National Library of Energy BETA

Sample records for 3 12 1979-2011

  1. 0%12*#$3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ")*+ ,)+-'.%*0%12*3" ""%&'"()*%(&+',-&.0,,123 )456%"&,&,(**6%,&(%)5"(&65&7("&-"6()'"-"%( ""%&'()'*+,+-'.'01234-'5637 ,'"8',9'' 8)%*"...

  2. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 12.3.1 Print Tuesday, 20 October 2009 09:33 Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE...

  3. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12.3.1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source...

  4. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.1 Beamline 12.3.1 Print Tuesday, 20 October 2009 09:33 Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated

  5. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Beamline 12.3.1 Print Tuesday, 20 October 2009 09:33 Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated

  6. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.3.2 Beamline 12.3.2 Print Tuesday, 20 October 2009 09:34 Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000

  7. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Beamline 12.3.2 Print Tuesday, 20 October 2009 09:34 Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors

  8. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for small samples with flux reduced to 1% and 12%, respectively. 120 m x 120 m Gaussian uncollimated beam shape at sample. Scientific discipline Structural biology...

  9. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  10. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  11. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  12. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  13. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  14. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics Superbend Energy range 5-17 keV (1% max flux) Frequency range 2.5-0.73 Angstrom wavelength Beam size 100 µm round beam default 10 µm and 30 µm collimators available for small samples with flux reduced to 1% and 12%, respectively. 120 µm x 120 µm Gaussian uncollimated beam shape at sample. Scientific discipline

  15. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics...

  16. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  17. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  18. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  19. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  20. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  1. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  2. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  3. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  4. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Microdiffraction Scientific disciplines: Materials, earth and environmental sciences GENERAL BEAMLINE INFORMATION Operational Now Source characteristics Superbend magnet Energy range 6-22 keV Frequency range 2.1-0.56 Ångström wavelength Monochromator White light and monochromatic [four-bounce Si(111)] Calculated flux (1.9 GeV, 400 mA) Typically 8.5 keV: 1 x 109 photons/s/µm2/3x10-4BW (1 x 1 µm spot) Resolving power (E/ΔE) 7000 Detectors Dectris Pilatus 1M Pixel detector, Silicon

  5. Saltstone 3QCY12 TCLP Results

    SciTech Connect (OSTI)

    Eibling, R. E.

    2012-12-19

    A Saltstone waste form was prepared in the Savannah River National Laboratory (SRNL) from a Tank 50H sample and Z-Area premix material for the third quarter of calendar year 2012 (3QCY12). After a 34 day cure, samples of the saltstone were collected, and the waste form was shown to meet the South Carolina Hazardous Waste Management Regulations (SCHWMR) R.61-79.261.24 and R.61-79.268.48(a) requirements for a nonhazardous waste form with respect to RCRA metals and underlying hazardous constituents. These analyses met all quality assurance specifications of USEPA SW-846.

  6. Y-12 Beta-3 Racetracks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Y-12 Beta-3 Racetracks Y-12 Beta-3 Racetracks Y-12 Beta-3 Racetracks Built near the northeastern end of the Oak Ridge reservation, the Y-12 facility used the electromagnetic method to separate uranium-235 from the uranium-238 in natural uranium. During the Manhattan Project, Y-12 housed nine Alpha and eight Beta racetracks, which were arrangements of huge electromagnets containing a number of calutrons in the magnets' gaps. The calutrons sent a stream of charged particles through the magnetic

  7. DOE Final Report 3-28-12

    Office of Scientific and Technical Information (OSTI)

    These emissions are comparable to unfiltered coal combustion ... reduce their annual CO2 emissions by 1.3 x 106 tonsyr. ... need to store and transport glycerol out of their plants. ...

  8. Categorical Exclusion Determinations: B3.12 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Categorical Exclusion Determinations: B3.12 Existing Regulations B3.12: Microbiological and biomedical facilities Siting, construction, modification, operation, and decommissioning of microbiological and biomedical diagnostic, treatment and research facilities (excluding Biosafety Level-3 and Biosafety Level-4), in accordance with applicable requirements and best practices (such as Biosafety in Microbiological and Biomedical Laboratories, 5th Edition, Dec. 2009, U.S. Department of Health and

  9. Y-12 and some leaders in 1980s, part 3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Continuing with the mercury contamination at Y-12 and three of the leaders who had responsibility for addressing the issue in the 1980s, this final installment will conclude the...

  10. Official Foreign Travel (3-2-12) (Informational Purposes Only)

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-03-12

    This draft directive is scheduled for review by the Directives Review Board on 3/15/12. Any questions, comments, or concerns with the proposed directive can be sent to your Directives Review Board representative (https://www.directives.doe.gov/references/directives-review-board-members) through your Directives Point of Contact (https://www.directives.doe.gov/development-review/dpc-corner/2010-10-1.pdf).

  11. updated_supplemental_lists_1j-2j-3i_12-22-2011.xlsx | Department...

    Energy Savers [EERE]

    j-2j-3i12-22-2011.xlsx updatedsupplementallists1j-2j-3i12-22-2011.xlsx File updatedsupplementallists1j-2j-3i12-22-2011.xlsx More Documents & Publications...

  12. 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Beta-Decays Diagram 12Be(β-)12B Evaluated Data 12B(β-)12C Evaluated Data 12N(β+)12C Evaluated Data Back to Ground-State Decays Data Main Page Back to Datacomp Home Page Last modified: 20

  13. WPN 12-3: Closeout Procedures for Recovery Act Grants Under the...

    Energy Savers [EERE]

    WPN 12-3: Closeout Procedures for Recovery Act Grants Under the Weatherization Assistance Program WPN 12-3: Closeout Procedures for Recovery Act Grants Under the Weatherization...

  14. Y-12s Environment, Safety and Health history part 3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    control of occupational safety and health hazards and the development, implementation and continuous improvement of their safety and health management system." Y-12 achieved the...

  15. Quality at Y-12, part 3 -- Or: Quality goes beyond nuclear weapons...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quality at Y-12, part 3 Or: Quality goes beyond nuclear weapons (title as it appeared in The Oak Ridger) As we continue our look at the history of Quality at Y-12, Bud Leete, Y-12 ...

  16. DOE G 413.3-12 PDRI v02 | Department of Energy

    Office of Environmental Management (EM)

    G 413.3-12 PDRI v02 DOE G 413.3-12 PDRI v02 File This DOE G 413.3-12 tool is similar to DOE G 413.3-19, Chg 1. More Documents & Publications Project Definition Rating Index (PDRI)...

  17. Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Mirant: Case 67a: Units 3 & 4 & 5 at Max Load for 12 hours and at Min Load for 12 hours Docket No. ...

  18. Y-12 Work for Others ? a historical perspective, part 3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Complex has remained the support of the nation's nuclear weapons program for its entire history. This fact is well understood by all, and those who are familiar with Y-12 know...

  19. Spectral properties of a novel laser crystal Y3(In,Ga)2Ga3O12:Cr(3+)--translation

    SciTech Connect (OSTI)

    Li, Y.; Tang, H.; Hang, Y.; Chen, S.

    1991-11-19

    Spectral properties of a novel phonon terminated laser crystal Yttrium(3)(Indium, Gallium)(2)Gallium(3)Oxygen(12): Chromium(3+) grown by the flux method are reported for the first time. The results show that the spectral properties of this novel crystal are compatible with those of Gadolinium(3)(Selenium, Gallium)(3)Gallium(3)Oxygen(12): Chromium(3+) and is a potential ambient temperature tunable laser crystal. Gadolinium(3)(Scandium, Gallium)(2)Gallium(3)Oxygen(12): Chromium(3+) (shortened to GSGG:CR3+) is a type of phonon-terminated laser crystal with excellent capabilities. It has a relatively weak crystal field and relatively strong electron-phonon coupling. At room temperatures a strong terminal phonon emission spectrum with a half width of about 100 nm can be observed. At the same time, experimentally at room temperatures, a wide band continuous tunable laser emission has been observed. Since it has been reported, a great deal of attention has been paid to it. However, since Scandium is rare and expensive its applications are limited.

  20. TTG Call 3-12-08 Final summary

    Office of Environmental Management (EM)

    TEC Tribal Topic Group Conference Call March 12, 2008 Call Lead: Julie Offner (U.S. Department of Energy/Office of Civilian Radioactive Waste Management/Office of Logistics Management, DOE/OCRWM/OLM) Other Participants: Tom Bailor (Confederated Tribes of the Umatilla Indian Reservation, CTUIR), Catherine Bohan (DOE/West Valley Demonstration Project, WVDP), Mike Coplin (Chickasaw Nation), Brad Frazier (Prairie Island Indian Community), Sydney Gieser (Booz Allen Hamilton, BAH), Elizabeth Helvey

  1. Process for the preparation of protected 3-amino-1,2-dihydroxypropane acetal and derivatives thereof

    DOE Patents [OSTI]

    Hollingsworth, Rawle I.; Wang, Guijun

    2000-01-01

    A process for producing protected 3-amino-1,2-dihydroxypropane acetal, particularly in chiral forms, for use as an intermediate in the preparation of various 3-carbon compounds which are chiral. In particular, the present invention relates to the process for preparation of 3-amino-1,2-dihydroxypropane isopropylidene acetal. The protected 3-amino-1,2-dihydroxypropane acetal is a key intermediate to the preparation of chiral 3-carbon compounds which in turn are intermediates to various pharmaceuticals.

  2. Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Citrix_2FA_Authentication_12_3_2009.doc Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc Microsoft Word - Citrix_2FA_Authentication_12_3_2009.doc (453.3 KB) More Documents & Publications Citrix_2FA_Authentication_09.09 Using Two-Factor RSA Token with WebVPN User guide for remote access to VDI and Workplace using RSA token

  3. FY12 Quarter 3 Computing Utilization Report LANL

    SciTech Connect (OSTI)

    Wampler, Cheryl L. [Los Alamos National Laboratory; McClellan, Laura Ann [Los Alamos National Laboratory

    2012-07-25

    DSW continues to dominate the capacity workload, with a focus in Q3 on common model baselining runs in preparation for the Annual Assessment Review (AAR) of the weapon systems. There remains unmet demand for higher fidelity simulations, and for increased throughput of simulations. Common model baselining activities would benefit from doubling the resolution of the models and running twice as many simulations. Capacity systems were also utilized during the quarter to prepare for upcoming Level 2 milestones. Other notable DSW activities include validation of new physics models and safety studies. The safety team used the capacity resources extensively for projects involving 3D computer simulations for the Furrow series of experiments at DARHT (a Level 2 milestone), fragment impact, surety theme, PANTEX assessments, and the 120-day study. With the more than tripling of classified capacity computing resources with the addition of the Luna system and the safety team's imminent access to the Cielo system, demand has been met for current needs. The safety team has performed successful scaling studies on Luna up to 16K PE size-jobs with linear scaling, running the large 3D simulations required for the analysis of Furrow. They will be investigating scaling studies on the Cielo system with the Lustre file system in Q4. Overall average capacity utilization was impacted by negative effects of the LANL Voluntary Separation Program (VSP) at the beginning of Q3, in which programmatic staffing was reduced by 6%, with further losses due to management backfills and attrition, resulting in about 10% fewer users. All classified systems were impacted in April by a planned 2 day red network outage. ASC capacity workload continues to focus on code development, regression testing, and verification and validation (V&V) studies. Significant capacity cycles were used in preparation for a JOWOG in May and several upcoming L2 milestones due in Q4. A network transition has been underway on the

  4. Microsoft Word - S09514_3Q12.docx

    Office of Legacy Management (LM)

    2 January 2013 LMS/RFS/S09514 This page intentionally left blank LMS/RFS/S09514 U.S. Department of Energy Office of Legacy Management Rocky Flats, Colorado, Site Quarterly Report of Site Surveillance and Maintenance Activities Third Quarter Calendar Year 2012 January 2013 This page intentionally left blank U.S. Department of Energy Rocky Flats Site Quarterly Report of Site Surveillance and Maintenance Activities-3rd Quarter CY 2012 January 2013 Doc. No. S09514 Page i Contents Abbreviations

  5. Subtask 3.12 - Oxygen-Fired CFBC

    SciTech Connect (OSTI)

    Douglas Hajicek; Mark Musich; Ann Henderson

    2007-02-28

    the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

  6. R&D Ex A (Rev. 3.3, 12/15/14) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 12/15/14) Exhibit A General Conditions Page 1 of 20 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  7. Nevada Bureau of Mines and Geology Open-File Report 12-3: Data...

    Open Energy Info (EERE)

    2012 Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Nevada Bureau of Mines and Geology Open-File Report 12-3: Data Tables and graphs of geothermal power...

  8. IDIQ BS Ex A (Rev. 3.4, 12/15/14) Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 12/15/14) Exhibit A General Conditions Page 1 of 20 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) ......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ....... 3 GC-3 INDEPENDENT CONTRACTOR (Jun 2009) ............................................................................ 4 GC-4 SUBCONTRACT INTERPRETATION (Jun

  9. In Vitro Metabolism and Stability of the Actinide Chelating Agent 3,4,3-LI(1,2-HOPO)

    SciTech Connect (OSTI)

    Choi, Taylor A.; Furimsky, Anna M.; Swezey, Robert; Bunin, Deborah I.; Byrge, Patricia; Iyer, Lalitha V.; Chang, Polly Y.; Abergel, Rebecca J.

    2015-02-27

    We report that the hydroxypyridinonate ligand 3,4,3-LI(1,2-HOPO) is currently under development for radionuclide chelation therapy. The preclinical characterization of this highly promising ligand comprised the evaluation of its in vitro properties, including microsomal, plasma, and gastrointestinal fluid stability, cytochrome P450 inhibition, plasma protein binding, and intestinal absorption using the Caco-2 cell line. When mixed with active human liver microsomes, no loss of parent compound was observed after 60 minutes, indicating compound stability in the presence of liver microsomal P450. At the tested concentrations, 3,4,3-LI(1,2-HOPO) did not significantly influence the activities of any of the cytochromal isoforms screened. Thus, 3,4,3-LI(1,2-HOPO) is unlikely to cause drug-drug interactions by inhibiting the metabolic clearance of co-administered drugs metabolized by these enzymes. Plasma protein binding assays revealed that the compound is protein-bound in dogs and less extensively in rats and humans. In the plasma stability study, the compound was stable after 1 h at 37°C in mouse, rat, dog, and human plasma samples. Finally, a bi-directional permeability assay demonstrated that 3,4,3-LI(1,2-HOPO) is not permeable across the Caco-2 monolayer, highlighting the need to further evaluate the effects of various compounds with known permeability enhancement properties on the permeability of the ligand in future studies.

  10. In Vitro Metabolism and Stability of the Actinide Chelating Agent 3,4,3-LI(1,2-HOPO)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Taylor A.; Furimsky, Anna M.; Swezey, Robert; Bunin, Deborah I.; Byrge, Patricia; Iyer, Lalitha V.; Chang, Polly Y.; Abergel, Rebecca J.

    2015-02-27

    We report that the hydroxypyridinonate ligand 3,4,3-LI(1,2-HOPO) is currently under development for radionuclide chelation therapy. The preclinical characterization of this highly promising ligand comprised the evaluation of its in vitro properties, including microsomal, plasma, and gastrointestinal fluid stability, cytochrome P450 inhibition, plasma protein binding, and intestinal absorption using the Caco-2 cell line. When mixed with active human liver microsomes, no loss of parent compound was observed after 60 minutes, indicating compound stability in the presence of liver microsomal P450. At the tested concentrations, 3,4,3-LI(1,2-HOPO) did not significantly influence the activities of any of the cytochromal isoforms screened. Thus, 3,4,3-LI(1,2-HOPO) ismore » unlikely to cause drug-drug interactions by inhibiting the metabolic clearance of co-administered drugs metabolized by these enzymes. Plasma protein binding assays revealed that the compound is protein-bound in dogs and less extensively in rats and humans. In the plasma stability study, the compound was stable after 1 h at 37°C in mouse, rat, dog, and human plasma samples. Finally, a bi-directional permeability assay demonstrated that 3,4,3-LI(1,2-HOPO) is not permeable across the Caco-2 monolayer, highlighting the need to further evaluate the effects of various compounds with known permeability enhancement properties on the permeability of the ligand in future studies.« less

  11. Jefferson Lab Awards $3.54 Million Contract To Pennsylvania Firm for 12 GeV

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project | Jefferson Lab 3.54 Million Contract To Pennsylvania Firm for 12 GeV Project Jefferson Lab Awards $3.54 Million Contract To Pennsylvania Firm for 12 GeV Project NEWPORT NEWS, Va., May 1, 2009 - A Pennsylvania company has been awarded a $3.54 million contract to provide 84 klystrons to the U.S. Department of Energy's Thomas Jefferson National Accelerator Facility. The 13 kW klystrons, devices which will generate the electromagnetic fields that will accelerate the CEBAF electron

  12. Lattice Effective Field Theory Calculations for A=3, 4, 6, 12 Nuclei

    SciTech Connect (OSTI)

    Epelbaum, Evgeny; Krebs, Hermann; Lee, Dean; Meissner, Ulf-G.

    2010-04-09

    We present lattice results for the ground state energies of tritium, helium-3, helium-4, lithium-6, and carbon-12 nuclei. Our analysis includes isospin breaking, Coulomb effects, and interactions up to next-to-next-to-leading order in chiral effective field theory.

  13. Application of the explicitly correlated coupled-cluster models CCSD(F12*) and CC3(F12*) to the hyperpolarizability of the Ne atom

    SciTech Connect (OSTI)

    Hanauer, Matthias; Khn, Andreas

    2015-01-22

    This work demonstrates the performance of the recently proposed explicitly correlated coupled-cluster method CCSD(F12*) and a new method using explicitly correlated triple excitations, CC3(F12*), in the calculation of the static ESHG hyperpolarizability of the Ne atom.

  14. High Schottky barrier at grain boundaries observed in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics

    SciTech Connect (OSTI)

    Somphan, Weeraya; Thongbai, Prasit; Yamwong, Teerapon; Maensiri, Santi

    2013-10-15

    Graphical abstract: - Highlights: NSCTO exhibits a high ?? of 7.08.4 10{sup 3} and low tan ? of 0.0300.041. NSCTO exhibits a high E{sub b} of ?2208 V cm{sup ?1} and large ? of 15.6. Giant ?? response is attributed to the electrically heterogeneous microstructure. High ?{sub b} values at grain boundaries are found to be 0.9250.964 eV. Formation of a potential barrier at grain boundaries is caused by Schottky effect. - Abstract: The dielectric properties and nonlinear currentvoltage characteristics of Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics prepared by a conventional solid state reaction method were investigated. Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics exhibited a high dielectric permittivity of 7.08.4 10{sup 3} and low loss tangent (tan ??0.0300.041). Non-Ohmic properties with a high breakdown voltage of ?2208 V cm{sup ?1} and large nonlinear coefficient of 15.6 were observed in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics. Using complex impedance analysis, Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics were shown to be electrically heterogeneous consisting of semiconducting grains and insulating grain boundaries. Giant dielectric properties were described based on the electrically heterogeneous microstructure. X-ray photoelectron spectroscopy analysis suggested that the semiconductive nature of grains may be related to the presence of Cu{sup +} and Ti{sup 3+}. The formation of an electrostatic potential barrier at the grain boundaries of Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics was suggested to be caused by the Schottky effect. Interestingly, high electrostatic potential barriers at grain boundaries in Na{sub 1/2}Sm{sub 1/2}Cu{sub 3}Ti{sub 4}O{sub 12} ceramics were calculated and found to be 0.9250.964 eV.

  15. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore »diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  16. Role of Ce4+ in the scintillation mechanism of codoped Gd3Ga3Al2O12:Ce

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Yuntao; Meng, Fang; Li, Qi; Koschan, Merry; Melcher, Charles L.

    2014-10-17

    To control the time-response performance of widely used cerium-activated scintillators in cutting-edge medical-imaging devices, such as time-of-flight positron-emission tomography, a comprehensive understanding of the role of Ce valence states, especially stable Ce4+, in the scintillation mechanism is essential. However, despite some progress made recently, an understanding of the physical processes involving Ce4+ is still lacking. The aim of this work is to clarify the role of Ce4+ in scintillators by studying Ca2+ codoped Gd3Ga3Al2O12∶Ce (GGAG∶Ce). By using a combination of optical absorption spectra and x-ray absorption near-edge spectroscopies, the correlation between Ca2+codoping content and the Ce4+ fraction is seen. The energy-levelmore » diagrams of Ce3+ and Ce4+ in the Gd3Ga3Al2O12 host are established by using theoretical and experimental methods, which indicate a higher position of the 5d1 state of Ce4+ in the forbidden gap in comparison to that of Ce3+. Underlying reasons for the decay-time acceleration resulting from Ca2+ codoping are revealed, and the physical processes of the Ce4+-emission model are proposed and further demonstrated by temperature-dependent radioluminescence spectra under x-ray excitation.« less

  17. Department of Energy Personal Property Management Program (3-7-12) (Informational Purposes Only)

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2012-03-12

    This draft directive is scheduled for review by the Directives Review Board on 3/15/12. Any questions, comments, or concerns with the proposed directive can be sent to your Directives Review Board representative (https://www.directives.doe.gov/references/directives-review-board-members) through your Directives Point of Contact (https://www.directives.doe.gov/development-review/dpc-corner/2010-10-1.pdf).

  18. PDSF Users Meeting 12/3/13 at 11:15 am

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2/3/13 at 11:15 am PDSF Users Meeting 12/3/13 at 11:15 am November 20, 2013 The PDSF Users' meeting will be held in room 50B-2222. Come join us! Subscribe via RSS Subscribe Browse by Date February 2014 January 2014 November 2013 October 2013 September 2013 August 2013 March 2012 February 2012 January 2012 October 2011 July 2011 May 2011 April 2011 March 2011 February 2011 January 2011 December 2010 Last edited: 2013-11-20 17:46:10

  19. 3-16-12-signed-BAC-Final-EA-FONSI.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Goals | Department of Energy 3 Ways Solar Energy Programs Are Helping Achieve President Obama's Climate Goals 3 Ways Solar Energy Programs Are Helping Achieve President Obama's Climate Goals September 8, 2015 - 12:36pm Addthis Minh Le Minh Le Deputy Director, Solar Energy Technologies Office Since President Obama took office in 2009, U.S. solar energy capacity has grown more than twenty-fold. And solar stands to grow even more -- with renewable energy capacity in the U.S. slated to

  20. Microsoft PowerPoint - Subregion 3 Presentation 5-12-09.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Southwest Power Pool Sub-Regional Planning Meeting Sub-Regional Area 3 David Sargent May 12, 2009 Southwestern Power Administration Slide 2 Southwestern Power Administration Slide 3 Five Year Construction Plan 2009 Bull Shoals Dam Bus Upgrade - from 600 to 1200/2000 amps The bus is a limiting element for the line going from Bull Shoals toward Harrison. New Madrid 161/69 kV Autotransformer Replacement New Madrid-Malden-Piggott-Kennett 69 kV Line Rebuild - 55 miles of line collapsed during an ice

  1. Strain tuning of electronic structure in Bi4Ti3O12-LaCoO3 epitaxial thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Woo Seok; Lee, Ho Nyung

    2015-05-08

    In this study, we investigated the crystal and electronic structures of ferroelectric Bi4Ti3O12 single-crystalline thin films site-specifically substituted with LaCoO3 (LCO). The epitaxial films were grown by pulsed laser epitaxy on NdGaO3 and SrTiO3 substrates to vary the degree of strain. With increasing the LCO substitution, we observed a systematic increase in the c-axis lattice constant of the Aurivillius phase related with the modification of pseudo-orthorhombic unit cells. These compositional and structural changes resulted in a systematic decrease in the band gap, i.e., the optical transition energy between the oxygen 2p and transition-metal 3d states, based on a spectroscopic ellipsometrymore » study. In particular, the Co 3d state seems to largely overlap with the Ti t2g state, decreasing the band gap. Interestingly, the applied tensile strain facilitates the band-gap narrowing, demonstrating that epitaxial strain is a useful tool to tune the electronic structure of ferroelectric transition-metal oxides.« less

  2. Wnt/{beta}-catenin signaling changes C2C12 myoblast proliferation and differentiation by inducing Id3 expression

    SciTech Connect (OSTI)

    Zhang, Long; Shi, Songting; Zhang, Juan; Zhou, Fangfang; Dijke, Peter ten

    2012-03-02

    Highlights: Black-Right-Pointing-Pointer Expression of Id3 but not Id1 is induced by Wnt3a stimulation in C2C12 cells. Black-Right-Pointing-Pointer Wnt3a induces Id3 expression via canonical Wnt/{beta}-catenin pathway. Black-Right-Pointing-Pointer Wnt3a-induced Id3 expression does not depend on BMP signaling activation. Black-Right-Pointing-Pointer Induction of Id3 expression is critical determinant in Wnt3a-induced cell proliferation and differentiation. -- Abstract: Canonical Wnt signaling plays important roles in regulating cell proliferation and differentiation. In this study, we report that inhibitor of differentiation (Id)3 is a Wnt-inducible gene in mouse C2C12 myoblasts. Wnt3a induced Id3 expression in a {beta}-catenin-dependent manner. Bone morphogenetic protein (BMP) also potently induced Id3 expression. However, Wnt-induced Id3 expression occurred independent of the BMP/Smad pathway. Functional studies showed that Id3 depletion in C2C12 cells impaired Wnt3a-induced cell proliferation and alkaline phosphatase activity, an early marker of osteoblast cells. Id3 depletion elevated myogenin induction during myogenic differentiation and partially impaired Wnt3a suppressed myogenin expression in C2C12 cells. These results suggest that Id3 is an important Wnt/{beta}-catenin induced gene in myoblast cell fate determination.

  3. Spin-phonon coupling in Gd(Co{sub 1/2}Mn{sub 1/2})O{sub 3} perovskite

    SciTech Connect (OSTI)

    Silva, R. X.; Reichlova, H.; Marti, X.; Barbosa, D. A. B.; Lufaso, M. W.; Araujo, B. S.; Ayala, A. P.; and others

    2013-11-21

    We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co{sub 1/2}Mn{sub 1/2})O{sub 3} perovskite ceramics in the temperature range from 40?K to 300?K. The samples crystallized in an orthorhombic distorted simple perovskite, whose symmetry belongs to the Pnma space group. The data reveal spin-phonon coupling near the ferromagnetic transition occurring at around 120?K. The correlation of the Raman and magnetization data suggests that the structural order influences the magnitude of the spin-phonon coupling.

  4. Modeling Volatile Species Retention Experiments: Interim Progress Report (M3FT-12LA0202053)

    SciTech Connect (OSTI)

    Carlson, Neil N. [Los Alamos National Laboratory

    2012-07-06

    Metal nuclear fuel is a candidate transmutation fuel form for advanced fuel cycles. One constituent of the fuel, americium, has a high vapor pressure, and there is a concern that excessive volatility losses of americium will occur during casting of the metal. A number of experiments have been performed using americium and surrogate metals, including experiments slated for FY12, to address the concern. The present task is to model and numerically simulate these experiments. This report describes a system-level model of the relevant experiments that has been developed together with some results. It also describes some initial 3D, full-physics simulations of portions of the experiments that have been performed.

  5. Exoplanet transit spectroscopy using WFC3: WASP-12 b, WASP-17 b, and WASP-19 b

    SciTech Connect (OSTI)

    Mandell, Avi M.; Haynes, Korey; Sinukoff, Evan; Madhusudhan, Nikku; Burrows, Adam; Deming, Drake

    2013-12-20

    We report an analysis of transit spectroscopy of the extrasolar planets WASP-12 b, WASP-17 b, and WASP-19 b using the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST). We analyze the data for a single transit for each planet using a strategy similar, in certain aspects, to the techniques used by Berta et al., but we extend their methodology to allow us to correct for channel- or wavelength-dependent instrumental effects by utilizing the band-integrated time series and measurements of the drift of the spectrum on the detector over time. We achieve almost photon-limited results for individual spectral bins, but the uncertainties in the transit depth for the band-integrated data are exacerbated by the uneven sampling of the light curve imposed by the orbital phasing of HST's observations. Our final transit spectra for all three objects are consistent with the presence of a broad absorption feature at 1.4 ?m most likely due to water. However, the amplitude of the absorption is less than that expected based on previous observations with Spitzer, possibly due to hazes absorbing in the NIR or non-solar compositions. The degeneracy of models with different compositions and temperature structures combined with the low amplitude of any features in the data preclude our ability to place unambiguous constraints on the atmospheric composition without additional observations with WFC3 to improve the signal-to-noise ratio and/or a comprehensive multi-wavelength analysis.

  6. Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Verde, Michael G.; Liu, Haodong; Carroll, Kyler J.; Baggetto, Loïc; Veith, Gabriel M.; Meng, Y. Shirley

    2014-10-02

    We have determined the electrochemical characteristics of the high voltage, high capacity Li-ion battery cathode material Li[Li 2/12Ni3/12Mn7/12]O2 prepared using three different synthesis routes: sol-gel, hydroxide co-precipitation, and carbonate co-precipitation. Each route leads to distinct morphologies and surface areas while maintaining the same crystal structures. X-ray photoelectron spectroscopy (XPS) measurements reveal differences in their surface chemistries upon cycling, which correlate with voltage fading. As expected, we observed the valence state of Mn on the surface to decrease upon lithiation, and this reduction is specifically correlated to discharging below 3.6V. Furthermore, the data shows a correlation of the formation of Li2CO3more » with Mn oxidation state from the« less

  7. Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(trans-dpmn) and 1,2-Os3(CO)10(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os3(CO)10(dpmn) and Isomer-Dependent Diphosphine Ligand Activation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Li; Nesterov, Vladimir N.; Wang, Xiaoping; Richmond, Michael G.

    2014-07-23

    The bicyclic diphosphines trans- and cis-2,3-bis(diphenylphosphinomethyl)-5-norbornene (dpmn) react with 1,2-Os3(CO)10(MeCN)2 (1) to furnish the corresponding ligand-bridged clusters Os3(CO)10(trans-dpmn) (2) and Os3(CO)10(cis-dpmn) (3). Both new products have been isolated and the molecular structures established by X-ray diffraction analyses. The dihydroxyl-bridged cluster 1,2-Os3(CO)8(μ-OH)2(cis-dpmn) (4), which accompanied the formation of 3 in one reaction, has been isolated and characterized by mass spectrometry and X-ray crystallography. Whereas cluster 2 is stable in toluene at 373 K, 3 is thermally sensitive under identical conditions and undergoes loss of CO (2 equiv), coupled with the activation of three norbornene C-H bonds and one P-C(phenyl) bond, tomore » furnish the dihydride cluster H2Os3(CO)8[μ3-2-PhPC-3-endo-Ph2PCH2(C7H7)] (5). The solid-state structure of 5 confirms the multiple activation of the cis-dpmn ligand and accompanying formation of the face-capping 2-PhPC-3-endo-Ph2PCH2(C7H7) moiety in the product. DFT calculations on 2 and 3 indicate that the former cluster is the thermodynamically more stable isomer, and the conversion of 3→ 5 + 2CO + benzene is computed to be exergonic by 12.7 kcal/mol and is entropically favored due to the release of the CO and benzene by-products.« less

  8. Structure and Stoichiometry in Supervalent Doped Li7La3 Zr2O12

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mukhopadhyay, Saikat; Thompson, Travis; Sakamoto, Jeff; Huq, Ashfia; Wolfenstine, Jeff; Allen, Jan L.; Bernstein, Noam; Stewart, Derek A.; Johannes, M. D.

    2015-04-20

    The oxide garnet material Li7La3 Zr2O12 shows remarkably high ionic conductivity when doped with supervalent ions that are charge compensated by Li vacancies and is currently one of the best candidates for development of a technologically relevant solid electrolyte. Determination of optimal dopant concentration, however, has remained a persistent problem due to the extreme difficulty of establishing the actual (as compared to nominal) stoichiometry of intentionally doped materials and by the fact that it is still not entirely clear what level of lattice expansion/contraction best promotes. ionic diffusion. By combining careful synthesis, neutron diffraction, high-resolution X-ray diffraction (XRD), Raman measurements,more » and density functional theory calculations, we show that structure and stoichiometry are intimately related such that the former can in many cases be used as a gauge of the latter. We show that different Li-vacancy creating supervalent ions (Al3+ vs Ta5+) affect the structure very differently, both in terms of the lattice constant, which is easily measurable, and hi terms of the local structure, which can be difficult or impossible to access experimentally but may have important ramifications for conduction. We carefully correlate the lattice constant to dopant type/concentration via Vegard's law and then further correlate these quantities to relevant local structural parameters. In conclusion, our work opens the possibility of developing a codopant scheme that optimizes the Li vacancy concentration and the lattice size simultaneously.« less

  9. The nature and role of bridged carbonyl intermediates in theultrafast photo-induced rearrangement of Ru3(CO)12.

    SciTech Connect (OSTI)

    Glascoe, Elizabeth A.; Kling, Matthias F.; Shanoski, Jennifer E.; Harris, Charles B.

    2005-09-18

    The photochemistry of the trimetal cluster,Ru(3)(CO)12, was investigated on the ultrafast timescale using UV-vis pump, infrared probe spectroscopy in order to study the transient intermediates formed upon photoexcitation.

  10. Elastic Properties of the Solid Electrolyte Li7La3Zr2O12 (LLZO)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Seungho; Schmidt, Robert D.; Garcia-mendez, Regina; Herbert, Erik G.; Dudney, Nancy J.; Wolfenstine, Jeff; Sakamoto, Jeff; Seigel, Donald

    2015-12-16

    The oxide known as LLZO, with nominal composition Li7La3Zr2O12, is a promising solid electrolyte for Li-based batteries due to its high Li-ion conductivity and chemical stability with respect to lithium. Solid electrolytes may also enable the use of metallic Li anodes by serving as a physical barrier that suppresses dendrite initiation and propagation during cycling. Prior linear elasticity models of the Li electrode/solid electrolyte interface suggest that the stability of this interface is highly dependent on the elastic properties of the solid separator. For example, dendritic suppression is predicted to be enhanced as the electrolyte s shear modulus increases. Inmore » the present study a combination of first-principles calculations, acoustic impulse excitation measurements, and nanoindentation experiments are used to determine the elastic constants and moduli for highconductivity LLZO compositions based on Al and Ta doping. The calculated and measured isotropic shear moduli are in good agreement and fall within the range of 56-61 GPa. These values are an order of magnitude larger than that for Li metal and far exceed the minimum value ( 8.5 GPa) believed to be necessary to suppress dendrite initiation. These data suggest that LLZO exhibits sufficient stiffness to warrant additional development as a solid electrolyte for Li batteries.« less

  11. Elastic Properties of the Solid Electrolyte Li7La3Zr2O12 (LLZO)

    SciTech Connect (OSTI)

    Yu, Seungho; Schmidt, Robert D.; Garcia-mendez, Regina; Herbert, Erik G.; Dudney, Nancy J.; Wolfenstine, Jeff; Sakamoto, Jeff; Seigel, Donald

    2015-12-16

    The oxide known as LLZO, with nominal composition Li7La3Zr2O12, is a promising solid electrolyte for Li-based batteries due to its high Li-ion conductivity and chemical stability with respect to lithium. Solid electrolytes may also enable the use of metallic Li anodes by serving as a physical barrier that suppresses dendrite initiation and propagation during cycling. Prior linear elasticity models of the Li electrode/solid electrolyte interface suggest that the stability of this interface is highly dependent on the elastic properties of the solid separator. For example, dendritic suppression is predicted to be enhanced as the electrolyte s shear modulus increases. In the present study a combination of first-principles calculations, acoustic impulse excitation measurements, and nanoindentation experiments are used to determine the elastic constants and moduli for highconductivity LLZO compositions based on Al and Ta doping. The calculated and measured isotropic shear moduli are in good agreement and fall within the range of 56-61 GPa. These values are an order of magnitude larger than that for Li metal and far exceed the minimum value ( 8.5 GPa) believed to be necessary to suppress dendrite initiation. These data suggest that LLZO exhibits sufficient stiffness to warrant additional development as a solid electrolyte for Li batteries.

  12. Completion Report for Well ER-12-3 Corrective Action Unit 99: Rainier Mesa - Shoshone Mountain

    SciTech Connect (OSTI)

    U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office; Bechtel Nevada Corporation

    2006-05-01

    Well ER-12-3 was drilled for the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office, in support of the Nevada Environmental Restoration Project at the Nevada Test Site, Nye County, Nevada. The well was drilled in March and April 2005 as part of a hydrogeologic investigation program for the Rainier Mesa-Shoshone Mountain Corrective Action Unit. The overall purpose of the well was to gather subsurface data to better characterize the hydrogeology of central Rainier Mesa, especially in the older Tertiary volcanic rocks and Paleozoic sedimentary rocks. The main 47.0-centimeter hole was drilled to a depth of 799.2 meters and cased with 33.97-centimeter casing to 743.1 meters. The hole diameter was then decreased to 31.1 centimeters, and the well was drilled to a total depth of 1,496.0 meters. The completion string consisted of 13.97-centimeter stainless steel casing, with two slotted intervals open to the lower carbonate aquifer, suspended from 19.37-centimeter carbon steel casing. A piezometer string was installed outside the 33.97-centimeter casing to a depth of 467.1 meters to monitor a zone of perched water within the Tertiary volcanic section. Data gathered during and shortly after hole construction include composite drill cuttings samples collected every 3 meters (extra cuttings samples were collected from the Paleozoic rocks for paleontological analyses), sidewall core samples from 35 depths, various geophysical logs, and water level measurements. These data indicate that the well penetrated 674.2 meters of Tertiary volcanic rocks and 821.7 meters of Paleozoic dolomite and limestone. Forty-nine days after the well was completed, but prior to well development and testing, the water level inside the main hole was tagged at the depth of 949.1 meters, and the water level inside the piezometer string was tagged at 379.9 meters.

  13. Investigations of Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} single crystal as a scintillator

    SciTech Connect (OSTI)

    Zhang, Zhi-Jun; Hu, Guan-Qin; Wang, Hong; Zhu, Lin-Lin; Zhao, Jing-Tai

    2014-04-01

    Highlights: • Eu{sup 2+}-activated Ba{sub 3}BP{sub 3}O{sub 12} single crystals have been grown by the top-seeded solution growth method (TSSG) for the first time. • Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} single crystal exhibits wide transparency in the wavelength range from 250 to 700 nm. • Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} single crystal shows high overall scintillation efficiency (1.8 times of BGO) and moderate decay time (860 ns). - Abstract: Single crystals of Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} with high optical quality have been grown by the top-seeded solution growth (TSSG) method using BPO{sub 4}–NaF mixture as the flux. Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} single crystal exhibits wide transparency in the wavelength range from 250 to 700 nm, and shows a broad emission band in the wavelength range of 350–650 nm when excited by X-ray radiation. The overall scintillation efficiency is about 1.8 times of that of BGO crystal under the same conditions. Its room temperature fluorescence decay curve exhibits a single-exponent shape with decay time of about 860 ns. It is worth noting that Ba{sub 3}BP{sub 3}O{sub 12}:Eu{sup 2+} single crystal may be of great interest for applications in the field of scintillation materials considering its scintillation properties, as well as the good chemical stability.

  14. Local structural distortion and electrical transport properties of Bi(Ni1/2Ti1/2)O3 perovskite under high pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Jinlong; Yang, Liuxiang; Wang, Hsiu -Wen; Zhang, Jianzhong; Yang, Wenge; Hong, Xinguo; Jin, Changqing; Zhao, Yusheng

    2015-12-16

    Perovskite-structure materials generally exhibit local structural distortions that are distinct from long-range, average crystal structure. The characterization of such distortion is critical to understanding the structural and physical properties of materials. In this work, we combined Pair Distribution Function (PDF) technique with Raman spectroscopy and electrical resistivity measurement to study Bi(Ni1/2Ti1/2)O3 perovskite under high pressure. PDF analysis reveals strong local structural distortion at ambient conditions. As pressure increases, the local structure distortions are substantially suppressed and eventually vanish around 4 GPa, leading to concurrent changes in the electronic band structure and anomalies in the electrical resistivity. We find, consistent withmore » PDF analysis, Raman spectroscopy data suggest that the local structure changes to a higher ordered state at pressures above 4 GPa.« less

  15. Microsoft PowerPoint - NEAC CASL Presentation 12-10-14 v3.pptx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * 204 pins per assembly Fuel Pins * 300-400 pellets stacked within 12' high x 0.61 mm thick Zr-4 cladding tube Fuel Pellets * 9.29 mm diameter x 10.0 mm high Fuel ...

  16. Y-12's first Open House - September 2-3, 1967, part 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This was a tremendously interesting telecast that was delayed from its normal time to prime time. A "special exclusive" edition of the Y-12 Bulletin was published that was used...

  17. Octahedral tilt transitions in the relaxor ferroelectric Na{sub 1/2}Bi{sub 1/2}TiO{sub 3}

    SciTech Connect (OSTI)

    Meyer, Kai-Christian Gröting, Melanie; Albe, Karsten

    2015-07-15

    The kinetics of octahedral tilt transitions in the lead-free relaxor material sodium bismuth titanate Na{sub 1/2}Bi{sub 1/2}TiO{sub 3} (NBT) is investigated by electronic structure calculations within density functional theory. Energy barriers for transitions between tetragonal, rhombohedral and orthorhombic tilts in cation configurations with [001]- and [111]-order on the A-sites are determined by nudged elastic band calculations. By tilting entire layers of octahedra simultaneously we find that the activation energy is lower for structures with 001-order compared to such with 111-order. The energetic coupling between differently tilted layers is, however, negligibly small. By introducing a single octahedral defect we create local tilt disorder and find that the deformation energy of the neighboring octahedra is less in a rhombohedral than in a tetragonal structure. By successively increasing the size of clusters of orthorhombic defects in a rhombohedral matrix with 001-order, we determine a critical cluster size of about 40 Å . Thus groups of about ten octahedra can be considered as nuclei for polar nanoregions, which are the cause of the experimentally observed relaxor behavior of NBT. - Graphical abstract: Nine orthorhombic oxygen octahedral tilt defects in a rhombohedral tilt configuration. - Highlights: • Chemical order influences energy barriers of octahedral tilt transitions. • The octahedral deformation energy is lower in rhombohedral phases. • Tilt defect clusters are more likely in rhombohedral structures. • Tilt defect clusters can act as nuclei for polar nanoregions.

  18. Electric-field-induced strain contributions in morphotropic phase boundary composition of (Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-BaTiO{sub 3} during poling

    SciTech Connect (OSTI)

    Khansur, Neamul H.; Daniels, John E.; Hinterstein, Manuel; Wang, Zhiyang; Groh, Claudia; Jo, Wook

    2015-12-14

    The microscopic contributions to the electric-field-induced macroscopic strain in a morphotropic 0.93(Bi{sub 1/2}Na{sub 1/2}TiO{sub 3})−0.07(BaTiO{sub 3}) with a mixed rhombohedral and tetragonal structure have been quantified using full pattern Rietveld refinement of in situ high-energy x-ray diffraction data. The analysis methodology allows a quantification of all strain mechanisms for each phase in a morphotropic composition and is applicable to use in a wide variety of piezoelectric compositions. It is shown that during the poling of this material 24%, 44%, and 32% of the total macroscopic strain is generated from lattice strain, domain switching, and phase transformation strains, respectively. The results also suggest that the tetragonal phase contributes the most to extrinsic domain switching strain, whereas the lattice strain primarily stems from the rhombohedral phase. The analysis also suggests that almost 32% of the total strain is lost or is a one-time effect due to the irreversible nature of the electric-field-induced phase transformation in the current composition. This information is relevant to on-going compositional development strategies to harness the electric-field-induced phase transformation strain of (Bi{sub 1/2}Na{sub 1/2})TiO{sub 3}-based lead-free piezoelectric materials for actuator applications.

  19. Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one

    SciTech Connect (OSTI)

    Wang, G.-F. Gong, Q.-J. Sun, H.; Yao, C-Z.

    2013-12-15

    The title compound, C{sub 30}H{sub 24}N{sub 2}O{sub 4}, 3,3′-[1,2-ethanediyl-bis(oxy-2,1-phenylene)]bis[1-(2-pyridyl) -2-propen-1-one] was synthesized and characterized by elemental analysis, FT-IR spectra, {sup 1}H NMR, and X-ray single-crystal diffraction. In the molecule, the pyridine plane and the adjacent phenyl plane are almost coplanar with the dihedral angle of 3.07°, while the dihedral angle between the mean planes of the two asymmetric units is 67.56°. The crystal packing is stabilized by weak intermolecular C-H...N and C-H...O hydrogen bonds, C-H...π and π...π stacking interactions.

  20. Optimizing white light luminescence in Dy{sup 3+}-doped Lu{sub 3}Ga{sub 5}O{sub 12} nano-garnets

    SciTech Connect (OSTI)

    Haritha, P.; Linganna, K.; Venkatramu, V.; Martn, I. R.; Monteseguro, V.; Rodrguez-Mendoza, U. R.; Babu, P.; Len-Luis, S. F.; Jayasankar, C. K.; Lavn, V.

    2014-11-07

    Trivalent dysprosium-doped Lu{sub 3}Ga{sub 5}O{sub 12} nano-garnets have been prepared by sol-gel method and characterized by X-ray powder diffraction, high-resolution transmission electron microscopy, dynamic light scattering, and laser excited spectroscopy. Under a cw 457?nm laser excitation, the white luminescence properties of Lu{sub 3}Ga{sub 5}O{sub 12} nano-garnets have been studied as a function of the optically active Dy{sup 3+} ion concentration and at low temperature. Decay curves for the {sup 4}F{sub 9/2} level of Dy{sup 3+} ion exhibit non-exponential nature for all the Dy{sup 3+} concentrations, which have been well-fitted to a generalized energy transfer model for a quadrupole-quadrupole interaction between Dy{sup 3+} ions without diffusion. From these data, a simple rate-equations model can be applied to predict that intense white luminescence could be obtained from 1.8?mol% Dy{sup 3+} ions-doped nano-garnets, which is in good agreement with experimental results. Chromaticity color coordinates and correlated color temperatures have been determined as a function of temperature and are found to be within the white light region for all Dy{sup 3+} concentrations. These results indicate that 2.0?mol% Dy{sup 3+} ions doped nano-garnet could be useful for white light emitting device applications.

  1. "Table HC3.12 Home Electronics Usage Indicators by Owner-Occupied...

    U.S. Energy Information Administration (EIA) Indexed Site

    "Personal Computers" "Do Not Use a Personal Computer",35.5,20.3,14.8,1.2,0.6,0.9,2.8 "Use a Personal Computer",75.6,57.8,49.2,2.9,1.2,1.4,3 "Most-Used Personal ...

  2. Synthesis and Luminescence Characteristics of Cr3+ doped Y3Al5O12 Phosphors

    SciTech Connect (OSTI)

    Smith, Brenda A.; Dabestani, Reza T.; Lewis, Linda A.; Thompson, Cyril V.; Collins, Case T.; Aytug, Tolga

    2015-10-01

    Luminescence performance of yttrium aluminum garnet (Y3Al5O12) phosphors as a function of Cr3+ concentration has been investigated via two different wet-chemical synthesis techniques, direct- (DP) and hydrothermal-precipitation (HP). Using either of these methods, the red-emitting phosphor [Y3Al5-xCrxO12 (YAG: Cr3+)] showed similar photoluminescence (PL) intensities once the dopant concentration was optimized. Specifically, the YAG: Cr3+ PL emission intensity reached a maximum at Cr3+ concentrations of x = 0.02 (0.4 at.%) and x = 0.13 (2.6 at.%) for DP and HP processed samples, respectively. The results indicated the strong influence of the processing method on the optimized YAG: Cr3+ performance, where a more effective energy transfer rate between a pair of Cr3+ activators at low concentration levels was observed by using the DP synthesis technique. Development of a highly efficient phosphor, using a facile synthesis approach, could significantly benefit consumer and industrial applications by improving the operational efficiency of a wide range of practical devices.

  3. Microsoft Word - DOE-ID-12-033 Nebraska EC B3-6 B3-10.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 SECTION A. Project Title: Radiation tolerance and mechanical properties of nanostructured ceramic/metal composites - University of Nebraska SECTION B. Project Description This project will consist of studying the ion irradiation and mechanical response of amorphous Si-C-O and Si-Al-C-O alloys, understanding the role of amorphous-ceramic/metal interface on irradiation and mechanical properties, and evaluating structural integrity and overall mechanical performance of the composite under extreme

  4. Microsoft Word - DOE-ID-12-035 BNL EC B3-6 B3-10.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 SECTION A. Project Title: Radiation-induced ductility enhancement in amorphous Fe and Al2O3+TiO2 nanostructured coatings in fast neutron and high temperature environments of next generation reactors - Brookhaven National Laboratory SECTION B. Project Description The effects of fast neutrons on the nanostructured coatings deposited on steel alloy and titanium alloy substrates will be studied with particular focus on ductility restoration and the influence of temperature. Irradiated specimens

  5. Chemical and structural effects on the high-temperature mechanical behavior of (1−x)(Na{sub 1/2}Bi{sub 1/2})TiO{sub 3}-xBaTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Deluca, Marco; Picht, Gunnar; Hoffmann, Michael J.; Rechtenbach, Annett; Töpfer, Jörg; Schader, Florian H.; Webber, Kyle G.

    2015-04-07

    Bismuth sodium titanate–barium titanate [(1−x)(Na{sub 1/2}Bi{sub 1/2})TiO{sub 3}-xBaTiO{sub 3}, NBT-100xBT] is one of the most well studied lead-free piezoelectric materials due in large part to the high field-induced strain attainable in compositions near the morphotropic phase boundary (x = 0.06). The BaTiO{sub 3}-rich side of the phase diagram, however, has not yet been as comprehensively studied, although it might be important for piezoelectric and positive temperature coefficient ceramic applications. In this work, we present a thorough study of BaTiO{sub 3}-rich NBT-100xBT by ferroelastic measurements, dielectric permittivity, X-ray diffraction, and Raman spectroscopy. We show that the high-temperature mechanical behavior, i.e., above the Curie temperature, T{sub C}, is influenced by local disorder, which appears also in pure BT. On the other hand, in NBT-100xBT (x < 1.0), lattice distortion, i.e., tetragonality, increases, and this impacts both the mechanical and dielectric properties. This increase in lattice distortion upon chemical substitution is counterintuitive by merely reasoning on the ionic size, and is due to the change in the A-O bond character induced by the Bi{sup 3+} electron lone pair, as indicated by Raman spectroscopy.

  6. Resonance Raman Spectroscopy of 0-A12O3- Supported Vanadium Oxide Catalysts for Butane Dehydrogenation

    SciTech Connect (OSTI)

    Wu, Zili; Kim, Hack-Sung; Stair, Peter

    2008-01-01

    This chapter contains sections titled: Introduction; Structure of Al{sub 2}O{sub 3}-Supported Vanadia Catalysts; Quantification of Surface VOx Species on Supported Vanadia Catalysts; Conclusion; Acknowledgements; and References.

  7. Planar Hall effect in Y{sub 3}Fe{sub 5}O{sub 12}/IrMn films

    SciTech Connect (OSTI)

    Zhang, X. Zou, L. K.

    2014-12-29

    The planar Hall effect of IrMn on an yttrium iron garnet (YIG = Y{sub 3}Fe{sub 5}O{sub 12}) was measured in the magnetic field rotating in the film plane. The magnetic field angular dependence of planar Hall resistance (PHR) was observed in YIG/IrMn bilayer at different temperatures, while the Gd{sub 3}Ga{sub 5}O{sub 12}/IrMn film shows constant PHR for different magnetic field angles at both 10 K and 300 K. This provides evidence that IrMn has interfacial spins which can be led by ferrimagnetic layer in YIG/IrMn structure. A hysteresis can be observed in PHR-magnetic field angle loop of YIG/IrMn film at 10 K, indicative of the irreversible switching of IrMn interfacial spins at low temperature.

  8. Intrinsic quantum anomalous Hall effect in the kagome lattice Cs2LiMn3F12

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Gang; Lian, Biao; Zhang, Shou -Cheng

    2015-10-27

    In a kagome lattice, the time reversal symmetry can be broken by a staggered magnetic flux emerging from ferromagnetic ordering and intrinsic spin-orbit coupling, leading to several well-separated nontrivial Chern bands and intrinsic quantum anomalous Hall effect. Based on this idea and ab initio calculations, we propose the realization of the intrinsic quantum anomalous Hall effect in the single layer Cs2Mn3F12 kagome lattice and on the (001) surface of a Cs2LiMn3F12 single crystal by modifying the carrier coverage on it, where the band gap is around 20 meV. Furthermore, a simplified tight binding model based on the in-plane ddσ antibondingmore » states is constructed to understand the topological band structures of the system.« less

  9. Y-12 Plant remedial action Technology Logic Diagram: Volume 3, Technology evaluation data sheets: Part A, Remedial action

    SciTech Connect (OSTI)

    1994-09-01

    The Y-12 Plant Remedial Action Technology Logic Diagram (TLD) was developed to provide a decision-support tool that relates environmental restoration (ER) problems at the Y-12 Plant to potential technologies that can remediate these problems. The TLD identifies the research, development, demonstration, testing, and evaluation needed for sufficient development of these technologies to allow for technology transfer and application to remedial action (RA) activities. The TLD consists of three volumes. Volume 1 contains an overview of the TLD, an explanation of the program-specific responsibilities, a review of identified technologies, and the rankings of remedial technologies. Volume 2 contains the logic linkages among environmental management goals, environmental problems and the various technologies that have the potential to solve these problems. Volume 3 contains the TLD data sheets. This report is Part A of Volume 3 and contains the Remedial Action section.

  10. Two SBIR Grants Awarded for SSL Technology (FY12 Phase I Release 3) |

    Broader source: Energy.gov (indexed) [DOE]

    SYNTHESIS OF OPERATIONAL MITIGATION STUDIES TO REDUCE BAT FATALITIES AT WIND ENERGY FACILITIES IN NORTH AMERICA Prepared for: The National Renewable Energy Laboratory 15013 Denver West Parkway Golden, CO 80401 Prepared by: Edward B. Arnett 1 , Gregory D. Johnson 2 , Wally P. Erickson 2 , and Cris D. Hein 3 1 Theordore Roosevelt Conservation Partnership 2 Western EcoSystems Technology, Inc. 3 Bat Conservation International March 2013 CITATION Arnett, E. B., G. D. Johnson, W. P. Erickson, and C.

  11. In-situ observation of domain wall motion in Pb(In{sub 1/2}Nb{sub 1/2})O{sub 3}-Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}-PbTiO{sub 3} crystals

    SciTech Connect (OSTI)

    Lin, Dabin; Cai, Changlong [Laboratory of Thin Film Techniques and Optical Test, Xi'an Technological University, Xi'an 710032 (China); Li, Zhenrong, E-mail: zhrli@mail.xjtu.edu.cn; Li, Fei; Xu, Zhuo [Electronic Materials Research Laboratory, Key Laboratory of Education Ministry and International Center for Dielectric Research, Xi'an Jiaotong University, Xi'an 710049 (China); Zhang, Shujun, E-mail: soz1@psu.edu [Materials Research Institute, Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Cheng, Yaojin [Science and Technology on Low-Light-Level Night Vision Laboratory, Xi'an 710065 (China)

    2014-07-21

    Various domain structures, including wave-like domains, mixed needle-like and laminar domains, typical embedded 90 and 180 domains, have been observed in unpoled rhombohedral, monoclinic, and tetragonal Pb(In{sub 1/2}Nb{sub 1/2})O{sub 3}-Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}-PbTiO{sub 3} (PIN-PMN-PT) crystals by polarizing light microscope; while in poled tetragonal crystals, the parallel 180 domains were reversed and only vertical 90 domain walls were observed. For 0.24PIN-0.42PMN-0.34PT crystals with morphotropic phase boundary composition, the domain wall motion was in-situ observed as a function of applied electric field along crystallographic [100] direction. With increasing the electric field from 0 to 12?kV/cm, the rhombohedral (R) domains were found to change to monoclinic (M) domains and then to tetragonal (T) domains. The electric field-induced phase transition was also confirmed by X-ray diffraction and the temperature-dependent dielectric behavior.

  12. Report on Fission Time Projection Chamber M3FT-12IN0210052

    SciTech Connect (OSTI)

    James K. Jewell

    2012-08-01

    The Time Projection Chamber is a collaborative effort to implement an innovative approach and deliver unprecedented fission measurements to DOE programs. This 4?-detector system will provide unrivaled 3-D data about the fission process. Shown here is a half populated TPC (2?) at the LLNL TPC laboratory as it undergoes testing before being shipped to LANSCE for beam experiments.

  13. Structural phase transition, narrow band gap, and room-temperature ferromagnetism in [KNbO{sub 3}]{sub 1?x}[BaNi{sub 1/2}Nb{sub 1/2}O{sub 3??}]{sub x} ferroelectrics

    SciTech Connect (OSTI)

    Zhou, Wenliang; Yang, Pingxiong Chu, Junhao; Deng, Hongmei

    2014-09-15

    Structural phase transition, narrow band gap (E{sub g}), and room-temperature ferromagnetism (RTFM) have been observed in the [KNbO{sub 3}]{sub 1?x}[BaNi{sub 1/2}Nb{sub 1/2}O{sub 3??}]{sub x} (KBNNO) ceramics. All the samples have single phase perovskite structure, but exhibit a gradual transition behaviour from the orthorhombic to a cubic structure with the increase of x. Raman spectroscopy analysis not only corroborates this doping-induced change in normal structure but also shows the local crystal symmetry for x ? 0.1 compositions to deviate from the idealized cubic perovskite structure. A possible mechanism for the observed specific changes in lattice structure is discussed. Moreover, it is noted that KBNNO with compositions x?=?0.10.3 have quite narrow E{sub g} of below 1.5?eV, much smaller than the 3.2?eV band gap of parent KNbO{sub 3} (KNO), which is due to the increasing Ni 3d electronic states within the gap of KNO. Furthermore, the KBNNO materials present RTFM near a tetragonal to cubic phase boundary. With increasing x from 0 to 0.3, the magnetism of the samples develops from diamagnetism to ferromagnetism and paramagnetism, originating from the ferromagneticantiferromagnetic competition. These results are helpful in the deeper understanding of phase transitions, band gap tunability, and magnetism variations in perovskite oxides and show the potential role, such materials can play, in perovskite solar cells and multiferroic applications.

  14. Piezo-/dielectric properties of perovskite-structure high-temperature relaxor ferroelectrics: The Pb(Lu{sub 1/2}Nb{sub 1/2})O{sub 3}–Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3}–PbTiO{sub 3} ternary ceramics

    SciTech Connect (OSTI)

    Li, Tao; Long, Xifa

    2014-03-01

    Graphical abstract: - Highlights: • Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3}-based ternary ferroelectric ceramics were prepared by solid-state synthesis method. • Morphotropic phase boundary region has been determined by XRD, di-/piezoelectric properties. • The compositions near MPB region exhibit excellent piezoelectric properties. - Abstract: A new compositional system of relaxor ferroelectrics was investigated based on the high piezoelectricity Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3}–PbTiO{sub 3} ferroelectric perovskite family. Compositions were fabricated near an estimated morphotropic phase boundary (MPB) of the Pb(Lu{sub 1/2}Nb{sub 1/2})O{sub 3}–Pb(Zn{sub 1/3}Nb{sub 2/3})O{sub 3}–PbTiO{sub 3} (PLZNT) ternary system by a two-step synthetic process. Their structures have been analyzed by means of X-ray diffraction technique. On the basis of X-ray powder diffraction, the morphotropic phase boundary (MPB) region for the ternary system was obtained. The Curie temperature T{sub C} of ternary system varied from 240 °C to 330 °C and the coercive fields E{sub c}s > 10 kV/cm. The values of piezoelectric coefficients d{sub 33} vary in the range of 260–450 pC/N with different PZN contents. It is worth noting that the optimum compositions were located at MPB region but near the tetragonal phase. The new PLZNT ceramics exhibit wider range of T{sub C}s and E{sub c}s, making it a promising material for high-powder ultrasound transducers using in a large temperature range.

  15. Twelve-month, 12 km resolution North American WRF-Chem v3.4 air quality simulation: performance evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tessum, C. W.; Hill, J. D.; Marshall, J. D.

    2015-04-07

    We present results from and evaluate the performance of a 12-month, 12 km horizontal resolution year 2005 air pollution simulation for the contiguous United States using the WRF-Chem (Weather Research and Forecasting with Chemistry) meteorology and chemical transport model (CTM). We employ the 2005 US National Emissions Inventory, the Regional Atmospheric Chemistry Mechanism (RACM), and the Modal Aerosol Dynamics Model for Europe (MADE) with a volatility basis set (VBS) secondary aerosol module. Overall, model performance is comparable to contemporary modeling efforts used for regulatory and health-effects analysis, with an annual average daytime ozone (O3) mean fractional bias (MFB) of 12%more » and an annual average fine particulate matter (PM2.5) MFB of −1%. WRF-Chem, as configured here, tends to overpredict total PM2.5 at some high concentration locations and generally overpredicts average 24 h O3 concentrations. Performance is better at predicting daytime-average and daily peak O3 concentrations, which are more relevant for regulatory and health effects analyses relative to annual average values. Predictive performance for PM2.5 subspecies is mixed: the model overpredicts particulate sulfate (MFB = 36%), underpredicts particulate nitrate (MFB = −110%) and organic carbon (MFB = −29%), and relatively accurately predicts particulate ammonium (MFB = 3%) and elemental carbon (MFB = 3%), so that the accuracy in total PM2.5 predictions is to some extent a function of offsetting over- and underpredictions of PM2.5 subspecies. Model predictive performance for PM2.5 and its subspecies is in general worse in winter and in the western US than in other seasons and regions, suggesting spatial and temporal opportunities for future WRF-Chem model development and evaluation.« less

  16. Twelve-month, 12 km resolution North American WRF-Chem v3.4 air quality simulation: performance evaluation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tessum, C. W.; Hill, J. D.; Marshall, J. D.

    2014-12-02

    We present results from and evaluate the performance of a 12 month, 12 km horizontal resolution air pollution simulation for the contiguous United States using the WRF-Chem (Weather Research and Forecasting with Chemistry) meteorology and chemical transport model (CTM). We employ the 2005 US National Emissions Inventory, the Regional Atmospheric Chemistry Mechanism (RACM), and the Modal Aerosol Dynamics Model for Europe (MADE) with a Volatility Basis Set (VBS) secondary aerosol module. Overall, model performance is comparable to contemporary models used for regulatory and health-effects analysis, with an annual average daytime ozone (O3) mean fractional bias (MFB) of 12% and anmore » annual average fine particulate matter (PM2.5) MFB of −1%. WRF-Chem, as configured here, tends to overpredict total PM2.5 at some high concentration locations, and generally overpredicts average 24 h O3 concentrations, with better performance at predicting average daytime and daily peak O3 concentrations. Predictive performance for PM2.5 subspecies is mixed: the model overpredicts particulate sulfate (MFB = 65%), underpredicts particulate nitrate (MFB = −110%) and organic carbon (MFB = −65%), and relatively accurately predicts particulate ammonium (MFB = 3%) and elemental carbon (MFB = 3%), so that the accuracy in total PM2.5 predictions is to some extent a function of offsetting over- and underpredictions of PM2.5 subspecies. Model predictive performance for PM2.5 and its subspecies is in general worse in winter and in the western US than in other seasons and regions, suggesting spatial and temporal opportunities for future WRF-Chem model development and evaluation.« less

  17. Quarterly SSP Experiment Summary-FY12-3Qv2 1

    National Nuclear Security Administration (NNSA)

    3Qv2 1 Summary of Experiments Conducted in Support of Stockpile Stewardship July 2012 The U.S. Stockpile Stewardship Program is a robust program of scientific inquiry used to sustain and assess the nuclear weapons stockpile without the use of underground nuclear tests. The experiments carried out within the program are used in combination with Advanced Simulation and Computing (ASC) to continually assess the stockpile to ensure it is safe, secure, and effective. (For links to the ASC program,

  18. Microsoft Word - DOE-ID-12-040 ORNL EC B3-6.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    40 SECTION A. Project Title: Radiation Resistant Electrical Insulation Materials for Nuclear Reactors Using Novel Nanocomposite Dielectrics - Oak Ridge National Laboratory SECTION B. Project Description Nanocomposite materials that are based on XLPE and other epoxy resins incorporating TiO2, MgO, SiO2, and AL2O3 nanoparticles, will be fabricated using a novel in situ method established at ORNL to demonstrate materials with increased resistance to radiation and thermal degradation. In order to

  19. Cyclic electric field response of morphotropic Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-BaTiO{sub 3} piezoceramics

    SciTech Connect (OSTI)

    Hinterstein, M.; Schmitt, L. A.; Hoelzel, M.; Jo, W.; Rödel, J.; Kleebe, H.-J.; Hoffman, M.

    2015-06-01

    In this study, the evolution of field induced mechanisms in lead-free piezoelectric ceramics (1−x)Bi{sub 1/2}Na{sub 1/2}TiO{sub 3}-xBaTiO{sub 3} with x = 0.06 and 0.07 was investigated by transmission electron microscopy, neutron, and X-ray diffraction. Preliminary investigations revealed a strong degradation of macroscopic electromechanical properties within the first 100 bipolar electric cycles. Therefore, this structural investigation focuses on a comparative diffraction study of freshly prepared, poled, and fatigued specimens. Transmission electron microscopy and neutron diffraction of the initial specimens reveal the coexistence of a rhombohedral and a tetragonal phase with space group R3c and P4bm, respectively. In situ electric field X-ray diffraction reveals a pronounced field induced phase transition from a pseudocubic state to a phase composition of significantly distorted phases upon poling with an external electric field of 4 kV/mm. Although the structures of the two compositions are pseudocubic and almost indistinguishable in the unpoled virgin state, the electric field response shows significant differences depending on composition. For both compositions, the application of an electric field results in a field induced phase transition in the direction of the minority phase. Electric cycling has an opposite effect on the phase composition and results in a decreased phase fraction of the minority phase in the fatigued remanent state at 0 kV/mm.

  20. Reg review - DOE RFI - EEI cmts 2-3-12.pdf

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3, 2012 U.S. Department of Energy Office of the General Counsel, Room 6A245 1000 Independence Avenue, SW Washington, DC 20585 Submitted via e-mail to: Regulatory.Review@hq.doe.gov Re: Reducing Regulatory Burden RFI, 76 Fed. Reg. 75798 (Dec. 5, 2011) Dear DOE staff: The Edison Electric Institute (EEI) is submitting these comments in response to the above-referenced request for information (RFI) issued by the Department of Energy (DOE). In the RFI, DOE is asking for information on ways to

  1. DYNA3D course notes, fall 1982: CE 3151-12. Revision 1

    SciTech Connect (OSTI)

    Hallquist, J.O.

    1986-05-01

    DYNA3D is an explicit three-dimensional finite element code for analyzing the large deformation dynamic response of inelastic solids and structures. A series of viewgraphs present the features of this code in a concise and abbreviated form. A contact-impact algorithm permits gaps and sliding along material interfaces with friction. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, 2-node beam elements, 4-node shell elements, 8-node solid shell elements, and rigid bodies. The equations-of-motion are integrated in time by the central difference method. 50 refs.

  2. DYNA3D course notes, fall 1982. CE 3151-12

    SciTech Connect (OSTI)

    Hallquist, J.O.

    1983-09-01

    DYNA3D is an explicit three-dimensional finite element code for analyzing the large deformation dynamic response of inelastic solids and structures. A series of viewgraphs present the features of this code in a concise and abbreviated form. A contact-impact algorithm permits gaps and sliding along material interfaces with friction. By a specialization of this algorithm, such interfaces can be rigidly tied to admit variable zoning without the need of transition regions. Spatial discretization is achieved by the use of 8-node solid elements, 2-node beam elements, 4-node shell elements, 8-node solid shell elements, and rigid bodies. The equations-of-motion are integrated in time by the central difference method.

  3. Deepwater royalty relief product of 3 1/2 year U.S. political effort

    SciTech Connect (OSTI)

    Davis, R.E.; Neff, S.

    1996-04-01

    Against the backdrop of more than 20 years of increasingly stringent environmental regulation, ever-expanding exploration and development moratoria on the Outer Continental Shelf (OCS), and reductions in producer tax incentives, oil and natural gas exploration companies active in deep waters of the Gulf of Mexico recently won a significant legislative victory. On Nov. 28, 1995, President Clinton signed into law S.395, the Alaska Power Administration Sale Act. Title 3 of S.395 embodies the Outer Continental Shelf Deep Water Royalty Relief Act. This landmark legislation provides substantial incentives for oil and natural gas production in the gulf of Mexico by temporarily eliminating royalties on certain deepwater leases. It is the first direct incentive for oil and gas production enacted at the federal level in many years. This paper reviews the elements used to arrive at this successful legislation including the congressional leadership. It describes debates, cabinet level discussions, and use of parlimentary procedures.

  4. Softening of antiferroelectricity in PbZrO{sub 3}-Pb(Mn{sub 1/2}W{sub 1/2})O{sub 3} complex perovskite solid solution

    SciTech Connect (OSTI)

    Ren, Zihe; Zhang, Nan; Su, Lun-Wei; Wu, Hua; Ye, Zuo-Guang

    2014-07-14

    A new solid solution of complex perovksite structure, (1-x)PbZrO{sub 3}-xPb(Mn{sub 1/2}W{sub 1/2})O{sub 3} (PZ-xPMnW, with x?=?00.1), is prepared by solid state reaction method. Its crystal structure, dielectric properties, and antiferroelectricity are investigated. It is found that the crystal structure of the solid solution remains in the orthorhombic Pbam symmetry with x???0.1. The induced ferroelectric polarization (P{sub Ind}) is enhanced, whereas the critical field (E{sub Cr}) is decreased, with increasing PMnW concentration, indicating the softening of antiferroelectricity in PZ. The Curie temperature (T{sub C}) is also decreased with the substitution of PMnW for PZ. The grain size is significantly enlarged, which could be attributed to the presence of a transient liquid phase during the sintering process. Measurements of the magnetization by means of SQUID confirm that the Mn ion exists in a high spin state with a 2+ oxidation state. The softening of antiferroelectric order and the improvement in induced polarization make the PZ-PMnW ceramics an interesting material system for such applications as energy storage devices.

  5. Quantum-mechanical simulation of the IR reflectance spectrum of Mn{sub 3}Al{sub 2}Si{sub 3}O{sub 12} spessartine

    SciTech Connect (OSTI)

    Ferrari, A. M.; Demichelis, R.; Meyer, A.; Maschio, L.; Dovesi, R.; Pascale, F.

    2015-01-22

    The reflectance spectrum of one member of the garnet family, Mn{sub 3}Al{sub 2}Si{sub 3}O{sub 12} spessartine, was computed at the ab initio level with an all electron Gaussian type basis set and the B3LYP Hamiltonian. The static high frequency dielectric constant was obtained by applying the Coupled Perturbed Kohn Sham scheme as implemented in the CRYSTAL code; the Hessian matrix was evaluated numerically starting from the analytical gradients of the total energy with respect to the Cartesian coordinates of the atoms; the oscillator strengths were computed from well localized Wannier functions. An excellent agreement was obtained with the corresponding experimental spectrum, the exception being the very low frequency region.

  6. Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe)3]+/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane)

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Smith, Frances N.; Wang, Zheming; Hightower, Sean E.; Sullivan, Brian P.; Heineman, William R.; Seliskar, Carl J.; Bryan, Samuel A.

    2013-12-05

    The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3]2+ (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in solution at room temperature, and is compared to its Re analogue. Surprisingly, both [M(dmpe)3]2+* (M = Re, Tc) species have extremely large excited-state potentials (ESPs) as oxidants - the highest for any simple coordination complex of a transition metal. Furthermore, this potential is available using a photon of visible light (calculated for M = Re(Tc); E1/2* = +2.61(2.48) V versus SCE; ?max = 526(585) nm). Open shell TDDFT calculations support the assignment of the lowest energy transition in both the technetium and rhenium complexes to be a doublet-doublet process that involve predominantly LMCT (dmpe-to-metal) character and is in agreement with past assignments for the Re system. As expected for highly oxidizing excited state potentials, quenching is observed for the excited states by both the rhenium and technetium complexes. Stern-Volmer analysis resulted in quenching parameters for both the rhenium and technetium complexes under identical conditions, and are compared using Rehm-Weller analysis. Of particular interest is the fact that both benzene and toluene are oxidized by both the Re and Tc systems.

  7. Crystal Chemistry and Luminescence of Ce3+ -Doped Lu2CaMg2(Si,Ge)3O12 and Its Use in LED Based Lighting

    SciTech Connect (OSTI)

    Setlur,A.; Heward, W.; Gao, Y.; Srivastava, A.; Chandron, R.; Shankar, M.

    2006-01-01

    In this paper, we describe the formation and luminescence of a new garnet phosphor for light emitting diode (LED) based lighting, Lu{sub 2}CaMg{sub 2}(Si,Ge){sub 3}O{sub 12}:Ce{sup 3+}.The regions for garnet phase formation are initially described with respect to larger rare earth substitution and show reasonable correlation to previous crystal chemistry studies for the garnet parent structure. While the pure silicate phosphor also has apatite second phases, a significant amount of Ce{sup 3+} enters the garnet phase, giving Ce{sup 3+} luminescence that is significantly redder when compared to typical Al{sup 3+} garnet phosphors with quantum efficiencies comparable to commercial Ce{sup 3+} garnet phosphors. Potential reasons for the emission red shift and the high quantum efficiency are discussed. Finally, the performance of these new phosphors is tested within LED based lamps. Lamps using these phosphors can reach color temperatures required for general illumination lighting and also have comparable phosphor conversion efficiencies when compared to lamps using typical garnet phosphors.

  8. October 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 October 12 PDSF Users Meeting 10/12/10 Attending: Eric, Jay and Katie from NERSC and users Craig Jeff P., Jeff A., Marjorie and Andrei. Cluster status: Cluster usage is fairly heavy but not filled to capacity for the most part. Outages: There have been problems with slowness which is related to a particular ATLAS user's jobs starting. It's not clear why his jobs are so bad and further testing is needed. pdsff3 went down yesterday which was related to the kernel bug. Were down for a day

  9. Thermally stable compositions including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt

    DOE Patents [OSTI]

    Hiskey, Michael A.; Huynh, My Hang

    2010-01-26

    An explosive formulation including 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt and a high temperature binder is disclosed together with a process of preparing 2,4,8,10-tetranitro-5H-pyrido[3',2':4,5][1,2,3]triazolo[1,2-a]benzotriazo- l-6-ium, inner salt.

  10. Interface-dependent magnetotransport properties for thin Pt films on ferrimagnetic Y{sub 3}Fe{sub 5}O{sub 12}

    SciTech Connect (OSTI)

    Shiomi, Y.; Ohtani, T.; Iguchi, S.; Sasaki, T.; Qiu, Z.; Nakayama, H.; Uchida, K.; Saitoh, E.

    2014-06-16

    We have studied magnetoresistance and Hall effects for 1.8-nm-thick Pt films grown on a ferrimagnetic insulator Y{sub 3}Fe{sub 5}O{sub 12} in a wide temperature (0.46–300 K) and magnetic-field (−15 to 15 T) region. In the low-temperature regime where quantum corrections to conductivity are observed, weak antilocalization behavior observed in Pt films is critically suppressed when the film is attached to Y{sub 3}Fe{sub 5}O{sub 12}. Hall resistance in the Pt film is also affected by Y{sub 3}Fe{sub 5}O{sub 12}, and it exhibits logarithmic temperature dependence in a broad temperature range. The magnetotransport properties in the high-field range are significantly influenced by the interface between Pt and Y{sub 3}Fe{sub 5}O{sub 12}.

  11. Thermal expansion of Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12} solid solutions

    SciTech Connect (OSTI)

    Ari, M.; Jardim, P.M.; Marinkovic, B.A. Rizzo, F.; Ferreira, F.F.

    2008-06-15

    The transition temperature from monoclinic to orthorhombic and the thermal expansion of the orthorhombic phase were investigated for three systems of the family A{sub 2}M{sub 3}O{sub 12}: Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12}. It was possible to obtain a single-phase solid solution in all studied samples (x=0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1). A linear relationship between the transition temperature and the fraction of A{sup 3+} cations (x) was observed for each system. In all orthorhombic solid solutions studied here the observed thermal expansion was anisotropic. These anisotropic thermal expansion properties of crystallographic axes a, b and c result in a low positive or near-zero overall linear coefficient of thermal expansion ({alpha}{sub l}={alpha}{sub V}/3). The relationship between the size of A{sup 3+} cations in A{sub 2}M{sub 3}O{sub 12} and the coefficient of thermal expansion is discussed. Near-zero thermal expansion of Cr{sub 2}Mo{sub 3}O{sub 12} is explained by the behavior of Cr-O and Mo-O bond distances, Cr-Mo non-bond distances and Cr-O-Mo bond angles with increasing temperature, estimated by Rietveld analysis of synchrotron X-ray powder diffraction data. - Graphical abstract: In this figure, all published overall linear coefficients of thermal expansion for orthorhombic A{sub 2}M{sub 3}O{sub 12} family obtained through diffraction methods as a function of A{sup 3+} cation radii size, together with dilatometric results, are plotted. Our results indicate that Cr{sub 2}Mo{sub 3}O{sub 12} does not exactly follow the established relationship.

  12. Synthesis of the Stereoisomeric Clusters 1,2-Os3(CO)10(trans-dpmn) and 1,2-Os3(CO)10(cis-dpmn) [where dpmn = 2,3-bis(diphenylphosphinomethyl)-5-norbornene]: DFT Evaluation of the Isomeric Clusters 1,2-Os3(CO)10(dpmn) and Isomer-Dependent Diphosphine Ligand Activation

    SciTech Connect (OSTI)

    Yang, Li; Nesterov, Vladimir N.; Wang, Xiaoping; Richmond, Michael G.

    2014-07-23

    The bicyclic diphosphines trans- and cis-2,3-bis(diphenylphosphinomethyl)-5-norbornene (dpmn) react with 1,2-Os3(CO)10(MeCN)2 (1) to furnish the corresponding ligand-bridged clusters Os3(CO)10(trans-dpmn) (2) and Os3(CO)10(cis-dpmn) (3). Both new products have been isolated and the molecular structures established by X-ray diffraction analyses. The dihydroxyl-bridged cluster 1,2-Os3(CO)8(μ-OH)2(cis-dpmn) (4), which accompanied the formation of 3 in one reaction, has been isolated and characterized by mass spectrometry and X-ray crystallography. Whereas cluster 2 is stable in toluene at 373 K, 3 is thermally sensitive under identical conditions and undergoes loss of CO (2 equiv), coupled with the activation of three norbornene C-H bonds and one P-C(phenyl) bond, to furnish the dihydride cluster H2Os3(CO)83-2-PhPC-3-endo-Ph2PCH2(C7H7)] (5). The solid-state structure of 5 confirms the multiple activation of the cis-dpmn ligand and accompanying formation of the face-capping 2-PhPC-3-endo-Ph2PCH2(C7H7) moiety in the product. DFT calculations on 2 and 3 indicate that the former cluster is the thermodynamically more stable isomer, and the conversion of 3→ 5 + 2CO + benzene is computed to be exergonic by 12.7 kcal/mol and is entropically favored due to the release of the CO and benzene by-products.

  13. Changes in Moisture Flux Over the Tibetan Plateau During 1979-2011: Insights from a High Resolution Simulation

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Zhang, Yongxin; Cuo, Lan

    2015-05-01

    Net precipitation (precipitation minus evapotranspiration, P-E) changes from a high resolution regional climate simulation and its reanalysis forcing are analyzed over the Tibet Plateau (TP) and compared to the global land data assimilation system (GLDAS) product. The mechanism behind the P-E changes is explored by decomposing the column integrated moisture flux convergence into thermodynamic, dynamic, and transient eddy components. High-resolution climate simulation improves the spatial pattern of P-E changes over the best available global reanalysis. Improvement in simulating precipitation changes at high elevations contributes dominantly to the improved P-E changes. High-resolution climate simulation also facilitates new and substantial findings regarding the role of thermodynamics and transient eddies in P-E changes reflected in observed changes in major river basins fed by runoff from the TP. The analysis revealed the contrasting convergence/divergence changes between the northwestern and southeastern TP and feedback through latent heat release as an important mechanism leading to the mean P-E changes in the TP.

  14. Changes in Moisture Flux over the Tibetan Plateau during 1979-2011: Insights from a High Resolution Simulation

    SciTech Connect (OSTI)

    Gao, Yanhong; Leung, Lai-Yung R.; Zhang, Yongxin; Cuo, Lan

    2015-05-15

    Net precipitation (precipitation minus evapotranspiration, P-E) changes between 1979 and 2011 from a high resolution regional climate simulation and its reanalysis forcing are analyzed over the Tibet Plateau (TP) and compared to the global land data assimilation system (GLDAS) product. The high resolution simulation better resolves precipitation changes than its coarse resolution forcing, which contributes dominantly to the improved P-E change in the regional simulation compared to the global reanalysis. Hence, the former may provide better insights about the drivers of P-E changes. The mechanism behind the P-E changes is explored by decomposing the column integrated moisture flux convergence into thermodynamic, dynamic, and transient eddy components. High-resolution climate simulation improves the spatial pattern of P-E changes over the best available global reanalysis. High-resolution climate simulation also facilitates new and substantial findings regarding the role of thermodynamics and transient eddies in P-E changes reflected in observed changes in major river basins fed by runoff from the TP. The analysis revealed the contrasting convergence/divergence changes between the northwestern and southeastern TP and feedback through latent heat release as an important mechanism leading to the mean P-E changes in the TP.

  15. November 12, 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cafs November 12, 2010 November 12, 2010 Print Friday, 12 November 2010 00:00 christine beavers Having a ball in the wild world of fullerenes Christine Beavers, Beamline 11.3.1 ...

  16. Site-related near-infrared luminescence in MAl{sub 12}O{sub 19} (M = Ca, Sr, Ba):Fe{sup 3+} phosphors

    SciTech Connect (OSTI)

    Li, Y.J.; Ma, Y.Y.; Ye, S.; Hu, G.P.; Zhang, Q.Y.

    2014-03-01

    Graphical abstract: - Highlights: • Intense 700–850 nm NIR emissions in MAl{sub 12}O{sub 19} (M = Ca, Sr, Ba):1%Fe{sup 3+} has been obtained. • The NIR emissions can be ascribed to the octahedral Fe{sup 3+} sites. • The site symmetry of Fe{sup 3+} in CA{sub 6} and SA{sub 6} may be lower than that in BA{sub 6}. • The phosphors may be potentially applied in the high-resolution bioimaging. - Abstract: Intense and broad near-infrared (NIR) photoluminescence (PL) peaks locating at 777, 808 and 810 nm is observed for BaAl{sub 12}O{sub 19} (BA{sub 6}):1%Fe{sup 3+}, CaAl{sub 12}O{sub 19} (CA{sub 6}):1%Fe{sup 3+} and SrAl{sub 12}O{sub 19} (SA{sub 6}):1%Fe{sup 3+}, respectively. Electron paramagnetic resonance (EPR) spectra show that Fe{sup 3+} ions substitute for the different types of Al{sup 3+} sites simultaneously. Meanwhile, the luminescence of Fe{sup 3+} in MAl{sub 12}O{sub 19} (M = Ca, Sr and Ba) are ascribed to octahedral Fe{sup 3+}. In addition, the site symmetry of Fe{sup 3+} in CA{sub 6}/SA{sub 6} is lower compared with BA{sub 6}, deduced from the photoluminescence excitation (PLE), EPR and Fourier-transform infrared (FT-IR) spectra. These phosphors can be considered as good candidates for the applications in the field of high-resolution bioimaging.

  17. 12B

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B β--Decay Evaluated Data Measurements 1948JE03: 12B; measured T1/2. 1956TA07, 1957CO59, 1958CO66, 1958KA31: 12B. 1957CO57: 12B; measured T1/2. 1958KR65: 12B; measured T1/2. 1959FA03: 12B; measured T1/2. 1961SC09: 12B; measured not abstracted; deduced nuclear properties. 1962NE14: 12B; measured not abstracted; deduced nuclear properties. 1962PO02: 12B; measured not abstracted; deduced nuclear properties. 1963AL15: 12B; measured not abstracted; deduced nuclear properties. 1963FI05: 12B; measured

  18. 12N

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N β+-Decay Evaluated Data Measurements 1949AL05: 12N; measured T1/2. 1958VE20: 12N; measured T1/2. 1959FA03: 12N; measured T1/2. 1962MA22: 12N; measured not abstracted; deduced nuclear properties. 1962PO02: 12N; measured not abstracted; deduced nuclear properties. 1963FI05: 12N; measured not abstracted; deduced nuclear properties. 1963GL04: 12N; measured not abstracted; deduced nuclear properties. 1963PE10: 12N; measured not abstracted; deduced nuclear properties. 1963WI05: 12N; measured not

  19. file://C:\Documents%20and%20Settings\VM3\My%20Documents\hc6-12a

    U.S. Energy Information Administration (EIA) Indexed Site

    2a. Usage Indicators by West Census Region, Million U.S. Households, 2001 ____________________________________________________________________________________________ | | | | | West Census Region | | |___________________________________| | | | | | | | Census Division | | | |_______________________| | Total | | | | Usage Indicators | U.S. | Total | Mountain | Pacific | |___________|___________|___________|___________| RSE | | | | | Row RSE Column Factor: | 0.5 | 1.0 | 1.6 | 1.2 |Factors

  20. Think Uranium. Think Y-12 | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Think Uranium. Think Y-12 Think Uranium. Think Y-12 Posted: July 22, 2013 - 3:12pm | Y-12 Report | Volume 10, Issue 1 | 2013 Uranium fever: Much like the California gold rush of ...

  1. Data:Eac1dd3a-0268-4e5c-b1d1-ed9feeb2a12a | Open Energy Information

    Open Energy Info (EERE)

    Eac1dd3a-0268-4e5c-b1d1-ed9feeb2a12a No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading......

  2. Local structural distortion and electrical transport properties of Bi(Ni1/2Ti1/2)O3 perovskite under high pressure

    SciTech Connect (OSTI)

    Zhu, Jinlong; Yang, Liuxiang; Wang, Hsiu -Wen; Zhang, Jianzhong; Yang, Wenge; Hong, Xinguo; Jin, Changqing; Zhao, Yusheng

    2015-12-16

    Perovskite-structure materials generally exhibit local structural distortions that are distinct from long-range, average crystal structure. The characterization of such distortion is critical to understanding the structural and physical properties of materials. In this work, we combined Pair Distribution Function (PDF) technique with Raman spectroscopy and electrical resistivity measurement to study Bi(Ni1/2Ti1/2)O3 perovskite under high pressure. PDF analysis reveals strong local structural distortion at ambient conditions. As pressure increases, the local structure distortions are substantially suppressed and eventually vanish around 4 GPa, leading to concurrent changes in the electronic band structure and anomalies in the electrical resistivity. We find, consistent with PDF analysis, Raman spectroscopy data suggest that the local structure changes to a higher ordered state at pressures above 4 GPa.

  3. A Historical Evaluation of the U12t Tunnel, Nevada Test Site, Nye County, Nevada, Volume 3 of 6

    SciTech Connect (OSTI)

    Harold Drollinger; Robert C. Jones; and Thomas F. Bullard; Desert Research Institute, Laurence J. Ashbaugh, Southern Nevada Courier Service and Wayne R. Griffin, Stoller-Navarro Joint Venture

    2009-02-01

    This report presents a historical evaluation of the U12t Tunnel on the Nevada Test Site in southern Nevada. The work was conducted by the Desert Research Institute at the request of the U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office and the U.S. Department of Defense, Defense Threat Reduction Agency (DTRA). The U12t Tunnel is one of a series of tunnels used for underground nuclear weapons effects tests on the east side of Rainier and Aqueduct Mesas. Six nuclear weapons effects tests, Mint Leaf, Diamond Sculls, Husky Pup, Midas Myth/Milagro, Mighty Oak, and Mission Ghost, and one high explosive test, SPLAT, were conducted within the U12t Tunnel from 1970 to 1987. All six of the nuclear weapons effects tests and the high explosive test were sponsored by DTRA. Two conventional weapons experiments, Dipole Knight and Divine Eagle, were conducted in the tunnel portal area in 1997 and 1998. These experiments were sponsored by the Defense Special Weapons Agency. The U12t Tunnel complex is composed of the Portal and Mesa Areas and includes an underground tunnel with a main access drift and nine primary drifts, a substantial tailings pile fronting the tunnel portal, a series of discharge ponds downslope of the tailings pile, and two instrumentation trailer parks and 16 drill holes on top of Aqueduct Mesa. A total of 89 cultural features were recorded: 54 at the portal and 35 on the mesa. In the Portal Area, cultural features are mostly concrete pads and building foundations; other features include the portal, rail lines, the camel back, ventilation and cooling system components, communication equipment, and electrical equipment. On the mesa are drill holes, a few concrete pads, a loading ramp, and electrical equipment.

  4. Effect of Morphology and Manganese Valence on the Voltage Fade and Capacity Retention of Li[Li 2/12Ni3/12Mn7/12]O2

    SciTech Connect (OSTI)

    Verde, Michael G.; Liu, Haodong; Carroll, Kyler J.; Baggetto, Loïc; Veith, Gabriel M.; Meng, Y. Shirley

    2014-10-02

    We have determined the electrochemical characteristics of the high voltage, high capacity Li-ion battery cathode material Li[Li 2/12Ni3/12Mn7/12]O2 prepared using three different synthesis routes: sol-gel, hydroxide co-precipitation, and carbonate co-precipitation. Each route leads to distinct morphologies and surface areas while maintaining the same crystal structures. X-ray photoelectron spectroscopy (XPS) measurements reveal differences in their surface chemistries upon cycling, which correlate with voltage fading. As expected, we observed the valence state of Mn on the surface to decrease upon lithiation, and this reduction is specifically correlated to discharging below 3.6V. Furthermore, the data shows a correlation of the formation of Li2CO3 with Mn oxidation state from the

  5. Development of a 27.12 MHz radio frequency driven ion source with 3 mTorr operation pressure for neutron generators

    SciTech Connect (OSTI)

    Jiang Ximan; Chen Ye; Ji Lili; Ji Qing; Leung, K.-N.

    2005-10-15

    An inductively coupled rf plasma ion source has been developed for neutron generators. The ion source configuration has been optimized for low pressure operation. Both 13.56 and 27.12 MHz rf powers have been used to generate hydrogen plasma. Experimental results show that 27.12 MHz operation is more efficient than 13.56 MHz in a low pressure region. The ion source can also be operated in pulsed mode. Current density higher than 30 mA/cm{sup 2} can be extracted from a 2-mm-diam aperture at 2 kW rf input power and 3 mTorr operation pressure.

  6. 12Be

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Be β--Decay Evaluated Data Measurements 1965PO03: 12Be; measured not abstracted; deduced nuclear properties. 1978AL10: 12Be; measured T1/2, delayed neutrons; deduced upper limit delayed neutron branch. 1984DU15: 12Be(β-); measured T1/2. 1986CU01: 12Be(β-); measured β-decay T1/2. 1986HAYX: 12Be; measured β-decay T1/2. 1994KE06: 12Be(β-); measured βγ-coin, T1/2; deduced ft. 12B levels deduced β-branching ratio. 1994RE1R, 1991RE02: 12Be(β-n); measured T1/2, neutron emission probabilities.

  7. A novel broadband emission phosphor Ca{sub 2}KMg{sub 2}V{sub 3}O{sub 12} for white light emitting diodes

    SciTech Connect (OSTI)

    Li, Junfu; Qiu, Kehui; Li, Junfeng; Li, Wei; Yang, Qian; Li, Junhan

    2010-05-15

    A novel broadband emission phosphor Ca{sub 2}KMg{sub 2}V{sub 3}O{sub 12} was first synthesized by solution combustion method. The X-ray diffraction showed that Ca{sub 2}KMg{sub 2}V{sub 3}O{sub 12} phase can be obtained at 600-900 {sup o}C through combustion route. The crystal structure of this material was refined by Rietveld method using powder X-ray diffraction. It crystallizes in cubic system and belongs to space group Ia3d with z = 8, a = 0.12500 nm. The excitation band of Ca{sub 2}KMg{sub 2}V{sub 3}O{sub 12} peaks at 320 nm in a region between 260 nm and 425 nm, and the emission spectrum exhibits an intense band centered at about 528 nm covering from 400 nm to 800 nm. The colour coordinates of samples prepared at different ignition temperatures are in a range of x = 0.323-0.339, y = 0.430-0.447.

  8. Using the Antenna Effect as a Spectroscopic Tool; Photophysics and Solution Thermodynamics of the Model Luminescent Hydroxypyridonate Complex [EuIII(3,4,3-LI(1,2-HOPO))]-

    SciTech Connect (OSTI)

    Abergel, Rebecca J.; D'Aleo, Anthony; Ng Pak Leung, Clara; Shuh, David; Raymond, Kenneth

    2009-11-20

    While widely used in bioassays, the spectrofluorimetric method described here uses the antenna effect as a tool to probe the thermodynamic parameters of ligands that sensitize lanthanide luminescence. The Eu3+ coordination chemistry, solution thermodynamic stability and photophysical properties of the spermine-based hydroxypyridonate octadentate chelator 3,4,3-LI(1,2-HOPO) are reported. The complex [EuIII(3,4,3-LI(1,2-HOPO))]- luminesces with a long lifetime (805 mu s) and a quantum yield of 7.0percent in aqueous solution, at pH 7.4. These remarkable optical properties were exploited to determine the high (and proton-independent) stability of the complex (log beta 110 = 20.2(2)) and to define the influence of the ligand scaffold on the stability and photophysical properties.

  9. WARM SPITZER PHOTOMETRY OF THREE HOT JUPITERS: HAT-P-3b, HAT-P-4b AND HAT-P-12b

    SciTech Connect (OSTI)

    Todorov, Kamen O.; Deming, Drake; Knutson, Heather A.; Burrows, Adam; Fortney, Jonathan J.; Laughlin, Gregory; Lewis, Nikole K.; Cowan, Nicolas B.; Agol, Eric; Desert, Jean-Michel; Sada, Pedro V.; Charbonneau, David; Langton, Jonathan; Showman, Adam P.

    2013-06-20

    We present Warm Spitzer/IRAC secondary eclipse time series photometry of three short-period transiting exoplanets, HAT-P-3b, HAT-P-4b and HAT-P-12b, in both the available 3.6 and 4.5 {mu}m bands. HAT-P-3b and HAT-P-4b are Jupiter-mass objects orbiting an early K and an early G dwarf star, respectively. For HAT-P-3b we find eclipse depths of 0.112%+0.015%-0.030% (3.6 micron) and 0.094%+0.016%-0.009% (4.5 {mu}m). The HAT-P-4b values are 0.142%+0.014%-0.016% (3.6 micron) and 0.122%+0.012%-0.014% 4.5 {mu}m). The two planets' photometry is consistent with inefficient heat redistribution from their day to night sides (and low albedos), but it is inconclusive about possible temperature inversions in their atmospheres. HAT-P-12b is a Saturn-mass planet and is one of the coolest planets ever observed during secondary eclipse, along with the hot Neptune GJ 436b and the hot Saturn WASP-29b. We are able to place 3{sigma} upper limits on the secondary eclipse depth of HAT-P-12b in both wavelengths: <0.042% (3.6 {mu}m) and <0.085% (4.5 {mu}m). We discuss these results in the context of the Spitzer secondary eclipse measurements of GJ 436b and WASP-29b. It is possible that we do not detect the eclipses of HAT-P-12b due to high eccentricity, but find that weak planetary emission in these wavelengths is a more likely explanation. We place 3{sigma} upper limits on the |e cos {omega}| quantity (where e is eccentricity and {omega} is the argument of periapsis) for HAT-P-3b (<0.0081) and HAT-P-4b (<0.0042), based on the secondary eclipse timings.

  10. 2011 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2011 Mon, 2011-12-19 14:00 Section of CEBAF Blvd. to be Closed Jan. 3-5, 2012 Thu, 2011-12-15 14:00 Before Leaving JLab: Holiday Break Housekeeping, Electronics Instructions Wed, 2011-12-14 14:00 Personal Dosimeter Change Out is Dec. 19; Sign 2012 RWP by Dec. 31 Tue, 2011-12-13 14:00 2011 Lab Shutdown/Exception Process Tue, 2011-12-13 14:00 Extensive JLab Power Outage Over Holiday Shutdown Tue, 2011-12-13 14:00 Upcoming rate restructuring at the SURA Residence Facility Tue, 2011-12-13

  11. Data:12a45141-7972-4ec8-a2dc-37fedc8133d3 | Open Energy Information

    Open Energy Info (EERE)

    ec8-a2dc-37fedc8133d3 No revision has been approved for this page. It is currently under review by our subject matter experts. Jump to: navigation, search Loading... 1. Basic...

  12. I=1/2 and 3/2 K pi scattering in a qqq-bar q-bar potential model

    SciTech Connect (OSTI)

    Nathan Isgur; J. Weinstein

    1991-01-01

    We present the results of a study of I=1/2 and 3/2 K pi scattering based on our earlier analysis of the I=0, 1, and 2 pseudoscalar-pseudoscalar systems. While the latter systems formed KK-bar molecules in both I=0 and 1, here, with the same parameters, we find that neither K pi , K eta , nor K eta ' form bound states. Both I=1/2 and 3/2 phase-shift predictions are found to agree with experimental data. A shift in the mass and width of the ''bare'' qq-bar state K*{sub 0}is induced by the coupled-channel interactions, which also provide a physical source for the low-energy ''background'' phase shift normally introduced in analyses of K pi data.

  13. Intrinsic quantum anomalous Hall effect in the kagome lattice Cs2LiMn3F12

    SciTech Connect (OSTI)

    Xu, Gang; Lian, Biao; Zhang, Shou -Cheng

    2015-10-27

    In a kagome lattice, the time reversal symmetry can be broken by a staggered magnetic flux emerging from ferromagnetic ordering and intrinsic spin-orbit coupling, leading to several well-separated nontrivial Chern bands and intrinsic quantum anomalous Hall effect. Based on this idea and ab initio calculations, we propose the realization of the intrinsic quantum anomalous Hall effect in the single layer Cs2Mn3F12 kagome lattice and on the (001) surface of a Cs2LiMn3F12 single crystal by modifying the carrier coverage on it, where the band gap is around 20 meV. Furthermore, a simplified tight binding model based on the in-plane ddσ antibonding states is constructed to understand the topological band structures of the system.

  14. High-Temperature Thermoelectric Properties of the Solid–Solution Zintl Phase Eu11Cd6Sb12–xAsx (x < 3)

    SciTech Connect (OSTI)

    Kazem, Nasrin; Xie, Weiwei; Ohno, Saneyuki; Zevalkink, Alexandra; Miller, Gordon J; Snyder, G Jeffrey; Kauzlarich, Susan M

    2014-02-11

    Zintl phases are compounds that have shown promise for thermoelectric applications. The title solid–solution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu11Cd6Sb12–xAsx (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr11Cd6Sb12 structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ~3 resulted in structures other than the Sr11Cd6Sb12 structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu11Cd6Sb10As2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.78–0.49 W/mK for x = 0; 0.72–0.53 W/mK for x = 1; and 0.70–0.56 W/mK for x = 2. Eu11Cd6Sb12 shows a high p-type Seebeck coefficient (from +118 to 153 μ V/K) but also high electrical resistivity (6.8 to 12.8 mΩ·cm). The value of zT reaches 0.23 at 774 K. The properties of Eu11Cd6Sb12–xAsx are interpreted in discussion with the As site substitution.

  15. Resolving the grain boundary and lattice impedance of hot-pressed Li7La3Zr2O12 garnet electrolytes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tenhaeff, Wyatt E.; Wang, Yangyang; Sokolov, Alexei P.; Wolfenstine, Jeff; Sakamoto, Jeffrey; Dudney, Nancy J.; Rangasamy, Ezhiyl

    2013-07-24

    Here, the cubic-stabilized garnet solid electrolyte with a nominal composition of Li6.28Al0.24La3Zr2O12 is thoroughly characterized by impedance spectroscopy. By varying the frequency of the applied AC signal over 11 orders of magnitude for characterizations from –100 to +60 °C, the relative contributions of grain and grain boundary conduction are unambiguously resolved.

  16. Influence of processing route on electrical properties of Bi{sub 4}Ti{sub 3}O{sub 12} ceramics obtained by tape-casting technology

    SciTech Connect (OSTI)

    Ranieri, M.G.A.; Aguiar, E.C.; Cilense, M.; Stojanovic, B.D.; Simões, A.Z.; Varela, J.A.

    2015-10-15

    Highlights: • Bi{sub 4}Ti{sub 3}O{sub 12} thick films were obtained by SSR and PPM methods. • Both systems crystallize in an orthorhombic structure. • Textured characteristics were evidenced. • Grain morphology affects the P–E loops. - Abstract: Bismuth titanate powders (Bi{sub 4}Ti{sub 3}O{sub 12}-BIT) were fabricated by solid state reaction (SSR) and polymeric precursor method (PPM). From these powders, Bi{sub 4}Ti{sub 3}O{sub 12} pellets were obtained by tape-casting using plate-like templates particles prepared by a molten salt method. The BIT phase crystallizes in an orthorhombic structure type with space group Fmmm. Agglomeration of the particles, which affects the densification of the ceramic, electrical conduction and leakage current at high electric fields, was monitored by transmission electronic microscopy (TEM) analyses. FEG-SEM indicated that different shape of grains of BIT ceramics was influenced by the processing route. Both SSR and PPM methods lead to unsaturated P–E loops of BIT ceramics originating from the highly c-axis orientation and high conductivity which was affected by charge carriers flowing normally to the grain boundary of the crystal lattice.

  17. Microsoft Word - DOE-ID-12-043 UC-Davis EC B3-6[1].doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 SECTION A. Project Title: Study of intermetallic nanostructures for light-water reactor materials - Regents of the University of California SECTION B. Project Description This project will investigate if intermetallic coherent particles can be used to remove the radiation damage from the matrix in material to create a radiation tolerant structural material. It is the aim of this proposal to perform systematic experimental and computational investigations to understand the role of the

  18. Microsoft Word - DOE-ID-12-036 Battelle-PNWD EC B3-6 B3-10.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 SECTION A. Project Title: Nanocrystalline SiC and Ti3SiC2 alloys for High-Temperature Reactor Materials - Battelle-PNWD, Operator of PNNL for US DOE SECTION B. Project Description This research will focus on the structural response to ion irradiation to high doses at elevated temperatures and modification of mechanical properties of SiC/Ti3SiC2 nanocomposites, with and without carbon nanotube reinforcements. An integrated experimental and computational approach will be used to study the

  19. Biomimetic Actinide Chelators: An Update on the Preclinical Development of the Orally Active Hydroxypyridonate Decorporation Agents 3,4,3-LI(1,2-HOPO) and 5-LIO(Me-3,2-HOPO)

    SciTech Connect (OSTI)

    Durbin, Patricia W.; Kullgren, Birgitta; Ebbe, Shirley N.; Xu, Jide; Chang, Polly Y.; Bunin, Deborah I.; Blakely, Eleanor A.; Bjornstad, Kathleen A.; Rosen, Chris J.; Shuh, David K.; Raymond, Kenneth N.

    2011-07-13

    The threat of a dirty bomb or other major radiological contamination presents a danger of large-scale radiation exposure of the population. Because major components of such contamination are likely to be actinides, actinide decorporation treatments that will reduce radiation exposure must be a priority. Current therapies for the treatment of radionuclide contamination are limited and extensive efforts must be dedicated to the development of therapeutic, orally bioavailable, actinide chelators for emergency medical use. Using a biomimetic approach based on the similar biochemical properties of plutonium(IV) and iron(III), siderophore-inspired multidentate hydroxypyridonate ligands have been designed and are unrivaled in terms of actinide-affinity, selectivity, and efficiency. A perspective on the preclinical development of two hydroxypyridonate actinide decorporation agents, 3,4,3-LI(1,2-HOPO) and 5-LIO(Me-3,2-HOPO), is presented. The chemical syntheses of both candidate compounds have been optimized for scale-up. Baseline preparation and analytical methods suitable for manufacturing large amounts have been established. Both ligands show much higher actinide-removal efficacy than the currently approved agent, diethylenetriaminepentaacetic acid (DTPA), with different selectivity for the tested isotopes of plutonium, americium, uranium and neptunium. No toxicity is observed in cells derived from three different human tissue sources treated in vitro up to ligand concentrations of 1 mM, and both ligands were well tolerated in rats when orally administered daily at high doses (>100 micromol kg d) over 28 d under good laboratory practice guidelines. Both compounds are on an accelerated development pathway towards clinical use.

  20. Remedial Investigation Work Plan for Upper East Fork Poplar Creek Operable Unit 3 at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. Environmental Restoration Program

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Upper East Fork Popular Creek Operable Unit 3 (UEFPC OU 3) is a source term OU composed of seven sites, and is located in the western portion of the Y-12 Plant. For the most part, the UEFPC OU 3 sites served unrelated purposes and are geographically removed from one another. The seven sites include the following: Building 81-10, the S-2 Site, Salvage Yard oil storage tanks, the Salvage Yard oil/solvent drum storage area, Tank Site 2063-U, the Salvage Yard drum deheader, and the Salvage Yard scrap metal storage area. All of these sites are contaminated with at least one or more hazardous and/or radioactive chemicals. All sites have had some previous investigation under the Y-12 Plant RCRA Program. The work plan contains summaries of geographical, historical, operational, geological, and hydrological information specific to each OU 3 site. The potential for release of contaminants to receptors through various media is addressed, and a sampling and analysis plan is presented to obtain objectives for the remedial investigation. Proposed sampling activities are contingent upon the screening level risk assessment, which includes shallow soil sampling, soil borings, monitoring well installation, groundwater sampling, and surface water sampling. Data from the site characterization activities will be used to meet the above objectives. A Field Sampling Investigation Plan, Health and Safety Plan, and Waste Management Plan are also included in this work plan.

  1. Thermoelectric Properties of P-type Skutterudites YbxFe3.5Ni0.5Sb12 (0.8 x 1)

    SciTech Connect (OSTI)

    Cho, Jung Y; Ye, Zuxin; Tessema, M.; Waldo, R.A.; Salvador, James R.; Yang, Jihui; Cai, Wei; Wang, Hsin

    2012-01-01

    P-type skutterudites, with nominal compositions YbxFe3.5Ni0.5Sb12 (0.8 x 1), have been synthesized by induction melting with subsequent annealing, and their thermoelectric properties evaluated from 3.5 K to 745 K to assess their suitability for thermoelectric based waste heat recovery applications. We report results for the synthesis and measurements of Seebeck coefficient (S), electrical resistivity ( ), thermal conductivity ( ), Hall coefficient (RH), and effective mass (m*/m0) of YbxFe3.5Ni0.5Sb12 (0.8 x 1). Powder x-ray diffraction and electron probe microanalysis (EPMA) show that this system has a narrow filling fraction range of x ~ 0.84 to 0.86 for Yb in the crystallographic voids. All samples show positive RH for the entire temperature range studied with carrier concentrations ranging from 9.6 1020 to 2.8 1021 cm-3 at room temperature. Relatively high values of S result in high power factors up to 17 Wcm-1K-2 at room temperature. However, large values of and a sharp reduction in the S at high temperature due to bipolar conduction prevent the attainment of high thermoelectric figure of merit.

  2. An anion substitution route to low loss colossal dielectric CaCu{sub 3}Ti{sub 4}O{sub 12}

    SciTech Connect (OSTI)

    Smith, Andrew E.; Calvarese, T.G.; Sleight, A.W.; Subramanian, M.A.

    2009-02-15

    An anion substitution route was utilized for lowering the dielectric loss in CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) by partial replacement of oxygen by fluorine. This substitution reduced the dielectric loss, and retained a high dielectric constant that was essentially temperature independent from 25 to 200 deg. C. In particular, CaCu{sub 3}Ti{sub 4}O{sub 11.7}F{sub 0.3} exhibited a giant dielectric constant over 6000 and low dielectric loss below 0.075 at 100 kHz within a temperature range of 25-200 deg. C. Fluorine analysis confirmed the presence of fluorine in all samples measured. - Grapical Abstract: An anion substitution route was utilized for lowering the dielectric loss in CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) by partial replacement of oxygen by fluorine. This substitution, confirmed by fluorine analysis, reduced tan {delta}, and retained a high dielectric constant that was essentially temperature independent from 25 to 200 deg. C at 100 kHz.

  3. 2014 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2014 Wed, 2014-12-17 16:26 Jefferson Lab Weekly Briefs December 17, 2014 Wed, 2014-12-10 17:59 Jefferson Lab Weekly Briefs December 10, 2014 Wed, 2014-12-03 17:13 Jefferson Lab Weekly Briefs December 3

  4. Anomalous change in dielectric constant of CaCu{sub 3}Ti{sub 4}O{sub 12} under violet-to-ultraviolet irradiation

    SciTech Connect (OSTI)

    Masingboon, C.; Faculty of Science and Engineering, Kasetsart University, Chalermphrakiat Sakon Nakhon Province Campus, Sakon Nakhon 47000 ; Eknapakul, T.; Suwanwong, S.; Buaphet, P.; Nakajima, H.; Mo, S.-K.; Thongbai, P.; King, P. D. C.; Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 ; Maensiri, S.; Meevasana, W.; Thailand Center of Excellence in Physics, CHE, Bangkok 10400; NANOTEC-SUT Center of Excellence on Advanced Functional Nanomaterials, Suranaree University of Technology, Nakhon Ratchasima 30000

    2013-05-20

    The influence of light illumination on the dielectric constant of CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) polycrystals is studied in this work. When exposed to 405-nm laser light, a reversible enhancement in the room temperature capacitance as high as 22% was observed, suggesting application of light-sensitive capacitance devices. To uncover the microscopic mechanisms mediating this change, we performed electronic structure measurements, using photoemission spectroscopy, and measured the electrical conductivity of the CCTO samples under different conditions of light exposure and oxygen partial pressure. Together, these results suggest that the large capacitance enhancement is driven by oxygen vacancies induced by the irradiation.

  5. 12O

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O Ground-State Decay Evaluated Data Measured Ground-State Γcm for 12O Adopted value: 0.40 ± 0.25 MeV (1990AJ01) Measured Mass Excess for 12O Adopted value: 32048 ± 18 keV (2003AU02) Measurements 1978KE06: 16O(α, 8He), E = 117 MeV; measured σ(θ); deduced Q. 12O deduced mass excess, Γcm, diproton decay. 1980BU15: 12C(π+, π-), E = 180 MeV; measured σ(θ), Q. 12O deduced masses. 1980MOZX: 12C(π+, π-), E = 180 MeV; measured mass spectra, θ = 5°. 12O deduced masses. 1986FAZY: 12C(π+,

  6. Lithium protects against methamphetamine-induced neurotoxicity in PC12 cells via Akt/GSK3β/mTOR pathway

    SciTech Connect (OSTI)

    Wu, Jintao; Zhu, Dexiao; Zhang, Jing; Li, Guibao; Liu, Zengxun; Sun, Jinhao

    2015-09-25

    Methamphetamine (MA) is neurotoxic, especially in dopaminergic neurons. Long-lasting exposure to MA causes psychosis and increases the risk of Parkinson's disease. Lithium (Li) is a known mood stabilizer and has neuroprotective effects. Previous studies suggest that MA exposure decreases the phosphorylation of Akt/GSK3β pathway in vivo, whereas Li facilitates the phosphorylation of Akt/GSK3β pathway. Moreover, GSK3β and mTOR are implicated in the locomotor sensitization induced by psychostimulants and mTOR plays a critical role in MA induced toxicity. However, the effect of MA on Akt/GSK3β/mTOR pathway has not been fully investigated in vitro. Here, we found that MA exposure significantly dephosphorylated Akt/GSK3β/mTOR pathway in PC12 cells. In addition, Li remarkably attenuated the dephosphorylation effect of MA exposure on Akt/GSK3β/mTOR pathway. Furthermore, Li showed obvious protective effects against MA toxicity and LY294002 (Akt inhibitor) suppressed the protective effects of Li. Together, MA exposure dephosphorylates Akt/GSK3β/mTOR pathway in vitro, while lithium protects against MA-induced neurotoxicity via phosphorylation of Akt/GSK3β/mTOR pathway. - Highlights: • Lithium protects against methamphetamine-induced neurotoxicity in vitro. • Methamphetamine exposure dephosphorylates Akt/GSK3β/mTOR pathway. • Lithium attenuates methamphetamine-induced toxicity via phosphorylating Akt/GSK3β/mTOR pathway.

  7. ZPR-3 Assembly 12 : A cylindrical assembly of highly enriched uranium, depleted uranium and graphite with an average {sup 235}U enrichment of 21 atom %.

    SciTech Connect (OSTI)

    Lell, R. M.; McKnight, R. D.; Perel, R. L.; Wagschal, J. J.; Nuclear Engineering Division; Racah Inst. of Physics

    2010-09-30

    Over a period of 30 years, more than a hundred Zero Power Reactor (ZPR) critical assemblies were constructed at Argonne National Laboratory. The ZPR facilities, ZPR-3, ZPR-6, ZPR-9 and ZPPR, were all fast critical assembly facilities. The ZPR critical assemblies were constructed to support fast reactor development, but data from some of these assemblies are also well suited for nuclear data validation and to form the basis for criticality safety benchmarks. A number of the Argonne ZPR/ZPPR critical assemblies have been evaluated as ICSBEP and IRPhEP benchmarks. Of the three classes of ZPR assemblies, engineering mockups, engineering benchmarks and physics benchmarks, the last group tends to be most useful for criticality safety. Because physics benchmarks were designed to test fast reactor physics data and methods, they were as simple as possible in geometry and composition. The principal fissile species was {sup 235}U or {sup 239}Pu. Fuel enrichments ranged from 9% to 95%. Often there were only one or two main core diluent materials, such as aluminum, graphite, iron, sodium or stainless steel. The cores were reflected (and insulated from room return effects) by one or two layers of materials such as depleted uranium, lead or stainless steel. Despite their more complex nature, a small number of assemblies from the other two classes would make useful criticality safety benchmarks because they have features related to criticality safety issues, such as reflection by soil-like material. ZPR-3 Assembly 12 (ZPR-3/12) was designed as a fast reactor physics benchmark experiment with an average core {sup 235}U enrichment of approximately 21 at.%. Approximately 68.9% of the total fissions in this assembly occur above 100 keV, approximately 31.1% occur below 100 keV, and essentially none below 0.625 eV - thus the classification as a 'fast' assembly. This assembly is Fast Reactor Benchmark No. 9 in the Cross Section Evaluation Working Group (CSEWG) Benchmark Specifications

  8. Lattice Mn3+ Behaviors in Li4Ti5O12/LiNi0.5Mn1.5O4 Full Cells

    SciTech Connect (OSTI)

    Zheng, Jianming; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2013-05-28

    High voltage spinels LiNi0.5Mn1.5O4 (LNMO) with different contents of residual Mn3+ ions have been evaluated in full cells using Li4Ti5O12 (LTO) as standard anode. Greatly improved cycling stability has been observed for all spinels in LTO-limited full cell, compared with those in LNMO-limited ones, while the underlying mechanisms are quite different. It has been discovered that the participation of active Mn3+ in the extended cycling and thus its observable contribution to Li+ diffusion kinetics depend on the limiting electrode and the sufficiency of Li+ ions. Potential Mn dissolution has also been discussed to identify the key factors that need to be considered to construct full cells employing high voltage spinel as the cathode.

  9. Spin current and inverse spin Hall effect in ferromagnetic metals probed by Y{sub 3}Fe{sub 5}O{sub 12}-based spin pumping

    SciTech Connect (OSTI)

    Wang, Hailong; Du, Chunhui; Chris Hammel, P. Yang, Fengyuan

    2014-05-19

    Using ferromagnetic (FM) resonance spin pumping, we observe injection of spin currents from Y{sub 3}Fe{sub 5}O{sub 12} (YIG) films to FM metals, including Ni{sub 81}Fe{sub 19} (Py), Fe, Co, and Ni, and detection of spin currents by inverse spin Hall effect (ISHE) in the FM metals. We obtain a high effective spin mixing conductance of 6.3 × 10{sup 18} m{sup −2} in a YIG/Cu/Py trilayer and a spin Hall angle of 0.020 for Py. The spin pumping signals in Fe, Co, and Ni confirm the mechanism of ISHE in FMs is the inverse process of the anomalous Hall effect.

  10. Beta 3 at Y-12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    235 for Little Boy. The feed material from first the Alpha calutrons, next the S-50 Thermal Diffusion Plant and finally the output of the K-25 Gaseous Diffusion Plant was...

  11. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Print Structurally Integrated Biology for Life Sciences (SIBYLS) Scientific discipline: Structural biology GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics...

  12. Beamline 12.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Microprobe, polychromatic and monochromatic experiments Scientific applications Stress measurements in thin films and bulk materials. Spatially resolved sample characterization...

  13. Beamline 12.3.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    view it Life Sciences Division, Berkeley Lab Phone: (510) 486-8179 Fax: (510) 486-5298 Jane Tanamachi Life Sciences Division, Berkeley Lab Phone: (510) 495-22404 Fax: (510)...

  14. Microstructure and electrical properties in W/Nb co-doped Aurivillius phase Bi{sub 4}Ti{sub 3}O{sub 12} piezoelectric ceramics

    SciTech Connect (OSTI)

    Peng, Zhihang; Chen, Qiang; Chen, Yu; Xiao, Dingquan; Zhu, Jianguo

    2014-11-15

    Highlights: • W/Nb codoped BIT ceramics were prepared by the mixed oxides route. • High nd{sup 0} electronic configuration of W/Nb reduces the lattice distortion and T{sub C}. • Oxygen vacancy is responsible for dielectric relaxation and DC conduction process. • W/Nb additives significantly enhanced the piezoelectric coefficient d{sub 33} value. • BWNb-10 ceramics possessed large remnant polarization and a wide sintering window. - Abstract: Aurivillius-type Bi{sub 4}Ti{sub 3-x}W{sub x/2}Nb{sub x/2}O{sub 12} ceramics were prepared by a conventional solid-state sintering method. The XRD patterns demonstrated that all compositions were a single three layered crystalline structure, involving a reduction of lattice distortion with an increase in W/Nb doping level. The electrical properties including dielectric, electrical conduction and piezoelectric properties were tailored by W/Nb additives. The Curie-temperature decreased, whereas the electrical resistivity drastically increased with introduction of W/Nb donor dopants. As a result, a high electric field can be applied during the poling process. The Bi{sub 4}Ti{sub 2.9}W{sub 0.05}Nb{sub 0.05}O{sub 12} ceramics exhibited optimum piezoelectric coefficient (d{sub 33} ∼22.8 pC/N), large remnant polarization (2P{sub r} ∼26.8 μC/cm{sup 2} @ 200 °C) together with a high Curie temperature (T{sub C} ∼635 °C). Furthermore, this composition possessed a wide sintering window with outstanding piezoelectric properties. These parameters indicate that Bi{sub 4}Ti{sub 2.9}W{sub 0.05}Nb{sub 0.05}O{sub 12}-based ceramic is a promising candidate for high temperature piezoelectric applications.

  15. Identification of process related trace level impurities in the actinide decorporation agent 3,4,3-LI(1,2-HOPO): Nozzle–skimmer fragmentation via ESI LC–QTOFMS

    SciTech Connect (OSTI)

    Panyala, Nagender R.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J.

    2014-08-12

    We report that 3,4,3-LI(1,2-HOPO) is a chelating ligand and decorporation agent that can remove radioactive lanthanides and actinides from the body. Identification of trace impurities in drug samples is gaining much interest due to their significant influence on drug activity. In this study, trace impurities were detected in manufactured lots of 3,4,3-LI(1,2-HOPO) by a developed method of Liquid Chromatography coupled with photo-diode array UV detection and Electrospray Ionization-Quadrupole Time of Flight Mass spectrometry (LC-QTOFMS), via induced-in-source or collision-induced mass fragmentation (Nozzle-Skimmer Fragmentation). Molecular ions were fragmented within the nozzle-skimmer region of electrospray ionization (ESI) mass spectrometer equipped with a Time of Flight detector. Eight major (detected at levels higher than a 0.1% threshold) and seven minor trace impurities were identified. The respective structures of these impurities were elucidated via analysis of the generated fragment ions using mass fragmentation and elemental composition software. Proposed structures of impurities were further confirmed via isotopic modeling.

  16. Identification of process related trace level impurities in the actinide decorporation agent 3,4,3-LI(1,2-HOPO): Nozzle–skimmer fragmentation via ESI LC–QTOFMS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Panyala, Nagender R.; Sturzbecher-Hoehne, Manuel; Abergel, Rebecca J.

    2014-08-12

    We report that 3,4,3-LI(1,2-HOPO) is a chelating ligand and decorporation agent that can remove radioactive lanthanides and actinides from the body. Identification of trace impurities in drug samples is gaining much interest due to their significant influence on drug activity. In this study, trace impurities were detected in manufactured lots of 3,4,3-LI(1,2-HOPO) by a developed method of Liquid Chromatography coupled with photo-diode array UV detection and Electrospray Ionization-Quadrupole Time of Flight Mass spectrometry (LC-QTOFMS), via induced-in-source or collision-induced mass fragmentation (Nozzle-Skimmer Fragmentation). Molecular ions were fragmented within the nozzle-skimmer region of electrospray ionization (ESI) mass spectrometer equipped with a Timemore » of Flight detector. Eight major (detected at levels higher than a 0.1% threshold) and seven minor trace impurities were identified. The respective structures of these impurities were elucidated via analysis of the generated fragment ions using mass fragmentation and elemental composition software. Proposed structures of impurities were further confirmed via isotopic modeling.« less

  17. Synthesis and crystal structure of bis(3-ammoniumphenyl) sulfone dinitrate [C{sub 12}H{sub 14}N{sub 2}O{sub 2}S](NO{sub 3}){sub 2}

    SciTech Connect (OSTI)

    Mahroug, A.; Belhouchet, M. Mhiri, T.

    2013-07-15

    A new organic nitrate with the formula [C{sub 12}H{sub 14}N{sub 2}O{sub 2}S](NO{sub 3}){sub 2}, has been prepared and analyzed by X-ray diffraction. This compound crystallizes in the orthorhombic system: a = 16.771 (3), b = 13.884(2), c = 13.884(2) A, V = 3232.7(7)A{sup 3}, Z = 8, space group Pna2{sub 1}. Crystal structure can be described as a succession of organic and inorganic layers parallel to b, c plane. H-bonds between the different species play an important role in the three-dimensional network cohesion.

  18. Influence of Yb{sub 2}O{sub 3} on electrical and microstructural characteristics of CaCu{sub 3}Ti{sub 4}O{sub 12} ceramics

    SciTech Connect (OSTI)

    He, Kai; Luo, Yun; Yu, Renhong; Qi, Jiapeng; Sun, Xiujuan; Yang, Yongtao; Xu, Hongxing; Ma, Jing; Xu, Dong

    2015-09-15

    Graphical abstract: Some Yb atoms entered in the lattice of CCTO substituted the Ca sites, the rest of Yb atoms concentrated at grain boundaries decreased the grain size. The dielectric constant was decreased by Yb doping. The dielectric loss of the CCTO could be greatly reduced at low frequency. - Highlights: • Yb atoms may take the place of Ca sites and concentrate at grain boundaries. • Tiny second phase corresponding to Yb may decrease the grain size. • Decrease of the grain size leads to the decrease of dielectric constant. • Yb doping could decrease the dielectric loss of CCTO. - Abstract: This paper focuses on the remarkable effects of Yb{sub 2}O{sub 3} doping on the microstructure and dielectric characteristics of CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO). Samples were prepared by the solid phase reaction method and sintered in air at 1030 °C for 12 h. X-ray diffraction and X-ray photoelectron spectroscopy studies confirm that the primary phase is CCTO. Some Yb{sup 3+} ions may substitute into the Ca site at the center or zenith sites of the CCTO lattice hexahedron, while the rest of the Yb atoms may concentrate at grain boundaries. The grain size of Yb{sub 2}O{sub 3}-doped CCTO ceramics were examined by scanning electron microscopy and demonstrate sharp grain size reduction with Yb{sub 2}O{sub 3} doping. From dielectric property measurements, the Yb{sub 2}O{sub 3} doping reduces the dielectric constant of CCTO, and the dielectric loss is also reduced.

  19. HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

    SciTech Connect (OSTI)

    John D. Bess; Barbara H. Dolphin; James W. Sterbentz; Luka Snoj; Igor Lengar; Oliver Köberl

    2013-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.

  20. HTR-PROTEUS Pebble Bed Experimental Program Cores 1, 1A, 2, and 3: Hexagonal Close Packing with a 1:2 Moderator-to-Fuel Pebble Ratio

    SciTech Connect (OSTI)

    John D. Bess; Barbara H. Dolphin; James W. Sterbentz; Luka Snoj; Igor Lengar; Oliver Köberl

    2012-03-01

    In its deployment as a pebble bed reactor (PBR) critical facility from 1992 to 1996, the PROTEUS facility was designated as HTR-PROTEUS. This experimental program was performed as part of an International Atomic Energy Agency (IAEA) Coordinated Research Project (CRP) on the Validation of Safety Related Physics Calculations for Low Enriched HTGRs. Within this project, critical experiments were conducted for graphite moderated LEU systems to determine core reactivity, flux and power profiles, reaction-rate ratios, the worth of control rods, both in-core and reflector based, the worth of burnable poisons, kinetic parameters, and the effects of moisture ingress on these parameters. Four benchmark experiments were evaluated in this report: Cores 1, 1A, 2, and 3. These core configurations represent the hexagonal close packing (HCP) configurations of the HTR-PROTEUS experiment with a moderator-to-fuel pebble ratio of 1:2. Core 1 represents the only configuration utilizing ZEBRA control rods. Cores 1A, 2, and 3 use withdrawable, hollow, stainless steel control rods. Cores 1 and 1A are similar except for the use of different control rods; Core 1A also has one less layer of pebbles (21 layers instead of 22). Core 2 retains the first 16 layers of pebbles from Cores 1 and 1A and has 16 layers of moderator pebbles stacked above the fueled layers. Core 3 retains the first 17 layers of pebbles but has polyethylene rods inserted between pebbles to simulate water ingress. The additional partial pebble layer (layer 18) for Core 3 was not included as it was used for core operations and not the reported critical configuration. Cores 1, 1A, 2, and 3 were determined to be acceptable benchmark experiments.

  1. Chapter 12 - HOISTS JIB CRANES AND MONORAILS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0 - HOISTS, JIB CRANES, AND MONORAIL SYSTEMS January 4, 2016 Rev 1 Page 1 CHAPTER 12.0 TABLE OF CONTENTS 12.0 HOISTS, JIB CRANES, AND MONORAIL SYSTEMS ............................................................ 3 12.1 SCOPE ......................................................................................................................................... 3 12.2 GENERAL REQUIREMENTS ................................................................................................. 3 12.3

  2. Y-12

    National Nuclear Security Administration (NNSA)

    to shear and trap bolt heads during demolition projects, has been licensed by Y-12 to Green Arc Labs (GAL) of Chattanooga.

  3. ch_12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    .0 12.0 Distribution Distribution List List - New Information - 12-1 DOE/EIS-0287 The U.S. Department of Energy (DOE) pro- vided copies of this Final Environmental Impact Statement (EIS) to Federal, state, and local elected and appointed officials and agencies of government; Native American groups; national, state, and local environmental and public interest groups; and other organizations and individuals list- ed below. In addition, DOE sent copies of the Final EIS to all persons who comment-

  4. CHAPTER 12

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    . 12-1 CHAPTER 12 INTER-ENTITY TRANSACTIONS 1. INTRODUCTION. a. Purpose. The chapter establishes the principles and procedures of financing and accounting for costs of work performed by one DOE office or site/facility management contractor for another, and sets forth the policy governing property transfers to and from Federal agencies. Specific accounts to be used for transfers are further identified in the Standard General Ledger Chart of Accounts and Related Codes. b. Applicability. The

  5. A study of suppressed formation of low-conductivity phases in doped Li7La3Zr2O12 garnets by in situ neutron diffraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Yan; Rangasamy, Ezhiylmurugan; dela Cruz, Clarina R.; Liang, Chengdu; An, Ke

    2015-09-28

    Doped Li7La3Zr2O12 garnets, oxide-based solids with good Li+ conductivity and compatibility, show great potential as leading electrolyte material candidates for all-solid-state lithium ion batteries. Still yet, the conductive bulk usually suffers from the presence of secondary phases and the transition towards a low-conductivity tetragonal phase during synthesis. Dopants are designed to stabilize the high-conductive cubic phase and suppress the formation of the low-conductivity phases. In situ neutron diffraction enables a direct observation of the doping effects by monitoring the phase evolutions during garnet synthesis. It reveals the reaction mechanism involving the temporary presence of intermediate phases. The off-stoichiometry due tomore » the liquid Li2CO3 evaporation leads to the residual of the low-conductivity intermediate phase in the as-synthesized bulk. Appropriate doping of an active element may alter the component of the intermediate phases and promote the completion of the reaction. While the dopants aid to stabilize most of the cubic phase, a small amount of tetragonal phase tends to form under a diffusion process. Lastly, the in situ observations provide the guideline of process optimization to suppress the formation of unwanted low-conductivity phases.« less

  6. Nonlinear optical absorption tuning in Bi{sub 3.15}Nd{sub 0.85}Ti{sub 3}O{sub 12} ferroelectric thin films by thickness

    SciTech Connect (OSTI)

    Li, S.; Zhong, X. L. E-mail: jbwang@xtu.edu.cn; Zhang, Y.; Wang, J. B. E-mail: jbwang@xtu.edu.cn; Song, H. J.; Tan, C. B.; Li, B.; Cheng, G. H.; Liu, X.

    2015-04-06

    The tunability of nonlinear optical (NLO) absorption in Bi{sub 3.15}Nd{sub 0.85}Ti{sub 3}O{sub 12} (BNT) ferroelectric thin films was investigated through the open aperture Z-scan method with femtosecond laser pulses at the wavelength of 800 nm. NLO absorption responses of the BNT films were observed to be highly sensitive to the film thickness. As the film thickness increases from 106.8 to 139.7 nm, the NLO absorption changes from saturable absorption (SA) to reverse saturable absorption (RSA). When the film thickness further increases to 312.9 nm, the RSA effect is enhanced. A band-gap-related competition between the ground-state excitation and the two-photon absorption is responsible for the absorption switching behavior. Such a tunable NLO absorption can widen the photonic application of the BNT thin films.

  7. LM 12-13

    Office of Energy Efficiency and Renewable Energy (EERE)

    NEPA ID: LM 12-13Determination: B1.3Short Title: Road maintenance on roads used to access groundwater monitoring wells south of the Tuba City, Arizona, Uranium Mill Tailing Remedial Action (UMTRA)...

  8. 12C Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p, X) (Current as of 05/15/2012) NSR Reaction Ep (MeV) Cross Section File X4 Dataset Date Added 2001NE15 12C(p, γ): σ, deduced S(E) ratio < 160 keV X4 10/28/2014 1993CH02 12C(p, X): σ for η production ≤ 0.9 GeV X4 03/07/2012 1974RO29 12C(p, γ): σ 150 - 3000 keV X4 08/27/2013 1951GO1B 12C(p, p): yield curve of elastic scattering 0.2 - 4.0 θ = 164° 11/05/2014 1976ME22 12C(p, p): absolute σ 0.3 - 2.0 X4 08/07/2013 2008BU19 12C(p, γ): σ, deduced S-factors. 354, 390, 460, 463, 565,

  9. Growth and luminescent properties of scintillators based on the single crystalline films of Lu{sub 3−x}Gd{sub x}Al{sub 5}O{sub 12}:Ce garnet

    SciTech Connect (OSTI)

    Zorenko, Yu; Gorbenko, V.; Vasylkiv, Ja; Zelenyj, A.; Fedorov, A.; Kucerkova, R.; Mares, J.A.; Nikl, M.; Bilski, P.; Twardak, A.

    2015-04-15

    Highlights: • Single crystalline films of Lu{sub 3−x}Gd{sub x}Al{sub 5}O{sub 12} garnets at x = 0 ÷ 3.0 were grown by LPE method onto YAG substrates. • Lattice constant of Lu{sub 3−}Gd{sub x}Al{sub 5}O{sub 12}:Ce film and the misfit m between films and YAG substrate changed linearly with increasing of Gd content. • Effective Gd{sup 3+}–Ce{sup 3+} energy transfer occurs in the Lu{sub 3−x}Gd{sub x}Al{sub 5}O{sub 12}:Ce films. • Best scintillation light yield is observed in the Lu{sub 3}Al{sub 5}O{sub 12}:Ce and Lu{sub 2.4}Gd{sub 0.6}Al{sub 5}O{sub 12}:Ce films. • Increase of the Gd content in x = 1.5–2.5 range results in decreasing the scintillation LY of Lu{sub 3−x}Gd{sub x}Al{sub 5}O{sub 12}:Ce films. - Abstract: The work is related to the growth of scintillators based on the single crystalline films (SCF) of Ce{sup 3+} doped Lu{sub 3−}Gd{sub x}Al{sub 5}O{sub 12} mixed rare-earth garnets by Liquid Phase Epitaxy (LPE) method. We have shown, that full set of Lu{sub 3−}Gd{sub x}Al{sub 5}O{sub 12} SCFs with x values ranging from 0 to 3.0 can be successfully crystallized by the LPE method onto Y{sub 3}Al{sub 5}O{sub 12} (YAG) substrates from the melt-solutions based on PbO-B{sub 2}O{sub 3} flux. The absorption, X-ray excited luminescence, photoluminescence, thermoluminescence and light yield measurements, the latter under excitation by α-particles of {sup 239}Pu and {sup 241}Am radioisotopes, were applied for their characterization.

  10. 12B

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Neutron Capture Evaluated Data Measurements 1989TAZR: 11B(n, γ), E = thermal; measured Eγ. 12B deduced absolute γ-yields. 2003MOZU: 11B(n, γ); compiled, analyzed capture σ, neutron binding energies. 2008FIZZ: 11B(n, γ), E = thermal; measured cross sections; deduced cross section balance. 2010LE02: 11B(n, γ); 2H(11B, p); E = 81 MeV; deduced reaction rates of astrophysical relevance, and abundances of 11B and 12B in r process. 2011SL01: 11B(n, γ), E = thermal; compiled, evaluated

  11. Uranium at Y-12: Accountability | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Uranium at Y-12: Accountability Posted: July 22, 2013 - 3:37pm | Y-12 Report | Volume 10, Issue 1 | 2013 Accountability of enriched uranium is facilitated by the ability to put ...

  12. Uranium at Y-12: Inspection | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inspection Uranium at Y-12: Inspection Posted: July 22, 2013 - 3:36pm | Y-12 Report | Volume 10, Issue 1 | 2013 Inspection of enriched uranium is performed by dimensional checks and ...

  13. Uranium at Y-12: Recovery | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recovery Uranium at Y-12: Recovery Posted: July 22, 2013 - 3:44pm | Y-12 Report | Volume 10, Issue 1 | 2013 Recovery involves reclaiming uranium from numerous sources and ...

  14. Uranium at Y-12: Casting | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Casting Uranium at Y-12: Casting Posted: July 22, 2013 - 3:42pm | Y-12 Report | Volume 10, Issue 1 | 2013 Buttons and other recycled metal are used in casting components for ...

  15. Y-12 Bulletin Uranium Articles | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bulletin Uranium ... Y-12 Bulletin Uranium Articles Posted: July 22, 2013 - 3:13pm | Y-12 Report | Volume 10, Issue 1 | 2013 These and other articles can be found in archived ...

  16. Y-12/UT | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    /UT Y-12/UT The mp4 video format is not supported by this browser. Download video Captions: On Time: 3:33 min. Learn how Y-12 and UT are benefitting by working together

  17. Tuning magnetotransport in PdPt/Y{sub 3}Fe{sub 5}O{sub 12}: Effects of magnetic proximity and spin-orbit coupling

    SciTech Connect (OSTI)

    Zhou, X.; Ma, L.; Shi, Z.; Zhou, S. M.; Guo, G. Y.; Hu, J.; Wu, R. Q.

    2014-07-07

    We report that anisotropic magnetoresistance (AMR) and anomalous Hall conductivity (AHC) in the Pd{sub 1−x}Pt{sub x}/Y{sub 3}Fe{sub 5}O{sub 12} (YIG) bilayers could be tuned by varying the Pt concentration (x) and also temperature (T). In particular, the AHC at low T changes its sign when x increases from 0 to 1, agreeing with the negative and positive AHC predicted by our ab initio calculations for the magnetic proximity (MP)-induced ferromagnetic Pd and Pt, respectively. The AMR ratio is enhanced by ten times when x increases from 0 to 1. Furthermore, the AMR of PdPt/YIG bilayers shows similar T-dependence as the magnetic susceptibility of the corresponding bulk Pd/Pt, also indicating the MP effect as the origin of the AMR. The present work demonstrates that the alloying of Pt and Pd not only offers tunable spin-orbit coupling but also is useful to reveal the nature of the AMR and AHC in Pt/YIG bilayers, which are useful for spintronics applications.

  18. Neutron Scattering Studies of the Interplay of Amyloid β Peptide(1–40) and An Anionic Lipid 1,2-dimyristoyl-sn-glycero-3-phosphoglycerol

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rai, Durgesh K.; Sharma, Veerendra K.; Anunciado, Divina; O’Neill, Hugh; Mamontov, Eugene; Urban, Volker; Heller, William T.; Qian, Shuo

    2016-08-09

    The interaction between lipid bilayers and Amyloid β peptide (Aβ) plays a critical role in proliferation of Alzheimer’s disease (AD). AD is expected to affect one in every 85 humans by 2050, and therefore, deciphering the interplay of Aβ and lipid bilayers at the molecular level is of profound importance. In this work, we applied an array of neutron scattering methods to study the structure and dynamics of Aβ(1–40) interacting 1,2-dimyristoyl-sn-glycero-3-phosphoglycerol (DMPG) bilayers. In the structural investigations of lipid bilayer’s response to Aβ binding, Small Angle Neutron Scattering and Neutron Membrane Diffraction revealed that the Aβ anchors firmly to themore » highly charged DMPG bilayers in the interfacial region between water and hydrocarbon chain, and it doesn’t penetrate deeply into the bilayer. This association mode is substantiated by the dynamics studies with high resolution Quasi-Elastic Neutron Scattering experiments, showing that the addition of Aβ mainly affects the slower lateral motion of lipid molecules, especially in the fluid phase, but not the faster internal motion. The results revealed that Aβ associates with the highly charged membrane in surface with limited impact on the structure, but the altered membrane dynamics could have more influence on other membrane processes.« less

  19. Dynamic compression of dense oxide (Gd3Ga5O12) from 0.4 to 2.6 TPa: Universal Hugoniot of fluid metals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ozaki, N.; Nellis, W. J.; Mashimo, T.; Ramzan, M.; Ahuja, R.; Kaewmaraya, T.; Kimura, T.; Knudson, M.; Miyanishi, K.; Sakawa, Y.; et al

    2016-05-19

    Materials at high pressures and temperatures are of great current interest for warm dense matter physics, planetary sciences, and inertial fusion energy research. Shock-compression equation-of-state data and optical reflectivities of the fluid dense oxide, Gd3Ga5O12 (GGG), were measured at extremely high pressures up to 2.6 TPa (26 Mbar) generated by high-power laser irradiation and magnetically-driven hypervelocity impacts. Above 0.75 TPa, the GGG Hugoniot data approach/reach a universal linear line of fluid metals, and the optical reflectivity most likely reaches a constant value indicating that GGG undergoes a crossover from fluid semiconductor to poor metal with minimum metallic conductivity (MMC). Thesemore » results suggest that most fluid compounds, e.g., strong planetary oxides, reach a common state on the universal Hugoniot of fluid metals (UHFM) with MMC at sufficiently extreme pressures and temperatures. Lastly, the systematic behaviors of warm dense fluid would be useful benchmarks for developing theoretical equation-of-state and transport models in the warm dense matter regime in determining computational predictions.« less

  20. Investigation of phase evolution of CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) by in situ synchrotron high-temperature powder diffraction

    SciTech Connect (OSTI)

    Ouyang, Xin; Huang, Saifang; Zhang, Weijun; Cao, Peng; Huang, Zhaohui; Gao, Wei

    2014-03-15

    In situ synchrotron X-ray powder diffraction was used to study the high-temperature phase evolution of CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) precursors prepared via solid-state and sol–gel methods. After the precursors are heated to 1225 °C, the CCTO phase is the main phase observed in the calcined powder, with the presence of some minor impurities. Comparing the two precursors, we found that the onset temperature for the CCTO phase formation is 800 °C in the sol–gel precursor, lower than that in the solid-state precursor (875 °C). Intermediate phases were only observed in the sol–gel precursor. Both precursors are able to be calcined to sub-micrometric sized powders. Based on the synchrotron data along with differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA), the phase formation sequence and mechanism during calcination are proposed in this study. -- Graphical abstract: The in situ synchrotron HT-XRD patterns of CCTO sol–gel and solid-state precursor. Highlights: • Phase formation sequence/mechanism in two CCTO precursors has been established. • Formation temperature of CCTO via sol–gel method is lower than solid-state method. • Intermediate phases are only observed in the sol–gel precursor. • Both precursors are able to be calcined into sub-micrometric sized powders.

  1. A=12B (1990AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    states are populated (1986AS02). 6. 9Be(7Li, )12B Qm 10.460 Observed -particle groups are displayed in Table Prev. Table 12.3 preview 12.3 (in PDF or PS). Angular...

  2. 12C Cross Section

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    α, X) (Current as of 05/14/2012) NSR Reaction Eα (MeV) Cross Section File X4 Dataset Date Added 2009MA70 12C(α, γ0): σ 0 - 2.27 X4 05/01/2012 2012OU01 12C(α, γ): deduced S-factor Ecm = 0.3 - 3.5 X4 02/12/2015 1997KU18 12C(α, γ): analyzed S-factor Ecm = 0.9 - 3 X4 05/10/2012 1987RE02 12C(α, γ): σ, deduced S-factor 0.94 - 2.84 X4 05/09/2012 2001HA31 12C(α, γ): deduced S-factors Ecm = 0.95 - 2.78 E1, E2 06/18/2012 2001KU09 12C(α, γ): deduced S-factor Ecm = 0.95 - 2.8 X4 05/09/2012

  3. Grain size dependent phase stabilities and presence of a monoclinic (Pm) phase in the morphotropic phase boundary region of (1?x)Bi(Mg{sub 1/2}Ti{sub 1/2})O{sub 3}-xPbTiO{sub 3} piezoceramics

    SciTech Connect (OSTI)

    Upadhyay, Ashutosh; Singh, Akhilesh Kumar E-mail: aksingh.mst@itbhu.ac.in

    2015-04-14

    Results of the room temperature structural studies on (1?x)Bi(Mg{sub 1/2}Ti{sub 1/2})O{sub 3}-xPbTiO{sub 3} ceramics using Rietveld analysis of the powder x-ray diffraction data in the composition range 0.28???x???0.45 are presented. The morphotropic phase boundary region exhibits coexistence of monoclinic (space group Pm) and tetragonal (space group P4?mm) phases in the composition range 0.33???x???0.40. The structure is nearly single phase monoclinic (space group Pm) in the composition range 0.28???x???0.32. The structure for the compositions with x???0.45 is found to be predominantly tetragonal with space group P4?mm. Rietveld refinement of the structure rules out the coexistence of rhombohedral and tetragonal phases in the morphotropic phase boundary region reported by earlier authors. The Rietveld structure analysis for the sample x?=?.35 calcined at various temperatures reveals that phase fraction of the coexisting phases in the morphotropic phase boundary region varies with grain size. The structural parameters of the two coexisting phases also change slightly with changing grain size.

  4. New coordination polymers from 1D chain, 2D layer to 3D framework constructed from 1,2-phenylenediacetic acid and 1,3-bis(4-pyridyl)propane flexible ligands

    SciTech Connect (OSTI)

    Xin Lingyun; Liu Guangzhen; Wang Liya

    2011-06-15

    The hydrothermal reactions of Cd, Zn, or Cu(II) acetate salts with H{sub 2}PHDA and BPP flexible ligands afford three new coordination polymers, including [Cd(PHDA)(BPP)(H{sub 2}O)]{sub n}(1), [Zn(PHDA)(BPP)]{sub n}(2), and [Cu{sub 2}(PHDA){sub 2}(BPP)]{sub n}(3) (H{sub 2}PHDA=1,2-phenylenediacetic acid, BPP=1,3-bis(4-pyridyl)propane). The single-crystal X-ray diffractions reveal that all three complexes feature various metal carboxylate subunits extended further by the BPP ligands to form a diverse range of structures, displaying a remarked structural sensitivity to metal(II) cation. Complex 1 containing PHDA-bridged binuclear cadmium generates 1D double-stranded chain, complex 2 results in 2D{yields}2D interpenetrated (4,4) grids, and complex 3 displays a 3D self-penetrated framework with 4{sup 8}6{sup 6}8 rob topology. In addition, fluorescent analyses show that both 1 and 2 exhibit intense blue-violet photoluminescence in the solid state. - Graphical Abstract: We show diverse supramolecular frameworks based on the same ligands (PHDA and BPP) and different metal acetate salts including 1D double-stranded chain, 2D {yields} 2D twofold interpenetrated layer, and 3D self-penetration networks. Highlights: > Three metal(II = 2 /* ROMAN ) coordination polymers were synthesized using H{sub 2}PHDA and BPP. > The diversity of structures show a remarked sensitivity to metal(II) center. > Complexes show the enhancement of fluorescence compared to that of free ligand.

  5. c12.pdf

    U.S. Energy Information Administration (EIA) Indexed Site

    4,014 3,199 4,138 3,252 0.08 0.06 0.06 0.07 1.59 1.32 1.24 1.41 Table C12. Electricity Expenditures by Census Region, 1999 Total Electricity Expenditures (million...

  6. Synthesis and equation of state of post-perovskites in the (Mg,Fe)[subscript 3]Al[subscript 2]Si[subscript 3]O[subscript 12] system

    SciTech Connect (OSTI)

    Shieh, Sean R.; Dorfman, Susannah M.; Kubo, Atsushi; Prakapenka, Vitali B.; Duffy, Thomas S.

    2012-02-06

    The formation and properties of the post-perovskite (CaIrO{sub 3}-type) phase were studied in Fe-rich compositions along the pyrope-almandine ((Mg,Fe){sub 3}Al{sub 2}Si{sub 3}O{sub 12}) join. Natural and synthetic garnet starting materials with almandine fractions from 38 to 90 mol% were studied using synchrotron X-ray diffraction in the laser-heated diamond anvil cell. Single-phase post-perovskite could be successfully synthesized from garnet compositions at pressures above 148 GPa and temperatures higher than 1600 K. In some cases, evidence for a minor amount of Al{sub 2}O{sub 3} post-perovskite was observed for Alm38 and Alm54 compositions in the perovskite + post-perovskite two-phase region. Pressure-volume data for the post-perovskite phases collected during decompression show that incorporation of Fe leads to a systematic increase of unit cell volume broadly similar to the variation observed in the (Mg,Fe)SiO{sub 3} system. The presence of Al{sub 2}O{sub 3} increases the stability of perovskite relative to post-perovskite, requiring higher pressures (> 148 GPa) for synthesis of pure post-perovskites. Our data together with those of Tateno et al. (2005) also suggest that in the Al-rich system the presence of Fe has no strong effect on the pressure required to synthesize the pure post-perovskite phase, but the two-phase perovskite and post-perovskite region may be broad and its width dependent on Fe content. Our results suggest that any regions highly enriched in Al{sub 2}O{sub 3} may consist of either the perovskite phase or a mixture of perovskite and post-perovskite phases throughout the entire thickness of the D* region. The observed synthesis pressures (> 148 GPa) for a pure post-perovskite phase are beyond that at the Earth's core-mantle boundary ({approx} 135 GPa).

  7. The greening of Y-12 | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The greening of Y-12 The greening of Y-12 Posted: September 9, 2013 - 2:48pm With more than 1,230 pollution prevention initiatives reducing some 2.07 billion pounds of waste since 1993, Y-12 sustainability programs yielded $70.7 million in cost efficiencies to the Y-12 Complex, and consequently, to taxpayers. Here are a few other Y-12 green facts: In FY 2012, Y-12 recycled more than 3 million pounds of materials off-site including routine paper, cardboard, wooden pallets, scrap metal, lamps,

  8. A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} for near UV white light-emitting diodes

    SciTech Connect (OSTI)

    Yang, Zhigang; Zhao, Zhengyan; Shi, Yurong; Wang, Yuhua

    2013-10-15

    Graphical abstract: - Highlights: Novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was prepared by solid-state reaction. Excitation spectra suggested an obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited a red emission at 614 nm. Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white LEDs. - Abstract: A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was synthesized using a solid-state reaction method, and its luminescence characteristics and charge compensators effect (Li{sup +}, Na{sup +}, K{sup +}) were investigated. The excitation spectra showed a obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited an intense red emission at 614 nm. The Commission Internationale de lEclairage (CIE) chromaticity coordinates and quantum efficiency (QE) were (0.65, 0.35) and 62.3%, respectively. The good color saturation, high quantum efficiency and small thermal-quenching properties indicate that Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white light-emitting diodes.

  9. 1996 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Dec 1996 Fri, 1996-12-20 12:00 Hampton University Scientists Complete Historic Experiment

  10. A=12B (1980AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p)12B Qm -6.886 See (1968AJ02). 7. 9Be(7Li, )12B Qm 10.462 Observed -particle groups are displayed in Table 12.3 (in PDF or PS). Angular distributions have been...

  11. Synthesis, crystal structure, spectroscopic and thermal properties of [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl)-A new compound with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster core

    SciTech Connect (OSTI)

    Peric, Berislav; Jozic, Drazan; Planinic, Pavica; Brnicevic, Nevenka; Giester, Gerald

    2009-09-15

    A new hexanuclear cluster compound, [Et{sub 4}N][Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]Br{sub 4}.4H{sub 2}O (Et=ethyl) (1), with the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} cluster entity, was synthesized and characterized by elemental and TG/DTA analyses, IR and UV/Vis spectroscopy and by a single-crystal X-ray diffraction study. The presence of the paramagnetic [Ta{sub 6}Br{sub 12}]{sup 3+} unit was confirmed also by the room-temperature magnetic and EPR measurements. The compound crystallizes in the tetragonal I4{sub 1}/a space group, with a=14.299(5), c=21.241(5) A, Z=4, R{sub 1}(F)/wR{sub 2}(F{sup 2})=0.0296/0.0811. The structure contains discrete [Ta{sub 6}Br{sub 12}(H{sub 2}O){sub 6}]{sup 3+} cations with an octahedron of metal atoms edge-bridged by bromine atoms and with water molecules occupying all six terminal positions. The cluster units are positioned in the vertices of the three-dimensional (pseudo)diamond lattice. The structure shows similarities with literature reported structures of cluster compounds crystallizing in the diamond (Fd3-barm) space group. - Graphical abstract: Two interpenetrating (pseudo)diamond nets formed by packing of the paramagnetic [Ta{sub 6}Br{sub 12}(H{sub 2}O)]{sup 3+} (octahedral) and diamagnetic [Et{sub 4}N]{sup +} (spheres) cations.

  12. 12_01_1990.tex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.1 from (1990AJ01): Energy levels of 12 Be E x J π ; T τ 1/2 Decay Reactions (MeV ± keV) 0 0 + ; 2 τ 1/2 = 23.6 ± 0.9 ms β - 1, 2, 3 2.102 ± 12 2 + ; 2 a γ 2, 3 2.702 ± 17 a 2, 3 4.56 ± 25 b 2 5.70 ± 25 b 2 a See discussion in (1982BE42). b This state has an appreciable intrinsic width: see (1978AL29).

  13. The structure, thermal expansion and phase transition properties of Ho{sub 2}Mo{sub 3−x}W{sub x}O{sub 12} (x = 0, 1.0, 2.0) solid solutions

    SciTech Connect (OSTI)

    Liu, X.Z.; Hao, L.J.; Wu, M.M.; Ma, X.B.; Chen, D.F.; Liu, Y.T.

    2015-10-15

    Graphical abstract: A polymorph with Gd{sub 2}Mo{sub 3}O{sub 12}-type structure (space group: Pba2) for negative thermal expansion material Ho{sub 2}Mo{sub 3}O{sub 12} is observed above 700 °C, this polymorphism could be effectively supressed by W-substiution for Mo, the give the temperature dependence of Pba2 phase contents for Ho{sub 2}Mo{sub 3−x}W{sub x}O{sub 12} (x = 0.0, 1.0, 2.0). - Highlights: • The solid solution Ho{sub 2}Mo{sub 3−x}W{sub x}O{sub 12} was investigated by in situ X-ray diffraction. • It is found that the substitution slightly influence thermal expansion property. • A polymorph of Ho{sub 2}Mo{sub 3}O{sub 12} with Pba2 space group was observed above 700 °C. • The W-substitution for Mo effectively suppresses this transformation. - Abstract: Three solid solutions of Ho{sub 2}Mo{sub 3−x}W{sub x}O{sub 12}(x = 0, 1.0, 2.0) were prepared by solid state reaction method, the temperature dependent in-situ X-ray diffraction and thermal analysis were performed to investigate their structure and thermal expansion. All samples have orthorhombic structure(space group Pbcn# 60) with negative thermal expansion at the room temperature. the substitution of W for Mo enlarges the lattice constant and slightly influences the negative thermal expansion. An irreversible phase transformation to the Pba2 phase(Tb{sub 2}Mo{sub 3}O{sub 12} structure) was observed at high temperature for Mo-rich samples. This ploymorphism could be effectively suppressed by the W-substitution for Mo, this phenomenon could be explained by the lower electronegativity of W{sup 6+} than Mo{sup 6+}.

  14. Luminescence-Based Spectroelectrochemical Sensor for [Tc(dmpe)3]2+/+ (dmpe = 1,2-bis(dimethylphosphino)ethane) within a Charge-Selective Polymer Film

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Edwards, Matthew K.; Bryan, Samuel A.; Kaval, Necati; Pantelic, Nebojsa; Morris, Laura K.; Heineman, W. R.; Seliskar, Carl J.

    2011-03-01

    A spectroelectrochemical sensor consisting of an indium tin oxide (ITO) optically transparent electrode (OTE) coated with a thin film of sulfonated polystyrene-blockpoly(ethylene-ran-butylene)-block-polystyrene (SSEBS) was developed for [Tc(dmpe)3]+.. [Tc(dmpe)3]+ preconcentrated by ion-exchange into the SSEBS film after 20 min exposure to aqueous [Tc(dmpe)3]+ solution, resulting in a 14-fold increase in cathodic peak current compared to a bare OTE. Colorless [Tc(dmpe)3]+ was reversibly oxidized to colored [Tc(dmpe)3]2+ by cyclic voltammetry. Detection of [Tc(dmpe)3]2+ was accomplished by electrochemically cycling the complex between non-emissive [Tc(dmpe)3]+ and emissive [Tc(dmpe)3]2+ and monitoring the modulated emission (?exc = 532 nm; ?em = 660 nm). The sensor gave a linear response over the range of 0.16 to 340.0 M.

  15. Y-12 Knows Uranium | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Y-12 Knows Uranium Y-12 Knows Uranium Posted: July 22, 2013 - 3:45pm | Y-12 Report | Volume 10, Issue 1 | 2013 Y-12 produces many forms of uranium. They may be used in chemical processing steps on-site or shipped elsewhere to serve as raw materials for nuclear fuel or as research tools. All of uranium's uses, defense related and otherwise, are critical to the nation. Y-12's understanding of uranium, coupled with the site's work with enriched uranium metal, alloys, oxides, compounds and

  16. 2014 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 - 12 Dec 2014 Fri, 12/05/2014 - 10:14am Substantial Progress towards

  17. 2015 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2015 Mon, 12/21/2015 - 01:21pm 12 GeV!

  18. 2009 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Dec 2009 Tue, 2009-12-01 16:52 On Target December

  19. 2013 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Dec 2013 Thu, 2013-12-05 13:36 On Target December

  20. 2014 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Dec 2014 Thu, 2014-12-18 11:54 On Target December

  1. 2011 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2011 Wed, 12/07/2011 - 12:00am Awards

  2. 2012 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2012 Tue, 12/18/2012 - 12:00am 121212

  3. [Ni(H{sub 2}O){sub 4}]{sub 3}[U(OH,H{sub 2}O)(UO{sub 2}){sub 8}O{sub 12}(OH){sub 3}], crystal structure and comparison with uranium minerals with U{sub 3}O{sub 8}-type sheets

    SciTech Connect (OSTI)

    Rivenet, Murielle; Vigier, Nicolas; Roussel, Pascal; Abraham, Francis

    2009-04-15

    The new U(VI) compound, [Ni(H{sub 2}O){sub 4}]{sub 3}[U(OH,H{sub 2}O)(UO{sub 2}){sub 8}O{sub 12}(OH){sub 3}], was synthesized by mild hydrothermal reaction of uranyl and nickel nitrates. The crystal-structure was solved in the P-1 space group, a=8.627(2), b=10.566(2), c=12.091(4) A and alpha=110.59(1), beta=102.96(2), gamma=105.50(1){sup o}, R=0.0539 and wR=0.0464 from 3441 unique observed reflections and 151 parameters. The structure of the title compound is built from sheets of uranium polyhedra closely related to that in beta-U{sub 3}O{sub 8}. Within the sheets [(UO{sub 2})(OH)O{sub 4}] pentagonal bipyramids share equatorial edges to form chains, which are cross-linked by [(UO{sub 2})O{sub 4}] and [UO{sub 4}(H{sub 2}O)(OH)] square bipyramids and through hydroxyl groups shared between [(UO{sub 2})(OH)O{sub 4}] pentagonal bipyramids. The sheets are pillared by sharing the apical oxygen atoms of the [(UO{sub 2})(OH)O{sub 4}] pentagonal bipyramids with the oxygen atoms of [NiO{sub 2}(H{sub 2}O){sub 4}] octahedral units. That builds a three-dimensional framework with water molecules pointing towards the channels. On heating [Ni(H{sub 2}O){sub 4}]{sub 3}[U(OH,H{sub 2}O)(UO{sub 2}){sub 8}O{sub 12}(OH){sub 3}] decomposes into NiU{sub 3}O{sub 10}. - Graphical abstract: The framework of [Ni(H{sub 2}O){sub 4}]{sub 3}[U(OH,H{sub 2}O)(UO{sub 2}){sub 8}O{sub 12}(OH){sub 3}] built from uranium polyhedra sheets pillared by Ni-centered octahedra.

  4. 3

    National Nuclear Security Administration (NNSA)

    Laboratory, Special Operations and Research Division BAPC State of Nevada Bureau of Air Pollution Control BLM Bureau of Land Management BN Bechtel Nevada CAA Clean Air Act CaCO 3 ...

  5. NEPA Determination: LM-12a-12

    Broader source: Energy.gov [DOE]

    Additional Considerations Amendment to LM #12-12, Routine and Non-Routine Activities at the Grand Junction, Colorado, Office Site 

  6. Y-12 Volunteer Day 2015 | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Volunteer Day 2015 Y-12 Volunteer Day 2015 The mp4 video format is not supported by this browser. Download video Captions: On Time: 3:57 min. Hundreds of Y-12 employees friends and family members spread across several counties during Y-12's Day of Volunteering. View a short film highlighting efforts at the Volunteer Ministry Center in Knoxville, the Oak Ridge Nursery School, the Children's Museum of Oak Ridge and the Oak Ridge Heritage and Preservation Association

  7. A=12N (68AJ02)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    68AJ02) (See Energy Level Diagrams for 12N) GENERAL: See (NA64D, SH64H, ST64, KE66C, KE67F). See also Table 12.27 [Table of Energy Levels] (in PDF or PS). Mass of 12N: From a weighted average of the Q0 values for 10B(3He, n)12N and 12C(p, n)12N (see reactions 2 and 3), M - A for 12N = 17.342 ± 0.005 MeV. 1. 12N(β+)12C Qm = 17.342 Measured values of the half-life are displayed in Table 12.28 (in PDF or PS). The decay is complex; 12N decays to the ground state of 12C and to several excited

  8. One step, microwave assisted green synthesis of biocompatible carbon quantum dots and their composites with [α−PW{sub 12}O{sub 40}{sup 3−}] for visible light photocatalysis

    SciTech Connect (OSTI)

    Sahasrabudhe, Atharva Pant, Shashank Chatti, Manjunath Maiti, Binoy De, Priyadarsi Roy, Soumyajit

    2014-04-24

    We report a simple, rapid and green route for synthesis of fluorescent carbon quantum dots (CQDs) by microwave assisted pyrolysis method using polyleucine polymer (Boc-L-Leu-HEMA) as precursor and self-passivating agent. The as synthesized CQDs were found to possess low cytotoxicity, thus making them suitable candidates for bioimaging and bio-labelling. Moreover, nanocomposites of as prepared CQDs with [α−PW{sub 12}O{sub 40}{sup 3−}] polyoxometalate were synthesized and were shown to possess excellent photocatalytic properties under visible light towards degradation of organic dye pollutants. Based on the control experiments, a suitable mechanism has been proposed to explain the remarkable photoactivity of the CQD/[α−PW{sub 12}O{sub 40}{sup 3−}] composites.

  9. High-Temperature Thermoelectric Properties of the Solid-Solution Zintl Phase Eu11Cd6Sb12-xAsx (x < 3)

    SciTech Connect (OSTI)

    Kazem, Nasrin; Xie, Weiwei; Ohno, Saneyuki; Zevalkink, Alexandra; Miller, Gordon J.; Snyder, G. Jeffrey; Kauzlarich, Susan M.

    2014-02-20

    Zintl phases are compounds that have shown promise for thermoelectric applications. The title solid–solution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu11Cd6Sb12–xAsx (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr11Cd6Sb12 structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ~3 resulted in structures other than the Sr11Cd6Sb12 structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu11Cd6Sb10As2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.78–0.49 W/mK for x = 0; 0.72–0.53 W/mK for x = 1; and 0.70–0.56 W/mK for x = 2. Eu11Cd6Sb12 shows a high p-type Seebeck coefficient (from +118 to 153 μ V/K) but also high electrical resistivity (6.8 to 12.8 mΩ·cm). The value of zT reaches 0.23 at 774 K. The properties of Eu11Cd6Sb12–xAsx are interpreted in discussion with the As site substitution.

  10. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  11. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  12. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  13. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  14. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  15. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  16. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  17. Beamline 12.0.1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2.0.1 Print EUV optics testing and interferometry, angle- and spin-resolved photoemission Scientific discipline: Applied science, correlated electron systems Endstations: Angle- and spin-resolved photoemission (12.0.1.1) Berkeley Dose Calibration Tool (DCT)(12.0.1.2) SEMATECH Berkeley Microfield Exposure Tool (MET) (12.0.1.3) GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 8-cm-period undulator (U8) Energy range See endstation tables Monochromator See endstation tables

  18. Synthesis and physicochemical properties of Zr-MCM-41 mesoporous molecular sieves and Pt/H{sub 3}PW{sub 12}O{sub 40}/Zr-MCM-41 catalysts

    SciTech Connect (OSTI)

    Chen, L.F. Wang, J.A.; Norena, L.E.; Aguilar, J.; Navarrete, J.; Salas, P.; Montoya, J.A.; Del Angel, P.

    2007-10-15

    For the first time, modifications of the surface and framework of Si-MCM-41 by depositing a heteropolyacid on the surface and by introducing foreign Zr{sup 4+} ions into the framework are investigated. The Zr-modified Si-MCM-41 mesoporous materials (hereafter referred as WSZn, n=Si/Zr=25, 15, 8, 4) were synthesized through a surfactant-templated preparation approach, using low-cost fumed silica as the Si precursor. After impregnation with 25 wt% of H{sub 3}PW{sub 12}O{sub 40}, the surface Broensted acidity of the Pt/H{sub 3}PW{sub 12}O{sub 40}/WSZn catalysts was greatly enhanced by 2-10 times relative to the bare WSZn support. Two kinds of supported heteropolyacids were formed: (i) bulk-like heteropolyacid crystals with unchanged Keggin structures, and (ii) highly dispersed heteropolyacid with distorted Keggin units. The formation of various kinds of heteropolyacid structures is closely related to the interaction between the heteropolyanions and the hydroxyl groups in the host support. - Graphical abstract: Modifications of the surface and framework of Si-MCM-41 by depositing a heteropolyacid on the surface and by introducing foreign Zr{sup 4+} ions into the framework are investigated. Broensted acidity of the Pt/H{sub 3}PW{sub 12}O{sub 40}/Zr-MCM-41 catalysts was greatly enhanced by 2-10 times relative to the bare Zr-MCM-41 support.

  19. B&W Y-12 responds to NNSA's show cause letter | Y-12 National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    responds to ... B&W Y-12 responds to NNSA's show cause letter Posted: September 12, 2012 - 3:29pm On September 10, B&W Y-12 provided its response to the National Nuclear Security ...

  20. Y-12 Plant decontamination and decommissioning technology logic diagram for Building 9201-4. Volume 3: Technology evaluation data sheets; Part A: Characterization, dismantlement

    SciTech Connect (OSTI)

    1994-09-01

    The Y-12 Plant Decontamination and Decommissioning Technology Logic Diagram for Building 9201-4 (TLD) was developed to provide a decision-support tool that relates decontamination and decommissioning (D and D) problems at Bldg. 9201-4 to potential technologies that can remediate these problems. The TLD uses information from the Strategic Roadmap for the Oak Ridge Reservation, the Oak Ridge K-25 Site Technology Logic Diagram, the Oak Ridge National Laboratory Technology Logic Diagram, and a previous Hanford logic diagram. This TLD identifies the research, development, demonstration, testing, and evaluation needed for sufficient development of these technologies to allow for technology transfer and application to D and D and waste management (WM) activities. It is essential that follow-on engineering studies be conducted to build on the output of this project. These studies will begin by selecting the most promising technologies identified in the TLD and by finding an optimum mix of technologies that will provide a socially acceptable balance between cost and risk. This report consists of the characterization and dismantlement data sheets.

  1. Phase equilibria and crystal chemistry of the CaO1/2 Nd{sub 2}O{sub 3}CoO{sub z} system at 885 C in air

    SciTech Connect (OSTI)

    Wong-Ng, W.; Laws, W.; Talley, K.R.; Huang, Q.; Yan, Y.; Martin, J.; Kaduk, J.A.

    2014-07-01

    The phase diagram of the CaO1/2 Nd{sub 2}O{sub 3}CoO{sub z} system at 885 C in air has been determined. The system consists of two calcium cobaltate compounds that have promising thermoelectric properties, namely, the 2D thermoelectric oxide solid solution, (Ca{sub 3?x}Nd{sub x})Co{sub 4}O{sub 9?z} (0?x?0.5), which has a misfit layered structure, and Ca{sub 3}Co{sub 2}O{sub 6} which consists of 1D chains of alternating CoO{sub 6} trigonal prisms and CoO{sub 6} octahedra. Ca{sub 3}Co{sub 2}O{sub 6} was found to be a point compound without the substitution of Nd on the Ca site. The reported Nd{sub 2}CoO{sub 4} phase was not observed at 885 C. A ternary (Ca{sub 1?x}Nd{sub 1+x})CoO{sub 4?z} (x=0) phase, or (CaNdCo)O{sub 4?z}, was found to be stable at this temperature. A solid solution region of distorted perovskite (Nd{sub 1?x}Ca{sub x})CoO{sub 3?z} (0?x?0.25, space group Pnma) was established. In the peripheral binary systems, while a solid solution region was identified for (Nd{sub 1?x}Ca{sub x}){sub 2}O{sub 3?z} (0?x?0.2), Nd was not found to substitute in the Ca site of CaO. Six solid solution tie-line regions and six three-phase regions were determined in the CaONd{sub 2}O{sub 3}CoO{sub z} system in air. - Graphical abstract: Phase diagram of the 1/2 Nd{sub 2}O{sub 3}CaOCoO{sub x} system at 885 C, showing the limits of various solid solutions, and the tie-line relationships of various phases. - Highlights: Phase diagram of the CaO1/2 Nd{sub 2}O{sub 3}CoO{sub z} system constructed. System consists of thermoelectric oxide (Ca{sub 3?x}Nd{sub x})Co{sub 4}O{sub 9?z} (0?x?0.5). Structures of (Nd{sub 1?x}Ca{sub x})CoO{sub 3?z} and (CaNdCo)O{sub 4?z} determined.

  2. A=12N (59AJ76)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    59AJ76) (See the Energy Level Diagram for 12N) GENERAL: See also Table 12.12 [Table of Energy Levels] (in PDF or PS). Mass of 12N: From the Q of the 10B(3He, n)12N reaction, 1.46 ± 0.06 MeV, and the Wapstra (WA55C) atomic masses for 10B, 3He and n, the mass excess of 12N is 21.00 ± 0.06 MeV. 1. 12N(β+)12C Qm = 17.46 The half life is 12.5 ± 1 msec; Eβ(max) = 16.6 ± 0.2 MeV (AL49A), τ1/2 = 11.43 ± 0.05 msec; Eβ(max) = 16.37 ± 0.06 MeV (VE58A). The decay is complex; 12N decays to the

  3. 2012 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2012 Wed, 2012-12-19 14:00 Jefferson Lab Weekly Briefs December 19, 2012 Wed, 2012-12-12 12:00 Jefferson Lab Weekly Briefs December 12, 2012 Wed, 2012-12-05 14:00 Jefferson Lab Weekly Briefs December 5

  4. Synthesis and structural characterization of Al{sub 7}C{sub 3}N{sub 3}-homeotypic aluminum silicon oxycarbonitride, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5)

    SciTech Connect (OSTI)

    Urushihara, Daisuke; Kaga, Motoaki; Asaka, Toru; Nakano, Hiromi; Fukuda, Koichiro

    2011-08-15

    A new aluminum silicon oxycarbonitride, (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}), has been synthesized and characterized by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS). The title compound is hexagonal with space group P6{sub 3}/mmc and unit-cell dimensions a=0.322508(4) nm, c=3.17193(4) nm and V=0.285717(6) nm{sup 3}. The atom ratios of Al:Si and those of O:C:N were, respectively, determined by EDX and EELS. The initial structural model was successfully derived from the XRPD data by the direct methods and further refined by the Rietveld method. The crystal is most probably composed of four types of domains with nearly the same fraction, each of which is isotypic to Al{sub 7}C{sub 3}N{sub 3} with space group P6{sub 3}mc. The existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}), which must be homeotypic to Al{sub 8}C{sub 3}N{sub 4}, has been also demonstrated by XRPD and TEM. - Graphical abstract: A new oxycarbonitride discovered in the Al-Si-O-C-N system, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5). The crystal is composed of four types of domains (I, II, III and IV), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al, Si){sub 4}(O, C, N){sub 4}] unit layers and B-type [(Al, Si)(O, C, N){sub 2}] single layers. Highlights: > (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}) as a new aluminum silicon oxycarbonitride. > Crystal structure is determined and represented by a split-atom model. > Existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}) is demonstrated. > Both new materials are formed by oxidation and nitridation of (Al, Si){sub 6}(O, C){sub 5}.

  5. Y-12 Calutron | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Calutron Y-12 Calutron Calutron at Y-12 Plant.

  6. Draft environmental impact statement for the siting, construction, and operation of New Production Reactor capacity. Volume 3, Sections 7-12, Appendices A-C

    SciTech Connect (OSTI)

    Not Available

    1991-04-01

    This Environmental Impact Statement (EIS) assesses the potential environmental impacts, both on a broad programmatic level and on a project-specific level, concerning a proposed action to provide new tritium production capacity to meet the nation`s nuclear defense requirements well into the 21st century. A capacity equivalent to that of about a 3,000-megawatt (thermal) heavy-water reactor was assumed as a reference basis for analysis in this EIS; this is the approximate capacity of the existing production reactors at DOE`s Savannah River Site near Aiken, South Carolina. The EIS programmatic alternatives address Departmental decisions to be made on whether to build new production facilities, whether to build one or more complexes, what size production capacity to provide, and when to provide this capacity. Project-specific impacts for siting, constructing, and operating new production reactor capacity are assessed for three alternative sites: the Hanford Site near Richland, Washington; the Idaho National Engineering Laboratory near Idaho Falls, Idaho; and the Savannah River Site. For each site, the impacts of three reactor technologies (and supporting facilities) are assessed: a heavy-water reactor, a light-water reactor, and a modular high-temperature gas-cooled reactor. Impacts of the no-action alternative also are assessed. The EIS evaluates impacts related to air quality; noise levels; surface water, groundwater, and wetlands; land use; recreation; visual environment; biotic resources; historical, archaeological, and cultural resources; socioeconomics; transportation; waste management; and human health and safety. The EIS describes in detail the potential radioactive releases from new production reactors and support facilities and assesses the potential doses to workers and the general public. This volume contains references; a list of preparers and recipients; acronyms, abbreviations, and units of measure; a glossary; an index and three appendices.

  7. Y{sub 3}Fe{sub 5}O{sub 12} spin pumping for quantitative understanding of pure spin transport and spin Hall effect in a broad range of materials (invited)

    SciTech Connect (OSTI)

    Du, Chunhui; Wang, Hailong; Hammel, P. Chris; Yang, Fengyuan

    2015-05-07

    Using Y{sub 3}Fe{sub 5}O{sub 12} (YIG) thin films grown by our sputtering technique, we study dynamic spin transport in nonmagnetic, ferromagnetic, and antiferromagnetic (AF) materials by ferromagnetic resonance spin pumping. From both inverse spin Hall effect and damping enhancement, we determine the spin mixing conductance and spin Hall angle in many metals. Surprisingly, we observe robust spin conduction in AF insulators excited by an adjacent YIG at resonance. This demonstrates that YIG spin pumping is a powerful and versatile tool for understanding spin Hall physics, spin-orbit coupling, and magnetization dynamics in a broad range of materials.

  8. 2012 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2012 Wed, 2012-12-19 00:00 JAG Thanks all Holiday Event Participants, volunteers Tue, 2012-12-18 14:00 ODH Signs Posted for Hall D, Bldg. 203, on Dec. 18 Fri, 2012-12-14 14:00 Effective Dec. 14: Bldg. 97 is Construction Zone (Counting House) Fri, 2012-12-14 14:00 Important Notices for All JLab Radiologically Trained Individuals: Wed, 2012-12-12 14:00 ODH Postings for Buildings 200 & 204 Changing as of Dec. 12 Wed, 2012-12-12 14:00 All Staff: Shutdown Time Accounting & Work Guidance

  9. 2015 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2015 Mon, 2015-12-21 09:19 Jefferson Lab EIC Physics Group Leader Thu, 2015-12-17 14:12 Message from Hugh Montgomery: Search for Associate Director for Theory Tue, 2015-12-15 15:12 CEBAF Center North Atrium Entrance & Deck Sidewalk to Close on Dec. 16 Mon, 2015-12-14 16:21 Security Awareness Reminders & Tips for the Jefferson Lab Community Tue, 2015-12-08 09:36 Sentara Mobile Mammography Tue, 2015-12-08 09:27 TIAA-CREF 401(k) GSRA Open Enrollment Begins Today Mon, 2015-12-07 16:22

  10. March 2009 Y-12 Times

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 March 2009 www.y12.doe.gov/news/times.php P.O. Box 2009 Oak Ridge, TN 37831-8245 Managing Editors Amy Alley: alleyab@y12.doe.gov Heidi Spurling: spurlinghw@y12.doe.gov Layout/Design Lisa Harris Contributors Ellen Boatner Ken Davis Kathy Fahey Vicki Hinkel Jamie Loveday Mary Murray W H A T ' S I N S I D E W H A T ' S I N S I D E Page 2 Page 2 New UPF room is out of sight Page 3 Page 3 Training simulates terrorist attack, prepares fi rst responders Page 3 Page 3 Tanker cars on the right track

  11. A=12B (1985AJ01)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10.9). See also (1983AU1C). 7. 9Be(7Li, )12B Qm 10.460 Observed -particle groups are displayed in Table 12.3 (in PDF or PS). Angular distributions have been...

  12. the Y-12 Times, March 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 March 2010 www.y12.doe.gov/news/times.php P.O. Box 2009 Oak Ridge, TN 37831-8245 W H A T ' S I N S I D E Page 2 Y-12's nuclear forensics role Page 3 First Y-12 demolition funded by ARRA Page 4 Bird's-eye view enhances security Page 6 Y-12 UW campaign has best year ever Page 6 Turn your bright idea into a patent B&W Technical Services Y-12, LLC, a partnership between Babcock & Wilcox Technical Services Group Inc. and Bechtel National Inc., operates the Y-12 National Security Complex. A

  13. 12. mu. m band tunable ammonia laser

    SciTech Connect (OSTI)

    Li Yuteh; Kuang Ichung; Hsun Hungtao

    1987-01-01

    The 9.4 ..mu..m R(30) line from a TEA-CO/sub 2/ laser was used to pump a NH/sub 3/ laser. Tunable NH/sub 3/ laser emission in the 12 ..mu..m band has been obtained. The output energy at 12.247, 12.261, and 12.079 ..mu..m is 18.6, 23, and 26 mJ, respectively.

  14. 2011 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2011 Mon, 2011-12-12 13:00 Jan. 24 Science Series Lecturer to Discuss Volcanoes in Virginia! Mon, 2011-12-05 13:00 Jefferson Lab to Test New Siren Warning System on Tuesday Afternoon

  15. Teachers (K-12)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (K-12) Teachers (K-12) The Laboratory provides resources and opportunities in science, technology, engineering and math education to teachers of Northern New Mexico. August 28,...

  16. Microsoft Word - ADM 12

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ADM 12 REV 2 September 2010 ADMINISTRATIVE RECORDS SCHEDULE 12: COMMUNICATIONS RECORDS September 2010 Revision 2 The principal records documenting communication functions include ...

  17. 1998 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 1998 Sat, 1998-12-12 00:00 Don't be late: Lecture is on Time (Daily Press

  18. 2002 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2002 Thu, 2002-12-12 00:00 Wide Range Student Makes Full Use of His Many Talents (Daily Press

  19. 2011 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - 12 Dec 2011 Sun, 2011-12-04 00:00 From Nepal to JLab â€" One Scientist's Journey

  20. 2013 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2013 Mon, 2013-12-09 09:15 Newly Invented Shielding For Stopping Neutrons Cold Thu, 2013-12-05 14:59

  1. 2013 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 Dec 2013 Mon, 2013-12-09 10:30 New Shielding Is Designed to Put the Block on Neutrons

  2. Synthesis and crystal structure of a copper complex with (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3, 4-dihydronaphthalen-1(2H)-one ligand

    SciTech Connect (OSTI)

    Sun, Shu-Wen; Zhang, Xiao; Wang, Gao-Feng

    2015-12-15

    The title compound, C{sub 35}H{sub 23}CuF{sub 6}N{sub 3}O{sub 5}S{sub 2} (1), was synthesized by the reaction of Cu(tta){sub 2} and L{sup 1}, (L{sup 1} = (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3, 4-dihydronaphthalen-1(2H)-one) in the dichloromethane solution. It crystallizes in the monoclinic, space group P2{sub 1}/c with a = 33.8388(5), b = 9.3874(2), c = 21.8194(4) Å, β = 95.522(2), V = 6898.9(2) Å{sup 3}, Z = 8, D{sub x} = 1.554 Mg/m{sup 3}, F(000) = 3272, µ = 0.834 mm{sup –1}, R{sub 1} = 0.0639, wR{sub 2} = 0.1637. The copper(II) ion of 1 is in a distorted square-pyramidal environment with four O atoms of the two tta ligands and one N atom of triazole ligand L{sup 1}. Single-crystal X-ray diffraction data revealed that the hydrogen bonds, weak C–H···π and π···π interactions in the crystals link the coordination units to form 3D supramolecular structures.

  3. Grain size effect on the giant dielectric constant of CaCu{sub 3}Ti{sub 4}O{sub 12} nanoceramics prepared by mechanosynthesis and spark plasma sintering

    SciTech Connect (OSTI)

    Ahmad, Mohamad M.; Yamada, Koji

    2014-04-21

    In the present work, CaCu{sub 3}Ti{sub 4}O{sub 12} (CCTO) nanoceramics with different grain sizes were prepared by spark plasma sintering (SPS) at different temperatures (SPS-800, SPS-900, SPS-975, and SPS-1050) of the mechanosynthesized nano-powder. Structural and microstructural properties were studied by XRD and field-emission scanning electron microscope measurements. The grain size of CCTO nanoceramics increases from 80?nm to ?200?nm for the ceramics sintered at 800?C and 975?C, respectively. Further increase of SPS temperature to 1050?C leads to micro-sized ceramics of 23??m. The electrical and dielectric properties of the investigated ceramics were studied by impedance spectroscopy. Giant dielectric constant was observed in CCTO nanoceramics. The dielectric constant increases with increasing the grain size of the nanoceramics with values of 8.3??10{sup 3}, 2.4??10{sup 4}, and 3.2??10{sup 4} for SPS-800, SPS-900, and SPS-975, respectively. For the micro-sized SPS-1050 ceramics, the dielectric constant dropped to 2.14??10{sup 4}. The dielectric behavior is interpreted within the internal barrier layer capacitance picture due to the electrical inhomogeneity of the ceramics. Besides the resistive grain boundaries that are usually observed in CCTO ceramics, domain boundaries appear as a second source of internal layers in the current nanoceramics.

  4. Y-12 Times, February 2009

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 February 2009 www.y12.doe.gov/news/times.php P.O. Box 2009 Oak Ridge, TN 37831-8245 Managing Editors Amy Alley: alleyab@y12.doe.gov Heidi Spurling: spurlinghw@y12.doe.gov Layout/Design Lisa Harris Contributors Ellen Boatner Amanda Byrge Ken Davis Kathy Fahey Stuart Hames Jamie Loveday Jane Miller Kathryn King-Jones W H A T ' S I N S I D E W H A T ' S I N S I D E Page 2 Page 2 Building steam on schedule Page 3 Page 3 Being 'Rich' helps Y-12 taxes Page 4 Page 4 Social networking: Is it safe?

  5. LLW Notes, Volume 12, Number 3

    SciTech Connect (OSTI)

    Norris, C.; Brown, H. [eds.; Colsant, J.; Lovinger, T.; Scheele, L.; Shaker, M.A.

    1997-03-01

    Contents include articles entitled: California DHS sues US Interior Department to compel land transfer; LLW Forum holds winter meeting; LLW Forum waste information working group meets; LLW Forum regulatory issues discussion group meets; Envirocare investigation transferred to feds; Host state TCC meets in Laughlin, Nevada; BLM to require new permit for California site testing; Federal agencies and committees; Pena sworn in as Energy Secretary, Grumbly departs DOE; U.S. Supreme Court tackles property rights issues; GAO to study DOI`s actions; Congress scrutinizes FY `98 budget requests; and Senate committee passes high-level waste bill: Clinton threatens to veto.

  6. TableHC12.3.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Payment Method for Utility Bills Some Paid by Household...... 97.5 22.8 15.7 7.1 Some Paid, Some in Rent...... 4.7 ...

  7. NUG Meeting November 12, 2001

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NUG Meeting November 12, 2001 Dates November 12, 2001 Location SC2001 Denver Marriott City Center, 1701 California Street, Denver, Colorado Presentations Agenda Agenda NERSC User Group Meeting, November 12, 2001 Note: all times are Mountain Time. 8:00- 8:30 Continental Breakfast 8:30- 8:45 Ryne Welcome / Introductions 8:45- 9:30 Kramer Overview: NERSC status report and plans for FY02 NERSC-3 status, user survey, mass storage, networking, elimination of clear text passwords in the near future

  8. Low loss composition of BaxSryCa1-x-yTiO3: Ba0.12-0.25Sr0.35-0.47Ca0.32-0.53TiO3

    DOE Patents [OSTI]

    Xiang, Xiao-Dong; Chang, Hauyee; Takeuchi, Ichiro

    2001-01-01

    A dielectric thin-film material for microwave applications, including use as a capacitor, the thin-film comprising a composition of barium strontium calcium and titanium of perovskite type (Ba.sub.x Sr.sub.y Ca.sub.1-x-y)TiO.sub.3. Also provided is a method for making a dielectric thin film of that formula over a wide compositional range through a single deposition process.

  9. 2000 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2000 Fri, 2000-12-01 14:00 OnTarget December

  10. 2001 - 12 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Dec 2001 Sat, 2001-12-01 14:00 OnTarget December