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Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

S M Stoller Pinellas Environmental Restoration Project - 4.5...  

Office of Legacy Management (LM)

Chloroform ND 1.0 0.50 ugl 110-75-8 2-Chloroethyl vinyl ether ND 5.0 2.5 ugl 56-23-5 Carbon tetrachloride ND 1.0 0.50 ugl 75-34-3 1,1-Dichloroethane ND 1.0 0.50 ugl 75-35-4...

2

S M Stoller Star Center-WWNA Monthly; Largo, FL  

Office of Legacy Management (LM)

Chloroform ND 1.0 0.50 ugl 110-75-8 2-Chloroethyl vinyl ether ND 5.0 2.5 ugl 56-23-5 Carbon tetrachloride ND 1.0 0.50 ugl 75-34-3 1,1-Dichloroethane ND 1.0 0.50 ugl 75-35-4...

3

S M Stoller Monthly Sampling, STAR Center, Largo, FL  

Office of Legacy Management (LM)

Chloroform ND 1.0 0.50 ugl 110-75-8 2-Chloroethyl vinyl ether ND 5.0 2.5 ugl 56-23-5 Carbon tetrachloride ND 1.0 0.50 ugl 75-34-3 1,1-Dichloroethane ND 1.0 0.50 ugl 75-35-4...

4

Biosynthesis and urinary excretion of methyl sulfonium derivatives of the sulfur mustard analog, 2-chloroethyl ethyl sulfide, and other thioethers  

SciTech Connect (OSTI)

Thioether methyltransferase was previously shown to catalyze the S-adenosylmethionine-dependent methylation of diemthyl selenide, dimethyl telluride, and various thioethers to produce the corresponding methyl onium ions. In this paper we show that the following thioethers are also substrates for this enzyme in vitro: 2-hydroxyethyl ethyl sulfide, 2-chloroethyl ethyl sulfide, thiodiglycol, t-butyl sulfide, and isopropyl sulfide. To demonstrate thioether methylation in vivo, mice were injected with (methyl-{sup 3}H)methionine plus different thioethers, and extracts of lungs, livers, kidneys, and urine were analyzed by high-performance liquid chromatography for the presence of ({sup 3}H)methyl sulfonium ions. The following thioethers were tested, and all were found to be methylated in vivo: dimethyl sulfide, diethyl sulfide, methyl n-propyl sulfide, tetrahydrothiophene, 2-(methylthio)ethylamine, 2-hydroxyethyl ethyl sulfide, and 2-chloroethyl ethyl sulfide. This supports our hypothesis that the physiological role of thioether methyltransferase is to methylate seleno-, telluro-, and thioethers to more water-soluble onium ions suitable for urinary excretion. Conversion of the mustard gas analog, 2-chloroethyl ethyl sulfide, to the methyl sulfonium derivative represents a newly discovered mechanism for biochemical detoxification of sulfur mustards, as this conversion blocks formation of the reactive episulfonium ion that is the ultimate alkylating agent for this class of compounds.

Mozier, N.M.; Hoffman, J.L. (Univ. of Louisville, KY (USA))

1990-12-01T23:59:59.000Z

5

Miscoding properties of 1,N{sup 6}-ethanoadenine, a DNA adduct derived from reaction with antitumor agent 1,3-bis(2-chloroethyl)-1-nitrosourea  

SciTech Connect (OSTI)

1,N{sup 6}-Ethanoadenine (EA) is an exocyclic adduct formed from DNA reaction with the antitumor agent, 1,3-bis(2-chloroethyl)-1-nitrosourea (BCNU). To understand the role of this adduct in the mechanism of mutagenicity or carcinogenicity by BCNU, an oligonucleotide with a site-specific EA was synthesized using phosphoramidite chemistry. We now report the in vitro miscoding properties of EA in translesion DNA synthesis catalyzed by mammalian DNA polymerases (pols) {alpha}, {beta}, {eta} and {iota}. These data were also compared with those obtained for the structurally related exocyclic adduct, 1,N{sup 6}-ethenoadenine ({var_epsilon}A). Using a primer extension assay, both pols {alpha} and {beta} were primarily blocked by EA or {var_epsilon}A with very minor extension. Pol {eta} a member of the Y family of polymerases, was capable of catalyzing a significant amount of bypass across both adducts. Pol {eta} incorporated all four nucleotides opposite EA and {var_epsilon}A, but with differential preferences and mainly in an error-prone manner. Human pol {iota}, a paralog of human pol {eta}, was blocked by both adducts with a very small amount of synthesis past {var_epsilon}A. It incorporated C and, to a much lesser extent, T, opposite either adduct. In addition, the presence of an A adduct, e.g. {var_epsilon}A, could affect the specificity of pol {iota} toward the template T immediately 3 feet to the adduct. In conclusion, the four polymerases assayed on templates containing an EA or {var_epsilon}A showed differential bypass capacity and nucleotide incorporation specificity, with the two adducts not completely identical in influencing these properties. Although there was a measurable extent of error-free nucleotide incorporation, all these polymerases primarily misincorporated opposite EA, indicating that the adduct, similar to {var_epsilon}A, is a miscoding lesion.

Hang, Bo; Guliaev, Anton B.; Chenna, Ahmed; Singer, B.

2003-03-05T23:59:59.000Z

6

Preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, Gerald Charles (Kingsport, TN); Zoeller, Joseph Robert (Kingsport, TN); Depew, Leslie Sharon (Kingsport, TN)

1998-01-01T23:59:59.000Z

7

Preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting a mixture of hydrogen and ketene with a heterogeneous catalyst containing a transition metal to produce acetaldehyde, which is then reacted with ketene in the presence of an acid catalyst to produce vinyl acetate.

Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

1998-03-24T23:59:59.000Z

8

Copolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Metal Catalyst  

E-Print Network [OSTI]

monomers with polar functionality (such as vinyl acetate (VA), vinyl chloride (VC), and acrylates).1 OverCopolymerization Studies of Vinyl Chloride and Vinyl Acetate with Ethylene Using a Transition-Flory constants were identical (0.81) for the ethylene homopolymerizations and the ethylene/vinyl chloride

Goddard III, William A.

9

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M [Stanford, CA; Muller, Jochen A [Baltimore, MD; Rosner, Bettina M [Berlin, DE; Von Abendroth, Gregory [Mannheim, DE; Meshulam-Simon, Galit [Los Angeles, CA; McCarty, Perry L [Stanford, CA

2014-02-11T23:59:59.000Z

10

Microbial reductive dehalogenation of vinyl chloride  

DOE Patents [OSTI]

Compositions and methods are provided that relate to the bioremediation of chlorinated ethenes, particularly the bioremediation of vinyl chloride by Dehalococcoides-like organisms. An isolated strain of bacteria, Dehalococcoides sp. strain VS, that metabolizes vinyl chloride is provided; the genetic sequence of the enzyme responsible for vinyl chloride dehalogenation; methods of assessing the capability of endogenous organisms at an environmental site to metabolize vinyl chloride; and a method of using the strains of the invention for bioremediation.

Spormann, Alfred M. (Stanford, CA); Muller, Jochen A. (Baltimore, MD); Rosner, Bettina M. (Berlin, DE); Von Abendroth, Gregory (Nannhein, DE); Meshulam-Simon, Galit (Los Altos, CA); McCarty, Perry L (Stanford, CA)

2011-11-22T23:59:59.000Z

11

Rheology of silicon carbide/vinyl ester nanocomposites  

E-Print Network [OSTI]

New York, 1999. SILICON CARBIDE/VINYL ESTER NANOCOMPOSITESRheology of Silicon Carbide/Vinyl Ester NanocompositesABSTRACT: Silicon carbide (SiC) nanoparticles with no

Yong, Virginia; Hahn, H. Thomas

2006-01-01T23:59:59.000Z

12

Guidance Document Carcinogenic Substances  

E-Print Network [OSTI]

Mustard gas (bis(2-chloroethyl)sulfide) Formaldehyde (gas) Vinyl chloride Acetaldehyde Carbon tetrachloride 1,4-Dioxane Chloroform Ethyl carbamate (uret 3-Chloro-2-methylpropene Hexamethylphosphor 1

13

Low pressure vinylation of aryl and vinyl halides via HeckMizoroki reactions using ethylene  

E-Print Network [OSTI]

Low pressure vinylation of aryl and vinyl halides via Heck­Mizoroki reactions using ethylene Craig with ethylene under ambient pressure (15­30 psi) to give the corresponding vinylarenes. The reactions work of ethylene) of functionalized vinylarenes and 1,3-di- enes.4 When fully developed, we hope, many

RajanBabu, T. V. "Babu"

14

Emulsion polymerization of ethylene-vinyl acetate-branched vinyl ester using a pressure reactor system.  

E-Print Network [OSTI]

??A new pressure reactor system was designed to synthesize a novel branched ester-ethylene-vinyl acetate (BEEVA) emulsion polymer. The reactor system was capable of handling pressure (more)

Tan, Chee Boon

2008-01-01T23:59:59.000Z

15

Process for the preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85.degree. and 200.degree. C. and removing the reaction products from the contact zone.

Tustin, Gerald Charles (Kingsport, TN); Zoeller, Joseph Robert (Kingsport, TN); Depew, Leslie Sharon (Kingsport, TN)

1998-01-01T23:59:59.000Z

16

Process for the preparation of vinyl acetate  

DOE Patents [OSTI]

This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85 and 200 C and removing the reaction products from the contact zone.

Tustin, G.C.; Zoeller, J.R.; Depew, L.S.

1998-02-17T23:59:59.000Z

17

Effects of stereochemistry and ?-substituents on the rates of vinylic SN2 reaction of hypervalent vinyl(phenyl)-?3-iodanes with tetrabutylammonium halides  

Science Journals Connector (OSTI)

Both stereoisomers of ?-(2-phenylethoxy)vinyl-?3-iodane and (Z)-?-aroyloxyvinyl-?3-iodane were prepared stereoselectively. These substituted vinyl-?3-iodanes undergo nucleophilic vinylic substitutions with n-Bu4NX (X=Cl, Br, I) under mild conditions, yielding vinyl halides. The observed inversion of configuration at the ipso vinylic carbon atom is compatible with a concerted vinylic SN2 mechanism. Kinetic measurements indicated that the rates for vinylic SN2 reaction of (Z)-vinyl-?3-iodane are greater than those of the E-isomer, probably because of the higher ground state energy of the Z-isomer. Electronic effects of ?-substituents of vinyl-?3-iodanes in the vinylic SN2 reaction are also discussed.

Kazunori Miyamoto; Takuji Okubo; Masaya Hirobe; Munetaka Kunishima; Masahito Ochiai

2010-01-01T23:59:59.000Z

18

VINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING  

E-Print Network [OSTI]

. The "irreversible effects threshold" is the maximum concentration of pollutant in the air for a given exposure timeVINYL CHLORIDE ACUTE TOXICITY THRESHOLDS IN THE CONTEXT OF CONTROLLING URBAN DEVELOPMENT OR LAND of vinyl Chloride , the french procedure to set acute toxicity thresholds in the context of controlling

Boyer, Edmond

19

Reduction of Vinyl Chloride in Metallic Iron-Water Systems  

E-Print Network [OSTI]

residence time for contaminated ground- water to degrade VC to below its maximum contamination levelReduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department). Remediation of groundwater contaminated with chlori- nated ethylenes, including vinyl chloride, has been chal

Deng, Baolin

20

Why sequence ethene and vinyl chloride-oxidizing Mycobacterium strains?  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sequence ethene and vinyl sequence ethene and vinyl chloride-oxidizing Mycobacterium strains? Mycobacteria are known for causing human and animal diseases but they are also important degraders of hard-to-break-down water contaminants such as polyaromatic hydrocarbons (PAHs) and methyl tert-butyl ether (MTBE). So far the handful of bacterial species representing the Mycobacterium genus that have been sequenced all break down PAHs. In this project, researchers focus on the genomes of mycobacterial species isolated from soil, freshwater and marine environments that use the alkene compounds ethene and vinyl chloride as carbon sources. Chlorinated ethene compounds are difficult to remove from contaminated groundwater but necessary because of their toxicity. Additionally these compounds reduce the ozone levels in the atmosphere.

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Research Needs: Glass Solar Reflectance and Vinyl Siding  

SciTech Connect (OSTI)

The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

2011-07-07T23:59:59.000Z

22

Reactor-chromatographic determination of vinyl chloride in polyvinyl chloride  

SciTech Connect (OSTI)

The authors carry out a chromatographic study of the volatile products that evolve when various grades of domestic polyvinyl chloride are heated, to determine the concentration of residual monomer. To find vinyl chloride in complex mixtures of air pollutants the authors used sorptive reaction concentration of impurities. This new combination of methods is based on preliminary separation at the sampling stage of impurities that interfere in the analysis, followed by concentration of the desired components in a trap with an adsorbent, and chromatographic determination of the concentrated trace materials. The method obtains low vinyl chloride concentrations (down to 10/sup -4/-10/sup -5/ wt. %) with +/-5 relative error.

Berezkin, V.G.

1986-08-01T23:59:59.000Z

23

Synthesis of vinyl acetate on palladium-based catalysts  

E-Print Network [OSTI]

Vinyl acetate (VA) is an important monomer used in the production of paints, surface coatings and adhesives. Synthesis of VA is usually carried out over supported Pd alloy catalysts with a selectivity as high as 96% and described as C2H4 + CH3COOH...

Kumar, Dheeraj

2009-06-02T23:59:59.000Z

24

Vinyl Kraft Windows and Doors | Open Energy Information  

Open Energy Info (EERE)

Vinyl Kraft Windows and Doors Vinyl Kraft Windows and Doors Jump to: navigation, search Name Vinyl Kraft Windows and Doors Address 3404 Rhodes Ave Place New Boston, Ohio Zip 45662 Sector Buildings, Efficiency, Services Product Business and legal services;Consulting;Energy audits/weatherization; Installation; Maintenance and repair;Manufacturing; Retail product sales and distribution Phone number 740-464-0144 Website http://www.vinylkraft.com Coordinates 38.7456°, -82.9459° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.7456,"lon":-82.9459,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

25

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide  

Science Journals Connector (OSTI)

Electronic Structure Calculations on the Reaction of Vinyl Radical with Nitric Oxide ... Methyl isocyanate 19 is calculated to be the most stable isomer. ... Methods of Calculation ...

Raman Sumathi; Hue Minh Thi Nguyen; Minh Tho Nguyen; Jozef Peeters

2000-02-15T23:59:59.000Z

26

Chemical modification of poly(vinyl chloride) with nitrogen nucleophiles assisted by microwave irradiation.  

E-Print Network [OSTI]

??In this work we had performed nucleophilic substitution reactions (Sn2) of some chlorine atoms in commercial samples of poly (vinyl chloride) (PVC), nitrile groups and (more)

Mauro Vincius Almeida da Silva

2013-01-01T23:59:59.000Z

27

Vinyl chloride monomer and other contaminants in PVC welding fumes  

SciTech Connect (OSTI)

An investigation into the nature of fumes produced during thermal welding of plasticized PVC sheeting has been carried out with the objective of determining if the known carcinogen vinyl chloride monomer (VCM) is formed and to assess the level of exposure to the operator. The results show that the atmospheric concentrations of VCM are well below accepted occupational exposure limits. This finding is consistent with reports in the technical literature which suggest that VCM is produced during thermal degradation of PVC only at temperatures considerably higher than those encountered during plastic welding.

Williamson, J.; Kavanagh, B.

1987-05-01T23:59:59.000Z

28

Cytotoxicity of N,N-Bis(2-chloroethyl)-N-nitrosourea in Hypoxic Rat Hepatocytes  

Science Journals Connector (OSTI)

...AMP were used to calculate the energy from the formula [ATP...BCNU. Effects of BCNU on Cellular Energy Charge. The efflux of glutathione...concentration on cellular adenine nucleo tide contents and energy charge. Isolated hepatocytes were...

James C. Veltman and M. W. Anders

1987-10-01T23:59:59.000Z

29

Microcontact Imprinting of Algae on Poly(ethylene-co-vinyl alcohol) for Biofuel Cells  

Science Journals Connector (OSTI)

Microcontact Imprinting of Algae on Poly(ethylene-co-vinyl alcohol) for Biofuel Cells ... The roadmap of algae biofuels technology in the U.S. has been elucidated since 2008 (http://www.orau.gov/algae2008/resources.htm). ...

Wen-Janq Chen; Mei-Hwa Lee; James L. Thomas; Po-Hsun Lu; Ming-Huan Li; Hung-Yin Lin

2013-10-06T23:59:59.000Z

30

Degradation of Vinyl Chloride and 1,2-Dichloroethane by Advanced Reduction Processes  

E-Print Network [OSTI]

A new treatment technology, called Advanced Reduction Process (ARP), was developed by combining UV irradiation with reducing reagents to produce highly reactive species that degrade contaminants rapidly. Vinyl chloride (VC) and 1,2-dichloroethane (1...

Liu, Xu

2013-07-27T23:59:59.000Z

31

Cohort and case-control analyses of workers exposed to vinyl chloride: An update  

SciTech Connect (OSTI)

The mortality in a cohort of workers at a vinyl chloride polymerization plant has been updated, extending the period of observation in the original study from 1974 to 1986. Workers at this plant may have been exposed to vinyl chloride monomer and/or polyvinyl chloride dust, or may have had no exposure to either substance. Seventy-six percent of the work force worked in jobs with potential exposure to vinyl chloride monomer. Among the total cohort, statistically significant excess risks were observed for liver, lung, and brain cancer. For the subcohort of workers exposed to vinyl chloride monomer, the standardized mortality ratio (SMR) for liver cancer was 333 (90% confidence interval (CI) 202 to 521). However, there were no significant excesses of either brain (SMR = 145, 90% CI 78 to 249) or lung cancer (SMR = 115, 90% CI 96 to 141). To investigate dose response, nested case-control studies for liver, brain, and lung cancer were conducted among the total cohort (including the nonexposed). For these studies there were two exposure variables, cumulative dose of vinyl chloride monomer and cumulative dose of polyvinyl chloride dust. Cumulative dose was defined as the product of level and duration of exposure. The only significant association between disease risk and cumulative dose was for liver cancer and cumulative dose of vinyl chloride monomer. Further division of the liver cancers into angiosarcoma (n = 12) and other liver cancers (n = 7), based on review of death certificates and medical records, showed that the dose response existed only for angiosarcomas.

Wu, W.A.; Steenland, K.; Brown, D.; Wells, V.; Jones, J.; Schulte, P.; Halperin, W.

1989-06-01T23:59:59.000Z

32

Processing Research snd Development of Green Polymer Nanoclay Composites Containing a Polyhydroxybutyrate, Vinyl Acetates, and Modified Montmorillonite Clay.  

E-Print Network [OSTI]

??The purpose of this research was to determine the feasibility of direct melt-blending (intercalation) montmorillonite nanoclay to polyhydroxybutyrate along with vinyl acetate, at different weight (more)

McKirahan, James N. Jr.

2013-01-01T23:59:59.000Z

33

Nucleophilic vinylic substitutions of (Z)-(2-aroyloxyvinyl)phenyl-?3-iodanes with tetrabutylammonium halides: vinylic SN2 reactions and ligand coupling on iodine(III)  

Science Journals Connector (OSTI)

Treatment of (Z)-(?-benzoyloxyvinyl)phenyl-?3-iodanes, readily prepared from ethynyl(phenyl)(tetrafluoroborato)-?3-iodane via stereoselective Michael-type addition of benzoic acids in methanol in the presence of sodium benzoates, with tetrabutylammonium halides in THF at 65C results in a vinylic SN2 reaction to give the inverted (E)-?-benzoyloxyvinyl halides in high yields.

Masahito Ochiai; Yoshio Nishi; Masaya Hirobe

2005-01-01T23:59:59.000Z

34

Room Temperature Copper(II)-Catalyzed Oxidative Cyclization of Enamides to 2,5-Disubstituted Oxazoles via Vinylic CH Functionalization  

E-Print Network [OSTI]

A copper(II)-catalyzed oxidative cyclization of enamides to oxazoles via vinylic CH bond functionalization at room temperature is described. Various 2,5-disubstituted oxazoles bearing aryl, vinyl, alkyl, and heteroaryl ...

Cheung, Chi Wai

35

Structural and electronic properties of poly(vinyl alcohol) using density functional theory  

SciTech Connect (OSTI)

The first principles calculations have been carried out to investigate the structural, electronic band structure density of states along with the projected density of states for poly(vinyl alcohol). Our structural calculation suggests that the poly(vinyl alcohol) exhibits monoclinic structure. The calculated structural lattice parameters are in excellent agreement with available experimental values. The band structure calculations reveal that the direct and indirect band gaps are 5.55 eV and 5.363 eV respectively in accordance with experimental values.

Dabhi, Shweta, E-mail: shwetadabhi1190@gmail.com; Jha, Prafulla K., E-mail: shwetadabhi1190@gmail.com [Department of Physics, Maharaja Krishnakumasinhji Bhavnagar University, Bhavnagar-364001 (India)

2014-04-24T23:59:59.000Z

36

Inversion versus Retention of Configuration for Nucleophilic Substitution at Vinylic Carbon  

E-Print Network [OSTI]

of Glukhovtsev, Pross, and Radom that the SN2 reaction of Cl- with unactivated vinyl chloride in the gas phase. However, moderately activated dihaloethylenes such as 1-chloro-1-fluoroethylene undergo gas-phase SN2. It is generally assumed that bimolecular SN2 nucleophilic substitution at saturated carbon (sp3) proceeds

Schlegel, H. Bernhard

37

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures  

E-Print Network [OSTI]

Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures James D. Van de Ven, unpigmented state are highly transmissive of light in the near-infrared range, thus allowing laser of light detection [2, 3]. Within the near-infrared region nat- ural polymers have nearly no absorption [2

Van de Ven, James D.

38

Effect of composite microstructure on electrical and mechanical properties of poly(vinyl acetate) composites with carbon black and clay.  

E-Print Network [OSTI]

The electrical and mechanical behavior of carbon black filled poly(vinyl acetate) latex-based and solution-based polymer composites was examined. A set of experiments were performed to distinguish composites with a segregated network (emulsion...

Miriyala, Sethu M.

2009-05-15T23:59:59.000Z

39

Palladium-Catalyzed Enantioselective ?-Arylation and ?-Vinylation of Oxindoles Facilitated by an Axially Chiral P-Stereogenic Ligand  

E-Print Network [OSTI]

The enantioselective ?-arylation and ?-vinylation of oxindoles catalyzed by Pd and a biarylmonophosphine ligand with both axial and phosphorus-based chirogenicity is reported. The resultant quaternary carbon stereocenters ...

Taylor, Alexander M.

40

Diffusion of Binary Non-solvent Mixtures in Polymers: Aqueous Ethanol Solutions in Poly(vinyl acetate)  

Science Journals Connector (OSTI)

The diffusion of binary non-solvent mixtures of ethanol and deuterium oxide (D2O) into poly(vinyl acetate) (PVAc) was studied by FT-IR imaging. Initial diffusion rates...

Rafferty, Denise Wade; Koenig, Jack L

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Modifications in the correlation function in poly(vinyl alcohol)/silica hybrid wet gels  

Science Journals Connector (OSTI)

Small-angle X-ray scattering was used to study modifications in the correlation function in tetraethoxysilane-derived poly(vinyl alcohol)/silica hybrids. An additional scattering at low q was found to overlap the fundamental mass-fractal scattering from the basic silica. The fraction of both contributions to the total correlation function was estimated; this is the first time that such a study has been carried out for mass-fractal structures.

Vollet, D.R.

2008-11-28T23:59:59.000Z

42

Evaluation of the association between birth defects and exposure to ambient vinyl chloride  

SciTech Connect (OSTI)

Birth defects incidence for infants born to residents of Shawinigan, Canada in 1966-1979 were significantly higher than in three comparison communities. Since there has been a vinyl chloride polymerization plant in this town since 1943 from which ten cases of angiosarcoma of the liver have been identified, this study explores the possible association between exposure to vinyl chloride monomer (VCM) in ambient air and the occurrence of birth defects in the community. The excess of birth defects fluctuated seasonally in a way that corresponded to changes in VCM concentration in the environment. Mothers who gave birth to malformed children were younger on average in Shawinigan than in the comparison communities. However, there was no excess of still-births in Shawinigan. The excess in birth defects involved most organ systems, and variation in birth-defect rates among school districts could not be accounted for by estimates of VCM in the atmosphere. The occupational and residential histories of parents who gave birth to malformed infants were compared with those of parents of normal infants. The two groups did not differ in occupational exposure or closeness of residence to the vinyl chloride polymerization plant. Some descriptive data from this study raised the hypothesis of an association between VCM in the air and birth defects in the exposed community, but as a whole, within the sample size available, such an association could not be substantiated.

Theriault, G.; Iturra, H.; Gingras, S.

1983-06-01T23:59:59.000Z

43

A study of the effects of nanoparticle modification on the thermal, mechanical and hygrothermal performance of carbon/vinyl ester composites.  

E-Print Network [OSTI]

?? Enhancement of mechanical, thermal and hygrothermal properties of carbon fiber/vinyl ester (CFVE) composites through nanoparticle reinforcement has been investigated. CFVE composites are becoming more (more)

Powell, Felicia M.

2012-01-01T23:59:59.000Z

44

A study of the effects of nanoparticle modification on the thermal, mechanical and hygrothermal performance of carbon/vinyl ester compounds.  

E-Print Network [OSTI]

??Enhancement of mechanical, thermal and hygrothermal properties of carbon fiber/vinyl ester (CFVE) composites through nanoparticle reinforcement has been investigated. CFVE composites are becoming more and (more)

Powell, Felicia M.

2012-01-01T23:59:59.000Z

45

Effect of ethylene-vinyl acetate copolymer-based depressants on the low-temperature properties of components of light- and heavy-grade marine fuels  

Science Journals Connector (OSTI)

The possibility of using ethylene copolymers with vinyl acetate as additives for light and heavy distillate marine fuels for improving their low-temperature properties has...

N. K. Kondrasheva

2013-09-01T23:59:59.000Z

46

Solid Sorbent Collection and Gas Chromatographic Determination of Bis(2-chloroethyl)sulfide in Air at Trace Concentrations  

Science Journals Connector (OSTI)

......mustard vapor from a vapor generator continuously through two sampling...vapor concentration in the generator was about 40 g/m3 . In addition...Dressier. Hydrocarbon and water quenching of the flame photometric...in monitoring devices for atmospheric oxidants. Anal. Lett. 14A......

William K. Fowler; Josiah E. Smith; Jr.

1990-03-01T23:59:59.000Z

47

In Vivo Clonogenic Tumor Cell Kinetics following 1,3-Bis(2-chloroethyl)-1-Nitrosourea Brain Tumor Therapy  

Science Journals Connector (OSTI)

...2-chlorcethyl)-1-nitrosourea; CFE, colony-forming efficiency; LD,0...occasionally are noted. A comparison of the CFE between untreated tumors and tumors treated...for a tumor with an untreated CFEof 25%. CFE (treated)= 2/14 2@ 16 A. Measured...

Mark L. Rosenblum; Kathy D. Knebel; Dolores A. Vasquez; Charles B. Wilson

1976-10-01T23:59:59.000Z

48

European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.25 MODELLING THE CURING DYNAMICS OF ETHYLENE-VINYL ACETATE  

E-Print Network [OSTI]

.25 MODELLING THE CURING DYNAMICS OF ETHYLENE-VINYL ACETATE S. Kajari-Schröder1 , U. Eitner1 , C. Oprisoni2 , T Hannover, Germany ABSTRACT: The encapsulation of solar cells in polymeric sheets such as ethylene PV module [1]. Ethylene-vinyl acetate (EVA) is the most common encapsulant in the PV industry

49

Genome Sequence of the Ethene- and Vinyl Chloride-Oxidizing Actinomycete Nocardioides sp Strain JS614  

SciTech Connect (OSTI)

Nocardioides sp. strain JS614 grows on ethene and vinyl chloride (VC) as sole carbon and energy sources and is of interest for bioremediation and biocatalysis. Sequencing of the complete genome of JS614 provides insight into the genetic basis of alkene oxidation, supports ongoing research into the physiology and biochemistry of growth on ethene and VC, and provides biomarkers to facilitate detection of VC/ethene oxidizers in the environment. This is the first genome sequence from the genus Nocardioides and the first genome of a VC/ethene-oxidizing bacterium.

Coleman, Nicholas V [University of Sydney, Australia; Wilson, Neil L [University of Sydney, Australia; Barry, Kerrie [U.S. Department of Energy, Joint Genome Institute; Bruce, David [Los Alamos National Laboratory (LANL); Copeland, A [U.S. Department of Energy, Joint Genome Institute; Dalin, Eileen [U.S. Department of Energy, Joint Genome Institute; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Glavina Del Rio, Tijana [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Han, Shunsheng [Los Alamos National Laboratory (LANL); Hauser, Loren John [ORNL; Israni, Sanjay [U.S. Department of Energy, Joint Genome Institute; Kim, Edwin [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Larimer, Frank W [ORNL; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Richardson, Paul [U.S. Department of Energy, Joint Genome Institute; Schmutz, Jeremy [Stanford University; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Thompson, Sue [Los Alamos National Laboratory (LANL); Tice, Hope [U.S. Department of Energy, Joint Genome Institute; Spain, Jim C [Georgia Institute of Technology; Gossett, James G [Cornell University; Mattes, Timothy E [University of Iowa

2011-01-01T23:59:59.000Z

50

European Photovoltaic Solar Energy Conference, Valencia, Spain, 6-10 September 2010, 4AV.3.115 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS  

E-Print Network [OSTI]

.115 1 NON-LINEAR MECHANICAL PROPERTIES OF ETHYLENE-VINYL ACETATE (EVA) AND ITS RELEVANCE ABSTRACT: Polymers such as ethylene-vinyl acetate (EVA) encapsulants are known for their non for PV modules is ethylene-vinyl acetate (EVA). It is thus essential for mechanical module and lamination

51

Crystallization in the Thin and Ultrathin Films of Poly(ethylene-vinyl acetate) and Linear Low-Density Polyethylene  

E-Print Network [OSTI]

-Density Polyethylene Y. Wang, S. Ge, M. Rafailovich,*, J. Sokolov, Y. Zou, H. Ade, J. Lu1 ning,§ A. Lustiger, and G(ethylene-vinyl acetate) and linear low-density polyethylene (LLDPE) films spun-cast from the polymer/toluene solutions spherulite to sheaflike ag- gregates in polyethylene thin films at a critical thickness of 400 nm. Scho

52

Coking phenomena in the pyrolysis of ethylene dichloride into vinyl chloride  

SciTech Connect (OSTI)

Pyrolysis of ethylene dichloride (EDC) into vinyl chloride (VCM) which is the monomer for polyvinyl chloride, one of the most popular polymers, has been established commercially for quite a time. The process around 500{degrees}C has been proved to give VCM of high purity at very high selectivity about 99% and a reasonable conversion about 50%. However, the coking is a major problem in the long run, requiring decoking treatment every two months. The present paper describes features of carbons produced in the pyrolysis process. Coke of respective features was found in the reactor, the transfer line, the heat exchanger and the rapid quencher. Typical pyrolytic carbon, anisotropic coke produced in the liquid phase, isotropic carbon was produced on the reactor wall as low as 500{degrees}C. The mechanisms for their formation are discussed.

Sotowa, Chiaki; Korai, Yozo; Mochida, Isao [Kyushu Univ., Kasuga, Fukuoka (Japan)] [and others

1995-12-31T23:59:59.000Z

53

Procedures for Harvesting tissue for Genotyping with SolCAP Vinyl mesh (not metal) screen from local hardware store cut in plate size rectangles  

E-Print Network [OSTI]

Procedures for Harvesting tissue for Genotyping with SolCAP Supplies: Vinyl mesh (not metal) screen (Fisher part# 14-387-90) 1 quart Ziploc bags Silca: Fisher part# s161-212 Procedures 1. Label plate

Douches, David S.

54

Plug repairs of marine glass fiber / vinyl ester laminates subjected to in-plane shear stress or in-plane bending moment  

E-Print Network [OSTI]

Glass fiber / vinyl ester composite laminates represent an important class of modem fiber composites being proposed or used in state-of-the-art shipbuilding. This thesis examined the effectiveness of chopped strand mat ...

Urrutia Valenzuela, Roberto

2010-01-01T23:59:59.000Z

55

The characteristics of cobalt or copper salt-coordinated poly(4-vinylpyridine-co-2,4-diamino-6-vinyl-s-triazine) membrane for reverse osmosis  

Science Journals Connector (OSTI)

Poly(4-vinylpyridine-co-2,4-diamino-6-vinyl-s-triazine) membranes in which a part of pyridine rings was coordinated with cobalt or copper salt, considerably enhanced salt rejection without appreciable reductio...

Eizo Oikawa; Yoshiji Honda; Yuji Sawada

1981-12-01T23:59:59.000Z

56

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

57

Alternate fuels and chemicals from synthesis gas: Vinyl acetate monomer. Final report  

SciTech Connect (OSTI)

There has been a long-standing desire on the part of industry and the U.S. Department of Energy to replace the existing ethylene-based vinyl acetate monomer (VAM) process with an entirely synthesis gas-based process. Although there are a large number of process options for the conversion of synthesis gas to VAM, Eastman Chemical Company undertook an analytical approach, based on known chemical and economic principles, to reduce the potential candidate processes to a select group of eight processes. The critical technologies that would be required for these routes were: (1) the esterification of acetaldehyde (AcH) with ketene to generate VAM, (2) the hydrogenation of ketene to acetaldehyde, (3) the hydrogenation of acetic acid to acetaldehyde, and (4) the reductive carbonylation of methanol to acetaldehyde. This report describes the selection process for the candidate processes, the successful development of the key technologies, and the economic assessments for the preferred routes. In addition, improvements in the conversion of acetic anhydride and acetaldehyde to VAM are discussed. The conclusion from this study is that, with the technology developed in this study, VAM may be produced from synthesis gas, but the cost of production is about 15% higher than the conventional oxidative acetoxylation of ethylene, primarily due to higher capital associated with the synthesis gas-based processes.

Richard D. Colberg; Nick A. Collins; Edwin F. Holcombe; Gerald C. Tustin; Joseph R. Zoeller

1999-01-01T23:59:59.000Z

58

Endovascular Treatment of Acute Arterial Hemorrhage in Trauma Patients Using Ethylene Vinyl Alcohol Copolymer (Onyx)  

SciTech Connect (OSTI)

Purpose: This study was designed to determine the feasibility and efficacy of endovascular embolization with liquid embolic agent ethylene vinyl alcohol copolymer (Onyx) in patients with acute traumatic arterial bleeding. Methods: This is a retrospective review of 13 patients (9 men and 4 women; mean age 45 years) with severe trauma who underwent embolotherapy using Onyx from November 2003 to February 2009. Bleeding was located in the pelvis (5 patients), kidney (3 patients), mesenteric region (2 patients), retroperitoneal space (2 patients), neck (1 patient), and thigh (1 patient). In three cases (23.1%), Onyx was used in conjunction with coils. We evaluate the technical and clinical success, procedural and embolization time, occurrence of rebleeding, and embolotherapy-related complications, such as necrosis or migration of Onyx into nontarget vessels. Results: In all patients, embolotherapy was technically and clinically successful on the first attempt. Control of bleeding could be reached with a mean time of 19 (range, 4-63) min after correct placement of the microcatheter in the feeding artery. No recurrent bleeding was detected. No unintended necrosis or migration of Onyx into a nontarget region was observed. During the follow-up period, three patients (23.1%) died due to severe intracranial hemorrhage, cardiac arrest, and sepsis. Conclusions: Transcatheter embolization with new liquid embolic agent Onyx is technically feasible and effective in trauma patients with acute arterial hemorrhage.

Mueller-Wille, R., E-mail: rene.mueller-wille@klinik.uni-regensburg.de; Heiss, P., E-mail: peter.heiss@klinik.uni-regensburg.de [University Medical Center Regensburg, Department of Radiology (Germany); Herold, T., E-mail: thomas.herold@helios-kliniken.de [Helios Klinikum Berlin-Buch, Department of Radiology (Germany); Jung, E. M., E-mail: ernst-michael.jung@klinik.uni-regensburg.de; Schreyer, A. G., E-mail: andreas.schreyer@klinik.uni-regensburg.de; Hamer, O. W., E-mail: okka.hamer@klinik.uni-regensburg.de; Rennert, J., E-mail: janine.rennert@klinik.uni-regensburg.de; Hoffstetter, P., E-mail: P.hoffstetter@asklepios.com; Stroszczynski, C., E-mail: christian.stros@klinik.uni-regensburg.de [University Medical Center Regensburg, Department of Radiology (Germany); Zorger, N., E-mail: Niels.Zorger@barmherzige-regensburg.de [Krankenhaus Barmherzige Brueder Regensburg, Department of Radiology (Germany)

2012-02-15T23:59:59.000Z

59

Investigation of electrochemical properties of a poly(vinyl alcohol)/poly(acrylic acid) polymer blend  

SciTech Connect (OSTI)

Chemical sensors have wide applications in medicine, environmental monitoring, industrial applications, and others because of their versatility, ruggedness, sensitivity, selectivity, and economy. Electrochemical sensors are constructed by using a conducting medium, in this case graphite, and applying a constant potential while measuring changes in the current. Polymers are used for electrochemical sensors to exclude interferents from the electrode surface, to preconcentrate the analyte near the electrode, and in some cases to provide a matrix for the immobilization of analytes, such as enzymes. These functions of the polymer can serve to improve the detection limit of the sensor. This project involves the evaluation of a new polymer for electrode modification. The poly(vinyl alcohol)/poly(acrylic acid) (PVA/PAA) polymer was originally developed as an ion exchanger for use in space batteries. It has also been used in wastewater cleanup because it will concentrate heavy metals in the presence of calcium ion. This polymer is also optically clear, so it can potentially be used for an optical sensor. We are interested in investigating the ion exchange properties of the PVA/PAA polymer, as well as the ability of this polymer to preconcentrate and exclude analytes on the basis of size, charge, and hydrophilic/hydrophobic interactions.

DeSantis, C.O.; Seliskar, C.; Heineman, W.R. [Univ. of Cincinnati, OH (United States)

1995-12-31T23:59:59.000Z

60

Nonlinear optical properties of ZnO/poly (vinyl alcohol) nanocomposite films  

SciTech Connect (OSTI)

Extensive studies have already been reported on the optical characteristics of ZnO/polymer nanocomposite films, using a variety of polymers including transparent polymers such as polystyrene, polymethyl methacrylate etc and many interesting results have been established regarding the non linear optical characteristics of these systems. Poly (vinyl alcohol)(PVA) is a water soluble polymer. Though the structural and optical studies of ZnO/PVA nanocomposite films have already been investigated, there are no detailed reports on the nonlinear optical characteristics of ZnO/PVA nanocomposite films, irrespective of the fact that these nanocomposite films can be synthesized using quite easy and cost effective methods. The present work is an attempt to study in detail the nonlinear optical behaviour of ZnO/PVA nanocomposite films using Z-scan technique. Highly transparent ZnO/PVA nanocomposite films were prepared from the ZnO incorporated PVA solution in water using spin coating technique. The ZnO nanoparticles were synthesized by the simple chemical route at room temperature. High-resolution transmission electron microscopy studies show that the ZnO nanoparticles are of size around 10 nm. The ZnO/PVA nanocomposite films were structurally characterized by X-ray diffraction technique, from which the presence of both PVA and ZnO in the nanocomposite was established. The optical absorptive nonlinearity in the nanocomposite films was investigated using open aperture Z-scan technique. The results indicate optical limiting type nonlinearity in the films due to two photon absorption in ZnO with efficiency more than 50%. These films also show a self defocusing type negative nonlinear refraction in closed aperture Z-scan experiment. The present studies indicate that, highly transparent and homogeneous films of ZnO/PVA nanocomposite can be obtained on glass substrates using simple methods, in a highly cost effective way, since PVA is water soluble. These nanocomposite films offer prospects of application as efficient optical limiters to protect light sensitive devices from the possible damage on exposure to high intensity radiation.

Jeeju, P. P., E-mail: jeejupp@gmail.com [Department of Physics, S N M College, Maliankara, Ernakulam, Kerala (India); Jayalekshmi, S., E-mail: jayalekshmi@cusat.ac.in [Division for Research in Advanced Materials, Department of Physics, Cochin University of Science and Technology, Kochi 682 022 (India); Chandrasekharan, K. [Department of Physics, National Institute of Technology, Calicut, Kerala (India)

2014-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The formation of PdCx over Pd-based catalysts in vapor-phase vinyl acetate synthesis: does a PdAu alloy catalyst resist carbide formation?  

E-Print Network [OSTI]

­Au alloy catalyst resist carbide formation? Y.-F. Han, D. Kumar, C. Sivadinarayana, A. Clearfield, and D October 2003; accepted 24 February 2004 The formation of Pd carbide (PdCx) during the synthesis of vinyl­Au/SiO2; XRD. 1. Introduction The formation of carbides over supported Pd catalysts was first reported

Goodman, Wayne

62

Development of a copper-catalyzed amidation-base-promoted cyclization sequence for the synthesis of 2-aryl- and 2-vinyl1-4 quinolones  

E-Print Network [OSTI]

A direct two-step method for the preparation of 2-aryl- and 2-vinyl-4-quinolones that utilizes a copper-catalyzed amidation of ortho-halophenones followed by a base-promoted Camps cyclization of the resulting N-(2-keto-aryl)amides ...

Jones, Carrie Preston

2007-01-01T23:59:59.000Z

63

Quantification by Gas Chromatography of N,N?-Di-(2-chloroethyl)-phosphorodiamidic Acid in the Plasma of Patients Receiving Isophosphamide  

Science Journals Connector (OSTI)

...Analysis of Phenanthrols in Human Urine by Gas Chromatography-Mass Spectrometry: Potential...phenanthrols were silylated and analyzed by gas chromatography-positive ion chemical ionization-mass...chromatography [(HPLC); refs. 29 -34], gas chromatography [GC; refs. 35, 36...

Bruce M. Bryant; Michael Jarman; Michael H. Baker; Ian E. Smith; John F. Smyth

1980-12-01T23:59:59.000Z

64

Pharmacokinetics of Positron-labeled 1,3-Bis(2-chloroethyl)nitrosourea in Human Brain Tumors Using Positron Emission Tomography  

Science Journals Connector (OSTI)

...April 10, 1984. MATERIALS AND METHODS Tomograph...Since storing and handling of ethyleneimine is...Chart 1 shows a flow diagram for handling blood samples. Plasma...Gel| Chart 1. Flow diagram showing handling of blood samples...

Mirko Diksic; Kazuhiro Sako; William Feindel; Amami Kato; Y. Lucas Yamamoto; Simin Farrokhzad; and Christopher Thompson

1984-07-01T23:59:59.000Z

65

DNA Damage in Rat 9L Cells Treated with Nitrogen Mustard and 1,3-Bis(2-chloroethyl)-1-nitrosourea Assayed by Viscoelastometry and S1 Nuclease  

Science Journals Connector (OSTI)

...2 Recipient of USPHS Grant NS12745. To whom requests...Northwestern University Medical School, Evanston Hospital...Duke University Medical School, Durham, North Carolina...3 Recipient of USPHS Grant CA11898. 4 Recipient...of each tumor with a computer-assisted digitizing...

Richard H. Shafer and Eric S. Chase

1980-09-01T23:59:59.000Z

66

Free radical production from the interaction of 2-chloroethyl vesicants (mustard gas) with pyridine nucleotide-driven flavoprotein electron transport systems  

SciTech Connect (OSTI)

The biochemical sequelae to chloroethyl mustard exposure correspond very well to toxic processes initiated by free radicals. Additionally, mustard solutions contain spontaneously formed cyclic onium ions which produce carbon free radicals when reduced electrochemically. Therefore, we hypothesized that the onium ions of sulfur or nitrogen mustards might produce carbon free radicals upon being reduced enzymatically, and that these radicals might constitute a metabolic activation. We set out to document radical production using an in vitro metabolic system and electron paramagnetic resonance (EPR). Our system consisted of NADPH, one of several pyridine nucleotide-driven flavoprotein reductases, cytochrome c as a terminal electron acceptor, various sulfur or nitrogen mustards and the spin trap {alpha}-[4-pyridyl-1-oxide]-N-tert-butylnitrone in buffer. Reactions were started by adding the reductase to the other materials, vortexing and immediately transferring the mixture to a 10 mm EPR flat cell. Repeated scans on a Bruker ESP 300E EPR spectrometer produced a triplet of doublets with hyperfine splitting constants of a{sub N} = 15.483 G and a{sub H} = 2.512 G. The outcome supported our hypothesis that carbon-centered free radicals are produced when mustard-related onium ions are enzymatically reduced. The EPR results varied little with the chloroethyl compound used or with porcine or human cytochrome P450 reductase, the reductase domain of rat brain neuronal nitric oxide synthase or rat liver thioredoxin reductase. Our results offer new insight into the basis for mustard-induced vesication and the outcome of exposure to different mustards. The free radical model provides an explanation for similarities in the lesions arising from mustard exposure and energy-based lesions such as those from heat, ultraviolet and nuclear radiation as well as damage across tissue types such as skin, eyes or airway epithelium.

Brimfield, A.A. [U.S. Army Medical Research Institute of Chemical Defense, Aberdeen Proving Ground, MD, 21010 (United States)], E-mail: alan.a.brimfield@us.army.mil; Mancebo, A.M. [U.S. Army Medical Research Institute of Chemical Defense, Aberdeen Proving Ground, MD, 21010 (United States); Mason, R.P.; Jiang, J.J.; Siraki, A.G. [Laboratory of Pharmacology and Chemistry, NIEHS, Research Triangle Park, NC, 27709 (United States); Novak, M.J. [Department of Chemistry, Florida Institute of Technology, Melbourne, FL, 32901 (United States)

2009-01-01T23:59:59.000Z

67

Brain tumor cell lines resistant to O6-benzylguanine/1,3-bis(2-chloroethyl)-1-nitrosourea chemotherapy have O6-alkylguanine-DNA alkyltransferase mutations  

Science Journals Connector (OSTI)

...MED. Determined by in vitro MMR reaction using a G:T mismatch (48...on how O 6-BG binds prior to a SN2 reaction with Cys145 and can be used as...backbone (20). In the proposed reaction mechanism by Daniels et al...

Manny D. Bacolod; Stewart P. Johnson; Anthony E. Pegg; M. Eileen Dolan; Robert C. Moschel; Nancy S. Bullock; Qingming Fang; O. Michael Colvin; Paul Modrich; Darell D. Bigner; and Henry S. Friedman

2004-09-01T23:59:59.000Z

68

Simvastatin, an Inhibitor of Cholesterol Biosynthesis, Shows a Synergistic Effect with N,N?-Bis(2-chloroethyl)-N-nitrosourea and ?-Interferon on Human Glioma Cells  

Science Journals Connector (OSTI)

...supported by M. P. I. Maurizio R. Soma 2 Pietro Pagliarini Giorgio...University of Milan, Milan [M. R. S., P. Pag., R. P., R...1990. 37. Hagemenas, F. C., Pappu, A. S., and Illingworth, D. R. The effect of simv astatin on...

Maurizio R. Soma; Pietro Pagliarini; Giorgio Butti; Rodolfo Paoletti; Pietro Paoletti; and Remo Fumagalli

1992-08-15T23:59:59.000Z

69

Mechanical and morphological characterization of novel vinyl plastisols with epoxidized linseed oil as natural-based plasticizer  

SciTech Connect (OSTI)

Poly(vinyl chloride)(PVC) is one of the most commonly used plastics in the current market due to its low cost and versatility in processing, combined with its satisfactory physical and chemical properties. However, there is an important problem associated to the use of plasticized PVC. This problem is regarding to the toxicity of the most common plasticized used like DOP, DEHP, DINP, due to its possible migration. This problem limits the use of the plasticized PVC in the industry. In this work we have used epoxidized linseed oil (ELO) as a non toxic plasticizer for PVC. This type of natural oil is characterized by acting as both plasticizer and stabilizer of PVC. With this purpose, ELO have been added to PVC. The processing conditions (temperature and time of curing) are vital to determine the final properties of the material. A study of the processing conditions shows the adequate temperature and time to achieve the optimum properties.

Fenollar, O.; Balart, R.; Sanchez-Nacher, L.; Garcia-Sanoguera, D.; Boronat, T. [Institute of Materials Technology (ITM), Polytechnic University of Valencia (UPV), Plaza Ferrandiz y Carbonell s/n, 03801, Alcoy, Alicante (Spain)

2010-06-02T23:59:59.000Z

70

Osha`s 1974 vinyl chloride standard. Retrospective evaluation of the rulemaking`s feasibility/impact estimates. Case study  

SciTech Connect (OSTI)

This report documents a case study of the Occupational Safety and Health Administration`s (OSHA) permanent health standard of 1974 for workplace exposures to vinyl chloride (monomer). OSHA`s assessment of hazard control options and estimates of compliance costs and other regulatory impacts prepared as part of the rationale for the rulemaking are reviewed and then compared and contrasted with the actual post-promulgation outcomes as affected industries adjusted to the new compliance requirements. This case study has been prepared as part of a larger Office of Technology Assessment (OTA) evaluation of the control technology and regulatory impact analyses that OSHA prepares to support its rulemakings. Congress requested in May 1992 that OTA examine OSHA`s procedures and methods in these regards. The case reported here is one of eight OSHA health and safety standards that have been similarly studied on a pre- and post-promulgation basis.

Boroush, M.A.

1993-11-01T23:59:59.000Z

71

Stereoselective synthesis of trans-olefins by the copper-mediated SN2? reaction of vinyl oxazines with Grignard reagents. Asymmetric synthesis of d-threo-sphingosines  

Science Journals Connector (OSTI)

The SN2? reaction of 6-vinyl-5,6-dihydro-4H-[1,3]oxazines with Grignard reagents in the presence of CuCN was studied, and high trans selectivity for the formation of double bond was observed with a variety of RMgX. The SN2? reaction, coupled with regioselective asymmetric aminohydroxylation reaction, provided a highly efficient route for the asymmetric synthesis of d-threo-N-acetylsphingosine.

Om V. Singh; Hyunsoo Han

2007-01-01T23:59:59.000Z

72

Poly(vinyl alcohol) gel sublayers for reverse osmosis membranes. I. Insolubilization by acid-catalyzed dehydration  

SciTech Connect (OSTI)

Both flat-sheet and tubular composite reverse osmosis (RO) membranes were prepared by depositing aqueous solutions of poly(vinyl alcohol) (PVA) and a dehydration catalyst on asymmetric poly(arylether sulfone) (PES) substrate membranes. The PVA coatings were insolubilized by heat treatment to create stable hydrophilic gel-layer membranes. The influence of variables such as PVA concentration, catalyst concentration, curing time, and curing temperature was investigated. It was shown that a simple manipulation of one or two variables could lead to membranes with widely differing salt retention and water permeability characteristics. The insolubilized PVA coatings were intended to serve as hydrophilic gel sublayers on which ultra thin salt-retention barriers could ultimately be formed by interfacial polycondensation. For this purpose, high-flux gel layers were required, whereas salt-retention capabilities were not regarded as important. However, the promising salt retentions obtained as 2 MPa (up to 85% NaCl retention and 92% MgSO[sub 4] retention) showed that some of these PES-PVA composite membranes could function as medium-retention, medium-flux RO membranes, even in the absence of an interfacially formed salt-retention barrier.

Immelman, E.; Sanderson, R.D.; Jacobs, E.P.; Van Reenan, A.J. (Univ. of Stellenbosch, (South Africa). Inst. of Polymer Science)

1993-11-10T23:59:59.000Z

73

Mortality and cancer morbidity in workers exposed to low levels of vinyl chloride monomer at a polyvinyl chloride processing plant  

SciTech Connect (OSTI)

To study whether exposure to low levels of vinyl chloride monomer (VCM) causes increased risk for cancer morbidity and death from ischemic heart disease, a cohort study was performed among 2,031 male workers at a polyvinyl chloride (PVC) processing plant who had been employed for at least 3 months during the period 1945-1980. An almost significantly increased total mortality (SMR = 116, 95% CI 99-136) was found. Deaths caused by violence or intoxication were significantly increased (SMR = 153, 95% CI 109-213), but not deaths from ischemic heart disease (SMR = 100, 95% CI 73-135). A significant increase in total cancer morbidity was observed (SMR = 128, 95% CI 101-161). Respiratory cancers were significantly increased (SMR = 213, 95% CI 127-346). Furthermore, six brain tumors (vs. 2.6 expected) were observed. This increase, however, was not significant (SMR = 229, 95% CI 84-498). No liver hemangiosarcoma was observed. Applying a latency period of greater than or equal to 10 years from start of employment did not change the risk patterns. There were no significant exposure-response associations between exposure estimates for VCM, asbestos, and plasticizers and cancer morbidity.

Hagmar, L.; Akesson, B.; Nielsen, J.; Andersson, C.; Linden, K.; Attewell, R.; Moeller, T. (University Hospital, Lund (Sweden))

1990-01-01T23:59:59.000Z

74

Study of vinyl chloride formation at landfill sites in California. Final report, 16 July 1985-15 January 1987  

SciTech Connect (OSTI)

The purpose of this study was to determine if vinyl chloride (VC) detected in air above California landfills is produced in situ. Experiments were performed with N and S California landfill samples and anaerobic-digestor sewage sludge. Test materials were incubated with various chlorocarbons and with /sup 13/C-trichloroethylene (TCE) to confirm biological production of /sup 13/C-VC. These experiments confirmed the biological dechlorination of chloroethylenes as the most likely route for VC emission from landfills, rather than chemical or photochemical routes, or PVC degradation. Leaching from PVC could be a minor source of VC, though there was less than 0.1% (estimated) plastic in the landfill samples, containing at most 330 ppm of VC monomer. A landfill sample known to produce VC was used to start an anaerobic chemostat using methanol as sole carbon source. The enriched culture resulting was homogeneous, and when incubated with /sup 13/C-TCE, produced (13)C-VC, confirmed by GC/MS.

Molton, P.M.; Hallen, R.T.; Payne, J.W.

1987-01-01T23:59:59.000Z

75

Self-supported poly(methyl methacrylateacrylonitrilevinyl acetate)-based gel electrolyte for lithium ion battery  

Science Journals Connector (OSTI)

Self-supported gel polymer electrolyte (GPE) was prepared based on copolymer, poly(methyl methacrylateacrylonitrilevinyl acetate) (P(MMAANVAc)). The copolymer P(MMAANVAc) was synthesized by emulsion polymerization and the copolymer membrane was prepared through phase inversion. The structure and the performance of the copolymer, the membrane and the GPE were characterized by FTIR, NMR, SEM, XRD, DSC/TG, LSV, CA, and EIS. It is found that the copolymer was formed through the breaking of double bond CC in each monomer. The membrane has low crystallinity and has low glass transition temperature, 39.1C, its thermal stability is as high as 310C, and its mechanical strength is improved compared with P(MMAAN). The GPE is electrochemically stable up to 5.6V (vs. Li/Li+) and its conductivity is 3.48נ10?3Scm?1 at ambient temperature. The lithium ion transference number in the GPE is 0.51 and the conductivity model of the GPE is found to obey the VogelTammanFulcher (VTF) equation.

Y.H. Liao; D.Y. Zhou; M.M. Rao; W.S. Li; Z.P. Cai; Y. Liang; C.L. Tan

2009-01-01T23:59:59.000Z

76

Reaction of Cp*(CO)2ReRe(CO)2Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CRCRCO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes  

Science Journals Connector (OSTI)

Reaction of Cp*(CO)2ReRe(CO)2Cp* with Alkynes Produces Dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CRCRCO)Re(CO)Cp* Which React with Acid To Form Cationic Bridging Vinyl Complexes ... Cp*(CO)2ReRe(CO)2Cp* reacted with terminal alkynes HC?CR to produce dimetallacyclopentenones Cp*(CO)2Re(?-?1,?3-CHCRCO)Re(CO)Cp*. ... Protonation of the dimetallacyclopentenones with CF3CO2H produced (?-vinyl)dirhenium cations [Cp*(CO)2Re(?-?1,?2-CHCHR)Re(CO)2Cp*]+. ...

Charles P. Casey; Ronald S. Cario; Hiroyuki Sakaba

1997-02-04T23:59:59.000Z

77

Radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. IV. Effect of diundecyl phthalate: dependence of physical properties on composition. [Electron beam ion sources  

SciTech Connect (OSTI)

Blends of poly(vinyl chloride)(PVC) with polyfunctional monomers may be crosslinked by ionizing radiation. The physical properties of PVC blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) were studied. The TMPTMA monomer crosslinked the blend by homopolymerization and/or grafting to PVC. The plasticizer, DUP, was chemically inert under irradiation but, by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. Characteristics of the glass transitions and the tensile mechanical properties have been correlated with blend composition and radiation dose. Before irradiation, poly(vinyl chloride) was plasticized by both DUP and TMPTMA monomer. The increase in glass transition temperature and mechanical strength following irradiation to 5 Mrad was correlated with the TMPTMA content of the blend. Both the molecular structure of the network and the DUP content of the blend were factors in determining the physical properties of the final crosslinked blend. The molecular structure was determined by the kinetics of the crosslinking reactions, which in turn were determined by the blend composition. A molecular interpretation consistent with the physical properties, chemical kinetics, and mechanism of the crosslinking system has been presented. 24 figures, 2 tables.

Bowmer, T.N.; Vroom, W.I.

1983-11-01T23:59:59.000Z

78

Northern Tool + Equipment Find the Right Fitting for Your Pressure Washer at Northern Tool! NorthernTool.com/PressureWashers Pristine Pressure Pressure/power washing in Maryland Vinyl siding cleaned, decks cleaned www.pristinepressure.com  

E-Print Network [OSTI]

ability to clean while saving on our most important resources, water and energy." In recognition! NorthernTool.com/PressureWashers Pristine Pressure Pressure/power washing in Maryland Vinyl siding cleaned, decks cleaned www.pristinepressure.com Siding Cleaning Bring back the life to your siding! Estimates

Sóbester, András

79

The radiation crosslinking of poly(vinyl chloride) with trimethylolpropanetrimethacrylate. III. Effect of diundecyl phthalate: chemical kinetics of a three-component system  

SciTech Connect (OSTI)

The radiation chemistry of poly(vinyl chloride) (PVC) blended with trimethylolpropanetrimethacrylate (TMPTMA) and diundecyl phthalate (DUP) has been examined. This three-component mixture contains a base resin (PVC), a crosslinking sensitizer (TMPTMA), and a physical modifier (DUP). These are the basic components in any radiation-curable coating. The kinetics and mechanism of the crosslinking reactions were studied with reference to the dependence on radiation dose and blend composition. The polyfunctional TMPTMA underwent polymerization incorporating the PVC into a 3-dimensional network. DUP remained chemically inert during the irradiation, not being bound to the network. However, DUP by plasticizing the macromolecules and diluting the monomer, changed the kinetics extensively. DUP enhanced TMPTMA homopolymerization, TMPTMA grafting, and PVC crosslinking reaction rates. The effect of the competition between polymerization, grafting, and degradation reactions was examined in terms of enhanced mobility of the reacting species. The influence of these kinetics considerations in selecting a blend composition for a coating application was discussed.

Bowmer, T.N.; Vroom, W.I.; Hellman, M.Y.

1983-08-01T23:59:59.000Z

80

Poly vinyl acetate used as a binder for the fabrication of a LiFePO4-based composite cathode for lithium-ion batteries  

Science Journals Connector (OSTI)

ABSTRACT This paper describes a method for the preparation of composite cathodes for lithium ion-batteries by using poly vinyl acetate (PVAc) as a binder. \\{PVAc\\} is a non-fluorinated water dispersible polymer commonly used in a large number of industrial applications. The main advantages for using of this polymer are related to its low cost and negligible toxicity. Furthermore, since the \\{PVAc\\} is water processable, its use allows to replace the organic solvent, employed to dissolve the fluorinated polymer normally used as a binder in lithium battery technology, with water. In such a way it is possible to decrease the hazardousness of the preparation process as well as the production costs of the electrodes. In the paper the preparation, characterization and electrochemical performance of a LiFePO4 electrode based on \\{PVAc\\} as the binder is described. Furthermore, to assess the effect of the \\{PVAc\\} binder on the electrode properties, its performance is compared to that of a conventional electrode employing PVdF-HFP as a binder.

Pier Paolo Prosini; Maria Carewska; Cinzia Cento; Amedeo Masci

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The germination and development of seedlings from seeds treated with growth regulators: (2-chloroethyl) trimethylammonium chloride, succinic acid 2,2 dimethylhydrazide and 2,3-dihydro-5-6-diphenyl-1,4 oxathiin  

E-Print Network [OSTI]

. (May 1976) Marihelen Kamp, B. S. Texas Tech University Chairman of Advisory Committee: Dr. Arthur F. . Nightingale 0 th d ' h d d 'gl t. y 1 f I ~1 c. v. cactus flowered were soaked in each of three different growth retarding chemicals SADH... E NIE N T The author of this thesis extends most sincere thanks to Dr. Arthur E. Nightingale for his assistance in the preparation of this thesis and for his invaluable guidance in her graduate studies. Special appreciation is given also to Dr...

Kamp, Marihelen

1976-01-01T23:59:59.000Z

82

Effect of Thiourea on Survival and DNA Cross-Link Formation in Cells Treated with Platinum(II) Complexes, l-Phenylalanine Mustard, and Bis(2-chloroethyl)methylamine  

Science Journals Connector (OSTI)

...accumulation of the activated monoad duct to favor reaction with thiourea (Reaction 6). This condition H,N C@ NH HN Ci @ oe...mustards, such as HN2, that have the kinetics of SN2 reactions, than by those like L PAM that have kinetics...

Leonard A. Zwelling; Jan Filipski; and Kurt W. Kohn

1979-12-01T23:59:59.000Z

83

Vinyls: Expansion Is the Word  

Science Journals Connector (OSTI)

Resins entered billion-pound class in 1959 and new development should push them to even greater heights ...

1960-01-04T23:59:59.000Z

84

Acetylene Inhibition of Trichloroethene and Vinyl Chloride  

E-Print Network [OSTI]

and enhanced anaerobic remediation of chloroethenes at contaminated sites. The results also suggest that acetylene produced abiotically by reactions of chlorinated ethenes with zero-valent iron could inhibit water standard (2 µg/L) (3). A variety of biochemical tools have been used to probe the complexity

Semprini, Lewis

85

Reductive Dechlorination of the Vinyl Chloride Surrogate  

E-Print Network [OSTI]

in contaminated groundwater. For this study, E-/Z-chlorofluoroethene (E-/Z-CFE) was evaluated as a surrogate at a TCE-contaminated field site by injecting E-/Z-CFE and monitoring for the formation of fluoroethene (FE) over a period of up to 80 days. The rates for VC transformation to ethene and E-CFE transformation

Semprini, Lewis

86

Methods for the synthesis of deuterated vinyl pyridine monomers  

DOE Patents [OSTI]

Methods for synthesizing deuterated vinylpyridine compounds of the Formula (1), wherein the method includes: (i) deuterating an acyl pyridine of the Formula (2) in the presence of a metal catalyst and D.sub.2O, wherein the metal catalyst is active for hydrogen exchange in water, to produce a deuterated acyl compound of Formula (3); (ii) reducing the compound of Formula (3) with a deuterated reducing agent to convert the acyl group to an alcohol group, and (iii) dehydrating the compound produced in step (ii) with a dehydrating agent to afford the vinylpyridine compound of Formula (1). The resulting deuterated vinylpyridine compounds are also described.

Hong, Kunlun; Yang, Jun; Bonnesen, Peter V

2014-02-25T23:59:59.000Z

87

Research Needs: Glass Solar Reflectance and Vinyl Siding  

E-Print Network [OSTI]

mm MPa NFRC PIB psi PVC SHGC sq ft U.S. USDA of Agriculturesolar heat gain coefficient (SHGC) requirements insulating

Hart, Robert

2012-01-01T23:59:59.000Z

88

Synthesis of poly(vinyl alcohol)-graft-poly(-caprolactone) and poly(vinyl alcohol)-graft-poly(lactide) in melt with magnesium hydride as catalyst  

E-Print Network [OSTI]

)-graft-poly(lactide) in melt with magnesium hydride as catalyst Nadia Guerrouani, André Mas* , François Schué UMR 5253 CNRS-UM2%) was investigated using MgH2 environmental catalyst and melt-grown ring opening polymerization (ROP) of -caprolactone (CL) and L- lactide (LA), that avoiding undesirable toxic catalyst and solvent. The ability of Mg

Paris-Sud XI, Université de

89

Alkyl Fumarate?Vinyl Acetate Copolymer as Flow Improver for High Waxy Indian Crude Oils  

Science Journals Connector (OSTI)

Regional Research Laboratory, Jorhat 785006, Assam, India ... The efficacy of these copolymers as flow improvers (FI)/pour point depressants (PPD) was tested on Indian crude oils having similar wax (points is a well-established phenomenon. ...

A. Borthakur; D. Chanda; S. R. Dutta Choudhury; K. V. Rao; B. Subrahmanyam

1996-05-21T23:59:59.000Z

90

Synthetic Approaches to Skeletally Diverse Sultams Using Vinyl- and ?-Halo Benzenesulfonamides  

E-Print Network [OSTI]

of the corresponding benzothiazepine (n = 1)/benzothiazocine (n = 2) 1,1-dioxides as governing factors in this notable thermodynamic equilibration of atropdiastereomers. Current efforts are focused on the computational calculation for the energy barrier between two...

Jeon, KyuOk

2012-08-31T23:59:59.000Z

91

Neutron Scattering Study of Vermiculite?Poly(vinyl methyl ether) Mixtures  

Science Journals Connector (OSTI)

Neutrons scattered by the gel samples were recorded on a two-dimensional area detector, software coded as 128 128 pixels, situated 1.5 m behind the samples, covering the approximate q range between 0.2 and 2 nm-1, where the wavenumber q is defined by the equation with ? being the scattering angle. ... The quartz sample cells used were practically transparent to neutrons at the wavelength utilized on the SANS-J, and the small angle neutron scattering from D2O was of low intensity and completely unstructured over the q range studied. ...

H. Jinnai; M. V. Smalley; T. Hashimoto; S. Koizumi

1996-03-06T23:59:59.000Z

92

Determination of properties of PVE lubricants with HFC refrigerants[PolyVinylEther  

SciTech Connect (OSTI)

Polyalkyleneglycol (PAG) and polyol ester (POE) have been developed as refrigeration lubricants, used with HFC134a. PAG is used for automotive air conditioning systems and POE is used for domestic reciprocating refrigerators and for A/C systems. Although PAG exhibits good lubricity performance, it is difficult to use for domestic reciprocating refrigerators due to its low dielectric property. POE is difficult to use for automotive A/C systems, due to hydrolysis and poor lubricity performance. Polyvinylether (PVE) can be used in place of PAG and POE with HFC refrigerants. PVE is used for A/C systems as well as refrigerator and freezer applications. PVE is an ideal lubricant for use with HFCs.

Kaneko, Masato; Sakanoue, Shuichi; Tazaki, Toshihiro; Tominaga, Shoichi; Takagi, Minoru; Goodin, M.

1999-07-01T23:59:59.000Z

93

Poly(vinyl alcohol)-based buffering membranes for isoelectric trapping separations  

E-Print Network [OSTI]

Isoelectric trapping (IET) in multicompartment electrolyzers (MCE) has been widely used for the electrophoretic separation of ampholytic compounds such as proteins. In IET, the separation occurs in the buffering membranes that form a step-wise p...

Craver, Helen C.

2009-05-15T23:59:59.000Z

94

Energetics of Homogeneous Intermolecular Vinyl and Allyl Carbon-Hydrogen Bond Activation by the  

E-Print Network [OSTI]

of alkanes for both industrial and synthetic applications. While the goal of catalytic activation-H bonds,4 few have allowed for quantification of activated products crucial to the assessment of a C-H bond to a coordinatively unsaturated late-metal center (d8 Rh and Ir), generating a relatively

Jones, William D.

95

The impact of improved materials in poly(vinyl chloride)-based endotracheal tubes  

E-Print Network [OSTI]

Endotracheal tubes (ETs) are used to aid artificial ventilation in millions of medical patients every year and are known to invoke the proliferative phase in the cell linings. The technical objective of this work was to ...

Domike, Kristin Rebecca, 1981-

2004-01-01T23:59:59.000Z

96

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

97

Accelerated Ovarian Failure Induced by 4-Vinyl Cyclohexene Diepoxide in Nrf2 Null Mice  

Science Journals Connector (OSTI)

...Exposure to 2-bromopropane at the work place...sensitive than rats to VCH ovotoxicity...euthanized by CO2 inhalation. The liver and...4-vinylcyclohexene in rat and mouse liver...containing 2-bromopropane. Scand. J...1999. 2-Bromopropane causes ovarian...oocytes in female rats. Toxicol. Appl...

Xiaoming Hu; Jenny R. Roberts; Patrick L. Apopa; Yuet Wai Kan; Qiang Ma

2006-02-01T23:59:59.000Z

98

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

2005) Genome sequence of the PCE-dechlorinating bacteriumlevels and pseudo-steady-state PCE respiration rates inreductive dehalogenases in a PCE-dechlorinating flow column.

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

99

Geometry-Selective Synthesis of E or ZN-Vinyl Ureas (N-Carbamoyl Enamines)  

Science Journals Connector (OSTI)

Julien Lefranc , Daniel J. Tetlow , Morgan Donnard , Alberto Minassi , Erik Glvez , and Jonathan Clayden * ... Violette, A.; Averlant-Petit, M. C.; Semetey, V.; Hemmerlin, C.; Casimir, R.; Graff, R.; Marraud, M.; Briand, J.-P.; Rognan, D.; Guichard, G. J. Org. ...

Julien Lefranc; Daniel J. Tetlow; Morgan Donnard; Alberto Minassi; Erik Ga?lvez; Jonathan Clayden

2010-12-17T23:59:59.000Z

100

Phosgene in the Thermal Decomposition Products of Poly (Vinyl Chloride): Generation, Detection and Measurement  

Science Journals Connector (OSTI)

......3) an electrical discharge between wires covered...insulation; and (4) electric arc initiated flaming combustion...phosgene is found by the electric arc decomposition, the...PVC generated by an electric discharge show that this substance......

James E. Brown; Merritt M. Birky

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

The effect of temperature and relative humidity levels upon charcoal tube sampling for vinyl choloride  

E-Print Network [OSTI]

. O cart-per-million (ppm), and a ceiling 5. 0 ppm averaged over any period not exceeding 15 (5) minutes. ' In an effo rt to determine a worker's TWA for UCM, a tube packed with activated carbon is used as an adsorbent. The accumulated samole.... Organic vapors, as far back as the 1950's have been successfully collected on solid adsorbents followed by desorption into a GC-FID. The chromatograph is able to separate a mixture into components, and quantitatively measure each one, making it superior...

McCaskill, Gerald Daniel

2012-06-07T23:59:59.000Z

102

Synthesis and Properties of Biodegradable Poly(vinyl alcohol)/Organo-nanoclay Bionanocomposites  

Science Journals Connector (OSTI)

Biodegradable nanocomposites comprising of biodegradable polymers and bioactive organically modified layered silicates commonly reveal extremely enhanced mechanical and various other properties when compared to t...

Shadpour Mallakpour; Mohammad Dinari

2012-09-01T23:59:59.000Z

103

Rate-dependent deformation behavior of poss-filled and plasticized poly(vinyl chloride)  

E-Print Network [OSTI]

Polymers are known to exhibit strong time-dependent mechanical behavior. In different temperatures or frequency regimes, the rate sensitivities of polymers change as various primary and secondary molecular mobility mechanisms ...

Soong, Sharon Yu-Wen

2007-01-01T23:59:59.000Z

104

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

105

Synthesis and Modification of Alternating Copolymers Based on Vinyl Ethers, Chlorotrifluoroethylene, and  

E-Print Network [OSTI]

, in dynamic mode, under air, showed decomposition temperatures (Td,10%) higher than 200 °C. Electrochemical recent fuel cells technology, combining the best of both alkaline batteries and solid polymer electrolyte-exchange membranes, do not require noble metals (Pt, Ru...) as catalysts to function, which is one of the main

Paris-Sud XI, Université de

106

Tetrahedron: Asymmetry report number 86 a-Vinylic amino acids: occurrence, asymmetric synthesis,  

E-Print Network [OSTI]

-Substituted . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3. c-Substituted . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3.1. MVG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 871 2.3.2. AVG

Berkowitz, David

107

Localized Plasticity in the Streamlined Genomes of Vinyl Chloride Respiring Dehalococcoides  

E-Print Network [OSTI]

dehalogenation of chlorinated dioxins by an anaerobic14], phenols [15], dibenzo-p-dioxins [16], dibenzofurans,

McMurdie, Paul J.

2010-01-01T23:59:59.000Z

108

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton dissociation of vinyl  

E-Print Network [OSTI]

Effect of pulse intensity distributions on fragment internal energy in the infrared multiphoton of laser intensity on the production of fragment energy distribu- tions. Laser induced fluorescence (LIF pumping is pro- portional to the light intensity, the final energy of the parent molecule

Zare, Richard N.

109

Facile monomer stabilization approach to fabricate iron/vinyl ester resin nanocomposites  

E-Print Network [OSTI]

such as photovol- taic (solar) cells [11], polymer-electrolyte membrane fuel cells [12], and magnetic data storage in the marine (Naval sub- marine) industry [18] due to its good mechanical properties such as large Young

Guo, John Zhanhu

110

Solute Diffusion in Poly(vinyl alcohol)/Poly(acrylic acid) Interpenetrating Networks  

E-Print Network [OSTI]

) and poly(acrylic acid) (PAA) by varying the content of PAA in the hydrogel membrane. We also compared the permeation of solutes through interpen- etrating polymer networks (IPNs) at pH 3 (below the pKa of PAA) and pH 6 (above the pKa of PAA) and determined that permeation is a function of size exclu- sion parameters

Peppas, Nicholas A.

111

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network [OSTI]

Ethylene Carbonate in Li-Ion Battery Electrolyte Guoyingof a commercial Li-ion battery electrolyte containing 2 %are an important part of Li-ion battery technology yet their

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

112

Energy Efficiency Improvement and Cost Saving Opportunities for the Petrochemical Industry - An ENERGY STAR(R) Guide for Energy and Plant Managers  

E-Print Network [OSTI]

930F) to produce vinyl chloride monomer. VCM is convertedDichloride / Vinyl Chloride Monomer Optimize recycle loopsEthylene dichloride and vinyl chloride monomer. A number of

Neelis, Maarten

2008-01-01T23:59:59.000Z

113

HOSPITAL VENTILATION STANDARDS AND ENERGY CONSERVATION: A SUMMARY OF THE LITERATURE WITH CONCLUSIONS AND RECOMMENDATIONS, FY 78 FINAL REPORT  

E-Print Network [OSTI]

TLV (EEm) ACGIH Vinyl Chloride (Monomer) 5 mg/m ACGIH NPPainters - Solvent Vinyl Chloride (Monomer) Engineering -IUPAC Naming System Vinyl Chloride (monomer) Route of Entry:

DeRoos, R.L.

2011-01-01T23:59:59.000Z

114

Quantitation by Gas Chromatography-Chemical Ionization-Mass Spectrometry of Phenylalanine Mustard in Plasma of Patients  

Science Journals Connector (OSTI)

...1980 research-article Quantification by Gas Chromatography of N,N-Di-(2-chloroethyl...addressed. A sensitive method, based on gas chromatography using a phosphorus-specific...derivatization process has been elucidated using gas chromatography-electron impact mass spectrometry...

Sharon L. Pallante; Catherine Fenselau; Robert G. Mennel; Robert B. Brundrett; Mark Appler; Neil B. Rosenshein; Michael Colvin

1980-07-01T23:59:59.000Z

115

Plant Physiol. (1991) 97, 409-414 0032-0889/91 /97/0409/06/$01 .00/0  

E-Print Network [OSTI]

inhibitor (2-chloroethyl)trimethylammonium chloride can cause abortion of flowers in Pharbitis if applied 7 Institutes of Health grant GM40553. Abbreviations: GA, gibberellin; PMC(s), pollen mother cell to a certain point, but then normal development ceases and flower buds eventually abort. Nester and Zeevaart

Jacobsen, Steve

116

A BRIEF HISTORY OF INDUSTRIAL CATALYSIS  

E-Print Network [OSTI]

HYDROGENATIONS VINYL CHLORIDE MONOMER ( OXYCHLORINA'I'ION)and other monomers, such as vinyl- chloride, which cannot be

Heinemann, Heinz

2013-01-01T23:59:59.000Z

117

E-Print Network 3.0 - acetylenes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Materials Science 2 Acetylene Inhibition of Trichloroethene and Vinyl Chloride Summary: Acetylene Inhibition of Trichloroethene and Vinyl Chloride Reductive...

118

Ambipolar Behavior in All-Carbon-Nanotube Field-Effect Transistors by Poly(Vinyl Alcohol) Coating  

E-Print Network [OSTI]

parameter analyzer (Agilent 4156C) at room temperature under ambient conditions. Fig. 1 Schematic of device including SWNT diameter distribution, capacitances of PVA film, and I-V characteristics when coating. Wang, M. Shim, K. Roy, M. A. Alam and J. A. Rogers, Nature 454, 495 (2008). 2. D. M. Sun, M. Y

Maruyama, Shigeo

119

Control technology of vinyl chloride in EDC-VCM and PVC plants at main source points and fugitive emissions  

E-Print Network [OSTI]

for the adsorption step and vacuum and indirect steam heating for the regeneration step (see Figure 3). There are two possible mechanisms for thermal cycles; indirect heating by jacket or steam coils, and direct heating with a hot purge gas, which most often... of rupture discs upstream of relief valves, double seals in compressors and pumps, and the establishment of an effective procedure of monitoring to identify leaks, development of an adequate maintenance program, installation of a fixed point monitor...

Parra, Dario Antonio

1983-01-01T23:59:59.000Z

120

Durability of E-glass fiber reinforced vinyl ester polymer composites with nanoclay in an alkaline environment.  

E-Print Network [OSTI]

??This study was conducted to determine the effect of clay content in the GFRP (glass fiber reinforced polymer) composite samples as they are aged in (more)

Ravindran, Naveenkamal.

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Effect of nanoclay on the phase separation behavior of poly(methyl methacrylate)/poly(vinyl acetate) binary polymer blends  

Science Journals Connector (OSTI)

The effect of nanoclay on the phase-separation behavior of poly(...T c and delay time t D of isothermal phase-separation also decrease, and the variation amplitude depends on the m...

Ji-shi Zhao; Min Zuo ??; Chao-ying Lin; Qiang Zheng

2014-11-01T23:59:59.000Z

122

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network [OSTI]

columns. Industrial & Engineering Chemistry, 20:11961200,process. Industrial & Engineering Chemistry Research, 42:process. Industrial & Engineering Chemistry Research, 50:

Tu, TungSheng

2013-01-01T23:59:59.000Z

123

Model Predictive Control of a Nonlinear Large-Scale Process Network Used in the Production of Vinyl Acetate  

E-Print Network [OSTI]

both dynamic economic optimization and process control isand R. Amrit. Optimizing process economic performance usingOptimizing chemical processes from an economic perspective

Tu, TungSheng

2013-01-01T23:59:59.000Z

124

Photoredox Vinylation of Amino Acids and NAryl Amines Adam Noble and David W. C. MacMillan*  

E-Print Network [OSTI]

-tert- butoxycarbonyl (N-Boc) -amino acids,7,8 a CO2-extrusion mechanism that has implications for the use of biomass feedstocks in conjugate additions and organometallic couplings. Allylic amines have long been attractive

MacMillan, David W. C.

125

Poly(N-vinyl-2-pyrrolidone) elution from polysulfone dialysis membranes by varying solvent and wall shear stress  

Science Journals Connector (OSTI)

Packed water was collected from both the dialysate and blood sides of the wet-type dialyzer APS-15SA. The dialysate and blood sides of the moist- and dry-type dialyzers CX-1.6U and FX140, respectively...

Koki Namekawa; Masato Matsuda; Makoto Fukuda; Ami Kaneko

2012-06-01T23:59:59.000Z

126

Polymer Preprints 2004, 45(2), CHARGE DENSITY EFFECTS IN SALT -FREE  

E-Print Network [OSTI]

-methyl-2-vinyl pyridinium chloride (PMVP-Cl) with various charge density and uncharged neutral parent poly of the random copolymers of 2-vinyl pyridine and N- methyl-2-vinyl pyridinium chloride. First, the parent dry P2 by serial dilution. Polymer concentration is reported in moles of monomers (vinyl pyridine or vinyl

Colby, Ralph H.

127

The synthesis of symmetrical bis-1,2,5-thiadiazole ligandsq Dean M. Philipp,a  

E-Print Network [OSTI]

for coordination catalysts for the copolymerization of polar monomers (such as vinyl chloride and vinyl acetate there have been no reliable reports of the coordination polymerization of vinyl acetate or vinyl chloride-hydroxy thia- diazole; Vinyl chloride. q Supplementary data associated with this article can be found

Goddard III, William A.

128

Polymer Reactor Design, Optimization and Control in Latex Production Technology.  

E-Print Network [OSTI]

?? During continuous emulsion polymerization of many monomers (e.g. vinyl acetate, vinyl chloride), sustained oscillations (limit cycles) occur in conversion and all the latex and (more)

Penlidis, Alexander

1986-01-01T23:59:59.000Z

129

E-Print Network 3.0 - acid monomer induced Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Vinyl Chloride in Relation to the Low Thermal Stability of Poly(Vinyl Chloride) Summary: to be immediately attached to a monomer molecule, initiating new chain...

130

Palladium-Catalyzed Asymmetric Alkylation in the Synthesis of Cyclopentanoid and Cycloheptanoid Core Structures Bearing All-  

E-Print Network [OSTI]

, iodoethane, acrylonitrile, methyl vinyl ketone, and acrolein were distilled prior to use. Purified water

Stoltz, Brian M.

131

Chemico-Biological Interactions 166 (2007) 301316 Mortality patterns among industrial workers exposed to  

E-Print Network [OSTI]

of industrial workers exposed to chloroprene (CD) and other substances, including vinyl chloride monomer (VC

Illinois at Chicago, University of

132

Engineering and Health Impact Methods in Green Design Student projects PH 290 Sec 07  

E-Print Network [OSTI]

materials; process chemistry in producing vinyl chloride monomer; choices of antibacterial agents; need

Iglesia, Enrique

133

Charge Density Effects in Salt-Free Polyelectrolyte Solution Rheology  

E-Print Network [OSTI]

of 2-vinyl pyridine and N-methyl-2-vinyl pyridinium chloride random copolymers in ethylene glycol of 2-vinyl pyridine and N- methyl-2-vinyl pyridinium chloride (PMVP-Cl) of any charge density was studied over wide ranges of con- centration and effective charge. The fraction of quaternized monomers

Colby, Ralph H.

134

Tetrahydrofuran Hydrate Crystal Growth Inhibition by Trialkylamine Oxides and Synergism with the Gas Kinetic Hydrate Inhibitor Poly(N-vinyl caprolactam)  

Science Journals Connector (OSTI)

High Pressure Gas Hydrate Rocker Rig Equipment Test Methods ... Solid plugs caused by gas hydrate formation are a menace in various stages of the upstream oil and gas industry such as in production lines, during drilling (especially in deep water), and in work-over operations. ... (1, 4-7) In particular, the design of a new field development with LDHI technology can give large CAPEX savings. ...

Malcolm A. Kelland; Ann Helen Kvstad; Erik Langeland Astad

2012-06-26T23:59:59.000Z

135

Mechanistic investigation of vinylic carbonfluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF  

E-Print Network [OSTI]

using Cp*2ZrH2 and Cp*2ZrHF Bradley M. Kraft a , Eric Clot b , Odile Eisenstein b , William W behaves similarly [4]. In contrast, Cp*Rh(PMe3)H2 reacts with C6F6 by way of an SNAr2 attack by its conjugate base to give Cp*Rh(PMe3)(C6F5)H and fluoride ion, resulting in an autocatalytic reaction [5]. Cp

Jones, William D.

136

Poly(vinyl alcohol) based hydrogen-bonded multilayers : from pH-controlled multi-stage dissolution to zwitter-wettable surfaces  

E-Print Network [OSTI]

Understanding the mechanisms that govern the structure and function of synthetic polymer thin films is of fundamental and practical significance for developing a diverse range of functional surfaces including antifogging ...

Lee, Hyomin, Ph. D. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

137

Gold catalysts for the hydrochlorination of acetylene.  

E-Print Network [OSTI]

??The direct, gas-phase hydrochlorination of acetylene is a method by which vinyl chloride monomer (VCM) is produced industrially. VCM is polymerised to produce poly-vinyl chloride (more)

Davies, Catherine

2013-01-01T23:59:59.000Z

138

Method of recovering uranium from aqueous solution  

SciTech Connect (OSTI)

Anion exchange resin derived from insoluble crosslinked polymers of vinyl benzyl chloride which are prepared by polymerizing vinyl benzyl chloride and a crosslinking monomer are particularly suitable in the treatment of uranium bearing leach liquors.

Albright, R.L.

1980-01-22T23:59:59.000Z

139

E-Print Network 3.0 - acid mono-2-ethylhexyl ester Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B. Magnetic properties a b s t r a c t FeVinyl ester... surfactant or coupling agent. Vinyl ester monomer serves as a coupling agent with one side covalently bound Source: Guo,...

140

Accelerated Wear Tests on Common Floor-covering Materials.  

E-Print Network [OSTI]

materials indicated there are variations in the changes of appearance and wear in these materials. Solid sheet vinyls and rubber tiles showed significantly less wear than asphalt tiles, vinyl- asbestos tiles, linoleums and cork. Asphalt tiles showed... in home installations. Six common floor covering materials-solid .sheet vinyls, rubber tiles, vinyl-asbestos tiles, J linoleums, corks and asphalt tiles-were used to construct 63 test specimens 2 x 2 feet in size. 1 T'ariations in specimens were...

Stewart, B. R.; Kunze, O. R.; Hobgood, Price.

1958-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Prototyping Process and Tools An abbreviated overview of lifecycle  

E-Print Network [OSTI]

Woomoo) · Physical objects ­ cardboard, clay, vinyl, etc. ­ 3D-printed Realistic Interaction · More

Golub, Evan

142

Antithrombogenic and antibiotic compositions and methods of preparation thereof  

DOE Patents [OSTI]

Antithrombogenic and antibiotic composition of matter and method of preparation thereof. A random copolymer of a component of garlic and a biocompatible polymer has been prepared and found to exhibit antithrombogenic and antibiotic properties. Polymerization occurs selectively at the vinyl moiety in 2-vinyl-4H-1,3-dithiin when copolymerized with N-vinyl pyrrolidone. 4 figs., 2 tabs.

Hermes, R.E.

1988-04-19T23:59:59.000Z

143

Chemico-Biological Interactions 166 (2007) 264276 Chemical process-based reconstruction of exposures for an  

E-Print Network [OSTI]

, the chloroprene (CD) and vinyl chloride monomer (VCM) exposures were modeled for plant specific job title classes to chloroprene (CD) and vinyl chloride monomer (VCM), the historical exposure levels were reconstructed of exposures for an epidemiological study Part II. Estimated exposures to chloroprene and vinyl chloride Nurtan

Illinois at Chicago, University of

144

XRCC1 and CYP2E1 Polymorphisms as Susceptibility Factors of Plasma Mutant p53 Protein and Anti-p53 Antibody Expression in Vinyl Chloride Monomer-exposed Polyvinyl Chloride Workers  

Science Journals Connector (OSTI)

...sufficient statistical discriminatory power to detect the difference between mutant...working indoor or outdoor, as well as wind direction and velocity. This reconstructed...although there was limited statistical power to note the effect of the CYP2E1 c2c2...

Ruey-Hong Wong; Chung-Li Du; Jung-Der Wang; Chang-Chuan Chan; Jiin-Chyuan J. Luo; and Tsun-Jen Cheng

2002-05-01T23:59:59.000Z

145

LABORATORY STUDIES ON THE FORMATION OF THREE C2H4O ISOMERS--ACETALDEHYDE (CH3CHO), ETHYLENE OXIDE (c-C2H4O), AND VINYL ALCOHOL (CH2CHOH)--IN INTERSTELLAR  

E-Print Network [OSTI]

fractional abundances of these isomers are higher than can be accounted for by gas-phase reactions alone/1995 O1 (Hale-Bopp) and also suggest a presence of both isomers in Titan's atmosphere. Subject Galaxy and consists of gas (99%) and submicrometer-sized grain particles (1%) with aver- aged number

Kaiser, Ralf I.

146

JOURNAL OF MATERIALS SCIENCE 2012, IN PRESS DOI: 10.1007/S10853-012-6927-8 Viscoelastic properties of hollow glass particle filled vinyl ester matrix syntactic foams: effect of temperature and loading  

E-Print Network [OSTI]

to generate master curves for storage modulus over a wide frequency range. The room temperature storage vibration response, high temperature mechanical properties, and energy absorption capabilities. Dynamic]. The storage modulus provides a measure of energy stored in the material while loss modulus refers

Gupta, Nikhil

147

Study on thermal properties and crystallization behavior of electron beam irradiated ethylene vinyl acetate (EVA)/waste tyre dust (WTD) blends in the presence of polyethylene graft maleic anhydride (PEgMAH)  

SciTech Connect (OSTI)

The aim of this article is to show the effects of the electron beam irradiation dose and presence of a compatibiliser on the thermal properties and crystallinity of EVA/WTD blends. The purpose of applying electron beam radiation with doses range 50 to 200 kGy and adding a compatibiliser was to enhance the compatibility of the studied blends and at the same time to investigate the possibility of using this technique in the process of recycling polymeric materials. As the compatibilisers, the polyethylene grafted maleic anhydride (PEgMAH) was utilized, they were added at the amounts of 1-5 phr respectively. The enhancement of thermal properties was accompanied by the following effects, discussed in this article: i) an irradiated EVA/WTD blend at 200kGy was found to improve the thermal properties of EVA, ii) the addition of PEgMAH in EVA/WTD blends and the subsequent irradiation allowed prevention of degradation mechanism. iii) the ?H{sub f} and crystallinity percentage decrease at higher PEgMAH content.

Ramli, Syuhada; Ahmad, S. H. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan (Malaysia); Ratnam, C. T. [Radiation Processing Technology Division, Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang (Malaysia); Athirah, Nurul [School of Materials and Mineral Resources, USM Engineering Campus (Malaysia)

2013-11-27T23:59:59.000Z

148

Sondes fluorescentes vinyl-triphnylamines optimises pour la microscopie biphotonique : Etude des intractions non covalentes avec l'ADN et la HSA et application l'imagerie cellulaire.  

E-Print Network [OSTI]

??Lavnement de la microscopie biphotonique et des techniques dites de super-rsolution ont permis damliorer les performances de la microscopie de fluorescence et de (more)

Dumat, Blaise

2012-01-01T23:59:59.000Z

149

Computational studies of environmentally-related topics: part I. elucidating mechanisms of rhenium-mediated carbon dioxide conversion : part II. investigating vinyl radical and methyl peroxy radical combustion intermediates.  

E-Print Network [OSTI]

??Combustion processes are a major contributor of pollutants in the atmosphere; they emit particles of soot, and greenhouse gases like carbon dioxide and nitrogen oxides. (more)

Agarwal, Jay

2013-01-01T23:59:59.000Z

150

XRCC1 and CYP2E1 Polymorphisms as Susceptibility Factors of Plasma Mutant p53 Protein and Anti-p53 Antibody Expression in Vinyl Chloride Monomer-exposed Polyvinyl Chloride Workers  

Science Journals Connector (OSTI)

...sufficient statistical discriminatory power to detect the difference between mutant p53...working indoor or outdoor, as well as wind direction and velocity. This reconstructed...although there was limited statistical power to note the effect of the CYP2E1 c2c2 genotype...

Ruey-Hong Wong; Chung-Li Du; Jung-Der Wang; Chang-Chuan Chan; Jiin-Chyuan J. Luo; and Tsun-Jen Cheng

2002-05-01T23:59:59.000Z

151

Improvement in impact insulation ratings of common floor/ceiling assemblies in multi?family dwellings with standard floor coverings  

Science Journals Connector (OSTI)

Improvement in the field?rated impact insulation class [FIIC] was measured for several common floor/ceiling assemblies in existing multi?family buildings utilizing several standard grades of carpet pad and various vinyl products. Testing included determination of FIIC ratings with existing floor coverings and with other more effective floor coverings including ordinary cushioned vinyl thickly cushion?backed vinyl and vinyl products with fiber board and particle board underlayment. Test results indicate that a significant improvement in the FIIC ratings of existing vinyl covered floor/ceiling assemblies can be achieved by the superposition of an appropriate cushioned vinyl on top of the existing standard vinyl. The test results also indicate that a significant increase in FIIC ratings of existing carpeted floor/ceiling assemblies can be achieved by appropriate selection of new pad and carpet. Test data from measurements performed in accordance with ISO recommendation R140 are presented in the paper for several representative configurations.

Stanley M. Rosen

1981-01-01T23:59:59.000Z

152

http://ecfr.gpoaccess.gov/cgi/t/text/text-idx?c=ecfr&rgn=div5...  

National Nuclear Security Administration (NNSA)

the drinking water, such as: Vinyl lined asbestos cement pipe. Coal tar lined pipes and tanks. Page 64 of 227 Electronic Code of Federal Regulations: 6292011 http:...

153

CX-005562: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

(install vinyl siding) at the Heritage Estates Senior Center, and 2) upgrade of existing street lights. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-005562.pdf More Documents &...

154

Sustainable syntrophic growth of Dehalococcoides ethenogenes strain 195 with Desulfovibrio vulgaris Hildenborough and Methanobacterium congolense: Global transcriptomic and proteomic analyses  

E-Print Network [OSTI]

2005). Genome sequence of the PCE-dechlorinating bacteriumHong Kong. chloroethene (PCE) and trichloroethene (TCE) toexperimental co-culture, PCE was dechlorinated to vinyl

Men, Y.

2012-01-01T23:59:59.000Z

155

JOURNAL OF BACTERIOLOGY, Aug. 2009, p. 52245231 Vol. 191, No. 16 0021-9193/09/$08.00 0 doi:10.1128/JB.00085-09  

E-Print Network [OSTI]

in Clostridium kluyveri. Chlorinated organic compounds, such as tetrachloroethene (PCE) and trichloroethene (TCE reductively dechlorinate PCE, TCE, and their daughter compounds di- chloroethene (DCE) and vinyl chloride (VC

Alvarez-Cohen, Lisa

156

High temperature, optically transparent plastics from biomass  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

temperature, optically transparent plastics from biomass At a Glance Rapid, selective catalytic system to produce vinyl plastics from renewable biomass Stereoregular...

157

E-Print Network 3.0 - asymmetric hetero-diels-alder reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Correction Paper No. b927076k Summary: . The classic hetero-Diels Alder reaction of acrolein with methyl vinyl ketone (Scheme 3) was examined in great... is unsymmetrically...

158

Center for Nanophase Materials Sciences (CNMS) - Call For Proposals  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

materials Deuterated vinyl and diene monomers and polymers Soft matter TEM OPTOELECTRONIC NANOSTRUCTURES Laser and CVD synthesis of carbon nanomaterials, oxide film...

159

Modeling an EDC Cracker using Computational Fluid Dynamics (CFD).  

E-Print Network [OSTI]

?? The process used by the Norwegian company Hydro for making Vinyl Chloride Monomer (VCM) from natural gas and sodium chloride has been studied. A (more)

Kaggerud, Torbjrn Herder

2007-01-01T23:59:59.000Z

160

E-Print Network 3.0 - anionic linear-globular dendrimer-cis-platinum...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 47 Computational Study of 10-X-2 Ate Complexes Derived from Vinyllithiums and Vinyl Halides Summary: complexes, and removal of the formally cationic lithium from the...

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - aspect ratio domains Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of California, Irvine Collection: Mathematics 73 Weld line strength of poly(vinyl chloride)polyethylene blends , J.W. Summersb Summary: Image Analysis System. The...

162

E-Print Network 3.0 - anions Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 45 Computational Study of 10-X-2 Ate Complexes Derived from Vinyllithiums and Vinyl Halides Summary: complexes, and removal of the formally cationic lithium from the...

163

E-Print Network 3.0 - acid bilayers observed Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Docosahexaenoic Acid-Containing Phospholipid Bilayers as Studied by 2H NMR... of vinyl perdeuterated arachidonic acid chains in bilayers of 1-palmitoyl-2-vinylperdeuterioara...

164

E-Print Network 3.0 - active polymeric functional Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Biology and Medicine ; Environmental Sciences and Ecology 39 Poly(vinyl chloride) (PVC) is one of the most successful modern synthetic materials. Because of its...

165

E-Print Network 3.0 - acid dehalogenase enzyme Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of halorespi- ration in Desulfitobacterium dehalogenans. J. Biol. Chem... of vinyl chloride (VC) to ethene. Degenerate primers targeting conserved regions in reductive...

166

E-Print Network 3.0 - anions organic acids Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is determined by the acidity of the reaction intermediate, vinyldiazomethane. Thus, the vinyl- diazomethyl anion... Structure of the Vinyldiazomethyl Anion and Energetic Comparison...

167

E-Print Network 3.0 - anomalous bcd mrk Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of peracetylated b-Cyclodextrin (perBCD) on the suspension... polymerization of vinyl chloride was studied. Addition of perBCD resulted in larger particles with broader......

168

E-Print Network 3.0 - activated ester terminated Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Developmental Biology, University of Michigan Collection: Biology and Medicine 39 Synthesis of Higher Fatty Acid Starch Esters using Vinyl Laurate and Stearate as Reactants...

169

Low pour crude oil compositions  

SciTech Connect (OSTI)

This patent describes and improvement in the process of transporting waxy crude oils through a pipeline. It comprises: incorporating into the crude oil an effective pour point depressant amount of an additive comprising a polymer selected from the group consisting of copolymers of ethylene and acrylonitrile, and terpolymers of ethylene, acrylonitrile and a third monomer selected from the group consisting of vinyl acetate, carbon monoxide, alkyl acrylates, alkyl methacrylates, alkyl vinyl ethers, vinyl chloride, vinyl fluoride, acrylic acid, and methacrylic acid, wherein the amount of third monomer in the terpolymer ranges from about 0.1 to about 10.0 percent by weight.

Motz, K.L.; Latham, R.A.; Statz, R.J.

1990-05-22T23:59:59.000Z

170

AIAA-2000-0057 This work was supported by Sandia National Laboratories under  

E-Print Network [OSTI]

ABSTRACT The DOE/MSU Fatigue Database has been expanded Delamination is a dominant failure mode purpose polyesters, vinyl esters, and epoxies) used in characteristics (all materials were prepared unsaturated delamination resistance of most blade materials is polyesters, vinyl esters, epoxies

171

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 0099-2240/98/$04.00 0  

E-Print Network [OSTI]

Acceptors for Anaerobic Microbial Oxidation of Vinyl Chloride and Dichloroethene PAUL M. BRADLEY,1 * FRANCIS Received 24 March 1998/Accepted 4 June 1998 Anaerobic oxidation of [1,2-14 C]vinyl chloride and [1,2-14 C. The chlorinated solvents tetrachloroethene (PCE) and tri- chloroethene (TCE) are common groundwater contaminants

Lovley, Derek

172

Appendix A: The Names of Polymers and Polymeric  

E-Print Network [OSTI]

or methylpentene polymethylpentene vinyl chloride poly(vinyl chloride) co-aminocaproic poly(co-aminocaproic acid MATERIALS For homopolymers Monomer name Polymer name X polyX XY poiy(XY) for example ethylene polyethylene acid) [nylon 6] Where the monomer name consists of two words, it should be bracketed in the polymer

Hall, Christopher

173

Graphene Quantum Dots Embedded in a Polymer Film S. Ushiba1,2, X. He2, E. Haroz2, J. Peng3, P. M. Ajayan3 and J. Kono2  

E-Print Network [OSTI]

-polymer composite film by drying a mixture solution of GQD and poly-vinyl alcohol (PVA). GQDs were homogeneously-polymer composite. Here we demonstrate the composite film by drying a mixture solution of GQD and poly-vinyl alcohol Photoluminescence of GQDs Daylight UV light GQDs in water The absorbance peak at 310 nm is a feature of GQDs due

Mellor-Crummey, John

174

Bibliography and Index to the Literature on Gas Chromatography: January 1, 1963 to November 1, 1963  

Science Journals Connector (OSTI)

......ACIDS. PART X. THE SYNTHESIS OF THE ds-ISOMERS...1963) 115 THE SYNTHESIS OF LIGNIN MODEL...POLYCETHYLENE VINYL ACETATE) PYRO- LlZATES...ORGANIC COMPOUNDS BY LITHIUM IN LOW MOLECULAR...REACTION OF VINYL ACETATE AND BENZENE, Pepper...1963) 1028 THE SYNTHESIS AND PURIFICATION......

Seaton T. Preston; Jr.; Geneva Hyder; Mignon Gill

1963-12-01T23:59:59.000Z

175

Green-Yellow Electroluminescence from a host-dopant blended system as the active layer in a bilayer polymer light emitting diode: Poly(n-vinyl carbazole) as the host and a new soluble thiophene based copolymer [poly(2,2?-BT)-co-(3-DDT)] as the dopant  

Science Journals Connector (OSTI)

Abstract A new type of bilayer Polymer Light Emitting Diode (PLED) which emits green-yellow light is reported. In this PLED, a novel thiophene-based copolymer [poly(2,2?-BT)-co-(3-DDT)] with an excellent electron transporting property has been doped in hole transporting and electron blocking poly(n-vinylcarbazole) (PVK). Formation of type-II heterojunctions among nm-size features in PVK:poly(2,2?-BT)-co-(3-DDT) blended system makes exciplex and electroplex emissions would be dominant in the Electroluminescence (EL) spectrum of the device. These cross recombinations between electrons in the LUMO of poly(2,2?-BT)-co-(3-DDT) and holes in the HOMO of PVK is a reason for the low driving voltage of the PLED because there is no need for the charge carriers to hop or tunnel to the adjacent polymer. Morphological investigations demonstrate that the mixing degree between the components is high, favoring formation of exciplexes and electroplexes at the interface of the components.

Afshin Shahalizad; Sohrab Ahmadi-Kandjani; Hossein Movla; Hafez Omidi; Bakhshali Massoumi; Mohammad Sadegh Zakerhamidi; Ali Akbar Entezami

2014-01-01T23:59:59.000Z

176

Electrophilic Metal Alkyl Chemistry in New Ligand Environments  

SciTech Connect (OSTI)

The goals of this project were to design new electrophilic metal alkyl complexes and to exploit these systems in fundamental studies of olefin polymerization and other important and new catalytic reactions. A key target reaction is insertion copolymerization of olefins and polar CH2=CHX vinyl monomers such as vinyl halides and vinyl ethers. During the period covered by this report we (i) investigated the properties of ortho-alkoxy-arylphosphine ligands in Ni-based olefin polymerization catalysts, (ii) studied the synthesis of double-end-capped polyethylene using group 4 metal catalysts that contain tris-pyrazolylborate ligands, (iii) explored the ethylene insertion reactivity of group 4 metal tris-pyrazolyl-borate complexes, (iv) showed that (?-diimine)PdMe{sup +} species undergo multiple insertion of silyl vinyl ethers, (v) synthesized and explored the reactivity of base-free Ni benzyl complexes that contain ortho-phosphino-arene sulfonate ligands, (vi) established the mechanism of the reaction of vinyl chloride with (?-diimine)PdMe{sup +} catalysts, (vii) explored the role of cationic polymerization and insertion chemistry in the reactions of vinyl ethers with (?-diimine)PdMe{sup +} species, (viii) discovered a new class of self-assembled tetranuclear Pd catalysts that produce high molecular weight linear polyethylene and copolymerize ethylene and vinyl fluoride, and (ix) developed model systems that enabled investigation of cis-trans isomerization of {phosphine-sulfonate}Pd(II) complexes.

Jordan, Richard F. [University of Chicago] University of Chicago

2013-06-30T23:59:59.000Z

177

Sulforaphane induces phase II detoxication enzymes in mouse skin and prevents mutagenesis induced by a mustard gas analog  

SciTech Connect (OSTI)

Mustard gas, used in chemical warfare since 1917, is a mutagenic and carcinogenic agent that produces severe dermal lesions for which there are no effective therapeutics; it is currently seen as a potential terrorist threat to civilian populations. Sulforaphane, found in cruciferous vegetables, is known to induce enzymes that detoxify compounds such as the sulfur mustards that react through electrophilic intermediates. Here, we observe that a single topical treatment with sulforaphane induces mouse epidermal levels of the regulatory subunit of glutamate-cysteine ligase, the rate-limiting enzyme in glutathione biosynthesis, and also increases epidermal levels of reduced glutathione. Furthermore, a glutathione S-transferase, GSTA4, is also induced in mouse skin by sulforaphane. In an in vivo model in which mice are given a single mutagenic application of the sulfur mustard analog 2-(chloroethyl) ethyl sulfide (CEES), we now show that therapeutic treatment with sulforaphane abolishes the CEES-induced increase in mutation frequency in the skin, measured four days after exposure. Sulforaphane, a natural product currently in clinical trials, shows promise as an effective therapeutic against mustard gas. -- Highlights: ? Sulforaphane induces increased levels of glutathione in mouse skin. ? Sulforaphane induces increased levels of GSTA4 in mouse skin. ? Sulforaphane, applied after CEES-treatment, completely abolishes CEES-mutagenesis. ? The therapeutic effect may suggest a long biological half-life for CEES in vivo.

Abel, E.L. [Department of Molecular Carcinogenesis, The University of Texas MD Anderson Cancer Center, Science Park, Smithville, TX 78957 (United States)] [Department of Molecular Carcinogenesis, The University of Texas MD Anderson Cancer Center, Science Park, Smithville, TX 78957 (United States); Boulware, S. [Division of Pharmacy and Toxicology, College of Pharmacy, The University of Texas at Austin, Dell Pediatric Research Institute, 1400 Barbara Jordan Blvd., Austin, TX 78723 (United States)] [Division of Pharmacy and Toxicology, College of Pharmacy, The University of Texas at Austin, Dell Pediatric Research Institute, 1400 Barbara Jordan Blvd., Austin, TX 78723 (United States); Fields, T.; McIvor, E.; Powell, K.L. [Department of Molecular Carcinogenesis, The University of Texas MD Anderson Cancer Center, Science Park, Smithville, TX 78957 (United States)] [Department of Molecular Carcinogenesis, The University of Texas MD Anderson Cancer Center, Science Park, Smithville, TX 78957 (United States); DiGiovanni, J.; Vasquez, K.M. [Division of Pharmacy and Toxicology, College of Pharmacy, The University of Texas at Austin, Dell Pediatric Research Institute, 1400 Barbara Jordan Blvd., Austin, TX 78723 (United States)] [Division of Pharmacy and Toxicology, College of Pharmacy, The University of Texas at Austin, Dell Pediatric Research Institute, 1400 Barbara Jordan Blvd., Austin, TX 78723 (United States); MacLeod, M.C., E-mail: mcmacleod@mdanderson.org [Department of Molecular Carcinogenesis, The University of Texas MD Anderson Cancer Center, Science Park, Smithville, TX 78957 (United States)

2013-02-01T23:59:59.000Z

178

Next Generation Non-particulate Dry Nonwoven Pad for Chemical Warfare Agent Decontamination  

SciTech Connect (OSTI)

New, non-particulate decontamination materials promise to reduce both military and civilian casualties by enabling individuals to decontaminate themselves and their equipment within minutes of exposure to chemical warfare agents or other toxic materials. One of the most promising new materials has been developed using a needlepunching nonwoven process to construct a novel and non-particulate composite fabric of multiple layers, including an inner layer of activated carbon fabric, which is well-suited for the decontamination of both personnel and equipment. This paper describes the development of a composite nonwoven pad and compares efficacy test results for this pad with results from testing other decontamination systems. The efficacy of the dry nonwoven fabric pad was demonstrated specifically for decontamination of the chemical warfare blister agent bis(2-chloroethyl)sulfide (H or sulfur mustard). GC/MS results indicate that the composite fabric was capable of significantly reducing the vapor hazard from mustard liquid absorbed into the nonwoven dry fabric pad. The mustard adsorption efficiency of the nonwoven pad was significantly higher than particulate activated carbon (p=0.041) and was similar to the currently fielded US military M291 kit (p=0.952). The nonwoven pad has several advantages over other materials, especially its non-particulate, yet flexible, construction. This composite fabric was also shown to be chemically compatible with potential toxic and hazardous liquids, which span a range of hydrophilic and hydrophobic chemicals, including a concentrated acid, an organic solvent and a mild oxidant, bleach.

Ramkumar, S S; Love, A; Sata, U R; Koester, C J; Smith, W J; Keating, G A; Hobbs, L; Cox, S B; Lagna, W M; Kendall, R J

2008-05-01T23:59:59.000Z

179

Infrared Thermography Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hollow vs. Foam-Filled Vinyl Windows Hollow vs. Foam-Filled Vinyl Windows Hollow vs. Foam-filled Vinyl Windows (100K) These two windows are the same except for what is inside the vinyl frames. The frame on the left is hollow, while the frame on the right is filled with insulating foam. The units have the same insulated glazing unit, a superwindow with R-8 center of glass. The hollow window frame allows air to circulate inside the frame; this convective effect is observed by noticing the frame temperatures are cooler at the bottom than at the top. The foam-filled window doesnÌt show this effect. These windows are being cooled on the back side with wind at -15°C (5°F). For more information contact: Howdy Goudey Building Technologies Program 510-486-6046 (fax) Return to the IRlab page Building Technologies | Energy & Environment Division | Lawrence Berkeley National Laboratory

180

Catalytic studies of supported Pd-Au catalysts  

E-Print Network [OSTI]

reaction conditions is the ultimate goal. This thesis is mainly focused on the application of Pd-Au supported catalysts for vinyl acetate synthesis and CO oxidation reactions using highsurface area catalysts. We have attempted to improve the conventional Pd...

Boopalachandran, Praveenkumar

2006-08-16T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Initial viscosity  

Science Journals Connector (OSTI)

n....A term used in the vinyl plastisol industry to denote the viscosity measured immediately after the plastisol has been mixed. The viscosity normally rises at a declining rate after...

2007-01-01T23:59:59.000Z

182

Viscosity depressant  

Science Journals Connector (OSTI)

n....A substance that, when added in a relatively minor amount to a liquid, lowers its viscosity. Such materials, e.g., ethoxylated ... often incorporated in vinyl plastisols to lower their viscosities

2007-01-01T23:59:59.000Z

183

Initial Viscosity  

Science Journals Connector (OSTI)

n...A term used in the vinyl plastisol industry to denote the viscosity measured immediately after the plastisol has been mixed. The viscosity normally rises at a declining rate after...

Jan W. Gooch

2011-01-01T23:59:59.000Z

184

The effect of moisture on a glass/epoxy composite  

E-Print Network [OSTI]

Research was done to determine the effect of moisture on the transverse tensile strength and the interfacial shear strength of a glass/epoxy composite. Specimens with two different fiber sizings, one epoxy compatible and one vinyl-ester compatible...

Chatawanich, Candy Suda

2012-06-07T23:59:59.000Z

185

Removal of spin-spin coupling in NMR spectrum of N-vinylpyrazole by paramagnetic additives  

Science Journals Connector (OSTI)

An explanation is given for the change in the multiplicity of the signals of the protons of the vinyl group in the NMR spectrum of 1-vinylpyrazole, taken with the addition of a nickel salt.

V. K. Voronov; L. A. Shestova; E. S. Domnina

1976-02-01T23:59:59.000Z

186

Effect of the finishing oil of acrylic fibers in the optical rotation of the Raman scattered light  

Science Journals Connector (OSTI)

Polarized Raman spectra have been obtained from polyacrylonitrile copolymers fibers with vinyl acetate Poly(AN-co-VA), and methyl acrylate Poly(AN-co-MA) with finishing and without...

Rosales-Candelas, I; Soto-Bernal, J J; Gonzalez-Mota, R; Frausto-Reyes, C

2013-01-01T23:59:59.000Z

187

NATIONAL LF.hD COMPANY OF C4IIO  

Office of Legacy Management (LM)

.in the future, this equipment was stored ,in an isolated area, covered with vinyl plastic,. and roped off; This sren will not be used andor congested with personnel st.;sny...

188

A Versatile Catalyst System for Suzuki?Miyaura Cross-Coupling Reactions of C(sp[superscript 2])-Tosylates and Mesylates  

E-Print Network [OSTI]

A catalyst system for the Suzuki?Miyaura cross-coupling reactions of aryl and vinyl tosylates and mesylates has been developed. This catalyst displays excellent functional group tolerance and allows the coupling of ...

Bhayana, Brijesh

189

Intern experience at the Conoco VCM plant: an internship report  

E-Print Network [OSTI]

's position in the organization of the plant. Major projects assigned during the internship are defined. The problem of occupational exposure to vinyl chloride, a toxic chemical, is addressed and a system for monitoring employee exposure...

Hall, James Josiah

2013-03-13T23:59:59.000Z

190

Effect of SiO2 and nanoclay on the properties of wood polymer nanocomposite  

Science Journals Connector (OSTI)

Wood polymer composite (WPC) were developed by using solution blended high density polyethylene, low density polyethylene, polypropylene, poly(vinyl chloride), Phragmites karka wood flour and polyethylene-co...-g...

Biplab K. Deka; Tarun K. Maji

2013-02-01T23:59:59.000Z

191

Effect of monomer/nanoclay interaction on the kinetics of atom transfer radical homo- and copolymerization of styrene and methyl acrylate  

Science Journals Connector (OSTI)

Atom transfer radical homo- and copolymerization of styrene and methyl acrylate initiated with CCl3...-terminated poly(vinyl acetate) macroinitiator were performed at 90C in the presence of nanoclay (Cloisite 30...

Mahdi Abdollahi; Mohammad Ali Semsarzadeh

2012-04-01T23:59:59.000Z

192

Conductive composites based on coreshell polyaniline nanoclay by latex blending  

Science Journals Connector (OSTI)

A simple and versatile method for the preparation of conductive composites based on coreshell polyaniline (PANI) one-dimensional nanoclay distributed in poly(ethylene-vinyl acetate) ( ... and anilinium salts. Tw...

Yingfeng Yu; Xinhui Zhong; Wenjun Gan

2009-04-01T23:59:59.000Z

193

Studies on properties of softwood (Ficus hispida)/PMMA nanocomposites reinforced with polymerizable surfactant-modified nanoclay  

Science Journals Connector (OSTI)

In addition to vinyl monomer, cross-linker, nanosized filler, or reinforcement will make a remarkable improvement in thermal, physical, and mechanical properties of wood. Montmorillonite (MMT) is commonly used...

A. Hazarika; R. R. Devi; T. K. Maji

2012-04-01T23:59:59.000Z

194

Subscriber access provided by University Libraries | University of Notre Dame Organic Letters is published by the American Chemical Society. 1155 Sixteenth  

E-Print Network [OSTI]

primarily for use as a precursor monomer for poly(vinyl chloride).5 More reactive chloroalkanes are em NH residues which greatly accelerate N-alkylation by activating the chloride leaving group

Smith, Bradley D.

195

Physicochemical properties of talc ore from Pout-Kelle and Memel deposits (central Cameroon)  

Science Journals Connector (OSTI)

...L., Leroy E. Lopez-Cuesta J.M. (2005) Influence of talc physical properties on the fire retarding behaviour of (Etylene-vinyl acetate copolymer/magnesium hydroxide/talc) composites. Polymer Degradation and Stability , 88 , 504-511...

C. NKOUMBOU; F. VILLIERAS; O. BARRES; I. BIHANNIC; M. PELLETIER; A. RAZAFITIANAMAHARAVO; V. METANG; C. YONTA NGOUNE; D. NJOPWOUO; J. YVON

196

PyrolysisGas Chromatography: A Bibliography (19601963)  

Science Journals Connector (OSTI)

......THE PYROLYSIS OF TOULENE, Price, S. J., Can. J. Chem...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYLACRYLATE) AND POLY(ETHYLENE VINYL ACETATE) PYROLY- SATES...CHROMATOGRAPHIC ANALYSIS OF POLY(ETHYLENE ETHYL ACRYLATE) AND POLY......

R. W. McKinney

1964-12-01T23:59:59.000Z

197

Methods Development for On-Line Gas Chromatography  

Science Journals Connector (OSTI)

......contractual specifications. Used to determine value and sale price of product. Monitors liquid or gas effluent wastes for loss...vinyl chloride on dioctylsebacate and Car- bowax 550. (A) ethylene, (B) propane, (C) propylene, (D) isobutane, (E......

Richard Villalobos

1990-07-01T23:59:59.000Z

198

EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or  

E-Print Network [OSTI]

-benezene 4-Aminodiphenyl Asbestos Coal tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1,2-dibromo-3-chloropropane Lead Cadmium Benzene Cotton dust Chromium VI

199

A Review of NCI's Extramural Grant Portfolio: Identifying Opportunities for Future Research in Genes and Environment in Cancer  

Science Journals Connector (OSTI)

...vinyl chloride, benzidine, diesel exhaust particles, polycyclic...energy balance, methods, or general. Specific environmental terms...more than a single funding cycle and our goal was to evaluate the funding cycle included in this report, publications...

Armen A. Ghazarian; Naoko I. Simonds; Kelly Bennett; Camilla B. Pimentel; Gary L. Ellison; Elizabeth M. Gillanders; Sheri D. Schully; and Leah E. Mechanic

2013-04-01T23:59:59.000Z

200

Preparation and characterization of the covalent-integrated poly(lactic acid) and scrap leather fiber composites  

Science Journals Connector (OSTI)

Scrap leather fibers (SLFs) modified with active silane containing epoxide groups were incorporated into poly(lactic acid) (PLA) modified by vinyl trimethoxysilane, i.e., the PLA/SLF composites were prepared for ...

Jing-kuan Duan ???; Chang-xiu Fan ???

2012-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Thermal Performance Impacts of Center-of-Glass Deflections in Installed Insulating Glazing Units  

E-Print Network [OSTI]

6] M. Bernier, Effects of Glass Plate Curvature on the U-Selkowitz, Research Needs: Glass Solar Reflectance and VinylAnalysis of Insulating Glass Units, Journal of Structural

Hart, Robert

2014-01-01T23:59:59.000Z

202

Enhanced phytoremediation of volatile environmental pollutants with transgenic trees  

E-Print Network [OSTI]

trichloroethylene, vinyl chloride, carbon tetrachloride, benzene, and chloroform, are com- mon environmental conventional techniques. CYP2E1 P450 poplar trichloroethylene carbon tetrachloride Phytoremediation is the use greater public approval. Phytoremediation also yields other benefits including carbon sequestration, soil

203

THE DYNAMIC SHEAR MODULUS AND DAMPING RATIO OF CLAY NANOCOMPOSITES  

Science Journals Connector (OSTI)

...vinyl acrylic in nanoclay composites, the secant shear...properties of nanoclay filled sisal fibre reinforced epoxy composites. Composites...nanocomposites. Composites Science and Technology...P. (2006) Nanoclay reinforced bio-based...

Z. Nese Kurt; Suat Akbulut

204

Green chemistry : dense carbon dioxide and water as environmentally benign reaction media  

E-Print Network [OSTI]

(cont.) was investigated in scCO?, and the cycloaddition between cyclopentadiene and methyl vinyl ketone (MVK) was studied in an scCO?/liquid water environment. Nitrogen chemistry, specifically the synthesis of nitrogen ...

Allen, Andrew J. (Andrew John), 1978-

2004-01-01T23:59:59.000Z

205

Nonaqueous composition for slip casting or cold forming refractory material into solid shapes  

SciTech Connect (OSTI)

A composition is described for slip casting or cold forming non-oxide refractory material(s) into solid shape comprising finely divided solid refractory materials selected from the group consisting of metal boride, refractory carbide, nitride, silicide and a refractory metal of tungsten, molybdenum, tantalum and chromium suspended in a nonaqueous liquid slip composition consisting essentially of a deflocculent composed of a vinyl chloride-vinyl acetate resin dissolved in an organic solvent.

Montgomery, L.C.

1993-08-24T23:59:59.000Z

206

Observations on the biology of the smoky brown cockroach  

E-Print Network [OSTI]

, sheetrock, unfinished plywood, tar paper, painted wood, sheetmetal, and vinyl asbestos tile. Smoky brown cockroaches were found throughout southeast, central, and east Texas vdth the population decreasing south of Corpus Christi, west of San Antonio..., vegetables, mixtures, etc, Materials tested for pre- , I ferred resting surfaces were sheetmetal, sheetrock, concrete, tar paper, painted wbi)d, 5 unfinished wood?and vinyl asbestos tile. Laboratory Test Procedures Three phases of tests were conducted...

Clark, Jerry Lee

2012-06-07T23:59:59.000Z

207

Indentation and Recovery Tests of Common Resilient Floor Coverings.  

E-Print Network [OSTI]

the total indentation character- istics of rubber, vinyl-asbestos and cork tile. The total indentation was smaller under the heavy and medium loads for the thinner materials. Little effect was noted under the light load. Differences in residual... indentation of materials due to material thickness was significant for cork and vinyl-asbestos tile. Tests indicated that residual indentation was greater for the thicker samples. The thinner gage of rubber tile tended to retain more residual indentation...

Stewart, B. R.; Kunze, O. R.; Hobgood, Price

1960-01-01T23:59:59.000Z

208

ARC-coal acetylene process development program. Phase 1B. Final technical progress report, 15 September 1979-31 September 1980  

SciTech Connect (OSTI)

For many years, acetylene was a major feedstock in the chemical industry, being used for the manufacture of such important large-volume chemicals as vinyl chloride, vinyl acetate, acrylonitrile, acetaldehyde, and several others chemicals. Since the mid-1960's, however, acetylene has been largely replaced by olefins like ethylene and propylene. These olefins, though sometimes less suitable as feedstocks than acetylene, became more economical as they became readily available at prices considerably lower than acetylene. The successful development of the Arc-Coal process appears to offer a new competitive option to ethylene while reducing the risk of feedstock shortage by relying on the vast coal resources within the US. The Arc-Coal Acetylene process has been tested successfully at both the 100 kW and 1 MW levels, clearly demonstrating that acetylene can be economically produced from coal in a one-step reaction, and that the current reactor design approach is capable of being scaled up to commercial size. The process is shown to be commercially competitive with the currently available process for acetylene manufacture and, more importantly, competes attractively with ethylene in the manufacture of vinyl chloride and vinyl acetate. With the commercial advent of the arc-coal acetylene process, it will become possible to manufacture acetylene more economically than by conventional process. Substantial ethylene price increases tied closely to, and driven by, higher crude oil and natural gas prices are a clear long-term trend which appears certain to continue well into the foreseeable future with periodic market variations. This situation will make the Arc-coal Acetylene process a leading contender for the production of chemicals such as vinyl chloride and vinyl acetate, substituting a coal feedstock process for the current liquid hydrocarbon-fed ethylene-to-vinyl monomers processes.

Not Available

1980-10-30T23:59:59.000Z

209

Discoloration resistant, flexible, radiation curable coating compositions  

SciTech Connect (OSTI)

A low dosage radiation polymerizable protective and decorative coating composition or paint, coated articles bearing such a protective coating and processess for preparing such articles. The radiation polymerizable coating composition comprises an organic resin/monomer mixture of: (A) between about 97 and about 3 weight percent alphabeta olefinically unsaturated organic resin containing between about 0.5 and about 5 vinyl unsaturation units per 1000 molecular weight of said resin, and (B) between about 3 and about 97 weight percent vinyl monomers polymerizable with said resin upon exposure to radiation, characterized in that said vinyl monomers include N-vinyl-2-pyrrolidone in an amount of from about 3 and up to about 10 weight percent based on the total weight of (A) and (B). The flexible coating exhibits excellent physical qualtities and good adhesion to a variety of substrates being particularly suitable for use on vinyl chloride fabric, wherein it is discoloration resistant after heat aging. Preferred articles bearing such a coating, which may comprise large amounts of pigment, are preferably cured by exposure to electron beam radiation.

Cassatta, J.C.; Garrett, D.L. Jr.; Van Oene, H.

1984-10-16T23:59:59.000Z

210

Radionuclides in the terrestrial ecosystem near a Canadian uranium mill -- Part 3: Atmospheric deposition rates (pilot test)  

SciTech Connect (OSTI)

Atmospheric deposition rates of uranium series radionuclides were directly measured at three sites near the operating Key Lake uranium mill in northern Saskatchewan. Sites impacted by windblown tailings and mill dusts had elevated rates of uranium deposition near the mill and elevated {sup 226}Ra deposition near the tailings compared to a control site. Rainwater collectors, dust jars, and passive vinyl collectors previously used at the Ranger Mine in Australia were pilot-tested. Adhesive vinyl surfaces (1 m{sup 2}) were oriented horizontally, vertically, and facing the ground as a means of measuring gravitational settling, wind impaction, and soil resuspension, respectively. Although the adhesive glue on the vinyls proved difficult to digest, relative differences in deposition mode were found among radionuclides and among sites. Dry deposition was a more important transport mechanism for uranium, {sup 226}Ra, and {sup 210}Pb than rainfall, while more {sup 210}Po was deposited with rainfall.

Thomas, P.A.

2000-06-01T23:59:59.000Z

211

Iron porphyrin polymer films: Materials for the modification of electrode surfaces and the detection of nitric oxide  

SciTech Connect (OSTI)

We are currently investigating a new method for the detection and quantification of nitric oxide (NO) based on a carbon electrode chemically modified with an iron porphyrin polymer film. Commercially available vinyl-substituted iron porphyrin monomers can be polymerized directly onto electrode surfaces through a published electrochemical polymerization process. We are also developing a synthesis for a new vinyl-substituted monomer, iron 5,10,15-triphenyl-20-vinyl porphyrin chloride, in hopes of improving polymer film stability. The electrochemistry of NO is also being investigated at electrodes chemically modified with an iron porphyrin polymer film. We are studying the catalytic oxidation of iron porphyrin bound NO to nitrate by molecular oxygen. The reaction with molecular oxygen is preceded by a one electron reduction of the iron porphyrin-NO complex. If currents proportional to nitric oxide concentration can be measured, a new NO electrochemical sensor will be designed.

McGuire, M.; Drew, S.M. [Carleton College, Northfield, MN (United States)

1996-10-01T23:59:59.000Z

212

Recoil carbon-11 atom reactions with 1,3-butadiene in the gas phase  

E-Print Network [OSTI]

. . 2. Reactions of Recoil Carbon-11 Atoms with 1, 3- Butadiene as a Function of Pressure. 3. Reactions of Recoil Carbon-11 Atoms with 1, 3- Butadiene as a Function of Oxygen. 4. The Addition of Silane (SiH4) to the 1, 3-8utadiene System. CHAPTER.... III-13 Ratio as a Function of 02. Plot of the Yield of C-labeled Vinyl Aliene as a 11 Function of 02. Plot of the Yield of C-labeled Vinyl Cyclopropane 11 as a Function of 02 Variation in the C-labeled Product Spectra with 11 Increasing Silane...

Baltuskonis, Dennis Alan Anthony

2012-06-07T23:59:59.000Z

213

Passivation-free solid state battery  

DOE Patents [OSTI]

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

Abraham, K.M.; Peramunage, D.

1998-06-16T23:59:59.000Z

214

Passivation-free solid state battery  

DOE Patents [OSTI]

This invention pertains to passivation-free solid-state rechargeable batteries composed of Li.sub.4 Ti.sub.5 O.sub.12 anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn.sub.2 O.sub.4, LiCoO.sub.2, LiNiO.sub.2 and LiV.sub.2 O.sub.5 and their derivatives.

Abraham, Kuzhikalail M. (Needham, MA); Peramunage, Dharmasena (Norwood, MA)

1998-01-01T23:59:59.000Z

215

Developing the Manufacturing Process for VCE: Binder for Filled Elastomers  

SciTech Connect (OSTI)

This topical report presents work completed to re-establish the manufacturing process for poly(ethylene-co-vinyl acetate-co-vinyl alcohol) terpolymer called VCE. The new VCE formulations meet the material requirements and have lower melt viscosity, which results in improved production for the next assembly. In addition, the reaction conditions were optimized in order to achieve a satisfactory conversion rate to enable production in a single work shift. Several equipment and process changes were made to yield a manufacturing process with improved product quality, yield, efficiency, and worker safety.

E.A. Eastwood

2009-11-01T23:59:59.000Z

216

A Boron Subphthalocyanine Polymer: Poly(4-methylstyrene)-co-poly(phenoxy boron subphthalocyanine)  

Science Journals Connector (OSTI)

A Boron Subphthalocyanine Polymer: Poly(4-methylstyrene)-co-poly(phenoxy boron subphthalocyanine) ... Deuterated chloroform with 0.05% (v/v) tetramethylsilane (TMS) was purchased from Cambridge Isotope Laboratories (St. ... Before additional effort was put into obtaining a BsubPc vinyl monomer we first wanted to determine whether or not the BsubPc group is a radical scavenger. ...

Jeremy D. Dang; Jessica D. Virdo; Benot H. Lessard; Elijah Bultz; Andrew S. Paton; Timothy P. Bender

2012-09-28T23:59:59.000Z

217

Enhanced biodegradation of phenol by a microbial consortium in a solidliquid two phase partitioning bioreactor  

E-Print Network [OSTI]

partitioning bioreactor George P. Prpich & Andrew J. Daugulis* Department of Chemical Engineering, Queen polymer beads (com- prised of ethylene vinyl acetate, or EVA) as the second phase. Polymer modification, and detrimentally, from indus- trial activities such as petroleum processing, plastic manufacturing

Daugulis, Andrew J.

218

A silicoboron carbonitride ceramic stable to 2,000C  

Science Journals Connector (OSTI)

... formation of two chiral oc-C atoms. Compound 1 is obtained by hydroboration of the silane at the vinylic ot- or |3-C atoms in the ratio 2:1 ( ... solutions. Fibre formation is favoured by the two-dimensional structure of polymer 2. Subsequent pyrolysis of the polymer fibres is conducted in Ar up to 1,100C, with ...

Ralf Riedel; Andreas Kienzle; Wolfgang Dressler; Lutz Ruwisch; Joachim Bill; Fritz Aldinger

1996-08-29T23:59:59.000Z

219

The competitive adsorption of human proteins onto natural-based biomaterials  

Science Journals Connector (OSTI)

...of bulk chemistry, surface energy, wettability and phase interconnectivity...Biodegradable polymeric blends of corn starch with: (i) cellulose...2007 The influence of surface energy on competitive protein adsorption...Polyvinyls 0 Serum Albumin 0 corn starch-co-ethylene vinyl...

2010-01-01T23:59:59.000Z

220

Hybrid Silica-PVA Nanofibers via Sol-Gel Electrospinning Tahira Pirzada,,  

E-Print Network [OSTI]

Hybrid Silica-PVA Nanofibers via Sol-Gel Electrospinning Tahira Pirzada,,§ Sara A. Arvidson,,§ Carl: We report on the synthesis of poly(vinyl alcohol) (PVA)-silica hybrid nanofibers via sol-gel electro is under- taken and reveals a composition window in which defect-free hybrid nanofibers with diameters

Khan, Saad A.

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Division of Administration and Finance University Services  

E-Print Network [OSTI]

FORMAT PRINTER ON CAMPUS AT THE UNIVERSITY COPY CENTER Houston, July 26, 2011 ­ Services expand at the University Copy Center. "As the University of Houston continues to expand their facilities and grow. Projects can be printed on gloss paper, vinyl, banner paper, wall paper, polyester, and more. The latex ink

Azevedo, Ricardo

222

Communications Counterion Effects in Liquid Crystal  

E-Print Network [OSTI]

of nanostructured CdS templated directly with ion-doped liquid crystals.13,14 In both cases the mesoporous solidCommunications Counterion Effects in Liquid Crystal Templating of Nanostructured CdS V. Tohver, P system, nanostructured particles consisting of alternat- ing sheets of CdS and oligomeric vinyl alcohol

Braun, Paul

223

Adsorption and chemical reaction of Cu(hfac)(vtms) on Young Su Chung, Hyoo Suk Lee, Yoon Sup Lee, Sehun Kim *  

E-Print Network [OSTI]

Adsorption and chemical reaction of Cu(hfac)(vtms) on Cu(1 1 1) Young Su Chung, Hyoo Suk Lee, Yoon the adsorption and reaction of Cu(hfac) (vtms) (hexa¯uoroacetylacetonate, hfac; vinyl tri- methyl silane, vtms between adsorbed Cu(hfac) molecules were observed to occur between 240 and 400 K. The adsorption geo

Kim, Sehun

224

List of Journal Publications T. Wu, M. Frydrych, K. O'Kelly, B. Chen*: Poly(glycerol sebacate urethane)-cellulose  

E-Print Network [OSTI]

List of Journal Publications · T. Wu, M. Frydrych, K. O'Kelly, B. Chen*: Poly(glycerol sebacate and Engineering C: Materials for Biological Applications. 2014, 34, 50-53. · T. Wu, R. Farnood, K. O'Kelly, B, K. O'Kelly, B. Chen*: Poly(vinyl alcohol) particle-reinforced elastomer composites with water

Ojovan, Michael

225

(N-heterocyclic-carbene)Copper(I)-catalyzed carbon-carbon bond formation using carbon dioxide  

E-Print Network [OSTI]

This thesis presents work towards the development of a new catalytic C-C bond forming reaction. Alkynes and olefins insert into [(IPr)CuH]2 (IPr = N,N-bis-(2,6-diisopropylphenyl)-1,3-imidazol-2-ylidene) to give copper vinyl ...

Sirokman, Gergely

2007-01-01T23:59:59.000Z

226

Prochlorococcus, a Marine Photosynthetic Prokaryote of Global Significance  

Science Journals Connector (OSTI)

...4-Vinyl-4-desetyl chlorophyll : a new naturally occurring chlorophyll...Herndl G. Ultraviolet-B radiation and bacterial metabolism in...within the cyanobacterial radiation. . Urbach E. Scanlan D...F. W. Resistance to co-occuring phages enables marine Synechococcus...

F. Partensky; W. R. Hess; D. Vaulot

1999-03-01T23:59:59.000Z

227

Synthesis and evaluation of a stabilized propellane analog of the proteasome inhibitor salinosporamide A and total synthesis of mearsine and synthetic studies towards grandisine B  

E-Print Network [OSTI]

Relevant to Chapter Three ppm (f1) O 2 eq vinyl acetate t-to Chapter Four O Me ant i/ sy n ppm (f1) OEt OEt MeO O ppm (f1) 100 MHz in CDCl3 Me d.r. undetermined OH OEt N

Vamos, Mitchell Dennis

2009-01-01T23:59:59.000Z

228

Polypropylene/Glass Fiber Hierarchical Composites Incorporating Inorganic Fullerene-like Nanoparticles for Advanced Technological Applications  

Science Journals Connector (OSTI)

In particular, the incorporation of nanoclays to GFRPs has been reported to improve significantly the heat distortion temperature, flexural and impact strengths. ... Enhanced mech., thermal and vibration properties were obsd. in nanoclay dispersed composites over vinyl ester-glass fiber composite. ...

Ana M. Dez-Pascual; Mohammed Naffakh

2013-09-09T23:59:59.000Z

229

Initiated chemical vapor deposition of fluoropolymer coatings for the surface modification of complex geometries  

E-Print Network [OSTI]

Initiated chemical vapor deposition (iCVD) is a one-step, soventless process that can be used to produce polymeric thin films. The iCVD technique has been used to polymerize a wide variety of vinyl monomers such as glycidyl ...

Gupta, Malancha, 1980-

2007-01-01T23:59:59.000Z

230

Kinetic isotope effects, dynamic effects, and mechanistic studies of organic reactions  

E-Print Network [OSTI]

?-conjugating substituent is distal to the oxazolidinone but decreased steric interaction when the Ï?-conjugating substituent is proximal to the oxazolidinone. Dynamic effects were studied in Diels-Alder reaction between acrolein and methyl vinyl ketone. This reaction...

Wang, Zhihong

2007-04-25T23:59:59.000Z

231

J. Am. Chem. SOC.1992, 114, 4265-4268 4265 allyl alcohol vs that of acrolein). Alternatively, one could argue  

E-Print Network [OSTI]

J. Am. Chem. SOC.1992, 114, 4265-4268 4265 allyl alcohol vs that of acrolein). Alternatively, one could argue that acrolein liberates vinyl groups and allyl alcohol liberates acetylene; the former would The principal influences of the C = C group of allyl alcohol and acrolein are on the bonding configuration

Helgaker, Trygve

232

Shrink Sleeve Flexo Inks Veronika Pekarovicova*, Alexandra Pekarovicova*, and Paul D. Fleming III*  

E-Print Network [OSTI]

containing monomers such as amide, ester, and/or ethylene/vinyl acetate are also frequently used. Shrink rate as the substrates. Several film materials are available such as polyvinyl chloride (PVC), oriented be also formed from polymers and copolymers of olefin monomers containing from 2 to about 12 carbon atoms

Fleming, Paul D. "Dan"

233

Plasmachemical Amine Functionalization of Porous Polystyrene Spheres: The Importance of Particle Size  

E-Print Network [OSTI]

dissolving stabilizers (2 g of poly- (vinyl alcohol) and 2 g of sodium chloride) in 400 mL of hot water. Upon polymer structure by copolymerization of monomers.8 However, the number of commercial monomers is limited by the addition of a mixture of monomer (5 mL of styrene), cross-linker (45 mL of divinylbenzene), porogen (50 m

Davis, Ben G.

234

Synthesis of an A/B/C Triblock Copolymer for Battery Materials Applications  

E-Print Network [OSTI]

Section tert-Butylamine, cobalt chloride, and ethyl vinyl ether were purchased from Aldrich. Butyllithium incorporate metal salts. The organocobalt monomer was chosen due to the difficulty of polymerizing a lithium- containing monomer. The electrochemical reaction shown in reaction 1 is different from other lithium battery

Rubloff, Gary W.

235

Influence of plasticizer molecular weight on plasticizer retention in PVC geomembranes  

E-Print Network [OSTI]

, the repeating unit is the vinyl chloride monomer. The chemical and structural Geosynthetics In. Geosynthetics International, 12, No. 2, 000- 000. 1. INTRODUCTION Polyvinyl chloride (PVC) is one of the oldest by a series of small and simple repeating chemical units. These repeating units are called monomers. In PVC

236

Peroxide grafted PDMS: hydrosilylation reaction study and thiol-ene chemistry as an alternative pathway  

E-Print Network [OSTI]

of azobiscyanopentanoyl chloride with amino terminated polysiloxane1 , and peroxycarbamate groups were introduced) groups were inserted in a polydimethylsiloxane backbone by hydrosilylation of a vinyl functional silaneBAP with mercaptopropylsilane monomer (DM3PSi) affords functionalized monomer (BP3DM2Si). Polycondensation of this monomer

Paris-Sud XI, Université de

237

Acetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts  

E-Print Network [OSTI]

of commercially important materials like vinyl acetate monomer (VAM), cellulose acetate, and acetate esters. MoreAcetic Acid from the Carbonylation of Chloride Methane Over Rhodium Based Catalysts Yafang Fan ? that makes use of the latest advance in methyl chloride production is reported. Acetic acid was produced from

Bao, Xinhe

238

Glossary of Colloid and Polymer Science Adrian R. Rennie, 2008.1 Glossary of Terms in Colloid and  

E-Print Network [OSTI]

are based on olefinic and other monomers that react like this such as styrene, vinyl chloride, butadiene etc that occurs by addition of a monomer to a double bond between two carbon atoms. The reaction will remove © Adrian R. Rennie, 2008.3 An alternating copolymer is a polymer formed from two monomers in a regular

Rennie, Adrian

239

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network [OSTI]

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

240

Random and Sequential Radical Cotelomerizations of 3,3,3-Trifluoropropene (TFP, H2C=CHCF3) with Vinylidene  

E-Print Network [OSTI]

is quite reactive in contrast to longer perfluorinated chain vinyl-type monomers (e.g. CnF2n+1-CH=CH2, benzyl chloride, under redox complexes (e.g. Fe(CO)5), UV or gamma rays initiatons.7-19 In addition

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Analytical Challenges and Recent Advances in the Determination of Estrogens in Water Environments  

Science Journals Connector (OSTI)

......MIPs for E2 were synthesized from 4-vinyl pyridine and ethylene dimethacrylate as a functional monomer and cross-linking...2007). 91. D.D. Fine, G.P. Breidenbach, T.L. Price, and S.R. Hutchins. Quantitation of estrogens in ground......

Rodica Domnica Briciu; Agata Kot-Wasik; Jacek Namiesnik

2009-02-01T23:59:59.000Z

242

Analysis of Phthalate Contamination in Infusion Solutions by Automated On-Line In-Tube Solid-Phase Microextraction Coupled with High-Performance Liquid Chromatography  

Science Journals Connector (OSTI)

......such as polyethy- lene (PE), polypropylene (PP), and ethylene-vinyl acetate copolymer(EVA)instead ofPVC.However...L.E.Gray, C. Wolf, C. Lambright, P.Mann, M. Price,R.L.Cooper, and J. Ostby. Administration of potentially......

Kurie Mitani; Fumio Izushi; Hiroyuki Kataoka

2004-10-01T23:59:59.000Z

243

ADVERTISERS' INDEX:  

Science Journals Connector (OSTI)

......Wildwood Rd. Toledo, Ohio 43614, or call 419/882-1643 Price $400.00 ppd U.S. Abstractors Desired Preston Publications...IO-IIH) times compared with FID- to I'l'li levels for ethylene oxide and sub Pf'H levels for vinyl chloride Detects I'l'li......

Advertisers' Index

1982-11-01T23:59:59.000Z

244

Radioiodinated glucose analogues for use as imaging agents  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1988-01-01T23:59:59.000Z

245

Radioiodinated branched carbohydrates  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1989-01-01T23:59:59.000Z

246

NEWSLETTER OF BEN-GURION UNIVERSITY OF THE NEGEV Learn more about Green Campus  

E-Print Network [OSTI]

's Green Campus standards and incorporate energy saving technologies. See architectural renderings below - NEWSLETTER OF BEN-GURION UNIVERSITY OF THE NEGEV Learn more about Green Campus /http://cmsprod.bgu.ac.il/Eng/Units/green became an extremely successful business, manufacturing plastics and vinyl products for the flooring

Yekutieli, Amnon

247

Polymerizable 2(2-hydroxynaphthyl)2H-benzotriazole compounds  

DOE Patents [OSTI]

Benzotriazole compounds having the formula: ##STR1## wherein R.sub.1 is H, Cl, or OCH.sub.3 ; R.sub.2 is a hydroxynaphthyl group; and R.sub.3 is a vinyl unsaturated polymerizable group. Homopolymers or copolymers thereof are effective as UV light stabilizers and absorbers.

Gomez, P.M.; Neidlinger, H.H.

1991-07-16T23:59:59.000Z

248

An Au-Catalyzed Cyclialkylation of Electron-Rich Arenes with Epoxides To Prepare 3-Chromanols  

E-Print Network [OSTI]

, this species might be able to add to other functional groups such as epoxides in an SN2 manner. We tested epoxides (Figure 1B). The endo addition products were obtained exclusively, and the reaction(III) species in this reaction. This species then attacks methyl vinyl ketone in a manner like a Michael

He, Chuan

249

Chiral r-Substituted Carbonyls and Alcohols from the SN2 Displacement of Cuprates on Chiral Carbonates: An Alternative  

E-Print Network [OSTI]

of reactions, based on the anti-selective SN2 addition of cuprates to allylic carbonates, transforms alkynesChiral r-Substituted Carbonyls and Alcohols from the SN2 Displacement of Cuprates on Chiral freedom of the vinyl group in 6 during the SN2 displacement step; the stereoselectivity of the cuprate

Spino, Claude

250

J. Phys. II France 2 (1992) 2221~2235 DECEMBER 1992, PAGE 2221 Classification  

E-Print Network [OSTI]

of neutron reflectometry has been shown to provide good resolution for the determination of polymer density,12E 61.40K 68.45 68.60 Neutron reflectivity study of end-adsorbed diblock copolymers : cross-over from Sepiember 1992) Abstract. We report neutron reflectivity data on polystyrene-poly(vinyl~2-pyridine) (PS

Boyer, Edmond

251

Sandia National Laboratories: 13,051 lbs of Carpet Sent for Reuse  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

13,051 lbs of Carpet Sent for Reuse 13,051 lbs of Carpet Sent for Reuse November 01, 2011 carpet for reuse Sandia National Laboratories/NM has found a new home for excess carpet generated during interior renovations of its existing buildings. Sandia's Pollution Prevention (P2) Team has been collecting vinyl backed and foam backed (polyurethane) carpet for many years; however it was limited to recycling opportunities due to the lack of options in the carpet industry. Previous shipments sent out for recycle were delivered to Interface Carpet in Atlanta, GA, where the manufacture has an extensive recycling program that recycles vinyl backed carpet in addition to the nylon fiber surface. Unfortunately, the polyurethane backed carpet is non recyclable and sent for waste-to-energy recovery. forklift carrying carpet

252

Buildings Energy Data Book: 1.4 Environmental Data  

Buildings Energy Data Book [EERE]

3 3 "Typical" Construction Waste Estimated for a 2,000-Square-Foot Home (1) Material Solid Sawn Wood 20% 6 Engineered Wood 18% 5 Drywall 25% 6 Cardboard (OCC) 8% 20 Metals 2% 1 Vinyl (PVC) (3) 2% 1 Masonry (4) 13% 1 Hazardous Materials 1% - Other 13% 11 Total (5) 100% 50 Note(s): Source(s): 1) See Table 2.2.7 for materials used in the construction of a new single-family home. 2) Volumes are highly variable due to compressibility and captured air space in waste materials. 3) Assuming 3 sides of exterior clad in vinyl siding. 4) Assuming a brick veneer on home's front facade. 5) Due to rounding, sum does not add up to total. NAHB's Internet web site, www.nahb.org, Residential Construction Waste: From Disposal to Management, Oct. 1996. 150 150 1,000 50 1,050 8,000

253

Synthesis and thermal chemistry of selected N-vinylisoquinuclidenes  

E-Print Network [OSTI]

. wi th thi onyl 0 Ph I 0 H02C H02C / N 0 CH 0 C CH 02C Ph g=0 OCH3 CH302C CH3 2 =0 27 chloride in anhydrous methanol at 25'C t'o furnish, in 81K yield, an interesting product g. This new product contained not only the desired..., 690 cm 1 UV (CH3CN) ~ 287 nm (c 20, 900; H-NMR (CDC13)6 3. 75 (m, 2H, H-5 and H-6), 4. 1 (m, 1H, H-4), 4. 0 (s, 6H, OCH3), 5. 4 (m, 1H, H-l), 6. 4 (d, 1H, J=16 Hz, N-vinyl), 6. 9 (m, 2H, H-7 and H-8 vinyl), 7. 6 (m, SH, aromatic), 7. 8 (d, 1H, J=16...

Beamer, Ralph Lewis

1978-01-01T23:59:59.000Z

254

Total Synthesis of the Antimitotic Marine Macrolide (?)-Leiodermatolide  

E-Print Network [OSTI]

the corresponding stereodefined vinyl triflate 4. In practice, controlled addition of TBSO(CH2)4MgBr to 8 provided the required ketone (88%), which was converted into 4 with high selectivity (82%, > 20:1 Z/E) by treatment of the kinetically generated lithium enolate... ] of silyl ketene acetal 19, mediated by BF3OEt2 at Scheme 2. Preparation of vinyl stannane 2. Reagents and conditions: a) TBSO(CH2)4MgBr, THF, #2;78 8C, 88%; b) LiHMDS, THF; Comins reagent, #2;78!#2;20 8C, 82%; c) (MeBO)3, [Pd(PPh3)4] (10 mol%), K2CO3...

Paterson, Ian; Ng, Kenneth K.-H.; Williams, Simon; Millican, David C.; Dalby, Stephen M.

2014-01-30T23:59:59.000Z

255

Silicon dendritic web material process development. First quarterly report, March 28-June 30, 1980  

SciTech Connect (OSTI)

Initial values of pressure, power, and speed have been determined for seam bonding interconnects to dendritic web solar cells. Satisfactory bond strengths and high yield have been achieved without cell damage. However, in case of processing large numbers of cells for module fabrication, further testing is required to assure reproducibility of this technique. Various techniques have been developed for fabricating solar modules by lamination using ethylene vinyl acetate with a glass superstrate, and no cell breakage has been noted.

Campbell, R. B.; Stapleton, R. E.; Sienkiewicz, L.; Rai-Choudhury, P.

1980-01-01T23:59:59.000Z

256

Thermal Chemistry of Styrene on Si(100)21 and Modified Surfaces:? Electron-Mediated Condensation Oligomerization and Posthydrogenation Reactions  

Science Journals Connector (OSTI)

Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada ... In the present work, we examine the interactions of styrene with the 21 and modified surfaces of Si(100) using thermal desorption spectrometry (TDS), low-energy electron diffraction (LEED), and Auger electron spectroscopy (AES) to better understand not only the important roles of the vinyl and phenyl groups in organosilicon surface chemistry but also the nature of different thermal surface processes for different surface conditions. ...

Q. Li; K. T. Leung

2005-01-05T23:59:59.000Z

257

J. Am. Chem. SOC.1992, 114, 11003-1 1004 11003 addition to elucidating the mechanism of COHED, our results  

E-Print Network [OSTI]

solvents has only been possible for the exceptional cases of vinyl,2cy~lopropyl,~a-alk~xyalkyl,~and more ( I ) (a) Reich, H. J.; Bowe, M. D. J.Am. Chem.SOC.1990,112,8994. (b) Reich, H. J.; Green, D. P.; Phillips, N. H. J. Am. Chem.SOC.1991,113, 1414. (c) Green, D. P. PhD Thesis, University of Wisconsin

Reich, Hans J.

258

Method of making carbon nanotube composite materials  

DOE Patents [OSTI]

The present invention is a method of making a composite polymeric material by dissolving a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes and optionally additives in a solvent to make a solution and removing at least a portion of the solvent after casting onto a substrate to make thin films. The material has enhanced conductivity properties due to the blending of the un-functionalized and hydroxylated carbon nanotubes.

O'Bryan, Gregory; Skinner, Jack L; Vance, Andrew; Yang, Elaine Lai; Zifer, Thomas

2014-05-20T23:59:59.000Z

259

General engineering specifications for 6000 tpd SRC-I Demonstration Plant  

SciTech Connect (OSTI)

This volume contains specifications for architectural features of buildings for the SRC-1 Demonstration Plant: skylights, ventilators, sealants, doors, mirrors, furring and lathing, gypsum plaster, lightweight plaster, wallboard, ceramic tile, acoustic ceiling systems, resilient flooring, carpeting, brick flooring, architectural painting, vinyl wall covering, chalkboards, tackboards, toilets, access flooring, lockers, partitions, washroom accessories, unit kitchens, dock levels, seals, shelters, custom casework, auditorium seats, drapery tacks, prefabricated buildings, stairs, elevators, shelves, etc. (LTN).

Not Available

1981-11-01T23:59:59.000Z

260

CuC1 thermochemical cycle for hydrogen production  

DOE Patents [OSTI]

An electrochemical cell for producing copper having a dense graphite anode electrode and a dense graphite cathode electrode disposed in a CuCl solution. An anion exchange membrane made of poly(ethylene vinyl alcohol) and polyethylenimine cross-linked with a cross-linking agent selected from the group consisting of acetone, formaldehyde, glyoxal, glutaraldehyde, and mixtures thereof is disposed between the two electrodes.

Fan, Qinbai (Chicago, IL); Liu, Renxuan (Chicago, IL)

2012-01-03T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

Fontana, J.J.; Elling, D.; Reams, W.

1988-05-26T23:59:59.000Z

262

Optimum energy and by-product recovery in chlorinated hydrocarbon disposal systems  

SciTech Connect (OSTI)

This paper covers the three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer facility. These are the incineration, the energy recovery system, and the by-product recovery system. It is shown that the overall efficiency of the energy and by-product recovery systems is dependent on the optimization of the primary combustor (incineration system). 11 refs.

Santoleri, J.J.

1982-01-01T23:59:59.000Z

263

Electrically conductive polymer concrete coatings  

DOE Patents [OSTI]

A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

Fontana, Jack J. (Shirley, NY); Elling, David (Centereach, NY); Reams, Walter (Shirley, NY)

1990-01-01T23:59:59.000Z

264

Neutron Absorbing Alloys  

DOE Patents [OSTI]

A process for making homogeneous copolymers of vinylpyrrolidone (VP) and vinyl acetate (VA) which form clear aqueous solutions and have high cloud points. The process involves precharging VP and VA monomers in a predetermined ratio, and then feeding VP and VA at a predetermined rate, the ratio of the components in the initial charge and the feeding rates for the monomer being selected in accordance with the reactivity rates of the monomers towards copolymerization as opposed to homopolymerization.

Zhong, Yuanzhen (Wayne, NJ), Parikh, Hemant (Harriman, NY); Smith, Terry E. (Murray, KY)

2002-05-28T23:59:59.000Z

265

EMI shield enhancement through the addition of copper coated glass fibers  

E-Print Network [OSTI]

E. , University of Wisconsin-Madison Chair of Committee: Dr. G. W. Halldin This research investigated the feasibility of using copper coated glass fibers to increase the EMI shielding characteristics of vinyl ester thermosetting resin. The fibers were coated... 35 36 37 41 41 48 55 57 58 58 58 58 60 61 62 62 62 Plate Times. Surface Area Analysis Scanning Electron Microscopy. MOLDED COMPOSITE MATERIALS. Resin. Sample Preparation. Evaluation. Scanning Electron Microscopy Flexural...

Montanye, Jeffrey Richard

1988-01-01T23:59:59.000Z

266

Microbial based chlorinated ethene destruction  

DOE Patents [OSTI]

A mixed culture of Dehalococcoides species is provided that has an ability to catalyze the complete dechlorination of polychlorinated ethenes such as PCE, TCE, cDCE, 1,1-DCE and vinyl chloride as well as halogenated ethanes such as 1,2-DCA and EDB. The mixed culture demonstrates the ability to achieve dechlorination even in the presence of high source concentrations of chlorinated ethenes.

Bagwell, Christopher E. (Aiken, SC); Freedman, David L. (Clemson, SC); Brigmon, Robin L. (North Augusta, SC); Bratt, William B. (Atlanta, GA); Wood, Elizabeth A. (Marietta, GA)

2009-11-10T23:59:59.000Z

267

Composite bipolar plate for electrochemical cells  

DOE Patents [OSTI]

A bipolar separator plate for fuel cells consists of a molded mixture of a vinyl ester resin and graphite powder. The plate serves as a current collector and may contain fluid flow fields for the distribution of reactant gases. The material is inexpensive, electrically conductive, lightweight, strong, corrosion resistant, easily mass produced, and relatively impermeable to hydrogen gas. The addition of certain fiber reinforcements and other additives can improve the properties of the composite material without significantly increasing its overall cost.

Wilson, Mahlon S. (Los Alamos, NM); Busick, Deanna N. (Los Alamos, NM)

2001-01-01T23:59:59.000Z

268

Polysulfones for conservation in the ethylene polymer industry. Progress report No. 7, October 1979-March 1980  

SciTech Connect (OSTI)

Ethylene-SO/sub 2/ polysulfone copolymers were prepared by /sup 60/Co gamma radiation, as well as by electron-beam radiation and by thermocatalysis, as a means of incorporating a polluting waste product material such as SO/sub 2/ into ethylene polymers for the purpose of conserving ethylene feedstock. Ethylene-SO/sub 2/ copolymer was pressure molded into discs which had a high degree of hardness as well as partial transparency, but were also very brittle. Differential Scanning Calorimetry (DSC) and Thermal Gravimetric Analysis (TGA) indicated peak decomposition at 350/sup 0/C. Long term heat aging tests showed stability to 175/sup 0/C and initiation of decomposition at 200/sup 0/C in air after 900 h. Decomposition became severe as the temperature was increased to 300/sup 0/C. The activation energies for decomposition were 57.3 and 56.8 kcal/mole for liquid-phase and gas-phase formed copolymers, respectively. The ethylene-SO/sub 2/ copolymer was modified by the incorporation of monomeric styrene, 2-vinyl pyridine, 4-vinyl pyridine, and N-vinyl pyrrolidine. A summary of characterization studies by INCO which includes solubility, infra-red and x-ray analysis of the ethylene-SO/sub 2/ copolymer and with additives are presented.

Steinberg, M.; Johnson, R.; Elling, D.; Bernstein, P.; Varker, A.E.

1980-06-01T23:59:59.000Z

269

Contribution of floor treatment characteristics to background noise levels in health care facilities, Part 1  

Science Journals Connector (OSTI)

Acoustical tests were conducted on five types of commercial-grade flooring to assess their potential contribution to noise generated within health care facilities outside of patient rooms. The floor types include sheet vinyl (with and without a 5 mm rubber backing) virgin rubber (with and without a 5 mm rubber backing) and a rubber-backed commercial grade carpet for comparison. The types of acoustical tests conducted were ISO-3741 compliant sound power level testing (using two source types: a tapping machine to simulate footfalls and a rolling hospital cart) and sound absorption testing as per ASTM-C423. Among the non-carpet samples the material type that produced the least sound power was determined to be the rubber-backed sheet vinyl. While both 5 mm-backed samples showed a significant difference compared to their un-backed counterparts with both source types the rubber-backed sheet vinyl performed slightly better than the rubber-backed virgin rubber in the higher frequency bands in both tests. The performance and suitability of these flooring materials in a health care facility compared to commercial carpeting will be discussed. [Work supported by Paul S. Veneklasen Research Foundation.

Adam L. Paul; David A. Arena; Eoin A. King

2014-01-01T23:59:59.000Z

270

2010SR05.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Big Top Tent Keeps TRU Waste Trucks, Tanks Big Top Tent Keeps TRU Waste Trucks, Tanks Dry before Inspection and Shipping Big Top Aids Solid Waste Management in Shipping Protocol Aiken, S.C. - Important projects for the Recovery Act - and not a circus act - are being performed under the Big Top at Solid Waste Management facility at the Department of Energy's (DOE) Savannah River Site (SRS). The jumbo-size vinyl tent with a metal frame measuring 160 feet long, 24 feet wide, and

271

Environment/Health/Safety/Security (EHSS)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 JHA Templates Construction JHA 2013 Instructions Mobilization & Overall Scope of Work Abatement (Lead, Asbestos & Mold) Aerial and Scissor Lifts ASHRAE Testing 110 Acoustical Ceilings (T-bar) All Terrain & Powered Industrial Trucks (PIT) Arborist - Vegetation Management Blank JHA Cabinetry Installation Carpentry, Forming, Framing or Wood Working Chemical Use Concrete Work - Truck & Pumping Confined Space Containment ... Dust Particulate Isolation Core Drilling Concrete (wet method) Crane Lifts Demolition Electrical Work (LOTO) Excavating, Trenching & Pot Holing Fall Protection Flooring Installation Carpet - Sheet Vinyl - VCT - Ceramic Tile Hot Tap Insulation (Wall or Pipe with PVC fittings) Ladders Mechanical Ducting Operating Hand, Power Tools & Equipment

272

Public Meeting Transcript: Sustainable Design Standards for Federal Buildings  

Broader source: Energy.gov (indexed) [DOE]

OFFICE OF ENERGY EFFICIENCY AND RENEWABLE ENERGY PUBLIC MEETING SUSTAINABLE DESIGN STANDARDS FOR FEDERAL BUILDINGS U.S. Department of Energy 1000 Independence Avenue, SW Washington, DC 20585 Room 8E-089 Wednesday July 28, 2010 Chair: Cyrus Nasseri Department of Energy (FEMP) Facilitator: Jim Raba Department of Energy Executive Court Reporters (301) 565-0064 2 Participants Identified: Mark Ames American Society of Heating, Refrigerating and Air- Conditioning Engineers (ASHRAE) Margo Appel US Department of Energy (DOE) Todd Apple Dupont Tim Ballo Earthjustice John Barry International Union of Operating Engineers National Training Fund Allen Blakey The Vinyl Institute Nadine Block Sustainable Forestry Initiative

273

Public Meeting Transcript: Sustainable Design Standards for Federal Buildings  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

UNITED STATES OF AMERICA UNITED STATES OF AMERICA OFFICE OF ENERGY EFFICIENCY AND RENEWABLE ENERGY PUBLIC MEETING SUSTAINABLE DESIGN STANDARDS FOR FEDERAL BUILDINGS U.S. Department of Energy 1000 Independence Avenue, SW Washington, DC 20585 Room 8E-089 Wednesday July 28, 2010 Chair: Cyrus Nasseri Department of Energy (FEMP) Facilitator: Jim Raba Department of Energy Executive Court Reporters (301) 565-0064 2 Participants Identified: Mark Ames American Society of Heating, Refrigerating and Air- Conditioning Engineers (ASHRAE) Margo Appel US Department of Energy (DOE) Todd Apple Dupont Tim Ballo Earthjustice John Barry International Union of Operating Engineers National Training Fund Allen Blakey The Vinyl Institute

274

 

Broader source: Energy.gov (indexed) [DOE]

energy energy The proposed activity includes implementing the following list of energy efficiency improvements in existing Tribal buildings: * Foam Insulation for the Administration Building * Install new Energy Star oil furnace at the Maintenance Garage * Install new Energy Star oil furnace at the Construction Office * Window replacement at the Family Support Building and Department of Social Services using Energy Star qualified Double Hung Vinyl Windows * Install new Energy Star oil furnace at Terrance House Energy Efficiency and Conservation Block Grants Saint Regis Mohawk Tribe Energy Efficiency Retrofits Saint Regis Mohawk Tribe New York Nov 2, 2009 Jane Summerson Print Form for Records Submit via E-mail Billie Newland Digitally signed by Billie Newland

275

A mammoth of a project: the conservation of a columbian mammoth  

E-Print Network [OSTI]

). All bone samples being treated were compared to this sample. MTMS Methyltrimethoxysilane (MTMS) is a ?silane cross linker selected from a phenyl, hydrogen, vinyl, or an alkyl group having one or two carbon atoms? (Klosowski 2004:5). It?s a... This experiment looked at using the silane cross-linker, MTMS, with a catalyst to finalize the treatment. The catalyst, also known as a hardener, initiates and maintains the cross-linking process (Wheatcraft 1994: 37). The catalyst used in this experiment...

Daniel, Shanna LaRea

2009-05-15T23:59:59.000Z

276

Treatment of addiction to ethanol and addictive-related behavior  

DOE Patents [OSTI]

The present invention provides a highly efficient method for treating alcohol addiction and for changing addiction-related behavior of a mammal suffering from alcohol addiction. The method includes administering to a mammal an effective amount of gamma vinylGABA or a pharmaceutically acceptable salt thereof. In one embodiment, the method of the present invention includes administering to the mammal an effective amount of a composition which increase central nervous system GABA levels wherein the effective amount is sufficient to diminish, inhibit or eliminate behavior associated with craving or use of alcohol.

Dewey, Stephen L. (Manorville, NY); Brodie, Jonathan D. (Cos Cob, CT); Ashby, Jr., Charles R. (Miller Place, NY)

2001-01-01T23:59:59.000Z

277

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member and/or six member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

278

Nanopatterns by phase separation of patterned mixed polymer monolayers  

DOE Patents [OSTI]

Micron-size and sub-micron-size patterns on a substrate can direct the self-assembly of surface-bonded mixed polymer brushes to create nanoscale patterns in the phase-separated mixed polymer brush. The larger scale features, or patterns, can be defined by a variety of lithographic techniques, as well as other physical and chemical processes including but not limited to etching, grinding, and polishing. The polymer brushes preferably comprise vinyl polymers, such as polystyrene and poly(methyl methacrylate).

Huber, Dale L; Frischknecht, Amalie

2014-02-18T23:59:59.000Z

279

Influence of Cobalt Nanoparticles Incorporation on the Magnetic Properties of the Nickel Nanofibers: Cobalt-Doped Nickel Nanofibers Prepared by Electrospinning  

Science Journals Connector (OSTI)

Nickel(II) acetate tetrahydrate (Ni(AOc), 98%) and poly(vinyl alcohol) (PVA, molecular weight (MW) = 65?000 g/mol) were obtained from Showa Co., Japan and Aldrich Co., USA, respectively. ... In this study, three mixtures have been individually electrospun; Ni(AOc)/PVA, Co nanoparticles/PVA, and Co nanoparticles/Ni(AOc)/PVA. A PVA aqueous solution (10 wt %) was utilized in all mixtures. ... Briefly, Ni(AOc)/PVA sol?gel was prepared by mixing of aqueous Ni(AOc) solution (20 wt %) and the prepared PVA solution in a weight ratio of 1:3. ...

Nasser A. M. Barakat; Bongsoo Kim; Chuan Yi; Younghun Jo; Myung-Hwa Jung; Kong Hee Chu; Hak Yong Kim

2009-10-19T23:59:59.000Z

280

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Second quarter 1993  

SciTech Connect (OSTI)

Groundwater monitoring continued at the Savannah River Plant. During second quarter 1993, nine constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents. Chloroethene (vinyl chloride), dichloromethane (methylene chloride), 1,1-dichloroethylene, gross alpha, lead, nonvolatile beta, or tetrachloroethylene also exceeded standards in one or more wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Health assessment for H and H Incorporated Burn Site, Farrington, Virginia, Region 3. CERCLIS No. VAD980539878. Preliminary report  

SciTech Connect (OSTI)

The H H Incorporated Burn Site, located in Hanover County, Virginia, contains a pit where dry printing ink residues were disposed of. Groundwater contaminants of concern (and maximum concentrations) include benzene (25 ppb), toluene (1180 ppb), chromium (110 ppb), barium (1,300 ppb), beryllium (20 ppb). Organics, including phthalates (131,000 ppb), vinyl chloride (3,600 ppb), toluene (82 ppb), and xylenes (45 ppb), were detected in leachate and/or runoff, presumably emanating from the pit area. The site is considered to be of potential public health concern because of the risk to human health caused by the possibility of human exposure to hazardous substances.

Not Available

1988-05-05T23:59:59.000Z

282

Identification and Developmental Expression of Xenopus laevis SUMO Proteases  

E-Print Network [OSTI]

]. Human SENP1 and SENP2 are most closely related to each other, and can catalyze processing and deconjugation of all SUMO paralogues [12,13,14]. Human SENP3 and SENP5 are likewise most closely related to each other, but they show a strong preference... derivatives of tagged SUMO-1 and -2 (HA-SU1-VME and HA-SU2-VME; [44]). In all cases, actin was used as a loading control to assure that equivalent amounts of protein were loaded in each lane. In a manner similar to their vinyl sulfone counterparts, HA-SU1-VME...

Wang, Yonggang; Mukhopadhyay, Debaditya; Mathew, Smita; Hasebe, Takashi; Heimeier, Rachel A.; Azuma, Yoshiaki; Kolli, Nagamalleswari; Shi, Yun-bo; Wilkinson, Keith D.; Dasso, Mary

2009-12-24T23:59:59.000Z

283

Fluorescence emission as a probe to investigate electrochemical polymerization of 9-vinylanthracene  

SciTech Connect (OSTI)

The cationic polymerization of 9-vinylanthracene can be initiated at a transparent SnO/sub 2/ electrode with the application of anodic potentials (E > 1.1 V vs. saturated sodium chloride calomel electrode) in acetonitrile solutions. The excimer emission (emission maximum approx.500 nm) of poly(9-vinyl-anthracene) which is distinguishable from the monomer fluorescence emission (emission maxima 410, 430 nm) has been used to probe the electrochemical polymerization process directly. The in situ spectroelectrochemical technique, which would be useful in obtaining kinetic and mechanistic information of the electropolymerization process, is described.

Kamat, P.V.

1987-07-01T23:59:59.000Z

284

Resource recovery - a byproduct of hazardous waste incineration  

SciTech Connect (OSTI)

Three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer (VCM) facility are described: the incinerator, the energy-recovery system, and the byproduct-recovery system. The overall efficiency of the energy- and *byproduct-recovery systems is dependent on the optimization of the primary combustor. An example is presented in table form which lists typical waste quantities for the plant and operating costs, including utility requirements for the incinerator system, the quench, absorber and scrubber. Savings that can result by the addition of the energy- and acid-recovery systems can pay for the waste disposal system and return money to the plant.

Santoleri, J.J.

1982-11-01T23:59:59.000Z

285

Cationically polymerizable monomers derived from renewable sources  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year's research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

286

Temperature-responsive surface-functionalized polyethylene films  

E-Print Network [OSTI]

precursors. PhotograAing on these surfaces (Equation 1) in the presence of various vinyl monomers was found to be very effective, as XPS and ATR-IR data indicated the extent of grafting could be controlled by monomer concentration and the solvent employed... in this case was measured by following the percent quenching of pyrene as these films were suspended in varying concentrations of a quenching agent, such as N-N'-dimethylethanolamine, in solvents such as THF, methylene chloride and ethanol. The value...

Ponder, Bill C.

2012-06-07T23:59:59.000Z

287

Global petrochemical R and D focus on projects that provide a return  

SciTech Connect (OSTI)

Because of tough market conditions, the research and development of new petrochemical products is down along with spending. The paper discusses the new marketing strategy used by petrochemical developers while relenting all blue sky research to academia. The paper discusses developments and research in the four main targeted research areas. These include basic petrochemicals such as ethylene an propylene; petrochemical intermediates such as 1,4 butanediol and vinyl chloride monomer; commodity polymers, notably linear low density polyethylene; and, specialty polymers such as engineering plastics. The advances in production technologies in these areas are then discussed.

Knott, D.

1996-08-26T23:59:59.000Z

288

Cationically polymerizable monomers derived from renewable sources. Annual performance report  

SciTech Connect (OSTI)

The objectives of this project are to design and synthesize novel monomers which orginate from renewable biological sources and to carry out their rapid, efficient, pollution-free and energy efficient cationic polymerization to useful products under the influence of ultraviolet light or heat. A summary of the results of the past year`s research on cationically polymerizable monomers derived from renewable sources is presented. Three major areas of investigation corresponding to the different classes of naturally occurring starting materials were investigated; epoxidized terpenes and natural rubber and vinyl ethers from alcohols and carbohydrates.

Crivello, J.V.

1992-10-01T23:59:59.000Z

289

Ultra Accelerated Testing of PV Module Components  

SciTech Connect (OSTI)

Using concentrated natural sunlight at the NREL High Flux Solar Furnace, we have exposed several materials to acceleration factors of up to 400 times the normal outdoor UV exposure dose. This accelerated rate allows the exposure of materials such that a year of outdoor exposure can be simulated in about 5 hours. We have studied the solarization of cerium containing glass, the degradation of ethylene vinyl acetate laminated between borosilicate glass, and the yellowing of standard polystyrene test coupons. The first two candidates are of interest to the photovoltaics (PV) program, and the last candidate material is a widely used dosimeter for ultra violet (UV) exposure in accelerated weathering chambers

Pitts, J. R.; King, D. E.; Bingham, C.; Czanderna, A. W.

1998-10-28T23:59:59.000Z

290

U.S. Department of Energy NEPA Categorical Exclusion Determination Form  

Broader source: Energy.gov (indexed) [DOE]

AK AK Project Title ID-TEP-NEZ PERCE TRIBE Location: Tribal NEZ PERCE TRIBE FOA Number: DE-FOA-0000423 Proposed Action or Project Descriptio The Nez Perce Tribe of Idaho proposes to conduct building retrofits to the Nez Perce Tribal Executive Committee (NPTEC)/Office of Legal Counsel (OLC) (1970), Veteran's Memorial Building (1977-78), Pi Nee Waus Community Building (1963), Water Resources Building (1978), and Boy's and Girl's Club (newer facility). Energy efficiency measures proposed on the five buildings would include: the four older buildings would receive vinyl, double-pane, Low-E windows; increased blown-in attic insulation; and

291

Buildings Energy Data Book: 2.6 Residential Home Improvement  

Buildings Energy Data Book [EERE]

6 6 2010-2011 National Professional Remodeling Cost and Amount Recouped in Resale Value Envelope Siding Replacement - Vinyl 11.4 8.2 72% Window Replacement - Vinyl 11.1 7.9 72% Window Replacement - Wood 12.0 8.7 72% Roofing Replacement 21.5 12.8 60% Entry Door Replacement - Fiberglass 3.6 2.1 60% Entry Door Replacement - Steel 1.2 1.2 102% Remodel Minor Kitchen Remodel 21.7 15.8 73% Major Kitchen Remodel 58.4 40.1 69% Bathroom Remodel 16.6 10.7 64% Attic Bedroom Remodel 51.4 37.1 72% Basement Remodel 64.5 45.2 70% Home Office Remodel 28.9 13.2 46% Additions Deck Addition - Wood 11.0 8.0 73% Deck Addition - Composite 15.6 10.3 66% Bathroom Addition 40.7 21.7 53% Garage Addition 60.6 35.9 59% Sunroom Addition 75.2 36.5 49% Family Room Addition 85.7 53.6 63% Master Suite Addition 108.1 68.1 63% Two-Story Addition 165.2 107.3 65%

292

Treatment of addiction and addiction-related behavior  

DOE Patents [OSTI]

The present invention provides a highly efficient method for treating substance addiction and for changing addiction-related behavior of a mammal suffering from substance addiction. The method includes administering to a mammal an effective amount of gamma vinylGABA or a pharmaceutically acceptable salt thereof. The present invention also provides a method of treatment of cocaine, morphine, heroin, nicotine, amphetamine, methamphetamine, or ethanol addiction by treating a mammal with an effective amount of gamma vinylGABA or a pharmaceutically acceptable salt thereof. In one embodiment, the method of the present invention includes administering to the mammal an effective amount of a composition which increases central nervous system GABA levels wherein the effective amount is sufficient to diminish, inhibit or eliminate behavior associated with craving or use of drugs of abuse. The composition includes GVG, gabapentin, valproic acid, progabide, gamma-hydroxybutyric acid, fengabine, cetylGABA, topiramate or tiagabine or a pharmaceutically acceptable salt thereof, or an enantiomer or a racemic mixture thereof.

Dewey, Stephen L. (Manorville, NY); Brodie, Jonathan D. (Cos Cob, CT); Ashby, Jr., Charles R. (Miller Place, NY)

2003-01-01T23:59:59.000Z

293

Virtual Optical Comparator  

SciTech Connect (OSTI)

The Virtual Optical Comparator, VOC, was conceived as a result of the limitations of conventional optical comparators and vision systems. Piece part designs for mechanisms have started to include precision features on the face of parts that must be viewed using a reflected image rather than a profile shadow. The VOC concept uses a computer generated overlay and a digital camera to measure features on a video screen. The advantage of this system is superior edge detection compared to traditional systems. No vinyl charts are procured or inspected. The part size and expensive fixtures are no longer a concern because of the range of the X-Y table of the Virtual Optical Comparator. Product redesigns require only changes to the CAD image overlays; new vinyl charts are not required. The inspection process is more ergonomic by allowing the operator to view the part sitting at a desk rather than standing over a 30 inch screen. The procurement cost for the VOC will be less than a traditional comparator with a much smaller footprint with less maintenance and energy requirements.

Thompson, Greg

2008-10-20T23:59:59.000Z

294

Synthesis and characterization of self-assembling water-soluble polymers  

SciTech Connect (OSTI)

The synthesis is proposed of water-soluble vinyl and other polymers capable of self-assembly through hydrophobic bonding of pendent fluorocarbon and other hydrophobic groups. The self-assembly process will be studied by viscometry and dynamic viscoelasticity, and by static and dynamic light scattering. These investigations are aimed at identifying the structural features of polymers that are important in enhancing the viscosity of aqueous polymer solutions at very low polymer concentrations (< 1,000 ppm). The authors also initiate small angle neutron scattering (SANS) measurements aimed at the determination of the size of the fluorocarbon-containing hydrophobic aggregates. They will be interested in the degree of self assembly as a function of the type and length of the hydrophobic groups and of the type and length of the flexible spacer group linking the hydrophobic to the polymer backbone. The nature of the hydrophilic chain will also be of interest. Thus, they investigate a number of hydrophilic comonomers such as acrylamide, N-vinylpyrrolidone and anionic or cationic vinyl monomers. Surface interactions of these interesting copolymers will be studied by adsorption onto appropriate modified latex spheres. Finally, they propose to explore the synthesis of water-soluble polymers capable of self assembly through interactions of pendent polyanions and polycations.

Hogen-Esch, T.E.; Amis, E.J.

1992-05-01T23:59:59.000Z

295

Field lysimeter investigations: Low-level waste data base development program for fiscal year 1995. Volume 8, Annual report, October 1994-- September 1995  

SciTech Connect (OSTI)

The Field Lysimeter Investigations: Low-Level Waste Data Base Development Program, funded by the U.S. Nuclear Regulatory Commission, is (a) studying the degradation effects in organic ion-exchange resins caused by radiation, (b) examining the adequacy of test procedures recommended in the Branch Technical Position on Waste Form to meet the requirements of 10 CFR 61 using solidified ion-exchange resins, (c) obtaining performance information on solidified ion- exchange resins in a disposal environment, and (d) determining the condition of liners used to dispose the ion-exchange resins. Compressive test results of 12-year-old cement and vinyl ester- styrene solidified waste form samples are presented, which show effects of aging and self-irradiation. Results of the tenth year of data acquisition from the field testing are presented and discussed. During the continuing field testing, both portland type I-II cement and Dow vinyl ester-styrene waste form samples are being tested in lysimeter arrays located at Argonne National Laboratory-East in Illinois and at Oak Ridge National Laboratory. The study is designed to provide continuous data on nuclide release and movement, as well as environmental conditions, over a 20-year period.

McConnell, J.W. Jr.; Rogers, R.D.; Larsen, I.L. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States); Jastrow, J.D. [Argonne National Lab., IL (United States); Sanford, W.E. [Oak Ridge National Lab., TN (United States); Sullivan, T.M. [Brookhaven National Lab., Upton, NY (United States)

1996-06-01T23:59:59.000Z

296

Blower upkeep, energy savings estimated at $20,000/yr  

SciTech Connect (OSTI)

Vinyl chloride gas must be removed from operating vessels in a polymerization process at Occidental Chemical, Addis, LA. If left intact, the gases can polymerize and form deposits. Considered for this function were reciprocating and liquid ring type compressors. They were rejected, however, because of anticipated high valve maintenance and energy consumption. Since high reliability and leak-free performance are essential, two double-mechanical-sealed, positive displacement blowers were installed with water injection in 1980. The blowers are designed for those special applications where gas leak tightness is required or where continuous, high-pressure or vacuum, single-stage or two-stage is needed. The lobe-type blowers were selected by Occidental because they were considered to be best suited for the low-pressure differential operation. All internal surfaces are specially cleaned to reduce contamination and may be operated with non-hydrocarbon lubricants. A back-up seal on the drive shaft provides protection against leakage of process gas to the atmosphere. Maintenance and energy savings are estimated at $20,000/yr. The blowers were used with the water injection technique because previous experience vinyl chloride monomer indicated that there were major deposits inside the compressors and ring units. The blowers have provided contaminant-free (oil-free) monomer, and the water injection has prevented the polymerization material from sticking to the surfaces of the blowers. This has ensured practically trouble-free operation, and has greatly reduced maintenance and operation downtime, significantly reducing cost.

Diehl, R.; Powers, J.

1987-05-01T23:59:59.000Z

297

Surface nano-patterning through styrene adsorption on Si(100)  

E-Print Network [OSTI]

We present an ab initio study of the structural and electronic properties of styrene molecules adsorbed on the dimerized Si(100) surface at different coverages, ranging from the single-molecule to the full monolayer. The adsorption mechanism primarily involves the vinyl group via a [2+2] cycloaddition process that leads to the formation of covalent Si-C bonds and a local surface derelaxation, while it leaves the phenyl group almost unperturbed. The investigation of the functionalized surface as a function of the coverage (e.g. 0.5 -- 1 ML) and of the substrate reconstruction reveals two major effects. The first results from Si dimer-vinyl interaction and concerns the controlled variation of the energy bandgap of the interface. The second is associated to phenyl-phenyl interactions, which gives rise to a regular pattern of electronic wires at surface, stemming from the pi-pi coupling. These findings suggest a rationale for tailoring the surface nano-patterning of the surface, in a controlled way.

A. Calzolari; A. Ruini; M. J. Caldas; E. Molinari

2005-07-27T23:59:59.000Z

298

Hydrogenation of Acetylene-Ethylene Mixtures over Pd and Pd-Ag Alloys: First-Principles Based Kinetic Monte Carlo Simulations  

SciTech Connect (OSTI)

The kinetics for the selective hydrogenation of acetylene-ethylene mixtures over model Pd(111) and bimetallic Pd-Ag alloy surfaces were examined using first principles based kinetic Monte Carlo (KMC) simulations to elucidate the effects of alloying as well as process conditions (temperature and hydrogen partial pressure). The mechanisms that control the selective and unselective routes which included hydrogenation, dehydrogenation and C-?C bond breaking pathways were analyzed using first-principle density functional theory (DFT) calculations. The results were used to construct an intrinsic kinetic database that was used in a variable time step kinetic Monte Carlo simulation to follow the kinetics and the molecular transformations in the selective hydrogenation of acetylene-ethylene feeds over Pd and Pd-Ag surfaces. The lateral interactions between coadsorbates that occur through-surface and through-space were estimated using DFT-parameterized bond order conservation and van der Waal interaction models respectively. The simulation results show that the rate of acetylene hydrogenation as well as the ethylene selectivity increase with temperature over both the Pd(111) and the Pd-Ag/Pd(111) alloy surfaces. The selective hydrogenation of acetylene to ethylene proceeds via the formation of a vinyl intermediate. The unselective formation of ethane is the result of the over-hydrogenation of ethylene as well as over-hydrogenation of vinyl to form ethylidene. Ethylidene further hydrogenates to form ethane and dehydrogenates to form ethylidyne. While ethylidyne is not reactive, it can block adsorption sites which limit the availability of hydrogen on the surface and thus act to enhance the selectivity. Alloying Ag into the Pd surface decreases the overall rated but increases the ethylene selectivity significantly by promoting the selective hydrogenation of vinyl to ethylene and concomitantly suppressing the unselective path involving the hydrogenation of vinyl to ethylidene and the dehydrogenation ethylidene to ethylidyne. This is consistent with experimental results which suggest only the predominant hydrogenation path involving the sequential addition of hydrogen to form vinyl and ethylene exists over the Pd-Ag alloys. Ag enhances the desorption of ethylene and hydrogen from the surface thus limiting their ability to undergo subsequent reactions. The simulated apparent activation barriers were calculated to be 32-44 kJ/mol on Pd(111) and 26-31 kJ/mol on Pd-Ag/Pd(111) respectively. The reaction was found to be essentially first order in hydrogen over Pd(111) and Pd-Ag/Pd(111) surfaces. The results reveal that increases in the hydrogen partial pressure increase the activity but decrease ethylene selectivity over both Pd and Pd-Ag/Pd(111) surfaces. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

Mei, Donghai; Neurock, Matthew; Smith, C Michael

2009-10-22T23:59:59.000Z

299

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

41 - 20950 of 28,560 results. 41 - 20950 of 28,560 results. Download Techniques and Technologies for Field Detection of Asbestos Containing Materials Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement(transite) siding. http://energy.gov/em/downloads/techniques-and-technologies-field-detection-asbestos-containing Article Former Assistant Secretary Reflects on Career High Point Leading EM: 'Well Worth the Effort' WASHINGTON, D.C. - In an occasional EM Update series, we feature interviews with former EM Assistant Secretaries to reflect on their achievements and challenges in the world's largest nuclear cleanup and to discuss endeavors in life after EM. http://energy.gov/em/articles/former-assistant-secretary-reflects-career-high-point-leading-em-well-worth-effort

300

Energy Efficiency and Conservation Block Grant Program  

Broader source: Energy.gov (indexed) [DOE]

MI-City-Clinton, Charter Township of MI-City-Clinton, Charter Township of Location: City Clinton, Charter MI Township of American Recovery and Reinvestment Act: Proposed Action or Project Description: 1) Energy efficiency retrofits (install vinyl siding) at the Heritage Estates Senior Center, and 2) upgrade of existing street lights. Conditions: None Categorical Exclusion(s) Applied: B2.5, B5.1 *-For the complete DOE National Environmental Policy Act regulations regarding categorical exclusions, see Subpart D of 10 CFR10 21 This action would not: threaten a violation of applicable statutory, regulatory, or permit requirements for environment, safety, and health, including DOE and/or Executive Orders; require siting, construction, or major expansion of waste storage, disposal, recovery, or

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Program or Field Office: Office of Legacy Management Project Title and I.D. No.: Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida,  

Broader source: Energy.gov (indexed) [DOE]

Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, Bioremediation Injection and Related Activities at the Pinellas Site, Largo, Florida, LM 13-13 Location: Largo, Florida Proposed Action or Project Description: DOE proposes to use a Geoprobe to inject emulsified edible soybean oil (EEO) and anaerobic microbial solution into the surficial aquifer at the 4.5 Acre Site adjacent to the DOE Young - Rainey STAR Center (Pinellas Site) in Largo, Florida. The proposed action would enhance naturally occurring anaerobic biodegradation, thereby reducing vinyl chloride contamination along the southwest boundary of the 4.5 Acre Site. Dehalococcoides ethenogenes (DHE) is a type of microbe that occurs naturally in the aquifer. Bioaugmentation with a commercially available DHE culture used in conjunction with the EEO would maximize the efficiency of contaminant biodegradation. No genetically engineered or

302

Indoor Residential Chemical Emissions as Risk Factors for Children's  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Indoor Residential Chemical Emissions as Risk Factors for Children's Indoor Residential Chemical Emissions as Risk Factors for Children's Respiratory Health Speaker(s): Mark Mendell Date: February 23, 2007 - 12:00pm Location: 90-3122 Most research into the effects of residential indoor air exposures on asthma and allergies has focused on exposures to biologic allergens, moisture and mold, endotoxin, or combustion byproducts. A growing body of research suggests that chemical emissions from common indoor materials and finishes have adverse effects, including increased risk of asthma, allergies, and pulmonary infections. The identified risk factors include specific organic compounds such as formaldehyde, benzene, and phthalates, as well as indoor materials or finishes such as vinyl flooring, carpet, paint, and plastics. This presentation presents a brief review of studies

303

ENVIRONMENTAL REVIEW for CATEGORICAL EXCLUSION DETERMINATION  

Broader source: Energy.gov (indexed) [DOE]

Casper Service Center Garage Door Insulation Casper Service Center Garage Door Insulation Natrona County, Wyoming A. Brief Description of Proposal: Western Area Power Administration (Western) would replace the insulation in the garage door at the Casper Service Center (CSC), Natrona County, Wyoming. The vinyl-faced fiberglass insulation replacement would include all insulation batts damaged from roof leaks. The proposed work at CSC consists of the following: maintenance crews would remove the damaged insulation and replace and install new fiberglass insulation batts in the garage door. All work would be conducted within the existing service center yard and directly outside of the buildings. B. Number and Title of the Categorical Exclusion Being Applied: (See text in 10 CFR Part 1021, Subpart D.)

304

The Risk Assessment Information System  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2-DICHLOROETHANE 2-DICHLOROETHANE NOTE: Although the toxicity values presented in these toxicity profiles were correct at the time they were produced, these values are subject to change. Users should always refer to the Toxicity Value Database for the current toxicity values. May 1994 Prepared by Dennis M. Opresko, Ph.D., Chemical Hazard Evaluation and Communication Program, Biomedical and Environmental Information Analysis Section, Health Sciences Research Division, *, Oak Ridge, Tennessee. Prepared for OAK RIDGE RESERVATION ENVIRONMENTAL RESTORATION PROGRAM. *Managed by Martin Marietta Energy Systems, Inc., for the U.S. Department of Energy under contract No. DE-AC05-84OR21400. 1,2-Dichloroethane is used primarily in the manufacture of vinyl chloride, as well as in the synthesis of tetrachloroethylene, trichloroethylene,

305

Novel PMDA-ODA Polyimide/Polystyrene Nanocomposite Membranes for Carbon Dioxide Separation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

This work was supported by the National Natural Science Foundation of China (Grant Nos. 59703005) Novel PMDA-ODA Polyimide/Polystyrene Nanocomposite Membranes for Carbon Dioxide Separation Zhi-Kang Xu*, Li Xiao, Jianli Wang, You-Yi Xu Institute of Polymer Science, Zhejiang University, 310027, Hangzhou, P. R. China Tel: +86-571-7951342-8218, E-mail: xuzk@ipsm.zju.edu.cn ABSTRACT Using N,N-dimethylacetalamide (DMAc) as the suspension media of polystyrene (PS) and poly[styrene-co-(4-vinyl-pyridin)] (PSVP) nanoparticles, in- situ condensation polymerization of dianhydride and diamine was carried out and homogenous polyamic acid solution containing the nanoparticles were obtained. Novel PMDA-ODA nanocomposite membranes with various contents of nanoparticles were prepared by the casting of polyamic acid solution followed

306

ENVIRONMENTAL REVIEW for CATEGORICAL EXCLUSION DETERMINATION  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Casper Service Center Garage Door Insulation Casper Service Center Garage Door Insulation Natrona County, Wyoming A. Brief Description of Proposal: Western Area Power Administration (Western) would replace the insulation in the garage door at the Casper Service Center (CSC), Natrona County, Wyoming. The vinyl-faced fiberglass insulation replacement would include all insulation batts damaged from roof leaks. The proposed work at CSC consists of the following: maintenance crews would remove the damaged insulation and replace and install new fiberglass insulation batts in the garage door. All work would be conducted within the existing service center yard and directly outside of the buildings. B. Number and Title of the Categorical Exclusion Being Applied: (See text in 10 CFR Part 1021, Subpart D.)

307

Techniques and Technologies for Field Detection of Asbestos Containing Materials  

Broader source: Energy.gov (indexed) [DOE]

DOE-Environmental Management DOE-Complex Wide Techniques and Technologies for Field Detection of Asbestos Containing Materials Challenge Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement (transite) siding. Inhalation of asbestos can result in non-malignant asbestosis, lung cancer and mesothelioma in workers. Currently, 40 CFR 763, Subpart E requires a certain number of bulk samples of suspected asbestos-containing material (ACM) to be collected within each designated homogeneous area (HA). If real time (or near-real), in-situ detection techniques/technologies of  5, and preferably  3 weight percent asbestos, were available, sample numbers

308

Fume Hood Sash Stickers Increases Laboratory Safety and Efficiency at Minimal Cost  

Broader source: Energy.gov (indexed) [DOE]

confused by labels placed at 18 inches confused by labels placed at 18 inches that say "Place Sash here for Maximum Safety." The authors of these labels have confused "maximum" and "minimum", not realizing that a hood is least safe when fully open. A Basic Solution To address the confusion at the University of California, a lab manager and a hood safety specialist designed a bold vinyl sticker to attach on the exterior sidewall of a fume hood (Figure 1). The sticker cleverly uses the ubiquitous traffic light color scheme, with a red zone above 18 inches, and a large arrow pointing down with the words, "More Safe, Less Energy" changing from yellow at the midpoint to green at the bottom when the sash is closed completely. Interestingly,

309

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

11 - 23820 of 29,416 results. 11 - 23820 of 29,416 results. Download Contractor Fee Payments- Portsmouth Paducah Project Office See the amount of fees earned on EM's major contracts for each evaluated fee period and the total contract to date at the Portsmouth Paducah Project Office on these charts. http://energy.gov/em/downloads/contractor-fee-payments-portsmouth-paducah-project-office Download Techniques and Technologies for Field Detection of Asbestos Containing Materials Asbestos has been used in numerous applications at DOE sites including sprayed-on fireproofing, asphalt and vinyl floor tile, and asbestos-cement(transite) siding. http://energy.gov/em/downloads/techniques-and-technologies-field-detection-asbestos-containing Article Former Assistant Secretary Reflects on Career High Point Leading

310

To: John R. Novak Radiation Safety - IRS From: G. T. Lonergan Radiation Safety - II§  

Office of Legacy Management (LM)

7, 19% 7, 19% To: John R. Novak Radiation Safety - IRS From: G. T. Lonergan Radiation Safety - II§ Subject: Extrusion of Billets, Titus Metals, Inc., Waterloo, Iowa A grpup of ANL aqloyees consisting of LE. Walker and S. Matsas (MET), E. Leverens (SSE), I(. C.~Buffy'(SPM), and G. T. Lonergan (IRS), traveled to Waterloo, Iowa, on June 29 where they accomplished the extrusion of U308 billets into fuel plates for Argonaut. Prior to beginning the extrusion operation, the floor area around the press, run-out table, stretch straightener, and all accessible portions of the press were surveyed. No activity was detected. The floor area from the furnace (uhere the billets were heated) to the press was coveredwith a layer of vinyl approximately 48fl wide and topped

311

Center for Nanophase Materials Sciences (CNMS) - Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5 PUBLICATIONS 5 PUBLICATIONS Links to individual papers are provided when available online. These links will take you to other web sites and will open in a new window. Subscription may be required to access online publications. Carbon J. Bernholc, W. Lu, S. M. Nakhmanson, V. Meunier, and M. Buongiorno Nardelli, "Multiscale Simulations of Quantum Structures," p. 18 in Proceedings of DoD 2005 Users Group Conference, IEEE Computer Society (2005). J.-G. Che and H. P. Cheng, "First-Principles Investigation of a Monolayer of C60 on h-BN/Ni(111)," Phys. Rev. B: Condens. Matter 72, 115436 (2005). K. A. S. Fernando, Y. Lin, B. Zhou, R. Joseph, L. F. Allard, and Y.-P. Sun, "Poly(ethylene-co-vinyl alcohol)-Functionalized Single-Walled Carbon Nanotubes and Related Nanocomposites," J. Nanosci. Nanotech. 5 (7), 1050 (2005).

312

Research on stable, high-efficiency amorphous silicon multijunction modules. Semiannual subcontract report, 1 January 1992--30 June 1992  

SciTech Connect (OSTI)

This report describes research on semiconductor and non-semiconductor materials to enhance the performance of multi-band-gap, multijunction panel with an area greater than 900 cm{sup 2} by 1992. Double-junction and triple-junction cells are mode on a Ag/ZnO back reflector deposited on stainless steel substrates. An a-SiGe alloy is used for the i-layer in the bottom and the middle cells; the top cell uses an amorphous silicon alloy. After the evaporation of an antireflection coating, silver grids and bus bars are put on the top surface and the panel is encapsulated in an ethylene vinyl acetate (EVA)/Tefzel structure to make a 1-ft{sup 2} monolithic module.

Guha, S. [United Solar Systems Corp., Troy, MI (United States)

1992-09-01T23:59:59.000Z

313

Research on stable, high-efficiency amorphous silicon multijunction modules  

SciTech Connect (OSTI)

This report describes research on semiconductor and non-semiconductor materials to enhance the performance of multi-band-gap, multijunction panel with an area greater than 900 cm[sup 2] by 1992. Double-junction and triple-junction cells are mode on a Ag/ZnO back reflector deposited on stainless steel substrates. An a-SiGe alloy is used for the i-layer in the bottom and the middle cells; the top cell uses an amorphous silicon alloy. After the evaporation of an antireflection coating, silver grids and bus bars are put on the top surface and the panel is encapsulated in an ethylene vinyl acetate (EVA)/Tefzel structure to make a 1-ft[sup 2] monolithic module.

Guha, S. (United Solar Systems Corp., Troy, MI (United States))

1992-09-01T23:59:59.000Z

314

Experimental Design for a Macrofoam-Swab Study Relating the Recovery Efficiency and False Negative Rate to Low Concentrations of Two Bacillus anthracis Surrogates on Four Surface Materials  

SciTech Connect (OSTI)

This report describes the experimental design for a laboratory study to quantify the recovery efficiencies and false negative rates of a validated, macrofoam-swab sampling method for low concentrations of Bacillus anthracis Sterne (BAS) and Bacillus atrophaeus (BG) spores on four surface materials (stainless steel, glass, vinyl tile, plastic light cover panel). Two analytical methods (culture and polymerase chain reaction) will be used. Only one previous study has investigated how the false negative rate depends on test factors. The surrogates BAS and BG have not been tested together in the same study previously. Hence, this study will provide for completing gaps in the available information on the performance of macrofoam-swab sampling at low concentrations.

Piepel, Gregory F.; Hutchison, Janine R.

2014-12-05T23:59:59.000Z

315

Accelerated leach test development program  

SciTech Connect (OSTI)

In FY 1989, a draft accelerated leach test for solidified waste was written. Combined test conditions that accelerate leaching were validated through experimental and modeling efforts. A computer program was developed that calculates test results and models leaching mechanisms. This program allows the user to determine if diffusion controls leaching and, if this is the case, to make projections of releases. Leaching mechanisms other than diffusion (diffusion plus source term partitioning and solubility limited leaching) are included in the program is indicators of other processes that may control leaching. Leach test data are presented and modeling results are discussed for laboratory scale waste forms composed of portland cement containing sodium sulfate salt, portland cement containing incinerator ash, and vinyl ester-styrene containing sodium sulfate. 16 refs., 38 figs., 5 tabs.

Fuhrmann, M.; Pietrzak, R.F.; Heiser, J.; Franz, E.M.; Colombo, P.

1990-11-01T23:59:59.000Z

316

Achieving minimum impact insulation class 50 rating using resilient clip technology in lightweight construction.  

Science Journals Connector (OSTI)

Resilient clip technology is an alternative to resilient channel for supporting gypsum wallboard in fire rated wall and floor?ceiling assemblies. Lightweight wood frame construction presents challenges in meeting building code requirements for impact insulation class (IIC) and sound transmission class (STC) ratings in floor?ceiling assemblies. Through laboratory testing we were able to compare different floor?ceiling assemblies commonly used in multi?family construction. Two different structures were tested an 18 in. open web truss 24 in. o.c. and a 12 in. engineered joist (TJI) 24 in. o.c. Various finish floor coverings were used including ceramic tile vinyl and engineered wood. Structures achieved minimum IIC and STC 50 with and without 3/4 in. Gypsum concrete. Resilient rubber underlayment of varying thickness can further improve the IIC and STC ratings of the assembly as can adding a second layer of gypsum wallboard.

Wilson Byrick

2010-01-01T23:59:59.000Z

317

Research in chemical kinetics. Annual report, 1993  

SciTech Connect (OSTI)

Progress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}.

Rowland, F.S.

1993-12-31T23:59:59.000Z

318

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, E.D. Jr.

1995-07-11T23:59:59.000Z

319

Method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from impeding the flow of fluid in a fluid system. An additive is contacted with clathrate hydrate masses in the system to prevent those clathrate hydrate masses from impeding fluid flow. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include poly(N-vinyl-2-pyrrolidone) and hydroxyethylcellulose, either in combination or alone. Additives can also contain multiple cyclic chemical groupings having different size rings. One such additive is sold under the name Gaffix VC-713.

Sloan, Jr., Earle D. (Golden, CO)

1995-01-01T23:59:59.000Z

320

Coated metal fiber coalescing cell  

SciTech Connect (OSTI)

A cell is described for coalescing oil droplets dispersed in a water emulsion including an elongated perforated tube core into which the emulsion is injected, layers of oleophilic plastic covered metal mat wound about the core through which the emulsion is forced to pass, the fibers of the metal mat being covered by oleophilic plastic such as vinyl, acrylic, polypropylene, polyethylene, polyvinyl chloride, the metal being in the form of layers of expanded metal or metal fibers, either aluminum or stainless steel. In manufacturing the cell a helix wound wire is formed around the cylindrical plastic coated metal to retain it in place and resist pressure drop of fluid flowing through the metal fibers. In addition, the preferred arrangement includes the use of an outer sleeve formed of a mat of fibrous material such as polyester fibers, acrylic fibers, modacrylic fibers and mixtures thereof.

Rutz, W.D.; Swain, R.J.

1980-12-23T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Alkyne Activation DOI: 10.1002/anie.201101090  

E-Print Network [OSTI]

2 T [8C] t [h] Yield [%][a] 1 CO2tBu Ph TES iPr RT 12 83 2 CO2Et H TES iPr 0 4 87 3 CO2Et H TES Bn 0 4 67 4 COSBu Ph TES iPr ?20 1 69 5 COStBu Ph TMS iPr ?20 1 67 6 COStBu Ph TIPS iPr ?20 1 75 7 COStBu Ph TES tBu ?20 1 78 8 COStBu vinyl TES iPr ?20 1 71 9 COStBu 2-naph TES iPr ?20 1 76 10 COStBu o

Lepore, Salvatore D.

322

Microwavable thermal energy storage material  

DOE Patents [OSTI]

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene-vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments.

Salyer, Ival O. (Dayton, OH)

1998-09-08T23:59:59.000Z

323

Microwavable thermal energy storage material  

DOE Patents [OSTI]

A microwavable thermal energy storage material is provided which includes a mixture of a phase change material and silica, and a carbon black additive in the form of a conformable dry powder of phase change material/silica/carbon black, or solid pellets, films, fibers, moldings or strands of phase change material/high density polyethylene/ethylene vinyl acetate/silica/carbon black which allows the phase change material to be rapidly heated in a microwave oven. The carbon black additive, which is preferably an electrically conductive carbon black, may be added in low concentrations of from 0.5 to 15% by weight, and may be used to tailor the heating times of the phase change material as desired. The microwavable thermal energy storage material can be used in food serving applications such as tableware items or pizza warmers, and in medical wraps and garments. 3 figs.

Salyer, I.O.

1998-09-08T23:59:59.000Z

324

Mixed Waste Management Facility (MWMF) groundwater monitoring report. Fourth quarter 1993 and 1993 summary  

SciTech Connect (OSTI)

During fourth quarter 1993, 10 constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Carbon tetrachloride, chloroform, chloroethane (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone 2B{sub 2} (Water Table) and Aquifer Zone 2B{sub 1}, (Barnwell/McBean) wells and in two Aquifer Unit 2A (Congaree) wells. The groundwater flow direction and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Butler, C.T.

1994-03-01T23:59:59.000Z

325

Mixed Waste Management Facility (MWMF) groundwater monitoring report: Third quarter 1993  

SciTech Connect (OSTI)

During third quarter 1993, eight constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, and the proposed Hazardous Waste/Mixed Waste Disposal Vaults. As in previous quarters, tritium and trichloroethylene were the most widespread constituents Chloroethene (vinyl chloride), 1,1-dichloroethylene, dichloromethane (methylene chloride), lead, mercury, or tetrachloroethylene also exceeded standards in one or more wells. The elevated constituents were found in Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1} (Barnwell/McBean) wells. No elevated constituents were exhibited in Aquifer Unit IIA (Congaree) wells. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1993-12-01T23:59:59.000Z

326

Mixed Waste Management Facility groundwater monitoring report, First quarter 1994  

SciTech Connect (OSTI)

During first quarter 1994, nine constituents exceeded final Primary Drinking Water Standards in groundwater samples from downgradient monitoring wells at the Mixed Waste Management Facility, the Old Burial Ground, the E-Area Vaults, the proposed Hazardous Waste/Mixed Waste Disposal Vaults, and the F-Area Sewage Sludge Application Site. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents. Chloroethene (vinyl chloride), copper, 1,1-dichloroethylene, lead, mercury, nonvolatile beta, or tetrachloroethylene also exceeded standards in one or more wells. Elevated constituents were found in numerous Aquifer Zone IIB{sub 2} (Water Table) and Aquifer Zone IIB{sub 1}, (Barnwell/McBean) wells and in one Aquifer Unit IIA (Congaree) well. The groundwater flow directions and rates in the three hydrostratigraphic units were similar to those of previous quarters.

Not Available

1994-06-01T23:59:59.000Z

327

Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.  

SciTech Connect (OSTI)

In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

2012-02-01T23:59:59.000Z

328

Effect of Lamination Conditions on the Gas Permeability and Adhesion Strength of Green Ceramic Tapes  

SciTech Connect (OSTI)

The gas permeability and adhesion strength of laminated green ceramic tapes were determined for samples comprised of barium titanate as the dielectric, and poly(vinyl butyral) and dioctyl phthalate as the main components of the binder mixture. The green tapes were laminated for times of 2-10 min, pressures of 1.8-7 MPa, and temperatures of 35-85?C. The adhesion strength, which was measured by a peel test, increased with increasing lamination time, temperature, and pressure. The permeability, which was determined from gas flux measurements, decreased with increasing lamination time, temperature, and pressure. The dependence of the permeability and adhesion strength on lamination time, temperature, and pressure is qualitatively consistent with a mechanistic description of the lamination process as one of binder flow in porous media

D. Krueger

2007-08-31T23:59:59.000Z

329

Robust Magnetic/Polymer Hybrid Nanoparticles Designed for Crude Oil Entrapment and Recovery in Aqueous Environments  

Science Journals Connector (OSTI)

Department of Chemistry, Washington University in St. Louis, St. Louis, Missouri 63130, United States ... (10) Similarly, highly hydrophobic hybrid nanoparticles coated with vinyl triethoxysilane have also proven to be an efficient method for oil separation and removal, as demonstrated by Zhu et al.(15) Although these materials were shown to selectively absorb hydrophobic pollutants in aqueous environments, experiments have been conducted against contaminants of limited complexity, such as lubricating oil, mineral oil, and other homogeneous oils, without the broad range of components that would be experienced in a crude oil spill. ... Gas chromatographymass spectrometry (GC-MS) was used to perform a qualitative comparison of the weathered crude oil and the oil extracted from the testing groups. ...

Adriana Pava-Sanders; Shiyi Zhang; Jeniree A. Flores; Jonathan E. Sanders; Jeffery E. Raymond; Karen L. Wooley

2013-08-29T23:59:59.000Z

330

Experimental Design for a Macrofoam Swab Study Relating the Recovery Efficiency and False Negative Rate to Low Concentrations of Two Bacillus anthracis Surrogates on Four Surface Materials  

SciTech Connect (OSTI)

This report describes the experimental design for a laboratory study to quantify the recovery efficiencies and false negative rates of a validated, macrofoam swab sampling method for low concentrations of Bacillus anthracis Sterne (BAS) and Bacillus atrophaeus (BG) spores on four surface materials (stainless steel, glass, vinyl tile, plastic light cover panel). Two analytical methods (plating/counting and polymerase chain reaction) will be used. Only one previous study has investigated false negative as a function of affecting test factors. The surrogates BAS and BG have not been tested together in the same study previously. Hence, this study will provide for completing gaps in the available information on the performance of macrofoam swab sampling at low concentrations.

Piepel, Gregory F.; Hutchison, Janine R.

2014-04-16T23:59:59.000Z

331

Greenbelt Homes Pilot Energy Efficiency Program Phase 1 Summary: Existing Conditions and Baseline Energy Use  

SciTech Connect (OSTI)

A multi-year pilot energy efficiency retrofit project has been undertaken by Greenbelt Homes, Inc, (GHI) a 1,566 co-operative of circa 1930 and '40 homes. The three predominate construction methods of the townhomes in the community are materials common to the area and climate zone including 8" CMU block, wood frame with brick veneer and wood frame with vinyl siding. GHI has established a pilot project that will serve as a basis for decision making for the roll out of a decade-long community upgrade program that will incorporate energy efficiency to the building envelope and equipment with the modernization of other systems like plumbing, mechanical equipment, and cladding.

Wiehagen, J.; Del Bianco, M.; Wood, A.

2013-02-01T23:59:59.000Z

332

Embedded Piezoresistive Microcantilever Sensors Functionalized for the Detection of Methyl Salicylate  

SciTech Connect (OSTI)

Sensors designed to detect the presence of methyl salicylate (MeS) have been tested. These sensors use a sensor platform based on the embedded piezoresistive microcantilever (EPM) design. Sensing materials tested in this study included the polymer poly (ethylene vinyl acetate), or PEVA as well as a composite sensing material consisting of the enzyme SA-binding protein 2, or SABP-2. The SABP-2 was immobilized within a biocompatible Hypol gel matrix. The PEVA-based sensors exhibited slower but reversible responses to MeS vapors, recovering fully to their initial state after the analyte was removed. SABP-2 sensors exhibited faster overall response to the introduction of MeS, responding nearly instantly. These sensors, however, do not recover after exposures have ended. Sensors using the SABP-2 sensing materials act instead as integrating sensors, measuring irreversibly the total MeS dose obtained.

Porter, T. L. [UNLV; Venedam, R. J. [NSTec

2013-03-01T23:59:59.000Z

333

Image analysis of jet structure on electrospinning from free liquid surface  

SciTech Connect (OSTI)

The work analyses intra-jet distances during electrospinning from a free surface of water based poly(vinyl alcohol) solution confined by two thin metallic plates employed as a spinning electrode. A unique computer vision system and digital image processing were designed in order to track position of every polymer jet. Here, we show that jet position data are in good compliance with theoretically predicted intra-jet distances by linear stability analysis. Jet density is a critical parameter of electrospinning technology, since it determines the process efficiency and homogeneity of produced nanofibrous layer. Achievements made in this research could be used as essential approach to study jetting from two-dimensional spinning electrodes, or as fundamentals for further development of control system related to Nanospider{sup } technology.

Kula, Jiri, E-mail: jiri.kula@tul.cz; Linka, Ales, E-mail: ales.linka@tul.cz; Tunak, Maros, E-mail: maros.tunak@tul.cz [Department of Textile Evaluation, Faculty of Textile Engineering, Technical University of Liberec, Studentska 2, 461 17 Liberec (Czech Republic); Lukas, David, E-mail: david.lukas@tul.cz [Department of Nonwoven and Nanofibrous Materials, Faculty of Textile Engineering, Technical University of Liberec, Studentska 2, 461 17 Liberec (Czech Republic); Centre for Nanomaterials Advanced Technologies and Innovation, Technical University of Liberec, Studentska 2, 461 17 Liberec (Czech Republic)

2014-06-16T23:59:59.000Z

334

Porosity in Polysilsesquioxane Xerolgels  

SciTech Connect (OSTI)

Polymerization of organotrialkoxysilanes is a convenient method for introducing organic functionality into hybrid organic-inorganic materials. However, not much is known about the effects of the organic substituent on the porosity of the resulting xerogels. In this study, we prepared a series of polysilsesquioxane xerogels from organotrialkoxysilanes, RSi(OR{sup 1}){sub 3}, with different organic groups (R = H, Me, Et dodecyl, hexadecyl, octadecyl, vinyl, chloromethyl, (p-chloromethyl) phenyl, cyanoethyl). Polymerizations of the monomers were carried out under a variety of conditions, varying monomer concentration, type of catalyst, and alkoxide substituent. The effect of the organic substituent on the sol-gel process was often dramatic. In many cases, gels were formed only at very high monomer concentration and/or with only one type of catalyst. All of the gels were processed as xerogels and characterized by scanning electron microscopy and nitrogen sorption porosimetry to evaluate their pore structure.

Baugher, B.M.; Loy, D.A.; Rahimian, K.

1999-08-17T23:59:59.000Z

335

Waste management health risk assessment: A case study of a solid waste landfill in South Italy  

SciTech Connect (OSTI)

An integrated risk assessment study has been performed in an area within 5 km from a landfill that accepts non hazardous waste. The risk assessment was based on measured emissions and maximum chronic population exposure, for both children and adults, to contaminated air, some foods and soil. The toxic effects assessed were limited to the main known carcinogenic compounds emitted from landfills coming both from landfill gas torch combustion (e.g., dioxins, furans and polycyclic aromatic hydrocarbons, PAHs) and from diffusive emissions (vinyl chloride monomer, VCM). Risk assessment has been performed both for carcinogenic and non-carcinogenic effects. Results indicate that cancer and non-cancer effects risk (hazard index, HI) are largely below the values accepted from the main international agencies (e.g., WHO, US EPA) and national legislation ( and ).

Davoli, E., E-mail: enrico.davoli@marionegri.i [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Fattore, E.; Paiano, V.; Colombo, A.; Palmiotto, M. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy); Rossi, A.N.; Il Grande, M. [Progress S.r.l., Via Nicola A. Porpora 147, 20131 Milano (Italy); Fanelli, R. [Istituto di Ricerche Farmacologiche 'Mario Negri', Environmental Health Sciences Department, Via Giuseppe La Masa 19, 20156 Milano (Italy)

2010-08-15T23:59:59.000Z

336

OMV studies ethylene expansion in Germany  

SciTech Connect (OSTI)

OMV(Vienna) is evaluating plans to debottleneck its ethylene plant at Burghausen from 310,000 m.t./year to at least 400,000 m.t./year. Senior v.p. Jochen Berger says OMV is studying the limits to which the cracker can be expanded. {open_quotes}We`re pretty sure we can go to 400,000 m.t./year, but in two months we`ll have a better idea,{close_quotes} says Berger. The expansion will also depend on the future requirements of downstream operations at the Burghausen site, which include OMV plastics subsidiary PCD`s high-density polyethylene and polypropylene units and the vinyl chloride monomer and polyvinyl chloride units operated by Hoechst-Wacker joint venture Vinnolit.

NONE

1996-10-23T23:59:59.000Z

337

Liver and biliary tract cancer among chemical workers  

SciTech Connect (OSTI)

A recent cohort mortality study of male, hourly wage employees of a large Michigan chemical production and research facility had found a greater than expected number of deaths coded to liver and biliary tract cancer. In response, an additional investigation was then undertaken of the 44 liver and biliary tract cancer deaths observed between 1940 and 1982. A random sample (N = 1,888) of subjects was selected from the total cohort (N = 21,437) to serve as referents. Company work history records were used to classify cases and referents by work area assignment and potential for exposure to 11 selected chemical agents which have been shown to produce cancer of the liver or biliary passages in experimental animals. Statistically significant associations in both positive and negative directions were found for several work areas within the facility. A suggestive association was found for vinyl chloride monomer, based on five cases with presumed exposure.

Bond, G.G.; McLaren, E.A.; Sabel, F.L.; Bodner, K.M.; Lipps, T.E.; Cook, R.R. (Dow Chemical Company, Midland, MI (USA))

1990-01-01T23:59:59.000Z

338

Responsive copolymers for enhanced petroleum recovery. Quarterly technical progress report, June 23--September 21, 1994  

SciTech Connect (OSTI)

Summaries are given on the technical progress on three tasks of this project. Monomer and polymer synthesis discusses the preparation of 1(7-aminoheptyloxymethyl)naphthalene and poly(maleic anhydride-alt-ethyl vinyl ether). Task 2, Characterization of molecular structure, discusses terpolymer solution preparation, UV analysis, fluorescence analysis, low angle laser light scattering, and viscometry. The paper discusses the effects of hydrophobic groups, the effect of pH, the effect of electrolyte addition, and photophysical studies. Task 3, Solution properties, describes the factorial experimental design for characterizing polymer solutions by light scattering, the light scattering test model, orthogonal factorial test design, linear regression in coded space, confidence level for coded space test mode coefficients, coefficients of the real space test model, and surface analysis of the model equations.

McCormick, C.; Hester, R.

1994-12-31T23:59:59.000Z

339

Low-temperature emission spectra of 9-alkylanthracene esters: Dimer photodecomposition and monomer pair interactions in polymer hosts  

SciTech Connect (OSTI)

Effects due to variation in the alkyl chain length of photodimers of 9-alkylanthracene esters on their photodecomposition efficiencies at 12 K and, by implication, the photoproduct migration as a function of temperature within polymer hosts are investigated. It is shown that dimers with longer alkyl chains have a lower photodecomposition efficiency. The extent of photoproduct migration within the polymer following photodecomposition was also studied as a function of alkyl chain length. This migration and its modulation of the interaction between the separating monomers is shown to affect the emission spectrum. Thus, monomer migration was studied in temperature cycling experiments. It was also found, for the polymer hosts investigated - poly(methyl methacrylate), poly(vinyl chloride), and polystyrene - that these properties are host dependent. This result is probably due to the void space differences that exist among these polymers. 17 refs., 10 figs.

Salt, K.; Scott, G.W. (Univ. of California, Riverside, CA (United States))

1994-10-06T23:59:59.000Z

340

Apply reliability centered maintenance to sealless pumps  

SciTech Connect (OSTI)

This paper reports on reliability centered maintenance (RCM) which is considered a crucial part of future reliability engineering. RCM determines the maintenance requirements of plants and equipment in their operating context. The RCM method has been applied to the management of critical sealless pumps in fire/toxic risk services, typical of the petrochemical industry. The method provides advantages from a detailed study of any critical engineering system. RCM is a team exercise and fosters team spirit in the plant environment. The maintenance strategy that evolves is based on team decisions and relies on maximizing the inherent reliability built into the equipment. RCM recommends design upgrades where this inherent reliability is being questioned. Sealless pumps of canned motor design are used as main reactor charge pumps in PVC plants. These pumps handle fresh vinyl chloride monomer (VCM), which is both carcinogenic and flammable.

Pradhan, S. (Exxon Chemicals Canada, Ontario (Canada))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Revamp of Ukraine VCM plant will boost capacity, reduce emissions  

SciTech Connect (OSTI)

Oriana Concern (formerly P.O. Chlorvinyl) is revamping its 250,000 metric ton/year (mty) vinyl chloride monomer (VCM) plant at Kalusch, Ukraine. At the core of the project area new ethylene dichloride (EDC) cracking furnace and direct chlorination unit, and revamp of an oxychlorination unit to use oxygen rather than air. The plant expansion and modernization will boost capacity to 370,000 mty. New facilities for by-product recycling and recovery, waste water treatment, and emissions reduction will improve the plant`s environmental performance. This paper shows expected feedstock and utility consumption for VCM production. Techmashimport and P.O. Chlorvinyl commissioned the Kalusch plant in 1975. The plant was built by Uhde GmbH, Dortmund, Germany. The paper also provides a schematic of the Hoechst/Uhde VCM process being used for the plant revamp. The diagram is divided into processing sections.

NONE

1996-05-13T23:59:59.000Z

342

Thailand's downstream projects proliferate  

SciTech Connect (OSTI)

Thailand continues to press expansion and modernization of its downstream sector. Among recent developments: Construction of an olefins unit at Thailand's second major petrochemical complex and a worldscale aromatics unit in Thailand is threatened by rising costs. Thailand's National Petrochemical Corp (NPC) let a 9 billion yen contract to Mitsui Engineering and Shipbuilding Co. and C. Itoh and Co. for a dual fuel cogeneration power plant at its Mab Ta Phud, Rayong province, petrochemical complex. Financing is in place to flash a green light for a $530 million Belgian-Thai joint venture sponsoring a worldscale polyvinyl chloride/vinyl chloride monomer plant in Thailand. Work is more than 50% complete on the $345 million second phase expansion of Thai Oil's Sri Racha refinery in Chon Buri province. Petroleum Authority of Thailand (PTT) endorsed a plan to install two more natural gas processing plants in Thailand to meet rapidly growing domestic demand for petroleum gas.

Not Available

1991-06-03T23:59:59.000Z

343

New route for degradation of chlorinated ethylenes in exhaust gases from ground water remediation  

Science Journals Connector (OSTI)

On the basis of an approximate finite-size description, a UV photoreactor was devised and constructed for studying the photooxidation of the chlorinated ethylenes perchloroethylene (PCE), trichloroethylene (TCE), 1,2-dichloroethylenes (DCE), vinyl chloride (VC) and several saturated chlorinated hydrocarbons (CHC). In the cases of PCE and TCE, the efficiency of the photooxidation using irradiation by a 222nm excimer lamp and subsequent photolysis for the initiation of the process was found to be sufficiently high so that a scaling up to an industrial purification plant of exhaust gases from ground water remediation can be hopefully envisaged. Thanks to consecutive reactions with the chain-sustaining chlorine atoms, this degradation route proves capable of decomposing the other chlorinated ethylenes which are not amenable to photolysis in a direct way. For saturated CHC the utilisability of this approach is limited.

Lutz Prager; Eberhard Hartmann

2001-01-01T23:59:59.000Z

344

Density Functional Investigation of Melamine-Formaldehyde Crosslinking Agents Part 1: Partially Substituted Melamine  

SciTech Connect (OSTI)

Computational modeling has been performed on the cross-linking mechanism of partially substituted melamine reacting with poly(vinyl alcohol). Ab initio calculations were performed with density functional theory employing the BLYP functional and double numerical DND basis set. The mechanism, general acid catalysis, has been modeled with respect to structures, protonation, and reaction with a polymer. Protonation of the oxygen is required initially, followed by liberation of methanol. The reaction can take one of two pathways after methanol liberation. The conjugate base of the weak acid can abstract a proton, generating a Schiff-base intermediate. The O-H on the polymer then adds to the C-N double bond, producing the polymer-melamine bond. The alternative is that the polymer adds to the charged melamine, using the specific acid catalysis mechanism. After polymer addition, the proton is abstracted, producing the product.

Benson, Michael Timothy

2003-07-01T23:59:59.000Z

345

Copolymers useful as additives for lowering the cloud point of middle hydrocarbon distillates, and compositions of middle hydrocarbon distillates comprising them  

SciTech Connect (OSTI)

Products useful as additives for lowering the cloud point of middle distillates have a molecular weight from 1,000 to 50,000, and are obtained by reacting a compound of the formula R-Z((CH/sub 2/) /SUB n/ NH) /SUB m/ H or HO-CH/sub 2/-R'-NH/sub 2/ where R is a monovalent saturated aliphatic radical of 1-30 carbon atoms, Z is -NH- or oxygen, n is 2 to 4, m is zero or 1 to 4 and R' is a saturated divalent aliphatic radical of 1-18 carbon atoms, with a copolymer comprising recurrent units (A) from an alkyl ester of an unsaturated monocarboxylic acid and/or a vinyl ester of a saturated monocarboxylic acid, recurrent units (B) from diisobutylene and recurrent units (C) from an unsaturated a,b-dicarboxylic compound.

Durand, J. P.; Damin, B.; Dawans, F.; Leger, R.

1985-03-05T23:59:59.000Z

346

Composition and method for encapsulating photovoltaic devices  

DOE Patents [OSTI]

A composition and method for encapsulating a photovoltaic device which minimizes discoloration of the encapsulant. The composition includes an ethylene-vinyl acetate encapsulant, a curing agent, an optional ultraviolet light stabilizer, and/or an optional antioxidant. The curing agent is preferably 1,1-di-(t-butylperoxy)-3,3,5-trimethylcyclohexane; the ultraviolet light stabilizer is bis-(N-octyloxy-tetramethyl) piperidinyl sebacate and the antioxidant is selected from the group consisting of tris (2,4-di-tert-butylphenyl) phosphite, tetrakis methylene (3,5-di-tert-butyl-4-hydroxyhydrocinnamate) methane, octadecyl 3,5-di-tert-butyl-4-hydroxyhydrocinnamate, and 2,2'-ethylidene bis(4,6-di-t-butylphenyl) fluorophosponite. The composition is applied to a solar cell then cured. The cured product contains a minimal concentration of curing-generated chromophores and resists UV-induced degradation.

Pern, Fu-Jann (Golden, CO)

2000-01-01T23:59:59.000Z

347

Use of tannin anticorrosive reaction primer to improve traditional coating systems  

SciTech Connect (OSTI)

Different anticorrosive schemes applied over plain or previously shot-blasted surfaces of AISI 1010 (UNS G10100) steel plates were compared. Plates were painted with alkydic, vinylic, and epoxy anticorrosive schemes over metal treated previously with pine tannin reaction primer and over its own schemes without previous primer treatment. Anticorrosive tests were conducted in a salt fog chamber according to ASTM B 117-73. Rusting, blistering, and adhesion were assessed over time. The survey was complemented with potentiodynamic scanning tests in sodium chloride (NaCl) solution with a concentration equivalent to seawater. Corrosion currents were determined using Tafel and polarization resistance techniques. Results showed the reaction primer inhibited corrosion by improving adherence. Advantages over traditional conversion primers formulated in a base of zinc chromate in phosphoric medium were evident.

Matamala, G.; Droguett, G. (Universidad de Concepcion (Chile)); Smeltzer, W. (McMaster Univ., Hamilton, Ontario (Canada). Inst. for Materials Research)

1994-04-01T23:59:59.000Z

348

Study of immobilized catalysts. XVI. Study of structural features and catalytic properties of immobilized mono-and binuclear cobalt complexes  

SciTech Connect (OSTI)

A series of polymeric carriers with chelate-forming groups of diacylamine and aminovinyl ketone types and also mono- and binuclear Co (II) complexes based on them were obtained by methods of polymer-analogous transformations, startting from polyethylene (PE)-grafted (rgr-) polyacetylonitrile (PE-gr-PAN), PE-gr-polyacrylamide (PE-gr-PAA), or PE-gr-poly(methyl vinyl ketone) CPE-grPMVK). From the data of spectral and magnetic studies, a conclusion was made on the chelate structure of the Co (II) complexes synthesized with a tetrahedral configuration of the coordination unit. It was found that the immobilized Co (II) chelates have a high and stable catalytic activity in the sterospecific 1,4-cispolymerization of butadiene. It was shown that an increase in the number of Co (II) ions in the complex molecule leads to a decrease in the specific activity of the catalytic systems based on them.

Pomogailo, A.D.; Golubeva, N.D.; Uflyand, I.E.

1986-06-01T23:59:59.000Z

349

Recent Progress in NIF Mandrel Production  

SciTech Connect (OSTI)

The production of spherical poly({alpha}-methylstyrene) (P{alpha}MS) mandrels utilizes a small amount (<0.1wt%) of high-molecular-weight poly(acrylic acid) (PAA) in the suspending medium, which substantially increases the interfacial tension during curing relative to methods using poly(vinyl alcohol) (PVA). However, fully cured capsules made by this method displayed a significant level of high frequency surface debris that became especially problematic when the mandrels were subsequently overcoated. To solve this problem we examined the use of PAA in conjunction with PVA in order to reduce these surface features, and explored numerous variations of concentration and timing of the PVA addition. The optimum conditions were found to be initial use of PAA for centering and symmetry of the mandrels, followed by removal of the PAA medium, washing of the mandrels with water, and finally transfer to PVA solution for completion of the curing cycle.

Takagi, M; Cook, R; McQuillan, B; Nikroo, A

2003-09-03T23:59:59.000Z

350

Influence of complexation processes on the catalytic properties of some polymer-based cobalt compounds for oxygen electroreduction  

SciTech Connect (OSTI)

Electrochemical and X-ray absorption techniques have been used to determine the influence of complexation processes on the catalytic properties of heat-treated systems composed by the mixture of one polymer and Co acetate. Three non-nitrogenous polymers were studied: poly(methyl vinyl ketone) (PVK), poly(acrylic acid) (PAA); and polystyrene (PE). The catalysts composed by PE and PAA presented very low activity for the O{sub 2} reduction; a maximum of activity was found for the PVK catalyst at 100{degree}C. XAFS experiments at the Co, N, C, and O K edges showed that complexation between Co ions and the polymer yields a good dispersion of the Co ions and formation of small Co clusters during the thermal treatment. The absence of complexation leads to very poor activity, as in the case of PE and PAA. 14 refs., 13 figs., 5 tabs.

Alves, M.C.M.; Tourillon, G. [LURE, Orsay (France)

1996-05-02T23:59:59.000Z

351

Pervaporation separation of binary organic-aqueous liquid mixtures using crosslinked PVA membranes. I. Characterization of the reaction between PVA and PAA  

SciTech Connect (OSTI)

For the purpose of the water-selective membrane material development for pervaporation separation, poly(vinyl alcohol) (PVA) was crosslinked with a low molecular weight of poly(acrylic acid) (PAA). The crosslinking reactions between PVA and PAA were characterized through IR spectroscopy, differential scanning calorimetry (DSC), and tensile tests when varying the reaction conditions, that is, time, temperature, amounts of cross-linking agents, PAA. It was found that the crosslinking reaction was fast: in other words, that the reaction mainly occurred at the initial step of each reaction condition. The best reaction conditions for preparing the crosslinked PVA membranes were found to be: reaction time not over 1 h, reaction temperature in the range of 150-180 C. PAA contents of 15-20 wt% were found satisfactory with respect to the application areas.

Jiwon Rhim; Kewho Lee (Korea Research Inst. of Chemical Technology, Taejon (Korea, Republic of). Membranes and Separation Lab.); Minyoung Sohn; Hyeokjong Joo (Chungnam National Univ., Taejon (Korea, Republic of). Dept. of Polymer Science and Engineering)

1993-10-20T23:59:59.000Z

352

Method of making gold thiolate and photochemically functionalized microcantilevers  

DOE Patents [OSTI]

Highly sensitive sensor platforms for the detection of specific reagents, such as chromate, gasoline and biological species, using microcantilevers and other microelectromechanical systems (MEMS) whose surfaces have been modified with photochemically attached organic monolayers, such as self-assembled monolayers (SAM), or gold-thiol surface linkage are taught. The microcantilever sensors use photochemical hydrosilylation to modify silicon surfaces and gold-thiol chemistry to modify metallic surfaces thereby enabling individual microcantilevers in multicantilever array chips to be modified separately. Terminal vinyl substituted hydrocarbons with a variety of molecular recognition sites can be attached to the surface of silicon via the photochemical hydrosilylation process. By focusing the activating UV light sequentially on selected silicon or silicon nitride hydrogen terminated surfaces and soaking or spotting selected metallic surfaces with organic thiols, sulfides, or disulfides, the microcantilevers are functionalized. The device and photochemical method are intended to be integrated into systems for detecting specific agents including chromate groundwater contamination, gasoline, and biological species.

Boiadjiev, Vassil I. (Knoxville, TN) [Knoxville, TN; Brown, Gilbert M. (Knoxville, TN) [Knoxville, TN; Pinnaduwage, Lal A. (Knoxville, TN) [Knoxville, TN; Thundat, Thomas G. (Knoxville, TN) [Knoxville, TN; Bonnesen, Peter V. (Knoxville, TN) [Knoxville, TN; Goretzki, Gudrun (Nottingham, GB) [Nottingham, GB

2009-08-25T23:59:59.000Z

353

Commodity chemicals from natural gas by methane chlorination  

SciTech Connect (OSTI)

Ethylene and vinyl chloride monomer (VCM) can be produced from natural gas through methane chlorination by reacting methane and chlorine at 900/sup 0/C or higher. Experimental results indicate total ethylene equivalent yield from methane of 45%(wt) and marginal process economics. Fundamental kinetic modeling predicts improved C/sub 2/ yields of up to 70%(wt) at optimum reaction conditions. This optimum condition established the basis for the process design study to evaluate the potential for producing ethylene and VCM from natural gas. HCl by-product is recycled for economic viability. Using the Kel-Chlor process for recycling HCl, the proposed plant produces 27,200 TPA of C/sub 2/H/sub 4/ and 383,800 TPA of VCM. The Midwest is an ethylene consumption area requiring imports of ethylene derivatives from other regions. A methane chlorination plant located on a Midwestern natural gas pipeline network has a good commercial potential.

Che, S.C.; Minet, R.G.; Giacobbe, F.; Mullick, S.L.

1987-01-01T23:59:59.000Z

354

Polybenzimidazole compounds  

DOE Patents [OSTI]

A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2010-08-10T23:59:59.000Z

355

Polybenzimidazole compounds, polymeric media, and methods of post-polymerization modifications  

DOE Patents [OSTI]

A PBI compound includes imidazole nitrogens at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2-- where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least 5 equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about 15.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2007-08-21T23:59:59.000Z

356

Fume Hood Sash Stickers Increases Laboratory Safety and Efficiency at Minimal Cost  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

confused by labels placed at 18 inches confused by labels placed at 18 inches that say "Place Sash here for Maximum Safety." The authors of these labels have confused "maximum" and "minimum", not realizing that a hood is least safe when fully open. A Basic Solution To address the confusion at the University of California, a lab manager and a hood safety specialist designed a bold vinyl sticker to attach on the exterior sidewall of a fume hood (Figure 1). The sticker cleverly uses the ubiquitous traffic light color scheme, with a red zone above 18 inches, and a large arrow pointing down with the words, "More Safe, Less Energy" changing from yellow at the midpoint to green at the bottom when the sash is closed completely. Interestingly,

357

Ohio's 2nd congressional district: Energy Resources | Open Energy  

Open Energy Info (EERE)

Ohio. Ohio. Registered Energy Companies in Ohio's 2nd congressional district AHL-TECH Ameridian Speciality Services CECO Environmental Corp CIMx Software Cinergy Ventures II LLC DELTEC INC Eagle Energy LLC Global Energy Inc Green Builder Media /Green Builder College Icon Solar Power, LLC Innovative Solutions Unlimited, LLC (InSolves) KATZEN International Inc Macy's Manuta Chemical Consulting Inc. Melink Industries Melink Solar OnPower Inc Pilus Energy SEMCO THOR Turner Hunt Ocean Renewable LLC The Utilities Group Inc Ultimate Best Buy LLC Vinyl Kraft Windows and Doors Vision Energy Energy Generation Facilities in Ohio's 2nd congressional district Melink Solar Canopy at the Cincinnati Zoo Retrieved from "http://en.openei.org/w/index.php?title=Ohio%27s_2nd_congressional_district&oldid=196998

358

Dudley Herschbach: Chemical Reactions and Molecular Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dudley Herschbach: Dudley Herschbach: Chemical Reactions and Molecular Beams Resources with Additional Information Dudley Herschbach Courtesy of Texas A&M University As a co-recipient of the 1986 Nobel Prize in Chemistry, 'Dudley Herschbach was cited for "providing a much more detailed understanding of how chemical reactions take place". Using molecular beams, he studied elementary reactions such as K + CH3I and K + Br2, where it became possible to correlate reaction dynamics with the electronic structures of reactants and products. Exchanges proceeded through a persistent complex that lasted for many rotational periods, with product angular distributions reflecting the degree of reagent entanglement. Later this work was extended to H + Cl2, Cl + HI, halogen substitution reactions with vinyl and allyl halides, as well as such systems as Xe + Ar2 → XeAr + Ar. Herschbach has been a pioneer in the measurement and theoretical interpretation of vector properties of reaction dynamics, a field known as "molecular stereodynamics".

359

Special waste-form lysimeters - arid: 1984--1992 data summary and preliminary interpretation  

SciTech Connect (OSTI)

A lysimeter facility constructed at the Hanford Site in south-central Washington State has been used since 1984 to monitor the leaching of buried waste forms under natural conditions. The facility is generating data that are useful in evaluating source-term models used in radioactive waste transport analyses. The facility includes ten bare-soil lysimeters (183 cm diameter by 305 cm depth) containing buried waste forms generated at nuclear reactors in the United States and solidified with Portland M cement, masonry cement, bitumen, and vinyl-ester styrene. The waste forms contained in the lysimeters have been leached under natural, semiarid conditions. In spite of the semiarid conditions, from 1984 through 1992, an average of 45 cm of water leached through the lysimeters, representing 27% of area precipitation. Leachate samples have been routinely collected and analyzed for radionuclide and chemical content. To date, tritium, cobalt-60, and cesium-137 have been identified in the lysimeter leachate samples. From 1984 through 1992, over 4000 {mu}Ci of tritium, representing 76 and 71 % of inventory (not decay corrected), have been leached from the two waste forms containing tritium. Cobalt-60 has been found in the leachate from all six of the waste forms that originally contained > 1 mCi of inventory. The leached amounts of cobalt-60 represent < 0.1 % of original cobalt inventories. Mobile cobalt is believed to be chelated with organic compounds, such as ethylenediaminetetraacetic acid (EDTA), that are present in the waste. Trace amounts of cesium-137 have occasionally been identified in leachate from two waste forms since 1991. Qualitatively, the field leaching results confirm laboratory studies suggesting that tritium is readily leached from cement, and that cobalt-60 is generally leached more easily from cement than from vinyl-ester styrene.

Jones, T.L. [New Mexico State Univ., Las Cruces, NM (United States); Serne, R.J. [Pacific Northwest Lab., Richland, WA (United States)

1994-10-01T23:59:59.000Z

360

Solidification of ion exchange resin wastes  

SciTech Connect (OSTI)

Solidification media investigated included portland type I, portland type III and high alumina cements, a proprietary gypsum-based polymer modified cement, and a vinyl ester-styrene thermosetting plastic. Samples formulated with hydraulic cement were analyzed to investigate the effects of resin type, resin loading, waste-to-cement ratio, and water-to-cement ratio. The solidification of cation resin wastes with portland cement was characterized by excessive swelling and cracking of waste forms, both after curing and during immersion testing. Mixed bed resin waste formulations were limited by their cation component. Additives to improve the mechanical properties of portland cement-ion exchange resin waste forms were evaluated. High alumina cement formulations dislayed a resistance to deterioration of mechanical integrity during immersion testing, thus providing a significant advantage over portland cements for the solidification of resin wastes. Properties of cement-ion exchange resin waste forms were examined. An experiment was conducted to study the leachability of /sup 137/Cs, /sup 85/Sr, and /sup 60/Co from resins modified in portland type III and high alumina cements. The cumulative /sup 137/Cs fraction release was at least an order of magnitude greater than that of either /sup 85/Sr or /sup 60/Co. Release rates of /sup 137/Cs in high alumina cement were greater than those in portland III cement by a factor of two.Compressive strength and leach testing were conducted for resin wastes solidified with polymer-modified gypsum based cement. /sup 137/Cs, /sup 85/Sr, and /sup 60/Co fraction releases were about one, two and three orders of magnitude higher, respectively, than in equivalent portland type III cement formulations. As much as 28.6 wt % dry ion exchange resin was successfully solidified using vinyl ester-styrene compared with a maximum of 25 wt % in both portland and gypsum-based cement.

Not Available

1982-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Thai group set to invest in Chinese petchem complex  

SciTech Connect (OSTI)

A $5-billion refinery and petrochemical complex is planned by Thailand's Charoen Pokphand (Bangkok) at the seaport of Nimpoh, near Shanghai. The company has discussed the project with the central government of China, and state oil and petrochemicals company Sinopec (Beijing) is due to complete a feasibility study within the next two months. Charoen's plastics processing subsidiary, Kuo Shen (Hong Kong), is expected to hold 70% in the venture, Sinopec 20%, and the Chinese government the remaining 10%. Western companies have been invited to participate. Solvay (Brussels), a 49% partner with Charoen Pokphand in the Vinythai polyvinyl chloride (PVC) joint venture at Map Ta Pud, Thailand, has not yet made a commitment. The 5-million m.t./year oil refinery would feed the complex, which will be based on a 450,000-m.t./year ethylene plant, downstream aromatics units, and a range of derivatives plants. The complex, which falls outside the many announced for Thailand's current five-year economic plan, is expcted to be implemented in stages. To begin with, a 120,000-m.t./year PVC plant will be built that will be fed on imported vinyl chloride monomer. Charoen is in discussions with process licensers, including Solvay, European Vinyl Corp., BFGoodrich, and Shinetsu. Half the PVC output will be consumed by Kuo Shen in China, where Charoen has several plastics processing units, including one in Shanghai and one in Nimpoh. Meanwhile, Sinopec's Hong Kong subsidiary is seeking partners to invest in joint venture projects in China. Sinopec president Liu Xuemin says the company is willing to cooperate with overseas companies to establish small petrochemical projects. In addition, Sinopec is negotiating with officials of Dayang in Jiangsu province and the special economic zone of Shen Zhen, near Hong Kong, on joint ventures for plastics and food additives.

Alperowicz, N.

1993-01-06T23:59:59.000Z

362

Vapor-liquid equilibria for copolymer+solvent systems: Effect of intramolecular repulsion  

SciTech Connect (OSTI)

Role of intramolecular interactions in blend miscibility is well documented for polymer+copolymer mixtures. Some copolymer+polymer mixtures are miscible although their corresponding homopolymers are not miscible; for example, over a range of acrylonitrile content, styrene/acrylonitrile copolymers are miscible with poly(methyl methacrylate) but neither polystyrene nor polyacrylonitrile is miscible with poly(methyl methacrylate). Similarly, over a composition range, butadiene/acrylonitrile copolymers are miscible with poly(vinyl chloride) while none of the binary combinations of the homopolymers [polybutadiene, polyacrylonitrile, and poly(vinyl chloride)] are miscible. This behavior has been attributed to ``intramolecular repulsion`` between unlike copolymer segments. We have observed similar behavior in vapor-liquid equilibria (VLE) of copolymer+solvent systems. We find that acrylonitrile/butadiene copolymers have higher affinity for acetonitrile solvent than do polyacrylonitrile or polybutadiene. We attribute this non-intuitive behavior to ``intramolecular repulsion`` between unlike segments of the copolymer. This repulsive interaction is weakened when acetonitrile molecules are in the vicinity of unlike copolymer segments, favoring copolymer+solvent miscibility. We find similar behavior when acetonitrile is replaced by methyl ethyl ketone. To best knowledge, this effect has not been reported previously for VLE. We have obtained VLE data for mixtures containing a solvent and a copolymer as a function of copolymer composition. It appears that, at a given solvent partial pressure, there may be copolymer composition that yields maximum absorption of the solvent. This highly non-ideal VLE phase behavior may be useful for optimum design of a membrane for a separation process.

Gupta, R.B.; Prausnitz, J.M.

1995-03-01T23:59:59.000Z

363

Influence of relaxation transitions on radiation-initiated cationic graft polymerization. [Gamma radiation  

SciTech Connect (OSTI)

Radiation grafting of vinyl n-butyl ether (VBE) to polyvinyl chloride (PVC) over a broad temperature range was investigated. The relaxation transitions in the PVC/VBE system were also determined. Grafting of vinyl alkyl ethers proceeds entirely by a cationic mechanism in a reaction medium that has been dried to a water concentration no greater than 0.1-1.0 ppm. In this connection, the diffusion properties of water in the temperature region were studied. Commercial films of unplasticized PVC (thickness 200 M); were subjected to swelling in two systems: in a 50% solution of VBE in benzene at 25/sup 0/C, and in the pure monomer at 40/sup 0/C. The reaction mixtures were first dried over metallic sodium in a deaerated atmosphere. The specimens were irradiated in a Co gamma-radiation unit to a dose of 10 kGy at a dose rate of 3 Gy/sec. The first reaction mixture was investigated over a range of temperatures from -60/sup 0/ to +70/sup 0/C, and the second from -15/sup 0/ to +50/sup 0/C. The degree of grafting was determined from the increase in weight of the original ungrafted film. The temperature was held to within +/-1/sup 0/C. The relaxation transitions in the swollen polymer systems were determined by two methods, thermostimulated current (TSC) and thermomechanics (TM). It was found that in the region of the glass transition of a swollen PVC-VBE system, radiation-initiated cationic graft polymerization proceeds at a maximal rate, and there are changes in state of the water molecules (the agents of breaking the ion reaction chain) and in their diffusion properties within the matrix.

Kudryavtsev, V.N.; Kabanov, V.Ya.; Chalykh, A.E.; Spitsyn, V.I.

1982-05-01T23:59:59.000Z

364

Occupational health and safety regulation in the coal mining industry: public health at the workplace  

SciTech Connect (OSTI)

The strategy for preventing occupational disease and injury in the coal mining industry employs several elements. Standards are set and enforced; technical assistance, research, and development are provided; and surveillance is conducted. Compensation for black lung is a vivid reminder of the consequences of failure to prevent disease. And, workers are represented by a union that encourages active participation in all aspects of this strategy. There are significant problems in each of these elements. Regulatory reform threatens to weaken many standards, there is a decline in government research budgets, surveillance is not well monitored, and compensation for black lung is significantly more difficult to obtain now than in the past. Moreover, the conservative governments of the past decade are not friendly towards unions. Nevertheless, the fundamental structure of disease and injury prevention remains intact and, more importantly, it has a historical record of success. The Mine Safety and Health Act provided for a wide array of basic public health measures to prevent occupational disease and injury in the mining industry. These measures have been effective in reducing both risk of fatal injury and exposure to respirable coal mine dust. They are also associated with temporary declines in productivity. In recent years, however, productivity has increased, while risk of fatal injury and exposure to respirable dust have declined. At individual mines, productivity with longwall mining methods appear to be associated with increases in exposure to respirable dust. These trends are not inconsistent with similar trends following implementation of regulations by OSHA. When OSHA promulgated regulations to control exposure to vinyl chloride monomer, enforcement of the standard promoted significant efficiencies in vinyl chloride production (5).21 references.

Weeks, J.L. (Department of Occupational Health and Safety, United Mine Workers of America, Washington, DC (USA))

1991-01-01T23:59:59.000Z

365

Mechamisms of gas permeation through polymer membranes. Progress report, July 1, 1982-May 31, 1983  

SciTech Connect (OSTI)

The main objective of this study is to assess the validity of a free-volume model of gas permeation through rubbery polymer membranes. Such information is of importance for the development of new membrane processes for the separation of gas mixtures. Steady-state permeability coefficients for N/sub 2/O in polyethylene between 20 and 50/sup 0/C and at pressures up to 15 atm were found to be 45% higher (on the average) than values predicted by the free-volume model. The difference between the experimental and theoretical permeability coefficients for N/sub 2/O is about twice as large as observed with many other gases in polyethylene. Permeability, diffusion time-lags, and absorption measurements were made with n-C/sub 4/H/sub 10/ in poly(eta-butyl methacrylate) at 30/sup 0/C and subatmospheric pressures. The experimental time-lags agreed satisfactorily with values predicted by the free-volume model, using model parameters obtained from gas absorption measurements. However, the experimental permeability coefficients were substantially higher than the theoretical values. This may be due to a non-Fickian transport component because the measurements were made at only 3/sup 0/C above the glass transition temperature of the polymer. This study was recently extended to the solution and transport of gases and vapors in glassy polymers. Satisfactory agreement between experiment and theory was found for the solution, permeation, and diffusion of acetone, benzene, and methanol in ethyl cellulose and water vapor in poly(acrylonitrile) and for the solution of vinyl chloride monomer in poly(vinyl chloride). A generalized model of transport of small molecules in polymers has been developed. The model incorporates free-volume and dual-mode sorption concepts, and should be applicable both to rubbery and glassy polymers.

Stern, S.A.; Mauze, G.R.; Sampat, S.R.

1983-05-01T23:59:59.000Z

366

Ethylene oxidation in a well-stirred reactor  

SciTech Connect (OSTI)

The detailed ethylene oxidation data set of Thornton, obtained for a well-stirred reactor operated fuel-lean at atmospheric pressure and for temperatures of 1003K to 1253K, is used as a basis for the comparison of chemical kinetic mechanisms reported in the literature and for the development of a new ethylene oxidation mechanism. The mechanisms examined are those of Westbrook and Pitz and Dagaut et al. These mechanisms indicated that unusually large rates for the vinyl decomposition reaction are required to obtain agreement with the Thornton data set. A new ethylene oxidation mechanism is developed in order to overcome some of the drawbacks of the previous mechanisms. The new mechanism closely simulates the overall rate of loss of ethylene, and the concentation of CO, CO{sub 2}, H{sub 2}, CH{sub 2}O, C{sub 2}H{sub 2}, CH{sub 3}OH, CH{sub 4}, and C{sub 2}H{sub 6} measured for the stirred reactor. Predictions by this mechanism are dependent on a new high temperature vinyl oxidation route, C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}CHO + O with a k{sub C2H3+O2=CH2CHO+O}/k{sub C2H3+O2=CH2O+HCO} branching ratio of 1.20 at 1053K to 2.05 at 1253K. The branching ratio values were dependent upon the extent of fall-off for the C{sub 2}H{sub 3} + O{sub 2} = CH{sub 2}O + HCO reaction.

Marinov, N.M. [Lawrence Livermore National Lab., CA (United States); Malte, P.C. [Washington Univ., Seattle, WA (United States). Dept. of Mechanical Engineering

1994-10-01T23:59:59.000Z

367

Energy Saving Glass Lamination via Selective Radio Frequency Heating  

SciTech Connect (OSTI)

This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination identifying castable molds for

Allan, Shawn M.

2012-02-27T23:59:59.000Z

368

Energy Saving Glass Lamination via Selective Radio Frequency Heating  

SciTech Connect (OSTI)

This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North America. The second task dealt with a study of current lamination processes in the various laminate industries, and development of concepts for integrating RF lamination into new or existing processes. The third task explored the use of a non-destructive technique for analyzing laminate adhesion with the University of Illinois at Urbana-Champaign. The fourth task focused on developing concepts for curved glass lamination using RF lamination. The fifth and sixth tasks together comprised an analysis of laminate product markets, ranking for applicability and commercialization potential, and the development of commercialization strategies for those products. In addition, throughout the project as new experimental data and conventional process data were obtained, the benefits analysis of RF lamination was refined. The goals of the project described above were achieved, positioning RF lamination for the next stage growth envisioned in the original Industrial Grand Challenge proposal. Working with Pilkington North America, lamination of flat autoglass with PVB was achieved, meeting all 16 stringent industry tests. In particular, PVB laminates made with RF lamination passed environmental tests including the high temperature, 120 ???°C bake test, without significant formation of bubbles (defects). The adhesion of PVB to glass was measured using the pummel method. Adhesion values ranging from 1 to 7 out of 10 were obtained. The significant process parameters affecting the environmental and adhesion performance were identified through a designed experiment. Pre-lamination process variables including PVB storage humidity and the de-airing process (vacuum or nip rolling) were significant, as well as the level of pressure applied to the laminate during the RF process. Analysis of manufacturing with RF lamination equipment, based on the processes developed indicated that 3 RF presses could replace a typical auto-industry autoclave to achieve equal or greater throughput with possibly less capital cost and smaller footprint. Concepts for curved lamination id

Allan, Shawn M.; Baranova, Inessa; Poley, Joseph; Reis, Henrique

2012-02-27T23:59:59.000Z

369

Porphyrin electrode films prepared by electrooxidation of metalloprotoporphyrins  

SciTech Connect (OSTI)

Electrooxidation in organic solvents of the dimethyl esters of several metalloprotoporphyrins (PP) (Ni/sup II/PP, Zn/sup II/PP, Co/sup II/PP, (Fe/sup III/PP)Cl, (Fe/sup III/PP)/sub 2/O, and (Cr/sup III/PP)/sub 2/O) leads to the deposition of thick (approx. 1000 monolayer equivalents), electroactive porphyrin films, which have been characterized by cyclic voltammetry and absorption spectroscopy on transparent SnO/sub 2/ electrodes. The films are stable toward organic solvents and aqueous acids and bases, but are removed by treatment with hot concentrated acids. The resonance Raman spectrum of the NiPP film indicates that one of the two vinyl groups is saturated on most of the porphyrin units. Deposition continues for some minutes after the current is interrupted. This evidence is consistent with a mechanism involving electroinitiated cationic vinyl polymerization. No film is formed if the metal, rather than the ring, is oxidized. Thus the first oxidation step of Co/sup II/PP, to (Co/sup III/PP)/sup +/, does not support film formation (although the potential is as high as for ring oxidation in ZnPP), but the second step, to (Co/sup III/PP)/sup 2 +/, does. Lack of film formation for (Mn/sup III/PP)Cl and (Cr/sup IV/PP)O suggests metal, rather than ring oxidation, to Mn/sup IV/ and Cr/sup V/. However, (CrPP)/sub 2/O oxidation does produce a film, suggesting ring oxidation, analogous to (FePP)/sub 2/O, which also produces a film. However, while (CrPP)/sub 2/O is incorporated intact into the film, the (FePP)/sub 2/O film contains monomer units. Incorporation of other metal ions can be accomplished by soaking a ZnPP-coated electrode in H/sub 2/SO/sub 4/ followed by contact wtih a solution of the metal dihalide in refluxing DMF. The porphyrin sites are accessible to small ions, as shown by chloride coordination of ZnPP film upon soaking in chloride solution. 49 references, 13 figures, 1 table.

Macor, K.A.; Spiro, T.G.

1983-08-24T23:59:59.000Z

370

On the Reaction Mechanism of Acetaldehyde Decomposition on Mo(110)  

SciTech Connect (OSTI)

The strong Mo-O bond strength provides promising reactivity of Mo-based catalysts for the deoxygenation of biomass-derived oxygenates. Combining the novel dimer saddle point searching method with periodic spin-polarized density functional theory calculations, we investigated the reaction pathways of a acetaldehyde decomposition on the clean Mo(110) surface. Two reaction pathways were identified, a selective deoxygenation and a nonselective fragmentation pathways. We found that acetaldehyde preferentially adsorbs at the pseudo 3-fold hollow site in the ?2(C,O) configuration on Mo(110). Among four possible bond (?-C-H, ?-C-H, C-O and C-C) cleavages, the initial decomposition of the adsorbed acetaldehyde produces either ethylidene via the C-O bond scission or acetyl via the ?-C-H bond scission while the C-C and the ?-C-H bond cleavages of acetaldehyde leading to the formation of methyl (and formyl) and formylmethyl are unlikely. Further dehydrogenations of ethylidene into either ethylidyne or vinyl are competing and very facile with low activation barriers of 0.24 and 0.31 eV, respectively. Concurrently, the formed acetyl would deoxygenate into ethylidyne via the C-O cleavage rather than breaking the C-C or the C-H bonds. The selective deoxygenation of acetaldehyde forming ethylene is inhibited by relatively weaker hydrogenation capability of the Mo(110) surface. Instead, the nonselective pathway via vinyl and vinylidene dehydrogenations to ethynyl as the final hydrocarbon fragment is kinetically favorable. On the other hand, the strong interaction between ethylene and the Mo(110) surface also leads to ethylene decomposition instead of desorption into the gas phase. This work was financially supported by the National Advanced Biofuels Consortium (NABC). Computing time was granted by a user project (emsl42292) at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). This work was financially supported by the National Advanced Biofuels Consortium (NABC). Computing time was granted by a user project (emsl42292) at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL). The EMSL is a U.S. Department of Energy (DOE) national scientific user facility located at Pacific Northwest National Laboratory (PNNL) and supported by the DOE Office of Biological and Environmental Research. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Mei, Donghai; Karim, Ayman M.; Wang, Yong

2012-02-16T23:59:59.000Z

371

Triclosan removal by laccase immobilized on mesoporous nanofibers: Strong adsorption and efficient degradation  

Science Journals Connector (OSTI)

Abstract Triclosan is difficult to remove or degrade in natural aquatic environment due to its stable chemical structure and low concentration. This study aimed to enhance its removal rate from water through combining the biocatalytic activity of laccase with high adsorption capacity of mesoporous materials. Vinyl-modified poly(acrylic acid)/SiO2 nanofibrous membranes prepared in this work possessed mesoporous structure (pore size 1.733.54nm, pore volume 0.379cm3/g) and high specific surface area (542.91m2/g). Laccase was immobilized on the membranes through covalent crosslinking and the enzyme loading was about 417mg/g. The physical, chemical, biochemical properties of the immobilized laccase and its application in triclosan removal were comprehensively investigated. The immobilized laccase showed better storage stability and higher tolerance to the changes in pH and temperature compared with free laccase. It also exhibited a better performance (65% removal, 2h) in triclosan removal than free laccase (29.2% removal, 2h) under the optimum conditions (pH=4, 30C). The results demonstrated that the mesostructure of nanofibers was beneficial for the adsorption and degradation of triclosan. It may provide a new idea for removal of organic pollutants from water environment using enzyme and adsorption technology.

Ran Xu; Yifang Si; Xiaotao Wu; Fengting Li; Bingru Zhang

2014-01-01T23:59:59.000Z

372

Use of Sequential Injection Analysis to construct a Potentiometric Electronic Tongue: Application to the Multidetermination of Heavy Metals  

SciTech Connect (OSTI)

An automated potentiometric electronic tongue (ET) was developed for the quantitative determination of heavy metal mixtures. The Sequential Injection Analysis (SIA) technique was used in order to automate the obtaining of input data, and the combined response was modeled by means of Artificial Neural Networks (ANN). The sensor array was formed by four sensors: two based on chalcogenide glasses Cd sensor and Cu sensor, and the rest on poly(vinyl chloride) membranes Pb sensor and Zn sensor. The Ion Selective Electrode (ISE) sensors were first characterized with respect to one and two analytes, by means of high-dimensionality calibrations, thanks to the use of the automated flow system; this characterization enabled an interference study of great practical utility. To take profit of the dynamic nature of the sensor's response, the kinetic profile of each sensor was compacted by Fast Fourier Transform (FFT) and the extracted coefficients were used as inputs for the ANN in the multidetermination applications. In order to identify the ANN which provided the best model of the electrode responses, some of the network parameters were optimized. Finally analyses were performed employing synthetic samples and water samples of the river Ebro; obtained results were compared with reference methods.

Mimendia, Aitor; Merkoci, Arben; Valle, Manel del [Sensors and Biosensors Group, Chemistry Dept., Universitat Autonoma de Barcelona, Edifici Cn, 08193 Bellaterra, Barcelona (Spain); Legin, Andrey [Chemistry Dept, St. Petersburg University, Universitetskaya nab. 7/9, 199034 St. Petersburg (Russian Federation)

2009-05-23T23:59:59.000Z

373

Investigation of proposed process sequence for the array automated assembly task. Phase I and II. Final report, October 1, 1977-June 30, 1980  

SciTech Connect (OSTI)

A selected process sequence for the low cost fabrication of photovoltaic modules was defined during this contract. Each part of the process sequence was looked at regarding its contribution to the overall dollars per watt cost. During the course of the research done, some of the initially included processes were dropped due to technological deficiencies. The printed dielectric diffusion mask, codiffusion of the n+ and p+ regions, wraparound front contacts and retention of the diffusion oxide for use as an AR coating were all the processes that were removed for this reason. Other process steps were retained to achieve the desired overall cost and efficiency. Square wafers, a polymeric spin-on PX-10 diffusion source, a p+ back surface field and silver front contacts are all processes that have been recommended for use in this program. The printed silver solderable pad for making contact to the aluminum back was replaced by an ultrasonically applied tin-zinc pad. Also, the texturized front surface was dropped as inappropriate for the sheet silicon likely to be available in 1986. Progress has also been made on the process sequence for module fabrication. A shift from bonding with a conformal coating to laminating with ethylene vinyl acetate and a glass superstrate is recommended for further module fabrication. The finalized process sequence is described.

Mardesich, N.; Garcia, A.; Eskenas, K.

1980-08-01T23:59:59.000Z

374

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hindrance and/or charge repulsion. Also, polymers having an amide on which a C{sub 1}-C{sub 4} group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, E.D. Jr.; Christiansen, R.L.; Lederhos, J.P.; Long, J.P.; Panchalingam, V.; Du, Y.; Sum, A.K.W.

1997-06-17T23:59:59.000Z

375

Additives and method for controlling clathrate hydrates in fluid systems  

DOE Patents [OSTI]

Discussed is a process for preventing clathrate hydrate masses from detrimentally impeding the possible flow of a fluid susceptible to clathrate hydrate formation. The process is particularly useful in the natural gas and petroleum production, transportation and processing industry where gas hydrate formation can cause serious problems. Additives preferably contain one or more five member, six member and/or seven member cyclic chemical groupings. Additives include polymers having lactam rings. Additives can also contain polyelectrolytes that are believed to improve conformance of polymer additives through steric hinderance and/or charge repulsion. Also, polymers having an amide on which a C.sub.1 -C.sub.4 group is attached to the nitrogen and/or the carbonyl carbon of the amide may be used alone, or in combination with ring-containing polymers for enhanced effectiveness. Polymers having at least some repeating units representative of polymerizing at least one of an oxazoline, an N-substituted acrylamide and an N-vinyl alkyl amide are preferred.

Sloan, Jr., Earle Dendy (Golden, CO); Christiansen, Richard Lee (Littleton, CO); Lederhos, Joseph P. (Wheatridge, CO); Long, Jin Ping (Dallas, TX); Panchalingam, Vaithilingam (Lakewood, CO); Du, Yahe (Golden, CO); Sum, Amadeu Kun Wan (Golden, CO)

1997-01-01T23:59:59.000Z

376

Fort Devens: Cold Climate Market-Rate Townhomes Targeting HERS Index of 40, Harvard, Massachusetts (Fact Sheet)  

SciTech Connect (OSTI)

Achieving aggressive energy efficiency targets requires tight coordination and clear communication among owners, designers, builders, and subcontractors. For this townhome project, MassDevelopment, the quasi-governmental agency owner, selected Metric Development of Boston, teaming with the U.S. Department of Energy (DOE) Consortium for Advanced Residential Buildings (CARB) and Cambridge Seven Architects, to build very high performing market-rate homes. Fort Devens is part of a decommissioned army base in working-class Harvard, Massachusetts, approximately one hour northwest of Boston. The team proposed 12 net zero energy-ready townhomes, meaning that the application of renewable energy systems would result in annual net zero energy use in the homes. The homes were also designed to achieve a Home Energy Rating System (HERS) Index Score of 41 before adding renewables. For this project, CARB drew on its experience working with Rural Development Inc. on a series of affordable townhomes in northern Massachusetts. The team carefully planned the site to maximize solar access, daylighting, and efficient building forms. The basic strategy was to design a very efficient thermal enclosure while minimizing incremental cost increases compared with standard construction. Using BEopt modeling software, the team established the requirements of the enclosure and investigated multiple assembly options. They settled on double-wall construction with dense-pack cellulose fill. High performance vinyl windows (U-0.24, solar heat gain coefficient [SHGC]-0.22), a vented R-59 attic, and exceptional air sealing completed the package.

Not Available

2013-11-01T23:59:59.000Z

377

Testing Protocol for Module Encapsulant Creep (Presentation)  

SciTech Connect (OSTI)

Recently there has been an interest in the use of thermoplastic encapsulant materials in photovoltaic modules to replace chemically crosslinked materials, e.g., ethylene-vinyl acetate. The related motivations include the desire to: reduce lamination time or temperature; use less moisture-permeable materials; or use materials with better corrosion characteristics. However, the use of any thermoplastic material in a high-temperature environment raises safety and performance concerns, as the standardized tests currently do not expose the modules to temperatures in excess of 85C, yet modules may experience temperatures above 100C in operation. Here we constructed eight pairs of crystalline-silicon modules and eight pairs of glass/encapsulation/glass mock modules using different encapsulation materials of which only two were designed to chemically crosslink. One module set was exposed outdoors with insulation on the back side in Arizona in the summer, and an identical set was exposed in environmental chambers. High precision creep measurements and performance measurements indicate that despite many of these polymeric materials being in the melt state at some of the highest outdoor temperatures achievable, very little creep was seen because of their high viscosity, temperature heterogeneity across the modules, and in the case of the crystalline-silicon modules, the physical restraint of the backsheet. These findings have very important implications for the development of IEC and UL qualification and safety standards, and in regards to the necessary level of cure during the processing of crosslinking encapsulants.

Kempe, M. D.; Miller, D. C.; Wohlgemuth, J. H.; Kurtz, S. R.; Moseley, J. M.; Shah, Q.; Tamizhmani, G.; Sakurai, K.; Inoue, M.; Doi, T.; Masuda, A.

2012-02-01T23:59:59.000Z

378

Polymer/clay aerogel composites with flame retardant agents: Mechanical, thermal and fire behavior  

Science Journals Connector (OSTI)

Abstract Aerogel is a class of material characterized by its high void content and extreme lightness. Different polymer/clay aerogels have been prepared by a simply freezethaw process from a suspension with poly(vinyl alcohol) (PVOH) and clay (Na+-MMT). Low density polymer/clay aerogels modified with flame retardant agents were prepared using a similar approach. The addition of flame retardant agents slightly increased the apparent density of the final composites whereas the compression properties were reduced due to the decrease in the polymer/clay interfacial bonding. An exception was the sample containing Al(OH)3 that exhibited higher modulus and stress at maximum deformation. Regarding thermal properties, the presence of ammonium polyphosphate (APP) or silica gel (SG) significantly slowed the rate of aerogel decomposition at the temperature range from 250C to 500C while the onset of polymer decomposition was not affected. Fire behavior was analyzed through cone calorimeter suggesting that either the presence of Al(OH)3 or APP reduced the heat release rate of PVOH/clay systems.

Liang Wang; Miguel Snchez-Soto; Maria Lluisa Maspoch

2013-01-01T23:59:59.000Z

379

Theoretical kinetic estimates for the recombination of hydrogen atoms with propargyl and allyl radicals  

SciTech Connect (OSTI)

Ab initio quantum chemical simulations are coupled with variational transition state theory in estimating rate constants for the H+C{sub 3}H{sub 3} and H+C{sub 3}H{sub 5} recombination reactions. The energy of interaction between the H atom and each of the radicals is evaluated at the CAS+1+2 level for the range of separations and relative orientations spanning the transition state region. An analytic representation of these interaction energies is then implemented in variable reaction coordinate transition state theory calculations of the high pressure limit recombination rate constant for temperatures ranging from 200 to 2000 K. For the propargyl reaction the overall addition rate is separated into contributions correlating with the initial formation of allene and propyne. These theoretical results are compared with the available experimental data as well as with corresponding theoretical estimates for the H+C{sub 2}H{sub 3} and H+C{sub 2}H{sub 5} reactions. The H+propargyl and H+allyl total recombination rates are remarkably similar, with both being greater than the H+vinyl and H+ethyl rates, due to the presence of twice as many addition channels.

Harding, L. B.; Klippenstein, S. J.

2000-01-12T23:59:59.000Z

380

Sanitary landfill groundwater monitoring report. Fourth quarter 1996 and 1996 summary  

SciTech Connect (OSTI)

A maximum of eighty-nine wells of the LFW series monitor groundwater quality in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill at the Savannah River Site (SRS). These wells are sampled quarterly to comply with the South Carolina Department of Health and Environmental Control Domestic Waste Permit DWP-087A and as part of the SRS Groundwater Monitoring Program. Dichloromethane, a common laboratory contaminant, and chloroethene (vinyl chloride) were the most widespread constituents exceeding standards during 1996. Benzene, trichloroethylene, 1,4-dichlorobenzene, 1,1-dichloroethylene, lead (total recoverable), gross alpha, mercury (total recoverable), tetrachloroethylene, fluoride, thallium, radium-226, radium-228, and tritium also exceeded standards in one or more wells. The groundwater flow direction in the Steed Pond Aquifer (Water Table) beneath the Sanitary Landfill was to the southeast (universal transverse Mercator coordinates). The flow rate in this unit was approximately 141 ft/year during first quarter 1996 and 132 ft/year during fourth quarter 1996

NONE

1997-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Validation of formability of laminated sheet metal for deep drawing process using GTN damage model  

SciTech Connect (OSTI)

In this study, we studied formability of PET/PVC laminated sheet metal which named VCM (Vinyl Coated Metal). VCM offers various patterns and good-looking metal steel used for appliances such as refrigerator and washing machine. But, this sheet has problems which are crack and peeling of film when the material is formed by deep drawing process. To predict the problems, we used finite element method and GTN (Gurson-Tvergaard-Needleman) damage model to represent damage of material. We divided the VCM into 3 layers (PET film, adhesive and steel added PVC) in finite element analysis model to express the crack and peeling phenomenon. The material properties of each layer are determined by reverse engineering based on tensile test result. Furthermore, we performed the simple rectangular deep drawing and simulated it. The simulation result shows good agreement with drawing experiment result in position, punch stroke of crack occurrence. Also, we studied the fracture mechanism of PET film on VCM by comparing the width direction strain of metal and PET film.

Lim, Yongbin; Cha, Wan-gi; Kim, Naksoo [Department of Mechanical Engineering, Sogang University, 1 Sinsu-dong, Mapo-gu, Seoul, 121-742 (Korea, Republic of); Ko, Sangjin [Mold/die and forming technology team, Product prestige research lab, LG electronics, 222, LG-ro, Jinwi-myeon, Pyeongtaek-si, Gyeonggi-do, 451-713 (Korea, Republic of)

2013-12-16T23:59:59.000Z

382

Mixed Waste Management Facility groundwater monitoring report. Second quarter 1994  

SciTech Connect (OSTI)

Currently, 125 wells monitor groundwater quality in the uppermost aquifer beneath the Mixed Waste Management Facility (MWMF) at the Savannah River Site. Samples from the wells are analyzed for selected heavy metals, indicator parameters, radionuclides, volatile organic compounds, and other constituents. During second quarter 1994, chloroethene (vinyl chloride), 1,1-dichloroethylene, gross alpha, lead, tetrachloroethylene, trichloroethylene, or tritium exceeded final Primary Drinking Water Standards (PDWS) in approximately half of the downgradient wells at the MWMF. Consistent with historical trends, elevated constituent levels were found primarily in Aquifer Zone. As in previous quarters, tritium and trichloroethylene were the most widespread elevated constituents during second quarter 1994. Sixty-two of the 125 monitoring wells contained elevated tritium activities. Trichloroethylene concentrations exceeded the final PDWS in 23 wells. Chloroethene, 1,1-dichloroethylene, lead, and tetrachloroethylene, elevated in one or more wells during second quarter 1994, also occurred in elevated levels during first quarter 1994. These constituents generally were elevated in the same wells during both quarters. Gross alpha, which was not elevated in any well during first quarter 1994, was elevated in one well during second quarter. Copper, mercury, and nonvolatile beta were elevated during first quarter 1994 but not during second quarter.

Chase, J.A.

1994-09-01T23:59:59.000Z

383

Nanoengineering core/shell structured brucite@polyphosphate@amine hybrid system for enhanced flame retardant properties  

Science Journals Connector (OSTI)

Abstract A novel organic-inorganic hybrid flame retardant consisting of a brucite core and a dodecylamine polyphosphate shell was synthesized by a facile nanoengineering route. The flammability characterization and synergistic flame retardant mechanism of the core/shell flame retardant (CFR) in ethylene-vinyl acetate (EVA) blends had been compared with EVA/physical mixture (PM, with the given proportion of brucite and dodecylamine polyphosphate as well as CFR) and EVA/brucite blends. With the same loading amount (40wt%) of fillers in EVA, the peak heat release rate and smoke production rate of EVA/CFR blends were significantly reduced to 49% and 48% of that of EVA/PM blends, respectively. Meanwhile, the limiting oxygen index (LOI) was increased up to 32 (14.3% higher than that of EVA/PM blends) and the UL-94 test could achieve the V-0 rating. These remarkable properties were obtained just by nanoengineeing the core/shell structured brucite@polyphosphate@amine hybrid system, facilitating the formation of intact and compact residue with fence structure in process of polymer composite burning.

Xuesong Wang; Hongchang Pang; Wendan Chen; Yuan Lin; Guiling Ning

2013-01-01T23:59:59.000Z

384

A novel Whole Air Sample Profiler (WASP) for the quantification of volatile organic compounds in the boundary layer  

SciTech Connect (OSTI)

The emission and fate of reactive VOCs is of inherent interest to those studying chemical biosphere-atmosphere interactions. In-canopy VOC observations are obtainable using tower-based samplers, but the lack of suitable sampling systems for the full boundary 5 layer has limited the data characterizing the vertical structure of such gases above the canopy height and still in the boundary layer. This is the important region where many reactive VOCs are oxidized or otherwise removed. Here we describe an airborne sampling system designed to collect a vertical profile of air into a 3/800 OD tube 150m in length. The inlet ram air pressure is used to flow sampled air through the 10 tube, which results in a varying flow rate based on aircraft speed and altitude. Since aircraft velocity decreases during ascent, it is necessary to account for the variable flow rate into the tube. This is accomplished using a reference gas that is pulsed into the air stream so that the precise altitude of the collected air can be reconstructed post-collection. The pulsed injections are also used to determine any significant effect 15 from diffusion/mixing within the sampling tube, either during collection or subsequent extraction for gas analysis. This system has been successfully deployed, and we show some measured vertical profiles of isoprene and its oxidation products methacrolein and methyl vinyl ketone from a mixed canopy near Columbia, Missouri.

Mak, J. E.; Su, L.; Guenther, Alex B.; Karl, Thomas G.

2013-10-16T23:59:59.000Z

385

Characterization of Nanoclay Orientation in Polymer Nanocomposite Film by Small-angle X-ray Scattering  

SciTech Connect (OSTI)

The orientation distribution of layer-shaped nanoclays (e.g. organoclays and pristine clays) dispersed in a polymer matrix is an important parameter to control the properties of polymer nanocomposites. In this study, we demonstrate that the use of multi-directional 2-D small-angleX-rayscattering (SAXS) can quantitatively describe the orientation distribution of organoclays (e.g. Cloisite C20A) in melt-pressed nanocompositefilms, containing ethylene-vinyl acetate (EVA) copolymers as polymer matrices. Different weight fractions of organoclays were used to alter the orientation profile of nanocompositefilms, in which the dispersion and morphology of organoclays were also characterized by complementary 2-D and 3-D transmission electron microscopy (TEM). All nanocomposites exhibited mixed intercalation/exfoliation clay morphology, where the intercalated structure possessed partial orientation parallel to the in-plane direction of the film. The higher content of the clay loading showed a higher clay orientation. A simple analytical scheme for SAXS data analysis to determine the orientation parameter (P{sub 2}) was demonstrated, the results of which are in agreement with the gas permeation properties of the nanocompositefilms.

P Nawani; C Burger; L Rong; B Chu; B Hsiao; A Tsou; W Weng

2011-12-31T23:59:59.000Z

386

Synergistic flame retardant effect of metal hydroxide and nanoclay in EVA composites  

Science Journals Connector (OSTI)

This study focused on the flame retardancy of ethylene-vinyl acetate copolymer (EVA) in combination with metal hydroxide and nanoclay. Fire tests, such as limiting oxygen index (LOI), flammability (UL-94), cone calorimeter, and smoke density chamber were employed to evaluate the effect of composition variation for the metal hydroxide and the nanoclay in EVA composites. The experimental results showed that when the nanoclay of 1 or 2 weight per cent was substituted for the aluminum hydroxide or magnesium hydroxide in EVA blends, the LOI value was significantly improved while the V-0 rating was maintained. The data obtained from the cone calorimeter test indicated that the peak heat release rate (pk-HRR) is reduced by about 28%47%. The smoke density data (maximal smoke density, Dm) showed a reduction by about 16%25%. The thermogravimetric analysis (TGA) data also showed that the nanoclay increased the thermal stability and char residue of the EVA samples. Hence, it is suggested that the metal oxide layer on the burning surface is reinforced by the formation of silicate layer, which is both structured and compacted and acts as the insulation, and the newly formed layer responds to the synergistic effect of flame retardancy as well as smoke suppression observed in the EVA blends.

Ynh-Yue Yen; Hsin-Ta Wang; Wen-Jen Guo

2012-01-01T23:59:59.000Z

387

Synthesis And Characterization of Pt Clusters in Aqueous Solutions  

SciTech Connect (OSTI)

Extended X-ray absorption fine structure (EXAFS) and UV-visible (UV-vis) spectroscopies were used to monitor the various steps involved in the synthesis of unprotected and poly(vinyl alcohol) (PVA)-protected aqueous colloidal Pt suspensions. The results indicate that on hydrolysis of the H{sub 2}PtCl{sub 6} precursor, the Cl{sup -} ligands were partially replaced by aquo ligands in the first coordination shell of Pt to form [PtCl{sub 2}(H{sub 2}O){sub 4}]{sup 2+}. Treatment of these species with NaBH{sub 4} under controlled pH conditions led to the formation of nearly uniform Pt{sub 4} and Pt{sub 6} clusters in the absence and presence of PVA, respectively. These highly dispersed colloidal Pt suspensions were stable for several months. The addition of 2-propanol (IPA) to both types of Pt suspensions led to some sintering of the Pt clusters, although both suspensions retained their colloidal nature. Less sintering was evident in the PVA-protected Pt suspension. Both the unprotected and the PVA-protected colloidal Pt suspensions were catalytically active for the liquid-phase selective oxidation of 2-propanol to acetone, with the unprotected suspension exhibiting the highest activity.

Siani, A.; Wigal, K.R.; Alexeev, O.S.; Amiridis, M.D.

2009-05-26T23:59:59.000Z

388

Cast polycrystalline silicon photovoltaic module manufacturing technology improvements. Annual subcontract report, 1 January 1996--31 December 1996  

SciTech Connect (OSTI)

This report describes Solarex`s accomplishments during this phase of the Photovoltaic Manufacturing Technology (PVMaT) program. During this reporting period, Solarex researchers converted 79% of production casting stations to increase ingot size and operated them at equivalent yields and cell efficiencies; doubled the casting capacity at 20% the cost of buying new equipment to achieve the same capacity increase; operated the wire saws in a production mode with higher yields and lower costs than achieved on the ID saws; purchased additional wire saws; developed and qualified a new wire-guide coating material that doubles the wire-guide lifetime and produces significantly less scatter in wafer thickness; ran an Al paste back-surface-field process on 25% of all cells in manufacturing; completed environmental qualification of modules using cells produced by an all-print metallization process; qualified a vendor-supplied Tedlar/ethylene vinyl acetate (EVA) laminate to replace the combination of separate sheets of EVA and Tedlar backsheet; substituted RTV adhesive for the 3M Very High Bond tape after several field problems with the tape; demonstrated the operation of a prototype unit to trim/lead attach/test modules; demonstrated the use of light soldering for solar cells; demonstrated the operation of a wafer pull-down system for cassetting wet wafers; and presented three PVMaT-related papers at the 25th IEEE Photovoltaic Specialists Conference.

Wohlgemuth, J. [Solarex Corp., Frederick, MD (United States)

1997-10-01T23:59:59.000Z

389

Technical support document for proposed 1994 revision of the MEC thermal envelope requirements  

SciTech Connect (OSTI)

This report documents the development of the proposed revision of the Council of American Building Officials` (CABO) 1994 supplement to the 1993 Model Energy Code (MEC) building thermal envelope requirements for maximum component U{sub 0}-value. The 1994 amendments to the 1993 MEC were established in last year`s code change cycle and did not change the envelope requirements. The research underlying the proposed MEC revision was conducted by Pacific Northwest Laboratory (PNL) for the US Department of Energy (DOE) Building Energy Standards program. The goal of this research was to develop revised guidelines based on an objective methodology that determines the most cost-effective (least total cost) combination of energy conservation measures (ECMs) (insulation levels and window types) for residential buildings. This least-cost set of ECMs was used as a basis for proposing revised MEC maximum U{sub 0}-values (thermal transmittances). ECMs include window types (for example, double-pane vinyl) and insulation levels (for example, R-19) for ceilings, walls, and floors.

Conner, C.C.; Lucas, R.G.

1994-03-01T23:59:59.000Z

390

Field Lysimeter Investigations - test results: Low-Level Waste Data Base Development Program: Test results for fiscal years 1994-1995  

SciTech Connect (OSTI)

The Field Lysimeter Investigations: Low-Level Waste Data Base Development Program, funded by the U.S. Nuclear Regulatory Commission (NRC), is (1) studying the degradation effects in EPICOR-II organic ion-exchange resins caused by radiation, (2) examining the adequacy of test procedures recommended in the Branch Technical Position on Waste Form to meet the requirements of 10 CFR 61 using solidified EPICOR-II resins, (3) obtaining performance information on solidified EPICOR-II ion-exchange resins in a disposal environment, and (4) determining the condition of EPICOR-II liners. Results of the final 2 (10 total) years of data acquisition from operation of the field testing are presented and discussed. During the continuing field testing, both portland type I-II cement and Dow vinyl ester-styrene waste forms are being tested in lysimeter arrays located at Argonne National Laboratory-East in Illinois and at Oak Ridge National Laboratory. The experimental equipment is described and results of waste form characterization using tests recommended by the NRC`s {open_quotes}Technical Position on Waste Form{close_quotes} are presented. The study is designed to provide continuous data on nuclide release and movement, as well as environmental conditions, over a 20-year period. At the end of the tenth year, the experiment was closed down. Examination of soil and waste forms is planned to be conducted next and will be reported later.

McConnell, J.W. Jr.; Rodgers, R.D.; Hilton, L.D.; Neilson, R.M. Jr. [and others

1996-06-01T23:59:59.000Z

391

Field lysimeter investigations - test results. Low-level waste data base development program: Test results for fiscal years 1986, 1987, 1988, and 1989  

SciTech Connect (OSTI)

The Field Lysimeter Investigations: Low-Level Waste Data Base Development Program, funded by the U.S. Nuclear Regulatory Commission (NRC), is (a) studying the degradation effects in EPICOR-II organic ion-exchange resins caused by radiation, (b) examining the adequacy of test procedures recommended in the Branch Technical Position on Waste Form to meet the requirements of 10 CFR 61 using solidified EPICOR-II resins, (c) obtaining performance information on solidified EPICOR-II ion-exchange resins in a disposal environment, and (d) determining the condition of EPICOR-II liners. Results of the first 4 years of data acquisition from the field testing are presented and discussed. During the continuing field testing, both Portland type I-II cement and Dow vinyl ester-styrene waste forms are being tested in lysimeter arrays located at Argonne National Laboratory-East in Illinois and at Oak Ridge National Laboratory. The experimental equipment is described and results of waste form characterization using tests recommended by the NRC`s {open_quotes}Technical Position on Waste Form{close_quotes} are presented. The study is designed to provide continuous data on nuclide release and movement, as well as environmental conditions, over a 20-year period.

McConnell, J.W. Jr.; Rogers, R.D.; Findlay, M.W.; Davis, E.C.; Jastrow, J.D.; Neilson, R.M. Jr.; Hilton, L.D.

1995-05-01T23:59:59.000Z

392

Field Lysimeter Investigations -- Test results. Low-Level Waste Data Base Development Program: Test results for fiscal years 1990, 1991, 1992, and 1993; Volume 2  

SciTech Connect (OSTI)

The Field Lysimeter Investigations: Low-Level Waste Data Base Development Program, funded by the US Nuclear Regulatory Commission (NRC), is (a) studying the degradation effects in EPICOR-II organic ion-exchange resins caused by radiation, (b) examining the adequacy of test procedures recommended in the Branch Technical Position on Waste Form to meet the requirements of 10 CFR 61 using solidified EPICOR-II resins, (c) obtaining performance information on solidified EPICOR-II ion-exchange resins in a disposal environment, and (d) determining the condition of EPICOR-II liners. Results of the second 4 years of data acquisition from the field testing are presented and discussed. During the continuing field testing, both portland type 1--2 cement and Dow vinyl ester-styrene waste forms are being tested in lysimeter arrays located at Argonne National Laboratory-East in Illinois and at Oak Ridge National Laboratory. The experimental equipment is described and results of waste form characterization using tests recommended by the NRC`s ``Technical Position on Waste Form`` are presented. The study is designed to provide continuous data on nuclide release and movement, as well as environmental conditions, over a 20-year period.

McConnell, J.W. Jr.; Rogers, R.D.; Brey, R.R.; Neilson, R.M. Jr.; Hilton, L.D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering Lab.; Jastrow, J.D. [Argonne National Lab., IL (United States); Wickliff Hicks, D.S.; Sanford, W.E. [Oak Ridge National Lab., TN (United States); Sullivan, T.M. [Brookhaven National Lab., Upton, NY (United States)

1995-12-01T23:59:59.000Z

393

Evaluating fugacity models for trace components in landfill gas  

Science Journals Connector (OSTI)

A fugacity approach was evaluated to reconcile loadings of vinyl chloride (chloroethene), benzene, 1,3-butadiene and trichloroethylene in waste with concentrations observed in landfill gas monitoring studies. An evaluative environment derived from fictitious but realistic properties such as volume, composition, and temperature, constructed with data from the Brogborough landfill (UK) test cells was used to test a fugacity approach to generating the source term for use in landfill gas risk assessment models (e.g. GasSim). SOILVE, a dynamic Level II model adapted here for landfills, showed greatest utility for benzene and 1,3-butadiene, modelled under anaerobic conditions over a 10year simulation. Modelled concentrations of these components (95?300?gm?3; 43?gm?3) fell within measured ranges observed in gas from landfills (24?300180?000?gm?3; 2070?gm?3). This study highlights the need (i) for representative and time-referenced biotransformation data; (ii) to evaluate the partitioning characteristics of organic matter within waste systems and (iii) for a better understanding of the role that gas extraction rate (flux) plays in producing trace component concentrations in landfill gas.

Sophie Shafi; Andrew Sweetman; Rupert L. Hough; Richard Smith; Alan Rosevear; Simon J.T. Pollard

2006-01-01T23:59:59.000Z

394

Beneficial reuse of treated media from remediation at an industrial site  

SciTech Connect (OSTI)

Remediation at an active PVC resin manufacturing plant in southeastern Pennsylvania has involved closure of lagoons under a RCRA plan and design of a groundwater pump and treat program under CERCLA. Both the CERCLA and RCRA programs involve beneficial reuse of the treated media, which in effect has offset some costs of the remediation. The lagoons were used to settle the PVC residual material from wastewater generated by the facility. Analysis of the residual material showed that the polymer content would allow it to be used as a low-grade PVC resin after drying. The treatment process selected for the RCRA lagoon closure involved indirect steam stripping and filter pressing which produced a filter cake that was both nonhazardous and marketable. Approximately 6,000 tons of product was sent to market from the lagoons. The groundwater, which will be remediated at the site, contains trichlorethylene (TCE), vinyl chloride monomer (VCM), and other volatile organic compounds. An average 400 gpm of groundwater will be extracted and treated by carbon absorbents and an air stripper. The groundwater will be used by the plant in the production process after it is treated by the CERCLA remediation system.

Erdman, D.E. [Smith Environmental Technologies, Plymouth Meeting, PA (United States); Weston, A.F. [Occidental Chemical Corp., Niagara Falls, NY (United States); Morrissey, B.J. [Occidental Chemical Corp., Houston, TX (United States)

1996-12-31T23:59:59.000Z

395

Chemical phenomena in solid-state voltammetry in polymer solvents  

SciTech Connect (OSTI)

This paper, aimed at delineating significant chemical effects in solid-state voltammetry, describes electrochemical oxidations and reductions of electroactive monomer solutes dissolved in and diffusing through rigid and semirigid polymer electrolyte solvents. Sorption of organic monomer vapors into poly(ethylene oxide) films yields polymer solvents whose chemistry is dominated by that of the sorbed monomer as shown by coordination and precipitation effects. The dynamics of plasticization-induced changes in transport rates are quite rapid. Physical diffusion in the polymer solvent in slow enough that electron hopping reactions measurably enhance charge transport rates; the effect was used to estimate a lower limit for the (Co(bpy)/sub 3/)/sup 2+/+/ self-exchange rate constant of 2 /times/ 10/sup 9/ M/sup /minus/1/ s/sup /minus/1/. It is possible to erect polymeric film transport barriers at the electrode/polymer solvent interface and to measure the rate of permeation of monomer complexes from the polymer solvent into the polymer transport barrier film. Polymeric films of Os and Ru polypyridine complexes can be electropolymerized from polymer solutions of the corresponding monomers. Solid-state voltammetry can be extended to other polymer solvents including sulfonated polystyrene, poly(vinyl chloride), Nafion, and poly(acrylamide) gel.

Geng, L.; Reed, R.A.; Kim, M.H.; Wooster, T.T.; Oliver, B.N.; Egekeze, J.; Kennedy, R.T.; Jorgenson, J.W.; Parcher, J.F.; Murray, R.W.

1989-03-01T23:59:59.000Z

396

Hoechst and Wacker plan joint venture in PVC  

SciTech Connect (OSTI)

Restructuring of Europe's petrochemical industry has taken a further step with the announcement that Hoechst (Frankfurt) and Wacker Chemie (Munich) are planning a joint venture in polyvinyl chloride (PVC). The venture would include production, R D, sales and marketing, plus both companies' PVC recycling activities. However, their vinyl chloride monomer (VCM) plants, and Hoechst's Kalle PVC film business, have been left out. Erich Schnitzler, head of Hoechst's PVC business unit, does not anticipate problems with the European Community's competition directorate. We are both among the middle-sized European PVC producers, and together we would have a 9%-10% market share. Our joint venture would not limit competition. Both partners are hoping for approval from Brussels in first-quarter 1993. Hoechst has 255,000 m.t./year of PVC capacity at Gendorfand Knapsack, while Wacker has 365,000 m.t./year at Burghausen and Cologne. All the units, except Wacker's Cologne plant, are back integrated to VCM. The joint venture would buy VCM from the two parent companies and on the merchant market.

Young, I.

1992-12-02T23:59:59.000Z

397

Coke formation during pyrolysis of 1,2-dichloroethane  

SciTech Connect (OSTI)

Most processes involving hydrocarbons or carbon oxides at high temperatures suffer from the disadvantage of coke formation. The formation of coke deposits during pyrolysis of hydrocarbons or chlorinated hydrocarbons is of significant practical importance. Examples of such processes are the steam cracking of alkanes to produce olefins and the thermal decomposition of 1,2-dichloroethane (EDC) for the production of vinyl chloride monomer (VCM). Even id the rate of coke production is low, the cumulative nature of the solid product will result in reactor fouling. The present work deals with the thermal decomposition of EDC. Coke formation has been studied on metal surfaces in a quartz tubular reactor. The rate of coke deposition was measures on metal foils hanging from one arm of a microbalance. A complete analysis of the product gas was accomplished using on-line gas chromatography. The results show that coke deposition during thermal decomposition of EDC depends on the composition of the feed as well as on the nature of the surface of the metal foil. Small amounts of other components (contamination with other chlorinated hydrocarbons as an example) may have a large influence on the rate of coke formation. The results are discussed in terms of surface composition/morphology of the metal foil and the free radical mechanism for thermal decomposition of FDC.

Holmen, A. [Norwegian Institute of Technology, Trondheim (Norway); Lindvag, O.A. [SINTEF Applied Chemistry, Trondheim (Norway)

1995-12-31T23:59:59.000Z

398

Preparation and characterization of gradient polymer films  

SciTech Connect (OSTI)

Gradient polymers are multicomponent polymers whose chemical constitution varies with depth in the sample. Although these polymers may possess unique mechanical, optical, and barrier properties they remain relatively unexplored. This work is a study of the preparation of gradient polymers by sequential exposure of films to a diffusing monomer followed by electron beam irradiation. Initial experiments involved immersion of poly(vinyl chloride) (PVC) films in styrene or n-butyl methacrylate (BMA) for various time periods followed by irradiation with 1 or 10 megarads of accelerated electrons. A significant amount of poly(n-butyl methacrylate) (PBMA) formed in PVC/BMA systems, but little polystyrene could be found in the PVC/styrene films. A second set of experiments involved immersion of PVC and polyethylene (PE) films in BMA for 20, 40, 60, and 720 minutes followed by irradiation with 10 megarads of electrons. These films were then characterized using optical microscopy, quantitative transmission Fourier transform infrared spectroscopy (FTIR), and a depth profiling procedure based on quantitative attenuated total reflection (ATR) FTIR. It was concluded that the mechanism of PBMA formation in the polyethylene films was a result of events immediately following irradiation. Atmospheric oxygen diffusing into irradiated films trapped free radicals at the film surfaces. This was followed by storage in an evacuated desiccator where unintentional exposure to BMA vapor took place. This BMA reacted with free radicals that remained within the film cores, polymerizing to PBMA.

Smith, S.C.

1987-01-01T23:59:59.000Z

399

Proper design hikes gas-lift system efficiency  

SciTech Connect (OSTI)

Proper design of gas-lift pumping systems, used for pumping corrosive or erosive fluids, involves the correct selection of submergence ratio, flow regime, pipe diameter, and physical properties of the fluid. Correlations for maximum lifting efficiency on a friction-free basis vs. submergence ratio have been developed based on experimental data. The Oshinowo and Charles flow map for vertical upward flow has been chosen for determining the two-phase flow regimes. For large-diameter gas-lifting systems, the effects of fluid physical properties on the maximum lifting efficiency become diminished. Gas-lift pumping systems are widely used in the process industry as well as in oil and gas production. In an ethylene dichloride/vinyl chloride monomer (EDC/VCM) plant, quench column bottoms are recirculated back to the column by gas lift of the EDC/VCM stream from the EDC pyrolysis furnace. Gas lift is utilized instead of pumps to alleviate the plugging and erosion problems caused by the presence of coke/tar particulates. Other process applications include those where pumps suffer severe corrosion from the fluids pumped.

Tsai, T.C.

1986-06-30T23:59:59.000Z

400

Porosity in polysilsesquioxane xerogels  

SciTech Connect (OSTI)

Polysilsesquioxanes, [RSiO{sub 1.5}]{sub n} are a class of hybrid organic-inorganic materials in which silicon atoms are linked with up to three siloxane bonds to other monomer units in the polymer and the organic group is a pendent functionality. Polysilsesquioxanes are prepared by the hydrolysis and condensation of organotrialkoxysilanes (Scheme l). Organotrialkoxysilanes RSi(OR{prime}){sub 3}, have been extensively used as coupling agents for composites or surface treatments for materials. Polysilsesquioxanes have become increasingly popular for generating specialty coatings such as low k dielectric materials for microelectronic applications. While there is extensive information on the formation of polysilsesquioxanes, there has not been a survey of the ability of organotrialkoxysilanes to form gels until recently. The formation of polysilsesquioxanes gels has been shown to be very sensitive to the nature of the organic group. Many monomers will only form soluble oligomers or polymers upon hydrolysis and condensation, even when the reaction is conducted solvent-free with neat monomer and aqueous catalyst. Furthermore, there is little information concerning the influence of the organic group, R, on the porosity of the polysilsesquioxanes gels that are formed. In this paper the authors describe the preparation of polysilsesquioxane gels where R = H, methyl, ethyl, cyanoethyl, vinyl, dodecyl, hexadecyl, octadecyl, chloromethyl, and chloromethylphenyl, and the characterization of the porosity of the respective xerogels. Gels were prepared from the hydrolysis and condensation of organotrimethoxysilanes, RSi(OEt){sub 3}, and organotriethoxy-silanes, RSi(OEt){sub 3}.

LOY,DOUGLAS A.; SCHNEIDER,DUANE A.; BAUGHER,BRIGITTA M.; RAHIMIAN,KAMYAR

2000-05-09T23:59:59.000Z

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Gas chromatograph monitors for VCM, automatically alerts emergency team  

SciTech Connect (OSTI)

Delaware City, located on the Delaware River with a metropolitan population of around 100,000, has played host to numerous companies in the CPI. The community has witnessed the expansion to a current level of eleven plants and a large oil refinery. Identified by the DNREC as possibly the most serious of recent problems was the potential for release of vinyl chloride monomer (VCM) gas. VCM is a recognized carcinogen and is considered a hazardous waste and a priority pollutant by the EPA. A Citizens' Advisory Committee recommended that a permanent air monitor for detection of VCM be strategically located in Delaware City. It needed to be capable of detecting VCM at 50 ppb and utilize a suitable alarm procedure to alert the public. The committee also recommended the use of a mobile monitor equipped to track a VCM release which could by-pass the Delaware City monitor and threaten nearby residents during certain wind conditions. A gas chromatography with photoionization detector (PID) was selected based on the required specifications and on commercial availability. The Delaware City firehouse was selected as the most publicly acceptable location with sufficient security and unobstructed sampling at an adequate height. The air in Delaware City has been monitored continuously since December 9, 1985. As of April, 1986, the instrument has completed, 30,000 combined sample and calibration runs. No unusual problems have been encountered with maintenance or with anomalous data. It has required only routine service, surpassing the manufacturer's guarantees for parts and service.

Rogers, J.C.; Ormond, D.L.

1986-09-01T23:59:59.000Z

402

Exploratory case-control study of brain tumors in adults  

SciTech Connect (OSTI)

An exploratory study of brain tumors in adults was carried out using 215 cases diagnosed in Southern Ontario between 1979 and 1982, with an individually matched, hospital control series. Significantly elevated risks were observed for reported use of spring water, drinking of wine, and consumption of pickled fish, together with a significant protective effect for the regular consumption of any of several types of fruit. While these factors are consistent with a role for N-nitroso compounds in the etiology of these tumors, for several other factors related to this hypothesis, no association was observed. Occupation in the rubber industry was associated with a significant relative risk of 9.0, though no other occupational associations were seen. Two previously unreported associations were with smoking nonfilter cigarettes with a significant trend and with the use of hair dyes or sprays. The data do not support an association between physical head trauma requiring medical attention and risk of brain tumors and indicate that exposure to ionizing radiation and vinyl chloride monomer does not contribute any appreciable fraction of attributable risk in the population studied. The findings warrant further detailed investigation in future epidemiologic studies.

Burch, J.D.; Craib, K.J.; Choi, B.C.; Miller, A.B.; Risch, H.A.; Howe, G.R.

1987-04-01T23:59:59.000Z

403

Detecting and defining air pollutants: one laboratory's experiences and approaches  

SciTech Connect (OSTI)

The Texas Air Control Board is the agency responsible for maintaining the quality of the ambient air of Texas. An extensive network of continuous and noncontinuous monitors is used to defect air quality trends in the state. The samples submitted may be gaseous, liquid, or solid. X-ray fluorescence spectroscopy (XRF) is used for various elements. XRF was used specifically for lead emissions, sulfur dioxide emissions and toxic metals. However, atomic absorption is better for beryllium and arsenic. Gas chromatography (GC), high pressure liquid chromatography (HPLC), and gas chromatography/mass spectrometry (GC/MS) are employed in organic analysis as complements to each other. HPLC has been effectively used in the analysis of samples for herbicides. The defection of vinyl chloride monomer (VCM) is accomplished with a photoionization defector (PID) and flame ionization detector (FID) in series. There are many examples of a multi-instrument approach to analysis of samples. Gas chromatography and mass spectroscopy were used for nitrobenzene analysis. The complexity of ambient air sampler often requires a multinstrumental approach if the sample is to be qualitatively and quantitatively analyzed so that the information can be used for corrective action or to identify potential problems of air pollution. 2 figures. (DP)

Lindgren, J.L.; Krauss, H.J.; Mgebroff, J.S.

1980-08-01T23:59:59.000Z

404

Understanding Molecular Interactions within Chemically Selective Layered Polymer Assemblies  

SciTech Connect (OSTI)

This work focuses on two broad issues. These are (1) the molecular origin of the chemical selectivity achieved with ultrathin polymer multilayers, and (2) how the viscoelastic properties of the polymer layers are affected by exposure to solvent and analytes. These issues are inter-related, and to understand them we need to design experiments that probe both the energetic and kinetic aspects of interfacial adsorption processes. This project focuses on controling the chemical structure, thickness, morphology and sequential ordering of polymer layers bound to interfaces using maleimide-vinyl ether and closely related alternating copolymerization chemistry and efficient covalent cross-linking reactions that allow for layer-by-layer polymer deposition. This chemistry has been developed during the funding cycle of this Grant. We have measure the equilibrium constants for interactions between specific layers within the polymer interfaces and size-controlled, surface-functionalized gold nanoparticles. The ability to control both size and functionality of gold nanoparticle model analytes allows us to evaluate the average pore size that characterizes our polymer films. We have measured the bulk viscosity and shear modulus of the ultrathin polymer films as a function of solvent overlayer identity using quartz crystal microbalance complex impedance measurements. We have measured microscopic viscosity at specific locations within the layered polymer interfaces with time-resolved fluorescence lifetime and depolarization techniques. We combine polymer, cross-linking and nanoparticle synthetic expertise with a host of characterization techniques, including QCM gravimetry and complex impedance analysis, steady state and time-resolved spectroscopies.

Gary J. Blanchard

2009-06-30T23:59:59.000Z

405

Investigation of test methods, material properties, and processes for solar cell encapsulants. Annual report  

SciTech Connect (OSTI)

The goal of this program is to identify, evaluate, and recommend encapsulant materials and processes for the production of cost-effective, long-life solar cell modules. Technical activities during the past year have covered a number of topics and have emphasized the development of solar module encapsulation technology that employs ethylene/vinyl acetate, copolymer (EVA) as the pottant. These activities have included: (1) continued production of encapsulation grade EVA in sheet form to meet the needs of the photovoltaic industry; (2) investigations of three non-blocking techniques for EVA sheet; (3) performed an economic analysis of the high volume production of each pottant in order to estimate the large volume selling price (EVA, EPDM, aliphatic urethane, PVC plastisol, and butyl acrylate); (4) initiated an experimental corrosion protection program to determine if metal components could be successfully protected by encapsulation; (5) began an investigation to determine the maximum temperature which can be tolerated by the candidate pottant material in the event of hot spot heating or other temperature override; (6) continuation of surveys of potentially useful outer cover materials; and (7) continued with the accelerated artificial weathering of candidate encapsulation materials. Study results are presented. (WHK)

Willis, P. B.; Baum, B.; Schnitzer, H. S.

1980-07-01T23:59:59.000Z

406

Investigation of mortality from cancer and other causes of death among workers employed at an east Texas chemical plant  

SciTech Connect (OSTI)

The cause-specific mortality of 2,510 males employed at an east Texas chemical plant was examined in a historical prospective study to evaluate a suspected increase in deaths from multiple myeloma and brain cancer. Potential exposures from chemicals, either used in manufacturing processes or produced during the study period 1952-1977, included the fuel additive tetraethyl lead, ethylene dibromide and dichloride, inorganic lead, and vinyl chloride monomer. Overall mortality for all workers (156 observed vs. 211.14 expected) and for workers first employed between 1952 and 1959 (131 observed vs. 167.33 expected) when tetraethyl lead was the single major product was lower than expected when compared to the United States general population. There were no significant increases in mortality from malignancies or other causes of death. The deficits may be due to the small number of total deaths, and the low power for detecting excess risk of mortality from multiple myeloma (Z1-beta = 27, alpha = .05), brain cancer (Z1-beta = 31, alpha = .05), or other rare causes of death; lack of complete workplace exposure data for production workers; and the absence of historical measurements on the extent of environmental exposure to tetraethyl lead and other chemicals.

Sweeney, M.H.; Beaumont, J.J.; Waxweiler, R.J.; Halperin, W.E.

1986-01-01T23:59:59.000Z

407

Ceramic membrane treatment of petrochemical wastewater  

SciTech Connect (OSTI)

Ceramic alumina microfiltration membranes were evaluated for treatment of 3 aqueous streams containing heavy metals, oils, and solids at petrochemical manufacturing facilities. To the best of the author's knowledge, this is the first reported use of ceramic alumina membranes for process water and wastewater treatment in a US petrochemical plant. In a pilot test at a vinyl chloride monomer (VCM) plant, precipitated heavy metal solids were filtered with the membranes. On another stream at that site, the ceramic membrane pilot system successfully treated emulsions of 1,2-dichloroethane (EDC), water, and solids. Membrane filtration of a linear alkyl benzene (LAB) oily wastewater stream produced water with less than 5 ppmw oil and grease, after pretreatment with HCl and ferric chloride. A preliminary financial analysis shows that the installed system cost for a ceramic membrane unit is comparable to other membrane technologies, while operating costs are anticipated to be lower. Specific process conditions that are particularly amenable to treatment by ceramic membrane microfiltration are also given in the paper. 10 refs., 11 figs., 7 tabs.

Lahiere, R.J. (Vista Chemical Co., Houston, TX (United States)); Goodboy, K.P.

1993-05-01T23:59:59.000Z

408

Subdue solids in towers  

SciTech Connect (OSTI)

Many distillation, absorption, and stripping columns operate with solids present in the system. The presence of solids may be either intentional or unintentional. But, in all cases, the solids must be handled or tolerated by the vapor/liquid mass-transfer equipment. Such solids should be dealt with by a combination of four methods. From most favorable to least favorable, these are: (1) keep the solids out; (2) keep the solids moving; (3) put the solids somewhere harmless; and (4) make it easier to clean the hardware. The key precept for all these approaches is the realization that solids present in a system just don't disappear. In this article, the authors review the techniques and design issues involved in making a vapor/liquid mass-transfer system operate with solids present. They assume that the solids cannot be kept out, eliminating the first choice. The type of mass-transfer service does not matter. The same principles apply equally well to distillation, adsorption, and stripping. They include equipment design criteria based on the methods outlined above, as well as detailed recommendations for each of the major equipment choices that can be made for mass-transfer devices. Then, they illustrate the approach via an example--a vinyl chloride monomer (VCM) unit having solids as an inherent part of its feed.

Sloley, A.W.; Martin, G.R.

1995-01-01T23:59:59.000Z

409

Initiation of atomic layer deposition of metal oxides on polymer substrates by water plasma pretreatment  

SciTech Connect (OSTI)

The role of surface hydroxyl content in atomic layer deposition (ALD) of aluminum oxide (AO) on polymers is demonstrated by performing an atomic layer deposition of AO onto a variety of polymer types, before and after pretreatment in a plasma struck in water vapor. The treatment and deposition reactions are performed in situ in a high vacuum chamber that is interfaced to an x-ray photoelectron spectrometer to prevent adventitious exposure to atmospheric contaminants. X-ray photoelectron spectroscopy is used to follow the surface chemistries of the polymers, including theformation of surface hydroxyls and subsequent growth of AO by ALD. Using dimethyl aluminum isopropoxide and water as reactants, ALD is obtained for water-plasma-treated poly(styrene) (PS), poly(propylene) (PP), poly(vinyl alcohol) (PVA), and poly(ethylene naphthalate) (PEN). For PS, PP, and PEN, initial growth rates of AO on the native (untreated) polymers are at least an order of magnitude lower than on the same polymer surface following the plasma treatment. By contrast, native PVA is shown to initiate ALD of AO as a result of the presence of intrinsic surface hydroxyls that are derived from the repeat unit of this polymer.

Steven Brandt, E.; Grace, Jeremy M. [Eastman Kodak Company, 1999 Lake Avenue, Rochester, New York 14650-2022 (United States)

2012-01-15T23:59:59.000Z

410

Methanol's transformation to commodity status stretches supply  

SciTech Connect (OSTI)

Methanol is undergoing a renaissance. Beginning in the US in the fourth quarter of 1993, methanol has seen a transformation from a low-growth, low-priced, overly abundant commodity chemical into a high-demand, undersupplied, cost-price driven product. As the economic recovery has spread to the rest of the world, methanol demand has dramatically increased. this meteoric rise has been further sparked in the US by increased use of methanol as an ingredient in gasoline oxygenates required by the federal government. Increased demand has led to the consolidation of producers, a scramble to reopen existing capacity, addition of capacity via product conversion, and plans for various future capacity expansions. Methanol fits alongside the other long-standing, major organic commodity chemicals-ethylbenzene, ethylene, ethylene dichloride, formaldehyde, propylene, styrene, terephthalic acid, and vinyl chloride. Methanol also serves both as a building block for many other chemicals--formaldehyde, acetic acid, and terephthalic acid--and as a solvent for many industrial uses.

Peaff, G.

1994-10-24T23:59:59.000Z

411

Accelerated Exposure Tests of Encapsulated Si Solar Cells and Encapsulation Materials  

SciTech Connect (OSTI)

We have conducted a series of accelerated exposure test (AET) studies for various crystalline-Si (c-Si) and amorphous-Si (a-Si) cell samples that were encapsulated with different superstrates, pottants, and substrates. Nonuniform browning patterns of ethylene vinyl acetate (EVA) pottants were observed for glass/EVA/glass-encapsulated c-Si cell samples under solar simulator exposures at elevated temperatures. The polymer/polymer-configured laminates with Tedlar or Tefzel did not discolor because of photobleaching reactions, but yellowed with polyester or nylon top films. Delamination was observed for the polyester/EVA layers on a-Si minimodules and for a polyolefin-based thermoplastic pottant at high temperatures. For all tested c-Si cell samples, irregular changes in the current-voltage parameters were observed that could not be accounted for simply by the transmittance changes of the superstrate/pottant layers. Silicone-type adhesives used under UV-transmitting polymer top films were observed to cause greater cell current/efficiency loss than EVA or polyethylene pottants.

Pern, F. J.; Glick, S. H.

1998-10-08T23:59:59.000Z

412

Mercury-control technology-assessment study: D. F. Goldsmith Chemical and Metal Corporation, Evanston, Illinois. In-depth survey report for the site visit of May 4-6, 1982. Final report  

SciTech Connect (OSTI)

An in-depth survey was conducted at the D. F. Goldsmith Chemical and Metal Corporation in Evanston, Illinois; emphasis was placed on the recirculating air unit for control of mercury vapor. Major products were prime virgin mercury, precious metals, and rare inorganic chemicals. Mercury was poured into an open vessel which was subsequently covered, and the mercury treated by agitation with an acidic or caustic solution. Mercury was then transferred to the still where it was batch-distilled. After distillation, mercury was bottled in 1 or 5 pound quantities and packed and shipped. The ventilation system included local exhaust, dilution, and recirculation steps. Local exhaust ventilation was particularly important at the bottle-filling station. Personal protective equipment included respirators, disposable lab coats, vinyl coated cloth gloves, plastic shoe coverings, and barrier creams. Work practices were controlled, and biological and air monitoring were in place. The recirculating unit removed 76% of the mercury vapor in the air stream. The authors recommend that a study be made of the advisability of using a charcoal filter in addition to the manganese oxide precoat bag filter with post filtration.

Telesca, D.R.

1982-09-01T23:59:59.000Z

413

Examination of a Standardized Test for Evaluating the Degree of Cure of EVA Encapsulation: Preprint  

SciTech Connect (OSTI)

The curing of cross-linkable encapsulation is a critical consideration for photovoltaic (PV) modules manufactured using a lamination process. Concerns related to ethylene-co-vinyl acetate (EVA) include the quality (e.g., expiration and uniformity) of the films or completion (duration) of the cross-linking of the EVA within a laminator. Because these issues are important to both EVA and module manufacturers, an international standard has recently been proposed by the Encapsulation Task-Group within the Working Group 2 (WG2) of the International Electrotechnical Commission (IEC) Technical Committee 82 (TC82) for the quantification of the degree of cure for EVA encapsulation. The present draft of the standard calls for the use of differential scanning calorimetry (DSC) as the rapid, enabling secondary (test) method. Both the residual enthalpy- and melt/freeze-DSC methods are identified. The DSC methods are calibrated against the gel content test, the primary (reference) method. Aspects of other established methods, including indentation and rotor cure metering, were considered by the group. Key details of the test procedure will be described.

Miller, D. C.; Gu, X.; Haldenman, S.; Hidalgo, M.; Malguth, E.; Reid, C. G.; Shioda, T.; Schulze, S. H.; Wang, Z. Y.; Wohlgemuth, J. H.

2013-11-01T23:59:59.000Z

414

Examination of a Standardized Test for Evaluating the Degree of Cure of EVA Encapsulation (Presentation)  

SciTech Connect (OSTI)

The curing of cross-linkable encapsulation is a critical consideration for photovoltaic (PV) modules manufactured using a lamination process. Concerns related to ethylene-co-vinyl acetate (EVA) include the quality (e.g., expiration and uniformity) of the films or completion (duration) of the cross-linking of the EVA within a laminator. Because these issues are important to both EVA and module manufacturers, an international standard has recently been proposed by the Encapsulation Task-Group within the Working Group 2 (WG2) of the International Electrotechnical Commission (IEC) Technical Committee 82 (TC82) for the quantification of the degree of cure for EVA encapsulation. The present draft of the standard calls for the use of differential scanning calorimetry (DSC) as the rapid, enabling secondary (test) method. Both the residual enthalpy- and melt/freeze-DSC methods are identified. The DSC methods are calibrated against the gel content test, the primary (reference) method. Aspects of other established methods, including indentation and rotor cure metering, were considered by the group. Key details of the test procedure will be described.

Miller, D.; Wohlgemuth, J.; Gu, X.; Haldeman, S.; Hidalgo, M.; Malguth, E.; Reid, C.; Shioda, T.; Schulze, S.; Wang, Z.

2013-11-01T23:59:59.000Z

415

Integrated Hatchery Operations Team: Operations Plans for Anadromous Fish Production Facilities in the Columbia River Basin, Volume IV of IV; Washington: Rocky Reach Hatchery Addendum, 1992 Annual Report.  

SciTech Connect (OSTI)

Rocky Reach Hatchery is located along the Columbia Paver, just downstream from Rocky Reach Dam. Site elevation is 800 feet above sea level. The Turtle Rock Island facility, located 2 miles upstream, is operated as a satellite facility (shared with the Washington Department of Wildlife). The facility is staffed with 2.75 FTE`S. The hatchery was originally designed as a mile-long spawning channel at Turtle Rock Island. Rearing units consist of eight vinyl raceways at Rocky Reach and four rearing ponds at Turtle Rock. Water rights are held by Chelan County PUD and total 3,613 gpm from the Columbia River. Water available for use in the Turtle Rock rearing ponds averages 12,000 gpm from the Columbia River. Rocky Reach Hatchery and the Turtle Rock satellite facility are owned by Chelan County PUD. They are operated as mitigation facilities for the fishery impacts caused by the construction and operation of Rocky Reach Dam. Rocky Reach Hatchery is used for incubation and early rearing of upriver bright (URB) fall chinook. Fingerlings are later transferred to the Turtle Rock facility for final rearing and release.

Peck, Larry

1993-08-01T23:59:59.000Z

416

Interaction modes between heavy metal ions and water-soluble polymers. 2. Spectroscopic and magnetic reexamination of the aqueous solutions of cupric ions and poly(acrylic acid)  

SciTech Connect (OSTI)

The interaction between cupric ions and poly(acrylic acid) (PAA) in aqueous solutions has been reexamined by EPR, magnetic susceptibility, and optical absorption. Cupric ions exist in solutions at pH < 3 as ordinary hydrated ions, and in the pH range 3-8, two mononuclear complexes with carboxyl groups of PAA are formed in equilibrium with other complex species; the two complexes have the same coordination structures as Cu(OAc)/sup +/ and Cu(OAc)/sub 2/, where OAc/sup -/ denotes acetate anion. Around pH 4, two slightly different binuclear copper(II) complexes of the cupric acetate type are formed in high yields; at (PAA polymer residue)/(Cu/sup 2 +/) less than or equal to 10, about 90% of the cupric ions form such binuclear complexes. At pH > 6, Cu(OH)/sub 2/ is gradually formed and complex species other than Cu(OH)/sub 2/ finally disappear at pH > 9. Cu(OH)/sub 2/ does not deposit but remains in solution by hydrophobic interaction with PAA, as in the case with poly(vinyl alcohol).

Yokoi, H.; Kawata, S.; Iwaizumi, M.

1986-06-11T23:59:59.000Z

417

Versatility of Alkyne-Modified Poly(Glycidyl Methacrylate) Layers for Click Reactions  

SciTech Connect (OSTI)

Functional soft interfaces are of interest for a variety of technologies. We describe three methods for preparing substrates with alkyne groups, which show versatility for 'click' chemistry reactions. Two of the methods have the same root: formation of thin, covalently attached, reactive interfacial layers of poly(glycidyl methacrylate) (PGMA) via spin coating onto silicon wafers followed by reactive modification with either propargylamine or 5-hexynoic acid. The amine or the carboxylic acid moieties react with the epoxy groups of PGMA, creating interfacial polymer layers decorated with alkyne groups. The third method consists of using copolymers comprising glycidyl methacrylate and propargyl methacrylate (pGP). The pGP copolymers are spin coated and covalently attached on silicon wafers. For each method, we investigate the factors that control film thickness and content of alkyne groups using ellipsometry, and study the nanophase structure of the films using neutron reflectometry. Azide-terminated polymers of methacrylic acid and 2-vinyl-4,4-dimethylazlactone synthesized via reversible addition-fragmentation chain transfer polymerization were attached to the alkyne-modified substrates using 'click' chemistry, and grafting densities in the range of 0.007-0.95 chains nm{sup -2} were attained. The maximum density of alkyne groups attained by functionalization of PGMA with propargylamine or 5-hexynoic acid was approximately 2 alkynes nm{sup -3}. The alkyne content obtained by the three decorating approaches was sufficiently high that it was not the limiting factor for the click reaction of azide-capped polymers.

Soto-Cantu, Dr. Erick [University of Tennessee, Knoxville (UTK); Lokitz, Bradley S [ORNL; Hinestrosa Salazar, Juan Pablo [Clemson University; Deodhar, Chaitra [University of Tennessee, Knoxville (UTK); Messman, Jamie M [ORNL; Ankner, John Francis [ORNL; Kilbey, II, S Michael [ORNL

2011-01-01T23:59:59.000Z

418

Designing Functionality and Stimuli-Responsiveness into Azlactone-Based Polymers  

SciTech Connect (OSTI)

There continues to be considerable interest in stimuli-responsive and reactive polymers for drug delivery vehicles or gene therapy agents, as well as soft interfaces capable of being patterned or chemically modified to serve as a biomaterial coating. One class of materials with particularly interesting potential are polymers based on 2-vinyl-4,4-dimethylazlactone (VDMA), which react rapidly with various nucleophiles without producing a leaving group or requiring a catalyst. In this contribution we describe the synthesis and characterization of polymers and copolymers incorporating VDMA, and their conjugation with biomolecules. By using reversible addition fragmentation chain transfer (RAFT) polymerization we are able to produce well-defined VDMA-containing homopolymers and block copolymers having tailored molecular weights and narrow molecular weight distributions. The conversion of these materials into polyelectrolytes and bioconjugates can be monitored in real time using infrared spectroscopy. Poly(VDMA)-based brushes can be synthesized by RAFT polyermization using surface-tethered chain transfer agents, and these brushes can be modified in situ and structural changes monitored using neutron reflectometry.

Messman, Jamie M [ORNL; Lokitz, Bradley S [ORNL; Ankner, John Francis [ORNL; Kilbey, II, S Michael [ORNL

2008-01-01T23:59:59.000Z

419

Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors formed by such methods  

DOE Patents [OSTI]

Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.

Fox, Robert V.; Rodriguez, Rene G.; Pak, Joshua J.; Sun, Chivin; Margulieux, Kelsey R.; Holland, Andrew W.

2014-09-09T23:59:59.000Z

420

NETL: Oil & Natural Gas Projects  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Synthesis and Evaluation of Inexpensive CO2 Thickeners Designed by Molecular Modeling The Synthesis and Evaluation of Inexpensive CO2 Thickeners Designed by Molecular Modeling DE-FC26-04NT15533 Project Goal The goal of this project is to use molecular modeling and experimental results to design inexpensive, environmentally benign, CO2-soluble compounds that can decrease the mobility of CO2 at typical enhanced oil recovery (EOR) reservoir conditions. Performers University of Pittsburgh, Pittsburgh, PA Yale University, New Haven, CT Background The research group previously formulated the only known CO2 thickener, a (fluoroacrylate-styrene) random copolymer, but this proof-of-concept compound was expensive and environmentally unacceptable because it was fluorous. They then identified the most CO2-soluble, high-molecular-weight, conventional polymer composed solely of carbon, hydrogen, and oxygen: poly(vinyl acetate), or PVAc. PVAc could not dissolve at pressures below the minimum miscibility pressure (MMP), however. The current research effort, therefore, was directed at using molecular modeling and experimental tools to design polymers that are far more CO2-soluble than PVAc. The subsequent goal was to incorporate this polymer into a thickening agent that will dissolve in CO2 below the MMP and generate a two- to ten-fold decrease in CO2 mobility at concentrations of 0.01–1.0 percent by weight. Although most of the thickeners envisioned are copolymers, researchers will also evaluated several small hydrogen-bonding agents and surfactants with oligomeric (very short polymer) tails that form viscosity-enhancing structures in solution , and novel CO2 soluble surfactants that may be able to generate foams in situ as they mix with reservoir brine (without the need for the injection of alternating slugs of water).

Note: This page contains sample records for the topic "110-75-8 2-chloroethyl vinyl" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331  

SciTech Connect (OSTI)

Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

422

Remedial investigation report on waste area grouping 5 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Volume 4, Appendix C, Risk assessment  

SciTech Connect (OSTI)

Waste Area Grouping (WAG) 5 is part of Oak Ridge National Laboratory (ORNL) and is located on the United States Department of Energy`s Oak Ridge Reservation (DOE-ORR). The site lies southeast of Haw Ridge in Melton Valley and comprises approximately 32 ha (80 ac) [12 ha (30 ac) of forested area and the balance in grassed fields]. Waste Area Grouping 5 consists of several contaminant source areas for the disposal of low-level radioactive, transuranic (TRU), and fissile wastes (1959 to 1973) as well as inorganic and organic chemical wastes. Wastes were buried in trenches and auger holes. Radionuclides from buried wastes are being transported by shallow groundwater to Melton Branch and White Oak Creek. Different chemicals of potential concern (COPCs) were identified (e.g., cesium-137, strontium-90, radium-226, thorium-228, etc.); other constituents and chemicals, such as vinyl chloride, bis(2-ethylhexyl)phthalate, trichloroethene, were also identified as COPCs. Based on the results of this assessment contaminants of concern (COCs) were subsequently identified. The objectives of the WAG 5 Baseline Human Health Risk Assessment (BHHRA) are to document the potential health hazards (i.e., risks) that may result from contaminants on or released from the site and provide information necessary for reaching informed remedial decisions. As part of the DOE-Oak Ridge Operations (ORO), ORNL and its associated waste/contamination sites fall under the auspices of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), also known as Superfund under the Superfund Amendments and Reauthorization Act (SARA). The results of the BHHRA will (1) document and evaluate risks to human health, (2) help determine the need for remedial action, (3) determine chemical concentrations protective of current and future human receptors, and (4) help select and compare various remedial alternatives.

NONE

1995-09-01T23:59:59.000Z

423

Technical area status report for low-level mixed waste final waste forms. Volume 1  

SciTech Connect (OSTI)

The Final Waste Forms (FWF) Technical Area Status Report (TASR) Working Group, the Vitrification Working Group (WG), and the Performance Standards Working Group were established as subgroups to the FWF Technical Support Group (TSG). The FWF TASR WG is comprised of technical representatives from most of the major DOE sites, the Nuclear Regulatory Commission (NRC), the EPA Office of Solid Waste, and the EPA`s Risk Reduction Engineering Laboratory (RREL). The primary activity of the FWF TASR Working Group was to investigate and report on the current status of FWFs for LLNM in this TASR. The FWF TASR Working Group determined the current status of the development of various waste forms described above by reviewing selected articles and technical reports, summarizing data, and establishing an initial set of FWF characteristics to be used in evaluating candidate FWFS; these characteristics are summarized in Section 2. After an initial review of available information, the FWF TASR Working Group chose to study the following groups of final waste forms: hydraulic cement, sulfur polymer cement, glass, ceramic, and organic binders. The organic binders included polyethylene, bitumen, vinyl ester styrene, epoxy, and urea formaldehyde. Section 3 provides a description of each final waste form. Based on the literature review, the gaps and deficiencies in information were summarized, and conclusions and recommendations were established. The information and data presented in this TASR are intended to assist the FWF Production and Assessment TSG in evaluating the Technical Task Plans (TTPs) submitted to DOE EM-50, and thus provide DOE with the necessary information for their FWF decision-making process. This FWF TASR will also assist the DOE and the MWIP in establishing the most acceptable final waste forms for the various LLMW streams stored at DOE facilities.

Mayberry, J.L.; DeWitt, L.M. [Science Applications International Corp., Idaho Falls, ID (United States); Darnell, R. [EG and G Idaho, Inc., Idaho Falls, ID (United States)] [and others

1993-08-01T23:59:59.000Z

424

Cast polycrystalline silicon photovoltaic module manufacturing technology improvements. Semiannual technical report, 1 January 1996--30 June 1996  

SciTech Connect (OSTI)

Two specific objectives of Solarex`s program are to reduce the manufacturing cost for polycrystalline silicon photovoltaic modules to less than $1.20/watt and to increase the manufacturing capacity by a factor of three. This report highlights accomplishments during the period of January 1 through June 30, 1996. Accomplishments include: began the conversion of production casting stations to increase ingot size; operated the wire saw in a production mode with higher yields and lower costs than achieved on the ID saws; developed and qualified a new wire guide coating material that doubles the wire guide lifetime and produces significantly less scatter in wafer thickness; completed a third pilot run of the cost-effective Al paste back-surface-field (BSF) process, verifying a 5% increase in cell efficiency and demonstrating the ability to process and handle the BSF paste cells; completed environmental qualification of modules using cells produced by an all-print metallization process; optimized the design of the 15.2-cm by 15.2-cm polycrystalline silicon solar cells; demonstrated the application of a high-efficiency process in making 15.2-cm by 15.2-cm solar cells; demonstrated that cell efficiency increases with decreasing wafer thickness for the Al paste BSF cells; qualified a vendor-supplied Tedlar/ethylene vinyl acetate (EVA) laminate to replace the combination of separate sheets of EVA and Tedlar backsheet; demonstrated the operation of a prototype unit to trim/lead attach/test modules; and demonstrated the operation of a wafer pull-down system for cassetting wet wafers.

Wohlgemuth, J. [Solarex Corp., Frederick, MD (United States)] [Solarex Corp., Frederick, MD (United States)

1997-01-01T23:59:59.000Z

425

The Copper Sulfide Coating on Polyacrylonitrile with Chelating Agents by an Electroless Deposition Method and its EMI Shielding Effectiveness  

SciTech Connect (OSTI)

In this study, a variety of concentrations of chelating agents were added to obtain the anchoring effect and chelating effect in the electroless plating bath. The mechanism of the Cu{sub x(x=1,2)}S growth and the electromagnetic interference shielding effectiveness (EMI SE) of the composite were studied. It was found that the vinyl acetate residued in PAN substrate would be purged due to the swelling effect by chelating agents solution. And then, the anchoring effect occurred due to the hydrogen bonding between the pits of PAN substrate and the chelating agent. Consequently, the copper sulfide layer deposited by the electroless plating reaction with EDTA and TEA. The swelling degree (S{sub d}) was proposed and evaluated from the FT-IR spectra. The relationship between swelling degree of the PAN films and EDTA (C) is expressed as: S{sub d} = 0.13+0.90xe and (-15.15C). And TEA series is expressed as: S{sub d} = 0.07+1.00xe and (-15.15C). On the other hand, the FESEM micrograph showed that the average thickness of copper sulfide increased from 76 nm to 383 nm when the concentration of EDTA increased from 0.00M to 0.20M. Consequently, the EMI SE of the composites increased from 10{approx}12 dB to 25{approx}27 dB. The GIA-XRD analyze indicated that the deposited layer consisted of CuS and Cu{sub 2}S.

Roan, M.-L. [Department of Electro-optical Engineering, Lan-Yan Institute of Technology, Taiwan (China); Chen, Y.-H.; Huang, C.-Y. [Department of Materials Engineering, Tatung University, Taiwan (China)

2008-08-28T23:59:59.000Z

426

Volatile organic chemical emissions from carpets. Final report  

SciTech Connect (OSTI)

The primary objective of this research, was to measure the emission rates of selected individual VOC, including low molecular-weight aldehydes, released by samples of four new carpets that are typical of the major types of carpets used in residences, schools and offices. The carpet samples were collected directly from the manufacturers` mills and packaged to preserve their chemical integrity. The measurements of the concentrations and emission rates of these compounds were made under simulated indoor conditions in a 20-M{sup 3} environmental chamber designed specifically for investigations of VOC. The measurements were conducted over a period of one week following the installation of the carpet samples in the chamber. Duplicate experiments were conducted for one carpet. In addition, the concentrations and emission rates of VOC resulting from the installation of a new carpet in a residence were measured over a period of seven weeks. The stabilities of the week-long ventilation rates and temperatures were one percent relative standard deviation. The four carpets emitted a variety of VOC, 40 of which were positively identified. Eight of these were considered to be dominant. They were (in order of chromatographic retention time) formaldehyde, vinyl acetate, 2,2,4-trimethylpentane (isooctane), 1,2-propanediol (propylene glycol), styrene, 2-ethyl-l-hexanol, 4-phenylcyclohexene (4-PCH), and 2,6 di-tert-butyl-4-methylphenol (BHT). With the exception of formaldehyde, only limited data are available on the toxicity and irritancy of these compounds at low concentrations. Therefore, it is difficult to determine at this time the potential magnitude of the health and comfort effects that may occur among the population from exposures to emissions from new carpets. The concentrations and emission rates of most compounds decreased rapidly over the first 12 h of the experiments.

Hodgson, A.T.; Wooley, J.D.; Daisey, J.M.

1992-04-01T23:59:59.000Z

427

Elf Atochem sets five-year emission targets  

SciTech Connect (OSTI)

As part of its first annual environmental report, released this month, Elf Atochem (Paris) has set targets for emission reductions at its sites for the next five years. Under the program, the company aims to slash the level of contaminants in discharge water by 30%; cut by half emissions of 17 [open quotes]priority[close quotes] substances-including ammonia, chlorofluorocarbons, vinyl chloride monomer, methyl methacrylate, aromatics, chlorinated solvent, ethylbenzene, and styrene-for which 1992 emissions totaled 15,996 m.t.; reduce nitrogen oxides (NO[sub x]) emissions by 25%; and increase the proportions of toxic waste treated in installations on the company's own sites, from 90% of 1992's 383,00 m.t., to 95%. Implementation of its environmental policy cost the company about F2 billion ($375 million), or 3.5%-4% of sales, in 1992. The policy focuses on safer and more efficient technologies, toxic emissions and waste, improving energy efficiency, and cooperation with customers and public authorities on the introduction of more environmentally friendly products. Atochem says it has led to a fourfold reduction in accidents at work between 1984 and 1992. Over the same period, water contamination at the company's French sites has been cut by 67%, measured against the French chemical industry association's [open quotes]water index[close quotes]. Some sites did even better than the average, with the Carling steam cracker complex in eastern France registering a drop in water contamination of more than 90% following a F150-million joint project with local French and German water authorities.

Young, I.

1993-04-21T23:59:59.000Z

428

Polymerization of trialkoxysilanes. Effect of the organic substituent on the formation of gels  

SciTech Connect (OSTI)

Hydrolysis and condensation of trialkoxysilanes, R-Si(OR{prime}){sub 3}, generally leads to the formation of silsesquioxane oligomers and polymers. These polymers are composed of a monomer repeat unit, [R-SiO{sub 1.5}]{sub n}, with a single silicon atom attached to other repeat units in the polymer through one to three siloxane bonds. The remaining substituent is an organic group attached to the silicon through a silicon-carbon single bond. Silsesquioxanes have been the subject of intensive study in the past and are becoming important again as a vehicle for introducing organic functionalities into hybrid organic-inorganic materials through sol-gel processing. Despite all of this interest, there has not been a systematic study of the ability of trialkoxysilanes to form gels through the sol-gel process. In fact, it has been noted that silsesquioxanes are generally isolated as soluble resins rather than the highly crosslinked network polymers (gels) one would expect from a tri-functional monomer. In this study, the authors have examined the sol-gel chemistry of a variety of trialkoxysilanes with different organic substituents (R = H, Me, Et, n-Pr, i-Pr, n-Bu, i-Bu, t-Bu, n-octadecyl, n-dodecyl, cyclohexyl, vinyl, phenyl, benzyl, phenethyl), with methoxide or ethoxide substituents on silicon, at varying monomer concentrations ranging up to neat monomer, and with different catalysts (HCl, NaOH, formic acid, fluoride). Gels were prepared from tetramethoxysilane and tetraethoxysilane at identical concentrations for purposes of comparison.

Loy, D.A.; Baugher, B.M.; Schneider, D.A.

1998-09-01T23:59:59.000Z

429

Responsive copolymers for enhanced petroleum recovery. Second annual report  

SciTech Connect (OSTI)

The authors describe second year efforts in synthesis, characterization, and rheology to develop polymers with significantly improved efficiency in mobility control and conformance. These advanced polymer systems would maintain high viscosities or behave as virtual gels under low shear conditions and at elevated electrolyte concentrations. At high fluid shear rates, associates would deaggregate yielding low viscosity solutions, reducing problems of shear degradation or face plugging during injection. Polymeric surfactants were also developed with potential for use in higher salt, higher temperature reservoirs for mobilization of entrapped oil. Chapters include: Ampholytic terpolymers of acrylamide with sodium 3-acrylamido-3-methylbutanoate and 2-acrylamido-2-methylpropanetrimethylammonium chloride; Hydrophilic sulfobetaine copolymers of acrylamide and 3-(2-acrylamido-methylpropane-dimethylammonio)-1-propanesulfonate; Copolymerization of maleic anhydride and N-vinylformamide; Reactivity ratio of N-vinylformamide with acrylamide, sodium acrylate, and n-butyl acrylate; Effect of the distribution of the hydrophobic cationic monomer dimethyldodecyl(2-acrylamidoethyl)ammonium bromide on the solution behavior of associating acrylamide copolymers; Effect of surfactants on the solution properties of amphipathic copolymers of acrylamide and N,N-dimethyl-N-dodecyl-N-(2-acrylamidoethyl)ammonium bromide; Associative interactions and photophysical behavior of amphiphilic terpolymers prepared by modification of maleic anhydride/ethyl vinyl ether copolymers; Copolymer compositions of high-molecular-weight functional acrylamido water-soluble polymers using direct-polarization magic-angle spinning {sup 13}C NMR; Use of factorial experimental design in static and dynamic light scattering characterization of water soluble polymers; and Porous medium elongational rheometer studies of NaAMB/AM copolymer solutions.

McCormick, C.; Hester, R.

1995-05-01T23:59:59.000Z

430

Removable fibrous glass insulation fitted to complex equipment shapes results in $178,000/yr savings  

SciTech Connect (OSTI)

In early 1980, PPG Industries embarked on a general plant energy conservation effort at its Lake Charles, LA plant where chlor-alkalis, various chlorinated hydrocarbons, and vinyl chloride monomer are manufactured. Company engineers sought a means of insulating process steam components that, because of their complex shapes, were not (and normally are not) insulated. These components included flanges on heat exchanger heads and reboilers, steam valves in process areas, manways and other equipment. PPG plant engineers specified removable, reusable blanket insulation. The blankets are constructed of a fibrous glass mat form insulation encased in a silicone-impregnated glass cloth or similar weather barrier. Each insulation blanket was custom-made for its particular equipment shape and service application to ensure a close fit and optimal energy efficiency. Insulation thickness, type of weather barrier, and mesh were specified according to intended use. For protection from abrasion or puncture, some of the blankets also were covered with stainless steel, Monel, or Inconel wire mesh. Overall, the blankets provide high strength, durability, low thermal conductivity ratings, and an operating range of up to 1200/sup 0/F. Reduced maintenance costs and improved worker productivity have been evidenced since installing the blanket insulation. Further, PPG has increased energy efficiency. Project savings were tracked for 30 months (insulation and installation costs vs. fuel and maintenance savings) and revealed annual plant savings of $178,000-$130,000 in energy savings and $48,000 in maintenance savings. With the cost of the insulation blankets being about $125,000, PPG recovered its investment in under a year.

Not Available

1985-08-01T23:59:59.000Z

431

An electrocyclic strategy to poly(triarylmethyl radical) polymers: Potential organic ferromagnets  

SciTech Connect (OSTI)

Recent interest in organic ferromagnetism has been stimulated by the idea that large poly(triarylmethyl radical) polymers in which the radical centers are connected by [open quotes]meta[close quotes]-aryl groups may possess ferromagnetic properties. However, synthesis of these polyradicals has been limited by stepwise methods that are unsuitable for the preparation of large polymers. This limitation represents a primary challenge confronting the field. The authors have developed the first polymeric strategy to poly (m-triarylmethyl radical) precursors that involves an electrocyclic formation of the [open quotes]meta[close quotes]-substituted triarylmethyl chloride repeating unit from a polypropynol precursor. Poly[(E)-6-[beta]-chloroethenyl-1,3-phenylene-1-phenylpropynol-1,3-ylene] was prepared by palladium-catalyzed coupling of a bifunctional acetylene-aryl iodide monomer. The stable polymer reacted with thionyl chloride to form an unstable polychloroallene intermediate that underwent an electrocyclic conversion to the polyradical precursor, poly(1-chloro-2,7-naphthalenechlorobenzylidene). The reduced polyradicals exhibited properties of radical-radical coupling, and preparation of a second generation polymer that would overcome this problem has been initiated. The polymeric strategy was based on model studies that showed that (E)-3-(2-[beta]-chloroethenylphenyl)-1,1-diphenylpropynol, when converted to the corresponding chloroallene with thionyl chloride, underwent an electrocyclic conversion to [beta]-(1-chlornaphthyl)diphenylmethyl chloride. The strategy expanded upon the use of triarylpropynes as precursors to triarylmethyl chlorides, and extension of both approaches to higher analogs was demonstrated with dimeric systems. The electrocyclic processes were found to occur only for the trans-vinyl chlorides; the cis-isomers were found to undergo an alternative concerted cyclization to benzofluorene products.

Morelli, J.P.

1992-01-01T23:59:59.000Z

432

Microstructure and Crystal-Amorphous Interphases in Melt-Miscible Semicrystalline Polymer Blends. Ph.D. Thesis  

SciTech Connect (OSTI)

Small-angle x ray scattering, differential scanning calorimetry, dielectric spectroscopy and dynamic mechanical thermal analysis were performed to study the microstructure of the semicrystalline polymers poly(etylene oxide) (PEO) and poly (epsilon-caprolactone) (PCL) as well as several melt miscible blends. Four amorphous polymers were blended with PEO: two which interact weakly with PEO poly(methyl methacrylate) (PMMA) and poly(vinyl acetate) (PVAc) and two which are considered strongly interacting due to the formation of hydrogen bonds with PEO (two random copolymers, one containing 50% styrene and 50% hydroxystyrene (50/50 ScHS) and another of ethylene with 55% methacrylic acid (EMA55)). Further, one of the weakly interacting amorphous polymers and one of the strongly interacting polymers was selected based on its relatively high T(sub g)s. The other amorphous polymers have relatively low T(sub g)s (i.e., at or below the crystallization temperature). The solid state microstructure of miscible blends containing a semicrystalline and an amorphous polymer is shown to be critically dependent on two factors: (1) the strength of interactions between the two copolymers; and (2) the mobility of the amorphous material at the crystallization temperature. The influence of interaction strength on the region of partial order at the crystal surface (the crystal-amorphous interphase) is demonstrated. The results are consistent with theoretical predictions that this region changes from pure crystallizable material to a mixture containing both the crystalizable and the amorphous components as chi becomes more favorable. In the blends which contain a high T(sub g) amorphous polymer and in those with strong intermolecular interactions, there were no observed changes in the microstructure with crystallization temperature. Apparently, in the high T(sub g) systems, the amorphous polymer is unable to escape the interlamellar zone since it has insufficient mobility.

Barron, C.A.

1994-01-01T23:59:59.000Z

433

Potential health impacts from range fires at Aberdeen Proving Ground, Maryland.  

SciTech Connect (OSTI)

This study uses atmospheric dispersion computer models to evaluate the potential for human health impacts from exposure to contaminants that could be dispersed by fires on the testing ranges at Aberdeen Proving Ground, Maryland. It was designed as a screening study and does not estimate actual human health risks. Considered are five contaminants possibly present in the soil and vegetation from past human activities at APG--lead, arsenic, trichloroethylene (TCE), depleted uranium (DU), and dichlorodiphenyltrichloroethane (DDT); and two chemical warfare agents that could be released from unexploded ordnance rounds heated in a range fire--mustard and phosgene. For comparison, dispersion of two naturally occurring compounds that could be released by burning of uncontaminated vegetation--vinyl acetate and 2-furaldehyde--is also examined. Data from previous studies on soil contamination at APG are used in conjunction with conservative estimates about plant uptake of contaminants, atmospheric conditions, and size and frequency of range fires at APG to estimate dispersion and possible human exposure. The results are compared with US Environmental Protection Agency action levels. The comparisons indicate that for all of the anthropogenic contaminants except arsenic and mustard, exposure levels would be at least an order of magnitude lower than the corresponding action levels. Because of the compoundingly conservative nature of the assumptions made, they conclude that the potential for significant human health risks from range fires is low. The authors recommend that future efforts be directed at fire management and control, rather than at conducting additional studies to more accurately estimate actual human health risk from range fires.

Willians, G.P.; Hermes, A.M.; Policastro, A.J.; Hartmann, H.M.; Tomasko, D.

1998-03-01T23:59:59.000Z

434

Dosimetry quality assurance in Martin Marietta Energy Systems' centralized external dosimetry system  

SciTech Connect (OSTI)

External dosimetry needs at the four Martin Marietta Energy Systems facilities are served by Energy Systems Centralized External Dosimetry System (CEDS). The CEDS is a four plant program with four dosimeter distribution centers and two dosimeter processing centers. Each plant has its own distribution center, while processing centers are located at ORNL and the Y-12 Plant. The program has been granted accreditation by the Department of Energy Laboratory Accreditation Program (DOELAP). The CEDS is a TLD based system which is responsible for whole-body beta-gamma, neutron, and extremity monitoring. Beta-gamma monitoring is performed using the Harshaw/Solon Technologies model 8805 dosimeter. Effective October 1, 1992 the standard silver mylar has been replaced with an Avery mylar foil blackened on the underside with ink. This was done in an effort to reduce the number of light induced suspect readings. At this time we have little operational experience with the new blackened mylars-The CEDS neutron dosimeter is the Harshaw model 8806B. This card/holder configuration contains two TLD-600/TLD-700 chip pairs; one pair is located beneath a cadmium filter and one pair is located beneath a plastic filter. In routine personnel monitoring the CEDS neutron dosimeter is always paired with a CEDS beta-gamma dosimeter.The CEDS extremity dosimeter is composed of a Harshaw thin TLD-700 dosiclip placed inside a Teledyne RB-4 finger sachet. The finger sachet provides approximately 7 mg/cm[sup 2] filtration over the chip. A teflon ring surrounds the dosiclip to help prevent tearing of the vinyl sachet.

Souleyrette, M.L.

1992-10-23T23:59:59.000Z

435

Fabrication of extended-release patient-tailored prednisolone tablets via fused deposition modelling (FDM) 3D printing  

Science Journals Connector (OSTI)

Abstract Rapid and reliable tailoring of the dose of controlled release tablets to suit an individual patient is a major challenge for personalized medicine. The aim of this work was to investigate the feasibility of using a fused deposition modelling (FDM) based 3D printer to fabricate extended release tablet using prednisolone loaded poly(vinyl alcohol) (PVA) filaments and to control its dose. Prednisolone was loaded into a PVA-based (1.75mm) filament at approximately 1.9% w/w via incubation in a saturated methanolic solution of prednisolone. The physical form of the drug was assessed using differential scanning calorimetry (DSC) and X-ray powder diffraction (XRPD). Dose accuracy and in vitro drug release patterns were assessed using HPLC and pH change flow-through dissolution test. Prednisolone loaded PVA filament demonstrated an ability to be fabricated into regular ellipse-shaped solid tablets using the FDM-based 3D printer. It was possible to control the mass of printed tablet through manipulating the volume of the design (R2=0.9983). On printing tablets with target drug contents of 2, 3, 4, 5, 7.5 and 10mg, a good correlation between target and achieved dose was obtained (R2=0.9904) with a dose accuracy range of 88.7107%. Thermal analysis and XRPD indicated that the majority of prednisolone existed in amorphous form within the tablets. In vitro drug release from 3D printed tablets was extended up to 24h. FDM based 3D printing is a promising method to produce and control the dose of extended release tablets, providing a highly adjustable, affordable, minimally sized, digitally controlled platform for producing patient-tailored medicines.

Justyna Skowyra; Katarzyna Pietrzak; Mohamed A. Alhnan

2014-01-01T23:59:59.000Z

436

Spectrally selective laminated glazing consisting of solar control and heat mirror coated glass: preparation, characterization and modelling of heat transfer  

Science Journals Connector (OSTI)

In this study, solar control coatings were prepared by sequential depositions of thin films of ZnS (40nm)CuS (150nm) and ZnS (40nm)Bi2S3 (75nm)CuS (150nm) from chemical baths on 3mm thick commercial sheet glass. These were laminated to 3mm thick clear glass or commercially available SnO2 based heat mirror coating of sheet resistance 15? on float glass of 3mm thickness using a poly(ethylene vinyl acetate), EVA, sheet of 0.36mm thickness in a vacuum process at 120C for 30min. In total, the thickness of the glazing was 6.35mm. The glazings possess visible transmittance, weighted for D65 solar spectra and sensitivity of the human eye for daylight vision, of 36% or 14% with solar absorptance of 71% or 78% depending on the coating type, i.e ZnSCuS or ZnSBi2S3CuS-heat mirror respectively. The solar heat gain coefficient (SHGC) was evaluated for these glazings at exterior temperatures of 15 and 32C for an exterior convective heat transfer coefficient (hex) of 6100Wm?2K?1 using a mathematical model. The model predicts the extent of reduction in SHGC through the presence of the heat mirror coating as a function of hex and hence helps to decide on the relative benefit, which may be derived through their use in different locations. Though the deposition technique mentioned here involves longer duration compared with vacuum techniques, it may be developed into a low throughput, low-capital alternate technology for small-scale production.

G. Alvarez; J.J. Flores; J.O. Aguilar; O. Gmez-Daza; C.A. Estrada; M.T.S. Nair; P.K. Nair

2005-01-01T23:59:59.000Z

437

Nonphotochemical hole burning of organic dyes and rare earth ions in polymers and glasses: a probe of the amorphous state  

SciTech Connect (OSTI)

New and in depth studies of amorphous materials (e.g., glasses and polymers) probed via the low temperature optical technique of nonphotochemical hole burning (NPHB) are presented. An extensive review of the phenomena itself, along with selected topics involving the use of persistent hole burning techniques, is given. In addition, a semi-complete tabulation of essentially all hole burning systems to date is included. The deuteration dependence in an amorphous host is examined for the system of tetracene in an ethanol/methanol mixture. The results illustrate the importance of hydrogen bonding in the hole burning process. The discovery of a highly efficient (or facile) class of hole burning systems, i.e., ionic dyes in hydroxylated polymers (i.e., poly(vinyl alcohol) (PVOH) and poly(acrylic acid) (PAA)), is presented and discussed. Ultrafast relaxation processes (i.e., dephasing) are studied for the system of cresyl violet perchlorate (CV) in PVOH. Further, for the first time, NPHB of rare earth ions, specifically Pr/sup +3/ and Nd/sup +3/, in a soft organic glass (i.e., PVOH) is discussed briefly. Detailed experimental results of two related phenomena, spontaneous hole filling (SPHF) and laser induced hole filling (LIHF), are presented and discussed for several systems: rhodamine 560 perchlorate (R560), rhodamine 640 perchlorate (R640), CV, Pr/sup +3/ and Nd..mu../sup 3/ in either PVOH or PAA. A theoretical model is developed for SPHF. The model invokes a correlated feedback mechanism from the anti-hole, which is able to account for the fact that no line broadening is observed. A tentative model is also presented for the phenomenon of LIHF.

Fearey, B.L.

1986-01-01T23:59:59.000Z

438

Blade System Design Study. Part II, final project report (GEC).  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy's Low Wind Speed Turbine program, Global Energy Concepts LLC (GEC)1 has studied alternative composite materials for wind turbine blades in the multi-megawatt size range. This work in one of the Blade System Design Studies (BSDS) funded through Sandia National Laboratories. The BSDS program was conducted in two phases. In the Part I BSDS, GEC assessed candidate innovations in composite materials, manufacturing processes, and structural configurations. GEC also made recommendations for testing composite coupons, details, assemblies, and blade substructures to be carried out in the Part II study (BSDS-II). The BSDS-II contract period began in May 2003, and testing was initiated in June 2004. The current report summarizes the results from the BSDS-II test program. Composite materials evaluated include carbon fiber in both pre-impregnated and vacuum-assisted resin transfer molding (VARTM) forms. Initial thin-coupon static testing included a wide range of parameters, including variation in manufacturer, fiber tow size, fabric architecture, and resin type. A smaller set of these materials and process types was also evaluated in thin-coupon fatigue testing, and in ply-drop and ply-transition panels. The majority of materials used epoxy resin, with vinyl ester (VE) resin also used for selected cases. Late in the project, testing of unidirectional fiberglass was added to provide an updated baseline against which to evaluate the carbon material performance. Numerous unidirectional carbon fabrics were considered for evaluation with VARTM infusion. All but one fabric style considered suffered either from poor infusibility or waviness of fibers combined with poor compaction. The exception was a triaxial carbon-fiberglass fabric produced by SAERTEX. This fabric became the primary choice for infused articles throughout the test program. The generally positive results obtained in this program for the SAERTEX material have led to its being used in innovative prototype blades of 9-m and 30-m length, as well as other non-wind related structures.

Griffin, Dayton A. (DNV Global Energy Concepts Inc., Seattle, WA)

2009-05-01T23:59:59.000Z

439

Field Derived Emission Factors For Formaldehyde and other Volatile Organic Compounds in FEMA Temporary Housing Units  

SciTech Connect (OSTI)

Sixteen previously occupied temporary housing units (THUs) were studied to assess emissions of volatile organic compounds. The whole trailer emission factors wereevaluated for 36 VOCs including formaldehyde. Indoor sampling was carried out in the THUs located in Purvis staging yard in Mississippi, USA. Indoor temperature andrelative humidity (RH) were also measured in all the trailers during sampling. Indoor temperatures were varied (increased or decreased) in a selection of THUs using theheating, ventilation and air conditioning (HVAC) systems. Indoor temperatures during sampling ranged from 14o C to 33o C, and relative humidity (RH) varied between 35percentand 74percent. Ventilation rates were increased in some trailers using bathroom fans and vents during some of the sampling events. Ventilation rates measured during some aselection of sampling events varied from 0.14 to 4.3 h-1. Steady state indoor formaldehyde concentrations ranged from 10 mu g-m-3 to 1000 mu g-m-3. The formaldehyde concentrations in the trailers were of toxicological significance. The effects of temperature, humidity and ventilation rates were also studied. A linearregression model was built using log of percentage relative humidity, inverse of temperature (in K-1), and inverse log ACH as continuous independent variables, trailermanufacturer as a categorical independent variable, and log of the chemical emission factors as the dependent variable. The coefficients of inverse temperature, log relativehumidity, log inverse ACH with log emission factor were found to be statistically significant for all the samples at the 95percent confidence level. The regression model wasfound to explain about 84percent of the variation in the dependent variable. Most VOC concentrations measured indoors in the Purvis THUs were mostly found to be belowvalues reported in earlier studies by Maddalena et al.,1,2 Hodgson et al.,3 and Hippelein4. Emissions of TMPB-DIB (a plasticizer found in vinyl products) were found to be higher than values reported in comparable housing by Hodgson et al.,3. Emissions of phenol were also found to be slightly higher than values reported in earlier studies1,2,3. This study can assist in retrospective formaldehyde exposure assessments of THUs where estimates of the occupants indoor formaldehyde exposures are needed.

Parthasarathy, Srinandini; Maddalena, Randy L.; Russell, Marion L.; Apte, Michael G.

2010-10-01T23:59:59.000Z

440

Scaleable production and separation of fermentation-derived acetic acid. Final CRADA report.  

SciTech Connect (OSTI)

Half of U.S. acetic acid production is used in manufacturing vinyl acetate monomer (VAM) and is economical only in very large production plants. Nearly 80% of the VAM is produced by methanol carbonylation, which requires high temperatures and exotic construction materials and is energy intensive. Fermentation-derived acetic acid production allows for small-scale production at low temperatures, significantly reducing the energy requirement of the process. The goal of the project is to develop a scaleable production and separation process for fermentation-derived acetic acid. Synthesis gas (syngas) will be fermented to acetic acid, and the fermentation broth will be continuously neutralized with ammonia. The acetic acid product will be recovered from the ammonium acid broth using vapor-based membrane separation technology. The process is summarized in Figure 1. The two technical challenges to success are selecting and developing (1) microbial strains that efficiently ferment syngas to acetic acid in high salt environments and (2) membranes that efficiently separate ammonia from the acetic acid/water mixture and are stable at high enough temperature to facilitate high thermal cracking of the ammonium acetate salt. Fermentation - Microbial strains were procured from a variety of public culture collections (Table 1). Strains were incubated and grown in the presence of the ammonium acetate product and the fastest growing cultures were selected and incubated at higher product concentrations. An example of the performance of a selected culture is shown in Figure 2. Separations - Several membranes were considered. Testing was performed on a new product line produced by Sulzer Chemtech (Germany). These are tubular ceramic membranes with weak acid functionality (see Figure 3). The following results were observed: (1) The membranes were relatively fragile in a laboratory setting; (2) Thermally stable {at} 130 C in hot organic acids; (3) Acetic acid rejection > 99%; and (4) Moderate ammonia flux. The advantages of producing acetic acid by fermentation include its appropriateness for small-scale production, lower cost feedstocks, low energy membrane-based purification, and lower temperature and pressure requirements. Potential energy savings of using fermentation are estimated to be approximately 14 trillion Btu by 2020 from a reduction in natural gas use. Decreased transportation needs with regional plants will eliminate approximately 200 million gallons of diesel consumption, for combined savings of 45 trillion Btu. If the fermentation process captures new acetic acid production, savings could include an additional 5 trillion Btu from production and 7 trillion Btu from transportation energy.

Snyder, S. W.; Energy Systems

2010-02-08T23:59:59.000Z

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441

NETL: Oil & Natural Gas Technologies Reference Shelf - Presentation on  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Increasing the Viscosity of CO2 to Improve EOR Performance Increasing the Viscosity of CO2 to Improve EOR Performance Increasing the Viscosity of CO2 to Improve EOR Performance Authors: D. Xing, NETL; R. Erick, NETL and University of Pittsburgh Department of Chemical and Petroleum Engineering; K. Trickett, J. Eastoe, M. Hollamby, and K.Mutch, Bristol University School of Chemistry; S. Rogers and R. Heenan, ISIS STFC, Rutherford Appleton Laboratory, Chilton, UK; and D. Steytler, University of East Anglia School of Chemical Sciences, Norwich, UK. Venue: May 20, 2009, ISASF-ENSIC 9th International Symposium on Supercritical Fluids, Bordeaux, France, May 18-20, 2009. http://www.issf2009.cnrs.fr/ [external site] Abstract: About 1.5 billion standard cubic feet of CO2 is injected into US oil fields each day, resulting in the recovery of about 200,000 barrels per day of oil, but the low viscosity of CO2 results in viscous fingering and poor volumetric sweep efficiency. If the viscosity of dense CO2 could be increased by a factor of 2-20, much less CO2 would be required to recover the oil. Further, there would be no need for the injection of alternating slugs of water into the reservoir to reduce the relative permeability of the CO2. Researchers have identified two polymeric thickeners for CO2: a fluoroacrylate-styrene copolymer and a vinyl acetate-styrene copolymer. They have also hypothesized that it is possible to increase the viscosity (thicken) dense, high-pressure CO2 via the self-assembly of CO2-soluble surfactants into rod-like micelles. Three semi-fluorinated surfactants have been synthesized in order to test this concept; one with a monovalent cation and a single twin-tail, Na+1((COOCH2C4F8H)2CH2CHSO3)-1, and two with a divalent cation and two twin-tails, Ni+2(((COOCH2C4F8H)2CH2CHSO3)-1)2 and Co+2(((COOCH2C4F8H)2CH2CHSO3)-1)2. Phase behavior results indicate that all three surfactants are soluble to at least 5 wt% in CO2 at 295K and pressures less than 20 MPa. SANS results indicate that only the surfactants with divalent metal ions and two twin tails form cylindrical micelles in CO2. No viscosity enhancement was detected for the surfactant with the monovalent cation. Falling cylinder viscometry results will illustrate the degree of “CO2 thickening” that was achieved by the formation of rod-like micelles at relatively high shear rates. The mobility of the surfactant solution flowing through Berea sandstone was also provided to determine the effectiveness of the thickener at extremely low shear rates characteristic of enhanced oil recovery projects. The performance of the copolymeric and surfactant thickeners will be compared. The strategy for the development of CO2-soluble non-fluorous surfactants capable of forming rod-like micelles will also be presented.

442

Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Temporary Housing Units Title Formaldehyde and Other Volatile Organic Chemical Emissions in Four FEMA Temporary Housing Units Publication Type Journal Article Year of Publication 2009 Authors Maddalena, Randy L., Marion L. Russell, Douglas P. Sullivan, and Michael G. Apte Journal Environmental Science and Technology Volume 43 Start Page Chapter Pagination 5626-5632 Publisher Lawrence Berkeley National Laboratory Abstract Four unoccupied FEMA temporary housing units (THUs) were studied to assess their indoor emissions of volatile organic compounds including formaldehyde. Measurement of whole-THUVOC and aldehyde emission factors (µg h-1 per m2 of floor area) for each of the four THUs were made at FEMA's Purvis MS staging yard using a mass balance approach. Measurements were made in the morning, and again in the afternoon in each THU. Steady-state indoor formaldehydeconcentrations ranged from 378 µg m-3 (0.31ppm) to 632 µg m-3 (0.52 ppm) in the AM, and from 433 µg m-3 (0.35 ppm) to 926 µg m-3 (0.78 ppm) in the PM. THU air exchange rates ranged from 0.15 h-1 to 0.39 h-1. A total of 45 small (approximately 0.025 m2) samples of surface material, 16 types, were collected directly from the four THUs and shipped to Lawrence Berkeley Laboratory. The material samples were analyzed for VOC and aldehyde emissions in small stainless steel chambers using a standard, accurate mass balance method. Quantification of VOCs was done via gas chromatography - mass spectrometry and low molecular weight aldehydes via high performance liquid chromatography. Material specific emission factors (µg h-1 per m2 of material) were quantified. Approximately 80 unique VOCs were tentatively identified in the THU field samples, of which forty-five were quantified either because of their toxicological significance or because their concentrations were high. Whole-trailer and materialspecific emission factors were calculated for 33 compounds. The THU emission factors and those from their component materials were compared against those measured from other types of housing and the materials used in their construction. Whole THU emission factors for most VOCs were typically similar to those from comparative housing. The three exceptions were exceptionally large emissions of formaldehyde and TMPD-DIB (a common plasticizer in vinyl products), and somewhat elevated for phenol. Of these three compounds, formaldehyde was theonly one with toxicological significance at the observed concentrations. Whole THU formaldehyde emissions ranged from 173 to 266 µg m-2 h-1 in the morning and 257 to 347 µg m-2 h-1 in the afternoon. Median formaldehyde emissions in previously studied site-built and manufactured homes were 31 and 45 µg m-2 h-1, respectively. Only one of the composite wood materials that was tested appeared to exceed the HUD formaldehyde emission standard (430 µg/m2 h-1 for particleboard and 130 µg/m2 h-1 for plywood). The high loading factor (materialsurface area divided by THU volume) of composite wood products in the THUs and the low fresh air exchange relative to the material surface area may be responsible for the excessive concentrations observed for some of the VOCs and formaldehyde

443

Inexpensive CO2 Thickening Agents for Improved Mobility Control of CO2 Floods  

SciTech Connect (OSTI)

The objective of this research was the design, synthesis and evaluation of inexpensive, non-fluorous carbon dioxide thickening agents. We followed the same strategy employed in the design of fluorinated CO{sub 2} polymeric thickeners. First, a highly CO{sub 2}-philic, hydrocarbon-based monomer was to be identified. Polymers or oligomers of this monomer were then synthesized. The second step was to design a CO{sub 2}-thickener based on these CO{sub 2}-philic polymers. Two types of thickeners were considered. The first was a copolymer in which the CO{sub 2}-philic monomer was combined with a small proportion of CO{sub 2}-phobic associating groups that could cause viscosity-enhancing intermolecular interactions to occur. The second was a small hydrogen-bonding compound with urea groups in the core to promote intermolecular interactions that would cause the molecules to 'stack' in solution while the arms were composed of the CO{sub 2}-philic oligomers. Although we were not able to develop a viable thickener that exhibited high enough CO{sub 2} solubility at EOR MMP conditions to induce a viscosity increase, we made significant progress in our understanding of CO{sub 2}-soluble compounds that can be used in subsequent studies to design CO{sub 2}-soluble thickeners or CO{sub 2}-soluble surfactant-based foaming agents. These findings are detailed in this final report. In summary, we assessed many polymers and verified that the most CO{sub 2}-soluble oxygenated hydrocarbon polymer is poly(vinyl acetate), PVAc. This is primarily due to the presence of both ether and carbonyl oxygens associated with acetate-rich compounds. In addition to polymers, we also made small acetate-rich molecules that were also capable of associating in solution via the inclusion of hydrogen-bonding groups in hopes of forming viscosity-enhancing macromolecules. Despite the presence of multiple acetate groups in these compounds, which can impart incredible CO{sub 2}-solubility to many compounds, our attempts to make acetate-rich high molecular weight polymers and small hydrogen-bonding compounds did not yield a highly CO{sub 2}-soluble polymer or hydrogen-bonding associative thickener. The conclusions of our molecular modeling calculations confirmed that although acetates are indeed 'CO{sub 2}-philic', nitrogen-containing amines also interact favorably with CO{sub 2} and should also be examined. Therefore we obtained and synthesized many N-rich (e.g. amine-containing) polymers. Unfortunately, we found that the intermolecular polymer-polymer interactions between the amines were so strong that the polymers were essentially insoluble in CO{sub 2}. For the convenience of the reader, a table of all of the polymers evaluated during this research is provided.

Robert Enick; Eric Beckman; Andrew Hamilton

2005-08-31T23:59:59.000Z

444

Reactive Membrane Barriers for Containment of Subsurface Contamination  

SciTech Connect (OSTI)

The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was used in place of deionized water. The performance of high density polyethylene (HDPE) membranes containing Fe{sup 0} was then evaluating using carbon tetrachloride as the target contaminant. Only with a hydrophilic additive (glycerol), was the iron able to extend lag times. Lag times were increased by a factor of 15, but only 2-3% of the iron was used, likely due to formation of oxide precipitates on the iron surface, which slowed the reaction. With thicker membranes and lower carbon tetrachloride concentrations, it is expected that performance will improve. Previous models for reactive membranes were also extended. The lag time is a measurement of when the barrier is breached, but contaminants do slowly leak through prior to the lag time. Thus, two parameters, the leakage and the kill time, were developed to determine when a certain amount of pollutant has escaped (the kill time) or when a given exposure (concentration x time) occurs (the leakage). Finally, a model was developed to explain the behavior of mobile reaction products in reactive barrier membranes. Although the goal of the technology is to avoid such products, it is important to be able to predict how these products will behave. Interestingly, calculations show that for any mobile reaction products, one half of the mass will diffuse into the containment area and one half will escape, assuming that the volumes of the containment area and the surrounding environment are much larger than the barrier membrane. These parameters/models will aid in the effective design of barrier membranes.

William A. Arnold; Edward L. Cussler

2007-02-26T23:59:59.000Z

445

Novel Approaches to Immobilized Heteropoly Acid Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes - Final Report  

SciTech Connect (OSTI)

Original research was carried out at the CSM and the 3M Company from March 2007 through September 2011. The research was aimed at developing new to the world proton electrolyte materials for use in hydrogen fuel cells, in particular with high proton conductivity under hot and dry conditions (>100mS/cm at 120C and 50%RH). Broadly stated, the research at 3M and between 3M and CSM that led to new materials took place in two phases: In the first phase, hydrocarbon membranes that could be formed by photopolymerization of monomer mixtures were developed for the purpose of determining the technical feasibility of achieving the program's Go/No-Go decision conductivity target of >100mS/cm at 120C and 50%RH. In the second phase, attempts were made to extend the achieved conductivity level to fluorinated material systems with the expectation that durability and stability would be improved (over the hydrocarbon material). Highlights included: Multiple lots of an HPA-immobilized photocurable terpolymer derived from di-vinyl-silicotungstic acid (85%), n-butyl acrylate, and hexanediol diacrylate were prepared at 3M and characterized at 3M to exhibit an initial conductivity of 107mS/cm at 120C and 47%RH (PolyPOM85v) using a Bekktech LLC sample fixture and TestEquity oven. Later independent testing by Bekktech LLC, using a different preheating protocol, on the same material, yielded a conductivity value of approximately 20mS/cm at 120C and 50%RH. The difference in measured values is likely to have been the result of an instability of properties for the material or a difference in the measurement method. A dispersed catalyst fuel cell was fabricated and tested using a 150m thick HPA-based photocurable membrane (above, PolyPOM75v), exhibiting a current density of greater than 300mA/cm2 at 0.5V (H2/Air 800/1800sccm 70C/75%RH ambient outlet pressure). Multiple lots of a co-polymer based on poly-trifluorovinylether (TFVE) derived HPA were synthesized and fabricated into films, Generation II films. These materials showed proton conductivities as high as 1 S/cm under high RH conditions. However, the materials suffered from compromised properties due to impure monomers and low molecular weights. Multiple lots of an HPA-immobilized fluoropolymer derived from preformed PVDF-HFP (Generation III films) were synthesized and formed into membranes at 3M and characterized at 3M to exhibit conductivity reaching approximately 75mS/cm at 120C/40%RH using a Bekktech sample fixture and TestEquity oven (optimized membrane, at close of program). Initial fuel cell fabrication and testing for this new class of membrane yielded negative results (no measureable proton conductivity); however, the specific early membrane that was used for the two 5cm2 MEAs was later determined to have <1 mS/cm at 80C/80%RH using the Bekktech fixture, vs. ca. 200 mS/cm at 80C/80%RH for samples of the later-optimized type described above. Future work in this area (beyond the presently reported contract) should include additional attempts to fabricate and test fuel cells based on the later-optimized Generation II and III polymer. A manufacturing study was performed which predicted no difficulties in any future scale up of the materials.

Herring, Andrew M; Horan, James L; Aieta, Niccolo V; Sachdeva, Sonny; Kuo, Mei-Chen; Ren, Hui; Lingutla, Anitha; Emery, Michael; Haugen, Gregory M; Yandrasits, Michael A; Sharma, Neeraj; Coggio, William D; Hamrock, Steven J; Frey, Matthew H

2012-05-20T23:59:59.000Z

446

A STUDY OF FUNDAMENTAL REACTION PATHWAYS FOR TRANSITION METAL ALKYL COMPLEXES. I. THE REACTION OF A NICKEL METHYL COMPLEX WITH ALKYNES. II. THE MECHANISM OF ALDEHYDE FORMATION IN THE REACTION OF A MOLYBDENUM HYDRIDE WITH MOLYBDENUM ALKYLS  

SciTech Connect (OSTI)

I. This study reports the rapid reaction under mild conditions of internal or terminal alkynes with methyl (acetyl~ acetonato) (triphenylphosphine) nickel (1) in either aromatic or ether solvents. In all cases vinylnickel products 2 are formed by insertion of the alkyne into the nickel=methyl bond. These complexes may be converted into a variety of organic products (e.g. alkenes, esters, vinyl halides) by treatment with appropriate reagents. Unsymmetrical alkynes give selectively the one regioisomer with the sterically largest substituent next to the nickel atom. In order to investigate the stereochemistry of the initial insertion, a x-ray diffraction study of the reaction of 1 with diphenylacetylene was carried out. This showed that the vinylnickel complex formed by overall trans insertion was the product of the reaction. Furthermore, subsequent slow isomerization of this complex, to a mixture of it and the corresponding cis isomer, demonstrated that this trans addition product is the kinetic product of the reaction. In studies with other alkynes, the product of trans addition was not always exclusively (or even predominantly) formed, but the ratio of the stereoisomers formed kinetically was substantially different from the thermodynamic ratio. Isotope labeling, added phosphine, and other experiments have allowed us to conclude that the mechanism of this reaction does involve initial cis addition. However, a coordinatively unsaturated vinylnickel complex is initially formed which can undergo rapid, phosphine-catalyzed cis-trans isomerization in competition with its conversion to the isolable phosphine-substituted kinetic reaction products. II. The reaction of CpMo(CO){sub 3}H (1a) with CpMo(CO){sub 3}R (2, R= CH{sub 3}, C{sub 2}H{sub 5}) at 50{degrees} C in THF gives the aldehyde RCHO and the dimers [CpMo(CO){sub 3}]{sub 2} (3a) and [CpMo(CO){sub 2}]{sub 2} (4a). Labeling one of the reactants with a methylcyclopentadienyl ligand it was possible to show that the mixed dimers MeCpMo(CO){sub 3}-(CO){sub 3}MoCp (3b) and MeCpMo(CO){sub 2}{triple_bond}(CO){sub 2}MoCp (4b) are the predominant kinetic products of the reaction. Additionally labeling the carbonyl ligands of 1a with {sup 13}CO led to the conclusion that all three of the carbonyl ligands in 1a end up in the tetracarbonyl dimers 4a if the reaction is carried out under a continuous purge of argon Trapping studies failed to find any evidence for the intermediacy of either [CpMo(CO){sub 3}]{sup -} or [CpMo(CO){sub 3}]{sup +} in this reaction. A mechanism is proposed that involves the initial migration of the alkyl ligand in 2 to CO forming an unsaturated acyl complex which reacts with 1a to give a binuclear complex containing a three center-two electron Mo-H-Mo bond. This complex then selectively looses a carbonyl from the acyl molybdenum, migrates the hydride to that same metal, and forms a metal-metal bond. This binuclear complex with the hydride and acyl ligands on one metal reductively eliminates aldehyde, and migrates a carbonyl ligand, to give 4a directly. The other product 3a is formed by addition of two molecules of free CO to 4a.

Huggins, John Mitchell

1980-06-01T23:59:59.000Z

447

Preparation of NIF Scale Poly ((alpha)-METHYLSTYRENE) Mandrels  

SciTech Connect (OSTI)

All planned National Ignition Facility (NIF) capsule targets except machined beryllium require a plastic mandrel upon which the ablator is applied. This mandrel must at least meet if not exceed the symmetry and surface finish requirements of the final capsule. The mandrels are produced by a two-step process. In the first step a thin-walled poly({alpha}-methylstyrene)(P{alpha}MS) shell is produced using microencapsulation techniques. This shell is overcoated with 10 to 15 {micro}m of glow discharge polymer (GDP) and then pyrolyzed at 300 C. This pyrolysis causes the P{alpha}MS to depolymerize to gas phase monomer that diffuses away through the more thermally stable plasma polymer shell, which retains all the symmetry of the original P{alpha}MS shell. Thus our challenge has been to produce 2-mm-diameter P{alpha}MS shells to serve as these initial ''decomposable'' mandrels that meet or exceed the current NIF design specifications. The basic microencapsulation process used in producing P{alpha}MS mandrels involves using a droplet generator to produce a water droplet (Wl) encapsulated by a fluorobenzene solution of P{alpha}MS (O), this compound droplet being suspended in a stirred aqueous bath (W2). Historically this bath has contained poly(vinyl alcohol) (PVA, 88% hydrolyzed, mol. wt. {approx}25,000 g/mol) to prevent agglomeration of the initially fluid compound droplets. As the compound droplets are stirred in the bath, the fluorobenzene solvent slowly dissipates leaving a solid P{alpha}MS shell. The internal water is subsequently removed by low temperature drying. We found using these techniques that 2-mm shells could easily be produced, however their low mode sphericity did not meet design specifications. In our last published report we detailed how replacement of the PVA with poly(acrylic acid) (PAA) resulted in a major improvement in sphericity due to a greatly increased interfacial tension between the bath and the compound droplet, relative to the use of PVA as the bath additive. P{alpha}MS mandrels produced using PAA in the bath along with slow curing to suppress Marangoni convection that was perturbing the mode 10 to 20 symmetry resulted in 2-mm-diameter P{alpha}MS shells with mode 2 out-of-round{sup 10} (OOR) of {approx}0.5 {micro}m (as well as non-concentricity (NC) < 1%) which meet the capsule design requirements. A representative set of equatorial traces produced by our AFM-based Spheremapper along with the computed power spectrum is shown in Figure 1 for an average shell. Although the power spectrum is at or below the design specification at nearly all modes one can see in the traces some degree of roughness which manifests itself at the very high modes in the power spectrum.

Takagi, M; Cook, R; McQuillan, B; Elsner, F; Stephens, R; Nikroo, A; Paguio, S

2002-06-07T23:59:59.000Z

448

Synthesis of main group, rare-earth, and d{sup 0} metal complexes containing beta-hydrogen  

SciTech Connect (OSTI)

A series of organometallic compounds containing the tris(dimethylsilyl)methyl ligand are described. The potassium carbanions KC(SiHMe{sub 2}){sub 3} and KC(SiHMe{sub 2}){sub 3}TMEDA are synthesized by deprotonation of the hydrocarbon HC(SiHMe{sub 2}){sub 3} with potassium benzyl. KC(SiHMe{sub 2}){sub 3}TMEDA crystallizes as a dimer with two types of three-center-two-electron KH- Si interactions. Homoleptic Ln(III) tris(silylalkyl) complexes containing ?-SiH groups M{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) are synthesized from salt elimination of the corresponding lanthanide halide and 3 equiv. of KC(SiHMe{sub 2}){sub 3}. The related reactions with Sc yield bis(silylalkyl) ate-complexes containing either LiCl or KCl. The divalent calcium and ytterbium compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) are prepared from MI{sub 2} and 2 equiv of KC(SiHMe{sub 2}){sub 3}. The compounds M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and La{C(SiHMe{sub 2}){sub 3}}{sub 3} react with 1 equiv of B(C{sub 6}F{sub 5}){sub 3} to give 1,3- disilacyclobutane {Me2Si-C(SiHMe2)2}2 and MC(SiHMe2)3HB(C6F5)3L, and La{C(SiHMe{sub 2}){sub 3}}{sub 2}HB(C{sub 6}F{sub 5}){sub 3}, respectively. The corresponding reactions of Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu) give the ?-SiH abstraction product [{(Me{sub 2}HSi){sub 3}C}{sub 2}LnC(SiHMe{sub 2}){sub 2}SiMe{sub 2}][HB(C{sub 6}F{sub 5}){sub 3}] (Ln = Y, Lu), but the silene remains associated with the Y or Lu center. The abstraction reactions of M{C(SiHMe{sub 2}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2 }or TMEDA) and Ln{C(SiHMe{sub 2}){sub 3}}{sub 3} (Ln = Y, Lu, La) and 2 equiv of B(C{sub 6}F{sub 5}){sub 3} give the expected dicationic M{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2}L (M = Ca, Yb; L = THF{sub 2} or TMEDA) and dicationic mono(silylalkyl) LnC(SiHMe{sub 2}){sub 3}{HB(C{sub 6}F{sub 5}){sub 3}}{sub 2} (Ln = Y, Lu, La), respectively. Salt metathesis reactions of Cp{sub 2}(NR{sub 2})ZrX (X = Cl, I, OTf; R = t-Bu, SiHMe{sub 2}) and lithium hydrosilazide ultimately afford hydride products Cp{sub 2}(NR{sub 2})ZrH that suggest unusual ?-hydrogen elimination processes. A likely intermediate in one of these reactions, Cp{sub 2}Zr[N(SiHMe{sub 2})t-Bu][N(SiHMe{sub 2}){sub 2}], is isolated under controlled synthetic conditions. Addition of alkali metal salts to this zirconium hydrosilazide compound produces the corresponding zirconium hydride. However as conditions are varied, a number of other pathways are also accessible, including C-H/Si-H dehydrocoupling, ?-abstraction of a CH, and ?-abstraction of a SiH. Our observations suggest that the conversion of (hydrosilazido)zirconocene to zirconium hydride does not follow the classical four-center ?- elimination mechanism. Elimination and abstraction reactions dominate the chemistry of ligands containing ?- hydrogen. In contrast, Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}H and Cp{sub 2}Zr{N(SiHMe{sub 2}){sub 2}}Me undergo selective ?-CH bond activation to yield the azasilazirconacycle Cp{sub 2Zr}{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}}, even though there are reactive ?-hydrogen available for abstraction. The ?-SiH groups in metallacycle provide access to new pathways for sixteen-electron zirconium alkyl compounds, in which Cp{sub 2}Zr{?{sup 2}-N(SiHMe{sub 2})SiHMeCH{sub 2}} undergoes a rare ?-bond metathesis reaction with ethylene. The resulting vinyl intermediate undergoes ?-hydrogen abstraction to reform ethylene and a silanimine zirconium species that reacts with ethylene to give a metallacyclopentane as the isolated product. The pendent ?-SiH in metallocycle also reacts with paraformaldehyde through an uncatalyzed hydrosilylation to form an exocyclic methoxysilyl moiety, while the zirconium-carbon bond in metallocycle is surprisingly inert toward formaldehyde. Still, the Zr-C moiety in metallocycle is available for chemistry, and it interacts with the carbon monoxide and strong electrophile B(C{sub 6}F{sub 5}){sub 3} to provide Cp{sub 2}Zr[?{sup 2}- OC(=CH{sub 2})SiMeHN(SiHMe

Yan, Ka King [Ames Laboratory

2013-05-02T23:59:59.000Z