of hydrogen-bondformation between guanine (G) and cytusine (C) in o-dichloro- benzene and in chloroformat 25°C forming hydrogen bonds. Consequently, hydrogen-bond formation in our system is primarily between the bases

  17. Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch Relaxation

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Dissociation and Reformation in Methanol Oligomers Following Hydroxyl Stretch, 2002 Vibrational relaxation and hydrogen bond dynamics in methanol-d dissolved in CCl4 have been-d molecules both accepting and donating hydrogen bonds at 2500 cm-1 . Following vibrational relaxation

  18. Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen bond breaking probed with multidimensional stimulated vibrational echo correlation September 2003 Hydrogen bond population dynamics are extricated with exceptional detail using ultrafast ( 50 of methanol­OD oligomers in CCl4 . Hydrogen bond breaking makes it possible to acquire data for times much

  19. Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a,

    E-Print Network [OSTI]

    White, Stephen

    Review Hydrogen bond dynamics in membrane protein function Ana-Nicoleta Bondar a, , Stephen H 30 November 2011 Available online 8 December 2011 Keywords: Membrane protein structure Hydrogen bond Membrane protein dynamics Lipid­protein interactions Changes in inter-helical hydrogen bonding

  20. Hydrogen bond dynamics in the active site of photoactive yellow protein

    E-Print Network [OSTI]

    Herschlag, Dan

    Hydrogen bond dynamics in the active site of photoactive yellow protein Paul A. Sigala, Mark A for review February 5, 2009) Hydrogen bonds play major roles in biological structure and function. Nonetheless, hydrogen-bonded protons are not typically observed by X-ray crystallography, and most structural

  1. Hydrogen bonding in solid ammonia from ab initio calculations A. D. Fortes,a)

    E-Print Network [OSTI]

    Vocadlo, Lidunka

    Hydrogen bonding in solid ammonia from ab initio calculations A. D. Fortes,a) J. P. Brodholt, I. G the tendency toward symmetrization of the hydrogen bonds at high pressures and find that, unlike pure ice that ammonia IV does not contain a bifurcated hydrogen bond, as has previously been suggested. © 2003 American

  2. Hydrogen bond dynamics in aqueous NaBr solutions Sungnam Park

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen bond dynamics in aqueous NaBr solutions Sungnam Park and M. D. Fayer§ Department. D. Fayer, August 19, 2007 (sent for review July 27, 2007) Hydrogen bond dynamics of water in Na pump­probe experiments. The hydrogen bond structural dynamics are observed by measuring spectral

  3. A CH O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices

    E-Print Network [OSTI]

    Babu, M. Madan

    A C­H· · ·O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C Terminus of Helices of Science Bangalore 560012, India The serendipitous observation of a C­H· · ·O hydrogen bond mediated­N hydrogen bond involving the side- chain of residue T 2 4 and the N­H group of residue T ţ 3. In as many

  4. Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate

    E-Print Network [OSTI]

    Sancho, Javier

    Native Hydrogen Bonds in a Molten Globule: The Apoflavodoxin Thermal Intermediate MarőÂa P. IruÂn1 in surface- exposed hydrogen bonds connecting secondary-structure elements in the native protein. All hydrogen bonds analysed are formed in the molten globule intermediate, either with native strength

  5. Bond Price Volatility c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 75

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 75 #12;"Well Taiwan University Page 76 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds here. c2012 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 77 #12;Price Volatility

  6. Bond Price Volatility c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 71

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 71 #12;"Well Taiwan University Page 72 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds throughout. c 2008 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 73 #12;Price Volatility

  7. Bond Price Volatility c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 74

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Bond Price Volatility c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 74 #12;"Well Taiwan University Page 75 #12;Price Volatility · Volatility measures how bond prices respond to interest-coupon bonds throughout. c 2011 Prof. Yuh-Dauh Lyuu, National Taiwan University Page 76 #12;Price Volatility

  8. Stoichiometric Valence and Structural Valence--Two Different Sides of the Same Coin: "Bonding Power"

    E-Print Network [OSTI]

    Wang, Xiqu

    concept is one of the cornerstones of chemistry. Valence,[1] that is, the bonding power of atoms,[2 affects the structure and stability of compounds. Therefore, knowledge of atomic bonding power is not only is equivalent to three moles of hydrogen. The property of an atom to compensate the bonding power of an equiva

  9. Can the Bond Price Reaction to Earnings Announcements Predict Future Stock Returns?

    E-Print Network [OSTI]

    Tipple, Brett

    Can the Bond Price Reaction to Earnings Announcements Predict Future Stock Returns? Omri Even. #12;Abstract In this paper I show that the bond price reaction to earnings announcements has. By demonstrating that a firm's bond price reaction to an earnings announcement can predict future stock returns

  10. From ab initio quantum chemistry to molecular dynamics: The delicate case of hydrogen bonding in ammonia

    E-Print Network [OSTI]

    Martin, Jan M.L.

    energies of this nonlinear hydrogen bond. We present a novel density functional, HCTH/407 , which leads to two equivalent ``hydrogen bonding contacts,'' is extremely close in energy on an overall flatFrom ab initio quantum chemistry to molecular dynamics: The delicate case of hydrogen bonding

  11. Wafer bonded virtual substrate and method for forming the same

    DOE Patents [OSTI]

    Atwater, Jr., Harry A. (So. Pasadena, CA); Zahler, James M. (Pasadena, CA); Morral, Anna Fontcuberta i (Paris, FR)

    2007-07-03

    A method of forming a virtual substrate comprised of an optoelectronic device substrate and handle substrate comprises the steps of initiating bonding of the device substrate to the handle substrate, improving or increasing the mechanical strength of the device and handle substrates, and thinning the device substrate to leave a single-crystal film on the virtual substrate such as by exfoliation of a device film from the device substrate. The handle substrate is typically Si or other inexpensive common substrate material, while the optoelectronic device substrate is formed of more expensive and specialized electro-optic material. Using the methodology of the invention a wide variety of thin film electro-optic materials of high quality can be bonded to inexpensive substrates which serve as the mechanical support for an optoelectronic device layer fabricated in the thin film electro-optic material.

  12. Characterization of Fuel-Cladding Bond Strength Using Laser Shock

    SciTech Connect (OSTI)

    James A. Smith; David L. Cottle; Barry H. Rabin

    2014-04-01

    This paper describes new laser-based capabilities for characterization of fuel-cladding bond strength in nuclear fuels, and presents preliminary results obtained from studies on as-fabricated monolithic fuel consisting of uranium-10 wt.% molybdenum alloys clad in 6061 aluminum by hot isostatic pressing. Two complementary experimental methods are employed, laser-shock testing and laser-ultrasonic imaging. Measurements are spatially localized, non-contacting and require minimum specimen preparation, and are therefore ideally suited for applications involving radioactive materials, including irradiated materials. The theoretical principles and experimental approaches employed in characterization of nuclear fuel plates are described. The ability to measure layer thicknesses, elastic properties of the constituents, and the location and nature of laser-shock induced debonds is demonstrated, and preliminary bond strength measurement results are discussed.

  13. Membrane adhesion via competing receptor/ligand bonds

    E-Print Network [OSTI]

    Mesfin Asfaw; Bartosz Rozycki; Reinhard Lipowsky; Thomas R. Weikl

    2006-10-01

    The adhesion of biological membranes is controlled by various types of receptor and ligand molecules. In this letter, we present a statistical-mechanical model for membranes that interact via receptor/ligand bonds of two different lengths. We show that the equilibrium phase behavior of the membranes is governed by an effective double-well potential. The depths of the two potential wells depend on the concentrations and binding energies of the receptors and ligands. The membranes are unbound for small, and bound for larger potential depths. In the bound state, the length mismatch of the receptor/ligand bonds can lead to lateral phase separation. We derive explicit scaling laws for the critical points of unbinding and phase separation, and determine the prefactors by comparison with Monte Carlo results.

  14. Cold bond agglomeration of waste oxides for recycling

    SciTech Connect (OSTI)

    D`Alessio, G.; Lu, W.K. [McMaster Univ., Hamilton, Ontario (Canada). Dept. of Materials Science and Engineering

    1996-12-31

    Recycling of waste oxides has been an on-going challenge for integrated steel plants. The majority of these waste oxides are collected from the cleaning systems of ironmaking and steelmaking processes, and are usually in the form of fine particulates and slurries. In most cases, these waste materials are contaminated by oils and heavy metals and often require treatment at a considerable expense prior to landfill disposal. This contamination also limits the re-use or recycling potential of these oxides as secondary resources of reliable quality. However, recycling of some selected wastes in blast furnaces or steelmaking vessels is possible, but first requires agglomeration of the fine particulate by such methods as cold bond briquetting. Cold bond briquetting technology provides both mechanical compacting and bonding (with appropriate binders) of the particulates. This method of recycling has the potential to be economically viable and environmentally sustainable. The nature of the present study is cold bond briquetting of iron ore pellet fines with a molasses-cement-H{sub 2}O binder for recycling in a blast furnace. The inclusion of molasses is for its contribution to the green strength of briquettes. During the curing stage, significant gains in strength may be credited to molasses in the presence of cement. The interactions of cement (and its substitutes), water and molasses and their effects on the properties of the agglomerates during and after various curing conditions were investigated. Tensile strengths of briquettes made in the laboratory and subjected to experimental conditions which simulated the top part of a blast furnace shaft were also examined.

  15. Deconfinement of electric charges in hydrogen-bonded ferroelectrics

    E-Print Network [OSTI]

    Bo-Jie Huang; Chyh-Hong Chern

    2015-04-15

    In addition to the gauge charges, a new charge degree of freedom is found in the deconfined phase in the lattice Ising gauge theory. While applying to the hydrogen-bonded ferroelectrics, the new charge is essentially the electric charge, leading to the divergent dielectric susceptibility. The new degree of freedom paves an experimentally accessible way to identify the deconfined phase in the lattice Ising gauge theory.

  16. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM); Roybal, Herman E. (Santa Fe, NM)

    1985-01-01

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al.sub.2 O.sub.3 yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  17. Oxford Area Community School District (Michigan) Bonds Case Study

    Broader source: Energy.gov [DOE]

    Michigan’s Oxford Area Community School District entered into an energy savings performance contract and issued limited tax general obligation bonds to fund the up-front costs of almost $3 million of energy-related improvements. Case study is excerpted from Financing Energy Upgrades for K-12 School Districts: A Guide to Tapping into Funding for Energy Efficiency and Renewable Energy Improvements. Author: Merrian Borgeson and Mark Zimring

  18. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, G.W.; Roybal, H.E.

    1983-11-14

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al/sub 2/O/sub 3/ yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  19. Quantum Confinement in Hydrogen Bond of DNA and RNA

    E-Print Network [OSTI]

    da Silva dos Santos; Elso Drigo Filho; Regina Maria Ricotta

    2015-02-09

    The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

  20. Quantum Confinement in Hydrogen Bond of DNA and RNA

    E-Print Network [OSTI]

    Santos, da Silva dos; Ricotta, Regina Maria

    2015-01-01

    The hydrogen bond is a fundamental ingredient to stabilize the DNA and RNA macromolecules. The main contribution of this work is to describe quantitatively this interaction as a consequence of the quantum confinement of the hydrogen. The results for the free and confined system are compared with experimental data. The formalism to compute the energy gap of the vibration motion used to identify the spectrum lines is the Variational Method allied to Supersymmetric Quantum Mechanics.

  1. Compacting Plastic-Bonded Explosive Molding Powders to Dense Solids

    SciTech Connect (OSTI)

    B. Olinger

    2005-04-15

    Dense solid high explosives are made by compacting plastic-bonded explosive molding powders with high pressures and temperatures for extended periods of time. The density is influenced by manufacturing processes of the powders, compaction temperature, the magnitude of compaction pressure, pressure duration, and number of repeated applications of pressure. The internal density variation of compacted explosives depends on method of compaction and the material being compacted.

  2. Effect of hydrogen bond cooperativity on the behavior of water

    E-Print Network [OSTI]

    Kevin Stokely; Marco G. Mazza; H. Eugene Stanley; Giancarlo Franzese

    2009-08-27

    Four scenarios have been proposed for the low--temperature phase behavior of liquid water, each predicting different thermodynamics. The physical mechanism which leads to each is debated. Moreover, it is still unclear which of the scenarios best describes water, as there is no definitive experimental test. Here we address both open issues within the framework of a microscopic cell model by performing a study combining mean field calculations and Monte Carlo simulations. We show that a common physical mechanism underlies each of the four scenarios, and that two key physical quantities determine which of the four scenarios describes water: (i) the strength of the directional component of the hydrogen bond and (ii) the strength of the cooperative component of the hydrogen bond. The four scenarios may be mapped in the space of these two quantities. We argue that our conclusions are model-independent. Using estimates from experimental data for H bond properties the model predicts that the low-temperature phase diagram of water exhibits a liquid--liquid critical point at positive pressure.

  3. Bonding energies and long-range order in the trialuminides

    SciTech Connect (OSTI)

    Sparks, C.J.; Specht, E.D.; Ice, G.E.; Zschack, P.; Schneibel, J.

    1990-01-01

    The degree of long-range order in the trialuminides is determined by X-ray powder diffraction techniques. Long-range order exists to their melting points. For the binary trialuminides Al{sub 3}Ti, Al{sub 73}Ti{sub 27}, and Al{sub 3}Sc, the degree of long-range order is nearly perfect and is a measure of the lack of mixing of the aluminum atoms onto the sublattice occupied by either Ti or Sc. A calculation of the bond energy between neighboring pairs of atoms from the ordering (melting) temperature is made following the Bragg-Williams mean field theory approach. These bond energies compare favorably with more sophisticated calculations. Bond energies are found to be larger than the energy difference between the crystal structure forms DO{sub 22}, Ll{sub 2}, and DO{sub 23}, and therefore, more relevant to understanding the mechanical and chemical behavior of the trialuminides. Ordering or melting temperatures of these intermetallics reflect the strong Al-metal near-neighbor pair potentials and may provide insights to their brittle properties. 11 refs., 2 figs., 2 tabs.

  4. Vacuum fusion bonded glass plates having microstructures thereon

    DOE Patents [OSTI]

    Swierkowski, Steve P. (Livermore, CA); Davidson, James C. (Livermore, CA); Balch, Joseph W. (Livermore, CA)

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  5. Data:6f7cda2e-3572-486a-b3aa-4129977e9ead | Open Energy Information

    Open Energy Info (EERE)

    cda2e-3572-486a-b3aa-4129977e9ead No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1....

  6. Data:32b0abb8-a929-4537-b5ed-ab1155e4aa0b | Open Energy Information

    Open Energy Info (EERE)

    -b5ed-ab1155e4aa0b No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  7. CdL in Informatica --a.a. 2004/2005 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerd 18 novembre 2005

    E-Print Network [OSTI]

    Cutolo, Giovanni

    CdL in Informatica -- a.a. 2004/2005 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerdě . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ­ Il teorema di Stone sui reticoli di Boole finiti afferma che

  8. CdL in Informatica --a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerd 12 ottobre 2007

    E-Print Network [OSTI]

    Cutolo, Giovanni

    : . . . . . . . . . . . . . . . . . . . . ., oppure: non ne esistono un'algebra di Boole di cardinalit`a compresa tra 20 e 30CdL in Informatica -- a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerdě

  9. Concept of chemical bond and aromaticity based on quantum information theory

    E-Print Network [OSTI]

    Szilvási, T; Legeza, Ö

    2015-01-01

    Quantum information theory (QIT) emerged in physics as standard technique to extract relevant information from quantum systems. It has already contributed to the development of novel fields like quantum computing, quantum cryptography, and quantum complexity. This arises the question what information is stored according to QIT in molecules which are inherently quantum systems as well. Rigorous analysis of the central quantities of QIT on systematic series of molecules offered the introduction of the concept of chemical bond and aromaticity directly from physical principles and notions. We identify covalent bond, donor-acceptor dative bond, multiple bond, charge-shift bond, and aromaticity indicating unified picture of fundamental chemical models from ab initio.

  10. Coexistence of dilute and densely packed domains of ligand-receptor bonds in membrane adhesion

    E-Print Network [OSTI]

    Daniel Schmidt; Timo Bihr; Udo Seifert; Ana-Sun?ana Smith

    2012-07-11

    We analyze the stability of micro-domains of ligand-receptor bonds that mediate the adhesion of biological model membranes. After evaluating the effects of membrane fluctuations on the binding affinity of a single bond, we characterize the organization of bonds within the domains by theoretical means. In a large range of parameters, we find the commonly suggested dense packing to be separated by a free energy barrier from a regime in which bonds are sparsely distributed. If bonds are mobile, a coexistence of the two regimes should emerge, which agrees with recent experimental observations.

  11. Esercizi di Matematica Discreta --CdS in Informatica, a.a.2003-2004 Funzioni composte e funzioni invertibili

    E-Print Network [OSTI]

    Robbiano, Lorenzo

    Esercizi di Matematica Discreta -- CdS in Informatica, a.a.2003-2004 Funzioni composte e funzioni´e dominio e codominio delle tre funzioni sono uguali, si possono costruire 6 funzioni composte, hanno tutte(h(x)) = h(-x) = x. Solo le due funzioni composte h f e f h sono uguali. 5 #12;Es.3 g f : Z � Z Z � Z `e

  12. BANDO PER BORSE DI STUDIO PER TESI DI LAUREA ALL'ESTERO A.A. 2014/2015

    E-Print Network [OSTI]

    Di Pillo, Gianni

    BANDO PER BORSE DI STUDIO PER TESI DI LAUREA ALL'ESTERO A.A. 2014/2015 IL PRESIDE VISTO l'art. 15 studi; VISTO il Regolamento per l'attribuzione delle borse di studio per tesi all'estero emanato con D.389,00 euro per Borse di studio per tesi all'estero; VISTA la comunicazione del 27 marzo 2015, dell

  13. The 1999aa-like Type Ia Supernova iPTF14bdn in the Ultraviolet and Optical

    E-Print Network [OSTI]

    Smitka, Michael T; Suntzeff, Nicholas B; Zhang, Jujia; Wang, Xiaofeng; Zhai, Qian; Mo, Jun; Zhang, Tianmeng

    2015-01-01

    We present ultraviolet (UV) and optical photometry and spectra of the 1999aa-like supernova (SN) iPTF14bdn. The UV data were observed using the Swift Ultraviolet/Optical Telescope (UVOT) and constitute the first UV spectral series of a 1999aa-like SN. From the photometry we measure $\\Delta m_{15}({\\it B})\\,=\\,0.84 \\pm0.05$ mag and blue UV colors at epochs earlier than $-5$ days. The spectra show that the early-time blue colors are the result of less absorption between $2800 - 3200 \\,\\AA~$ than is present in normal SNe Ia. Using model spectra fits of the data at $-10 $ and $+10 $ days, we identify the origin of this spectral feature to be a temperature effect in which doubly ionized iron group elements create an opacity 'window'. We determine that the detection of high temperatures and large quantities of iron group elements at early epochs imply the mixing of a high Ni mass into the outer layers of the SN ejecta. We also identify the source of the I-band secondary maximum in iPTF14bdn to be the decay of Fe II...

  14. Magnetic Reconnection Rates and Energy Release in a Confined X-class Flare

    E-Print Network [OSTI]

    Veronig, A M

    2015-01-01

    We study the energy-release process in the confined X1.6 flare that occurred on 22 October 2014 in AR 12171. Magnetic-reconnection rates and reconnection fluxes are derived from three different data sets: space-based data from the Atmospheric Imaging Assembly (AIA) 1600 {\\AA} filter onboard the Solar Dynamics Observatory (SDO) and ground-based H$\\alpha$ and Ca II K filtergrams from Kanzelh\\"ohe Observatory. The magnetic-reconnection rates determined from the three data sets all closely resemble the temporal profile of the hard X-rays measured by the Ramaty High Energy Solar Spectroscopic Imager (RHESSI), which are a proxy for the flare energy released into high-energy electrons. The total magnetic-reconnection flux derived lies between $4.1 \\times 10^{21}$ Mx (AIA 1600 {\\AA}) and $7.9 \\times 10^{21}$ Mx (H$\\alpha$), which corresponds to about 2 to 4% of the total unsigned flux of the strong source AR. Comparison of the magnetic-reconnection flux dependence on the GOES class for 27 eruptive events collected fr...

  15. Statistics of reversible bond dynamics observed in force-clamp spectroscopy

    E-Print Network [OSTI]

    Gregor Diezemann; Thomas Schlesier; Burkhard Geil; Andreas Janshoff

    2010-10-30

    We present a detailed analysis of two-state trajectories obtained from force-clamp spectroscopy (FCS) of reversibly bonded systems. FCS offers the unique possibility to vary the equilibrium constant in two-state kinetics, for instance the unfolding and refolding of biomolecules, over many orders of magnitude due to the force dependency of the respective rates. We discuss two different kinds of counting statistics, the event-counting usually employed in the statistical analysis of two-state kinetics and additionally the so-called cycle-counting. While in the former case all transitions are counted, cycle-counting means that we focus on one type of transitions. This might be advantageous in particular if the equilibrium constant is much larger or much smaller than unity because in these situations the temporal resolution of the experimental setup might not allow to capture all transitions of an event-counting analysis. We discuss how an analysis of FCS data for complex systems exhibiting dynamic disorder might be performed yielding information about the detailed force-dependence of the transition rates and about the time scale of the dynamic disorder. In addition, the question as to which extent the kinetic scheme can be viewed as a Markovian two-state model is discussed.

  16. Rotational rate sensor

    DOE Patents [OSTI]

    Hunter, Steven L. (Livermore, CA)

    2002-01-01

    A rate sensor for angular/rotational acceleration includes a housing defining a fluid cavity essentially completely filled with an electrolyte fluid. Within the housing, such as a toroid, ions in the fluid are swept during movement from an excitation electrode toward one of two output electrodes to provide a signal for directional rotation. One or more ground electrodes within the housing serve to neutralize ions, thus preventing any effect at the other output electrode.

  17. Title 43 CFR 3104 Bonds | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al., 2013)Open EnergyTinoxOpen Energy Information 155104 Bonds Jump

  18. Chemical bond and entanglement of electrons in the hydrogen molecule

    E-Print Network [OSTI]

    Nikos Iliopoulos; Andreas F. Terzis

    2014-08-01

    We theoretically investigate the quantum correlations (in terms of concurrence of indistinguishable electrons) in a prototype molecular system (hydrogen molecule). With the assistance of the standard approximations of the linear combination of atomic orbitals and the con?guration interaction methods we describe the electronic wavefunction of the ground state of the H2 molecule. Moreover, we managed to ?find a rather simple analytic expression for the concurrence (the most used measure of quantum entanglement) of the two electrons when the molecule is in its lowest energy. We have found that concurrence does not really show any relation to the construction of the chemical bond.

  19. Fuel cell system with separating structure bonded to electrolyte

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY); Quek, Shu Ching (Clifton Park, NY); Hasz, Wayne Charles (Pownal, VT); Powers, James Daniel (Santa Monica, CA)

    2010-09-28

    A fuel cell assembly comprises a separating structure configured for separating a first reactant and a second reactant wherein the separating structure has an opening therein. The fuel cell assembly further comprises a fuel cell comprising a first electrode, a second electrode, and an electrolyte interposed between the first and second electrodes, and a passage configured to introduce the second reactant to the second electrode. The electrolyte is bonded to the separating structure with the first electrode being situated within the opening, and the second electrode being situated within the passage.

  20. Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes

    E-Print Network [OSTI]

    Jones, William D.

    Carbon-Fluorine Bond Cleavage by Zirconium Metal Hydride Complexes Brian L. Edelbach, A. K. Fazlur, Rochester, New York 14627 Received April 8, 1999 The zirconium hydride dimer [Cp2ZrH2]2 reacts with C6F6. [Cp2ZrH2]2 reacts with C6F5H to give Cp2Zr(p-C6F4H)F, Cp2ZrF2, C6F4H2, and H2. The zirconium hydride

  1. Qualified Energy Conservation Bonds (QECBs) & New Clean Renewable Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 - Oct. 7, 2011 |1 DOE HydrogenDepartmentU.S. Department ofBonds

  2. Bond County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental JumpInformationBio-GasIllinois:Energy Authority Jump to:Bolivia:Vermont:BonBond

  3. Time-Resolved Study of Bonding in Liquid Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr.Theories (JournalTime-Resolved Study of Bonding in

  4. Nitrogen-tuned bonding mechanism of Li and Ti adatom embedded graphene

    SciTech Connect (OSTI)

    Lee, Sangho; Chung, Yong-Chae, E-mail: yongchae@hanyang.ac.kr

    2013-09-15

    The effects of nitrogen defects on the bonding mechanism and resultant binding energy between the metal and graphene layer were investigated using density functional theory (DFT) calculations. For the graphitic N-doped graphene, Li adatom exhibited ionic bonding character, while Ti adatom showed features of covalent bonding similar to that of pristine graphene. However, in the cases of pyridinic and pyrrolic structures, partially covalent bonding characteristic occurred around N atoms in the process of binding with metals, and this particular bond formation enhanced the bond strength of metal on the graphene layer as much as it exceeded the cohesive energy of the metal bulk. Thus, Li and Ti metals are expected to be dispersed with atomic accuracy on the pyridinic and pyrrolic N-doped graphene layers. These results demonstrate that the bonding mechanism of metal–graphene complex can change according to the type of N defect, and this also affects the binding results. - Graphical abstract: Display Omitted - Highlights: • Nitrogen defects changed the bonding mechanism between metal and graphene. • Bonding character and binding results were investigated using DFT calculations. • Covalent bonding character occurred around pyridinic and pyrrolic N-doped graphene. • Pyridinic and pyrrolic N atoms are effective for metal dispersion on the graphene.

  5. Experimental and Theoretical Investigations of Energy Transfer and Hydrogen-Bond Breaking in Small Water and HCl Clusters

    E-Print Network [OSTI]

    Reisler, Hanna

    Experimental and Theoretical Investigations of Energy Transfer and Hydrogen-Bond Breaking in Small illustrating ubiquitous hydrogen bonding (H-bonding) in the gas phase, liquids, crystals, and amorphous solids and experiment are enlisted to determine bond dissociation energies (D0) of small dimers and cyclic trimers

  6. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on GlobalRachel2RateCaseElements Sign In About | Careers |

  7. Rate Design and Renewables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on GlobalRachel2RateCaseElements Sign In About | Careers

  8. Fuel Fabrication Capability WBS 01.02.01.05 - HIP Bonding Experiments Final Report

    SciTech Connect (OSTI)

    Dickerson, Patricia O'Donnell; Summa, Deborah Ann; Liu, Cheng; Tucker, Laura Arias; Chen, Ching-Fong; Aikin, Beverly; Aragon, Daniel Adrian; Beard, Timothy Vance; Montalvo, Joel Dwayne; Pena, Maria Isela; Dombrowski, David E.

    2015-06-10

    The goals of this project were to demonstrate reliable, reproducible solid state bonding of aluminum 6061 alloy plates together to encapsulate DU-10 wt% Mo surrogate fuel foils. This was done as part of the CONVERT Fuel Fabrication Capability effort in Process Baseline Development . Bonding was done using Hot Isotatic Pressing (HIP) of evacuated stainless steel cans (a.k.a HIP cans) containing fuel plate components and strongbacks. Gross macroscopic measurements of HIP cans prior to HIP and after HIP were used as part of this demonstration, and were used to determine the accuracy of a finitie element model of the HIP bonding process. The quality of the bonding was measured by controlled miniature bulge testing for Al-Al, Al-Zr, and Zr-DU bonds. A special objective was to determine if the HIP process consistently produces good quality bonding and to determine the best characterization techniques for technology transfer.

  9. Polyurethane spray coating of aluminum wire bonds to prevent corrosion and suppress resonant oscillations

    E-Print Network [OSTI]

    Joseph M. Izen; Matthew Kurth; Rusty Boyd

    2016-01-04

    Unencapsulated aluminum wedge wire bonds are common in particle physics pixel and strip detectors. Industry-favored bulk encapsulation is eschewed due to the range of operating temperatures and radiation. Wire bond failures are a persistent source of tracking-detector failure. Unencapsulated bonds are vulnerable to condensation-induced corrosion, particularly when halides are present. Oscillations from periodic Lorentz forces are documented as another source of wire bond failure. Spray application of polyurethane coatings, performance of polyurethane-coated wire bonds after climate chamber exposure, and resonant properties of polyurethane-coated wire bonds and their resistance to periodic Lorentz forces are under study for use in a future High Luminosity Large Hadron Collider detector such as the ATLAS Inner Tracker upgrade.

  10. Polyurethane spray coating of aluminum wire bonds to prevent corrosion and suppress resonant oscillations

    E-Print Network [OSTI]

    Izen, Joseph M; Boyd, Rusty

    2015-01-01

    Unencapsulated aluminum wedge wire bonds are common in particle physics pixel and strip detectors. Industry-favored bulk encapsulation is eschewed due to the range of operating temperatures and radiation. Wire bond failures are a persistent source of tracking-detector failure. Unencapsulated bonds are vulnerable to condensation-induced corrosion, particularly when halides are present. Oscillations from periodic Lorentz forces are documented as another source of wire bond failure. Spray application of polyurethane coatings, performance of polyurethane-coated wire bonds after climate chamber exposure, and resonant properties of polyurethane-coated wire bonds and their resistance to periodic Lorentz forces are under study for use in a future High Luminosity Large Hadron Collider detector such as the ATLAS Inner Tracker upgrade.

  11. Energy Management Through Innovative Rates 

    E-Print Network [OSTI]

    Williams, M. L.

    1982-01-01

    of energy efficiency in the industrial sector and specific rate design alternatives for doing so....

  12. Atomic Structures of Graphene, Benzene and Methane with Bond Lengths as Sums of the Single, Double and Resonance Bond Radii of Carbon

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-04-25

    Two dimensional layers of graphene are currently drawing a great attention in fundamental and applied nanoscience. Graphene consists of interconnected hexagons of carbon atoms as in graphite. This article presents for the first time the structures of graphene at the atomic level and shows how it differs from that of benzene, due to the difference in the double bond and resonance bond based radii of carbon. The carbon atom of an aliphatic compound such as methane has a longer covalent single bond radius as in diamond. All the atomic structures presented here have been drawn to scale.

  13. Early Results with the Use of Heparin-bonded Stent Graft to Rescue Failed Angioplasty of Chronic Femoropopliteal Occlusive Lesions: TASC D Lesions Have a Poor Outcome

    SciTech Connect (OSTI)

    Kuhan, Ganesh, E-mail: gkuhan@nhs.net; Abisi, Said; Braithwaite, Bruce D.; MacSweeney, Shane T. R. [Nottingham University Hospitals, Vascular and Endovascular Unit, Queens Medical Centre (United Kingdom); Whitaker, Simon C.; Habib, Said B. [Nottingham University Hospitals, Department of Radiology, Queen's Medical Centre (United Kingdom)

    2012-10-15

    Purpose: To evaluate early patency rate of the heparin-bonded stent grafts in atherosclerotic long femoropopliteal occlusive disease, and to identify factors that affect outcome. Methods: Heparin-bonded Viabahn stent grafts were placed in 33 limbs in 33 patients during 2009-2010. The stents were deployed to rescue failed conventional balloon angioplasty. Mean age was 69 (range 44-88) years, and 67 % (22 of 33) were men. Most procedures (21 of 33, 64 %) were performed for critical limb ischemia (33 % for rest pain, 30 % tissue loss). Kaplan-Meier plots and Cox regression analysis were used to identify significant risk factors. Results: The average length of lesions treated was 25 {+-} 10 cm, and they were predominantly TASC (Transatlantic Intersociety Consensus) D (n = 13) and C (n = 17) lesions. The median primary patency was 5.0 months (95 % confidence interval 1.22-8.77). The mean secondary patency was 8.6 months (95 % confidence interval 6.82-10.42). Subsequently, 4 patients underwent bypass surgery and 5 patients underwent major amputation. One patient died. There were 5 in-stent or edge-stent stenoses. Cox multivariate regression analysis identified TASC D lesions to be a significant risk factor for early occlusion (p = 0.035). Conclusion: TASC D lesions of femoropopliteal occlusions have poor patency rates with the use of heparin-bonded stent grafts after failed conventional angioplasty. Alternative options should be considered for these patients.

  14. Partial-Transient-Liquid-Phase Bonding of Advanced Ceramics Using Surface-Modified Interlayers

    E-Print Network [OSTI]

    Reynolds, Thomas Bither

    2012-01-01

    Brazing." Zeitschrift Für Metallkunde 85, 828–832 (1994).Bonding." Zeitschrift Für Metallkunde 85, 775– Shalz, M. ,Molybdän." Zeitschrift Für Metallkunde 46, 187–194 (1955).

  15. Making it Easier to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on How to to Complete Clean Energy Projects with Qualified Energy Conservation Bonds (QECBs)

  16. Thermal barrier and overlay coating systems comprising composite metal/metal oxide bond coating layers

    DOE Patents [OSTI]

    Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL); Vance, Steven J. (Orlando, FL)

    2001-01-01

    The present invention generally describes multilayer coating systems comprising a composite metal/metal oxide bond coat layer. The coating systems may be used in gas turbines.

  17. First Steps toward Automated Design of Mechatronic Systems Using Bond Graphs and Genetic Programming

    E-Print Network [OSTI]

    Fernandez, Thomas

    First Steps toward Automated Design of Mechatronic Systems Using Bond Graphs and Genetic for mechatronic systems. The domain of mechatronic systems includes mixtures of, for example, electrical

  18. EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    Broader source: Energy.gov [DOE]

    DOE prepared a EIS that evaluated the potential environmental impacts of treatment and management of DOE-owned sodium bonded spent nuclear fuel.

  19. Liquid Metal Bond for Improved Heat Transfer in LWR Fuel Rods

    SciTech Connect (OSTI)

    Donald Olander

    2005-08-24

    A liquid metal (LM) consisting of 1/3 weight fraction each of Pb, Sn, and Bi has been proposed as the bonding substance in the pellet-cladding gap in place of He. The LM bond eliminates the large AT over the pre-closure gap which is characteristic of helium-bonded fuel elements. Because the LM does not wet either UO2 or Zircaloy, simply loading fuel pellets into a cladding tube containing LM at atmospheric pressure leaves unfilled regions (voids) in the bond. The HEATING 7.3 heat transfer code indicates that these void spaces lead to local fuel hot spots.

  20. Microsoft Word - News Release -- EN Bond Sale goes well 8-19...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    borrowing authority and saved approximately 500 million in interest under BPA's Debt Optimization Program. The bond proceeds will be used to pay off Energy Northwest debt that...

  1. Carbon Disclosure Project Webinar: Climate Change: A Challenge for Bond Analysts

    Broader source: Energy.gov [DOE]

    Hosted by the Carbon Disclosure Project, this webinar will cover climate change and how its impacts can present significant risks for municipalities and municipal bond investors.

  2. Metal-and hydrogen-bonding competition during water absorption on Pd(111) and Ru(0001)

    E-Print Network [OSTI]

    Tatarkhanov, Mouslim

    2010-01-01

    Metal- and hydrogen-bonding competition during waterthe molecules bind to the metal substrate through the O-loneplane perpendicular to the metal surface with reduced water-

  3. Bimetallic cleavage of aromatic C-H bonds by rare-earth-metal complexes

    E-Print Network [OSTI]

    Huang, W; Huang, W; Dulong, F; Khan, SI; Cantat, T; Diaconescu, PL

    2014-01-01

    of Aromatic C-H Bonds by Rare Earth Metal Complexes Wenliangone week prior to use. Rare earth metal oxides (scandium,

  4. Covalent features in the hydrogen bond of a water dimer: molecular orbital analysis

    E-Print Network [OSTI]

    Wang, Bo; Dai, Xing; Gao, Yang; Wang, Zhigang; Zhang, Rui-Qin

    2015-01-01

    The covalent-like characteristics of hydrogen bonds offer a new perspective on intermolecular interactions. Here, using density functional theory and post-Hartree-Fock methods, we reveal that there are two bonding molecular orbitals (MOs) crossing the O and H atoms of the hydrogen-bond in water dimer. Energy decomposition analysis also shows a non-negligible contribution of the induction term. These results illustrate the covalent-like character of the hydrogen bond between water molecules, which contributes to the essential understanding of ice, liquid water, related materials, and life sciences.

  5. Tuning the Metal-Adsorbate Chemical Bond through the Ligand Effect...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tuning the Metal-Adsorbate Chemical Bond through the Ligand Effect on Platinum Subsurface Alloys Tuesday, July 31, 2012 The ability to design and control the activities of...

  6. ANL/AA-19 Land Use and Energy K. E. Robeck, S. W. Ballou, D. W. South,

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby a contractor ofvar generationAA-19 Land Use and Energy K.

  7. Hybrid valence-bond states for universal quantum computation

    E-Print Network [OSTI]

    Tzu-Chieh Wei; Poya Haghnegahdar; Robert Raussendorf

    2015-01-29

    The spin-3/2 Affleck-Kennedy-Lieb-Tasaki (AKLT) valence-bond state on the hexagonal lattice was shown to be a universal resource state for measurement-based quantum computation (MBQC). Can AKLT states of higher spin magnitude support universal MBQC? We demonstrate that several hybrid 2D AKLT states involving mixture of spin-2 and other lower-spin entities, such as spin-3/2 and spin-1, are also universal for MBQC. This significantly expands universal resource states in the AKLT family. Even though frustration may be a hinderance to quantum computational universality, lattices can be modified to yield AKLT states that are universal. The family of AKLT states thus provides a versatile playground for quantum computation.

  8. Kinetics of bond formation in crosslinked gelatin gels

    E-Print Network [OSTI]

    T. Abete; E. Del Gado; D. Hellio Serughetti; L. de Arcangelis; M. Djabourov; A. Coniglio

    2006-11-07

    In chemical crosslinking of gelatin solutions, two different time scales affect the kinetics of the gel formation in the experiments. We complement the experimental study with Monte Carlo numerical simulations of a lattice model. This approach shows that the two characteristic time scales are related to the formation of single bonds crosslinker-chain and of bridges between chains. In particular their ratio turns out to control the kinetics of the gel formation. We discuss the effect of the concentration of chains. Finally our results suggest that, by varying the probability of forming bridges as an independent parameter, one can finely tune the kinetics of the gelation via the ratio of the two characteristic times.

  9. Method of making bonded or sintered permanent magnets

    DOE Patents [OSTI]

    McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

    1995-11-28

    An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density. 14 figs.

  10. Method of making bonded or sintered permanent magnets

    DOE Patents [OSTI]

    McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

    1993-08-31

    An isotropic permanent magnet is made by mixing a thermally responsive, low viscosity binder and atomized rare earth-transition metal (e.g., iron) alloy powder having a carbon-bearing (e.g., graphite) layer thereon that facilitates wetting and bonding of the powder particles by the binder. Prior to mixing with the binder, the atomized alloy powder may be sized or classified to provide a particular particle size fraction having a grain size within a given relatively narrow range. A selected particle size fraction is mixed with the binder and the mixture is molded to a desired complex magnet shape. A molded isotropic permanent magnet is thereby formed. A sintered isotropic permanent magnet can be formed by removing the binder from the molded mixture and thereafter sintering to full density.

  11. Double site-bond percolation model for biomaterial implants

    E-Print Network [OSTI]

    Mely, H

    2011-01-01

    We present a double site-bond percolation model to account, on the one hand, for the vascularization and/or resorption of biomaterial implant in bones and, on the other hand, for its mechanical continuity. The transformation of the implant into osseous material, and the dynamical formation/destruction of this osseous material is accounted for by creation and destruction of links and sites in two, entangled, networks. We identify the relevant parameters to describe the implant and its evolution, and separate their biological or chemical origin from their physical one. We classify the various phenomena in the two regimes, percolating or non-percolating, of the networks. We present first numerical results in two dimensions.

  12. Interstellar Isomers: The Importance of Bonding Energy Differences

    E-Print Network [OSTI]

    Anthony J. Remijan; J. M. Hollis; F. J. Lovas; D. F. Plusquellic; P. R. Jewell

    2005-06-21

    We present strong detections of methyl cyanide, vinyl cyanide, ethyl cyanide and cyanodiacetylene molecules with the Green Bank Telescope (GBT) toward the Sgr B2(N) molecular cloud. Attempts to detect the corresponding isocyanide isomers were only successful in the case of methyl isocyanide for its J(K)=1(0)-0(0) transition, which is the first interstellar report of this line. To determine the spatial distribution of methyl isocyanide, we used archival Berkeley-Illinois-Maryland Association (BIMA) array data for the J(K)=4(K)-3(K) (K=0-3) transitions but no emission was detected. From ab initio calculations, the bonding energy difference between the cyanide and isocyanide molecules is >8500 cm^-1 (>12,000 K). That we detect methyl isocyanide emission with a single antenna (Gaussian beamsize(Omega_B)=1723 arcsec^2) but not with an interferometer (Omega_B=192 arcsec^2), strongly suggests that methyl isocyanide has a widespread spatial distribution toward the Sgr B2(N) region. Thus, large-scale, non-thermal processes in the surrounding medium may account for the conversion of methyl cyanide to methyl isocyanide while the LMH hot core, which is dominated by thermal processes, does not produce a significant amount of methyl isocyanide. Ice analog experiments by other investigators have shown that radiation bombardment of methyl cyanide can produce methyl isocyanide, thus supporting our observations. We conclude that isomers separated by such large bonding energy differences are distributed in different interstellar environments, making the evaluation of column density ratios between such isomers irrelevant unless it can be independently shown that these species are co-spatial.

  13. Effect of Superalloy Substrate and Bond Coating on TBC Lifetime

    SciTech Connect (OSTI)

    Pint, Bruce A; Haynes, James A; Zhang, Ying

    2010-01-01

    Several different single-crystal superalloys were coated with different bond coatings to study the effect of composition on the cyclic oxidation lifetime of an yttria-stabilized zirconia (YSZ) top coating deposited by electron beam physical vapor deposition from a commercial source. Three different superalloys were coated with a 7 {micro}m Pt layer that was diffused into the surface prior to YSZ deposition. One of the superalloys, N5, was coated with a low activity, Pt-modified aluminide coating and Pt-diffusion coatings with 3 and 7 {micro}m of Pt. Three coatings of each type were furnace cycled to failure in 1 h cycles at 1150 C to assess average coating lifetime. The 7 {micro}m Pt diffusion coating on N5 had an average YSZ coating lifetime >50% higher than a Pt-modified aluminide coating on N5. Without a YSZ coating, the Pt-modified aluminide coating on N5 showed the typical surface deformation during cycling, however, the deformation was greatly reduced when constrained by the YSZ coating. The 3 {micro}m Pt diffusion coating had a similar average lifetime as the Pt-modified aluminide coating but a much wider scatter. The Pt diffusion bond coating on superalloy X4 containing Ti exhibited the shortest YSZ coating lifetime, this alloy-coating combination also showed the worst alumina scale adhesion without a YSZ coating. The third generation superalloy N6 exhibited the longest coating lifetime with a 7 {micro}m Pt diffusion coating.

  14. National Utility Rate Database: Preprint

    SciTech Connect (OSTI)

    Ong, S.; McKeel, R.

    2012-08-01

    When modeling solar energy technologies and other distributed energy systems, using high-quality expansive electricity rates is essential. The National Renewable Energy Laboratory (NREL) developed a utility rate platform for entering, storing, updating, and accessing a large collection of utility rates from around the United States. This utility rate platform lives on the Open Energy Information (OpenEI) website, OpenEI.org, allowing the data to be programmatically accessed from a web browser, using an application programming interface (API). The semantic-based utility rate platform currently has record of 1,885 utility rates and covers over 85% of the electricity consumption in the United States.

  15. Bubble growth rates in boiling

    E-Print Network [OSTI]

    Griffith, P.

    1956-01-01

    The conditions determining the growth rate of a bubble on a surface in boiling are considered and a mathematical model framed in the light of these conditions. The growth rate is then calculated for bubbles growing under ...

  16. 2007 Wholesale Power Rate Schedules : 2007 General Rate Schedule Provisions.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    2006-11-01

    This schedule is available for the contract purchase of Firm Power to be used within the Pacific Northwest (PNW). Priority Firm (PF) Power may be purchased by public bodies, cooperatives, and Federal agencies for resale to ultimate consumers, for direct consumption, and for Construction, Test and Start-Up, and Station Service. Rates in this schedule are in effect beginning October 1, 2006, and apply to purchases under requirements Firm Power sales contracts for a three-year period. The Slice Product is only available for public bodies and cooperatives who have signed Slice contracts for the FY 2002-2011 period. Utilities participating in the Residential Exchange Program (REP) under Section 5(c) of the Northwest Power Act may purchase Priority Firm Power pursuant to the Residential Exchange Program. Rates under contracts that contain charges that escalate based on BPA's Priority Firm Power rates shall be based on the three-year rates listed in this rate schedule in addition to applicable transmission charges. This rate schedule supersedes the PF-02 rate schedule, which went into effect October 1, 2001. Sales under the PF-07 rate schedule are subject to BPA's 2007 General Rate Schedule Provisions (2007 GRSPs). Products available under this rate schedule are defined in the 2007 GRSPs. For sales under this rate schedule, bills shall be rendered and payments due pursuant to BPA's 2007 GRSPs and billing process.

  17. Commercial Building Asset Rating Program

    Broader source: Energy.gov [DOE]

    Slides from a Commercial Building Initiative webinar outlining the Commercial Building Asset Rating Program on August 23, 2011.

  18. Methane oxidation rates by AMS

    E-Print Network [OSTI]

    Pack, M; Heintz, M; ReeburGh, WS; Trumbore, SE; Valentine, DL; Xu, X

    2009-01-01

    second case. Number of cases Methane oxidation rates by AMSIn the marine environment methane (CH 4 ) oxidation consumes

  19. Strained Si, SiGe, and Ge on-insulator: review of wafer bonding fabrication techniques

    E-Print Network [OSTI]

    Strained Si, SiGe, and Ge on-insulator: review of wafer bonding fabrication techniques Gianni was arranged by Prof. C.K. Maiti Abstract Techniques for fabricating strained Si, SiGe, and Ge on-insulator include SIMOX, Ge condensation and wafer bonding. In this paper, a brief introduction of each method

  20. Materials Science and Engineering A 458 (2007) 101107 Fluxless silicon-to-alumina bonding using electroplated

    E-Print Network [OSTI]

    Chen, Zhongping

    2007-01-01

    electroplated Au­Sn­Au structure at eutectic composition Jong S. Kima, Won S. Choia,1, Dongwook Kima,2, Andrei successfully bonded to alumina substrates with electroplated Au/Sn/Au structure at the eutectic composition. Keywords: Fluxless bonding; Fluxless soldering; Soldering; Eutectic Au­Sn alloys; Electroplating 1

  1. Alkane Contamination Effects on PFPE Lubricant Bonding to a-CHx Overcoats

    E-Print Network [OSTI]

    Gellman, Andrew J.

    Alkane Contamination Effects on PFPE Lubricant Bonding to a-CHx Overcoats Ryan Z. Lei and Andrew J contamination on the bonding of perfluoropolyalkyl ether (PFPE) lubricants to amorphous hydrogenated carbon (a, respectively, of the common disk lubricant Fomblin Zdol. Temperature-programmed desorption experiments were

  2. Effect of freezethaw cycles on the bond durability between fibre reinforced polymer plate

    E-Print Network [OSTI]

    Labossičre, Pierre

    Effect of freeze­thaw cycles on the bond durability between fibre reinforced polymer plate polymer (FRP) plates and sheets, are being developed. To apply these rehabilitation methods in Canada using both single lap pull-off and bond beam specimens. Only uniaxial carbon FRP strips were considered

  3. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    E-Print Network [OSTI]

    Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures

  4. Bonded carbon or ceramic fiber composite filter vent for radioactive waste

    DOE Patents [OSTI]

    Brassell, Gilbert W. (13237 W. 8th Ave., Golden, CO 80401); Brugger, Ronald P. (Lafayette, CO)

    1985-02-19

    Carbon bonded carbon fiber composites as well as ceramic or carbon bonded ceramic fiber composites are very useful as filters which can separate particulate matter from gas streams entraining the same. These filters have particular application to the filtering of radioactive particles, e.g., they can act as vents for containers of radioactive waste material.

  5. Accepted Manuscript Superconductivity in Entirely End-bonded Multi-Walled Carbon Nanotubes

    E-Print Network [OSTI]

    Maruyama, Shigeo

    Accepted Manuscript Superconductivity in Entirely End-bonded Multi-Walled Carbon Nanotubes I, Superconductivity in Entirely End-bonded Multi-Walled Carbon Nanotubes, Physica C (2007), doi: 10.1016/ j.physc.2007 disclaimers that apply to the journal pertain. #12;ACCEPTED MANUSCRIPT Physica C 1 Superconductivity

  6. Bond Computing Systems: a Biologically Inspired and High-level Dynamics Model for Pervasive Computing

    E-Print Network [OSTI]

    Dang, Zhe

    Bond Computing Systems: a Biologically Inspired and High-level Dynamics Model for Pervasive. Targeting at modeling the high-level dynamics of pervasive comput- ing systems, we introduce Bond Computing are regular, and study their computation power and verification problems. Among other results, we show

  7. Combining Bond-Graphs with Genetic Programming for Unified/Automated Design of Mechatronic or

    E-Print Network [OSTI]

    Fernandez, Thomas

    Combining Bond-Graphs with Genetic Programming for Unified/Automated Design of Mechatronic or Multi of a mechatronic system makes it difficult to model using a single modeling technique over the whole system and polymorphic modeling and simulation technique. Bond-Graph model of the mechatronic system can be directly

  8. Solvent Control of the Soft Angular Potential in Hydroxyl-Hydrogen Bonds: Inertial Orientational Dynamics

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solvent Control of the Soft Angular Potential in Hydroxyl- Hydrogen Bonds: Inertial Orientational with the hydrogen bond. The complexes studied are composed of phenol-OD (hydroxyl hydrogen replaced by deuterium orientational motions of phenol-OD (phenyl hydroxyl hydrogen replaced by deuterium) in phenol/-base complexes

  9. Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH

    E-Print Network [OSTI]

    Stixrude, Lars

    Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

  10. The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model.

    E-Print Network [OSTI]

    Kovchegov, Yevgeniy

    The Brownian Bridge Asymptotics in the Subcritical Phase of Bernoulli Bond Percolation Model)-dimensional Brownian bridge. 1 1 Introduction. In this paper we describe the limiting structure of a bond presented in [9] and [11]. We will also recall the definition of Brownian bridge. The result

  11. STANDARD OPERATING PROCEDURE FOR TUBE "A2-WetOxBond" furnace in TRL.

    E-Print Network [OSTI]

    Reif, Rafael

    STANDARD OPERATING PROCEDURE FOR TUBE "A2-WetOxBond" furnace in TRL. INTRODUCTION Tube "A2-Wet. Three Eurotherm temperature controllers provide a 20 inch long, flat profile in the Center Zone resistant gloves to handle those parts PROCEDURE. 1) "ENGAGE" the machine in CORAL for TRL tube "A2-WetOxBond"machine

  12. ForPeerReview Bond graph model of a switched reluctance machine

    E-Print Network [OSTI]

    Batlle, Carles

    Keywords: Electric machines, Reluctance machines, Modeling Are any of authors IEEE Member?: No Are any the electromechanical energy transformation in electrical machines, is used for a SRM. The bond graph modelForPeerReview Bond graph model of a switched reluctance machine Journal: Transactions on Industrial

  13. Mechanical switching and coupling between two dissociation pathways in a P-selectin adhesion bond

    E-Print Network [OSTI]

    Heinrich, Volkmar

    Mechanical switching and coupling between two dissociation pathways in a P-selectin adhesion bond energy barrier. Using a sensitive force probe to test the leukocyte adhesion bond P-selectin glycoprotein interactions among large multidomain proteins underlie most adhesive functions in biology. Well known

  14. Adhesively bonded lap joints with extreme interface geometry Babak Haghpanah, Shihung Chiu, Ashkan Vaziri n

    E-Print Network [OSTI]

    Vaziri, Ashkan

    Adhesively bonded lap joints with extreme interface geometry Babak Haghpanah, Shihung Chiu, Ashkan 2013 Keywords: Adhesively bonded joint Interface profile Failure Finite element a b s t r a c t The role of adhesive­adherend interface morphology (through intentional deviation from a flat joint plane

  15. Technical note Degradation of the bond between old and new mortar under cyclic shear

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    shrinkage of the new concrete, the quality of the bond is limited. Destructive measurement of the shear bond was used for mixing, which was conducted for 5 min. After that, the mix was poured into oiled molds. A vibrator was used to facilitate compaction and decrease the amount of air bubbles. A cylindrical piece

  16. System-Level Synthesis of MEMS via Genetic Programming and Bond Graphs

    E-Print Network [OSTI]

    Hu, Jianjun

    System-Level Synthesis of MEMS via Genetic Programming and Bond Graphs Zhun Fan+ , Kisung Seo for automatic synthesis of MEMS system-level lumped parameter models using genetic programming and bond graphs. This paper first dis- cusses the necessity of narrowing the problem of MEMS synthesis into a certain specific

  17. Modeling the metal-semiconductor interaction: Analytical bond-order potential for platinum-carbon

    E-Print Network [OSTI]

    Nordlund, Kai

    Modeling the metal-semiconductor interaction: Analytical bond-order potential for platinum for this potential makes use of the fact that chemical bonding in both covalent systems and d-transition metals can for describing the C-C/Pt-Pt/Pt-C interactions. It resembles, in the case of the pure metal interaction

  18. Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Don L. DeVoe

    E-Print Network [OSTI]

    Rubloff, Gary W.

    REVIEW Bonding of thermoplastic polymer microfluidics Chia-Wen Tsao Ć Don L. DeVoe Received: 20 Abstract Thermoplastics are highly attractive substrate materials for microfluidic systems, with important microchannels and other microfluidic elements, and thus bonding remains a critical step in any thermo- plastic

  19. Estimation of Bond Dissociation Energies and Radical Stabilization Energies by ESR Spectroscopy

    E-Print Network [OSTI]

    Brocks, Jochen J.

    stabilization enthalpies (RSE) and with BDE(C-H), the C-H bond dissociation energies for the corresponding stabilization energies and bond dissociation enthalpies (BDE) are useful for the prediction or inter- pretation be measured directly but must be deduced indirectly from the results of thermochemical, kinetic

  20. MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897 905 Dynamics and hydrogen bonding in liquid ethanol

    E-Print Network [OSTI]

    Saiz, Leonor

    MOLECULAR PHYSICS, 1999, VOL. 97, NO. 7, 897± 905 Dynamics and hydrogen bonding in liquid ethanol L of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol measurements of the frequency-dependent dielectric permittivity of liquid ethanol. 1. Introduction A detailed

  1. Coherent low-frequency motions of hydrogen bonded acetic acid dimers in the liquid phase

    E-Print Network [OSTI]

    Mukamel, Shaul

    of 1­2 ps. Calculations of the vibrational potential energy surface based on density functional theoryCoherent low-frequency motions of hydrogen bonded acetic acid dimers in the liquid phase Karsten; accepted 22 April 2004 Ultrafast vibrational dynamics of cyclic hydrogen bonded dimers and the underlying

  2. The Development of Werner-type Cobalt Complexes in Enantioselective Hydrogen Bond Mediated Catalysis 

    E-Print Network [OSTI]

    Lewis, Kyle

    2013-12-03

    nitrogen-hydrogen bonds of the diamine ligands could activate Lewis basic substrates towards nucleophilic addition via hydrogen bonding. Towards this end, the diastereomeric trications ?-[Co((S,S)-dpen)_(3)]^(3+) and ?-[Co((S,S)-dpen)_(3)]^(3+) (dpen...

  3. FRONTIERS ARTICLE Imaging bond breaking and vibrational energy transfer in small water

    E-Print Network [OSTI]

    Reisler, Hanna

    FRONTIERS ARTICLE Imaging bond breaking and vibrational energy transfer in small water containing it is possible to generate accurate potential energy surfaces (PESs) for small clusters, such as those of water (REMPI) are used to determine accurate bond dissociation energies (D0) of (H2O)2, (H2O)3, HCl­H2O and NH3

  4. The Production Rate and Employment of Ph.D. Astronomers

    E-Print Network [OSTI]

    Travis S. Metcalfe

    2007-12-19

    In an effort to encourage self-regulation of the astronomy job market, I examine the supply of, and demand for, astronomers over time. On the supply side, I document the production rate of Ph.D. astronomers from 1970 to 2006 using the UMI Dissertation Abstracts database, along with data from other independent sources. I compare the long-term trends in Ph.D. production with federal astronomy research funding over the same time period, and I demonstrate that additional funding is correlated with higher subsequent Ph.D. production. On the demand side, I monitor the changing patterns of employment using statistics about the number and types of jobs advertised in the AAS Job Register from 1984 to 2006. Finally, I assess the sustainability of the job market by normalizing this demand by the annual Ph.D. production. The most recent data suggest that there are now annual advertisements for about one postdoctoral job, half a faculty job, and half a research/support position for every new domestic Ph.D. recipient in astronomy and astrophysics. The average new astronomer might expect to hold up to 3 jobs before finding a steady position.

  5. Structural Aspects of Hydrogen Bonding with Nitrate and Sulfate: Design Criteria for Polyalcohol Hosts

    SciTech Connect (OSTI)

    Hay, Benjamin P.; Dixon, David A.; Lumetta, Gregg J.; Vargas, Rubicelia; Garza, Jorge

    2004-01-01

    Organic hosts for oxyanion complexation can be constructed by combining two or more hydrogen bonding sites. The deliberate design of architectures for such hosts requires knowledge of the optimal geometry for the hydrogen bonds formed between the host and the guest. Important structural parameters include the O--H distance, the O--H-D angle, the X-O--H angle, and the X-O--H-D dihedral angle (H-D=hydrogen bond donor, X=any atom). This information can be obtained through the analysis of hydrogen bonding observed in crystal structures and electronic structure calculations on simple gas-phase complexes. In this chapter, we present an analysis of hydrogen bonding structural parameters for alcohol hydrogen donors and the oxygen atom acceptors in nitrate and sulfate.

  6. Optical characterization of gaps in directly bonded Si compound optics using infrared spectroscopy

    E-Print Network [OSTI]

    Gully-Santiago, Michael; White, Victor

    2015-01-01

    Silicon direct bonding offers flexibility in the design and development of Si optics by allowing manufacturers to combine subcomponents with a potentially lossless and mechanically stable interface. The bonding process presents challenges in meeting the requirements for optical performance because air gaps at the Si interface cause large Fresnel reflections. Even small (35 nm) gaps reduce transmission through a direct bonded Si compound optic by 4% at $\\lambda = 1.25 \\; \\mu$m at normal incidence. We describe a bond inspection method that makes use of precision slit spectroscopy to detect and measure gaps as small as 14 nm. Our method compares low finesse Fabry-P\\'{e}rot models to high precision measurements of transmission as a function of wavelength. We demonstrate the validity of the approach by measuring bond gaps of known depths produced by microlithography.

  7. Wholesale Power Rate Schedules | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rate Schedules Wholesale Power Rate Schedules Wholesale Power Rate Schedules October 1, 2012 ALA-1-N Wholesale Power Rate Schedule Area: PowerSouth Energy Cooperative System:...

  8. Manganese Porphyrins Catalyze Selective C-H Bond Halogenations

    SciTech Connect (OSTI)

    Liu, Wei; Groves, John T

    2010-01-01

    We report a manganese porphyrin mediated aliphatic C?H bond chlorination using sodium hypochlorite as the chlorine source. In the presence of catalytic amounts of phase transfer catalyst and manganese porphyrin Mn(TPP)Cl 1, reaction of sodium hypochlorite with different unactivated alkanes afforded alkyl chlorides as the major products with only trace amounts of oxygenation products. Substrates with strong C?H bonds, such as neopentane (BDE =?100 kcal/mol) can be also chlorinated with moderate yield. Chlorination of a diagnostic substrate, norcarane, afforded rearranged products indicating a long-lived carbon radical intermediate. Moreover, regioselective chlorination was achieved by using a hindered catalyst, Mn(TMP)Cl, 2. Chlorination of trans-decalin with 2 provided 95% selectivity for methylene-chlorinated products as well as a preference for the C2 position. This novel chlorination system was also applied to complex substrates. With 5?-cholestane as the substrate, we observed chlorination only at the C2 and C3 positions in a net 55% yield, corresponding to the least sterically hindered methylene positions in the A-ring. Similarly, chlorination of sclareolide afforded the equatorial C2 chloride in a 42% isolated yield. Regarding the mechanism, reaction of sodium hypochlorite with the Mn{sup III} porphyrin is expected to afford a reactive Mn{sup V}?O complex that abstracts a hydrogen atom from the substrate, resulting in a free alkyl radical and a Mn{sup IV}—OH complex. We suggest that this carbon radical then reacts with a Mn{sup IV}—OCl species, providing the alkyl chloride and regenerating the reactive Mn{sup V}?O complex. The regioselectivity and the preference for CH{sub 2} groups can be attributed to nonbonded interactions between the alkyl groups on the substrates and the aryl groups of the manganese porphyrin. The results are indicative of a bent [Mn{sup v}?O---H---C] geometry due to the C—H approach to the Mn{sup v}?O (d??p?)* frontier orbital.

  9. Mean first passage times for bond formation for a Brownian particle in linear shear flow above a wall

    E-Print Network [OSTI]

    C. Korn; U. S. Schwarz

    2007-07-16

    Motivated by cell adhesion in hydrodynamic flow, here we study bond formation between a spherical Brownian particle in linear shear flow carrying receptors for ligands covering the boundary wall. We derive the appropriate Langevin equation which includes multiplicative noise due to position-dependent mobility functions resulting from the Stokes equation. We present a numerical scheme which allows to simulate it with high accuracy for all model parameters, including shear rate and three parameters describing receptor geometry (distance, size and height of the receptor patches). In the case of homogeneous coating, the mean first passage time problem can be solved exactly. In the case of position-resolved receptor-ligand binding, we identify different scaling regimes and discuss their biological relevance.

  10. A&A 491, 297309 (2008) DOI: 10.1051/0004-6361:200810362

    E-Print Network [OSTI]

    Priest, Eric

    2008-01-01

    for the reconnection rate and inflow speed, the coronal plasma and the Alfvén transit time. Key words. Sun: magnetic (about 4600 K). It is thought that the heating mecha- nism for the corona is of magnetic origin: the magnetic energy stored in the corona is released and converted into heat either by magnetic reconnection

  11. GE Healthcare Data File 11-0035-45 AA Multimodal media

    E-Print Network [OSTI]

    Lebendiker, Mario

    exchanger. It belongs to the Capto family of BioProcessTM media for fast, efficient and cost flow rates and low back pressure at large scale. The characteristics of Capto MMC are summarized those of a weak cation exchanger. However, in addition to the ionic interactions several other types

  12. A&A 466, 11971204 (2007) DOI: 10.1051/0004-6361:20064981

    E-Print Network [OSTI]

    Millar, Tom

    2007-01-01

    -neutral rate coefficients are included. Results. These two reactions sets have been used in a dark cloud model are available on the World Wide Web at www.udfa.net. Key words. molecular data ­ molecular processes ­ ISM to diffuse and dark interstellar clouds (Stantcheva & Herbst 2004; Lee et al. 2004), interstellar shocks

  13. Semi-emprical Molecular Orbital Calculation on XeF2 The bonding in XeF2 can be interpreted in terms the three-center four-electron bond. In linear XeF2 the molecular

    E-Print Network [OSTI]

    Rioux, Frank

    the three-center four-electron bond. In linear XeF2 the molecular orbital can be considered to be a linear electrons each in the bonding and non-bonding orbitals for a total energy of -72.14 eV. The energy. The fluorine atoms have a kernel charge of +7. They get credit for 6 non-bonding atomic electrons, 42

  14. Method of waste stabilization with dewatered chemically bonded phosphate ceramics

    DOE Patents [OSTI]

    Wagh, Arun; Maloney, Martin D.

    2010-06-29

    A method of stabilizing a waste in a chemically bonded phosphate ceramic (CBPC). The method consists of preparing a slurry including the waste, water, an oxide binder, and a phosphate binder. The slurry is then allowed to cure to a solid, hydrated CBPC matrix. Next, bound water within the solid, hydrated CBPC matrix is removed. Typically, the bound water is removed by applying heat to the cured CBPC matrix. Preferably, the quantity of heat applied to the cured CBPC matrix is sufficient to drive off water bound within the hydrated CBPC matrix, but not to volatalize other non-water components of the matrix, such as metals and radioactive components. Typically, a temperature range of between 100.degree. C.-200.degree. C. will be sufficient. In another embodiment of the invention wherein the waste and water have been mixed prior to the preparation of the slurry, a select amount of water may be evaporated from the waste and water mixture prior to preparation of the slurry. Another aspect of the invention is a direct anyhydrous CBPC fabrication method wherein water is removed from the slurry by heating and mixing the slurry while allowing the slurry to cure. Additional aspects of the invention are ceramic matrix waste forms prepared by the methods disclosed above.

  15. Method for bonding thin film thermocouples to ceramics

    DOE Patents [OSTI]

    Kreider, Kenneth G. (Potomac, MD)

    1993-01-01

    A method is provided for adhering a thin film metal thermocouple to a ceramic substrate used in an environment up to 700 degrees Centigrade, such as at a cylinder of an internal combustion engine. The method includes the steps of: depositing a thin layer of a reactive metal on a clean ceramic substrate; and depositing thin layers of platinum and a platinum-10% rhodium alloy forming the respective legs of the thermocouple on the reactive metal layer. The reactive metal layer serves as a bond coat between the thin noble metal thermocouple layers and the ceramic substrate. The thin layers of noble metal are in the range of 1-4 micrometers thick. Preferably, the ceramic substrate is selected from the group consisting of alumina and partially stabilized zirconia. Preferably, the thin layer of reactive metal is in the range of 0.015-0.030 micrometers (15-30 nanometers) thick. The preferred reactive metal is chromium. Other reactive metals may be titanium or zirconium. The thin layer of reactive metal may be deposited by sputtering in ultra high purity argon in a vacuum of approximately 2 milliTorr (0.3 Pascals).

  16. Specificity, flexibility and valence of DNA bonds guide emulsion architecture

    E-Print Network [OSTI]

    Lang Feng; Lea-Laetitia Pontani; Remi Dreyfus; Paul Chaikin; Jasna Brujic

    2013-03-25

    The specificity and thermal reversibility of DNA interactions have enabled the self-assembly of crystal structures, self-replicating materials and colloidal molecules. Grafting DNA onto liquid interfaces of emulsions leads to exciting new architectural possibilities due to the mobility of the DNA ligands and the patches they form between bound droplets. Here we show that the size and number of these adhesion patches (valency) can be controlled. Valence 2 leads to flexible polymers of emulsion droplets, while valence above 4 leads to rigid droplet networks. A simple thermodynamic model quantitatively describes the increase in the patch size with droplet radii, DNA concentration and the stiffness of the tether to the sticky-end. The patches are formed between droplets with complementary DNA strands or alternatively with complementary colloidal nanoparticles to mediate DNA binding between droplets. This emulsion system opens the route to directed self-assembly of more complex structures through distinct DNA bonds with varying strengths and controlled valence and flexibility.

  17. A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular C-O Bond Formation with Secondary and Primary Alcohols

    E-Print Network [OSTI]

    Wu, Xiaoxing

    Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the ...

  18. ADSORPTION AND BONDING OF BUTANE AND PENTANE ON THE Pt(111) CRYSTAL SURFACES. EFFECTS OF OXYGEN TREATMENTS AND DEUTERIUM PREADSORPTION

    E-Print Network [OSTI]

    Salmeron, M.

    2012-01-01

    ADSORPTION AND BONDING OF BUTANE AND PENTANE ON THE .Pt(111)ADSORPTION AND BONDING OF BUTANE AND PENTANE ON THE Pt(lll)adsorption characteristics of butane and pentane on the (

  19. An On-Target Performic Acid Oxidation Method Suitable for Disulfide Bond Elucidation Using Capillary Electrophoresis - Mass Spectrometry 

    E-Print Network [OSTI]

    Williams, Brad J.

    2011-08-08

    advancements, the detection and proper assignment of disulfide bonds have remained experimentally difficult. Therefore, we have developed an alternative method for disulfide bond elucidation using capillary electrophoresis-mass spectrometry (CE-MS) combined...

  20. The Dependence of Electrical Properties on Miscut Orientation in Direct Bonded III-V Solar Cell Layers

    E-Print Network [OSTI]

    Seal, Mark K.

    2015-01-01

    GaInAs concentrator solar cells with 44.7% efficiency",wafer-bonded tandem solar cells”, 38 th IEEE Photovoltaicfor Wafer-Bonded Tandem Solar Cells”, ECS Trans. 50 99 (

  1. Transient-Liquid-Phase (TLP) Bonding of Al2O3 Using Nb-based Multilayer Interlayers

    E-Print Network [OSTI]

    Hong, Sung Moo

    2009-01-01

    Brazing. Zeitschrift Fur Metallkunde, vol. 85, no. 12 (1994)Bonding. Zeitschrift Für Metallkunde, vol. 85, no. 11 (1994)

  2. C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices

    E-Print Network [OSTI]

    Bansal, Manju

    C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices Anirban Ghosh and Manju-pair as well as cross-strand C-H..O hydrogen bonds in the minor groove. The C2-H2..O2 hydrogen bonds within leads to a narrow minor groove in these regions. # 1999 Academic Press Keywords: C-H..O hydrogen bonds

  3. Density and water content of nanoscale solid C-S-H formed in alkali-activated slag (AAS) paste and implications for chemical shrinkage

    SciTech Connect (OSTI)

    Thomas, Jeffrey J., E-mail: jthomas39@slb.com [Schlumberger-Doll Research, Cambridge, MA 02139 (United States); Allen, Andrew J. [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Jennings, Hamlin M. [CSHub, Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States)

    2012-02-15

    Alkali-activated slag (AAS) paste was analyzed using small-angle neutron scattering (SANS). The scattering response indicates that the microstructure consists of a uniform matrix of hydration product with a high surface area studded with unhydrated cores of slag particles. In contrast with portland cement paste, no surface fractal scattering regime was detected, and elevated temperature curing (at 60 Degree-Sign C) had no detectable effect on the microstructure at any length scale studied. The specific surface area of the AAS pastes is about 25% higher than that of a portland cement paste cured under the same conditions. The composition and mass density of the nanoscale solid C-S-H phase formed in the AAS paste was determined using a previously developed neutron scattering method, in conjunction with a hydration model. The result ((CaO){sub 0.99}-SiO{sub 2}-(Al{sub 2}O{sub 3}){sub 0.06}-(H{sub 2}O){sub 0.97}, d = (2.73 {+-} 0.02) g/cm{sup 3}) is significantly lower in calcium and in water as compared to portland cement or pure tricalcium silicate paste. These values were used to calculate the chemical shrinkage that would result from complete hydration of the AAS paste. The result, (12.2 {+-} 1.5) cm{sup 3} of volumetric shrinkage per 100 g of unhydrated cement, is about twice the amount of chemical shrinkage exhibited by normal cement pastes.

  4. ARCHITECTURE Of SMALL COMPUTING CLUSTERS IN HIGH ENERGY PHYSICS A.N. Lodkin, A.A. Oreshkin, A.Y. Shevel, T.S. Serebrova

    E-Print Network [OSTI]

    Titov, Anatoly

    329 ARCHITECTURE Of SMALL COMPUTING CLUSTERS IN HIGH ENERGY PHYSICS A.N. Lodkin, A.A. Oreshkin, A computing architecture might be used by small physicist's teams. Contemporary architecture of small architecture someone can easily send jobs to another cluster where the data are, i.e. it possible to use more

  5. PREDICTION OF REGIONAL WIND POWER T.S. Nielsen1, H. Madsen1, H. Aa. Nielsen1, L. Landberg2, G. Giebel2

    E-Print Network [OSTI]

    PREDICTION OF REGIONAL WIND POWER T.S. Nielsen1, H. Madsen1, H. Aa. Nielsen1, L. Landberg2, G the total wind power production in a larger region based on a combination of on-line measurements of power production from selected wind farms, power measure- ments for all wind turbines in the area and numerical

  6. RevMexAA (Serie de Conferencias), 00, 1--8 (2000) THE AGE OF THE GALAXY FROM THORIUM COSMOCHRONOMETRY 3

    E-Print Network [OSTI]

    Cowan, John

    2000-01-01

    RevMexAA (Serie de Conferencias), 00, 1--8 (2000) THE AGE OF THE GALAXY FROM THORIUM. The long­lived radioactive element thorium can potentially provide a simple and direct clock to determine the age of our Galaxy. Spectroscopic investigations of thorium in metal­poor stars have yielded some

  7. PREDICTION OF REGIONAL WIND POWER T.S. Nielsen1, H. Madsen1, H. Aa. Nielsen1, L. Landberg2, G. Giebel2

    E-Print Network [OSTI]

    PREDICTION OF REGIONAL WIND POWER T.S. Nielsen1, H. Madsen1, H. Aa. Nielsen1, L. Landberg2, G, Denmark Tel: +45 4525 3428, Fax: +45 4588 2673, E-mail: tsn@imm.dtu.dk 2Department of Wind Energy Risř the total wind power production in a larger region based on a combination of on-line measurements of power

  8. Automi e Linguaggi Formali { A.A. 2013/2014 1. Dire se esiste un algoritmo (che termini in tempo nito) che, dato in

    E-Print Network [OSTI]

    Rossi, Francesca

    Automi e Linguaggi Formali { A.A. 2013/2014 Homework 7 22.11.2013 1. Dire se esiste un algoritmo ferma per la stringa ab 2. Dire se esiste un algoritmo (che termini in tempo #12;nito) che, dato

  9. Automi e Linguaggi Formali A.A. 2011/2012 1. Dire se esiste un algoritmo (che termini in tempo finito) che, dato in

    E-Print Network [OSTI]

    Rossi, Francesca

    Automi e Linguaggi Formali ­ A.A. 2011/2012 Homework 7 24.11.2011 1. Dire se esiste un algoritmo ferma per la stringa ab 2. Dire se esiste un algoritmo (che termini in tempo finito) che, dato in input

  10. N AA Knows Climate "The climate challenge before us is real. Climate change impacts will touch nearly every aspect of our lives. Meeting the

    E-Print Network [OSTI]

    N AA Knows Climate "The climate challenge before us is real. Climate change impacts will touch activities have been directly affected by climate change. Our scientist have implemented programs to understand the effects of climate change on marine resources and are working with our managers to modify

  11. In Journal of Parallel and Distributed Computing, vol. 26, pp. 125131, 1995. Analysis of the Convergence and Generalization of AA1

    E-Print Network [OSTI]

    Martinez, Tony R.

    Science, Brigham Young University Abstract AA1 is an incremental learning algorithm for Adaptive Self a renewed interest in connectionist computing. Some of the reasons for this interest can be traced' functions. Adaptive Self­Organizing Concurrent Systems (ASOCS) are dynamic networks that learn by adapting

  12. EEO/AA Institution. 10,000 copies of this public document were printed at a cost of $X,XXX or $.XX per copy. OFFICE OF ADMISSIONS

    E-Print Network [OSTI]

    Olszewski Jr., Edward A.

    EEO/AA Institution. 10,000 copies of this public document were printed at a cost of $X,XXX or $.XX in campus through student organizations, academic and/or social opportunities, and meeting new friends for fall entry. Additional first-year students may be offered admission in our First Year Spring Admit

  13. CdL in Informatica --a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerd 16 marzo 2007

    E-Print Network [OSTI]

    Cutolo, Giovanni

    CdL in Informatica -- a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerdě un numero naturale n tale che 140 | n5 e 7 n3 . vero falso dati insufficienti · Esiste un'algebra di Boole di ordine 512. vero falso dati insufficienti · 98 divide 25 38 54 78 116 . vero falso dati

  14. CdS in Informatica --a.a. 2007/2008 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerd 19 dicembre 2008

    E-Print Network [OSTI]

    Cutolo, Giovanni

    ) di tipo (2, 2, 1, 0, 0) `e un'algebra di Boole se e solo se: · (A, , 0) e (A, , 1) sonoCdS in Informatica -- a.a. 2007/2008 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) venerdě

  15. CdL in Informatica --a.a. 2004/2005 Esercitazione scritta di ALGEBRA (Prof. Rao) venerd 20 maggio 2005

    E-Print Network [OSTI]

    Cutolo, Giovanni

    algebra di Boole, di anello booleano e di reticolo booleano. Sia x S e sia T = {A P(S) | x A}. In PCdL in Informatica -- a.a. 2004/2005 Esercitazione scritta di ALGEBRA (Prof. Rao) venerdě 20 maggio(S), con riferimento alle strutture pertinenti, T `e una sottoalgebra di Boole? s`i no impossibile

  16. CdL in Informatica --a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) luned 15 gennaio 2007

    E-Print Network [OSTI]

    Cutolo, Giovanni

    CdL in Informatica -- a.a. 2006/2007 Esercitazione scritta di ALGEBRA (Proff. Cutolo e Rao) lunedě tale che B (con l'ordinamento indotto da ) sia un reticolo di Boole. `E B = A? s`i no . `E B = A? s

  17. On the accuracy of density-functional theory exchange-correlation functionals for H bonds in small water clusters. II. The water hexamer

    E-Print Network [OSTI]

    Alavi, Ali

    On the accuracy of density-functional theory exchange-correlation functionals for H bonds in small for hydro- gen H bonds? What is the best exchange-correlation xc functional for treating H bonds? Questions

  18. LMS SUBSCRIPTION RATES & NOTES 2014/15 SUBSCRIPTION RATES

    E-Print Network [OSTI]

    1 LMS SUBSCRIPTION RATES & NOTES 2014/15 SUBSCRIPTION RATES LMS membership subscription: Ł US.00 Associate membership 16.00 32.00 Free membership (see note 2) Print only Online only Print & online* LMS, or are unemployed or otherwise in hardship. Contact membership@lms.ac.uk to enquire further. #12;LMS PUBLICATIONS 4

  19. LMS SUBSCRIPTION RATES & NOTES 2013/14 SUBSCRIPTION RATES

    E-Print Network [OSTI]

    1 LMS SUBSCRIPTION RATES & NOTES 2013/14 SUBSCRIPTION RATES LMS membership subscription: Ł US.00 Associate membership 15.00 30.00 Free membership (see note 2) Print only Online only Print & online* LMS, or are unemployed or otherwise in hardship. Contact membership@lms.ac.uk to enquire further. #12;LMS PUBLICATIONS 4

  20. Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon wafers

    E-Print Network [OSTI]

    Akin, Tayfun

    Plasma-activated direct bonding of diamond-on-insulator wafers to thermal oxide grown silicon microscopy, profilometer and wafer bow measurements. Plasma-activated direct bonding of DOI wafers to thermal September 2010 Keywords: Diamond-on-insulator Plasma activation Ultrananocrystalline diamond Direct bonding

  1. A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a Short Bi-Bi Bond: Synthesis and Structure

    E-Print Network [OSTI]

    A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a Short Bi-Bi Bond: Synthesis and Structure Li UniVersity of Notre Dame, Notre Dame, Indiana 46556 ReceiVed July 12, 1999 We have made a naked of substituted diatomic species with single bonds.1,6,7 Singly bonded naked molecules are also known but all

  2. Volume 136, number 6 CHEMICAL PHYSICS LETTERS 22 May 1987 MECHANISM FOR BOND-SELECTIVE PROCESSES IN LASER DESORPTION

    E-Print Network [OSTI]

    for short pulse excitation. Deviations from such statistical behavior require the existence of "bottlenecks pumped. A bottleneck may occur however in the energy flow from the sur- face-adsorbate van der Waals bond to be pumped via excitation of the physisorption bond. The energy flow out of this bond and into the mol- 0 009

  3. Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton-Coupled Electron Transfer in BLUF

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Hydrogen Bond Switching among Flavin and Amino Acids Determines the Nature of Proton results from a hydrogen bond switch between the flavin and its surrounding amino acids that preconfigures a rearrangement of the hydrogen bond network around the flavin takes place leading to a 10-15 nm red shift

  4. Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed by Ultrafast Infrared Spectroscopy

    E-Print Network [OSTI]

    van Stokkum, Ivo

    Hydrogen Bond Switching among Flavin and Amino Acid Side Chains in the BLUF Photoreceptor Observed hydrogen-bond network with nearby amino acid side chains, including a highly conserved tyrosine and glutamine. The participation of particular amino acid side chains in the ultrafast hydrogen-bond switching

  5. Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen

    E-Print Network [OSTI]

    Agard, David

    Subangstrom Crystallography Reveals that Short Ionic Hydrogen Bonds, and Not a His-Asp Low-Barrier Hydrogen Bond, Stabilize the Transition State in Serine Protease Catalysis Cynthia N. Fuhrmann, Matthew D that destabilizes the His57-Ser195 hydrogen bond, preventing the back-reaction. In both structures the His57-Asp102

  6. Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through Deuterium Exchange

    E-Print Network [OSTI]

    Crofts, Antony R.

    Hydrogen Bonds Involved in Binding the Qi-site Semiquinone in the bc1 Complex, Identified through them. The strength of interactions indicates that the protons are involved in hydrogen bonds with SQ. The hyperfine cou- plings differ from values typical for in-plane hydrogen bonds previously observed in model

  7. Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Alexei Khalizov, and Renyi Zhang*

    E-Print Network [OSTI]

    Hydrogen-Bonding Interaction in Molecular Complexes and Clusters of Aerosol Nucleation Precursors, water, and ammonia. A central feature of the complexes is the presence of two hydrogen bonds. Organic acid-sulfuric acid complexes show one strong and one medium-strength hydrogen bond whereas

  8. Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran and cyclohexane rings in organic crystals

    E-Print Network [OSTI]

    de Gispert, Adriŕ

    Paper Hydrogen bonding preference of equatorial versus axial hydroxyl groups in pyran of the hydrogen bonding counts in crystalline pyranose monosaccharides, we noticed that equatorial hydroxyls formed more hydrogen bonds, on average, than axial groups. A survey of the Cambridge Structural Database

  9. Chemistry of Materials 1989, 1,83-101 How C-C Bonds Are Formed and How They Influence

    E-Print Network [OSTI]

    Li, Jing

    Chemistry of Materials 1989, 1,83-101 How C-C Bonds Are Formed and How They Influence Structural Choices in Some Binary and Ternary Metal Carbides 83 Jing Li and Roald Hoffmann* Department of Chemistry properties. In the UC2structure, both uranium-carbon bonding and carbon-carbon bonding are enhanced upon

  10. Classification of metal-oxide bonded interactions based on local potential-and kinetic-energy densities

    E-Print Network [OSTI]

    Downs, Robert T.

    of the local potential-energy density and G rc is the local kinetic-energy density, each evaluated at a bond rc and the local electronic energy density, H rc =G rc +V rc , in the H­F study, yielded practically the bond critical point and local energy density properties with the bond lengths displayed by the H

  11. Inhibition of Hotspot Formation in Polymer Bonded Explosives Using an Interface Matching Low Density Polymer Coating at the Polymer-

    E-Print Network [OSTI]

    Goddard III, William A.

    Inhibition of Hotspot Formation in Polymer Bonded Explosives Using an Interface Matching Low Density Polymer Coating at the Polymer- Explosive Interface Qi An, William A. Goddard, III,*, Sergey V/s) on a prototype polymer bonded explosive (PBX) consisting of cyclotrimethylene trinitramine (RDX) bonded

  12. Production of mini-(gluon)jets and strangeness enhancement in pA and AA collisions at relativistic energies

    E-Print Network [OSTI]

    Tai An; Sa Ben-Hao

    1998-04-01

    The idea that effective string tension increases as a result of the hard gluon kinks on a string is applied to study the strange particle production in proton-nucleus and nucleus-nucleus collisions. It is found that the effective string tension increases with the increase of centrality and mass of the colliding system as a consequence of the mini-(gluon)jet production stemming from the collective string-string interaction. This mechanism leads to strangeness enhancement in pA and AA collisions through the enhanced production of the strange quark pairs from the color field of strings. We discuss different roles played by this mechanism and rescattering of the final state hadrons in the production of strange particles and compare our results with experimental data.

  13. Estimate of Solar Maximum using the 1-8 \\AA$\\,$Geostationary Operational Environmental Satellites X-ray Measurements

    E-Print Network [OSTI]

    Winter, L M

    2014-01-01

    We present an alternate method of determining the progression of the solar cycle through an analysis of the solar X-ray background. Our results are based on the NOAA Geostationary Operational Environmental Satellites (GOES) X-ray data in the 1-8 \\AA$\\,$band from 1986 - present, covering solar cycles 22, 23, and 24. The X-ray background level tracks the progression of the solar cycle through its maximum and minimum. Using the X-ray data, we can therefore make estimates of the solar cycle progression and date of solar maximum. Based upon our analysis, we conclude that the Sun reached its hemisphere-averaged maximum in Solar Cycle 24 in late 2013. This is within six months of the NOAA prediction of a maximum in Spring 2013.

  14. Upper Great Plains Rates information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 2014 (112 KB .pdf) FRN Notice of Proposed Transmission and Ancillary Services Formula Rates November 3, 2014 (93 KB .pdf) SPP Membership Information Integrated System (IS)...

  15. Sustainable Building Rating Systems Summary

    SciTech Connect (OSTI)

    Fowler, Kimberly M.; Rauch, Emily M.

    2006-07-01

    The purpose of this document is to offer information that could be used to compare and contrast sustainable building rating systems.

  16. Bond Energy Sums in Benzene, Cyclohexatriene and Cyclohexane Prove Resonance Unnecessary

    E-Print Network [OSTI]

    Raji Heyrovska

    2008-07-27

    The recent new structure of benzene shows that it consists of three C atoms of radii as in graphite alternating with three C atoms with double bond radii. This is different from the hypothetical cyclohexatriene (Kekule structure) involving alternate double and single bonds. It was shown that the difference in the bond energy sum of the atomic structure of benzene from that of the Kekule structure is the energy (erroneously) assumed to be due to resonance. Here it is shown that the present structure of benzene also explains the energy of hydrogenation into cyclohexane and its difference from that of cyclohexatriene.

  17. A Strong Bond Model for Stress Relaxation of Soft Solid Interfaces

    E-Print Network [OSTI]

    Arun K. Singh; Vinay A. Juvekar

    2014-11-29

    In this article, we propose a mathematical model which explains the formation of strong bonds during the relaxation process of a soft solid on a hard surface. As a result, the soft solid relaxes to a non zero residual stress level. The model assumes that formation of strong bonds occurs owing to transition from weak to strong bonds at a critical time. Parametric studies are carried out to understand the effect of different friction parameters related with the model on the relaxation process. The relaxation model is, in turn, validated with experiments and corresponding numerical values are justified.

  18. Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces

    SciTech Connect (OSTI)

    James A. Smith; Jeffrey M. Lacy; Barry H. Rabin

    2014-07-01

    12. Other advances in QNDE and related topics: Preferred Session Laser-ultrasonics Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces 41st Annual Review of Progress in Quantitative Nondestructive Evaluation Conference QNDE Conference July 20-25, 2014 Boise Centre 850 West Front Street Boise, Idaho 83702 James A. Smith, Jeffrey M. Lacy, Barry H. Rabin, Idaho National Laboratory, Idaho Falls, ID ABSTRACT: The US National Nuclear Security Agency has a Global Threat Reduction Initiative (GTRI) which is assigned with reducing the worldwide use of high-enriched uranium (HEU). A salient component of that initiative is the conversion of research reactors from HEU to low enriched uranium (LEU) fuels. An innovative fuel is being developed to replace HEU. The new LEU fuel is based on a monolithic fuel made from a U-Mo alloy foil encapsulated in Al-6061 cladding. In order to complete the fuel qualification process, the laser shock technique is being developed to characterize the clad-clad and fuel-clad interface strengths in fresh and irradiated fuel plates. The Laser Shockwave Technique (LST) is being investigated to characterize interface strength in fuel plates. LST is a non-contact method that uses lasers for the generation and detection of large amplitude acoustic waves to characterize interfaces in nuclear fuel plates. However the deposition of laser energy into the containment layer on specimen’s surface is intractably complex. The shock wave energy is inferred from the velocity on the backside and the depth of the impression left on the surface from the high pressure plasma pulse created by the shock laser. To help quantify the stresses and strengths at the interface, a finite element model is being developed and validated by comparing numerical and experimental results for back face velocities and front face depressions with experimental results. This paper will report on initial efforts to develop a finite element model for laser shock.

  19. Hydrogen bond studies. 85. A very short, asymmetrical, intramolecular hydrogen bond: A neutron diffraction study of pyridine?2,3?dicarboxylic acid (C7H5NO4)

    E-Print Network [OSTI]

    Kvick, Å ke; Koetzle, Thomas F.; Thomas, Robert; Takusagawa, Fusao

    1974-01-01

    ) 1" '09 204 50) " . 305 ,9, '" 201 lb9 '" '" 281 1" 324 'I' ll,209 '!b '" 49' 240 '" '" 234 261 "4 219 m Rw"[6W IFg-IFcI212/6WF6r/2,,0.082 The corresponding conventional R(F) was 0.040 if the 453 reflexions with F ~ < 3uc(F~) were... crystal forces distort the symmetry of the short hydrogen bond. Asymmetry in the molecule does not always give asymmetry in com­ parable bonds, however. This is illustrated in potassi­ um hydrogen chloromaleate, 15 where the hydrogen atom is effectively...

  20. Innovative Rates Program. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-06-21

    Title II of the Energy Conservation and Production Act (ECPA) as amended by the Public Utility Regulatory Policies Act (PURPA) provided financial assistance to state utility regulatory commissions, nonregulated electric utilities, and the Tennessee Valley Authority through the Innovative Rates Program. The financial assistance was to be used to plan or carry out electric utility regulatory rate reform initiatives relating to innovative rate structures that encourage conservation of energy, electric utility efficiency and reduced costs, and equitable rates to consumers. The Federal and local objectives of the project are described. Activities planned and accomplishments are summarized for the following: project management, data collection, utility bill evaluation, billing enclosure/mailing evaluation, media program evaluation, display evaluation, rate study sessions evaluation, speakers bureau evaluation, and individual customer contacts. A timetable/milestone chart and financial information are included. (MHR)

  1. Feasibility study on bonding quality inspection of microfluidic devices by optical coherence tomography

    E-Print Network [OSTI]

    Li, Shiguang

    This paper reports the feasibility of optical coherence tomography (OCT) technology for inspection of bonding quality of microfluidic devices in manufacturing environments. A compact optical-fiber–based OCT is developed ...

  2. Metal Catalyzed sp2 Bonded Carbon - Large-scale Graphene Synthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Catalyzed sp2 Bonded Carbon - Large-scale Graphene Synthesis and Beyond December 1, 2009 at 3pm36-428 Peter Sutter Center for Functional Nanomaterials sutter abstract:...

  3. Palladium(0)-Catalyzed Intermolecular Amination of Unactivated C[3 over sp]-H Bonds

    E-Print Network [OSTI]

    Pan, Jun

    Filling out the space: The title reaction of unactivated C[3 over sp]-H bonds using aryl amines as the nitrogen source is disclosed (see scheme; dba=dibenzylideneacetone, Tf=trifluoromethanesulfonyl). Either the C-N ...

  4. Mutant microorganisms useful for cleavage of organic C-S bonds

    DOE Patents [OSTI]

    Kilbane, II, John J. (Woodstock, IL)

    1991-01-01

    A mutant Bacillus sphaericus strain ATC No. 53969 which has the property of sulfur removal and sulfur metabolism by selective cleavage of C-S bonds in organic carbonaceous materials.

  5. Scaling of the dynamics of flexible Lennard-Jones chains. II. Effects of harmomic bonds

    E-Print Network [OSTI]

    Veldhorst, Arno A; Schrřder, Thomas B

    2015-01-01

    The previous paper [Veldhorst et al., J. Chem. Phys. 141, 054904 (2014)] demonstrated that the isomorph theory explains the scaling properties of a liquid of flexible chains consisting of ten Lennard-Jones particles connected by rigid bonds. We here investigate the same model with harmonic bonds. The introduction of harmonic bonds almost completely destroys the correlations in the equilibrium fluctuations of the potential energy and the virial. According to the isomorph theory, only if these correlations are strong does a system have isomorphs, which are curves in the phase diagram along which structure, dynamics and the excess entropy are invariant. The liquid with harmonic bonds does have curves in the phase diagram along which the structure and dynamics are invariant. The excess entropy is not invariant on these curves, which we therefore refer to as "pseudoisomorphs". In particular this means that Rosenfeld's excess-entropy scaling (the dynamics being a function of excess entropy only) does not apply for ...

  6. EFFECT OF EXCIMER LASER IRRADIATION OF BIODEGRADABLE POLYMER ON ITS CHEMICAL BONDING

    E-Print Network [OSTI]

    Yao, Y. Lawrence

    EFFECT OF EXCIMER LASER IRRADIATION OF BIODEGRADABLE POLYMER ON ITS CHEMICAL BONDING Paper M1306 profile is favorable for surface treatment. The effects of excimer laser irradiation on the surface irradiation as a hea

  7. Commercialization of low temperature copper thermocompression bonding for 3D integrated circuits

    E-Print Network [OSTI]

    Nagarajan, Raghavan

    2008-01-01

    Wafer bonding is a key process and enabling technology for realization of three-dimensional integrated circuits (3DIC) with reduced interconnect delay and correspondingly increased circuit speed and decreased power ...

  8. Distal hydrogen-bonding effects and cofacial bimetallic salen architectures for oxygen activation chemistry

    E-Print Network [OSTI]

    Yang, Jenny Yue-fon

    2007-01-01

    Two distinct structural scaffolds elaborated from Schiff-base macrocycles were designed to study the proton-coupled electron transfer chemistry of 0-0 bond forming and activation chemistry. The "Hangman" architecture is ...

  9. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  10. An Investigation of Bonding Mechanism in Metal Cladding by Warm Rolling 

    E-Print Network [OSTI]

    Yang, Wei

    2012-02-14

    Clad metals are extensively used for their multi-functionality and their optimal combination of quality and cost. Roll bonding is an effective and economic processing approach to making clad metals. This dissertation ...

  11. Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

    SciTech Connect (OSTI)

    Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

    1994-06-01

    The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

  12. Tubulin Bond Energies and Microtubule Biomechanics Determined from Nanoindentation in Silico

    E-Print Network [OSTI]

    Barsegov, Valeri

    Tubulin Bond Energies and Microtubule Biomechanics Determined from Nanoindentation in Silico Olga explore the biomechanics of microtubule polymers using multi- scale computational modeling and experimental force-deformation spectra enabled us to correlate the microtubule biomechanics with dynamic

  13. Environmental durability of FRP bond to concrete subjected to freeze-thaw action

    E-Print Network [OSTI]

    Dohnálek, Pavel

    2006-01-01

    An experimental study was performed to determine the environmental durability of the adhesive bond between fiber-reinforced plastic (FRP) and concrete. The study specifically focused on freeze-thaw cycling exposure of such ...

  14. Hybrid Two-Dimensional Electronic Systems and Other Applications of sp-2 Bonded Light Elements

    E-Print Network [OSTI]

    Kessler, Brian Maxwell

    2010-01-01

    A.4 A.5 vii List of Tables DOE Hydrogen Storage Targets forsp-2 Bonded Materials 5 Hydrogen Storage 5.1 Motivation andJeffrey R. Long. Hydrogen storage in a microporous metal-

  15. From molecular chemistry to supramolecular chemistry to superdupermolecular chemistry. Controlling covalent bond formation

    E-Print Network [OSTI]

    Turro, Nicholas J.

    From molecular chemistry to supramolecular chemistry to superdupermolecular chemistry. Controlling covalent bond formation through non-covalent and magnetic interactions Nicholas J. Turro Chemistry. Introduction Carbon centered radicals are among the most reactive species encountered in organic chemistry

  16. Mourning 2.0: Continuing Bonds between the Living and the Dead on Facebook

    E-Print Network [OSTI]

    Irwin, Melissa D.

    2012-05-31

    This study examines the burgeoning phenomenon of Facebook memorial pages and how this research about dynamic, online social networking environments can contribute to the existing literature related to Klass et al's (1996) continuing bonds thesis...

  17. The contribution of tyrosine water=hydrogen bonds to protein stability 

    E-Print Network [OSTI]

    Bechert, Charles John

    2013-02-22

    The goal of this research was to determine how protein stability is affected when tyrosines form specific inter and/or intramolecular hydrogen bonds in the folded state. Our model protein, the enzyme RNase Sa, contains four Tyr residues believed...

  18. Fluorescein and Rosamine Derivatives as Donors/Acceptors for "Through-bond" Energy Transfer Cassettes 

    E-Print Network [OSTI]

    Castro, Juan C.

    2010-07-14

    A series of fluorescein and rosamine derivatives have been prepared and their spectroscopical properties analyzed to determine their usefulness as donor and/or acceptors in "through-bond" energy transfer systems. Such new ...

  19. Catalytic C-N and C-F bond formation by organometallic group 11 complexes

    E-Print Network [OSTI]

    Akana, Jennifer Anne

    2007-01-01

    This thesis presents a study of the reaction between an (NHC)gold(I) fluoride complex (NHC = N-heterocyclic carbene) and alkynes (Chapter 1). Gold(I) and fluoride add trans across the triple bond of 3-hexyne and ...

  20. Mechanistic studies on metal-catalyzed carbon-nitrogen bond forming reactions

    E-Print Network [OSTI]

    Strieter, Eric R

    2005-01-01

    Mechanistic studies on copper and palladium-catalyzed C-N bond forming reactions are described. To understand the mechanistic details of these processes, several principles of physical organic chemistry have been employed. ...