National Library of Energy BETA

Sample records for 75-09-2 methylene chloride

  1. Methylene chloride exposure and birthweight in Monroe County, New York

    SciTech Connect (OSTI)

    Bell, B.P.; Franks, P.; Hildreth, N.; Melius, J. )

    1991-06-01

    This study examined the relationship between birthweight and exposure to emissions of methylene chloride (DCM) from manufacturing processes of the Eastman Kodak Company at Kodak Park in Rochester, Monroe County, New York. County census tracts were categorized as exposed to high, moderate, low or no DCM based on the Kodak Air Monitoring Program (KAMP) model, a theoretical dispersion model of DCM developed by Eastman Kodak Company. Birthweight and information on variables known to influence birthweight were obtained from 91,302 birth certificates of white singleton births to Monroe County residents from 1976 to 1987. No significant adverse effects of exposure to DCM on birthweight were found. Adjusted birthweight in high exposure census tracts was 18.7 g less than in areas with no exposure (95% confidence interval for the difference between high and no exposure - 51.6, 14.2 g). Problems inherent in the method of estimation of exposure, which may decrease power or bias the results, are discussed. Better methods to estimate exposure to emissions from multiple industrial point sources are needed.

  2. ANALYSIS OF VAPORS FROM METHYLENE CHLORIDE EXTRACTS OF NUCLEAR GRADE HEPA FILTER FIBERGLASS SAMPLES

    SciTech Connect (OSTI)

    FRYE JM; ANASTOS HL; GUTIERREZ FC

    2012-06-07

    While several organic compounds were detected in the vapor samples used in the reenactment of the preparation of mounts from the extracts of nuclear grade high-efficiency particulate air filter fiberglass samples, the most significant species present in the samples were methylene chloride, phenol, phenol-d6, and 2-fluorophenol. These species were all known to be present in the extracts, but were expected to have evaporated during the preparation of the mounts, as the mounts appeared to be dry before any vapor was collected. These species were present at the following percentages of their respective occupational exposure limits: methylene chloride, 2%; phenol, 0.4%; and phenol-d6, 0.6%. However, there is no established limit for 2-fluorophenol. Several other compounds were detected at low levels for which, as in the case of 2-fluorophenol, there are no established permissible exposure limits. These compounds include 2-chlorophenol; N-nitroso-1-propanamine; 2-fluoro-1,1{prime}-biphenyl; 1,2-dihydroacenaphthylene; 2,5-cyclohexadiene-1,4-dione,2,6-bis(1,1-dimethylethyl); trimethyl oxirane; n-propylpropanamine; 2-(Propylamino)ethanol; 4-methoxy-1-butene; 6-methyl-5-hepten-2-one; and 3,4-dimethylpyridine. Some of these were among those added as surrogates or spike standards as part ofthe Advanced Technologies and Laboratories International, Inc. preparation ofthe extract of the HEPA filter media and are indicated as such in the data tables in Section 2, Results; other compounds found were not previously known to be present. The main inorganic species detected (sulfate, sodium, and sulfur) are also consistent with species added in the preparation of the methylene chloride extract of the high-efficiency particulate air sample.

  3. Substitutes for methylene chloride paint strippers -- performance evaluation and adaptation to aircraft maintenance procedures

    SciTech Connect (OSTI)

    Baker, G.E.; Hollins, E.F.

    1997-12-31

    The US Air Force is conducting a focused review of alternative solvents for use in depainting aircraft. This effort is to provide a replacement for methylene chloride, which is a suspected carcinogen, a listed hazardous air pollutant, presents a serious workplace hazard, and is nearly eliminated from use as a paint stripper by the Aerospace Rule of the National Emissions Standards for Hazardous Air Pollutants. An evaluation of available alternatives was conducted through a background and literature search, laboratory analytical work on a subset of alternative candidates, and actual field testing of alternative solvents on removable components of KC-135 aircraft at Tinker AFB, OK. The literature search and lab analyses resulted in a recommendation for field testing of seven alternative products; one of these emerged as superior in removal power testing and was recommended for full scale prototype testing on a KC-135. The entire effort was conducted to identify and test alternatives for use on polyurethane topcoats with a Koroflex (polyurethane) primer paint system. Additional testing of alternative solvents on panels employing three different primer systems: epoxy, BMS 10-11, and a self-priming topcoat are currently planned for the next steps. This project represents the only Air Force project aimed at finding a chemical replacement for methylene chloride. The experimental design of each phase of the project, the specific analytical and technical criteria used in screening and evaluating each alternative, and the documentation of the results in a series of technical reports have yielded not only several viable alternatives, but, more importantly, a detailed methodology for conducting similar projects.

  4. Exposure to methylene chloride from controlled use of a paint remover in residences

    SciTech Connect (OSTI)

    Hodgson, A.T.; Girman, J.R.

    1987-06-01

    A recent laboratory investigation characterized personal exposures to methylene chloride (CH/sub 2/Cl/sub 2/) for simulated typical uses of paint removers and aerosol finishes containing CH/sub 2/Cl/sub 2/ in a room-size environmental chamber at two ventilation rates. Because paint removers produced relatively large exposures to CH/sub 2/Cl/sub 2/ in these experiments, the present investigation was undertaken to measure exposures to CH/sub 2/Cl/sub 2/ for standardized use of a paint remover in a variety of residential environments. A total of 21 experiments were conducted outdoors and indoors in a garage, a basement workshop, and large and small rooms of a house. In the indoor work areas, ventilation patterns and rates were varied by opening windows and doors and by the use of a household fan. Finishes were removed from uniformly-prepared panels and from chairs. The personal exposure of the worker was determined from the continuous measurement of CH/sub 2/Cl/sub 2/ concentration in a pumped breathing-zone sample. Personal exposures resulting from the outdoor use of paint remover were very low (6 to 36 ppM.h). Exposures resulting from the use of paint remover indoors without mechanical exhaust ventilation were considerably higher (190 to 2090 ppM-h). In each indoor location, an open window or exterior door (11 to 142 ppM.h). A single-equation mass-balance model was used to produce estimates of theoretical exposures for experiments conducted indoors. The efficacy of the model for predicting exposures was evaluated by comparing theoretical and measured personal exposures. The model performed best for small-volume work areas with low ventilation rates. In general, the model had an accuracy of +-50 percent when applied to experiments conducted in enclosed work areas without an exhaust fan.

  5. Source characterization and control technology assessment of methylene chloride emissions from Eastman Kodak Company, Rochester, NY. Final report, July 1988-April 1989

    SciTech Connect (OSTI)

    Walata, S.A.; Rehm, R.M.

    1989-07-01

    This report gives results of an assessment of potential control technologies for methylene chloride (also known as dichloromethane or DCM) emission sources at Eastman Kodak Company's Kodak Park facility in Rochester, NY. DCM is a solvent used by Kodak in the manufacture of cellulose triacetate film support. Work has involved: a plant visit where major DCM emission sources were inspected, and evaluation of current and potential control technologies for the DCM emission sources. The report contains information gathered during the plant visit to the Kodak Park facility. Included are emission estimates determined by Kodak of all emission points greater than 8000 lb (3600 kg)/yr DCM, as well as a description of each point observed during the visit. Also included are results of an evaluation of control technologies that might be applied to the major emission sources. A cost analysis of different add-on control devices is provided for four of the uncontrolled emission points.

  6. Chloride removal from vitrification offgas

    SciTech Connect (OSTI)

    Slaathaug, E.J. [Westinghouse Hanford Co., Richland, WA (United States)

    1995-06-01

    This study identified and investigated techniques of selectively purging chlorides from the low-level waste (LLW) vitrification process with the purge stream acceptable for burial on the Hanford Site. Chlorides will be present in high concentration in several individual feeds to the LLW Vitrification Plant. The chlorides are highly volatile in combustion type melters and are readily absorbed by wet scrubbing of the melter offgas. The Tank Waste Remediation System (TWRS) process flow sheets show that the resulting chloride rich scrub solution is recycled back to the melter. The chlorides must be purged from the recycle loop to prevent the buildup of excessively high chloride concentrations.

  7. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  8. Regeneration of zinc chloride hydrocracking catalyst

    DOE Patents [OSTI]

    Zielke, Clyde W.

    1979-01-01

    Improved rate of recovery of zinc values from the solids which are carried over by the effluent vapors from the oxidative vapor phase regeneration of spent zinc chloride catalyst is achieved by treatment of the solids with both hydrogen chloride and calcium chloride to selectively and rapidly recover the zinc values as zinc chloride.

  9. Method for the abatement of hydrogen chloride

    DOE Patents [OSTI]

    Winston, S.J.; Thomas, T.R.

    1975-11-14

    A method is described for reducing the amount of hydrogen chloride contained in a gas stream by reacting the hydrogen chloride with ammonia in the gas phase so as to produce ammonium chloride. The combined gas stream is passed into a condensation and collection vessel, and a cyclonic flow is created in the combined gas stream as it passes through the vessel. The temperature of the gas stream is reduced in the vessel to below the condensation temperature of ammonium chloride in order to crystallize the ammonium chloride on the walls of the vessel. The cyclonic flow creates a turbulence which breaks off the larger particles of ammonium chloride which are, in turn, driven to the bottom of the vessel where the solid ammonium chloride can be removed from the vessel. The gas stream exiting from the condensation and collection vessel is further cleaned and additional ammonium chloride is removed by passing through additional filters.

  10. Microbial reductive dehalogenation of vinyl chloride

    DOE Patents [OSTI]

    Spormann, Alfred M [Stanford, CA; Muller, Jochen A [Baltimore, MD; Rosner, Bettina M [Berlin, DE; Von Abendroth, Gregory [Mannheim, DE; Meshulam-Simon, Galit [Los Angeles, CA; McCarty, Perry L [Stanford, CA

    2014-02-11

    Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

  11. Microbial reductive dehalogenation of vinyl chloride

    DOE Patents [OSTI]

    Spormann, Alfred M.; Muller, Jochen A.; Rosner, Bettina M.; Von Abendroth, Gregory; Meshulam-Simon, Galit; McCarty, Perry L

    2011-11-22

    Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

  12. Copper (II) chloride-tetrachloroaluminate battery

    SciTech Connect (OSTI)

    Erbacher, J.K.; Hussey, C.L.; King, L.A.

    1980-06-10

    A pelletized, light weight, thermal battery having copper (II) chloride and an alkali tetrachloroaluminate as electrolytic components is disclosed.

  13. REMOVAL OF CHLORIDE FROM AQUEOUS SOLUTIONS

    DOE Patents [OSTI]

    Schulz, W.W.

    1959-08-01

    The removal of chlorides from aqueons solutions is described. The process involves contacting the aqueous chloride containing solution with a benzene solution about 0.005 M in phenyl mercuric acetate whereby the chloride anions are taken up by the organic phase and separating the organic phase from the aqueous solutions.

  14. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  15. Production of chlorine from chloride salts

    DOE Patents [OSTI]

    Rohrmann, Charles A. (Kennewick, WA)

    1981-01-01

    A process for converting chloride salts and sulfuric acid to sulfate salts and elemental chlorine is disclosed. A chloride salt and sulfuric acid are combined in a furnace where they react to produce a sulfate salt and hydrogen chloride. Hydrogen chloride from the furnace contacts a molten salt mixture containing an oxygen compound of vanadium, an alkali metal sulfate and an alkali metal pyrosulfate to recover elemental chlorine. In the absence of an oxygen-bearing gas during the contacting, the vanadium is reduced, but is regenerated to its active higher valence state by separately contacting the molten salt mixture with an oxygen-bearing gas.

  16. The feasibility of using methylene blue sensitized polyvinylalcohol film as a linear polarizer

    SciTech Connect (OSTI)

    Jyothilakshmi, K.; Anju, K. S.; Arathy, K.; John, Beena Mary; Krishna, P. B.; Sruthi, C. T.; Chacko, Maria

    2014-01-28

    Linear light polarizing films selectively transmit radiations vibrating along an electromagnetic radiation vector and selectively absorb radiations vibrating along a second electromagnetic radiation vector. It happens according to the anisotropy of the film . In the present study the polarization effects of methylene blue sensitized polyvinyl alcohol is investigated. The polarization effects on the dye concentration, heating and stretching of film also are evaluated.

  17. Graphene oxide functionalized with methylene blue and its performance in singlet oxygen generation

    SciTech Connect (OSTI)

    Wojtoniszak, M.; Rogi?ska, D.; Machali?ski, B.; Drozdzik, M.; Mijowska, E.

    2013-07-15

    Graphical abstract: - Highlights: Adsorption of methylene blue (MB) on graphene oxide (GO). Characterization of graphene oxidemethylene blue nanocomposite (MBGO). Examination of MBGO efficiency in singlet oxygen generation (SOG). MBGO performs higher SOG efficiency than pristine MB. - Abstract: Due to unique electronic, mechanical, optical and structural properties, graphene has shown promising applications in many fields, including biomedicine. One of them is noninvasive anticancer therapy photodynamic therapy (PDT), where singlet oxygen (SO), generated under the irradiation of light with appropriate wavelengths, kills cancer cells. In this study, authors report graphene oxide (GO) noncovalent functionalization with methylene blue (MB). MB molecules underwent adsorption on the surface of GO. Detailed characterization of the obtained material was carried out with UVvis spectroscopy, Raman spectroscopy, FT-IR spectroscopy, and confocal laser scanning microscopy. Furthermore, its performance in singlet oxygen generation (SOG) under irradiation of laser with excitation wavelengths of 785 nm was investigated. Interestingly, GO functionalized with MB (MBGO) showed enhanced efficiency in singlet oxygen generation compared to pristine MB. The efficiency in SOG was detected by photobleaching of 9,10-anthracenediyl-bis(methylene)dimalonic acid (ABMDMA). These results indicate the material is promising in PDT anticancer therapy and further in vitro and in vivo studies are required.

  18. Process for synthesis of beryllium chloride dietherate

    DOE Patents [OSTI]

    Bergeron, Charles; Bullard, John E.; Morgan, Evan

    1991-01-01

    A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

  19. Hydrocracking with molten zinc chloride catalyst containing 2-12% ferrous chloride

    DOE Patents [OSTI]

    Zielke, Clyde W.; Bagshaw, Gary H.

    1981-01-01

    In a process for hydrocracking heavy aromatic polynuclear carbonaceous feedstocks to produce hydrocarbon fuels boiling below about 475.degree. C. by contacting the feedstocks with hydrogen in the presence of a molten zinc chloride catalyst and thereafter separating at least a major portion of the hydrocarbon fuels from the spent molten zinc chloride catalyst, an improvement comprising: adjusting the FeCl.sub.2 content of the molten zinc chloride to from about 2 to about 12 mol percent based on the mixture of ferrous chloride and molten zinc chloride.

  20. Fight chloride corrosion in aqueous systems

    SciTech Connect (OSTI)

    Kirby, G.N.

    1995-02-01

    In iron-based alloys like carbon steel or stainless steel, the chloride ion increases corrosion by increasing the water's conductivity and by penetrating the alloy's protective oxides. It can increase overall or general corrosion, and can cause localized corrosion such as pitting and stress corrosion cracking. The chloride ion occurs naturally in seawater, in ground waters, in potable water, in condensate after incinerating waste materials such as polyvinyl chloride, and from the hydrolysis or decomposition of chlorinated hydrocarbons such as carbon tetrachloride or trichloroethane. Chlorides can also occur as trace impurities in bulk chemicals where they are neither expected nor analyzed for, but nonetheless can cause serious corrosion. This trace effect is worsened by the tendency of chlorides to concentrate in pits and crevices, especially on heated or intermittently wet and dry surfaces, to amounts that can be orders of magnitude greater than the percentage of chlorides in the bulk liquid. In this article the effects of chloride corrosion, as well as corrosion resistance are discussed.

  1. Modeling acid-gas generation from boiling chloride brines (Journal...

    Office of Scientific and Technical Information (OSTI)

    Modeling acid-gas generation from boiling chloride brines Citation Details In-Document Search Title: Modeling acid-gas generation from boiling chloride brines This study ...

  2. Method of electrode fabrication and an electrode for metal chloride...

    Office of Scientific and Technical Information (OSTI)

    Method of electrode fabrication and an electrode for metal chloride battery Title: Method of electrode fabrication and an electrode for metal chloride battery A method of ...

  3. Electrochemical preparation of poly(methylene blue)/graphene nanocomposite thin films

    SciTech Connect (OSTI)

    Erar?kc?, Elif; Da?c?, Kader; Topu, Ezgi; Alanyal?o?lu, Murat

    2014-07-01

    Highlights: Poly(MB)/graphene thin films are prepared by a simple electrochemical approach. Graphene layers in the film show a broad band in visible region of absorbance spectra. Morphology of composite films indicates both disordered and ordered regions. XRD reveals that nanocomposite films include rGO layers after electropolymerization process. Chemically prepared graphene is better than electrochemically prepared graphene for electrooxidation of nitrite. - Abstract: Poly(methylene blue)/graphene nanocomposite thin films were prepared by electropolymerization of methylene blue in the presence of graphene which have been synthesized by two different methods of a chemical oxidation process and an electrochemical approach. Synthesized nanocomposite thin films were characterized by using cyclic voltammetry, UVvis. absorption spectroscopy, powder X-ray diffraction, and scanning tunneling microscopy techniques. Electrocatalytical properties of prepared poly(methylene blue)/graphene nanocomposite films were compared toward electrochemical oxidation of nitrite. Under optimized conditions, electrocatalytical effect of nanocomposite films of chemically prepared graphene through electrochemical oxidation of nitrite was better than that of electrochemically prepared graphene.

  4. Infrared spectroscopy of the methanol cation and its methylene-oxonium isomer

    SciTech Connect (OSTI)

    Mosley, J. D.; Young, J. W.; Duncan, M. A. E-mail: maduncan@uga.edu; Huang, M.; McCoy, A. B. E-mail: maduncan@uga.edu

    2015-03-21

    The carbenium ion with nominal formula [C,H{sub 4},O]{sup +} is produced from methanol or ethylene glycol in a pulsed-discharge supersonic expansion source. The ion is mass selected, and its infrared spectrum is measured from 2000 to 4000 cm{sup ?1} using laser photodissociation spectroscopy and the method of rare gas atom tagging. Computational chemistry predicts two isomers, the methanol and methylene-oxonium cations. Predicted vibrational spectra based on scaled harmonic and reduced dimensional treatments are compared to the experimental spectra. The methanol cation is the only isomer produced when methanol is used as a precursor. When ethylene glycol is used as the precursor, methylene-oxonium is produced in addition to the methanol cation. Theoretical results at the CCSD(T)/cc-pVTZ level show that methylene-oxonium is lower in energy than methanol cation by 6.4 kcal/mol, and is in fact the global minimum isomer on the [C,H{sub 4},O]{sup +} potential surface. Methanol cation is trapped behind an isomerization barrier in our source, providing a convenient method to produce and characterize this transient species. Analysis of the spectrum of the methanol cation provides evidence for strong CH stretch vibration/torsion coupling in this molecular ion.

  5. Enhanced photocatalytic degradation of methylene blue by metal-modified silicon nanowires

    SciTech Connect (OSTI)

    Brahiti, N.; Hadjersi, T.; Menari, H.; Amirouche, S.; El Kechai, O.

    2015-02-15

    Highlights: • SiNWs modified with Pd, Au and Pt were used as photocatalysts to degrade MB. • Yield of photodegardation increases with UV irradiation time. • SiNWs modified with Pd nanoparticles show the best photocatalytic activity. • A degradation of 97% was obtained after 200 min of UV irradiation. - Abstract: Silicon nanowires (SiNWs) modified with Au, Pt and Pd nanoparticles were used as heterogeneous photocatalysts for the photodegradation of methylene blue in water under UV light irradiation. The modification of SiNWs was carried out by deposition of metal nanoparticles using the electroless metal deposition (EMD) technique. The effect of metal nanoparticles deposition time on the photocatalytic activity was studied. It was found that the photocatalytic activity of modified SiNWs was enhanced when the deposition time of metal nanoparticles was increased. In addition of modified SiNWs with Pt, Au and Pd nanoparticles, oxidized silicon substrate (Ox-Si), oxidized silicon nanowires (Ox-SiNWs) and hydrogen-terminated silicon nanowires (H-SiNWs) were also evaluated for the photodegradation of methylene blue.

  6. Absorption media for irreversibly gettering thionyl chloride

    DOE Patents [OSTI]

    Buffleben, George; Goods, Steven H.; Shepodd, Timothy; Wheeler, David R.; Whinnery, Jr., LeRoy

    2002-01-01

    Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

  7. Thermoelectrochemical hydrogen production using sodium chloride

    SciTech Connect (OSTI)

    El-Bassuoni, A.M.A.; Sheffield, J.W.; Veziroglu, T.N.

    1981-01-01

    Three closed-cycle processes for the thermoelectrochemical production of hydrogen from water using sodium chloride are under investigation. The maximum required temperature of 700/degree/C can be achieved by solar energy using various concentration techniques. By means of photovoltaic cells or a solar power station, the required electric power can be obtained. 11 refs.

  8. An Exocyclic Methylene Group Acts As a Bioisostere of the 2′-Oxygen Atom in LNA

    SciTech Connect (OSTI)

    Seth, Punit P.; Allerson, Charles R.; Berdeja, Andres; Siwkowski, Andrew; Pallan, Pradeep S.; Gaus, Hans; Prakash, Thazha P.; Watt, Andrew T.; Egli, Martin; Swayze, Eric E.

    2010-12-07

    We show for the first time that it is possible to obtain LNA-like (Locked Nucleic Acid 1) binding affinity and biological activity with carbocyclic LNA (cLNA) analogs by replacing the 2{prime}-oxygen atom in LNA with an exocyclic methylene group. Synthesis of the methylene-cLNA nucleoside was accomplished by an intramolecular cyclization reaction between a radical at the 2{prime}-position and a propynyl group at the C-4{prime} position. Only methylene-cLNA modified oligonucleotides showed similar thermal stability and mismatch discrimination properties for complementary nucleic acids as LNA. In contrast, the close structurally related methyl-cLNA analogs showed diminished hybridization properties. Analysis of crystal structures of cLNA modified self-complementary DNA decamer duplexes revealed that the methylene group participates in a tight interaction with a 2{prime}-deoxyribose residue of the 5{prime}-terminal G of a neighboring duplex, resulting in the formation of a CH...O type hydrogen bond. This indicates that the methylene group retains a negative polarization at the edge of the minor groove in the absence of a hydrophilic 2{prime}-substituent and provides a rationale for the superior thermal stability of this modification. In animal experiments, methylene-cLNA antisense oligonucleotides (ASOs) showed similar in vivo activity but reduced toxicity as compared to LNA ASOs. Our work highlights the interchangeable role of oxygen and unsaturated moieties in nucleic acid structure and emphasizes greater use of this bioisostere to improve the properties of nucleic acids for therapeutic and diagnostic applications.

  9. Measurement of diffusion potentials at porous diaphragms separating chloride and chloride-fluoride melts

    SciTech Connect (OSTI)

    Mitysev, V.S.; Komarov, V.E.

    1985-09-01

    An attempt was made in this work to measure the potential drops across diaphragms separating chloride and chloride-fluoride melts. These values can then be taken into account when analyzing the results of emf measurements made with the galvanic cell expressed here, and will help to make them more reliable, according to the authors. To check whether the activities of the alkali metal in alloys of the two half cells remained equal throughout the entire experiment, an experimental cell was used where alloy M-Bi was placed into a crucible of metallic molybdenum (d = 10 mm, h = 10 mm), which was immersed in turns into the chloride melt and into the chloride-fluoride melt while keeping the setup closed. The emf values increase with increasing temperature and alkali-metal fluoride concentration. They decrease with increasing cation radius in the salt medium.

  10. Lithium: Thionyl chloride battery state-of-the-art assessment...

    Office of Scientific and Technical Information (OSTI)

    Lithium: Thionyl chloride battery state-of-the-art assessment Citation Details In-Document Search Title: Lithium: Thionyl chloride battery state-of-the-art assessment You are ...

  11. Density of sodium chloride solutions at high temperatures and...

    Office of Scientific and Technical Information (OSTI)

    Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; SEAWATER; DENSITY; SODIUM CHLORIDES; AQUEOUS SOLUTIONS; CHEMICAL COMPOSITION; CORRELATIONS; EQUATIONS; HIGH ...

  12. Precipitation of metal nitrides from chloride melts

    SciTech Connect (OSTI)

    Slater, S.A.; Miller, W.E.; Willit, J.L.

    1996-12-31

    Precipitation of actinides, lanthanides, and fission products as nitrides from molten chloride melts is being investigated for use as a final cleanup step in treating radioactive salt wastes generated by electrometallurgical processing of spent nuclear fuel. The radioactive components (eg, fission products) need to be removed to reduce the volume of high-level waste that requires disposal. To extract the fission products from the salt, a nitride precipitation process is being developed. The salt waste is first contacted with a molten metal; after equilibrium is reached, a nitride is added to the metal phase. The insoluble nitrides can be recovered and converted to a borosilicate glass after air oxidation. For a bench-scale experimental setup, a crucible was designed to contact the salt and metal phases. Solubility tests were performed with candidate nitrides and metal nitrides for which there are no solubility data. Experiments were performed to assess feasibility of precipitation of metal nitrides from chloride melts.

  13. Method for the regeneration of spent molten zinc chloride

    DOE Patents [OSTI]

    Zielke, Clyde W.; Rosenhoover, William A.

    1981-01-01

    In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

  14. The interactions of azure B, a metabolite of methylene blue, with acetylcholinesterase and butyrylcholinesterase

    SciTech Connect (OSTI)

    Petzer, Anél; Harvey, Brian H.; Petzer, Jacobus P.

    2014-02-01

    Methylene blue (MB) is reported to possess diverse pharmacological actions and is attracting increasing attention for the treatment of neurodegenerative disorders such as Alzheimer's disease. Among the pharmacological actions of MB, is the significant inhibition of acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE). These activities may, at least in part, underlie MB's beneficial effects in Alzheimer's disease. MB is metabolized to yield N-demethylated products of which azure B, the monodemethyl metabolite, is the predominant species. Azure B has been shown to be pharmacologically active and also possesses a variety of biological actions. Azure B therefore may contribute to the pharmacological profile of MB. Based on these considerations, the present study investigates the possibility that azure B may, similar to MB, act as an inhibitor of human AChE and BuChE. The results document that azure B inhibits AChE and BuChE with IC{sub 50} values of 0.486 μM and 1.99 μM, respectively. The results further show that azure B inhibits AChE and BuChE reversibly, and that the modes of inhibition are most likely competitive. Although the AChE and BuChE inhibitory activities of azure B are twofold and fivefold, respectively, less potent than those recorded for MB [IC{sub 50}(AChE) = 0.214 μM; IC{sub 50}(BuChE) = 0.389 μM] under identical conditions, azure B may be a contributor to MB's in vivo activation of the cholinergic system and beneficial effects in Alzheimer's disease. - Highlights: • Methylene blue (MB) is a known inhibitor of AChE and BuChE. • Azure B, the major metabolite of MB, also is an inhibitor of AChE and BuChE. • Azure B may be a contributor to MB's in vivo activation of the cholinergic system. • Azure B may contribute to MB's potential in Alzheimer's disease therapy.

  15. Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani

    2010-08-03

    Regenerable hydrogen chloride removal sorbent and regenerable multi-functional hydrogen sulfide and hydrogen chloride removal sorbent for high temperature gas streams

  16. Cesium chloride compatibility testing program: Final report

    SciTech Connect (OSTI)

    Bryan, G.H.

    1989-11-01

    The US Department of Energy is considering the geologic disposal of the doubly encapsulated cesium chloride (CsCl) produced at the Waste Encapsulation and Storage Facility (WESF). Reliable estimates of long-term corrosion of the inner capsule material by the CsCl under repository storage conditions are needed to assess the hazards associated with geologic disposal of the fission product Cs. The Cesium Chloride Compatibility Program was carried out at PNL to obtain the short-term corrosion data required to accurately estimate long-term attack. In the compatibility tests six standard WESF CsCl capsules were placed vertically in individual insulated containers and allowed to self-heat to a nominal maximum 316L SS/CsCl interface temperature of 450{degree}C. The capsules were held at temperature for times ranging from 0.25 to 6 years. When a test was completed, the capsule was removed from the container and sectioned. Four samples were cut from the inner capsule at prescribed locations and subjected to metallographic examination. Corrosion was determined from photomicrographs of the samples. 16 refs., 41 figs., 16 tabs.

  17. Localized Plasticity in the Streamlined Genomes of Vinyl Chloride...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides Citation ... Here we report the first, to our knowledge, complete genome ...

  18. VOLATILE CHLORIDE PROCESS FOR THE RECOVERY OF METAL VALUES

    DOE Patents [OSTI]

    Hanley, W.R.

    1959-01-01

    A process is presented for recovering uranium, iron, and aluminum from centain shale type ores which contain uranium in minute quantities. The ore is heated wiih a chlorinating agent. such as chlorine, to form a volatilized stream of metal chlorides. The chloride stream is then passed through granular alumina which preferentially absorbs the volatile uranium chloride and from which the uranium may later be recovered. The remaining volatilized chlorides, chiefly those of iron and aluminum, are further treated to recover chlorine gas for recycle, and to recover ferric oxide and aluminum oxide as valuable by-products.

  19. Interactions of Lysozyme in Guanidinium Chloride Solutions FromStatic...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHLORIDES; LIGHT SCATTERING; LYSOZYME Word Cloud More ...

  20. Viscosity and density tables of sodium chloride solutions (Technical...

    Office of Scientific and Technical Information (OSTI)

    A file is presented containing tabulated data extracted from the scientific literature on the density and viscosity of aqueous sodium chloride solutions. Also included is a ...

  1. Nanoscale Periodic Modulations on Sodium Chloride Induced by...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Nanoscale Periodic Modulations on Sodium Chloride Induced by Surface Charges Citation Details In-Document Search Title: Nanoscale Periodic Modulations on Sodium ...

  2. Tubular structured hierarchical mesoporous titania material derived from natural cellulosic substances and application as photocatalyst for degradation of methylene blue

    SciTech Connect (OSTI)

    Huang, Haiqing; Liu, Xiaoyan; Huang, Jianguo

    2011-11-15

    Graphical abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material with high photocatalytic activity under UV light was fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template using a one-pot sol-gel method. Highlights: {yields} Tubular structured mesoporous titania material was fabricated by sol-gel method. {yields} The titania material faithfully recorded the hierarchical structure of the template substrate (cotton). {yields} The titania material exhibited high photocatalytic activity in decomposition of methylene blue. -- Abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material was designed and fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template by one-pot sol-gel method. The tubular structured hierarchical mesoporous titania material processes large specific surface area (40.23 m{sup 2}/g) and shows high photocatalytic activity in the photodegradation of methylene blue under UV light irradiation.

  3. Method for synthesizing pollucite from chabazite and cesium chloride

    DOE Patents [OSTI]

    Pereira, Candido

    1999-01-01

    A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

  4. Method for synthesizing pollucite from chabazite and cesium chloride

    DOE Patents [OSTI]

    Pereira, C.

    1999-02-23

    A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

  5. Apparatus and method for making metal chloride salt product

    DOE Patents [OSTI]

    Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

    2007-05-15

    A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

  6. Method for the production of uranium chloride salt

    DOE Patents [OSTI]

    Westphal, Brian R.; Mariani, Robert D.

    2013-07-02

    A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

  7. Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California

    SciTech Connect (OSTI)

    Haizlip, J.R.; Truesdell, A.H.

    1988-01-01

    Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350 C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350 C). Within this pH range, liquid at 250 C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350 C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

  8. Methylene megration and coupling on a non-reducible metal oxide: the reaction of dichloromethane on stoichiometric -Cr2O3(0001)

    SciTech Connect (OSTI)

    Dong, Yujung; Brooks, John; Chen, Tsung-Liang; Mullins, David R; Cox, David F.

    2015-01-01

    The reaction of CH2Cl2 over the nearly-stoichiometric -Cr2O3(0001) surface produces gas phase ethylene, methane and surface chlorine adatoms. The reaction is initiated by the decomposition of CH2Cl2 into surface methylene and chlorine. Photoemission indicates that surface cations are the preferred binding sites for both methylene and chlorine adatoms. Two reaction channels are observed for methylene coupling to ethylene in temperature-programmed desorption (TPD). A desorption-limited, low-temperature route is attributed to two methylenes bound at a single site. The majority of ethylene is produced by a reaction-limited process involving surface migration (diffusion) of methylene as the rate-limiting step. DFT calculations indicate the surface diffusion mechanism is mediated by surface oxygen anions. The source of hydrogen for methane formation is adsorbed background water. Chlorine adatoms produced by the dissociation of CH2Cl2 deactivate the surface by simple site-blocking of surface Cr3+ sites. A comparison of experiment and theory shows that DFT provides a better description of the surface chemistry of the carbene intermediate than DFT+U using reported parameters for a best representation of the bulk electronic properties of -Cr2O3.

  9. Methylene megration and coupling on a non-reducible metal oxide: the reaction of dichloromethane on stoichiometric -Cr2O3(0001)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dong, Yujung; Brooks, John; Chen, Tsung-Liang; Mullins, David R; Cox, David F.

    2015-01-01

    The reaction of CH2Cl2 over the nearly-stoichiometric -Cr2O3(0001) surface produces gas phase ethylene, methane and surface chlorine adatoms. The reaction is initiated by the decomposition of CH2Cl2 into surface methylene and chlorine. Photoemission indicates that surface cations are the preferred binding sites for both methylene and chlorine adatoms. Two reaction channels are observed for methylene coupling to ethylene in temperature-programmed desorption (TPD). A desorption-limited, low-temperature route is attributed to two methylenes bound at a single site. The majority of ethylene is produced by a reaction-limited process involving surface migration (diffusion) of methylene as the rate-limiting step. DFT calculations indicate themore » surface diffusion mechanism is mediated by surface oxygen anions. The source of hydrogen for methane formation is adsorbed background water. Chlorine adatoms produced by the dissociation of CH2Cl2 deactivate the surface by simple site-blocking of surface Cr3+ sites. A comparison of experiment and theory shows that DFT provides a better description of the surface chemistry of the carbene intermediate than DFT+U using reported parameters for a best representation of the bulk electronic properties of -Cr2O3.« less

  10. Methylene migration and coupling on a non-reducible metal oxide: The reaction of dichloromethane on stoichiometric α-Cr2O3(0001)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dong, Yujung; Brooks, John D.; Chen, Tsung-Liang; Mullins, David R.; Cox, David F.

    2014-09-17

    The reaction of CH2Cl2 over the nearly-stoichiometric α-Cr2O3(0001) surface produces gas phase ethylene, methane and surface chlorine adatoms. The reaction is initiated by the decomposition of CH2Cl2 into surface methylene and chlorine. Photoemission indicates that surface cations are the preferred binding sites for both methylene and chlorine adatoms. Two reaction channels are observed for methylene coupling to ethylene in temperature-programmed desorption (TPD). A desorption-limited, low-temperature route is attributed to two methylenes bound at a single site. The majority of ethylene is produced by a reaction-limited process involving surface migration (diffusion) of methylene as the rate-limiting step. DFT calculations indicate themore » surface diffusion mechanism is mediated by surface oxygen anions. The source of hydrogen for methane formation is adsorbed background water. Chlorine adatoms produced by the dissociation of CH2Cl2 deactivate the surface by simple site-blocking of surface Cr3+ sites. Finally, a comparison of experiment and theory shows that DFT provides a better description of the surface chemistry of the carbene intermediate than DFT+U using reported parameters for a best representation of the bulk electronic properties of α-Cr2O3.« less

  11. Automatic electrochemical ambient air monitor for chloride and chlorine

    DOE Patents [OSTI]

    Mueller, Theodore R.

    1976-07-13

    An electrochemical monitoring system has been provided for determining chloride and chlorine in air at levels of from about 10-1000 parts per billion. The chloride is determined by oxidation to chlorine followed by reduction to chloride in a closed system. Chlorine is determined by direct reduction at a platinum electrode in 6 M H.sub.2 SO.sub.4 electrolyte. A fully automated system is utilized to (1) acquire and store a value corresponding to electrolyte-containing impurities, (2) subtract this value from that obtained in the presence of air, (3) generate coulometrically a standard sample of chlorine mixed with air sample, and determine it as chlorine and/or chloride, and (4) calculate, display, and store for permanent record the ratio of the signal obtained from the air sample and that obtained with the standard.

  12. SOLVENT EXTRACTION PROCESS FOR URANIUM FROM CHLORIDE SOLUTIONS

    DOE Patents [OSTI]

    Blake, C.A. Jr.; Brown, K.B.; Horner, D.E.

    1960-05-24

    An improvement was made in a uranium extraction process wherein the organic extractant is a phosphine oxide. An aqueous solution containing phosphate ions or sulfate ions together with uranium is provided with a source of chloride ions during the extraction step. The presence of the chloride ions enables a phosphine oxide to extract uranium in the presence of strong uranium- complexing ions such as phosphate or sulfate ions.

  13. Chloride chemical form in various types of fly ash

    SciTech Connect (OSTI)

    Fenfen Zhu; Masaki Takaoka; Kenji Shiota; Kazuyuki Oshita; Yoshinori Kitajima

    2008-06-01

    Chloride content is a critical problem for the reuse of fly ash as a raw material in cement, and the method used by recyclers to reduce the fly ash chloride content depends on the chemical form of the chlorides. However, limited information is available on the quantitative distribution of chlorides and the identity of some chlorides such as Friedel's salt. We examined chloride forms and percentages using X-ray absorption near edge structure and X-ray diffraction analyses, as well as corresponding washing experiments. Approximately 15% of the chlorine in raw fly ash was estimated to be in the form of NaCl, 10% in KCl, 50% in CaCl{sub 2}, and the remainder in the form of Friedel's salt. Fly ash collected in a bag filter with the injection of calcium hydroxide for acid gas removal (CaFA) contained 35% chlorine as NaCl, 11% as KCl, 37% as CaCl{sub 2}, 13% as Friedel's salt, and the remaining 4% as CaClOH. In fly ash collected in a bag filter with the injection of sodium bicarbonate for acid gas removal (NaFA), approximately 79% of chlorine was in NaCl, 12% was in KCl, and 9% was in Friedel's salt. 25 refs., 4 figs., 4 tabs.

  14. Azure B, a metabolite of methylene blue, is a high-potency, reversible inhibitor of monoamine oxidase

    SciTech Connect (OSTI)

    Petzer, Anél; Harvey, Brian H.; Wegener, Gregers; Petzer, Jacobus P.

    2012-02-01

    Methylene blue (MB) has been shown to act at multiple cellular and molecular targets and as a result possesses diverse medical applications. Among these is a high potency reversible inhibition of monoamine oxidase A (MAO-A) that may, at least in part, underlie its adverse effects but also its psycho- and neuromodulatory actions. MB is metabolized to yield N-demethylated products of which azure B, the monodemethyl species, is the major metabolite. Similar to MB, azure B also displays a variety of biological activities and may therefore contribute to the pharmacological profile of MB. Based on these observations, the present study examines the interactions of azure B with recombinant human MAO-A and -B. The results show that azure B is a potent MAO-A inhibitor (IC{sub 50} = 11 nM), approximately 6-fold more potent than is MB (IC{sub 50} = 70 nM) under identical conditions. Measurements of the time-dependency of inhibition suggest that the interaction of azure B with MAO-A is reversible. Azure B also reversibly inhibits the MAO-B isozyme with an IC{sub 50} value of 968 nM. These results suggest that azure B may be a hitherto under recognized contributor to the pharmacology and toxicology of MB by blocking central and peripheral MAO-A activity and as such needs to be considered during its use in humans and animals. Highlights: ► Methylene blue (MB) is a known potent MAO-A inhibitor. ► Azure B, the major metabolite of MB, is more potent as a MAO-A inhibitor. ► Azure B may be a contributor to the CNS pharmacology and toxicology of MB.

  15. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F.; Krumpelt, Michael; Horwitz, E. Philip

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  16. Uniform Cu{sub 2}Cl(OH){sub 3} hierarchical microspheres: A novel adsorbent for methylene blue adsorptive removal from aqueous solution

    SciTech Connect (OSTI)

    Wei, Wei; Gao, Pin; Xie, Jimin Zong, Sekai; Cui, Henglv; Yue, Xuejie

    2013-08-15

    Using the solution phase method without any surfactants or templates, the hierarchical of Cu{sub 2}Cl(OH){sub 3} microspheres were synthesized by freeze drying. The size and surface area of the microspheres are ca. 12 m and 76.61 m{sup 2} g{sup ?1}, respectively. A possible formation mechanism is presented based on the experimental results. Methylene blue was chosen to investigate the adsorption capacity of the as-prepared adsorbent. The effects of various experimental parameters, such as pH, initial dye concentration, and contact time were investigated. The results showed that the dye removal increased with the increasing in the initial concentration of the dye and also increased in the amount of microspheres used and initial pH. Adsorption data fitted well with the Freundlich adsorption isotherm. The thermodynamic analysis presented the exothermic, spontaneous and more ordered arrangement process. The microspheres could be employed effective for removal of dyes from aqueous solution. - Graphical abstract: The single-crystalline hierarchical Cu{sub 2}Cl(OH){sub 3} spheres can be prepared for the first time by using a template-free process through freeze-drying. Meanwhile, the hierarchical spheres exhibited high adsorption capacity to methylene blue. Display Omitted - Highlights: Cu{sub 2}Cl(OH){sub 3} microspheres were successfully synthesized through a freeze drying process. A possible formation mechanism of hierarchical microspheres was presented. The Cu{sub 2}Cl(OH){sub 3} microspheres have high methylene blue adsorption capacity. Methylene blue adsorption is a spontaneous and exothermic process. The adsorption mechanism of microspheres onto dye was proposed in detail.

  17. Synthesis of pore-variable mesoporous CdS and evaluation of its photocatalytic activity in degrading methylene blue

    SciTech Connect (OSTI)

    Zhang, Wei-Min; Jiang, Yao-Quan; Cao, Xiao-Yan; Chen, Meng; Ge, Dong-Lai; Sun, Zhong-Xi

    2013-10-15

    Graphical abstract: - Highlights: Self-templated synthesis of tubular CdS. Cadmium complexes of aliphatic acids sustain the network of mesoporous structures. Aliphatic acids affect the phase composition and particle size. Pore size and volume vary with aliphatic acids having different hydrocarbonyl. - Abstract: In this study, mesoporous CdS polycrystallites have been synthesized using aliphatic acids of hexanoic acid, octanoic acid, and oleic acid as coordinating and capping agents, respectively. The fibrous Cdfatty acid salts act as a template to form the tubular CdS. The organic species are found to be necessary for maintaining the network of mesoporous CdS. The characterization results indicate that the shorter carbon chain length in aliphatic acids favors the wurtzite phase and particle size growth the specific surface area, pore diameter and pore volume show a monotonic raise with increasing carbon chain. The photocatalytic activities of mesoporous CdS tubes exhibit much higher efficiency than those of nanosized CdS powders in decolorizing methylene blue under simulated visible light.

  18. CPP-603 Chloride Removal System Decontamination and Decommissioning. Final report

    SciTech Connect (OSTI)

    Moser, C.L.

    1993-02-01

    The CPP-603 (annex) Chloride Removal System (CRS) Decontamination and Decommissioning (D&D) Project is described in this report. The CRS was used for removing Chloride ions and other contaminants that were suspended in the waters of the underwater fuel storage basins in the CPP-603 Fuel Receiving and Storage Facility (FRSF) from 1975 to 1981. The Environmental Checklist and related documents, facility characterization, decision analysis`, and D&D plans` were prepared in 1991. Physical D&D activities were begun in mid summer of 1992 and were completed by the end of November 1992. All process equipment and electrical equipment were removed from the annex following accepted asbestos and radiological contamination removal practices. The D&D activities were performed in a manner such that no radiological health or safety hazard to the public or to personnel at the Idaho National Engineering Laboratory (INEL) occurred.

  19. Solgel synthesis of SnO{sub 2}MgO nanoparticles and their photocatalytic activity towards methylene blue degradation

    SciTech Connect (OSTI)

    Bayal, Nisha; Jeevanandam, P.

    2013-10-15

    Graphical abstract: - Highlights: A simple solgel method for the synthesis of SnO{sub 2}MgO nanoparticles is reported. Band gap of SnO{sub 2} can be tuned by varying the magnesium content in SnO{sub 2}MgO. SnO{sub 2}MgO shows good photocatalytic activity towards degradation of methylene blue. - Abstract: SnO{sub 2}MgO mixed metal oxide nanoparticles were prepared by a simple solgel method. The nanoparticles were characterized by power X-ray diffraction, scanning electron microscopy coupled with energy dispersive X-ray analysis, transmission electron microscopy and UVvis diffuse reflectance spectroscopy. The XRD results indicate the formation of mixed metal oxide nanoparticles and also a decrease of SnO{sub 2} crystallite size in the mixed metal oxide nanoparticles with increasing magnesium oxide content. The reflectance spectroscopy results show a blue shift of the band gap of SnO{sub 2} in the mixed metal oxide nanoparticles. The photocatalytic activity of the SnO{sub 2}MgO nanoparticles was tested using the photodegradation of aqueous methylene blue in the presence of sunlight. The results indicate that the mixed metal oxide nanoparticles possess higher efficiency for the photodegradation of methylene blue compared to pure SnO{sub 2} nanoparticles.

  20. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, William E.; Ackerman, John P.; Battles, James E.; Johnson, Terry R.; Pierce, R. Dean

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800.degree. C. to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

  1. Uranium chloride extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

    1992-08-25

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

  2. MO-G-18C-07: Improving T2 Determination and Quantification of Lipid Methylene Protons in Proton Magnetic Resonance Spectroscopy at 3 T

    SciTech Connect (OSTI)

    Breitkreutz, D.; Fallone, B. G.; Yahya, A.

    2014-06-15

    Purpose: To improve proton magnetic resonance spectroscopy (MRS) transverse relaxation (T{sub 2}) determination and quantification of lipid methylene chain (1.3 ppm) protons by rewinding their J-coupling evolution. Methods: MRS experiments were performed on four lipid phantoms, namely, almond, corn, sunflower and oleic acid, using a 3 T Philips MRI scanner with a transmit/receive birdcage head coil. Two PRESS (Point RESolved Spectroscopy) pulse sequences were used. The first PRESS sequence employed standard bandwidth (BW) (?550 Hz) RF (radiofrequency) refocussing pulses, while the second used refocussing pulses of narrow BW (?50 Hz) designed to rewind J-coupling evolution of the methylene protons in the voxel of interest. Signal was acquired with each sequence from a 555 mm{sup 3} voxel, with a repetition time (TR) of 3000 ms, and with echo times (TE) of 100 to 200 ms in steps of 20 ms. 2048 sample points were measured with a 2000 Hz sampling bandwidth. Additionally, 30 mm outer volume suppression slabs were used to suppress signal outside the voxel of interest. The frequency of the RF pulses was set to that of the methylene resonance. Methylene peak areas were calculated and fitted in MATLAB to a monexponentially decaying function of the form M{sub 0}exp(-TE/T{sub 2}), where M{sub 0} is the extrapolated area when TE = 0 ms and yields a measure of concentration. Results: The determined values of M{sub 0} and T{sub 2} increased for all fatty acids when using the PRESS sequence with narrow BW refocussing pulses. M{sub 0} and T{sub 2} values increased by an average amount (over all the phantoms) of 31% and 14%, respectively. Conclusion: This investigation has demonstrated that J-coupling interactions of lipid methylene protons causes non-negligible signal losses which, if not accounted for, Result in underestimations of their levels and T{sub 2} values when performing MRS measurements. Funded by the Natural Sciences and Engineering Research Council of Canada and the

  3. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  4. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, Michele A.; Pereira, Candido

    1997-01-01

    A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  5. Method of preparing sodalite from chloride salt occluded zeolite

    DOE Patents [OSTI]

    Lewis, M.A.; Pereira, C.

    1997-03-18

    A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

  6. Chloride stress corrosion cracking of austenitic stainless steels in hydroprocessing units

    SciTech Connect (OSTI)

    Bagdasarian, A.J.; Truax, D.J.

    1997-09-01

    Ammonium bisulfide has been the well known main culprit of aqueous corrosion in hydroprocessing units. A lesser understood and, at times, more menacing aqueous corrosion problem in these units has been due to chloride salts. Chlorides can be introduced into the system through the feed and/or through the make-up hydrogen gas. This paper describes case histories of chloride related problems and the means for minimizing such occurrences.

  7. Optimizing Reinjection Strategy at Palinpinon, Philippines Based on Chloride Data

    SciTech Connect (OSTI)

    Urbino, Ma. Elena G.; Horne, Roland N.

    1992-03-24

    One of the guidelines established for the safe and efficient management of the Palinpinon Geothermal Field is to adopt a production and well utilization strategy such that the rapid rate and magnitude of reinjection fluid returns leading to premature thermal breakthrough would be minimized. To help achieve this goal, sodium fluorescein and radioactive tracer tests have been conducted to determine the rate and extent of communication between the reinjection and producing sectors of the field. The first objective of this paper is to show how the results of these tests, together with information on field geometry and operating conditions were used in algorithms developed in Operations Research to allocate production and reinjection rates among the different Palinpinon wells. Due to operational and economic constraints, such tracer tests were very limited in number and scope. This prevents obtaining information on the explicit interaction between each reinjection well and the producing wells. Hence, the chloride value of the producing well, was tested to determine if use of this parameter would enable identifying fast reinjection paths among different production/reinjection well pairs. The second aim, therefore, of this paper is to show the different methods of using the chloride data of the producing wells and the injection flow rates of the reinjection wells to provide a ranking of the pair of wells and, thereby, optimize the reinjection strategy of the field.

  8. Hydrodynamic simulation of a lithium chloride salt system.

    SciTech Connect (OSTI)

    Eberle, C. S.; Herrmann, S. D.; Knighton, G. C.

    1999-02-12

    A fused lithium chloride salt system's constitutive properties were evaluated and compared to a number of fluid properties, and water was shown to be an excellent simulant of lithium chloride salt. With a simple flow model, the principal scaling term was shown to be a function of the kinematic viscosity. A water mock-up of the molten salt was also shown to be within a {+-}3% error in the scaling analysis. This made it possible to consider developing water scaled tests of the molten salt system. Accurate flow velocity and pressure measurements were acquired by developing a directional velocity probe. The device was constructed and calibrated with a repeatable accuracy of {+-}15%. This was verified by a detailed evaluation of the probe. Extensive flow measurements of the engineering scale mockup were conducted, and the results were carefully compared to radial flow patterns of a straight blade stirrer. The flow measurements demonstrated an anti-symmetric nature of the stirring, and many additional effects were also identified. The basket design was shown to prevent fluid penetration into the fuel baskets when external stirring was the flow mechanism.

  9. Potassium chloride-bearing ice VII and ice planet dynamics (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: Potassium chloride-bearing ice VII and ice planet dynamics Authors: Frank, Mark R. ; Scott, Henry P. ; Aarestad, Elizabeth ; Prakapenka, Vitali B. 1 ; UC) 2 ; NIU) 2 + ...

  10. Vitrification of Polyvinyl Chloride Waste from Korean Nuclear Power Plants

    SciTech Connect (OSTI)

    Sheng, Jiawei [Kyoto University (Japan); Choi, Kwansik [Nuclear Environment Technology Institute (Korea, Republic of); Yang, Kyung-Hwa [Nuclear Environment Technology Institute (Korea, Republic of); Lee, Myung-Chan [Nuclear Environment Technology Institute (Korea, Republic of); Song, Myung-Jae [Nuclear Environment Technology Institute (Korea, Republic of)

    2000-02-15

    Vitrification is considered as an economical and safe treatment technology for low-level radioactive waste (LLW) generated from nuclear power plants (NPPs). Korea is in the process of preparing for its first ever vitrification plant to handle LLW from its NPPs. Polyvinyl chloride (PVC) has the largest volume of dry active wastes and is the main waste stream to treat. Glass formulation development for PVC waste is the focus of study. The minimum additive waste stabilization approach has been utilized in vitrification. It was found that glasses can incorporate a high content of PVC ash (up to 50 wt%), which results in a large volume reduction. A glass frit, KEP-A, was developed to vitrify PVC waste after the optimization of waste loading, melt viscosity, melting temperature, and chemical durability. The KEP-A could satisfactorily vitrify PVC with a waste loading of 30 to 50 wt%. The PVC-frit was tolerant of variations in waste composition.

  11. Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method

    SciTech Connect (OSTI)

    Cooper, Clay A; Hershey, Ronald L; Healey, John M; Lyles, Brad F

    2013-07-01

    Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

  12. Chloride, bromide and iodide scintillators with europium doping

    DOE Patents [OSTI]

    Zhuravleva, Mariya; Yang, Kan

    2014-08-26

    A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

  13. Cesium chloride compatibility testing program. Annual report, fiscal year 1985

    SciTech Connect (OSTI)

    Bryan, G.H.

    1986-03-01

    At Hanford, fission product cesium, containing 20 to 40% /sup 137/Cs, has been recovered from the high-level waste (HLW) and converted to cesium chloride (CsCl). Recovery of the Cs, as a nitrate, from the HLW and its subsequent purification, takes place in B-Plant. Conversion of the purified product to CsCl, encapsulation of the CsCl, and water storage of the CsCl capsules takes place in the Waste Encapsulation and Storage Facility (WESF). The CsCl is doubly encapsulated in high-integrity 316L stainless steel (SS) capsules. The CsCl is loaded into the inner 316L SS capsules by melt casting. Each inner capsule, which has an ID of 2 in. (50.8 mm) and an inner length of approx.19 in. (483 mm), contains up to 3 kg of CsCl. The capsules contain up to approx.70,000 Ci of /sup 137/Cs, depending on the fission product Cs and the purity of the CsCl. To evaluate the potential hazards associated with the geologic disposal of the WESF CsCl capsules, reliable estimates of long-term attack of the capsule material by the CsCl at disposal temperatures are required. Available data on the compatibility of WESF-produced CsCl with 316L SS are not adequate for making the required evaluations. This report summarizes the program activities for FY 1985. 3 refs., 7 figs., 2 tabs.

  14. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-01-01

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  15. Revealing a New Conformational State in a Chloride/Proton Exchanger |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stanford Synchrotron Radiation Lightsource Revealing a New Conformational State in a Chloride/Proton Exchanger Friday, January 29, 2016 "CLC" transporters are secondary active-transport membrane proteins that catalyze the transmembrane exchange of chloride (Cl-) for protons (H+). This exchange plays an essential role in proper cardiovascular, neuronal, muscular and epithelial functions. Several diseases arise from CLC defects, and several CLCs are therapeutic targets. For example,

  16. MgCl2: The Key Ingredient to Improve Chloride Containing Electrolytes for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rechargeable Magnesium-Ion Batteries - Joint Center for Energy Storage Research June 4, 2016, Research Highlights MgCl2: The Key Ingredient to Improve Chloride Containing Electrolytes for Rechargeable Magnesium-Ion Batteries The addition of MgCl2 into Grignard reagents, APC, and alkoxide Mg electrolytes improves all the aspects of their electrochemical properties. Scientific Achievement The effect of MgCl2 on a series of chloride containing magnesium electrolytes has been experimentally

  17. Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes

    DOE Patents [OSTI]

    Lewis, Michele A.; Johnson, Terry R.

    1993-09-07

    The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

  18. Respiratory symptoms among glass bottle makers exposed to stannic chloride solution and other potentially hazardous substances

    SciTech Connect (OSTI)

    Levy, B.S.; Davis, F.; Johnson, B.

    1985-04-01

    Concern about upper respiratory tract irritation and other symptoms among workers at a glass bottle manufacturing plant led to an epidemiologic and an industrial hygiene survey. Questionnaire responses from 35 hot end and 53 cold end workers indicated that the incidence of wheezing, chest pain, dyspnea on exertion, and cough was significantly elevated among hot end workers. Among both smokers and nonsmokers, hot end workers reported higher, but not significantly higher, rates of wheezing and chest pain. Among smokers, hot end workers reported significantly higher rates of dyspnea on exertion and cough than did cold end workers. Data suggest that reported exposure to stannic chloride solution likely caused these symptoms. The industrial hygiene survey, conducted when stannic chloride use had been reduced, cleaning had been done, and ventilation improved, focused on measuring air contaminants that might possibly cause symptoms. Levels of hydrogen chloride, which apparently was formed by the combination of stannic chloride and water in the presence of heat, were elevated. The finding of increased prevalence of respiratory symptoms among hot end workers was consistent with this exposure. Recommendations were made to reduce hazardous exposures at this plant. Individuals responsible for occupational health should be aware that relatively benign substances, such as stannic chloride and water, can combine spontaneously to form hazardous substances.

  19. Metal chloride-treated graphene oxide to produce high-performance polymer solar cells

    SciTech Connect (OSTI)

    Choi, Eun-Su; Noh, Yong-Jin; Kwon, Sung-Nam; Na, Seok-In; Jeon, Ye-Jin; Kim, Seok-Soon; Kim, Tae-Wook

    2015-07-13

    We introduce a simple but effective graphene oxide (GO) modification with metal chloride treatments to produce high-performance polymer solar cells (PSCs). The role of various metal chlorides on GO and their effects on device performances of PSCs was investigated. X-ray photoelectron spectroscopy, ultraviolet photoemission spectroscopy, and current-voltage measurement studies demonstrated that metal chloride can induce a p-doping effect and increase the GO work-function, thus resulting in an improved built-in potential and interfacial resistance in PSCs. The resultant PSCs with metal chloride exhibited improved device efficiency than those with the neat GO. Furthermore, with the metal chloride-doped GO, we finally achieved an excellent PSC-efficiency of 6.58% and a very desirable device stability, which constitute a highly similar efficiency but much better PSC life-time to conventional device with poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). This study could be a valuable way to produce various PEDOT:PSS alternatives and beneficial for producing high-performance and cost-efficient polymeric devices.

  20. LOW TEMPERATURE PROCESS FOR THE REMOVAL AND RECOVERY OF CHLORIDES AND NITRATES FROM AQUEOUS NITRATE SOLUTIONS

    DOE Patents [OSTI]

    Savolainen, J.E.

    1963-01-29

    A method is described for reducing the chloride content of a solution derived from the dissolution of a stainless steel clad nuclear fuel element with an aqua regia dissolution medium. The solutlon is adjusted to a nitric acid concentration in the range 5 to 10 M and is countercurrently contacted at room temperature with a gaseous oxide of nitrogen selected from NO, NO/sub 2/, N/sub 2/ O/sub 3/, and N/sub 2/O/sub 4/. Chlo ride is recovered from the contacted solution as nitrosyl chloride. After reduction of the chloride content, the solution is then contacted with gaseous NO to reduce the nitric acid molarity to a desired level. (AEC)

  1. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, Ira D.; Nelson, Paul A.; Vissers, Donald R.

    1993-01-01

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 .OMEGA.cm.sup.2 than those resistivity values of approximately 1.0-1.5 .OMEGA.cm.sup.2 exhibited by currently available electrodes.

  2. Current Status of Health and Safety Issues of Sodium/Metal Chloride (Zebra) Batteries

    SciTech Connect (OSTI)

    Trickett, D.

    1998-12-15

    This report addresses environmental, health, and safety (EH&S) issues associated with sodium/ metal chloride batteries, in general, although most references to specific cell or battery types refer to units developed or being developed under the Zebra trademark. The report focuses on issues pertinent to sodium/metal chloride batteries and their constituent components; however, the fact that some ''issues'' arise from interaction between electric vehicle (EV) and battery design compels occasional discussion amid the context of EV vehicle design and operation. This approach has been chosen to provide a reasonably comprehensive account of the topic from a cell technology perspective and an applications perspective.

  3. Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene

    SciTech Connect (OSTI)

    Ajayi, O. A. E-mail: cww2104@columbia.edu; Wong, C. W. E-mail: cww2104@columbia.edu; Anderson, N. C.; Wolcott, A.; Owen, J. S.; Cotlet, M.; Petrone, N.; Hone, J.; Gu, T.; Gesuele, F.

    2014-04-28

    We examine the time-resolved resonance energy transfer of excitons from single n-butyl amine-bound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4 reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.

  4. Method of electrode fabrication and an electrode for metal chloride battery

    DOE Patents [OSTI]

    Bloom, I.D.; Nelson, P.A.; Vissers, D.R.

    1993-03-16

    A method of fabricating an electrode for use in a metal chloride battery and an electrode are provided. The electrode has relatively larger and more uniform pores than those found in typical electrodes. The fabrication method includes the steps of mixing sodium chloride particles selected from a predetermined size range with metal particles selected from a predetermined size range, and then rigidifying the mixture. The electrode exhibits lower resistivity values of approximately 0.5 [Omega]cm[sup 2] than those resistivity values of approximately 1.0-1.5 [Omega]cm[sup 2] exhibited by currently available electrodes.

  5. The economic impact of removing chloride from closed-loop wet limestone FGD systems. Volume 1. Final report

    SciTech Connect (OSTI)

    Phillips, J.L.; Horton, W.M.

    1995-01-01

    High chloride concentrations in wet limestone FGD systems increase the corrosion rates of certain materials and decrease SO{sub 2} removal efficiency and limestone utilization. This study revealed four different technologies that could be used to control chloride concentrations in closed-loop wet limestone FGD systems: reverse osmosis, electrodialysis reversal, vapor compression evaporation, and duct injection. This two-volume report describes each option in detail, discusses the basis for selecting the chloride threshold levels along with approximate cost estimates for combined chloride removal and waste disposal options, and presents flow sheets and detailed material balances for the least-cost combined options. The total annualized costs for chloride removal and waste disposal estimated in this study for a 300-MW plant range from 0.8 to 1.3 mils/kWh for controlling chloride at 3000 ppm to prevent corrosion and range from 0.3 to 0.7 mils/kWh for controlling chloride at 15,000 ppm to prevent decreased SO{sub 2} removal. The design coal has a relatively high chloride-to-sulfur ratio; costs for other coals would be lower.

  6. The economic impact of removing chloride from closed-loop wet limestone GFD systems. Volume 2. Final report

    SciTech Connect (OSTI)

    Phillips, J.L.; Horton, W.M.

    1995-01-01

    High chloride concentrations in wet limestone FGD systems increase the corrosion rates of certain materials and decrease SO{sub 2} removal efficiency and limestone utilization. This study revealed four different technologies that could be used to control chloride concentrations in closed-loop wet limestone FGD systems: reverse osmosis, electrodialysis reversal, vapor compression evaporation, and duct injection. This two-volume report describes each option in detail, discusses the basis for selecting the chloride threshold levels along with approximate cost estimates for combined chloride removal and waste disposal options, and presents flow sheets and detailed material balances for the least-cost combined options. The total annualized costs for chloride removal and waste disposal estimated in this study for a 300-MW plant range from 0.8 to 1.3 mils/kWh for controlling chloride at 3000 ppm to prevent corrosion and range from 0.3 to 0.7 mils/kWh for controlling chloride at 15,000 ppm to prevent decreased SO{sub 2} removal. The design coal has a relatively high chloride-to-sulfur ratio; costs for other coals would be lower.

  7. Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)

    SciTech Connect (OSTI)

    Stolle, A. |; Ollivier, J.; Salauen, J.

    1992-05-20

    The 1-ethenylcyclopropylsulfonates 2e,f and 2-cyclopropylideneethyl esters 10b,c, readily available from cyclopropanone hemiacetal 1, undergo regioselective Pd(0) catalyzed nucleophilic substitution via the unsymmetric 1,1-dimethylene-{pi}-allyl complex 23. With stabilized anions (enolates of malonic ester, {beta}-dicarbonyl compounds, {beta}-sulfonyl ester, and Schiff bases as well as acetate anion, sulfonamide anion, etc.) the nucleophilic substitution occurs at the terminal vinylic position exclusively, providing cyclopropylideneethyl derivatives as building blocks of high synthetic potential. Competition experiments have disclosed that 1-ethenylcyclopropyl tosylate (2e) and cyclopropylideneethyl acetate (10b) are more reactive than dimethylallyl acetates 19 and 22, respectively. Use of chiral phosphines as ligands in the palladium catalyst can provide optically active methylenecyclopropane derivatives. With phenyl-, methyl-, and even n-butylzinc chloride as nucleophiles, the reaction apparently proceeds with initial transfer of the organic residue to palladium, followed by reductive elimination entailing tertiary substitution on the cyclopropane ring exclusively; the same type of product is obtained with azide and bis(trimethylsilyl)amide. But the site of hydride attack to yield reduction products depends on the hydride source. 1-Alkynylcyclopropyl chlorides 12, 13, and 14 react only with organozinc chlorides (nonstabilized nucleophiles) to provide mixtures of ethenylidenecyclopropanes 65 and alkynylcyclopropanes 66, via the {sigma}-palladium complexes 69 and 70, while chloride 15 undergoes mainly reduction. Other transition metal catalysts (Ni, Mo) also induce substitutions, but with poorer regioselectivity. 81 refs., 9 figs., 3 tabs.

  8. Performance of high molybdenum superaustenitic stainless steel welds in harsh chloride environments

    SciTech Connect (OSTI)

    Stenvall, P.; Liljas, M.; Wallen, B.

    1996-11-01

    Superaustenitic steels are normally welded with nickel-based alloys as filler materials. To clarify the understanding of weld behavior in superaustenitic stainless steels this paper presents the development history of 6Mo and 7Mo steels, and results of laboratory tests and field tests on welds of UNS S31254 (6Mo) and UNS S32654 (7 Mo) in different types of chloride containing environments. The laboratory tests consisted of the well known ferric chloride test (ASTM G 48 Method A). Shielded metal arc welds, gas tungsten arc welds and submerged arc welds in both grades were tested. The critical pitting temperatures were determined and the locations of the attack were noted. Some specimens were sectioned at the position of the attack followed by studies using light optical microscopy. The critical pitting temperatures of the welds in S31254 and S32654 were at normal levels for both grades, i.e., 40--50 C for S31254 and 60--75 C for S32654. The locations of the attack differed depending on the welding process. In shielded metal arc welds the attack was mostly located in the weld metal. In gas tungsten arc welds the attack was predominantly located next to the fusion line. The field tests showed that the behavior of welds and parent metal of superaustenitic stainless steels, as well as of nickel-based alloys, is much dependent on the corrosive environment. In oxidizing chloride solutions, similar results to those of the ferric chloride test, are observed. However, crevice corrosion in the parent material is at a greater risk than pitting corrosion in the welds. In very oxidizing solutions of low chloride concentrations, welds made of nickel-based fillers may corrode faster than the stainless steel base metal due to transpassive uniform corrosion. The opposite situation exists when active uniform corrosion prevails, i.e., welds made of nickel-based fillers corrode less than the stainless steel parent material.

  9. Evaluation of DUSTRAN Software System for Modeling Chloride Deposition on Steel Canisters

    SciTech Connect (OSTI)

    Tran, Tracy T.; Jensen, Philip J.; Fritz, Brad G.; Rutz, Frederick C.; Devanathan, Ram

    2015-07-29

    The degradation of steel by stress corrosion cracking (SCC) when exposed to atmospheric conditions for decades is a significant challenge in the fossil fuel and nuclear industries. SCC can occur when corrosive contaminants such as chlorides are deposited on a susceptible material in a tensile stress state. The Nuclear Regulatory Commission has identified chloride-induced SCC as a potential cause for concern in stainless steel used nuclear fuel (UNF) canisters in dry storage. The modeling of contaminant deposition is the first step in predictive multiscale modeling of SCC that is essential to develop mitigation strategies, prioritize inspection, and ensure the integrity and performance of canisters, pipelines, and structural materials. A multiscale simulation approach can be developed to determine the likelihood that a canister would undergo SCC in a certain period of time. This study investigates the potential of DUSTRAN, a dust dispersion modeling system developed by Pacific Northwest National Laboratory, to model the deposition of chloride contaminants from sea salt aerosols on a steel canister. Results from DUSTRAN simulations run with historical meteorological data were compared against measured chloride data at a coastal site in Maine. DUSTRAN’s CALPUFF model tended to simulate concentrations higher than those measured; however, the closest estimations were within the same order of magnitude as the measured values. The decrease in discrepancies between measured and simulated values as the level of abstraction in wind speed decreased suggest that the model is very sensitive to wind speed. However, the influence of other parameters such as the distinction between open-ocean and surf-zone sources needs to be explored further. Deposition values predicted by the DUSTRAN system were not in agreement with concentration values and suggest that the deposition calculations may not fully represent physical processes. Overall, results indicate that with parameter

  10. Branchial and renal pathology in the fish exposed chronically to methoxy ethyl mercuric chloride

    SciTech Connect (OSTI)

    Gill, T.S.; Pant, J.C.; Tewari, H.

    1988-08-01

    Pathological manifestations causally related to pesticide poisoning have been described in both surficial and internal tissues of the fishes. Among the various organomercurials are phenyl mercuric acetate, methyl mercuric dicyanidiamide, methoxy ethyl mercuric chloride, methoxy ethyl mercuric silicate etc. Of these, the methoxy ethyl mercuric chloride (MEMC) is used in agriculture as an antifungal seed dressing, and its toxicity is primarily manifest in the Hg/sup 2 +/ ion. This report describes pathogenesis of branchial and renal lesions in the common freshwater fish, Puntius conchonius exposed chronically to sublethal levels of MEMC. Prior to this, alterations in the peripheral blood and metabolite levels in response to experimental MEMC poisoning have been demonstrated in this species.

  11. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  12. Speciation of aqueous palladium(II) chloride solutions using optical spectroscopies

    SciTech Connect (OSTI)

    Tait, C.D.; Janecky, D.R.; Rogers, P.S.Z. (Los Alamos National Lab., NM (United States))

    1991-05-01

    Spectroscopic measurements of palladium(II) chloride solutions have been performed under ambient to elevated temperature conditions with systematic changes in pH and (Cl{sup {minus}}). Spectral signatures from electronic absorption spectra (Uv/Vis) and Raman vibrational spectra were determined, and these were subsequently used to systematically map out species along several paths of the predominance diagram. The species PdCl{sub x}(H{sub 2}O){sub 4{minus}x}{sup 2{minus}x} (x = 2, 3, or 4) and Pd(OH){sub 2} were observed, along with a precipitation product formed from > 10 {mu}M (Pd{sup 2+}) solutions under near-neutral conditions. The elemental composition of the precipitation product was examined with a scanning electron micrograph (SEM) and was found to contain chloride as well as palladium. While sub-stoichiometric amounts of available OH{sup {minus}} ligand produced UV/Vis solution spectra likely to be from mixed Pd-Cl-OH species, the pH field of these species would be vanishingly small at low, geologically relevant palladium ion concentrations where (OH{sup {minus}}) is no longer the limiting reagent in the transformation. In mildly acidic media, where chloropalladium(II) species predominate, elevated temperatures (up to 90C) cause lower charged palladium-chloride species to be favored, consistent with the lowered dielectric constant of water at higher temperatures.

  13. Characterization of poly(vinyl chloride) aged in a bromine containing electrolyte

    SciTech Connect (OSTI)

    Arnold, C. Jr.; Leo, A.; Tarjani, M.

    1988-01-01

    Poly(vinyl chloride) (PVC) is being considered for use as a flow frame material in a developmental zinc/bromine battery. The choice of PVC was based on its low cost and the ease with which it can be molded into complex parts. The electrolyte used in this battery is a highly corrosive mixture of bromine, zinc bromide, zinc chloride, potassium bromide, potassium chloride and a quaternary amine salt. The quaternary salt serves to reduce the concentration of free bromine in the electrolyte by virtue of its complexing capability. It is well known that aqueous bromine is capable of oxidizing organic compounds. The purpose of the current study was to investigate the effect of a bromine electrolyte on two PVC formulations, PVC-1 and PVC-4. PVC-1 is the designation given to one of B.F. Goodrich's commercial formulations and is the present baseline material for the flow frame. PVC-4 is an experimental B.F. Goodrich formulation that was developed especially for battery applications. We sought answers to such questions as (1) does oxidation and/or bromination take place. (2) does bromine penetrate into the sample and, if so, how far. (3) how are the mechanical and morphological properties affected. and (4) are there differences in stability between PVC-1 and PVC-4. To accelerate the aging processes we aged the PVC samples at an elevated temperature in an electrolyte which did not contain any complexing agent. 5 refs., 6 figs.

  14. Systems and methods for solar cells with CIS and CIGS films made by reacting evaporated copper chlorides with selenium

    SciTech Connect (OSTI)

    Albin, David S.; Noufi, Rommel

    2015-06-09

    Systems and methods for solar cells with CIS and CIGS films made by reacting evaporated copper chlorides with selenium are provided. In one embodiment, a method for fabricating a thin film device comprises: providing a semiconductor film comprising indium (In) and selenium (Se) upon a substrate; heating the substrate and the semiconductor film to a desired temperature; and performing a mass transport through vapor transport of a copper chloride vapor and se vapor to the semiconductor film within a reaction chamber.

  15. Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brown, Suree; Yue, Yanfeng; Kuo, Li-Jung; Mehio, Nada; Li, Meijun; Gill, Gary; Tsouris, Costas; Mayes, Richard T.; Saito, Tomonori; Dai, Sheng

    2016-03-11

    The need to secure future supplies of energy attracts researchers in several countries to a vast resource of nuclear energy fuel: uranium in seawater (estimated at 4.5 billion tons in seawater). In this study, we developed effective adsorbent fibers for the recovery of uranium from seawater via atom-transfer radical polymerization (ATRP) from a poly-(vinyl chloride)-co-chlorinated poly(vinyl chloride) (PVC-co-CPVC) fiber. ATRP was employed in the surface graft polymerization of acrylonitrile (AN) and tert-butyl acrylate (tBA), precursors for uranium-interacting functional groups, from PVC-co-CPVC fiber. The [tBA]/[AN] was systematically varied to identify the optimal ratio between hydrophilic groups (from tBA) and uranyl-binding ligandsmore » (from AN). The best performing adsorbent fiber, the one with the optimal [tBA]/[AN] ratio and a high degree of grafting (1390%), demonstrated uranium adsorption capacities that are significantly greater than those of the Japan Atomic Energy Agency (JAEA) reference fiber in natural seawater tests (2.42 3.24 g/kg in 42 days of seawater exposure and 5.22 g/kg in 49 days of seawater exposure, versus 1.66 g/kg in 42 days of seawater exposure and 1.71 g/kg in 49 days of seawater exposure for JAEA). Lastly, adsorption of other metal ions from seawater and their corresponding kinetics were also studied. The grafting of alternative monomers for the recovery of uranium from seawater is now under development by this versatile technique of ATRP.« less

  16. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    SciTech Connect (OSTI)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  17. Reactivity of liquid and semisolid secondary organic carbon with chloride and nitrate in atmospheric aerosols

    SciTech Connect (OSTI)

    Wang, Bingbing; O'Brien, Rachel E.; Kelly, Stephen T.; Shilling, John E.; Moffet, Ryan C.; Gilles, Mary K.; Laskin, Alexander

    2015-05-14

    Constituents of secondary organic carbon (SOC) in atmospheric aerosols are often mixed with inorganic components and compose a significant mass fraction of fine particulate matter in the atmosphere. Interactions between SOC and other condensed-phase species are not well understood. Here, we investigate the reactions of liquid-like and semi-solid SOC from ozonolysis of limonene (LSOC) and ?-pinene (PSOC) with NaCl using a set of complementary micro-spectroscopic analyses. These reactions result in chloride depletion in the condensed phase, release of gaseous HCl, and formation of organic salts. The reactions attributed to acid displacement by SOC acidic components are driven by the high volatility of HCl. Similar reactions can take place in SOC/NaNO? particles. The results show that an increase in SOC mass fraction in the internally mixed SOC/NaCl particles leads to higher chloride depletion. Glass transition temperatures and viscosity of PSOC were estimated for atmospherically relevant conditions. Data show that the reaction extent depends on SOC composition, particle phase state and viscosity, mixing state, temperature, relative humidity (RH), and reaction time. LSOC shows slightly higher potential to deplete chloride than PSOC. Higher particle viscosity at low temperatures and RH can hinder these acid displacement reactions. Formation of organic salts from these overlooked reactions can alter particle physiochemical properties and may affect their reactivity and ability to act as cloud condensation and ice nuclei. The release and potential recycling of HCl and HNO? from reacted aerosol particles may have important implications for atmospheric chemistry.

  18. Generalized chloride mass balance: Forward and inverse solutions for one-dimensional tracer convection under transient flux

    SciTech Connect (OSTI)

    Ginn, T.R.; Murphy, E.M.

    1996-12-01

    Forward and inverse solutions are provided for analysis of inert tracer profiles resulting from one-dimensional convective transport under fluxes which vary with time and space separately. The developments are displayed as an extension of conventional chloride mass balance (CMB) techniques to account for transient as well as space-dependent water fluxes. The conventional chloride mass balance has been used over two decades to estimate recharge over large time scales in arid environments. In this mass balance approach, the chloride concentration in the pore water, originating from atmospheric fallout, is inversely proportional to the flux of water through the sediments. The CMB method is especially applicable to arid and semi-arid regions where evapotranspirative enrichment of the pore water produces a distinct chloride profile in the unsaturated zone. The solutions presented allow incorporation of transient fluxes and boundary conditions in CMB analysis, and allow analysis of tracer profile data which is not constant with depth below extraction zone in terms of a rational water transport model. A closed-form inverse solution is derived which shows uniqueness of model parameter and boundary condition (including paleoprecipitation) estimation, for the specified flow model. Recent expressions of the conventional chloride mass balance technique are derived from the general model presented here; the conventional CMB is shown to be fully compatible with this transient flow model and it requires the steady-state assumption on chloride mass deposition only (and not on water fluxes or boundary conditions). The solutions and results are demonstrated on chloride profile data from west central New Mexico.

  19. Effect of nonlinear absorption on electric field applied lead chloride by Z-scan technique

    SciTech Connect (OSTI)

    Rejeena, I.; Lillibai,; Nampoori, V. P. N.; Radhakrishnan, P.; Rahimkutty, M. H.

    2014-10-15

    The preparation, spectral response and optical nonlinearity of gel grown lead chloride single crystals subjected to electric field of 20V using parallel plate arrangements have been investigated. Optical band gap of the samples were determined using linear absorption spectra. Open aperture z-scan was employed for the determination of nonlinear absorption coefficient of PbCl{sub 2} solution. The normalized transmittance curve exhibits a valley shows reverse saturable absorption. The non linear absorption at different input fluences were recorded using a single Gaussian laser beam in tight focus geometry. The RSA nature of the sample makes it suitable for optical limiting applications.

  20. The effects of a stannous chloride-based remediation system in a mercury contaminated stream

    SciTech Connect (OSTI)

    Mathews, Teresa J; Looney, Brian; BryanJr., Larry; Smith, John G; Miller, Carrie L; Peterson, Mark J

    2015-01-01

    Remediation of mercury (Hg)-contaminated watersheds is often challenging because of the complex nature of Hg biogeochemistry. Stream ecosystems have been shown to be particularly susceptible to Hg contamination and bioaccumulation in fish. Decreasing total Hg loading to stream systems, however, has shown variable performance in decreasing Hg concentrations in fish tissues. In this study, we assess the impacts of an innovative treatment system in reducing releases of Hg to a small stream system in the southeastern United States. The treatment system, installed in 2007, removes Hg from water using tin (Sn) (II) chloride followed by air stripping. Mercury concentrations in the receiving stream, Tims Branch, decreased from > 100 to ~10 ng/L in the four years following treatment, and Hg body burdens in redfin pickerel (Esox americanus) decreased by 70 % at the most contaminated site. Tin concentrations in water and fish increased significantly in the tributary leading to Tims Branch, but concentrations remain below levels of concern for human health or ecological risks. While other studies have shown that Sn may be environmentally methylated and methyltin can transfer its methyl group to Hg, results from our field studies and sediment incubation experiments suggest that the added Sn to the Tims Branch watershed is not contributing to MeHg production and bioaccumulation. The stannous chloride treatment system installed at Tims Branch was effective at removing Hg inputs and reducing Hg bioaccumulation in the stream with minimal impacts on the environment due to the increased Sn in the system.

  1. Methyl chloride via oxyhydrochlorination of methane: A building block for chemicals and fuels from natural gas

    SciTech Connect (OSTI)

    Benson, R.L.; Brown, S.S.D.; Ferguson, S.P.; Jarvis, R.F. Jr.

    1995-12-31

    The objectives of this program are to (a) develop a process for converting natural gas to methyl chloride via an oxyhydrochlorination route using highly selective, stable catalysts in a fixed-bed, (b) design a reactor capable of removing the large amount of heat generated in the process so as to control the reaction, (c) develop a recovery system capable of removing the methyl chloride from the product stream and (d) determine the economics and commercial viability of the process. The general approach has been as follows: (a) design and build a laboratory scale reactor, (b) define and synthesize suitable OHC catalysts for evaluation, (c) select first generation OHC catalyst for Process Development Unit (PDU) trials, (d) design, construct and startup PDU, (e) evaluate packed bed reactor design, (f) optimize process, in particular, product recovery operations, (g) determine economics of process, (h) complete preliminary engineering design for Phase II and (i) make scale-up decision and formulate business plan for Phase II. Conclusions regarding process development and catalyst development are presented.

  2. Crystal growth, structure and characterizations of a new semiorganic nonlinear optical material-{beta}-Alanine zinc chloride

    SciTech Connect (OSTI)

    Anbuchezhiyan, M.; Ponnusamy, S.; Muthamizhchelvan, C.; Sivakumar, K.

    2010-08-15

    The title compound, {beta}-alanine zinc chloride-a new semiorganic nonlinear optical crystal was grown by slow evaporation technique. Single crystals of {beta}-alanine zinc chloride have been subjected to X-ray diffraction analysis to determine the crystal structure. The powder X-ray diffractogram of the crystal has also been recorded. The amount of carbon, nitrogen and hydrogen in the crystals was also estimated. Fourier Transform Infrared and Raman spectral measurements have been carried out on the grown crystals in order to identify the functional groups. The presence of hydrogen and carbon in the {beta}-alanine zinc chloride was confirmed by using proton and carbon nuclear magnetic resonance spectral analyses. The percentage of zinc in the crystal was determined by atomic absorption spectroscopy. Optical behavior such as ultraviolet-vis-near infrared transmittance spectrum and second harmonic generation has been investigated. The mechanical strength and thermal behavior of the grown crystal have been analyzed.

  3. Synergistic extraction of trivalent lanthanides and actinides from acidic chloride media by tetra(n-octyl)diglycolamide

    SciTech Connect (OSTI)

    McAlister, D.R.; Horwitz, E. Philip

    2008-07-01

    Ferric chloride has been found to induce a significant synergistic enhancement of the extraction of trivalent lanthanides and actinides by tetra(n-octyl)diglycolamide (TODGA) from acidic chloride media. In this manuscript, results of a thorough investigation of the TODGA-HCl-Fe(III) system using solvent-extraction experiments designed to elucidate the stoichiometry of the synergistic species will be described. Results for Ac(III), Am(III), Eu(III), Pm(III), Y(III), Th(IV), Pu(IV), and U(VI) will be discussed. (authors)

  4. Microsoft Word - Class 1 New Permit Corrections- FINAL 122710...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... methylene chloride; carbon tetrachloride; 1,1,1- ... 17 APPENDIX B2 MAPS ......Right-of-Way for Water Pipeline NM53809 081783 In ...

  5. DECONTAMINATION OF PLUTONIUM FOR FLUORIDE AND CHLORIDE DURING OXALATE PRECIPITATION, FILTRATION AND CALCINATION PROCESSES

    SciTech Connect (OSTI)

    Kyser, E.

    2012-07-25

    Due to analytical limitations for the determination of fluoride (F) and chloride (Cl) in a previous anion exchange study, an additional study of the decontamination of Pu from F and Cl by oxalate precipitation, filtration and calcination was performed. Anion product solution from the previous impurity study was precipitated as an oxalate, filtered, and calcined to produce an oxide for analysis by pyrohydrolysis for total Cl and F. Analysis of samples from this experiment achieved the purity specification for Cl and F for the proposed AFS-2 process. Decontamination factors (DF's) for the overall process (including anion exchange) achieved a DF of {approx}5000 for F and a DF of {approx}100 for Cl. Similar experiments where both HF and HCl were spiked into the anion product solution to a {approx}5000 {micro}g /g Pu concentration showed a DF of 5 for F and a DF of 35 for Cl across the combined precipitation-filtration-calcination process steps.

  6. Electrochemical Polishing Applications and EIS of a Novel Choline Chloride-Based Ionic Liquid

    SciTech Connect (OSTI)

    Wixtrom, Alex I.; Buhler, Jessica E.; Reece, Charles E.; Abdel-Fattah, Tarek M.

    2013-06-01

    Minimal surface roughness is a critical feature for high-field superconducting radio frequency (SRF) cavities used to engineer particle accelerators. Current methods for polishing Niobium cavities typically utilize solutions containing a mixture of concentrated sulfuric and hydrofluoric acid. Polishing processes such as these are effective, yet there are many hazards and costs associated with the use (and safe disposal) of the concentrated acid solutions. An alternative method for electrochemical polishing of the cavities was explored using a novel ionic liquid solution containing choline chloride. Potentiostatic electrochemical impedance spectroscopy (EIS) was used to analyze the ionic polishing solution. Final surface roughness of the Nb was found to be comparable to that of the acid-polishing method, as assessed by atomic force microscopy (AFM). This indicates that ionic liquid-based electrochemical polishing of Nb is a viable replacement for acid-based methods for preparation of SRF cavities.

  7. Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System

    SciTech Connect (OSTI)

    Yongchun Tang; John Ma

    2012-03-23

    The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

  8. Simulation of spray drying with reaction: Absorption of hydrogen sulfide in ammoniacal solution of zinc chloride

    SciTech Connect (OSTI)

    Chander, H.; Ghosh, P.K. ); Baveja, K.K.; Dhingra, S.C. )

    1993-01-01

    Absorption of hydrogen sulfide gas in ammoniacal solution of zinc chloride is accompanied with an instantaneous chemical reaction forming zinc sulfide precipitates. Such reactions are most suited for operation of spray drying with reaction. A mathematical model for the system which incorporates chemical reaction, heat, mass and momentum transfer has been proposed. It is assumed that the gases and the spray is considered monodisperse for sake of simplicity. The differential equations derived for the model have been solved as an initial value problem using the Runge-Kutta method. The variations of temperature, humidity, droplet diameter, moisture content and concentrations of reactants are predicted along the length of the column and compared with experimental data.

  9. Recovery of the actinides by electrochemical methods in molten chlorides using solid aluminium cathode

    SciTech Connect (OSTI)

    Malmbeck, R.; Mendes, E.; Serp, J.; Soucek, P.; Glatz, J.P.; Cassayre, L.

    2007-07-01

    An electrorefining process in molten chloride salts is being developed at ITU to reprocess the spent nuclear fuel. According to the thermochemical properties of the system, aluminium is the most promising electrode material for the separation of actinides (An) from lanthanides (Ln). The actinides are selectively reduced from the fission products and stabilized by the formation of solid and compact actinide-aluminium alloys with the reactive cathode material. In this work, the maximum loading of aluminium with actinides was investigated by potentiostatic and galvano-static electrorefining of U-Pu- Zr alloys. A very high aluminium capacity was achieved, as the average loading was 1.6 g of U and Pu into 1 g of aluminium and the maximum achieved loading was 2.3 g. For recovery of the actinides from aluminium, a process based on chlorination and a subsequent sublimation of AlCl{sub 3} is proposed. (authors)

  10. Calcium chloride electron injection/extraction layers in organic electronic devices

    SciTech Connect (OSTI)

    Qu, Bo, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn; Gao, Zhi; Yang, Hongsheng; Xiao, Lixin; Chen, Zhijian; Gong, Qihuang, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)

    2014-01-27

    Nontoxic calcium chloride (CaCl{sub 2}) was introduced into organic electronic devices as cathode buffer layer (CBL). The turn-on voltage and maximum luminance of organic light-emitting diode (OLED) with 1.5?nm CaCl{sub 2} was 3.5?V and 21960?cd/m{sup 2}, respectively. OLED with 1.5?nm CaCl{sub 2} possessed comparable electroluminescent characteristics to that of the commonly used LiF. Moreover, the performance of the organic photovoltaic device with 0.5?nm CaCl{sub 2} was comparable to that of the control device with LiF. Therefore, CaCl{sub 2} has the potential to be used as the CBL for organic electronic devices.

  11. The effects of a stannous chloride-based water treatment system in a mercury contaminated stream

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mathews, Teresa J.; Looney, Brian B.; Smith, John G.; Miller, Carrie L.; Peterson, Mark J.; Bryan, A. Lawrence; Southworth, George R.

    2015-06-09

    Remediation of mercury (Hg)-contaminated watersheds is often challenging because of the complex nature of Hg biogeochemistry. Stream ecosystems have been shown to be particularly susceptible to Hg contamination and bioaccumulation in fish. Decreasing total Hg loading to stream systems, however, has shown variable performance in decreasing Hg concentrations in fish tissues. In this study, we assess the impacts of an innovative treatment system in reducing releases of Hg to a small stream system in the southeastern United States. The treatment system, installed in 2007, removes Hg from water using tin (Sn) (II) chloride followed by air stripping. Mercury concentrations inmore » the receiving stream, Tims Branch, decreased from > 100 to ~10 ng/L in the four years following treatment, and Hg body burdens in redfin pickerel (Esox americanus) decreased by 70 % at the most contaminated site. Tin concentrations in water and fish increased significantly in the tributary leading to Tims Branch, but concentrations remain below levels of concern for human health or ecological risks. While other studies have shown that Sn may be environmentally methylated and methyltin can transfer its methyl group to Hg, results from our field studies and sediment incubation experiments suggest that the added Sn to the Tims Branch watershed is not contributing to MeHg production and bioaccumulation. The stannous chloride treatment system installed at Tims Branch was effective at removing Hg inputs and reducing Hg bioaccumulation in the stream with minimal impacts on the environment due to the increased Sn in the system.« less

  12. The effects of a stannous chloride-based remediation system in a mercury contaminated stream

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mathews, Teresa J; Looney, Brian; BryanJr., Larry; Smith, John G; Miller, Carrie L; Peterson, Mark J

    2015-01-01

    Remediation of mercury (Hg)-contaminated watersheds is often challenging because of the complex nature of Hg biogeochemistry. Stream ecosystems have been shown to be particularly susceptible to Hg contamination and bioaccumulation in fish. Decreasing total Hg loading to stream systems, however, has shown variable performance in decreasing Hg concentrations in fish tissues. In this study, we assess the impacts of an innovative treatment system in reducing releases of Hg to a small stream system in the southeastern United States. The treatment system, installed in 2007, removes Hg from water using tin (Sn) (II) chloride followed by air stripping. Mercury concentrations inmore » the receiving stream, Tims Branch, decreased from > 100 to ~10 ng/L in the four years following treatment, and Hg body burdens in redfin pickerel (Esox americanus) decreased by 70 % at the most contaminated site. Tin concentrations in water and fish increased significantly in the tributary leading to Tims Branch, but concentrations remain below levels of concern for human health or ecological risks. While other studies have shown that Sn may be environmentally methylated and methyltin can transfer its methyl group to Hg, results from our field studies and sediment incubation experiments suggest that the added Sn to the Tims Branch watershed is not contributing to MeHg production and bioaccumulation. The stannous chloride treatment system installed at Tims Branch was effective at removing Hg inputs and reducing Hg bioaccumulation in the stream with minimal impacts on the environment due to the increased Sn in the system.« less

  13. ?-Fe{sub 2}O{sub 3} nanoparticles: An easily recoverable effective photo-catalyst for the degradation of rose bengal and methylene blue dyes in the waste-water treatment plant

    SciTech Connect (OSTI)

    Dutta, Amit Kumar; Maji, Swarup Kumar; Adhikary, Bibhutosh

    2014-01-01

    Graphical abstract: - Highlights: ?-Fe{sub 2}O{sub 3} NPs from a single-source precursor and characterized by XRD, TEM, UVvis spectra. The NPs were tested as effective photocatalyst toward degradation of RB and MB dyes. The possible pathway of the photocatalytic decomposition process has been discussed. The active species, OH, was detected by TA photoluminescence probing techniques. - Abstract: ?-Fe{sub 2}O{sub 3} nanoparticles (NPs) were synthesized from a single-source precursor complex [Fe{sub 3}O(C{sub 6}H{sub 5}COO){sub 6}(H{sub 2}O){sub 3}]NO{sub 3} by a simple thermal decomposition process and have been characterized by X-ray diffraction analysis (XRD), transmission electron microscopy (TEM) and UVvis spectroscopic techniques. The NPs were highly pure and well crystallized having hexagonal morphology with an average particle size of 35 nm. The prepared ?-Fe{sub 2}O{sub 3} (maghemite) NPs show effective photo-catalytic activity toward the degradation of rose bengal (RB) and methylene blue (MB) dyes under visible light irradiation and can easily be recoverable in the presence of magnetic field for successive re-uses. The possible photo-catalytic decomposition mechanism is discussed through the detection of hydroxyl radical (OH) by terephthalic acid photo-luminescence probing technique.

  14. Mechanisms, Chemistry, and Kinetics of Anaerobic Biodegradation of cis-Dichloroethene and Vinyl Chloride

    SciTech Connect (OSTI)

    McCarty, P.L.; Spormann, A.M.

    2000-12-01

    Anaerobic biological processes can result in PCE and TCE destruction through conversion to cis-dichloroethene (cDCE) then to vinyl chloride (VC), and finally to ethene. Here, the chlorinated aliphatic hydrocarbons (CAHs) serve as electron acceptors in energy metabolism, requiring electron donors such as hydrogen from an external source. The purpose of this study was to learn more about the biochemistry of cDCE and VC conversion to ethene, to better understand the requirements for electron donors, and to determine factors affecting the rates of CAH degradation and organism growth. The biochemistry of reductive dehalogenation of VC was studied with an anaerobic mixed culture enriched on VC. In other studies on electron donor needs for dehalogenation of cDCE and VC, competition for hydrogen was found to occur between the dehalogenators and other microorganisms such as methanogens and homoacetogens in a benzoate-acclimated dehalogenating methanogenic mixed culture. Factors affecting the relative rates of destruction of the solvents and their intermediate products were evaluated. Studies using a mixed PCE-dehalogenating culture as well as the VC enrichment for biochemical studies suggested that the same species was involved in both cDCE and VC dechlorination, and that cDCE and VC competitively inhibited each other's dechlorination rate.

  15. Electrochemical, galvanic, and mechanical responses of grade 2 titanium in 6% sodium chloride solution

    SciTech Connect (OSTI)

    Wang, Z.F.; Briant, C.L.; Kumar, K.S.

    1999-02-01

    The electrochemical, galvanic, and mechanical responses of grade 2 titanium in 6% sodium chloride (NaCl) solution at different temperatures were investigated. The initial corrosion potential and cathodic reaction rate increased with decreasing pH and increasing temperature. The initial corrosion potential changed when titanium was coupled with other metals. Naval brass and alloy 600 (UNS N06600) anodically polarized titanium, while zinc and aluminum caused titanium to become a cathode. HY80 steel (UNS K31820), type 316 stainless steel ([SS] UNS S31600), and Monel K500 (UNS N05500, a copper-nickel alloy), polarized titanium anodically or cathodically depending upon temperature and pH. Hydrides formed on the titanium surface at potentials < {approximately} {minus}600 mV{sub SCE} to {minus}700 mV{sub SCE}. Zinc at all temperatures and HY80 at high temperatures caused hydride formation in titanium when coupled galvanically with titanium. Mechanical tests showed an {approx} 10% decrease in ductility under prior and dynamic hydrogen charging conditions.

  16. Electrolytic conditioning of a magnesium aluminum chloride complex for reversible magnesium deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barile, Christopher J.; Barile, Elizabeth C.; Zavadil, Kevin R.; Nuzzo, Ralph G.; Gewirth, Andrew A.

    2014-12-04

    We describe in this report the electrochemistry of Mg deposition and dissolution from the magnesium aluminum chloride complex (MACC). The results define the requirements for reversible Mg deposition and definitively establish that voltammetric cycling of the electrolyte significantly alters its composition and performance. Elemental analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (SEM-EDS) results demonstrate that irreversible Mg and Al deposits form during early cycles. Electrospray ionization-mass spectrometry (ESI-MS) data show that inhibitory oligomers develop in THF-based solutions. These oligomers form via the well-established mechanism of a cationic ring-opening polymerization of THF during the initial synthesis of the MACC andmore » under resting conditions. In contrast, MACC solutions in 1,2-dimethoxyethane (DME), an acyclic solvent, do not evolve as dramatically at open circuit potential. Furthermore, we propose a mechanism describing how the conditioning process of the MACC in THF improves its performance by both tuning the Mg:Al stoichiometry and eliminating oligomers.« less

  17. Rare earth elements in chloride-rich groundwater, Palo Duro Basin, Texas, USA

    SciTech Connect (OSTI)

    Gosselin, D.C. ); Smith, M.R.; Lepel, E.A. ); Laul, J.C. )

    1992-04-01

    Rare earth element (REE) data for groundwater samples from the Deep-Basin Brine aquifer of the Palo Duro Basin, Texas, USA, illustrates the potential use of REE for inferring groundwater flow paths through different geologic materials. The REE content of the groundwaters range over 2.5 orders of magnitude and are depleted by 10{sup 2} to 10{sup 5} relative to aquifer materials. The shale-normalized REE patterns for groundwater that have primarily interacted with arkosic sandstones (granite wash) are flat with similar heavy REE (HREE) enrichments ((Lu/La){sub n} = 0.60 to 0.80). The samples with highest REE contents and REE patterns, which are enriched in the intermediate REEs (IREEs; Sm-Tb) reflect variable degrees of interaction with carbonate rocks. The IREE enrichment is the result of fluid interaction with Fe-Mn coatings on carbonate minerals and/or secondary minerals in fractures and vugs. The chloride complex. (LnCl{sup 2+}), and free-ions are the predominant REE species, accounting for over 95% of the REEs. Carbonate and sulfate species account for the other 5% and have very little influence on the behavior of the REEs. Although this study indicates a potentially important role for the REEs in understanding geochemical transport and groundwater movement, it also indicates the necessity for developing a better understanding of REE speciation in high ionic strength solutions.

  18. Electrolytic conditioning of a magnesium aluminum chloride complex for reversible magnesium deposition

    SciTech Connect (OSTI)

    Barile, Christopher J.; Barile, Elizabeth C.; Zavadil, Kevin R.; Nuzzo, Ralph G.; Gewirth, Andrew A.

    2014-12-04

    We describe in this report the electrochemistry of Mg deposition and dissolution from the magnesium aluminum chloride complex (MACC). The results define the requirements for reversible Mg deposition and definitively establish that voltammetric cycling of the electrolyte significantly alters its composition and performance. Elemental analysis, scanning electron microscopy, and energy-dispersive X-ray spectroscopy (SEM-EDS) results demonstrate that irreversible Mg and Al deposits form during early cycles. Electrospray ionization-mass spectrometry (ESI-MS) data show that inhibitory oligomers develop in THF-based solutions. These oligomers form via the well-established mechanism of a cationic ring-opening polymerization of THF during the initial synthesis of the MACC and under resting conditions. In contrast, MACC solutions in 1,2-dimethoxyethane (DME), an acyclic solvent, do not evolve as dramatically at open circuit potential. Furthermore, we propose a mechanism describing how the conditioning process of the MACC in THF improves its performance by both tuning the Mg:Al stoichiometry and eliminating oligomers.

  19. Solubilities and other physical parameters of aromatic hydrocarbons in water and aqueous sodium chloride solutions as determined by headspace analysis

    SciTech Connect (OSTI)

    Lowry, M.A.H.

    1991-12-31

    The solubility, Henry`s law constant, aqueous-vapor partition coefficients, and oil-aqueous distribution coefficients of benzene, toluene, ethylbenzene, o-xylene,m-xylene and p-xylene were determined in water and aqueous sodium chloride solutions at 25C. Values are in agreement with using gas chromatography of headspace literature. The salting-out effect of sodium chloride on the solute properties measured was illustrated using the empirical relationship deduced by Setschenow (1889). The empirical relationship predicts that the logarithm of solubility will be a function of ionic strength. The solubility data obtained in this work obeys this relationship. It was also found that the logarithm of the Henry`s law constant, partition coefficient, and distribution coefficient are linear functions of ionic strength. 10 tabs, 6 figs.

  20. Catalytic destruction of perchlorate in ferric chloride and hydrochloric acid solution with control of temperature, pressure and chemical reagents

    DOE Patents [OSTI]

    Gu, Baohua; Cole, David R.; Brown, Gilbert M.

    2004-10-05

    A method is described to decompose perchlorate in a FeCl.sub.3 /HCl aqueous solution such as would be used to regenerate an anion exchange resin used to remove perchlorate. The solution is mixed with a reducing agent, preferably an organic alcohol and/or ferrous chloride, and can be heated to accelerate the decomposition of perchlorate. Lower temperatures may be employed if a catalyst is added.

  1. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    SciTech Connect (OSTI)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at

  2. Cesium chloride compatibility testing program: Annual report for fiscal year 1986

    SciTech Connect (OSTI)

    Bryan, G.H.

    1987-05-01

    A program was started to evaluate the compatibility of Waste Encapsulation and Storage Facility (WESF)-produced cesium chloride (CsCl) with 316L stainless steel (SS) under thermal conditions that may be encountered in a geologic repository. Objective is compatibility testing of six standard WESF capsules at a max metal/CsCl interface temperature of approx.450/sup 0/C. Test capsule No. C-1351 was removed from its insulated container after being held at temperature for 28,268 h (3.2 y). The average max interface temperature for the 3.2-y capsule was 445/sup 0/C. Metal corrosion in the 3.2-y capsule was extensive throughout the capsule, except in the upper portion of the capsule where the interface temperature was below 400/sup 0/C. The maximum corrosion found was 460 ..mu..m (0.018 in.). Overall corrosion in the hotter portion of the 3.2-y capsule increased linearly with time. Intergranular attack was much more apparent in the tests of longer duration, while pitting and a general surface attack appeared to predominate in the shorter tests. In the area where the temperature was below 400/sup 0/C, the attack was greatly reduced. Results indicate that in the hotter portion of the capsule (where the metal/CsCl interface temperature is above 400/sup 0/C the corrosion is proceeding at a linear rate. If metal corrosion at the higher temperatures proceeds at a linear rate for an extended period of time, it has serious implications for the geologic disposal of the WESF CsCl capsules. Estimates of long-term metal attack in a geological repository are discussed.

  3. Methyl chloride via oxyhydrochlorination of methane. Quarterly technical progress report No. 13, October--December 1994

    SciTech Connect (OSTI)

    1995-02-01

    The purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts in fixed-bed reactors designed to remove the large amount of heat generated, so as to control the reaction temperature. Further, the objective is to obtain the engineering data base necessary for developing a commercially feasible process and to evaluate t economics of the process. Significant progress was made in six different technical areas during this quarter. These key highlights are: (1) Evaluation of catalyst samples from UCI led to the ordering of the OHC PDU catalyst batch. This catalyst batch arrived, was screened and found to be defective, and was reordered. (2) Natural gas containing higher hydrocarbons was used as a methane source. The reactant mixture formed oxygenates at temperatures lower than observed in the past. Burning at such low temperatures seems to create a product stream containing very little CH{sub 2}Cl{sub 2}. (3) Although it has not been decided if the PDU will use natural gas from the plant or methane or natural gas from cylinders as a methane feed source, it was concluded that an adsorption unit to remove sulfur and higher hydrocarbons is not necessary at this time. (4) PDU construction was completed in December. The bulk of insulation work was completed at the end of November. Much effort has been put into pressure testing the PDU`s systems. The startup team has become adept at finding and correcting such leaks. (5) SOP writing for the PDU was completed this quarter with communication with the software programmer to insure agreement between the software and SOP.

  4. Composition dependent structural organization in trihexyl(tetradecyl)phosphonium chloride ionic liquid-methanol mixtures

    SciTech Connect (OSTI)

    Gupta, Aditya; Sharma, Shobha; Kashyap, Hemant K.

    2015-04-07

    This article reports results from the molecular dynamics simulations on the structural arrangement of the ions and molecules in the mixtures of trihexyl(tetradecyl)phosphonium chloride ([P{sub 666,14}{sup +}][Cl{sup ?}]) ionic liquid (IL) and methanol (MeOH) over the entire composition range. Effects of composition on the charge and polarity orderings have been investigated via computation of X-ray scattering structure function, S(q), and by using a partitioning scheme proposed for such multi-component mixtures. Except for the neat methanol liquid, the total S(q) shows two peaks in its intermolecular region for all the mole-fractions. The lowest q peak is dominated primarily by anion-anion, cation-anion, and methanol-anion correlations. Our results signify that the methanol bulk structure, which predominantly has short-distance characteristic correlations and is governed by polar group of methanol, is retained for x{sub IL} ? 0.1. Then, the mixture goes through gradual structural changes from methanol-like to the IL-like for 0.1 < x{sub IL} ? 0.7. The dipolar interaction between methanol molecules weakens in this range, and the structural landscape of the mixture is steered by strong ion-ion, anion-methanol, and nonpolar interactions. The IL-like structural arrangement is virtually recovered for x{sub IL} > 0.7. At all the compositions studied, while the cation head groups are predominantly solvated by anions and subsequently by methanol molecules, the polar hydroxyl group of methanol is preferentially solvated by the anions. The radial distribution functions of selected pair of atomic species have also confirmed these observations.

  5. Individual and combined effects of chloride, sulfate, and magnesium ions on hydrated Portland-cement paste

    SciTech Connect (OSTI)

    Poole, T.S.; Wakeley, L.D.; Young, C.L.

    1994-03-01

    Ground water with a high concentration of magnesium ion is known to cause deterioration to portland cement concretes. A proposed mechanism for this deterioration process published previously involves an approximate 1:1 replacement of Ca ions by Mg ions in the crystalline phases of hydrated cement. The current study was undertaken to determine which ions, among magnesium, chloride, and sulfate, cause deterioration; whether their deleterious action is individual or interdependent; and to relate this mechanism of deterioration to the outlook for a 100-yr service life of concretes used in mass placements at the Waste Isolation Pilot Plant. Loss of Ca ion by cement pastes was found to be strongly related to the concentration of Mg ion in simulated ground-water solutions in which the paste samples were aged. This was true of both salt- containing and conventional cement pastes. No other ion in the solutions exerted a strong effect on Ca loss. Ca ion left first from calcium hydroxide in the pastes, depleting all calcium hydroxide by 60 days. Some calcium silicate hydrate remained even after 90 days in the solutions with the highest concentration of Mg ion, while the paste samples deteriorated noticeably. The results indicated a mechanism that involves dissolution of Ca phases and transport of Ca ions to the surface of the sample, followed by formation of Mg-bearing phases at this reaction surface rather than directly by substitution within the microstructure of hydrated cement. Given that calcium hydroxide and calcium silicate hydrate are the principal strength-giving phases of hydrated cement, this mechanism indicates the likelihood of significant loss of integrity of a concrete exposed to Mg-bearing ground water at the WIPP. The rate of deterioration ultimately will depend on Mg-ion concentration, the microstructure materials of the concrete exposed to that groundwater, and the availability of brine.

  6. Corrosion Effects of Calcium Chloride Injection for Mercury Control on the Pollution Control Equipment

    SciTech Connect (OSTI)

    Vijay Sethi; M.P. Sharma

    2009-02-28

    In response to the Clean Air Mercury Rule (CAMR) of 2005, Black Hills Power (BHP) initiated testing of a calcium chloride (CaCl{sub 2}) injection method in their Wygen 1 (Gillette, WY) coal-fired power plant to help lower mercury emissions. In 2006, Babcock & Wilcox (B&W) was contracted to test their CaCl{sub 2} technology in-situ by adding a CaCl{sub 2} solution onto the raw, pre-pulverized coal during normal operation of Wygen 1. Follow-up tests were conducted by BHP in 2007. Data were collected from these two time periods and analyzed by a collaborative investigation team from Western Research Institute (WRI) and the University of Wyoming (UW) to see if there were any effects on the current air pollution control systems. During a CaCl{sub 2} injection period in 2007, corrosion was monitored in the flue and recycle ash system by placing corrosion coupons in strategic locations to test if corrosion was enhanced by the CaCl{sub 2} injection. While the CaCl{sub 2} produced a reduction in stack mercury levels, there was some evidence of beneficial impacts on the removal of SO{sub 2} from the flue gas during CaCl{sub 2} injection. Data on NOx remained inconclusive. It was also discovered that corrosion was enhanced significantly in the Spray Drier Absorber (SDA) vessel and corresponding outlet ductwork during CaCl{sub 2} injections. Further studies are being carried out in the field and lab to better understand the corrosive effects of CaCl{sub 2} to help formulate operation controls to manage the increased corrosion rates.

  7. Reactant ion chemistry for detection of TNT, RDX, and PETN using an ion mobility spectrometer

    SciTech Connect (OSTI)

    Klassen, S.E.; Rodacy, P.; Silva, R.

    1997-09-01

    This report describes the responses of three energetic materials (TNT, RDX, and PETN) to varying reactant ion chemistries and IMS cell temperatures. The following reactant ion chemistries were evaluated; air-dry; air-wet; methylene chloride-dry; methylene chloride-wet; methylene bromide-dry; nitrogen dioxide-wet; sulfur dioxide-wet. The temperature was varied between 160 - 220{degrees}C.

  8. Thermal Analysis of Surrogate Simulated Molten Salts with Metal Chloride Impurities for Electrorefining Used Nuclear Fuel

    SciTech Connect (OSTI)

    Toni Y. Gutknecht; Guy L. Fredrickson; Vivek Utgikar

    2012-04-01

    This project is a fundamental study to measure thermal properties (liquidus, solidus, phase transformation, and enthalpy) of molten salt systems of interest to electrorefining operations, which are used in both the fuel cycle research & development mission and the spent fuel treatment mission of the Department of Energy. During electrorefining operations the electrolyte accumulates elements more active than uranium (transuranics, fission products and bond sodium). The accumulation needs to be closely monitored because the thermal properties of the electrolyte will change as the concentration of the impurities increases. During electrorefining (processing techniques used at the Idaho National Laboratory to separate uranium from spent nuclear fuel) it is important for the electrolyte to remain in a homogeneous liquid phase for operational safeguard and criticality reasons. The phase stability of molten salts in an electrorefiner may be adversely affected by the buildup of fission products in the electrolyte. Potential situations that need to be avoided are: (i) build up of fissile elements in the salt approaching the criticality limits specified for the vessel (ii) freezing of the salts due to change in the liquidus temperature and (iii) phase separation (non-homogenous solution) of elements. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This work describes the experimental results of typical salts compositions, consisting of chlorides of strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium (as a surrogate for both uranium and plutonium), used in the processing of used nuclear fuels. Differential scanning calorimetry was used to analyze numerous salt samples providing results on the thermal properties. The property of most interest to pyroprocessing is the liquidus temperature. It was

  9. Equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride

    SciTech Connect (OSTI)

    Majumdar, A.; Mahmoodaghdam, E.; Bishnoi, P.R.

    2000-02-01

    Natural gas components such as hydrogen sulfide, carbon dioxide, and ethane form gas hydrates of structure I under suitable temperature and pressure conditions. Information on such conditions is vital to the oil and gas industry in order to design and operate processing equipment and pipelines so that hydrate formation is avoided. Incipient equilibrium hydrate formation conditions for hydrogen sulfide, carbon dioxide, and ethane in aqueous solutions of ethylene glycol and sodium chloride were experimentally obtained in the temperature range 264--290 K and the pressure range 0.23--3.18 MPa. A variable-volume sapphire cell was used for the measurements.

  10. The Heat Output of the Waimangu, Waiotapu-Waikite and Reporoa Geothermal Systems (NZ): Do Chloride Fluxes Provide an Accurate Measure?

    SciTech Connect (OSTI)

    Bibby, H.M.; Glover, R.B.; Whiteford, P.C.

    1995-01-01

    Geothermal waters from the Waimangu, Waiotapu-Waikite and Reporoa geothermal systems find their way into three separate watersheds. The heat flow data from each of these drainage areas have been assessed making it possible to compare the heat outputs from two independent methods: direct heat measurements and the chloride flux method. For both the Waiotapu/Reporoa Valley drainage and the Waikite drainage a discrepancy exists between the two assessments, with the heat output observed at the surface (Waiotapu-540 {+-} 110 MW; Waikite-80 MW) nearly double of that calculated from the chloride flux (300 MW; 36 MW respectively). It appears that much of the throughput of chloride does not reach the surface within the area which was monitored and the basic assumption on which the method is based has been violated. For Waimangu the direct heat output is assessed as 510 {+-} 60 MW. However the ratio of enthalpy to chloride concentration of the source fluid is not well determined. Depending on the ratio chosen the heat output could lie between 360 and 800 MW. Although the chloride flux is accurately known, the heat output cannot be measured accurately without well determined data on the source fluid at depth.

  11. Radiation Stability of Benzyl Tributyl Ammonium Chloride towards Technetium-99 Extraction - 13016

    SciTech Connect (OSTI)

    Paviet-Hartmann, Patricia; Horkley, Jared; Campbell, Keri; Roman, Audrey; Nunez, Ana; Espartero, Amparo

    2013-07-01

    launched to investigate the suitability of new macro-compounds such as crown-ethers, aza-crown ethers, quaternary ammonium salts, and resorcin-arenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO{sub 4}{sup -} by benzyl tributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand's matrix conditions and concentration, as well as varying the organic phase composition (i.e. diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using an external Co-60 source. Post-irradiation solvent extraction measurements will be discussed. (authors)

  12. Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction

    SciTech Connect (OSTI)

    Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

    2013-02-01

    investigate the suitability of new macrocompounds such as crown-ethers, aza-crown ethers, and resorcinarenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO4- by benzyltributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand’s matrix conditions and concentration, as well as varying the organic phase composition (i.e., diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using external Co-60 source. Post-irradiation solvent extraction measurements will be discussed.

  13. The relative importance of water hardness and chloride levels in modifying the acute toxicity of silver to rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Galvez, F.; Wood, C.M.

    1997-11-01

    Static-renewal 7-d toxicity tests for silver nitrate (AgNO{sub 3}) were performed with juvenile rainbow trout (Oncorhynchus mykiss Walbaum). The relative influences of calcium and chloride concentrations on median lethal time (LT50) were assessed. For both calcium salts, a 100-fold elevation in concentration increased the LT50 approximately 10-fold. However, a 100-fold elevation in KCl ameliorated silver (Ag) toxicity at least 100-fold, while NaCl protected against Ag toxicity even more substantially, demonstrating the much greater protective effect of chloride relative to calcium. In a separate series of bioassays, fish were exposed to 0.92 {micro}M Ag with varying amounts of NaCl titrated into each tank to alter the free [Ag{sup +}]. The 7-d LC50 occurred at a [NaCl] of 2,500 {micro}M. Using MINEQL{sup +}, the predicted free [Ag{sup +}] at this LC50 value is 0.0285 {micro}M. Further bioassays were performed in which [chloride] was maintained at either 50 or 225 {micro}M, while total [Ag] was independently varied from 0.0092 to 0.0694 {micro}M (1.0--7.5 {micro}g/L). The 7-d LC50 value was calculated at 0.0294 {micro}M Ag (3.18 {micro}g/L) at a chloride concentration of 50 {micro}M, very similar to the free [Ag{sup +}] value of 0.031 {micro}M calculated from an earlier LC50 test at a fixed [chloride] of 730 {micro}M. Elevating chloride concentrations from 50 to 225 {micro}M did not alter the accumulation of Ag in the liver. In addition, there were no significant differences in hepatic Ag accumulation between any of the Ag-exposed fish, irrespective of the total Ag concentration used during the exposure.

  14. Influence of microstructure on the corrosion resistance of AISI type 304L and type 316L sintered stainless steels exposed to ferric chloride solution

    SciTech Connect (OSTI)

    Otero, E.; Pardo, A.; Utrilla, M.V.; Perez, F.J.; Saenz, E.

    1995-10-01

    The corrosion behavior of type 304L and type 316L austenitic stainless steels, produced by powder metallurgy, when exposed to a ferric chloride solution was studied. The exposures were conducted according to ASTM G48-76, Method A. The influence of ferric chloride concentration and exposure temperature on the corrosion kinetics of these materials was evaluated. A mechanism is proposed to explain the associated morphology observed in the microstructures produced after exposure of these P/M alloys to the aggressive medium.

  15. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, R.H.; Schaffers, K.I.; Payne, S.A.; Krupke, W.F.; Beach, R.J.

    1997-12-02

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 {micro}m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 {micro}m. Related halide materials, including bromides and iodides, are also useful. The Dy{sup 3+}-doped metal chlorides can be pumped with laser diodes and yield 1.3 {micro}m signal gain levels significantly beyond those currently available. 9 figs.

  16. Optical amplifier operating at 1.3 microns useful for telecommunications and based on dysprosium-doped metal chloride host materials

    DOE Patents [OSTI]

    Page, Ralph H.; Schaffers, Kathleen I.; Payne, Stephen A.; Krupke, William F.; Beach, Raymond J.

    1997-01-01

    Dysprosium-doped metal chloride materials offer laser properties advantageous for use as optical amplifiers in the 1.3 .mu.m telecommunications fiber optic network. The upper laser level is characterized by a millisecond lifetime, the host material possesses a moderately low refractive index, and the gain peak occurs near 1.31 .mu.m. Related halide materials, including bromides and iodides, are also useful. The Dy.sup.3+ -doped metal chlorides can be pumped with laser diodes and yield 1.3 .mu.m signal gain levels significantly beyond those currently available.

  17. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  18. Effects of didecyldimethylammonium chloride on the biochemistry, swimming performance, gill histology and disease resistance of juvenile rainbow trout (Oncorhynchus mykiss)

    SciTech Connect (OSTI)

    Johnston, B.D.; Wood, A.W.; Farrell, A.P.; Kennedy, C.J.

    1995-12-31

    The acute lethal and sublethal toxicity of the antisapstain didecyldimethylammonium chloride (DDAC) to juvenile rainbow trout (Oncorhynchus mykiss) was investigated. The 96-h LC{sub 50} value in a flow-through exposure system was 0.4 mg-1{sup {minus}1}. Plasma cortisol, glucose and lactate levels were significantly elevated after an acute 24-h exposure to 0.4 mg-1{sup {minus}1}. Values for hepato-somatic index (HSI), haematocit, leucocrit, plasma haemoglobin, and liver glycogen remained unchanged. Swimming performance decreased significantly after exposure to 0.2 mg-1{sup {minus}1} for exposure durations of 12-h and 24-h and to 0.4 mg{sup {minus}1} for exposure durations of 12-h, 24-h, and 48-h. Scanning electron microscopic analysis revealed no gross lesions in gill epithelia as a result of toxicant exposure. In disease challenge experiments, exposure to sublethal concentrations of DDAC for 24-h did not effect the susceptibility of rainbow trout to the pathogen Vibrio anguilarum. Of a suite of toxicity tests, specific biochemical markers were unsatisfactory in revealing sublethal toxic effects. These were best revealed by an integrative measure of performance, namely swimming performance, but not disease resistance.

  19. Re-passivation Potential of Alloy 22 in Chloride plus Nitrate Solutions using the Potentiodynamic-Galvano-static-Potentiostatic Method

    SciTech Connect (OSTI)

    Evans, Kenneth J.; Rebak, Raul B.

    2007-07-01

    In general, the susceptibility of Alloy 22 to suffer crevice corrosion is measured using the Cyclic Potentiodynamic Polarization (CPP) technique. This is a fast technique that gives rather accurate and reproducible values of re-passivation potential (ER1) in most cases. In the fringes of susceptibility, when the environment is not highly aggressive, the values of re-passivation potential using the CPP technique may not be highly reproducible, especially because the technique is fast. To circumvent this, the re-passivation potential of Alloy 22 was measured using a slower method that combines Potentiodynamic-Galvano-static-Potentiostatic steps (called here the Tsujikawa-Hisamatsu Electrochemical or THE method). The THE method applies the charge to the specimen in a more controlled way, which may give more reproducible re-passivation potential values, especially when the environment is not aggressive. The values of re-passivation potential of Alloy 22 in sodium chloride plus potassium nitrate solutions were measured using the THE and CPP methods. Results show that both methods yield similar values of re-passivation potential, especially under aggressive conditions. (authors)

  20. Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)

    SciTech Connect (OSTI)

    Solehudin, Agus; Nurdin, Isdiriayani

    2014-03-24

    Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

  1. Effect of hydrogen sulfide partial pressure, pH, and chloride content on the SSC resistance of martensitic stainless steels and martensitic precipitation hardening stainless steels

    SciTech Connect (OSTI)

    Vitale, D.D.

    1999-11-01

    Centrifugal compressor applications require the use of martensitic stainless and martensitic precipitation hardening stainless steels at high hydrogen sulfide partial pressures. These materials do not perform well when tested with standard TM0177 test solutions. This paper describes the effect of hydrogen sulfide partial pressure, pH, and chloride content on their SSC resistance and explains their successful field operational experience. Environmental limits are determined for several materials and heat treat conditions.

  2. Improved Methods for the Production of Polyurethane Foam

    Office of Energy Efficiency and Renewable Energy (EERE)

    Methylene chloride, a toxic chemical that contributes to air pollution, was recently eliminated from use in the U.S. polyurethane industry. This mandated elimination did not permit production of as...

  3. On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Derek J. Fray

    2011-11-01

    electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

  4. Structure of complexes of nitrilo tris methylene phosphonic acid with copper, [CuN(CH{sub 2}PO{sub 3}){sub 3}(H{sub 2}O){sub 3}] and Na{sub 4}[CuN(CH{sub 2}PO{sub 3}){sub 3}]{sub 2} · 19H{sub 2}O, as bactericides and inhibitors of scaling and corrosion

    SciTech Connect (OSTI)

    Somov, N. V.; Chausov, F. F.

    2015-03-15

    Nitrilotris methylene phosphonate triaqua copper and octasodium bis(nitrilotris methylene phosphonate cuprate(II)) nonadecahydrate have been synthesized and investigated. [CuN(CH{sub 2}PO{sub 3}){sub 3}(H{sub 2}O){sub 3}] is crystallized in the sp. gr. P2{sub 1}/c, Z = 4, a = 9.2506(2) Å, b = 15.9815(2) Å, c = 9.5474(2) Å, β = 113.697(2)°. The copper atom is coordinated by oxygen atoms in the configuration of elongated octahedron; the ligand (of bridge type) links neighboring copper atoms. Na{sub 8}[CuN(CH{sub 2}PO{sub 3}){sub 3}]{sub 2} · 19H{sub 2}O is crystallized in the sp. gr. P2{sub 1}/c, Z = 2, a = 11.24550(10) Å, b = 17.38980(10) Å, c = 13.5852(2) Å, β = 127.8120(10)°. This complex is chelating; the copper atom closes three five-membered N-C-P-O-Cu cycles with a shared Cu-N bond. Copper is coordinated in a distorted trigonal-bipyramidal configuration.

  5. Influence of pH and chloride concentration on the pitting and crevice corrosion behavior of high-alloy stainless steels

    SciTech Connect (OSTI)

    Pardo, A.; Otero, E.; Merino, M.C.; Lopez, M.D.; Utrilla, M.V.; Moreno, F.

    2000-04-01

    Localized corrosion resistance (pitting and crevice corrosion) of two high-alloy stainless steels (superduplex and superaustenitic) was studied in solutions with chloride concentrations of 200, 400, 600, and 6,000 ppm at pH values ranging from 2 to 6.5. Critical temperatures for pitting and crevice corrosion were calculated for these test media using electrochemical techniques (continuous current). From results obtained for cyclic polarization, the critical pitting temperature (CPT) and critical crevice temperature (CCT) of these materials in the different test media were determined. Under the tested conditions, the resistance of these materials to localized corrosion was very high. Only in test conditions of higher aggressivity (6,000 ppm CL{sup {minus}} and pH 6.5), pitting or crevice corrosion was observed. In those cases, values of pitting potential (E{sub pit}) and crevice potential (E{sub cre}) showed little tendency to decrease with an increase in CL{sup {minus}} concentration, temperature, and pH. Moreover, the CPT of these steels was determined in a ferric chloride (FeCl{sub 3}) medium, which corresponds to the standard ASTM G48 practice (Method A).

  6. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  7. The environmental chemical tributyltin chloride (TBT) shows both estrogenic and adipogenic activities in mice which might depend on the exposure dose

    SciTech Connect (OSTI)

    Penza, M.; Jeremic, M.; Marrazzo, E.; Maggi, A.; Ciana, P.; Rando, G.; Grigolato, P.G.; Di Lorenzo, D.

    2011-08-15

    Exposure during early development to chemicals with hormonal action may be associated with weight gain during adulthood because of altered body homeostasis. It is known that organotins affect adipose mass when exposure occurs during fetal development, although no knowledge of effects are available for exposures after birth. Here we show that the environmental organotin tributyltin chloride (TBT) exerts adipogenic action when peripubertal and sexually mature mice are exposed to the chemical. The duration and extent of these effects depend on the sex and on the dose of the compound, and the effects are relevant at doses close to the estimated human intake (0.5 {mu}g/kg). At higher doses (50-500 {mu}g/kg), TBT also activated estrogen receptors (ERs) in adipose cells in vitro and in vivo, based on results from acute and longitudinal studies in ERE/luciferase reporter mice. In 3T3-L1 cells (which have no ERs), transiently transfected with the ERE-dependent reporter plus or minus ER{alpha} or ER{beta}, TBT (in a dose range of 1-100 nM) directly targets each ER subtype in a receptor-specific manner through a direct mechanism mediated by ER{alpha} in undifferentiated preadipocytic cells and by ER{beta} in differentiating adipocytes. The ER antagonist ICI-182,780 inhibits this effect. In summary, the results of this work suggest that TBT is adipogenic at all ages and in both sexes and that it might be an ER activator in fat cells. These findings might help to resolve the apparent paradox of an adipogenic chemical being also an estrogen receptor activator by showing that the two apparently opposite actions are separated by the different doses to which the organism is exposed. - Research Highlights: > The environmental organotin tributyltin chloride shows dose-dependent estrogenic and adipogenic activities in mice. > The duration and extent of these effects depend on the sex and the dose of the compound. > The estrogenic and adipogenic effects of TBT occur at doses closed to

  8. Reactions of Ethyl Groups on a Model Chromia Surface: Ethyl Chloride on Stoichiometric Alpha-Cr2O3(1012)

    SciTech Connect (OSTI)

    Brooks, J.; Ma, Q; Cox, D

    2009-01-01

    The reaction of CH3CH2Cl over the nearly-stoichiometric ?-Cr2O3 (1 0 View the MathML source 2) surface yields gas phase CH2double bond; length as m-dashCH2, CH3CH3, H2 and surface chlorine adatoms. The decomposition reaction is initiated via C-Cl bond cleavage to give a surface ethyl (CH3CH2-) intermediate. A rate-limiting ?-hydride elimination from the surface ethyl species produces gas phase CH2double bond; length as m-dashCH2 and surface hydrogen atoms. Two parallel competing reactions form CH3CH3, via ?-hydride addition to remaining surface ethyl species (reductive elimination), and H2, via the combination of two surface hydrogen atoms. The chlorine freed from the dissociation of CH3CH2Cl binds at the five-coordinate surface Cr3+ sites on the stoichiometric surface and inhibits the surface chemistry via simple site blocking. No surface carbon deposition is observed from the thermal reaction of ethyl chloride, suggesting that ethyl intermediates are not primary coke forming intermediates in the dehydrogenation of ethane over (1 0 View the MathML source 2) facets of ?-Cr2O3.

  9. Highly chemoselective palladium-catalyzed conjugate reduction of. cap alpha. ,. beta. -unsaturated carbonyl compounds with silicon hydrides and zinc chloride cocatalyst

    SciTech Connect (OSTI)

    Keinan, E.; Greenspoon, N.

    1986-11-12

    A three-component system comprised of a soluble palladium catalyst, hydridosilane, and zinc chloride is capable of efficient conjugate reduction of ..cap alpha..,..beta..-unsaturated ketones and aldehydes. The optimal set of conditions includes diphenylsilane as the most effective hydride donor, any soluble palladium complex in either the O or II oxidation state, when it is stabilized by phosphine ligands, and ZnCl/sub 2/ as the best Lewis acid cocatalyst. The reaction is very general with respect to a broad range of unsaturated ketones and aldehydes, and it is highly selective for these Michael acceptors, as reduction of ..cap alpha..,..beta..-unsaturated carboxylic acid derivatives is very sluggish under these conditions. When dideuteriodiphenylsilane is used to reduce unsaturated ketones, deuterium is stereoselectivity introduced at the less-hindered fact of the substrate and regioselectively at the ..beta..-position. Conversely, when reductions are carried out in the presence of traces of D/sub 2/O, deuterium incorporation occurs at the ..cap alpha..-position. On the basis of deuterium-incorporation experiments and /sup 1/H NMR studies a catalytic cycle is postulated in which the first step involves reversible coordination of the palladium complex to the electron-deficient olefin and oxidative addition of silicon hydride to form a hydridopalladium olefin complex.

  10. Anisotropy Characterization of I-125 Seed with Attached Encapsulated Cobalt Chloride Complex Contrast Agent Markers for MRI-Based Prostate Brachytherapy

    SciTech Connect (OSTI)

    Frank, Steven J., E-mail: sjfrank@mdanderson.or [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Tailor, Ramesh C.; Kudchadker, Rajat J. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Martirosyan, Karen S. [Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX (United States); Stafford, R. Jason; Elliott, Andrew M. [Department of Imaging Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Swanson, David A. [Department of Urology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Sing, David; Choi, Jonathan [Department of Radiation Oncology, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States); Mourtada, Firas; Ibbott, Geoffrey S. [Department of Radiation Physics, University of Texas M. D. Anderson Cancer Center, Houston, TX (United States)

    2011-07-01

    We have developed a novel MRI marker for prostate brachytherapy. The purpose of this study was to evaluate the changes in anisotropy when cobalt chloride complex contrast agent encapsulated contrast agent markers (C4-ECAM) were placed adjacent to an iodine-125 (I-125) titanium seed, and to verify that the C4-ECAMs were visible on magnetic resonance imaging (MRI) after radiation exposure. Two C4-ECAMs were verified to be MRI visible in a phantom before radiation exposure. The C4-ECAMs were then attached to each end of a 12.7-U (10-mCi) I-125 titanium seed in a polymer tube. Anisotropy was measured and analyzed with the seed alone and with attached C4-ECAMs by suspending thermoluminescent dosimeters in a water phantom in 2 circles surrounding the radioactive source with radius of 1 or 2 cm. A T1-weighted MRI evaluation of C4-ECAMs was then performed after exposure to the amount of radiation typically delivered during 1 month of prostate brachytherapy. Measured values of the anisotropy function F(r, {theta}) for the I-125 seed with and without the C4-ECAMs were mutually statistically indistinguishable (standard error of the mean <4.2%) and agreed well with published TG-43 values for the bare seed. As expected, the anisotropy function {phi}{sub an}(r) for the 2 datasets (with and without C4-ECAMs) derived from the measured F(r, {theta}) did not exhibit statistically measurable difference. Both datasets showed agreement with the published TG-43 {phi}{sub an}(r) for the bare seed. The C4-ECAMs were well visualized by MRI after 1 month of radiation exposure. There were no changes in anisotropy when the C4-ECAMs were placed next to an I-125 radioactive seed, and the C4-ECAMs were visualized after radiation exposure.

  11. Gold(I) chloride adducts of 1,3-bis(di-2-pyridylphosphino)propane: synthesis, structural studies and antitumour activity

    SciTech Connect (OSTI)

    Humphreys, Anthony S.; Filipovska, Aleksandra; Berners-Price, Susan J.; Koutsantonis, George A.; Skelton, Brian W.; White, Allan H.

    2008-06-30

    The novel water soluble bidentate phosphine ligand 1,3-bis(di-2-pyridylphosphino)propane (d2pypp) has been synthesized by a convenient route involving treatment of 2-pyridyllithium with Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} and isolation in crystalline form as the hydrochloride salt. The synthesis of the precursor Cl{sub 2}P(CH{sub 2}){sub 3}PCl{sub 2} has been optimized by the use of triphosgene as the chlorinating agent. The 2:1 and 1:2 AuCl:d2pypp adducts have been synthesized and characterized by NMR spectroscopy and single crystal X-ray studies, and shown to be of the form (AuCl){sub 2}({mu}-d2pypp-P,P{prime}) and Au(d2pypp-P,P{prime}){sub 2}Cl(-3.75H{sub 2}O), respectively. The latter is more lipophilic than analogous 1:2 adducts of gold(I) chloride with the diphosphine ligands 1,2-bis(di-n-pyridylphosphino)ethane (dnpype) for n = 2, 3 and 4, based on measurement of the n-octanol-water partition coefficient (log P = -0.46). A single crystal structure determination of the 1:2 Au(I) complex of the 3-pyridyl ethane ligand shows it to be of the form [Au(d3pype-P,P{prime}){sub 2}]Cl {center_dot} 5H{sub 2}O. The in vitro cytotoxic activity of [Au(d2pypp){sub 2}]Cl was assessed in human normal and cancer breast cells and selective toxicity to the cancer cells found. The significance of these results to the antitumour properties of chelated 1:2 Au(I) diphosphine complexes is discussed.

  12. Cobalt chloride decreases fibroblast growth factor-21 expression dependent on oxidative stress but not hypoxia-inducible factor in Caco-2 cells

    SciTech Connect (OSTI)

    Liu, Yanlong; Department of Medicine, University of Louisville, Louisville, KY ; Wang, Chunhong; Department of Medicine, University of Louisville, Louisville, KY ; Wang, Yuhua; Department of Medicine, University of Louisville, Louisville, KY ; Ma, Zhenhua; Department of Medicine, University of Louisville, Louisville, KY ; Xiao, Jian; McClain, Craig; Department of Pharmacology and Toxicology, University of Louisville, Louisville, KY; Alcohol Research Center, University of Louisville, Louisville, KY; Robley Rex Veterans Affairs Medical Center, Louisville, KY ; Li, Xiaokun; Feng, Wenke; Department of Medicine, University of Louisville, Louisville, KY; Alcohol Research Center, University of Louisville, Louisville, KY

    2012-10-15

    Fibroblast growth factor-21 (FGF21) is a potential metabolic regulator with multiple beneficial effects on metabolic diseases. FGF21 is mainly expressed in the liver, but is also found in other tissues including the intestine, which expresses β-klotho abundantly. The intestine is a unique organ that operates in a physiologically hypoxic environment, and is responsible for the fat absorption processes including triglyceride breakdown, re-synthesis and absorption into the portal circulation. In the present study, we investigated the effects of hypoxia and the chemical hypoxia inducer, cobalt chloride (CoCl{sub 2}), on FGF21 expression in Caco-2 cells and the consequence of fat accumulation. Physical hypoxia (1% oxygen) and CoCl{sub 2} treatment decreased both FGF21 mRNA and secreted protein levels. Gene silence and inhibition of hypoxia-inducible factor-α (HIFα) did not affect the reduction of FGF21 mRNA and protein levels by hypoxia. However, CoCl{sub 2} administration caused a significant increase in oxidative stress. The addition of n-acetylcysteine (NAC) suppressed CoCl{sub 2}-induced reactive oxygen species (ROS) formation and completely negated CoCl{sub 2}-induced FGF21 loss. mRNA stability analysis demonstrated that the CoCl{sub 2} administration caused a remarkable reduction in FGF21 mRNA stability. Furthermore, CoCl{sub 2} increased intracellular triglyceride (TG) accumulation, along with a reduction in mRNA levels of lipid lipase, hormone sensitive lipase (HSL) and adipose triglyceride lipase (ATGL), and an increase of sterol regulatory element-binding protein-1c (SREBP1c) and stearoyl-coenzyme A (SCD1). Addition of both NAC and recombinant FGF21 significantly attenuated the CoCl{sub 2}-induced TG accumulation. In conclusion, the decrease of FGF21 in Caco-2 cells by chemical hypoxia is independent of HIFα, but dependent on an oxidative stress-mediated mechanism. The regulation of FGF21 by hypoxia may contribute to intestinal lipid metabolism and

  13. Storm-water characterization and lagoon sediment analysis, Grand Forks Air Force Base, North Dakota. Final report

    SciTech Connect (OSTI)

    Garland, J.G.; Vaughn, R.W.; Scott, P.T.

    1990-08-01

    Sampling was conducted in the wastewater treatment lagoons and stormwater runoff at Grand Forks AFB. The base was concerned about whether the unlined lagoons were creating a potential groundwater contamination problem and whether their stormwater runoff met North Dakota state stream standards. Lagoon sediment did not contain Extraction Procedure hazardous chemicals. Stormwater runoff exceeded state standards for boron, phosphates, and phenols and contained trace levels of methylene chloride. Characterization of lagoon influent showed it to be generally representative of domestic sewage, but also contained trace levels of boron, phenols, toluene, cyanide, chloroform, methylene chloride and ethyl benzene.

  14. Method of separating organic contaminants from fluid feedstreams with polyphosphazene membranes

    DOE Patents [OSTI]

    McCaffrey, Robert R. (Milford, MA); Cummings, Daniel G. (Idaho Falls, ID)

    1991-01-01

    A method is provided for separating halogenated hydrocarbons from a fluid feedstream. The fluid feedstream is flowed across a first surface of a polyphosphazene semipermeable membrane. At least one halogenated hydrocarbon from the fluid feedstream permeates through the polyphosphazene semipermeable membrane to a second opposed surface of the semipermeable membrane. Then the permeated polar hydrocarbon is removed from the second opposed surface of the polyphosphazene semipermeable membrane. Outstanding and unexpected separation selectivities on the order of 10,000 were obtained for methylene chloride when a methylene chloride in water feedstream was flowed across the polyphosphazene semipermeable membrane in the invented method.

  15. Sr{sub 4}Ru{sub 6}ClO{sub 18}, a new Ru{sup 4+/5+} oxy-chloride, solved by precession electron diffraction: Electric and magnetic behavior

    SciTech Connect (OSTI)

    Roussel, Pascal; Palatinus, Lukas; Belva, Frdric; Daviero-Minaud, Sylvie; Mentre, Olivier; Huve, Marielle

    2014-04-01

    The crystal structure of Sr{sub 4}Ru{sub 6}ClO{sub 18}, a new Ru{sup 4+/5+} oxo-chloride, has been determined from Precession Electron Diffraction (PED) data acquired on a nanocrystal in a transmission electron microscope using the technique of electron diffraction tomography. This approach is described in details following a pedagogic route and a systematic comparison is made of this rather new method with other experimental methods of electron diffraction, and with the standard single crystal X-ray diffraction technique. Both transport and magnetic measurements, showed a transition at low temperature that may be correlated to Ru{sup 4+}/Ru{sup 5+} charge ordering. - Graphical abstract: Structure of Sr{sub 4}Ru{sub 6}ClO{sub 18}, determined using Precession Electron Diffraction data. - Highlights: Structure of Sr{sub 4}Ru{sub 6}ClO{sub 18} was solved ab initio using precession electron diffraction. This was done both on a nanometric sample and on a micrometric one. Different type of experimental methods of electron diffraction are compared. Single crystal X-ray diffraction was used to confirm the results. Transport properties were characterized and show exotic behavior.

  16. Theoretical predictions of properties and volatility of chlorides and oxychlorides of group-4 elements. I. Electronic structures and properties of MCl{sub 4} and MOCl{sub 2} (M = Ti, Zr, Hf, and Rf)

    SciTech Connect (OSTI)

    Pershina, V.; Borschevsky, A.; Iliaš, M.

    2014-08-14

    Relativistic, infinite order exact two-component, density functional theory electronic structure calculations were performed for MCl{sub 4} and MOCl{sub 2} of group-4 elements Ti, Zr, Hf, and element 104, Rf, with the aim to predict their behaviour in gas-phase chromatography experiments. RfCl{sub 4} and RfOCl{sub 2} were shown to be less stable than their lighter homologs in the group, tetrachlorides and oxychlorides of Zr and Hf, respectively. The oxychlorides turned out to be stable as a bent structure, though the stabilization energy with respect to the flat one (C{sub 2v}) is very small. The trend in the formation of the tetrachlorides from the oxychlorides in group 4 is shown to be Zr < Hf < Rf, while the one in the formation of the oxychlorides from the chlorides is opposite. All the calculated properties are used to estimate adsorption energy of these species on various surfaces in order to interpret results of gas-phase chromatography experiments, as is shown in Paper II.

  17. Fluid diversion and sweep improvement with chemical gels in oil recovery processes. [Four types of gels: resorcinol-formaldehyde; colloidal silica; Cr sup 3+ (chloride)-xanthan; and Cr sup 3+ (acetate)-polyacrylamide

    SciTech Connect (OSTI)

    Seright, R.S.; Martin, F.D.

    1992-09-01

    The objectives of this project were to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants were examined, including polymer-based gelants, a monomer-based gelant, and a colloidal-silica gelant. This research was directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work examined how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals included determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. During this three-year project, a number of theoretical analyses were performed to determine where gel treatments are expected to work best and where they are not expected to be effective. The most important, predictions from these analyses are presented. Undoubtedly, some of these predictions will be controversial. However, they do provide a starting point in establishing guidelines for the selection of field candidates for gel treatments. A logical next step is to seek field data that either confirm or contradict these predictions. The experimental work focused on four types of gels: (1) resorcinol-formaldehyde, (2) colloidal silica, (3) Cr{sup 3+}(chloride)-xanthan, and (4) Cr{sup 3+}(acetate)-polyacrylamide. All experiments were performed at 41{degrees}C.

  18. Microbial reductive dehalogenation of vinyl chloride (Patent...

    Office of Scientific and Technical Information (OSTI)

    Inventors: Spormann, Alfred M. 1 ; Muller, Jochen A. 2 ; Rosner, Bettina M. 3 ; Von Abendroth, Gregory 4 ; Meshulam-Simon, Galit 5 ; McCarty, Perry L 1 + Show Author ...

  19. Microbial reductive dehalogenation of vinyl chloride (Patent...

    Office of Scientific and Technical Information (OSTI)

    Inventors: Spormann, Alfred M 1 ; Muller, Jochen A 2 ; Rosner, Bettina M 3 ; Von Abendroth, Gregory 4 ; Meshulam-Simon, Galit 5 ; McCarty, Perry L 1 + Show Author ...

  20. Sodium/nickel-chloride battery development

    SciTech Connect (OSTI)

    Redey, L.; Prakash, J.; Vissers, D.R.; Dowgiallo, E.J.

    1994-02-28

    The performance of the Ni/NiCl{sub 2} positive electrode for the Na/NiCl{sub 2} battery has been significantly improved compared to that of our earlier electrodes, representative for 1990. This improvement has been achieved by lowering the impedance and increasing the usable capacity through the use of chemical additives and a tailored electrode morphology. The improved electrode has excellent performance even at 250{degrees}C and can be recharged within one hour. The performance of this new electrode was measured by the conventional interrupted galvanostatic method and under simulated driving profiles. These measurements were used to project the performance of 40- to 60-kWh batteries built with this new electrode combined with the already highly developed sodium/{beta}{double_prime}-alumina negative electrode. These calculated results yielded a specific power of 150--400 W/kg and a specific energy of 110--200 Wh/kg for batteries with single-tube and bipolar cell designs. This high performance, along with the high cell voltage, mid-temperature operation, fast recharge capability, and short-circuited failure mode of the electrode couple, makes the Na/NiCl{sub 2} battery attractive for electric vehicle applications.

  1. Microbial reductive dehalogenation of vinyl chloride (Patent...

    Office of Scientific and Technical Information (OSTI)

    MLA APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Send to Email Send to Email Email address: Content: Close Send Cite: MLA Format Close Cite: APA Format ...

  2. Orientation imaging microscopy of polycrystalline sodium chloride

    SciTech Connect (OSTI)

    Staiger, M.P.; Kolbeinsson, I.; Newman, J.; Woodfield, T.; Sato, T.

    2010-04-15

    A novel preparation technique is described that makes possible grain size analysis of polycrystalline NaCl using orientation imaging microscopy via electron backscatter diffraction (EBSD). The preparation methodology is specifically developed to overcome difficulties in preparing microporous NaCl for microscopy. The grain size and crystallographic texture of polycrystalline NaCl samples, prepared via solution pressure and sintered in the range of 650-780 deg. C, were able to be measured successfully with EBSD. The limitations of the preparation technique for EBSD analysis of NaCl are also discussed.

  3. Microbial reductive dehalogenation of vinyl chloride (Patent...

    Office of Scientific and Technical Information (OSTI)

    Assignee: The Board of Trustees of the Leland Stanford Junior University (Palo Alto, CA) DOEEMSP Patent Number(s): 8,647,824 Application Number: 13294,927 Contract Number: ...

  4. Method of polymerizing exo-methylene cyclic organic compounds using homogeneous ring-opening catalysts

    DOE Patents [OSTI]

    Marks, Tobin J.; Yang, Xinmin; Jia, Li

    1994-01-01

    The regiospecific (1,2-Me.sub.2 C.sub.5 H.sub.3).sub.2 ZrMe.sup.+ MeB(C.sub.6 F.sub.5).sub.3.sup.- mediated ring-opening polymerization of methylenecyclobutane and its copolymerization with ethylene to polyolefins of microstructure--{CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.n and {--[CH.sub.2 CHR]--.sub.x [CH.sub.2 CH.sub.2 CH.sub.2 C(CH.sub.2)]--.sub.y }.sub.n' respectively, is disclosed.

  5. Molecular Quantum Mechanics 2010: From Methylene to DNA and Beyond Conference Support

    SciTech Connect (OSTI)

    2013-05-15

    This grant was $12500 for partial support of an international conference, Molecular Quantum Mechanics 2010, which was held on the campus of the University of California, Berkeley, from 24 to 29 May 2010. The conference involved more than 250 participants. The conference schedule ran from as early as 8:00 AM to as late as 10:30 PM at night, in order to accommodate six historical lectures, 16 plenary lectures, 42 invited talks and two very strong poster sessions containing 143 contributed posters. Since 1989, the Molecular Quantum Mechanics (MQM) series of international conferences has show- cased the frontiers of research in quantum chemistry with a strong focus on basic theory and algorithms, as well as highlights of topical applications. Both were strongly in evidence at MQM 2010. At the same time as embracing the future, the MQM conferences also honour the lifetime contributions of some of the most prominent scientists in the field of theoretical and computational quantum chemistry. MQM 2010 recognised the work of Prof. Henry F. ‘Fritz’ Schaefer of the Center for Computational Chemistry at the University of Georgia, who was previously on the faculty at Berkeley The travel of invited speakers was partially covered by sponsorships from Dell Computer, Hewlett-Packard, Journal of Chemical Theory and Computation, Virginia Tech College of Science, Molecular Physics, Q-Chem Inc and the American Institute of Physics. By contrast, the conference grant from the Department of Energy was used to provide fellowships and scholarships to enable graduate students and postdoctoral fellows to attend the meeting, and thereby broaden the participation of young scientists at a meeting where in the past most of the attendees have been more senior faculty researchers. We believe that we were very successful in this regard: 118 students and postdocs attended out of the total of 256 participants. In detail, the DOE sponsorship money was partially used for dormitory scholarships that covered the cost of shared accommodation for students and postdocs at Berkeley dormitories. This covered the $200-$305 cost of a shared room for the 5-day duration of the conference. The only condition of these scholarships was that the awardee must present a poster at the meeting. Approximately $7565 was spent for these dormitory scholarships. The remaining expenditures of $4800 was used for 12 merit scholarships which were awarded to students whose poster presentations were judged the best at the conference. This amount covered a significant part of their travel and registration fees.

  6. Method of polymerizing exo-methylene cyclic organic compounds using homogeneous ring-opening catalysts

    DOE Patents [OSTI]

    Marks, T.J.; Yang, X.; Jia, L.

    1994-04-05

    The regiospecific (1,2-Me[sub 2]C[sub 5]H[sub 3])[sub 2]ZrMe[sup +]MeB(C[sub 6]F[sub 5])[sub 3][sup [minus

  7. Parametric Optimization of the MEO Process for Treatment of Mixed Waste Residues

    SciTech Connect (OSTI)

    Cournoyer, M.E.; Smith, W.H.

    1999-02-28

    A series of bench-scale experiments were conducted to determine the optimum reaction conditions for destruction of styrene-divinyl benzene based cation resin and methylene chloride by the mediated electrochemical oxidation (MEO) process. Reaction parameters examined include choice of electron transfer mediator, reaction temperature and solvent system. For the cation exchange resins, maximum destruction efficiencies were obtained using cerium (IV) as mediator in nitric acid at a temperature of 70 C. Reasonable efficiencies were also realized with silver(II) and cobalt (III) at ambient temperature in the same solvent. Use of sulfuric acid as the solvent yielded much lower efficiencies under equivalent conditions. Methylene chloride was found to react only with silver (II) at ambient temperature in nitric acid media, cobalt (III) and cerium (IV) were totally ineffective. These results demonstrate a need to perform bench-scale experiments to determine optimum operating conditions for each organic substrate targeted for treatment by the MEO process.

  8. A [Cyclentetrakis(methylene)]tetrakis[2-hydroxybenzamide]Ligand That Complexes and Sensitizes Lanthanide(III) Ions

    SciTech Connect (OSTI)

    D'Aleo, Anthony; Xu, Jide; Do, King; Muller, Gilles; Raymond, Kenneth N.

    2009-04-30

    The synthesis of a cyclen derivative containing four isophthalamide groups (L{sup 1}) is described. The spectroscopic properties of the Ln(III) complexes of L{sup 1} (Ln = Gd, Tb, Yb, Eu) reveal changes of the UV/visible absorption, circular dichroism absorption, luminescence and circularly polarized luminescence properties. It is shown that at least two metal complex species are present in solution, whose relative amounts are pH dependent. When at pH > 8.0, an intense long lived emission is observed (for [L{sup 1}Tb] and [L{sup 1}Yb]) while at pH < 8.0, a weaker, shorter-lived species predominates. Unconventional Ln(III) emitters (Pr, Nd, Sm, Dy and Tm) were sensitized in basic solution, both in the visible and in the near infra-red, to measure the emission of these ions.

  9. Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera...

    Open Energy Info (EERE)

    volcanics are < 100,000 years. Authors Usha Rao, U. Fehn, R. T. D. Teng and Fraser E. Goff Published Journal Journal of Volcanology and Geothermal Research, 1996 DOI Not Provided...

  10. Viscosity and density tables of sodium chloride solutions (Technical...

    Office of Scientific and Technical Information (OSTI)

    Authors: Fair, J.A. ; Ozbek, H. 1 + Show Author Affiliations (comps.) comps. Publication Date: 1977-04-01 OSTI Identifier: 6765156 Report Number(s): DOETIC-11364 DOE Contract ...

  11. Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional...

    Open Energy Info (EERE)

    Hawaii Abstract Because of the complex geological and hydrological conditions and the virtual lack of thermal springs, regional geothermal investigations in Hawaii require the use...

  12. Thermal conductivity of aqueous sodium chloride solutions from...

    Office of Scientific and Technical Information (OSTI)

    Experimental values were converted where necessary to a set of consistent units of degree ... the correlation which reproduces the experimental data to +- 2% up to 80sup 0C. ...

  13. Redox flow batteries based on supporting solutions containing chloride

    DOE Patents [OSTI]

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

    2014-01-14

    Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

  14. Method for making a uranium chloride salt product

    DOE Patents [OSTI]

    Miller, William E.; Tomczuk, Zygmunt

    2004-10-05

    The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

  15. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests ...

  16. Thermophysical Properties of Sodium Nitrate and Sodium Chloride

    Office of Scientific and Technical Information (OSTI)

    The smaller the permeability, the more water is transferred into the saline environment. Effects of permeability on water flow are also complicated by effects of capillary pressure ...

  17. Localized Plasticity in the Streamlined Genomes of Vinyl Chloride...

    Office of Scientific and Technical Information (OSTI)

    in distinct genomic islands (GEIs) with different predicted integration sites, suggesting that these genes were acquired horizontally and independently by distinct mechanisms. ...

  18. Toluene pyrolysis studies and high temperature reactions of propargyl chloride

    SciTech Connect (OSTI)

    Kern, R.D.; Chen, H.; Qin, Z.

    1993-12-01

    The main focus of this program is to investigate the thermal decompositions of fuels that play an important role in the pre-particle soot formation process. It has been demonstrated that the condition of maximum soot yield is established when the reaction conditions of temperature and pressure are sufficient to establish a radical pool to support the production of polyaromatic hydrocarbon species and the subsequent formation of soot particles. However, elevated temperatures result in lower soot yields which are attributed to thermolyses of aromatic ring structures and result in the bell-shaped dependence of soot yield on temperature. The authors have selected several acyclic hydrocarbons to evaluate the chemical thermodynamic and kinetic effects attendant to benzene formation. To assess the thermal stability of the aromatic ring, the authors have studied the pyrolyses of benzene, toluene, ethylbenzene, chlorobenzene and pyridine. Time-of-flight mass spectrometry (TOF) is employed to analyze the reaction zone behind reflected shock waves. Reaction time histories of the reactants, products, and intermediates are constructed and mechanisms are formulated to model the experimental data. The TOF work is often performed with use of laser schlieren densitometry (LS) to measure density gradients resulting from the heats of various reactions involved in a particular pyrolytic system. The two techniques, TOF and LS, provide independent and complementary information about ring formation and ring rupture reactions.

  19. VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150o...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: DE-AC02-05CH11231 Resource Type: Conference Resource Relation: Conference: American Chemical Society 29th Southeast Regional Meeting, Tampa, FL, November 9-11, ...

  20. Redox flow batteries based on supporting solutions containing chloride

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang

    2015-07-07

    Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

  1. Redox flow batteries based on supporting solutions containing chloride

    SciTech Connect (OSTI)

    Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Nie, Zimin; Chen, Baowei; Zhang, Jianlu; Xia, Guanguang

    2015-09-01

    Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

  2. Stability of numerous novel potassium chlorides at high pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Weiwei; Oganov, Artem R.; Lobanov, Sergey S.; Stavrou, Elissaios; Goncharov, Alexander F.; Zhu, Qiang

    2016-05-23

    K-Cl is a simple system displaying all four main types of bonding, as it contains (i) metallic potassium, (ii) elemental chlorine made of covalently bonded Cl2 molecules held together by van der Waals forces, and (iii) an archetypal ionic compound KCl. The charge balance rule, assigning classical charges of “+1” to K and “–1” to Cl, predicts that no compounds other than KCl are possible. However, our quantum-mechanical variable-composition evolutionary simulations predict an extremely complex phase diagram, with new thermodynamically stable compounds K3Cl, K2Cl, K3Cl2, K4Cl3, K5Cl4, K3Cl5, KCl3 and KCl7. Of particular interest are 2D-metallic homologs Kn+1Cln, the presencemore » of positively charged Cl atoms in KCl7, and the predicted stability of KCl3 already at nearly ambient pressures at zero Kelvin. We have synthesized cubic Pm3¯n -KCl3 at 40–70 GPa and trigonal P3¯cl -KCl3 at 20–40 GPa in a laser-heated diamond anvil cell (DAC) at temperature exceeding 2000 K from KCl and Cl2. These phases were identified using in situ synchrotron X-ray diffraction and Raman spectroscopy. Lastly, upon unloading to 10 GPa, P3¯cl -KCl3 transforms to a yet unknown structure before final decomposition to KCl and Cl2 at near-ambient conditions.« less

  3. Thermophysical properties of sodium nitrate and sodium chloride...

    Office of Scientific and Technical Information (OSTI)

    ... Authors: Xu, Tianfu ; Pruess, Karsten Publication Date: 2001-10-01 OSTI Identifier: 790019 Report Number(s): LBNL--48913 R&D Project: 80BC01; TRN: US0200332 DOE Contract Number: ...

  4. Use of encapsulated zinc particles in a eutectic chloride salt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    agglomeration or other type of particle degradation. The measured enhancement in volumetric thermal storage capacity of the composite with just 10 vol% of coated Zn...

  5. VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150o...

    Office of Scientific and Technical Information (OSTI)

    the aid of an empirical equation to facilitate interpolation and computer calculations. ... Country of Publication: United States Language: English Subject: 99; COMPUTER ...

  6. Electrochemical studies of calcium chloride-based molten salt systems

    SciTech Connect (OSTI)

    Blanchard, T.P. Jr.

    1992-12-01

    Conductance and EMF studies of CaCl{sub 2}-based melts were performed in the temperature range 790--990 C. Conductivity data collected using magnesia tubes and capillaries showed deviations from the data recommended by the National Bureau of Standards. These deviations are attributed to the slow dissolution of magnesia by the CaCl{sub 2}-CaO melt. Conductivity data for molten CaCl{sub 2} using a pyrolytic boron nitride capillary were in reasonable agreement with the recommended data; however, undissolved CaO in CaCl{sub 2} may have caused blockage of the pyrolytic boron nitride capillary, resulting in fluctuations in the measured resistance. The utility of the AgCl/Ag reference electrode in CaCl{sub 2}-AgCl and CaCl{sub 2}-CaO-AgCl melts, using asbestos diaphragms and Vycor glass as reference half-cell membranes, was also investigated. Nernstian behavior was observed using both types of reference half-cell membranes in CaCl{sub 2}-AgCl melts. The AgCl/Ag reference electrode also exhibited Nernstian behavior in CaCl{sub 2}-CaO-AgCl melts using a Vycor reference half-cell membrane and a magnesia crucible. The use of CaCl{sub 2} as a solvent is of interest since it is used in plutonium metal purification, as well as various other commercial applications. 97 refs., 33 figs., 13 tabs.

  7. Testing of a model to estimate vapor concentration of various organic chemicals. Master's thesis

    SciTech Connect (OSTI)

    Bakalyar, S.M.

    1990-01-01

    A model developed by Dr. Parker C. Reist to predict the build-up and decay rates of vapor concentrations following a chemical spill and clean-up was tested. The chemicals tested were: acetone, butyl acetate, ethyl acetate, hexane, methylene chloride, methyl ethyl ketone, and toluene. The evaporation rates of these chemicals were determined both by prediction, using a model developed by I. Kawamura and D. Mackay, and empirically and these rates were used in the Reist model. Chamber experiments were done to measure actual building-up and decay of vapor concentrations for simulated spills and simulated clean-up.

  8. Production of permeable cellulose triacetate membranes

    DOE Patents [OSTI]

    Johnson, Bruce M.

    1986-01-01

    A phase inversion process for the preparation of cellulose triacetate (CTA) and regenerated cellulose membranes is disclosed. Such membranes are useful as supports for liquid membranes in facilitated transport processes, as microfiltration membranes, as dialysis or ultrafiltration membranes, and for the preparation of ion-selective electrodes. The process comprises the steps of preparing a casting solution of CTA in a solvent comprising a mixture of cyclohexanone and methylene chloride, casting a film from the casting solution, and immersing the cast film in a methanol bath. The resulting CTA membrane may then be hydrolyzed to regenerated cellulose using conventional techniques.

  9. Production of permeable cellulose triacetate membranes

    DOE Patents [OSTI]

    Johnson, B.M.

    1986-12-23

    A phase inversion process for the preparation of cellulose triacetate (CTA) and regenerated cellulose membranes is disclosed. Such membranes are useful as supports for liquid membranes in facilitated transport processes, as microfiltration membranes, as dialysis or ultrafiltration membranes, and for the preparation of ion-selective electrodes. The process comprises the steps of preparing a casting solution of CTA in a solvent comprising a mixture of cyclohexanone and methylene chloride, casting a film from the casting solution, and immersing the cast film in a methanol bath. The resulting CTA membrane may then be hydrolyzed to regenerated cellulose using conventional techniques.

  10. Process for the manufacture of 117Sn diethylenetriaminepentaacetic acids

    DOE Patents [OSTI]

    Srivastava, Suresh C.; Li, Zizhong; Meinken, George

    2003-01-01

    Novel methods are provided for the manufacture of .sup.117m Sn(Sn.sup.4+) DTPA. The method allows the use of DTPA, a toxic chelating agent, in an approximately 1:1 ratio to .sup.117m Sn(Sn.sup.4+) via either aqueous conditions, or using various organic solvents, such as methylene chloride. A pharmaceutical composition manufactured by the novel method is also provided, as well as methods for treatment of bone tumors and pain associated with bone cancer using the pharmaceutical composition of the invention.

  11. Health hazard evaluation report HETA 91-0292-2467, Magnetics Division of Spang and Company, Butler, Pennsylvania

    SciTech Connect (OSTI)

    Blade, L.M.; Bresler, F.T.

    1994-11-01

    In response to an employee request, an investigation was begun into possible exposures to paint, paint thinners, and Freon at the Magnetics Division of Spang and Company (SIC-3679), Butler, Pennsylvania. The division employed about 450 people and manufactured two types of magnetic cores used in a variety of electronic devices. Workers in the Tape Core Paint Room had experienced light headedness or fainted episodes. Only one sample contained measurable levels of 2-ethoxyethyl-acetate (111159) but the level was 0.25 parts per million (ppm), one half of the NIOSH recommended exposure limit for full shift time weighted average exposure. Methylene-chloride (75092) was detected in all but one of the air samples with levels ranging up to 35ppm. One personal breathing zone sample had a lead (7439921) concentration of 36 micrograms/cubic meter (microg/m3) which exceeded the OSHA action level for lead of 30 microg/m3. The paint booth exhaust systems appeared to be operating efficiently and there were good work practices among the painters. The authors conclude that workers were exposed to methylene-chloride, considered by NIOSH to be a potential occupational carcinogen. Exposures to lead and 2-ethoxyethyl-acetate may exceed the evaluation criteria. Some workers may experience symptoms when working near solvents and paints, even though the measured exposures were below the permissible exposure limits. The authors recommend that efforts be made to reduce exposures in the paint room.

  12. Macromolecular coal structure as revealed by novel diffusion tests

    SciTech Connect (OSTI)

    Peppas, N.A.; Olivares, J.; Drummond, R.; Lustig, S.

    1990-01-01

    The main goal of the present work was the elucidation of the mechanistic characteristics of dynamic transport of various penetrants (solvents) in thin sections of coals by examining their penetrant uptake, front swelling and stress development. An important objective of this work was the study of coal network structure in different thermodynamically compatible penetrants and the analysis of dynamic swelling in terms of present anomalous transport theories. Interferometry/polariscopy, surface image analysis and related techniques were used to quantify the stresses and solvent concentration profiles in these sections. Dynamic and equilibrium swelling behavior were correlated using the polar interaction contributions of the solvent solubility parameters. The penetrant front position was followed in thin coal sections as a function of time. The initial front velocity was calculated for various coals and penetrants. Our penetrant studies with thin coal section from the same coal sample but with different thickness show that within the range of 150 {mu}m to 1500{mu}m the transport mechanism of dimethyl formamide in the macromolecular coal network is non-Fickian. In fact, for the thickest samples the transport mechanism is predominately Case-II whereas in the thinner samples penetrant uptake may be diffusion-controlled. Studies in various penetrants such as acetone, cyclohexane, methanol, methyl ethyl ketone, toluene and methylene chloride indicated that penetrant transport is a non-Fickian phenomenon. Stresses and cracks were observed for transport of methylene chloride. 73 refs., 88 figs., 15 tabs.

  13. Characterization of Cerro Negro crude. Part II. Chemical analysis. [Project sponsored by Bartlesville Energy Technology Center and Institute de Tecnologico del Venezolana Petroleo

    SciTech Connect (OSTI)

    Sturm, G.P. Jr.; Grindstaff, Q.G.; Hirsch, D.E.; Scheppele, S.E.; Hazos, M.

    1981-09-01

    The cooperative research program is explained in Part I. An evaluation is presented of the resolution attained in the separation of a 425 to 550/sup 0/C petroleum distillate fraction according to compound classes using 2 chromatographic methods. Samples were separated by high performance liquid chromatography using 2 columns in series containing 2,4-dinitroanalinopropyl silica and silica, respectively. Initial elution was attained using 1% methylene chloride in pentane followed by a linear gradient up to 30% methylene chloride. In the 2nd method, developed in the American Petroleum Institute's Research Project 60, fractions designated as saturates, monoaromatics, diaromatics, and polyaromatics were collected froma dual silica/alumina column using step gradient elution with pentane, 5% benzene in pentane, 15% benzene in pentane, and 20% ethyl ether, 20% benzene, 60% methanol, followed by pure methanol. The results wil be used to evaluate the quality of the separation in terms of the success in producing fractions containing similar compound classes. 1 figure, 4 tables.

  14. Existing technology transfer report: analytical capabilities. Volume 2. Appendix A. [Methods and procedures for analysis

    SciTech Connect (OSTI)

    Tewari, K.C.

    1984-06-01

    This volume contains 10 attachments entitled: Monthly progress reports; Method CHN-4 (Carbon, Hydrogen and Nitrogen analysis by Perkin-Elmer elemental analyses); Method Oxygen-6 (oxygen analyzer); Method Nitrogen-8 (Low level nitrogen analysis by Perkin-Elmer 240 elemental analyzer); Method Sulfur-10 (sulfur analysis by oxidative microcoulometry); Method TGA-3 (thermogravimetric analysis of coal liquefaction products and process solvents); Method DSC-5 (Determination of glass transition temperature by differential scanning calorimetry); Method GC-1 (gas chromatography of Fischer-Tropsch products); Method GC-2 (gas chromatography of distillate products from coal liquefaction); Analytical Method No. 1160 (estimation of OH, NH, NH/sub 2/, concentration in methylene chloride soluble materials from SRC liquids); x-ray diffraction method for determining the orientation tendency in calcined coke; and evaluation of mass spectrometers.

  15. Treatment of VOCs in high strength wastes using an anaerobic expanded-bed GAC reactor

    SciTech Connect (OSTI)

    Narayanian, B.; Suidan, M.T.; Gelderloos, A.B.; Brenner, R.C.

    1993-01-01

    The potential of the expanded-bed granular activated carbon (GAC) anaerobic reactor in treating a high strength waste containing RCRA volatile organic compounds (VOCs) was studied. A total of six VOCs, methylene chloride, chlorobenzene, carbon tetrachloride, chloroform, toluene and tetrachloroethylene, were fed to the reactor in a high strength matrix of background solvents. Performance was evaluated. The reactor was found to effect excellent removal of all VOCs (97%). Chloroform, while itself removed at levels in excess of 97%, was found to inhibit the degradation of acetate and acetone, two of the background solvents. Without any source of chloroform in the feed, excellent COD removals were obtained in addition to near-complete removal of all the VOCs.

  16. Field test of a generic method for halogenated hydrocarbons: Semivost test at a chemical manufacturing facility. Final project report, August 1992-August 1993

    SciTech Connect (OSTI)

    McGaughey, J.F.; Bursey, J.T.; Merrill, R.G.

    1996-11-01

    The candidate methods for semivolatile organic compounds are SW-846 Sampling Method 0010 and Analytical Method 8270, which are applicable to stationary sources. Two field tests were conducted using quadruple sampling trains with dynamic spiking were performed according to the guidelines of EPA Method 301. The first field test was performed at a site with low levels of moisture. The second test reported here was conducted at a chemical manufacturing facility where chemical wastes were burned in a coal-fired boiler. Poor recoveries obtained for the spiked analytes at the second test were attributed to wet sorbent from the sampling train, use of methanol to effect complete transfer of wet sorbent from the sampling module, and use of extraction techniques which did not effect a complete separation of methylene chloride from methanol. A procedure to address problems with preparation of samples from Method 0010 is included in the report.

  17. Reduction of chlorinated solvents at the Y-12 Oak Ridge Plant

    SciTech Connect (OSTI)

    Thompson, L.M.; Simandl, R.F.; Richards, H.L.

    1989-11-01

    The Oak Ridge Y-12 Plant has been actively seeking replacements for chlorinated solvents for several years. The first step in the reduction program was the identification of the solvents and their usages. The four main solvents used at the plant include Freon, methyl chloroform, perchloroethylene, and methylene chloride. The main reduction has been in the use of perchloroethylene. Other significant reductions have occurred in the area of changing out vapor degreasers which utilized perchloroethylene or methyl chloroform. These degreasers were replaced with ultrasonic cleaners which utilize aqueous detergent for cleaning. Ultrasonic cleaning has many advantages, but the one disadvantage is that it requires a rinse step. Currently, the work on reduction of chlorinate solvents is focused on finding solvents which can be substituted for squirt bottle type applications. Concerns which were addressed when looking at replacement solvents were disposal, compatibility, and health effects.

  18. Product analysis from direct liquefaction of several high-moisture biomass feedstocks

    SciTech Connect (OSTI)

    Elliott, D.C.; Sealock, L.J. Jr.; Butner, R.S.

    1987-04-01

    Product analysis in support of the process development research in biomass direct liquefaction began at rudimentary level of determining solvent-soluble portions of the product. Analysis was soon extended to elemental analyses and proximate analyses, such as ash and moisture. Later, spectrometric analyses were performed followed by detailed chemical analyses used in conjunction with chromatographic separation techniques. At all stages of development, the significant differences in composition between the products of flash pyrolysis and high-pressure processing have been evident. While polar solvents are most effective for both products, less polar solvents such as methylene chloride and even benzene and toluene have been used as extractants for high-pressure product oils.

  19. Ammonium chloride complex formation during downstream microwave ammonia plasma treatment of parylene-C

    SciTech Connect (OSTI)

    Pruden, K.G.; Beaudoin, S.P.

    2005-11-15

    In this work, parylene-C is exposed to the effluent from a microwave ammonia plasma with a goal of producing primary amine groups on the parylene-C. These amine groups are desired as sites for the attachment of various biomolecules that will influence the biocompatibility of the parylene-C. Ammonia plasma treatment is an effective approach for creating amine species on polymers. In this work, attenuated total reflectance infrared spectroscopy studies showed that no primary amine groups resulted from this treatment of parylene-C. Instead, reactive nitrogen-bearing radicals from the plasma appear to have been complexed by chlorine in the polymer. The formation of these complexes scavenged nitrogen-bearing radicals from the plasma and prevented the formation of nitrogenous species, such as the desired primary amines, on the parylene-C. These results are consistent with results of ammonia plasma treatment of other chlorinated polymers and suggest that alternative approaches are required to create nitrogen-bearing species on parylene-C.

  20. The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zalupski, Peter R.; McDowell, Rocklan; Dutech, Guy

    2014-08-05

    Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces.more » The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.« less

  1. The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

    SciTech Connect (OSTI)

    Zalupski, Peter R.; McDowell, Rocklan; Dutech, Guy

    2014-08-05

    Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

  2. Chloride-free processing of aluminum scrap to recover by-product materials

    SciTech Connect (OSTI)

    Riley, W.D.; Jong, B.W.

    1995-12-31

    The US Bureau of Mines has developed technology to recover by-product materials from aluminum scrap using engineered scavenger compounds (ESC). ESCs are structural oxides with a channel or tunnel structure that allows them to hold ions of a specific sizes and charges. The scavenging reaction is easily reversible allowing the ESC to be recharged for continued use and the ion is recovered as an electrodeposit. Key features of this novel technology are: (a) ESC systems are designed to have a high degree of selectivity for a desired ionic species. (b) The recovered material requires little or no additional reprocessing prior to reuse. Two current uses for the ESC technology that are described in this paper are the removal and recycle of lithium (Li) from lithium aluminum (Li-Al) alloys; and, using ESCs as a replacement for the conventional demaging (magnesium removal) technology used by the secondary casting industry. Research indicates that the ESC technology proposed for both these applications has either distinct economic and/or environmental advantages over previously employed methods of recovering metal values from aluminum scrap.

  3. Revealing a New Conformational State in a Chloride/Proton Exchanger...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "CLC" transporters are secondary active-transport membrane proteins that catalyze the ... Since these membrane-protein crystals show wide variations in diffraction, the SAM ...

  4. Cuprous-chloride-modified nanoporous alumina membranes for ethylene-ethane separation

    SciTech Connect (OSTI)

    Lin, Y.S.; Wang, Y.; Ji, W.; Higgins, R.J.

    1999-06-01

    This paper reports an attempt to synthesize a CuCl-modified {gamma}-alumina membrane for separation of ethylene from ethane. CuCl was effectively coated in the 4 nm pore {gamma}-alumina top layers of disk-shaped and tubular alumina membranes by the reservoir method. Permeation of a single gas and binary mixture of ethylene and ethane was measured to characterize separation properties of the modified membranes. Pure ethylene permeance of the CuCl-modified membrane is 10--40% lower than that predicted from the pure ethane permeance by the Knudsen theory. This result is explained by a model based on the adsorbed layer of ethylene via {pi}-complexation. Such an adsorbed layer hinders the diffusion of ethylene in the nanopores of CuCl-modified {gamma}-alumina. Multiple gas permeation measurements on the CuCl-modified membranes show a separation factor for ethylene over ethane larger than the Knudsen value. This confirms a positive contribution of the surface flow of ethylene to the permeance of ethylene in the multiple gas permeation system. A maximum separation factor for ethylene over ethane of 1.4 is obtained for the CuCl-modified membrane at 60 C.

  5. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect (OSTI)

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  6. Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications

    SciTech Connect (OSTI)

    Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

    2013-04-22

    Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

  7. The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.

    SciTech Connect (OSTI)

    Peter Zalupski; Rocklan McDowell; Guy Dutech

    2014-10-01

    Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

  8. The dynamic shape factor of sodium chloride nanoparticles as regulated by drying rate

    SciTech Connect (OSTI)

    Wang, Z.; Lewis, E.; King, S. M.; Freney, E.; Rosenoern, T.; Smith, M.; Chen, Q.; Kuwata, M.; Poschl, U.; Wang, W.; Buseck, P. R.; Martin, S. T.

    2010-09-01

    The influence of drying rate on the dynamic shape factor {chi} of NaCl particles was investigated. The drying rate at the efflorescence relative humidity (ERH) of 45% was controlled in a laminar flow tube and varied from 5.5 {+-} 0.9 to 101 {+-} 3 RH s{sup -1} at ERH, where RH represents one percent unit of relative humidity. Dry particles having mobility diameters of 23-84 nm were studied, corresponding to aqueous particles of 37-129 nm at the RH (57%) prior to drying. At each mobility diameter and drying rate, the critical supersaturation of cloud-condensation activation was also measured. The mobility diameter and the critical supersaturation were combined in an analysis to determine the value of {chi}. The measured values varied from 1.02 to 1.26. For fixed particle diameter the {chi} value decreased with increasing drying rate. For fixed drying rate, a maximum occurred in {chi} between 35- and 40-nm dry mobility diameter, with a lower {chi} for both smaller and larger particles. The results of this study, in conjunction with the introduced apparatus for obtaining quantified drying rates, can allow the continued development of a more detailed understanding of the morphology of submicron salt particles, with the potential for the follow-on development of quantitative modeling of evaporation and crystal growth at these dimensions.

  9. Ultraviolet-B radiation enhancement in dielectric barrier discharge based xenon chloride exciplex source by air

    SciTech Connect (OSTI)

    Gulati, P.; Prakash, R.; Pal, U. N.; Kumar, M.; Vyas, V.

    2014-07-07

    A single barrier dielectric barrier discharge tube of quartz with multi-strip Titanium-Gold (Ti-Au) coatings have been developed and utilized for ultraviolet-B (UV-B) radiation production peaking at wavelength 308 nm. The observed radiation at this wavelength has been examined for the mixtures of the Xenon together with chlorine and air admixtures. The gas mixture composition, chlorine gas content, total gas pressure, and air pressure dependency of the UV intensity, has been analyzed. It is found that the larger concentration of Cl{sub 2} deteriorates the performance of the developed source and around 2% Cl{sub 2} in this source produced optimum results. Furthermore, an addition of air in the xenon and chlorine working gas environment leads to achieve same intensity of UV-B light but at lower working gas pressure where significant amount of gas is air.

  10. Petrographic evidence of calcium oxychloride formation in mortars exposed to magnesium chloride solution

    SciTech Connect (OSTI)

    Sutter, Lawrence . E-mail: cee@mtu.edu; Peterson, Karl . E-mail: cee@mtu.edu; Touton, Sayward . E-mail: cee@mtu.edu; Van Dam, Tom . E-mail: cee@mtu.edu; Johnston, Dan . E-mail: Dan.Johnston@state.sd.us

    2006-08-15

    Many researchers have reported chemical interactions between CaCl{sub 2} and MgCl{sub 2} solutions and hardened Portland cement paste. One potentially destructive phase reported in the literature is calcium oxychloride (3CaO.CaCl{sub 2}.15H{sub 2}O). In the past, limited numbers of researchers have reported identification of this phase by X-ray diffraction. In this work, petrographic evidence of oxychloride formation is presented based on optical microscopy, scanning electron microscopy and microanalysis. This evidence indicates that calcium oxychloride does form in mortars exposed to MgCl{sub 2} solutions.

  11. Immobilization of chloride-rich radioactive wastes produced by pyrochemical operations

    SciTech Connect (OSTI)

    McDaniel, E.W.; Terry, J.W.

    1997-08-01

    A a result of its former role as a producer of nuclear weapons components, the Rocky Flats Environmental Technology Site (RFETS), Golden, Colorado accumulated a variety of plutonium-contaminated materials. When the level of contamination exceeded a predetermined level (the economic discard limit), the materials were classified as residues rather than waste and were stored for later recovery of the plutonium. Although large quantities of residues were processed, others, primarily those more difficult to process, remain in storage at the site. It is planned for the residues with lower concentrations of plutonium to be disposed of as wastes at an appropriate disposal facility, probably the Waste Isolation Pilot Plant (WIPP). Because the plutonium concentration is too high or because the physical or chemical form would be difficult to get into a form acceptable to WIPP, it may not be possible to dispose of a portion of the residues at WIPP. The pyrochemical salts are among the residues that are difficult to dispose of. For a large percentage of the pyrochemical salts, safeguards controls are required, but WIPP was not designed to accommodate safeguards controls. A potential solution would be to immobilize the salts. These immobilized salts would contain substantially higher plutonium concentrations than is currently permissible but would be suitable for disposal at WIPP. This document presents the results of a review of three immobilization technologies to determine if mature technologies exist that would be suitable to immobilize pyrochemical salts: cement-based stabilization, low-temperature vitrification, and polymer encapsulation. The authors recommend that flow sheets and life-cycle costs be developed for cement-based and low-temperature glass immobilization.

  12. Development of Mercury and Hydrogen Chloride Emission Monitors for Coal Gasifiers

    SciTech Connect (OSTI)

    G. Norton; D. Eckels; C. Chriswell

    2001-02-26

    The gas conditioning issues involved with coal gasification streams are very complex and do not have simple solutions. This is particularly true in view of the fact that the gas conditioning system must deal with tars, high moisture contents, and problems with NH{sub 3} without affecting low ppb levels of Hg, low levels (low ppm or less) of HCl, or the successful operation of conditioner components and analytical systems. Those issues are far from trivial. Trying to develop a non-chemical system for gas conditioning was very ambitious in view of the difficult sampling environment and unique problems associated with coal gasification streams. Although a great deal was learned regarding calibration, sample transport, instrumentation options, gas stream conditioning, and CEM design options, some challenging issues still remain. Sample transport is one area that is often not adequately considered. Because of the gas stream composition and elevated temperatures involved, special attention will need to be given to the choice of materials for the sample line and other plumbing components. When using gas stream oxidation, there will be sample transport regions under oxidizing as well as reducing conditions, and each of those regions will require different materials of construction for sample transport. The catalytic oxidation approach worked well for removal of tars and NH{sub 3} on a short term basis, but durability issues related to using the catalyst tube during extended testing periods still require study.

  13. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; Meinhardt, Kerry D.; Chang, Hee -Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

    2016-02-11

    Here we demonstrate for the first time that planar Na-NiCl2 batteries can be operated at an intermediate temperature of 190°C with ultra-high energy density. A specific energy density of 350 Wh/kg, which is 3 times higher than that of conventional tubular Na-NiCl2 batteries operated at 280°C, was obtained for planar Na-NiCl2 batteries operated at 190°C over a long-term cell test (1000 cycles). The high energy density and superior cycle stability are attributed to the slower particle growth of the cathode materials (NaCl and Ni) at 190°C. The results reported in this work demonstrate that planar Na-NiCl2 batteries operated at anmore » intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.« less

  14. EVIDENCE OF CORROSIVE GAS FORMED BY RADIOLYSIS OF CHLORIDE SALTS IN PLUTONIUM-BEARING MATERIALS

    SciTech Connect (OSTI)

    Dunn, K.; Louthan, M.

    2010-02-01

    Corrosion and pitting have been observed in headspace regions of stainless steel containers enclosing plutonium oxide/salt mixtures. These observations are consistent with the formation of a corrosive gas, probably HCl, and transport of that gas to the headspace regions of sealed containers. The NH{sub 4}Cl films found on the walls of the sealed containers is also indicative of the presence of HCl gas. Radiolysis of hydrated alkaline earth salts is the probable source of HCl.

  15. Flow and morphological conditions associated with the directional solidification of aqueous ammonium chloride

    SciTech Connect (OSTI)

    Magirl, C.S.; Incropera, F.P.

    1993-01-01

    Using 27% aq. NH[sub 4]Cl solutions as transparent analog, shadowgraphy and dye injection were used to observe flow and morphology in unidirectional solidification (UDS) from below. Dendritic crystals that form at the cold surface reject lighter, solute-deficient fluid, and instability is shown by finger-type double-diffusive convection. As the mushy two-phase region grows, perturbations at the liquidus interface cause localized remelting and downward development of channels. Solsutal plumes emanate from the channels, and in time, double-diffusive convection layers also form in the melt. When the solution is chilled at the sides as well as at the bottom, conditions are influenced by detachment and settling of crystals from the sidewall and by plumes from slanted channels. When a slow, oscillatory rocking motion is imposed on UDS, the freckle-type segregates in the final cast is suppressed. Within the melt, plumes and double-diffusive convection are eliminated. Inertially induced convection mixes the melt and produces a dense slurry. Although channels are eliminated from the bottom mushy region, overall heat transfer and macrosegregation in the cavity are unaffected by the slow rocking. Numerical simulations qualitatively predict trends in the field variables and provide insights on interdendritic flows and macrosegregation (freckle-, A-type segregates), although its quantitative predictions are hampered by simplifying assumptions.

  16. Flow and morphological conditions associated with the directional solidification of aqueous ammonium chloride. Annual performance report

    SciTech Connect (OSTI)

    Magirl, C.S.; Incropera, F.P.

    1993-01-01

    Using 27% aq. NH{sub 4}Cl solutions as transparent analog, shadowgraphy and dye injection were used to observe flow and morphology in unidirectional solidification (UDS) from below. Dendritic crystals that form at the cold surface reject lighter, solute-deficient fluid, and instability is shown by finger-type double-diffusive convection. As the mushy two-phase region grows, perturbations at the liquidus interface cause localized remelting and downward development of channels. Solsutal plumes emanate from the channels, and in time, double-diffusive convection layers also form in the melt. When the solution is chilled at the sides as well as at the bottom, conditions are influenced by detachment and settling of crystals from the sidewall and by plumes from slanted channels. When a slow, oscillatory rocking motion is imposed on UDS, the freckle-type segregates in the final cast is suppressed. Within the melt, plumes and double-diffusive convection are eliminated. Inertially induced convection mixes the melt and produces a dense slurry. Although channels are eliminated from the bottom mushy region, overall heat transfer and macrosegregation in the cavity are unaffected by the slow rocking. Numerical simulations qualitatively predict trends in the field variables and provide insights on interdendritic flows and macrosegregation (freckle-, A-type segregates), although its quantitative predictions are hampered by simplifying assumptions.

  17. Purificaiton of Lanthanides for Large Neutrino Detectors: Thorium Removal from Gadolinium Chloride

    SciTech Connect (OSTI)

    Yeh, M.; Cumming, J.B.; Hans, S.; Hahn, R.L.

    2010-06-01

    Metal-loaded liquid scintillators are the detectors of choice for various neutrino experiments. Procedures have been developed to transfer metals into organic liquids by solvent extraction or direct dissolution of a metallic compound. Traces of natural radioactivity introduced into the scintillator with the metal may produce undesirable backgrounds. Measurements using a {sup 229}Th tracer indicate that the inclusion of a pH-controlled partial hydrolysis and filtration prior to the preparation of a gadolinium-loading compound can reduce thorium by a factor of {approx}100. This 'self-scavenging' procedure has the advantage that it uses only reagents encountered in the production process. Addition of non-elemental scavengers such as iron, or the use of solvent extraction or ion exchange procedures can be avoided. It also improves the optical transmission in the blue region by removing traces of iron. This purification method has potential applications to the large-scale production of other metal-loaded liquid scintillators and for the removal of traces of thorium in the industrial production of lanthanides.

  18. Cationic quaternization of cellulose with methacryloyloxy ethyl trimethyl ammonium chloride via ATRP method

    SciTech Connect (OSTI)

    Supeno; Daik, Rusli; El-Sheikh, Said M.

    2014-09-03

    The synthesis of a cationic cellulose copolymer from cellulose macro-initiator (MCC-BiB) and quaternary compound monomer (METMA) via atom transfer radical polymerization (ATRP) was studied. By using dimethylformamide (DMF), the optimum condition for successful synthesis was at the mole ratio of MCC-BIB:Catalyst:METMA = 1:1:26. The highest copolymer recovery was 93.2 % for 6 h and at 40°C. The copolymer was insoluble in weak polar solvents such as THF and DMF but soluble in methanol and water. The chemistry of cellulose copolymer was confirmed by the FTIR and TGA in which the METMA monomer was used as a reference. The absence of CC bond in the CiB-g-METMA spectrum indicated that graft copolymerization occurred.

  19. Correlations between structure, spectra, and thermodynamics in solutions of cobalt chloride in sodium tetrachloroaluminates

    SciTech Connect (OSTI)

    Newman, D.S.; Tumidajski, P.J.; Blander, M.

    1990-01-01

    An EMF technique using the cell Co/CoCl{sub 2} {minus} Na AlCl{sub 4}//(AgCl)x {minus} NaAlCl{sub 4} (x fixed)/Ag was used to measure the solubility of CoCl{sub 2} in NaCl{center dot}AlCl{sub 3} melts. The changes in EMF as a function of changes in melt composition were correlated with changes in the UV-Vis spectra of the dissolved cobalt species. From these data the microscopic structural contributions to the macroscopic thermodynamic properties of the solutions were estimated. 14 refs., 5 figs., 1 tab.

  20. Heavy Oil Process Monitor: Automated On-Column Asphaltene Precipitation and Re-Dissolution

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani; Mark Sanderson

    2007-03-31

    An automated separation technique was developed that provides a new approach to measuring the distribution profiles of the most polar, or asphaltenic components of an oil, using a continuous flow system to precipitate and re-dissolve asphaltenes from the oil. Methods of analysis based on this new technique were explored. One method based on the new technique involves precipitation of a portion of residua sample in heptane on a polytetrafluoroethylene-packed (PTFE) column. The precipitated material is re-dissolved in three steps using solvents of increasing polarity: cyclohexane, toluene, and methylene chloride. The amount of asphaltenes that dissolve in cyclohexane is a useful diagnostic of the thermal history of oil, and its proximity to coke formation. For example, about 40 % (w/w) of the heptane asphaltenes from unpyrolyzed residua dissolves in cyclohexane. As pyrolysis progresses, this number decrease to below 15% as coke and toluene insoluble pre-coke materials appear. Currently, the procedure for the isolation of heptane asphaltenes and the determination of the amount of asphaltenes soluble in cyclohexane spans three days. The automated procedure takes one hour. Another method uses a single solvent, methylene chloride, to re-dissolve the material that precipitates on heptane on the PTFE-packed column. The area of this second peak can be used to calculate a value which correlates with gravimetric asphaltene content. Currently the gravimetric procedure to determine asphaltenes takes about 24 hours. The automated procedure takes 30 minutes. Results for four series of original and pyrolyzed residua were compared with data from the gravimetric methods. Methods based on the new on-column precipitation and re-dissolution technique provide significantly more detail about the polar constituent's oils than the gravimetric determination of asphaltenes.

  1. Sanitary Landfill Groundwater Monitoring Report, Fourth Quarter 1999 and 1999 Summary

    SciTech Connect (OSTI)

    Chase, J.

    2000-03-13

    A maximum of thirty eight-wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill Area at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Iron (Total Recoverable), Chloroethene (Vinyl Chloride) and 1,1-Dichloroethane were the most widespread constituents exceeding the Final Primary Drinking Water Standards during 1999. Trichloroethylene, 1,1-Dichloroethylene, 1,2-Dichloroethane, 1,4-Dichlorobenzene, Aluminum (Total Recoverable), Benzene, cis-1,2-Dichloroethylene, Dichlorodifluoromethane, Dichloromethane (Methylene Chloride), Gross Alpha, Mercury (Total Recoverable), Nonvolatile Beta, Tetrachloroethylene, Total Organic Halogens, Trichlorofluoromethane, Tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill is to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 144.175 ft/year during first quarter 1999 and 145.27 ft/year during fourth quarter 1999.

  2. A study of the effect of chloride on mercury removal in a fluidized bed combustion (FBC) system

    SciTech Connect (OSTI)

    Liu, K.; Gao, Y.; Li, F.; Pan, W.P.; Riley, J.T.; Mehta, A.K.; Ho, K.K.; Smith, S.R.

    2000-07-01

    Mercury exists in three forms, which are elemental mercury, inorganic mercury compounds, and organic mercury. Each form of mercury has a very different exposure potential. Oxidized mercury is soluble and has a tendency to associate with particles. Nearly all the post-combustion flue gas cleaning systems proposed to remove mercury may be categorized as either scrubbers or adsorbers. Therefore, the mercury sink in the cleaning system will be either the excess water of a wet scrubber or the mercury laden sorbent from an absorber. The major problem for post-combustion mercury capture systems is capturing the practically water-insoluble elemental mercury. Co-firing with high chlorine coal or RDF in utility boiler systems can provide an HCI atmosphere for the oxidation of elemental mercury in flue gas at relatively low temperatures (500--600 C). The objective of this study is to increase the efficiency of mercury emission cleaning methods by using HCl to convert elemental mercury to oxidized mercury species at low monetary costs and lower other toxic air emissions. When high chlorine (0.3--0.5%) coals were burned and a high intensity vortex flow (from secondary air) was used, around 70% of the total mercury in the fuel was condensed and absorbed by the fly ash (including calcium compounds). The remaining 30% of total fuel mercury was emitted in the gas phase in the flue gas. As for the gas phase mercury, about 98% of it exists in an oxidized form with a higher boiling temperature than elemental mercury and can be easily captured by an ESP or FGP apparatus. Only about 0.5% of the total fuel mercury was released to the atmosphere in elemental form.

  3. Actinide Corroles: Synthesis and Characterization of Thorium(IV) and Uranium(IV) bis(-chloride) Dimers

    SciTech Connect (OSTI)

    Ward, Ashleigh L.; Buckley, Heather L.; Gryko, Daniel T.; Lukens, Wayne W.; Arnold, John

    2013-12-01

    The first synthesis and structural characterization of actinide corroles is presented. Thorium(IV) and uranium(IV) macrocycles of Mes2(p-OMePh)corrole were synthesised and characterized by single-crystal X-ray diffraction, UV-Visible spectroscopy, variable-temperature 1H NMR, ESI mass spectrometry and cyclic voltammetry.

  4. Mechanical properties and microstructures of a magnesium alloy gas tungsten arc welded with a cadmium chloride flux

    SciTech Connect (OSTI)

    Zhang, Z.D.; Liu, L.M. Shen, Y.; Wang, L.

    2008-01-15

    Gas tungsten arc (GTA) welds were prepared on 5-mm thick plates of wrought magnesium AZ31B alloy, using an activated flux. The microstructural characteristics of the weld joint were investigated using optical and scanning microscopy, and the fusion zone microstructure was compared with that of the base metal. The elemental distribution was also investigated by electron probe microanalysis (EPMA). Mechanical properties were determined by standard tensile tests on small-scale specimens. The as-welded fusion zone prepared using a CdCl{sub 2} flux exhibited a larger grain size than that prepared without flux; the microstructure consisted of matrix {alpha}-Mg, eutectic {alpha}-Mg and {beta}-Al{sub 12}Mg{sub 17}. The HAZ was observed to be slightly wider for the weld prepared with a CdCl{sub 2} flux compared to that prepared without flux; thus the tensile strength was lower for the flux-prepared weld. The fact that neither Cd nor Cl was detected in the weld seam by EPMA indicates that the CdCl{sub 2} flux has a small effect on convection in the weld pool.

  5. Kinetics and mechanism of the outer-sphere oxidation of metal carbonyl anions with coordination complexes containing chloride

    SciTech Connect (OSTI)

    Lai, C.K.; Corraine, M.S.; Atwood, J.D.

    1992-02-01

    Reactions of metal carbonyl anions, CpFe(CO){sub 2}{sup -}, Re(CO){sub 5}{sup -}, Mn(CO){sub 5}{sup -}, CpMo(CO){sub 3}{sup -}, CpCr(CO){sub 3}{sup -}, and Co(CO){sub 4}{sup -}, with CrCl{sub 3}{center_dot}3S (S = THF, CH{sub 3}CN) and reactions of Mn(CO){sub 5}{sup -} and Re(CO){sub 5}{sup -} with [Co(o-phen){sub 2}Cl{sub 2}]CIO{sub 4} are reported. Net oxidation/reduction chemistry is observed with formation of metal carbonyl dimers and CrCl{sub 2}{center_dot}4S or Co(o-phen){sub 2}Cl{sub 2}. Metal carbonyl halides are also observed and shown to arise from a secondary reaction of the metal carbonyl dimer with the oxidant. The products and rates are most consistent with outer-sphere electron-transfer reactions. Reactions of CpFe(CO){sub 2}{sup -} with CpFe(CO){sub 2}X (X = Cl, Br, I) are also reported. The rate dependence on X is very small and in the order expected for nucleophilic substitution. 21 refs. 1 fig., 4 tabs.

  6. Chloride-dependent acceleration of cell cycle via modulation of Rb and cdc2 in osteoblastic cells

    SciTech Connect (OSTI)

    Maki, Masahiro; Miyazaki, Hiroaki; Nakajima, Ken-ichi; Yamane, Junko; Niisato, Naomi; Morihara, Toru; Kubo, Toshikazu; Marunaka, Yoshinori

    2007-10-05

    In the present study, we investigated if Cl{sup -} regulates the proliferation of the MC3T3-E1 osteoblastic cells. The proliferation of MC3T3-E1 osteoblastic cells was diminished by lowering the extracellular Cl{sup -} concentration ([Cl{sup -}]{sub o}) in the culture medium. The lowered in [Cl{sup -}]{sub o} increased the periods of the G{sub 0}/G{sub 1} and the G{sub 2}/M phases in cell cycle. We further studied the effects of [Cl{sup -}]{sub o} on the key enzymes, Rb and cdc2, playing key roles in checking points of the G{sub 0}/G{sub 1} and the G{sub 2}/M phases in cell cycle. The lowered in [Cl{sup -}]{sub o} diminished the active forms of enzymes, Rb and cdc2. We further found that the action of lowered [Cl{sup -}]{sub o} on the cell proliferation, the cell cycle, Rb and cdc2 was abolished by the presence of 2 mM glutamine, but not by that of pyruvate as another Krebs cycle substrate. Taken together, these observations indicate here for the first time that Cl{sup -} modulates Rb and cdc2, enhancing the proliferation of the MC3T3-E1 osteoblastic cells.

  7. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

  8. Time-course analysis of the Shewanella amazonensis SB2B proteome in response to sodium chloride shock

    SciTech Connect (OSTI)

    Parnell, John J.; Callister, Stephen J.; Rompato, Giovanni; Nicora, Carrie D.; Pasa-Tolic, Ljiljana; Williamson, Ashley; Pfrender, Michael E.

    2011-06-29

    Organisms in the genus Shewanella have become models for response to environmental stress. One of the most important environmental stresses is change in osmolarity. In this study, we experimentally determine the response mechanisms of Shewanella amazonensis SB2B during osmotic stress. Osmotic stress in SB2B was induced through exposure to NaCl, and the time-course proteomics response was measured using liquid chromatography mass spectrometry. Protein trends were qualitatively compared to gene expression trends and to phenotypic characterization. Osmotic stress affects motility, and has also been associated with a change in the membrane fatty acid composition (due to induction of branched chain amino acid degradation pathways); however, we show this is not the case for SB2B. Although proteins and genes involved with branched chain amino acid degradation are induced, fatty acid degradation pathways are not induced and no change in the fatty acid profile occurs in SB2B as a result of osmotic shock. The most extensive response of SB2B over the time course of acclimation to high salt involves an orchestrated sequence of events comprising increased expression of signal transduction associated with motility and restricted cell division and DNA replication. After SB2B has switched to increased branched chain amino acid degradation, motility, and cellular replication proteins return to pre-perturbed levels.

  9. Structural response in FeCl2 (iron chloride) to pressure-induced electro-magnetic transitions

    SciTech Connect (OSTI)

    Taylor, R D; Rozenberg, G Kh; Pasternak, M P; Gorodetsky, P; Xu, W M; Dubrovinsky, L S; Le Bihan, T L

    2009-01-01

    High pressure (HP) synchrotron x-ray diffraction studies were carried out in FeCl{sub 2} together with resistivity (R) studies, at various temperatures and pressures to 65 GPa using diamond anvil cells. This work follows a previous HP {sup 57}Fe Mossbauer study in which two pressure-induced (PI) electronic transitions were found interpreted as: (i) quenching of the orbital-term contribution to the hyperfine field concurring with a tilting of the magnetic moment by 55 degrees and (ii) collapse of the magnetism concurring with a sharp decrease of the isomer shift (IS). The R(P,T) studies affirm that the cause the collapse of the magnetism is a PI p-d correlation breakdown, leading to an insulator-metal transition at {approx}45 GPa and is not due to a spi-Ir,crossover (S=2 {yields} S=0). The structure response to the pressure evolution of the two electronic phase transitions starting at low pressures (LP), through an intermediate phase (IP) 30-57 GPa, and culminating in a high-pressure phase (HP), P >32 GPa, can clearly be quantified. The IP-HP phases coexist through the 32-57 GPa range in which the HP abundance increases monotonically at the expense of the IP phase. At the LP-IP interface no volume change is detected, yet the c-axis increases and the a-axis shrinks by 0.21 Angstroms and 0.13 Angstroms, respectively. The fit of the equation of state of the combined LP-IP phases yields a bulk modulus K{sub 0} = 35.3(1.8) GPa. The intralayer CI-CI distances increases, but no change is observed in Fe-CI bond-length nor are there substantial changes in the interlayer spacing. The pressure-induced electronic IP-HP transition leads to a first-order structural phase transition characterized by a decrease in Fe-CI bond length and an abrupt drop in V(P) by {approx}3.5% accompanying the correlation breakdown. In this transition no symmetry change is detected,and the XRD data could be satisfactorily fitted with the CdI{sub 2} structure. The bulk modulus of the HP phase is practically the same as that of the LP-IP phases suggesting negligible changes in the phonon density of state.

  10. EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposal to advance Oxyhydrochlorination technology to an integrated engineering-scale process.

  11. Application and results of whole-body autoradiography in distribution studies of organic solvents

    SciTech Connect (OSTI)

    Bergman, K.

    1983-01-01

    With the growing concern for the health hazards of occupational exposure to toxic substances attention has been focused on the organic solvents, which are associated with both deleterious nervous system effects and specific tissue injuries. Relatively little is known about the distribution of organic solvents and their metabolites in the living organism. Knowledge of the specific tissue localizations and retention of solvents and solvent metabolites is of great value in revealing and understanding the sites and mechanisms of organic solvent toxicity. Whole-body autoradiography has been modified and applied to distribution studies of benzene, toluene, m-xylene, styrene, methylene chloride, chloroform, carbon tetrachloride, trichloroethylene and carbon disulfide. The high volatility of these substances has led to the development of cryo-techniques. Whole-body autoradiographic techniques applicable to the study of volatile substances are reviewed. The localizations of nonvolatile solvent metabolites and firmly bound metabolites have also been examined. The obtained results are discussed in relation to toxic effects and evaluated by comparison with other techniques used in distribution studies of organic solvents and their metabolites.

  12. HEAVY OIL PROCESS MONITOR: AUTOMATED ON-COLUMN ASPHALTENE PRECIPITATION AND RE-DISSOLUTION

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani Jr; Mark Sanderson

    2006-06-01

    About 37-50% (w/w) of the heptane asphaltenes from unpyrolyzed residua dissolve in cyclohexane. As pyrolysis progresses, this number decrease to below 15% as coke and toluene insoluble pre-coke materials appear. This solubility measurement can be used after coke begins to form, unlike the flocculation titration, which cannot be applied to multi-phase systems. Currently, the procedure for the isolation of heptane asphaltenes and the determination of the amount of asphaltenes soluble in cyclohexane spans three days. A more rapid method to measure asphaltene solubility was explored using a novel on-column asphaltene precipitation and re-dissolution technique. This was automated using high performance liquid chromatography (HPLC) equipment with a step gradient sequence using the solvents: heptane, cyclohexane, toluene:methanol (98:2). Results for four series of original and pyrolyzed residua were compared with data from the gravimetric method. The measurement time was reduced from three days to forty minutes. The separation was expanded further with the use of four solvents: heptane, cyclohexane, toluene, and cyclohexanone or methylene chloride. This provides a fourth peak which represents the most polar components, in the oil.

  13. Monitoring DNAPL pumping using integrated geophysical techniques

    SciTech Connect (OSTI)

    Newmark, R.L.

    1997-01-01

    The removal of DNAPL during pumping was monitored. At Hill AFB in Utah, a free-product DNAPL plume (predominantly TCE, with some TCA, PCE, methylene chloride) is pooled in water-wet soil on a thick clay aquitard. Groundwater pumping at Operable Unit 2 began in 1994; to date, nearly 30,000 gal DNAPL have been recovered. From Sept. 1994 through Sept. 1995, changes in the basin during DNAPL pumping were monitored using fiber optic chemical sensors, neutron logs, and electrical resistance tomography (ERT). The first two sensor types verify the presence of DNAPL in vicinity of 3 boreholes which form a cross section from the perimeter of the basin to its center. Cross borehole ERT images the changes in formation electrical properties due to removal of DNAPL, extending the understanding of DNAPL removal between the boreholes. During pumping, electrical resistivities decreased; we suggest these decreases are directly caused by the reduction in DNAPL. During ground water pumping, water with relatively low resistivity replaces some of the DNAPL pockets as the highly insulating DNAPL is removed. Results suggest that, as DNAPL is pumped from a nearby well, product slowly drains along the top of an aquitard and into the pump well, where it collects.

  14. Destruction of Representative Navy Wastes Using Supercritical Water Oxidation. Final report

    SciTech Connect (OSTI)

    Rice, S.F.; Steeper, R.R.; LaJeunesse, C.A.

    1993-10-01

    Supercritical water oxidation (SCWO) is a rapidly emerging technology that presents potential as a hazardous waste treatment method for a wide variety of industrial chemicals ranging from common organic solvents to complex formulations such as paints, lubricating oils, and degreasers. The Naval Civil Engineering Laboratory is contributing to the development of this technology for application to waste materials generated at naval shipyards and bases. These wastes include paint stripping and changeout fluids generated from equipment service procedures as well as herbicides, pesticides, paint, and numerous other materials associated with base facility maintenance. An important design consideration in the development of SCWO systems centers on choosing a reactor operating temperature such that the destruction of the waste organic is sufficiently complete. This report examines the temperature dependence of the oxidation in supercritical water of seven common organic compounds and three industrial commercial materials over the temperature range of 430{degree}C to 585{degree}C and reaction times ranging from seven to thirty seconds at a pressure of 27.5 MPa (4000 psi). The materials studies are methanol, phenol, methyl ethyl ketone, ethylene glycol, acetic acid, methylene chloride, 1,1,1-tichloroethane (TCA), latex paint, motor oil, and Roundup, a commercial general purpose herbicide. The results indicate that for most materials, temperatures over 530{degree}C and residence times near 20 seconds afford destruction efficiencies of greater than 99.95%

  15. Recovery of cesium

    DOE Patents [OSTI]

    Izatt, Reed M.; Christensen, James J.; Hawkins, Richard T.

    1984-01-01

    A process of recovering cesium ions from mixtures of ions containing them and other ions, e.g., a solution of nuclear waste materials, which comprises establishing a separate source phase containing such a mixture of ions, establishing a separate recipient phase, establishing a liquid membrane phase in interfacial contact with said source and recipient phases, said membrane phase containing a ligand, preferably a selected calixarene as depicted in the drawing, maintaining said interfacial contact for a period of time long enough to transport by said ligand a substantial portion of the cesium ion from the source phase to the recipient phase, and recovering the cesium ion from the recipient phase. The separation of the source and recipient phases may be by the membrane phase only, e.g., where these aqueous phases are emulsified as dispersed phases in a continuous membrane phase, or may include a physical barrier as well, e.g., an open-top outer container with an inner open-ended container of smaller cross-section mounted in the outer container with its open bottom end spaced from and above the closed bottom of the outer container so that the membrane phase may fill the outer container to a level above the bottom of the inner container and have floating on its upper surface a source phase and a recipient phase separated by the wall of the inner container as a physical barrier. A preferred solvent for the ligand is a mixture of methylene chloride and carbon tetrachloride.

  16. Solvent Extraction of Chemical Attribution Signature Compounds from Painted Wall Board: Final Report

    SciTech Connect (OSTI)

    Wahl, Jon H.; Colburn, Heather A.

    2009-10-29

    This report summarizes work that developed a robust solvent extraction procedure for recovery of chemical attribution signature (CAS) compound dimethyl methyl phosphonate (DMMP) (as well as diethyl methyl phosphonate (DEMP), diethyl methyl phosphonothioate (DEMPT), and diisopropyl methyl phosphonate (DIMP)) from painted wall board (PWB), which was selected previously as the exposed media by the chemical attribution scientific working group (CASWG). An accelerated solvent extraction approach was examined to determine the most effective method of extraction from PWB. Three different solvent systems were examined, which varied in solvent strength and polarity (i.e., 1:1 dichloromethane : acetone,100% methanol, and 1% isopropanol in pentane) with a 1:1 methylene chloride : acetone mixture having the most robust and consistent extraction for four original target organophosphorus compounds. The optimum extraction solvent was determined based on the extraction efficiency of the target analytes from spiked painted wallboard as determined by gas chromatography x gas chromatography mass spectrometry (GCxGC-MS) analysis of the extract. An average extraction efficiency of approximately 60% was obtained for these four compounds. The extraction approach was further demonstrated by extracting and detecting the chemical impurities present in neat DMMP that was vapor-deposited onto painted wallboard tickets.

  17. Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate

    SciTech Connect (OSTI)

    Dilek, N.; Guenes, B.; Bueyuekguengoer, O.; Guep, R.

    2013-01-15

    The crystal structure of title compound (Fe[(C{sub 25}H{sub 21}N{sub 7}O{sub 4}S{sub 2})] {center_dot} 4(C{sub 3}NOH{sub 7}), where C{sub 3}NOH{sub 7} is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) A, {beta} = 108.753(2) Degree-Sign . The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.

  18. X-ray Photoelectron Spectroscopic Analyses of Corrosion Products Formed on Rock Bolt Carbon Steel in Chloride Media with Bicarbonate and Silicate Ions

    SciTech Connect (OSTI)

    Deodeshmukh, Vinay; Venugopal, A; Chandra, Dhanesh; Yilmaz, Ahmet; Daemen, Jack; Jones, D A.; Lea, Alan S.; Engelhard, Mark H.

    2004-11-01

    The passivation behavior of Yucca Mountain Repository rock bolt carbon steel in deaerated 3.5% NaCl solution containing SiO{sub 3}{sup 2} and HCO{sub 3} ions was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopic methods. Polarization results indicate that combinations of silicate and bicarbonate anions decrease the passive current density and raise the pitting potential. XPS results indicate the enrichment of silica at passive potentials and the formation of mixed FeCO{sub 3} and silica film at lower potentials. This change in film composition was responsible for the changes in corrosion rate at lower and higher potentials. XPS results also support the thermodynamic data with regard to the occurrence of second oxidation peak observed in the polarization curves to be due to the oxidation of FeCO{sub 3} to Fe{sub 2}O{sub 3}.

  19. Novel Electrolytes for Lithium ...

    Office of Scientific and Technical Information (OSTI)

    ... Solid State Lett. 2011, 14, A161- A164. Methylene Ethylene Carbonate: Novel Additive to ... Electrolytes, Brandon Knight, Daniel Seo, and Brett F. Fucht Manuscript in Preparation. ...

  20. Determination of a cost-effective air pollution control technology for the control of VOC and HAP emissions from a steroids processing plant

    SciTech Connect (OSTI)

    Hamel, T.M.

    1997-12-31

    A steroids processing plant located in northeastern Puerto Rico emits a combined average of 342 lb/hr of hazardous air pollutants (HAPs) and volatile organic compounds (VOCs) from various process operations. The approach that this facility used to implement maximum achievable control technology (MACT) may assist others who must contend with MACT for pharmaceutical or related manufacturing facilities. Federal air regulations define MACT standards for stationary sources emitting any of 189 HAPs. The MACT standards detailed in the NESHAPs are characterized by industry and type of emission control system or technology. It is anticipated that the standard will require HAP reductions of approximately 95%. The steroid plant`s emissions include the following pollutant loadings: VOC/HAP Emission Rate (lb/hr): Methanol 92.0; Acetone 35.0; Methylene chloride 126.0; Chloroform 25.0; Ethyl acetate 56.0; Tetrahydrofuran 5.00; and 1,4-Dioxane 3.00. The facility`s existing carbon adsorption control system was nearing the end of its useful life, and the operators sought to install an air pollution control system capable of meeting MACT requirements for the pharmaceutical industry. Several stand-alone and hybrid control technologies were considered for replacement of the carbon adsorption system at the facility. This paper examines the following technologies: carbon adsorption, membrane separation, thermal oxidation, membrane separation-carbon adsorption, and condensation-carbon adsorption. Each control technology is described; the advantages and disadvantages of utilizing each technology for the steroid processing plant are examined; and capital and operating costs associated with the implementation of each technology are presented. The rationale for the technology ultimately chosen to control VOC and HAP emissions is presented.

  1. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  2. Method of processing aluminous ores

    DOE Patents [OSTI]

    Loutfy, Raouf O.; Keller, Rudolf; Yao, Neng-Ping

    1981-01-01

    A method of producing aluminum chloride from aluminous materials containing compounds of iron, titanium and silicon comprising reacting the aluminous materials with carbon and a chlorine-containing gas at a temperature of about 900.degree. K. to form a gaseous mixture containing chlorides of aluminum, iron, titanium and silicon and oxides of carbon; cooling the gaseous mixture to a temperature of about 400.degree. K. or lower to condense the aluminum chlorides and iron chlorides while titanium chloride and silicon chloride remain in the gas phase to effect a separation thereof; heating the mixture of iron chlorides and aluminum chlorides to a temperature of about 800.degree. K. to form gaseous aluminum chlorides and iron chlorides; passing the heated gases into intimate contact with aluminum sulfide to precipitate solid iron sulfide and to form additional gaseous aluminum chlorides; and separating the gaseous aluminum chloride from the solid iron sulfide.

  3. Studies of the regeneration of activated bauxite used as granular...

    Office of Scientific and Technical Information (OSTI)

    BED FILTERS; HOT GAS CLEANUP; POTASSIUM CHLORIDES; SORPTION; SODIUM CHLORIDES; AIR POLLUTION CONTROL; COAL; FLUIDIZED-BED COMBUSTORS; ALKALI METAL COMPOUNDS; ALUMINIUM ORES; ...

  4. DATE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing & Molten Chloride Fast Reactor Development - Southern Company Services, Inc. ... readiness of the Molten Chloride Fast Reactor (MCFR) technology under development by ...

  5. CO2-H2O Mixtures in the Geological Sequestration of CO2. II....

    Office of Scientific and Technical Information (OSTI)

    and Duan and Sun (2003), which can be extended to chloride solutions other than NaCl. ... BRINES; CHLORIDES; MIXTURES; REACTION KINETICS; SOLUBILITY; SUN; THERMODYNAMIC ACTIVITY

  6. Geochemistry of Thermal Waters in Long Valley, Mono County, California...

    Open Energy Info (EERE)

    Long Valley, California, issue sodium bicarbonate-chloride waters containing 1000-1420 mgl of dissolved solids. Thermal waters of sodium bicarbonate-chloride composition are...

  7. February | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    ... to widely familiar acid-base behavior in solution, electrons spurred the chemical reaction between hydrogen chloride and ammonia when they reacted to form ammonium chloride. ...

  8. Synthesis of CdS nanoparticles for photocatalytic application of methyleneblue degradation

    SciTech Connect (OSTI)

    Muthuraj, V.; Umadevi, M.; Sankarasubramanian, K.; Kajamuhideen, M. S.

    2014-04-24

    CdS nanoparticles were prepared by the reaction of cadmium acetate with thiourea in the presence and absence of methylene blue dye (MB). The nanoparticles were characterized by, XRD, FT-IR, UV-Vis. XRD study shows the presence of hexagonal phase for the nanoparticles whereas in case of the bulk samples only the hexagonal phase is observed. Fourier transform infrared spectroscopy (FT-IR) showed a strong interaction of methyl groups with CdS nanoparticles. The degradation of methylene blue was analysed using UV-Vis absorbance spectrum. Thus the results authenticate that methylene blue dye influences the structural and optical properties of the CdS nanoparticles.

  9. PERFORMANCE OF LIQUI-CEL EXTRA-FLOW MEMBRANE CONTRACTOR IN A PURE WATER AND IN A 0.2% SODIUM CHLORIDE SOLUTION (SNO-STR-2001-11).

    SciTech Connect (OSTI)

    YEH,M.; BOGER,J.; HAHN,R.L.

    2001-11-05

    After completion of SNO's first phase measurement of the neutrino charge current, two tons of salt were added into the SNO heavy water to increase the sensitivity of the neutral current measurement (Phase II). Liqui-Cel Extra-Flow Membrane Contactors (simply called Liqui-Cel) are used in the SNO heavy-water circulating system to remove the dissolved gases, such as oxygen, nitrogen, radon, and water vapor from the liquid water. One possible scenario with phase II operation is that the salt may leak through the Liqui-Cel Membrane and come in contact with the vacuum pumps and other metal components of the Heavy-Water Vapor Recovery System. In this scenario, corrosion will damage these components, especially the vacuum pump (Pfeiffer UniDry Pump with cast iron interior), and increase the operational difficulties. A series of tests for the behavior of the Liqui-Cel System in pure water and in salt systems was conducted at the Brookhaven National Laboratory in order to measure the transfer of (a) water vapor and (b) salt, if there is any, through the membrane. Initially a 10-inch by 28-inch Liqui-Cel unit, identical to those used in the SNO heavy-water circulating system, was obtained from SNO site. However, extensive analysis showed that the membrane in this unit was defective: a replacement membrane would cost several thousand dollars. Instead, a smaller, 2.5-inch x 8-inch Liqui-Cel, obtained from Dr. Richard Helmers of the University of British Columbia, was used in this experiment. A comparison of the present experiment with the SNO heavy-water system is done with theoretical calculations. The results are discussed in the following sections.

  10. Corrosion Resistances of Iron-Based Amorphous Metals with Yttrium and Tungsten Additions in Hot Calcium Chloride Brine & Natural Seawater: Fe48Mo14Cr15Y2C15B6 and W-Containing Variants

    SciTech Connect (OSTI)

    Farmer, J C; Haslam, J; Day, S; Lian, T; Saw, C; Hailey, P; Choi, J; Yang, N; Blue, C; Peter, W; Payer, J; Branagan, D J

    2006-10-20

    Yttrium-containing SAM1651 (Fe{sub 48.0}Cr{sub 15.0}Mo{sub 14.0}B{sub 6.0}C{sub 15.0}Y{sub 2.0}), has a critical cooling rate (CCR) of approximately 80 Kelvin per second, while SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) with no yttrium has a higher critical cooling rate of approximately 600 Kelvin per second. SAM1651's low CCR enables it to be rendered as a completely amorphous material in practical materials processes. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The passive film stability of these Fe-based amorphous metal formulations have been found to be superior to that of conventional stainless steels, and comparable to that of Ni-based alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates.