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While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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1

Methylene Chloride Management Plan Review and Approval Authority  

E-Print Network [OSTI]

-8172 (Medical Consultation and Evaluation) Facilities Management Work Control Center (301) 405-2222 (RepairMETHYLENE CHLORIDE MANAGEMENT PLAN #12;#12;Methylene Chloride Management Plan Review and Approval Date #12;ii Methylene Chloride Management Plan #12;Methylene Chloride Management Plan Table of Contents

Rubloff, Gary W.

2

Methylene chloride exposure and birthweight in Monroe County, New York  

SciTech Connect (OSTI)

This study examined the relationship between birthweight and exposure to emissions of methylene chloride (DCM) from manufacturing processes of the Eastman Kodak Company at Kodak Park in Rochester, Monroe County, New York. County census tracts were categorized as exposed to high, moderate, low or no DCM based on the Kodak Air Monitoring Program (KAMP) model, a theoretical dispersion model of DCM developed by Eastman Kodak Company. Birthweight and information on variables known to influence birthweight were obtained from 91,302 birth certificates of white singleton births to Monroe County residents from 1976 to 1987. No significant adverse effects of exposure to DCM on birthweight were found. Adjusted birthweight in high exposure census tracts was 18.7 g less than in areas with no exposure (95% confidence interval for the difference between high and no exposure - 51.6, 14.2 g). Problems inherent in the method of estimation of exposure, which may decrease power or bias the results, are discussed. Better methods to estimate exposure to emissions from multiple industrial point sources are needed.

Bell, B.P.; Franks, P.; Hildreth, N.; Melius, J. (Department of Family Medicine, University of Rochester School of Medicine and Dentistry, New York (USA))

1991-06-01T23:59:59.000Z

3

ANALYSIS OF VAPORS FROM METHYLENE CHLORIDE EXTRACTS OF NUCLEAR GRADE HEPA FILTER FIBERGLASS SAMPLES  

SciTech Connect (OSTI)

While several organic compounds were detected in the vapor samples used in the reenactment of the preparation of mounts from the extracts of nuclear grade high-efficiency particulate air filter fiberglass samples, the most significant species present in the samples were methylene chloride, phenol, phenol-d6, and 2-fluorophenol. These species were all known to be present in the extracts, but were expected to have evaporated during the preparation of the mounts, as the mounts appeared to be dry before any vapor was collected. These species were present at the following percentages of their respective occupational exposure limits: methylene chloride, 2%; phenol, 0.4%; and phenol-d6, 0.6%. However, there is no established limit for 2-fluorophenol. Several other compounds were detected at low levels for which, as in the case of 2-fluorophenol, there are no established permissible exposure limits. These compounds include 2-chlorophenol; N-nitroso-1-propanamine; 2-fluoro-1,1{prime}-biphenyl; 1,2-dihydroacenaphthylene; 2,5-cyclohexadiene-1,4-dione,2,6-bis(1,1-dimethylethyl); trimethyl oxirane; n-propylpropanamine; 2-(Propylamino)ethanol; 4-methoxy-1-butene; 6-methyl-5-hepten-2-one; and 3,4-dimethylpyridine. Some of these were among those added as surrogates or spike standards as part ofthe Advanced Technologies and Laboratories International, Inc. preparation ofthe extract of the HEPA filter media and are indicated as such in the data tables in Section 2, Results; other compounds found were not previously known to be present. The main inorganic species detected (sulfate, sodium, and sulfur) are also consistent with species added in the preparation of the methylene chloride extract of the high-efficiency particulate air sample.

FRYE JM; ANASTOS HL; GUTIERREZ FC

2012-06-07T23:59:59.000Z

4

A preliminary study of extraction solvents for CW-agents and their decomposition products [3:1 (methylene chloride:isopropanol) vs. methylene chloride  

SciTech Connect (OSTI)

The major focus of this study was to explore the possibility of using different extraction solvents (or solvent combinations) to isolate CW agents and their degradation products from environmental and industrial samples. The general approach for extracting, e.g. water samples, required the use of a 3:1 (methylene chloride:isopropanol) extraction solvent. Although the 3:1 solvent extraction work-up methods provided excellent results in several Inter-laboratory Comparison Tests, the implementation of these methods for CW on-site analysis exercises was difficult (the methods require cumbersome equipment and are labor intensive). However, due to the time, power, and size restraints set forth by the Chemical Warfare Convention (CWC) for a CW on-site inspection, LLNL developed new sample work-up methods. The approach selected by LLNL incorporated solid phase extraction (SPE) techniques. It is evident from this preliminary study that new or previously used extraction solvents should be re-investigated. It was determined that care must be taken in handling the samples prior to NMR measurements. Also, it was determined that the four target compounds used in this study were extracted on average 18% higher with 3:1 (CH{sub 2}Cl{sub 2}: IPA) vs. CH{sub 2}Cl{sub 2}. However, additional target compounds need to be investigated using this extraction solvent to determine which classes of compounds are better extracted by the use of a 3:1 solvent system. This preliminary study clearly reveals that a mixed solvent system can yield better extraction efficiencies for mixture of compounds in aqueous samples.

Alcaraz, A.; Ward, R.L.; Hulsey, S.S.; Andresen, B.D.

1994-09-15T23:59:59.000Z

5

Mr. John E. Kieling, Bureau Chief Hazardous Waste Bureau  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

12014 9022 WQSP-4 Methylene Chloride U 7112014 0.4 75-09-2 CEMRC 712014 9022 WQSP-4 Carbon Tetrachloride U 7112014 0.4 56-23-5 CEMRC 712014 9022 WQSP-4...

6

Mr. John E. Kieling  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9129 WQSP-4 Methylene Chloride U 1172014 0.4 75-09-2 CEMRC PPBV 1152014 9129 WQSP-4 Carbon Tetrachloride U 1172014 0.4 56-23-5 CEMRC PPBV 1152014 9129 WQSP-4...

7

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). Abstract: The chemistry and photochemistry...

8

Purification and characterization of a methylene urea-hydrolyzing enzyme from Rhizobium radiobacter (Agrobacterium tumefaciens)  

E-Print Network [OSTI]

efficiency and reduce environmental impact. The release of nitrogen from methylene urea, a common slow of methylene urea are subjected to hydrolysis, and the hydrolysis proceeds via methylurea, urea and other yet is degraded into soluble, plant available nitrogen forms, NH4 þ and NO3 2 , by a specific microbial activity

Hammock, Bruce D.

9

Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene  

DOE Patents [OSTI]

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1982-03-31T23:59:59.000Z

10

Reactor-chromatographic determination of vinyl chloride in polyvinyl chloride  

SciTech Connect (OSTI)

The authors carry out a chromatographic study of the volatile products that evolve when various grades of domestic polyvinyl chloride are heated, to determine the concentration of residual monomer. To find vinyl chloride in complex mixtures of air pollutants the authors used sorptive reaction concentration of impurities. This new combination of methods is based on preliminary separation at the sampling stage of impurities that interfere in the analysis, followed by concentration of the desired components in a trap with an adsorbent, and chromatographic determination of the concentrated trace materials. The method obtains low vinyl chloride concentrations (down to 10/sup -4/-10/sup -5/ wt. %) with +/-5 relative error.

Berezkin, V.G.

1986-08-01T23:59:59.000Z

11

An Exocyclic Methylene Group Acts As a Bioisostere of the 2?-Oxygen Atom in LNA  

SciTech Connect (OSTI)

We show for the first time that it is possible to obtain LNA-like (Locked Nucleic Acid 1) binding affinity and biological activity with carbocyclic LNA (cLNA) analogs by replacing the 2{prime}-oxygen atom in LNA with an exocyclic methylene group. Synthesis of the methylene-cLNA nucleoside was accomplished by an intramolecular cyclization reaction between a radical at the 2{prime}-position and a propynyl group at the C-4{prime} position. Only methylene-cLNA modified oligonucleotides showed similar thermal stability and mismatch discrimination properties for complementary nucleic acids as LNA. In contrast, the close structurally related methyl-cLNA analogs showed diminished hybridization properties. Analysis of crystal structures of cLNA modified self-complementary DNA decamer duplexes revealed that the methylene group participates in a tight interaction with a 2{prime}-deoxyribose residue of the 5{prime}-terminal G of a neighboring duplex, resulting in the formation of a CH...O type hydrogen bond. This indicates that the methylene group retains a negative polarization at the edge of the minor groove in the absence of a hydrophilic 2{prime}-substituent and provides a rationale for the superior thermal stability of this modification. In animal experiments, methylene-cLNA antisense oligonucleotides (ASOs) showed similar in vivo activity but reduced toxicity as compared to LNA ASOs. Our work highlights the interchangeable role of oxygen and unsaturated moieties in nucleic acid structure and emphasizes greater use of this bioisostere to improve the properties of nucleic acids for therapeutic and diagnostic applications.

Seth, Punit P.; Allerson, Charles R.; Berdeja, Andres; Siwkowski, Andrew; Pallan, Pradeep S.; Gaus, Hans; Prakash, Thazha P.; Watt, Andrew T.; Egli, Martin; Swayze, Eric E. (Isis Pharm.); (Vanderbilt)

2010-12-07T23:59:59.000Z

12

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M. (Stanford, CA); Muller, Jochen A. (Baltimore, MD); Rosner, Bettina M. (Berlin, DE); Von Abendroth, Gregory (Nannhein, DE); Meshulam-Simon, Galit (Los Altos, CA); McCarty, Perry L (Stanford, CA)

2011-11-22T23:59:59.000Z

13

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M [Stanford, CA; Muller, Jochen A [Baltimore, MD; Rosner, Bettina M [Berlin, DE; Von Abendroth, Gregory [Mannheim, DE; Meshulam-Simon, Galit [Los Angeles, CA; McCarty, Perry L [Stanford, CA

2014-02-11T23:59:59.000Z

14

Graphene oxide functionalized with methylene blue and its performance in singlet oxygen generation  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Adsorption of methylene blue (MB) on graphene oxide (GO). • Characterization of graphene oxide–methylene blue nanocomposite (MB–GO). • Examination of MB–GO efficiency in singlet oxygen generation (SOG). • MB–GO performs higher SOG efficiency than pristine MB. - Abstract: Due to unique electronic, mechanical, optical and structural properties, graphene has shown promising applications in many fields, including biomedicine. One of them is noninvasive anticancer therapy – photodynamic therapy (PDT), where singlet oxygen (SO), generated under the irradiation of light with appropriate wavelengths, kills cancer cells. In this study, authors report graphene oxide (GO) noncovalent functionalization with methylene blue (MB). MB molecules underwent adsorption on the surface of GO. Detailed characterization of the obtained material was carried out with UV–vis spectroscopy, Raman spectroscopy, FT-IR spectroscopy, and confocal laser scanning microscopy. Furthermore, its performance in singlet oxygen generation (SOG) under irradiation of laser with excitation wavelengths of 785 nm was investigated. Interestingly, GO functionalized with MB (MB–GO) showed enhanced efficiency in singlet oxygen generation compared to pristine MB. The efficiency in SOG was detected by photobleaching of 9,10-anthracenediyl-bis(methylene)dimalonic acid (ABMDMA). These results indicate the material is promising in PDT anticancer therapy and further in vitro and in vivo studies are required.

Wojtoniszak, M., E-mail: mwojtoniszak@zut.edu.pl [West Pomeranian University of Technology in Szczecin, Institute of Chemical and Environment Engineering, Pulaskiego 10, 70-322 Szczecin (Poland); Rogi?ska, D.; Machali?ski, B. [Pomeranian Medical University, Department of General Pathology, Powsta?ców Wlkp. 72, 70-111 Szczecin (Poland); Drozdzik, M. [Pomeranian Medical University, Department of Pharmacology, Powsta?ców Wlkp. 72, 70-111 Szczecin (Poland); Mijowska, E. [West Pomeranian University of Technology in Szczecin, Institute of Chemical and Environment Engineering, Pulaskiego 10, 70-322 Szczecin (Poland)

2013-07-15T23:59:59.000Z

15

The feasibility of using methylene blue sensitized polyvinylalcohol film as a linear polarizer  

SciTech Connect (OSTI)

Linear light polarizing films selectively transmit radiations vibrating along an electromagnetic radiation vector and selectively absorb radiations vibrating along a second electromagnetic radiation vector. It happens according to the anisotropy of the film . In the present study the polarization effects of methylene blue sensitized polyvinyl alcohol is investigated. The polarization effects on the dye concentration, heating and stretching of film also are evaluated.

Jyothilakshmi, K.; Anju, K. S.; Arathy, K. [Department of Physics, Vimala College, Thrissur-9, Kerala (India); John, Beena Mary, E-mail: beenamary@gmail.com [Department of Physics, Bharata Mata College, Thrikkakara, Cochin-21,Kerala (India); Krishna, P. B.; Sruthi, C. T.; Chacko, Maria [Department of Physics, Cochin University of Science and Technology, Cochin-22, Kerala (India)

2014-01-28T23:59:59.000Z

16

Application of the Modified Methylene Blue Test to Detect Clay Minerals in Coarse Aggregate Fines  

E-Print Network [OSTI]

APPLICATION OF THE MODIFIED METHYLENE BLUE TEST TO DETECT CLAY MINERALS IN COARSE AGGREGATE FINES A Thesis by BRANDON THOMAS PITRE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...: Civil Engineering Copyright 2012 Brandon Thomas Pitre ii ABSTRACT The purpose of this study was to implement a new, rapid field method to effectively and accurately detect harmful clay minerals in aggregate fines by using the modified...

Pitre, Brandon

2012-12-04T23:59:59.000Z

17

Process for synthesis of beryllium chloride dietherate  

DOE Patents [OSTI]

A low temperature method of producing beryllium chloride dietherate through the addition of hydrogen chloride gas to a mixture of beryllium metal in ether in a reaction vessel is described. A reflux condenser provides an exit for hydrogen produced form the reaction. A distillation condenser later replaces the reflux condenser for purifying the resultant product.

Bergeron, Charles (Baton Rouge, LA); Bullard, John E. (Kendall Park, NJ); Morgan, Evan (Lynchburg, VA)

1991-01-01T23:59:59.000Z

18

Hydrocracking with molten zinc chloride catalyst containing 2-12% ferrous chloride  

DOE Patents [OSTI]

In a process for hydrocracking heavy aromatic polynuclear carbonaceous feedstocks to produce hydrocarbon fuels boiling below about 475.degree. C. by contacting the feedstocks with hydrogen in the presence of a molten zinc chloride catalyst and thereafter separating at least a major portion of the hydrocarbon fuels from the spent molten zinc chloride catalyst, an improvement comprising: adjusting the FeCl.sub.2 content of the molten zinc chloride to from about 2 to about 12 mol percent based on the mixture of ferrous chloride and molten zinc chloride.

Zielke, Clyde W. (McMurray, PA); Bagshaw, Gary H. (Library, PA)

1981-01-01T23:59:59.000Z

19

Evaluation of the kinetics of Cr-51 methylene diphosphonate: a potential therapeutic radiopharmaceutical for osteogenic sarcoma  

E-Print Network [OSTI]

, have been observed (3). Although there is no unanimity of agreement on which of these radiopharmaceuticals is preferred for skeletal imaging, the majority of the recent work suggests that 99m-Tc labeled methylene diphosphonate (99m-Tc HDP) ofi... in dog D and dog E. 1 represents dog D while 2 represents dog E. 33 DISCUSSION The normal bone scan when using Tc-99m MDP as the radiopharmaceutical, usually follows relatively predictable In Vivo kinetics. Tc-99m labeled diphosphonates provide a...

Poteet, Brian Allen

1987-01-01T23:59:59.000Z

20

Absorption media for irreversibly gettering thionyl chloride  

DOE Patents [OSTI]

Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

ammonium chlorides: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 87 Influence...

22

aryl chlorides bromides: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 152 Fuerst et...

23

actinium chlorides: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 40...

24

aqueous sodium chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 58 Systematic...

25

ammonium chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 87 Influence...

26

The interactions of azure B, a metabolite of methylene blue, with acetylcholinesterase and butyrylcholinesterase  

SciTech Connect (OSTI)

Methylene blue (MB) is reported to possess diverse pharmacological actions and is attracting increasing attention for the treatment of neurodegenerative disorders such as Alzheimer's disease. Among the pharmacological actions of MB, is the significant inhibition of acetylcholinesterase (AChE) and butyrylcholinesterase (BuChE). These activities may, at least in part, underlie MB's beneficial effects in Alzheimer's disease. MB is metabolized to yield N-demethylated products of which azure B, the monodemethyl metabolite, is the predominant species. Azure B has been shown to be pharmacologically active and also possesses a variety of biological actions. Azure B therefore may contribute to the pharmacological profile of MB. Based on these considerations, the present study investigates the possibility that azure B may, similar to MB, act as an inhibitor of human AChE and BuChE. The results document that azure B inhibits AChE and BuChE with IC{sub 50} values of 0.486 ?M and 1.99 ?M, respectively. The results further show that azure B inhibits AChE and BuChE reversibly, and that the modes of inhibition are most likely competitive. Although the AChE and BuChE inhibitory activities of azure B are twofold and fivefold, respectively, less potent than those recorded for MB [IC{sub 50}(AChE) = 0.214 ?M; IC{sub 50}(BuChE) = 0.389 ?M] under identical conditions, azure B may be a contributor to MB's in vivo activation of the cholinergic system and beneficial effects in Alzheimer's disease. - Highlights: • Methylene blue (MB) is a known inhibitor of AChE and BuChE. • Azure B, the major metabolite of MB, also is an inhibitor of AChE and BuChE. • Azure B may be a contributor to MB's in vivo activation of the cholinergic system. • Azure B may contribute to MB's potential in Alzheimer's disease therapy.

Petzer, Anél, E-mail: 12264954@nwu.ac.za [Centre of Excellence for Pharmaceutical Sciences, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom 2520 (South Africa); Harvey, Brian H. [Centre of Excellence for Pharmaceutical Sciences, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom 2520 (South Africa); Petzer, Jacobus P. [Division of Pharmaceutical Chemistry, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom 2520 (South Africa)

2014-02-01T23:59:59.000Z

27

Method for the regeneration of spent molten zinc chloride  

DOE Patents [OSTI]

In a process for regenerating spent molten zinc chloride which has been used in the hydrocracking of coal or ash-containing polynuclear aromatic hydrocarbonaceous materials derived therefrom and which contains zinc chloride, zinc oxide, zinc oxide complexes and ash-containing carbonaceous residue, by incinerating the spent molten zinc chloride to vaporize the zinc chloride for subsequent condensation to produce a purified molten zinc chloride: an improvement comprising the use of clay in the incineration zone to suppress the vaporization of metals other than zinc. Optionally water is used in conjunction with the clay to further suppress the vaporization of metals other than zinc.

Zielke, Clyde W. (McMurray, PA); Rosenhoover, William A. (Pittsburgh, PA)

1981-01-01T23:59:59.000Z

28

Tubular structured hierarchical mesoporous titania material derived from natural cellulosic substances and application as photocatalyst for degradation of methylene blue  

SciTech Connect (OSTI)

Graphical abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material with high photocatalytic activity under UV light was fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template using a one-pot sol-gel method. Highlights: {yields} Tubular structured mesoporous titania material was fabricated by sol-gel method. {yields} The titania material faithfully recorded the hierarchical structure of the template substrate (cotton). {yields} The titania material exhibited high photocatalytic activity in decomposition of methylene blue. -- Abstract: Bio-inspired, tubular structured hierarchical mesoporous titania material was designed and fabricated employing natural cellulosic substance (cotton) as hard template and cetyltrimethylammonium bromide (CTAB) surfactant as soft template by one-pot sol-gel method. The tubular structured hierarchical mesoporous titania material processes large specific surface area (40.23 m{sup 2}/g) and shows high photocatalytic activity in the photodegradation of methylene blue under UV light irradiation.

Huang, Haiqing [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Fuzhou, Jiangxi 344000 (China)] [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Fuzhou, Jiangxi 344000 (China); Liu, Xiaoyan [Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027 (China)] [Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027 (China); Huang, Jianguo, E-mail: jghuang@zju.edu.cn [Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027 (China)] [Department of Chemistry, Zhejiang University, Hangzhou, Zhejiang 310027 (China)

2011-11-15T23:59:59.000Z

29

Probing the role of chloride in Photosystem II from Thermosynechococcus elongatus by exchanging chloride for iodide  

E-Print Network [OSTI]

Center, Ehime University, Bunkyo-cho, Matsuyama Ehime, 790­8577, Japan, and PRESTO, Japan Science 2012 Keywords: Photosystem II Chloride Oxygen evolution The active site for water oxidation in Photosystem II (PSII) goes through five sequential oxidation states (S0 to S4) before O2 is evolved

30

Methylene megration and coupling on a non-reducible metal oxide: the reaction of dichloromethane on stoichiometric -Cr2O3(0001)  

SciTech Connect (OSTI)

The reaction of CH2Cl2 over the nearly-stoichiometric -Cr2O3(0001) surface produces gas phase ethylene, methane and surface chlorine adatoms. The reaction is initiated by the decomposition of CH2Cl2 into surface methylene and chlorine. Photoemission indicates that surface cations are the preferred binding sites for both methylene and chlorine adatoms. Two reaction channels are observed for methylene coupling to ethylene in temperature-programmed desorption (TPD). A desorption-limited, low-temperature route is attributed to two methylenes bound at a single site. The majority of ethylene is produced by a reaction-limited process involving surface migration (diffusion) of methylene as the rate-limiting step. DFT calculations indicate the surface diffusion mechanism is mediated by surface oxygen anions. The source of hydrogen for methane formation is adsorbed background water. Chlorine adatoms produced by the dissociation of CH2Cl2 deactivate the surface by simple site-blocking of surface Cr3+ sites. A comparison of experiment and theory shows that DFT provides a better description of the surface chemistry of the carbene intermediate than DFT+U using reported parameters for a best representation of the bulk electronic properties of -Cr2O3.

Dong, Yujung [Virginia Polytechnic Institute and State University; Brooks, John [Virginia Polytechnic Institute and State University; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Cox, David F. [Virginia Polytechnic Institute and State University

2015-01-01T23:59:59.000Z

31

Reduction of Vinyl Chloride in Metallic Iron-Water Systems  

E-Print Network [OSTI]

Reduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department to groundwater and soil contamination. In particular, VC can be produced as an intermediate in the reductive). Remediation of groundwater contaminated with chlori- nated ethylenes, including vinyl chloride, has been chal

Deng, Baolin

32

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence  

E-Print Network [OSTI]

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

Ghosh, Ruby N.

33

VINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING  

E-Print Network [OSTI]

. The "irreversible effects threshold" is the maximum concentration of pollutant in the air for a given exposure timeVINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING URBAN DEVELOPMENT OR LAND of vinyl Chloride , the french procedure to set acute toxicity thresholds in the context of controlling

Boyer, Edmond

34

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

Pereira, C.

1999-02-23T23:59:59.000Z

35

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

Pereira, Candido (Naperville, IL)

1999-01-01T23:59:59.000Z

36

Apparatus and method for making metal chloride salt product  

DOE Patents [OSTI]

A method of producing metal chlorides is disclosed in which chlorine gas is introduced into liquid Cd. CdCl.sub.2 salt is floating on the liquid Cd and as more liquid CdCl.sub.2 is formed it separates from the liquid Cd metal and dissolves in the salt. The salt with the CdCl.sub.2 dissolved therein contacts a metal which reacts with CdCl.sub.2 to form a metal chloride, forming a mixture of metal chloride and CdCl.sub.2. After separation of bulk Cd from the salt, by gravitational means, the metal chloride is obtained by distillation which removes CdCl.sub.2 and any Cd dissolved in the metal chloride.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Homer Glen, IL); Richmann, Michael K. (Carlsbad, NM)

2007-05-15T23:59:59.000Z

37

E-Print Network 3.0 - acute cadmium chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... CalOSHAReproToxin Benzyl chloride AcutelyHazardousWaste Benzyl violet 4B...

38

Calibration of the On-Line Aerosol Monitor (OLAM) with ammonium chloride and sodium chloride aerosols  

SciTech Connect (OSTI)

The On-Line Aerosol Monitor (OLAM) is a light attenuation device designed and built at the Idaho National Engineering Laboratory (INEL) by EG&G Idaho. Its purpose is to provide an on-line indication of aerosol concentration in the PHEBUS-FP tests. It does this by measuring the attenuation of a light beam across a tube through which an aerosol is flowing. The OLAM does not inherently give an absolute response and must be calibrated. A calibration has been performed at Sandia National Laboratories` (SNL) Sandia Aerosol Research Laboratory (SARL) and the results are described here. Ammonium chloride and sodium chloride calibration aerosols are used for the calibration and the data for the sodium chloride aerosol is well described by a model presented in this report. Detectable instrument response is seen over a range of 0.1 cm{sup 3} of particulate material per m{sup 3} of gas to 10 cm{sup 3} of particulate material per m{sup 3} of gas.

Brockmann, J.E.; Lucero, D.A.; Romero, T. [Sandia National Labs., Albuquerque, NM (United States); Pentecost, G. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

1993-12-01T23:59:59.000Z

39

E-Print Network 3.0 - argon chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and 266 nm photoreaction of acetyl chloride in xenon and argon... matrixes. Experimental Section Neat and argon matrix-isolated thin films of acid chlorides are deposited... -gas...

40

Method for the production of uranium chloride salt  

DOE Patents [OSTI]

A method for the production of UCl.sub.3 salt without the use of hazardous chemicals or multiple apparatuses for synthesis and purification is provided. Uranium metal is combined in a reaction vessel with a metal chloride and a eutectic salt- and heated to a first temperature under vacuum conditions to promote reaction of the uranium metal with the metal chloride for the production of a UCl.sub.3 salt. After the reaction has run substantially to completion, the furnace is heated to a second temperature under vacuum conditions. The second temperature is sufficiently high to selectively vaporize the chloride salts and distill them into a condenser region.

Westphal, Brian R.; Mariani, Robert D.

2013-07-02T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Azure B, a metabolite of methylene blue, is a high-potency, reversible inhibitor of monoamine oxidase  

SciTech Connect (OSTI)

Methylene blue (MB) has been shown to act at multiple cellular and molecular targets and as a result possesses diverse medical applications. Among these is a high potency reversible inhibition of monoamine oxidase A (MAO-A) that may, at least in part, underlie its adverse effects but also its psycho- and neuromodulatory actions. MB is metabolized to yield N-demethylated products of which azure B, the monodemethyl species, is the major metabolite. Similar to MB, azure B also displays a variety of biological activities and may therefore contribute to the pharmacological profile of MB. Based on these observations, the present study examines the interactions of azure B with recombinant human MAO-A and -B. The results show that azure B is a potent MAO-A inhibitor (IC{sub 50} = 11 nM), approximately 6-fold more potent than is MB (IC{sub 50} = 70 nM) under identical conditions. Measurements of the time-dependency of inhibition suggest that the interaction of azure B with MAO-A is reversible. Azure B also reversibly inhibits the MAO-B isozyme with an IC{sub 50} value of 968 nM. These results suggest that azure B may be a hitherto under recognized contributor to the pharmacology and toxicology of MB by blocking central and peripheral MAO-A activity and as such needs to be considered during its use in humans and animals. Highlights: ? Methylene blue (MB) is a known potent MAO-A inhibitor. ? Azure B, the major metabolite of MB, is more potent as a MAO-A inhibitor. ? Azure B may be a contributor to the CNS pharmacology and toxicology of MB.

Petzer, Anél, E-mail: 12264954@nwu.ac.za [Unit for Drug Research and Development, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa)] [Unit for Drug Research and Development, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa); Harvey, Brian H. [Division of Pharmacology, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa)] [Division of Pharmacology, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa); Wegener, Gregers [Centre for Psychiatric Research, Aarhus University Hospital-Risskov, Skovagervej 2, 8240 Risskov (Denmark)] [Centre for Psychiatric Research, Aarhus University Hospital-Risskov, Skovagervej 2, 8240 Risskov (Denmark); Petzer, Jacobus P. [Division of Pharmaceutical Chemistry, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa)] [Division of Pharmaceutical Chemistry, School of Pharmacy, North-West University, Private Bag X6001, Potchefstroom, 2520 (South Africa)

2012-02-01T23:59:59.000Z

42

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera...  

Open Energy Info (EERE)

Of Chloride In Hydrothermal Fluids From The Valles Caldera, New Mexico- A 36Cl Study Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Sources Of...

43

Magnesium and Copper (II) Chloride: A Curious Redox Reaction .  

E-Print Network [OSTI]

??The focus of this research is to follow the oxidation-reduction reaction of solid magnesium metal and an aqueous solution of copper (II) chloride (CuCl2), both… (more)

Mannard, Moira

2014-01-01T23:59:59.000Z

44

Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional...  

Open Energy Info (EERE)

Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal Indicator in Hawaii Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

45

Cotton responses to mepiquat chloride and PGR-IV treatments  

E-Print Network [OSTI]

Plant growth regulators (PGRS) are applied to cotton (Gossypium hirsutum L.) to control vegetative growth, increase yields and hasten maturity. Two of these PGRS, mepiquat chloride (MC) and PGR-IV, affect plant growth in different ways. MC inhibits...

Biles, Stephen Paul

1998-01-01T23:59:59.000Z

46

The Salt or Sodium Chloride Content of Feeds  

E-Print Network [OSTI]

of Sodium Chloride.--In order to test the recovery of added salt, several molasses feeds were selected, weighed out, and varying amounts of salt added, in the form of a N/10 solution of sodium chloride. The salt was added hy a different person from... ............................... . . Preliminary ~vork on laboratory methocls ........ . . ............................... Laboratory method adopted.. ............................. Tests of the laboratory niethod. ................... Application of the methold to feed mixtures...

Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

1920-01-01T23:59:59.000Z

47

Uniform Cu{sub 2}Cl(OH){sub 3} hierarchical microspheres: A novel adsorbent for methylene blue adsorptive removal from aqueous solution  

SciTech Connect (OSTI)

Using the solution phase method without any surfactants or templates, the hierarchical of Cu{sub 2}Cl(OH){sub 3} microspheres were synthesized by freeze drying. The size and surface area of the microspheres are ca. 1–2 µm and 76.61 m{sup 2} g{sup ?1}, respectively. A possible formation mechanism is presented based on the experimental results. Methylene blue was chosen to investigate the adsorption capacity of the as-prepared adsorbent. The effects of various experimental parameters, such as pH, initial dye concentration, and contact time were investigated. The results showed that the dye removal increased with the increasing in the initial concentration of the dye and also increased in the amount of microspheres used and initial pH. Adsorption data fitted well with the Freundlich adsorption isotherm. The thermodynamic analysis presented the exothermic, spontaneous and more ordered arrangement process. The microspheres could be employed effective for removal of dyes from aqueous solution. - Graphical abstract: The single-crystalline hierarchical Cu{sub 2}Cl(OH){sub 3} spheres can be prepared for the first time by using a template-free process through freeze-drying. Meanwhile, the hierarchical spheres exhibited high adsorption capacity to methylene blue. Display Omitted - Highlights: • Cu{sub 2}Cl(OH){sub 3} microspheres were successfully synthesized through a freeze drying process. • A possible formation mechanism of hierarchical microspheres was presented. • The Cu{sub 2}Cl(OH){sub 3} microspheres have high methylene blue adsorption capacity. • Methylene blue adsorption is a spontaneous and exothermic process. • The adsorption mechanism of microspheres onto dye was proposed in detail.

Wei, Wei; Gao, Pin; Xie, Jimin, E-mail: xiejm391@sohu.com; Zong, Sekai; Cui, Henglv; Yue, Xuejie

2013-08-15T23:59:59.000Z

48

Synthesis of pore-variable mesoporous CdS and evaluation of its photocatalytic activity in degrading methylene blue  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • Self-templated synthesis of tubular CdS. • Cadmium complexes of aliphatic acids sustain the network of mesoporous structures. • Aliphatic acids affect the phase composition and particle size. • Pore size and volume vary with aliphatic acids having different hydrocarbonyl. - Abstract: In this study, mesoporous CdS polycrystallites have been synthesized using aliphatic acids of hexanoic acid, octanoic acid, and oleic acid as coordinating and capping agents, respectively. The fibrous Cd–fatty acid salts act as a template to form the tubular CdS. The organic species are found to be necessary for maintaining the network of mesoporous CdS. The characterization results indicate that the shorter carbon chain length in aliphatic acids favors the wurtzite phase and particle size growth the specific surface area, pore diameter and pore volume show a monotonic raise with increasing carbon chain. The photocatalytic activities of mesoporous CdS tubes exhibit much higher efficiency than those of nanosized CdS powders in decolorizing methylene blue under simulated visible light.

Zhang, Wei-Min, E-mail: chm_zhangwm@ujn.edu.cn [School of Chemistry and Chemical Engineering, University of Jinan (China); Jiang, Yao-Quan [School of Chemistry and Chemical Engineering, University of Jinan (China); Cao, Xiao-Yan [Key Laboratory of Marine Chemistry Theory and Technology, Ocean University of China, Ministry of Education (China); Chen, Meng; Ge, Dong-Lai [School of Chemistry and Chemical Engineering, University of Jinan (China); Sun, Zhong-Xi, E-mail: sunzx@ujn.edu.cn [School of Chemistry and Chemical Engineering, University of Jinan (China)

2013-10-15T23:59:59.000Z

49

Production and mitigation of acid chlorides in geothermal steam  

SciTech Connect (OSTI)

Measurements of the equilibrium distribution of relatively nonvolatile solutes between aqueous liquid and vapor phases have been made at temperatures to 350{degrees}C for HCl(aq) and chloride salts. These data are directly applicable to problems of corrosive-steam production in geothermal steam systems. Compositions of high-temperature brines which could produce steam having given concentrations of chlorides may be estimated at various boiling temperatures. Effects of mitigation methods (e.g., desuperheating) can be calculated based on liquid-vapor equilibrium constants and solute mass balances under vapor-saturation conditions.

Simonson, J.M.; Palmer, D.A.

1995-06-01T23:59:59.000Z

50

Sol–gel synthesis of SnO{sub 2}–MgO nanoparticles and their photocatalytic activity towards methylene blue degradation  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • A simple sol–gel method for the synthesis of SnO{sub 2}–MgO nanoparticles is reported. • Band gap of SnO{sub 2} can be tuned by varying the magnesium content in SnO{sub 2}–MgO. • SnO{sub 2}–MgO shows good photocatalytic activity towards degradation of methylene blue. - Abstract: SnO{sub 2}–MgO mixed metal oxide nanoparticles were prepared by a simple sol–gel method. The nanoparticles were characterized by power X-ray diffraction, scanning electron microscopy coupled with energy dispersive X-ray analysis, transmission electron microscopy and UV–vis diffuse reflectance spectroscopy. The XRD results indicate the formation of mixed metal oxide nanoparticles and also a decrease of SnO{sub 2} crystallite size in the mixed metal oxide nanoparticles with increasing magnesium oxide content. The reflectance spectroscopy results show a blue shift of the band gap of SnO{sub 2} in the mixed metal oxide nanoparticles. The photocatalytic activity of the SnO{sub 2}–MgO nanoparticles was tested using the photodegradation of aqueous methylene blue in the presence of sunlight. The results indicate that the mixed metal oxide nanoparticles possess higher efficiency for the photodegradation of methylene blue compared to pure SnO{sub 2} nanoparticles.

Bayal, Nisha; Jeevanandam, P., E-mail: jeevafcy@iitr.ernet.in

2013-10-15T23:59:59.000Z

51

The effect of freezing on the sulfate-chloride and density-chloride ratios of sea-water  

E-Print Network [OSTI]

in the sulphate-chloride ratio would be expected to have a corresponi- ingly larger effect, on density than would one of the less abundant iona. CHAPTER II LITERATURE REVIEW Evidence for Sulphate Enricl ment in Ice The sulphate-chloride ratio was studied... as early as 1907 vhen Ringer performed laboratory freezing experiments vith sea-vater in which he cooled sea-water until solid salts began to freeze out. of solution. l Portions of the ice and the brine below the ice vere collected and analyzed...

Burkhalter, Albert Charles

1967-01-01T23:59:59.000Z

52

Membrane Transport Chloride Transport Across Vesicle and Cell  

E-Print Network [OSTI]

Membrane Transport Chloride Transport Across Vesicle and Cell Membranes by Steroid-Based Receptors-established that molecules which transport cations across cell membranes (cationophores) can have potent biological effects the formation of an ion pair.[4a­g] Anion transport by purely electroneutral systems is still quite rare.[4j

Smith, Bradley D.

53

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis  

E-Print Network [OSTI]

Lithium Diisopropylamide-Mediated Ortholithiations: Lithium Chloride Catalysis Lekha Gupta, 2008 Ortholithiations of a range of arenes mediated by lithium diisopropylamide (LDA) in THF at -78 °C protocols with unpurified commercial samples of n-butyl- lithium to prepare LDA or commercially available

Collum, David B.

54

1 INTRODUCTION In Spain, Plasticized polyvinyl chloride (PVC-  

E-Print Network [OSTI]

1 INTRODUCTION In Spain, Plasticized polyvinyl chloride (PVC- P) geomembranes began being used in waterproof- ing of infrastructure in the seventies. Early usage of PVC-P geomembranes was not particularly for the PVC-P homogeneous geomem- branes used in roofing. Subsequently, other stan- dards were drafted

Zornberg, Jorge G.

55

Soil stabilization using optimum quantity of calcium chloride with Class F fly ash  

E-Print Network [OSTI]

On-going research at Texas A&M University indicated that soil stabilization using calcium chloride filter cake along with Class F fly ash generates high strength. Previous studies were conducted with samples containing calcium chloride filter cake...

Choi, Hyung Jun

2006-10-30T23:59:59.000Z

56

awaited calcium-activated chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with either sodium chloride or potassium chloride. The addition of 75 or 150 porn N02 did not lower plate counts (P&0. 05... Kayfus, Timothy Jon 2012-06-07 38...

57

E-Print Network 3.0 - arsenic chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

that the chloride anion was responsible for the difference in the effect of CaCO3 and CaCl2 on plant arsenic uptake... depends on plant species and chloride concentration. The...

58

E-Print Network 3.0 - aluminium chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Summary: and aluminium. The adsorption of chloride ions to oxide covered...

59

Beam damage of poly(vinyl chloride) [PVC] as observed by x-ray...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

damage of poly(vinyl chloride) PVC as observed by x-ray photoelectron spectroscopy at 143 K, 303 K and 373 K. Beam damage of poly(vinyl chloride) PVC as observed by x-ray...

60

Beam Damage of Poly(Vinyl Chloride) [PVC] Film as Observed by...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Damage of Poly(Vinyl Chloride) PVC Film as Observed by X-ray Photoelectron Spectroscopy. Beam Damage of Poly(Vinyl Chloride) PVC Film as Observed by X-ray Photoelectron...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

E-Print Network 3.0 - atmospheric chloride deposition Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

secondary atmospheric chloride (SAC) with a d37 Cl value 2.10%. Our model suggests that sublimation tills... for chlorides in the MDV is the secondary atmo- ... Source: Sharp,...

62

apical sodium-chloride cotransporter: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

g magnesium chloride, 3.24 g magnesium sulfate bromide, 34 mg strontium chloride, 22 mg boric acid, 4 mg sodium silicate, 2.4 mg sodium fluoride, 1.6 mg Bae, Jin-Woo 302 The...

63

Copolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Metal Catalyst  

E-Print Network [OSTI]

monomers with polar functionality (such as vinyl acetate (VA), vinyl chloride (VC), and acrylates).1 OverCopolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Flory constants were identical (0.81) for the ethylene homopolymerizations and the ethylene/vinyl chloride

Goddard III, William A.

64

A fluorescent assay for chloride transport; identification of a synthetic anionophore with improved activity  

E-Print Network [OSTI]

A fluorescent assay for chloride transport; identification of a synthetic anionophore with improved on the chloride-sensitive probe, lucigenin, is developed for monitoring chloride transport into vesicles, and used to compare the effectiveness of three steroid- derived transporters. A topic of growing interest

Smith, Bradley D.

65

Neuroendocrine effects of acute nickel chloride administration in rats  

SciTech Connect (OSTI)

An sc injection of nickel chloride (20 and 10 mg/kg) led to a profound and consistent increase of circulating prolactin (PRL) levels after 1 day and lasted for 4 days (p < 0.001) in male rats. Increases in insulin levels occurred 1 and 2 days postinjection. The nickel-induced PRL rise could be abolished by a simultaneous administration of 2-bromo-..cap alpha..-ergocryptine (CB 154). In vitro incubation of pituitaries from rats that received 20 mg/kg of nickel chloride 48 hr prior to sacrifice released more PRL into the culture medium, as well as contained more PRL in the final tissue than did the pituitaries from control animals. The hypothalamic extracts (HE) obtained from hypothalami of nickel-injected rats were tested also in vitro on normal rat pituitaries and the results showed that the HE from such rats released more PRL and therefore had less prolactin-inhibiting factor (PIF) than the HE obtained from control rats. The results show that nickel chloride has effects on the endocrine system that (a) last considerably longer than previously reported, (b) are mediated through the neuroendocrine system, and (c) instead of specifically inhibiting PRL secretion from the pituitary promote high circulating PRL levels lasting from 1 to 4 days.

Clemons, G.K.; Garcia, J.F.

1981-01-01T23:59:59.000Z

66

Uranium chloride extraction of transuranium elements from LWR fuel  

DOE Patents [OSTI]

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800 C to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein. 1 figure.

Miller, W.E.; Ackerman, J.P.; Battles, J.E.; Johnson, T.R.; Pierce, R.D.

1992-08-25T23:59:59.000Z

67

Uranium chloride extraction of transuranium elements from LWR fuel  

DOE Patents [OSTI]

A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels containing rare earth and noble metal fission products as well as other fission products is disclosed. The oxide fuel is reduced with Ca metal in the presence of Ca chloride and a U-Fe alloy which is liquid at about 800.degree. C. to dissolve uranium metal and the noble metal fission product metals and transuranium actinide metals and rare earth fission product metals leaving Ca chloride having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein. The Ca chloride and CaO and the fission products contained therein are separated from the U-Fe alloy and the metal values dissolved therein. The U-Fe alloy having dissolved therein reduced metals from the spent nuclear fuel is contacted with a mixture of one or more alkali metal or alkaline earth metal halides selected from the class consisting of alkali metal or alkaline earth metal and Fe or U halide or a combination thereof to transfer transuranium actinide metals and rare earth metals to the halide salt leaving the uranium and some noble metal fission products in the U-Fe alloy and thereafter separating the halide salt and the transuranium metals dissolved therein from the U-Fe alloy and the metals dissolved therein.

Miller, William E. (Naperville, IL); Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Pierce, R. Dean (Naperville, IL)

1992-01-01T23:59:59.000Z

68

Reactions of Methylene Hydrogen  

E-Print Network [OSTI]

was orystallized out as a yellow solid from aloohol and then from ethyl aostate. Melting point 170°C Analysis: Calculated for C17H14O2U s - 10.10$ Found I = 10.00$ SUMMARY 0 It was found that the methods given in the literature for the preparation... following* 1. Metallic sodium replaces either one, or both of the hydrogens, the latter being given off as a free gas. 2. Sodium hydroxide replaces the hydrogen by the metal, with a splitting off of water. 3. Sodium ethylate reacts, giving the metal 3...

Griffin, E. L.

1912-05-15T23:59:59.000Z

69

Modeling acid-gas generation from boiling chloride brines  

SciTech Connect (OSTI)

This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

2009-11-16T23:59:59.000Z

70

Vinyl chloride monomer and other contaminants in PVC welding fumes  

SciTech Connect (OSTI)

An investigation into the nature of fumes produced during thermal welding of plasticized PVC sheeting has been carried out with the objective of determining if the known carcinogen vinyl chloride monomer (VCM) is formed and to assess the level of exposure to the operator. The results show that the atmospheric concentrations of VCM are well below accepted occupational exposure limits. This finding is consistent with reports in the technical literature which suggest that VCM is produced during thermal degradation of PVC only at temperatures considerably higher than those encountered during plastic welding.

Williamson, J.; Kavanagh, B.

1987-05-01T23:59:59.000Z

71

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method is described for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000 K to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, M.A.; Pereira, C.

1997-03-18T23:59:59.000Z

72

Method of preparing sodalite from chloride salt occluded zeolite  

DOE Patents [OSTI]

A method for immobilizing waste chloride salts containing radionuclides and hazardous nuclear material for permanent disposal starting with a substantially dry zeolite and sufficient glass to form leach resistant sodalite with occluded radionuclides and hazardous nuclear material. The zeolite and glass are heated to a temperature up to about 1000.degree. K. to convert the zeolite to sodalite and thereafter maintained at a pressure and temperature sufficient to form a sodalite product near theoretical density. Pressure is used on the formed sodalite to produce the required density.

Lewis, Michele A. (Naperville, IL); Pereira, Candido (Lisle, IL)

1997-01-01T23:59:59.000Z

73

Experience survey of chloride resistant alloys in process plants  

SciTech Connect (OSTI)

The Society of Chemical Engineers, Japan (SCEJ), and The Japan Petroleum Institute (JPI) have jointly surveyed the experience of so called Chloride-SCC resistant stainless steels in petrochemical plants and refinery plants. The survey covered more than one hundred cases of applications of duplex stainless steels, 400 series stainless steels, high nickel alloys and austenitic stainless steels. The survey included the following: (1) countermeasures taken in advance of or after the occurrence of the damage; (2) environmental conditions of the equipment considered; and (3) performance of the adopted countermeasure materials. As a conclusion, detailed analysis has clarified safe limits of SCC resistant alloys, some unexpected weak points, and remarkable performances.

Sakai, J. [Kokan Keisoku, Kawasaki (Japan); Matsumoto, Keiichi [Toyo Engineering Corp., Narashino, Chiba (Japan)

1999-11-01T23:59:59.000Z

74

The influence of chloride ions on the corrosion of copper in soil  

E-Print Network [OSTI]

work the influence of chloride ions upon corrosion behavior of copper in soil has been studied. Open circuit potential, linear polarization and overvoltage data were used to obtain a history of the instantaneous corrosion rate of copper in soil..., evidence exists that pitting corrosion of copper is intensified in the presence of chloride ions. The primary objective of this study was to determine quantitatively the influence of chloride ions upon the corrosion of copper in soil. Instantaneous...

Hirani, Raju K

1980-01-01T23:59:59.000Z

75

E-Print Network 3.0 - ammonium chloride pc Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Acetic acid was produced from... the carbonylation of methyl chloride by carbon monoxide over a variety of catalysts. The presence of promoters Source: Bao, Xinhe - State Key...

76

E-Print Network 3.0 - antimony chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tissuesw Summary: Laboratory Chemicals, Australia) or antimony(III) chloride (Merck, Germany) and potassium hexahydroxoanti... Observations on the measurement of total antimony...

77

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

zinc and chloride by atomic absorption by the spectroscopy.College The atomic absorption spectroscopy was performed ofrandom error is about atomic absorption spectroscopy. Many

Mc Vay, L.

2011-01-01T23:59:59.000Z

78

E-Print Network 3.0 - activates apical chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(freshwater apicalL15 media basolateral... and chloride cells, were examined. Lipids (labeled with 32 P and 14 C) were ... Source: Grosell, Martin - Rosenstiel School...

79

E-Print Network 3.0 - americium chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with NIST traceable standards: americium- 241 for alpha and strontium... , chlorobenzene, carbon tetrachloride, methyl chloride, and acetone) are analyzed under this category ......

80

E-Print Network 3.0 - aluminum sodium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

agents Water Acetyl chloride, alkaline and alkaline... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium ... Source: Hall, Sharon J. - School of Life Sciences, Arizona...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Electrodeposition of nickel-aluminum alloys from the aluminum chloride-1-methyl-3-ethylimidazolium chloride room temperature molten salt  

SciTech Connect (OSTI)

The electrodeposition of Ni and Ni-Al alloys on glassy carbon was investigated in the 66.7--33.3 mole percent (m/o) Al chloride-1-methyl-3-ethylimidazolium chloride molten salt containing electrogenerated Ni(II) at 40 C. The electrodeposition of Ni on glassy carbon involves 3-D progressive nucleation on a finite number of active sites with hemispherical diffusion-controlled growth of the nuclei. At potentials slightly more negative than those needed to induce the reduction of Ni(II) to the metal, Al is codeposited with Ni to produce Ni-Al alloys. Controlled-potential and controlled-current experiments revealed that it is possible to produce alloy deposits containing up to approximately 40 atomic percent (a/o) Al under conditions that circumvent the bulk deposition of Al. The Al content of the Ni-Al deposit was found to vary linearly with the deposition potential but nonlinearly with the current density. The electrodeposited Ni-Al alloys are thermodynamically unstable with respect to Ni(II), i.e., immersion of the alloy deposit in melt containing Ni(II) under open-circuit conditions leads to a reduction in the Al content of the alloy. The mechanism of alloy formation appears to involve underpotential deposition of Al on the developing Ni deposit; however, alloy formation must be kinetically hindered because the Al content is always less than predicted from theoretical considerations. Ni-Al alloys produced at 0.30 V in melt containing Ni(II) and 20% (w/w) benzene as a cosolvent contained about 15 a/o Ni and were of high quality with a disordered fcc structure, but alloys produced at more negative potentials had the visual appearance of a loosely adherent, finely divided, black powder and were heavily contaminated with chloride, probably as a result of the occlusion of the molten salt solvent by the dendritic alloy deposit during deposit growth.

Pitner, W.R.; Hussey, C.L. [Univ. of Mississippi, University, MS (United States). Dept. of Chemistry; Stafford, G.R. [National Inst. of Standards and Technology, Gaithersburg, MD (United States). Materials Science and Engineering Lab.

1996-01-01T23:59:59.000Z

82

Mortality and cancer morbidity in workers exposed to low levels of vinyl chloride monomer at a polyvinyl chloride processing plant  

SciTech Connect (OSTI)

To study whether exposure to low levels of vinyl chloride monomer (VCM) causes increased risk for cancer morbidity and death from ischemic heart disease, a cohort study was performed among 2,031 male workers at a polyvinyl chloride (PVC) processing plant who had been employed for at least 3 months during the period 1945-1980. An almost significantly increased total mortality (SMR = 116, 95% CI 99-136) was found. Deaths caused by violence or intoxication were significantly increased (SMR = 153, 95% CI 109-213), but not deaths from ischemic heart disease (SMR = 100, 95% CI 73-135). A significant increase in total cancer morbidity was observed (SMR = 128, 95% CI 101-161). Respiratory cancers were significantly increased (SMR = 213, 95% CI 127-346). Furthermore, six brain tumors (vs. 2.6 expected) were observed. This increase, however, was not significant (SMR = 229, 95% CI 84-498). No liver hemangiosarcoma was observed. Applying a latency period of greater than or equal to 10 years from start of employment did not change the risk patterns. There were no significant exposure-response associations between exposure estimates for VCM, asbestos, and plasticizers and cancer morbidity.

Hagmar, L.; Akesson, B.; Nielsen, J.; Andersson, C.; Linden, K.; Attewell, R.; Moeller, T. (University Hospital, Lund (Sweden))

1990-01-01T23:59:59.000Z

83

Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts  

E-Print Network [OSTI]

of commercially important materials like vinyl acetate monomer (VAM), cellulose acetate, and acetate esters. MoreAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan Ã? that makes use of the latest advance in methyl chloride production is reported. Acetic acid was produced from

Bao, Xinhe

84

Cohort and case-control analyses of workers exposed to vinyl chloride: An update  

SciTech Connect (OSTI)

The mortality in a cohort of workers at a vinyl chloride polymerization plant has been updated, extending the period of observation in the original study from 1974 to 1986. Workers at this plant may have been exposed to vinyl chloride monomer and/or polyvinyl chloride dust, or may have had no exposure to either substance. Seventy-six percent of the work force worked in jobs with potential exposure to vinyl chloride monomer. Among the total cohort, statistically significant excess risks were observed for liver, lung, and brain cancer. For the subcohort of workers exposed to vinyl chloride monomer, the standardized mortality ratio (SMR) for liver cancer was 333 (90% confidence interval (CI) 202 to 521). However, there were no significant excesses of either brain (SMR = 145, 90% CI 78 to 249) or lung cancer (SMR = 115, 90% CI 96 to 141). To investigate dose response, nested case-control studies for liver, brain, and lung cancer were conducted among the total cohort (including the nonexposed). For these studies there were two exposure variables, cumulative dose of vinyl chloride monomer and cumulative dose of polyvinyl chloride dust. Cumulative dose was defined as the product of level and duration of exposure. The only significant association between disease risk and cumulative dose was for liver cancer and cumulative dose of vinyl chloride monomer. Further division of the liver cancers into angiosarcoma (n = 12) and other liver cancers (n = 7), based on review of death certificates and medical records, showed that the dose response existed only for angiosarcomas.

Wu, W.A.; Steenland, K.; Brown, D.; Wells, V.; Jones, J.; Schulte, P.; Halperin, W.

1989-06-01T23:59:59.000Z

85

ORIGINAL PAPER Natural Fiber Reinforced Poly(vinyl chloride) Composites: Effect  

E-Print Network [OSTI]

ORIGINAL PAPER Natural Fiber Reinforced Poly(vinyl chloride) Composites: Effect of Fiber Type Science+Business Media, LLC 2008 Abstract Poly(vinyl chloride) (PVC) and natural fiber composites were copolymer on composite properties was investigated. Mechanical analysis showed that storage modulus

86

Investigation of the near-infrared spectral character of putative Martian chloride deposits  

E-Print Network [OSTI]

Investigation of the near-infrared spectral character of putative Martian chloride deposits Heidi B in near-infrared ratio spectra. It is hypothesized that the admixture of anhydrous chlorides or unoxidized of these deposits. Citation: Jensen, H. B., and T. D. Glotch (2011), Investigation of the near-infrared spectral

Glotch, Timothy D.

87

Influence of weather and global warming in chloride ingress into concrete: a stochastic approach  

E-Print Network [OSTI]

Influence of weather and global warming in chloride ingress into concrete: a stochastic approach E the influence of weather conditions and global warming on chloride ingress into concrete. The assessment including seasonal variations and global warming is also proposed in this work. Three scenarios of global

Paris-Sud XI, Université de

88

Effect of sodium chloride concentration on the heat resistance and recovery of  

E-Print Network [OSTI]

Effect of sodium chloride concentration on the heat resistance and recovery of Salmonella inhibitory effect in the recovery media. Keywords : Salmonella typhimurium, Sodium chloride, Heat treatment, but they also generate damaged cells. The ability of heated cells to survive depends on the recovery conditions

Paris-Sud XI, Université de

89

Control of structure and reactivity by ligand design : applications to small molecule activation by low-valent uranium complexes  

E-Print Network [OSTI]

methylene chloride and acetonitrile solvent molecules aremethylene chloride CH 3 CN acetonitrile calcd calculated xiiand co-crystallized benzene and acetonitrile are omitted for

Lam, Oanh Phi

2010-01-01T23:59:59.000Z

90

Structural study of 2,4,6-triisopropylbenzenesulfonyl chloride  

SciTech Connect (OSTI)

The structure of 2,4,6-triisopropylbenzenesulfonyl chloride (TPSCl) (I) was studied by X-ray diffraction. Compound I is a highly selective condensing agent first suggested by Khorana for the formation of the C3'-C5' interribonucleotide linkage in the oligo- and polyribonucleotide synthesis. I crystals are orthorhombic. At -120 deg. C, the unit-cell parameters are a = 14.184(4) A, b = 11.344(5) A, c = 19.883(6) A, V = 3199(2) A{sup 3}, d{sub calc} = 1.257 g/cm{sup 3}, Z = 8, sp. gr. Pbca. Molecule I adopts a strongly flattened boat conformation with the carbon atoms C-SO{sub 2}Cl (C{sub 1}) and C-i-Pr (C4) of the benzene ring deviating from the bottom of the boat by 0.065(1) and 0.032(1) A, respectively. Molecule I is sterically overcrowded, resulting in an increase in the bond lengths and bond-angle distortions in the fragment containing the SO{sub 2}Cl group and two ortho-i-Pr groups. Nonbonded contacts that are present in the molecule can be considered weak intramolecular hydrogen bonds (for example, the (CH{sub 3}){sub 2}C-H-O=S bond). There is no rotation of the SO{sub 2}Cl, ortho-i-Pr, and CH{sub 3} groups. The above-mentioned facts are, apparently, responsible for the specific selectivity of TPSCl. New readily available sterically hindered arenesulfonyl chlorides were designed.

Laba, V. I., E-mail: shchem@dol.ru; Sviridova, A. V. [Russian Academy of Sciences, Zelinsky Institute of Organic Chemistry (Russian Federation); Nesterov, V. N. [Russian Academy of Sciences, Nesmeyanov Institute of Organoelement Compounds (Russian Federation)

2009-01-15T23:59:59.000Z

91

Estimation of Groundwater Recharge at Pahute Mesa using the Chloride Mass-Balance Method  

SciTech Connect (OSTI)

Groundwater recharge on Pahute Mesa was estimated using the chloride mass-balance (CMB) method. This method relies on the conservative properties of chloride to trace its movement from the atmosphere as dry- and wet-deposition through the soil zone and ultimately to the saturated zone. Typically, the CMB method assumes no mixing of groundwater with different chloride concentrations; however, because groundwater is thought to flow into Pahute Mesa from valleys north of Pahute Mesa, groundwater flow rates (i.e., underflow) and chloride concentrations from Kawich Valley and Gold Flat were carefully considered. Precipitation was measured with bulk and tipping-bucket precipitation gauges installed for this study at six sites on Pahute Mesa. These data, along with historical precipitation amounts from gauges on Pahute Mesa and estimates from the PRISM model, were evaluated to estimate mean annual precipitation. Chloride deposition from the atmosphere was estimated by analyzing quarterly samples of wet- and dry-deposition for chloride in the bulk gauges and evaluating chloride wet-deposition amounts measured at other locations by the National Atmospheric Deposition Program. Mean chloride concentrations in groundwater were estimated using data from the UGTA Geochemistry Database, data from other reports, and data from samples collected from emplacement boreholes for this study. Calculations were conducted assuming both no underflow and underflow from Kawich Valley and Gold Flat. Model results estimate recharge to be 30 mm/yr with a standard deviation of 18 mm/yr on Pahute Mesa, for elevations >1800 m amsl. These estimates assume Pahute Mesa recharge mixes completely with underflow from Kawich Valley and Gold Flat. The model assumes that precipitation, chloride concentration in bulk deposition, underflow and its chloride concentration, have been constant over the length of time of recharge.

Cooper, Clay A [DRI] [DRI; Hershey, Ronald L [DRI] [DRI; Healey, John M [DRI] [DRI; Lyles, Brad F [DRI] [DRI

2013-07-01T23:59:59.000Z

92

The effects of mepiquat chloride on the water relations of cotton  

E-Print Network [OSTI]

(Member) C. R. Benedict (Nember) Norris G. Nerkle (Member) (Department Head) E. C. A. Runge Nay 1983 ABSTRACT The Effects of Mepiquat Chloride on the Water Relations of Cotton (May 1983) Bryan Lee Stuart, B. S. , Texas A&M University Co...-Chairmen of Advisory Committee: Dr. C. W. Wendt Dr. J. R. Abernathy Field tests were conducted in 1979 and 1980 near Lubbock, Texas to determine the effects of the growth regulator mepiquat chloride (1, 1 dimethyl piperidinium chloride) on t (~G' h L. ) t *1 t...

Stuart, Bryan Lee

1983-01-01T23:59:59.000Z

93

Tolerance Test of Eisenia Fetida for Sodium Chloride  

SciTech Connect (OSTI)

Saltwater spills that make soil excessively saline often occur at petroleum exploration and production (E&P) sites and are ecologically damaging. Brine scars appear when produced water from an E&P site is spilled onto surrounding soil, causing loss of vegetation and subsequent soil erosion. Revegetating lands damaged by brine water can be difficult. The research reported here considers earthworms as a bioremedial treatment for increasing the salt mobility in this soil and encouraging plant growth and a healthy balance of soil nutrients. To determine the practical application of earthworms to remediate brine-contaminated soil, a 17-d test was conducted to establish salt tolerance levels for the common compost earthworm (Eisenia fetida) and relate those levels to soil salinity at brine-spill sites. Soil samples were amended with sodium chloride in concentrations ranging from 1 to 15 g/kg, which represent contamination levels at some spill sites. The survival rate of the earthworms was near 90% in all tested concentrations. Also, reproduction was noted in a number of the lower-concentration test replicates but absent above the 3-g/kg concentrations. Information gathered in this investigation can be used as reference in further studies of the tolerance of earthworms to salty soils, as results suggest that E. fetida is a good candidate to enhance remediation at brine-damaged sites.

Kerr, M.; Stewart, A.J.

2003-01-01T23:59:59.000Z

94

Chloride, bromide and iodide scintillators with europium doping  

DOE Patents [OSTI]

A halide scintillator material is disclosed where the halide may comprise chloride, bromide or iodide. The material is single-crystalline and has a composition of the general formula ABX.sub.3 where A is an alkali, B is an alkali earth and X is a halide which general composition was investigated. In particular, crystals of the formula ACa.sub.1-yEu.sub.yI.sub.3 where A=K, Rb and Cs were formed as well as crystals of the formula CsA.sub.1-yEu.sub.yX.sub.3 (where A=Ca, Sr, Ba, or a combination thereof and X=Cl, Br or I or a combination thereof) with divalent Europium doping where 0.ltoreq.y.ltoreq.1, and more particularly Eu doping has been studied at one to ten mol %. The disclosed scintillator materials are suitable for making scintillation detectors used in applications such as medical imaging and homeland security.

Zhuravleva, Mariya; Yang, Kan

2014-08-26T23:59:59.000Z

95

Conversion of waste polyvinyl chloride (PVC) to useful chemicals  

SciTech Connect (OSTI)

Developments of recycling technologies are expected one of the most important keys for saving energy and resources, and minimization impact for environment. For instance, combustion of waste for power generation and conversion of plastics into liquid fuels have been studying for thermal energy recycling. However, PVC has been excepted from the most of these experiments. Because, heat of combustion of PVC is almost a half of other plastics, hydrogen chloride, which is produced at low temperature, corrodes the combustion chamber, and PVC causes coking reaction during pyrolysis of plastics. Numerous investigations have been conducted on degradation of PVC. However, most of these experiments were done to improve heat resistance of PVC or to study reaction mechanism of PVC degradation. Pyrolysis of PVC into liquid products have been studying since 1960`s from a view of environmental protection. Recently, Y. Maezawa et al. reported PVC was converted into oil at 600 T with sodium hydroxide. However, more than 50 % of hydrocarbon fraction of PVC was converted to residue and gas in their experiment. We are going to develop a new technology to convert of PVC into useful chemicals or liquid fuels at high efficiency by using hydrogen donor solvent.

Kamo, T.; Yamamoto, Y.; Miki, K.; Sato, Y. [National Institute for Resources and Environment, Tsukuba-shi, Ibaraki (Japan)

1995-12-31T23:59:59.000Z

96

Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns  

E-Print Network [OSTI]

Chloride and Lithium Transport in Large Arrays of Undisturbed Silt Loam and Sandy Loam Soil Columns al., 1998); and (iii) sloping lay- were extremely variable among columns. Lithium adsorption

Walter, M.Todd

97

Degradation of Vinyl Chloride and 1,2-Dichloroethane by Advanced Reduction Processes  

E-Print Network [OSTI]

A new treatment technology, called Advanced Reduction Process (ARP), was developed by combining UV irradiation with reducing reagents to produce highly reactive species that degrade contaminants rapidly. Vinyl chloride (VC) and 1,2-dichloroethane (1...

Liu, Xu

2013-07-27T23:59:59.000Z

98

Iron (III) Chloride doping of large-area chemical vapor deposition graphene  

E-Print Network [OSTI]

Chemical doping is an effective method of reducing the sheet resistance of graphene. This thesis aims to develop an effective method of doping large area Chemical Vapor Deposition (CVD) graphene using Iron (III) Chloride ...

Song, Yi, S.M. Massachusetts Institute of Technology

2013-01-01T23:59:59.000Z

99

E-Print Network 3.0 - anhydrous magnesium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

magnesium ion concentration dependence of strand exchange... M Tris-acetate or Tris-HCI (pH 7.5), IO mM magnesium acetate or magnesium chloride, 3.7% glycerol, 1 m... and...

100

E-Print Network 3.0 - apical chloride channels Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

P2Y-mediated activation of a CFTR-like channel (1). ATP not only increased chloride... secretion, but it also increased the capacitance of the apical ... Source: Burnstock,...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Release mechanism of octadecyl rhodamine B chloride from Au nanorods by ultrafast laser pulses  

E-Print Network [OSTI]

We investigated the release of octadecyl rhodamine B chloride (R[subscript 18]) loaded onto cetyltrimethylammonium bromide (CTAB) coated gold nanorods (NR) by pulsed ultrafast laser excitation. R[subscript 18] intercalates ...

Alper, Joshua Daniel

102

Electron Beam Damage in Poly(Vinyl Chloride) and Poly(Acrylonitrile...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electron Spectroscopy. Abstract: AES spectra of spun-cast films of poly(vinyl chloride) (PVC) and poly(acrylonitrile) (PAN) were collected over a period of time to determine...

103

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate Solutions  

E-Print Network [OSTI]

Sodium-Copper Exchange on Wyoming Montmorillonite in Chloride, Perchlorate, Nitrate, and Sulfate. The copper exchange capacity (CuEC) and Na-Cu exchange reactions on Wyoming montmo- rillonite were studied

Sparks, Donald L.

104

Contribution of garbage burning to chloride and PM[subscript 2.5] in Mexico City  

E-Print Network [OSTI]

The contribution of garbage burning (GB) emissions to chloride and PM[subscript 2.5] in the Mexico City Metropolitan Area (MCMA) has been investigated for the period of 24 to 29 March during the MILAGRO-2006 campaign using ...

Li, G.

105

Method for immobilizing mixed waste chloride salts containing radionuclides and other hazardous wastes  

DOE Patents [OSTI]

The invention is a method for the encapsulation of soluble radioactive waste chloride salts containing radionuclides such as strontium, cesium and hazardous wastes such as barium so that they may be permanently stored without future threat to the environment. The process consists of contacting the salts containing the radionuclides and hazardous wastes with certain zeolites which have been found to ion exchange with the radionuclides and to occlude the chloride salts so that the resulting product is leach resistant.

Lewis, Michele A. (Naperville, IL); Johnson, Terry R. (Wheaton, IL)

1993-01-01T23:59:59.000Z

106

A study of the reaction between antimony (III) chloride and organic amine hydrochlorides  

E-Print Network [OSTI]

A STUDY OF THE REACTION BET'WEEN ANTIMONY PII) CHLORIDE AND ORGANIC AMINE HYDROCHLORIDES A Thesis by Donald Ernst Linder Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE January, 1964 Major Subject: Chemistry A STUDY OF THE REACTION BETWEEN ANTIMONY (III) CHLORIDE AND ORGANIC AMINE HYDROCHLORIDES A Thesis by Donald Ernst Linder Approved as to style and content by: r rf (- &t r (Head...

Linder, Donald Ernst

1964-01-01T23:59:59.000Z

107

The phase behavior and absorption spectra of the ternary system cobaltous chloride-water-acetonitrile  

E-Print Network [OSTI]

CONCIUSION Interpretation of Zxoerimental Results Summary and Suggestions for Further Study APP 'NDICES ~ 1 3 8 11 12 14 15 15 24 36 36 39 41 Cobaltous Chloride-Nater Solutions Prepared for Phase Diagram Determination . Cobaltous Chloride-Acetonitrile... Solutions Prepared for Phase Diagram Determination . Density of Acetonitrile as 1'unction of Temperature BIBLIOGRAPHY 44 45 LIST OF TABLES A%3 FIGURZS TABLE 1 Activity Coefficients of Acetonitrile and Water in a Binary Solution 1'age TAB'Z 2 Pnase...

Bobbitt, Jeffrey Lovett

1967-01-01T23:59:59.000Z

108

Evaluation of PFP Furnace Systems for Thermal Stabilization of Washed High Chloride Plutonium Oxide Items  

SciTech Connect (OSTI)

High chloride content plutonium (HCP) oxides are impure plutonium oxide scrap which contains NaCl, KCl, MgCl2 and/or CaCl2 salts at potentially high concentrations and must be stabilized at 950 C per the DOE Standard, DOE-STD-3013-2000. The chlorides pose challenges to stabilization because volatile chloride salts and decomposition products can corrode furnace heating elements and downstream ventilation components. A high-temperature furnace (same make and model as used at the RMC at Plutonium Finishing Plant) and the associated offgas system were set up at PNNL to identify system vulnerabilities and to investigate alternative materials and operating conditions that would mitigate any corrosion and plugging of furnace and offgas components. The key areas of interest for this testing were the furnace heating elements, the offgas line located inside the furnace, the offgas line between the furnace and the filter/knockout pot, the filter/knockout pot, the sample boat, and corrosion coupons to evaluate alternative materials of construction. The evaluation was conducted by charging the furnace with CeO2 that had been impregnated with a mixture of chloride salts (selected to represent the expected residual chloride salt level in washed high chloride items) and heated in the furnace in accordance with the temperature ramp rates and hold times used at PFP.

Fischer, Christopher M.; Elmore, Monte R.; Schmidt, Andrew J.; Gerber, Mark A.; Muzatko, Danielle S.; Gano, Susan R.; Thornton, Brenda M.

2002-12-17T23:59:59.000Z

109

Strontium-copper selenite-chlorides: Synthesis and structural investigation  

SciTech Connect (OSTI)

Two new complex selenite-chlorides of strontium and copper Sr{sub 2}Cu(SeO{sub 3}){sub 2}Cl{sub 2} (I) and SrCu{sub 2}(SeO{sub 3}){sub 2}Cl{sub 2} (II) were obtained and characterized by X-ray diffraction technique, DTA and IR spectroscopy. Both compounds crystallize in the monoclinic system I: Sp. gr. P2{sub 1}/n, a=5.22996(3) A, b=6.50528(4) A, c=12.34518(7) A, beta=91.3643(2){sup o}, Z=2; II: Sp. gr. P2{sub 1}, a=7.1630(14) A, b=7.2070(14) A, c=8.0430(16) A, beta=95.92(3){sup o}, Z=2. Comparison of the crystal structure of (I) with the structures of Sr{sub 2}M(SeO{sub 3}){sub 2}Cl{sub 2} (M=Co, Ni) was performed. The substitution of strontium atom in the structure of (I) by Cu{sup 2+} ion with a 3d{sup 9} Jahn-Teller distorted surrounding leads to the lowering of the structure symmetry and to the appearance of the noncentrosymmetric structure of (II). The noncentrosymmetric character of the structure of (II) was confirmed by SHG signal (1.2 units relative to an alpha-quartz powder sample). - Graphical abstract: Sr{sub 2}Cu(SeO{sub 3}){sub 2}Cl{sub 2} and SrCu{sub 2}(SeO{sub 3}){sub 2}Cl{sub 2} were obtained and characterized by X-ray diffraction technique, DTA and IR spectroscopy.

Berdonosov, Peter S., E-mail: berdonosov@inorg.chem.msu.r [Department of Chemistry, Moscow State University, 119991 GSP-1, Leninskie Gory, 1 build. 3, Moscow (Russian Federation); Olenev, Andrei V.; Dolgikh, Valery A. [Department of Chemistry, Moscow State University, 119991 GSP-1, Leninskie Gory, 1 build. 3, Moscow (Russian Federation)

2009-09-15T23:59:59.000Z

110

Raman spectroscopic studies of chemical speciation in calcium chloride melts  

SciTech Connect (OSTI)

Raman spectroscopy was applied to CaCl2 melts at 900 degrees C under both non-electrolyzed and electrolyzed conditions. The later used titania cathodes supplied by TIMET, Inc. and graphite anodes. Use of pulse-gating to collect the Raman spectra successfully eliminated any interference from black-body radiation and other stray light. The spectrum of molten CaCl2 exhibited no distinct, resolvable bands that could be correlated with a calcium chloride complex similar to MgCl42- in MgCl2 melts. Rather, the low frequency region of the spectrum was dominated by a broad “tail” arising from collective oscillations of both charge and mass in the molten salt “network.” Additions of both CaO and Ca at concentrations of a percent or two resulted in no new features in the spectra. Addition of CO2, both chemically and via electrolysis at concentrations dictated by stability and solubility at 900 degrees C and 1 bar pressure, also produced no new bands that could be correlated with either dissolved CO2 or the carbonate ion. These results indicated that Raman spectroscopy, at least under the conditions evaluated in the research, was not well suited for following the reactions and coordination chemistry of calcium ions, nor species such as dissolved metallic Ca and CO2 that are suspected to impact current efficiency in titanium electrolysis cells using molten CaCl2. Raman spectra of TIMET titania electrodes were successfully obtained as a function of temperature up to 900 degrees C, both in air and in-situ in CaCl2 melts. However, spectra of these electrodes could only be obtained when the material was in the unreduced state. When reduced, either with hydrogen or within an electrolysis cell, the resulting electrodes exhibited no measurable Raman bands under the conditions used in this work.

Windisch, Charles F.; Lavender, Curt A.

2005-02-01T23:59:59.000Z

111

Respiratory symptoms among glass bottle makers exposed to stannic chloride solution and other potentially hazardous substances  

SciTech Connect (OSTI)

Concern about upper respiratory tract irritation and other symptoms among workers at a glass bottle manufacturing plant led to an epidemiologic and an industrial hygiene survey. Questionnaire responses from 35 hot end and 53 cold end workers indicated that the incidence of wheezing, chest pain, dyspnea on exertion, and cough was significantly elevated among hot end workers. Among both smokers and nonsmokers, hot end workers reported higher, but not significantly higher, rates of wheezing and chest pain. Among smokers, hot end workers reported significantly higher rates of dyspnea on exertion and cough than did cold end workers. Data suggest that reported exposure to stannic chloride solution likely caused these symptoms. The industrial hygiene survey, conducted when stannic chloride use had been reduced, cleaning had been done, and ventilation improved, focused on measuring air contaminants that might possibly cause symptoms. Levels of hydrogen chloride, which apparently was formed by the combination of stannic chloride and water in the presence of heat, were elevated. The finding of increased prevalence of respiratory symptoms among hot end workers was consistent with this exposure. Recommendations were made to reduce hazardous exposures at this plant. Individuals responsible for occupational health should be aware that relatively benign substances, such as stannic chloride and water, can combine spontaneously to form hazardous substances.

Levy, B.S.; Davis, F.; Johnson, B.

1985-04-01T23:59:59.000Z

112

Effect of chloride content of molten nitrate salt on corrosion of A516 carbon steel.  

SciTech Connect (OSTI)

The corrosion behavior of A516 carbon steel was evaluated to determine the effect of the dissolved chloride content in molten binary Solar Salt. Corrosion tests were conducted in a molten salt consisting of a 60-40 weight ratio of NaNO{sub 3} and KNO{sub 3} at 400{sup o}C and 450{sup o}C for up to 800 hours. Chloride concentrations of 0, 0.5 and 1.0 wt.% were investigated to determine the effect on corrosion of this impurity, which can be present in comparable amounts in commercial grades of the constituent salts. Corrosion rates were determined by descaled weight losses, corrosion morphology was examined by metallographic sectioning, and the types of corrosion products were determined by x-ray diffraction. Corrosion proceeded by uniform surface scaling and no pitting or intergranular corrosion was observed. Corrosion rates increased significantly as the concentration of dissolved chloride in the molten salt increased. The adherence of surface scales, and thus their protective properties, was degraded by dissolved chloride, fostering more rapid corrosion. Magnetite was the only corrosion product formed on the carbon steel specimens, regardless of chloride content or temperature.

Bradshaw, Robert W.; Clift, W. Miles

2010-11-01T23:59:59.000Z

113

Free energy, enthalpy, and entropy changes for the transference of zinc chloride from enthylene glycol to water solutions  

E-Print Network [OSTI]

in ethylene glycol is coupled with a silver-silver chloride half-cell, also containing zinc chloride dissolved in ethylene glycol, and if a similar cell with zinc chloride in aqueous solution are put back to back by use of a common amalgam reservoir...FREE ENERGY, ENTlDKPY, AND ENTROPY CHANGES FOR THE TRANCE OF ZINC CHLORIDE FROM ETHYLENE GLYCOL TO WATER SOLUTIONS A Thesis JOHN NICHOLAS'8 LOMONTE Submitted to the Graduate School of' the Agricultural and. Mechanical College of' Texas...

Lomonte, John Nicholas

1960-01-01T23:59:59.000Z

114

Current techniques in acid-chloride corrosion control and monitoring at The Geysers  

SciTech Connect (OSTI)

Acid chloride corrosion of geothermal well casings, production piping and power plant equipment has resulted in costly corrosion damage, frequent curtailments of power plants and the permanent shut-in of wells in certain areas of The Geysers. Techniques have been developed to mitigate these corrosion problems, allowing continued production of steam from high chloride wells with minimal impact on production and power generation facilities.The optimization of water and caustic steam scrubbing, steam/liquid separation and process fluid chemistry has led to effective and reliable corrosion mitigation systems currently in routine use at The Geysers. When properly operated, these systems can yield steam purities equal to or greater than those encountered in areas of The Geysers where chloride corrosion is not a problem. Developments in corrosion monitoring techniques, steam sampling and analytical methodologies for trace impurities, and computer modeling of the fluid chemistry has been instrumental in the success of this technology.

Hirtz, Paul; Buck, Cliff; Kunzman, Russell

1991-01-01T23:59:59.000Z

115

Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene  

SciTech Connect (OSTI)

We examine the time-resolved resonance energy transfer of excitons from single n-butyl amine-bound, chloride-terminated nanocrystals to two-dimensional graphene through time-correlated single photon counting. The radiative biexponential lifetime kinetics and blinking statistics of the individual surface-modified nanocrystal elucidate the non-radiative decay channels. Blinking modification as well as a 4× reduction in spontaneous emission were observed with the short chloride and n-butylamine ligands, probing the energy transfer pathways for the development of graphene-nanocrystal nanophotonic devices.

Ajayi, O. A., E-mail: oaa2114@columbia.edu, E-mail: cww2104@columbia.edu; Wong, C. W., E-mail: oaa2114@columbia.edu, E-mail: cww2104@columbia.edu [Optical Nanostructures Laboratory, Center for Integrated Science and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027 (United States); Department of Mechanical Engineering, Columbia University, New York, New York 10027 (United States); Anderson, N. C.; Wolcott, A.; Owen, J. S. [Department of Chemistry, Columbia University, New York, New York 10027 (United States); Cotlet, M. [Brookhaven National Laboratory, Upton, New York, New York 11973 (United States); Petrone, N.; Hone, J. [Department of Mechanical Engineering, Columbia University, New York, New York 10027 (United States); Gu, T.; Gesuele, F. [Optical Nanostructures Laboratory, Center for Integrated Science and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027 (United States)

2014-04-28T23:59:59.000Z

116

An investigation of the transfer of alkali metal chlorides from dimethyl sulfoxide to water  

E-Print Network [OSTI]

-to-back' with water as the solvent in one cell and a non- aqueous solvent in the other. The two cells used in this investigation were each composed of silver-silver chloride electrodes in the same solution with dropping alkali metal amalgam electrodes. The solute.... The dropping amalgam electrodes are written only once since they were connected by a common amalgam reservoir. When the external circuit between the two silver-silver chloride electrodes was closed a current flowed and the net result oi the electrode...

Williams, Roger

1966-01-01T23:59:59.000Z

117

A description of the vapor phase in the lithium thionyl chloride battery  

E-Print Network [OSTI]

A DESCRIPTION OF TIIE YAPOP, PHASE IN THF. LITHIUM THIONYI. CHLORIDE BATTERY A Thesis by RODOLFO MORALES, JR. Submitted to the Graduate College of Texas AEzM University in partial fulfrHment of the requirement for the degree oi' MASTER... OF SCIENCE August 1988 Major Subject: Chemical Engineering A DESCRIPTION OF THE VAPOR PHASE IN THE LITHIUM THIONYL CHLORIDE BATTERY A Thesis bv RODOLFO 'vIORALES, JR. Approved as to style and content by: Ralph E. White (Chairman of Committee) James...

Morales, Rodolfo

1988-01-01T23:59:59.000Z

118

Evaluation of calcium chloride and ammonium thiosulfate as ammonia volatilization inhibitors for surface-applied urea  

E-Print Network [OSTI]

(Fenn and Kissel, 1973). Ammonia exiting the soil chainber with the air-flow was captured in a boric acid indicator trap containing 40 mL of boric acid indicator solution. The boric acid indicator traps were changed every 24 h and titrated... as 90%. Calcium chloride reacts with the (NH4)2CO2 formed during urea hydrolysis in the following manner: (NH4)2CO2 + CaC12 CaCO& + 2NH4C1 Ammonium chloride is a slightly acidic product and does not produce (NH4)2CO2 in a calcareous soil. Ammonia...

Sloan, John J.

1989-01-01T23:59:59.000Z

119

Synthesis of macrocycles and their biological evaluation as antitumor and antibacterial agents  

E-Print Network [OSTI]

methylene chloride and acetonitrile (1:1) to 0.1M. Reactionsmethylene chloride and acetonitrile (1:1 ratio) resulting inmethylene chloride and acetonitrile (1:1 ratio, 0.1M). The

Pan, Po-Shen

2008-01-01T23:59:59.000Z

120

Hot Pin Welding of Thin Poly(vinyl chloride) Sheet James D. Van de Ven, Arthur G. Erdman  

E-Print Network [OSTI]

Hot Pin Welding of Thin Poly(vinyl chloride) Sheet James D. Van de Ven, Arthur G. Erdman Mechanical of welding two thin sheets of poly(vinyl chloride) (PVC) with a heated pin, thus allowing construction of a relationship between the weld temperature and weld strength. Constructing a relationship between weld strength

Van de Ven, James D.

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Facilitated transport of sodium or potassium chloride across vesicle membranes using a ditopic salt-binding macrobicycle  

E-Print Network [OSTI]

Facilitated transport of sodium or potassium chloride across vesicle membranes using a ditopic salt or potassium chloride as a contact ion-pair, is shown to effect- ively transport either salt across vesicle membranes. Sig- nificant transport is observed even when the transporter : phospholipid ratio is as low as 1

Smith, Bradley D.

122

Theoretical Study of Solvent Effects on the Thermodynamics of Iron(III) [Tetrakis(pentafluorophenyl)]porphyrin Chloride Dissociation  

E-Print Network [OSTI]

on the extent of iron(III) [tetrakis- (pentafluorophenyl)]porphyrin chloride dissociation in acetonitrile in acetonitrile primarily because of the strong specific interactions between the chloride anion and the solvent methanol molecules in its first solvation shell. These interactions are weaker in acetonitrile. The final

Bell, Alexis T.

123

Photochemistry of Matrix-Isolated and Thin Film Acid Chlorides: Quantum Yields and Product Structures  

E-Print Network [OSTI]

the differences between gas- and condensed-phase photochemistry strengthens our understanding of many, and well-known gas-phase reaction mechanisms are often modified in the condensed phase or completely the photoreaction of condensed acid chloride samples by comparison of reaction quantum yields for acetyl (CH3COCl

Ellison, Barney

124

The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments  

E-Print Network [OSTI]

The Corrosion / Electrochemistry of Beryllium and Beryllium Weldments in Aqueous Chloride Environments submitted by: Mary Ann Hill, Darryl P. Butt, R. Scott Lillard Materials Corrosion year. Our goals for FY '96 were two-fold: 1) develop a sensor for monitoring the corrosion of beryllium

125

Simultaneous measurement of laser reflection and transmission of poly,,vinyl chloride...  

E-Print Network [OSTI]

, unpigmented state are highly transmissive of light in the near-infrared range, al- lowing laser transmissionSimultaneous measurement of laser reflection and transmission of poly,,vinyl chloride... James D reflection, emphasizing the light transmitted through a material. This paper presents work creating a low

Van de Ven, James D.

126

Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion  

E-Print Network [OSTI]

1 Hydrogen and chloride ions effects on the automobile interstitial-free steel corrosion L.Q. Guo 1 abilities of deep formability and fatigue resistance [1,2]. As the main material of the automobile's body. The high susceptibility to atmospheric corrosion limits the automobile steel applications. Although

Volinsky, Alex A.

127

Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies  

E-Print Network [OSTI]

1 Bonding in Sodium Chloride Nanotubes: A New Analysis via Madelung Constants and Cohesive Energies is introduced which employs a linear relationship between nanotube cohesive energies determined via Density between ionic and cohesive bonding energies indicate that, as the nanotubes become longer, ionic bonding

Hanusa, Christopher

128

Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow  

E-Print Network [OSTI]

Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow W.B. Gu and C.Y. Wang GATE Center of Excellence for Advanced Energy Storage Department of Mechanical are performed using a finite volume method of computational fluid dynamics. The predicted discharge curves

Wang, Chao-Yang

129

EFFECT OF INITIAL SCARIFICATION AND OVERLAY TREATMENT1 TIMING ON CHLORIDE CONCENTRATIONS  

E-Print Network [OSTI]

.nolan@kiewit.com and Dale P. Bentz Chemical Engineer Inorganic Materials Group Materials and Construction Research Division 8615 Gaithersburg, MD 20899 (301) 975-5865 Voice (301) 990-6891 Fax dale.bentz@nist.gov Transportation of reinforcing steel due to chloride ingress. Given the need to develop guidelines for the initial timing of SO

Bentz, Dale P.

130

Nucleophilic substitutions of 1-alkenylcyclopropyl esters and 1-alkynylcyclopropyl chlorides catalyzed by palladium (0)  

SciTech Connect (OSTI)

The 1-ethenylcyclopropylsulfonates 2e,f and 2-cyclopropylideneethyl esters 10b,c, readily available from cyclopropanone hemiacetal 1, undergo regioselective Pd(0) catalyzed nucleophilic substitution via the unsymmetric 1,1-dimethylene-{pi}-allyl complex 23. With stabilized anions (enolates of malonic ester, {beta}-dicarbonyl compounds, {beta}-sulfonyl ester, and Schiff bases as well as acetate anion, sulfonamide anion, etc.) the nucleophilic substitution occurs at the terminal vinylic position exclusively, providing cyclopropylideneethyl derivatives as building blocks of high synthetic potential. Competition experiments have disclosed that 1-ethenylcyclopropyl tosylate (2e) and cyclopropylideneethyl acetate (10b) are more reactive than dimethylallyl acetates 19 and 22, respectively. Use of chiral phosphines as ligands in the palladium catalyst can provide optically active methylenecyclopropane derivatives. With phenyl-, methyl-, and even n-butylzinc chloride as nucleophiles, the reaction apparently proceeds with initial transfer of the organic residue to palladium, followed by reductive elimination entailing tertiary substitution on the cyclopropane ring exclusively; the same type of product is obtained with azide and bis(trimethylsilyl)amide. But the site of hydride attack to yield reduction products depends on the hydride source. 1-Alkynylcyclopropyl chlorides 12, 13, and 14 react only with organozinc chlorides (nonstabilized nucleophiles) to provide mixtures of ethenylidenecyclopropanes 65 and alkynylcyclopropanes 66, via the {sigma}-palladium complexes 69 and 70, while chloride 15 undergoes mainly reduction. Other transition metal catalysts (Ni, Mo) also induce substitutions, but with poorer regioselectivity. 81 refs., 9 figs., 3 tabs.

Stolle, A. [George-August-Universitaet, Goettingen (Germany)]|[Universite de Paris-Sud, Orsay (France); Ollivier, J.; Salauen, J. [Universite de Paris-Sud, Orsay (France)] [and others

1992-05-20T23:59:59.000Z

131

Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride  

E-Print Network [OSTI]

Chlorination of dibenzofuran and dibenzo-p-dioxin vapor by copper (II) chloride Jae-Yong Ryu, James limited in- vestigation of dibenzo-p-dioxin (DD) chlorination by CuCl2 to form chlorinated DD (CDD 2003 Elsevier Science Ltd. All rights reserved. Keywords: Dibenzofuran; Dibenzo-p-dioxin; CDF; CDD

Mulholland, James A.

132

Note and Record A note on polyvinyl chloride (PVC) pipe traps for  

E-Print Network [OSTI]

Note and Record A note on polyvinyl chloride (PVC) pipe traps for sampling vegetation of traditional traps, and many are furtive (Myers et al., 2007; Pittman et al., 2008). PVC pipe traps, which and Hyperolius (see Channing, 2001; du Preez & Carruthers, 2009), may be attracted to artificial refugia of PVC

Pretoria, University of

133

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators  

E-Print Network [OSTI]

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators Reza Loloee1@msu.edu Abstract--Dissolved oxygen concentration is considered the most important water quality variable in fish culture. Reliable and continuous (24/7) oxygen monitoring of dissolved oxygen (DO) in the 1 ­ 11 mg

Ghosh, Ruby N.

134

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures  

E-Print Network [OSTI]

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures James D. Van de Ven, unpigmented state are highly transmissive of light in the near-infrared range, thus allowing laser of light detection [2, 3]. Within the near-infrared region nat- ural polymers have nearly no absorption [2

Van de Ven, James D.

135

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion of Silver  

E-Print Network [OSTI]

Effects of Sodium Chloride Particles, Ozone, UV, and Relative Humidity on Atmospheric Corrosion The corrosion of Ag contaminated with NaCl particles in gaseous environments containing humidity and ozone analyzed using a coulometric reduction technique. The atmospheric corrosion of Ag was greatly accelerated

136

Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration Devices  

E-Print Network [OSTI]

be seen in the field. Based on model results, shallow groundwater will be rapidly and highly impactedModeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration device. Introduction Urbanization has increased the amount of impervious surfaces, leading to an increase

Clark, Shirley E.

137

Ultraviolet irradiation selectively disrupts the gamma-aminobutyric acid/benzodiazepine receptor-linked chloride ionophore  

SciTech Connect (OSTI)

The ability of UV light to affect radioligand binding and 36Cl-uptake at the gamma-aminobutyric acidA (GABAA) receptor-chloride channel complex was examined. Exposure to 302 nm UV light produced a rapid (t1/2 = 4 min) reduction in (35S)t-butylbicyclo-phosphorothionate binding (assayed in the presence of 200 mM chloride) to sites associated with the GABAA receptor-coupled chloride ionophore. Saturation analysis revealed that this effect could be attributed entirely to a decrease in the maximum number of binding sites. Exposure to UV irradiation at lower (254 nm) and higher (366 nm) wavelengths also inhibited (35S)t-butylbicy-clophosphorothionate binding, but the respective rates of inactivation were 8- and 27-fold slower, compared with 302 nm. Other anion-dependent interactions at the GABAA receptor complex were disrupted in a similar manner. In the absence of permeant anion, (3H)flunitrazepam binding to benzodiazepine receptors was unaffected by 302 nm UV irradiation, whereas chloride-enhanced (3H)flunitrazepam binding was inhibited markedly. In the presence of 250-500 mM chloride, (3H)methyl-6,7-dimethoxy-4-ethyl-beta-carboline-3-carboxylate binding to benzodiazepine receptors was also inhibited after UV exposure. Basal 36Cl- uptake into synaptoneurosomes was nearly doubled after 15 min of exposure to 302 nm light, whereas pentobarbital- and muscimol-stimulated 36Cl- uptake were reduced significantly. UV irradiation at 302 nm appears to disrupt selectively the anion-dependent functional interactions at the GABAA receptor complex. The apparent wavelength specificity suggests that the gating structure (channel) may contain tryptophan and/or tyrosine residues vital to the regulation of anion movement through the ionophore portion of this supramolecular receptor-ion channel complex.

Evoniuk, G.; Moody, E.J.; Skolnick, P. (National Institute of Diabetes and Digestive and Kidney Diseases, Bethesda, MD (USA))

1989-05-01T23:59:59.000Z

138

Photochemical oxidation of coals and some selected model compounds by using copper(II) chloride  

SciTech Connect (OSTI)

The H-donor ability of different rank coals was examined by using a copper(II)chloride-acetonitrile system as the dehydrogenator. A bituminous coal and two lignites were irradiated in the UV in the presence of copper(II)chloride in acetonitrile. The coal was dehydrogenated while the Cu(II) was reduced to CU(I). Considerable amounts of aliphatic or alicyclic hydrogen were removed from the coals. In the process, while the oxygen contents of coals do not increase, more condensed aromatic products occur. It was concluded that lignites are better reducing agents than bituminous coals. A photooxidation mechanism is proposed on the basis of the model compound reaction. Photooxidation of alcohols (ethanol, 2-propanol, benzyl alcohol, 4-hydroxybenzyl alcohol, and diphenyl carbinol), a hydroaromatic compound (tetrahydronaphthalene), and an aromatic ether (dibenzyl ether) was performed under similar reaction conditions.

Yilmaz, M.

1999-12-01T23:59:59.000Z

139

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect (OSTI)

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

140

Removal of Chloride from Wastewater by Advanced Softening Process Using Electrochemically Generated Aluminum Hydroxide  

E-Print Network [OSTI]

produced mass of aluminum and theoretical mass as predicted by Faraday’s law vs time during electrolysis of 30 mM NaCl electrolyte solution. ........................................................................................... 35 Figure 8 Change... of pH versus time during electrolysis performed at different current values of 30mM NaCl electrolyte solution. ...................................................... 36 Figure 9 Removal of chloride during advanced softening experiment performed after...

Mustafa, Syed Faisal

2014-07-23T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

The ultra-high lime with aluminum process for removing chloride from recirculating cooling water  

E-Print Network [OSTI]

THE ULTRA-HIGH LIME WITH ALUMINUM PROCESS FOR REMOVING CHLORIDE FROM RECIRCULATING COOLING WATER A Dissertation by AHMED IBRAHEEM ALI ABDEL-WAHAB Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...-WAHAB Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content by: Bill Batchelor (Chair of Committee) Robin L. Autenrieth (Member...

Abdel-wahab, Ahmed Ibraheem Ali

2004-09-30T23:59:59.000Z

142

A study of the reaction between antimony (V) chloride and organic amine hydrochlorides  

E-Print Network [OSTI]

. The mercury turned grey and formed. very small droplets when the reduction was proceeding properly. 12 The addition of a small amount of mercuric iona to the sample solution aided the reduction process for those compounds that were difficult to start... Chloride content of the salts was determined potentio- metrically using a silver indicating electrode and a mercury- mercurous sulfate reference electrode. Duplicate samples of approximately 0. 2 gram of each com- pound, weighed to the nearest 0. 1...

Bier, Harold Dean

1962-01-01T23:59:59.000Z

143

Determination of transport parameters from coincident chloride and tritium plumes at the Idaho National Engineering Laboratory  

E-Print Network [OSTI]

-radioactive waste, but rad1onuclides are often toxic at far lower concentrations than are hazardous non-radi oacti ve speci es (Freeze and Cherry, 1979). Most radioactive waste, in terms of activity, is generated at vari ous stages of what Freeze and Cherry...DETERMINATION OF TRANSPORT PARAMETERS FROM COINCIDENT CHLORIDE AND TRITIUM PLUMES AT THE IDAHO NATIONAL ENGINEERING LABORATORY A Thesis by ALAN ERNEST FRYAR Submitted to the Graduate College of Texas A&M University in partial fulfillment...

Fryar, Alan Ernest

1986-01-01T23:59:59.000Z

144

Concrete cover cracking with reinforcement corrosion of RC beam during chloride-induced corrosion process  

SciTech Connect (OSTI)

This paper deals with the evolution of the corrosion pattern based on two beams corroded by 14 years (beam B1CL1) and 23 years (beam B2CL1) of conservation in a chloride environment. The experimental results indicate that, at the cracking initiation stage and the first stage of cracking propagation, localized corrosion due to chloride ingress is the predominant corrosion pattern and pitting corrosion is the main factor that influences the cracking process. As corrosion cracking increases, general corrosion develops rapidly and gradually becomes predominant in the second stage of cracking propagation. A comparison between existing models and experimental results illustrates that, although Vidal et al.'s model can better predict the reinforcement corrosion of beam B1CL1 under localized corrosion, it cannot predict the corrosion of beam B2CL1 under general corrosion. Also, Rodriguez's model, derived from the general corrosion due to electrically accelerated corrosion experiments, cannot match natural chloride corrosion irrespective of whether corrosion is localized or general. Thus, for natural general corrosion in the second stage of cracking propagation, a new model based on the parameter of average steel cross-section loss is put forward to predict steel corrosion from corrosion cracking.

Zhang Ruijin, E-mail: rjzhang@mail.neu.edu.c [Modern Design and Analysis Research Institute, Northeastern University, Shenyang (China); Castel, Arnaud; Francois, Raoul [LMDC - Laboratoire Materiaux et Durabilite des Constructions, Universite de Toulouse, UPS, INSA, Toulouse (France)

2010-03-15T23:59:59.000Z

145

Evaluation of the association between birth defects and exposure to ambient vinyl chloride  

SciTech Connect (OSTI)

Birth defects incidence for infants born to residents of Shawinigan, Canada in 1966-1979 were significantly higher than in three comparison communities. Since there has been a vinyl chloride polymerization plant in this town since 1943 from which ten cases of angiosarcoma of the liver have been identified, this study explores the possible association between exposure to vinyl chloride monomer (VCM) in ambient air and the occurrence of birth defects in the community. The excess of birth defects fluctuated seasonally in a way that corresponded to changes in VCM concentration in the environment. Mothers who gave birth to malformed children were younger on average in Shawinigan than in the comparison communities. However, there was no excess of still-births in Shawinigan. The excess in birth defects involved most organ systems, and variation in birth-defect rates among school districts could not be accounted for by estimates of VCM in the atmosphere. The occupational and residential histories of parents who gave birth to malformed infants were compared with those of parents of normal infants. The two groups did not differ in occupational exposure or closeness of residence to the vinyl chloride polymerization plant. Some descriptive data from this study raised the hypothesis of an association between VCM in the air and birth defects in the exposed community, but as a whole, within the sample size available, such an association could not be substantiated.

Theriault, G.; Iturra, H.; Gingras, S.

1983-06-01T23:59:59.000Z

146

EFFECT OF CHLORIDE AND SULFATE CONCENTRATION ON PROBABLITY BASED CORROSION CONTROL FOR LIQUID WASTE TANKS- PART IV  

SciTech Connect (OSTI)

A series of cyclic potentiodynamic polarization tests was performed on samples of A537 carbon steel in support of a probability-based approach to evaluate the effect of chloride and sulfate on corrosion susceptibility. Testing solutions were chosen to build off previous experimental results from FY07, FY08, FY09 and FY10 to systemically evaluate the influence of the secondary aggressive species, chloride, and sulfate. The FY11 results suggest that evaluating the combined effect of all aggressive species, nitrate, chloride, and sulfate, provides a consistent response for determining corrosion susceptibility. The results of this work emphasize the importance for not only nitrate concentration limits, but also chloride and sulfate concentration limits as well.

Hoffman, E.

2012-08-23T23:59:59.000Z

147

Nickel-catalyzed asymmetric cross-couplings of secondary allylic chlorides and planar-chiral compounds in asymmetric synthesis  

E-Print Network [OSTI]

In Part I, nickel-catalyzed asymmetric carbon-carbon bond-forming reactions are described. A nickel/Pybox system effectively catalyzes regio- and enantioselective cross-couplings between racemic secondary allylic chlorides ...

Son, Sunghee

2008-01-01T23:59:59.000Z

148

Firmness and cell wall characteristics of pasteurized jalapeno pepper rings affected by acetic acid, calcium chloride and preheating  

E-Print Network [OSTI]

pasteurization and storage, especially when high acid brines are used. Development of treatments to retard softening may result in a higher quality product. This study was undertaken to investigate the effects of calcium chloride (CaCI2), acetic acid...

Burma, Prashanthi V

2012-06-07T23:59:59.000Z

149

Infrared and visible laser double resonance studies of vibrational energy transfer processes in polyatomic molecules. [Chromyl chloride solutions  

SciTech Connect (OSTI)

A study of the spectroscopy of chromyl chloride (CrO{sub 2}Cl{sub 2} ) in dilute solutions has been initiated. A discussion is given of its spectra and emission bands. 17 refs, 5 figs, 1 tab. (DLC)

Bhatnagar, R. (Texas Southern Univ., Houston, TX (United States). Dept. of Chemistry)

1991-01-01T23:59:59.000Z

150

Control technology of vinyl chloride in EDC-VCM and PVC plants at main source points and fugitive emissions  

E-Print Network [OSTI]

in a boiler and the combustion gases scrubbed with water or a caustic solution to remove the hydrogen chloride to form hydrochloric acid or sodium chloride. According to the Trane Thermal Company, thermal incineration is a basic proven process... and fugitive emissions, (b) collection of data by using a questionaire ? survey from industries located in the United States, and (c) a statistical analysis of the data. It was found that thermal incineration is considered the best approach to control...

Parra, Dario Antonio

1983-01-01T23:59:59.000Z

151

Long-Term Hydrologic Responses To Shrub Removal In A SW Texas Rangeland: Using Soil Chloride To Estimate Deep Drainage  

E-Print Network [OSTI]

LONG-TERM HYDROLOGIC RESPONSES TO SHRUB REMOVAL IN A SW TEXAS RANGELAND: USING SOIL CHLORIDE TO ESTIMATE DEEP DRAINAGE A Thesis by DAVID ANTHONY BARRE Submitted to the Office of Graduate Studies of Texas A&M University... of the study were to identify those biotic and abiotic factors facilitating deep drainage and to examine differences in recharge for the years following clearing of natural shrub vegetation. Soil chloride was examined to estimate long-term recharge rates...

Barre, David Anthony

2010-10-12T23:59:59.000Z

152

The Effect of Continuous and Pulse Dose Ammonium Chloride Regimens on the Urine pH of Goats  

E-Print Network [OSTI]

i THE EFFECT OF CONTINUOUS AND PULSE DOSE AMMONIUM CHLORIDE REGIMENS ON THE URINE PH OF GOATS A Thesis by PHILIPPA MAY SPRAKE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 2012 Major Subject: Biomedical Sciences ii The effect of continuous and pulse dose ammonium chloride regimens on the urine pH of goats. Copyright...

Sprake, Philippa May

2012-10-19T23:59:59.000Z

153

An inverse analytical technique applied to a chloride contamination of groundwater at Indian School and Levering sites, Michigan  

E-Print Network [OSTI]

AN INVERSE ANALYTICAL TECHNIQUE APPLIED TO A CHLORIDE CONTAMINATION OF GROUNDWATER AT ZNDIAN SCHOOL AND LEVERZNG SITES, MZCHZGAN A Thesis by Helen Shumway Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIFNCE Decanter "99" Major Subject: Geology AN INVERSE ANALYTICAL TECHNIQUE APPLIED TO A CHLORIDE CONTAMINATION OF GROUNDWATER AT INDIAN SCHOOL AND LEVERING SITES, MICHIGAN A Thesis...

Shumway, Helen

1992-01-01T23:59:59.000Z

154

E-Print Network 3.0 - acrylic acid synthesized Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

peracetic acid in an overnight... % trifluoroacetic acid (TFA) solution in methylene chloride, allowing for high conversion to the final vinyl product Source: Harth, Eva M. -...

155

The effect of sodium chloride on the dissolution of calcium silicate hydrate gels  

SciTech Connect (OSTI)

The use of cement based materials will be widespread in the long-term management of radioactive materials in the United Kingdom. One of the applications could be the Nirex reference vault backfill (NRVB) as an engineered barrier within a deep geological repository. NRVB confers alkaline conditions, which would provide a robust chemical barrier through the control of the solubility of some key radionuclides, enhanced sorption and minimised corrosion of steel containers. An understanding of the dissolution of C-S-H gels in cement under the appropriate conditions (e.g., saline groundwaters) is necessary to demonstrate the expected evolution of the chemistry over time and to provide sufficient cement to buffer the porewater conditions for the required time. A programme of experimental work has been undertaken to investigate C-S-H gel dissolution behaviour in sodium chloride solutions and the effect of calcium/silicon ratio (C/S), temperature and cation type on this behaviour. Reductions in calcium concentration and pH values were observed with samples equilibrated at 45 deg. C compared to those prepared at 25 deg. C. The effect of salt cation type on salt-concentration dependence of the dissolution of C-S-H gels was investigated by the addition of lithium or potassium chloride in place of sodium chloride for gels with a C/S of 1.0 and 1.8. With a C/S of 1.0, similar increases in dissolved calcium concentration with increasing ionic strength were recorded for the different salts. However, at a C/S of 1.8, anomalously high calcium concentrations were observed in the presence of lithium.

Hill, J. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom)]. E-mail: joanne.hill@nirex.co.uk; Harris, A.W. [UK Nirex Limited, Curie Avenue, Harwell, Didcot Oxfordshire, OX11 0RH (United Kingdom); Manning, M. [Formerly AEA Technology, Building 220, Harwell, Didcot Oxfordshire, OX11 0RA (United Kingdom); Chambers, A. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom); Swanton, S.W. [Serco Assurance, Building 150, Harwell International Business Centre, Didcot, Oxfordshire, OX11 0RA (United Kingdom)

2006-07-01T23:59:59.000Z

156

Preparation of graphene–Ag composites and their application for electrochemical detection of chloride  

SciTech Connect (OSTI)

Highlights: ? Graphene–Ag composites were prepared in situ using ascorbic acid as green reducing agent. ? The morphology of Ag particles was irregular sheet and Ag particles homogeneously distributed on the graphene matrix. ? The surface-enhanced Raman scattering enhancement factor of D band is 5.85 for composites. ? The composites exhibited good sensitivity for the detection of chloride ions. -- Abstract: Graphene–Ag composites were prepared in situ using ascorbic acid as green reducing agent. The composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected-area electronic diffraction (SAED), and Raman spectrometer. It was showed that Ag particles homogeneously distributed on the graphene matrix. The morphology of Ag particles was irregular sheet with (1 1 1) basal plane. The surface-enhanced Raman scattering (SERS) enhancement factor of D band is 5.85 for composites. The application of the composites for electrochemical detection of chloride was studied by cyclic voltammetry. The composites exhibited good sensitivity for the detection of chloride ions. The maximum peak current of cyclic voltammetry curve in 5 mM KCl was 0.80 mA. In the range of 500 ?M to 50 mM for Cl{sup ?}, the current response was proportional and linear to the Cl{sup ?} concentration. The sensitivity to the detection for Cl{sup ?} was 0.059 (mA/mM) and the detection limit was 61 ?M for Cl{sup ?}. It indicates graphene–Ag composites would be a competitive material for detection of halide.

Yu, Mei, E-mail: yumei@buaa.edu.cn [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China)] [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China); Liu, Pengrui; Zhang, Shilu; Liu, Jianhua; An, Junwei; Li, Songmei [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China)] [School of Materials Science and Engineering, Beihang University, Beijing 100191 (China)

2012-11-15T23:59:59.000Z

157

Data Qualification Report: Precipitation Chloride Data for Use on the Yucca Mountain Project  

SciTech Connect (OSTI)

The data covered by this qualification report have been cited in analysis/model reports (AMRs) to support the Site Recommendation in determining the suitability of Yucca Mountain as a repository for high level nuclear waste. Those analyses cited both qualified and unqualified hydrochemical data. This report evaluates unqualified precipitation chloride data based on the pedigree of the data and within the context of supporting analyses on the Yucca Mountain Project (YMP). The following AMRs use the unqualified chloride data considered in this report: (1) AMR S0040, ''Geochemical and Isotopic Constraints on Groundwater Flow Directions, Mixing and Recharge at Yucca Mountain'' (ANL-NBS-HS-000021) (Kwicklis 2000)--an analysis of groundwater recharge rates, flow directions and velocities, and mixing proportions of water from different source areas based on groundwater geochemical and isotopic data. (2) AMR U0085, ''Analysis of Geochemical Data for the Unsaturated Zone'' (ANL-NBS-HS-000017) (Fabryka-Martin 2000)--identifies fluid geochemical parameters for the unsaturated zone, local precipitation, and surface water; discusses the occurrence and origins of fracture minerals; and presents a thermal history of the unsaturated zone. These data are being evaluated for inclusion in technical products to include AMRs and Process Modeling Reports (PMRs) that support the Site Recommendation and that may also be used to support the License Application. A finding that the precipitation chloride data are qualified means that the data are adequate for generalized use and can be appropriately used in a wide variety of applications, so long as consideration is given to limitations on the accuracy, precision and representativeness of the data for an intended use in a technical product.

C. Wilson

2000-09-30T23:59:59.000Z

158

Effect of nonlinear absorption on electric field applied lead chloride by Z-scan technique  

SciTech Connect (OSTI)

The preparation, spectral response and optical nonlinearity of gel grown lead chloride single crystals subjected to electric field of 20V using parallel plate arrangements have been investigated. Optical band gap of the samples were determined using linear absorption spectra. Open aperture z-scan was employed for the determination of nonlinear absorption coefficient of PbCl{sub 2} solution. The normalized transmittance curve exhibits a valley shows reverse saturable absorption. The non linear absorption at different input fluences were recorded using a single Gaussian laser beam in tight focus geometry. The RSA nature of the sample makes it suitable for optical limiting applications.

Rejeena, I. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala, India and M.S.M. College, Kayamkulam, Kerala (India); Lillibai,; Nampoori, V. P. N.; Radhakrishnan, P. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala (India); Rahimkutty, M. H. [M.S.M. College, Kayamkulam, Kerala (India)

2014-10-15T23:59:59.000Z

159

Unexpected synthesis and structural characterization of Pt(II)Cl2-1,5-hexadiene from reaction of allyl chloride and K2PtCl4  

E-Print Network [OSTI]

4 and allyl chloride in the presence of so- dium acetateacetate nor acetic acid, which would be lost on rotary evaporation, nor allyl-

Nair, Reji N; Golen, James A; Rheingold, Arnold L; Grotjahn, Douglas B

2010-01-01T23:59:59.000Z

160

Crystal growth, structure and characterizations of a new semiorganic nonlinear optical material-{beta}-Alanine zinc chloride  

SciTech Connect (OSTI)

The title compound, {beta}-alanine zinc chloride-a new semiorganic nonlinear optical crystal was grown by slow evaporation technique. Single crystals of {beta}-alanine zinc chloride have been subjected to X-ray diffraction analysis to determine the crystal structure. The powder X-ray diffractogram of the crystal has also been recorded. The amount of carbon, nitrogen and hydrogen in the crystals was also estimated. Fourier Transform Infrared and Raman spectral measurements have been carried out on the grown crystals in order to identify the functional groups. The presence of hydrogen and carbon in the {beta}-alanine zinc chloride was confirmed by using proton and carbon nuclear magnetic resonance spectral analyses. The percentage of zinc in the crystal was determined by atomic absorption spectroscopy. Optical behavior such as ultraviolet-vis-near infrared transmittance spectrum and second harmonic generation has been investigated. The mechanical strength and thermal behavior of the grown crystal have been analyzed.

Anbuchezhiyan, M. [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India)] [Department of Physics, Valliammai Engineering College, S.R.M. Nagar, Kattankulathur, Chennai 603203 (India); Ponnusamy, S., E-mail: suruponnus@gmail.com [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Muthamizhchelvan, C. [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India)] [Centre for Material Science and Nano Devices, Department of Physics, SRM University, Kattankulathur, Kanchipuram, Chennai 603203 (India); Sivakumar, K. [Department of Physics, Anna University, Chennai 600 025 (India)] [Department of Physics, Anna University, Chennai 600 025 (India)

2010-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Using electroless nickel to coat reinforcing steel in chloride contaminated concrete  

SciTech Connect (OSTI)

This work is a study of the behavior of steel rebar coated by electroless nickel in chloride-contaminated concrete. The steel rebars were coated in an electroless nickel bath for 1, 2 and 3 hours. They were then subjected to heat treatment at 400 C for periods of 1, 2 and 3 hours. The nickel-coated rebars were embedded in concrete samples with NaCl concentrations at 0.00; 0.10; 0.15 and 0.20 %, based on concrete weight. Their behavior was evaluated by measurement of potentials, polarization resistance, potentiodynamic polarization curves, electrical resistance and visual inspection. Corrosion rates were less than 0.01 {micro}A/cm{sup 2} after 40 months` testing.

Sanchez, M.A.; Parra, L.A.; Perez, O.A.; Rincon, O. de [Univ. del Zulia, Maracaibo (Venezuela)

1998-12-31T23:59:59.000Z

162

Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System  

SciTech Connect (OSTI)

The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

Yongchun Tang; John (Qisheng) Ma

2012-03-23T23:59:59.000Z

163

Corrosion of nickel-based alloys in acidified lithium chloride solutions  

SciTech Connect (OSTI)

Immersion tests were performed on nickel (Ni)-based alloys in acidified 2 M lithium chloride (LiCl) solutions as a function of temperature and pH. Results indicated alloy C-22 (UNS N06022) and alloy C-276 (UNS N10276) were very resistant to corrosion in this environment to pH 1 at 95 C. Other alloys revealed extreme corrosion at low pH (alloy G-30 [UNS N06030] and alloy 20Mo6 [UNS N08026]) or accelerated corrosion due to solution aeration (alloy B-2 [UNS N10665]) and were not recommended for the process described. Failures of C-276 in similar service environments were attributed to poor control of process pH, with values [le] 0.5 leading to extreme general corrosion.

Pawell, S.J. (Oak Ridge Y-12 Plant, TN (United States). Development Div.)

1993-11-01T23:59:59.000Z

164

Calcium chloride electron injection/extraction layers in organic electronic devices  

SciTech Connect (OSTI)

Nontoxic calcium chloride (CaCl{sub 2}) was introduced into organic electronic devices as cathode buffer layer (CBL). The turn-on voltage and maximum luminance of organic light-emitting diode (OLED) with 1.5?nm CaCl{sub 2} was 3.5?V and 21 960?cd/m{sup 2}, respectively. OLED with 1.5?nm CaCl{sub 2} possessed comparable electroluminescent characteristics to that of the commonly used LiF. Moreover, the performance of the organic photovoltaic device with 0.5?nm CaCl{sub 2} was comparable to that of the control device with LiF. Therefore, CaCl{sub 2} has the potential to be used as the CBL for organic electronic devices.

Qu, Bo, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn; Gao, Zhi; Yang, Hongsheng; Xiao, Lixin; Chen, Zhijian; Gong, Qihuang, E-mail: bqu@pku.edu.cn, E-mail: qhgong@pku.edu.cn [State Key Laboratory for Artificial Microstructures and Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China)

2014-01-27T23:59:59.000Z

165

Spectrophotometric determination of vanadium in metallurgical products with carminic acid and cetyltrimethylammonium chloride  

SciTech Connect (OSTI)

According to the authors, there is an increasing demand for sensitive, selective, and rapid methods of determining low levels of vanadium in metallurgical products, and solvent-extraction methods do not meet the requirements. The authors used an anthraquinone dye carminic acid (CA) as a chromophoric organic reagent: 1, 3, 4, 6-tetrahydroxy-2-R-5carboxy-8-methylanthra-9, 10-quinone. The CSA was cetyltrimethylammonium chloride CTA. The three-component system was examined in order to devise a reasonably sensitive and rapid method of determining vanadium in metallurgical products. A study is made of the complexing in the system formed by vanadium (IV) with CA and the CSA. The optimum conditions for the formation of the complex have been established together with the spectrophotometric characteristics. A spectrophotometric method has been devised for determining from 0.05 to 5% of vanadium in metallurgical products with a relative standard deviation of not more than 0.04.

Babenko, N.L.; Blokh, M. Sh.; Guseva, T.D.

1985-11-01T23:59:59.000Z

166

Electrochemical Polishing Applications and EIS of a Novel Choline Chloride-Based Ionic Liquid  

SciTech Connect (OSTI)

Minimal surface roughness is a critical feature for high-field superconducting radio frequency (SRF) cavities used to engineer particle accelerators. Current methods for polishing Niobium cavities typically utilize solutions containing a mixture of concentrated sulfuric and hydrofluoric acid. Polishing processes such as these are effective, yet there are many hazards and costs associated with the use (and safe disposal) of the concentrated acid solutions. An alternative method for electrochemical polishing of the cavities was explored using a novel ionic liquid solution containing choline chloride. Potentiostatic electrochemical impedance spectroscopy (EIS) was used to analyze the ionic polishing solution. Final surface roughness of the Nb was found to be comparable to that of the acid-polishing method, as assessed by atomic force microscopy (AFM). This indicates that ionic liquid-based electrochemical polishing of Nb is a viable replacement for acid-based methods for preparation of SRF cavities.

Wixtrom, Alex I. [Christopher Newport University, Newport News, VA (United States); Buhler, Jessica E. [Christopher Newport University, Newport News, VA (United States); Reece, Charles E. [Thomas Jefferson National Accelerator Facility, Newport News, VA (United States); Abdel-Fattah, Tarek M. [Christopher Newport University, Newport News, VA (United States)

2013-06-01T23:59:59.000Z

167

The effect of competition by chloride and sulfate anions on the adsorption of arsenate ion onto activated alumina  

E-Print Network [OSTI]

for adsorption sites on the activated alumina. The results of this study showed that the presence of 15 meq/L chloride anion depresses the ability of the arsenate to be adsorbed by F-1 activated alumina initial liquid phase arsenate ion concentration of 5 mg...

Janis, Patrick John

2000-01-01T23:59:59.000Z

168

Voltage-and calcium-dependent gating of TMEM16A/Ano1 chloride channels are physically  

E-Print Network [OSTI]

Voltage- and calcium-dependent gating of TMEM16A/Ano1 chloride channels are physically coupled by the first intracellular loop Qinghuan Xiaoa , Kuai Yua , Patricia Perez-Cornejob , Yuanyuan Cuia , Jorge in the first intracellular loop that is crucial for both Ca2+ and voltage sensing. Deleting 448EAVK

169

Periadolescent oral manganese exposure affects conditioned place preference by cocaine and conditioned place aversion by lithium chloride in rats  

E-Print Network [OSTI]

aversion (CPA) procedure was employed for Experiment 2. Animals received 40 mg/kg lithium chloride (i.p.) for 4 days, and alternatively, vehicle-only for 4 days. Animals exposed to 100 mg/kg/day Mn and 200 mg/kg/day Mn showed an increased place aversion...

Lee, Samuel Ming Hin

2013-02-22T23:59:59.000Z

170

Solvation of Magnesium Dication: Molecular Dynamics Simulation and Vibrational Spectroscopic Study of Magnesium Chloride in Aqueous Solutions  

E-Print Network [OSTI]

Solvation of Magnesium Dication: Molecular Dynamics Simulation and Vibrational Spectroscopic Study of Magnesium Chloride in Aqueous Solutions Karen M. Callahan, Nadia N. Casillas-Ituarte, Martina Roeselova 26, 2010 Magnesium dication plays many significant roles in biochemistry. While it is available

171

Formation and fluidity measurement of supported lipid bilayer on polyvinyl chloride membrane  

SciTech Connect (OSTI)

We prepared an artificial lipid bilayer on a plasticized poly(vinyl chloride) (PVC) membrane on a Si3N4 layer deposited on a Si wafer. We optimized the experimental condition for the fabrication of the PVC membrane, and obtained a PVC membrane with a flat and uniform surface on the scale of several hundreds of micrometer suitable for a substrate for supported lipid bilayers (SLBs). The SLB of 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) was formed on the PVC membrane by the vesicle fusion method. The observation with a conventional epi-fluorescence microscope and a confocal laser scanning microscope gave geometrically uniform images of the SLB on the PVC membrane. The fluidity and the mobile fraction of the SLB was evaluated by the fluorescence recovery after photobleaching method, and compared with that on a thermally oxidized SiO{sub 2}/Si substrate. The SLB on the PVC membrane contained immobile fraction ?30%, but the diffusion in the mobile fraction was two times faster than that in the SLB on SiO{sub 2}/Si, which had little immobile fraction.

Kobayashi, Takuji, E-mail: kobayashi-t@int.ee.tut.ac.jp; Kono, Akiteru, E-mail: kobayashi-t@int.ee.tut.ac.jp; Sawada, Kazuaki [Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka Tempaku-cho, Toyohashi, 441-8580 (Japan); Futagawa, Masato [Department of Electrical and Electronic Information Engineering and Head Office for the Tailor-Made and Baton-Zone Graduate Course, Toyohashi University of Technology, 1-1 Hibarigaoka Tempaku-cho, Toyohashi, 441-8580 (Japan); Tero, Ryugo, E-mail: tero@tut.jp [Electronics-Inspired Interdisciplinary Research Institute and Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka Tempaku-cho, Toyohashi, 441-8580 (Japan)

2014-02-20T23:59:59.000Z

172

High-temperature oxidation and corrosion of structural materials in molten chlorides.  

SciTech Connect (OSTI)

A molten salt-based process for treatment of spent oxide fuels is under development at the Argonne National Laboratory. A major part of the development effort involves identification of corrosion-resistant structural materials for the process vessels. Coupons of two stainless steels, tantalum, and two Inconel alloys were submitted to a corrosion test in an argon atmosphere with 10% oxygen. The coupons were partially immersed in molten lithium chloride salt containing small amounts of lithium metal, lithium oxide, and lithium nitride. Two sets of coupons were tested, the first at 750{sup o}C for 30 days and the second at 650{sup o}C for 6 days. Coupons of the first set corroded completely. In the second set of coupons, all corroded to some extent, but Inconel 600 showed the best performance overall. The salt-exposed region generally showed the greatest corrosion in the other coupons. One of the 316L SS coupons was welded and the weld area was severely attacked.

Indacochea, J. E.; Smith, J. L.; Litko, K. R.; Karell, E. J.; Raraz, A. G.; Chemical Engineering

2001-02-01T23:59:59.000Z

173

Mechanisms, Chemistry, and Kinetics of Anaerobic Biodegradation of cis-Dichloroethene and Vinyl Chloride  

SciTech Connect (OSTI)

Anaerobic biological processes can result in PCE and TCE destruction through conversion to cis-dichloroethene (cDCE) then to vinyl chloride (VC), and finally to ethene. Here, the chlorinated aliphatic hydrocarbons (CAHs) serve as electron acceptors in energy metabolism, requiring electron donors such as hydrogen from an external source. The purpose of this study was to learn more about the biochemistry of cDCE and VC conversion to ethene, to better understand the requirements for electron donors, and to determine factors affecting the rates of CAH degradation and organism growth. The biochemistry of reductive dehalogenation of VC was studied with an anaerobic mixed culture enriched on VC. In other studies on electron donor needs for dehalogenation of cDCE and VC, competition for hydrogen was found to occur between the dehalogenators and other microorganisms such as methanogens and homoacetogens in a benzoate-acclimated dehalogenating methanogenic mixed culture. Factors affecting the relative rates of destruction of the solvents and their intermediate products were evaluated. Studies using a mixed PCE-dehalogenating culture as well as the VC enrichment for biochemical studies suggested that the same species was involved in both cDCE and VC dechlorination, and that cDCE and VC competitively inhibited each other's dechlorination rate.

McCarty, P.L.; Spormann, A.M.

2000-12-01T23:59:59.000Z

174

Studies of micromorphology and current efficiency of zinc electrodeposited from flowing chloride electrolytes  

SciTech Connect (OSTI)

Results of a study of the micromorphology and current efficiency of zinc electrodeposited from flowing, acidic chloride solutions are reported. The effects of six variables were examined: flow rate, current density, zinc and hydrogen ion concentration, concentrations of nickel, iron and cadmium impurity ions, and the nature of the substrate. The development of micromorphology was studied in-situ by means of videomicrography and ex-situ by means of scanning electron microscopy. This investigation focused on the formation of grooved deposits, which are found under a wide range of deposition conditions. The major conclusions of this study are: the most important variable determining whether grooved deposits form is the interfacial concentration; large protrusions orient themselves parallel to the flow direction with the orientation starting upstream and progressing downstream; large protrusions become ridges due to growth of the highest current density portions of the electrode under mass transport control. The current efficiency was measured using EDTA titration and weight measurements. The fraction of the current taken by zinc deposition increased with zinc concentration, ranging up to 100%, and decreased with pH. The efficiency of zinc deposition was affected by the flow rate and the substrate employed. Impurities lowered the current efficiency.

Mc Vay, L.; Muller, R.H.; Tobias, C.W.

1986-05-01T23:59:59.000Z

175

Changes in niacin content produced by nickel-chloride in a rust susceptible wheat and oat variety  

E-Print Network [OSTI]

ONANNES IN NIACIN CONTENT PRODUOE9 BT NICKEL-CNLORIBE IN k RSST SOSOEPTIBLE NNEST SNB OST VSRXETT k Thesis Suhnitted to the Graduate School of the SSricultural and Nechanical Collage- of Tunas in partial fulfillment of the requireneat.... d typical standard curve for tha growth of 17-5 f Idee b ill d l . . . . . . . . . . , . . . . . 12 I, The affeot of nickel-chloride sprays on niacin content of 131 wheat conpared to controls at thre~ ages4 ~ 4 ~ ~ 4...

Lacy, Logan Wayne

1961-01-01T23:59:59.000Z

176

Induction of chloride secretory currents across mouse ileal tissues by rotavirus enterotoxic peptide in different age mice  

E-Print Network [OSTI]

INDUCTION OF CHLORIDE SECRETORY CURRENTS ACROSS MOUSE ILEAL TISSUES BY A ROTAVIRUS ENTEROTOXIC PEPTIDE IN DIFFERENT AGE MICE A Thesis by VIRGINIA WATERS COX Submitted to the Office of Graduate Studies of Texas Ak M University in partial... by VIRGINIA WATERS COX Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved as to style and content by: Judith M. Ball (Chair of Committee) Julian Lei os z (Member) Friedhelm...

Cox, Virginia Waters

2002-01-01T23:59:59.000Z

177

Accelerated quantification of critical parameters for predicting the service life and life cycle costs of chloride-laden reinforced concrete structures  

E-Print Network [OSTI]

The use of corrosion resistant steels (instead of conventional carbon steels) and/or high performance concrete can increase the overall service life and can reduce the life cycle cost (LCC) of reinforced concrete (RC) structures exposed to chloride...

Pillai Gopalakrishnan, Radhakrishna

2003-01-01T23:59:59.000Z

178

Study of the Susceptibility of Oxygen-Free Phosphorous Doped Copper to Corrosion in Simulated Groundwater in the Presence of Chloride and Sulfide  

SciTech Connect (OSTI)

Oxygen free high conductivity copper, doped with phosphorus (Cu OFP) has been chosen as the material for the fabrication of high level nuclear waste containers in Sweden. This material will be the corrosion barrier for spent fuel in the environment of a deep geological repository in granitic rock. The service life of this container is expected to exceed 1,000,000 years. During this time, which includes several glaciations, water of different compositions, including high concentration of chloride ions, will contact the copper surface. This work reports a study of the susceptibility of Cu OFP to corrosion when chloride ions are present, in deionized water (DW) and in synthetic groundwater (SGW). The techniques used were electrochemical methods such as corrosion potential evolution and Tafel curves. The system was studied with Electrochemical Impedance Spectroscopy (EIS). We also used as characterization techniques Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS). The main conclusions are that copper is more susceptible to corrosion at high chloride ion concentration. When the chloride concentration is low, it is possible to form copper chloride crystals, but at the highest concentration, copper chloride complexes are formed, leaving the copper surface without deposits. When the chloride concentration is low (<0.1 M) the corrosion process is mainly controlled by diffusion, while at higher concentrations (0.1 M to 1 M) corrosion is controlled by charge transfer processes. At low concentration of sulfide (<3 . 10{sup -5} M), copper corrosion in the presence of chloride is controlled by diffusional processes, while at higher concentrations corrosion is controlled by charge transfer processes. (authors)

Escobar, Ivan; Lamas, Claudia [Chilean Commission for Nuclear Energy, Amunategui No 95, Santiago, 834-0701 (Chile); Werme, Lars [Svensk Kaernbraenslehantering AB (SKB), Stockholm (Sweden)]|[Department of Physics, Uppsala University, Uppsala (Sweden); Oversby, Virginia [VMO Konsult, Stockholm (Sweden)

2007-07-01T23:59:59.000Z

179

Light transmission of glass, fiberglass, polyethylene, and polyvinyl chloride greenhouse covers as related to growth of Lycopersicon esculentum Mill. variety Homestead 24  

E-Print Network [OSTI]

LIGHT TRANSMISSION OF GLASS~ FIBERGLASS& POLYETHYLENEe AND POLYVINYL CHLORIDE GREENHOUSE COVERS AS RELATED TO GROWTH OF LYCOPERSICON ESCULENTUM MILL, VARIETY HOMESTEAD 24 A Thesis By VICTOR CLEMENS ESCHE Submitted to the Graduate College... of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August, 1966 Major Subject: Horticulture LIGHT TRANSMISSION OF GLASS, FIBERGLASS~ POLYETHYLENE, AND POLYVINYL CHLORIDE GREENHOUSE COVERS AS RELATED...

Esche, Victor Clemens

2012-06-07T23:59:59.000Z

180

The effect of iron chloride and glutamate on glutamine synthetase activity in primary cultured rat cortical astrocytes: a model for epileptic induction  

E-Print Network [OSTI]

THE EFFECT OF IRON CHLORIDE AND GLUTAMATE ON GLUTAMINE SYNTHETASE ACTIVITY IN PRIMARY CULTURED RAT CORTICAL ASTROCYTES: A MODEL POR EPILEPTIC INDUCTION A Thesis by JULIE ANN ROBERTS Submitted to the Graduate College of Texas ARM University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1986 Major Subject: Veterinary Anatomy THE EFFECT OF IRON CHLORIDE AND GLUTAMATE ON GLUTAMINE SYNTHETASE ACTIVITY IN PRIMARY CULTURED RAT CORTICAL ASTROCYTES: A...

Roberts, Julie Ann

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES  

SciTech Connect (OSTI)

Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

Gopala Krishnan; Raghubir Gupta

1999-09-01T23:59:59.000Z

182

Thermal Analysis of Surrogate Simulated Molten Salts with Metal Chloride Impurities for Electrorefining Used Nuclear Fuel  

SciTech Connect (OSTI)

This project is a fundamental study to measure thermal properties (liquidus, solidus, phase transformation, and enthalpy) of molten salt systems of interest to electrorefining operations, which are used in both the fuel cycle research & development mission and the spent fuel treatment mission of the Department of Energy. During electrorefining operations the electrolyte accumulates elements more active than uranium (transuranics, fission products and bond sodium). The accumulation needs to be closely monitored because the thermal properties of the electrolyte will change as the concentration of the impurities increases. During electrorefining (processing techniques used at the Idaho National Laboratory to separate uranium from spent nuclear fuel) it is important for the electrolyte to remain in a homogeneous liquid phase for operational safeguard and criticality reasons. The phase stability of molten salts in an electrorefiner may be adversely affected by the buildup of fission products in the electrolyte. Potential situations that need to be avoided are: (i) build up of fissile elements in the salt approaching the criticality limits specified for the vessel (ii) freezing of the salts due to change in the liquidus temperature and (iii) phase separation (non-homogenous solution) of elements. The stability (and homogeneity) of the phases can potentially be monitored through the thermal characterization of the salts, which can be a function of impurity concentration. This work describes the experimental results of typical salts compositions, consisting of chlorides of strontium, samarium, praseodymium, lanthanum, barium, cerium, cesium, neodymium, sodium and gadolinium (as a surrogate for both uranium and plutonium), used in the processing of used nuclear fuels. Differential scanning calorimetry was used to analyze numerous salt samples providing results on the thermal properties. The property of most interest to pyroprocessing is the liquidus temperature. It was previously known the liquidus temperature of the molten salt would change as spent fuel is processed through the Mk-IV electrorefiner. However, the extent of the increase in liquidus temperature was not known. This work is first of its kind in determining thermodynamic properties of a molten salt electrolyte containing transuranics, fission products and bond sodium. Experimental data concluded that the melting temperature of the electrolyte will become greater than the operating temperature of the Mk-IV ER during current fuel processing campaigns. Collected data also helps predict when the molten salt electrolyte will no longer be able to support electrorefining operations.

Toni Y. Gutknecht; Guy L. Fredrickson; Vivek Utgikar

2012-04-01T23:59:59.000Z

183

Standard test method for evaluating stress-corrosion cracking of stainless alloys with different nickel content in boiling acidified sodium chloride solution  

E-Print Network [OSTI]

1.1 This test method describes a procedure for conducting stress-corrosion cracking tests in an acidified boiling sodium chloride solution. This test method is performed in 25% (by mass ) sodium chloride acidified to pH 1.5 with phosphoric acid. This test method is concerned primarily with the test solution and glassware, although a specific style of U-bend test specimen is suggested. 1.2 This test method is designed to provide better correlation with chemical process industry experience for stainless steels than the more severe boiling magnesium chloride test of Practice G36. Some stainless steels which have provided satisfactory service in many environments readily crack in Practice G36, but have not cracked during interlaboratory testing using this sodium chloride test method. 1.3 This boiling sodium chloride test method was used in an interlaboratory test program to evaluate wrought stainless steels, including duplex (ferrite-austenite) stainless and an alloy with up to about 33% nickel. It may also b...

American Society for Testing and Materials. Philadelphia

2000-01-01T23:59:59.000Z

184

Test and evaluation of the Chloride Spegel S1P108/30 electric vehicle battery charger  

SciTech Connect (OSTI)

The Chloride Spegel Model S1P108/30 electric vehicle battery charger was tested by the Tennessee Valley Authority (TVA) as an account of work sponsored by the Electric Power Research Institute (EPRI). Charger input/output voltage, current, and power characteristics and input waveform distortion were measured; and induced electromagnetic interference was evaluated as the charger recharged a lead-acid battery pack. Electrical quantities were measured with precision volt-ampere-watt meters, frequency counters, a digital-storage oscilloscope, and a spectrum analyzer. THe Chloride charger required 8.5 hours to recharge a 216V tubular plate lead-acid battery from 100 percent depth of discharge (DOD). Energy efficiency was 83 percent, specific power was 37.4 W/kg (17.0 W/lb), input current distortion varied from 22.4 to 34.1 percent, and electromagnetic interference was observed on AM radio. Tests were conducted with the battery at initial DOD of 100, 75, 50, and 25 percent. Charge factor was 1.14 from 100-percent DOD, increasing to 1.39 from 25-percent DOD.

Driggans, R.L.; Keller, A.S.

1985-09-01T23:59:59.000Z

185

Performance of copper chloride-impregnated sorbents on mercury vapor control in an entrained-flow reactor system  

SciTech Connect (OSTI)

An entrained-flow system has been designed and constructed to simulate in-flight mercury (Hg) capture by sorbent injection in ducts of coal-fired utility plants. The test conditions of 1.2-sec residence time, 140{degree}C gas temperature, 6.7 m/sec (22 ft/sec) gas velocity, and 0-0.24 g/m{sup 3} (0-15 lbs of sorbent per 1 million actual cubic feet of flue gas sorbent injection rates were chosen to simulate conditions in the ducts. Four kinds of sorbents were used in this study. Darco Hg-LH (lignite-based) served as a benchmark sorbent with which Hg control capability of other sorbents could be compared. Also, Darco-FGD (lignite-based) was used as a representative raw activated carbon sorbent. Two different copper chloride-impregnated sorbents were developed in the laboratory and tested in the entrained-flow system to examine the possibility of using these sorbents at coal-fired power plants. The test results showed that one of the copper chloride sorbents has remarkable elemental mercury (Hg{sup 0}) oxidation capability, and the other sorbent demonstrated a better performance in Hg removal than Darco Hg-LH. 13 refs., 4 figs., 3 tabs.

Sang-Sup Lee; Joo-Youp Lee; Tim C. Keener [University of Cincinnati, Cincinnati, OH (United States). Department of Civil and Environmental Engineering

2008-11-15T23:59:59.000Z

186

Effects of loading mode on the critical cracking potential of duplex ([alpha] + [gamma]) stainless steel in a hot chloride solution  

SciTech Connect (OSTI)

One of the common characteristics in stress corrosion cracking (SCC) between austenitic and ferritic stainless steels in chloride environments is that cracking occurs at potentials noble to a critical value which has been designated as the critical cracking potential, E[sub cc]. For austenitic stainless steels, E[sub cc] is insensitive to prior cold work with or without the generation of martensite and has been interpreted as the minimum potential for crack propagation. On the other hand, for low interstitial ferritic stainless steels., E[sub cc] is extremely sensitive to microstructural variations induced by small amounts of cold work or grain coarsening. It has been demonstrated that E[sub cc] for the low interstitial ferritic stainless steels, when it is measured at constant load, is that for crack initiation and is determined by the competing rates of generation of a new surface by slip induced film breakdown and repassivation. However, the physical and/or electrochemical meaning for E[sub cc] of duplex stainless steels has not yet been studied. It is the purpose of this work to determine if E[sub cc] for duplex stainless is a potential for crack initiation or one for crack propagation in a hot chloride environment and to examine the effects of loading modes on the E[sub cc] of these alloys.

Kwon, Hyuk Sang (Korea Advanced Inst. of Science and Tech., Taejon (Korea, Republic of))

1993-08-01T23:59:59.000Z

187

Radiation Stability of Benzyl Tributyl Ammonium Chloride Towards Technetium-99 Extraction  

SciTech Connect (OSTI)

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning process, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, low nitric acid concentration in the aqueous phase of a UREX based process will co-extract U(VI) and Tc(VII) by tri-n-butyl phosphate (TBP). Technetium (Tc-99) is recognized to be one of the most abundant, long-lived radiotoxic isotopes in UNF (half-life, t1/2 = 2.13 × 105 years), and as such, it is targeted in UNF separation strategies for isolation and encapsulation in solid waste forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flow sheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste forms for ultimate disposal. Furthermore, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macrocompounds such as crown-ethers, aza-crown ethers, and resorcinarenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO4- by benzyltributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand’s matrix conditions and concentration, as well as varying the organic phase composition (i.e., diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using external Co-60 source. Post-irradiation solvent extraction measurements will be discussed.

Jared Horkley; Audrey Roman; Keri Campbell; Ana Nunez; Amparo Espartero

2013-02-01T23:59:59.000Z

188

Radiation Stability of Benzyl Tributyl Ammonium Chloride towards Technetium-99 Extraction - 13016  

SciTech Connect (OSTI)

A closed nuclear fuel cycle combining new separation technologies along with generation III and generation IV reactors is a promising way to achieve a sustainable energy supply. But it is important to keep in mind that future recycling processes of used nuclear fuel (UNF) must minimize wastes, improve partitioning processes, and integrate waste considerations into processes. New separation processes are being developed worldwide to complement the actual industrialized PUREX process which selectively separates U(VI) and Pu(IV) from the raffinate. As an example, the UREX process has been developed in the United States to co-extract hexavalent uranium (U) and hepta-valent technetium (Tc) by tri-n-butyl phosphate (TBP). Tc-99 is recognized to be one of the most abundant, long-lived radio-toxic isotopes in UNF (half-life, t{sub 1/2} = 2.13 x 10{sup 5} years), and as such, is targeted in UNF separation strategies for isolation and encapsulation in solid waste-forms for final disposal in a nuclear waste repository. Immobilization of Tc-99 by a durable solid waste-form is a challenge, and its fate in new advanced technology processes is of importance. It is essential to be able to quantify and locate 1) its occurrence in any new developed flowsheets, 2) its chemical form in the individual phases of a process, 3) its potential quantitative transfer in any waste streams, and consequently, 4) its quantitative separation for either potential transmutation to Ru-100 or isolation and encapsulation in solid waste-forms for ultimate disposal. In addition, as a result of an U(VI)-Tc(VII) co-extraction in a UREX-based process, Tc(VII) could be found in low level waste (LLW) streams. There is a need for the development of new extraction systems that would selectively extract Tc-99 from LLW streams and concentrate it for feed into high level waste (HLW) for either Tc-99 immobilization in metallic waste-forms (Tc-Zr alloys), and/or borosilicate-based waste glass. Studies have been launched to investigate the suitability of new macro-compounds such as crown-ethers, aza-crown ethers, quaternary ammonium salts, and resorcin-arenes for the selective extraction of Tc-99 from nitric acid solutions. The selectivity of the ligand is important in evaluating potential separation processes and also the radiation stability of the molecule is essential for minimization of waste and radiolysis products. In this paper, we are reporting the extraction of TcO{sub 4}{sup -} by benzyl tributyl ammonium chloride (BTBA). Experimental efforts were focused on determining the best extraction conditions by varying the ligand's matrix conditions and concentration, as well as varying the organic phase composition (i.e. diluent variation). Furthermore, the ligand has been investigated for radiation stability. The ?-irradiation was performed on the neat organic phases containing the ligand at different absorbed doses to a maximum of 200 kGy using an external Co-60 source. Post-irradiation solvent extraction measurements will be discussed. (authors)

Paviet-Hartmann, Patricia; Horkley, Jared; Campbell, Keri [Idaho National Laboratory, 2525 Fremont Street, Idaho Falls, ID 83402 (United States)] [Idaho National Laboratory, 2525 Fremont Street, Idaho Falls, ID 83402 (United States); Roman, Audrey [University of Nevada - Las Vegas, Harry Reid Center, 4505 S. Maryland Pkwy, Box 4009, Las Vegas, NV 89154-4009 (United States)] [University of Nevada - Las Vegas, Harry Reid Center, 4505 S. Maryland Pkwy, Box 4009, Las Vegas, NV 89154-4009 (United States); Nunez, Ana; Espartero, Amparo [CIEMAT, Avda Complutense, 40, 28040- Madrid (Spain)] [CIEMAT, Avda Complutense, 40, 28040- Madrid (Spain)

2013-07-01T23:59:59.000Z

189

A Systematic Study of Chloride Ion Solvation in Water using van der Waals Inclusive Hybrid Density Functional Theory  

E-Print Network [OSTI]

In this work, the solvation and electronic structure of the aqueous chloride ion solution was investigated using Density Functional Theory (DFT) based \\textit{ab initio} molecular dynamics (AIMD). From an analysis of radial distribution functions, coordination numbers, and solvation structures, we found that exact exchange ($E_{\\rm xx}$) and non-local van der Waals (vdW) interactions effectively \\textit{weaken} the interactions between the Cl$^-$ ion and the first solvation shell. With a Cl-O coordination number in excellent agreement with experiment, we found that most configurations generated with vdW-inclusive hybrid DFT exhibit 6-fold coordinated distorted trigonal prism structures, which is indicative of a significantly disordered first solvation shell. By performing a series of band structure calculations on configurations generated from AIMD simulations with varying DFT potentials, we found that the solvated ion orbital energy levels (unlike the band structure of liquid water) strongly depend on the un...

Bankura, Arindam; DiStasio, Robert A; Swartz, Charles W; Klein, Michael L; Wu, Xifan

2015-01-01T23:59:59.000Z

190

Osha`s 1974 vinyl chloride standard. Retrospective evaluation of the rulemaking`s feasibility/impact estimates. Case study  

SciTech Connect (OSTI)

This report documents a case study of the Occupational Safety and Health Administration`s (OSHA) permanent health standard of 1974 for workplace exposures to vinyl chloride (monomer). OSHA`s assessment of hazard control options and estimates of compliance costs and other regulatory impacts prepared as part of the rationale for the rulemaking are reviewed and then compared and contrasted with the actual post-promulgation outcomes as affected industries adjusted to the new compliance requirements. This case study has been prepared as part of a larger Office of Technology Assessment (OTA) evaluation of the control technology and regulatory impact analyses that OSHA prepares to support its rulemakings. Congress requested in May 1992 that OTA examine OSHA`s procedures and methods in these regards. The case reported here is one of eight OSHA health and safety standards that have been similarly studied on a pre- and post-promulgation basis.

Boroush, M.A.

1993-11-01T23:59:59.000Z

191

Assessment of susceptibility to chloride stress corrosion cracking of highly alloyed stainless steels. Part 2: A new immersion test method  

SciTech Connect (OSTI)

A new method for assessment of susceptibility to chloride stress corrosion cracking under severe evaporative conditions has been developed. The basic idea is to test under submerged conditions simulating the electrolyte composition and concentration of sea water during evaporation. Two duplex and one austenitic stainless steel were tested loaded to the yield point at the test temperature. Time to failure, potential and temperature were recorded continuously. The results showed cracking of the austenitic material UNS S31254 at 110 C by long term testing. For the duplex stainless steels UNS S31803 and UNS S32750 cracking was observed at 100 C. The time to cracking was longest for the last mentioned and highest alloyed duplex material.

Drugli, J.M.; Steinsmo, U. [SINTEF Materials Technology, Trondheim (Norway)

1997-12-01T23:59:59.000Z

192

Assessment of organic compound exposures, thermal comfort parameters, and HVAC system-driven air exchange rates in public school portable classrooms in California  

E-Print Network [OSTI]

ND m e t h y l e n e chloride MTBE chloroprene c a r b o ny l e n e chloride Max. ND MTBE chloroform 0.11 N D c a r b1,3-butadiene methylene chloride MTBE chloroprene chloroform

Shendell, Derek Garth

2010-01-01T23:59:59.000Z

193

Corrosion of 304 Stainless Steel Exposed To Nitric Acid -Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson  

E-Print Network [OSTI]

Corrosion of 304 Stainless Steel Exposed To Nitric Acid - Chloride Environments D.G. Kolman, D.K. Ford, D.P. Butt, and T.O. Nelson Materials Corrosion and Environmental Effects Laboratory Los AlamosCl, and temperature on the general corrosion behavior of 304 stainless steel (SS), electrochemical studies were

194

HYPERSONIC INVESTIGATION OF THE A -T y p E PHASE TRANSITION IN AMMONIUM-CHLORIDE M. GROSS -D. GERLICH -and S. SZAPIRO  

E-Print Network [OSTI]

HYPERSONIC INVESTIGATION OF THE A - T y p E PHASE TRANSITION IN AMMONIUM-CHLORIDE M. GROSS - D method.The hypersonic sound velocities and elastic constants have been measured in the immediate vicinity measurements. The difference between the present hypersonic measurement and previous ultrasonic results

Paris-Sud XI, Université de

195

Enhancement of specific heat capacity of high-temperature silica-nanofluids synthesized in alkali chloride salt eutectics for solar thermal-energy  

E-Print Network [OSTI]

chloride salt eutectics for solar thermal-energy storage applications Donghyun Shin, Debjyoti Banerjee for the anoma- lous enhancement of thermal conductivity over that of the neat solvent. Eastman et al. [5] reported thermal conductivity enhance- ment of 30% and 60% for water based nanofluids of Al2O3 and Cu

Banerjee, Debjyoti

196

Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy  

E-Print Network [OSTI]

91D magnesium alloy R. AMBAT, N.N. AUNG and W. ZHOU School of Mechanical and Production Engineering in revised form 20 January 2000 Key words: AZ91D alloy, chloride ion, corrosion, die-cast, ingot, magnesium of morphology. The corrosion product consisted of magnesium hydroxide, fallen b particles and magnesium

Zhou, Wei

197

VICKERY, JOHN D. Fundamental Properties and Bond Characteristics of Chlorinated Polyvinyl Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under  

E-Print Network [OSTI]

Chloride and SS340 Adhesive for Evaluation of Steel Tank Linings. (Under the Direction of Dr. Sami Rizkalla.) Tank linings are used to extend the service life of tanks and to avoid replacement of damaged tanks is to understand the behavior of the different materials proposed for lining typical bleach tanks used in the pulp

198

Dynamics of electron transfer at the localized-to- delocalized transition of mixed valency  

E-Print Network [OSTI]

minus 1 state of complex 5 in acetonitrile as a function ofcomplexes 1 - – 4 - in acetonitrile and methylene chloride.All data is for the complexes in acetonitrile at 298

Glover, Starla Demorest

2011-01-01T23:59:59.000Z

199

A Systematic Study of Chloride Ion Solvation in Water using van der Waals Inclusive Hybrid Density Functional Theory  

E-Print Network [OSTI]

In this work, the solvation and electronic structure of the aqueous chloride ion solution was investigated using Density Functional Theory (DFT) based \\textit{ab initio} molecular dynamics (AIMD). From an analysis of radial distribution functions, coordination numbers, and solvation structures, we found that exact exchange ($E_{\\rm xx}$) and non-local van der Waals (vdW) interactions effectively \\textit{weaken} the interactions between the Cl$^-$ ion and the first solvation shell. With a Cl-O coordination number in excellent agreement with experiment, we found that most configurations generated with vdW-inclusive hybrid DFT exhibit 6-fold coordinated distorted trigonal prism structures, which is indicative of a significantly disordered first solvation shell. By performing a series of band structure calculations on configurations generated from AIMD simulations with varying DFT potentials, we found that the solvated ion orbital energy levels (unlike the band structure of liquid water) strongly depend on the underlying molecular structures. In addition, these orbital energy levels were also significantly affected by the DFT functional employed for the electronic structure; as the fraction of $E_{\\rm xx}$ was increased, the gap between the highest occupied molecular orbital of Cl$^-$ and the valence band maximum of liquid water steadily increased towards the experimental value.

Arindam Bankura; Biswajit Santra; Robert A. DiStasio Jr.; Charles W. Swartz; Michael L. Klein; Xifan Wu

2015-03-25T23:59:59.000Z

200

Study of vinyl chloride formation at landfill sites in California. Final report, 16 July 1985-15 January 1987  

SciTech Connect (OSTI)

The purpose of this study was to determine if vinyl chloride (VC) detected in air above California landfills is produced in situ. Experiments were performed with N and S California landfill samples and anaerobic-digestor sewage sludge. Test materials were incubated with various chlorocarbons and with /sup 13/C-trichloroethylene (TCE) to confirm biological production of /sup 13/C-VC. These experiments confirmed the biological dechlorination of chloroethylenes as the most likely route for VC emission from landfills, rather than chemical or photochemical routes, or PVC degradation. Leaching from PVC could be a minor source of VC, though there was less than 0.1% (estimated) plastic in the landfill samples, containing at most 330 ppm of VC monomer. A landfill sample known to produce VC was used to start an anaerobic chemostat using methanol as sole carbon source. The enriched culture resulting was homogeneous, and when incubated with /sup 13/C-TCE, produced (13)C-VC, confirmed by GC/MS.

Molton, P.M.; Hallen, R.T.; Payne, J.W.

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Study of benzotriazole as corrosion inhibitors of carbon steel in chloride solution containing hydrogen sulfide using electrochemical impedance spectroscopy (EIS)  

SciTech Connect (OSTI)

Corrosion and inhibition studies on API 5LX65 carbon steel in chloride solution containing various concentrations of benzotriazole has been conducted at temperature of 70°C using Electrochemical Impedance Spectroscopy (EIS). Corroded carbon steel surface with and without inhibitor have been observed using X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Energy Dispersive Spectroscopy (EDS). The objectives of this research are to study the performance of benzotriazole as corrosion inhibitors. The experimental results of carbon steel corrosion in 3.5% NaCl solution containing 500 mg/l H{sub 2}S at different BTAH concentrations showed that corrosion rate of carbon steel decreases with increasing of BTAH concentrations from 0 to 10 mmol/l. The inhibition efficiency of BTAH was found to be affected by its concentration. The optimum efficiency obtained of BTAH is 93% at concentration of 5 mmol/l. The result of XRD and EDS analysis reveal the iron sulfide (FeS) formation on corroded carbon steel surface without inhibitor. The EDS spectrum show the Nitrogen (N) bond on carbon steel surface inhibited by BTAH.

Solehudin, Agus, E-mail: asolehudin@upi.edu [Department of Mechanical Engineering Education, Indonesia University of Education (UPI), Bandung, West Java (Indonesia); Nurdin, Isdiriayani [Department of Chemical Engineering, Bandung Institute of Technology, Bandung, West Java (Indonesia)

2014-03-24T23:59:59.000Z

202

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

203

Process for the polymerization of vinyl chloride in aqueous suspension utilizing an oil-soluble initiator and subsequently a water-soluble initiator and use of the powders obtained thereby  

SciTech Connect (OSTI)

Process for the polymerization of vinyl chloride in aqueous suspension in the presence of a dispersing system comprising a cellulosic derivative and an anionic emulsifying agent wherein the polymerizaton is initiated by an oil-soluble initiator and a water-soluble free radical polymerization initiator is added in the course of polymerization. The thus obtained polyvinyl chloride powders are particularly suitable for the production of battery separators.

Petit, A.

1981-01-06T23:59:59.000Z

204

On the preparation of TiAl alloy by direct reduction of the oxide mixtures in calcium chloride melt  

SciTech Connect (OSTI)

In recent years, TiAl-based intermetallic alloys are being increasingly considered for application in areas such as (i) automobile/transport sector (passenger cars, trucks and ships) (ii) aerospace industry (jet engines and High Speed Civil Transport propulsion system) and (iii) industrial gas turbines. These materials offer excellent (i) high temperature properties (at higher than 6000C) (ii) mechanical strength and (iii) resistance to corrosion and as a result have raised renewed interest. The combination of these properties make them possible replacement materials for traditional nickel-based super-alloys, which are nearly as twice as dense (than TiAl based alloys). Since the microstructures of these intermetallic alloys affect, to a significant extent, their ultimate performance, further improvements (by way of alteration/modification of these microstructures), have been the subject matter of intense research investigations. It has now been established that the presence of alloy additives, such as niobium, tantalum, manganese, boron, chromium, silicon, nickel and yttrium etc, in specific quantities, impart marked improvement to the properties, viz. fatigue strength, fracture toughness, oxidation resistance and room temperature ductility, of these alloys. From a number of possible alloy compositions, {gamma}-TiAl and Ti-Al-Nb-Cr have, of late, emerged as two promising engineering alloys/materials. . The conventional fabrication process of these alloys include steps such as melting, forging and heat treatment/annealing of the alloy compositions. However, an electrochemical process offers an attractive proposition to prepare these alloys, directly from the mixture of the respective oxides, in just one step. The experimental approach, in this new process, was, therefore, to try to electrochemically reduce the (mixed) oxide pellet to an alloy phase. The removal of oxygen, from the (mixed) oxide pellet, was effected by polarizing the oxide pellet against a graphite electrode in a pool of molten calcium chloride at a temperature of 9000C. The dominant mechanism of the oxygen removal was the ionization of oxygen followed by its subsequent discharge, as CO2/CO, at the anode surface. The removal of oxygen from the oxide mixture helped form the alloy in situ. The presentation shall cover the detailed experimental results pertaining to the preparation, evaluation and characterization of Ti-47Al-2Nb-2Cr (atom%) alloy.

Prabhat K. Tripathy; Derek J. Fray

2011-11-01T23:59:59.000Z

205

"Kohn-Shamification" of the classical density-functional theory of inhomogeneous polar molecular liquids with application to liquid hydrogen chloride  

E-Print Network [OSTI]

The Gordian knot of density-functional theories for classical molecular liquids remains finding an accurate free-energy functional in terms of the densities of the atomic sites of the molecules. Following Kohn and Sham, we show how to solve this problem by considering noninteracting molecules in a set of effective potentials. This shift in perspective leads to an accurate and computationally tractable description in terms of simple three-dimensional functions. We also treat both the linear- and saturation- dielectric responses of polar systems, presenting liquid hydrogen chloride as a case study.

Johannes Lischner; T. A. Arias

2008-06-27T23:59:59.000Z

206

An experimental investigation of the effect of sodium chloride on talc solubility and complexing of aqueous magnesium in supercritical hydrothermal fluids  

E-Print Network [OSTI]

using the Ag-AgCI buffer technique (Frantz and Eugster, 1973). At 500'C the concentration of total magnesium decreased in a nonlinear fashion from 2. 75 molal in the NaCl-free system to 1. 52 molal at 5. 13 molal total NaC1. The dominant Mg species... been studied in buffered chloride-bearing solutions using the Ag-AgCl buffer technique (Frantz and Eugster, 1973) to control the activity of aqueous HC1' (Chou and Eugster, 1977; Gunter and Eugster, 1978; Frantz and Popp, 1979; Popp and Frantz, 1979...

Grabman, Kenneth Bryan

1989-01-01T23:59:59.000Z

207

Study of the dependence of the specific output power of a copper chloride laser on the radial temperature profile of a gas plasma  

SciTech Connect (OSTI)

The design of a copper chloride laser is described, and the laser is optimised by studying the dependence of its output power on the buffer gas type. The voltage and current of the laser discharge at the optimum buffer gas pressure are measured. The influence of the diaphragm diameter on the specific output power is studied after optimisation of switch parameters. When an diaphragm producing the optimal temperature gradient in the laser gas-discharge tube, the record specific output power of 123 W L{sup -1} is obtained without any admixtures. (lasers)

Sadighi-Bonabi, R; Mohammadpour, R; Tavakoli, M [Physics Department, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Soltanmoradi, F [Bonab Research Center, Bonab, Azerbaijan province (Iran, Islamic Republic of); Zand, M [Laser Research Center, Tehran (Iran, Islamic Republic of)

2007-04-30T23:59:59.000Z

208

The synthesis and crystal structures of the first rare-earth alkaline-earth selenite chlorides MNd{sub 10}(SeO{sub 3}){sub 12}Cl{sub 8} (M=Ca and Sr)  

SciTech Connect (OSTI)

Two new alkaline-earth Nd selenite chlorides MNd{sub 10}(SeO{sub 3}){sub 12}Cl{sub 8} (M=Ca, Sr) were obtained using crystal growth from alkaline-earth chloride melts in quartz tubes. These new compounds crystallize in the orthorhombic system in space group C cca (no. 68). The compounds were studied by energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction. It was shown that both compounds adopt the same structure type, constructed by complex [M{sub 11}(SeO{sub 3}){sub 12}]{sup 8+} slabs separated by chloride anion layers perpendicular to the longest cell parameter. The SeO{sub 3} groups show a pyramidal shape and may be described as SeO{sub 3}E tetrahedra. Such SeO{sub 3} groups decorate the Nd-O skeletons forming the [M{sub 11}(SeO{sub 3}){sub 12}]{sup 8+} slabs. - Graphical abstract: Two new alkaline-earth Nd selenite chlorides MNd{sub 10}(SeO{sub 3}){sub 12}Cl{sub 8} (M=Ca, Sr) were synthesized. These structures are constructed by [M{sub 11}(SeO{sub 3}){sub 12}]{sup 8+} slabs separated by chloride anion layers.

Berdonosov, P.S. [Department of Chemistry, Moscow State University, Leninskie Gory, Moscow 119992 (Russian Federation)], E-mail: psberd@inorg.chem.msu.ru; Olenev, A.V.; Dolgikh, V.A. [Department of Chemistry, Moscow State University, Leninskie Gory, Moscow 119992 (Russian Federation); Lightfoot, P. [EaStChem, School of Chemistry, St. Andrews University, St. Andrews, KY16 9ST (United Kingdom)

2007-11-15T23:59:59.000Z

209

Radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. IV. Effect of diundecyl phthalate: dependence of physical properties on composition. [Electron beam ion sources  

SciTech Connect (OSTI)

Blends of poly(vinyl chloride)(PVC) with polyfunctional monomers may be crosslinked by ionizing radiation. The physical properties of PVC blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) were studied. The TMPTMA monomer crosslinked the blend by homopolymerization and/or grafting to PVC. The plasticizer, DUP, was chemically inert under irradiation but, by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. Characteristics of the glass transitions and the tensile mechanical properties have been correlated with blend composition and radiation dose. Before irradiation, poly(vinyl chloride) was plasticized by both DUP and TMPTMA monomer. The increase in glass transition temperature and mechanical strength following irradiation to 5 Mrad was correlated with the TMPTMA content of the blend. Both the molecular structure of the network and the DUP content of the blend were factors in determining the physical properties of the final crosslinked blend. The molecular structure was determined by the kinetics of the crosslinking reactions, which in turn were determined by the blend composition. A molecular interpretation consistent with the physical properties, chemical kinetics, and mechanism of the crosslinking system has been presented. 24 figures, 2 tables.

Bowmer, T.N.; Vroom, W.I.

1983-11-01T23:59:59.000Z

210

Technology Evaluations Related to Mercury, Technetium, and Chloride in Treatment of Wastes at the Idaho Nuclear Technology and Engineering Center of the Idaho National Engineering and Environmental Laboratory  

SciTech Connect (OSTI)

The Idaho High-Level Waste and Facility Disposition Environmental Impact Statement defines alternative for treating and disposing of wastes stored at the Idaho Nuclear Technology and Engineering Center. Development is required for several technologies under consideration for treatment of these wastes. This report contains evaluations of whether specific treatment is needed and if so, by what methods, to remove mercury, technetium, and chlorides in proposed Environmental Impact Statement treatment processes. The evaluations of mercury include a review of regulatory requirements that would apply to mercury wastes in separations processes, an evaluation of the sensitivity of mercury flowrates and concentrations to changes in separations processing schemes and conditions, test results from laboratory-scale experiments of precipitation of mercury by sulfide precipitation agents from the TRUEX carbonate wash effluent, and evaluations of methods to remove mercury from New Waste Calcining Facility liquid and gaseous streams. The evaluation of technetium relates to the need for technetium removal and alternative methods to remove technetium from streams in separations processes. The need for removal of chlorides from New Waste Calcining Facility scrub solution is also evaluated.

C. M. Barnes; D. D. Taylor; S. C. Ashworth; J. B. Bosley; D. R. Haefner

1999-10-01T23:59:59.000Z

211

Preparation and Properties of Poly(ethylene oxide) Star Nicholas A. Peppas, Ankush Argade, Saumitra Bhargava  

E-Print Network [OSTI]

(ethylene oxide) (PEO) star polymers were prepared by anionic polymerization of methacryloyl chloride and glyceryl) of molecular weight 400. The final product was washed with methylene chloride and analyzed with infrared with sequential polymerization of multifunctional monomers from styrene and divinylbenzene (DVB).1 First

Peppas, Nicholas A.

212

Exposure to Methylene Diphenyl Diisocyante (MDI) among polyurethane roof workers  

E-Print Network [OSTI]

in the typical symptoms of asthma, "' i. e. , recurrent episodes of difficulty in breathing, wheezing (especially on expiration), cough and thick mucus production. "' The asthmatic reaction may develop immediately or some time after the first exposure. Some... hyperreactivity, chronic deterioration in lung function, and hypersensitivity pneumonitis. '" At high isocyanate exposures, all employees can experience conjunctival irritation, nasal congestion, scratchy throat, nonproductive cough, and dyspnea. For longer...

Narvaez-Cuevas, Carmen Lourdes

1996-01-01T23:59:59.000Z

213

Methylene Blue as a Cerebral Metabolic and Hemodynamic Enhancer  

E-Print Network [OSTI]

. Glickman, MD, Endowed Chair in Ophthalmic Research. The funders had no role in study design, data the PLOS ONE policies on sharing data and materials. * E-mail: lina3@uthscsa.edu (ALL); shaohua.yang@unthsc.edu (SHY); duongt@uthscsa.edu (TD) Introduction As powerhouses in mammalian cells, mitochondria are respon

Duong, Timothy Q.

214

The gas phase reactions of methylene with propionaldehyde  

E-Print Network [OSTI]

. 03 2. 93 2. 01 11. 08 11. 03 9. 95 15. 82 14. 06 9. 80 11. 29 15. 96 11. 70 11, 49 9. 27 10. 56 2Z. 30 7. 96 7. 90 4. 64 1. 83 5. 97 2. 05 3. 41 2. 51 Z. 9Z 2. 74 3. 18 2. 87 1. 78 1. 94 2. 20 1. 86 2. 11 1. 73 1. 97... of the data in table IU fit to equa- tions 38-40 gave the f'ol lowing results. slope (eq. 38) ? 53~30 torr slope (eq. 39) =- 2~3 torr slope (eq. 40) = 14-22 torr intercept (eq. 48) = 21. 9. 4. 6 intercept (eq. 39) = 2. 46a0. 45 intercept (eq. 40) = 10...

Fuqua, Peter Joseph

1974-01-01T23:59:59.000Z

215

The radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. III. Effect of diundecyl phthalate: chemical kinetics of a three-component system  

SciTech Connect (OSTI)

The radiation chemistry of poly(vinyl chloride) (PVC) blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) has been examined. This three-component mixture contains a base resin (PVC), a crosslinking sensitizer (TMPTMA), and a physical modifier (DUP). These are the basic components in any radiation-curable coating. The kinetics and mechanism of the crosslinking reactions were studied with reference to the dependence on radiation dose and blend composition. The polyfunctional TMPTMA underwent polymerization incorporating the PVC into a 3-dimensional network. DUP remained chemically inert during the irradiation, not being bound to the network. However, DUP by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. DUP enhanced TMPTMA homopolymerization, TMPTMA grafting, and PVC crosslinking reaction rates. The effect of the competition between polymerization, grafting, and degradation reactions was examined in terms of enhanced mobility of the reacting species. The influence of these kinetics considerations in selecting a blend composition for a coating application was discussed.

Bowmer, T.N.; Vroom, W.I.; Hellman, M.Y.

1983-08-01T23:59:59.000Z

216

A group of new selenite-chlorides of strontium and d-metals (Co,Ni): Synthesis, thermal behavior and crystal chemistry  

SciTech Connect (OSTI)

The new selenite-chlorides with composition Sr{sub 3}(SeO{sub 3}){sub 2}Cl{sub 2} (I) and Sr{sub 2}M(SeO{sub 3}){sub 2}Cl{sub 2} (M=Co, Ni (II and III)) were obtained. They crystallize in monoclinic system I: space group C2/m, a=13.203(2) A, b=5.5355(8) A, c=6.6170(10) A, {beta}=95.89(1){sup o}, Z=2; II Space group P2{sub 1}/n, a=5.3400(10) A, b =6.4279(6) A, c=12.322(1) A, {beta}=92.44(1){sup o}, Z=2; III: space group P2{sub 1}/n, a=5.3254(11) A, b=6.4363(13) A, c=12.197(2), {beta}=92.53(3){sup o}, Z=2. All three compounds are constructed in the same manner. Sr polyhedra form infinite layers, which are interconnected into a 3D framework by means of Sr polyhedra in the case of I or Co and Ni polyhedra in the case of II and III. Se atoms are situated inside the channels of the 3D framework. The topological analysis of ELF for I confirmed that the lone electron pairs of SeO{sub 3} groups are located inside these channels. - Graphical abstract: Three new selenite-chlorides Sr{sub 3}(SeO{sub 3}){sub 2}Cl{sub 2} and Sr{sub 2}M(SeO{sub 3}){sub 2}Cl{sub 2} (M= Co,Ni)

Berdonosov, Peter S. [Department of Chemistry, Moscow State University, GSP-1, Leninskie Gory, 1 Build. 3, 119991 Moscow (Russian Federation)], E-mail: berdonosov@inorg.chem.msu.ru; Olenev, Andrey V.; Kuznetsov, Alexei N.; Dolgikh, Valery A. [Department of Chemistry, Moscow State University, GSP-1, Leninskie Gory, 1 Build. 3, 119991 Moscow (Russian Federation)

2009-01-15T23:59:59.000Z

217

Synthesis, crystal structure and magnetic property of a new nickel selenite chloride: Ni{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2}  

SciTech Connect (OSTI)

The new nickel selenite chloride, Ni{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2}, was obtained by high-temperature solid state reaction of NiCl{sub 2}, Ni{sub 2}O{sub 3} and SeO{sub 2} in a 1:2:4molar ratio at 700{sup o}C in an evacuated quartz tube. Its structure was established by single-crystal X-ray diffraction. Ni{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2} crystallizes in the triclinic system, space group P-1 (No. 2) with cell parameters of a=8.076(2), b=9.288(2), c=9.376(2)A, {alpha}=101.97(3), {beta}=105.60(3), {gamma}=91.83(3){sup o} and Z=2. All nickel(II) ions in Ni{sub 5}(SeO{sub 3}){sub 4}Cl{sub 2} are octahedrally coordinated by selenite oxygens or/and chloride anions (([Ni(1)O{sub 5}Cl], [Ni(2)O{sub 4}Cl{sub 2}], [Ni(3)O{sub 5}Cl], [Ni(4)O{sub 6}] and [Ni(5)O{sub 4}Cl]). The structure of the title compound features a condensed three-dimensional (3D) network built by Ni(II) ions interconnected by SeO{sub 3}{sup 2-} anions as well as Cl{sup -} anions. Magnetic property measurements show strong antiferromagnetic interaction between nickel(II) ions.

Shen Yueling [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China); Mao Jianggao [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China)]. E-mail: mjg@ms.fjirsm.ac.cn; Jiang Hailong [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, and the Graduate School of the Chinese Academy of Sciences, Fuzhou 350002 (China)

2005-09-15T23:59:59.000Z

218

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

219

Methyl chloride via oxyhydrochlorination of methane: A building block for chemicals and fuels from natural gas. Quarterly technical progress report No. 01, September 30, 1996--December 31, 1996  

SciTech Connect (OSTI)

The objectives of this cooperative agreement are to develop the oxyhydrochlorination (OHC) process for the conversion of methane to methyl chloride. In the first Phase of the project, Dow Corning has developed a stable selective catalyst and demonstrated the technology on a laboratory and a pilot plant scale. Specific tasks to achieve these objectives have been developed as follows: TASK 1 Fundamental Technical and Economic Evaluation TASK 2 Catalyst Selection Optimization and Characterization Studies TASK 3 Pilot Plant Design TASK 4 Pilot Plant Detailed Engineering, Procurement and Construction TASK 5 Pilot Plant Startup and Operation TASK 6 Pilot Plant Process Optimization TASK 7 Pilot Plant Extended Operation TASK 8 Pilot Plant Economic Evaluation/Scale-up Decision Significant progress has been completed in Task 1 with the objective to complete a fundamental technical and economic evaluation of learning gathered the Phase I effort of this project. A decision to proceed with the project will be made after completion of this Task. A computer model of the reactor system has been developed, which includes heat and mass transfer effects as well as reactions. Model validation is in progress. The Absorber/Stripper technology evaluated and implemented on the Phase I PDU to recover chlorocarbons (including methyl chloride) from reaction products has been scaled to evaluate economics for a commercial scale plant. In a parallel exercise, alternate recovery technologies were investigated for economic evaluation, to assure that the minimum capital option is pursued for the Phase II design. Commercial scale plant equipment and total plant costs are being evaluated using information from the Phase I PDU, reactor modeling and recovery system evaluation to estimate capital and operating costs for a commercial scale OHC unit.

Wineland, J.

1997-01-16T23:59:59.000Z

220

Effect of bicarbonate ion additives on pitting corrosion of type 316L stainless steel in aqueous 0.5 M sodium chloride solution  

SciTech Connect (OSTI)

The effect of bicarbonate ions (HCO{sub 3}{sup {minus}}) on pitting corrosion of type 316L stainless steel (SS, UNS S3 1603) was investigated in aqueous 0.5 M sodium chloride (NaCl) solution using potentiodynamic polarization, the abrading electrode technique, alternating current (AC) impedance spectroscopy combined with x-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). Addition of HCO{sub 3}{sup {minus}} ions to NaCl solutions extended the passive potential region in width and, at the same time, raised the pitting potential in value on the potentiodynamic polarization curve. Potentiostatic current transients obtained from the moment just after interrupting the abrading action showed the repassivation rate of propagating pits increased and that the pit growth rate decreased with increasing HCO{sub 3}{sup {minus}} ion concentration. Over the whole applied potential, the oxide film resistance was higher in the presence of HCO{sub 3}{sup {minus}} ions. The pit number density decreased with increasing HCO{sub 3}{sup {minus}} ion concentration. Moreover, addition of HCO{sub 3}{sup {minus}} ions to NaCl solutions retarded lateral pit growth, while promoting downward pit growth from the surface. The bare surface of the specimen repassivated preferentially along the pit mouth and walls, compared to the pit bottom, as a result of formation of a surface film with a high content of protective mixed ferrous-chromous carbonate ([Fe,Cr]CO{sub 3}) that formed from preferential adsorption of HCO{sub 3}{sup {minus}} ions.

Park, J.J.; Pyun, S.I.; Lee, W.J. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Materials Science and Engineering; Kim, H.P. [Korea Atomic Energy Research Inst., Taejon (Korea, Republic of)

1999-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Broensted superacidity of HCl in a liquid chloroaluminate. AlCl sub 3 -1-ethyl-3-methyl-1H-imidazolium chloride  

SciTech Connect (OSTI)

The system HCl (0.1-1 atm)/AlCl{sub 3}-EMIC (55.0 mol % AlCl{sub 3}) (EMIC = 1-ethyl-3-methyl-1H-imidazolium chloride) at 23{degree}C is a Broensted superacid capable of protonating arenes to a degree similar to that of liquid HF at 0{degree}C (H{sub 0} = {minus}15.1). Arenes used in this investigation were biphenyl (I), naphthalene (II), 9H-fluorene (III), chrysene (IV), 2-methylnaphthalene (V), mesitylene (VI), pentamethylbenzene (VII), hexamethylbenzene (VIII), anthracene (IX), and 9,10-dimethylanthracene (X). In both the chloroaluminate melt and HF I is a weak base while VIII-X are strong bases. In between these extremes the order of basicities in both media is II < III and IV < V < VI < VII < VIII. A study of the effect of HCl partial pressure showed, for example that V is 50% protonated at 0.3 atm HCl. The overall reaction is arene + HCl + Al{sub 2}Cl{sub 7}{sup {minus}} {r reversible} arene {times} H{sup +} + 2AlCl{sub 4}{sup {minus}} and is reversible. The degree of protonation was measured by optical absorption spectrophotometry. The arenes are stable in the liquid chloroaluminate for many hours, and their protonated forms (arenium ions) are stable for 1 h or more. A new procedure for the preparation of EMIC was developed that yields exceptionally clean AlCl{sub 3}-EMIC melts with very low concentrations of protic and oxidizing impurities. 17 refs., 6 figs., 2 tabs.

Smith, G.P.; Dworkin, A.S.; Zingg, S.P. (Oak Ridge National Lab., TN (USA)); Pagni, R.M. (Univ. of Tennessee, Knoxville (USA))

1989-01-18T23:59:59.000Z

222

Quality assurance in the Brenham Residue Lab  

E-Print Network [OSTI]

the methylene chloride layer through sodium sulfate into a 588 mL Kurdina-Danish flask with a 18 mL Mills Tube. Add 1 or 2 Carborundum boiling chips and attach a Snyder column and evaporate on a steam bath to about 2 mL. Take this to dzyness on a N...

Jackson, Jerry

1988-01-01T23:59:59.000Z

223

Precision measurements of binary and multicomponent diffusion coefficients in protein solutions relevant to crystal growth: Lysozyme chloride in water and aqueous NaCl at pH 4.5 and 25{degree}C  

SciTech Connect (OSTI)

Accurate models of protein diffusion are important in a number of applications, including liquid-liquid phase separation and growth of protein crystals for X-ray diffraction studies. In concentrated multicomponent protein systems, significant deviations from pseudobinary behavior can be expected. Rayleigh interferometry is used to measure the four elements (D{sub if}){sub v} of the ternary diffusion coefficient matrix for the extensively investigated protein, hen egg-white lysozyme (component 1) in aqueous NaCl (component 2) at pH 4.5 and 25 C. These are the first multicomponent diffusion coefficients measured for any protein system at concentrations high enough to be relevant to modeling and prediction of crystal growth or other phase transitions, and the first for a system involving lysozyme at any concentration. The four ternary diffusion coefficients for the system lysozyme chloride/NaCl/water are reported for lysozyme chloride at 0.60 mM (8.6 mg/mL) and NaCl at concentrations of 0.25, 0.50, 0.65, 0.90, and 1.30 M (1.4, 2.8, 3.7, 5.1, and 7.2 wt %), with the latter two compositions being supersaturated. One cross-term, (D{sub 21}){sub v}, is 80--259 times larger than the main term (D{sub 11}){sub v} and 7--18 times larger than (D{sub 22}){sub v}. Standard interferometric diagnostic tests indicate that aggregation is unimportant in the experiments. The authors also present binary diffusion coefficients D{sub v} for lysozyme chloride/water at concentrations from 0.43 to 3.08 mM (6.2--44.1 mg/mL), at the same pH and temperature. The precision of the results is about 0.1% for the binary diffusion coefficients and diagonal ternary diffusion coefficients, and about 1--2% for the cross-terms. For the ternary systems investigated, they show that a single pseudobinary diffusion coefficient does not accurately describe diffusive transport, and predictions by simple models such as the Nernst-Hartley equations are inaccurate at the higher concentrations considered here. Finally, dynamic light-scattering diffusion coefficients, differing form both the interferometrically measured (D{sub ij}){sub v} and a theoretical prediction of light-scattering diffusion coefficients in multicomponent systems, are reported for the same solutions used for the ternary experiments at 1.30 M.

Albright, J.G.; Annunziata, O. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; Miller, D.G. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Lawrence Livermore National Lab., CA (United States); Paduano, L. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Univ. di Napoli, Naples (Italy). Dipt. di Chimica; Pearlstein, A.J. [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering] [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering

1999-04-14T23:59:59.000Z

224

Fluid diversion and sweep improvement with chemical gels in oil recovery processes. [Four types of gels: resorcinol-formaldehyde; colloidal silica; Cr sup 3+ (chloride)-xanthan; and Cr sup 3+ (acetate)-polyacrylamide  

SciTech Connect (OSTI)

The objectives of this project were to identify the mechanisms by which gel treatments divert fluids in reservoirs and to establish where and how gel treatments are best applied. Several different types of gelants were examined, including polymer-based gelants, a monomer-based gelant, and a colloidal-silica gelant. This research was directed at gel applications in water injection wells, in production wells, and in high-pressure gas floods. The work examined how the flow properties of gels and gelling agents are influenced by permeability, lithology, and wettability. Other goals included determining the proper placement of gelants, the stability of in-place gels, and the types of gels required for the various oil recovery processes and for different scales of reservoir heterogeneity. During this three-year project, a number of theoretical analyses were performed to determine where gel treatments are expected to work best and where they are not expected to be effective. The most important, predictions from these analyses are presented. Undoubtedly, some of these predictions will be controversial. However, they do provide a starting point in establishing guidelines for the selection of field candidates for gel treatments. A logical next step is to seek field data that either confirm or contradict these predictions. The experimental work focused on four types of gels: (1) resorcinol-formaldehyde, (2) colloidal silica, (3) Cr{sup 3+}(chloride)-xanthan, and (4) Cr{sup 3+}(acetate)-polyacrylamide. All experiments were performed at 41{degrees}C.

Seright, R.S.; Martin, F.D.

1992-09-01T23:59:59.000Z

225

Water Content and Buildup of Poly(diallyldimethylammonium chloride)/ Poly(sodium 4-styrenesulfonate) and Poly(allylamine hydrochloride)/ Poly(sodium 4-styrenesulfonate) Polyelectrolyte Multilayers Studied by an in Situ Combination of a Quartz Crystal Micr  

E-Print Network [OSTI]

ABSTRACT: The buildup of polyelectrolyte multilayers (PEMs), fabricated by the layer-by-layer (LBL) assembly, was followed in situ by the combination of a quartz crystal microbalance with dissipation monitoring (QCM-D) and spectroscopic ellipsometry in a single device. PEMs composed of poly(allylamine hydrochloride) (PAH) and poly(sodium 4-styrenesulfonate) (PSS) polyelectrolyte pairs and of poly-(diallyldimethyl ammonium chloride) (PDADMAC) and PSS were built up to 17 layers. The combination of ellipsometry andQCM-D allowed simultaneous determination of the acousticmass, which comprises both the mass of the polymer and solvent, and the optical mass which corresponds to the polymer mass alone. From these parameters, the hydration of the PEMwas calculated layer by layer. The linearly growing PAH/ PSS PEMs showed a constant absolute content of water throughout the assembly, while the relative contribution of water to the PEM mass content approached zero, when grown in 0.5 M NaCl. Rinses with water between polyelectrolyte deposition steps resulted in a hydration of approximately 40%. The supralinearly growing PDADMAC/PSS PEMs exhibited a remarkable dependence of the hydration on the polyelectrolyte that was deposited last. Implications for the mechanism of assembly of the PEMs are discussed.

Jagoba J. Iturri Ramos; Stefan Stahl; Ralf P. Richter; Sergio E. Moya

2010-01-01T23:59:59.000Z

226

Isolation of a strain of Agrobacterium tumefaciens (Rhizobium radiobacter) utilizing methylene urea  

E-Print Network [OSTI]

(ureaformaldehyde) as nitrogen source Marja E. Koivunen, Christophe Morisseau, William R. Horwath, and Bruce D) held in the MU polymer has to be hydrolyzed and converted into ammonium ions in the soil. Benefits from

Hammock, Bruce D.

227

E-Print Network 3.0 - active methylene compounds Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Biology and Medicine ; Chemistry 48 1,4-Dimethyl-l,4,5,6-hexahydro-l,2,3,4-tetrazine. A Cyclic cis-2-Tetrazene Summary: . Received May 22, 1972 Abstract: The preparation...

228

E-Print Network 3.0 - active methylene groups Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Technology Collection: Chemistry 84 1,4-Dimethyl-l,4,5,6-hexahydro-l,2,3,4-tetrazine. A Cyclic cis-2-Tetrazene Summary: ) are described. The decrease in activation...

229

Reactions of dimethyl carbonyl ylide produced by singlet methylene reactions with acetone in the gas phase  

E-Print Network [OSTI]

and infinitely dilute systems at 436 nm and 365 nm irradiations Least squares plot of [NH][ACE]/[V][NP] ratio versus mole fraction of acetone at 436 nm. . . . . ~ RRKN results for diradical fragmentation to propene and formaldehyde RRKM results for ylide... fragmentation to propene and formaldehyde 93 Potential energy diagram for IBOX to 2HP isomerization 95 Entropy changes for diradical and ylide isomerizations 97 LIST OF FIGURES (continued) ~Fi e 16 17 18 19 RRKN results for diradical isomerization...

Buckley, Gary Steven

1978-01-01T23:59:59.000Z

230

Molecular Quantum Mechanics 2010: From Methylene to DNA and Beyond Conference Support  

SciTech Connect (OSTI)

This grant was $12500 for partial support of an international conference, Molecular Quantum Mechanics 2010, which was held on the campus of the University of California, Berkeley, from 24 to 29 May 2010. The conference involved more than 250 participants. The conference schedule ran from as early as 8:00 AM to as late as 10:30 PM at night, in order to accommodate six historical lectures, 16 plenary lectures, 42 invited talks and two very strong poster sessions containing 143 contributed posters. Since 1989, the Molecular Quantum Mechanics (MQM) series of international conferences has show- cased the frontiers of research in quantum chemistry with a strong focus on basic theory and algorithms, as well as highlights of topical applications. Both were strongly in evidence at MQM 2010. At the same time as embracing the future, the MQM conferences also honour the lifetime contributions of some of the most prominent scientists in the field of theoretical and computational quantum chemistry. MQM 2010 recognised the work of Prof. Henry F. ‘Fritz’ Schaefer of the Center for Computational Chemistry at the University of Georgia, who was previously on the faculty at Berkeley The travel of invited speakers was partially covered by sponsorships from Dell Computer, Hewlett-Packard, Journal of Chemical Theory and Computation, Virginia Tech College of Science, Molecular Physics, Q-Chem Inc and the American Institute of Physics. By contrast, the conference grant from the Department of Energy was used to provide fellowships and scholarships to enable graduate students and postdoctoral fellows to attend the meeting, and thereby broaden the participation of young scientists at a meeting where in the past most of the attendees have been more senior faculty researchers. We believe that we were very successful in this regard: 118 students and postdocs attended out of the total of 256 participants. In detail, the DOE sponsorship money was partially used for dormitory scholarships that covered the cost of shared accommodation for students and postdocs at Berkeley dormitories. This covered the $200-$305 cost of a shared room for the 5-day duration of the conference. The only condition of these scholarships was that the awardee must present a poster at the meeting. Approximately $7565 was spent for these dormitory scholarships. The remaining expenditures of $4800 was used for 12 merit scholarships which were awarded to students whose poster presentations were judged the best at the conference. This amount covered a significant part of their travel and registration fees.

None

2013-05-15T23:59:59.000Z

231

E-Print Network 3.0 - a-methylene-g-butyrolactones versatile...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

systems like Ges Source: Olsen Jr., Dan R. - Department of Computer Science, Brigham Young University Collection: Computer Technologies and Information Sciences 40 AN ALGORITHM...

232

Synthesis and physical properties of novel perfluorinated methylene oxide oligomers. The ultimate low temperature fluids  

SciTech Connect (OSTI)

Perfluorinated polyethers are a class of substances which are extremely inert and have both extraordinary high temperature stability and low temperature properties. The synthesis of perfluorinated polyformaldehydes with the highest oxygen content was designed to give the maximum liquid range and low temperature properties. Novel low molecular weight perfluorinated polyformaldehydes with stable and unreactive perfluoro-n-butyl end groups were prepared by liquid-phase direct fluorination. The boiling point of these compounds increases by approximately 20{degree}C with the addition of each difluoromethylene oxide unit. This trend does not continue for longer chain lengths (n > 4) where the increase in boiling point per CF{sub 2}O unit diminishes. The average increase of melting temperature is approximately 1-2{degree}C as the perfluorinated polyformaldehyde chain increases one difluoromethylene oxide unit. The new perfluoropolyether fluids produced have melting points ranging from -145 to -152{degree}C. 33 refs., 3 tabs.

Sung, K.; Lagow, R.J. [Univ. of Texas, Austin, TX (United States)

1995-04-19T23:59:59.000Z

233

Methylene Bromide Chemistry and Photochemistry on Rutile TiO2(110). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping theEnergyInnovation Portalarticles ofthe Yakama Nation

234

An XAFS Study of Nickel Chloride in the Ionic Liquid 1-ethyl-3-methyl Imidazolium Chloride/ Aluminum Chloride  

SciTech Connect (OSTI)

The electrodeposition of metals from aqueous solutions has a successful history for many metals. However, some metals cannot be deposited from aqueous solutions because their potentials fall outside of the window of stability for water. Using ionic liquids for the electrodeposition of metals can avoid some of these difficulties because they have a larger region of stability than water. The electrochemical window can be tailored to fit a particular application by choosing appropriate anions and cations to form the melt. There is also the possibility to deposit pure metals without the oxides and hydrides that can form in aqueous solutions. The study of the structure of metal salts in ionic liquids is an important step towards achieving these goals.

Roeper, D.; Cheek, G; Pandya, K; O'Gragy, W

2008-01-01T23:59:59.000Z

235

Acetylene Inhibition of Trichloroethene and Vinyl Chloride  

E-Print Network [OSTI]

and enhanced anaerobic remediation of chloroethenes at contaminated sites. The results also suggest that acetylene produced abiotically by reactions of chlorinated ethenes with zero-valent iron could inhibit water standard (2 µg/L) (3). A variety of biochemical tools have been used to probe the complexity

Semprini, Lewis

236

The physical characterization of dimethyldioctadecylammonium chloride vesicles  

E-Print Network [OSTI]

that liposomes are indeed single bilayers and sealed by selective line broadening experiments. When paramagnetic ions, such as Mn, are added to sonicated lipid-water solutions the proton +2 signals of 70%%d of the ii(CH3)3 broadened out. The signal broadened.... 0 0 O. ??? O O. l- t3 0 5- CG O U 0 tJ ??- O ??? O O? O O O ) ??l ??l ?P ??? C3 O O. ?D 5 O ?g E ?U tl ?A 5 ??l O? ?? 0 III 0. 0 CL I- 0 0l I- CJ t3 n5 Ql 0 0 CL 0 N I- nl I? nl Vl lI- 0 EU ln 0 Ql I...

Klahn, Patricia Lynn

2012-06-07T23:59:59.000Z

237

Chloride Depletion in Aged Sea Salt Particles  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation SitesStandingtheirCheck InChemistry OxideChenChevron,|X I

238

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Second quarter 1993  

SciTech Connect (OSTI)

Groundwater monitoring continued at the Savannah River Plant. During second quarter 1993, nine constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents. Chloroethene (vinyl chloride), dichloromethane (methylene chloride), 1,1-dichloroethylene, gross alpha, lead, nonvolatile beta, or tetrachloroethylene also exceeded standards in one or more wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-09-01T23:59:59.000Z

239

Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly(diallyldimethylammonium chloride)s  

E-Print Network [OSTI]

1 Preparation of Solid Alkaline Fuel Cell Binders Based on Fluorinated Poly to be used in a Solid Alkaline Fuel Cell (SAFC) needs to (i) be insoluble in both aqueous solutions,10% > 320 °C). When used in a fuel cell as a binder in the membrane-electrodes assembly (MEA

Paris-Sud XI, Université de

240

Highly Enantioselective Syntheses of Functionalized r-Methylene--butyrolactones via Rh(I)-catalyzed Intramolecular Alder Ene  

E-Print Network [OSTI]

the utility of our methodology, we introduced various functional groups at the allylic position (Table 3). If R2 is an acetyl group, the desired product is a vinyl acetate-substituted -lactone. If R2 is an alkyl group, a vinyl ether is the corresponding product. Due to the wide applications of vinyl acetates

Zhang, Xumu

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Mechanisms of growth inhibition induced by methylene-substituted and ring-substituted dims in breast cancer cells  

E-Print Network [OSTI]

-MB-231 and MDA-MB-453 breast cancer cell growth was inhibited after treatment with a novel series of methylenesubstituted DIMs (C-DIMs), namely 1,1-bis(3’-indolyl)-1-(p-substitutedphenyl) methanes containing trifluoromethyl (DIM-C-pPhCF3), t-butyl (DIM...

Vanderlaag, Kathryn Elisabeth

2009-05-15T23:59:59.000Z

242

Production of permeable cellulose triacetate membranes  

DOE Patents [OSTI]

A phase inversion process for the preparation of cellulose triacetate (CTA) and regenerated cellulose membranes is disclosed. Such membranes are useful as supports for liquid membranes in facilitated transport processes, as microfiltration membranes, as dialysis or ultrafiltration membranes, and for the preparation of ion-selective electrodes. The process comprises the steps of preparing a casting solution of CTA in a solvent comprising a mixture of cyclohexanone and methylene chloride, casting a film from the casting solution, and immersing the cast film in a methanol bath. The resulting CTA membrane may then be hydrolyzed to regenerated cellulose using conventional techniques.

Johnson, B.M.

1986-12-23T23:59:59.000Z

243

Production of permeable cellulose triacetate membranes  

DOE Patents [OSTI]

A phase inversion process for the preparation of cellulose triacetate (CTA) and regenerated cellulose membranes is disclosed. Such membranes are useful as supports for liquid membranes in facilitated transport processes, as microfiltration membranes, as dialysis or ultrafiltration membranes, and for the preparation of ion-selective electrodes. The process comprises the steps of preparing a casting solution of CTA in a solvent comprising a mixture of cyclohexanone and methylene chloride, casting a film from the casting solution, and immersing the cast film in a methanol bath. The resulting CTA membrane may then be hydrolyzed to regenerated cellulose using conventional techniques.

Johnson, Bruce M. (Bend, OR)

1986-01-01T23:59:59.000Z

244

Testing of a model to estimate vapor concentration of various organic chemicals. Master's thesis  

SciTech Connect (OSTI)

A model developed by Dr. Parker C. Reist to predict the build-up and decay rates of vapor concentrations following a chemical spill and clean-up was tested. The chemicals tested were: acetone, butyl acetate, ethyl acetate, hexane, methylene chloride, methyl ethyl ketone, and toluene. The evaporation rates of these chemicals were determined both by prediction, using a model developed by I. Kawamura and D. Mackay, and empirically and these rates were used in the Reist model. Chamber experiments were done to measure actual building-up and decay of vapor concentrations for simulated spills and simulated clean-up.

Bakalyar, S.M.

1990-01-01T23:59:59.000Z

245

Temperature-responsive surface-functionalized polyethylene films  

E-Print Network [OSTI]

precursors. PhotograAing on these surfaces (Equation 1) in the presence of various vinyl monomers was found to be very effective, as XPS and ATR-IR data indicated the extent of grafting could be controlled by monomer concentration and the solvent employed... in this case was measured by following the percent quenching of pyrene as these films were suspended in varying concentrations of a quenching agent, such as N-N'-dimethylethanolamine, in solvents such as THF, methylene chloride and ethanol. The value...

Ponder, Bill C.

2012-06-07T23:59:59.000Z

246

Process for the manufacture of 117Sn diethylenetriaminepentaacetic acids  

DOE Patents [OSTI]

Novel methods are provided for the manufacture of .sup.117m Sn(Sn.sup.4+) DTPA. The method allows the use of DTPA, a toxic chelating agent, in an approximately 1:1 ratio to .sup.117m Sn(Sn.sup.4+) via either aqueous conditions, or using various organic solvents, such as methylene chloride. A pharmaceutical composition manufactured by the novel method is also provided, as well as methods for treatment of bone tumors and pain associated with bone cancer using the pharmaceutical composition of the invention.

Srivastava, Suresh C. (Setauket, NY); Li, Zizhong (Upton, NY); Meinken, George (Middle Island, NY)

2003-01-01T23:59:59.000Z

247

Toluene pyrolysis studies and high temperature reactions of propargyl chloride  

SciTech Connect (OSTI)

The main focus of this program is to investigate the thermal decompositions of fuels that play an important role in the pre-particle soot formation process. It has been demonstrated that the condition of maximum soot yield is established when the reaction conditions of temperature and pressure are sufficient to establish a radical pool to support the production of polyaromatic hydrocarbon species and the subsequent formation of soot particles. However, elevated temperatures result in lower soot yields which are attributed to thermolyses of aromatic ring structures and result in the bell-shaped dependence of soot yield on temperature. The authors have selected several acyclic hydrocarbons to evaluate the chemical thermodynamic and kinetic effects attendant to benzene formation. To assess the thermal stability of the aromatic ring, the authors have studied the pyrolyses of benzene, toluene, ethylbenzene, chlorobenzene and pyridine. Time-of-flight mass spectrometry (TOF) is employed to analyze the reaction zone behind reflected shock waves. Reaction time histories of the reactants, products, and intermediates are constructed and mechanisms are formulated to model the experimental data. The TOF work is often performed with use of laser schlieren densitometry (LS) to measure density gradients resulting from the heats of various reactions involved in a particular pyrolytic system. The two techniques, TOF and LS, provide independent and complementary information about ring formation and ring rupture reactions.

Kern, R.D.; Chen, H.; Qin, Z. [Univ. of New Orleans, LA (United States)

1993-12-01T23:59:59.000Z

248

Interfacial tension between aluminum and chloride-fluoride melts  

SciTech Connect (OSTI)

Scrap and recycled aluminum have to be remelted and refined before being made into useful new products. This often involves melting the aluminum under a molten salt cover in order to prevent oxidation and to enhance the coalescence and recovery of the molten metal. A technique was developed for the measurement of the interfacial tension between liquid metals and molten salts at elevated temperatures. The technique is based on the measurement of the capillary depression occurring when a capillary, which is moved vertically down through the molten salt layer, passes through the salt/metal interface. The depression is measured by simultaneous video recording of the immersion height of the alumina capillary and the position of a liquid meniscus in a horizontal tube connected to the alumina capillary. The interfacial tension was measured for (a) aluminum and an equimolar melt of NaCl + KCl with several salt additions at 1,000 K, (b) aluminum and NaCl + NaF at 1,123 K, and (c) aluminum and NaCl + KF at 1,123 K. It was found that the interfacial tension decreases with increasing amount of NaF, increases with the increasing amount of MgCl{sub 2} additions, remains unchanged with AlF{sub 3} additions, and slightly decreases with the addition of MgF{sub 2} and Na{sub 3}AlF{sub 6}.

Silny, A. [Slovak Academy of Sciences, Bratislava (Slovakia). Inst. of Inorganic Chemistry] [Slovak Academy of Sciences, Bratislava (Slovakia). Inst. of Inorganic Chemistry; Utigard, T.A. [Univ. of Toronto, Ontario (Canada). Dept. of Metallurgy and Materials Science] [Univ. of Toronto, Ontario (Canada). Dept. of Metallurgy and Materials Science

1996-11-01T23:59:59.000Z

249

A Novel Low-Cost Sodium-Zinc Chloride Battery  

SciTech Connect (OSTI)

The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

2013-02-28T23:59:59.000Z

250

alkali metal chlorides: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

251

alkali metal chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NMR to explosives detec- tion and fundamental Romalis, Mike 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

252

Catalytic hydrogenation of an aromatic sulfonyl chloride into thiophenol  

E-Print Network [OSTI]

data collected in a continuous process mode show that the catalyst is deactivated during an experiment when the process time equal to two to three times the residence time of the liquid within the reactor. XRD analysis shows that the active sites...

Rouckout, Nicolas Julien

2009-05-15T23:59:59.000Z

253

Redox flow batteries based on supporting solutions containing chloride  

DOE Patents [OSTI]

Redox flow battery systems having a supporting solution that contains Cl.sup.- ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO.sub.4.sup.2- and Cl.sup.- ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V.sup.2+ and V.sup.3+ in a supporting solution and a catholyte having V.sup.4+ and V.sup.5+ in a supporting solution. The supporting solution can contain Cl.sup.- ions or a mixture of SO.sub.4.sup.2- and Cl.sup.- ions.

Li, Liyu; Kim, Soowhan; Yang, Zhenguo; Wang, Wei; Zhang, Jianlu; Chen, Baowei; Nie, Zimin; Xia, Guanguang

2014-01-14T23:59:59.000Z

254

The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides  

E-Print Network [OSTI]

The trifluoromethyl group can dramatically influence the properties of organic molecules, thereby increasing their applicability as pharmaceuticals, agrochemicals, or building blocks for organic materials. Despite the ...

Cho, Eun Jin

255

DOEEA-1157 ENVIRONlMENTAL ASSESSMENT METHYL CHLORIDE VIA OXYHYDROCHLOF...  

Broader source: Energy.gov (indexed) [DOE]

VIA OXYHYDROCHLOFUNATION OF METHANE: A BUILDING BLOCK FOR CHEMICALS AND FUELS FROM NATURAL GAS DOW CORNING CORPORATION CARROLLTON, KENTUCKY SEPTEMBER 1996 U.S. DEPARTMENT OF...

256

RESEARCH ARTICLE Increasing chloride concentrations in Lake Constance  

E-Print Network [OSTI]

contributed 52%, waste water 23%, farming 11%, soil weathering 9%, precipitation and solid waste incineration with population density, the density of roads, intensification of farming, and solid waste incineration

Wehrli, Bernhard

257

Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence  

E-Print Network [OSTI]

in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

Ghosh, Ruby N.

258

ammonium chloride solution: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

deduplication and compression with the cloud to reduce the storage footprint as well as CapEx and OpEx costs Chaudhuri, Surajit 337 On Lovelock vacuum solution HEP - Theory (arXiv)...

259

ammonium chloride surfactant: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

For vanishing hydrophobic forces this complex has the architecture of a molecular bottle-brush cylindrically centered around the stretched PE molecule. Upon increasing the...

260

aluminum chloride vapor: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theses and Dissertations Summary: ??This study investigated the adsorptive capacity and isotherm of HgCl2 onto spherical activated carbons (SAC) via thermogravimetric analysis...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network [OSTI]

for the Coal Slurry Reactor Calculations are shown here for= Total reactor pressure, psi. The calculation is iterative,

Joyce, Peter James

2011-01-01T23:59:59.000Z

262

Method for making a uranium chloride salt product  

DOE Patents [OSTI]

The subject apparatus provides a means to produce UCl.sub.3 in large quantities without incurring corrosion of the containment vessel or associated apparatus. Gaseous Cl is injected into a lower layer of Cd where CdCl.sub.2 is formed. Due to is lower density, the CdCl.sub.2 rises through the Cd layer into a layer of molten LiCl--KCL salt where a rotatable basket containing uranium ingots is suspended. The CdCl.sub.2 reacts with the uranium to form UCl.sub.3 and Cd. Due to density differences, the Cd sinks down to the liquid Cd layer and is reused. The UCl.sub.3 combines with the molten salt. During production the temperature is maintained at about 600.degree. C. while after the uranium has been depleted the salt temperature is lowered, the molten salt is pressure siphoned from the vessel, and the salt product LiCl--KCl-30 mol % UCl.sub.3 is solidified.

Miller, William E. (Naperville, IL); Tomczuk, Zygmunt (Lockport, IL)

2004-10-05T23:59:59.000Z

263

Modeling acid-gas generation from boiling chloride brines  

E-Print Network [OSTI]

Analysis Preliminary calculations assuming pure CaCl 2 solutions were carried out to investigate relationships between salt concentration, HCl gas fugacity (? partial pressure), and condensate

Zhang, Guoxiang

2010-01-01T23:59:59.000Z

264

Water content and morphology of sodium chloride aerosol particles  

E-Print Network [OSTI]

to explain the H2O content. The model in which the NaCl particles contain pockets of aqueous NaCl solution was found to be most consistent with the spectroscopic observations. The relevance of salt particle morphology and water content to atmospheric aerosol...

Weis, David D.; Ewing, George E.

1999-09-20T23:59:59.000Z

265

Accelerated Cellulose Depolymerization Catalyzed by Paired Metal Chlorides  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre the Effects ofAbout ScienceAbout OakMeasurement ofin Ionic

266

Thermophysical Properties of Sodium Nitrate and Sodium Chloride  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformation In closing, an National Carbon Capture Center at theDarkCarbonThermophysical

267

acid cupric chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

In the present study, bonding among formic, acetic and benzoic acids, sulfuric acid, ammonia, acetic, and benzoic acids with free and hydrated sulfuric acid has been...

268

Original article Effects of sodium chloride salinity on root growth  

E-Print Network [OSTI]

either 50 or 250 mM NaCl. Both moderate and high salinity treatment strongly altered root elongation. In contrast, specific respiration of roots was unaffected by the moderate salinity treatment while ecosystems [11].The effects of snow melt have been documented for wetland ecosystems [14] but

Paris-Sud XI, Université de

269

MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION  

E-Print Network [OSTI]

ix Introduction. A. Coal Liquefaction Overview B.L ZnCl 2-catalyzed Coal Liquefaction . . . . . . . . . • ,Results. . . • . ZnC1 2/MeOH Coal liquefaction Process

Joyce, Peter James

2011-01-01T23:59:59.000Z

270

A comparison of the catalytic effect of anhydrous ferric chloride and anhydrous aluminum chloride in Friedel and Crafts reactions  

E-Print Network [OSTI]

ebo ao4ivtlg Xeoreaeoe ek4h. teoeaeeo te cot yoi oeeh of foeeio 44lo?Mo' ee4 Ileoh84 e csete5he A4 4 yot ooe4 e{coehijyo 45 oxooee of 49 cot yes ooet* at htihee ooaoonleettoee of son to ohtoHCo %be cot&41@ eeeeeeeo4+ oee W eo 4eb4 ~ M yeti@ of %he...

Weddell, William MacNelley

1941-01-01T23:59:59.000Z

271

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Fourth quarter 1993 and 1993 summary  

SciTech Connect (OSTI)

During fourth quarter 1993, 10 constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Carbon tetrachloride, chloroform, chloroethane (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone 2B{sub 2} (Water Table) and Aquifer Zone 2B{sub 1}, (Barnwell/McBean) wells and in two Aquifer Unit 2A (Congaree) wells. The groundwater flow direction and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Butler, C.T.

1994-03-01T23:59:59.000Z

272

Mixed Waste Management Facility (MWMF) groundwater monitoring report: Third quarter 1993  

SciTech Connect (OSTI)

During third quarter 1993, eight constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents Chloroethene (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. The elevated constituents were found in Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1} (Barnwell/McBean) wells. No elevated constituents were exhibited in Aquifer Unit IIA (Congaree) wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-12-01T23:59:59.000Z

273

Sanitary Landfill Groundwater Monitoring Report. Fourth Quarter 1997 and 1997 Summary  

SciTech Connect (OSTI)

A maximum of forty-eight wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Chloroethene (vinyl chloride) and trichloroethylene were the most widespread constituents exceeding standards during 1997. Lead (total recoverable), 1,4-dichlorobenzene, mercury, benzene, dichloromethane (methylene chloride), a common laboratory contaminant, tetrachloroethylene, 1,2-dichloroethane, gross alpha, tritium, and 1.2-dichloropropane also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill was to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 139 ft/year during first quarter 1997 and 132 ft/year during fourth quarter.

Chase, J. [Westinghouse Savannah River Company, AIKEN, SC (United States)

1998-02-01T23:59:59.000Z

274

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

275

The nature and fate of natural resins in the geosphere - VIII - NMR and Py-GC-MS characterization of soluble labdanoid polymers isolated from holocene class I resins.  

SciTech Connect (OSTI)

Soluble polylabdanoids isolated by sequential solvent extraction have been characterized by liquid-state {sup 13}C- and {sup 1}H NMR and {sup 13}C-{sup 1}H HMQC (heteronuclear correlation) NMR spectroscopy in addition to solid-state NMR and Py-GC-MS techniques. Two Holocene resins originating from Santander, Colombia and Mombasa, Kenya were analyzed. Soluble polymers were isolated by extraction with a 1:1 (v/v) methylene chloride-methanol mixture following sequential extractions with methylene chloride and methanol. The molecular weight of polymer extracts was shown by GPC analyses to exceed that of non-polymeric occluded terpenoids. Py-GC-MS, solid-state {sup 13}C CP/MAS and {sup 13}C cross-polarization/depolarization NMR spectroscopy results indicated that chemical compositions of soluble polymers isolated from immature resins are highly representative of the structure of corresponding insoluble polymers, i.e. polylabdatrienes. These data provide evidence for cross-linking or cyclization of side-chain olefinic carbons during or shortly after polymerization. Generally, the characterization of soluble resin polymers by liquid-state NMR spectroscopy has proven to be an excellent means for investigating the maturation mechanism of polylabdanoid resinites, and has potential for furthering the application of Class I resinites as geothermal indicators.

Clifford, D. J.; Hatcher, P. G.; Botto, R. E.; Muntean, J. V.; Michaels, B.; Anderson, K. B.; Chemistry; Pennsylvania State Univ.; Amoco Oil Co.

1997-01-01T23:59:59.000Z

276

Effects of bacitracin methylene disalicylate, bacitracin zinc, and virginiamycin in combination with new coccidiostats on the performance of commercial broiler chickens  

E-Print Network [OSTI]

CONVERSION TO 48 DAYS OF AGE IN COMMERCIAL BROILERS TREATMENTS NO. OF BIRDS FEED CONVERSION (FEED/WEIGHT) 2 WK 4 WK 6 WK 48 DAYS MAXIBAN MAXI BAN + BMD 400 400 1. 066 1 ' 518 1. 071 1. 473 1. 933 (1) 1. 950 (2) 1. 842 1. 852y 1. 991 2 031x 1... or in combination with bacitracin Zn when added to the diet affects males and females alike. There were no statis- tically significant differences between the treatments in feed conversion at 2, 4 and 6 weeks, or 48 days of age (Tables 18 and 19). However...

Ofori Bekoe, Kwadwo

1988-01-01T23:59:59.000Z

277

J. Phys. Chem. 1990, 94, 6963-6969 6963 Singlet-Triplet Energy Gaps in Chlorine-Substituted Methylenes and Silylenest  

E-Print Network [OSTI]

induced dynamic nuclear po- larization (CIDNP) techniques, Roth2showed that reactions of singletJ. Phys. Chem. 1990, 94, 6963-6969 6963 Singlet-Triplet Energy Gaps in Chlorine.' There are two low-lying states, singlet and triplet, depending on whether the electronic configuration is u2or

Goddard III, William A.

278

Assimilation and respiration of radioactive ethylene glycol, in the presence of high sodium chloride concentrations, by a sodium chloride requiring bacterium  

E-Print Network [OSTI]

and the contents distilled over into 5 ml of a 2X boric acid solution containing 3 ml of a O. l%%d ethanolic solution of methyl red and 5. 7 ml of a 0. 1X ethanolic 29 solution of brom cresol green. The samples were titrated, with 0. 1N HC1 using a... limits. Sodium requirement Effect of pH on growth Utilization of carbon sources. Respiration studies. Quantitation of ethylene glycol carbon Disappearance of. glucose and ammonia-nitrogen from cultures of Bacterium T-52. Possible pathways...

Gonzalez, Carlos Francisco

1972-01-01T23:59:59.000Z

279

Health assessment for Medley Farms Site, Cherokee County, Gaffney, South Carolina, Region 4. CERCLIS No. SCD980558142. Preliminary report  

SciTech Connect (OSTI)

The Medley Farms site is proposed for inclusion on the National Priorities List. The South Carolina Department of Health and Environmental Control (SCDHEC) had not permitted the use of the property for disposal of hazardous materials. Approximately 5,300 55-gallon drums and 15-gallon containers were discovered during an investigation by SCDHEC staff. After the Environmental Protection Agency's 1983 emergency clean-up activities, on-site groundwater samples were collected in 1984 and 1986. Contaminants found in these samples were as follows: methylene chloride, chloroform, carbon tetrachloride, 1,1-dichloroethane, 1,2-dichloroethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,1-dichloroethylene, trans-1,2-dichloroethylene, and trichloroethylene. From the information reviewed, the site is concluded to be of potential health concern because of the possibility of human exposure to hazardous substances at concentrations which may result in adverse health effects.

Not Available

1989-04-14T23:59:59.000Z

280

Detecting multiple cell-secreted cytokines from the same aptamer-functionalized electrode  

E-Print Network [OSTI]

with anthraquinone (AQ) and methylene blue (MB) redox reporters respectively. Random immobilization of two aptamer

Ferrara, Katherine W.

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Effect of Brush Vegetation on Deep Drainage Using Chloride Mass Balance  

E-Print Network [OSTI]

is comparable to that by herbaceous vegetation (Wilcox, 2005). The canopy of an average-size, mature redberry and ashe juniper can intercept 26% and 37% of the annual precipitation, respectively. Redberry and ashe juniper litter can intercept 40% and 43..., superactive, thermic Pachic Paleustolls. Dominant woody-shrub vegetation cover includes juniper (Juniperus ashei) with other existing vegetation such as little bluestem (Schizachyrium scoparium) and threeawn (Aristida). Site G4 The soil at site G4...

Navarrete Ganchozo, Ronald J.

2011-02-22T23:59:59.000Z

282

STUDIES OF MICROMORPHOLOGY AND CURRENT EFFICIENCY OF ZINC ELECTRODEPOSITED FROM FLOWING CHLORIDE ELECTROLYTES  

E-Print Network [OSTI]

were then encased in The brass core with silver epoxy resin.epoxy resin, heat-cured and machined to the desired circularbolt that was coated with epoxy resin corrosion. The anodes

Mc Vay, L.

2011-01-01T23:59:59.000Z

283

E-Print Network 3.0 - acidic chloride solutions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- Department of Chemistry, Brock University Collection: Chemistry 46 Novel Carbon Monoxide Sensor for PEM Fuel Cell Systems C.T. Holt, A.-M. Azad, S.L. Swartz, W.J. Dawson, and...

284

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

2005) Genome sequence of the PCE-dechlorinating bacteriumlevels and pseudo-steady-state PCE respiration rates inreductive dehalogenases in a PCE-dechlorinating flow column.

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

285

The value of tetrazolium chloride test reagent in the evaluation of seed quality  

E-Print Network [OSTI]

cotton seed germination. Seed which stained a pink to dark red with tetrasolium were considered as germinating seed. In the hulled seed method, the hulled seed were tested in the germinator at 88 F. and counts were made the second day. They found... crops fumigated at 80 F. and stored ten months prior to a second fumigation at 95 P. are 0 presented in Table 5 . The analysis of vaziance of this data is given in Table 6. The differences in methods (stain vs. germination) were signifi- cant...

Metzer, Robert Benjamin

1959-01-01T23:59:59.000Z

286

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride As the Acid  

E-Print Network [OSTI]

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Supporting Information ABSTRACT: Routes to new tungsten alkylidene complexes that contain tert and tungsten, especially aryls that are mono- or disubstituted in the ortho position(s).2 However, it has

Müller, Peter

287

Selected genomic and phenotypic responses of Salmonella serovars to chlorine, chlorine dioxide, and cetylpyridinium chloride  

E-Print Network [OSTI]

but nonculturable (VBNC) state in Salmonella due to CPC was also investigated. The inactivation parameters for each serovar and the chemical were estimated based on the Hom's model, ln (N/N0) = -k C^n T^m and it appeared that while disinfectant contact time...

Kakani, Grihalakshmi

2012-07-11T23:59:59.000Z

288

Agronomic differences in growth and yield between BT and conventional cotton treated with mepiquat chloride  

E-Print Network [OSTI]

in the Department of Soil and Crop Sciences at Texas A&M University. In addition, thanks to BASF Chemical Company for providing the chemicals and finances necessary for completion of this thesis experiment. vn TABLE OF CONTENTS ABSTRACT. Page nl DEDICATION...

Underbrink, Shelley Marie

1999-01-01T23:59:59.000Z

289

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network [OSTI]

complexes between nitrogen dioxide, nitric acid, nitrous1992) Indoor ozone and nitrogen dioxide: A potential pathwaybed of SiO 2 pellets. Nitrogen dioxide is introduced from a

2009-01-01T23:59:59.000Z

290

Late Pleistocene and Holocene groundwater recharge from the chloride mass balance method and chlorine-36 data  

E-Print Network [OSTI]

rates, estimated from 36 Cl data, were lower in late Pleistocene than Holocene at Yucca Mountain, Nevada Pleistocene. Local recharge rates at Yucca Mountain were estimated from the 36 Cl/Cl ratios and Cl� concentrations in perched waters. The estimated recharge for Yucca Mountain is 5 ± 1 mm/yr for Holocene and 15

Polly, David

291

Polyvinyl Chloride/Silica Nanoporous Composite Separator for All-Vanadium Redox Flow Battery Applications  

SciTech Connect (OSTI)

Redox flow batteries (RFBs) are capable of reversible conversion between electricity and chemical energy. Potential RFB applications resolve around mitigating the discrepancy between electricity production and consumption to improve the stability and utilization of the power infrastructure and tackling the intermittency of renewables such as photovoltaics or wind turbines to enable their reliable integration [1, 2]. Because the energy is stored in externally contained liquid electrolytes and the energy conversion reactions take place at the electrodes, RFBs hold a unique capability to separate energy and power and thus possess considerable design flexibility to meet either energy management driven or power rating oriented grid applications, which is considered to be a unparalleled advantage over conventional solid-state secondary batteries [3]. Other advantages of RFBs include fast response to load changes, high round-trip efficiency, long calender and cycle lives, safe operations, tolerance to deep discharge, etc. [4]. Among various flow battery chemistries, all-vanadium redox flow battery (VRB) was invented by Maria Skyllas-Kazacos at the University of New South Wales in the 1980s [5, 6] and have attracted substantial attention in both research and industrial communities today [7, 8]. A well-recognized advantage that makes VRB stands out among other redox chemistries is the reduced crossover contamination ascribed to employing four different oxidation states of the same vanadium element as the two redox couples. Recently, great progress has led to remarkably improved energy density of VRB by using sulfuric-chloric mixed acid supporting electrolytes that were stable at 2.5M vanadium and had wider operational temperature window of -5~50oC [9], compared with the traditional sulfuric acid VRB system [10].

Wei, Xiaoliang; Nie, Zimin; Luo, Qingtao; Li, Bin; Sprenkle, Vincent L.; Wang, Wei

2013-04-22T23:59:59.000Z

292

Bleaching of F-centers in sodium chloride at room temperature by electron tunneling  

E-Print Network [OSTI]

, ronhot, o- met, er f LL', ali 1161ido crvs~&1? shat have been exposed tc io1Q. cinT radia bioni snch as z "aPJi MkiLbit absorption bands in the visible and near ultraviolet, which sm attributed to "color centers" crested in the orris...'-sls by the radiation. The caLm' centew consisb of various combi- nations of pvsitiv'c and, no@at, ive ion-vacancies with electrons and electron holes i hose with which She present, work is concei'ned are shown in H. g. 1. below. The F-center is a negative ion...

Carroll, Herbert Burnett

1967-01-01T23:59:59.000Z

293

E-Print Network 3.0 - alkaline earth chlorides Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: of the alkaline earth cations, magnesium, calcium, and barium on the dissolution kinetics of quartz PATRICIAM... and alkaline earth cations in near-neutralpH solutions. We...

294

Rate-dependent deformation behavior of poss-filled and plasticized poly(vinyl chloride)  

E-Print Network [OSTI]

Polymers are known to exhibit strong time-dependent mechanical behavior. In different temperatures or frequency regimes, the rate sensitivities of polymers change as various primary and secondary molecular mobility mechanisms ...

Soong, Sharon Yu-Wen

2007-01-01T23:59:59.000Z

295

The impact of improved materials in poly(vinyl chloride)-based endotracheal tubes  

E-Print Network [OSTI]

Endotracheal tubes (ETs) are used to aid artificial ventilation in millions of medical patients every year and are known to invoke the proliferative phase in the cell linings. The technical objective of this work was to ...

Domike, Kristin Rebecca, 1981-

2004-01-01T23:59:59.000Z

296

The rate of hydrolysis of benzoyl chloride as a function of water concentration in acetone  

E-Print Network [OSTI]

?XEu K?B ?XWH? gIHXBTHB WHWBWTL gIHgEHBRTBWIH Ij XIuW?Y T?WuE ?TGE gIH? XBTHB hWELuX Ij TL?hL T?WuEV iPWX KEPTGWIR 0TX WHBERmRE? BEu TX mRIIj Ij TH d:L YEgPTHWXY 0WBP TH WIHW?TBWIH XBEm RTBE gIHBRILLWH?? TX jILLI0Xn b CL XLI0 ? Aj BPE XILE m...?RmIXE Ij BPWX WHGEXBW?TBWIH PTu KEEH BPE uEBERYWHTBWIH Ij RETgBWIH YEgPTHWXY? T XWYWLTR BEgP? HW??E gI?Lu PTGE KEEH ?XEu TX XPI0H ELXE0PERE ?et?V oI0? EGER? BPE gPTLLEH?E Ij BPE WHXBR?YEHBTBWIH HEgEXXTRh jIR BPE YETX?REYEHB Ij E?BREYELh RTmWu RTBEX 0WBP...

Kelly, Minton Jones

2013-10-04T23:59:59.000Z

297

E-Print Network 3.0 - aluminium chloride beryllium Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

49 Chemicals Requiring Designated Areas The OSHA Laboratory Standard 29 CFR 1910.1450 mandates that an employer's Summary: -52-9 Beryl Ore 7440-41-7 Beryllium...

298

E-Print Network 3.0 - anhydrous uranyl chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were then warmed to -70C and rinsed three times with acetone... of fixatives: 10% acrolein, 0.2% osmium, and then 10% glutaraldehyde. Staining was with 0.5% uranyl acetate......

299

a-dependent cftr chloride: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: recently demonstrated that the oncogenic, constitutively kinase activated NPM-ALK protein was antiapoptotic identified as part of the NPM-ALK oncogenic fusion...

300

Cationic quaternization of cellulose with methacryloyloxy ethyl trimethyl ammonium chloride via ATRP method  

SciTech Connect (OSTI)

The synthesis of a cationic cellulose copolymer from cellulose macro-initiator (MCC-BiB) and quaternary compound monomer (METMA) via atom transfer radical polymerization (ATRP) was studied. By using dimethylformamide (DMF), the optimum condition for successful synthesis was at the mole ratio of MCC-BIB:Catalyst:METMA = 1:1:26. The highest copolymer recovery was 93.2 % for 6 h and at 40°C. The copolymer was insoluble in weak polar solvents such as THF and DMF but soluble in methanol and water. The chemistry of cellulose copolymer was confirmed by the FTIR and TGA in which the METMA monomer was used as a reference. The absence of CC bond in the CiB-g-METMA spectrum indicated that graft copolymerization occurred.

Supeno [Cenderawasih University, Jayapura, Papua, Indonesia and School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Daik, Rusli, E-mail: rusli@ukm.edu.my [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); El-Sheikh, Said M. [Nano-Structured Materials Division, Advanced Materials Department, Central Metallurgical Research and Development Institute, Cairo (Egypt)

2014-09-03T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Dietary ammonium chloride and the urinary excretion of chlortetracycline and oxytetracycline  

E-Print Network [OSTI]

concentrated upon the potentiation oi the antibiotics. An antib1ot1c potentiator is any agent or substance which will 1ncrease or enhance ant1b1otic absorp- tion or decrease excret1on, thus maintaining a high blood level of the drug. Finland (1958) states.... Dissertation, Texas AhN University. Finland, N. (1958). Antibiotic blood level enhance- ment. Anti. Ned. and There . 5, 359. Hayes, J. E. , Jr. , and H. G. DuBuy. (1961). A simple method for quantitative estimation of tetracycline antibiotics. Anal. Biochem...

Roberts, Ronald Curtis

1967-01-01T23:59:59.000Z

302

E-Print Network 3.0 - ammonium chloride adbac Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

113. P.H. GLEICK (1996). Basic water... and especially of quaternary ammoniums in rainwater stocked, which can be a source of exposition. For developing... molecules were...

303

Chloride improves fruit yield and quality of strawberry (Fragaria × ananassa Duch.)  

E-Print Network [OSTI]

concentration in strawberry fruits. Materials and Methods Inwas carried out with ten replicates. After fruit harvest,number of fruits per plant, single fruit weight, fruit

Bellof, Svenja; Schubert, Sven

2009-01-01T23:59:59.000Z

304

A Novel, Green Technology for the Production of Aromatic Thiol from Aromatic Sulfonyl Chloride  

E-Print Network [OSTI]

Functional Theory (DFT), a quantum mechanical method, was used to investigate the new aromatic thiol production technology at the molecular level in aspects including reaction species adsorption and transition state determination. Plant design methods...

Atkinson, Bradley R.

2010-01-16T23:59:59.000Z

305

E-Print Network 3.0 - analyzing polyvinyl chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Incineration of Refuse with 2 Percent and 4 Percent Additions of Four Plastics: Polyethylene, Polyurethane, Summary: : Polyethylene, Polyurethane, Polystyrene and Polyvinyl...

306

aerobic vinyl chloride-assimilating: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

organic sulfides,6 and perfluorinated polyesters,7,8 have been used to create release coatings Chaudhury, Manoj K. 425 1283J. Blumel, F. H. Kohler Metallated...

307

E-Print Network 3.0 - aqueous chloride environment Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

|J. Phys. Chem. Lett. 2011, 2, 25152520 Summary: )2SO4, and Na2CO3 Relative to CaCl2 and NaCl at the AirAqueous Interface Revealed by Heterodyne... Information Water...

308

E-Print Network 3.0 - aqueous potassium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

|J. Phys. Chem. Lett. 2011, 2, 25152520 Summary: )2SO4, and Na2CO3 Relative to CaCl2 and NaCl at the AirAqueous Interface Revealed by Heterodyne... Information Water...

309

Corrosion initiation and propagation on corrosion resistant alloys embedded in concrete by accelerated chloride transport.  

E-Print Network [OSTI]

??Two duplex stainless steels rebars: UNS32304SS and UNS32101SS, were selected to investigate the corrosion initiation and propagation in reinforced concrete specimens. The investigation is divided… (more)

Gutierrez Tellez, Francisco.

2013-01-01T23:59:59.000Z

310

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

variations in coal from rank to rank, mine to mine, seam tocoal was supplied by the Wyodak t. Resources Development Corporation from the Roland top seam

Holten, R.R.

2010-01-01T23:59:59.000Z

311

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

Alkylation of Pittsburgh Seam Coal, Fuel, Vol. 57, 697 Olah,The Wyodak coal was obtained from the Roland top seam of the

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

312

An In-depth Investigation of an Aluminum Chloride Retarded Mud Acid System on Sandstone Reservoirs  

E-Print Network [OSTI]

Sandstone acidizing using mud acid is a quick and complex process where dissolution and precipitation occur simultaneously. Retarded mud acids are less reactive with the rock reducing the reaction rate hence increased penetration into the formation...

Aneto, Nnenna

2012-07-16T23:59:59.000Z

313

Syntheses of Tungsten tert-Butylimido and Adamantylimido Alkylidene Complexes Employing Pyridinium Chloride as the Acid  

E-Print Network [OSTI]

Routes to new tungsten alkylidene complexes that contain tert-butylimido or adamantylimido ligands have been devised that begin with a reaction between WCl[subscript 6] and 4 equivalents of HNR(TMS) to give [W(NR)[subscript ...

Jeong, Hyangsoo

314

VISCOSITY OF AQUEOUS SODIUM CHLORIDE SOLUTIONS FROM 0 - 150oC  

E-Print Network [OSTI]

and evaluate data on geothermal energy for electrical andeconomic aspects of geothermal energy. While the larger workDivision of Geothermal Energy; Office of Environmental

Ozbek, H.

2010-01-01T23:59:59.000Z

315

E-Print Network 3.0 - ammonium chloride monolithic Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mixtures over a range of compositions yielded monolithic green... -gel method; Aerogels 1. Introduction Supercritical drying of monolithic V O gels2 5 formed from the...

316

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

Conceived and designed the experiments: PJM SFB FEL AMS.Performed the experiments: PJM SFB KMR.Analyzed the data: PJM SFB JAM JG KMR RW EG AL SH FEL AMS.

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

317

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

for Liquefaction and Gasification of Western Coals", in5272 (1976). COal Processing - Gasification, Liguefaction,or gaseous fuels, coal gasification has advanced furthest

Holten, R.R.

2010-01-01T23:59:59.000Z

318

Ligand-Gated Chloride Channels Are Receptors for Biogenic Amines in C. elegans  

E-Print Network [OSTI]

Biogenic amines such as serotonin and dopamine are intercellular signaling molecules that function widely as neurotransmitters and neuromodulators. We have identified in the nematode Caenorhabditis elegans three ligand-gated ...

Ringstad, Niels

319

An electron spin resonance investigation of irradiated potassium chloride crystals doped with sodium nitroprusside  

E-Print Network [OSTI]

's, attention was turned. to a large extent to the topic of organic n-radicals. Electron spin resonance was first observed in free rad1cals in 1907 by Kozyrev and. Salikhov ) in the case of pentaphenyclopentadienyl. In solid penta... radical possesses mainly spin magnetism in accordance with measurements of its static magnetic susceptibility. In l949 a systematic study of electron spin resonance spectra in free radicals was initiated, i. e. molecules in which at least one electron...

Mayers, Richard Ralph

2012-06-07T23:59:59.000Z

320

Time-resolved energy transfer from single chloride-terminated nanocrystals to graphene  

E-Print Network [OSTI]

and Engineering, Solid-State Science and Engineering, Columbia University, New York, New York 10027, USA 2 Department of Mechanical Engineering, Columbia University, New York, New York 10027, USA 3 Department of Chemistry, Columbia University, New York, New York 10027, USA 4 Brookhaven National Laboratory, Upton, New

Hone, James

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Comparative Neurotoxicity of Methylmercury and Mercuric Chloride In Vivo and In Vitro  

E-Print Network [OSTI]

) were determined using fluorescence microscopy or microplate reader assays. Young adult C57Bl/6 mice were exposed to a total dose of 0, 1.0, or 5.0 mg/kg body weight MeHg divided over postnatal days (P)35 to 39. Pregnant female mice were exposed to a...

Thuett, Kerry A.

2010-10-12T23:59:59.000Z

322

Chlorine activation indoors and outdoors via surface-mediated reactions of nitrogen oxides with hydrogen chloride.  

E-Print Network [OSTI]

garbage burning (7), incineration of municipal and medicalindustrial settings, incineration fa- cilities (5), biomass

2009-01-01T23:59:59.000Z

323

E-Print Network 3.0 - aerated sodium chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CONTROL SYSTEM FOR Summary: from this project: Aeration of large-scale municipal wastewater treatment plants: state of the art... , Diego Rosso, Lory E. Larson, Michael K....

324

Molecular Dynamics Simulation of the Transport Properties of Molten Transuranic Chloride Salts  

E-Print Network [OSTI]

are critical to modeling both the neutronics and heat transfer of an ADSMS system. There is a lack of experimental data on the density, heat capacity, electrical and thermal conductivities, and viscosity of TRUCl3 salt systems. Molecular dynamics simulations...

Baty, Austin Alan

2013-02-06T23:59:59.000Z

325

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network [OSTI]

Geochemistry, Springer Verlag, E2 EPRI ER-746-SR, Biofuels:and C.Z-1. Sliepcevivh, EPRI Rept. AF-974 TPS 77-716, (Jan.Cata- lytica Assocs. for EPRI (Oct. 1975). B7 D.M. Bodily,

Onu, Christopher O.

2013-01-01T23:59:59.000Z

326

E-Print Network 3.0 - acyl chloride-modified amorphous Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Science Collection: Computer Technologies and Information Sciences 2 Biosynthesis and secretion of plant cuticular wax L. Kunst, A.L. Samuels* Summary: the aerial portions of...

327

Thermodynamic analysis and growth of ZrO2 by chloride chemical vapor deposition  

E-Print Network [OSTI]

reaction [9­12], and simple chamber designs (e.g., vertical, cold-wall, axisymmetric chamber) to deposit flow injector can be used. A stagnation plane flow injector (for vertical, cold-wall CVD chambers homogeneous nucleation and/ or reactor wall deposition. For example, Holstein [17] de- monstrated that at high

Anderson, Timothy J.

328

E-Print Network 3.0 - astatine chlorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Medicine ; Environmental Sciences and Ecology 27 Zevenhoven & Kilpinen Halogens, dioxinsfurans 17.6.2001 7-1 Chapter 7 Halogens, Summary: .1 Introduction The halogens are...

329

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

dehalogenation of chlorinated dioxins by an anaerobic14], phenols [15], dibenzo-p-dioxins [16], dibenzofurans,

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

330

The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.  

SciTech Connect (OSTI)

Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

Peter Zalupski; Rocklan McDowell; Guy Dutech

2014-10-01T23:59:59.000Z

331

Loading effects of sodium chloride solutions on the high frequency titrimeter  

E-Print Network [OSTI]

'1c is r oh i S ihV -. S v. ' . -, . vi O ~ al I aolvt ticna {lead ih thitv ihwhati eats {!'h teal e made u!! f'rhN thea bv tbah hreual iut KII C f the eoluti{i!1e indetVShdaantl Vv bajca!! aa th? I agl{ ' t'oltc ' le vt orts ' I v . ' ' I fl rc...

Miller, Benjamin Peter

1952-01-01T23:59:59.000Z

332

Chloride improves fruit yield and quality of strawberry (Fragaria × ananassa Duch.)  

E-Print Network [OSTI]

1988; 88: 194-199 Martínez Barroso MC, Alvarez CE, Toxicityof 2 dS m -1 (Martínez Barroso and Alvarez 1997). Hypotheses

Bellof, Svenja; Schubert, Sven

2009-01-01T23:59:59.000Z

333

Purificaiton of Lanthanides for Large Neutrino Detectors: Thorium Removal from Gadolinium Chloride  

SciTech Connect (OSTI)

Metal-loaded liquid scintillators are the detectors of choice for various neutrino experiments. Procedures have been developed to transfer metals into organic liquids by solvent extraction or direct dissolution of a metallic compound. Traces of natural radioactivity introduced into the scintillator with the metal may produce undesirable backgrounds. Measurements using a {sup 229}Th tracer indicate that the inclusion of a pH-controlled partial hydrolysis and filtration prior to the preparation of a gadolinium-loading compound can reduce thorium by a factor of {approx}100. This 'self-scavenging' procedure has the advantage that it uses only reagents encountered in the production process. Addition of non-elemental scavengers such as iron, or the use of solvent extraction or ion exchange procedures can be avoided. It also improves the optical transmission in the blue region by removing traces of iron. This purification method has potential applications to the large-scale production of other metal-loaded liquid scintillators and for the removal of traces of thorium in the industrial production of lanthanides.

Yeh, M.; Cumming, J.B.; Hans, S.; Hahn, R.L.

2010-06-01T23:59:59.000Z

334

Ultraviolet-B radiation enhancement in dielectric barrier discharge based xenon chloride exciplex source by air  

SciTech Connect (OSTI)

A single barrier dielectric barrier discharge tube of quartz with multi-strip Titanium-Gold (Ti-Au) coatings have been developed and utilized for ultraviolet-B (UV-B) radiation production peaking at wavelength 308?nm. The observed radiation at this wavelength has been examined for the mixtures of the Xenon together with chlorine and air admixtures. The gas mixture composition, chlorine gas content, total gas pressure, and air pressure dependency of the UV intensity, has been analyzed. It is found that the larger concentration of Cl{sub 2} deteriorates the performance of the developed source and around 2% Cl{sub 2} in this source produced optimum results. Furthermore, an addition of air in the xenon and chlorine working gas environment leads to achieve same intensity of UV-B light but at lower working gas pressure where significant amount of gas is air.

Gulati, P., E-mail: pgulati1512@gmail.com [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India); Prakash, R.; Pal, U. N.; Kumar, M. [CSIR-Central Electronics Engineering Research Institute (CSIR-CEERI), Pilani, Rajasthan-333031 (India); Vyas, V. [Department of Physics, Banasthali University, P.O. Banasthali Vidyapith, Rajasthan 304022 (India)

2014-07-07T23:59:59.000Z

335

E-Print Network 3.0 - acidic chloride media Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CI Acid gases and mists were trapped in 1.5 N aq. NaOH contained in a Greenburg-Smith impinger... following the probe, Fig. 2, was combined with the alkaline collection...

336

Optical spectra and luminescence of REE and TRU for analytical purposes in chloride melts  

SciTech Connect (OSTI)

This paper analyzes absorption spectra of molten salts containing some of the actinide and rare-earth elements (REE) and evaluated the prospects of using the individual transitions to control the composition of the spent molten salts using adsorption and luminescence spectroscopy from the standpoint of the theory of Judd-Ofelt. It is shown that the fluorescent method can be recommended only for the monitoring of the degree of purification of the molten salt from the REE in the final stage, when only trace amounts of fission products are in the molten salt. In this case, the content of REE in the molten process is much smaller than that of the used model samples and that eliminates the problem of a significant decrease in the population levels of fluorescent Eu{sup 3+} by quenching impurities. In addition, the presence of salt in the matrix of americium and curium can cause self-luminescence of Eu{sup 3+} due to alpha disintegration energy of transuranics, which also complicates the quantitative measurement of luminescence for the determination of REE.

Aloy, A.S.; Gorshkov, N.G.; Nekhoroshkov, S.N. [FSUE RPA - V.G. Khlopin Radium Institute - KRI, 2 Murinsky Ave., 28, St. Petersburg, 194021(Russian Federation); Osipenko, A.G.; Mayorshin, A.A. [Federal State Unitary Enterprise - State Scientific Center of RF Research Institute of Atomic Reactors, Dimitrovgrad-10, Ulyanovsk region 43351 (Russian Federation)

2013-07-01T23:59:59.000Z

337

The Role of the Ocean in the Atmospheric Budgets of Methyl Bromide, Methyl Chloride and Methane  

E-Print Network [OSTI]

, which was 700 (490 to 920) Gg yr^-1 and -370 (-440 to -280) Gg yr^-1, respectively. The ocean accounts for 10 - 19 % in the global CH3Cl emission and 6 - 9 % in its global sinks. Methane (CH4) is a potent greenhouse gas, which has a warming potential...

Hu, Lei

2012-10-19T23:59:59.000Z

338

Palladium chloride to palladium metal two-dimensional nucleation and growth phenomena  

SciTech Connect (OSTI)

The reduction of a monolayer of surface-bound Pd(II) to Pd(0) on a palladium substrate reveals two-dimensional nucleation and growth phenomena. Using well-known 2D nucleation-growth theories, this reduction is shown to proceed by an instantaneous nucleation and growth mechanism. However, when a submonolayer of Pd(II) is present, this mechanism fails to account for the experimentally observed high cathodic currents seen at zero time. A model incorporating preexisting Pd(0) cylindrical sites on the partially oxidized Pd(0) surface has been successfully applied to account for the discrepancy between the experimental results and current 2D theories. Using this modified 2D model, values for the mathematical product of cylindrical growth rate and the square root of the nucleation site densities have been determined, and the overpotential dependence of the growth rate has been confirmed and quantified. These 2D nucleation-growth phenomena have practical consequences on the performance of the Pd(II)/Pd(0) system as a faradaic supercapacitor, and probably on the performance of other 2D faradaic supercapacitor systems. In addition, because many electrodes undergo monolayer surface oxidation-reduction reactions in other solvent systems, especially aqueous electrolytes, these 2D nucleation-growth phenomena may play a role in these important surface-modifying redox systems as well.

Long, H.C. de; Carlin, R.T. [Air Force Academy, CO (United States). Frank J. Seiler Research Lab.

1995-08-01T23:59:59.000Z

339

Development of Mercury and Hydrogen Chloride Emission Monitors for Coal Gasifiers  

SciTech Connect (OSTI)

The gas conditioning issues involved with coal gasification streams are very complex and do not have simple solutions. This is particularly true in view of the fact that the gas conditioning system must deal with tars, high moisture contents, and problems with NH{sub 3} without affecting low ppb levels of Hg, low levels (low ppm or less) of HCl, or the successful operation of conditioner components and analytical systems. Those issues are far from trivial. Trying to develop a non-chemical system for gas conditioning was very ambitious in view of the difficult sampling environment and unique problems associated with coal gasification streams. Although a great deal was learned regarding calibration, sample transport, instrumentation options, gas stream conditioning, and CEM design options, some challenging issues still remain. Sample transport is one area that is often not adequately considered. Because of the gas stream composition and elevated temperatures involved, special attention will need to be given to the choice of materials for the sample line and other plumbing components. When using gas stream oxidation, there will be sample transport regions under oxidizing as well as reducing conditions, and each of those regions will require different materials of construction for sample transport. The catalytic oxidation approach worked well for removal of tars and NH{sub 3} on a short term basis, but durability issues related to using the catalyst tube during extended testing periods still require study.

G. Norton; D. Eckels; C. Chriswell

2001-02-26T23:59:59.000Z

340

E-Print Network 3.0 - aqueous ammonium chloride Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids, chlorates, nitrites, sulfur, finely... hypochlorite, all oxidizing agents Carbon tetrachloride Sodium Chlorates Ammonium salts, acids, powdered metals... Ammonium...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

E-Print Network 3.0 - alkali chloride ternary Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

has been detected in alkali fluorides... that luminescence from alkali halides excited by ionizing radiation at low temperatures occurs through Source: Ecole Polytechnique, Centre...

342

E-Print Network 3.0 - aqueous metal chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Economics Collection: Materials Science ; Chemistry 2 Changes in Solvation of Metal Ions with Temperature: Atomic-level Interactions between Solvent and Solute Summary:...

343

Chloride Analysis of the Soils Overlaying the Carrizo-Wilcox Aquifer  

E-Print Network [OSTI]

to thank Dr. West for his time in making this research project possible, and nudging me in the right direction. I would also like to thank Ryan Mushinski and Brandon Cawthon for their help in the field, as well as in the lab. 3 CHAPTER...

Wolf, Emery

2013-09-28T23:59:59.000Z

344

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

to produce hydrogen for hydrotreating the liquid products orbed hydrocracking, hydrotreating, and reforming as conducted

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

345

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network [OSTI]

Toluene hexane R (gm ret. solv. / gm coal org. ) (gm) Corr.79 CaC12, 158 · 0 Ot-S c- N/C Solv. l_ncor Hex Tol Pyr CorrToluene Pyrid1ne (gm ret. solv. / hexane gm coal org. )

Onu, Christopher O.

2013-01-01T23:59:59.000Z

346

The effect of mechanical strain on the radiation-coloration of potassium chloride  

E-Print Network [OSTI]

XOQRAPHY ~ ~ ~ ~ t ~ ~ ~ ~ t t ~ ~ ~ ~ ~ ~ ~ ~ ~ 36 ldst of Drawings and Graphs Figure 1. The P-bands for several elhali halides . . . . . . . . . . . 4 Figurc 2. Absorption bends of KC1 caused by x-radiation, . . . . 4 Figure g. Units believed responsible for causing various absorption bands... Pohl and his co-workers began a series of experiments concerned with the nature of color centers and their production. They discovered that an alkali halide material exposed to any ionizing radiation (gamma rays, x-rays, etc. , as well as cathode...

Everett, James Eugene

1964-01-01T23:59:59.000Z

347

E-Print Network 3.0 - acids restore chloride Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Channel Restoration on Water Velocity, Transient Storage, and Nutrient Uptake... of stream restoration, but little is known of the interplay between hydrogeomorphic features...

348

E-Print Network 3.0 - ammonium chloride annual Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Chemistry 4 Cement-based biocide coatings for controlling algal growth in water distribution canals Summary: containing class F fly ash, silica fume, Zn oxide, copper slag,...

349

Relationships between potassium, chloride, and disease incidence in St. Augustinegrass and bermudagrass  

E-Print Network [OSTI]

on a Tifgreen bermudagrass green showed a strong correlation (r² = 0.9700) of reduction of dollar spot. K applied as K?SO? and Cl applied as CaCl? had little effect. Glasshouse results showed increasing K applied as K?SO? from 0 to 97.6 kg ha?¹ and Cl...

Rider, Larry Ray

2012-06-07T23:59:59.000Z

350

ZINC CHLORIDE CATALYSIS IN COAL AND BIOMASS LIQUEFACTION AT PREPYROLYSIS TEMPERATURES  

E-Print Network [OSTI]

Nature and Origin of Asphaltenes in Processed Coal, Mobilc 40 en j ~Asphaltenes ~ ~-------------------A----Melt-treated Coal Oils Asphaltenes Preasphaltenes o.ss 275°C

Onu, Christopher O.

2013-01-01T23:59:59.000Z

351

HYDROGENOLYSIS OF A SUB-BITUMINOUS COAL WITH MOLTEN ZINC CHLORIDE SOLUTIONS  

E-Print Network [OSTI]

molecular-weight ranges of asphaltenes and preasphaltenes.consecutive reactions: coal asphaltenes oil Since the firstfirst being con- verted to asphaltenes. Recently, Sternberg,

Holten, R.R.

2010-01-01T23:59:59.000Z

352

CATALYTIC LIQUEFACTION BY ZINC CHLORIDE MELTS AT PRE-PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

solubles ("oils" and "asphaltenes"). Characteristically, the50 and 80°C, and the asphaltenes between 120 and 200°C. A i~in the conversion of asphaltenes to oils, and raises the

Vermeulen, T.

2012-01-01T23:59:59.000Z

353

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

of Coal- derived Asphaltene, Fuel, Vol. 57, 676 (1978) Mayo,Castex, H. , Analysis of Asphaltenes by Carbon and Protonalso increased the asphaltene and preasphaltene content of

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

354

Molecular Dynamics Study of the Electrical Double Layer at Silver Chloride  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource ProgramModification and Application ofof a CoflowandElectrolyte

355

Sources Of Chloride In Hydrothermal Fluids From The Valles Caldera, New  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty Ltd Jump to:InformationSolergyAddison,Souderton,Geothermal Corporation

356

Beam Damage of Poly(Vinyl Chloride) [PVC] Film as Observed by X-ray  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi, P. Study

357

Beam damage of poly(vinyl chloride) [PVC] as observed by x-ray  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6 M. Babzien, I. Ben-Zvi, P. StudyBeam Historyby

358

Electron Beam Damage in Poly(Vinyl Chloride) and Poly(Acrylonitrile) as  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing Zirconia Nanoparticles as Selective Sorbents . |of ZnOdensityVerticalObserved by

359

Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy InformationLake South RangeChittenden, Vermont: Energy Resources

360

Copper(I) Chloride Carbonyl Polymers Austin B. Wiles and Robert D. Pike*  

E-Print Network [OSTI]

of Chemistry, College of William and Mary, P.O. Box 8795, Williamsburg, Virginia 23187-8795 ReceiVed February.; Gaudinski, C. M.; Miller, S. M.; Anderson, O. P.; Strauss, S. H. Organometallics 1999, 18, 3769. (c) Polyakov, A. G.; Nolan, B. G.; Fauber, B. P.; Miller, S. M.; Anderson, O. P.; Strauss, S. H. Inorg. Chem

Pike, Robert D.

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

E-Print Network 3.0 - aluminum chloride solution Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Aluminum Plants Background... . "DSIs" is often used interchangeably with aluminum smelters because aluminum smelters account... for the vast bulk of this categories'...

362

COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM  

E-Print Network [OSTI]

iv List of Tables . , I. INTRODUCTION e o Coal Chemistry B.Coal Liquefaction c.Coal Liquefaction a D. II. o Experiment Equipment Summary of

Gandhi, Shamim Ahmed

2013-01-01T23:59:59.000Z

363

Sanitary Landfill Groundwater Monitoring Report, Fourth Quarter 1999 and 1999 Summary  

SciTech Connect (OSTI)

A maximum of thirty eight-wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill Area at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Water Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Iron (Total Recoverable), Chloroethene (Vinyl Chloride) and 1,1-Dichloroethane were the most widespread constituents exceeding the Final Primary Drinking Water Standards during 1999. Trichloroethylene, 1,1-Dichloroethylene, 1,2-Dichloroethane, 1,4-Dichlorobenzene, Aluminum (Total Recoverable), Benzene, cis-1,2-Dichloroethylene, Dichlorodifluoromethane, Dichloromethane (Methylene Chloride), Gross Alpha, Mercury (Total Recoverable), Nonvolatile Beta, Tetrachloroethylene, Total Organic Halogens, Trichlorofluoromethane, Tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill is to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 144.175 ft/year during first quarter 1999 and 145.27 ft/year during fourth quarter 1999.

Chase, J.

2000-03-13T23:59:59.000Z

364

Sanitary Landfill Groundwater Monitoring Report - Third and Fourth Quarters 2000 and 2000 Summary  

SciTech Connect (OSTI)

A maximum of forty wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill Area at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Waste Permit DWP-087A and as part of the Sanitary Landfill Groundwater Quality Assessment Plan. Chloroethene (vinyl chloride) and trichloroethylene were the most widespread constituent exceeding the Final Primary Drinking Water Standards during the calendar year 2000. 1,4-Dichlorobenzene, benzene, dichloromethane (methylene chloride), gross alpha, lead (total recoverable) mercury (total recoverable), thallium (total recoverable), and tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill is to the southeast (universal transverse Mercator coordinates). The flow rate at this unit was approximately 122.64 ft/year during first quarter 2000 and 132.28 ft/year during fourth quarter 2000.

Chase, J.A.

2001-03-07T23:59:59.000Z

365

The Solvent Mediated Thermodynamics of Cellulose Deconstruction  

E-Print Network [OSTI]

5 Preferential Interactions between Lithium Chloride and5 – Preferential Interactions between Lithium Chloride and

Gross, Adam S

2012-01-01T23:59:59.000Z

366

6930 Journal of the American Chemical Society 1 100:22 / October 25, 1978 Low-Lying Electronic States of Unsaturated Carbenes.  

E-Print Network [OSTI]

States of Unsaturated Carbenes. Comparison with Methylene John W. Kenney, II1,la Jack Sirnons,*la George

Simons, Jack

367

Conditions for defect-free solidification of aqueous ammonium chloride in a quasi two-dimensional directional solidification facility  

E-Print Network [OSTI]

density coefficient, the thermal diffusivity and the kinematic viscosity of the melt. In particular, Wilberforce Road, Cambridge CB3 0WA, UK a r t i c l e i n f o Article history: Received 8 February 2008

Huppert, Herbert

368

Actinide Corroles: Synthesis and Characterization of Thorium(IV) and Uranium(IV) bis(-chloride) Dimers  

SciTech Connect (OSTI)

The first synthesis and structural characterization of actinide corroles is presented. Thorium(IV) and uranium(IV) macrocycles of Mes2(p-OMePh)corrole were synthesised and characterized by single-crystal X-ray diffraction, UV-Visible spectroscopy, variable-temperature 1H NMR, ESI mass spectrometry and cyclic voltammetry.

Ward, Ashleigh L.; Buckley, Heather L.; Gryko, Daniel T.; Lukens, Wayne W.; Arnold, John

2013-12-01T23:59:59.000Z

369

Quantitative analysis of heavy metals emission during the combustion and baling of polyvinyl chloride insulated copper wire  

E-Print Network [OSTI]

was conducted and compared to the airborne dust samples collected during the baling process. From these results, occupational exposures to heavy metals during the reclamation of PVC insulated copper wire were assessed. Bulk ash and dust samples were ?aken...

Pickard, David Paul

1996-01-01T23:59:59.000Z

370

A study of the condensation of propene and isobutene with benzene in the presence of anhydrous ferric chloride  

E-Print Network [OSTI]

. Distillsdioa of Csadeasaiioa Products osiag Porrio Chlosido aa4 JGaajaaa Chlox'ido ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ IC II. Kssillatioa of Polyaorkxaaioa Pzodue1s asiad Povris Chio&do sad Aloaiaaa Chlos ido ~ e ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ e l... (lygs) ~ due te the higher parity ef the slhoao whish was eeadeaood with tho areastio hfdrsearboa. lsobatsae pr?yare4 bf the dehydratiea ef tertiarf batrl sloohel is reported te have a parity greater thea 99 yer coat Qsiag oqaiaelsr ssswats...

Carpenter, Louis Linden

1938-01-01T23:59:59.000Z

371

A comparative study of extraction methods for analysis of chloride in plant tissue by means of the Cotlove chloridometer  

E-Print Network [OSTI]

of dried, pulverized mesh tissue. The sample is then stirr ed intermittently for at least five minutes at room temperature (37). It is recommended that the extract be analyzed by potentiometric titration using a silver billet electrode. Hanna (26... analysis indicates four methods which are most commonly used. These include Mohr and Volhard's methods of volumetric analysis (1, 8, 32), potentiometric titration using a silver or platinum electrode (6, 37), potentiometric titration using an ion...

Norris, Richard Eugene

1976-01-01T23:59:59.000Z

372

Fate of Magnesium Chloride Brine Applied to Suppress Dust from Unpaved Roads at the INEEL Subsurface Disposal Area  

SciTech Connect (OSTI)

Between 1984 and 1993, MgCl2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl– might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl– in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl– concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl– concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl– was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl– remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl– in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface

Larry Hull; Carolyn Bishop

2004-02-01T23:59:59.000Z

373

Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems  

SciTech Connect (OSTI)

The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

Not Available

1991-01-01T23:59:59.000Z

374

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas  

SciTech Connect (OSTI)

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01T23:59:59.000Z

375

Morphology of GaAs/sub 1-x/P/sub x/ superlattices grown by MOCVD and chloride VPE  

SciTech Connect (OSTI)

Distorted layer growth manifested by nonuniform etching may occur in GaAs/sub 1-x/P/sub x/ superlattices grown by MOCVD and VPE. The distortion was found to be more severe for MOCVD growth than for VPE. The distortion is decreased by decreasing the magnitude of the interlayer strain in the superlattice but does not depend upon the layer thickness. The rate of crystal growth, the temperature of growth and the strain rate in the layer supporting the superlattice also influence the distortion. Several possible causes of the effect are discussed, including nonuniform elastic stress and/or compositional nonuniformity. 12 references, 6 figures.

Blakeslee, A.E.; Kibbler, A.; Wanlass, M.W.

1985-03-01T23:59:59.000Z

376

Effect of different ratios of sodium to chloride using isokalemic diets for growing and finishing swine raised during hot weather  

E-Print Network [OSTI]

into the tubules (Guyton, 1976) The epithelial cells of the prox'mal tubules, distal tubules and collecting tubules secrete H ions into the tubular fluid. The process begins with C02 which under the influence of carbonic anhydrase enzyme combines with water...

Serna-Saldivar, Sergio Othon

1982-01-01T23:59:59.000Z

377

EA-1157: Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas, Carrollton, Kentucky  

Broader source: Energy.gov [DOE]

This EA evaluates the environmental impacts for the proposal to advance Oxyhydrochlorination technology to an integrated engineering-scale process.

378

Effect of pre-harvest calcium chloride applications on fruit calcium level and post-harvest anthracnose disease of papaya  

E-Print Network [OSTI]

-harvest anthracnose disease of papaya Babak Madani a,*, Mahmud Tengku Muda Mohamed a,**, Alan R. Biggs c , Jugah Kadir

Biggs, Alan R.

379

Influence of internal curing using lightweight aggregates on interfacial transition zone percolation and chloride ingress in mortars  

E-Print Network [OSTI]

paste [5]. If sufficient curing water is not readily available at early ages, the concrete will undergo on the nature of the aggregate, specifically its porosity and water absorption. Lightweight aggre- gates (LWA) with a porous surface layer have been noted to produce a dense ITZ microstructure that is equivalent

Bentz, Dale P.

380

Comparison of the cytotoxic effects of cadmium chloride and cadmium-metallothionein in LLC-PK[sub 1] cells  

SciTech Connect (OSTI)

Recent studies have shown that ionic cadmium (Cd[sup 2+]) can selectively damage the tight junctions between LLC-PK[sub 1] cells. The objective of the present studies was to determine if cadmium that is bound to metallothionein (CD-MT) can also damage the junctions between these cells. Cells on Falcon Cell Culture Inserts were exposed to Cd[sup 2+] or Cd-Mt from the apical and basolateral compartments. The integrity of cell junctions was assessed by monitoring the transepithelial electrical resistance, and cell viability was evaluated by monitoring the release of lactate dehydrogenase into the medium. Exposure to Cd[sup 2+] for 1-4 hours caused a pronounced decrease in the transepithelial resistance without affecting cell viability. By contrast, exposure to Cd-Mt had little effect on the electrical resistance until the cells began to die, which did not occur until 24-48 hours of exposure. Additional results showed that the cells accumulated Cd[sup 2+] more rapidly than Cd-Mt. These results indicate that Cd-Mt does not damage the junctions between LLC-PK[sub 1] cells, but that it can kill the cells after prolonged exposure.

Prozialeck, W.C.; Wellington, D.R.; Lamar, P.C. (Midwestern Univ., Downers Grove, IL (United States))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Treatment of recalcitrant plantar hyperhidrosis with type-A botulinum toxin injections and aluminum chloride in salicylic acid gel  

E-Print Network [OSTI]

hyperhidrosis. Needle-free anesthesia as an alternative toBenohanian A. Needle-free anesthesia: a promising techniqueunits (mu) per sole. Anesthesia was achieved through the

Benohanian, Antranik

2008-01-01T23:59:59.000Z

382

Effect of calcium chloride on pH and availability of zinc and phosphorus in three calcareous soils  

E-Print Network [OSTI]

has been shown that the concentration of Ca in the soil solution seriously affects the soil pH. The pH of the CaCO -CO -H 0 system in equilibrium with the CO concentration normally present in the atmosphere has been shown to be 8. 3. How- ever... to be more soluble than calcite which causes a higher pH, HCO3 and Ca concentration in the soil solution. They suggested that in a study of solubility of calcareous soils, measurements of P O, pH, 2 Ca p Mg p HC03 and ionic strength in equilibrium extracts...

Podisuk, Varangkana

1976-01-01T23:59:59.000Z

383

A 2000 year atmospheric history of methyl chloride from a South Pole ice core: Evidence for climate-controlled variability  

E-Print Network [OSTI]

from NW Atlantic and Pacific Ocean studies, J. Geophys.in both the Atlantic and Pacific oceans for elevated low

Williams, Margaret B; Aydin, Murat; Tatum, Cheryl; Saltzman, Eric S

2007-01-01T23:59:59.000Z

384

Impacts of Venturi Turbulent Mixing on the Size Distributions of Sodium Chloride and Dioctyl-Phthalate Aerosols  

SciTech Connect (OSTI)

Internal combustion engines are a major source of airborne particulate matter (PM). The size of the engine PM is in the sub-micrometer range. The number of engine particles per unit volume is high, normally in the range of 10{sup 12} to 10{sup 14}. To measure the size distribution of the engine particles dilution of an aerosol sample is required. A diluter utilizing a venturi ejector mixing technique is commercially available and tested. The purpose of this investigation was to determine if turbulence created by the ejector in the mini-dilutor changes the size of particles passing through it. The results of the NaCl aerosol experiments show no discernible difference in the geometric mean diameter and geometric standard deviation of particles passing through the ejector. Similar results were found for the DOP particles. The ratio of the total number concentrations before and after the ejector indicates that a dilution ratio of approximately 20 applies equally for DOP and NaCl particles. This indicates the dilution capability of the ejector is not affected by the particle composition. The statistical analysis results of the first and second moments of a distribution indicate that the ejector may not change the major parameters (e.g., the geometric mean diameter and geometric standard deviation) characterizing the size distributions of NaCl and DOP particles. However, when the skewness was examined, it indicates that the ejector modifies the particle size distribution significantly. The ejector could change the skewness of the distribution in an unpredictable and inconsistent manner. Furthermore, when the variability of particle counts in individual size ranges as a result of the ejector is examined, one finds that the variability is greater for DOP particles in the size range of 40-150 nm than for NaCl particles in the size range of 30 to 350 nm. The numbers or particle counts in this size region are high enough that the Poisson counting errors are small (<10%) compared with the tail regions. This result shows that the ejector device could have a higher bin-to-bin counting uncertainty for ''soft'' particles such as DOP than for a solid dry particle like NaCl. The results suggest that it may be difficult to precisely characterize the size distribution of particles ejected from the mini-dilution system if the particle is not solid.

Cheng, M-D.

2000-08-23T23:59:59.000Z

385

Impacts of Venturi Turbulent Mixing on the Size Distribution of Sodium Chloride and Dioctyl-Phthalate Aerosols  

SciTech Connect (OSTI)

Internal combustion engines are a major source of airborne particulate matter (PM). The size of the engine PM is in the sub-micrometer range. The number of engine particles per unit volume is high, normally in the range of 10{sup 12} to 10{sup 14}. To measure the size distribution of the engine particles dilution of an aerosol sample is required. A diluter utilizing a venturi ejector mixing technique is commercially available and tested. The purpose of this investigation was to determine if turbulence created by the ejector in the mini-dilutor changes the size of particles passing through it.

Cheng, M.-D.; Wainman, T.; Storey, J.

2000-08-01T23:59:59.000Z

386

The interrelations of mineral colloids and sodium chloride as measured by pH, conductivity, and water-soluble cations  

E-Print Network [OSTI]

?nos material, then any endothermic or exothermic re- action vill appear on the dehydratfon curve shoving the temperature differences as a function of the tenperature of the reference notarial. Page (43)x and Eendricks and Alexander {19) described equipnent... (exothermic) and a deflection in the opposite direction is noted on the gslvancmeter. Ths deflection on the galvancseter is proportional to e. m. f. created which is dependent upce the amount of heat abaca'bed or liberated in the sample being idcntif ied...

Crozier, Baalis B

1952-01-01T23:59:59.000Z

387

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z

388

Toxicologic evaluation of analytes from Tank 241-C-103  

SciTech Connect (OSTI)

Westinghouse Hanford Company requested PNL to assemble a toxicology review panel (TRP) to evaluate analytical data compiled by WHC, and provide advice concerning potential health effects associated with exposure to tank-vapor constituents. The team`s objectives would be to (1) review procedures used for sampling vapors from tanks, (2) identify constituents in tank-vapor samples that could be related to symptoms reported by workers, (3) evaluate the toxicological implications of those constituents by comparison to establish toxicological databases, (4) provide advice for additional analytical efforts, and (5) support other activities as requested by WHC. The TRP represents a wide range of expertise, including toxicology, industrial hygiene, and occupational medicine. The TRP prepared a list of target analytes that chemists at the Oregon Graduate Institute/Sandia (OGI), Oak Ridge National Laboratory (ORNL), and PNL used to establish validated methods for quantitative analysis of head-space vapors from Tank 241-C-103. this list was used by the analytical laboratories to develop appropriate analytical methods for samples from Tank 241-C-103. Target compounds on the list included acetone, acetonitrile, ammonia, benzene, 1, 3-butadiene, butanal, n-butanol, hexane, 2-hexanone, methylene chloride, nitric oxide, nitrogen dioxide, nitrous oxide, dodecane, tridecane, propane nitrile, sulfur oxide, tributyl phosphate, and vinylidene chloride. The TRP considered constituent concentrations, current exposure limits, reliability of data relative to toxicity, consistency of the analytical data, and whether the material was carcinogenic or teratogenic. A final consideration in the analyte selection process was to include representative chemicals for each class of compounds found.

Mahlum, D.D.; Young, J.Y.; Weller, R.E.

1994-11-01T23:59:59.000Z

389

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

930°F) to produce vinyl chloride monomer. VCM is convertedDichloride / Vinyl Chloride Monomer Optimize recycle loopsEthylene dichloride and vinyl chloride monomer. A number of

Neelis, Maarten

2008-01-01T23:59:59.000Z

390

HOSPITAL VENTILATION STANDARDS AND ENERGY CONSERVATION: A SUMMARY OF THE LITERATURE WITH CONCLUSIONS AND RECOMMENDATIONS, FY 78 FINAL REPORT  

E-Print Network [OSTI]

TLV (EEm) ACGIH Vinyl Chloride (Monomer) 5 mg/m ACGIH NPPainters - Solvent Vinyl Chloride (Monomer) Engineering -IUPAC Naming System Vinyl Chloride (monomer) Route of Entry:

DeRoos, R.L.

2011-01-01T23:59:59.000Z

391

Recovery of cesium  

DOE Patents [OSTI]

A process of recovering cesium ions from mixtures of ions containing them and other ions, e.g., a solution of nuclear waste materials, which comprises establishing a separate source phase containing such a mixture of ions, establishing a separate recipient phase, establishing a liquid membrane phase in interfacial contact with said source and recipient phases, said membrane phase containing a ligand, preferably a selected calixarene as depicted in the drawing, maintaining said interfacial contact for a period of time long enough to transport by said ligand a substantial portion of the cesium ion from the source phase to the recipient phase, and recovering the cesium ion from the recipient phase. The separation of the source and recipient phases may be by the membrane phase only, e.g., where these aqueous phases are emulsified as dispersed phases in a continuous membrane phase, or may include a physical barrier as well, e.g., an open-top outer container with an inner open-ended container of smaller cross-section mounted in the outer container with its open bottom end spaced from and above the closed bottom of the outer container so that the membrane phase may fill the outer container to a level above the bottom of the inner container and have floating on its upper surface a source phase and a recipient phase separated by the wall of the inner container as a physical barrier. A preferred solvent for the ligand is a mixture of methylene chloride and carbon tetrachloride.

Izatt, Reed M. (Provo, UT); Christensen, James J. (Provo, UT); Hawkins, Richard T. (Orem, UT)

1984-01-01T23:59:59.000Z

392

Control technology assessment of hazardous-waste-disposal operations in chemicals manufacturing: in-depth survey report of San Juan Cement Company, Dorado, Puerto Rico, November 1981  

SciTech Connect (OSTI)

A visit was made to the San Juan Cement Company, Dorado, Puerto Rico to evaluate control methods for a storage and delivery system for hazardous wastes used in a demonstration project as a supplemental fuel for cofiring a cement kiln. Analysis of the material during the visit revealed the presence of methylene chloride, carbon-tetrachloride, chloroform, acetone, hexane, ethanol, and ethyl acetate. Steel storage tanks were placed on an impermeable concrete slab surrounded by a sealed retaining wall. Steel piping with all welded joints carried the waste fuels from storage tanks to the kiln, where fuels were injected through a specially fabricated burner. Vapor emissions were suppressed by venting the displaced vapor through a recycle line. Exhaust gases from the kiln passed through a bag house type dust collector, and were vented to the atmosphere through a single stack. Half-mask air-purifying respirators were used when in the hazardous-waste storage/delivery area. Neoprene gloves were used when performing tasks with potential skin contact. Hard hats, safety glasses, and safety boots were all worn. The author concludes that the control methods used seemed effective in suppressing vapor emissions.

Crandall, M.S.

1982-07-01T23:59:59.000Z

393

Plant uptake of pentachlorophenol from sludge-amended soils  

SciTech Connect (OSTI)

A greenhouse study was conducted to determine the effects of sludge on plant uptake of {sup 14}C-pentachlorophenol (PCP). Plants included tall fescue (Festuca arundinacea Schreb.), lettuce (Latuca sativa L.), carrot (Daucus carota L.), and chile pepper (Capsicum annum L.). Minimal intact PCP was detected in the fescue and lettuce by gas chromatography/mass spectrometry (GC/MS) analysis. No intact PCP was detected in the carrot tissue extracts. Chile pepper was not analyzed for intact PCP because methylene chloride extracts contained minimal {sup 14}C. The GC/MS analysis of soil extracts at harvest suggests a half-life of PCP of about 10 d independent of sludge rate or PCP loading rate. Rapid degradation of PCP in the soil apparently limited PCP availability to the plant. Bioconcentration factors (dry plant wt./initial soil PCP concentration) based on intact PCP were <0.01 for all crops, suggesting little PCP uptake. Thus, food-chain crop PCP uptake in these alkaline soils should not limit land application of sludge.

Bellin, C.A.; O'Connor, G.A.

1990-01-01T23:59:59.000Z

394

Biological removal of organic constituents in quench waters from high-Btu coal-gasification pilot plants  

SciTech Connect (OSTI)

Studies were initiated to assess the efficiency of bench-scale, activated-sludge treatment for removal of organic constituents from coal-gasification process effluents. Samples of pilot-plant, raw-gas quench waters were obtained from the HYGAS process of the Institute of Gas Technology and from the slagging, fixed-bed (SFB) process of the Grand Forks Energy Technology Center. The types of coal employed were Bituminous Illinois No. 6 for the HYGAS and Indian Head lignite for the SFB process. These pilot-plant quench waters, while not strictly representative of commercial condensates, were considered useful to evaluate the efficiency of biological oxidation for the removal of organics. Biological-reactor influent and effluent samples were extracted using a methylene chloride pH-fractionation method into acid, base, and neutral fractions, which were analyzed by capillary-column gas-chromatography/mass-spectrometry. Influent acid fractions of both HYGAS and SFB condensates showed that nearly 99% of extractable and chromatographable organic material comprised phenol and alkylated phenols. Activated-sludge treatment removed these compounds almost completely. Removal efficiency of base-fraction organics was generally good, except for certain alkylated pyridines. Removal of neutral-fraction organics was also good, except for certain alkylated benzenes, certain polycyclic aromatic hydrocarbons, and certain cycloalkanes and cycloalkenes, especially at low influent concentrations.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

395

Biological removal of organic constituents in quench water from a slagging, fixed-bed coal-gasification pilot plant  

SciTech Connect (OSTI)

This study is part of an effort to assess the efficiency of activated-sludge treatment for removal of organic constituents from high-Btu coal-gasification pilot-plant quench waters. A sample of raw-gas quench water was obtained from the Grand Forks Energy and Technology Center's pilot plant, which employs the slagging, fixed-bed gasification process. The quench water generated in the processing of Indian Head lignite was pretreated to reduce ammonia and alkalinity, and then diluted and subjected to long-term biological treatment, followed by detailed characterization and analysis of organic constituents. The pretreated (influent) and treated (effluent) samples were extracted using a methylene chloride, pH-fractionation method to obtain acid, base, and neutral fractions, which were analyzed by capillary-column gas chromatography/mass spectrometry (GC/MS). Over 99% of the total extractable and chromatographable organic material in the influent acid fraction was composed of phenol and alkylated phenols. Biological treatment removed these compounds almost completely. Major components of the influent base fraction were alkylated pyridines, anilines, aminopyrroles, imidazoles and/or pyrazoles, diazines, and quinolines. Removal efficiency of these compounds ranged between 90 and 100%. The influent neutral fraction was composed mainly of cycloalkanes, cycloalkenes, naphthalene, indole, acetophenone, and benzonitrile. Alkylated benzenes were generally absent. Removal efficiencies of these compounds were generally very good, except for certain alkylated cycloalkanes and cycloalkenes. Results are compared with those of a similar study on HYGAS coal-gasification quench water.

Stamoudis, V C; Luthy, R G

1980-02-01T23:59:59.000Z

396

Oak Ridge K-25 Site chlorinated solvent pollution prevention opportunity assessment  

SciTech Connect (OSTI)

A pollution prevention opportunity assessment (PPOA) was conducted at the Oak Ridge K-25 Site to identify opportunities to reduce and better manage the use of chlorinated solvents. At the K-25 Site, 67 control areas were examined for their potential use of chlorinated solvents. Of these areas, 27 were found to be using (1) chlorinated solvents for cleaning, degreasing, and lubricating; (2) laboratory standards and solvents; and (3) test medium. Current management practices encourage the identification and use of nonhazardous chemicals, including the use of chlorinated solvents. The main pollution prevention principles are source reduction and recycling, and a number of pollution prevention options based on these principles were identified and evaluated as part of this chlorinated solvent PPOA. Source reduction options evaluated for the K-25 Site include the substitution of chlorinated solvents with nonchlorinated solvents. Recycling was identified for those areas that would benefit most from the reuse of the chlorinated solvents in use. The pollution prevention options that offer the greatest opportunity for success at the K-25 Site are the implementation of substitutes at the 10 control areas using chlorinated solvents for cleaning, degreasing, and lubrication. A change in the process may be all that is needed to eliminate the use of a chlorinated solvent. Once a decision is made to implement a substitution, the information should be communicated to all shops and laboratories. Another option to consider is the installation of recycling units to recycle the large amounts of methylene chloride used in the analytical sampling procedure.

Not Available

1994-08-01T23:59:59.000Z

397

Solvent Extraction of Chemical Attribution Signature Compounds from Painted Wall Board: Final Report  

SciTech Connect (OSTI)

This report summarizes work that developed a robust solvent extraction procedure for recovery of chemical attribution signature (CAS) compound dimethyl methyl phosphonate (DMMP) (as well as diethyl methyl phosphonate (DEMP), diethyl methyl phosphonothioate (DEMPT), and diisopropyl methyl phosphonate (DIMP)) from painted wall board (PWB), which was selected previously as the exposed media by the chemical attribution scientific working group (CASWG). An accelerated solvent extraction approach was examined to determine the most effective method of extraction from PWB. Three different solvent systems were examined, which varied in solvent strength and polarity (i.e., 1:1 dichloromethane : acetone,100% methanol, and 1% isopropanol in pentane) with a 1:1 methylene chloride : acetone mixture having the most robust and consistent extraction for four original target organophosphorus compounds. The optimum extraction solvent was determined based on the extraction efficiency of the target analytes from spiked painted wallboard as determined by gas chromatography x gas chromatography mass spectrometry (GCxGC-MS) analysis of the extract. An average extraction efficiency of approximately 60% was obtained for these four compounds. The extraction approach was further demonstrated by extracting and detecting the chemical impurities present in neat DMMP that was vapor-deposited onto painted wallboard tickets.

Wahl, Jon H.; Colburn, Heather A.

2009-10-29T23:59:59.000Z

398

Monitoring DNAPL pumping using integrated geophysical techniques  

SciTech Connect (OSTI)

The removal of DNAPL during pumping was monitored. At Hill AFB in Utah, a free-product DNAPL plume (predominantly TCE, with some TCA, PCE, methylene chloride) is pooled in water-wet soil on a thick clay aquitard. Groundwater pumping at Operable Unit 2 began in 1994; to date, nearly 30,000 gal DNAPL have been recovered. From Sept. 1994 through Sept. 1995, changes in the basin during DNAPL pumping were monitored using fiber optic chemical sensors, neutron logs, and electrical resistance tomography (ERT). The first two sensor types verify the presence of DNAPL in vicinity of 3 boreholes which form a cross section from the perimeter of the basin to its center. Cross borehole ERT images the changes in formation electrical properties due to removal of DNAPL, extending the understanding of DNAPL removal between the boreholes. During pumping, electrical resistivities decreased; we suggest these decreases are directly caused by the reduction in DNAPL. During ground water pumping, water with relatively low resistivity replaces some of the DNAPL pockets as the highly insulating DNAPL is removed. Results suggest that, as DNAPL is pumped from a nearby well, product slowly drains along the top of an aquitard and into the pump well, where it collects.

Newmark, R.L.

1997-01-01T23:59:59.000Z

399

A BRIEF HISTORY OF INDUSTRIAL CATALYSIS  

E-Print Network [OSTI]

HYDROGENATIONS VINYL CHLORIDE MONOMER ( OXYCHLORINA'I'ION)and other monomers, such as vinyl- chloride, which cannot be

Heinemann, Heinz

2013-01-01T23:59:59.000Z

400

E-Print Network 3.0 - acetylenes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science 2 Acetylene Inhibition of Trichloroethene and Vinyl Chloride Summary: Acetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

E-Print Network 3.0 - acetylene Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science 2 Acetylene Inhibition of Trichloroethene and Vinyl Chloride Summary: Acetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive...

402

Fluorinated Compounds DOI: 10.1002/anie.201301097  

E-Print Network [OSTI]

. Traditionally, benzylic fluorides can be prepared by halogen exchange, electrochemical methods was a marked preference for methylene CÃ?H bonds in carbocyclic rings, apparently owing to steric

Groves, John T.

403

Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate  

SciTech Connect (OSTI)

The crystal structure of title compound (Fe[(C{sub 25}H{sub 21}N{sub 7}O{sub 4}S{sub 2})] {center_dot} 4(C{sub 3}NOH{sub 7}), where C{sub 3}NOH{sub 7} is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) A, {beta} = 108.753(2) Degree-Sign . The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.

Dilek, N., E-mail: nefised@gmail.com [Aksaray University, Department of Physics, Arts and Sciences Faculty (Turkey); Guenes, B. [Gazi University, Department of Physics Education, Gazi Education Faculty (Turkey)] [Gazi University, Department of Physics Education, Gazi Education Faculty (Turkey); Bueyuekguengoer, O. [Ondokuz Mayis University, Department of Physics, Arts and Sciences Faculty (Turkey)] [Ondokuz Mayis University, Department of Physics, Arts and Sciences Faculty (Turkey); Guep, R. [Mugla University, Department of Chemistry, Arts and Sciences Faculty (Turkey)] [Mugla University, Department of Chemistry, Arts and Sciences Faculty (Turkey)

2013-01-15T23:59:59.000Z

404

Influence of varying levels of ammonium chloride on urine pH and specific gravity, overall feed conversion, and water consumption in mature wether goats.  

E-Print Network [OSTI]

). Phosphatic calculi are formed in response to a high-concentrate low-roughage with a low calcium-to-phosphorus ratio, high-magnesium diets, and alkaline urine (Hooper, 1998). Lambs fed a diet high in phosphorus and magnesium had a high incidence of calculi... America (Bailey, 1981). Diets high in silica along with high calcium-to-phosphorus ratios, that are supplemented with sodium bicarbonate may predispose the formation of silica calculi (Stewart et al., 1990). 4 Oxalate calculi are caused...

Kennedy, Matthew joseph

2009-05-15T23:59:59.000Z

405

doi:10.1016/j.gca.2005.01.015 CO2-H2O mixtures in the geological sequestration of CO2. II. Partitioning in chloride  

E-Print Network [OSTI]

molal CaCl2. Copyright © 2005 Elsevier Ltd 1. INTRODUCTION In Part I of this study (Spycher et al., 2003 moderately saline solutions up to 6 m NaCl and 4 m CaCl2. As before, the objective is to compute in the most sol- ubilities of CO2 in NaCl and CaCl2 solutions, as well as in seawater, with accuracies close

Santos, Juan

406

New method to minimize high-temperature corrosion resulting from alkali sulfate and chloride deposition in combustion systems. II. molybdenum salts  

SciTech Connect (OSTI)

The use of fuels other than natural gas in gas turbine generators still is fraught with blade corrosion problems that result from the formation of sodium sulfate or potassium sulfate, in the presence of chlorine. The present work illustrates that the addition of molybdenum salts to synthetic fuels (synfuels) modifies this deposition process and benign protective coatings of alkali polymolybdates are produced instead. This study is a follow-up to research published earlier in this journal that showed closely similar behavior with tungsten salt additives. In the case of molybdenum, a new preferential ranking of product formation on the surface is established that is closely related to the thermodynamic stabilities, namely, Na{sub 2}Mo{sub 2}O{sub 7} {gt} Na{sub 2}SO{sub 4} {gt} Na{sub 2}MoO{sub 4} {gt} NaCl and K{sub 2}Mo{sub 4}O{sub 13} {gt} K{sub 2}Mo{sub 3}O{sub 10} {gt} K{sub 2}Mo{sub 2}O{sub 7} {gt} K{sub 2}SO{sub 4} {gt} K{sub 2}MoO{sub 4} {gt} KCl. This chemistry exists under fuel-lean conditions and is otherwise not sensitive to the fuel, combustion conditions, surface temperature, or material. The required additive trace levels of molybdenum salt are on the order of twice that of the gaseous alkali, on an atomic basis. Consequently, when used as a final pre-gas turbine polishing technique and following other fuel precleaning methods, the approach offers a very practical and inexpensive solution. 63 refs., 6 figs., 1 tab.

Keith Schofield [University of California, Santa Barbara, CA (United States). Materials Research Laboratory

2005-10-01T23:59:59.000Z

407

Magnetic Exchange Coupling in Chloride-Bridged 5f-3d Heterometallic Complexes Generated via Insertion into a Uranium(IV) Dimethylpyrazolate  

E-Print Network [OSTI]

Insertion into a Uranium(IV) Dimethylpyrazolate Dimer Stosh A. Kozimor, Bart M. Bartlett, Jeffrey D. Rinehart, and Jeffrey R. Long* Department of Chemistry, UniVersity of California, Berkeley, California additional products were observed: a THF adduct, (Me2Pz)4U(THF), and a salt of the pentapyrazolate uranium

408

The effect of specific chloride adsorption on the electrochemical behavior of ultrathin Pd films deposited on Pt(111) in acid solution  

E-Print Network [OSTI]

the Pd surface coverage modifies the voltammetric profilesFigure 2 voltammetric profiles of the Pt(111)-Pd electrodethe voltammetric profiles that demonstrate the effect of Pd.

Arenz, M.; Stamenkovic, V.; Schmidt, T.J.; Wandelt, K.; Ross, P.N.; Markovic, N.M.

2002-01-01T23:59:59.000Z

409

Viscosities of the Mixtures of 1-Ethyl-3-Methylimidazolium Chloride with Water, Acetonitrile and Glucose: A Molecular Dynamics Simulation and Experimental Study  

E-Print Network [OSTI]

the world's dependence on fossil fuels and mitigating the net emission of CO2 into the atmosphere.1 dissolution, making it difficult to pump such solutions and causing a reduction in mass transfer rates

Bell, Alexis

410

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Technical progress report, October 1995--December 1995  

SciTech Connect (OSTI)

Coal liquefaction involves cleavage of methylene, dimethylene and ether bridges connecting polycyclic aromatic units and the reactions of various oxygen functional groups. Here in this quarterly, we report on the catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds in the reactions of dibenzothiophene (DBT) with hydrogen under conditions related to coal liquefaction. The catalytic effects of several molybdenum-, cobalt-, and iron-containing compounds have been examined in the hydrogenation and hydrodesulfurization reactions of dibenzothiophene (DBT) under conditions related to coal liquefaction. The metal compounds are candidate catalyst precursors for direct coal liquefaction. The reactions were carried out in batch microautoclave reactors at 400{degrees}C for 30 minutes with 6.9 MPa (cold) hydrogen pressure, and tridecane solvent. A metal loading of 0.5 mol% resulted in low conversion and only hydrogenation. Addition of sulfur in 4:1 molar ratio led only to a minor increase in conversion and hydrodesulfurization. The use of a higher boiling solvent (octadecane vs. tridecane) was beneficial in providing increased conversion, hydrodesulfurization, and hydrogenation. An increase in metal compound loading to 36.2 mol% led to a dramatic increase in conversion, hydrodesulfurization, and hydrocracking. Molybdenum hexacarbonyl at 36 mol% loading, with added sulfur at 6:1 ratio and octadecane solvent, gave 100% conversion of dibenzothiophene to other products with 100% hydrodesulfurization. Ammonium tetrathiomolybdate and molybdenum(III) chloride are less active under similar conditions. A cobalt-molybdenum thiocubane complex gave unexpectedly low conversions. Iron and cobalt carbonyls also provided very low conversions, even with added sulfur.

Song, C.; Cooke, W.S.; Schmidt, E.; Schobert, H.H.

1996-02-01T23:59:59.000Z

411

Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites  

SciTech Connect (OSTI)

Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

2014-05-06T23:59:59.000Z

412

A Small Aptamer with Strong and Specific Recognition of the Triphosphate of ATP  

E-Print Network [OSTI]

S1 A Small Aptamer with Strong and Specific Recognition of the Triphosphate of ATP Peter L. Sazani spacer at the C-8 position of adenine) agarose, ATP, ADP, AMP, GTP, CTP, ATP -S, - methyleneadenosine 5-triphosphate (- methylene ATP), - methyleneadenosine 5-triphosphate (- methylene ATP), adenosine 5-(--imido

Heller, Eric

413

Vasopressin, ATP and Catecholamines Differentially Control Potassium Secretion in Inner Ear Cell line  

E-Print Network [OSTI]

1 Vasopressin, ATP and Catecholamines Differentially Control Potassium Secretion in Inner Ear Cell and catecholamines stimulate while ATP inhibits apical potassium secretion by EC5v cells. These results open new OF ABBREVIATIONS ,-Me-ATP: ,-methylene-ATP ,-Me-ATP: ,-methylene ATP InsPs: total inositol phosphates Asn1 , Val5

Paris-Sud XI, Université de

414

E-Print Network 3.0 - antioxidant n-acetyl-l-cysteine ameliorates...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: ), N-acetyl-L-cysteine (NAC), sodium chloride (NaCl), calcium chloride (CaCl2), potassium chloride (KCl... to selenite in (A) one-way ANOVA: F5 5.97, p0.0002; and...

415

Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and  

E-Print Network [OSTI]

performed on stationary vinyl chloride monomer droplets and has provided values of effective reaction orders into the vinyl chloride monomer (VCM). As a c, ThierryOnline Monitoring of Vinyl Chloride Polymerization in a Microreactor Using Raman Spectroscopy

Paris-Sud XI, Université de

416

E-Print Network 3.0 - amine-type corrosion inhibitors Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Calcium Chloride with Nitrate Inhibitor Corrosion & Repassivation... in Artificial CaCl2 Brine with NO3 - Inhibitor Alloy 22 in Calcium Chloride with Nitrate Inhibitor...

417

Identification of a haloalkaliphilic and thermostable cellulase with improved ionic liquid tolerance  

E-Print Network [OSTI]

acetate ([Emim]Ac), 1-ethyl-3-methylimidazolium chloride ([Emim]Cl), 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) and 1-allyl-

Zhang, Tao

2012-01-01T23:59:59.000Z

418

Modeling an EDC Cracker using Computational Fluid Dynamics (CFD).  

E-Print Network [OSTI]

?? The process used by the Norwegian company Hydro for making Vinyl Chloride Monomer (VCM) from natural gas and sodium chloride has been studied. A… (more)

Kaggerud, Torbjørn Herder

2007-01-01T23:59:59.000Z

419

E-Print Network 3.0 - agent-loaded polymeric nanocapsules Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Chemistry ; Engineering 63 New Aspects of the Suspension Polymerization of Vinyl Chloride in Relation to the Low Thermal Stability of Poly(Vinyl Chloride) Summary: New...

420

E-Print Network 3.0 - acid monomer induced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Vinyl Chloride in Relation to the Low Thermal Stability of Poly(Vinyl Chloride) Summary: to be immediately attached to a monomer molecule, initiating new chain...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

E-Print Network 3.0 - autogenous skin-derived mesenchymal Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

422

E-Print Network 3.0 - autogenous costal perichondrial Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

423

E-Print Network 3.0 - autogenous translational regulation Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

424

E-Print Network 3.0 - autogenic osteoclast-based niche-like Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

425

E-Print Network 3.0 - autogenous aedes togoi Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

426

E-Print Network 3.0 - autogenous electrolyte non-pyrolytically...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

made with Aggregate Qtz. Use... chloride-ion penetrability). Keywords: aggregates, air entrainment, autogenous shrinkage, chloride Source: Wisconsin-Milwaukee, University of...

427

Synthesis of CdS nanoparticles for photocatalytic application of methyleneblue degradation  

SciTech Connect (OSTI)

CdS nanoparticles were prepared by the reaction of cadmium acetate with thiourea in the presence and absence of methylene blue dye (MB). The nanoparticles were characterized by, XRD, FT-IR, UV-Vis. XRD study shows the presence of hexagonal phase for the nanoparticles whereas in case of the bulk samples only the hexagonal phase is observed. Fourier transform infrared spectroscopy (FT-IR) showed a strong interaction of methyl groups with CdS nanoparticles. The degradation of methylene blue was analysed using UV-Vis absorbance spectrum. Thus the results authenticate that methylene blue dye influences the structural and optical properties of the CdS nanoparticles.

Muthuraj, V., E-mail: muthuraj75@gmail.com [Research Department of Chemistry, VHNSN College, Virudhunagar-626001 (India); Umadevi, M. [Department of Chemistry, Nehru Memorial College, Puthanampatti, Trichy-621007, Tamilnadu (India); Sankarasubramanian, K.; Kajamuhideen, M. S. [School of Physics, Madurai Kamaraj University, Madurai-625 021, Tamilnadu (India)

2014-04-24T23:59:59.000Z

428

)potash( . , )K(  

E-Print Network [OSTI]

;41 , : , . , . , , , , . , , , , , . , )( ) ( .)biofuels( , .2030 . : . K­ 94.5%­ Potassium Chloride (KCl( . K

Simon, Emmanuel

429

Chemico-Biological Interactions 166 (2007) 301316 Mortality patterns among industrial workers exposed to  

E-Print Network [OSTI]

of industrial workers exposed to chloroprene (CD) and other substances, including vinyl chloride monomer (VC

Illinois at Chicago, University of

430

Engineering and Health Impact Methods in Green Design Student projects PH 290 Sec 07  

E-Print Network [OSTI]

materials; process chemistry in producing vinyl chloride monomer; choices of antibacterial agents; need

Iglesia, Enrique

431

Carbon and Water Resource Management for Water Distribution Systems  

E-Print Network [OSTI]

Reliability Corporation Polyethylene Polyvinyl chloride Society of Environmental Toxicology and Chemistry Water Distribution System

Hendrickson, Thomas Peter

2013-01-01T23:59:59.000Z

432

Computational modelling of the mechanical behavior of nanocrystalline metals based on the deformation mechanisms and their transitions  

E-Print Network [OSTI]

ties of Nanostructured Nickel Produced by Electrodepositionnickel chloride and boric acid with properly chosen electrodeposition

Zhu, Baozhi

2006-01-01T23:59:59.000Z

433

EA-1157: Final Environmental Assessment  

Broader source: Energy.gov [DOE]

Methyl Chloride via Oxyhydrochlorination of Methane: A Building Black for Chemicals and Fuels from Natural Gas

434

A new class of photoresponsive surfactants  

E-Print Network [OSTI]

In this thesis, a new class of nonionic, photoresponsive surfactants consisting of a polar di(ethylene oxide) head group attached to an alkyl spacer of between two and eight methylene groups, coupled through an ether linkage ...

Shang, Tiangang, 1969-

2005-01-01T23:59:59.000Z

435

Detection and Quantification of Expansive Clay Minerals in Geologically-Diverse Texas Aggregate Fines  

E-Print Network [OSTI]

and asphalt concretes. The Texas Department of Transportation (TXDOT) and Texas A&M Transportation Institute (TTI) evaluated the methylene blue adsorption test for its potential to identify and estimate quantities of expansive clays in aggregate stockpiles...

Russell, George 1983-

2012-11-28T23:59:59.000Z

436

IBTM-Containing Gramicidin S Analogues: Evidence for IBTM as a Suitable Type II -Turn Mimetic1,2  

E-Print Network [OSTI]

Vance ACS Abstracts, October 1, 1997. (1) Abbreviations: AAA, amino acid analysis; Al, allyl; Boc, tert)methylene]-N-methylmethanaminium hexa- fluorophosphate N-oxide; HOAc, acetic acid; HOAt, 7-azahydroxybenzo- triazole; HOBt, 1

Pompeu Fabra, Universitat

437

PERFORMANCE OF LIQUI-CEL EXTRA-FLOW MEMBRANE CONTRACTOR IN A PURE WATER AND IN A 0.2% SODIUM CHLORIDE SOLUTION (SNO-STR-2001-11).  

SciTech Connect (OSTI)

After completion of SNO's first phase measurement of the neutrino charge current, two tons of salt were added into the SNO heavy water to increase the sensitivity of the neutral current measurement (Phase II). Liqui-Cel Extra-Flow Membrane Contactors (simply called Liqui-Cel) are used in the SNO heavy-water circulating system to remove the dissolved gases, such as oxygen, nitrogen, radon, and water vapor from the liquid water. One possible scenario with phase II operation is that the salt may leak through the Liqui-Cel Membrane and come in contact with the vacuum pumps and other metal components of the Heavy-Water Vapor Recovery System. In this scenario, corrosion will damage these components, especially the vacuum pump (Pfeiffer UniDry Pump with cast iron interior), and increase the operational difficulties. A series of tests for the behavior of the Liqui-Cel System in pure water and in salt systems was conducted at the Brookhaven National Laboratory in order to measure the transfer of (a) water vapor and (b) salt, if there is any, through the membrane. Initially a 10-inch by 28-inch Liqui-Cel unit, identical to those used in the SNO heavy-water circulating system, was obtained from SNO site. However, extensive analysis showed that the membrane in this unit was defective: a replacement membrane would cost several thousand dollars. Instead, a smaller, 2.5-inch x 8-inch Liqui-Cel, obtained from Dr. Richard Helmers of the University of British Columbia, was used in this experiment. A comparison of the present experiment with the SNO heavy-water system is done with theoretical calculations. The results are discussed in the following sections.

YEH,M.; BOGER,J.; HAHN,R.L.

2001-11-05T23:59:59.000Z

438

The germination and development of seedlings from seeds treated with growth regulators: (2-chloroethyl) trimethylammonium chloride, succinic acid 2,2 dimethylhydrazide and 2,3-dihydro-5-6-diphenyl-1,4 oxathiin  

E-Print Network [OSTI]

. (May 1976) Marihelen Kamp, B. S. Texas Tech University Chairman of Advisory Committee: Dr. Arthur F. . Nightingale 0 th d ' h d d 'gl t. y 1 f I ~1 c. v. cactus flowered were soaked in each of three different growth retarding chemicals SADH... E NIE N T The author of this thesis extends most sincere thanks to Dr. Arthur E. Nightingale for his assistance in the preparation of this thesis and for his invaluable guidance in her graduate studies. Special appreciation is given also to Dr...

Kamp, Marihelen

1976-01-01T23:59:59.000Z

439

Effects of certain chloride salts on properties of frankfurters, hams and restructured pork roasts and of certain non-meat protein products on properties of pork fat emulsions and mortadella sausage  

E-Print Network [OSTI]

by the functional contributions of NaC1. Salt decreases water activity (A ), enhances flavor, improves w binding in comminuted meats, and improves texture. Shelf- life, stability (microbiological) and food safety of salted meats is known to be associated... industry and research foundations to conduct research on ways to reduce sodium contents of processed foods without diminishing their palatability or safety. Salt is an essential part of the human diet. Sodium ions are required in mammals to maintain...

Hand, Larry Wayne

1981-01-01T23:59:59.000Z

440

Effect of glucose and pH on the microbial flora and sensory characteristics of normal and dark, firm, dry beef steaks displayed in polyvinyl chloride film and in vacuum packages  

E-Print Network [OSTI]

Ches ser, B. S. , Texas AEVI Uni vers i ty Cha1rman of Advisory Comm1ttee: Dr. C. Vanderzant Normal and DFD beef steaks with and without added glucose or ac1d (1. 3M disod1um c1trate or 1. 3M d1sodium c1trate - 1. 5M lactic acid) were packaged... of the meat to the meat surface. The average glucose concentration of normal, unstressed beef is approx1mately 100 ug/g of meat (wet weight) w1th an ultimate muscle pH of approximately 5. 5 (13). Animals which have undergone prolonged muscular act1vity...

Chesser, Linda Kay

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

CO2-H2O Mixtures in the Geological Sequestration of CO2. II. Partitioning in Chloride Brines at 12-100 °C and 1-600 bar.  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: Crystal structureComposite-- Energy, science, and technology - C L A! CJCO

442

EPR in Mn2+ doped betaine calcium chloride dihydrate single crystals J. L. Ribeiro (1), J. C. Fayet (2), J. Emery (2), M. Pdzeril (2), J. Albers (3), A. Klpperpieper (3),  

E-Print Network [OSTI]

devil's staircase. In this paper we report a study of Electronic Paramagnetic Resonance of Mn2 + doped

Paris-Sud XI, Université de

443

JOURNAL DE PHYSIQUE Colloque C6, supplkment au no 7, Tome 41, Juillet 1980,page C6-216 Point defect parameters for strontium chloride from ionic conductivity studies  

E-Print Network [OSTI]

. As a result of the HADES calculations good progress has been made in terms of theoretically evaluating-91, neutron scattering experiments 110-121, a HADES calculation of the defect ener- gies [13] and a molecular

Paris-Sud XI, Université de

444

A Preliminary Evaluation of Alternative Liquid Desiccants for a Hybrid Desiccant Air Conditioner  

E-Print Network [OSTI]

and the condenser of a vapor-compression air conditioner. The liquid desiccants studied were lithium chloride, lithium bromide, calcium chloride, and triethylene glycol. Each candidate desiccant was subjected to a screening process which weighed the merits...

Studak, J. W.; Peterson, J. L.

1988-01-01T23:59:59.000Z

445

E-Print Network 3.0 - acute ozone exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... toxins, biotoxins and acutely toxic substances is not exhaustive Chemical...

446

E-Print Network 3.0 - acute phenobarbital exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... toxins, biotoxins and acutely toxic substances is not exhaustive Chemical...

447

E-Print Network 3.0 - acute arsenic exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... OSHAReproToxin Arsenic 7440-38-2 and arsenic compounds IARC-1 Arsenic...

448

E-Print Network 3.0 - acute cadmium exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... toxins, biotoxins and acutely toxic substances is not exhaustive Chemical...

449

E-Print Network 3.0 - acute chemical exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... Ca(CN)2 AcutelyHazardousWaste Captafol 2425-06-1 IARC-2A ... Source:...

450

E-Print Network 3.0 - acute oral exposure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... toxins, biotoxins and acutely toxic substances is not exhaustive Chemical...

451

Gold catalysts for the hydrochlorination of acetylene.  

E-Print Network [OSTI]

??The direct, gas-phase hydrochlorination of acetylene is a method by which vinyl chloride monomer (VCM) is produced industrially. VCM is polymerised to produce poly-vinyl chloride… (more)

Davies, Catherine

2013-01-01T23:59:59.000Z

452

Method of recovering uranium from aqueous solution  

SciTech Connect (OSTI)

Anion exchange resin derived from insoluble crosslinked polymers of vinyl benzyl chloride which are prepared by polymerizing vinyl benzyl chloride and a crosslinking monomer are particularly suitable in the treatment of uranium bearing leach liquors.

Albright, R.L.

1980-01-22T23:59:59.000Z

453

Subscriber access provided by University Libraries | University of Notre Dame Organic Letters is published by the American Chemical Society. 1155 Sixteenth  

E-Print Network [OSTI]

primarily for use as a precursor monomer for poly(vinyl chloride).5 More reactive chloroalkanes are em NH residues which greatly accelerate N-alkylation by activating the chloride leaving group

Smith, Bradley D.

454

E-Print Network 3.0 - acute whole-body exposure Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

benzyl chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... toxins, biotoxins and acutely toxic substances is not exhaustive...

455

aerobic nicotinic acid: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

g magnesium chloride, 3.24 g magnesium sulfate bromide, 34 mg strontium chloride, 22 mg boric acid, 4 mg sodium silicate, 2.4 mg sodium fluoride, 1.6 mg Bae, Jin-Woo 189 XYLARIC...

456

activity-dependent polyadenylation site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 37 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

457

alpine site jungfraujoch: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 166 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

458

allosteric site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 69 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

459

affect redd site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 62 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

460

allosteric citalopram-binding site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 69 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

agnostic splice site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 279 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

462

adenine dinucleotide-binding site: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

commercial setting. Contaminants: Contaminants: Vinyl Chloride 43 Clinical Research Site Management Engineering Websites Summary: Clinical Research Site Management Dan...

463

TUDE CONOMIQUE DES DIFFRENTES MTHODES D'LABORATION DU NIOBIUM  

E-Print Network [OSTI]

or not by chlorides distillation, and finishing with an electron beam melting. That still gives high costs, indeed

Boyer, Edmond

464

E-Print Network 3.0 - acetate phthalate film Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

insecticides... acetate, tetrahydrofuran, cyclohexanone, organic tin compounds, and vinyl chloride TeflonTM nothing... polypropylene and polyethylene plasticizers and...

465

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

466

SciTech Connect: The determination of aluminum by atomic absorption...  

Office of Scientific and Technical Information (OSTI)

Language: English Subject: CHEMISTRY; ABSORPTION; ALUMINUM; CEMENTS; CHLORIDES; COMBUSTION; PHOTOMETRY; QUANTITATIVE ANALYSIS; SILICON OXIDES; SOLUTIONS; SPECTROSCOPY; STEELS...

467

Methylmercury Production in Tidal Salt Marsh Sediments and Potential Control Using Iron Amendments  

E-Print Network [OSTI]

phosphorus removal in treatment wetlands (Ann et al. 2000),within a wetland soil following ferric chloride treatment to

Ulrich, Patrick D.

2011-01-01T23:59:59.000Z

468

Chemico-Biological Interactions 166 (2007) 264276 Chemical process-based reconstruction of exposures for an  

E-Print Network [OSTI]

, the chloroprene (CD) and vinyl chloride monomer (VCM) exposures were modeled for plant specific job title classes to chloroprene (CD) and vinyl chloride monomer (VCM), the historical exposure levels were reconstructed of exposures for an epidemiological study Part II. Estimated exposures to chloroprene and vinyl chloride Nurtan

Illinois at Chicago, University of

469

Environmentally-friendly organochlorine waste processing and recycling  

E-Print Network [OSTI]

vinyl chloride monomer production more efficient, and on possible ways of industrial organochlorine, and vinyl chloride monomer. Polymerization and copolymeriza- tion of typical waste with and without the C5e and polymers. Ã? 2013 Elsevier Ltd. All rights reserved. 1. Introduction Vinyl chloride monomer (VCM) is one

Volinsky, Alex A.

470

The synthesis of symmetrical bis-1,2,5-thiadiazole ligandsq Dean M. Philipp,a  

E-Print Network [OSTI]

for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate there have been no reliable reports of the coordination polymerization of vinyl acetate or vinyl chloride-hydroxy thia- diazole; Vinyl chloride. q Supplementary data associated with this article can be found

Goddard III, William A.

471

Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and  

E-Print Network [OSTI]

. Real-time non-invasive Raman measurement has been performed on stationary vinyl chloride monomer of vinyl chloride (S-PVC) by a free-radical mechanism consists in dispersing liquid monomer under its-decomposition of the organic initiator into the vinyl chloride monomer (VCM). As a consequence, the reaction proceeds

Mailhes, Corinne

472

Theoretical susceptibilities of linear antiferromagnets  

E-Print Network [OSTI]

. TABLE OF CONTENTS CHAPTER I. INTRODUCTION II. THEORY AND APPLICATIONS A. Manganese(II) Chloride B. Iron(II) Chloride C. Cobalt(II) Chloride D. Nickel(II) Chloride E. Copper(II) Chloride F. Manganese(II) Squarate Dihydrate G. Iron(II) Squarate... Dihydrate H. Cobalt(II) Squarate Dihydrate I. Nickel(II) Squarate Dihydrate III. DISCUSSION IV. EXPERIMENTAL Page 12 15 18 20 26 29 52 54 57 APPENDIX A. Synthesis of Transition Metal Squarates. . . . . . . . . . . . . . 45 B. Electron Spin...

McSwain, Sulane

1968-01-01T23:59:59.000Z

473

The Action of Certain Acid Reagents on the Substituted Ureas  

E-Print Network [OSTI]

aniline and methyl phenyl urea chloride with pyridine - 6 Di-phenyl ethyl thio urea and phosgene with pyridine 7 Para mono brom di-phenyl thio urea and methyl phenyl urea chloride - 8 Di-phenyl thio urea and chlor formic ethyl ester with pyridine 9... Methyl ether of di-phenyl thio urea and methyl phenyl urea chloride with pyridine - - 10 Ethyl ether of ortho di-tolyl thio urea and methyl phenyl urea chloride 13 Ethyl ether of ortho di-tolyl thio urea and di-phenyl urea chloride 14 Methyl ether...

Brewster, Ray Q.

1915-01-01T23:59:59.000Z

474

Materials Chemistry and Physics 124 (2010) 319322 Contents lists available at ScienceDirect  

E-Print Network [OSTI]

for photocatalytic reactions, like V2O5/SmVO4 [19] and V2O5/BiVO4 [20] for the degradation of acetone and methylene. Introduction Photocatalysis offers a convenient technology to assist and accelerate chemical reactions under UV

2010-01-01T23:59:59.000Z

475

It is now generally accepted that ATP can act as a fast excitatory neurotransmitter at the autonomic neuromuscular  

E-Print Network [OSTI]

It is now generally accepted that ATP can act as a fast excitatory neurotransmitter a class of ligand-gated cation channels, the P2X receptors. ATP also plays a role in presynaptic North & Barnard, 1997). Thus, P2X1 and P2X� receptors are activated by á,â_methyleneATP (áâ_MeATP

Burnstock, Geoffrey

476

Computer simulation study of liquid CH2F2 with a new effective pair potential model  

E-Print Network [OSTI]

to reproduce the thermodynamic internal energy, density, heat capacity, vapor-liquid equilibrium and structuralComputer simulation study of liquid CH2F2 with a new effective pair potential model Pa potential model is proposed for computer simulations of liquid methylene fluoride and used in Monte Carlo

Mezei, Mihaly

477

Infrared Study of the Molecular Orientation in Ultrathin Films of Behenic Acid Methyl Ester: Comparison between  

E-Print Network [OSTI]

Infrared Study of the Molecular Orientation in Ultrathin Films of Behenic Acid Methyl Ester-Blodgett transfer. The presence in the infrared spectra of several bands due to the methylene wagging and twisting and infrared spectroscopy have been developed to study these films. Infrared spectroscopy is particularly

Pezolet, Michel

478

Northeastern University Department of Biology Bio U545/G245 Marine Science Center, Nahant Tuesdays, Fall Quarter, 2008  

E-Print Network [OSTI]

-frame video analysis and electrophysiological techniques. A term paper will involve a review of the behavior identified organisms, neuroanatomy, ethograms, video analysis of behavior, kinematic analysis, analysis Sept 16 Social Learning in Honeybees 2 23 Ladder like Chains, Methylene Blue, HRP, Cobalt, 3 30 Lobster

Ayers, Joseph

479

Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation  

E-Print Network [OSTI]

Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

Jones, William D.

480

Primary to secondary sphere coordination of 15-crown-5 to lanthanide(III) chlorides: Structural analysis of [MCl{sub 3}(15-crown-5)] (M = La, Ce) and [Er(OH{sub 2}){sub 8}]Cl{sub 3} {center_dot} 15-crown-5  

SciTech Connect (OSTI)

Complexes of LaCl{sub 3}{center_dot}7H{sub 2}O and CeCl{sub 3} {center_dot} 7H{sub 2}O directly coordinated to 15-crown-5 were prepared by placing the reactants in 3:1 CH{sub 3}CN:CH{sub 3}OH on opposite sides of a fine porosity glass frit in a U-shaped cell and passing a 10 {mu}A current through the cell. The crystal structures of the two anhydrous 8-coordinate complexes, [MCl{sub 3}(15-crown-5)] (M = La, Ce) have been determined. Each contains the lanthanide in a bicapped trigonal prismatic geometry. The two complexes are isostructural crystallizing in the monoclinic space group P2{sub 1}/c with (at 20{degrees}C) for M = La: a =8.217(8), b = 14.298(2), c = 14.341(9){angstrom}, {beta} = 104.79(8){degrees}, and D{sub calc} = 1.90 g cm{sup {minus}3} for Z = 4; for M = Ce: a = 8.208(9), b = 14.263(6), c = 14.270(8){angstrom}, {beta} = 104.74(7){degrees}, and D{sub calc} = 1.92 g cm{sup {minus}3} for Z = 4. Direct reaction of ErCl{sub 3}{center_dot}6H{sub 2}O with 15-crown-5 in 3:1 CH{sub 3}CN:CH{sub 3}OH resulted in the crystallization of the second sphere hydrogen bonded complex [Er(OH{sub 2}){sub 8}]Cl{sub 3}{center_dot}15-crown-5. This complex is monoclinic, P2{sub 1}/n with (at 18{degrees}C) a = 9.193(3), b = 17.235(9), c = 15.216(5){angstrom}, {beta} = 92.48(3){degrees}, and D{sub calc} = 1.76 g cm{sup {minus}3} for Z = 4. The Er{sup 3+} ion is dodecahedral.

Roger, R.D.; Rollins, A.N. [Northern Illinois Univ., DeKalb, IL (United States)

1994-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "75-09-2 methylene chloride" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Method for making carbon films  

SciTech Connect (OSTI)

A method for treating an organic polymer material, preferably a vinylidene chloride/vinyl chloride copolymer (Saran) to produce a flat sheet of carbon film material having a high surface area ([approx equal]1000 m[sup 2] /g) suitable as an electrode material for super capacitor applications. The method comprises heating a vinylidene chloride/vinyl chloride copolymer film disposed between two spaced apart graphite or ceramic plates to a first temperature of about 160 C for about 14 hours to form a stabilized vinylidene chloride/vinyl chloride polymer film, thereafter heating the stabilized film to a second temperature of about 750 C in an inert atmosphere for about one hour to form a carbon film; and finally activating the carbon film to increase the surface area by heating the carbon film in an oxidizing atmosphere to a temperature of at least 750--850 C for between 1--6 hours. 2 figs.

Tan, M.X.

1999-07-29T23:59:59.000Z

482

Synthesis of Sultams and Related Sulfur Heterocycles Using the Ring-Closing Metathesis Reaction  

E-Print Network [OSTI]

of preparing sulfonamides is by treatment of sulfonyl chlorides with ammonia or amines (Reaction 1, Scheme 1.1). 25 Treatment with ammonia gives primary sulfonamides, while primary and secondary amines give N-alkyl sulfonamides and N,N-dialkyl sulfonamides... respectively. Alternatively, sulfonamides can be prepared from the corresponding sulfinyl chlorides, which are coupled with amines to form sulfinamides and then oxidized into sulfonamides (Reaction 2, Scheme 1.1). 26 In cases where the sulfonyl chloride...

Jimenez, Maria del Sol

2007-09-19T23:59:59.000Z

483

Salt Brine Blending to Optimize Deicing and Anti-icing Performance and Cost  

E-Print Network [OSTI]

Chloride (MgCl2) w/additives ·Envirotech Serv., Scotwood Ind., NA Salt ·Calcium Chloride (CaCl2) ·Tiger 135% 90% 115% Thawrox Gold Treated MgCl2 150% 120% 115% Ice Slicer CaCl2 130% 95% 70% Ice Bite @ 3 gal to Salt Brine Material Base @ 12 F @20 F @ 28 F Calcium Chloride CaCl2 160% 185% 135% RGP-8 CaCl2 170% 80

Minnesota, University of

484

E-Print Network 3.0 - aniline compounds Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 Halogenated Compounds Allyl chloride Carbon tetrachloride... Nitrates and Acids Ammoniated Compounds and Hypochlorites and Bleach Organic Nitrates Source: Oliver, Douglas L. -...

485

JOURNAL OF BACTERIOLOGY, Aug. 2009, p. 52245231 Vol. 191, No. 16 0021-9193/09/$08.00 0 doi:10.1128/JB.00085-09  

E-Print Network [OSTI]

in Clostridium kluyveri. Chlorinated organic compounds, such as tetrachloroethene (PCE) and trichloroethene (TCE reductively dechlorinate PCE, TCE, and their daughter compounds di- chloroethene (DCE) and vinyl chloride (VC

Alvarez-Cohen, Lisa

486

E-Print Network 3.0 - affinity influx v-atpase-dependent Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Environmental Sciences and Ecology ; Biology and Medicine 47 Sodium and chloride transport in soft water and hard water acclimated zebrafish (Danio rerio) Summary:...

487

E-Print Network 3.0 - americium fluorides Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

REPRODUCTION Summary: Tritium Uranium Z34 Americium Z41 Cesium i37 Radium ZZ6 Strontium 90 Chloride Fluoride Nit rate Dissolved... Alpha (unidentified) Beta (Unidentified)...

488

E-Print Network 3.0 - acetophenone Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Carolina at Chapel Hill Collection: Physics 71 Photopatterned conjugated polymer electrochromic nanofibers Arvind Kumara Summary: -phenyl-acetophenone (DMPAP), ferric chloride...

489

Remedial Action Plan and Site Design for Stabilization of the Inactive Uranium Mill Tailings Site, Maybell, Colorado. Appendixes to Attachment 3: Appendix A, Hydrological services calculations: Appendix B, Ground water quality by location, Final report  

SciTech Connect (OSTI)

This report contains chemical analysis data for ground water for the following: elements; cyanides; chlorides; dissolved organic carbon; fluorides; silica; sulfates; sulfides; dissolved solids; nitrates; and nitrites.

Not Available

1994-06-01T23:59:59.000Z

490

E-Print Network 3.0 - allyl glycidyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 15 () Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane Summary: ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

491

A Summary of Tissue Lesions in Aquatic Animals Induced by Controlled Exposures to Environmental Contaminants,  

E-Print Network [OSTI]

AsO,) Zinc chloride (ZnCI,) Zinc sulphate (ZnSO,) Acrolein Amitrole-T Atrazine Dinoseb Diquat Hydrothol 191

492

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

493

RADIOACTIVE HIGH LEVEL WASTE TANK PITTING PREDICTIONS: AN INVESTIGATION INTO CRITICAL SOLUTION CONCENTRATIONS  

SciTech Connect (OSTI)

A series of cyclic potentiodynamic polarization tests was performed on samples of ASTM A537 carbon steel in support of a probability-based approach to evaluate the effect of chloride and sulfate on corrosion the steel?s susceptibility to pitting corrosion. Testing solutions were chosen to systemically evaluate the influence of the secondary aggressive species, chloride, and sulfate, in the nitrate based, high-level wastes. The results suggest that evaluating the combined effect of all aggressive species, nitrate, chloride, and sulfate, provides a consistent response for determining corrosion susceptibility. The results of this work emphasize the importance for not only nitrate concentration limits, but also chloride and sulfate concentration limits.

Hoffman, E.

2012-11-08T23:59:59.000Z

494

E-Print Network 3.0 - acid ammonium phosphate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Corrosive - base NH4OAc Ammonium acetate Irritant PBS Phosphate buffered saline PEG Polyethylene... Calcium chloride Irritant CAPS 3-(Cyclohexylamino)-1-propanesulfonic acid...

495

E-Print Network 3.0 - acetic acid production Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in methyl chloride production is reported. Acetic acid was produced from... of polyethylene terephthalate (PET) 11. Nowadays more than 60% of the industrial production of...

496

E-Print Network 3.0 - american thermoplastic extruder Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of pounds, dry weight basis) Major... selected thermoplastic resins: Low-Density Polyethylene Polyvinyl Chloride Linear-Low-Density Polyethylene... -Acrylonitrile Polystyrene...

497

E-Print Network 3.0 - acid allied chemical Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ABBREVIATION KEY ABBREVIATION CHEMICAL NAME HAZARDS BPB Bromophenol blue Harmful CaCl2... Calcium chloride Irritant CAPS 3-(Cyclohexylamino)-1-propanesulfonic acid Irritant...

498

Irrigation Water Quality Salinity Management  

E-Print Network [OSTI]

Na2SO4 Moderate to large Calcium chloride CaCl2 Moderate Calcium sulfate (gypsum) CaSO4 2H2O Moderate

499

E-Print Network 3.0 - acid induced chemical Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ABBREVIATION KEY ABBREVIATION CHEMICAL NAME HAZARDS BPB Bromophenol blue Harmful CaCl2... Calcium chloride Irritant CAPS 3-(Cyclohexylamino)-1-propanesulfonic acid Irritant...

500

Modeling of interaction between corrosion-induced concrete cover crack and steel corrosion rate.  

E-Print Network [OSTI]

??Chloride-induced corrosion of steel reinforcement in concrete may cause severe damage to RC structures. Longitudinal cover cracks may form during the rust expansion process. Currently,… (more)

Cao, Chong

2012-01-01T23:59:59.000Z