National Library of Energy BETA

Sample records for 200-meter cell size

  1. Analytical determination of critical crack size in solar cells

    SciTech Connect (OSTI)

    Chen, C.P.

    1988-05-01

    Although solar cells usually have chips and cracks, no material specifications concerning the allowable crack size on solar cells are available for quality assurance and engineering design usage. Any material specifications that the cell manufacturers use were developed for cosmetic reasons that have no technical basis. Therefore, the Applied Solar Energy Corporation (ASEC) has sponsored a continuing program for the fracture mechanics evaluation of GaAs. Fracture mechanics concepts were utilized to develop an analytical model that can predict the critical crack size of solar cells. This model indicates that the edge cracks of a solar cell are more critical than its surface cracks. In addition, the model suggests that the material specifications on the allowable crack size used for Si solar cells should not be applied to GaAs solar cells. The analytical model was applied to Si and GaAs solar cells, but it would also be applicable to the semiconductor wafers of other materials, such as a GaAs thin film on a Ge substrate, using appropriate input data.

  2. ARM - Publications: Science Team Meeting Documents: Stratocumulus cell size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and emittance at the ARM TWP Darwin site - implications for observations from CALIPSO Stratocumulus cell size and emittance at the ARM TWP Darwin site - implications for observations from CALIPSO Platt, C. Colorado State University and CSIRO Atmospheric Research Bennett, John CSIRO Atmospheric Research The NASA CALIPSO satellite instrument due to be launched in mid-2005 will carry a two-wavelength polarisation lidar and a scanning filter infrared radiometer viewing in the nadir. Preliminary

  3. Sandia Energy - Glitter-Sized Photovoltaic Cells in Utility-Scale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Glitter-Sized Photovoltaic Cells in Utility-Scale Solar Power Systems Home Renewable Energy Energy News Photovoltaic Solar Glitter-Sized Photovoltaic Cells in Utility-Scale Solar...

  4. Measuring the mass, density, and size of particles and cells using a suspended microchannel resonator

    SciTech Connect (OSTI)

    Godin, Michel; Bryan, Andrea K.; Burg, Thomas P.; Babcock, Ken; Manalis, Scott R.

    2007-09-17

    We demonstrate the measurement of mass, density, and size of cells and nanoparticles using suspended microchannel resonators. The masses of individual particles are quantified as transient frequency shifts, while the particles transit a microfluidic channel embedded in the resonating cantilever. Mass histograms resulting from these data reveal the distribution of a population of heterogeneously sized particles. Particle density is inferred from measurements made in different carrier fluids since the frequency shift for a particle is proportional to the mass difference relative to the displaced solution. We have characterized the density of polystyrene particles, Escherichia coli, and human red blood cells with a resolution down to 10{sup -4} g/cm{sup 3}.

  5. TUNING OF SIZE AND SHAPE OF AU-PT NANOCATALYST FOR DIRECT METHANOL FUEL CELLS

    SciTech Connect (OSTI)

    Murph, S.

    2011-04-20

    In this paper, we report the precise control of the size, shape and surface morphology of Au-Pt nanocatalysts (cubes, blocks, octahedrons and dogbones) synthesized via a seed-mediated approach. Gold 'seeds' of different aspect ratios (1 to 4.2), grown by a silver-assisted approach, were used as templates for high-yield production of novel Au-Pt nanocatalysts at a low temperature (40 C). Characterization by electron microscopy (SEM, TEM, HRTEM), energy dispersive X-ray analysis (EDX), UV-Vis spectroscopy, zeta-potential (surface charge), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and inductively coupled plasma mass spectrometry (ICP-MS) were used to better understand their physico-chemical properties, preferred reactivities and underlying nanoparticle growth mechanism. A rotating disk electrode was used to evaluate the Au-Pt nanocatalysts electrochemical performance in the oxygen reduction reaction (ORR) and the methanol oxidation reaction (MOR) of direct methanol fuel cells. The results indicate the Au-Pt dogbones are partially and in some cases completely unaffected by methanol poisoning during the evaluation of the ORR. The ORR performance of the octahedron particles in the absence of MeOH is superior to that of the Au-Pt dogbones and Pt-black, however its performance is affected by the presence of MeOH.

  6. Cell culture arrays using micron-sized ferromagnetic ring-shaped thin films

    SciTech Connect (OSTI)

    Huang, Chen-Yu; Wei, Zung-Hang; Lai, Mei-Feng; Ger, Tzong-Rong

    2015-05-07

    Cell patterning has become an important technology for tissue engineering. In this research, domain walls are formed at the two ends of a ferromagnetic ring thin film after applying a strong external magnetic field, which can effectively attract magnetically labeled cells and control the position for biological cell. Magnetophoresis experiment was conducted to quantify the magnetic nanoparticle inside the cells. A ring-shaped magnetic thin films array was fabricated through photolithography. It is observed that magnetically labeled cells can be successfully attracted to the two ends of the ring-shaped magnetic thin film structure and more cells were attracted and further attached to the structures. The cells are co-cultured with the structure and kept proliferating; therefore, such ring thin film can be an important candidate for in-vitro biomedical chips or tissue engineering.

  7. Kinetic (particle-in-cell) simulation of nonlinear laser absorption in a finite-size plasma with a background inhomogeneous magnetic field

    SciTech Connect (OSTI)

    Mehdian, H. Kargarian, A.; Hajisharifi, K.

    2015-06-15

    In this paper, the effect of an external inhomogeneous magnetic field on the high intensity laser absorption rate in a sub-critical plasma has been investigated by employing a relativistic electromagnetic 1.5 dimensional particle-in-cell code. Relying on the effective nonlinear phenomena such as phase-mixing and scattering, this study shows that in a finite-size plasma the laser absorption increases with inhomogeneity of the magnetic field (i.e., reduction of characteristic length of inhomogeneous magnetic field, ?{sub p}) before exiting a considerable amount of laser energy from the plasma due to scattering process. On the other hand, the presence of the external inhomogeneous magnetic field causes the maximum absorption of laser to occur at a shorter time. Moreover, study of the kinetic results associated with the distribution function of plasma particles shows that, in a special range of the plasma density and the characteristic length of inhomogeneous magnetic field, a considerable amount of laser energy is transferred to the particles producing a population of electrons with kinetic energy along the laser direction.

  8. 20% (AM1.5) efficiency GaAs solar cells on sub-mm grain-size poly-Ge and its transition to low-cost substrates

    SciTech Connect (OSTI)

    Venkatasubramanian, R.; O`Quinn, B.C.; Siivola, E.; Keyes, B.; Ahrenkiel, R.

    1997-12-31

    Some of the key material and device issues related to the development of GaAs solar cells on poly-Ge substrates, including the dark-current reduction mechanism with an undoped spacer at the p{sup +}-n depletion layer, are discussed. Device-structure optimization studies that have led the authors to achieve an AM1.5 efficiency of {approximately}20% for a 4-cm{sup 2}-area GaAs cell on sub-mm grain-size poly-Ge and an efficiency of {approximately}21% for a 0.25-cm{sup 2}-area cell are presented. This successful demonstration of high-efficiency GaAs cells on sub-mm grain-size poly-Ge substrates have motivated us to consider the development of high-quality GaAs materials on significantly lower-cost substrates such as glass and moly foils. To date, the authors have achieved a best minority-carrier lifetime of 0.41 nsec in an n-GaAs thin-film on moly. The role of Group-VI dopant in the possible passivation of grain-boundaries in poly-GaAs is discussed. Development of PV-quality GaAs material, with minority-carrier lifetime of 1 to 2 nsec, on los-cost moly foils can significantly impact both the terrestrial and the space PV applications.

  9. Simulation of quantum dots size and spacing effect for intermediate band solar cell application based on InAs quantum dots arrangement in GaAs

    SciTech Connect (OSTI)

    Hendra, P. I. B. Rahayu, F. Darma, Y.

    2014-03-24

    Intermediate band solar cell (IBSC) has become a promising technology in increasing solar cell efficiency. In this work we compare absorption coefficient profile between InAs quantum dots with GaAs bulk. We calculate the efficiency of GaAs bulk and GaAs doped with 2, 5, and 10 nm InAs quantum dot. Effective distances in quantum dot arrangement based on electron tunneling consideration were also calculated. We presented a simple calculation method with low computing power demand. Results showed that arrangement of quantum dot InAs in GaAs can increase solar cell efficiency from 23.9 % initially up to 60.4%. The effective distance between two quantum dots was found 2 nm in order to give adequate distance to prevent electron tunneling and wave functions overlap.

  10. Edison Job Size Charts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Job Size Charts Edison Job Size Charts Fraction of Hours Used per Job Size This chart shows the fraction of hours used on Edison in each of 5 job-core-size bins. 2015 Usage by Job Size Chart 2014 Fraction of Hours Used by Big Jobs This chart shows the fraction of hours used on Edison by jobs using 16,384 or more cores. 2015 Usage by Job Size Chart 2014 Last edited: 2015-02-18 16:06:26

  11. Hopper Job Size Charts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Job Size Charts Hopper Job Size Charts Fractional Jobs The following charts show the fraction of hours used on Hopper in each of five job-core-size bins: 2014 Usage by Job Size Chart 2013 2012 2011 Large Jobs The following charts show the fraction of hours used on Hopper by jobs using greater than 16,384 cores: 2014 2013 2012 Usage by Job Size Chart 2011 Last edited: 2014-12-22 12:16:26

  12. Does size matter?

    SciTech Connect (OSTI)

    Carreras, B. A.; Physics Department, College of Natural Science and Mathematics and Geophysical Institute, University of Alaska, Fairbanks, Alaska 99775; Physics Department, Universidad Carlos III de Madrid, Madrid ; Newman, D. E.; Dobson, Ian

    2014-06-15

    Failures of the complex infrastructures society depends on having enormous human and economic cost that poses the question: Are there ways to optimize these systems to reduce the risks of failure? A dynamic model of one such system, the power transmission grid, is used to investigate the risk from failure as a function of the system size. It is found that there appears to be optimal sizes for such networks where the risk of failure is balanced by the benefit given by the size.

  13. Size and charge effects of dopant M on the unit-cell parameters of monoclinic zirconia solid solutions Zr{sub 0.98}M{sub 0.02}O{sub 2{minus}{delta}} (M = Ce, La, Nd, Sm, Y, Er, Yb, Sc, Mg, Ca)

    SciTech Connect (OSTI)

    Yashima, Masatomo; Kakihana, Masato; Yoshimura, Masahiro; Hirose, Teruo; Suzuki, Yasuo

    1997-01-01

    The crystal structure of monoclinic phase [P2{sub 1}/c, Z = 4] has been refined by the Rietveld analysis of X-ray powder diffraction data to study the size and charge effects of dopant M{sup n+} on the unit-cell parameters of monoclinic ZrO{sub 2}-2 mol% MO{sub n/2} solid solutions (n = 4 for M = Ce; n = 3 for M = La, Nd, Sm, Y, Er, Yb, Sc; and n = 2 for M = Mg and Ca). For trivalent dopant (n = 3), the unit-cell parameters a{sub m}, b{sub m}, c{sub m} and unit-cell volume increase and {beta}{sub m} decreases with an increase of dopant size. Unit-cell volume increases with increasing of dopant charge n.

  14. The Importance of Domain Size and Purity in High-Efficiency Organic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymerorganic photovoltaic cells hinges on excitons-electronhole pairs energized by...

  15. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian (Port Jefferson, NY); Kulkarni, Pramod (Port Jefferson Station, NY)

    2007-11-20

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  16. ARM - Measurement - Cloud droplet size

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    droplet size Linear size (e.g. radius or diameter) of a cloud particle Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  17. Usage by Job Size Table

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Usage by Job Size Table Usage by Job Size Table page loading animation Usage Query Interface System All Hopper Edison Cori Carver Planck Matgen Franklin Hopper 1 Magellan Dirac...

  18. LIQUID & GAS NITROGEN LINE SIZING

    Office of Scientific and Technical Information (OSTI)

    These calculations supplement sizing that was done in D-Zero EN-416, rev. 62695, II Pipe Sizing for SolenoidVLPC Cryogenic Systems", EN-416 only looked at the Solenoid and...

  19. ARM - Measurement - Hydrometeor Size Distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of hydrometeors observed in a given size range. Categories Atmospheric State, Cloud Properties Instruments The above measurement is considered scientifically relevant for the...

  20. Organic Solar Cells: Absolute Measurement of Domain Composition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic Solar Cells: Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in Solar Cells Organic Solar Cells: Absolute Measurement of...

  1. Strategy Guideline: HVAC Equipment Sizing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategy Guideline: HVAC Equipment Sizing Arlan Burdick IBACOS, Inc. February 2012 This report received minimal editorial review at NREL NOTICE This report was prepared as an account of work sponsored by an agency of the United States government. Neither the United States government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information,

  2. Strategy Guideline: HVAC Equipment Sizing

    SciTech Connect (OSTI)

    Burdick, A.

    2012-02-01

    The heating, ventilation, and air conditioning (HVAC) system is arguably the most complex system installed in a house and is a substantial component of the total house energy use. A right-sized HVAC system will provide the desired occupant comfort and will run efficiently. This Strategy Guideline discusses the information needed to initially select the equipment for a properly designed HVAC system. Right-sizing of an HVAC system involves the selection of equipment and the design of the air distribution system to meet the accurate predicted heating and cooling loads of the house. Right-sizing the HVAC system begins with an accurate understanding of the heating and cooling loads on a space; however, a full HVAC design involves more than just the load estimate calculation - the load calculation is the first step of the iterative HVAC design procedure. This guide describes the equipment selection of a split system air conditioner and furnace for an example house in Chicago, IL as well as a heat pump system for an example house in Orlando, Florida. The required heating and cooling load information for the two example houses was developed in the Department of Energy Building America Strategy Guideline: Accurate Heating and Cooling Load Calculations.

  3. Fuel Cell Animation - Fuel Cell Stack (Text Version) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stack (Text Version) Fuel Cell Animation - Fuel Cell Stack (Text Version) This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts. Fuel cell stack with electrical circuit. Fuel cell: The amount of power produced by a fuel cell depends on several factors, including fuel cell type, cell size, temperature at which it operates, and pressure at which the gases are supplied to the cell. A single fuel cell

  4. Decreasing transmembrane segment length greatly decreases perfringolysin O pore size

    SciTech Connect (OSTI)

    Lin, Qingqing; Li, Huilin; Wang, Tong; London, Erwin

    2015-04-08

    Perfringolysin O (PFO) is a transmembrane (TM) β-barrel protein that inserts into mammalian cell membranes. Once inserted into membranes, PFO assembles into pore-forming oligomers containing 30–50 PFO monomers. These form a pore of up to 300 Å, far exceeding the size of most other proteinaceous pores. In this study, we found that altering PFO TM segment length can alter the size of PFO pores. A PFO mutant with lengthened TM segments oligomerized to a similar extent as wild-type PFO, and exhibited pore-forming activity and a pore size very similar to wild-type PFO as measured by electron microscopy and a leakage assay. In contrast, PFO with shortened TM segments exhibited a large reduction in pore-forming activity and pore size. This suggests that the interaction between TM segments can greatly affect the size of pores formed by TM β-barrel proteins. PFO may be a promising candidate for engineering pore size for various applications.

  5. Decreasing transmembrane segment length greatly decreases perfringolysin O pore size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Qingqing; Li, Huilin; Wang, Tong; London, Erwin

    2015-04-08

    Perfringolysin O (PFO) is a transmembrane (TM) β-barrel protein that inserts into mammalian cell membranes. Once inserted into membranes, PFO assembles into pore-forming oligomers containing 30–50 PFO monomers. These form a pore of up to 300 Å, far exceeding the size of most other proteinaceous pores. In this study, we found that altering PFO TM segment length can alter the size of PFO pores. A PFO mutant with lengthened TM segments oligomerized to a similar extent as wild-type PFO, and exhibited pore-forming activity and a pore size very similar to wild-type PFO as measured by electron microscopy and a leakagemore » assay. In contrast, PFO with shortened TM segments exhibited a large reduction in pore-forming activity and pore size. This suggests that the interaction between TM segments can greatly affect the size of pores formed by TM β-barrel proteins. PFO may be a promising candidate for engineering pore size for various applications.« less

  6. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print Wednesday, 27 March 2013 00:00 The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the

  7. Hazards of explosives dusts: Particle size effects

    SciTech Connect (OSTI)

    Cashdollar, K L; Hertzberg, M; Green, G M

    1992-02-01

    At the request of the Department of Energy, the Bureau of Mines has investigated the hazards of military explosives dispersed as dust clouds in a 20-L test chamber. In this report, the effect of particle size for HMX, HNS, RDX, TATB, and TNT explosives dusts is studied in detail. The explosibility data for these dusts are also compared to those for pure fuel dusts. The data show that all of the sizes of the explosives dusts that were studied were capable of sustaining explosions as dust clouds dispersed in air. The finest sizes (<10 [mu]m) of explosives dusts were less reactive than the intermediate sizes (20 to 60 [mu]m); this is opposite to the particle size effect observed previously for the pure fuel dusts. At the largest sizes studied, the explosives dusts become somewhat less reactive as dispersed dust clouds. The six sizes of the HMX dust were also studied as dust clouds dispersed in nitrogen.

  8. Organic Solar Cells: Absolute Measurement of Domain Composition and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Size Distribution Explains Performance in Solar Cells Organic Solar Cells: Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in Solar Cells Organic Solar Cells: Absolute Measurement of Domain Composition and Nanoscale Size Distribution Explains Performance in Solar Cells Print Tuesday, 22 January 2013 00:00 This front cover represents the morphology and resulting device dynamics in organic solar cell blend films of PTB7 and PC71BM, as

  9. ARM - Measurement - Cloud particle size distribution

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    size distribution ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud particle size distribution The number of cloud particles present in any given volume of air within a specified size range, including liquid and ice. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  10. Investigation of thermochemical biorefinery sizing and environmental...

    Office of Scientific and Technical Information (OSTI)

    Investigation of thermochemical biorefinery sizing and environmental sustainability impacts for conventional supply system and distributed pre-processing supply system designs...

  11. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  12. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  13. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  14. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  15. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  16. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  17. The Importance of Domain Size and Purity in High-Efficiency Organic Solar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells The Importance of Domain Size and Purity in High-Efficiency Organic Solar Cells Print The efficiency of polymer/organic photovoltaic cells hinges on excitons-electron/hole pairs energized by sunlight-getting to the interfaces of donor and acceptor domains quickly, before recombining. At the interfaces, they become free charges that must then reach device electrodes. With the discovery of mixed domains of donor and acceptor molecules, many have pictured the excitons' journey as easy

  18. Photovoltaic Cell Basics | Department of Energy

    Energy Savers [EERE]

    Basics Photovoltaic Cell Basics August 16, 2013 - 4:53pm Addthis Photovoltaic (PV) cells, or solar cells, take advantage of the photoelectric effect to produce electricity. PV cells are the building blocks of all PV systems because they are the devices that convert sunlight to electricity. Commonly known as solar cells, individual PV cells are electricity-producing devices made of semiconductor materials. PV cells come in many sizes and shapes, from smaller than a postage stamp to several inches

  19. Investigations of initiation spot size effects

    SciTech Connect (OSTI)

    Clarke, Steven A; Akinci, Adrian A; Leichty, Gary; Schaffer, Timothy; Murphy, Michael J; Munger, Alan; Thomas, Keith A

    2010-01-01

    As explosive components become smaller, a greater understanding of the effect of initiation spot size on detonation becomes increasingly critical. A series of tests of the effect of initiation spot size will be described. A series of DOI (direct optical initiation) detonators with initiation spots sizes from {approx}50 um to 1000um have been tested to determine laser parameters for threshold firing of low density PETN pressings. Results will be compared with theoretical predictions. Outputs of the initiation source (DOI ablation) have been characterized by a suite of diagnostics including PDV and schlieren imaging. Outputs of complete detonators have been characterized using PDV, streak, and/or schlieren imaging. At present, we have not found the expected change in the threshold energy to spot size relationship for DOI type detonators found in similar earlier for projectiles, slappers and EBWs. New detonators designs (Type C) are currently being tested that will allow the determination of the threshold for spot sizes from 250 um to 105um, where we hope to see change in the threshold vs. spot size relationship. Also, one test of an extremely small diameter spot size (50um) has resulted in preliminary NoGo only results even at energy densities as much as 8 times the energy density of the threshold results presented here. This gives preliminary evidence that 50um spot may be beyond the critical initiation diameter. The constant threshold energy to spot size relationship in the data to date does however still give some insight into the initiation mechanism of DOI detonators. If the DOI initiation mechanism were a 1D mechanism similar to a slapper or a flyer impact, the expected inflection point in the graph would have been between 300um and 500um diameter spot size, within the range of the data presented here. The lack of that inflection point indicates that the DOI initiation mechanism is more likely a 2D mechanism similar to a sphere or rod projectile. We expect to see a three region response as the results from the smaller spot size Type C detonators are completed.

  20. Size separation of analytes using monomeric surfactants

    DOE Patents [OSTI]

    Yeung, Edward S.; Wei, Wei

    2005-04-12

    A sieving medium for use in the separation of analytes in a sample containing at least one such analyte comprises a monomeric non-ionic surfactant of the of the general formula, B-A, wherein A is a hydrophilic moiety and B is a hydrophobic moiety, present in a solvent at a concentration forming a self-assembled micelle configuration under selected conditions and having an aggregation number providing an equivalent weight capable of effecting the size separation of the sample solution so as to resolve a target analyte(s) in a solution containing the same, the size separation taking place in a chromatography or electrophoresis separation system.

  1. Strategic Petroleum Reserve: Analysis of size options

    SciTech Connect (OSTI)

    Not Available

    1990-02-01

    This report presents the results of the deliberations of the interagency group formed to study the costs and benefits of expanding the size of the SPR. The study concentrated on severe oil supply disruptions involving sharp reductions in world oil production that were 2 to 4 times larger than the largest 1970s interruption. The disruption sizes and estimated probability of occurrence of these scenarios were supplied by the CIA. The most critical part of the CIA's analysis was the assessment of likelihood of these cases occurring. The CIA approached the likelihood problem by combining an examination of past oil supply disruptions with qualitative analysis of important oil market and regional trends. The study group then used statistical techniques and probability distributions to synthesize the historical data with CIA evaluations of as yet unobserved events. The SPR size study assumed direct purchases of SPR oil and did not assume the use of alternative financing mechanisms. Members of the working group with foreign policy and national security responsibilities provided an in-depth review of strategic considerations affecting SPR size. A number of prior studies, some classified, have addressed the strategic importance and insurance value of the SPR to the US and its allies. The results of these studies have also been incorporated in the current effort. 10 refs., 5 figs.

  2. Biomass Engineering: Size reduction, drying and densification

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Biomass Engineering: Size reduction, drying and densification March 25th, 2015 This presentation does not contain any proprietary, confidential, or otherwise restricted information Technology Review Area: Feedstock Supply and Logistics Jaya Shankar Tumuluru (PI) Research Team: Neal Yancey, Craig C Conner, Tyler Westover, Richard McCulloch, Kara Cafferty, and Mitch Plummer Organization: Biofuels and Renewable Energy Technology, Idaho National Laboratory DOE Bioenergy Technologies Office (BETO)

  3. NREL: Hydrogen and Fuel Cells Research - Stationary Fuel Cell Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis Stationary Fuel Cell Systems Analysis NREL's technology validation team analyzes the performance of stationary fuel cell systems operating in real-world conditions and reports on the technology's performance, progress, and challenges. This analysis includes multiple fuel cell types-proton exchange membrane, solid oxide, phosphoric acid, and molten carbonate-with system sizes ranging from 5 kW to 2.8 MW. Overview Composite Data Products Publications Learn More Contacts Photo of

  4. AVTA: Full-Size Electric Vehicle Specifications and Test Procedures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Full-Size Electric Vehicle Specifications and Test Procedures AVTA: Full-Size Electric Vehicle Specifications and Test Procedures PDF icon EV America Test Specifications PDF icon ...

  5. Sandia Energy - Self-Regulated Fabrication of Size-Controlled...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Home Highlights - Energy Research Self-Regulated Fabrication of Size-Controlled Quantum Nanostructures Previous...

  6. Sandia Energy - Enhanced Nanoparticle Size Control by Extending...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism Home Office of Science Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism Previous Next Enhanced...

  7. Small- and Medium-Size Building Automation and Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Michael ...

  8. Small- and Medium-Size Building Automation and Control System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Emerging ...

  9. Wide size range fast integrated mobility spectrometer

    DOE Patents [OSTI]

    Wang, Jian

    2013-10-29

    A mobility spectrometer to measure a nanometer particle size distribution is disclosed. The mobility spectrometer includes a conduit and a detector. The conduit is configured to receive and provide fluid communication of a fluid stream having a charged nanometer particle mixture. The conduit includes a separator section configured to generate an electrical field of two dimensions transverse to a dimension associated with the flow of the charged nanometer particle mixture through the separator section to spatially separate charged nanometer particles of the charged nanometer particle mixture in said two dimensions. The detector is disposed downstream of the conduit to detect concentration and position of the spatially-separated nanometer particles.

  10. LNG fleet increases in size and capabilities

    SciTech Connect (OSTI)

    Linser, H.J. Jr.; Drudy, M.J.; Endrizzi, F.; Urbanelli, A.A.

    1997-06-02

    The LNG fleet as of early 1997 consisted of 99 vessels with total cargo capacity of 10.7 million cu m, equivalent to approximately 4.5 million tons. One of the newest additions to the fleet, the 137,000-cu m tanker Al Zubarah, is five times the size of the original commercial vessel Methane Princess. Al Zubarah`s first loading of more than 60,000 tons occurred in December 1996 for deliver to Japanese buyers from the newly commissioned Qatargas LNG plant at Ras Laffan. That size cargo contains enough clean-burning energy to heat 60,000 homes in Japan for 1 month. Measuring nearly 1,000 ft long, the tanker is among the largest in the industry fleet and joined 70 other vessels of more than 100,000 cu m. Most LNG tankers built since 1975 have been larger-capacity vessels. The paper discusses LNG shipping requirements, containment systems, vessel design, propulsion, construction, operations and maintenance, and the future for larger vessels.

  11. Parameterizing Size Distribution in Ice Clouds

    SciTech Connect (OSTI)

    DeSlover, Daniel; Mitchell, David L.

    2009-09-25

    PARAMETERIZING SIZE DISTRIBUTIONS IN ICE CLOUDS David L. Mitchell and Daniel H. DeSlover ABSTRACT An outstanding problem that contributes considerable uncertainty to Global Climate Model (GCM) predictions of future climate is the characterization of ice particle sizes in cirrus clouds. Recent parameterizations of ice cloud effective diameter differ by a factor of three, which, for overcast conditions, often translate to changes in outgoing longwave radiation (OLR) of 55 W m-2 or more. Much of this uncertainty in cirrus particle sizes is related to the problem of ice particle shattering during in situ sampling of the ice particle size distribution (PSD). Ice particles often shatter into many smaller ice fragments upon collision with the rim of the probe inlet tube. These small ice artifacts are counted as real ice crystals, resulting in anomalously high concentrations of small ice crystals (D < 100 m) and underestimates of the mean and effective size of the PSD. Half of the cirrus cloud optical depth calculated from these in situ measurements can be due to this shattering phenomenon. Another challenge is the determination of ice and liquid water amounts in mixed phase clouds. Mixed phase clouds in the Arctic contain mostly liquid water, and the presence of ice is important for determining their lifecycle. Colder high clouds between -20 and -36 oC may also be mixed phase but in this case their condensate is mostly ice with low levels of liquid water. Rather than affecting their lifecycle, the presence of liquid dramatically affects the cloud optical properties, which affects cloud-climate feedback processes in GCMs. This project has made advancements in solving both of these problems. Regarding the first problem, PSD in ice clouds are uncertain due to the inability to reliably measure the concentrations of the smallest crystals (D < 100 m), known as the small mode. Rather than using in situ probe measurements aboard aircraft, we employed a treatment of ice cloud optical properties formulated in terms of PSD parameters in combination with remote measurements of thermal radiances to characterize the small mode. This is possible since the absorption efficiency (Qabs) of small mode crystals is larger at 12 m wavelength relative to 11 m wavelength due to the process of wave resonance or photon tunneling more active at 12 m. This makes the 12/11 m absorption optical depth ratio (or equivalently the 12/11 m Qabs ratio) a means for detecting the relative concentration of small ice particles in cirrus. Using this principle, this project tested and developed PSD schemes that can help characterize cirrus clouds at each of the three ARM sites: SGP, NSA and TWP. This was the main effort of this project. These PSD schemes and ice sedimentation velocities predicted from them have been used to test the new cirrus microphysics parameterization in the GCM known as the Community Climate Systems Model (CCSM) as part of an ongoing collaboration with NCAR. Regarding the second problem, we developed and did preliminary testing on a passive thermal method for retrieving the total water path (TWP) of Arctic mixed phase clouds where TWPs are often in the range of 20 to 130 g m-2 (difficult for microwave radiometers to accurately measure). We also developed a new radar method for retrieving the cloud ice water content (IWC), which can be vertically integrated to yield the ice water path (IWP). These techniques were combined to determine the IWP and liquid water path (LWP) in Arctic clouds, and hence the fraction of ice and liquid water. We have tested this approach using a case study from the ARM field campaign called M-PACE (Mixed-Phase Arctic Cloud Experiment). This research led to a new satellite remote sensing method that appears promising for detecting low levels of liquid water in high clouds typically between -20 and -36 oC. We hope to develop this method in future research.

  12. Offshore Lubricants Market Size | OpenEI Community

    Open Energy Info (EERE)

    Offshore Lubricants Market Size Home There are currently no posts in this category. Syndicate content...

  13. Coal Fired Power Generation Market Size | OpenEI Community

    Open Energy Info (EERE)

    Coal Fired Power Generation Market Size Home There are currently no posts in this category. Syndicate...

  14. Reduce Pumping Costs Through Optimum Pipe Sizing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pumping Costs Through Optimum Pipe Sizing Reduce Pumping Costs Through Optimum Pipe Sizing This tip sheet discusses how to reduce pumping system costs through optimum pipe sizing. PUMPING SYSTEMS TIP SHEET #9 PDF icon Reduce Pumping Costs Through Optimum Pipe Sizing (October 2005) More Documents & Publications Select an Energy-Efficient Centrifugal Pump Effect of Intake on Compressor Performance Pump Selection Considerations

  15. Variable area fuel cell process channels

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Borough, PA)

    1981-01-01

    A fuel cell arrangement having a non-uniform distribution of fuel and oxidant flow paths, on opposite sides of an electrolyte matrix, sized and positioned to provide approximately uniform fuel and oxidant utilization rates, and cell conditions, across the entire cell.

  16. Sizing a New Water Heater | Department of Energy

    Energy Savers [EERE]

    Heat & Cool » Water Heating » Sizing a New Water Heater Sizing a New Water Heater Is your water heater the right size for you house? | Photo credit ENERGY STAR® Is your water heater the right size for you house? | Photo credit ENERGY STAR® A properly sized water heater will meet your household's hot water needs while operating more efficiently. Therefore, before purchasing a water heater, make sure it's the correct size. Here you'll find information about how to size these systems:

  17. Sizing a New Water Heater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sizing a New Water Heater Sizing a New Water Heater Is your water heater the right size for you house? | Photo credit ENERGY STAR® Is your water heater the right size for you house? | Photo credit ENERGY STAR® A properly sized water heater will meet your household's hot water needs while operating more efficiently. Therefore, before purchasing a water heater, make sure it's the correct size. Here you'll find information about how to size these systems: Tankless or demand-type water heaters

  18. New program sizes pressure-relief drums

    SciTech Connect (OSTI)

    Durand, A.A.; Osorio, R.A.; Suarez, R.H.

    1996-05-06

    In accordance with API Recommended Practice 521, a new procedure has been developed for the design of relief drums. The calculation method determines by convergence the most economical length-to-diameter ratio for gas-liquid separation vessels. Drum sizing is based on the separation of a two-phase stream, taking into account the special condition of intermittent flow. Design parameters such as settling velocity and residence time also must be calculated to determine an optimum design. A new program based on a programmable algorithm can be converted from basic language to any other computer language to facilitate vessel-design computations. The program quickly and efficiently computes design values for relief systems used in refineries and petrochemical plants.

  19. Size dependence of cubic to trigonal structural distortion in silver micro- and nanocrystals under high pressure

    SciTech Connect (OSTI)

    Guo, Qixum; Zhao, Yusheng; Zin, Zhijun; Wang, Zhongwu; Skrabalak, Sara E; Xia, Younan

    2008-01-01

    Silver micro- and nanocrystals with sizes of {approx}2--3.5 {mu}m and {approx}50--100 nm were uniaxially compressed under nonhydrostatic pressures (strong deviatoric stress) up to {approx}30 GPa at room temperature in a symmetric diamond-anvil cell and studied in situ using angle-dispersive synchrotron X-ray diffraction. A cubic to trigonal structural distortion along a 3-fold rotational axis was discovered by careful and comprehensive analysis of the apparent lattice parameter and full width at half-maximum, which are strongly dependent upon the Miller index and crystal size.

  20. Opportunities for Micropower and Fuel Cell/Gas Turbine Hybrid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Micropower is defined as microturbines, fuel cells, and reciprocating engines under 1 MW. Fuel cell hybrid systems were analyzed for unit sizes of 250 kW to 20 MW. Report ...

  1. Fuel Cell Transit Bus Coordination and Evaluation Plan California Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transit Evaluation Team | Department of Energy Bus Coordination and Evaluation Plan California Fuel Cell Transit Evaluation Team Fuel Cell Transit Bus Coordination and Evaluation Plan California Fuel Cell Transit Evaluation Team The purpose of this document is to describe the coordination and evaluation of the demonstration of seven full-size (40-foot) fuel cell transit buses. The descriptions in this document include the partners, fuel cell bus demonstration sites, objectives... PDF icon

  2. Series cell light extinction monitor

    DOE Patents [OSTI]

    Novick, Vincent J.

    1990-01-01

    A method and apparatus for using the light extinction measurements from two or more light cells positioned along a gasflow chamber in which the gas volumetric rate is known to determine particle number concentration and mass concentration of an aerosol independent of extinction coefficient and to determine estimates for particle size and mass concentrations. The invention is independent of particle size. This invention has application to measurements made during a severe nuclear reactor fuel damage test.

  3. Solar Trackers Market Size | OpenEI Community

    Open Energy Info (EERE)

    Solar Trackers Market Size Home John55364's picture Submitted by John55364(100) Contributor 12 May, 2015 - 03:54 Solar Trackers Market - Global Industry Analysis, Size, Share,...

  4. Global Nuclear Energy Partnership Triples in Size to 16 Members...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Nuclear Energy Partnership Triples in Size to 16 Members Global Nuclear Energy Partnership Triples in Size to 16 Members September 16, 2007 - 2:33pm Addthis Nations Sign On...

  5. Quantum-size-controlled photoelectrochemical etching of semiconductor

    Office of Scientific and Technical Information (OSTI)

    nanostructures (Patent) | SciTech Connect Patent: Quantum-size-controlled photoelectrochemical etching of semiconductor nanostructures Citation Details In-Document Search Title: Quantum-size-controlled photoelectrochemical etching of semiconductor nanostructures Quantum-size-controlled photoelectrochemical (QSC-PEC) etching provides a new route to the precision fabrication of epitaxial semiconductor nanostructures in the sub-10-nm size regime. For example, quantum dots (QDs) can be

  6. Method for determining aerosol particle size device for determining aerosol particle size

    DOE Patents [OSTI]

    Novick, Vincent J.

    1998-01-01

    A method for determining the mass median diameter D of particles contained in a fluid is provided wherein the data of the mass of a pre-exposed and then a post-exposed filter is mathematically combined with data concerning the pressure differential across the same filter before and then after exposure to a particle-laden stream. A device for measuring particle size is also provided wherein the device utilizes the above-method for mathematically combining the easily quantifiable data.

  7. Femtosecond laser-induced size reduction of carbon nanodots in solution: Effect of laser fluence, spot size, and irradiation time

    SciTech Connect (OSTI)

    Nguyen, Vanthan; Yan, Lihe Si, Jinhai; Hou, Xun

    2015-02-28

    Photoluminescent carbon nanodots (C-dots) with size tunability and uniformity were fabricated in polyethylene glycol (PEG{sub 200N}) solution using femtosecond laser ablation method. The size distributions and photoluminescence (PL) properties of C-dots are well controlled by adjusting the combined parameters of laser fluence, spot size, and irradiation time. The size reduction efficiency of the C-dots progressively increases with decreasing laser fluence and spot size. The optimal PL spectra are red-shifted and the quantum yields decrease with the increase in C-dots size, which could be attributed to the more complex surface functional groups attached on C-dots induced at higher laser fluence and larger spot size. Moreover, an increase in irradiation time leads to a decrease in size of C-dots, but long-time irradiation will result in the generation of complex functional groups on C-dots, subsequently the PL spectra are red-shifted.

  8. Comparison of Fuel Cell Technologies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Information More information on the Fuel Cell Technologies Offce is available at http://www.hydrogenandfuelcells.energy.gov. Fuel Cell Type Common Electrolyte Operating Temperature Typical Stack Size Electrical Efficiency (LHV) Applications Advantages Challenges Polymer Electrolyte Membrane (PEM) Perfluorosulfonic acid <120°C <1 kW - 100 kW 60% direct H 2 ; i 40% reformed fuel ii * Backup power * Portable power * Distributed generation * Transportation * Specialty vehicles * Solid

  9. Phase Behavior and Domain Size in Sphingomyelin-Containing Lipid Bilayers

    SciTech Connect (OSTI)

    Petruzielo, Robin S [Cornell University; Heberle, Frederick A [ORNL; Drazba, Paul [ORNL; Katsaras, John [ORNL; Feigenson, Gerald [Cornell University

    2013-01-01

    Membrane raft size measurements are crucial to understanding the stability and functionality of rafts in cells. The challenge of accurately measuring raft size is evidenced by the disparate reports of domain sizes, which range from nanometers to microns for the ternary model membrane system sphingomyelin (SM)/1-palmitoyl-2-oleoyl-sn-glycero-3-phosphocholine (POPC)/cholesterol (Chol). Using F rster resonance energy transfer (FRET) and differential scanning calorimetry (DSC), we established phase diagrams for porcine brain SM (bSM)/dioleoyl-sn-glycero-3-phosphocholine (DOPC)/Chol and bSM/POPC/Chol at 15 and 25 C. By combining two techniqueswith different spatial sensitivities, namely FRET and small-angle neutron scattering (SANS),we have significantly narrowed the uncertainty in domain size estimates for bSM/POPC/Chol mixtures. Compositional trends in FRET data revealed coexisting domains at 15 and 25 C for bothmixtures, while SANS measurements detected no domain formation for bSM/POPC/Chol. Together these results indicate that liquid domains in bSM/POPC/Chol are between 2 and 7 nmin radius at 25 C: that is, domains must be on the order of the 2 6 nmF rster distance of the FRET probes, but smaller than the ~7 nm minimum cluster size detectable with SANS. However, for palmitoyl SM (PSM)/POPC/Chol at a similar composition, SANS detected coexisting liquid domains. This increase in domain size upon replacing the natural SMcomponent (which consists of amixture of chain lengths) with synthetic PSM, suggests a role for SM chain length in modulating raft size in vivo.

  10. Stabilized wide bandgap MAPbBrxI3-x perovskite by enhanced grain size and improved crystallinity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Miao; Bi, Cheng; Yuan, Yongbo; Bai, Yang; Huang, Jinsong

    2015-12-07

    In this study, the light instability of CH3NH3PbIxBr3–x has been raised one of the biggest challenges for its application in tandem solar cells. Here we show that an improved crystallinity and grain size of CH3NH3PbIxBr3–x films could stabilize these materials under one sun illumination, improving both the efficiency and stability of the wide-bandgap perovskite solar cells.

  11. THE SIZE DISTRIBUTION OF THE NEPTUNE TROJANS AND THE MISSING INTERMEDIATE-SIZED PLANETESIMALS

    SciTech Connect (OSTI)

    Sheppard, Scott S.; Trujillo, Chadwick A.

    2010-11-10

    We present an ultra-deep survey for Neptune Trojans using the Subaru 8.2 m and Magellan 6.5 m telescopes. The survey reached a 50% detection efficiency in the R band at m{sub R} = 25.7 mag and covered 49 deg{sup 2} of sky. m{sub R} = 25.7 mag corresponds to Neptune Trojans that are about 16 km in radius (assuming an albedo of 0.05). A paucity of smaller Neptune Trojans (radii < 45 km) compared with larger ones was found. The brightest Neptune Trojans appear to follow a steep power-law slope (q = 5 {+-} 1) similar to the brightest objects in the other known stable reservoirs such as the Kuiper Belt, Jupiter Trojans, and main belt asteroids. We find a roll-over for the Neptune Trojans that occurs around a radius of r = 45 {+-} 10 km (m{sub R} = 23.5 {+-} 0.3), which is also very similar to the other stable reservoirs. All the observed stable regions in the solar system show evidence for Missing Intermediate-Sized Planetesimals (MISPs). This indicates a primordial and not collisional origin, which suggests that planetesimal formation proceeded directly from small to large objects. The scarcity of intermediate- and smaller-sized Neptune Trojans may limit them as being a strong source for the short period comets.

  12. CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2015 Peer Review | Department of Energy Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: James Braun, Purdue University View the Presentation PDF icon CBEI: Coordinating RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications Control and Diagnostics for Rooftop Units - 2014 BTO Peer Review CBEI: Lessons

  13. SBA Increases Size Standards for Waste Remediation Services &

    Energy Savers [EERE]

    Information/Admin Support | Department of Energy Increases Size Standards for Waste Remediation Services & Information/Admin Support SBA Increases Size Standards for Waste Remediation Services & Information/Admin Support December 12, 2012 - 10:22am Addthis John Hale III John Hale III Director, Office of Small and Disadvantaged Business Utilization Earlier this week, the U.S. Small Business Administration announced that they have revised size definitions for small businesses in

  14. Fiber Sizing Sensor and Controller | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fiber Sizing Sensor and Controller Fiber Sizing Sensor and Controller Revolutionary Optical Technology Provides Rapid Measurement of Large Samples of Fiber Diameters Fiber size (or denier) has a significant effect on the performance of fiber-based products, such as filters, insulation, and composites. Fiber samples are generally characterized by optical or electron microscopy. Flow resistance of a sample of fibers (e.g., by the Micronaire(tm) technique) is also used to estimate the mean fiber

  15. Development of Model Filtration Media for Investigating Size-Dependent

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filtration Efficiency | Department of Energy Model Filtration Media for Investigating Size-Dependent Filtration Efficiency Development of Model Filtration Media for Investigating Size-Dependent Filtration Efficiency A novel method for fabricating custom porous filtration media for emission control has been developed. Controlled pore sizes could be used to optimize high-capture efficiency with low backpressure. PDF icon p-25_strzelec.pdf More Documents & Publications Fuel-Neutral Studies

  16. Sizing a New Water Heater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    systems: Tankless or demand-type water heaters Solar water heating system Storage and heat pump (with tank) water heaters. For sizing combination water and space heating systems --...

  17. Property:Incentive/EligSysSize | Open Energy Information

    Open Energy Info (EERE)

    minimum
    Recycled Energy: 15 Megawatt maximum Alameda Municipal Power - Solar Photovoltaics Rebate Program (California) + Maximum size is 1 MW or 110% of customer's...

  18. Solar Trackers Market - Global Industry Analysis, Size, Share...

    Open Energy Info (EERE)

    Solar Trackers Market - Global Industry Analysis, Size, Share, Growth, Trends and Forecast, 2010 - 2020 Home > Groups > Increase Natural Gas Energy Efficiency John55364's picture...

  19. Efficient Algorithm for Locating and Sizing Series Compensation...

    Office of Scientific and Technical Information (OSTI)

    Compensation Devices in Large Transmission Grids: Model Implementation We explore optimization methods for planning the placement, sizing and operations of Flexible Alternating...

  20. Scalable Heuristics for Planning, Placement and Sizing of Flexible...

    Office of Scientific and Technical Information (OSTI)

    SC and SVC devices are represented by modification of the transmission line inductances and reactive power nodal corrections respectively. We find one placement and sizing of FACTs ...

  1. CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Russell Taylor, United Technologies Research Center View the Presentation PDF icon ...

  2. Overview of Detailed Chemical Speciation and Particle Sizing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Diesel Exhaust, Both Real Time and Filter Based Measurements Overview of Detailed Chemical Speciation and Particle Sizing for Diesel Exhaust, Both Real Time and Filter Based ...

  3. Correlating Size and Composition-Dependent Effects with Magnetic...

    Office of Scientific and Technical Information (OSTI)

    Correlating Size and Composition-Dependent Effects with Magnetic, Mssbauer, and Pair Distribution Function Measurements in a Family of Catalytically Active Ferrite Nanoparticles ...

  4. CBEI: Coordinating RTUs in Small and Medium Sized Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RTUs in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: James Braun, Purdue University View the Presentation PDF icon CBEI: Coordinating RTUs in...

  5. SBA Increases Size Standards for Waste Remediation Services ...

    Broader source: Energy.gov (indexed) [DOE]

    one current revenue-based size standard in NAICS Sector 21: Mining, Quarrying, and Oil and Gas Extraction. SBA evaluated four industries in this sector to determine whether...

  6. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kWh Summary The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy...

  7. Droplet sizes, dynamics and deposition in vertical annular flow

    SciTech Connect (OSTI)

    Lopes, J C.B.; Dukler, A E

    1985-10-01

    The role of droplets in vertical upwards annular flow is investigated, focusing on the droplet size distributions, dynamics, and deposition phenomena. An experimental program was performed based on a new laser optical technique developed in these laboratories and implemented here for annular flow. This permitted the simultaneous measurement of droplet size, axial and radial velocity. The dependence of droplet size distributions on flow conditions is analyzed. The Upper-Log Normal function proves to be a good model for the size distribution. The mechanism controlling the maximum stable drop size was found to result from the interaction of the pressure fluctuations of the turbulent flow of the gas core with the droplet. The average axial droplet velocity showed a weak dependence on gas rates. This can be explained once the droplet size distribution and droplet size-velocity relationship are analyzed simultaneously. The surprising result from the droplet conditional analysis is that larger droplet travel faster than smaller ones. This dependence cannot be explained if the drag curves used do not take into account the high levels of turbulence present in the gas core in annular flow. If these are considered, then interesting new situations of multiplicity and stability of droplet terminal velocities are encountered. Also, the observed size-velocity relationship can be explained. A droplet deposition is formulated based on the particle inertia control. This permitted the calculation of rates of drop deposition directly from the droplet size and velocities data.

  8. Cell diameter measurements obtained with a handheld cell counter could be used as a surrogate marker of G2/M arrest and apoptosis in colon cancer cell lines exposed to SN-38

    SciTech Connect (OSTI)

    Tahara, Makiko; Inoue, Takeshi; Fujii, Hirofumi; Kotake, Kenjiro; Sugano, Kokichi

    2013-05-17

    Highlights: Chemo-sensitivity to SN-38 was assayed by the automated cell counter. Colon cancer cell line, HCT116 cells were more sensitive to SN-38 than HT29 cells. Increase of cell size reflects G2/M arrest. Appearance of small particles indicates cell apoptosis. -- Abstract: In vitro assessment of chemosensitivity are important for experiments evaluating cancer therapies. The Scepter 2.0 cell counter, an automated handheld device based on the Coulter principle of impedance-based particle detection, enables the accurate discrimination of cell populations according to cell size and volume. In this study, the effects of SN-38, the active metabolite of irinotecan, on the colon cancer cell lines HCT116 and HT29 were evaluated using this device. The cell count data obtained with the Scepter counter were compared with those obtained with the {sup 3}H-thymidine uptake assay, which has been used to measure cell proliferation in many previous studies. In addition, we examined whether the changes in the size distributions of these cells reflected alterations in the frequency of cell cycle arrest and/or apoptosis induced by SN-38 treatment. In our experiments using the Scepter 2.0 cell counter, the cell counts were demonstrated to be accurate and reproducible measure and alterations of cell diameter reflected G2/M cell cycle arrest and apoptosis. Our data show that easy-to-use cell counting tools can be utilized to evaluate the cell-killing effects of novel treatments on cancer cells in vitro.

  9. Method of producing submicron size particles and product produced thereby

    DOE Patents [OSTI]

    Bourne, R.S.; Eichman, C.C.; Welbon, W.W.

    1988-05-11

    Submicron size particles are produced by using a sputtering process to deposit particles into a liquid. The liquid is processed to recover the particles therefrom, and the particles have sizes in the range of twenty to two hundred Angstroms. Either metallic or non-metallic particles can be produced, and the metallic particles can be used in ''metallic inks.'' 4 figs.

  10. Comparison of Fuel Cell Technologies | Department of Energy

    Office of Environmental Management (EM)

    Comparison of Fuel Cell Technologies Comparison of Fuel Cell Technologies Each fuel cell technology has advantages and disadvantages. See how fuel cell technologies compare with one another. This comparison chart is also available as a fact sheet. Fuel Cell Type Common Electrolyte Operating Temperature Typical Stack Size Electrical Efficiency (LHV) Applications Advantages Disadvantages Polymer Electrolyte Membrane (PEM) Perfluorosulfonic acid <120°C <1 kW-100 kW 60% direct H2;a 40%

  11. Fuel Cell Handbook, Fifth Edition

    SciTech Connect (OSTI)

    Energy and Environmental Solutions

    2000-10-31

    Progress continues in fuel cell technology since the previous edition of the Fuel Cell Handbook was published in November 1998. Uppermost, polymer electrolyte fuel cells, molten carbonate fuel cells, and solid oxide fuel cells have been demonstrated at commercial size in power plants. The previously demonstrated phosphoric acid fuel cells have entered the marketplace with more than 220 power plants delivered. Highlighting this commercial entry, the phosphoric acid power plant fleet has demonstrated 95+% availability and several units have passed 40,000 hours of operation. One unit has operated over 49,000 hours. Early expectations of very low emissions and relatively high efficiencies have been met in power plants with each type of fuel cell. Fuel flexibility has been demonstrated using natural gas, propane, landfill gas, anaerobic digester gas, military logistic fuels, and coal gas, greatly expanding market opportunities. Transportation markets worldwide have shown remarkable interest in fuel cells; nearly every major vehicle manufacturer in the U.S., Europe, and the Far East is supporting development. This Handbook provides a foundation in fuel cells for persons wanting a better understanding of the technology, its benefits, and the systems issues that influence its application. Trends in technology are discussed, including next-generation concepts that promise ultrahigh efficiency and low cost, while providing exceptionally clean power plant systems. Section 1 summarizes fuel cell progress since the last edition and includes existing power plant nameplate data. Section 2 addresses the thermodynamics of fuel cells to provide an understanding of fuel cell operation at two levels (basic and advanced). Sections 3 through 8 describe the six major fuel cell types and their performance based on cell operating conditions. Alkaline and intermediate solid state fuel cells were added to this edition of the Handbook. New information indicates that manufacturers have stayed with proven cell designs, focusing instead on advancing the system surrounding the fuel cell to lower life cycle costs. Section 9, Fuel Cell Systems, has been significantly revised to characterize near-term and next-generation fuel cell power plant systems at a conceptual level of detail. Section 10 provides examples of practical fuel cell system calculations. A list of fuel cell URLs is included in the Appendix. A new index assists the reader in locating specific information quickly.

  12. Pore-size-distribution of cationic polyacrylamide hydrogels. Progress report

    SciTech Connect (OSTI)

    Kremer, M.; Prausnitz, J.M.

    1992-06-01

    The pore size distribution of a AAm/MAPTAC (acrylamide copolymerized with (3-methacrylamidopropyl)trimethylammonium chloride) hydrogel was investigated using Kuga`s mixed-solute-exclusion method, taking into account the wall effect. A Brownian-motion model is also used. Results show the feasibility of determining pore-size distribution of porous materials using the mixed-solute-exclusion method in conjunction with solution of the Fredholm equation; good agreement was obtained with experiment, even for bimodal pore structures. However, different pore size distributions were calculated for the two different probe-solutes (Dextran and poly(ethylene glycol/oxide)). Future work is outlined. 32 figs, 25 refs.

  13. Pore-size-distribution of cationic polyacrylamide hydrogels

    SciTech Connect (OSTI)

    Kremer, M.; Prausnitz, J.M.

    1992-06-01

    The pore size distribution of a AAm/MAPTAC (acrylamide copolymerized with (3-methacrylamidopropyl)trimethylammonium chloride) hydrogel was investigated using Kuga's mixed-solute-exclusion method, taking into account the wall effect. A Brownian-motion model is also used. Results show the feasibility of determining pore-size distribution of porous materials using the mixed-solute-exclusion method in conjunction with solution of the Fredholm equation; good agreement was obtained with experiment, even for bimodal pore structures. However, different pore size distributions were calculated for the two different probe-solutes (Dextran and poly(ethylene glycol/oxide)). Future work is outlined. 32 figs, 25 refs.

  14. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0.036kWh Summary The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy...

  15. 1999 Commercial Building Characteristics--Detailed Tables--Size...

    U.S. Energy Information Administration (EIA) Indexed Site

    Complete Set of 1999 CBECS Detailed Tables Detailed Tables- of Buildings Table B6. Building Size, Number of Buildings b6.pdf (PDF file), b6.xls (Excel spreadsheet file), b6.txt...

  16. Knowledge-based sizing of cogeneration plant in buildings

    SciTech Connect (OSTI)

    Williams, J.M.; Griffiths, A.J.; Knight, I.P.

    1998-10-01

    Cogeneration is now accepted as a cost-effective and environmentally friendly means of meeting some of a building`s heating and power needs. Cogeneration plants have been installed in many buildings throughout the United Kingdom. Because of commercial pressures, building owners and cogeneration companies are keen to reduce the time and money involved in sizing units, and a decision support tool has been developed to aid the engineer in selecting the unit size. An initial assessment of the sizing can be made with only knowledge of the building`s type, size, and location, which enables the model to be used in new build situations. For an existing building, the accuracy of the predictions can then be progressively improved by providing more information about the building`s energy use, enabling the optimum unit to be identified. This paper briefly describes the model and demonstrates its use through an example feasibility study.

  17. TVA - Mid-Sized Renewable Standard Offer Program | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    generation Green Power Providers Program by providing incentives for mid-sized renewable energy generators between 50kW and 20MW to enter into long term price contracts. The goal...

  18. Quantum-size-controlled photoelectrochemical etching of semiconductor...

    Office of Scientific and Technical Information (OSTI)

    For example, quantum dots (QDs) can be QSC-PEC-etched from epitaxial InGaN thin films using narrowband laser photoexcitation, and the QD sizes (and hence bandgaps and ...

  19. Model catalysis by size-selected cluster deposition

    SciTech Connect (OSTI)

    Anderson, Scott

    2015-11-20

    This report summarizes the accomplishments during the last four years of the subject grant. Results are presented for experiments in which size-selected model catalysts were studied under surface science and aqueous electrochemical conditions. Strong effects of cluster size were found, and by correlating the size effects with size-dependent physical properties of the samples measured by surface science methods, it was possible to deduce mechanistic insights, such as the factors that control the rate-limiting step in the reactions. Results are presented for CO oxidation, CO binding energetics and geometries, and electronic effects under surface science conditions, and for the electrochemical oxygen reduction reaction, ethanol oxidation reaction, and for oxidation of carbon by water.

  20. Particle size and shape distributions of hammer milled pine

    SciTech Connect (OSTI)

    Westover, Tyler Lott; Matthews, Austin Colter; Williams, Christopher Luke; Ryan, John Chadron Benjamin

    2015-04-01

    Particle size and shape distributions impact particle heating rates and diffusion of volatized gases out of particles during fast pyrolysis conversion, and consequently must be modeled accurately in order for computational pyrolysis models to produce reliable results for bulk solid materials. For this milestone, lodge pole pine chips were ground using a Thomas-Wiley #4 mill using two screen sizes in order to produce two representative materials that are suitable for fast pyrolysis. For the first material, a 6 mm screen was employed in the mill and for the second material, a 3 mm screen was employed in the mill. Both materials were subjected to RoTap sieve analysis, and the distributions of the particle sizes and shapes were determined using digital image analysis. The results of the physical analysis will be fed into computational pyrolysis simulations to create models of materials with realistic particle size and shape distributions. This milestone was met on schedule.

  1. TVA- Mid-Sized Renewable Standard Offer Program

    Broader source: Energy.gov [DOE]

    The Tennessee Valley Authority (TVA) now compliments the small generation Green Power Providers Program by providing incentives for mid-sized renewable energy generators between 50kW and 20MW to...

  2. Photoluminescent 1-2 nm sized silicon nanoparticles: A surface...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photoluminescent 1-2 nm sized silicon nanoparticles: A surface-dependent system Authors: Romero, J.J., Llansola-Portols, M.J., Dell'Arciprete, M.L., Rodrguez, H.B., Moore,...

  3. A stochastic method for stand-alone photovoltaic system sizing

    SciTech Connect (OSTI)

    Cabral, Claudia Valeria Tavora; Filho, Delly Oliveira; Martins, Jose Helvecio; Toledo, Olga Moraes

    2010-09-15

    Photovoltaic systems utilize solar energy to generate electrical energy to meet load demands. Optimal sizing of these systems includes the characterization of solar radiation. Solar radiation at the Earth's surface has random characteristics and has been the focus of various academic studies. The objective of this study was to stochastically analyze parameters involved in the sizing of photovoltaic generators and develop a methodology for sizing of stand-alone photovoltaic systems. Energy storage for isolated systems and solar radiation were analyzed stochastically due to their random behavior. For the development of the methodology proposed stochastic analysis were studied including the Markov chain and beta probability density function. The obtained results were compared with those for sizing of stand-alone using from the Sandia method (deterministic), in which the stochastic model presented more reliable values. Both models present advantages and disadvantages; however, the stochastic one is more complex and provides more reliable and realistic results. (author)

  4. AVTA: Full-Size Electric Vehicle Specifications and Test Procedures |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Full-Size Electric Vehicle Specifications and Test Procedures AVTA: Full-Size Electric Vehicle Specifications and Test Procedures PDF icon EV America Test Specifications PDF icon ETA-TP001 Implementation of SAE Standard J1263, February 1996 - Road Load Measurement and Dynamometer Simulation Using Coastdown Techniques PDF icon ETA-TP002 Implementation of SAE Standard J1666, May 1993 - Electric Vehicle Acceleration, Gradeability, and Deceleration Test Procedure PDF icon

  5. Overview of Detailed Chemical Speciation and Particle Sizing for Diesel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exhaust, Both Real Time and Filter Based Measurements | Department of Energy Detailed Chemical Speciation and Particle Sizing for Diesel Exhaust, Both Real Time and Filter Based Measurements Overview of Detailed Chemical Speciation and Particle Sizing for Diesel Exhaust, Both Real Time and Filter Based Measurements 2002 DEER Conference Presentation: University of Wisconsin - Madison PDF icon 2002_deer_foster.pdf More Documents & Publications The Impact of Oil Consumption Mechanisms on

  6. Global Nuclear Energy Partnership Triples in Size to 16 Members |

    Energy Savers [EERE]

    Department of Energy Triples in Size to 16 Members Global Nuclear Energy Partnership Triples in Size to 16 Members September 16, 2007 - 2:33pm Addthis Nations Sign On to International Cooperation for Safe Expansion of Nuclear Energy Worldwide VIENNA, AUSTRIA - U.S. Secretary of Energy Samuel W. Bodman and senior international officials from 16 nations today agreed to increase international nuclear energy cooperation through the Global Nuclear Energy Partnership (GNEP). China, France, Japan,

  7. Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism Citation Details In-Document Search Title: Enhanced Nanoparticle Size Control by Extending LaMer's Mechanism Authors: Vreeland, Erika C. ; Watt, John ; Schober, Gretchen B. ; Hance, Bradley G. ; Austin, Mariah J. ; Price, Andrew D. ; Fellows, Benjamin D. ; Monson, Todd C. ; Hudak, Nicholas S. ; Maldonado-Camargo, Lorena ; Bohorquez, Ana C. ; Rinaldi, Carlos ; Huber, Dale L. Publication Date:

  8. Evolution of droplet size distribution and autoconversion parameterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in turbulent clouds Evolution of droplet size distribution and autoconversion parameterization in turbulent clouds McGraw, Robert Brookhaven National Laboratory Liu, Yangang Brookhaven National Laboratory Category: Modeling Effects from turbulence-induced fluctuations in water vapor saturation on cloud droplet growth are examined using a Brownian diffusion model [McGraw and Liu, 2006]. The model predicts diffusive broadening of the droplet size distribution, tempered by enhanced

  9. Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Versatile Diesel Particulate Filter Cartridge Any Size, Any Shape Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_nixdorf.pdf More Documents & Publications Pleated Ceramic Fiber Diesel Particulate Filter Ultra-Lite Diesel Particulate Filter Cartridge for Reduced

  10. Scalable Heuristics for Planning, Placement and Sizing of Flexible AC

    Office of Scientific and Technical Information (OSTI)

    Transmission System Devices (Technical Report) | SciTech Connect Technical Report: Scalable Heuristics for Planning, Placement and Sizing of Flexible AC Transmission System Devices Citation Details In-Document Search Title: Scalable Heuristics for Planning, Placement and Sizing of Flexible AC Transmission System Devices Aiming to relieve transmission grid congestion and improve or extend feasibility domain of the operations, we build optimization heuristics, generalizing standard AC Optimal

  11. Size Effects in the Electrochemical Alloying and Cycling of

    Office of Scientific and Technical Information (OSTI)

    Electrodeposited Aluminum with Lithium. (Journal Article) | SciTech Connect Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium. Citation Details In-Document Search Title: Size Effects in the Electrochemical Alloying and Cycling of Electrodeposited Aluminum with Lithium. Abstract not provided. Authors: Hudak, Nicholas ; Huber, Dale L. Publication Date: 2011-10-01 OSTI Identifier: 1106948 Report Number(s): SAND2011-7589J 464917 DOE Contract

  12. Microsoft PowerPoint - ARM2007LetterSize.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote sensing microphysical retrieval and cloud microphysics parameterizations rely on a knowledge of the shape of cloud drop size distributions (DSD). These are often approximated by Gamma, lognormal, or, more specifically by Khrgian-Mazin, Marshall-Palmer type distributions. We ask the question which functional form approximates best the drop size distributions in drizzling stratocumulus? Specifically, we evaluate the accuracy of lognormal and Gamma-type distributions in approximating higher

  13. Effect of Particle Size and Operating Conditions on Pt3Co PEMFC Cathode Catalyst Durability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gummalla, Mallika; Ball, Sarah; Condit, David; Rasouli, Somaye; Yu, Kang; Ferreira, Paulo; Myers, Deborah; Yang, Zhiwei

    2015-05-29

    The initial performance and decay trends of polymer electrolyte membrane fuel cells (PEMFC) cathodes with Pt3Co catalysts of three mean particle sizes (4.9 nm, 8.1 nm, and 14.8 nm) with identical Pt loadings are compared. Even though the cathode based on 4.9 nm catalyst exhibited the highest initial electrochemical surface area (ECA) and mass activity, the cathode based on 8.1 nm catalyst showed better initial performance at high currents. Owing to the low mass activity of the large particles, the initial performance of the 14.8 nm Pt3Co-based electrode was the lowest. The performance decay rate of the electrodes with themore » smallest Pt3Co particle size was the highest and that of the largest Pt3Co particle size was lowest. Interestingly, with increasing number of decay cycles (0.6 to 1.0 V, 50 mV/s), the relative improvement in performance of the cathode based on 8.1 nm Pt3Co over the 4.9 nm Pt3Co increased, owing to better stability of the 8.1 nm catalyst. The electron microprobe analysis (EMPA) of the decayed membrane-electrode assembly (MEA) showed that the amount of Co in the membrane was lower for the larger particles, and the platinum loss into the membrane also decreased with increasing particle size. This suggests that the higher initial performance at high currents with 8.1 nm Pt3Co could be due to lower contamination of the ionomer in the electrode. Furthermore, lower loss of Co from the catalyst with increased particle size could be one of the factors contributing to the stability of ECA and mass activity of electrodes with larger cathode catalyst particles. To delineate the impact of particle size and alloy effects, these results are compared with prior work from our research group on size effects of pure platinum catalysts. The impact of PEMFC operating conditions, including upper potential, relative humidity, and temperature on the alloy catalyst decay trends, along with the EMPA analysis of the decayed MEAs, are reported.« less

  14. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cells Fact Sheets Research Team Members Key Contacts Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per 1000 hours over a

  15. ARM - Instrument - sodar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govInstrumentssodar Documentation ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Mini Sound Detection and Ranging (SODAR) Instrument Categories Atmospheric Profiling, Surface Meteorology The Mini-SODAR measures vertical wind in the lower 200 meters of the atmosphere. It uses phased array technology to reduce the size relative to a traditional SODAR. Output Datastreams sodar : Mini Sound Detection and

  16. CLIMATE CHANGE FUEL CELL PROGRAM

    SciTech Connect (OSTI)

    Mike Walneuski

    2004-09-16

    ChevronTexaco has successfully operated a 200 kW PC25C phosphoric acid fuel cell power plant at the corporate data center in San Ramon, California for the past two years and seven months following installation in December 2001. This site was chosen based on the ability to utilize the combined heat (hot water) and power generation capability of this modular fuel cell power plant in an office park setting . In addition, this project also represents one of the first commercial applications of a stationary fuel cell for a mission critical data center to assess power reliability benefits. This fuel cell power plant system has demonstrated outstanding reliability and performance relative to other comparably sized cogeneration systems.

  17. Imaging Liquids Using Microfluidic Cells

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

    2013-05-10

    Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

  18. Microbial Cell Imaging

    SciTech Connect (OSTI)

    Doktycz, Mitchel John; Sullivan, Claretta; Mortensen, Ninell P; Allison, David P

    2011-01-01

    Atomic force microscopy (AFM) is finding increasing application in a variety of fields including microbiology. Until the emergence of AFM, techniques for ivnestigating processes in single microbes were limited. From a biologist's perspective, the fact that AFM can be used to generate high-resolution images in buffers or media is its most appealing feature as live-cell imaging can be pursued. Imaging living cells by AFM allows dynamic biological events to be studied, at the nanoscale, in real time. Few areas of biological research have as much to gain as microbiology from the application of AFM. Whereas the scale of microbes places them near the limit of resolution for light microscopy. AFM is well suited for the study of structures on the order of a micron or less. Although electron microscopy techniques have been the standard for high-resolution imaging of microbes, AFM is quickly gaining favor for several reasons. First, fixatives that impair biological activity are not required. Second, AFM is capable of detecting forces in the pN range, and precise control of the force applied to the cantilever can be maintained. This combination facilitates the evaluation of physical characteristics of microbes. Third, rather than yielding the composite, statistical average of cell populations, as is the case with many biochemical assays, the behavior of single cells can be monitored. Despite the potential of AFM in microbiology, there are several limitations that must be considered. For example, the time required to record an image allows for the study of gross events such as cell division or membrane degradation from an antibiotic but precludes the evaluation of biological reactions and events that happen in just fractions of a second. Additionally, the AFM is a topographical tool and is restricted to imaging surfaces. Therefore, it cannot be used to look inside cells as with opticla and transmission electron microscopes. other practical considerations are the limitation on the maximum scan size (roughly 100 x 100 {mu}m) and the restricted movement of the cantilever in the Z (or height) direction. In most commercial AFMs, the Z range is restricted to roughly 10 {mu}m such that the height of cells to be imaged must be seriously considered. Nevertheless, AFM can provide structural-functional information at nanometer resolution and do so in physiologically relevant environments. Further, instrumentation for scanning probe microscopy continues to advance. Systems for high-speed imaging are becoming available, and techniques for looking inside the cells are being demonstrated. The ability to combine AFM with other imaging modalities is likely to have an even greater impact on microbiological studies. AFM studies of intact microbial cells started to appear in the literature in the 1990s. For example, AFM studies of Saccharomyces cerevisiae examined buddings cars after cell division and detailed changes related to cell growth processes. Also, the first AFM studies of bacterial biofilms appeared. In the late 1990s, AFM studies of intact fungal spores described clear changes in spore surfaces upon germination, and studies of individual bacterial cells were also described. These early bacterial imaging studies examined changes in bacterial morphology due to antimicrobial peptides exposure and bacterial adhesion properties. The majority of these early studies were carried out on dried samples and took advantage of the resolving power of AFM. The lack of cell mounting procedures presented an impediment for cell imaging studies. Subsequently, several approaches to mounting microbial cells have been developed, and these techniques are described later. Also highlighted are general considerations for microbial imaging and a description of some of the various applications of AFM to microbiology.

  19. Nanocluster production for solar cell applications

    SciTech Connect (OSTI)

    Al Dosari, Haila M.; Ayesh, Ahmad I.

    2013-08-07

    This research focuses on the fabrication and characterization of silver (Ag) and silicon (Si) nanoclusters that might be used for solar cell applications. Silver and silicon nanoclusters have been synthesized by means of dc magnetron sputtering and inert gas condensation inside an ultra-high vacuum compatible system. We have found that nanocluster size distributions can be tuned by various source parameters, such as the sputtering discharge power, flow rate of argon inert gas, and aggregation length. Quadrupole mass filter and transmission electron microscopy were used to evaluate the size distribution of Ag and Si nanoclusters. Ag nanoclusters with average size in the range of 3.68.3 nm were synthesized (herein size refers to the nanocluster diameter), whereas Si nanoclusters' average size was controlled to range between 2.9 and 7.4 nm by controlling the source parameters. This work illustrates the ability of controlling the Si and Ag nanoclusters' sizes by proper optimization of the operation conditions. By controlling nanoclusters' sizes, one can alter their surface properties to suit the need to enhance solar cell efficiency. Herein, Ag nanoclusters were deposited on commercial polycrystalline solar cells. Short circuit current (I{sub SC}), open circuit voltage (V{sub OC}), fill factor, and efficiency (?) were obtained under light source with an intensity of 30 mW/cm{sup 2}. A 22.7% enhancement in solar cell efficiency could be measured after deposition of Ag nanoclusters, which demonstrates that Ag nanoclusters generated in this work are useful to enhance solar cell efficiency.

  20. Residential Variable-Capacity Heat Pumps Sized to Heating Loads

    SciTech Connect (OSTI)

    Munk, Jeffrey D.; Jackson, Roderick K.; Odukomaiya, Adewale; Gehl, Anthony C.

    2014-01-01

    Variable capacity heat pumps are an emerging technology offering significant energy savings potential and improved efficiency. With conventional single-speed systems, it is important to appropriately size heat pumps for the cooling load as over-sizing would result in cycling and insufficient latent capacity required for humidity control. These appropriately sized systems are often under-sized for the heating load and require inefficient supplemental electric resistance heat to meet the heating demand. Variable capacity heat pumps address these shortcomings by providing an opportunity to intentionally size systems for the dominant heating season load without adverse effects of cycling or insufficient dehumidification in the cooling season. This intentionally-sized system could result in significant energy savings in the heating season, as the need for inefficient supplemental electric resistance heat is drastically reduced. This is a continuation of a study evaluating the energy consumption of variable capacity heat pumps installed in two unoccupied research homes in Farragut, a suburb of Knoxville, Tennessee. In this particular study, space conditioning systems are intentionally sized for the heating season loads to provide an opportunity to understand and evaluate the impact this would have on electric resistance heat use and dehumidification. The results and conclusions drawn through this research are valid and specific for portions of the Southeastern and Midwestern United States falling in the mixed-humid climate zone. While other regions in the U.S. do not experience this type of climate, this work provides a basis for, and can help understand the implications of other climate zones on residential space conditioning energy consumption. The data presented here will provide a framework for fine tuning residential building EnergyPlus models that are being developed.

  1. Size exclusion deep bed filtration: Experimental and modelling uncertainties

    SciTech Connect (OSTI)

    Badalyan, Alexander You, Zhenjiang; Aji, Kaiser; Bedrikovetsky, Pavel; Carageorgos, Themis; Zeinijahromi, Abbas

    2014-01-15

    A detailed uncertainty analysis associated with carboxyl-modified latex particle capture in glass bead-formed porous media enabled verification of the two theoretical stochastic models for prediction of particle retention due to size exclusion. At the beginning of this analysis it is established that size exclusion is a dominant particle capture mechanism in the present study: calculated significant repulsive Derjaguin-Landau-Verwey-Overbeek potential between latex particles and glass beads is an indication of their mutual repulsion, thus, fulfilling the necessary condition for size exclusion. Applying linear uncertainty propagation method in the form of truncated Taylor's series expansion, combined standard uncertainties (CSUs) in normalised suspended particle concentrations are calculated using CSUs in experimentally determined parameters such as: an inlet volumetric flowrate of suspension, particle number in suspensions, particle concentrations in inlet and outlet streams, particle and pore throat size distributions. Weathering of glass beads in high alkaline solutions does not appreciably change particle size distribution, and, therefore, is not considered as an additional contributor to the weighted mean particle radius and corresponded weighted mean standard deviation. Weighted mean particle radius and LogNormal mean pore throat radius are characterised by the highest CSUs among all experimental parameters translating to high CSU in the jamming ratio factor (dimensionless particle size). Normalised suspended particle concentrations calculated via two theoretical models are characterised by higher CSUs than those for experimental data. The model accounting the fraction of inaccessible flow as a function of latex particle radius excellently predicts normalised suspended particle concentrations for the whole range of jamming ratios. The presented uncertainty analysis can be also used for comparison of intra- and inter-laboratory particle size exclusion data.

  2. Evaluation of Powertrain Options and Component Sizing for MD...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Drive Cycles 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies ... Activities and Heavy Vehicle Systems Optimization Program Annual Progress Report

  3. Assessment of fuel cell propulsion systems

    SciTech Connect (OSTI)

    Altseimer, J.H.; Frank, J.A.; Nochumson, D.H.; Thayer, G.R.; Rahm, A.M.; Williamson, K.D. Jr.; Hardie, R.W.; Jackson, S.V.

    1983-11-01

    This report assesses the applicability of fuel cells to a wide variety of transportation vehicles and compares them with competing propulsion systems. The assessments include economic evaluations (initial capital cost and levelized-life-cycle costs) and noneconomic evaluations (vehicle performance, power plant size, environmental effects, safety, convenience and reliability). The report also recommends research and development areas to support the development of fuel cell systems. The study indicates that fork-lift trucks are an excellent application for fuel cells. Fuel cell use in urban delivery vans and city buses is promising because it would reduce air pollution. Fuel-cell-powered automobiles, pickup trucks, and intercity buses only look promising over the long term. Based on economic criteria, the use of fuel cells for small marine craft does not appear feasible. Because of economic uncertainties, further study is needed to assess the application of fuel cell systems to freight locomotives and large marine craft.

  4. Connections for solid oxide fuel cells

    DOE Patents [OSTI]

    Collie, Jeffrey C. (Pittsburgh, PA)

    1999-01-01

    A connection for fuel cell assemblies is disclosed. The connection includes compliant members connected to individual fuel cells and a rigid member connected to the compliant members. Adjacent bundles or modules of fuel cells are connected together by mechanically joining their rigid members. The compliant/rigid connection permits construction of generator fuel cell stacks from basic modular groups of cells of any desired size. The connections can be made prior to installation of the fuel cells in a generator, thereby eliminating the need for in-situ completion of the connections. In addition to allowing pre-fabrication, the compliant/rigid connections also simplify removal and replacement of sections of a generator fuel cell stack.

  5. Fuel Cell Transit Bus Coordination and Evaluation Plan California...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The purpose of this document is to describe the coordination and evaluation of the demonstration of seven full-size (40-foot) fuel cell transit buses. The descriptions in this ...

  6. Effect of particle size reduction on anaerobic sludge digestion

    SciTech Connect (OSTI)

    Koutsospyros, A.D.

    1990-01-01

    The majority of organic pollutants in primary sludge are suspended in the form of particulate rather than soluble matter. Microbial organisms cannot assimilate this material without initial solubilization. In anaerobic digestion, the initial size breakdown is accomplished by hydrolytic bacteria. The extent of solubilization is limited by the size of particulate matter. Thus, size reduction prior to digestion is a sound alternative. Size reduction pretreatment was achieved by means of ultrasonic waves. Sonication proved an effective method for size reduction of particulate matter in primary sludge. In addition, although the method produced relatively high amounts of finely dispered solids, the filtration properties of resulting sludges were not affected. Chemical characteristics of sludge, important in anaerobic digestion, were not affected, at least within the attempted range of sonication time and amplitude. The effect of size reduction of primary sludge solids was studied under batch and semi-continuous feed conditions. Preliminary batch digestion experiments were conducted in five 1.5 liter reactors that accepted sonicated feeds of varying pretreatment at four different feed loads (3.3-13.3% by volume). The digestion efficiency and gas production were increased by as much as 30 percent as a result of sonication without any deterioration in the filtration properties of the digester effluent. At higher feed loads the digester efficiency dropped drastically and significant deterioration of the effluent filtration properties from all reactors was evident. Semi-continuous runs were conducted in four reactors. Solids retention time (SRT) was varied from 8 to 20 days. Process efficiency and gas production were enhanced as a result of sonication. Process improvement was more evident under short SRT (8-10 days).

  7. Level: National Data; Row: Employment Sizes within NAICS Codes;

    Gasoline and Diesel Fuel Update (EIA)

    4 Consumption Ratios of Fuel, 2006; Level: National Data; Row: Employment Sizes within NAICS Codes; Column: Energy-Consumption Ratios; Unit: Varies. Consumption Consumption per Dollar Consumption per Dollar of Value NAICS per Employee of Value Added of Shipments Code(a) Economic Characteristic(b) (million Btu) (thousand Btu) (thousand Btu) Total United States 311 - 339 ALL MANUFACTURING INDUSTRIES Employment Size Under 50 562.6 4.7 2.4 50-99 673.1 5.1 2.4 100-249 1,072.8 6.5 3.0 250-499 1,564.3

  8. Level: National Data; Row: Employment Sizes within NAICS Codes;

    Gasoline and Diesel Fuel Update (EIA)

    4 Consumption Ratios of Fuel, 2010; Level: National Data; Row: Employment Sizes within NAICS Codes; Column: Energy-Consumption Ratios; Unit: Varies. Consumption Consumption per Dollar Consumption per Dollar of Value NAICS per Employee of Value Added of Shipments Code(a) Economic Characteristic(b) (million Btu) (thousand Btu) (thousand Btu) Total United States 311 - 339 ALL MANUFACTURING INDUSTRIES Employment Size Under 50 625.5 3.3 1.7 50-99 882.3 5.8 2.5 100-249 1,114.9 5.8 2.5 250-499 2,250.4

  9. Concentrations and Size Distributions of Particulate Matter Emissions from

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel | Department of Energy Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel Concentrations and Size Distributions of Particulate Matter Emissions from Catalyzed Trap-Equipped Heavy-duty Diesel Vehicles Operating on Ultra-low Sulfur EC-D Fuel 2002 DEER Conference Presentation: West Virginia

  10. Metal oxide porous ceramic membranes with small pore sizes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Xu, Qunyin (Madison, WI)

    1992-01-01

    A method is disclosed for the production of metal oxide ceramic membranes of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.

  11. Metal oxide porous ceramic membranes with small pore sizes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Xu, Qunyin (Madison, WI)

    1991-01-01

    A method is disclosed for the production of metal oxide ceramic membranes of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.

  12. Businesses Seek Fuel Cells to Meet Sustainability Goals, Provide Reliable Power

    Broader source: Energy.gov [DOE]

    Businesses of all sizes are increasingly adopting cost-effective fuel cell technology to improve electrical power reliability, increase efficiencies, and reduce carbon emissions of operations, according to The Business Case for Fuel Cells 2015: Powering Corporate Sustainability, a new report from the Fuel Cell Technologies Office, compiled by the Fuel Cell and Hydrogen Energy Association.

  13. Characterization of Chemical Properties, Unit Cell Parameters and Particle

    Office of Scientific and Technical Information (OSTI)

    Size Distribution of Three Zeolite Reference Materials: RM 8850 - Zeolite Y, RM 8851 - Zeolite A and RM 8852 - Ammonium ZSM-5 Zeolite (Journal Article) | SciTech Connect Journal Article: Characterization of Chemical Properties, Unit Cell Parameters and Particle Size Distribution of Three Zeolite Reference Materials: RM 8850 - Zeolite Y, RM 8851 - Zeolite A and RM 8852 - Ammonium ZSM-5 Zeolite Citation Details In-Document Search Title: Characterization of Chemical Properties, Unit Cell

  14. Method of controlling crystallite size in nuclear-reactor fuels

    DOE Patents [OSTI]

    Lloyd, Milton H. (Oak Ridge, TN); Collins, Jack L. (Knoxville, TN); Shell, Sam E. (Oak Ridge, TN)

    1985-01-01

    Improved spherules for making enhanced forms of nuclear-reactor fuels are prepared by internal gelation procedures within a sol-gel operation and are accomplished by first boiling the concentrated HMTA-urea feed solution before engaging in the spherule-forming operation thereby effectively controlling crystallite size in the product spherules.

  15. THE STICKINESS OF MICROMETER-SIZED WATER-ICE PARTICLES

    SciTech Connect (OSTI)

    Gundlach, B.; Blum, J.

    2015-01-01

    Water ice is one of the most abundant materials in dense molecular clouds and in the outer reaches of protoplanetary disks. In contrast to other materials (e.g., silicates), water ice is assumed to be stickier due to its higher specific surface energy, leading to faster or more efficient growth in mutual collisions. However, experiments investigating the stickiness of water ice have been scarce, particularly in the astrophysically relevant micrometer-sized region and at low temperatures. In this work, we present an experimental setup to grow aggregates composed of ?m-sized water-ice particles, which we used to measure the sticking and erosion thresholds of the ice particles at different temperatures between 114 K and 260 K. We show with our experiments that for low temperatures (below ?210 K), ?m-sized water-ice particles stick below a threshold velocity of 9.6 m s{sup 1}, which is approximately 10times higher than the sticking threshold of ?m-sized silica particles. Furthermore, erosion of the grown ice aggregates is observed for velocities above 15.3 m s{sup 1}. A comparison of the experimentally derived sticking threshold with model predictions is performed to determine important material properties of water ice, i.e., the specific surface energy and the viscous relaxation time. Our experimental results indicate that the presence of water ice in the outer reaches of protoplanetary disks can enhance the growth of planetesimals by direct sticking of particles.

  16. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  17. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1996-07-16

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm{sup 3}; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6{times}10{sup 4}cm{sup 2}/g of Ni. 6 figs.

  18. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I. (6851 Carpenter St., Downers Grove, IL 60516); Vissers, Donald R. (611 Clover Ct., Naperville, IL 60540); Prakash, Jai (2205 Arbor Cir. 8, Downers Grove, IL 60515)

    1996-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  19. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-02-01

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

  20. 2007 Fuel Cell Technologies Market Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FUEL CELL TECHNOLOGIES MARKET REPORT JULY 2009 Table of Contents Introduction 1 Worldwide Fuel Cell Shipments Increased 70% from 2006 to 2007 3 Percent Production Increase Highest in North America in 2007 4 North American Units Shipped Increased Three-Fold 6 Commercial Viability of Stationary Units Accompanied by Fewer Demonstrations 7 Large Stationary Units Continue to Increase in Size 8 Small Stationary Shipments Increase Led by Increases in PEM Units Manufactured in North America 9 Fuel

  1. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a .beta." alumina electrolyte and NaAlCl.sub.4 or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose.

  2. Load cell

    DOE Patents [OSTI]

    Spletzer, B.L.

    1998-12-15

    A load cell combines the outputs of a plurality of strain gauges to measure components of an applied load. Combination of strain gauge outputs allows measurement of any of six load components without requiring complex machining or mechanical linkages to isolate load components. An example six axis load cell produces six independent analog outputs, each directly proportional to one of the six general load components. 16 figs.

  3. Screen bowl centrifuge: a high-efficiency particle size separator

    SciTech Connect (OSTI)

    Mohanty, M.K.; Zhang, B.; Khanna, N.; Palit, A.; Dube, B.

    2008-05-15

    Over the years, screen bowl centrifuges have been widely used for dewatering fine coal in coal preparation plants in the United States and elsewhere. It is generally recognized in the engineering and scientific communities that screen bowl centrifuges provide some degree of particle size separation while dewatering fine coal in a common application. However, the extent of differential partitioning of coarse and fine particles achievable by a screen bowl centrifuge has not been systematically studied in the past. The present investigation was aimed at conducting a parametric study using a statistically designed experimental program to better understand and optimize the size classification performance of a screen bowl centrifuge. A continuously operating screen bowl centrifuge having a bowl diameter of 0.5 m was used for this study at the Illinois Coal Development Park. Three key operating parameters, i.e., feed flow rate, feed solid content and pool depth, were varied to conduct a total of 17 experiments using a three-level factorial test matrix. Some of the best size separation performances achieved in this study may be described as having an imperfection value of 0.13 at an effective separation size (d(50c)) of 38 mu m and an imperfection value of 0.27 at an effective separation size (d(50c)) of 2.8 mu m. Due to an effective separation of ultrafine high ash materials, the ash content of the screen bowl feed was reduced from 22.3% to a minimum of 8.84% with a combustible recovery of 84.1% and an ash rejection of 71.6%. A higher combustible recovery of 92.1% was achieved at a product ash content of 12.5% with a d(50c) of 2.8 mu m and imperfection of 0.27.

  4. Continuous-feed electrochemical cell with nonpacking particulate electrode

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA)

    1995-01-01

    An electrochemical cell providing full consumption of electrochemically active particles in a nonpacking, electrolyte-permeable bed has a tapered cell cavity bounded by two nonparallel surfaces separated by a distance that promotes bridging of particles across the cavity. The gap/particle size ratio is maintained as the particles are consumed, decrease in size, and travel from the point of entry to the narrower end of the cell. A cell of this configuration supports a bed of low packing density maintained in a dynamic steady state by alternate formation and collapse of particle bridges across the gap and associated voids over the entire active area of the cell. The cell design can be applied to refuelable zinc/air cells and zinc/ferrocyanide storage batteries.

  5. Continuous-feed electrochemical cell with nonpacking particulate electrode

    DOE Patents [OSTI]

    Cooper, J.F.

    1995-07-18

    An electrochemical cell providing full consumption of electrochemically active particles in a nonpacking, electrolyte-permeable bed has a tapered cell cavity bounded by two nonparallel surfaces separated by a distance that promotes bridging of particles across the cavity. The gap/particle size ratio is maintained as the particles are consumed, decrease in size, and travel from the point of entry to the narrower end of the cell. A cell of this configuration supports a bed of low packing density maintained in a dynamic steady state by alternate formation and collapse of particle bridges across the gap and associated voids over the entire active area of the cell. The cell design can be applied to refuelable zinc/air cells and zinc/ferrocyanide storage batteries. 6 figs.

  6. Magnetic agglomeration method for size control in the synthesis of magnetic nanoparticles

    DOE Patents [OSTI]

    Huber, Dale L. (Albuquerque, NM)

    2011-07-05

    A method for controlling the size of chemically synthesized magnetic nanoparticles that employs magnetic interaction between particles to control particle size and does not rely on conventional kinetic control of the reaction to control particle size. The particles are caused to reversibly agglomerate and precipitate from solution; the size at which this occurs can be well controlled to provide a very narrow particle size distribution. The size of particles is controllable by the size of the surfactant employed in the process; controlling the size of the surfactant allows magnetic control of the agglomeration and precipitation processes. Agglomeration is used to effectively stop particle growth to provide a very narrow range of particle sizes.

  7. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Myles, Kevin M.; Vissers, Donald R.; Prakash, Jai

    1996-01-01

    An electrochemical cell with a positive electrode having an electrochemically active layer of at least one transition metal chloride. A negative electrode of an alkali metal and a compatible electrolyte including an alkali metal salt molten at cell operating temperature is included in the cell. The electrolyte is present at least partially as a corrugated .beta." alumina tube surrounding the negative electrode interior to the positive electrode. The ratio of the volume of liquid electrolyte to the volume of the positive electrode is in the range of from about 0.1 to about 3. A plurality of stacked electrochemical cells is disclosed each having a positive electrode, a negative electrode of an alkali metal molten at cell operating temperature, and a compatible electrolyte. The electrolyte is at least partially present as a corrugated .beta." alumina sheet separating the negative electrode and interior to the positive electrodes. The alkali metal is retained in a porous electrically conductive ceramic, and seals for sealing the junctures of the electrolyte and the adjacent electrodes at the peripheries thereof.

  8. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Myles, K.M.; Vissers, D.R.; Prakash, J.

    1996-07-02

    An electrochemical cell is described with a positive electrode having an electrochemically active layer of at least one transition metal chloride. A negative electrode of an alkali metal and a compatible electrolyte including an alkali metal salt molten at cell operating temperature is included in the cell. The electrolyte is present at least partially as a corrugated {beta}{double_prime} alumina tube surrounding the negative electrode interior to the positive electrode. The ratio of the volume of liquid electrolyte to the volume of the positive electrode is in the range of from about 0.1 to about 3. A plurality of stacked electrochemical cells is disclosed each having a positive electrode, a negative electrode of an alkali metal molten at cell operating temperature, and a compatible electrolyte. The electrolyte is at least partially present as a corrugated {beta}{double_prime} alumina sheet separating the negative electrode and interior to the positive electrodes. The alkali metal is retained in a porous electrically conductive ceramic, and seals for sealing the junctures of the electrolyte and the adjacent electrodes at the peripheries thereof. 8 figs.

  9. Electrochemical cell

    DOE Patents [OSTI]

    Nagy, Z.; Yonco, R.M.; You, H.; Melendres, C.A.

    1992-08-25

    An electrochemical cell has a layer-type or sandwich configuration with a Teflon center section that houses working, reference and counter electrodes and defines a relatively narrow electrolyte cavity. The center section is surrounded on both sides with thin Teflon membranes. The membranes are pressed in place by a pair of Teflon inner frames which are in turn supported by a pair of outer metal frames. The pair of inner and outer frames are provided with corresponding, appropriately shaped slits that are in plane generally transverse to the plane of the working electrode and permit X-ray beams to enter and exit the cell through the Teflon membranes that cover the slits so that the interface between the working electrode and the electrolyte within the cell may be analyzed by transmission geometry. In one embodiment, the center section consists of two parts, one on top of the other. Alternatively, the center section of the electrochemical cell may consist of two intersliding pieces or may be made of a single piece of Teflon sheet material. The electrolyte cavity is shaped so that the electrochemical cell can be rotated 90[degree] in either direction while maintaining the working and counter electrodes submerged in the electrolyte. 5 figs.

  10. DNA fragment sizing and sorting by laser-induced fluorescence

    DOE Patents [OSTI]

    Hammond, Mark L.; Jett, James H.; Keller, Richard A.; Marrone, Babetta L.; Martin, John C.

    1996-01-01

    A method is provided for sizing DNA fragments using high speed detection systems, such as flow cytometry to determine unique characteristics of DNA pieces from a sample. In one characterization the DNA piece is fragmented at preselected sites to produce a plurality of DNA fragments. The DNA piece or the resulting DNA fragments are treated with a dye effective to stain stoichiometrically the DNA piece or the DNA fragments. The fluorescence from the dye in the stained fragments is then examined to generate an output functionally related to the number of nucleotides in each one of the DNA fragments. In one embodiment, the intensity of the fluorescence emissions from each fragment is linearly related to the fragment length. The distribution of DNA fragment sizes forms a characterization of the DNA piece for use in forensic and research applications.

  11. Method and apparatus for physical separation of different sized nanostructures

    DOE Patents [OSTI]

    Roberts, Christopher B.; Saunders, Steven R.

    2012-07-10

    The present application provides apparatuses and methods for the size-selective fractionation of ligand-capped nanoparticles that utilizes the tunable thermophysical properties of gas-expanded liquids. The nanoparticle size separation processes are based on the controlled reduction of the solvent strength of an organic phase nanoparticle dispersion through increases in concentration of the antisolvent gas, such as CO.sub.2, via pressurization. The method of nanomaterial separation contains preparing a vessel having a solvent and dispersed nanoparticles, pressurizing the chamber with a gaseous antisolvent, and causing a first amount of the nanoparticles to precipitate, transporting the solution to a second vessel, pressurizing the second vessel with the gaseous antisolvent and causing further nanoparticles to separate from the solution.

  12. Method for measuring the size distribution of airborne rhinovirus

    SciTech Connect (OSTI)

    Russell, M.L.; Goth-Goldstein, R.; Apte, M.G.; Fisk, W.J.

    2002-01-01

    About 50% of viral-induced respiratory illnesses are caused by the human rhinovirus (HRV). Measurements of the concentrations and sizes of bioaerosols are critical for research on building characteristics, aerosol transport, and mitigation measures. We developed a quantitative reverse transcription-coupled polymerase chain reaction (RT-PCR) assay for HRV and verified that this assay detects HRV in nasal lavage samples. A quantitation standard was used to determine a detection limit of 5 fg of HRV RNA with a linear range over 1000-fold. To measure the size distribution of HRV aerosols, volunteers with a head cold spent two hours in a ventilated research chamber. Airborne particles from the chamber were collected using an Andersen Six-Stage Cascade Impactor. Each stage of the impactor was analyzed by quantitative RT-PCR for HRV. For the first two volunteers with confirmed HRV infection, but with mild symptoms, we were unable to detect HRV on any stage of the impactor.

  13. A novel hybrid (wind-photovoltaic) system sizing procedure

    SciTech Connect (OSTI)

    Hocaoglu, Fatih O.; Gerek, Oemer N.; Kurban, Mehmet

    2009-11-15

    Wind-photovoltaic hybrid system (WPHS) utilization is becoming popular due to increasing energy costs and decreasing prices of turbines and photovoltaic (PV) panels. However, prior to construction of a renewable generation station, it is necessary to determine the optimum number of PV panels and wind turbines for minimal cost during continuity of generated energy to meet the desired consumption. In fact, the traditional sizing procedures find optimum number of the PV modules and wind turbines subject to minimum cost. However, the optimum battery capacity is either not taken into account, or it is found by a full search between all probable solution spaces which requires extensive computation. In this study, a novel description of the production/consumption phenomenon is proposed, and a new sizing procedure is developed. Using this procedure, optimum battery capacity, together with optimum number of PV modules and wind turbines subject to minimum cost can be obtained with good accuracy. (author)

  14. Table B6. Building Size, Number of Buildings, 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    B6. Building Size, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings ","Building Size" ,,"1,001 to 5,000 Square Feet","5,001 to 10,000 Square Feet","10,001 to 25,000 Square Feet","25,001 to 50,000 Square Feet","50,001 to 100,000 Square Feet","100,001 to 200,000 Square Feet","200,001 to 500,000 Square Feet","Over 500,000 Square Feet" "All Buildings

  15. Size and weight graded multi-ply laminar electrodes

    DOE Patents [OSTI]

    Liu, Chia-Tsun (Monroeville, PA); Demczyk, Brian G. (Rostrover Township, Westmoreland County, PA); Rittko, Irvin R. (Murrysville Borough, PA)

    1984-01-01

    An electrode is made comprising a porous backing sheet, and attached thereto a catalytically active layer having an electrolyte permeable side and a backing layer contacting side, where the active layer comprises a homogeneous mixture of active hydrophobic and hydrophilic agglomerates with catalyst disposed equally throughout the active layer, and where the agglomerate size increases from the electrolyte permeable side to the backing sheet contacting side.

  16. Synthesis of micro-sized interconnected Si-C composites

    DOE Patents [OSTI]

    Wang, Donghai; Yi, Ran; Dai, Fang

    2016-02-23

    Embodiments provide a method of producing micro-sized Si--C composites or doped Si--C and Si alloy-C with interconnected nanoscle Si and C building blocks through converting commercially available SiO.sub.x (0

  17. Finite-size instabilities in nuclear energy density functionals

    SciTech Connect (OSTI)

    Hellemans, V.; Heenen, P.-H.; Bender, M.

    2012-10-20

    The systematic lack of convergence of self-consistent mean-field calculations with certain parameterizations of the Skyrme energy density functional has been attributed to the appearance of finite-size instabilities. In this contribution, we investigate what happens at the instability associated with the C{sub 0}{sup {Delta}s}s{sub 0} Dot-Operator {Delta}s{sub 0} term in a high-spin state of the superdeformed band in {sup 194}Hg.

  18. Water holding capacities of fly ashes: Effect of size fractionation

    SciTech Connect (OSTI)

    Sarkar, A.; Rano, R.

    2007-07-01

    Water holding capacities of fly ashes from different thermal power plants in Eastern India have been compared. Moreover, the effect of size fractionation (sieving) on the water holding capacities has also been determined. The desorption rate of water held by the fly ash fractions at ambient temperature (25-30{sup o}C) has been investigated. The effect of mixing various size fractions of fly ash in increasing the water holding capacities of fly ash has been studied. It is observed that the fly ash obtained from a thermal power plant working on stoker-fired combustor has the highest water holding capacity, followed by the one that works on pulverized fuel combustor. Fly ash collected from super thermal power plant has the least water holding capacity (40.7%). The coarser size fractions of fly ashes in general have higher water holding capacities than the finer ones. An attempt has been made to correlate the results obtained, with the potential use in agriculture.

  19. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-08-23

    An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

  20. Electrochemical cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL)

    1984-01-01

    An improved secondary electrochemical cell is disclosed having a negative electrode of lithium aluminum, a positive electrode of iron sulfide, a molten electrolyte of lithium chloride and potassium chloride, and the combination that the fully charged theoretical capacity of the negative electrode is in the range of 0.5-1.0 that of the positive electrode. The cell thus is negative electrode limiting during discharge cycling. Preferably, the negative electrode contains therein, in the approximate range of 1-10 volume % of the electrode, an additive from the materials of graphitized carbon, aluminum-iron alloy, and/or magnesium oxide.

  1. Size tunable elemental copper nanoparticles: extracellular synthesis by thermoanaerobic bacteria and capping molecules

    SciTech Connect (OSTI)

    Jang, Gyoung Gug; Jacobs, Christopher B; Gresback, Ryan G; Ivanov, Ilia N; Meyer III, Harry M; Kidder, Michelle; Joshi, Pooran C; Jellison Jr, Gerald Earle; Phelps, Tommy Joe; Graham, David E; Moon, Ji Won

    2015-01-01

    Bimodal sized elemental copper (Cu) nanoparticles (NPs) were synthesized from inexpensive oxidized copper salts by an extracellular metal-reduction process using anaerobic Thermoanaerobacter sp. X513 bacteria in aqueous solution. The bacteria nucleate NPs outside of the cell, and they control the Cu2+ reduction rate to form uniform crystallites with an average diameter of 1.75 0.46 m after 3-day incubation. To control the size and enhance air stability of Cu NPs, the reaction mixtures were supplemented with nitrilotriacetic acid as a chelator, and the surfactant capping agents oleic acid, oleylamine, ascorbic acid, or L-cysteine. Time-dependent UV-visible absorption measurements and XPS studies indicated well-suspended, bimodal colloidal Cu NPs (70 150 and 5 10 nm) with extended air-stability up to 300 min and stable Cu NP films surfaces with 14% oxidation after 20 days. FTIR spectroscopy suggested that these capping agents were effectively adsorbed on the NP surface providing oxidation resistance in aqueous and dry conditions. Compared to previously reported Cu NP syntheses, this biological process substantially reduced the requirement for hazardous organic solvents and chemical reducing agents, while reducing the levels of Cu oxide impurities in the product. This process was highly reproducible and scalable from 0.01 to 1-L batches.

  2. Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent

    DOE Patents [OSTI]

    Fulton, J.L.; Yonker, C.R.; Hallen, R.R.; Baker, E.G.; Bowman, L.E.; Silva, L.J.

    1999-01-26

    Disclosed is a method of sizing and desizing yarn, or more specifically to a method of coating yarn with size and removing size from yarn with liquid carbon dioxide solvent. 3 figs.

  3. Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent

    DOE Patents [OSTI]

    Fulton, John L. (Richland, WA); Yonker, Clement R. (Richland, WA); Hallen, Richard R. (Richland, WA); Baker, Eddie G. (Richland, WA); Bowman, Lawrence E. (Richland, WA); Silva, Laura J. (Richland, WA)

    1999-01-01

    Disclosed is a method of sizing and desizing yarn, or more specifically to a method of coating yarn with size and removing size from yarn with liquid carbon dioxide solvent.

  4. Quantification of Lithium-ion Cell Thermal Runaway Energetics

    SciTech Connect (OSTI)

    Orendorff, Christopher J.; Lamb, Joshua; Steele, Leigh Anna Marie; Spangler, Scott Wilmer; Langendorf, Jill Louise

    2016-01-01

    Much of what is known about lithium-ion cell thermal runaway energetics has been measured and extrapolated from data acquired on relatively small cells (< 3 Ah). This work is aimed at understanding the effects of cell size on thermal runaway energetics on cells from 3 to 50 Ah of both LiFePO4 (LFP) and LiNi0.80Co0.15Al0.05O2 (NCA) chemistries. Results show that for both LFP and NCA cells, the normalized heating rate (W/Ah) increases roughly linearly for cells from 3-38 Ah while the normalized total heat released (kJ/Ah) is relatively constant over that cell size range. The magnitude of the normalized heating rate is on the order of 2x greater for NCA relative to LFP chemistries for 2-3 Ah cells, while that difference is on the order of 10x for 30-40 Ah cells. The total normalized heat release is ~ 15-20% greater for NCA relative to LFP cells across the entire size range studied 3-38 Ah.

  5. Photovoltaic cell

    DOE Patents [OSTI]

    Gordon, Roy G.; Kurtz, Sarah

    1984-11-27

    In a photovoltaic cell structure containing a visibly transparent, electrically conductive first layer of metal oxide, and a light-absorbing semiconductive photovoltaic second layer, the improvement comprising a thin layer of transition metal nitride, carbide or boride interposed between said first and second layers.

  6. Photoelectrodialytic cell

    DOE Patents [OSTI]

    Murphy, G.W.

    1983-09-13

    A multicompartment photoelectrodialytic demineralization cell is provided with a buffer compartment interposed between the product compartment and a compartment containing an electrolyte solution. Semipermeable membranes separate the buffer compartment from the product and electrolyte compartments. The buffer compartment is flushed to prevent leakage of the electrolyte compartment from entering the product compartment. 3 figs.

  7. Photoelectrodialytic cell

    DOE Patents [OSTI]

    Murphy, George W. (2328 Ashwood, Norman, OK 73069)

    1983-01-01

    A multicompartment photoelectrodialytic demineralization cell is provided with a buffer compartment interposed between the product compartment and a compartment containing an electrolyte solution. Semipermeable membranes separate the buffer compartment from the product and electrolyte compartments. The buffer compartment is flushed to prevent leakage of the electrolyte compartment from entering the product compartment.

  8. " Row: Employment Sizes within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    3. Consumption Ratios of Fuel, 1998;" " Level: National Data; " " Row: Employment Sizes within NAICS Codes;" " Column: Energy-Consumption Ratios;" " Unit: Varies." " "," ",,,"Consumption"," " " "," ",,"Consumption","per Dollar" " "," ","Consumption","per Dollar","of Value","RSE" "NAICS",,"per

  9. " Row: Employment Sizes within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Consumption Ratios of Fuel, 2002;" " Level: National Data; " " Row: Employment Sizes within NAICS Codes;" " Column: Energy-Consumption Ratios;" " Unit: Varies." " "," ",,,"Consumption"," " " "," ",,"Consumption","per Dollar" " "," ","Consumption","per Dollar","of Value","RSE" "NAICS",,"per

  10. " Row: Employment Sizes within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Consumption Ratios of Fuel, 2006;" " Level: National Data; " " Row: Employment Sizes within NAICS Codes;" " Column: Energy-Consumption Ratios;" " Unit: Varies." ,,,,"Consumption" ,,,"Consumption","per Dollar" ,,"Consumption","per Dollar","of Value" "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic

  11. " Row: Employment Sizes within NAICS Codes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Consumption Ratios of Fuel, 2010;" " Level: National Data; " " Row: Employment Sizes within NAICS Codes;" " Column: Energy-Consumption Ratios;" " Unit: Varies." ,,,,"Consumption" ,,,"Consumption","per Dollar" ,,"Consumption","per Dollar","of Value" "NAICS",,"per Employee","of Value Added","of Shipments" "Code(a)","Economic

  12. Micro-size gas turbines create market opportunities

    SciTech Connect (OSTI)

    Scott, W.G.

    1997-09-01

    Power plants in the 25 to 250 kW-size range will enable utilities, IPPs and ESCOs to provide economic power for a variety of applications. Small, low-cost, highly efficient gas turbines provide the utility industry with a four-generation technology that features numerous benefits and potential applications. These include firm power to isolated communities, commercial centers and industries; peak shaving for utility systems to reduce the incremental cost of additional loads; peak shaving for large commercial and industrial establishments to reduce demand charges, as well as standby, emergency power and uninterruptible power supply (UPS).

  13. Table B10. Employment Size Category, Number of Buildings, 1999

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Employment Size Category, Number of Buildings, 1999" ,"Number of Buildings (thousand)" ,"All Buildings","Number of Workers" ,,"Fewer than 5 Workers","5 to 9 Workers","10 to 19 Workers","20 to 49 Workers","50 to 99 Workers","100 to 249 Workers","250 or More Workers" "All Buildings ................",4657,2376,807,683,487,174,90,39 "Building Floorspace" "(Square

  14. Neutrons measure phase behavior in pores at Angstrom size

    SciTech Connect (OSTI)

    Bardoel, Agatha A; Melnichenko, Yuri B

    2012-01-01

    Researchers have measured the phase behavior of green house gases in pores at the Angstrom-level, using small angle neutron scattering (SANS) at the Oak Ridge National Laboratory's High Flux Isotope Reactor. Yuri Melnichenko, an instrument scientist on the General Purpose Small Angle Neutron Scattering (GP SANS) Diffractometer at ORNL's High Flux Isotope Reactor, his postdoctoral associate Lilin He and collaborators Nidia Gallego and Cristian Contescu from the Material Sciences Division (ORNL) were engaged in the work. They were studying nanoporous carbons to assess their attractiveness as storage media for hydrogen, with a view to potential use for on-board hydrogen storage for transportation applications. Nanoporous carbons can also serve as electrode material for supercapacitors and batteries. The researchers successfully determined that the most efficiently condensing pore size in a carbon nanoporous material for hydrogen storage is less than one nanometer. In a paper recently published by the Journal of the American Chemical Society, the collaborators used small angle neutron scattering to study how hydrogen condenses in small pores at ambient temperature. They discovered that the surface-molecule interactions create internal pressures in pores that may exceed the external gas pressure by a factor of up to 50. 'This is an exciting result,' Melnichenko said, 'as you achieve extreme densification in pores 'for free', i.e. without spending any energy. These results can be used to guide the development of new carbon adsorbents tailored to maximize hydrogen storage capacities.' Another important factor that defines the adsorption capacity of sub-nanometer pores is their shape. In order to get accurate structural information and maximize sorption capacity, it is important that pores are small and of approximately uniform size. In collaboration with Drexel University's Yury Gogotsi who supplied the samples, Melnichenko and his collaborators used the GP SANS instrument to study how the size and shape of pores in sub-nanometer porous carbons varies, depending on the manufacturing conditions. While small angle X-ray scattering (SAXS) can do the job too, Melnichenko says, the SANS method broke new ground in analyzing the shape and behavior of pores at subnanometer size, when subjected to varying synthesis temperature. 'We found that these very small pores are in fact spherical, and that when we change the synthesis conditions, they become elongated, even 'slit-like', and all of this on a subnanometer scale,' Melnichenko said.

  15. Size reduction techniques for vital compliant VHDL simulation models

    DOE Patents [OSTI]

    Rich, Marvin J.; Misra, Ashutosh

    2006-08-01

    A method and system select delay values from a VHDL standard delay file that correspond to an instance of a logic gate in a logic model. Then the system collects all the delay values of the selected instance and builds super generics for the rise-time and the fall-time of the selected instance. Then, the system repeats this process for every delay value in the standard delay file (310) that correspond to every instance of every logic gate in the logic model. The system then outputs a reduced size standard delay file (314) containing the super generics for every instance of every logic gate in the logic model.

  16. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  17. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  18. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  19. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  20. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  1. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar cells. With a suite of x-ray microprobe techniques, a multi-institutional collaboration led by researchers from the University of California, Berkeley, and Berkeley Lab studied the distribution of metal clusters in a variety of multicrystalline solar cells before and after processing. Their discovery that the size, spatial

  2. Fuel Cell Technologies Researcher Lightens Green Fuel Production |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fuel Cell Technologies Researcher Lightens Green Fuel Production Fuel Cell Technologies Researcher Lightens Green Fuel Production August 25, 2014 - 9:36am Addthis Research funded by EERE's Fuel Cell Technologies Office has dramatically increased the efficiency of biofuel production by changing certain genes in algae to make them pale green. Dr. Tasios Melis of the University of California, Berkeley is making stable changes to the algae's genes to reduce the size of the

  3. Electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-12-23

    This patent describes an electrochemical cell having a metal anode wherein the metal is selected from zinc and cadmium; a bromine cathode; and an aqueous electrolyte containing a metal bromide, the metal bromide having the same metal as the metal of the anode. The improvement described here comprises: a bromine complexing agent in the aqueous metal bromide electrolyte, the complexing agent consisting solely of a quaternary ammonium salt of an N-organo substituted alpha amino acid, ester, or betaine.

  4. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cells - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  5. Size-dependent structure of silver nanoparticles under high pressure

    SciTech Connect (OSTI)

    Koski, Kristie Jo

    2008-12-31

    Silver noble metal nanoparticles that are<10 nm often possess multiply twinned grains allowing them to adopt shapes and atomic structures not observed in bulk materials. The properties exhibited by particles with multiply twinned polycrystalline structures are often far different from those of single-crystalline particles and from the bulk. I will present experimental evidence that silver nanoparticles<10 nm undergo a reversible structural transformation under hydrostatic pressures up to 10 GPa. Results for nanoparticles in the intermediate size range of 5 to 10 nm suggest a reversible linear pressure-dependent rhombohedral distortion which has not been previously observed in bulk silver. I propose a mechanism for this transitiion that considers the bond-length distribution in idealized multiply twinned icosahedral particles. Results for nanoparticles of 3.9 nm suggest a reversible linear pressure-dependent orthorhombic distortion. This distortion is interpreted in the context of idealized decahedral particles. In addition, given these size-dependent measurements of silver nanoparticle compression with pressure, we have constructed a pressure calibration curve. Encapsulating these silver nanoparticles in hollow metal oxide nanospheres then allows us to measure the pressure inside a nanoshell using x-ray diffraction. We demonstrate the measurement of pressure gradients across nanoshells and show that these nanoshells have maximum resolved shear strengths on the order of 500 MPa to IGPa.

  6. Particle impactor assembly for size selective high volume air sampler

    DOE Patents [OSTI]

    Langer, Gerhard (Boulder, CO)

    1988-08-16

    Air containing entrained particulate matter is directed through a plurality of parallel, narrow, vertically oriented impactor slots of an inlet element toward an adjacently located, relatively large, dust impaction surface preferably covered with an adhesive material. The air flow turns over the impaction surface, leaving behind the relatively larger particles according to the human thoracic separation system and passes through two elongate exhaust apertures defining the outer bounds of the impaction collection surface to pass through divergent passages which slow down and distribute the air flow, with entrained smaller particles, over a fine filter element that separates the fine particles from the air. The elongate exhaust apertures defining the impaction collection surface are spaced apart by a distance greater than the lengths of elongate impactor slots in the inlet element and are oriented to be normal thereto. By appropriate selection of dimensions and the number of impactor slots air flow through the inlet element is provided a nonuniform velocity distribution with the lower velocities being obtained near the center of the impactor slots, in order to separate out particles larger than a certain predetermined size on the impaction collection surface. The impaction collection surface, even in a moderately sized apparatus, is thus relatively large and permits the prolonged sampling of air for periods extending to four weeks.

  7. The intrinsic two-dimensional size of Sagittarius A*

    SciTech Connect (OSTI)

    Bower, Geoffrey C.; Markoff, Sera; Brunthaler, Andreas; Falcke, Heino; Law, Casey; Maitra, Dipankar; Clavel, M.; Goldwurm, A.; Morris, M. R.; Witzel, Gunther; Meyer, Leo; Ghez, A. M.

    2014-07-20

    We report the detection of the two-dimensional structure of the radio source associated with the Galactic Center black hole, Sagittarius A*, obtained from Very Long Baseline Array observations at a wavelength of 7 mm. The intrinsic source is modeled as an elliptical Gaussian with major-axis size 35.4 12.6 R{sub S} in position angle 95 east of north. This morphology can be interpreted in the context of both jet and accretion disk models for the radio emission. There is supporting evidence in large angular-scale multi-wavelength observations for both source models for a preferred axis near 95. We also place a maximum peak-to-peak change of 15% in the intrinsic major-axis size over five different epochs. Three observations were triggered by detection of near infrared (NIR) flares and one was simultaneous with a large X-ray flare detected by NuSTAR. The absence of simultaneous and quasi-simultaneous flares indicates that not all high energy events produce variability at radio wavelengths. This supports the conclusion that NIR and X-ray flares are primarily due to electron excitation and not to an enhanced accretion rate onto the black hole.

  8. Method of assembly of molecular-sized nets and scaffolding

    DOE Patents [OSTI]

    Michl, Josef; Magnera, Thomas F.; David, Donald E.; Harrison, Robin M.

    1999-01-01

    The present invention relates to methods and starting materials for forming molecular-sized grids or nets, or other structures based on such grids and nets, by creating molecular links between elementary molecular modules constrained to move in only two directions on an interface or surface by adhesion or bonding to that interface or surface. In the methods of this invention, monomers are employed as the building blocks of grids and more complex structures. Monomers are introduced onto and allowed to adhere or bond to an interface. The connector groups of adjacent adhered monomers are then polymerized with each other to form a regular grid in two dimensions above the interface. Modules that are not bound or adhered to the interface are removed prior to reaction of the connector groups to avoid undesired three-dimensional cross-linking and the formation of non-grid structures. Grids formed by the methods of this invention are useful in a variety of applications, including among others, for separations technology, as masks for forming regular surface structures (i.e., metal deposition) and as templates for three-dimensional molecular-sized structures.

  9. Method of assembly of molecular-sized nets and scaffolding

    DOE Patents [OSTI]

    Michl, J.; Magnera, T.F.; David, D.E.; Harrison, R.M.

    1999-03-02

    The present invention relates to methods and starting materials for forming molecular-sized grids or nets, or other structures based on such grids and nets, by creating molecular links between elementary molecular modules constrained to move in only two directions on an interface or surface by adhesion or bonding to that interface or surface. In the methods of this invention, monomers are employed as the building blocks of grids and more complex structures. Monomers are introduced onto and allowed to adhere or bond to an interface. The connector groups of adjacent adhered monomers are then polymerized with each other to form a regular grid in two dimensions above the interface. Modules that are not bound or adhered to the interface are removed prior to reaction of the connector groups to avoid undesired three-dimensional cross-linking and the formation of non-grid structures. Grids formed by the methods of this invention are useful in a variety of applications, including among others, for separations technology, as masks for forming regular surface structures (i.e., metal deposition) and as templates for three-dimensional molecular-sized structures. 9 figs.

  10. The Cell Processor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2005 IBM Corporation The Cell Processor Architecture & Issues 2 2005 IBM Corporation Agenda Cell Processor Overview Programming the Cell Processor Concluding Remarks 3 ...

  11. SU-E-T-141: Effect of a Single Gold Nanoparticle with Different Sizes Inside a Small Water Phantom

    SciTech Connect (OSTI)

    Jing, J; Lin, H; Xiong, Z

    2014-06-01

    Purpose: This study is to investigate the effects of the gold nanoparticles (GNP), a series of micrometre scale simulations have been constructed with Geant4 to track particles and simulate the effects of those particles as they pass through water phantom. Methods: The simulations were used to calculate the number of secondary electrons which are emitted from the particle tracks and the amount of energy which is deposited in the cell tissue. More electrons means that more water molecules can undergo hydrolysis and create potentially dangerous free radical molecules, therefore breaking up DNA and killing off cells or causing damaging mutations. Results: For the 20nm GNP, all three proton energies saw a small increase of electrons above the control, while the X-rays nearly tripled the number of electrons in the phantom. For the 50 nm GNP, the 3 and 2 MeV protons saw a small increase again, however the 1 MeV protons saw a decrease in electrons, the X-rays saw a large increase of nearly 4 times the number of electrons. For the 110nm GNP, all three proton energies saw a decrease in the total number of electrons in the phantom, while the X-rays saw an increase of 8 times as many electrons. Conclusion: From the range of GNP sizes used, it was found that the X-rays have a larger dose enhancement effect as the GNP size increases, the relation between electron emissions and GNP size was linear. This is because the majority of the dose from the X-rays is delivered to the cell tissue through the initial high energy secondary electrons, any dose lost from the Augerelectrons being trapped inside the GNP volume is small compared to the dose that escapes with the high energy electrons.

  12. Size-exclusion chromatography system for macromolecular interaction analysis

    DOE Patents [OSTI]

    Stevens, Fred J.

    1988-01-01

    A low pressure, microcomputer controlled system employing high performance liquid chromatography (HPLC) allows for precise analysis of the interaction of two reversibly associating macromolecules such as proteins. Since a macromolecular complex migrates faster than its components during size-exclusion chromatography, the difference between the elution profile of a mixture of two macromolecules and the summation of the elution profiles of the two components provides a quantifiable indication of the degree of molecular interaction. This delta profile is used to qualitatively reveal the presence or absence of significant interaction or to rank the relative degree of interaction in comparing samples and, in combination with a computer simulation, is further used to quantify the magnitude of the interaction in an arrangement wherein a microcomputer is coupled to analytical instrumentation in a novel manner.

  13. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, J.E.; Kelly, T.F.

    1999-06-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains. 20 figs.

  14. Oscillating magnetocaloric effect in size-quantized diamagnetic film

    SciTech Connect (OSTI)

    Alisultanov, Z. Z.

    2014-03-21

    We investigate the oscillating magnetocaloric effect on a size-quantized diamagnetic film in a transverse magnetic field. We obtain the analytical expression for the thermodynamic potential in case of the arbitrary spectrum of carriers. The entropy change is shown to be the oscillating function of the magnetic field and the film thickness. The nature of this effect is the same as for the de Haas–van Alphen effect. The magnetic part of entropy has a maximal value at some temperature. Such behavior of the entropy is not observed in magneto-ordered materials. We discuss the nature of unusual behavior of the magnetic entropy. We compare our results with the data obtained for 2D and 3D cases.

  15. Strengthening of metallic alloys with nanometer-size oxide dispersions

    DOE Patents [OSTI]

    Flinn, John E. (Idaho Falls, ID); Kelly, Thomas F. (Madison, WI)

    1999-01-01

    Austenitic stainless steels and nickel-base alloys containing, by wt. %, 0.1 to 3.0% V, 0.01 to 0.08% C, 0.01 to 0.5% N, 0.05% max. each of Al and Ti, and 0.005 to 0.10% O, are strengthened and ductility retained by atomization of a metal melt under cover of an inert gas with added oxygen to form approximately 8 nanometer-size hollow oxides within the alloy grains and, when the alloy is aged, strengthened by precipitation of carbides and nitrides nucleated by the hollow oxides. Added strengthening is achieved by nitrogen solid solution strengthening and by the effect of solid oxides precipitated along and pinning grain boundaries to provide temperature-stabilization and refinement of the alloy grains.

  16. Medium-size high-temperature gas-cooled reactor

    SciTech Connect (OSTI)

    Peinado, C.O.; Koutz, S.L.

    1980-08-01

    This report summarizes high-temperature gas-cooled reactor (HTGR) experience for the 40-MW(e) Peach Bottom Nuclear Generating Station of Philadelphia Electric Company and the 330-MW(e) Fort St. Vrain Nuclear Generating Station of the Public Service Company of Colorado. Both reactors are graphite moderated and helium cooled, operating at approx. 760/sup 0/C (1400/sup 0/F) and using the uranium/thorium fuel cycle. The plants have demonstrated the inherent safety characteristics, the low activation of components, and the high efficiency associated with the HTGR concept. This experience has been translated into the conceptual design of a medium-sized 1170-MW(t) HTGR for generation of 450 MW of electric power. The concept incorporates inherent HTGR safety characteristics (a multiply redundant prestressed concrete reactor vessel (PCRV), a graphite core, and an inert single-phase coolant) and engineered safety features (core auxiliary cooling, relief valve, and steam generator dump systems).

  17. Diagnostic Studies on Lithium Battery Cells and Cell Components...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies on Lithium Battery Cells and Cell Components Diagnostic Studies on Lithium Battery Cells and Cell Components 2012 DOE Hydrogen and Fuel Cells Program and Vehicle ...

  18. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell...

  19. Energy Efficiency Services Sector: Workforce Size and Expectations for Growth

    SciTech Connect (OSTI)

    Goldman, Charles; Fuller, Merrian C.; Stuart, Elizabeth; Peters, Jane S.; McRae, Marjorie; Albers, Nathaniel; Lutzenhiser, Susan; Spahic, Mersiha

    2010-03-22

    The energy efficiency services sector (EESS) is poised to become an increasingly important part of the U.S. economy. Climate change and energy supply concerns, volatile and increasing energy prices, and a desire for greater energy independence have led many state and national leaders to support an increasingly prominent role for energy efficiency in U.S. energy policy. The national economic recession has also helped to boost the visibility of energy efficiency, as part of a strategy to support economic recovery. We expect investment in energy efficiency to increase dramatically both in the near-term and through 2020 and beyond. This increase will come both from public support, such as the American Recovery and Reinvestment Act (ARRA) and significant increases in utility ratepayer funds directed toward efficiency, and also from increased private spending due to codes and standards, increasing energy prices, and voluntary standards for industry. Given the growing attention on energy efficiency, there is a concern among policy makers, program administrators, and others that there is an insufficiently trained workforce in place to meet the energy efficiency goals being put in place by local, state, and federal policy. To understand the likelihood of a potential workforce gap and appropriate response strategies, one needs to understand the size, composition, and potential for growth of the EESS. We use a bottom-up approach based upon almost 300 interviews with program administrators, education and training providers, and a variety of EESS employers and trade associations; communications with over 50 sector experts; as well as an extensive literature review. We attempt to provide insight into key aspects of the EESS by describing the current job composition, the current workforce size, our projections for sector growth through 2020, and key issues that may limit this growth.

  20. Fuel Cell Buses

    Broader source: Energy.gov [DOE]

    Presentation slides from the Fuel Cell Technologies Office webinar Fuel Cell Buses Development held September 12, 2013.

  1. Effect of Particle Size and Operating Conditions on Pt3Co PEMFC Cathode Catalyst Durability

    SciTech Connect (OSTI)

    Gummalla, Mallika; Ball, Sarah; Condit, David; Rasouli, Somaye; Yu, Kang; Ferreira, Paulo; Myers, Deborah; Yang, Zhiwei

    2015-05-29

    The initial performance and decay trends of polymer electrolyte membrane fuel cells (PEMFC) cathodes with Pt3Co catalysts of three mean particle sizes (4.9 nm, 8.1 nm, and 14.8 nm) with identical Pt loadings are compared. Even though the cathode based on 4.9 nm catalyst exhibited the highest initial electrochemical surface area (ECA) and mass activity, the cathode based on 8.1 nm catalyst showed better initial performance at high currents. Owing to the low mass activity of the large particles, the initial performance of the 14.8 nm Pt3Co-based electrode was the lowest. The performance decay rate of the electrodes with the smallest Pt3Co particle size was the highest and that of the largest Pt3Co particle size was lowest. Interestingly, with increasing number of decay cycles (0.6 to 1.0 V, 50 mV/s), the relative improvement in performance of the cathode based on 8.1 nm Pt3Co over the 4.9 nm Pt3Co increased, owing to better stability of the 8.1 nm catalyst. The electron microprobe analysis (EMPA) of the decayed membrane-electrode assembly (MEA) showed that the amount of Co in the membrane was lower for the larger particles, and the platinum loss into the membrane also decreased with increasing particle size. This suggests that the higher initial performance at high currents with 8.1 nm Pt3Co could be due to lower contamination of the ionomer in the electrode. Furthermore, lower loss of Co from the catalyst with increased particle size could be one of the factors contributing to the stability of ECA and mass activity of electrodes with larger cathode catalyst particles. To delineate the impact of particle size and alloy effects, these results are compared with prior work from our research group on size effects of pure platinum catalysts. The impact of PEMFC operating conditions, including upper potential, relative humidity, and temperature on the alloy catalyst decay trends, along with the EMPA analysis of the decayed MEAs, are reported.

  2. Diode magnetic-field influence on radiographic spot size

    SciTech Connect (OSTI)

    Ekdahl, Carl A. Jr.

    2012-09-04

    Flash radiography of hydrodynamic experiments driven by high explosives is a well-known diagnostic technique in use at many laboratories. The Dual-Axis Radiography for Hydrodynamic Testing (DARHT) facility at Los Alamos was developed for flash radiography of large hydrodynamic experiments. Two linear induction accelerators (LIAs) produce the bremsstrahlung radiographic source spots for orthogonal views of each experiment ('hydrotest'). The 2-kA, 20-MeV Axis-I LIA creates a single 60-ns radiography pulse. For time resolution of the hydrotest dynamics, the 1.7-kA, 16.5-MeV Axis-II LIA creates up to four radiography pulses by slicing them out of a longer pulse that has a 1.6-{micro}s flattop. Both axes now routinely produce radiographic source spot sizes having full-width at half-maximum (FWHM) less than 1 mm. To further improve on the radiographic resolution, one must consider the major factors influencing the spot size: (1) Beam convergence at the final focus; (2) Beam emittance; (3) Beam canonical angular momentum; (4) Beam-motion blur; and (5) Beam-target interactions. Beam emittance growth and motion in the accelerators have been addressed by careful tuning. Defocusing by beam-target interactions has been minimized through tuning of the final focus solenoid for optimum convergence and other means. Finally, the beam canonical angular momentum is minimized by using a 'shielded source' of electrons. An ideal shielded source creates the beam in a region where the axial magnetic field is zero, thus the canonical momentum zero, since the beam is born with no mechanical angular momentum. It then follows from Busch's conservation theorem that the canonical angular momentum is minimized at the target, at least in principal. In the DARHT accelerators, the axial magnetic field at the cathode is minmized by using a 'bucking coil' solenoid with reverse polarity to cancel out whatever solenoidal beam transport field exists there. This is imperfect in practice, because of radial variation of the total field across the cathode surface, solenoid misalignments, and long-term variability of solenoid fields for given currents. Therefore, it is useful to quantify the relative importance of canonical momentum in determining the focal spot, and to establish a systematic methodology for tuning the bucking coils for minimum spot size. That is the purpose of this article. Section II provides a theoretical foundation for understanding the relative importance of the canonical momentum. Section III describes the results of simulations used to quantify beam parameters, including the momentum, for each of the accelerators. Section IV compares the two accelerators, especially with respect to mis-tuned bucking coils. Finally, Section IV concludes with a methodology for optimizing the bucking coil settings.

  3. Photoelectrochemical cell

    DOE Patents [OSTI]

    Rauh, R. David (Newton, MA); Boudreau, Robert A. (Norton, MA)

    1983-06-14

    A photoelectrochemical cell comprising a sealed container having a light-transmitting window for admitting light into the container across a light-admitting plane, an electrolyte in the container, a photoelectrode in the container having a light-absorbing surface arranged to receive light from the window and in contact with the electrolyte, the surface having a plurality of spaced portions oblique to the plane, each portion having dimensions at least an order of magnitude larger than the maximum wavelength of incident sunlight, the total surface area of the surface being larger than the area of the plane bounded by the container, and a counter electrode in the container in contact with the electrolyte.

  4. Electric mergers: Transmission pricing, market size, and effects on competition

    SciTech Connect (OSTI)

    Legato, C.D.

    1996-06-01

    The prospect of deregulation has introducted a wave of mergers among electric utilities. Most of these mergers would fail an antitrust review because, by combining generation assets of interconnected utilities, they have substantially reduced potential competition in generation. In fact, one can predict that most mergers of utilities that operate within the same power pool or reliability region will be anticompetitive, even if they are not interconnected. Using an antitrust analysis, this article illustrates the potential anticompetitive effects of mergers between interconnected utilities. It concludes that the relevant geographic market will be an area in which a single, area-wide transmission price is charged. Moreover, it concludes that this area and, hence, the relevant market will likely span an area no larger than the Mid-American Interconnected Network or the Virginia/Carolina subregion of the Southeastern Reliability Council. Assuming markets of this size, the data on resulting concentration will show severe consequences for mergers of the sort that were announced in 1995 and 1996.

  5. Scaling Semantic Graph Databases in Size and Performance

    SciTech Connect (OSTI)

    Morari, Alessandro; Castellana, Vito G.; Villa, Oreste; Tumeo, Antonino; Weaver, Jesse R.; Haglin, David J.; Choudhury, Sutanay; Feo, John T.

    2014-08-06

    In this paper we present SGEM, a full software system for accelerating large-scale semantic graph databases on commodity clusters. Unlike current approaches, SGEM addresses semantic graph databases by only employing graph methods at all the levels of the stack. On one hand, this allows exploiting the space efficiency of graph data structures and the inherent parallelism of graph algorithms. These features adapt well to the increasing system memory and core counts of modern commodity clusters. On the other hand, however, these systems are optimized for regular computation and batched data transfers, while graph methods usually are irregular and generate fine-grained data accesses with poor spatial and temporal locality. Our framework comprises a SPARQL to data parallel C compiler, a library of parallel graph methods and a custom, multithreaded runtime system. We introduce our stack, motivate its advantages with respect to other solutions and show how we solved the challenges posed by irregular behaviors. We present the result of our software stack on the Berlin SPARQL benchmarks with datasets up to 10 billion triples (a triple corresponds to a graph edge), demonstrating scaling in dataset size and in performance as more nodes are added to the cluster.

  6. Advanced Electrocatalysts for PEM Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Webinar on PEM Fuel Cells 2-12-2013 Advanced Electrocatalysts for PEM Fuel Cells Nenad M. Markovic Vojislav R. Stamenkovic Materials Science Division Argonne National Laboratory 1 st Layer 2 nd Layer 3 rd Layer Pt=100 at.% Pt=48 at.% Ni=52 at.% Pt=87 at.% Ni=13 at.% Pt[111]-Skin surface 5 nm (111) (100) 3 nm Size distribution c-15 nm Shape Bulk composition Surface structure ? HR-TEM: Characterization of Nanoscale Pt/C Catalyst x 15 x 5 Surface composition ? 2 Surface Science Approach design,

  7. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, Irwin Charles (Strongsville, OH); Greinke, Ronald Alfred (Medina, OH)

    1997-01-01

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (i) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (ii) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns. (b) a binder This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode.

  8. Heteroatom incorporated coke for electrochemical cell electrode

    DOE Patents [OSTI]

    Lewis, I.C.; Greinke, R.A.

    1997-06-17

    This invention relates to an electrode for a coke/alkali metal electrochemical cell comprising: (a) calcined coke particles: (1) that contain at least 0.5 weight percent of nitrogen heteroatoms and at least 1.0 weight percent sulfur heteroatoms, and (2) that have an average particle size from 2 microns to 40 microns with essentially no particles being greater than 50 microns and (b) a binder. This invention also relates to a coke/alkali metal electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrically conductive salt, and (c) a counterelectrode. 5 figs.

  9. Stabilized wide bandgap MAPbBrxI3-x perovskite by enhanced grain size and improved crystallinity

    SciTech Connect (OSTI)

    Hu, Miao; Bi, Cheng; Yuan, Yongbo; Bai, Yang; Huang, Jinsong

    2015-12-07

    In this study, the light instability of CH3NH3PbIxBr3x has been raised one of the biggest challenges for its application in tandem solar cells. Here we show that an improved crystallinity and grain size of CH3NH3PbIxBr3x films could stabilize these materials under one sun illumination, improving both the efficiency and stability of the wide-bandgap perovskite solar cells.

  10. Effect of Engine-Out NOx Control Strategies on PM Size Distribution...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in ...

  11. Better Buildings Alliance, Advanced Rooftop Unit Campaign: RTU Sizing Guidance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-09-01

    This fact sheet discusses the causes and consequences of incorrect RTU sizing (with respect to cooling tonnage and supply fan horsepower) and points to resources that can help ensure accurate sizing calculations.

  12. ON THE SIZE, SHAPE, AND DENSITY OF DWARF PLANET MAKEMAKE

    SciTech Connect (OSTI)

    Brown, M. E.

    2013-04-10

    A recent stellar occultation by the dwarf planet Makemake provided an excellent opportunity to measure the size and shape of one of the largest objects in the Kuiper belt. The analysis of these results provided what were reported to be precise measurements of the lengths of the projected axes, the albedo, and even the density of Makemake, but these results were, in part, derived from qualitative arguments. We reanalyzed the occultation timing data using a quantitative statistical description, and, in general, found the previously reported results on the shape of Makemake to be unjustified. In our solution, in which we use our inference from photometric data that Makemake is being viewed nearly pole-on, we find a 1{sigma} upper limit to the projected elongation of Makemake of 1.02, with measured equatorial diameter of 1434 {+-} 14 km and a projected polar diameter of 1422 {+-} 14 km, yielding an albedo of 0.81{sup +0.01}{sub -0.02}. If we remove the external constraint on the pole position of Makemake, we find instead a 1{sigma} upper limit to the elongation of 1.06, with a measured equatorial diameter of 1434{sup +48}{sub -18} km and a projected polar diameter of 1420{sup +18}{sub -24} km, yielding an albedo of 0.81{sup +0.03}{sub -0.05}. Critically, we find that the reported measurement of the density of Makemake was based on the misapplication of the volatile retention models. A corrected analysis shows that the occultation measurements provide no meaningful constraint on the density of Makemake.

  13. Building America Webinar: HVAC Right-Sizing Part 1-Calculating Loads |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy HVAC Right-Sizing Part 1-Calculating Loads Building America Webinar: HVAC Right-Sizing Part 1-Calculating Loads During this webinar, Building America Research Team IBACOS highlighted the key criteria required to create accurate heating and cooling load calculations. Current industry rules of thumb, perceptions and barriers to right-sizing HVAC were also discussed. File webinar_hvac_calculatingloads_20110428.wmv More Documents & Publications HVAC Right-Sizing Part 1:

  14. Fuel cell arrangement

    DOE Patents [OSTI]

    Isenberg, A.O.

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber. 3 figs.

  15. Fuel cell arrangement

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA)

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

  16. Comparing Server Energy Use and Efficiency Using Small Sample Sizes

    SciTech Connect (OSTI)

    Coles, Henry C.; Qin, Yong; Price, Phillip N.

    2014-11-01

    This report documents a demonstration that compared the energy consumption and efficiency of a limited sample size of server-type IT equipment from different manufacturers by measuring power at the server power supply power cords. The results are specific to the equipment and methods used. However, it is hoped that those responsible for IT equipment selection can used the methods described to choose models that optimize energy use efficiency. The demonstration was conducted in a data center at Lawrence Berkeley National Laboratory in Berkeley, California. It was performed with five servers of similar mechanical and electronic specifications; three from Intel and one each from Dell and Supermicro. Server IT equipment is constructed using commodity components, server manufacturer-designed assemblies, and control systems. Server compute efficiency is constrained by the commodity component specifications and integration requirements. The design freedom, outside of the commodity component constraints, provides room for the manufacturer to offer a product with competitive efficiency that meets market needs at a compelling price. A goal of the demonstration was to compare and quantify the server efficiency for three different brands. The efficiency is defined as the average compute rate (computations per unit of time) divided by the average energy consumption rate. The research team used an industry standard benchmark software package to provide a repeatable software load to obtain the compute rate and provide a variety of power consumption levels. Energy use when the servers were in an idle state (not providing computing work) were also measured. At high server compute loads, all brands, using the same key components (processors and memory), had similar results; therefore, from these results, it could not be concluded that one brand is more efficient than the other brands. The test results show that the power consumption variability caused by the key components as a group is similar to all other components as a group. However, some differences were observed. The Supermicro server used 27 percent more power at idle compared to the other brands. The Intel server had a power supply control feature called cold redundancy, and the data suggest that cold redundancy can provide energy savings at low power levels. Test and evaluation methods that might be used by others having limited resources for IT equipment evaluation are explained in the report.

  17. Differential white cell count by centrifugal microfluidics.

    SciTech Connect (OSTI)

    Sommer, Gregory Jon; Tentori, Augusto M.; Schaff, Ulrich Y.

    2010-07-01

    We present a method for counting white blood cells that is uniquely compatible with centrifugation based microfluidics. Blood is deposited on top of one or more layers of density media within a microfluidic disk. Spinning the disk causes the cell populations within whole blood to settle through the media, reaching an equilibrium based on the density of each cell type. Separation and fluorescence measurement of cell types stained with a DNA dye is demonstrated using this technique. The integrated signal from bands of fluorescent microspheres is shown to be proportional to their initial concentration in suspension. Among the current generation of medical diagnostics are devices based on the principle of centrifuging a CD sized disk functionalized with microfluidics. These portable 'lab on a disk' devices are capable of conducting multiple assays directly from a blood sample, embodied by platforms developed by Gyros, Samsung, and Abaxis. [1,2] However, no centrifugal platform to date includes a differential white blood cell count, which is an important metric complimentary to diagnostic assays. Measuring the differential white blood cell count (the relative fraction of granulocytes, lymphocytes, and monocytes) is a standard medical diagnostic technique useful for identifying sepsis, leukemia, AIDS, radiation exposure, and a host of other conditions that affect the immune system. Several methods exist for measuring the relative white blood cell count including flow cytometry, electrical impedance, and visual identification from a stained drop of blood under a microscope. However, none of these methods is easily incorporated into a centrifugal microfluidic diagnostic platform.

  18. Fuel cell-fuel cell hybrid system

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Williams, Mark C.

    2003-09-23

    A device for converting chemical energy to electricity is provided, the device comprising a high temperature fuel cell with the ability for partially oxidizing and completely reforming fuel, and a low temperature fuel cell juxtaposed to said high temperature fuel cell so as to utilize remaining reformed fuel from the high temperature fuel cell. Also provided is a method for producing electricity comprising directing fuel to a first fuel cell, completely oxidizing a first portion of the fuel and partially oxidizing a second portion of the fuel, directing the second fuel portion to a second fuel cell, allowing the first fuel cell to utilize the first portion of the fuel to produce electricity; and allowing the second fuel cell to utilize the second portion of the fuel to produce electricity.

  19. DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office: 2013 Fuel Cell Seminar and Energy Exposition DOE Fuel Cell Technologies Office: 2013 Fuel Cell Seminar and Energy Exposition Overview of DOE's Fuel Cell Technologies Office...

  20. A practical and theoretical definition of very small field size for radiotherapy output factor measurements

    SciTech Connect (OSTI)

    Charles, P. H. Crowe, S. B.; Langton, C. M.; Trapp, J. V.; Cranmer-Sargison, G.; Thwaites, D. I.; Kairn, T.; Knight, R. T.; Kenny, J.

    2014-04-15

    Purpose: This work introduces the concept of very small field size. Output factor (OPF) measurements at these field sizes require extremely careful experimental methodology including the measurement of dosimetric field size at the same time as each OPF measurement. Two quantifiable scientific definitions of the threshold of very small field size are presented. Methods: A practical definition was established by quantifying the effect that a 1 mm error in field size or detector position had on OPFs and setting acceptable uncertainties on OPF at 1%. Alternatively, for a theoretical definition of very small field size, the OPFs were separated into additional factors to investigate the specific effects of lateral electronic disequilibrium, photon scatter in the phantom, and source occlusion. The dominant effect was established and formed the basis of a theoretical definition of very small fields. Each factor was obtained using Monte Carlo simulations of a Varian iX linear accelerator for various square field sizes of side length from 4 to 100 mm, using a nominal photon energy of 6 MV. Results: According to the practical definition established in this project, field sizes ?15 mm were considered to be very small for 6 MV beams for maximal field size uncertainties of 1 mm. If the acceptable uncertainty in the OPF was increased from 1.0% to 2.0%, or field size uncertainties are 0.5 mm, field sizes ?12 mm were considered to be very small. Lateral electronic disequilibrium in the phantom was the dominant cause of change in OPF at very small field sizes. Thus the theoretical definition of very small field size coincided to the field size at which lateral electronic disequilibrium clearly caused a greater change in OPF than any other effects. This was found to occur at field sizes ?12 mm. Source occlusion also caused a large change in OPF for field sizes ?8 mm. Based on the results of this study, field sizes ?12 mm were considered to be theoretically very small for 6 MV beams. Conclusions: Extremely careful experimental methodology including the measurement of dosimetric field size at the same time as output factor measurement for each field size setting and also very precise detector alignment is required at field sizes at least ?12 mm and more conservatively?15 mm for 6 MV beams. These recommendations should be applied in addition to all the usual considerations for small field dosimetry, including careful detector selection.

  1. Ohio Fuel Cell Initiative

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Top 5 Fuel Cell States: Why Local Policies Mean Green Growth Jun 21 st , 2011 2 * Ohio Fuel Cell Initiative * Ohio Fuel Cell Coalition * Accomplishments * Ohio Successes Discussion Areas 3 Ohio's Fuel Cell Initiative * Announced on 5/9/02 * Part of Ohio Third Frontier Initiative * $85 million investment to date * Core focus areas: 1) Expand the state's research capabilities; 2) Participate in demonstration projects; and 3) Expand the fuel cell industry in Ohio 4 OHIO'S FUEL CELL INITIATIVE

  2. Method and apparatus for sizing and separating warp yarns using acoustical energy

    DOE Patents [OSTI]

    Sheen, Shuh-Haw (Naperville, IL); Chien, Hual-Te (Naperville, IL); Raptis, Apostolos C. (Downers Grove, IL); Kupperman, David S. (Oak Park, IL)

    1998-01-01

    A slashing process for preparing warp yarns for weaving operations including the steps of sizing and/or desizing the yarns in an acoustic resonance box and separating the yarns with a leasing apparatus comprised of a set of acoustically agitated lease rods. The sizing step includes immersing the yarns in a size solution contained in an acoustic resonance box. Acoustic transducers are positioned against the exterior of the box for generating an acoustic pressure field within the size solution. Ultrasonic waves that result from the acoustic pressure field continuously agitate the size solution to effect greater mixing and more uniform application and penetration of the size onto the yarns. The sized yarns are then separated by passing the warp yarns over and under lease rods. Electroacoustic transducers generate acoustic waves along the longitudinal axis of the lease rods, creating a shearing motion on the surface of the rods for splitting the yarns.

  3. Method and apparatus for sizing and separating warp yarns using acoustical energy

    DOE Patents [OSTI]

    Sheen, S.H.; Chien, H.T.; Raptis, A.C.; Kupperman, D.S.

    1998-05-19

    A slashing process is disclosed for preparing warp yarns for weaving operations including the steps of sizing and/or desizing the yarns in an acoustic resonance box and separating the yarns with a leasing apparatus comprised of a set of acoustically agitated lease rods. The sizing step includes immersing the yarns in a size solution contained in an acoustic resonance box. Acoustic transducers are positioned against the exterior of the box for generating an acoustic pressure field within the size solution. Ultrasonic waves that result from the acoustic pressure field continuously agitate the size solution to effect greater mixing and more uniform application and penetration of the size onto the yarns. The sized yarns are then separated by passing the warp yarns over and under lease rods. Electroacoustic transducers generate acoustic waves along the longitudinal axis of the lease rods, creating a shearing motion on the surface of the rods for splitting the yarns. 2 figs.

  4. Advanced Characterization of Particles and Particle-Cell Interactions |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Characterization of Particles and Particle-Cell Interactions Advanced Characterization of Particles and Particle-Cell Interactions 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Pacific Northwest National Laboratory PDF icon 2004_deer_cowin.pdf More Documents & Publications Real-Time Simultaneous Measurements of Size, Density, and Composition of Single Ultrafine Diesel Tailpipe Particles ACES: Evaluation of Tissue Response to Inhaled

  5. Extracting magnetic cluster size and its distributions in advanced perpendicular recording media with shrinking grain size using small angle x-ray scattering

    SciTech Connect (OSTI)

    Mehta, Virat; Ikeda, Yoshihiro; Takano, Ken; Terris, Bruce D.; Hellwig, Olav; Wang, Tianhan; Wu, Benny; Graves, Catherine; Drr, Hermann A.; Scherz, Andreas; Sthr, Jo

    2015-05-18

    We analyze the magnetic cluster size (MCS) and magnetic cluster size distribution (MCSD) in a variety of perpendicular magnetic recording (PMR) media designs using resonant small angle x-ray scattering at the Co L{sub 3} absorption edge. The different PMR media flavors considered here vary in grain size between 7.5 and 9.5?nm as well as in lateral inter-granular exchange strength, which is controlled via the segregant amount. While for high inter-granular exchange, the MCS increases rapidly for grain sizes below 8.5?nm, we show that for increased amount of segregant with less exchange the MCS remains relatively small, even for grain sizes of 7.5 and 8?nm. However, the MCSD still increases sharply when shrinking grains from 8 to 7.5?nm. We show evidence that recording performance such as signal-to-noise-ratio on the spin stand correlates well with the product of magnetic cluster size and magnetic cluster size distribution.

  6. Radioactive hot cell access hole decontamination machine

    DOE Patents [OSTI]

    Simpson, William E.

    1982-01-01

    Radioactive hot cell access hole decontamination machine. A mobile housing has an opening large enough to encircle the access hole and has a shielding door, with a door opening and closing mechanism, for uncovering and covering the opening. The housing contains a shaft which has an apparatus for rotating the shaft and a device for independently translating the shaft from the housing through the opening and access hole into the hot cell chamber. A properly sized cylindrical pig containing wire brushes and cloth or other disks, with an arrangement for releasably attaching it to the end of the shaft, circumferentially cleans the access hole wall of radioactive contamination and thereafter detaches from the shaft to fall into the hot cell chamber.

  7. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, T.D.; Smith, J.L.

    1986-07-08

    A molten electrolyte fuel cell is disclosed with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas. The cell enclosures collectively provide an enclosure for the array and effectively avoid the problems of electrolyte migration and the previous need for compression of stack components. The fuel cell further includes an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  8. Molten carbonate fuel cell

    DOE Patents [OSTI]

    Kaun, Thomas D. (New Lenox, IL); Smith, James L. (Lemont, IL)

    1987-01-01

    A molten electrolyte fuel cell with an array of stacked cells and cell enclosures isolating each cell except for access to gas manifolds for the supply of fuel or oxidant gas or the removal of waste gas, the cell enclosures collectively providing an enclosure for the array and effectively avoiding the problems of electrolyte migration and the previous need for compression of stack components, the fuel cell further including an inner housing about and in cooperation with the array enclosure to provide a manifold system with isolated chambers for the supply and removal of gases. An external insulated housing about the inner housing provides thermal isolation to the cell components.

  9. Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2011 Fuel Cell Seminar Fuel Cell Technologies Overview: 2011 Fuel Cell Seminar Presentation by Sunita Satyapal at the Fuel Cell Seminar on November 1, 2011. PDF icon Fuel Cell...

  10. CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings - 2015 Peer Review | Department of Energy Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Mark Stutman, PSU View the Presentation PDF icon CBEI: Lessons Learned from Integrated Retrofits in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications

  11. CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings - 2015 Peer Review | Department of Energy Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Mugdha Mokashi, Bayer Materials View the Presentation PDF icon CBEI: Packaged Masonry Wall Retrofit Solution for Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents &

  12. Current Size and Remaining Market Potential of the U.S. Energy Service

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Company Industry | Department of Energy Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry The study analyzes the size, growth and trends in the U.S. energy service company (ESCO) industry, drawing on information provided by industry executives and experts in 2012. The report also provides a preliminary estimate of remaining investment potential and annual blended

  13. CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review | Department of Energy AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Jin Wen, Drexel View the Presentation PDF icon CBEI: AHU FDD in Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications Compatible and Cost-Effective Fault Diagnostic Solutions for Air Handling Unit-Variable Air Volume and Air Handling Unit-Constant Air Volume

  14. CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Review | Department of Energy HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review Presenter: Russell Taylor, United Technologies Research Center View the Presentation PDF icon CBEI: HVAC Packages for Small and Medium Sized Commercial Buildings - 2015 Peer Review More Documents & Publications CBEI: FDD for Advanced RTUs - 2015 Peer Review CBEI: Lessons Learned from

  15. Dispersion of Cloud Droplet Size Distributions, Cloud Parameterizations and Indirect Aerosol Effects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dispersion of Cloud Droplet Size Distributions, Cloud Parameterizations, and Indirect Aerosol Effects P. H. Daum and Y. Liu Brookhaven National Laboratory Upton, New York Introduction Most studies of the effect of aerosols on cloud radiative properties have considered only changes in the cloud droplet concentration, neglecting changes in the spectral shape of the cloud droplet size distribution. However, it has been shown that that the spectral dispersion of the cloud droplet size distribution

  16. Tuning Pore Size to Enhance the Capacitance of Supercapacitors | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Tuning Pore Size to Enhance the Capacitance of Supercapacitors Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights Highlight Archives News & Events Publications History Contact BES Home 04.27.12 Tuning Pore Size to Enhance the Capacitance of Supercapacitors Print Text Size: A A A FeedbackShare Page Scientific Achievement Simulations of nanoporous super-capacitors confirm and help to understand the anomalous increase in

  17. Current Size and Remaining Market Potential of the U.S. Energy Service

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Company Industry | Department of Energy Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry "This report contains information on Current Size and Remaining Market Potential of the U.S. Energy Service Company Industry, prepared for the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy, Weatherization and Intergovernmental Program." PDF

  18. Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots Citation Details In-Document Search Title: Size Dependence of Two-Photon Absorption in Semiconductor Quantum Dots Quantum confinement plays an important role in the optical properties of semiconductor quantum dots (QDs). In this work, we combine experiment and modeling to systematically investigate the size dependence of the degenerate two-photon absorption (TPA) of below-band-gap

  19. Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines

    Energy Savers [EERE]

    Meet Certification Requirements | Department of Energy Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements October 1, 2015 - 1:04pm Addthis Energy Department Helps Manufacturers of Small and Mid-Size Wind Turbines Meet Certification Requirements Mark Higgins Operations Supervisor, Wind & Water Power Technologies Office On October 1, the Energy

  20. Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell Technologies Program describing hydrogen fuel cell technology. PDF icon Fuel Cells Fact Sheet More Documents & Publications Comparison of Fuel Cell Technologies: Fact Sheet Fuel Cells Fact Sheet 2011 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies

  1. Disorder and size effects on Kondo interactions and magneticcorrelations in CePt2 nanoscrystals

    SciTech Connect (OSTI)

    Chen, Y.Y.; Huang, P.H.; Ou, M.N.; Wang, C.R.; Yao, Y.D.; Lee,T.K.; Ho, M.Y.; Lawrence, J.M.; Booth, C.H.

    2006-12-12

    The evolution of the Kondo effect and magnetic correlations with size reduction in CePt{sub 2} nanoparticles (3.1-26 nm) is studied by analysis of the temperature-dependent specific heat and magnetic susceptibility. The antiferromagnetic correlations diminish with size reduction. The Kondo effect predominates at small particle size with trivalent, small Kondo temperature (T{sub K}) magnetic regions coexisting with strongly mixed valent, large T{sub K} nonmagnetic regions. We discuss the role of structural disorder, background density of states and the electronic quantum size effect on the results.

  2. The Dependence of Cirrus Cloud-Property Retrievals on Size-Distributio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path (IWP), effective particle size (Deff), and visible extinction optical thickness (tau). During this past year we began comparing our cirrus retrieval results with aircraft...

  3. Size Dependence of the Bandgap of Plasma Synthesized Silicon Nanoparticles Through Direct Introduction of Sulfur Hexafluoride

    SciTech Connect (OSTI)

    Theingi, S.; Guan, T. Y.; Kendrick, C.; Klafehn, G.; Gorman, B. P.; Taylor, P. C.; Lusk, M. T.; Stradins, Pauls; Collins, R. T.

    2015-10-19

    Developing silicon nanoparticle (SiNP) synthesis techniques that allow for straightforward control of nanoparticle size and associated optical properties is critical to potential applications of these materials. In addition, it is, in general, hard to probe the absorption threshold in these materials due to silicon's low absorption coefficient. In this study, size is controlled through direct introduction of sulfur hexafluoride (SF6) into the dilute silane precursor of plasma synthesized SiNPs. Size reduction by nearly a factor of two with high crystallinity independent of size is demonstrated. Optical absorption spectra of the SiNPs in the vicinity of the bandgap are measured using photothermal deflection spectroscopy. Bandgap as a function of size is extracted taking into account the polydispersity of the samples. A systematic blue shift inabsorption edge due to quantum confinement in the SiNPs is observed with increasing flow of SF6. Photoluminescence (PL) spectra show a similar blue shift with size. However, a ~300 meV difference in energy between emission and absorption for all sizes suggests that PL emission involves a defect related process. While PL may allow size-induced shifts in the bandgap of SiNPs to be monitored, it cannot be relied on to give an accurate value for the bandgap as a function of size.

  4. Ultrasonic processor reduces drill-cuttings size and eliminates subsea mounds

    SciTech Connect (OSTI)

    Gaddy, D.E.

    1997-10-06

    Drill cuttings size reduction using ultrasonics eliminated a subsea clean-up and significantly reduced the environmental impact in a North Sea drilling project. Reduction in cuttings size allows for a wider areal dispersion when released into the ocean because they are held in suspension longer than larger sizes. Thus, ocean currents carry the smaller cuttings farther away from the well template, leaving a much wider footprint than larger cuttings sizes. This eliminates the pile-up of cuttings that otherwise would contaminate and harm the marine habitat.

  5. Modeling of the electronic transport in multijunction solar cells

    SciTech Connect (OSTI)

    Rau, U.; Goldbach, M.

    1994-12-31

    Simulations of the electrical transport in multijunction thin-film solar cells made from polycrystalline silicon are presented. The authors investigate the effect of the grain size on the efficiency of the multijunction solar cell. Here, they concentrate on micro crystalline material with a high recombination velocity at the grain boundaries of 10{sup 4}cm/s. Typical results of their calculations demonstrate that based on the multijunction design structure consisting of 8 or more layers efficiencies of 14% may be obtained from 12--20 {micro}m thick solar cells.

  6. Direct-hydrogen-fueled proton-exchange-membrane fuel cell system for transportation applications: Conceptual vehicle design report pure fuel cell powertrain vehicle

    SciTech Connect (OSTI)

    Oei, D.; Kinnelly, A.; Sims, R.; Sulek, M.; Wernette, D.

    1997-02-01

    In partial fulfillment of the Department of Energy (DOE) Contract No. DE-AC02-94CE50389, {open_quotes}Direct-Hydrogen-Fueled Proton-Exchange-Membrane (PEM) Fuel Cell for Transportation Applications{close_quotes}, this preliminary report addresses the conceptual design and packaging of a fuel cell-only powered vehicle. Three classes of vehicles are considered in this design and packaging exercise, the Aspire representing the small vehicle class, the Taurus or Aluminum Intensive Vehicle (AIV) Sable representing the mid-size vehicle and the E-150 Econoline representing the van-size class. A fuel cell system spreadsheet model and Ford`s Corporate Vehicle Simulation Program (CVSP) were utilized to determine the size and the weight of the fuel cell required to power a particular size vehicle. The fuel cell power system must meet the required performance criteria for each vehicle. In this vehicle design and packaging exercise, the following assumptions were made: fuel cell power system density of 0.33 kW/kg and 0.33 kg/liter, platinum catalyst loading less than or equal to 0.25 mg/cm{sup 2} total and hydrogen tanks containing gaseous hydrogen under 340 atm (5000 psia) pressure. The fuel cell power system includes gas conditioning, thermal management, humidity control, and blowers or compressors, where appropriate. This conceptual design of a fuel cell-only powered vehicle will help in the determination of the propulsion system requirements for a vehicle powered by a PEMFC engine in lieu of the internal combustion (IC) engine. Only basic performance level requirements are considered for the three classes of vehicles in this report. Each vehicle will contain one or more hydrogen storage tanks and hydrogen fuel for 560 km (350 mi) driving range. Under these circumstances, the packaging of a fuel cell-only powered vehicle is increasingly difficult as the vehicle size diminishes.

  7. Quantitative Reflectance Spectra of Solid Powders as a Function of Particle Size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Blake, Thomas A.; Tonkyn, Russell G.; Ertel, Alyssa B.; Johnson, Timothy J.; Richardson, Robert L.

    2015-05-19

    We have recently developed vetted methods for obtaining quantitative infrared directional-hemispherical reflectance spectra using a commercial integrating sphere. In this paper, the effects of particle size on the spectral properties are analyzed for several samples such as ammonium sulfate, calcium carbonate, and sodium sulfate as well as one organic compound, lactose. We prepared multiple size fractions for each sample and confirmed the mean sizes using optical microscopy. Most species displayed a wide range of spectral behavior depending on the mean particle size. General trends of reflectance vs. particle size are observed such as increased albedo for smaller particles: for mostmorewavelengths, the reflectivity drops with increased size, sometimes displaying a factor of 4 or more drop in reflectivity along with a loss of spectral contrast. In the longwave infrared, several species with symmetric anions or cations exhibited reststrahlen features whose amplitude was nearly invariant with particle size, at least for intermediate- and large-sized sample fractions; that is, > ~150 microns. Trends of other types of bands (Christiansen minima, transparency features) are also investigated as well as quantitative analysis of the observed relationship between reflectance vs. particle diameter.less

  8. Grain size dependent mechanical properties of nanocrystalline diamond films grown by hot-filament CVD

    SciTech Connect (OSTI)

    Wiora, M; Bruehne, K; Floeter, A; Gluche, P; Willey, T M; Kucheyev, S O; Van Buuren, A W; Hamza, A V; Biener, J; Fecht, H

    2008-08-01

    Nanocrystalline diamond (NCD) films with a thickness of {approx}6 {micro}m and with average grain sizes ranging from 60 to 9 nm were deposited on silicon wafers using a hot-filament chemical vapor deposition (HFCVD) process. These samples were then characterized with the goal to identify correlations between grain size, chemical composition and mechanical properties. The characterization reveals that our films are phase pure and exhibit a relatively smooth surface morphology. The levels of sp{sup 2}-bonded carbon and hydrogen impurities are low, and showed a systematic variation with the grain size. The hydrogen content increases with decreasing grain size, whereas the sp{sup 2} carbon content decreases with decreasing grain size. The material is weaker than single crystalline diamond, and both stiffness and hardness decrease with decreasing grain size. These trends suggest gradual changes of the nature of the grain boundaries, from graphitic in the case of the 60 nm grain size material to hydrogen terminated sp{sup 3} carbon for the 9 nm grain size material. The films exhibit low levels of internal stress and freestanding structures with a length of several centimeters could be fabricated without noticeable bending.

  9. Preparation of 1,3,5-triamino-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P. (Livermore, CA); Moody, Gordon L. (Tracy, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-01-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  10. Preparation of 1,3,5-triamo-2,4,6-trinitrobenzene of submicron particle size

    DOE Patents [OSTI]

    Rigdon, Lester P. (Livermore, CA); Moody, Gordon L. (Tracy, CA); McGuire, Raymond R. (Brentwood, CA)

    2001-05-01

    A method is disclosed for the preparation of very small particle size, relatively pure 1,3,5-triamino-2,4,6-trinitrobenzene (TATB). Particles of TATB prepared according to the disclosed method are of submicron size and have a surface area in the range from about 3.8 to 27 square meters per gram.

  11. Measurement of interaction forces between red blood cells in aggregates by optical tweezers

    SciTech Connect (OSTI)

    Maklygin, A Yu; Priezzhev, A V; Karmenian, A; Nikitin, Sergei Yu; Obolenskii, I S; Lugovtsov, Andrei E; Kisun Li

    2012-06-30

    We have fabricated double-beam optical tweezers and demonstrated the possibility of their use for measuring the interaction forces between red blood cells (erythrocytes). It has been established experimentally that prolonged trapping of red blood cells in a tightly focused laser beam does not cause any visible changes in their shape or size. We have measured the interaction between red blood cells in the aggregate, deformed by optical tweezers.

  12. Diagnostic Studies on Lithium Battery Cells and Cell Components |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Studies on Lithium Battery Cells and Cell Components Diagnostic Studies on Lithium Battery Cells and Cell Components 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es032_abraham_2012_o.pdf More Documents & Publications Mitigating Performance Degradation of High-Energy Lithium-Ion Cells Diagnostic studies on Li-battery cells and cell components Cell Fabrication Facility Team Production

  13. Morphological changes in ultrafast laser ablation plumes with varying spot size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harilal, S. S.; Diwakar, P. K.; Polek, M. P.; Phillips, M. C.

    2015-06-04

    We investigated the role of spot size on plume morphology during ultrafast laser ablation of metal targets. Our results show that the spatial features of fs LA plumes are strongly dependent on the focal spot size. Two-dimensional self-emission images showed that the shape of the ultrafast laser ablation plumes changes from spherical to cylindrical with an increasing spot size from 100 to 600 ?m. The changes in plume morphology and internal structures are related to ion emission dynamics from the plasma, where broader angular ion distribution and faster ions are noticed for the smallest spot size used. The present resultsmoreclearly show that the morphological changes in the plume with spot size are independent of laser pulse width.less

  14. Vertical cavity surface-emitting laser scanning cytometer for high speed analysis of cells

    SciTech Connect (OSTI)

    Gourley, P.L.; McDonald, A.E.; Gourley, M.F.

    1995-12-31

    We have constructed a new semiconductor laser device that may be useful in high speed characterization of cell morphology for diagnosis of disease. This laser device has critical advantages over conventional cell fluorescence detection methods since it provides intense, monochromatic, low-divergence fight signals that are emitted from lasing modes confined by a cell. Further, the device integrates biological structures with semiconductor materials at the wafer level to reduce device size and simplify cell preparation. In this paper we discuss operational characteristics of the prototype cytometer and present preliminary data for blood cells and dielectric spheres.

  15. Fuel cells in distributed generation

    SciTech Connect (OSTI)

    O'Sullivan, J.B.

    1999-07-01

    In the past the vertically integrated electric utility industry has not utilized Distributed Generation (DG) because it was viewed as competition to central station power production. Gas utilities have been heavily and aggressively involved in the promotion of gas fired DG because for them it is additional load that may also balance the winter load. With deregulation and restructuring of the electricity industry DG is now viewed in a different light. For those utilities that have sold their generation assets DG can be a new retail service to provide to their customers. For those who are still vertically integrated, DG can be an asset management tool at the distribution level. DG can be utilized to defer capital investments involving line and substation upgrades. Coupled to this new interest in DG technologies and their performance characteristics are the associated interests in implementation issues. These range from the codes and standards requirements and hardware for interfacing to the grid as well as C{sup 3}-I (command, control, communication--intelligence) issues. The latter involves dispatching on-grid or customer sited resources, monitoring their performance and tracking the economic transactions. Another important aspect is the impact of DG resources (size, number and location) on service area dynamic behavior (power quality, reliability, stability, etc.). EPRI has ongoing programs addressing all these aspects of DG and the distribution grid. Since fuel cells can be viewed as electrochemical engines, and as with thermomechanical engines, there doesn't have to be a best fuel cell. Each engine can serve many markets and some will be better suited than others in a specific market segment (e.g. spark ignition in cars and turbines in planes). This paper will address the status of developing fuel cell technologies and their application to various market areas within the context of Distributed Generation.

  16. Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Update: 2010 Fuel Cell Seminar and Exposition Hydrogen and Fuel Cell Technologies Update: 2010 Fuel Cell Seminar and Exposition Presentation by Sunita Satyapal at the 2010 Fuel...

  17. Fuel Cell Technical Publications

    Broader source: Energy.gov [DOE]

    Technical information about fuel cells published in technical reports, conference proceedings, journal articles, and websites is provided here.

  18. Round-Robin Verification and Final Development of the IEC 62788-1-5 Encapsulation Size Change Test; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Wohlgemuth, J.; Bokria, J.; Gu, X.; Honeker, C.; Murua, N.; Nickel, N.; Sakurai, K.; Shioda, T.; Tamizhmani, G.; Wang, E.; Yang, S.; Yoshihara, T.

    2015-02-23

    Polymeric encapsulation materials may a change size when processed at typical module lamination temperatures. The relief of residual strain, trapped during the manufacture of encapsulation sheet, can affect module performance and reliability. For example, displaced cells and interconnects threaten: cell fracture; broken interconnects (open circuits and ground faults); delamination at interfaces; and void formation. A standardized test for the characterization of change in linear dimensions of encapsulation sheet has been developed and verified. The IEC 62788-1-5 standard quantifies the maximum change in linear dimensions that may occur to allow for process control of size change. Developments incorporated into the Committee Draft (CD) of the standard as well as the assessment of the repeatability and reproducibility of the test method are described here. No pass/fail criteria are given in the standard, rather a repeatable protocol to quantify the change in dimension is provided to aid those working with encapsulation. The round-robin experiment described here identified that the repeatability and reproducibility of measurements is on the order of 1%. Recent refinements to the test procedure to improve repeatability and reproducibility include: the use of a convection oven to improve the thermal equilibration time constant and its uniformity; well-defined measurement locations reduce the effects of sampling size -and location- relative to the specimen edges; a standardized sand substrate may be readily obtained to reduce friction that would otherwise complicate the results; specimen sampling is defined, so that material is examined at known sites across the width and length of rolls; and encapsulation should be examined at the manufacturers recommended processing temperature, except when a cross-linking reaction may limit the size change. EVA, for example, should be examined 100 C, between its melt transition (occurring up to 80 C) and the onset of cross-linking (often at 100 C).

  19. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2002-02-01

    The carbonate fuel cell promises highly efficient, cost-effective and environmentally superior power generation from pipeline natural gas, coal gas, biogas, and other gaseous and liquid fuels. FuelCell Energy, Inc. has been engaged in the development of this unique technology, focusing on the development of the Direct Fuel Cell (DFC{reg_sign}). The DFC{reg_sign} design incorporates the unique internal reforming feature which allows utilization of a hydrocarbon fuel directly in the fuel cell without requiring any external reforming reactor and associated heat exchange equipment. This approach upgrades waste heat to chemical energy and thereby contributes to a higher overall conversion efficiency of fuel energy to electricity with low levels of environmental emissions. Among the internal reforming options, FuelCell Energy has selected the Indirect Internal Reforming (IIR)--Direct Internal Reforming (DIR) combination as its baseline design. The IIR-DIR combination allows reforming control (and thus cooling) over the entire cell area. This results in uniform cell temperature. In the IIR-DIR stack, a reforming unit (RU) is placed in between a group of fuel cells. The hydrocarbon fuel is first fed into the RU where it is reformed partially to hydrogen and carbon monoxide fuel using heat produced by the fuel cell electrochemical reactions. The reformed gases are then fed to the DIR chamber, where the residual fuel is reformed simultaneously with the electrochemical fuel cell reactions. FuelCell Energy plans to offer commercial DFC power plants in various sizes, focusing on the subMW as well as the MW-scale units. The plan is to offer standardized, packaged DFC power plants operating on natural gas or other hydrocarbon-containing fuels for commercial sale. The power plant design will include a diesel fuel processing option to allow dual fuel applications. These power plants, which can be shop-fabricated and sited near the user, are ideally suited for distributed power generation, industrial cogeneration, marine applications and uninterrupted power for military bases. FuelCell Energy operated a 1.8 MW plant at a utility site in 1996-97, the largest fuel cell power plant ever operated in North America. This proof-of-concept power plant demonstrated high efficiency, low emissions, reactive power control, and unattended operation capabilities. Drawing on the manufacture, field test, and post-test experience of the full-size power plant; FuelCell Energy launched the Product Design Improvement (PDI) program sponsored by government and the private-sector cost-share. The PDI efforts are focused on technology and system optimization for cost reduction, commercial design development, and prototype system field trials. The program was initiated in December 1994. Year 2000 program accomplishments are discussed in this report.

  20. Biomarkers of cell senescence

    DOE Patents [OSTI]

    Dimri, G.P.; Campisi, J.; Peacocke, M.

    1998-08-18

    The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, {beta}-galactosidase activity is utilized as a means by which cell senescence may be assessed either in vitro cell cultures or in vivo. 1 fig.

  1. Biomarkers of cell senescence

    DOE Patents [OSTI]

    Dimri, Goberdhan P. (Simli U.P., IN); Campisi, Judith (Berkeley, CA); Peacocke, Monica (Newton, MA)

    1998-01-01

    The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, .beta.-galactosidase activity is utilized as a means by which cell senescence may be assessed either in vitro cell cultures or in vivo.

  2. Biomarkers of cell senescence

    DOE Patents [OSTI]

    Dirmi, Goberdhan P. (Simli U.P., IN); Campisi, Judith (Berkeley, CA); Peacocke, Monica (Newton, MA)

    1996-01-01

    The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, .beta.-galactosidase activity is utilized as a means by which cell senescence may be assessed either in in vitro cell cultures or in vivo.

  3. Rapidly refuelable fuel cell

    DOE Patents [OSTI]

    Joy, Richard W. (Santa Clara, CA)

    1983-01-01

    This invention is directed to a metal-air fuel cell where the consumable metal anode is movably positioned in the cell and an expandable enclosure, or bladder, is used to press the anode into contact with separating spacers between the cell electrodes. The bladder may be depressurized to allow replacement of the anode when consumed.

  4. Biomarkers of cell senescence

    DOE Patents [OSTI]

    Dirmi, G.P.; Campisi, J.; Peacocke, M.

    1996-02-13

    The present invention provides a biomarker system for the in vivo and in vitro assessment of cell senescence. In the method of the present invention, {beta}-galactosidase activity is utilized as a means by which cell senescence may be assessed either in in vitro cell cultures or in vivo. 1 fig.

  5. Appendix K Disposal Cell Groundwater Monitoring Plan

    Office of Legacy Management (LM)

    Disposal Cell Groundwater Monitoring Plan

  6. Pyroelectric response of ferroelectric nanowires: Size effect and electric energy harvesting

    SciTech Connect (OSTI)

    Morozovska, A. N.; Eliseev, E. A.; Svechnikov, S. V.; Kalinin, Sergei V

    2010-01-01

    The size effect on pyroelectric response of ferroelectric nanowires is analyzed. The pyroelectric coefficient strongly increases with the wire radius decrease and diverges at critical radius Rcr corresponding to the size-driven transition into paraelectric phase. Size-driven enhancement of pyroelectric coupling leads to the giant pyroelectric current and voltage generation by the polarized ferroelectric nanoparticles in response to the temperature fluctuation. The maximum efficiency of the pyroelectric energy harvesting and bolometric detection is derived, and is shown to approach the Carnot limit for low temperatures.

  7. Increased InAs quantum dot size and density using bismuth as a surfactant

    SciTech Connect (OSTI)

    Dasika, Vaishno D.; Krivoy, E. M.; Nair, H. P.; Maddox, S. J.; Park, K. W.; Yu, E. T.; Bank, S. R.; Jung, D.; Lee, M. L.

    2014-12-22

    We have investigated the growth of self-assembled InAs quantum dots using bismuth as a surfactant to control the dot size and density. We find that the bismuth surfactant increases the quantum dot density, size, and uniformity, enabling the extension of the emission wavelength with increasing InAs deposition without a concomitant reduction in dot density. We show that these effects are due to bismuth acting as a reactive surfactant to kinetically suppress the surface adatom mobility. This mechanism for controlling quantum dot density and size has the potential to extend the operating wavelength and enhance the performance of various optoelectronic devices.

  8. Finite-size effects on the radiative energy loss of a fast parton in hot

    Office of Scientific and Technical Information (OSTI)

    and dense strongly interacting matter (Journal Article) | SciTech Connect Finite-size effects on the radiative energy loss of a fast parton in hot and dense strongly interacting matter Citation Details In-Document Search Title: Finite-size effects on the radiative energy loss of a fast parton in hot and dense strongly interacting matter We consider finite-size effects on the radiative energy loss of a fast parton moving in a finite-temperature, strongly interacting medium, using the

  9. Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Carbon Reduction August 7 2009 _2_.docx | Department of Energy GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx PDF icon Microsoft Word - GRS Review_OMB White Paper - Real Property Right-sizing and Carbon Reduction August 7 2009 _2_.docx More Documents & Publications Executive Branch Management Scorecard 2013 guidance

  10. Plasma size and power scaling of ion temperature gradient driven turbulence

    SciTech Connect (OSTI)

    Idomura, Yasuhiro; Nakata, Motoki

    2014-02-15

    The transport scaling with respect to plasma size and heating power is studied for ion temperature gradient driven turbulence using a fixed-flux full-f gyrokinetic Eulerian code. It is found that when heating power is scaled with plasma size, the ion heat diffusivity increases with plasma size in a local limit regime, where fixed-gradient ?f simulations predict a gyro-Bohm scaling. In the local limit regime, the transport scaling is strongly affected by the stiffness of ion temperature profiles, which is related to the power degradation of confinement.

  11. Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2}

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2} Citation Details In-Document Search Title: Size-Dependent Pressure-Induced Amorphization in Nanoscale TiO{sub 2} We investigated the size-dependent high-pressure phase transition behavior of nanocrystalline anatase TiO{sub 2} with synchrotron x-ray diffraction and Raman spectroscopy to 45 GPa at ambient temperature. Pressure-induced amorphization results in a high-density amorphous (HDA)

  12. Particle size effect of hydrogen-induced lattice expansion of palladium nanoclusters.

    SciTech Connect (OSTI)

    Ingham, B.; Toney, M. F.; Hendy, S. C.; Cox, T.; Fong, D. D.; Eastman, J. A.; Fuoss, P. H.; Stevens, K. J.; Lassesson, A.; Brown, S. A.; Ryan, M. P.; Materials Science Division; Industrial Research Ltd.; Stanford Synchrotron Radiation Lab.; Victoria Univ. of Wellington; Quest Reliability Ltd.; Univ. of Canterbury; Imperial Coll.

    2008-12-01

    In situ synchrotron x-ray diffraction experiments on bare palladium nanoclusters prepared by inert-gas aggregation and size selected (1.7-6.0 nm) show significant changes in lattice parameter upon hydrogen loading and a narrowing of the miscibility gap, as the cluster size decreases. The results show that the miscibility gap is open for all cluster sizes studied, in contrast to previous literature results from surfactant-encapsulated palladium clusters. We interpret these results by showing that the nature of the surface is critical in the hydrogenation behavior of the nanoclusters.

  13. Particle Size Effect of Hydrogen-Induced Lattice Expansion of Palladium Nanoclusters

    SciTech Connect (OSTI)

    Ingham, B.; Toney, M.F.; Hendy, S.C.; Cox, T.; Fong, D.D.; Eastman, J.A.; Fuoss, P.H.; Stevens, K.J.; Lassesson, A.; Brown, S.A.; Ryan, M.P.

    2009-05-18

    In situ synchrotron x-ray diffraction experiments on bare palladium nanoclusters prepared by inert-gas aggregation and size selected (1.7-6.0 nm) show significant changes in lattice parameter upon hydrogen loading and a narrowing of the miscibility gap, as the cluster size decreases. The results show that the miscibility gap is open for all cluster sizes studied, in contrast to previous literature results from surfactant-encapsulated palladium clusters. We interpret these results by showing that the nature of the surface is critical in the hydrogenation behavior of the nanoclusters.

  14. Copper migration in CdTe heterojunction solar cells

    SciTech Connect (OSTI)

    Chou, H.C.; Rohatgi, A.; Jokerst, N.M.; Thomas, E.W.; Kamra, S.

    1996-07-01

    CdTe solar cells were fabricated by depositing a Au/Cu contact with Cu thickness in the range of 50 to 150A on polycrystalline CdTe/CdS/SnO{sub 2} glass structures. The increase in Cu thickness improves ohmic contact and reduces series resistance (R{sub s}), but the excess Cu tends to diffuse into CdTe and lower shunt resistance (R{sub sh}) and cell performance. Light I-V and secondary ion mass spectroscopy (SIMS) measurements were performed to understand the correlations between the Cu contact thickness, the extent of Cu incorporation in the CdTe cells, and its impact on the cell performance. The CdTe/CdS/SnO{sub 2} glass, CdTe/CdS/GaAs, and CdTe/GaAs structures were prepared in an attempt to achieve CdTe films with different degrees of crystallinity and grain size. A large grain polycrystalline CdTe thin film solar cell was obtained for the first time by selective etching the GaAs substrate coupled with the film transfer onto a glass substrate. SIMS measurement showed that poor crystallinity and smaller grain size of the CdTe film promotes Cu diffusion and decreases the cell performance. Therefore, grain boundaries are the main conduits for Cu migration and larger CdTe grain size or alternate method of contact formation can mitigate the adverse effect of Cu and improve the cell performance. 15 refs., 1 fig.,6 tabs.

  15. Fuel Cell Technologies Overview: 2012 Flow Cells for Energy Storage

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop | Department of Energy Overview: 2012 Flow Cells for Energy Storage Workshop Fuel Cell Technologies Overview: 2012 Flow Cells for Energy Storage Workshop Presentation by Sunita Satyapal and Dimitrios Papageorgopoulos, U.S. Department of Energy Fuel Cell Technologies Program, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC. PDF icon Fuel Cell Technologies Overview More Documents & Publications DOE Fuel Cell Technologies Office: 2013 Fuel Cell

  16. Solid Oxide Fuel Cells FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    further information, see: - Fuel Cell Handbook (Seventh Edition) SOLID OXIDE FUEL CELLS - ENVIRONMENT Q: How are fuel cells used? A: Fuel cells may be used to power anything that...

  17. Phosphorus removal from slow-cooled steelmaking slags: Grain size determination and liberation studies

    SciTech Connect (OSTI)

    Fregeau-Wu, E.; Iwasaki, I.

    1995-07-01

    The major obstacle in recycling steelmaking slags to the blast furnace is their phosphorus content. Removal of the phosphorus, which is primarily associated with the silicate and phosphate phases, would allow for greater recycle of these slags for their iron, manganese, and lime contents. Calculations show that separation of the silicates from the oxide phases would remove nearly 90% of the phosphorus from the slag. The variable grain size of the as-received slag made liberation by fine grinding difficult. Therefore, slow-cooling experiments were undertaken to improve the grain size distribution. The grain size distributions were determined using in-situ image analysis. The samples were ground to their apparent liberation size and high gradient magnetic separation was used to separate the magnetic oxides from the nonmagnetic silicates and phosphates. Liberation analysis and modeling was performed on selected separation products for discussion of benefication characteristics.

  18. The Effects of Transient Emotional State and Workload on Size Scaling in Perspective Displays

    SciTech Connect (OSTI)

    Tuan Q. Tran; Kimberly R. Raddatz

    2006-10-01

    Previous research has been devoted to the study of perceptual (e.g., number of depth cues) and cognitive (e.g., instructional set) factors that influence veridical size perception in perspective displays. However, considering that perspective displays have utility in high workload environments that often induce high arousal (e.g., aircraft cockpits), the present study sought to examine the effect of observers emotional state on the ability to perceive and judge veridical size. Within a dual-task paradigm, observers ability to make accurate size judgments was examined under conditions of induced emotional state (positive, negative, neutral) and high and low workload. Results showed that participants in both positive and negative induced emotional states were slower to make accurate size judgments than those not under induced emotional arousal. Results suggest that emotional state is an important factor that influences visual performance on perspective displays and is worthy of further study.

  19. Current Size and Remaining Market Potential of the U.S. Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The study analyzes the size, growth and trends in the U.S. energy service company (ESCO) ... Company (ESCO) Industry and Market Trends Speaker List for EE Forum Breakout ...

  20. Effect of A-site cation size mismatch on charge ordering behavior...

    Office of Scientific and Technical Information (OSTI)

    The schematic models are proposed for the incommensurate CO modulation in the samples with size mismatch sigmasup 2le0.003. The disappearance of the CO transition in the ...

  1. Cooperative storage of shared files in a parallel computing system with dynamic block size

    DOE Patents [OSTI]

    Bent, John M.; Faibish, Sorin; Grider, Gary

    2015-11-10

    Improved techniques are provided for parallel writing of data to a shared object in a parallel computing system. A method is provided for storing data generated by a plurality of parallel processes to a shared object in a parallel computing system. The method is performed by at least one of the processes and comprises: dynamically determining a block size for storing the data; exchanging a determined amount of the data with at least one additional process to achieve a block of the data having the dynamically determined block size; and writing the block of the data having the dynamically determined block size to a file system. The determined block size comprises, e.g., a total amount of the data to be stored divided by the number of parallel processes. The file system comprises, for example, a log structured virtual parallel file system, such as a Parallel Log-Structured File System (PLFS).

  2. Geek-Up[6.24.11]: Dust-sized 'Dragonfly' Device and Tiny Microvalves

    Broader source: Energy.gov [DOE]

    A dust-size "dragonfly-inspired" device -- which won a Sandia Lab design contest -- may ultimately enable the creation of tiny microvalves for experiments in biological research laboratories and medical facilities.

  3. Colorado - C.R.S. 42-4-510, Permits for Excess Size and Weight...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado - C.R.S. 42-4-510, Permits for Excess Size and WeightLegal Abstract Statute regulating...

  4. Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and Weight...

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: Colorado - C.R.S. 42-4-510 (3), Permits for Excess Size and WeightLegal Abstract Statute outlining...

  5. Finite-size effects on the radiative energy loss of a fast parton...

    Office of Scientific and Technical Information (OSTI)

    This is done by introducing the concept of a radiation rate in the presence of finite-size effects. This effectively extends the finite-temperature approach of Arnold, Moore, and ...

  6. Title 43 CFR 3206.12 What are the Minimum and Maximum Lease Sizes...

    Open Energy Info (EERE)

    .12 What are the Minimum and Maximum Lease Sizes? Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Federal RegulationFederal Regulation: Title 43...

  7. Effect on the Pore-Size Dependence of an Organic Electrolyte Supercapacitor

    SciTech Connect (OSTI)

    Jiang, Deen; Jin, Zhehui; Henderson, Douglous; Wu, Jianzhong

    2012-01-01

    Organic electrolytes such as tetraethylammonium tetrafluoroborate dissolved in acetonitrile (TEA-BF{sub 4}/ACN) are widely used in commercial supercapacitors and academic research, but conflicting experimental results have been reported regarding the dependence of surface-area-normalized capacitance on the pore size. Here we show from a classical density functional theory the dependence of capacitance on the pore size from 0.5 to 3.0 nm for a model TEA-BF{sub 4}/ACN electrolyte. We find that the capacitance-pore size curve becomes roughly flat after the first peak around the ion diameter, and the peak capacitance is not significantly higher than the large-pore average. We attribute the invariance of capacitance with the pore size to the formation of an electric double-layer structure that consists of counterions and highly organized solvent molecules. This work highlights the role of the solvent molecules in modulating the capacitance and reconciles apparently conflicting experimental reports.

  8. Careers in Fuel Cell Technologies

    Broader source: Energy.gov [DOE]

    Fact sheet produced by the Fuel Cell Technologies Office describing job growth potential in existing and emerging fuel cell applications.

  9. Method and apparatus for controlled size distribution of gel microspheres formed from aqueous dispersions

    DOE Patents [OSTI]

    Ryon, Allen D. (Oak Ridge, TN); Haas, Paul A. (Knoxville, TN); Vavruska, John S. (Santa Fe, NM)

    1984-01-01

    The present invention is directed to a method and apparatus for making a population of dense, closely size-controlled microspheres by sol-gel procedures wherein said microspheres are characterized by a significant percentage of said population being within a predetermined, relatively narrow size range. Microsphere populations thus provided are useful in vibratory-packed processes for nuclear fuels to be irradiated in LWR- and FBR-type nuclear reactors.

  10. Strain and particle size of palladium powders by time-of-flight neutron diffraction

    SciTech Connect (OSTI)

    Lawson, A.C.; Conant, J.W.; Talcott, C.L.; David, M.A.; Vaninetti, J.; Goldstone, J.A.; Williams, A.; Von Dreele, R.B.; Roof, R.B.; Hitterman, R.L.; Richardson, J.W. Jr.; Faber, J. Jr.

    1989-01-01

    We have determined the strain and particle size for several samples of palladium powder by time-of-flight neutron powder diffraction on two different diffractometers and by x-ray powder diffraction. The results are compared and found to be in fair agreement. The time-of-flight method gives good enough precision to reveal deficiencies in the simple models used for strain and particle size line broadening. 6 refs., 4 figs., 2 tabs.

  11. Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN

    Office of Scientific and Technical Information (OSTI)

    Quantum Dots (Journal Article) | SciTech Connect Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN Quantum Dots Citation Details In-Document Search Title: Quantum-Size-Controlled Photoelectrochemical Fabrication of Epitaxial InGaN Quantum Dots Authors: Xiao, Xiaoyin ; Fischer, Arthur J. ; Wang, George T. ; Lu, Ping ; Koleske, Daniel D. ; Coltrin, Michael E. ; Wright, Jeremy B. ; Liu, Sheng ; Brener, Igal ; Subramania, Ganesh ; Tsao, Jeffrey Y. Publication Date:

  12. Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in

    Office of Scientific and Technical Information (OSTI)

    Turbulent, Self-Gravitating Molecular Clouds (Technical Report) | SciTech Connect Technical Report: Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in Turbulent, Self-Gravitating Molecular Clouds Citation Details In-Document Search Title: Dynamical Expansion of HII Regions From Ultracompact to Compact Sizes in Turbulent, Self-Gravitating Molecular Clouds Authors: Low, Mordecai-Mark Mac ; Toraskar, Jayashree ; /Amer. Museum Natural Hist. ; Oishi, Jeffrey S. ; /Amer.

  13. Small- and Medium-Size Building Automation and Control System Needs:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scoping Study | Department of Energy Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Small- and Medium-Size Building Automation and Control System Needs: Scoping Study Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech05_brambley_040213.pdf More Documents & Publications PNNL: VOLTTRON Commercialization (CBI/ET Open Call) - 2015 Peer Review U.S. Industrial Energy Efficiency Programs CX-011262:

  14. Spontaneous radiation of a finite-size dipole emitter in hyperbolic media

    SciTech Connect (OSTI)

    Poddubny, Alexander N.; Belov, Pavel A.; Kivshar, Yuri S.

    2011-08-15

    We study the radiative decay and Purcell effect for a finite-size dipole emitter placed in a homogeneous uniaxial medium. We demonstrate that the radiative rate is strongly enhanced when the signs of the medium longitudinal and transverse dielectric constants are opposite, and that the isofrequency contour corresponds to a hyperbolic medium. We reveal that the Purcell enhancement factor remains finite even in the absence of losses and that it depends on the emitter size.

  15. Real-Time Simultaneous Measurements of Size, Density, and Composition of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single Ultrafine Diesel Tailpipe Particles | Department of Energy Simultaneous Measurements of Size, Density, and Composition of Single Ultrafine Diesel Tailpipe Particles Real-Time Simultaneous Measurements of Size, Density, and Composition of Single Ultrafine Diesel Tailpipe Particles 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_zelenyuk.pdf More Documents & Publications Microsoft PowerPoint - 4. ORNL- deer.ppt [Read-Only]

  16. Effect of particle size and doses of olivine addition on carbon dioxide

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures | Argonne National Laboratory Effect of particle size and doses of olivine addition on carbon dioxide sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures Title Effect of particle size and doses of olivine addition on carbon dioxide sequestration during anaerobic digestion of sewage sludge at ambient and mesophilic temperatures Publication Type Journal

  17. Measuring the Raindrop Size Distribution, ARM's Efforts at Darwin and SGP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measuring the Raindrop Size Distribution, ARM's Efforts at Darwin and SGP Bartholomew, Mary Jane Brookhaven National Laboratory Category: Instruments ARM has purchased two impact disdrometers for indefinite deployment. One is currently installed at the Tropical Western Pacific (TWP) Darwin facility and the other will be deployed at the central facility of the Southern Great Plains Site this spring. The disdrometers make measurements of raindrop diameter in 20 size bins over the range of 0.3 to

  18. Apparatus and method for the determination of grain size in thin films

    DOE Patents [OSTI]

    Maris, Humphrey J (Barrington, RI)

    2001-01-01

    A method for the determination of grain size in a thin film sample comprising the steps of measuring first and second changes in the optical response of the thin film, comparing the first and second changes to find the attenuation of a propagating disturbance in the film and associating the attenuation of the disturbance to the grain size of the film. The second change in optical response is time delayed from the first change in optical response.

  19. Apparatus and method for the determination of grain size in thin films

    DOE Patents [OSTI]

    Maris, Humphrey J (Barrington, RI)

    2000-01-01

    A method for the determination of grain size in a thin film sample comprising the steps of measuring first and second changes in the optical response of the thin film, comparing the first and second changes to find the attenuation of a propagating disturbance in the film and associating the attenuation of the disturbance to the grain size of the film. The second change in optical response is time delayed from the first change in optical response.

  20. The Impact of Oil Consumption Mechanisms on Diesel Exhaust Particle Size

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Distributions and Detailed Exhaust Chemical Composition | Department of Energy Oil Consumption Mechanisms on Diesel Exhaust Particle Size Distributions and Detailed Exhaust Chemical Composition The Impact of Oil Consumption Mechanisms on Diesel Exhaust Particle Size Distributions and Detailed Exhaust Chemical Composition 2003 DEER Conference Presentation: University of Wisconsin-Madison PDF icon 2003_deer_foster.pdf More Documents & Publications Mass Correlation of Engine Emissions with

  1. HVAC Right-Sizing Part 1: Calculating Loads | Department of Energy

    Energy Savers [EERE]

    HVAC Right-Sizing Part 1: Calculating Loads HVAC Right-Sizing Part 1: Calculating Loads This webinar, presented by IBACOS (a Building America Research Team) will highlight the key criteria required to create accurate heating and cooling load calculations, following the guidelines of the Air Conditioning Contractors of America (ACCA) Manual J version 8 PDF icon webinar_hvac_calculatingloads_20110428.pdf More Documents & Publications 2014-08-28 Issuance: Energy Conservation Standards for

  2. Measurements of Aerosol Charge and Size Distribution for Graphite, Gold, Palladium, and Silver Nanoparticles

    SciTech Connect (OSTI)

    Simones, Matthew P.; Gutti, Veera R.; Meyer, Ryan M.; Loyalka, Sudarshan K.

    2011-11-01

    The role of charge on aerosol evolution and hence the nuclear source term has been an issue of interest, and there is a need for both experimental techniques and modeling for quantifying this role. Our focus here is on further exploration of a tandem differential mobility analyzer (TDMA) technique to simultaneously measure both the size and charge (positive, negative and neutral) dependent aerosol distributions. We have generated graphite, gold, silver, and palladium nanoparticles (aerosol) using a spark generator. We measure the electrical mobility-size distributions for these aerosols using a TDMA, and from these data we deduce the full charge-size distributions. We observe asymmetry in the particle size distributions for negative and positive charges. This asymmetry could have a bearing on the dynamics of charged aerosols, indicating that the assumption of symmetry for size distributions of negatively and positively charged particles in source term simulations may not be always appropriate. Also, the experimental technique should find applications in measurements of aerosol rate processes that are affected by both particle charge and size (e.g. coagulation, deposition, resuspension), and hence in modeling and simulation of the nuclear source term.

  3. Low pressure shock initiation of porous HMX for two grain size distributions and two densities

    SciTech Connect (OSTI)

    Gustavsen, R.L.; Sheffield, S.A.; Alcon, R.R.

    1995-09-01

    Shock initiation measurements have been made on granular HMX (octotetramethylene tetranitrainine) for two particle size distributions and two densities. Samples were pressed to either 65% or 73% of crystal density from fine ({approx} 10 {mu}m grain size) and coarse (broad distribution of grain sizes peaking at {approx} 150 {mu}m) powders. Planar shocks of 0.2--1 GPa were generated by impacting gas gun driven projectiles on plastic targets containing the HMX. Wave profiles were measured at the input and output of the {approx} 3.9 mm thick HMX layer using electromagnetic particle velocity gauges. The initiation behavior for the two particle size distributions was very different. The coarse HMX began initiating at input pressures as low as 0.5 GPa. Transmitted wave profiles showed relatively slow reaction with most of the buildup occurring at the shock front. In contrast, the fine particle HMX did not begin to initiate at pressures below 0.9 GPa. When the fine powder did react, however, it did so much faster than the coarse HMX. These observations are consistent with commonly held ideas about bum rates being correlated to surface area, and initiation thresholds being correlated with the size and temperature of the hot spots created by shock passage. For each size, the higher density pressings were less sensitive than the lower density pressings.

  4. Using the depth-velocity-size diagram to interpret equilibrium bed configurations in river flows

    SciTech Connect (OSTI)

    Southard, J.B. (Massachusetts Institute of Technology, Cambridge, MA (USA))

    1990-05-01

    Data from flume studies that report equilibrium bed configuration as well as water temperature, flow depth, flow velocity, and sediment size were used to develop the best approximation to the relationships among the various bed phases (ripples, dunes, lower regime plane bed, upper regime plane bed, and antidunes) in a three-axis graph (depth-velocity-size diagram) with dimensionless measures of mean flow depth, mean flow velocity, and sediment size along the axis. Relationships are shown in a series of depth-velocity and velocity-size sections through the diagram. Boundaries between bed-phase stability fields are drawn as surfaces that minimize, misplacement of data points. A large subset of the data, for which reliable values of bed shear stress are reported, was also used to represent the stability relationships in a graph of dimensionless boundary shear stress against dimensionless sediment size, but with results less useful for fluvial flow interpretation. The diagram covers about one order of magnitude in flow depth. To be useful for river flows, the diagram must be extrapolated in flow depth by about one more order of magnitude, but this is not a serious problem for approximate work. The depth-velocity-size diagram permits prediction of equilibrium bed configuration in river flows when the approximate flow depth and mean flow velocity are known. Because the diagram is essentially dimensionless, the effect of water temperature (via the fluid viscosity) on the bed configuration is easily accounted for by use of the diagram.

  5. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7/21/2015 eere.energy.gov Fuel Cell Technologies Overview States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3/14/2012 Outline * Introduction - Technology and Market Overview * DOE Program Overview - Mission & Structure - R&D Progress - Demonstration & Deployments * State Activities - Examples of potential opportunities 2 | Fuel Cell Technologies Program Source: US DOE 7/21/2015

  6. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  7. Heterojunction solar cell

    DOE Patents [OSTI]

    Olson, Jerry M. (Lakewood, CO)

    1994-01-01

    A high-efficiency single heterojunction solar cell wherein a thin emitter layer (preferably Ga.sub.0.52 In.sub.0.48 P) forms a heterojunction with a GaAs absorber layer. The conversion effiency of the solar cell is at least 25.7%. The solar cell preferably includes a passivating layer between the substrate and the absorber layer. An anti-reflection coating is preferably disposed over the emitter layer.

  8. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    States Energy Advisory Board (STEAB) Washington, DC Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 3/14/2012 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov * Introduction - Technology and Market Overview * DOE Program Overview - Mission & Structure - R&D Progress - Demonstration & Deployments * State Activities - Examples of potential opportunities Outline 3 | Fuel Cell Technologies Program Source: US DOE

  9. Fuel Cells Fact Sheet

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells Fuel cells are the most energy efficient devices for extracting power from fuels. Capable of running on a variety of fuels, including hydrogen, natural gas, and biogas, fuel cells can provide clean power for applications ranging from less than a watt to multiple megawatts. Our transportation-including personal vehicles, trucks, buses, marine vessels, and other specialty vehicles such as lift trucks and ground support equipment, as well as auxiliary power units for traditional

  10. Heterojunction solar cell

    DOE Patents [OSTI]

    Olson, J.M.

    1994-08-30

    A high-efficiency single heterojunction solar cell is described wherein a thin emitter layer (preferably Ga[sub 0.52]In[sub 0.48]P) forms a heterojunction with a GaAs absorber layer. The conversion efficiency of the solar cell is at least 25.7%. The solar cell preferably includes a passivating layer between the substrate and the absorber layer. An anti-reflection coating is preferably disposed over the emitter layer. 1 fig.

  11. Fuel Cell Financing Options

    Broader source: Energy.gov [DOE]

    Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Financing Fuel Cell Installations, August 30, 2011.

  12. Financing Fuel Cells

    Broader source: Energy.gov [DOE]

    Presented at the Clean Energy States Alliance and U.S. Department of Energy Webinar: Financing Fuel Cell Installations, August 30, 2011.

  13. Micro fuel cell

    SciTech Connect (OSTI)

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  14. Fuel Cell Technologies Budget

    SciTech Connect (OSTI)

    EERE

    2012-03-16

    The Fuel Cell Technologies Office receives appropriations from Energy and Water Development. The offices's major activities and budget are outlined in this Web page.

  15. Hydrogen Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    The fuel cell — an energy conversion device that can efficiently capture and use the power of hydrogen — is the key to making it happen.

  16. Opportunities with Fuel Cells

    Reports and Publications (EIA)

    1994-01-01

    The concept for fuel cells was discovered in the nineteenth century. Today, units incorporating this technology are becoming commercially available for cogeneration applications.

  17. Microcomposite Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Summary of microcomposite fuel cell membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  18. Electrochemical cell method

    DOE Patents [OSTI]

    Kaun, T.D.; Eshman, P.F.

    1980-05-09

    A secondary electrochemical cell is prepared by providing positive and negative electrodes having outer enclosures of rigid perforated electrically conductive material defining an internal compartment containing the electrode material in porous solid form. The electrodes are each immersed in molten electrolyte salt prior to cell assembly to incorporate the cell electrolyte. Following solidification of the electrolyte substantially throughout the porous volume of the electrode material, the electrodes are arranged in an alternating positive-negative array with interelectrode separators of porous frangible electrically insulative material. The completed array is assembled into the cell housing and sealed such that on heating the solidified electrolyte flows into the interelectrode separator.

  19. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1983-01-01

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  20. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

    1982-02-09

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

  1. Fuel Cell Technologies Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Seminar Orlando, FL Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 11/1/2011 2 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov DOE Program Overview Budget Progress Next Steps Agenda 3 | Fuel Cell Technologies Program Source: US DOE 3/19/2013 eere.energy.gov DOE Program Structure The Program is an integrated effort, structured to address all the key challenges and obstacles facing widespread commercialization. The

  2. Molten salt lithium cells

    DOE Patents [OSTI]

    Raistrick, I.D.; Poris, J.; Huggins, R.A.

    1980-07-18

    Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

  3. Staged venting of fuel cell system during rapid shutdown

    DOE Patents [OSTI]

    Clingerman, Bruce J. (Palmyra, NY); Doan, Tien M. (Columbia, MD); Keskula, Donald H. (Webster, NY)

    2002-01-01

    A venting methodology and system for rapid shutdown of a fuel cell apparatus of the type used in a vehicle propulsion system. H.sub.2 and air flows to the fuel cell stack are slowly bypassed to the combustor upon receipt of a rapid shutdown command. The bypass occurs over a period of time (for example one to five seconds) using conveniently-sized bypass valves. Upon receipt of the rapid shutdown command, the anode inlet of the fuel cell stack is instantaneously vented to a remote vent to remove all H.sub.2 from the stack. Airflow to the cathode inlet of the fuel cell stack gradually diminishes over the bypass period, and when the airflow bypass is complete the cathode inlet is also instantaneously vented to a remote vent to eliminate pressure differentials across the stack.

  4. Staged venting of fuel cell system during rapid shutdown

    DOE Patents [OSTI]

    Keskula, Donald H.; Doan, Tien M.; Clingerman, Bruce J.

    2004-09-14

    A venting methodology and system for rapid shutdown of a fuel cell apparatus of the type used in a vehicle propulsion system. H.sub.2 and air flows to the fuel cell stack are slowly bypassed to the combustor upon receipt of a rapid shutdown command. The bypass occurs over a period of time (for example one to five seconds) using conveniently-sized bypass valves. Upon receipt of the rapid shutdown command, the anode inlet of the fuel cell stack is instantaneously vented to a remote vent to remove all H.sub.2 from the stack. Airflow to the cathode inlet of the fuel cell stack gradually diminishes over the bypass period, and when the airflow bypass is complete the cathode inlet is also instantaneously vented to a remote vent to eliminate pressure differentials across the stack.

  5. Nanodisperse transition metal electrodes (NTME) for electrochemical cells

    DOE Patents [OSTI]

    Striebel, Kathryn A. (Oakland, CA); Wen, Shi-Jie (Sunnyvale, CA)

    2000-01-01

    Disclosed are transition metal electrodes for electrochemical cells using gel-state and solid-state polymers. The electrodes are suitable for use in primary and secondary cells. The electrodes (either negative electrode or positive electrode) are characterized by uniform dispersion of the transition metal at the nanoscale in the polymer. The transition metal moiety is structurally amorphous, so no capacity fade should occur due to lattice expansion/contraction mechanisms. The small grain size, amorphous structure and homogeneous distribution provide improved charge/discharge cycling performance, and a higher initial discharge rate capability. The cells can be cycled at high current densities, limited only by the electrolyte conductivity. A method of making the electrodes (positive and negative), and their usage in electrochemical cells are disclosed.

  6. MEMS Switches Are XS in Size, XXL in Power | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    handling capability by nearly 2 orders of magnitude. This enables our MEMS microswitch devices to serve a wide range of applications from handheld electronics such as cell phones,...

  7. Design for the fabrication of high efficiency solar cells

    DOE Patents [OSTI]

    Simmons, Joseph H.

    1998-01-01

    A method and apparatus for a photo-active region for generation of free carriers when a first surface is exposed to optical radiation. The photo-active region includes a conducting transparent matrix and clusters of semiconductor materials embedded within the conducting transparent matrix. The clusters are arranged in the matrix material so as to define at least a first distribution of cluster sizes ranging from those with the highest bandgap energy near a light incident surface of the photo-active region to those with the smallest bandgap energy near an opposite second surface of the photo-active region. Also disclosed is a method and apparatus for a solar cell. The solar cell includes a photo-active region containing a plurality of semiconductor clusters of varying sizes as described.

  8. Electrolyte matrix in a molten carbonate fuel cell stack

    DOE Patents [OSTI]

    Reiser, Carl A. (Glastonbury, CT); Maricle, Donald L. (Glastonbury, CT)

    1987-04-21

    A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack.

  9. Electrolyte matrix in a molten carbonate fuel cell stack

    DOE Patents [OSTI]

    Reiser, C.A.; Maricle, D.L.

    1987-04-21

    A fuel cell stack is disclosed with modified electrolyte matrices for limiting the electrolytic pumping and electrolyte migration along the stack external surfaces. Each of the matrices includes marginal portions at the stack face of substantially greater pore size than that of the central body of the matrix. Consequently, these marginal portions have insufficient electrolyte fill to support pumping or wicking of electrolyte from the center of the stack of the face surfaces in contact with the vertical seals. Various configurations of the marginal portions include a complete perimeter, opposite edge portions corresponding to the air plenums and tab size portions corresponding to the manifold seal locations. These margins will substantially limit the migration of electrolyte to and along the porous manifold seals during operation of the electrochemical cell stack. 6 figs.

  10. New Solar Cell Is More Efficient, Less Costly - News Feature | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Solar Cell Is More Efficient, Less Costly November 8, 2013 In this photo, a researcher in glasses holds a solar wafer about the size of a CD case. In the background are two computer screens displaying graphs of the performance of similar wafers. Enlarge image NREL Principal Scientist Mowafak Al-Jassim holds a TetraSun PV cell in the cathodoluminescence lab at NREL. The TetraSun cell combines increased efficiency and low cost, breaking the usual rules for solar cells. Credit: Dennis Schroeder

  11. SIZE DISTRIBUTION AND RATE OF PRODUCTION OF AIRBORNE PARTICULATE MATTER GENERATED DURING METAL CUTTING

    SciTech Connect (OSTI)

    M.A. Ebadian, Ph.D.; S.K. Dua, Ph.D., C.H.P.; Hillol Guha, Ph.D.

    2001-01-01

    During deactivation and decommissioning activities, thermal cutting tools, such as plasma torch, laser, and gasoline torch, are used to cut metals. These activities generate fumes, smoke and particulates. These airborne species of matter, called aerosols, may be inhaled if suitable respiratory protection is not used. Inhalation of the airborne metallic aerosols has been reported to cause ill health effects, such as acute respiratory syndrome and chromosome damage in lymphocytes. In the nuclear industry, metals may be contaminated with radioactive materials. Cutting these metals, as in size reduction of gloveboxes and tanks, produces high concentrations of airborne transuranic particles. Particles of the respirable size range (size < 10 {micro}m) deposit in various compartments of the respiratory tract, the fraction and the site in the respiratory tract depending on the size of the particles. The dose delivered to the respiratory tract depends on the size distribution of the airborne particulates (aerosols) and their concentration and radioactivity/toxicity. The concentration of airborne particulate matter in an environment is dependent upon the rate of their production and the ventilation rate. Thus, measuring aerosol size distribution and generation rate is important for (1) the assessment of inhalation exposures of workers, (2) the selection of respiratory protection equipment, and (3) the design of appropriate filtration systems. Size distribution of the aerosols generated during cutting of different metals by plasma torch was measured. Cutting rates of different metals, rate of generation of respirable mass, as well as the fraction of the released kerf that become respirable were determined. This report presents results of these studies. Measurements of the particles generated during cutting of metal plates with a plasma arc torch revealed the presence of particles with mass median aerodynamic diameters of particles close to 0.2 {micro}m, arising from condensation of vaporized material and subsequent rapid formation of aggregates. Particles of larger size, resulting from ejection of melted material or fragments from the cutting zone, were also observed. This study presents data regarding the metal cutting rate, particle size distribution, and their generation rate, while using different cutting tools and metals. The study shows that respirable particles constitute only a small fraction of the released kerf.

  12. Fuel Cells in the States

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in the Fuel Cells in the States States State and Regional State and Regional Initiatives Working Group Initiatives Working Group July 12, 2006 July 12, 2006 Jennifer Gangi Jennifer Gangi Program Director Program Director Fuel Cells 2000 Fuel Cells 2000 Fuel Cells 2000 / BTI Fuel Cells 2000 / BTI U.S. nonprofit organization U.S. nonprofit organization Established in 1993 Established in 1993 Promotes fuel cells from public Promotes fuel cells from public interest perspective. interest perspective.

  13. Fuel cells and fuel cell catalysts

    DOE Patents [OSTI]

    Masel, Richard I.; Rice, Cynthia A.; Waszczuk, Piotr; Wieckowski, Andrzej

    2006-11-07

    A direct organic fuel cell includes a formic acid fuel solution having between about 10% and about 95% formic acid. The formic acid is oxidized at an anode. The anode may include a Pt/Pd catalyst that promotes the direct oxidation of the formic acid via a direct reaction path that does not include formation of a CO intermediate.

  14. Size dependent compressibility of nano-ceria: Minimum near 33 nm

    SciTech Connect (OSTI)

    Rodenbough, Philip P.; Song, Junhua; Chan, Siu-Wai; Walker, David; Clark, Simon M.; Kalkan, Bora

    2015-04-20

    We report the crystallite-size-dependency of the compressibility of nanoceria under hydrostatic pressure for a wide variety of crystallite diameters and comment on the size-based trends indicating an extremum near 33 nm. Uniform nano-crystals of ceria were synthesized by basic precipitation from cerium (III) nitrate. Size-control was achieved by adjusting mixing time and, for larger particles, a subsequent annealing temperature. The nano-crystals were characterized by transmission electron microscopy and standard ambient x-ray diffraction (XRD). Compressibility, or its reciprocal, bulk modulus, was measured with high-pressure XRD at LBL-ALS, using helium, neon, or argon as the pressure-transmitting medium for all samples. As crystallite size decreased below 100 nm, the bulk modulus first increased, and then decreased, achieving a maximum near a crystallite diameter of 33 nm. We review earlier work and examine several possible explanations for the peaking of bulk modulus at an intermediate crystallite size.

  15. Morphologically and size uniform monodisperse particles and their shape-directed self-assembly

    DOE Patents [OSTI]

    Collins, Joshua E.; Bell, Howard Y.; Ye, Xingchen; Murray, Christopher Bruce

    2015-11-17

    Monodisperse particles having: a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology are disclosed. Due to their uniform size and shape, the monodisperse particles self assemble into superlattices. The particles may be luminescent particles such as down-converting phosphor particles and up-converting phosphors. The monodisperse particles of the invention have a rare earth-containing lattice which in one embodiment may be an yttrium-containing lattice or in another may be a lanthanide-containing lattice. The monodisperse particles may have different optical properties based on their composition, their size, and/or their morphology (or shape). Also disclosed is a combination of at least two types of monodisperse particles, where each type is a plurality of monodisperse particles having a single pure crystalline phase of a rare earth-containing lattice, a uniform three-dimensional size, and a uniform polyhedral morphology; and where the types of monodisperse particles differ from one another by composition, by size, or by morphology. In a preferred embodiment, the types of monodisperse particles have the same composition but different morphologies. Methods of making and methods of using the monodisperse particles are disclosed.

  16. Ultrashort laser ablation of bulk copper targets: Dynamics and size distribution of the generated nanoparticles

    SciTech Connect (OSTI)

    Tsakiris, N.; Gill-Comeau, M.; Lewis, L. J.; Anoop, K. K.; Ausanio, G.; Bruzzese, R.; Amoruso, S.

    2014-06-28

    We address the role of laser pulse fluence on expansion dynamics and size distribution of the nanoparticles produced by irradiating a metallic target with an ultrashort laser pulse in a vacuum, an issue for which contrasting indications are present in the literature. To this end, we have carried out a combined theoretical and experimental analysis of laser ablation of a bulk copper target with ?50 fs, 800?nm pulses, in an interval of laser fluencies going from few to several times the ablation threshold. On one side, molecular dynamics simulations, with two-temperature model, describe the decomposition of the material through the analysis of the evolution of thermodynamic trajectories in the material phase diagram, and allow estimating the size distribution of the generated nano-aggregates. On the other side, atomic force microscopy of less than one layer nanoparticles deposits on witness plates, and fast imaging of the nanoparticles broadband optical emission provide the corresponding experimental characterization. Both experimental and numerical findings agree on a size distribution characterized by a significant fraction (?90%) of small nanoparticles, and a residual part (?10%) spanning over a rather large size interval, evidencing a weak dependence of the nanoparticles sizes on the laser pulse fluence. Numerical and experimental findings show a good degree of consistency, thus suggesting that modeling can realistically support the search for experimental methods leading to an improved control over the generation of nanoparticles by ultrashort laser ablation.

  17. The modulation of canine mesenchymal stem cells by nano-topographic cues

    SciTech Connect (OSTI)

    Wood, Joshua A.; Ly, Irene; Borjesson, Dori L.; Nealey, Paul F.; Russell, Paul; Murphy, Christopher J.

    2012-11-15

    Mesenchymal stem cells (MSCs) represent a promising cellular therapeutic for the treatment of a variety of disorders. On transplantation, MSCs interact with diverse extracellular matrices (ECMs) that vary dramatically in topographic feature type, size and surface order. In order to investigate the impact of these topographic cues, surfaces were fabricated with either isotropically ordered holes or anisotropically ordered ridges and grooves. To simulate the biologically relevant nano through micron size scale, a series of topographically patterned substrates possessing features of differing pitch (pitch=feature width+groove width) were created. Results document that the surface order and size of substratum topographic features dramatically modulate fundamental MSC behaviors. Topographically patterned (ridge+groove) surfaces were found to significantly impact MSC alignment, elongation, and aspect ratio. Novel findings also demonstrate that submicron surfaces patterned with holes resulted in increased MSC alignment to adjacent cells as well as increased migration rates. Overall, this study demonstrates that the presentation of substratum topographic cues dramatically influence MSC behaviors in a size and shape dependent manner. The response of MSCs to substratum topographic cues was similar to other cell types that have been studied previously with regards to cell shape on ridge and groove surfaces but differed with respect to proliferation and migration. This is the first study to compare the impact of anisotropically ordered ridge and groove topographic cues to isotropically order holed topographic cues on fundamental MSC behaviors across a range of biologically relevant size scales.

  18. Electrochemical cell stack assembly

    DOE Patents [OSTI]

    Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

    2010-06-22

    Multiple stacks of tubular electrochemical cells having a dense electrolyte disposed between an anode and a cathode preferably deposited as thin films arranged in parallel on stamped conductive interconnect sheets or ferrules. The stack allows one or more electrochemical cell to malfunction without disabling the entire stack. Stack efficiency is enhanced through simplified gas manifolding, gas recycling, reduced operating temperature and improved heat distribution.

  19. Metal halogen electrochemical cell

    DOE Patents [OSTI]

    Bellows, Richard J. (Hampton, NJ); Kantner, Edward (E. Brunswick, NJ)

    1988-08-23

    It has now been discovered that reduction in the coulombic efficiency of metal halogen cells can be minimized if the microporous separator employed in such cells is selected from one which is preferably wet by the aqueous electrolyte and is not wet substantially by the cathodic halogen.

  20. Fuel cell market applications

    SciTech Connect (OSTI)

    Williams, M.C.

    1995-12-31

    This is a review of the US (and international) fuel cell development for the stationary power generation market. Besides DOE, GRI, and EPRI sponsorship, the US fuel cell program has over 40% cost-sharing from the private sector. Support is provided by user groups with over 75 utility and other end-user members. Objectives are to develop and demonstrate cost-effective fuel cell power generation which can initially be commercialized into various market applications using natural gas fuel by the year 2000. Types of fuel cells being developed include PAFC (phosphoric acid), MCFC (molten carbonate), and SOFC (solid oxide); status of each is reported. Potential international applications are reviewed also. Fuel cells are viewed as a force in dispersed power generation, distributed power, cogeneration, and deregulated industry. Specific fuel cell attributes are discussed: Fuel cells promise to be one of the most reliable power sources; they are now being used in critical uninterruptible power systems. They need hydrogen which can be generated internally from natural gas, coal gas, methanol landfill gas, or other fuels containing hydrocarbons. Finally, fuel cell development and market applications in Japan are reviewed briefly.

  1. Programmed cell death

    SciTech Connect (OSTI)

    1995-12-31

    The purpose of this conference to provide a multidisciplinary forum for exchange of state-of-the-art information on the role programmed cell death plays in normal development and homeostasis of many organisms. This volume contains abstracts of papers in the following areas: invertebrate development; immunology/neurology; bcl-2 family; biochemistry; programmed cell death in viruses; oncogenesis; vertebrate development; and diseases.

  2. Tilted fuel cell apparatus

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine; Krueger, Roger L.

    2005-04-12

    Bipolar, tilted embodiments of high temperature, molten electrolyte electrochemical cells capable of directly converting carbon fuel to electrical energy are disclosed herein. The bipolar, tilted configurations minimize the electrical resistance between one cell and others connected in electrical series. The tilted configuration also allows continuous refueling of carbon fuel.

  3. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  4. Molten carbonate fuel cell reduction of nickel deposits

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Zwick, Stanley A. (Darien, IL)

    1987-01-01

    A molten carbonate fuel cell with anode and cathode electrodes and an eleolyte formed with two tile sections, one of the tile sections being adjacent the anode and limiting leakage of fuel gas into the electrolyte with the second tile section being adjacent the cathode and having pores sized to permit the presence of oxygen gas in the electrolyte thereby limiting the formation of metal deposits caused by the reduction of metal compositions migrating into the electrolyte from the cathode.

  5. Photovoltaic solar cell

    DOE Patents [OSTI]

    Nielson, Gregory N.; Gupta, Vipin P.; Okandan, Murat; Watts, Michael R.

    2015-09-08

    A photovoltaic solar concentrator is disclosed with one or more transverse-junction solar cells (also termed point contact solar cells) and a lens located above each solar cell to concentrate sunlight onto the solar cell to generate electricity. Piezoelectric actuators tilt or translate each lens to track the sun using a feedback-control circuit which senses the electricity generated by one or more of the solar cells. The piezoelectric actuators can be coupled through a displacement-multiplier linkage to provide an increased range of movement of each lens. Each lens in the solar concentrator can be supported on a frame (also termed a tilt plate) having three legs, with the movement of the legs being controlled by the piezoelectric actuators.

  6. A NEW RECIPE FOR OBTAINING CENTRAL VOLUME DENSITIES OF PRESTELLAR CORES FROM SIZE MEASUREMENTS

    SciTech Connect (OSTI)

    Tassis, Konstantinos; Yorke, Harold W. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2011-07-10

    We propose a simple analytical method for estimating the central volume density of prestellar molecular cloud cores from their column density profiles. Prestellar cores feature a flat central part of the column density and volume density profiles of the same size indicating the existence of a uniform-density inner region. The size of this region is set by the thermal pressure force which depends only on the central volume density and temperature of the core, and can provide a direct measurement of the central volume density. Thus, a simple length measurement can immediately yield a central density estimate independent of any dynamical model for the core and without the need for fitting. Using the radius at which the column density is 90% of the central value as an estimate of the size of the flat inner part of the column density profile yields an estimate of the central volume density within a factor of two for well-resolved cores.

  7. Nano-sized particles, processes of making, compositions and uses thereof

    DOE Patents [OSTI]

    O'Brien, Stephen; Yin, Ming

    2012-05-22

    The present invention describes methods for preparing high quality nanoparticles, i.e., metal oxide based nanoparticles of uniform size and monodispersity. The nanoparticles advantageously comprise organic alkyl chain capping groups and are stable in air and in nonpolar solvents. The methods of the invention provide a simple and reproducible procedure for forming transition metal oxide nanocrystals, with yields over 80%. The highly crystalline and monodisperse nanocrystals are obtained directly without further size selection; particle size can be easily and fractionally increased by the methods. The resulting nanoparticles can exhibit magnetic and/or optical properties. These properties result from the methods used to prepare them. Also advantageously, the nanoparticles of this invention are well suited for use in a variety of industrial applications, including cosmetic and pharmaceutical formulations and compositions.

  8. Field investigation of the relationship between battery size and PV system performance

    SciTech Connect (OSTI)

    Stevens, J.; Kratochvil, J. [Sandia National Labs., Albuquerque, NM (United States); Harrington, S. [Ktech Corp., Albuquerque, NM (United States)

    1993-07-01

    Four photovoltaic-powered lighting systems were installed in a National Forest Service campground in June of 1991. These systems have identical arrays, loads and charge controllers. The only difference was in the rated capacity of the battery bank for each system. The battery banks all use the same basic battery as a building block with the four systems utilizing either one battery, two batteries, three batteries or four batteries. The purpose of the experiment is to examine the effect of the various battery sizes on the ability of the system to charge the battery, energy available to the load, and battery lifetime. Results show an important trend in system performance concerning the impact of charge controllers on the relation between array size and battery size which results in an inability to achieve the days of battery storage originally designed for.

  9. Consideration of Grain Size Distribution in the Diffusion of Fission Gas to Grain Boundaries

    SciTech Connect (OSTI)

    Paul C. Millett; Yongfeng Zhang; Michael R. Tonks; S. B. Biner

    2013-09-01

    We analyze the accumulation of fission gas on grain boundaries in a polycrystalline microstructure with a distribution of grain sizes. The diffusion equation is solved throughout the microstructure to evolve the gas concentration in space and time. Grain boundaries are treated as infinite sinks for the gas concentration, and we monitor the cumulative gas inventory on each grain boundary throughout time. We consider two important cases: first, a uniform initial distribution of gas concentration without gas production (correlating with post-irradiation annealing), and second, a constant gas production rate with no initial gas concentration (correlating with in-reactor conditions). The results show that a single-grain-size model, such as the Booth model, over predicts the gas accumulation on grain boundaries compared with a polycrystal with a grain size distribution. Also, a considerable degree of scatter, or variability, exists in the grain boundary gas accumulation when comparing all of the grain boundaries in the microstructure.

  10. Measurement of the soot concentration and soot particle sizes in propane oxygen flames

    SciTech Connect (OSTI)

    Bockhorn, H.; Fetting, F.; Meyer, U.; Reck, R.; Wannemacher, G.

    1981-01-01

    Soot concentrations and particle sizes were measured by light scattering and probe measurements in the burnt gas region of atmospheric pressure propane-oxygen flames and propane-oxygen flames to which hydrogen or ammonia were added. The results show that the soot concentrations in propane-oxygen flames, to which hydrogen is added are lower compared to propane-oxygen flames. The decrease of soot concentration is much stronger when ammonia is added. Associated with the reduction of soot concentration is a reduction of mean particle size of the soot particles and a lower breadth of the particle size distributions. Electron micrographs of soot particles from the probe measurements showed that soot particles from flames with high soot concentrations (propane oxygen flames) are aggregates with chain or cluster structure while the structure of the particles from flames with lower soot concentration (propane oxygen flames with hydrogen or ammonia added) is more compact. 24 refs.

  11. Measurement of particle size, velocity and temperature in the plasma spray coating process

    SciTech Connect (OSTI)

    Fincke, J.R.; Swank, W.D.

    1991-01-01

    The quality and uniformity of coatings fabricated by the plasma spray process is controlled by the condition of the particles on impact. In this work a measurement technique for simultaneously obtaining particle size, velocity, and temperature is used to characterize the particle spray field. Particle size and velocity are obtained from a combination laser particle sizing system and laser Doppler velocimeter (LDV). The particle temperature is determined by a two-color pyrometer technique and the relative particle number density is derived from the data rate. The fraction of unheated or unprocessed particles which result from temperature and velocity fluctuations is also obtained. This fraction can approach 10% by mass of the total particle flow. 17 refs., 10 figs.

  12. Density-functional errors in ionization potential with increasing system size

    SciTech Connect (OSTI)

    Whittleton, Sarah R.; Sosa Vazquez, Xochitl A.; Isborn, Christine M.; Johnson, Erin R.

    2015-05-14

    This work investigates the effects of molecular size on the accuracy of density-functional ionization potentials for a set of 28 hydrocarbons, including series of alkanes, alkenes, and oligoacenes. As the system size increases, delocalization error introduces a systematic underestimation of the ionization potential, which is rationalized by considering the fractional-charge behavior of the electronic energies. The computation of the ionization potential with many density-functional approximations is not size-extensive due to excessive delocalization of the incipient positive charge. While inclusion of exact exchange reduces the observed errors, system-specific tuning of long-range corrected functionals does not generally improve accuracy. These results emphasize that good performance of a functional for small molecules is not necessarily transferable to larger systems.

  13. The effects of size reduction techniques on TCLP analysis of solidified mixed waste

    SciTech Connect (OSTI)

    Thiel, R.D.; McLaurin, A.W.; Kochen, R.L.

    1993-07-01

    The Rocky Flats Plant (RFP) generates and stores mixed wastes that are subject to regulation under the Resource Conservation and Recovery Act (RCRA) Land Disposal Restrictions (LDR). Low level mixed wastes at RFP are destined for disposal at the Nevada Test Site (NTS), and thus must meet stringent NTS Waste Acceptance Criteria (WAC), including free liquids, dispersible solids, and Toxicity Characteristic Leaching Procedure (TCLP) requirements. TCLP requires size reduction of the waste form to less than 0.95 centimeters. This can be accomplished by cutting, crushing, or grinding. These classic size reduction methods have the effect of exposing more surface area of the waste. Stabilization technologies under investigation at RFP include polymer encapsulation by co-extruding the waste with low density polyethylene and microwave melting. The objective of this study is to evaluate the effects of different size reduction methods on TCLP results for polyethylene-encapsulated and microwave melted surrogate waste.

  14. Human serum activates CIDEB-mediated lipid droplet enlargement in hepatoma cells

    SciTech Connect (OSTI)

    Singaravelu, Ragunath; National Research Council of Canada, Ottawa, Ontario K1A 0R6 ; Lyn, Rodney K.; National Research Council of Canada, Ottawa, Ontario K1A 0R6 ; Srinivasan, Prashanth; Delcorde, Julie; National Research Council of Canada, Ottawa, Ontario K1A 0R6 ; Steenbergen, Rineke H.; Tyrrell, D. Lorne; Li Ka Shing Institute of Virology, Katz Centre for Pharmacy and Health Research, Edmonton, Alberta T6G 2S2 ; Pezacki, John P.

    2013-11-15

    Highlights: Human serum induced differentiation of hepatoma cells increases cellular lipid droplet (LD) size. The observed increase in LD size correlates with increased PGC-1? and CIDEB expression. Induction of CIDEB expression correlates with rescue of VLDL secretion and loss of ADRP. siRNA knockdown of CIDEB impairs the human serum mediated increase in LD size. This system represents a cost-efficient model to study CIDEBs role in lipid biology. -- Abstract: Human hepatocytes constitutively express the lipid droplet (LD) associated protein cell death-inducing DFFA-like effector B (CIDEB). CIDEB mediates LD fusion, as well as very-low-density lipoprotein (VLDL) maturation. However, there are limited cell culture models readily available to study CIDEBs role in these biological processes, as hepatoma cell lines express negligible levels of CIDEB. Recent work has highlighted the ability of human serum to differentiate hepatoma cells. Herein, we demonstrate that culturing Huh7.5 cells in media supplemented with human serum activates CIDEB expression. This activation occurs through the induced expression of PGC-1?, a positive transcriptional regulator of CIDEB. Coherent anti-Stokes Raman scattering (CARS) microscopy revealed a correlation between CIDEB levels and LD size in human serum treated Huh7.5 cells. Human serum treatment also resulted in a rapid decrease in the levels of adipose differentiation-related protein (ADRP). Furthermore, individual overexpression of CIDEB was sufficient to down-regulate ADRP protein levels. siRNA knockdown of CIDEB revealed that the human serum mediated increase in LD size was CIDEB-dependent. Overall, our work highlights CIDEBs role in LD fusion, and presents a new model system to study the PGC-1?/CIDEB pathways role in LD dynamics and the VLDL pathway.

  15. Method and apparatus for controlled size distribution of gel microspheres formed from aqueous dispersions. [Patent application

    DOE Patents [OSTI]

    Ryon, A.D.; Haas, P.A.; Vavruska, J.S.

    1982-01-19

    The present invention is directed to a method and apparatus for making a population of dense, closely size-controlled microspheres by sol-gel procedures wherein said microspheres are characterized by a significant percentage of said population being within a predetermined, relatively narrow size range. This is accomplished by subjecting aqueous dispersions of a sol, within a water-immiscible organic liquid to a turbulent flow. Microsphere populations thus provided are useful in vibratory-packed processes for nuclear fuels to be irradiated in LWR- and FBR-type nuclear reactors.

  16. Waste Tank Size Determination for the Hanford River Protection Project Cold Test, Training, and Mockup Facility

    SciTech Connect (OSTI)

    Onishi, Yasuo; Wells, Beric E.; Kuhn, William L.

    2001-03-30

    The objective of the study was to determine the minimum tank size for the Cold Test Facility process testing of Hanford tank waste. This facility would support retrieval of waste in 75-ft-diameter DSTs with mixer pumps and SSTs with fluidic mixers. The cold test model will use full-scale mixer pumps, transfer pumps, and equipment with simulated waste. The study evaluated the acceptability of data for a range of tank diameters and depths and included identifying how the test data would be extrapolated to predict results for a full-size tank.

  17. Increased CPC batch size study for Tank 42 sludge in the Defense Waste Processing Facility

    SciTech Connect (OSTI)

    Daniel, W.E.

    2000-01-06

    A series of experiments have been completed at TNX for the sludge-only REDOX adjusted flowsheet using Tank 42 sludge simulant in response to the Technical Task Request HLW/DWPT/TTR-980013 to increase CPC batch sizes. By increasing the initial SRAT batch size, a melter feed batch at greater waste solids concentration can be prepared and thus increase melter output per batch by about one canister. The increased throughput would allow DWPF to dispose of more waste in a given time period thus shortening the overall campaign.

  18. Repository size for deep geological disposal of partitioning and transmutation high level waste

    SciTech Connect (OSTI)

    Nishihara, Kenji; Nakayama, Shinichi; Oigawa, Hiroyuki

    2007-07-01

    In order to reveal the impact of the partitioning and transmutation (PT) technology on the geological disposal, we investigated the production and disposal of the radioactive wastes from the PT facilities including the dry reprocessing for the spent fuel from accelerator-driven system. After classifying the PT wastes according to the heat generations, the emplacement configurations in the repository were assumed for each group based on the several disposal concepts proposed for the conventional glass waste form. Then, the sizes of the repositories represented by the vault length, emplacement area and excavation volume were estimated. The repository sizes were reduced by PT technology for all disposal concepts. (authors)

  19. Wake Flow Simulations for a Mid-Sized Rim Driven Wind Turbine

    SciTech Connect (OSTI)

    Rob O. Hovsapian; Various

    2014-06-01

    The onshore land where wind farms with conventional wind turbines can be places is limited by various factors including a requirement for relatively high wind speed for turbines' efficient operations. Where such a requirement cannot be met, mid-and small-sized turbines can be a solution. In the current paper simulations for near and for wakes behind a mid-sized Rim Driven Wind Turbine developed by Keuka Energy LLC is analyzed. The purposes of this study is to better understand the wake structure for more efficient wind farm planning. Simulations are conducted with the commercial CFD software STARCCM+

  20. Communication: Nucleation of water on ice nanograins: Size, charge, and quantum effects

    SciTech Connect (OSTI)

    Marciante, Mathieu; Calvo, Florent

    2015-05-07

    The sticking cross sections of water molecules on cold size-selected water clusters have been simulated using classical and quantum (path-integral) molecular dynamics trajectories under realistic conditions. The integrated cross sections for charged clusters show significant size effects with comparable trends as in experiments, as well as essentially no sign effect. Vibrational delocalization, although it contributes to enlarging the geometric cross sections, leads to a counter-intuitive decrease in the dynamical cross section obtained from the trajectories. These results are interpreted based on the apparent reduction in the effective interaction between the projectile and the target owing to zero-point effects.

  1. Impact of magnification and size bias on the weak lensing power spectrum

    Office of Scientific and Technical Information (OSTI)

    and peak statistics (Journal Article) | SciTech Connect Impact of magnification and size bias on the weak lensing power spectrum and peak statistics Citation Details In-Document Search Title: Impact of magnification and size bias on the weak lensing power spectrum and peak statistics Authors: Liu J. ; May M. ; Haiman, Z. ; Hui, L. ; Kratochvil, J.M. Publication Date: 2014-01-21 OSTI Identifier: 1132481 Report Number(s): BNL--104426-2014-JA KA3201020 DOE Contract Number: DE-AC02-98CH10886

  2. Influence of pH on the quantum-size-controlled photoelectrochemical etching

    Office of Scientific and Technical Information (OSTI)

    of epitaxial InGaN quantum dots (Journal Article) | SciTech Connect Influence of pH on the quantum-size-controlled photoelectrochemical etching of epitaxial InGaN quantum dots Citation Details In-Document Search This content will become publicly available on November 18, 2016 Title: Influence of pH on the quantum-size-controlled photoelectrochemical etching of epitaxial InGaN quantum dots Illumination by a narrow-band laser has been shown to enable photoelectrochemical (PEC) etching of InGaN

  3. A micrometer-size movable light emitting area in a resonant tunneling light emitting diode

    SciTech Connect (OSTI)

    Pettinari, G., E-mail: giorgio.pettinari@cnr.it [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); National Research Council (CNR), Institute for Photonics and Nanotechnologies (IFN-CNR), Via Cineto Romano 42, 00156 Roma (Italy); Balakrishnan, N.; Makarovsky, O.; Campion, R. P.; Patan, A. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)] [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom); Polimeni, A.; Capizzi, M. [CNISM-Dipartimento di Fisica, Sapienza Universit di Roma, P.le A. Moro 2, 00185 Roma (Italy)] [CNISM-Dipartimento di Fisica, Sapienza Universit di Roma, P.le A. Moro 2, 00185 Roma (Italy)

    2013-12-09

    We report on the fabrication of a micrometer-size movable light emitting area in a GaAs/AlAs quantum well resonant tunneling p-i-n diode. The spatial position of the micrometer-size light emitting area shifts linearly with increasing applied bias, up to 30??m for a bias increment of 0.2?V. Also, the simultaneous resonant tunneling injection of both electrons and holes into the quantum well states is achieved at specific positions of the diode, thus resulting in a tenfold increase of the electroluminescence intensity.

  4. What Is the Size of the Atomic Nucleus? | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    What Is the Size of the Atomic Nucleus? Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information » 02.29.16 What Is the Size of the Atomic Nucleus? The neutron skin of the nucleus

  5. Size-Dependent Specific Surface Area of Nanoporous Film Assembled by Core-Shell Iron Nanoclusters

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Antony, Jiji; Nutting, Joseph; Baer, Donald R.; Meyer, Daniel; Sharma, Amit; Qiang, You

    2006-01-01

    Nanoporous films of core-shell iron nanoclusters have improved possibilities for remediation, chemical reactivity rate, and environmentally favorable reaction pathways. Conventional methods often have difficulties to yield stable monodispersed core-shell nanoparticles. We produced core-shell nanoclusters by a cluster source that utilizes combination of Fe target sputtering along with gas aggregations in an inert atmosphere at 7 ∘ C . Sizes of core-shell iron-iron oxide nanoclusters are observed with transmission electron microscopy (TEM). The specific surface areas of the porous films obtained from Brunauer-Emmett-Teller (BET) process are size-dependent and compared with the calculated data.more »« less

  6. Fact #785: June 24, 2013 Many Cars Pollute Less Despite Increases in Size |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 5: June 24, 2013 Many Cars Pollute Less Despite Increases in Size Fact #785: June 24, 2013 Many Cars Pollute Less Despite Increases in Size As new vehicles become more efficient, the amount of carbon dioxide (CO2) they produce decreases. Shown below are several examples of model year (MY) 2012 cars that have decreased the amount of CO2 they produce (in grams per mile) despite the fact that they are larger (in interior volume) than they were ten years ago. Of the

  7. Effect of Engine-Out NOx Control Strategies on PM Size Distribution in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Diesel Engines Developed for 2010 | Department of Energy Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 Effect of Engine-Out NOx Control Strategies on PM Size Distribution in Heavy-Duty Diesel Engines Developed for 2010 A distinct relationship was found between engine-out and SCR-out PM distributions for single-mode testing. PDF icon deer08_ardanese.pdf More Documents & Publications Development of ADECS to Meet 2010

  8. Method of making metal oxide ceramic membranes with small pore sizes

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Xu, Qunyin (Madison, WI)

    1992-01-01

    A method for the production of metal oxide ceramic membranes is composed of very small pore size. The process is particularly useful in the creation of titanium and other transition metal oxide membranes. The method utilizes a sol-gel process in which the rate of particle formation is controlled by substituting a relatively large alcohol in the metal alkoxide and by limiting the available water. Stable, transparent metal oxide ceramic membranes are created having a narrow distribution of pore size, with the pore diameter being manipulable in the range of 5 to 40 Angstroms.

  9. 5 Super-Sized Solar Projects Transforming the Clean Energy Landscape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Super-Sized Solar Projects Transforming the Clean Energy Landscape 5 Super-Sized Solar Projects Transforming the Clean Energy Landscape April 8, 2013 - 4:00pm Addthis The California Valley Solar Ranch has a capacity of 250 MW -- enough energy to power the equivalent of every home in San Luis Obispo County. | Photo courtesy of SunPower. The California Valley Solar Ranch has a capacity of 250 MW -- enough energy to power the equivalent of every home in San Luis Obispo

  10. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  11. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  12. Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells for Supermarkets: Cleaner Energy with Fuel Cell Combined Heat and Power Systems ... U.S. Department of Energy Webinar: Fuel Cells for Supermarkets, April 4, 2011. PDF icon ...

  13. YAP/TAZ enhance mammalian embryonic neural stem cell characteristics in a Tead-dependent manner

    SciTech Connect (OSTI)

    Han, Dasol; Byun, Sung-Hyun; Park, Soojeong; Kim, Juwan; Kim, Inhee; Ha, Soobong; Kwon, Mookwang; Yoon, Keejung

    2015-02-27

    Mammalian brain development is regulated by multiple signaling pathways controlling cell proliferation, migration and differentiation. Here we show that YAP/TAZ enhance embryonic neural stem cell characteristics in a cell autonomous fashion using diverse experimental approaches. Introduction of retroviral vectors expressing YAP or TAZ into the mouse embryonic brain induced cell localization in the ventricular zone (VZ), which is the embryonic neural stem cell niche. This change in cell distribution in the cortical layer is due to the increased stemness of infected cells; YAP-expressing cells were colabeled with Sox2, a neural stem cell marker, and YAP/TAZ increased the frequency and size of neurospheres, indicating enhanced self-renewal- and proliferative ability of neural stem cells. These effects appear to be TEA domain family transcription factor (Tead)–dependent; a Tead binding-defective YAP mutant lost the ability to promote neural stem cell characteristics. Consistently, in utero gene transfer of a constitutively active form of Tead2 (Tead2-VP16) recapitulated all the features of YAP/TAZ overexpression, and dominant negative Tead2-EnR resulted in marked cell exit from the VZ toward outer cortical layers. Taken together, these results indicate that the Tead-dependent YAP/TAZ signaling pathway plays important roles in neural stem cell maintenance by enhancing stemness of neural stem cells during mammalian brain development. - Highlights: • Roles of YAP and Tead in vivo during mammalian brain development are clarified. • Expression of YAP promotes embryonic neural stem cell characteristics in vivo in a cell autonomous fashion. • Enhancement of neural stem cell characteristics by YAP depends on Tead. • Transcriptionally active form of Tead alone can recapitulate the effects of YAP. • Transcriptionally repressive form of Tead severely reduces stem cell characteristics.

  14. NREL: Hydrogen and Fuel Cells Research - Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cells Photo of scientific equipment in a laboratory setting. NREL scientist applies catalyst layer to a fuel cell through a spray process that delivers a more even distribution of material, improving performance. Photo by Dennis Schroeder, NREL What is a fuel cell? A single fuel cell consists of an electrolyte sandwiched between two electrodes. Bipolar plates on either side of the cell help distribute gases and serve as current collectors. Depending on the application, a fuel cell stack may

  15. NREL: Hydrogen and Fuel Cells Research - Early Fuel Cell Market

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Demonstrations Early Fuel Cell Market Demonstrations Photo of fuel cell backup power system in outdoor setting. Photo of fuel cell forklifts in warehouse setting. Fuel cell backup power systems offer longer continuous runtimes and greater durability than traditional batteries in harsh outdoor environments. For specialty vehicles such as forklifts, fuel cells can be a cost-competitive alternative to traditional lead-acid batteries. Learn More Subscribe to the biannual Fuel Cell and Hydrogen

  16. NREL: Hydrogen and Fuel Cells Research - Fuel Cell Technology Status

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis Fuel Cell Technology Status Analysis Get Involved Fuel cell developers interested in collaborating with NREL on fuel cell technology status analysis should send an email to NREL's Technology Validation Team at techval@nrel.gov. NREL's analysis of fuel cell technology provides objective and credible information about new fuel cell technologies with a focus on performance, durability, and price. As demand for fuel cells grows, U.S. manufacturers are developing these technologies for a

  17. Bipolar fuel cell

    DOE Patents [OSTI]

    McElroy, James F. (Suffield, CT)

    1989-01-01

    The present invention discloses an improved fuel cell utilizing an ion transporting membrane having a catalytic anode and a catalytic cathode bonded to opposite sides of the membrane, a wet-proofed carbon sheet in contact with the cathode surface opposite that bonded to the membrane and a bipolar separator positioned in electrical contact with the carbon sheet and the anode of the adjacent fuel cell. Said bipolar separator and carbon sheet forming an oxidant flowpath, wherein the improvement comprises an electrically conductive screen between and in contact with the wet-proofed carbon sheet and the bipolar separator improving the product water removal system of the fuel cell.

  18. Efficiency considerations for polycrystalline GaAs thin-film solar cells

    SciTech Connect (OSTI)

    Yamaguchi, M.; Itoh, Y.

    1986-07-01

    The effect of grain boundaries upon the efficiency of polycrystalline GaAs thin-film solar cells is analyzed. Solar-cell properties are calculated on a simple model where grain boundaries act as recombination centers to reduce the minority-carrier diffusion length in the solar cell's active layer and increase the space-charge layer recombination current. An effective diffusion length is expressed in terms of grain size, allowing the calculation of short-circuit current density and open-circuit voltage. Excellent agreement is obtained between theory and experiment. The fabrication of thin-film GaAs solar cells with an efficiency greater than 18% appears to be possible if the grain size in the thin-film GaAs layer with thickness of 3 ..mu..m is larger than 1000 ..mu..m.

  19. DOE Hydrogen & Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    t t 1 | Fuel Cell Technologies Program eere.energy.gov Fuel Cell Technologies Program DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U S D f E Overview U.S....

  20. Air Liquide - Biogas & Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    and the environment PT Loma WWTP, Biogas to Fuel Cell Power BioFuels Energy Biogas to BioMethane to 4.5 MW Fuel Cell Power 3 FCE Fuel Cells 2 via directed...

  1. Solar heating and cooling of residential buildings: sizing, installation and operation of systems. 1980 edition

    SciTech Connect (OSTI)

    1980-09-01

    This manual was prepared as a text for a training course on solar heating and cooling of residential buildings. The course and text are directed toward sizing, installation, operation, and maintenance of solar systems for space heating and hot water supply, and solar cooling is treated only briefly. (MHR)

  2. Characteristics and sources of intermediate size particles in recovery boilers : final project report.

    SciTech Connect (OSTI)

    Baxter, Larry L.; Shaddix, Christopher R.; Verrill, Christopher L.; Wessel, Richard A.

    2005-02-01

    As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

  3. Subnanometer and nanometer catalysts, method for preparing size-selected catalysts

    DOE Patents [OSTI]

    Vajda, Stefan; Pellin, Michael J.; Elam, Jeffrey W.; Marshall, Christopher L.; Winans, Randall A.; Meiwes-Broer, Karl-Heinz

    2012-03-27

    Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

  4. Subnanometer and nanometer catalysts, method for preparing size-selected catalysts

    DOE Patents [OSTI]

    Vajda, Stefan , Pellin, Michael J.; Elam, Jeffrey W.; Marshall, Christopher L.; Winans, Randall A.; Meiwes-Broer, Karl-Heinz

    2012-04-03

    Highly uniform cluster based nanocatalysts supported on technologically relevant supports were synthesized for reactions of top industrial relevance. The Pt-cluster based catalysts outperformed the very best reported ODHP catalyst in both activity (by up to two orders of magnitude higher turn-over frequencies) and in selectivity. The results clearly demonstrate that highly dispersed ultra-small Pt clusters precisely localized on high-surface area supports can lead to affordable new catalysts for highly efficient and economic propene production, including considerably simplified separation of the final product. The combined GISAXS-mass spectrometry provides an excellent tool to monitor the evolution of size and shape of nanocatalyst at action under realistic conditions. Also provided are sub-nanometer gold and sub-nanometer to few nm size-selected silver catalysts which possess size dependent tunable catalytic properties in the epoxidation of alkenes. Invented size-selected cluster deposition provides a unique tool to tune material properties by atom-by-atom fashion, which can be stabilized by protective overcoats.

  5. Magnetic nanoparticles for power absorption: Optimizing size, shape and magnetic properties

    SciTech Connect (OSTI)

    Gonzalez-Fernandez, M.A.; Torres, T.E.; Andres-Verges, M.; Costo, R.; Presa, P. de la; Serna, C.J.; Morales, M.P.; Marquina, C.; Ibarra, M.R.; Goya, G.F.

    2009-10-15

    We present a study on the magnetic properties of naked and silica-coated Fe{sub 3}O{sub 4} nanoparticles with sizes between 5 and 110 nm. Their efficiency as heating agents was assessed through specific power absorption (SPA) measurements as a function of particle size and shape. The results show a strong dependence of the SPA with the particle size, with a maximum around 30 nm, as expected for a Neel relaxation mechanism in single-domain particles. The SiO{sub 2} shell thickness was found to play an important role in the SPA mechanism by hindering the heat outflow, thus decreasing the heating efficiency. It is concluded that a compromise between good heating efficiency and surface functionality for biomedical purposes can be attained by making the SiO{sub 2} functional coating as thin as possible. - Graphical Abstract: The magnetic properties of Fe{sub 3}O{sub 4} nanoparticles from 5 to 110 nm are presented, and their efficiency as heating agents discussed as a function of particle size, shape and surface functionalization.

  6. Estimated size and performance of a natural gas fired duplex Stirling for domestic refrigeration applications

    SciTech Connect (OSTI)

    Berchowitz, D.M. ); Shonder, J. )

    1991-01-01

    Calibrated calculations are used to size an integrated Stirling cooler and engine (Duplex configuration). Fuel for the engine is natural gas and the working fluid is helium. The potential exists for long life and low noise. Performance is shown to be very competitive when compared to standard vapor compression systems. 10 refs., 8 figs., 1 tab.

  7. Small- and Medium-Sized Commercial Building Monitoring and Controls Needs: A Scoping Study

    SciTech Connect (OSTI)

    Katipamula, Srinivas; Underhill, Ronald M.; Goddard, James K.; Taasevigen, Danny J.; Piette, M. A.; Granderson, J.; Brown, Rich E.; Lanzisera, Steven M.; Kuruganti, T.

    2012-10-31

    Buildings consume over 40% of the total energy consumption in the U.S. A significant portion of the energy consumed in buildings is wasted because of the lack of controls or the inability to use existing building automation systems (BASs) properly. Much of the waste occurs because of our inability to manage and controls buildings efficiently. Over 90% of the buildings are either small-size (<5,000 sf) or medium-size (between 5,000 sf and 50,000 sf); these buildings currently do not use BASs to monitor and control their building systems from a central location. According to Commercial Building Energy Consumption Survey (CBECS), about 10% of the buildings in the U.S. use BASs or central controls to manage their building system operations. Buildings that use BASs are typically large (>100,000 sf). Lawrence Berkeley National Laboratory (LBNL), Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) were asked by the U.S. Department of Energys (DOEs) Building Technologies Program (BTP) to identify monitoring and control needs for small- and medium-sized commercial buildings and recommend possible solutions. This study documents the needs and solutions for small- and medium-sized buildings.

  8. Control of both particle and pore size in nanoporous palladium alloy powders

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jones, Christopher G.; Cappillino, Patrick J.; Stavila, Vitalie; Robinson, David B.

    2014-07-15

    Energy storage materials often involve chemical reactions with bulk solids. Porosity within the solids can enhance reaction rates. The porosity can be either within or between individual particles of the material. Greater control of the size and uniformity of both types of pore should lead to enhancements of charging and discharging rates in energy storage systems. Furthermore, to control both particle and pore size in nanoporous palladium (Pd)-based hydrogen storage materials, first we created uniformly sized copper particles of about 1 μm diameter by the reduction of copper sulfate with ascorbic acid. In turn, these were used as reducing agentsmore » for tetrachloropalladate in the presence of a block copolymer surfactant. The copper reductant particles are geometrically self-limiting, so the resulting Pd particles are of similar size. The surfactant induces formation of 10 nm-scale pores within the particles. Some residual copper is alloyed with the Pd, reducing hydrogen storage capacity; use of a more reactive Pd salt can mitigate this. The reaction is conveniently performed in gram-scale batches.« less

  9. Control of both particle and pore size in nanoporous palladium alloy powders

    SciTech Connect (OSTI)

    Jones, Christopher G.; Cappillino, Patrick J.; Stavila, Vitalie; Robinson, David B.

    2014-07-15

    Energy storage materials often involve chemical reactions with bulk solids. Porosity within the solids can enhance reaction rates. The porosity can be either within or between individual particles of the material. Greater control of the size and uniformity of both types of pore should lead to enhancements of charging and discharging rates in energy storage systems. Furthermore, to control both particle and pore size in nanoporous palladium (Pd)-based hydrogen storage materials, first we created uniformly sized copper particles of about 1 ?m diameter by the reduction of copper sulfate with ascorbic acid. In turn, these were used as reducing agents for tetrachloropalladate in the presence of a block copolymer surfactant. The copper reductant particles are geometrically self-limiting, so the resulting Pd particles are of similar size. The surfactant induces formation of 10 nm-scale pores within the particles. Some residual copper is alloyed with the Pd, reducing hydrogen storage capacity; use of a more reactive Pd salt can mitigate this. The reaction is conveniently performed in gram-scale batches.

  10. Effect of wood chip size on update gasifier-combustor operation

    SciTech Connect (OSTI)

    Payne, F.A.; Dunlap, J.L.; Caussanel, P.

    1984-01-01

    Three wood chip sizes were tested in a 0.3 GJ/h updraft gasifier-combustor. Thermal output did not vary significantly between wood chips. Pressure and temperature profiles were measured in the gasifier bed. Channeling occurred with the small wood chips. Efficiency of the combustor was determined by a mass and energy balance and an enthalpy technique.

  11. An analytical and computational study of combined rate and size effects on material properties.

    SciTech Connect (OSTI)

    Fang, Huei Eliot; Chen, Zhen; Shen, Luming University of Missouri-Columbia, Columbia, MO); Gan, Yong

    2005-05-01

    The recent interests in developing multiscale model-based simulation procedures have brought about the challenging tasks of bridging different spatial and temporal scales within a unified framework. However, the research focus has been on the scale effect in the spatial domain with the loading rate being assumed to be quasi-static. Although material properties are rate-dependent in nature, little has been done in understanding combined loading rate and specimen size effects on the material properties at different scales. In addition, the length and time scales that can be probed by the molecular level simulations are still fairly limited due to the limitation of computational capability. Based on the experimental and computational capabilities available, therefore, an attempt is made in this report to formulate a hyper-surface in both spatial and temporal domains to predict combined size and rate effects on the mechanical properties of engineering materials. To demonstrate the features of the proposed hyper-surface, tungsten specimens of various sizes under various loading rates are considered with a focus on the uniaxial loading path. The mechanical responses of tungsten specimens under other loading paths are also explored to better understand the size effect. It appears from the preliminary results that the proposed procedure might provide an effective means to bridge different spatial and temporal scales in a unified multiscale modeling framework, and facilitate the application of nanoscale research results to engineering practice.

  12. Estimating payload internal temperatures and radiator size for multimegawatt space platforms

    SciTech Connect (OSTI)

    Dobranich, D.

    1987-08-01

    A conceptual space platform consists of a payload, a power conditioning unit (PCU), and two radiators: the main radiator and a secondary radiator. A computer program was written to determine the required size of the two radiators and the temperatures of the PCU and payload for a given platform power level. An iterative approach is necessary because the required size of the main radiator depends on the size of the secondary radiator and vice versa. Also, the temperatures of the payload and PCU depend on the size of the radiators. The program user can subdivide the two radiators into any number of nodes to increase the accuracy of the radiant heat transfer solution. The use of more nodes also allows better prediction of the nonlinear temperature drop that occurs across the radiators as the working fluid deposits the platform's waste heat in the radiator. View factor expressions are automatically calculated for different choices of the number of nodes. The user can also select different separation distances between the various platform structures. A model is included to couple the radiant and conduction heat transfer that occurs between the payload and its meteoroid shell and between the PCU and its shell. Also, the program allows the use of a refrigerator to cool the payload. If a refrigerator is used, the program determines the amount of additional thermal power needed to run the refrigerator. The results of parametric calculations are included to demonstrate the use of the program.

  13. Probing the size and environment induced phase transformation in CdSe quantum dots

    SciTech Connect (OSTI)

    Karakoti, Ajay S.; Sanghavi, Shail P.; Nachimuthu, Ponnusamy; Yang, Ping; Thevuthasan, Suntharampillai

    2011-11-17

    The structural and electronic properties of CdSe quantum dots in toluene and drop-casted on Si wafer were investigated by in-situ micro X-ray diffraction, X-ray photoelectron spectroscopy and UV-Vis absorption and emission spectroscopy. The in-situ micro diffraction data show that the CdSe quantum dots capped with TOPO or hexadecylamine (HDA) in toluene exhibit predominantly wurtzite crystal structure, which undergoes a phase transformation to zinc blende crystal structure following drop casting on Si and this phase transition increases with decreasing the size of the CdSe quantum dots. Decreasing the size of quantum dots also increases the Se vacancies that facilitate the phase transformation. The X-ray photoelectron spectra show a systematic increase in the core level binding energies of Cd 3d and Se 3d, the band gap and the Cd/Se ratio as the size of the quantum dots decreases from 6.6nm to 2.1nm. This is attributed to the quantum confinement of CdSe crystallites by the capping ligands in toluene which increases with decreasing the size of the quantum dots. However, drop-casting quantum dots on Si alter the density and arrangement of capping ligands and solvent molecules on the quantum dots which causes significant phase transformation.

  14. An instrument to measure extended particle size and velocity ranges in multiphase flows

    SciTech Connect (OSTI)

    Wood, C.P.; Hess, C.F.

    1995-12-31

    This paper describes a miniaturized particle sizing velocimeter developed and built by MetroLaser to measure the spatial and temporal distributions of particle size and velocity. The instrument is the first of its kind to utilize the pulse displacement technique (PDT) to measure particle size. PDT is based on the detection of scattered refraction and reflection pulses which sweep past a detector at different times as a particle traverses a narrow laser sheet. In conjunction with Mie scattering and a time-of-fight velocity measuring technique, the instrument provides detailed distributions of particle size from 2 {micro}m to 6,000 {micro}m in two optical configurations, and particle velocity from 0.5 m/s to 150 m/s. This paper summarizes the theoretical foundation of PDT which allows the calculation of particle diameter from various optical parameters such as refractive index and collection angle. An overview of the instrument is presented, followed by a brief description of the miniaturized optical probe. The processing of data is described and, lastly, the results of experimental studies are presented which verify the accuracy and versatility of the instrument.

  15. Effects of Compressive Force, Particle Size and Moisture Content on Mechanical Properties of Biomass Grinds

    SciTech Connect (OSTI)

    Mani, Sudhagar; Tabil, Lope Jr.; Sokhansanj, Shahabaddine

    2006-03-01

    Chemical composition, moisture content, bulk and particle densities, and geometric mean particle size were determined to characterize grinds from wheat and barley straws, corn stover and switchgrass. The biomass grinds were compressed for five levels of compressive forces (1000, 2000, 3000, 4000, 4400 N) and three levels of particle sizes (3.2, 1.6 and 0.8 mm) at two levels of moisture contents (12% and 15% (wb) to establish the compression and relaxation data. Corn stover grind produced the highest compact density at low pressure during compression. Compressive force, particle size and moisture content of grinds significantly affected the compact density of barley straw, corn stover and switchgrass grinds. However, different particle sizes of wheat straw grind did not produce any significant difference on compact density. Barley straw grind had the highest asymptotic modulus among all other biomass grinds indicating that compact from barley straw grind were more rigid than those of other compacts. Asymptotic modulus increased with an increase in maximum compressive pressure. The trend of increase in asymptotic modulus (EA) with the maximum compressive pressure ( 0) was fitted to a second order polynomial equation. Keywords: Biomass grinds, chemical composition, compact density and asymptotic modulus

  16. Size and spacial distribution of micropores in SBA-15 using CM-SANS

    SciTech Connect (OSTI)

    Pollock, Rachel A; Walsh, Brenna R; Fry, Jason A; Ghampson, Tyrone; Centikol, Ozgul; Melnichenko, Yuri B; Kaiser, Helmut; Pynn, Roger; Frederick, Brian G

    2011-01-01

    Diffraction intensity analysis of small-angle neutron scattering measurements of dry SBA-15 have been combined with nonlocal density functional theory (NLDFT) analysis of nitrogen desorption isotherms to characterize the micropore, secondary mesopore, and primary mesopore structure. The radial dependence of the scattering length density, which is sensitive to isolated surface hydroxyls, can only be modeled if the NLDFT pore size distribution is distributed relatively uniformly throughout the silica framework, not localized in a 'corona' around the primary mesopores. Contrast matching-small angle neutron scattering (CM-SANS) measurements, using water, decane, tributylamine, cyclohexane, and isooctane as direct probes of the size of micropores indicate that the smallest pores in SBA-15 have diameter between 5.7 and 6.2 {angstrom}. Correlation of the minimum pore size with the onset of the micropore size distribution provides direct evidence that the shape of the smallest micropores is cylinderlike, which is consistent with their being due to unraveling of the polymer template.

  17. Business Continuity Planning Resources for Small- and Medium-Sized Businesses

    SciTech Connect (OSTI)

    Judd, Kathleen S.; Lesperance, Ann M.

    2010-05-14

    This document/memo summarizes existing resources and guidance on business continuity planning for small- to medium-sized businesses. DTRA will share this information with large commercial businesses who identified the need to help their suppliers and other key collaborators prepare business continuity plans in order to speed recovery from a wide-area bioterrorism incident.

  18. Deformation Behavior of Sub-micron and Micron Sized Alumina Particles in Compression.

    SciTech Connect (OSTI)

    Sarobol, Pylin; Chandross, Michael E.; Carroll, Jay; Mook, William; Boyce, Brad; Kotula, Paul G.; McKenzie, Bonnie B.; Bufford, Daniel Charles; Hall, Aaron Christopher.

    2014-09-01

    The ability to integrate ceramics with other materials has been limited due to high temperature (>800degC) ceramic processing. Recently, researchers demonstrated a novel process , aerosol deposition (AD), to fabricate ceramic films at room temperature (RT). In this process, sub - micro n sized ceramic particles are accelerated by pressurized gas, impacted on the substrate, plastically deformed, and form a dense film under vacuum. This AD process eliminates high temperature processing thereby enabling new coatings and device integration, in which ceramics can be deposited on metals, plastics, and glass. However, k nowledge in fundamental mechanisms for ceramic particle s to deform and form a dense ceramic film is still needed and is essential in advancing this novel RT technology. In this wo rk, a combination of experimentation and atomistic simulation was used to determine the deformation behavior of sub - micron sized ceramic particle s ; this is the first fundamental step needed to explain coating formation in the AD process . High purity, singl e crystal, alpha alumina particles with nominal size s of 0.3 um and 3.0 um were examined. Particle characterization, using transmission electron microscopy (TEM ), showed that the 0.3 u m particles were relatively defect - free single crystals whereas 3.0 u m p articles were highly defective single crystals or particles contained low angle grain boundaries. Sub - micron sized Al 2 O 3 particles exhibited ductile failure in compression. In situ compression experiments showed 0.3um particles deformed plastically, fractured, and became polycrystalline. Moreover, dislocation activit y was observed within the se particles during compression . These sub - micron sized Al 2 O 3 particles exhibited large accum ulated strain (2 - 3 times those of micron - sized particles) before first fracture. I n agreement with the findings from experimentation , a tomistic simulation s of nano - Al 2 O 3 particles showed dislocation slip and significant plastic deformation during compressi on . On the other hand, the micron sized Al 2 O 3 particles exhibited brittle f racture in compression. In situ compression experiments showed 3um Al 2 O 3 particles fractured into pieces without observable plastic deformation in compression. Particle deformation behaviors will be used to inform Al 2 O 3 coating deposition parameters and particle - particle bonding in the consolidated Al 2 O 3 coatings.

  19. Fuel Cell Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    IEA HIA Hydrogen Safety Stakeholder Workshop Bethesda, Maryland Fuel Cell Technologies Program Overview Dr. Sunita Satyapal U.S. Department of Energy Fuel Cell Technologies Program Program Manager 10/2/2012 2 | Fuel Cell Technologies Program eere.energy.gov Overview Fuel Cells - An Emerging Global Industry Clean Energy Patent Growth Index [1] shows that fuel cell patents lead in the clean energy field with over 950 fuel cell patents issued in 2011. * Nearly double the second place holder, solar,

  20. Uncertainty in Modeling Dust Mass Balance and Radiative Forcing from Size Parameterization

    SciTech Connect (OSTI)

    Zhao, Chun; Chen, Siyu; Leung, Lai-Yung R.; Qian, Yun; Kok, Jasper; Zaveri, Rahul A.; Huang, J.

    2013-11-05

    This study examines the uncertainties in simulating mass balance and radiative forcing of mineral dust due to biases in the aerosol size parameterization. Simulations are conducted quasi-globally (180oW-180oE and 60oS-70oN) using the WRF24 Chem model with three different approaches to represent aerosol size distribution (8-bin, 4-bin, and 3-mode). The biases in the 3-mode or 4-bin approaches against a relatively more accurate 8-bin approach in simulating dust mass balance and radiative forcing are identified. Compared to the 8-bin approach, the 4-bin approach simulates similar but coarser size distributions of dust particles in the atmosphere, while the 3-mode pproach retains more fine dust particles but fewer coarse dust particles due to its prescribed og of each mode. Although the 3-mode approach yields up to 10 days longer dust mass lifetime over the remote oceanic regions than the 8-bin approach, the three size approaches produce similar dust mass lifetime (3.2 days to 3.5 days) on quasi-global average, reflecting that the global dust mass lifetime is mainly determined by the dust mass lifetime near the dust source regions. With the same global dust emission (~6000 Tg yr-1), the 8-bin approach produces a dust mass loading of 39 Tg, while the 4-bin and 3-mode approaches produce 3% (40.2 Tg) and 25% (49.1 Tg) higher dust mass loading, respectively. The difference in dust mass loading between the 8-bin approach and the 4-bin or 3-mode approaches has large spatial variations, with generally smaller relative difference (<10%) near the surface over the dust source regions. The three size approaches also result in significantly different dry and wet deposition fluxes and number concentrations of dust. The difference in dust aerosol optical depth (AOD) (a factor of 3) among the three size approaches is much larger than their difference (25%) in dust mass loading. Compared to the 8-bin approach, the 4-bin approach yields stronger dust absorptivity, while the 3-mode approach yields weaker dust absorptivity. Overall, on quasi-global average, the three size parameterizations result in a significant difference of a factor of 2~3 in dust surface cooling (-1.02~-2.87 W m-2) and atmospheric warming (0.39~0.96 W m-2) and in a tremendous difference of a factor of ~10 in dust TOA cooling (-0.24~-2.20 W m-2). An uncertainty of a factor of 2 is quantified in dust emission estimation due to the different size parameterizations. This study also highlights the uncertainties in modeling dust mass and number loading, deposition fluxes, and radiative forcing resulting from different size parameterizations, and motivates further investigation of the impact of size parameterizations on modeling dust impacts on air quality, climate, and ecosystem.

  1. Solar cell array interconnects

    DOE Patents [OSTI]

    Carey, P.G.; Thompson, J.B.; Colella, N.J.; Williams, K.A.

    1995-11-14

    Electrical interconnects are disclosed for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb-Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb-Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value. 4 figs.

  2. Thin film photovoltaic cells

    DOE Patents [OSTI]

    Rothwarf, Allen (Philadelphia, PA)

    1981-01-01

    A solar cell has as its transparent electrical contact a grid made from a non-noble metal by providing a layer of copper oxide between the transparent electrical contact and the absorber-generator.

  3. Fuel cell water transport

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E. (Los Alamos, NM); Hedstrom, James C. (Los Alamos, NM)

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  4. Hydrogen Fuel Cell Demonstration ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Brothers, Ltd., at their facility in the Port of Honolulu. The pilot hydrogen fuel cell unit will be used in place of a diesel generator currently used to provide power for...

  5. Solar cell array interconnects

    DOE Patents [OSTI]

    Carey, Paul G. (Mountain View, CA); Thompson, Jesse B. (Brentwood, CA); Colella, Nicolas J. (Livermore, CA); Williams, Kenneth A. (Livermore, CA)

    1995-01-01

    Electrical interconnects for solar cells or other electronic components using a silver-silicone paste or a lead-tin (Pb-Sn) no-clean fluxless solder cream, whereby the high breakage of thin (<6 mil thick) solar cells using conventional solder interconnect is eliminated. The interconnects of this invention employs copper strips which are secured to the solar cells by a silver-silicone conductive paste which can be used at room temperature, or by a Pb-Sn solder cream which eliminates undesired residue on the active surfaces of the solar cells. Electrical testing using the interconnects of this invention has shown that no degradation of the interconnects developed under high current testing, while providing a very low contact resistance value.

  6. Photovoltaic solar cell

    DOE Patents [OSTI]

    Nielson, Gregory N; Cruz-Campa, Jose Luis; Okandan, Murat; Resnick, Paul J

    2014-05-20

    A photovoltaic solar cell for generating electricity from sunlight is disclosed. The photovoltaic solar cell comprises a plurality of spaced-apart point contact junctions formed in a semiconductor body to receive the sunlight and generate the electricity therefrom, the plurality of spaced-apart point contact junctions having a first plurality of regions having a first doping type and a second plurality of regions having a second doping type. In addition, the photovoltaic solar cell comprises a first electrical contact electrically connected to each of the first plurality of regions and a second electrical contact electrically connected to each of the second plurality of regions, as well as a passivation layer covering major surfaces and sidewalls of the photovoltaic solar cell.

  7. Photovoltaic solar cell

    DOE Patents [OSTI]

    Nielson, Gregory N; Okandan, Murat; Cruz-Campa, Jose Luis; Resnick, Paul J

    2013-11-26

    A photovoltaic solar cell for generating electricity from sunlight is disclosed. The photovoltaic solar cell comprises a plurality of spaced-apart point contact junctions formed in a semiconductor body to receive the sunlight and generate the electicity therefrom, the plurality of spaced-apart point contact junctions having a first plurality of regions having a first doping type and a second plurality of regions having a second doping type. In addition, the photovoltaic solar cell comprises a first electrical contact electrically connected to each of the first plurality of regions and a second electrical contact electrically connected to each of the second plurality of regions, as well as a passivation layer covering major surfaces and sidewalls of the photovoltaic solar cell.

  8. Reversible Fuel Cells Workshop

    Broader source: Energy.gov [DOE]

    The National Renewable Energy Laboratory hosted a workshop addressing the current state-of-the-art of reversible fuel cells that use hydrogen/air or hydrogen/oxygen on April 19, 2011, at the...

  9. Synthesis of CdSe quantum dots for quantum dot sensitized solar cell

    SciTech Connect (OSTI)

    Singh, Neetu Kapoor, Avinashi; Kumar, Vinod; Mehra, R. M.

    2014-04-24

    CdSe Quantum Dots (QDs) of size 0.85 nm were synthesized using chemical route. ZnO based Quantum Dot Sensitized Solar Cell (QDSSC) was fabricated using CdSe QDs as sensitizer. The Pre-synthesized QDs were found to be successfully adsorbed on front ZnO electrode and had potential to replace organic dyes in Dye Sensitized Solar Cells (DSSCs). The efficiency of QDSSC was obtained to be 2.06 % at AM 1.5.

  10. Composition and grain size effects on the structural and mechanical properties of CuZr nanoglasses

    SciTech Connect (OSTI)

    Adibi, Sara [Institute of High Performance Computing, A*STAR, 138632 Singapore (Singapore); Mechanical Engineering Department, National University of Singapore, 117576 Singapore (Singapore); Branicio, Paulo S., E-mail: branicio@ihpc.a-star.edu.sg; Zhang, Yong-Wei [Institute of High Performance Computing, A*STAR, 138632 Singapore (Singapore); Joshi, Shailendra P., E-mail: Shailendra@nus.edu.sg [Mechanical Engineering Department, National University of Singapore, 117576 Singapore (Singapore)

    2014-07-28

    Nanoglasses (NGs), metallic glasses (MGs) with a nanoscale grain structure, have the potential to considerably increase the ductility of traditional MGs while retaining their outstanding mechanical properties. We investigated the effects of composition on the structural and mechanical properties of CuZr NG films with grain sizes between 3 to 15?nm using molecular dynamics simulations. Results indicate a transition from localized shear banding to homogeneous superplastic flow with decreasing grain size, although the critical average grain size depends on composition: 5?nm for Cu{sub 36}Zr{sub 64} and 3?nm for Cu{sub 64}Zr{sub 36}. The flow stress of the superplastic NG at different compositions follows the trend of the yield stress of the parent MG, i.e., Cu{sub 36}Zr{sub 64} yield/flow stress: 2.54?GPa/1.29?GPa and Cu{sub 64}Zr{sub 36} yield/flow stress: 3.57?GPa /1.58?GPa. Structural analysis indicates that the differences in mechanical behavior as a function of composition are rooted at the distinct statistics of prominent atomic Voronoi polyhedra. The mechanical behavior of NGs is also affected by the grain boundary thickness and the fraction of atoms at interfaces for a given average grain size. The results suggest that the composition dependence of the mechanical behavior of NGs follows that of their parent MGs, e.g., a stronger MG will generate a stronger NG, while the intrinsic tendency for homogeneous deformation occurring at small grain size is not affected by composition.

  11. Size-dependent error of the density functional theory ionization potential in vacuum and solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sosa Vazquez, Xochitl A.; Isborn, Christine M.

    2015-12-22

    Density functional theory is often the method of choice for modeling the energetics of large molecules and including explicit solvation effects. It is preferable to use a method that treats systems of different sizes and with different amounts of explicit solvent on equal footing. However, recent work suggests that approximate density functional theory has a size-dependent error in the computation of the ionization potential. We here investigate the lack of size-intensivity of the ionization potential computed with approximate density functionals in vacuum and solution. We show that local and semi-local approximations to exchange do not yield a constant ionization potentialmore » for an increasing number of identical isolated molecules in vacuum. Instead, as the number of molecules increases, the total energy required to ionize the system decreases. Rather surprisingly, we find that this is still the case in solution, whether using a polarizable continuum model or with explicit solvent that breaks the degeneracy of each solute, and we find that explicit solvent in the calculation can exacerbate the size-dependent delocalization error. We demonstrate that increasing the amount of exact exchange changes the character of the polarization of the solvent molecules; for small amounts of exact exchange the solvent molecules contribute a fraction of their electron density to the ionized electron, but for larger amounts of exact exchange they properly polarize in response to the cationic solute. As a result, in vacuum and explicit solvent, the ionization potential can be made size-intensive by optimally tuning a long-range corrected hybrid functional.« less

  12. Larger sized wire arrays on 1.5 MA Z-pinch generator

    SciTech Connect (OSTI)

    Safronova, A. S. Kantsyrev, V. L. Weller, M. E. Shlyaptseva, V. V. Shrestha, I. K. Esaulov, A. A. Stafford, A.; Chuvatin, A. S.; Coverdale, C. A.; Jones, B.

    2014-12-15

    Experiments on the UNR Zebra generator with Load Current Multiplier (LCM) allow for implosions of larger sized wire array loads than at standard current of 1 MA. Advantages of larger sized planar wire array implosions include enhanced energy coupling to plasmas, better diagnostic access to observable plasma regions, and more complex geometries of the wire loads. The experiments with larger sized wire arrays were performed on 1.5 MA Zebra with LCM (the anode-cathode gap was 1 cm, which is half the gap used in the standard mode). In particular, larger sized multi-planar wire arrays had two outer wire planes from mid-atomic-number wires to create a global magnetic field (gmf) and plasma flow between them. A modified central plane with a few Al wires at the edges was put in the middle between outer planes to influence gmf and to create Al plasma flow in the perpendicular direction (to the outer arrays plasma flow). Such modified plane has different number of empty slots: it was increased from 6 up to 10, hence increasing the gap inside the middle plane from 4.9 to 7.7 mm, respectively. Such load configuration allows for more independent study of the flows of L-shell mid-atomic-number plasma (between the outer planes) and K-shell Al plasma (which first fills the gap between the edge wires along the middle plane) and their radiation in space and time. We demonstrate that such configuration produces higher linear radiation yield and electron temperatures as well as advantages of better diagnostics access to observable plasma regions and how the load geometry (size of the gap in the middle plane) influences K-shell Al radiation. In particular, K-shell Al radiation was delayed compared to L-shell mid-atomic-number radiation when the gap in the middle plane was large enough (when the number of empty slots was increased up to ten)

  13. Size-dependent error of the density functional theory ionization potential in vacuum and solution

    SciTech Connect (OSTI)

    Sosa Vazquez, Xochitl A.; Isborn, Christine M.

    2015-12-22

    Density functional theory is often the method of choice for modeling the energetics of large molecules and including explicit solvation effects. It is preferable to use a method that treats systems of different sizes and with different amounts of explicit solvent on equal footing. However, recent work suggests that approximate density functional theory has a size-dependent error in the computation of the ionization potential. We here investigate the lack of size-intensivity of the ionization potential computed with approximate density functionals in vacuum and solution. We show that local and semi-local approximations to exchange do not yield a constant ionization potential for an increasing number of identical isolated molecules in vacuum. Instead, as the number of molecules increases, the total energy required to ionize the system decreases. Rather surprisingly, we find that this is still the case in solution, whether using a polarizable continuum model or with explicit solvent that breaks the degeneracy of each solute, and we find that explicit solvent in the calculation can exacerbate the size-dependent delocalization error. We demonstrate that increasing the amount of exact exchange changes the character of the polarization of the solvent molecules; for small amounts of exact exchange the solvent molecules contribute a fraction of their electron density to the ionized electron, but for larger amounts of exact exchange they properly polarize in response to the cationic solute. As a result, in vacuum and explicit solvent, the ionization potential can be made size-intensive by optimally tuning a long-range corrected hybrid functional.

  14. Implications of access hole size on tank waste retrieval system design and cost

    SciTech Connect (OSTI)

    Babcock, S.M.; Kwon, D.S.; Burks, B.L.; Stoughton, R.S.; Evans, M.S.

    1994-05-01

    The DOE Environmental Restoration and Waste Management Robotics Technology Development Program has been investigating the application of robotics technology to the retrieval of waste from single-shell storage tanks for several years. The use of a large, ``long-reach`` manipulator to position and orient a variety of tools and other equipment has been recommended. The objective of this study is to determine the appropriate access hole size for the tank waste retrieval system installation. Previous reports on the impact of access hole size on manipulator performance are summarized. In addition, the practical limitation for access hole size based on structural limitations of the waste storage tanks, the state-of-the-art size limitations for the installation of new risers, the radiation safety implications of various access hole sizes, and overall system cost implications are considered. Basic conclusions include: (1) overall cost of remediation will; be dominated by the costs of the balance of plant and time required to perform the task rather than the cost of manipulator hardware or the cost of installing a riser, (2) the most desirable solution from a manipulator controls point of view is to make the manipulator as stiff as possible and have as high as possible a natural frequency, which implies a large access hole diameter, (3) beyond some diameter; simple, uniform cross-section elements become less advantageous from a weight standpoint and alternative structures should be considered, and (4) additional shielding and contamination control measures would be required for larger holes. Parametric studies summarized in this report considered 3,790,000 1 (1,000,000 gal) tanks, while initial applications are likely to be for 2,840,000 1 (750,000 gal) tanks. Therefore, the calculations should be somewhat conservative, recognizing the limitations of the specific conditions considered.

  15. Composite fuel cell membranes

    DOE Patents [OSTI]

    Plowman, Keith R. (Lake Jackson, TX); Rehg, Timothy J. (Lake Jackson, TX); Davis, Larry W. (West Columbia, TX); Carl, William P. (Marble Falls, TX); Cisar, Alan J. (Cypress, TX); Eastland, Charles S. (West Columbia, TX)

    1997-01-01

    A bilayer or trilayer composite ion exchange membrane suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.

  16. Composite fuel cell membranes

    DOE Patents [OSTI]

    Plowman, K.R.; Rehg, T.J.; Davis, L.W.; Carl, W.P.; Cisar, A.J.; Eastland, C.S.

    1997-08-05

    A bilayer or trilayer composite ion exchange membrane is described suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.

  17. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, D.F.; Suciu, D.F.; Harris, T.L.; Ingram, J.C.

    1993-04-06

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  18. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, W.H.; Payne, J.R.

    1982-09-14

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB[sub 2], for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints. 9 figs.

  19. Compliant fuel cell system

    DOE Patents [OSTI]

    Bourgeois, Richard Scott (Albany, NY); Gudlavalleti, Sauri (Albany, NY)

    2009-12-15

    A fuel cell assembly comprising at least one metallic component, at least one ceramic component and a structure disposed between the metallic component and the ceramic component. The structure is configured to have a lower stiffness compared to at least one of the metallic component and the ceramic component, to accommodate a difference in strain between the metallic component and the ceramic component of the fuel cell assembly.

  20. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Goodnow, Warren H. (Palo Alto, CA); Payne, John R. (Pleasanton, CA)

    1982-01-01

    The invention is directed to cathode modules comprised of refractory hard metal materials, such as TiB.sub.2, for an electrolytic cell for the reduction of alumina wherein the modules may be installed and replaced during operation of the cell and wherein the structure of the cathode modules is such that the refractory hard metal materials are not subjected to externally applied forces or rigid constraints.

  1. Fuel Cells at NASCAR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells at NASCAR Ned Stetson U.S. Department of Energy Fuel Cell Technologies Office Catherine Kummer - NASCAR Green Norm Bessette - Acumentrics Question and Answer * Please type your question into the question box hydrogenandfuelcells.energy.gov 3 Selected Milestone Accomplishments * 5 years of NASCAR Green with now most impactful sustainability platform in history of U.S. based on numbers; most impactful in sports * 75% of avid NASCAR fans are now aware of NASCAR green and believe the

  2. Fuel Cells in Telecommunications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cells Simply Powerful Fuel Cells in Telecommunications J. Blanchard December 2011 - ~ ReliOn Overview Markets Backup, grid supplement, and off grid power systems for critical communications infrastructure spanning telecom, transportation, government, utility, and OEM customers throughout the world. Products Purpose designed product portfolio of 175W to 2.5kW building blocks providing solutions up to 30kW for target markets. Broad range of hydrogen storage solutions supported by major

  3. Financing Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    organized by: ◦ US Department of Energy Fuel Cell Technologies Program ◦ Clean Energy States Alliance ◦ Technology Transition Corporation  Also briefing papers and materials for state policymakers and others on the Hydrogen and Fuel Cells Project page at www.cleanenergystates.org 2  A nonprofit coalition of state and sub-national clean energy funds and programs working together to develop and promote clean energy technologies and markets. www.cleanenergystates.org 3  For more

  4. Ice electrode electrolytic cell

    DOE Patents [OSTI]

    Glenn, David F. (Idaho Falls, ID); Suciu, Dan F. (Idaho Falls, ID); Harris, Taryl L. (Idaho Falls, ID); Ingram, Jani C. (Idaho Falls, ID)

    1993-01-01

    This invention relates to a method and apparatus for removing heavy metals from waste water, soils, or process streams by electrolytic cell means. The method includes cooling a cell cathode to form an ice layer over the cathode and then applying an electric current to deposit a layer of the heavy metal over the ice. The metal is then easily removed after melting the ice. In a second embodiment, the same ice-covered electrode can be employed to form powdered metals.

  5. Fuel Cell Technologies Office: Publications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell Technologies Office EERE Fuel Cell Technologies Office Share this resource Publications Advanced Search Browse by Topic Mail Requests Help Feature featured product...

  6. Hydrogen and Fuel Cell Activities

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Activities Mr. Pete Devlin U.S. Department of Energy Fuel Cell Technologies Program Market Transformation Manager Stationary Fuel Cell Applications First National Bank of Omaha...

  7. Fuel Cell Handbook (Seventh Edition)

    Office of Scientific and Technical Information (OSTI)

    ... In addition, because combustion is avoided, fuel cells produce power with minimal ... The only liquid in this fuel cell is water; thus, corrosion problems are minimal. ...

  8. Solar Cells Hellas SA | Open Energy Information

    Open Energy Info (EERE)

    Cells Hellas SA Jump to: navigation, search Name: Solar Cells Hellas SA Place: Athens, Greece Product: Greek manufacturer of PV wafers, cells and modules. References: Solar Cells...

  9. Fuel Cells Fact Sheet | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing hydrogen fuel cell technology. Fuel Cells More Documents & Publications Hydrogen and Fuel Cell...

  10. Fuel Cells Fact Sheet | Department of Energy

    Energy Savers [EERE]

    Cells Fact Sheet Fuel Cells Fact Sheet Fact sheet produced by the Fuel Cell Technologies Office describing fuel cell technologies. PDF icon Fuel Cells Fact Sheet More Documents & Publications Comparison of Fuel Cell Technologies: Fact Sheet Hydrogen and Fuel Cell Technologies Program: Fuel Cells Fact Sheet 2011 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program

  11. Fuel cell system

    DOE Patents [OSTI]

    Early, Jack (Perth Amboy, NJ); Kaufman, Arthur (West Orange, NJ); Stawsky, Alfred (Teaneck, NJ)

    1982-01-01

    A fuel cell system is comprised of a fuel cell module including sub-stacks of series-connected fuel cells, the sub-stacks being held together in a stacked arrangement with cold plates of a cooling means located between the sub-stacks to function as electrical terminals. The anode and cathode terminals of the sub-stacks are connected in parallel by means of the coolant manifolds which electrically connect selected cold plates. The system may comprise a plurality of the fuel cell modules connected in series. The sub-stacks are designed to provide a voltage output equivalent to the desired voltage demand of a low voltage, high current DC load such as an electrolytic cell to be driven by the fuel cell system. This arrangement in conjunction with switching means can be used to drive a DC electrical load with a total voltage output selected to match that of the load being driven. This arrangement eliminates the need for expensive voltage regulation equipment.

  12. MOLTEN CARBONATE FUEL CELL PRODUCT DESIGN IMPROVEMENT

    SciTech Connect (OSTI)

    H.C. Maru; M. Farooque

    2005-03-01

    The program was designed to advance the carbonate fuel cell technology from full-size proof-of-concept field test to the commercial design. DOE has been funding Direct FuelCell{reg_sign} (DFC{reg_sign}) development at FuelCell Energy, Inc. (FCE, formerly Energy Research Corporation) from an early state of development for stationary power plant applications. The current program efforts were focused on technology and system development, and cost reduction, leading to commercial design development and prototype system field trials. FCE, in Danbury, CT, is a world-recognized leader for the development and commercialization of high efficiency fuel cells that can generate clean electricity at power stations, or at distributed locations near the customers such as hospitals, schools, universities, hotels and other commercial and industrial applications. FCE has designed three different fuel cell power plant models (DFC300A, DFC1500 and DFC3000). FCE's power plants are based on its patented DFC{reg_sign} technology, where a hydrocarbon fuel is directly fed to the fuel cell and hydrogen is generated internally. These power plants offer significant advantages compared to the existing power generation technologies--higher fuel efficiency, significantly lower emissions, quieter operation, flexible siting and permitting requirements, scalability and potentially lower operating costs. Also, the exhaust heat by-product can be used for cogeneration applications such as high-pressure steam, district heating and air conditioning. Several sub-MW power plants based on the DFC design are currently operating in Europe, Japan and the US. Several one-megawatt power plant design was verified by operation on natural gas at FCE. This plant is currently installed at a customer site in King County, WA under another US government program and is currently in operation. Because hydrogen is generated directly within the fuel cell module from readily available fuels such as natural gas and waste water treatment gas, DFC power plants are ready today and do not require the creation of a hydrogen infrastructure. Product improvement progress made during the program period in the areas of technology, manufacturing processes, cost reduction and balance-of-plant equipment designs is discussed in this report.

  13. Final Report, Validation of Novel Planar Cell Design for MW-Scale SOFC Power Systems

    SciTech Connect (OSTI)

    Swartz, Dr Scott L.; Thrun, Dr Lora B.; Arkenberg, Mr Gene B.; Chenault, Ms Kellie M.

    2012-01-03

    This report describes the work completed by NexTech Materials, Ltd. during a three-year project to validate an electrolyte-supported planar solid oxide fuel cell design, termed the FlexCell, for coal-based, megawatt-scale power generation systems. This project was focused on the fabrication and testing of electrolyte-supported FlexCells with yttria-stabilized zirconia (YSZ) as the electrolyte material. YSZ based FlexCells were made with sizes ranging from 100 to 500 cm2. Single-cell testing was performed to confirm high electrochemical performance, both with diluted hydrogen and simulated coal gas as fuels. Finite element analysis modeling was performed at The Ohio State University was performed to establish FlexCell architectures with optimum mechanical robustness. A manufacturing cost analysis was completed, which confirmed that manufacturing costs of less than $50/kW are achievable at high volumes (500 MW/year).

  14. Validation of Novel Planar Cell Design for MW-Scale SOFC Power Systems

    SciTech Connect (OSTI)

    Scott Swartz; Lora Thrun; Gene Arkenberg; Kellie Chenault

    2011-09-30

    This report describes the work completed by NexTech Materials, Ltd. during a three-year project to validate an electrolyte-supported planar solid oxide fuel cell design, termed the FlexCell, for coal-based, megawatt-scale power generation systems. This project was focused on the fabrication and testing of electrolyte-supported FlexCells with yttria-stabilized zirconia (YSZ) as the electrolyte material. YSZ based FlexCells were made with sizes ranging from 100 to 500 cm{sup 2}. Single-cell testing was performed to confirm high electrochemical performance, both with diluted hydrogen and simulated coal gas as fuels. Finite element analysis modeling was performed at The Ohio State University was performed to establish FlexCell architectures with optimum mechanical robustness. A manufacturing cost analysis was completed, which confirmed that manufacturing costs of less than $50/kW are achievable at high volumes (500 MW/year). DISCLAIMER

  15. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

    1987-04-14

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

  16. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, James F. (Hamilton, MA); Chludzinski, Paul J. (Swampscott, MA); Dantowitz, Philip (Peabody, MA)

    1987-01-01

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

  17. Fuel Cell Animation - Fuel Cell Components (Text Version) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Components (Text Version) Fuel Cell Animation - Fuel Cell Components (Text Version) This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts. Fuel cell shown with its inputs and outputs. Hydrogen input on top, oxygen input in front, water and heat outputs out the back, with an electrical circuit going around the top. Polymer Electrolyte Membrane (PEM) in center, cathode/catalyst to the right

  18. TJ Solar Cell

    SciTech Connect (OSTI)

    Friedman, Daniel

    2009-04-17

    This talk will discuss recent developments in III-V multijunction photovoltaic technology which have led to the highest-efficiency solar cells ever demonstrated. The relationship between the materials science of III-V semiconductors and the achievement of record solar cell efficiencies will be emphasized. For instance, epitaxially-grown GAInP has been found to form a spontaneously-ordered GaP/InP (111) superlattice. This ordering affects the band gap of the material, which in turn affects the design of solar cells which incorporate GaInP. For the next generation of ultrahigh-efficiency III-V solar cells, we need a new semiconductor which is lattice-matched to GaAs, has a band gap of 1 eV, and has long minority-carrier diffusion lengths. Out of a number of candidate materials, the recently-discovered alloy GaInNAs appears to have the greatest promise. This material satisfies the first two criteria, but has to date shown very low diffusion lengths, a problem which is our current focus in the development of these next-generation cells.

  19. Importance of Size and Distribution of Ni Nanoparticles for the Hydrodeoxygenation of Microalgae Oil

    SciTech Connect (OSTI)

    Song, Wenji; Zhao, Chen; Lercher, Johannes A.

    2013-07-22

    Improved synthetic approaches for preparing small-sized Ni nanoparticles (d=3 nm) supported on HBEA zeolite have been explored and compared with the traditional impregnation method. The formation of surface nickel silicate/aluminate involved in the two precipitation processes are inferred to lead to the stronger interaction between the metal and the support. The lower Brnsted acid concentrations of these two Ni/HBEA catalysts compared with the parent zeolite caused by the partial exchange of Brnsted acid sites by Ni2+ cations do not influence the hydrodeoxygenation rates, but alter the product selectivity. Higher initial rates and higher stability have been achieved with these optimized catalysts for the hydrodeoxygenation of stearic acid and microalgae oil. Small metal particles facilitate high initial catalytic activity in the fresh sample and size uniformity ensures high catalyst stability.

  20. Porous silicon structures with high surface area/specific pore size

    DOE Patents [OSTI]

    Northrup, M. Allen (Berkeley, CA); Yu, Conrad M. (Antioch, CA); Raley, Norman F. (Danville, CA)

    1999-01-01

    Fabrication and use of porous silicon structures to increase surface area of heated reaction chambers, electrophoresis devices, and thermopneumatic sensor-actuators, chemical preconcentrates, and filtering or control flow devices. In particular, such high surface area or specific pore size porous silicon structures will be useful in significantly augmenting the adsorption, vaporization, desorption, condensation and flow of liquids and gasses in applications that use such processes on a miniature scale. Examples that will benefit from a high surface area, porous silicon structure include sample preconcentrators that are designed to adsorb and subsequently desorb specific chemical species from a sample background; chemical reaction chambers with enhanced surface reaction rates; and sensor-actuator chamber devices with increased pressure for thermopneumatic actuation of integrated membranes. Examples that benefit from specific pore sized porous silicon are chemical/biological filters and thermally-activated flow devices with active or adjacent surfaces such as electrodes or heaters.

  1. TECHNOLOGY EVALUATION FOR CONDITIONING OF HANFORD TANK WASTE USING SOLIDS SEGREGATION AND SIZE REDUCTION

    SciTech Connect (OSTI)

    Restivo, M.; Stone, M.; Herman, D.; Lambert, D.; Duignan, M.; SMITH, G.; WELLS, B.; LUMETTA, G.; ENDRELIN, C.; ADKINS, H.

    2014-04-15

    The Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL) team performed a literature search on current and proposed technologies for solids segregation and size reduction of particles in the slurry feed from the Hanford Tank Farm (HTF). The team also investigated technology research performed on waste tank slurries, both real and simulated, and reviewed academic theory applicable to solids segregation and size reduction. This review included text book applications and theory, commercial applications suitable for a nuclear environment, research of commercial technologies suitable for a nuclear environment, and those technologies installed in a nuclear environment, including technologies implemented at Department of Energy (DOE) facilities. Information on each technology is provided in this report along with the advantages and disadvantages of the technologies for this application.

  2. Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation

    SciTech Connect (OSTI)

    Hakim, Sikander H.; Sener, Canan; Alba Rubio, Ana C.; Gostanian, Thomas M.; O'neill, Brandon J; Ribeiro, Fabio H.; Miller, Jeffrey T.; Dumesic, James A

    2015-08-01

    Elucidation of active sites in supported bimetallic catalysts is complicated by the high level of dispersity in the nanoparticle size and composition that is inherent in conventional methods of catalyst preparation. We present a synthesis strategy that leads to highly dispersed, bimetallic nanoparticles with uniform particle size and composition by means of controlled surface reactions. We demonstrate the synthesis of three systems, RhMo, PtMo, and RhRe, consisting of a highly reducible metal with an oxophilic promoter. These catalysts are characterized by FTIR, CO chemisorption, STEM/EDS, TPR, and XAS analysis. The catalytic properties of these bimetallic nanoparticles were probed for the selective CO hydrogenolysis of (hydroxymethyl)tetrahydropyran to produce 1,6 hexanediol. Based on the characterization results and reactivity trends, the active sites in the hydrogenolysis reaction are identified to be small ensembles of the more noble metal (Rh, Pt) adjacent to highly reduced moieties of the more oxophilic metal (Mo, Re).

  3. Technology Evaluation for Conditioning of Hanford Tank Waste Using Solids Segregation and Size Reduction

    SciTech Connect (OSTI)

    Restivo, Michael L.; Stone, M. E.; Herman, D. T.; Lambert, Daniel P.; Duignan, Mark R.; Smith, Gary L.; Wells, Beric E.; Lumetta, Gregg J.; Enderlin, Carl W.; Adkins, Harold E.

    2014-04-24

    The Savannah River National Laboratory and the Pacific Northwest National Laboratory team performed a literature search on current and proposed technologies for solids segregation and size reduction of particles in the slurry feed from the Hanford Tank Farm. The team also investigated technology research performed on waste tank slurries, both real and simulated, and reviewed academic theory applicable to solids segregation and size reduction. This review included text book applications and theory, commercial applications suitable for a nuclear environment, research of commercial technologies suitable for a nuclear environment, and those technologies installed in a nuclear environment, including technologies implemented at Department of Energy facilities. Information on each technology is provided in this report along with the advantages and disadvantages of the technologies for this application. Any technology selected would require testing to verify the ability to meet the High-Level Waste Feed Waste Acceptance Criteria to the Hanford Tank Waste Treatment and Immobilization Plant Pretreatment Facility.

  4. Water Desalination Using Nanoporous Single-Layer Graphene with Tunable Pore Size

    SciTech Connect (OSTI)

    Surwade, Sumedh P [ORNL; Smirnov, Sergei N [ORNL; Vlassiouk, Ivan V [ORNL; Unocic, Raymond R [ORNL; Veith, Gabriel M [ORNL; Dai, Sheng [ORNL; Mahurin, Shannon Mark [ORNL

    2015-01-01

    Graphene has great potential to serve as a separation membrane due to its unique properties such as chemical and mechanical stability, flexibility and most importantly its one-atom thickness. In this study, we demonstrate first experimental evidence of the use of single-layer porous graphene as a desalination membrane. Nanometer-sized pores are introduced into single layer graphene using a convenient oxygen plasma etching process that permits tuning of the pore size. The resulting porous graphene membrane exhibited high rejection of salt ions and rapid water transport, thus functioning as an efficient water desalination membrane. Salt rejection selectivity of nearly 100% and exceptionally high water fluxes exceeding 105 g m-2 s-1 at 40 C were measured using saturated water vapor as a driving force.

  5. Porous silicon structures with high surface area/specific pore size

    DOE Patents [OSTI]

    Northrup, M.A.; Yu, C.M.; Raley, N.F.

    1999-03-16

    Fabrication and use of porous silicon structures to increase surface area of heated reaction chambers, electrophoresis devices, and thermopneumatic sensor-actuators, chemical preconcentrates, and filtering or control flow devices. In particular, such high surface area or specific pore size porous silicon structures will be useful in significantly augmenting the adsorption, vaporization, desorption, condensation and flow of liquids and gases in applications that use such processes on a miniature scale. Examples that will benefit from a high surface area, porous silicon structure include sample preconcentrators that are designed to adsorb and subsequently desorb specific chemical species from a sample background; chemical reaction chambers with enhanced surface reaction rates; and sensor-actuator chamber devices with increased pressure for thermopneumatic actuation of integrated membranes. Examples that benefit from specific pore sized porous silicon are chemical/biological filters and thermally-activated flow devices with active or adjacent surfaces such as electrodes or heaters. 9 figs.

  6. Real-time spot size camera for pulsed high-energy radiographic machines

    SciTech Connect (OSTI)

    Watson, S.A.

    1993-06-01

    The focal spot size of an x-ray source is a critical parameter which degrades resolution in a flash radiograph. For best results, a small round focal spot is required. Therefore, a fast and accurate measurement of the spot size is highly desirable to facilitate machine tuning. This paper describes two systems developed for Los Alamos National Laboratory`s Pulsed High-Energy Radiographic Machine Emitting X-rays (PHERMEX) facility. The first uses a CCD camera combined with high-brightness floors, while the second utilizes phosphor storage screens. Other techniques typically record only the line spread function on radiographic film, while systems in this paper measure the more general two-dimensional point-spread function and associated modulation transfer function in real time for shot-to-shot comparison.

  7. Real-time spot size camera for pulsed high-energy radiographic machines

    SciTech Connect (OSTI)

    Watson, S.A.

    1993-01-01

    The focal spot size of an x-ray source is a critical parameter which degrades resolution in a flash radiograph. For best results, a small round focal spot is required. Therefore, a fast and accurate measurement of the spot size is highly desirable to facilitate machine tuning. This paper describes two systems developed for Los Alamos National Laboratory's Pulsed High-Energy Radiographic Machine Emitting X-rays (PHERMEX) facility. The first uses a CCD camera combined with high-brightness floors, while the second utilizes phosphor storage screens. Other techniques typically record only the line spread function on radiographic film, while systems in this paper measure the more general two-dimensional point-spread function and associated modulation transfer function in real time for shot-to-shot comparison.

  8. A simulator designated to the help sizing of waste incineration plant with energy valorization

    SciTech Connect (OSTI)

    Lemoult, B.

    1998-07-01

    The integrated waste treatment (sorting, recycling, composting, incineration, tip) concept is increasing. In this concept, incineration remains the last way of destruction before tipping of refuse. With the aim to improve thermal and economic efficiencies of this kind of treatment, thermal and/or electrical energy are produced in incineration plants. If environmental rules lead to a steady increase of such plants, a lot of data have to be evaluated to find the best size, especially under economic aspects, for a given project. The author presents the specification of the software ARTEMIS, which helps a project manager to find the optimal size of a plant, to quantify the effect of various technical options, and to compare some operating management. Garbage deposit (quantity and quality), energy valorization (electricity price, thermal needs), machines (furnace, high and low pressure turbines, heat exchanger, auxiliary boiler) are taken into account. Energy and economic annual balance are also calculated with a hourly simulation step.

  9. Breakthrough Vehicle Development - Fuel Cells

    Fuel Cell Technologies Publication and Product Library (EERE)

    Document describing research and development program for fuel cell power systems for transportation applications.

  10. Seventh Edition Fuel Cell Handbook

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Provides an overview of fuel cell technology and research projects. Discusses the basic workings of fuel cells and their system components, main fuel cell types, their characteristics, and their development status, as well as a discussion of potential fuel cell applications.

  11. Size-dependent effects of nanoparticles on the activity of cytochrome P450 isoenzymes

    SciTech Connect (OSTI)

    Froehlich, Eleonore; Kueznik, Tatjana; Samberger, Claudia; Roblegg, Eva; Wrighton, Christopher

    2010-02-01

    Nanoparticles are known to be able to interfere with cellular metabolism and to cause cytotoxicity and moreover may interfere with specific cellular functions. Serious effects on the latter include changes in liver cell function. The cytochrome P450 system is expressed in many cells but is especially important in hepatocytes and hormone-producing cells. The interaction of polystyrene nanoparticles with the most important drug-metabolizing cytochrome P450 isoenzymes, CYP3A4, CYP2D6, CYP2C9 and CYP2A1 expressed individually in insect cells (BACULOSOMES) was studied by the cleavage of substrates coupled to a fluorescent dye. The data obtained for individual isoenzymes were compared to metabolism in microsomes isolated from normal liver and from the hepatoma cell line H4-II-E-C3. Small (20-60 nm) carboxyl polystyrene particles but not larger (200 nm) ones reached high intracellular concentrations in the vicinity of the endoplasmic reticulum. These small particles inhibited the enzymatic activity of CYP450 isoenzymes in BACULOSOMES and substrate cleavage in normal liver microsomes. They moreover increased the effect of known inhibitors of the cytochrome P450 system (cimetidine, phenobarbital and paclitaxel). Substrate cleavage by the hepatoma cell line H4-II-E-C3 in contrast was undetectable, making this cell line unsuitable for this type of study. Our results thus demonstrate that nanoparticles can inhibit the metabolism of xenobiotics by the CYP450 system in model systems in vitro. Such inhibition could also potentially occur in vivo and possibly cause adverse effects in persons receiving medication.

  12. Guidelines for conservation levels and for sizing passive-solar collection area

    SciTech Connect (OSTI)

    Balcomb, J.D.

    1983-01-01

    Guidelines are given for selecting R-values and infiltration levels, and determining the size of the solar collection area for passive solar building. The guidelines are based on balancing the incremental cost/benefit of conservation and solar strategies. Tables are given for 209 cities in the US and the results are also displayed on maps. The procedures are developed in an appendix, which gives the cost assumptions used and explains how to develop different guidelines for different costs.

  13. Platinum nanoparticle during electrochemical hydrogen evolution: Adsorbate distribution, active reaction species, and size effect

    SciTech Connect (OSTI)

    Tan, Teck L.; Wang, Lin -Lin; Zhang, Jia; Johnson, Duane D.; Bai, Kewu

    2015-03-02

    For small Pt nanoparticles (NPs), catalytic activity is, as observed, adversely affected by size in the 13 nm range. We elucidate, via first-principles-based thermodynamics, the operation H* distribution and cyclic voltammetry (CV) during the hydrogen evolution reaction (HER) across the electrochemical potential, including the underpotential region (U ? 0) that is difficult to assess in experiment. We consider multiple adsorption sites on a 1 nm Pt NP model and show that the characteristic CV peaks from different H* species correspond well to experiment. We next quantify the activity contribution from each H* species to explain the adverse effect of size. From the resolved CV peaks at the standard hydrogen electrode potential (U = 0), we first deduce that the active species for the HER are the partially covered (100)-facet bridge sites and the (111)-facet hollow sites. Upon evaluation of the reaction barriers at operation H* distribution and microkinetic modeling of the exchange current, we find that the nearest-neighbor (100)-facet bridge site pairs have the lowest activation energy and contribute to ~75% of the NP activity. Edge bridge sites (fully covered by H*) per se are not active; however, they react with neighboring (100)-facet H* to account for ~18% of the activity, whereas (111)-facet hollow sites contribute little. As a result, extrapolating the relative contributions to larger NPs in which the ratio of facet-to-edge sites increases, we show that the adverse size effect of Pt NP HER activity kicks in for sizes below 2 nm.

  14. Tensile strains give rise to strong size effects for thermal conductivities of silicene, germanene and stanene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuang, Youdi D.; Lindsay, Lucas R.; Shi, Sanqiang Q.; Zhen, Guangping P.

    2016-01-11

    Based on first principles calculations and self-consistent solution of linearized Boltzmann-Peierls equation for phonon transport approach within a three-phonon scattering framework, we characterize lattice thermal conductivities k of freestanding silicene, germanene and stanene under different isotropic tensile strains and temperatures. We find a strong size dependence of k for silicene with tensile strain, i.e., divergent k with increasing system size, in contrast, the intrinsic room temperature k for unstrained silicene converges with system size to 19.34 W/m–1 K–1 by 178 nm. The room temperature k of strained silicene becomes as large as that of bulk silicon by 84 m, indicatingmore » the possibility of using strain in silicene to manipulate k for thermal management. The relative contribution to the intrinsic k from out-of-plane acoustic modes is largest for unstrained silicene, –39% at room temperature. The single mode relaxation time approximation, which works reasonably well for bulk silicon, fails to appropriately describe phonon thermal transport in silicene, germanene and stanene within the temperature range considered. For large samples of silicene, k increases with tensile strain, peaks at –7% strain and then decreases with further strain. In germanene and stanene increasing strain hardens and stabilizes long wavelength out-of-plane acoustic phonons, and leads to similar k behaviors to those of silicene. As a result, these findings further our understanding of phonon dynamics in group-IV buckled monolayers and may guide transfer and fabrication techniques of these freestanding samples and engineering k by size and strain for applications of thermal management and thermoelectricity.« less

  15. EVIDENCE FOR (AND AGAINST) PROGENITOR BIAS IN THE SIZE GROWTH OF COMPACT RED GALAXIES

    SciTech Connect (OSTI)

    Keating, Stephanie K.; Abraham, Roberto G.; Schiavon, Ricardo; Graves, Genevieve; Damjanov, Ivana; Yan, Renbin; Newman, Jeffrey; Simard, Luc

    2015-01-01

    Most massive, passive galaxies are compact at high redshifts, but similarly compact massive galaxies are rare in the local universe. The most common interpretation of this phenomenon is that massive galaxies have grown in size by a factor of about five since redshift z = 2. An alternative explanation is that recently quenched massive galaxies are larger (a {sup p}rogenitor bias{sup )}. In this paper, we explore the importance of progenitor bias by looking for systematic differences in the stellar populations of compact early-type galaxies in the DEEP2 survey as a function of size. Our analysis is based on applying the statistical technique of bootstrap resampling to constrain differences in the median ages of our samples and to begin to characterize the distribution of stellar populations in our co-added spectra. The light-weighted ages of compact early-type galaxies at redshifts 0.5 < z < 1.4 are compared to those of a control sample of larger galaxies at similar redshifts. We find that massive compact early-type galaxies selected on the basis of red color and high bulge-to-total ratio are younger than similarly selected larger galaxies, suggesting that size growth in these objects is not driven mainly by progenitor bias, and that individual galaxies grow as their stellar populations age. However, compact early-type galaxies selected on the basis of image smoothness and high bulge-to-total ratio are older than a control sample of larger galaxies. Progenitor bias will play a significant role in defining the apparent size changes of early-type galaxies if they are selected on the basis of the smoothness of their light distributions.

  16. Ultrasonic Phased Array Technique for Accurate Flaw Sizing in Dissimilar Metal Welds

    SciTech Connect (OSTI)

    Jonathan D Buttram

    2005-03-11

    Described is a manual,portable non-destructive technique to determine the through wall height of cracks present in dissimilar metal welds used in the primary coolling systems of pressure water and boiler light water reactors. Current manual methods found in industry have proven not to exhibit the sizing accuracy required by ASME inspection requirement. The technique described demonstrated an accuracy approximately three times that required to ASME Section XI, Appendix 8 qualification.

  17. Level: National and Regional Data; Row: NAICS Codes, Value of Shipments and Employment Sizes;

    Gasoline and Diesel Fuel Update (EIA)

    2 Capability to Switch LPG to Alternative Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes, Value of Shipments and Employment Sizes; Column: Energy Sources; Unit: Million Barrels. Coal Coke NAICS Total Not Electricity Natural Distillate Residual and Code(a) Selected Subsectors and Industry Consumed(c) Switchable Switchable Receipts(d) Gas Fuel Oil Fuel Oil Coal Breeze Other(e) Total United States 311 Food 1 * 1 * * * * 0 0 * 3112 Grain and Oilseed Milling * * * * * * * 0

  18. Level: National and Regional Data; Row: NAICS Codes, Value of Shipments and Employment Sizes;

    Gasoline and Diesel Fuel Update (EIA)

    8 Capability to Switch Distillate Fuel Oil to Alternative Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes, Value of Shipments and Employment Sizes; Column: Energy Sources; Unit: Million Barrels. Coal Coke NAICS Total Not Electricity Natural Residual and Code(a) Selected Subsectors and Industry Consumed(c) Switchable Switchable Receipts(d) Gas Fuel Oil Coal LPG Breeze Other(e) Total United States 311 Food 4 * 3 * * * 0 * 0 * 3112 Grain and Oilseed Milling * * * * * * 0 *

  19. " Row: NAICS Codes, Value of Shipments and Employment Sizes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    2 Capability to Switch Natural Gas to Alternative Energy Sources, 2010;" " Level: National and Regional Data;" " Row: NAICS Codes, Value of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: Billion Cubic Feet." ,,"Natural Gas",,,"Alternative Energy Sources(b)" ,,,,,,,,,,"Coal Coke" "NAICS"," ","Total","

  20. " Row: NAICS Codes, Value of Shipments and Employment Sizes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    4 Capability to Switch Residual Fuel Oil to Alternative Energy Sources, 2010;" " Level: National and Regional Data;" " Row: NAICS Codes, Value of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: Million Barrels." ,,"Residual Fuel Oil",,,"Alternative Energy Sources(b)" ,,,,,,,,,,"Coal Coke" "NAICS"," ","Total","

  1. " Row: NAICS Codes, Value of Shipments and Employment Sizes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Capability to Switch Electricity to Alternative Energy Sources, 2010; " " Level: National and Regional Data;" " Row: NAICS Codes, Value of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: Million Kilowatthours." ,,"Electricity Receipts",,,"Alternative Energy Sources(b)" ,,,,,,,,,,"Coal Coke" "NAICS"," ","Total","

  2. " Row: NAICS Codes, Value of Shipments and Employment Sizes;"

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Capability to Switch Distillate Fuel Oil to Alternative Energy Sources, 2010; " " Level: National and Regional Data;" " Row: NAICS Codes, Value of Shipments and Employment Sizes;" " Column: Energy Sources;" " Unit: Million Barrels." ,,"Distillate Fuel Oil",,,"Alternative Energy Sources(b)" ,,,,,,,,,,"Coal Coke" "NAICS"," ","Total","

  3. Platinum nanoparticle during electrochemical hydrogen evolution: Adsorbate distribution, active reaction species, and size effect

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, Teck L.; Wang, Lin -Lin; Zhang, Jia; Johnson, Duane D.; Bai, Kewu

    2015-03-02

    For small Pt nanoparticles (NPs), catalytic activity is, as observed, adversely affected by size in the 1–3 nm range. We elucidate, via first-principles-based thermodynamics, the operation H* distribution and cyclic voltammetry (CV) during the hydrogen evolution reaction (HER) across the electrochemical potential, including the underpotential region (U ≤ 0) that is difficult to assess in experiment. We consider multiple adsorption sites on a 1 nm Pt NP model and show that the characteristic CV peaks from different H* species correspond well to experiment. We next quantify the activity contribution from each H* species to explain the adverse effect of size.more » From the resolved CV peaks at the standard hydrogen electrode potential (U = 0), we first deduce that the active species for the HER are the partially covered (100)-facet bridge sites and the (111)-facet hollow sites. Upon evaluation of the reaction barriers at operation H* distribution and microkinetic modeling of the exchange current, we find that the nearest-neighbor (100)-facet bridge site pairs have the lowest activation energy and contribute to ~75% of the NP activity. Edge bridge sites (fully covered by H*) per se are not active; however, they react with neighboring (100)-facet H* to account for ~18% of the activity, whereas (111)-facet hollow sites contribute little. As a result, extrapolating the relative contributions to larger NPs in which the ratio of facet-to-edge sites increases, we show that the adverse size effect of Pt NP HER activity kicks in for sizes below 2 nm.« less

  4. What Is the Size of the Atomic Nucleus? | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Highlights » 2016 » What Is the Size of the Atomic Nucleus? Advanced Scientific Computing Research (ASCR) ASCR Home About Research Facilities Science Highlights Benefits of ASCR Funding Opportunities Advanced Scientific Computing Advisory Committee (ASCAC) Community Resources Contact Information Advanced Scientific Computing Research U.S. Department of Energy SC-21/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-7486 F: (301) 903-4846 E: Email Us More

  5. Flutter Speed Predictions for MW-Sized Wind Turbine Blades Don W. Lobitz

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Introduction Flutter Speed Predictions for MW-Sized Wind Turbine Blades Don W. Lobitz Sandia National Laboratories* Albuquerque, New Mexico 87185 dwlobit@sandia.gov Classical aeroelastic flutter instability historically has not been a driving issue in wind turbine design. In fact, rarely has this issue even been addressed in the past. Commensurately, of the wind turbines that have been built, rarely has classical flutter ever been observed. However, with the advent of larger turbines fitted

  6. Size reduction of high- and low-moisture corn stalks by linear knife grid system

    SciTech Connect (OSTI)

    Womac, A.R. [University of Tennessee; Igathinathane, C. [Mississippi State University (MSU); Sokhansanj, Shahabaddine [ORNL; Narayan, S. [First American Scientific Co.

    2009-04-01

    High- and low-moisture corn stalks were tested using a linear knife grid size reduction device developed for first-stage size reduction. The device was used in conjunction with a universal test machine that quantified shearing stress and energy characteristics for forcing a bed of corn stalks through a grid of sharp knives. No published engineering performance data for corn stover with similar devices are available to optimize performance; however, commercial knife grid systems exist for forage size reduction. From the force displacement data, mean and maximum ultimate shear stresses, cumulative and peak mass-based cutting energies for corn stalks, and mean new surface area-based cutting energies were determined from 4 5 refill runs at two moisture contents (78.8% and 11.3% wet basis), three knife grid spacings (25.4, 50.8, and 101.6 mm), and three bed depths (50.8, 101.6, and 152.4 mm). In general, the results indicated that peak failure load, ultimate shear stress, and cutting energy values varied directly with bed depth and inversely with knife grid spacing. Mean separation analysis established that high- and low-moisture conditions and bed depths 101.6 mm did not differ significantly (P < 0.05) for ultimate stress and cutting energy values, but knife grid spacing were significantly different. Linear knife grid cutting energy requirements for both moisture conditions of corn stalks were much smaller than reported cutting energy requirements. Ultimate shear stress and cutting energy results of this research should aid the engineering design of commercial scale linear knife gird size reduction equipment for various biomass feedstocks.

  7. Software-Defined Solutions for Managing Energy Use in Small to Medium Sized Commercial Buildings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Software-Defined Solutions for Managing Energy Use in Small to Medium Sized Commercial Buildings 2014 Building Technologies Office Peer Review Building System Services Application Stack Physical Data/Device sMAP driver sMAP driver sMAP driver sMAP driver sMAP driver sMAP driver occupancy light HVAC lighting appliance sensors Database (Time series service) Transaction Manager Thermostat Light control Appliance control temperature actuators Building Operating System Services (BOSS) User

  8. Betatron radiation based measurement of the electron-beam size in a wakefield accelerator

    SciTech Connect (OSTI)

    Schnell, Michael; Saevert, Alexander; Reuter, Maria; and others

    2012-07-09

    We present a spatial and spectral characterization of a laser-plasma based betatron source which allows us to determine the betatron oscillation amplitude of the electrons which decreases with increasing electron energies. Due to the observed oscillation amplitude and the independently measured x-ray source size of (1.8{+-}0.3){mu}m we are able to estimate the electron bunch diameter to be (1.6{+-}0.3){mu}m.

  9. Size and composition-controlled fabrication of VO2 nanocrystals by terminated cluster growth

    SciTech Connect (OSTI)

    Anders, Andre; Slack, Jonathan

    2013-05-14

    A physical vapor deposition-based route for the fabrication of VO2 nanoparticles is demonstrated, consisting of reactive sputtering and vapor condensation at elevated pressures. The oxidation of vanadium atoms is an efficient heterogeneous nucleation method, leading to high nanoparticle throughtput. Fine control of the nanoparticle size and composition is obtained. Post growth annealing leads to crystalline VO2 nanoparticles with optimum thermocromic and plasmonic properties.

  10. Probing the dependence of electron transfer on size and coverage in carbon nanotube-quantum dot heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Lei; Wong, Stanislaus S.; Han, Jinkyu; Zhu, Yuqi; Jaye, Cherno; Liu, Haiqing; Li, Zhuo -Qun; Taylor, Gordon T.; Fischer, Daniel A.; Appenzeller, Joerg; et al

    2015-11-16

    As a model system for understanding charge transfer in novel architectural designs for solar cells, double-walled carbon nanotube (DWNT)–CdSe quantum dot (QD) (QDs with average diameters of 2.3, 3.0, and 4.1 nm) heterostructures have been fabricated. The individual nanoscale building blocks were successfully attached and combined using a hole-trapping thiol linker molecule, i.e., 4-mercaptophenol (MTH), through a facile, noncovalent π–π stacking attachment strategy. Transmission electron microscopy confirmed the attachment of QDs onto the external surfaces of the DWNTs. We herein demonstrate a meaningful and unique combination of near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopies bolstered by complementary electricalmore » transport measurements in order to elucidate the synergistic interactions between CdSe QDs and DWNTs, which are facilitated by the bridging MTH molecules that can scavenge photoinduced holes and potentially mediate electron redistribution between the conduction bands in CdSe QDs and the C 2p-derived states of the DWNTs. Specifically, we correlated evidence of charge transfer as manifested by (i) changes in the NEXAFS intensities of π* resonance in the C K-edge and Cd M3-edge spectra, (ii) a perceptible outer tube G-band downshift in frequency in Raman spectra, as well as (iii) alterations in the threshold characteristics present in transport data as a function of CdSe QD deposition onto the DWNT surface. Furthermore, the separate effects of (i) varying QD sizes and (ii) QD coverage densities on the electron transfer were independently studied.« less

  11. Probing the dependence of electron transfer on size and coverage in carbon nanotube-quantum dot heterostructures

    SciTech Connect (OSTI)

    Wang, Lei; Wong, Stanislaus S.; Han, Jinkyu; Zhu, Yuqi; Jaye, Cherno; Liu, Haiqing; Li, Zhuo -Qun; Taylor, Gordon T.; Fischer, Daniel A.; Appenzeller, Joerg; Zhu, Ruiping

    2015-11-16

    As a model system for understanding charge transfer in novel architectural designs for solar cells, double-walled carbon nanotube (DWNT)CdSe quantum dot (QD) (QDs with average diameters of 2.3, 3.0, and 4.1 nm) heterostructures have been fabricated. The individual nanoscale building blocks were successfully attached and combined using a hole-trapping thiol linker molecule, i.e., 4-mercaptophenol (MTH), through a facile, noncovalent ?? stacking attachment strategy. Transmission electron microscopy confirmed the attachment of QDs onto the external surfaces of the DWNTs. We herein demonstrate a meaningful and unique combination of near-edge X-ray absorption fine structure (NEXAFS) and Raman spectroscopies bolstered by complementary electrical transport measurements in order to elucidate the synergistic interactions between CdSe QDs and DWNTs, which are facilitated by the bridging MTH molecules that can scavenge photoinduced holes and potentially mediate electron redistribution between the conduction bands in CdSe QDs and the C 2p-derived states of the DWNTs. Specifically, we correlated evidence of charge transfer as manifested by (i) changes in the NEXAFS intensities of ?* resonance in the C K-edge and Cd M3-edge spectra, (ii) a perceptible outer tube G-band downshift in frequency in Raman spectra, as well as (iii) alterations in the threshold characteristics present in transport data as a function of CdSe QD deposition onto the DWNT surface. Furthermore, the separate effects of (i) varying QD sizes and (ii) QD coverage densities on the electron transfer were independently studied.

  12. Electrochemical cell operation and system

    DOE Patents [OSTI]

    Maru, Hansraj C. (Brookfield Center, CT)

    1980-03-11

    Thermal control in fuel cell operation is affected through sensible heat of process gas by providing common input manifolding of the cell gas flow passage in communication with the cell electrolyte and an additional gas flow passage which is isolated from the cell electrolyte and in thermal communication with a heat-generating surface of the cell. Flow level in the cell gas flow passage is selected based on desired output electrical energy and flow level in the additional gas flow passage is selected in accordance with desired cell operating temperature.

  13. COLOR DEPENDENCE IN THE SIZE DISTRIBUTION OF MAIN BELT ASTEROIDS REVISITED

    SciTech Connect (OSTI)

    August, Tyler M.; Wiegert, Paul A.

    2013-06-15

    The size distribution of the asteroid belt is examined with 16956 main belt asteroids detected in data taken from the Canada-France-Hawaii Telescope Legacy Survey in two filters (g' and r'). The cumulative H (absolute magnitude) distribution is examined in both filters, and both match well to simple power laws down to H = 17, with slopes in rough agreement with those reported the literature. This implies that disruptive collisions between asteroids are gravitationally dominated down to at least this size, and probably sub-kilometer scales. The slopes of these distributions appear shallower in the outer belt than the inner belt, and the g' distributions appear slightly steeper than the r'. The slope shallowing in the outer belt may reflect a real compositional difference: the inner asteroid belt has been suggested to consist mostly of stony and/or metallic S-type asteroids, whereas carbonaceous C-types are thought to be more prevalent further from the Sun. No waves are seen in the size distribution above H = 15. Since waves are expected to be produced at the transition from gravitationally-dominated to internal strength-dominated collisions, their absence here may imply that the transition occurs at sub-kilometer scales, much smaller than the H = 17 (diameter {approx} 1.6 km) cutoff of this study.

  14. A method for preparation and cleaning of uniformly sized arsenopyrite particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Parthasarathy, Hariprasad; Baltrus, John P; Dzombak, David A; Karamalidis, Athanasios K

    2014-10-11

    The oxidative dissolution of sulfide minerals, such as arsenopyrite (FeAsS), is of critical importance in many geochemical systems. A comprehensive understanding of their dissolution rates entails careful preparation of the mineral surface. Measurements of dissolution rates of arsenic from arsenopyrite are dependent on the size and degree of oxidation of its particles, among other factors. In this work, a method was developed for preparation and cleaning of arsenopyrite particles with size range of 150–250 μm. Four different cleaning methods were evaluated for effectiveness based on the removal of oxidized species of iron (Fe), arsenic (As) and sulfur (S) from themore » surface. The percentage oxidation of the surface was determined using X-ray photoelectron spectroscopy (XPS), and surface stoichiometry was measured using scanning electron microscopy – energy dispersive X-ray spectroscopy (SEM-EDS). Results indicate that sonicating the arsenopyrite particles and then cleaning them with 12N HCl followed by 50% ethanol, and drying in nitrogen was the most effective method. This method was successful in greatly reducing the oxide species of Fe while completely removing oxides of As and S from the arsenopyrite surface. Although sonication and acid cleaning have been widely used for mineral preparation, the method described in this study can significantly reduce grain size heterogeneity as well as surface oxidation, which enables greater control in surface and dissolution experiments.« less

  15. A method for preparation and cleaning of uniformly sized arsenopyrite particles

    SciTech Connect (OSTI)

    Parthasarathy, Hariprasad; Baltrus, John P; Dzombak, David A; Karamalidis, Athanasios K

    2014-10-11

    The oxidative dissolution of sulfide minerals, such as arsenopyrite (FeAsS), is of critical importance in many geochemical systems. A comprehensive understanding of their dissolution rates entails careful preparation of the mineral surface. Measurements of dissolution rates of arsenic from arsenopyrite are dependent on the size and degree of oxidation of its particles, among other factors. In this work, a method was developed for preparation and cleaning of arsenopyrite particles with size range of 150250 ?m. Four different cleaning methods were evaluated for effectiveness based on the removal of oxidized species of iron (Fe), arsenic (As) and sulfur (S) from the surface. The percentage oxidation of the surface was determined using X-ray photoelectron spectroscopy (XPS), and surface stoichiometry was measured using scanning electron microscopy energy dispersive X-ray spectroscopy (SEM-EDS). Results indicate that sonicating the arsenopyrite particles and then cleaning them with 12N HCl followed by 50% ethanol, and drying in nitrogen was the most effective method. This method was successful in greatly reducing the oxide species of Fe while completely removing oxides of As and S from the arsenopyrite surface. Although sonication and acid cleaning have been widely used for mineral preparation, the method described in this study can significantly reduce grain size heterogeneity as well as surface oxidation, which enables greater control in surface and dissolution experiments.

  16. The influence of size, shape, and surface coating on the stability of aqueous nanoparticle suspensions

    SciTech Connect (OSTI)

    Mulvihill, M.J.; Habas, S.E.; La Plante, I.J.; Wan, J.; Mokari, T.

    2010-09-03

    In response to the rapid development and emerging commercialization of nanoparticles, fundamental studies concerning the fate of nanoparticles in the environment are needed. Precise control over the nanoparticle size, shape, and surface coating of cadmium selenide particles modified with thiolate ligands has been used to analyze the effects of nanoparticle design on their stability in aqueous environments. Nanoparticle stability was quantified using the concept of critical coagulation concentration (CCC) in solutions of sodium chloride. These investigations characterized the instability of the ligand coatings, which varied directly with chain length of the capping ligands. The stability of the ligand coatings were characterized as a function of time, pH, and ionic strength. Ligand dissociation has been shown to be a primary mechanism for nanoparticle aggregation when short-chain (C2-C6) ligands are used in the ligand shell. Stable nanoparticle suspensions prepared with long chain ligands (C11) were used to characterize nanoparticle stability as a function of size and shape. A linear relationship between particle surface area and the CCC was discovered and was found to be independent of nanoparticle shape. Quantitative analysis of nanoparticle size, shape, and surface coating demonstrated the importance of ligand stability and particle surface area for the prediction of nanoparticle stability.

  17. Examination of a Size-Change Test for Photovoltaic Encapsulation Materials: Preprint

    SciTech Connect (OSTI)

    Miller, D. C.; Wohlgemuth, J. H.; Gu, X.; Ji, L.; Kelly, G.; Gu, X.; Nickel, N.; Norum, P.; Shioda, T.; Tamizhmani, G.

    2012-08-01

    We examine a proposed test standard that can be used to evaluate the maximum representative change in linear dimensions of sheet encapsulation products for photovoltaic modules (resulting from their thermal processing). The proposed protocol is part of a series of material-level tests being developed within Working Group 2 of the Technical Committee 82 of the International Electrotechnical Commission. The characterization tests are being developed to aid module design (by identifying the essential characteristics that should be communicated on a datasheet), quality control (via internal material acceptance and process control), and failure analysis. Discovery and interlaboratory experiments were used to select particular parameters for the size-change test. The choice of a sand substrate and aluminum carrier is explored relative to other options. The temperature uniformity of +/- 5C for the substrate was confirmed using thermography. Considerations related to the heating device (hot-plate or oven) are explored. The time duration of 5 minutes was identified from the time-series photographic characterization of material specimens (EVA, ionomer, PVB, TPO, and TPU). The test procedure was revised to account for observed effects of size and edges. The interlaboratory study identified typical size-change characteristics, and also verified the absolute reproducibility of +/- 5% between laboratories.

  18. Size and concentration measurements of particles produced in commercial chromium plating processes

    SciTech Connect (OSTI)

    Bonin, M.P.; Flower, W.L.; Renzi, R.F.; Peng, L.W.

    1995-11-01

    Optical measurements of particle size and concentration were made at the chromium plating tank and exhaust system at a commercial hexavalent chromium plating facility. Particles were examined at three locations in the exhaust system: (1) directly at the hexavalent chromium plating bath surface, (2) at the exit of a cyclone separator located in the exhaust system approximately three to four meters downstream of the bath, and (3) in the exhaust stack, downstream of the induced draft fan and all abatement devices. Particle diameters at the bath surface ranged from 0.3 to 25 {mu}m. Downstream of the cyclone exit and mesh pad filters, particle top sizes were approximately 5 and 0.7 mm, respectively. On a mass basis, the collection efficiency of all abatement devices was 99.997%. Assuming that droplets in the flow consist primarily of water and chromium, correcting the total particle mass flow against water content gives a chromium emission rate of 64,000 {mu}g/hr, which compares favorably with a value of 77,000 {mu}g/hr measured with EPA methods. This initial agreement, which should be validated through additional measurements over a broad range of flow conditions, raises the possibility of continuous monitoring for chromium metal emissions using particle size/mass as a surrogate. 6 refs., 7 figs.

  19. Photophysics of size-selected InP nanocrystals: Exciton recombination kinetics

    SciTech Connect (OSTI)

    Kim, S.; Wolters, R.H.; Heath, J.R.

    1996-11-01

    We report here on the size-dependent kinetics of exciton recombination in a III{endash}V quantum dot system, InP. The measurements reported include various frequency dependent quantum yields as a function of temperature, frequency dependent luminescence decay curves, and time-gated emission spectra. This data is fit to a three-state quantum model which has been previously utilized to explain photophysical phenomena in II{endash}VI quantum dots. The initial photoexcitation is assumed to place an electron in a (delocalized) bulk conduction band state. Activation barriers for trapping and detrapping of the electron to surface states, as well as activation barriers for surface-state radiationless relaxation processes are measured as a function of particle size. The energy barrier to detrapping is found to be the major factor limiting room temperature band-edge luminescence. This barrier increases with decreasing particle size. For 30 A particles, this barrier is found to be greater than 6 kJ/mol{emdash}a barrier which is more than an order of magnitude larger than that previously found for 32 A CdS nanocrystals. {copyright} {ital 1996 American Institute of Physics.}

  20. Oxidation of activated carbon fibers: Effect on pore size, surface chemistry, and adsorption properties

    SciTech Connect (OSTI)

    Mangun, C.L.; Benak, K.R.; Daley, M.A.; Economy, J.

    1999-12-01

    Activated carbon fibers (ACFs) were oxidized using both aqueous and nonaqueous treatments. As much as 29 wt% oxygen can be incorporated onto the pore surface in the form of phenolic hydroxyl, quinine, and carboxylic acid groups. The effect of oxidation on the pore size, pore volume, and the pore surface chemistry was thoroughly examined. The average micropore size is typically affected very little by aqueous oxidation while the micropore volume and surface area decreases with such a treatment. In contrast, the micropore size and micropore volume both increase with oxidation in air. Oxidation of the fibers produces surface chemistries in the pore that provide for enhanced adsorption of basic (ammonia) and polar (acetone) molecules at ambient and nonambient temperatures. The adsorption capacity of the oxidized fibers for acetone is modestly better than the untreated ACFs while the adsorption capacity for ammonia can increase up to 30 times compared to untreated ACFs. The pore surface chemical makeup was analyzed using elemental analysis, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and X-ray photoelectron spectroscopy (XPS).

  1. Design consideration and economic analysis of a community size biogas unit

    SciTech Connect (OSTI)

    Abbus, S.P.

    1983-12-01

    At present, various organizations in Pakistan are involved in RandD work in biogas technology. Most of them are government organizations. The units developed or advertised by these organizations are of small size, i.e., for a single family, to provide gas for cooking and lighting only. In this paper, the design of a community-size biogas unit for power generation has been discussed based on hydraulic flow characteristics. The type of digesters which have been discussed are plug flow, arbitrary flow and complete mix flow. As the biological activity of the organic material in the reactor depends on the residence time and also on the temperature of the digesting liquor, hence the flow characteristics play a major role in the sizing of the digestion reactor tank. A diesel engine coupled with the biogas unit has been discussed. This not only provides power for pumping water, power for cottage industries, etc., but also the waste heat from the internal combustion engine can be used to heat the digester or for other heating needs. The economic evaluation of such a plant has been completed and the payback period has been calculated.

  2. Supercapacitor Capacitance Exhibits Oscillatory Behavior as a Function of Nanopore Size

    SciTech Connect (OSTI)

    Feng, Guang; Cummings, Peter T

    2011-01-01

    Supercapacitors composed of slit-shaped micropores ranging in size from 0.67 to 1.8 nm in a room-temperature ionic liquid were studied to investigate the dependence of capacitance (C) on the pore size (d) using molecular dynamics simulations. The capacitance versus pore size (i.e., the Cd curve) was found to exhibit two peaks located at 0.7 and 1.4 nm, respectively. Specifically, as the pore shrinks from 1.0 to 0.7 nm, the capacitance of the micropore increases anomalously, in good agreement with experimental observations. We report herein that the second peak within 1.0 to 1.8 nm is a new feature of the Cd curve. Furthermore, by analogy to the wave interference, we demonstrate that the interference of two electrical double layers near each slit wall does not only explain the entire Cd curve, including the anomalous character, but also predicts the oscillatory behavior of Cd curve beyond 1.8 nm.

  3. Device for monitoring cell voltage

    DOE Patents [OSTI]

    Doepke, Matthias (Garbsen, DE); Eisermann, Henning (Edermissen, DE)

    2012-08-21

    A device for monitoring a rechargeable battery having a number of electrically connected cells includes at least one current interruption switch for interrupting current flowing through at least one associated cell and a plurality of monitoring units for detecting cell voltage. Each monitoring unit is associated with a single cell and includes a reference voltage unit for producing a defined reference threshold voltage and a voltage comparison unit for comparing the reference threshold voltage with a partial cell voltage of the associated cell. The reference voltage unit is electrically supplied from the cell voltage of the associated cell. The voltage comparison unit is coupled to the at least one current interruption switch for interrupting the current of at least the current flowing through the associated cell, with a defined minimum difference between the reference threshold voltage and the partial cell voltage.

  4. Solar cells with low cost substrates and process of making same

    DOE Patents [OSTI]

    Mitchell, Kim W. (Indian Hills, CO)

    1984-01-01

    A solar cell having a substrate and an intermediate recrystallized film and a semiconductor material capable of absorbing light with the substrate being selected from one of a synthetic organic resin, graphite, glass and a crystalline material having a grain size less than about 1 micron.sup.2. The intermediate recrystallized film has a grain size in the range of from about 10 microns.sup.2 to about 10,000 microns.sup.2 and a lattice mismatch with the semiconductor material not greater than about 4%. The semiconductor material has a grain size not less than about 10 microns.sup.2. An anti-reflective layer and electrical contact means are provided. Also disclosed is a subcombination of substrate, intermediate recrystallized film and semiconductor material. Also, methods of formulating the solar cell and subcombination are disclosed.

  5. Cell Phone Detection Techniques

    SciTech Connect (OSTI)

    Pratt, Richard M.; Bunch, Kyle J.; Puzycki, David J.; Slaugh, Ryan W.; Good, Morris S.; McMakin, Douglas L.

    2007-10-01

    A team composed of Rick Pratt, Dave Puczyki, Kyle Bunch, Ryan Slaugh, Morris Good, and Doug McMakin teamed together to attempt to exploit cellular telephone features and detect if a person was carrying a cellular telephone into a Limited Area. The cell phones electromagnetic properties were measured, analyzed, and tested in over 10 different ways to determine if an exploitable signature exists. The method that appears to have the most potential for success without adding an external tag is to measure the RF spectrum, not in the cell phone band, but between 240 and 400MHz. Figures 1- 7 show the detected signal levels from cell phones from three different manufacturers.

  6. Assessment of Available Particle Size Data to Support an Analysis of the Waste Feed Delivery System Transfer System

    SciTech Connect (OSTI)

    JEWETT, J.R.

    2000-08-10

    Available data pertaining to size distribution of the particulates in Hanford underground tank waste have been reviewed. Although considerable differences exist between measurement methods, it may be stated with 95% confidence that the median particle size does not exceed 275 {micro}m in at least 95% of the ten tanks selected as sources of HLW feed for Phase 1 vitrification in the RPP. This particle size is recommended as a design basis for the WFD transfer system.

  7. Interband Cascade Photovoltaic Cells

    SciTech Connect (OSTI)

    Yang, Rui Q.; Santos, Michael B.; Johnson, Matthew B.

    2014-09-24

    In this project, we are performing basic and applied research to systematically investigate our newly proposed interband cascade (IC) photovoltaic (PV) cells [1]. These cells follow from the great success of infrared IC lasers [2-3] that pioneered the use of quantum-engineered IC structures. This quantum-engineered approach will enable PV cells to efficiently convert infrared radiation from the sun or other heat source, to electricity. Such cells will have important applications for more efficient use of solar energy, waste-heat recovery, and power beaming in combination with mid-infrared lasers. The objectives of our investigations are to: achieve extensive understanding of the fundamental aspects of the proposed PV structures, develop the necessary knowledge for making such IC PV cells, and demonstrate prototype working PV cells. This research will focus on IC PV structures and their segments for utilizing infrared radiation with wavelengths from 2 to 5 ?m, a range well suited for emission by heat sources (1,000-2,000 K) that are widely available from combustion systems. The long-term goal of this project is to push PV technology to longer wavelengths, allowing for relatively low-temperature thermal sources. Our investigations address material quality, electrical and optical properties, and their interplay for the different regions of an IC PV structure. The tasks involve: design, modeling and optimization of IC PV structures, molecular beam epitaxial growth of PV structures and relevant segments, material characterization, prototype device fabrication and testing. At the end of this program, we expect to generate new cutting-edge knowledge in the design and understanding of quantum-engineered semiconductor structures, and demonstrate the concepts for IC PV devices with high conversion efficiencies.

  8. Dense pattern optical multipass cell

    DOE Patents [OSTI]

    Silver, Joel A [Santa Fe, NM

    2009-01-13

    A multiple pass optical cell and method comprising providing a pair of opposed cylindrical mirrors having curved axes with substantially equal focal lengths, positioning an entrance hole for introducing light into the cell and an exit hole for extracting light from the cell, wherein the entrance hole and exit hole are coextensive or non-coextensive, introducing light into the cell through the entrance hole, and extracting light from the cell through the exit hole.

  9. Dense pattern multiple pass cells

    DOE Patents [OSTI]

    Silver, Joel A. (Santa Fe, NM); Bomse, David S. (Santa Fe, NM)

    2010-09-21

    An optical cell and a method of operating an optical cell comprising employing a first mirror comprising a first hole therein at approximately a center of the first mirror and through which laser light enters the cell, employing a second mirror comprising a second hole therein at approximately a center of the second mirror and through which laser light exits the cell, and forming a Lissajous pattern of spots on the mirrors by repeated reflection of laser light entering the cell.

  10. Electrode for electrochemical cell

    DOE Patents [OSTI]

    Kaun, T.D.; Nelson, P.A.; Miller, W.E.

    1980-05-09

    An electrode structure for a secondary electrochemical cell includes an outer enclosure defining a compartment containing electrochemical active material. The enclosure includes a rigid electrically conductive metal sheet with perforated openings over major side surfaces. The enclosure can be assembled as first and second trays each with a rigid sheet of perforated electrically conductive metal at major side surfaces and normally extending flanges at parametric margins. The trays can be pressed together with moldable active material between the two to form an expandable electrode. A plurality of positive and negative electrodes thus formed are arranged in an alternating array with porous frangible interelectrode separators within the housing of the secondary electrochemical cell.

  11. Fuel cell stack arrangements

    DOE Patents [OSTI]

    Kothmann, Richard E. (Churchill Boro, PA); Somers, Edward V. (Murrysville, PA)

    1982-01-01

    Arrangements of stacks of fuel cells and ducts, for fuel cells operating with separate fuel, oxidant and coolant streams. An even number of stacks are arranged generally end-to-end in a loop. Ducts located at the juncture of consecutive stacks of the loop feed oxidant or fuel to or from the two consecutive stacks, each individual duct communicating with two stacks. A coolant fluid flows from outside the loop, into and through cooling channels of the stack, and is discharged into an enclosure duct formed within the loop by the stacks and seals at the junctures at the stacks.

  12. Aluminum reduction cell electrode

    DOE Patents [OSTI]

    Payne, John R. (Pleasanton, CA)

    1983-09-20

    The invention is directed to an anode-cathode structure for an electrolytic cell for the reduction of alumina wherein the structure is comprised of a carbon anode assembly which straddles a wedge-shaped refractory hard metal cathode assembly having steeply sloped cathodic surfaces, each cathodic surface being paired in essentially parallel planar relationship with an anode surface. The anode-cathode structure not only takes into account the structural weakness of refractory hard metal materials but also permits the changing of the RHM assembly during operation of the cell. Further, the anode-cathode structure enhances the removal of anode gas from the interpolar gap between the anode and cathode surfaces.

  13. Fuel Cells Go Live

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    green h y d r o g e n f u e l i n g POWer Fuel Cells Go live A closer look at the requirements to create a hydrogen-based warehouse M anagers of distribution centers are always on the lookout for new ways to gain competitive advantage through increased operational efficiency, productivity and worker safety. Around North America, some are finding success by integrating commercially available hydrogen fuel cell systems into their lift truck fleets. For operations with large fleets of electric lift

  14. Monolithic tandem solar cell

    DOE Patents [OSTI]

    Wanlass, Mark W. (Golden, CO)

    1991-01-01

    A single-crystal, monolithic, tandem, photovoltaic solar cell is described which includes (a) an InP substrate having upper and lower surfaces, (b) a first photoactive subcell on the upper surface of the InP substrate, and (c) a second photoactive subcell on the first subcell. The first photoactive subcell is GaInAsP of defined composition. The second subcell is InP. The two subcells are lattice matched. The solar cell can be provided as a two-terminal device or a three-terminal device.

  15. Separators for electrochemical cells

    DOE Patents [OSTI]

    Carlson, Steven Allen; Anakor, Ifenna Kingsley

    2014-11-11

    Provided are separators for use in an electrochemical cell comprising (a) an inorganic oxide and (b) an organic polymer, wherein the inorganic oxide comprises organic substituents. Preferably, the inorganic oxide comprises an hydrated aluminum oxide of the formula Al.sub.2O.sub.3.xH.sub.2O, wherein x is less than 1.0, and wherein the hydrated aluminum oxide comprises organic substituents, preferably comprising a reaction product of a multifunctional monomer and/or organic carbonate with an aluminum oxide, such as pseudo-boehmite and an aluminum oxide. Also provided are electrochemical cells comprising such separators.

  16. Getting More Electricity out of Solar Cells | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Getting More Electricity out of Solar Cells Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events EFRC News EFRC Events DOE Announcements Publications History Contact BES Home 05.27.14 Getting More Electricity out of Solar Cells Print Text Size: A A A Subscribe FeedbackShare Page New MIT model can guide design of solar cells that produce less waste heat, more useful current. This work, featured in the Office of Science's Stories of

  17. Exact solution of the thermodynamics and size parameters of a polymer confined to a lattice of finite size: Large chain limit

    SciTech Connect (OSTI)

    Snyder, Chad R. Guttman, Charles M.; Di Marzio, Edmund A.

    2014-01-21

    We extend the exact solutions of the Di Marzio-Rubin matrix method for the thermodynamic properties, including chain density, of a linear polymer molecule confined to walk on a lattice of finite size. Our extensions enable (a) the use of higher dimensions (explicit 2D and 3D lattices), (b) lattice boundaries of arbitrary shape, and (c) the flexibility to allow each monomer to have its own energy of attraction for each lattice site. In the case of the large chain limit, we demonstrate how periodic boundary conditions can also be employed to reduce computation time. Advantages to this method include easy definition of chemical and physical structure (or surface roughness) of the lattice and site-specific monomer-specific energetics, and straightforward relatively fast computations. We show the usefulness and ease of implementation of this extension by examining the effect of energy variation along the lattice walls of an infinite rectangular cylinder with the idea of studying the changes in properties caused by chemical inhomogeneities on the surface of the box. Herein, we look particularly at the polymer density profile as a function of temperature in the confined region for very long polymers. One particularly striking result is the shift in the critical condition for adsorption due to surface energy inhomogeneities and the length scale of the inhomogeneities; an observation that could have important implications for polymer chromatography. Our method should have applications to both copolymers and biopolymers of arbitrary molar mass.

  18. Solar Cell Simulation

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Students model the flow of energy from the sun as it enters a photovoltaic cell, moves along a wire and powers a load. The game-like atmosphere involves the younger students and helps them understand the continuous nature of the flow of energy. For a related lesson, please see the activity “Solar Powered System” (PDF 430 KB).

  19. Thin film photovoltaic cell

    DOE Patents [OSTI]

    Meakin, John D. (Newark, DE); Bragagnolo, Julio (Newark, DE)

    1982-01-01

    A thin film photovoltaic cell having a transparent electrical contact and an opaque electrical contact with a pair of semiconductors therebetween includes utilizing one of the electrical contacts as a substrate and wherein the inner surface thereof is modified by microroughening while being macro-planar.

  20. Fuel Cell Case Study

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kathy Loftus Global Leader, Sustainable Engineering, Maintenance & Energy Management Whole Foods Market, Inc. Fuel Cell Case Study 2 Holistic Approach from Development to Operation WFM Energy Management Negotiation Awareness Load Shaping Engineering Refrigeration HVAC Electrical Maintenance Performance Based Retailers Operational Practices Store Design & Construction Consultants Specifications Procurement Equipment Selection Life Cycle Costing Energy & Maintenance team can feedback