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Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Low pressure high speed Stirling air engine. Final technical report  

SciTech Connect (OSTI)

The purpose of this project was to design, construct and test a simple, appropriate technology low pressure, high speed, wood-fired Stirling air engine of 100 W output. The final design was a concentric piston/displacer engine of 454 in. bore and 1 in. stroke with a rhombic drive mechanism. The project engine was ultimately completed and tested, using a propane burner for all tests as a matter of convenience. The 100 W aim was exceeded, at atmospheric pressure, over a wide range of engine speed with the maximum power being 112 W at 1150 rpm. A pressure can was constructed to permit pressurization; however the grant funds were running out, and the only pressurized power test attempted was unsuccessful due to seal difficulties. This was a disappointment because numerous tests on the 4 cubic inch engine suggested power would be more than doubled with pressurization at 25 psig. A manifold was designed and constructed to permit operation of the engine over a standard No. 40 pot bellied stove. The engine was run successfully, but at reduced speed and power, over this stove. The project engine started out being rather noisy in operation, but modifications ultimately resulted in a very quiet engine. Various other difficulties and their solutions also are discussed. (LCL)

Ross, M.A.

1980-06-16T23:59:59.000Z

2

High temperature pressure gauge  

DOE Patents [OSTI]

A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

1981-01-01T23:59:59.000Z

3

Incoherent combining of 100-W Yb-fiber laser beams by PTR Bragg Igor V. Ciapurin,  

E-Print Network [OSTI]

nm) irradiation at 100 kW/cm2 . It opens the way to rugged, low-cost, efficient optics for highIncoherent combining of 100-W Yb-fiber laser beams by PTR Bragg grating Igor V. Ciapurin, Leonid B. Glebov, Larissa N. Glebova, Vadim I. Smirnov, Eugeniu V. Rotari School of Optics/CREOL, Univ. of Central

Glebov, Leon

4

High pressure counterflow CHF.  

E-Print Network [OSTI]

This is a report of the experimental results of a program in countercurrent flow critical heat flux. These experiments were performed with Freon 113 at 200 psia in order to model a high pressure water system. An internally ...

Walkush, Joseph Patrick

1975-01-01T23:59:59.000Z

5

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

Morris, D.E.

1993-09-14T23:59:59.000Z

6

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

7

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

8

High pressure furnace  

DOE Patents [OSTI]

A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1993-01-01T23:59:59.000Z

9

High-pressure neutron diffraction  

SciTech Connect (OSTI)

This lecture will cover progress and prospect of applications of high-pressure neutron diffraction techniques to Earth and materials sciences. I will first introduce general high-pressure research topics and available in-situ high-pressure techniques. Then I'll talk about high-pressure neutron diffraction techniques using two types of pressure cells: fluid-driven and anvil-type cells. Lastly, I will give several case studies using these techniques, particularly, those on hydrogen-bearing materials and magnetic transitions.

Xu, Hongwu [Los Alamos National Laboratory

2011-01-10T23:59:59.000Z

10

Electrokinetically pumped high pressure sprays  

DOE Patents [OSTI]

An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.

Schoeniger, Joseph S. (Oakland, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Luke (Pittsford, NY)

2002-01-01T23:59:59.000Z

11

Fundamentals of high pressure adsorption  

SciTech Connect (OSTI)

High-pressure adsorption attracts research interests following the world's attention to alternative fuels, and it exerts essential effect on the study of hydrogen/methane storage and the development of novel materials addressing to the storage. However, theoretical puzzles in high-pressure adsorption hindered the progress of application studies. Therefore, the present paper addresses the major theoretical problems that challenged researchers: i.e., how to model the isotherms with maximum observed in high-pressure adsorption; what is the adsorption mechanism at high pressures; how do we determine the quantity of absolute adsorption based on experimental data. Ideology and methods to tackle these problems are elucidated, which lead to new insights into the nature of high-pressure adsorption and progress in application studies, for example, in modeling multicomponent adsorption, hydrogen storage, natural gas storage, and coalbed methane enrichment, was achieved.

Zhou, Y.P.; Zhou, L. [Tianjin University, Tianjin (China). High Pressure Adsorption Laboratory

2009-12-15T23:59:59.000Z

12

High pressure storage vessel  

DOE Patents [OSTI]

Disclosed herein is a composite pressure vessel with a liner having a polar boss and a blind boss a shell is formed around the liner via one or more filament wrappings continuously disposed around at least a substantial portion of the liner assembly combined the liner and filament wrapping have a support profile. To reduce susceptible to rupture a locally disposed filament fiber is added.

Liu, Qiang

2013-08-27T23:59:59.000Z

13

Steam Oxidation at High Pressure  

SciTech Connect (OSTI)

A first high pressure test was completed: 293 hr at 267 bar and 670{degrees}C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar; Longer term exposures, over a range of temperatures and pressures, are planned to provide information as to the commercial implications of pressure effects; The planned tests are at a higher combination of temperatures and pressures than in the existing literature. A comparison was made with longer-term literature data: The short term exposures are largely consistent with the longer-term corrosion literature; Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points.

Holcomb, Gordon R. [NETL; Carney, Casey [URS

2013-07-19T23:59:59.000Z

14

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

2000-01-01T23:59:59.000Z

15

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based system. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

2003-06-03T23:59:59.000Z

16

Electrokinetic high pressure hydraulic system  

DOE Patents [OSTI]

An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA); Arnold, Don W. (Livermore, CA); Hencken, Kenneth R. (Pleasanton, CA); Schoeniger, Joseph S. (Oakland, CA); Neyer, David W. (Castro Valley, CA)

2001-01-01T23:59:59.000Z

17

High Pressure Hydrogen Materials Compatibility of Piezoelectric...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

18

High pressure ceramic joint  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 4 figures.

Ward, M.E.; Harkins, B.D.

1993-11-30T23:59:59.000Z

19

High pressure ceramic joint  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present joint when used with recuperators increases the use of ceramic components which do not react to highly corrosive gases. Thus, the present joint used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present joint is comprised of a first ceramic member, a second ceramic member, a mechanical locking device having a groove defined in one of the first ceramic member and the second ceramic member. The joint and the mechanical locking device is further comprised of a refractory material disposed in the groove and contacting the first ceramic member and the second ceramic member. The present joint mechanically provides a high strength load bearing joint having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Ward, Michael E. (Poway, CA); Harkins, Bruce D. (San Diego, CA)

1993-01-01T23:59:59.000Z

20

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature,...

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

High pressure synthesis gas conversion. Task 3: High pressure profiles  

SciTech Connect (OSTI)

The purpose of this research project was to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by C. 1jungdahlii. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors.

Not Available

1993-05-01T23:59:59.000Z

22

100 W.D. Funkhouser Building Lexington, Kentucky 40506-0054  

E-Print Network [OSTI]

Abroad! E C U A DOR #12;100 W.D. Funkhouser Building Lexington, Kentucky 40506-0054 From sea. Education Abroad at UK in the Office of International Affairs is the University of Kentucky's comprehensive

MacAdam, Keith

23

High pressure neon arc lamp  

DOE Patents [OSTI]

A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

Sze, Robert C.; Bigio, Irving J.

2003-07-15T23:59:59.000Z

24

High Temperature, High Pressure Devices for Zonal Isolation in...  

Broader source: Energy.gov (indexed) [DOE]

Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells DOE Geothermal Peer...

25

Electokinetic high pressure hydraulic system  

DOE Patents [OSTI]

A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

2000-01-01T23:59:59.000Z

26

High-pressure microhydraulic actuator  

DOE Patents [OSTI]

Electrokinetic ("EK") pumps convert electric to mechanical work when an electric field exerts a body force on ions in the Debye layer of a fluid in a packed bed, which then viscously drags the fluid. Porous silica and polymer monoliths (2.5-mm O.D., and 6-mm to 10-mm length) having a narrow pore size distribution have been developed that are capable of large pressure gradients (250-500 psi/mm) when large electric fields (1000-1500 V/cm) are applied. Flowrates up to 200 .mu.L/min and delivery pressures up to 1200 psi have been demonstrated. Forces up to 5 lb-force at 0.5 mm/s (12 mW) have been demonstrated with a battery-powered DC-DC converter. Hydraulic power of 17 mW (900 psi@ 180 uL/min) has been demonstrated with wall-powered high voltage supplies. The force and stroke delivered by an actuator utilizing an EK pump are shown to exceed the output of solenoids, stepper motors, and DC motors of similar size, despite the low thermodynamic efficiency.

Mosier, Bruce P. (San Francisco, CA) [San Francisco, CA; Crocker, Robert W. (Fremont, CA) [Fremont, CA; Patel, Kamlesh D. (Dublin, CA) [Dublin, CA

2008-06-10T23:59:59.000Z

27

NETL- High-Pressure Combustion Research Facility  

SciTech Connect (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2013-07-08T23:59:59.000Z

28

NETL- High-Pressure Combustion Research Facility  

ScienceCinema (OSTI)

NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

None

2014-06-26T23:59:59.000Z

29

Soot particle aerosol dynamics at high pressure  

SciTech Connect (OSTI)

The authors have used detailed calculations to analyze the coagulation dynamics of a soot aerosol at high pressures (20 and 50 atm). They find that the soot size distribution is altered compared to lower-pressure conditions because the mean free path at high pressures is reduced to the point that the particles are similar in size to the mean free path. At lower pressures the form of the size distribution becomes constant (self-preserving) in time, allowing optical measurements to be easily interpreted. However, the authors find that at pressures above about 5 atm the shape of the size distribution continually changes. As a result, proper and accurate interpretation of optical data at high pressures is more difficult than at lower pressures.

Harris, S.J. (General Motors Research Labs., Warren, MI (USA). Physics Dept.); Kennedy, I.M. (California Univ., Davis, CA (USA). Dept. of Mechanical Engineering)

1989-12-01T23:59:59.000Z

30

Portable high precision pressure transducer system  

DOE Patents [OSTI]

A high precision pressure transducer system is described for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum fluorescent display. 2 figures.

Piper, T.C.; Morgan, J.P.; Marchant, N.J.; Bolton, S.M.

1994-04-26T23:59:59.000Z

31

Portable high precision pressure transducer system  

DOE Patents [OSTI]

A high precision pressure transducer system for checking the reliability of a second pressure transducer system used to monitor the level of a fluid confined in a holding tank. Since the response of the pressure transducer is temperature sensitive, it is continually housed in an battery powered oven which is configured to provide a temperature stable environment at specified temperature for an extended period of time. Further, a high precision temperature stabilized oscillator and counter are coupled to a single board computer to accurately determine the pressure transducer oscillation frequency and convert it to an applied pressure. All of the components are powered by the batteries which during periods of availability of line power are charged by an on board battery charger. The pressure readings outputs are transmitted to a line printer and a vacuum florescent display.

Piper, Thomas C. (Idaho Falls, ID); Morgan, John P. (Idaho Falls, ID); Marchant, Norman J. (Idaho Falls, ID); Bolton, Steven M. (Pocatello, ID)

1994-01-01T23:59:59.000Z

32

High-pressure studies of ammonia hydrates   

E-Print Network [OSTI]

Ammonia and water are major components of many planetary bodies, from comets and icy moons such as Saturn's Titan to the interiors of the planets Neptune and Uranus. Under a range of high pressures and/or low temperatures known ...

Wilson, Craig W.

2014-06-28T23:59:59.000Z

33

High-pressure synthesis of electronic materials   

E-Print Network [OSTI]

High-pressure techniques have become increasingly important in the synthesis of ceramic and metallic solids allowing the discovery of new materials with interesting properties. In this research dense solid oxides have ...

Penny, George B. S.

2010-01-01T23:59:59.000Z

34

High Pressure Hydrogen Tank Manufacturing  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE and SUSTAINABLEIssues

35

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the reinforcing member and having a strengthening member wrapped around the refractory material. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Harkins, Bruce D. (San Diego, CA); Ward, Michael E. (Poway, CA)

1999-01-01T23:59:59.000Z

36

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures.

Harkins, Bruce D. (San Diego, CA); Ward, Michael E. (Poway, CA)

1998-01-01T23:59:59.000Z

37

High pressure ceramic heat exchanger  

DOE Patents [OSTI]

Many recuperators have components which react to corrosive gases and are used in applications where the donor fluid includes highly corrosive gases. These recuperators have suffered reduced life, increased service or maintenance, and resulted in increased cost. The present header assembly when used with recuperators reduces the brittle effect of a portion of the ceramic components. Thus, the present header assembly used with the present recuperator increases the life, reduces the service and maintenance, and reduces the increased cost associated with corrosive action of components used to manufacture recuperators. The present header assembly is comprised of a first ceramic member, a second ceramic member, a strengthening reinforcing member being in spaced relationship to the first ceramic member and the second ceramic member. The header assembly is further comprised of a refractory material disposed in contacting relationship with the first ceramic member, the second ceramic member and the strengthening reinforcing member. The present header assembly provides a high strength load bearing header assembly having good thermal cycling characteristics, good resistance to a corrosive environment and good steady state strength at elevated temperatures. 5 figs.

Harkins, B.D.; Ward, M.E.

1998-09-22T23:59:59.000Z

38

Efficient Spectral Broadening in the 100-W Average Power Regime Using Gas Filled Kagome HC-PCF and Pulse Compression  

E-Print Network [OSTI]

We present nonlinear pulse compression of a high-power SESAM-modelocked thin-disk laser (TDL) using an Ar-filled hypocycloid-core Kagome Hollow-Core Photonic Crystal Fiber (HC-PCF). The output of the modelocked Yb:YAG TDL with 127 W average power, a pulse repetition rate of 7 MHz, and a pulse duration of 740 fs was spectrally broadened 16-fold while propagating in a Kagome HC-PCF containing 13 bar of static Argon gas. Subsequent compression tests performed using 8.4% of the full available power resulted in a pulse duration as short as 88 fs using the spectrally broadened output from the fiber. Compressing the full transmitted power through the fiber (118 W) could lead to a compressed output of >100 W of average power and >100 MW of peak power with an average power compression efficiency of 88%. This simple laser system with only one ultrafast laser oscillator and a simple single-pass fiber pulse compressor, generating both high peak power >100 MW and sub-100-fs pulses at megahertz repetition rate, is very int...

Emaury, Florian; Debord, Benoit; Ghosh, Debashri; Diebold, Andreas; Gerome, Frederic; Suedmeyer, Thomas; Benabid, Fetah; Keller, Ursula

2014-01-01T23:59:59.000Z

39

High pressure, high current, low inductance, high reliability sealed terminals  

DOE Patents [OSTI]

The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

Hsu, John S. (Oak Ridge, TN) [Oak Ridge, TN; McKeever, John W. (Oak Ridge, TN) [Oak Ridge, TN

2010-03-23T23:59:59.000Z

40

High pressure chemistry of substituted acetylenes  

SciTech Connect (OSTI)

High pressure in situ synchrotron x-ray diffraction experiments were performed on substituted polyacetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C{triple_bond}CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-Si{triple_bond}CH] to investigate pressure-induced chemical reactions. The starting samples were the low temperature crystalline phases which persisted metastably at room temperature and polymerized beyond 11 GPa and 26 GPa for TBA and ETMS respectively. These reaction onset pressures are considerably higher than what we observed in the shockwave studies (6.1 GPa for TBA and 6.6 GPa for ETMS). Interestingly, in the case of ETMS, it was observed with fluid ETMS as starting sample, reacts to form a semi-crystalline polymer (crystalline domains corresponding to the low-T phase) at pressures less than {approx}2 GPa. Further characterization using vibrational spectroscopy is in progress.

Chellappa, Raja [Los Alamos National Laboratory; Dattelbaum, Dana [Los Alamos National Laboratory; Sheffield, Stephen [Los Alamos National Laboratory; Robbins, David [Los Alamos National Laboratory

2011-01-25T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

High pressure water jet mining machine  

DOE Patents [OSTI]

A high pressure water jet mining machine for the longwall mining of coal is described. The machine is generally in the shape of a plowshare and is advanced in the direction in which the coal is cut. The machine has mounted thereon a plurality of nozzle modules each containing a high pressure water jet nozzle disposed to oscillate in a particular plane. The nozzle modules are oriented to cut in vertical and horizontal planes on the leading edge of the machine and the coal so cut is cleaved off by the wedge-shaped body.

Barker, Clark R. (Rolla, MO)

1981-05-05T23:59:59.000Z

42

Consider Installing High-Pressure Boilers with BackpressureTurbine...  

Broader source: Energy.gov (indexed) [DOE]

High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of...

43

Automated High-Pressure Titration System with In Situ Infrared...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Abstract: A...

44

Bonfire Tests of High Pressure Hydrogen Storage Tanks | Department...  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks Bonfire Tests of High Pressure Hydrogen Storage Tanks These slides were presented at the International Hydrogen Fuel and...

45

Bonfire Tests of High Pressure Hydrogen Storage Tanks  

Broader source: Energy.gov (indexed) [DOE]

Bonfire Tests of High Pressure Hydrogen Storage Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010Beijing, P.R. China September 27, 2010 Bonfire Tests of High...

46

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

47

Advanced Diagnostics for High Pressure Spray Combustion.  

SciTech Connect (OSTI)

The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

2014-06-01T23:59:59.000Z

48

Dynamics of Low-Pressure and High-Pressure Fuel Cell Air Supply System1  

E-Print Network [OSTI]

comparing the low pressure system with the high- pressure system equipped with a high-speed compressor pressure of the FC that is defined as the pressure at which the reactant hydrogen and oxygen (air) are delivered to the FC stack flow fields. In the case of stored compressed hydrogen the pressure of the cathode

Peng, Huei

49

Viscosities of natural gases at high pressures and high temperatures  

E-Print Network [OSTI]

Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

Viswanathan, Anup

2007-09-17T23:59:59.000Z

50

Polymerization of Formic Acid under High Pressure  

SciTech Connect (OSTI)

We report combined Raman, infrared (IR) and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid under pressure up to 50 GPa. Contrary to the report of Allan and Clark (PRL 82, 3464 (1999)), we find an infinite chain low-temperature Pna2{sub 1} structure consisting of trans molecules to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intra-chain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of the long-range order at pressures above 40 GPa with a large hysteresis at decompression. We attribute this behavior to a three-dimensional polymerization of formic acid.

Goncharov, A F; Manaa, M R; Zaug, J M; Fried, L E; Montgomery, W B

2004-08-23T23:59:59.000Z

51

Engine having a high pressure hydraulic system and low pressure lubricating system  

DOE Patents [OSTI]

An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2000-01-01T23:59:59.000Z

52

High-pressure liquid chromatographic gradient mixer  

DOE Patents [OSTI]

A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

Daughton, C.G.; Sakaji, R.H.

1982-09-08T23:59:59.000Z

53

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

54

High pressure-resistant nonincendive emulsion explosive  

DOE Patents [OSTI]

An improved emulsion explosive composition including hollow microspheres/bulking agents having high density and high strength. The hollow microspheres/bulking agents have true particle densities of about 0.2 grams per cubic centimeter or greater and include glass, siliceous, ceramic and synthetic resin microspheres, expanded minerals, and mixtures thereof. The preferred weight percentage of hollow microspheres/bulking agents in the composition ranges from 3.0 to 10.0 A chlorinated paraffin oil, also present in the improved emulsion explosive composition, imparts a higher film strength to the oil phase in the emulsion. The emulsion is rendered nonincendive by the production of sodium chloride in situ via the decomposition of sodium nitrate, a chlorinated paraffin oil, and sodium perchlorate. The air-gap sensitivity is improved by the in situ formation of monomethylamine perchlorate from dissolved monomethylamine nitrate and sodium perchlorate. The emulsion explosive composition can withstand static pressures to 139 bars and dynamic pressure loads on the order of 567 bars.

Ruhe, Thomas C. (Duquesne, PA); Rao, Pilaka P. (Baghlingampalli, IN)

1994-01-01T23:59:59.000Z

55

A University Consortium on Efficient and Clean High-Pressure...  

Broader source: Energy.gov (indexed) [DOE]

Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines 2010 DOE Vehicle Technologies and...

56

DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project...  

Broader source: Energy.gov (indexed) [DOE]

Delivery High-Pressure Tanks and Analysis Project Review Meeting DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review Meeting On February 8-9, 2005, the Department...

57

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

1992-12-01T23:59:59.000Z

58

Reversible high-pressure carbon nanotube vessel  

E-Print Network [OSTI]

Applying a full pressure loop, i.e., loading and unloading, on a nanocrystal with in situ observation remains a challenge to experimentalists up until now. Using a multiwalled carbon nanotube, we realize the pressure loop ...

Wang, Lifeng

59

Effect of high pressure on structural oddities   

E-Print Network [OSTI]

This thesis describes the effect of pressure on crystal structures that are in some way unusual. The aim was to investigate whether pressure could be used to force these ‘structural oddities’ to conform to more conventional ...

Johnstone, Russell D. L.

2010-01-01T23:59:59.000Z

60

Condensed matter at high shock pressures  

SciTech Connect (OSTI)

Experimental techniques are described for shock waves in liquids: Hugoniot equation-of-state, shock temperature and emission spectroscopy, electrical conductivity, and Raman spectroscopy. Experimental data are reviewed and presented in terms of phenomena that occur at high densities and temperatures in shocked He, Ar, N/sub 2/, CO, SiO/sub 2/-aerogel, H/sub 2/O, and C/sub 6/H/sub 6/. The superconducting properties of Nb metal shocked to 100 GPa (1 Mbar) and recovered intact are discussed in terms of prospects for synthesizing novel, metastable materials. Ultrahigh pressure data for Cu is reviewed in the range 0.3 to 6TPa (3 to 60 Mbar). 56 refs., 9 figs., 1 tab.

Nellis, W.J.; Holmes, N.C.; Mitchell, A.C.; Radousky, H.B.; Hamilton, D.

1985-07-12T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

High pressure fiber optic sensor system  

DOE Patents [OSTI]

The present application provides a fiber optic sensor system. The fiber optic sensor system may include a small diameter bellows, a large diameter bellows, and a fiber optic pressure sensor attached to the small diameter bellows. Contraction of the large diameter bellows under an applied pressure may cause the small diameter bellows to expand such that the fiber optic pressure sensor may measure the applied pressure.

Guida, Renato; Xia, Hua; Lee, Boon K; Dekate, Sachin N

2013-11-26T23:59:59.000Z

62

accessing high pressure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

place, rem... Liva, Gianluigi; Chiani, Marco 2010-01-01 102 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

63

Fundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering, Edited by Maximillian Lackner,  

E-Print Network [OSTI]

[2]. Furthermore, gas turbine combustion pres- sures have been increasing at a near linear rateFundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering of the following chapter is to present an overview of the fundamentals of combustion processes in high pressure

Miller, Richard S.

64

Automated high pressure cell for pressure jump x-ray diffraction  

SciTech Connect (OSTI)

A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M. [Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Terrill, Nick J. [Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom); Rogers, Sarah E. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)

2010-06-15T23:59:59.000Z

65

High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds  

SciTech Connect (OSTI)

The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

John C. Chen; Vinayak N. Kabadi

1998-11-12T23:59:59.000Z

66

Elasticity of Materials at High Pressure  

E-Print Network [OSTI]

implications for lower mantle mineralogy, Earth Planet. Sci.C.R. (1998), Lower mantle mineralogy and the geophysical,in Ultrahigh-Pressure Mineralogy: Physics and Chemistry of

Gleason, Arianna Elizabeth

2010-01-01T23:59:59.000Z

67

High-Pressure Tube Trailers and Tanks  

Broader source: Energy.gov (indexed) [DOE]

bending stress: continuous fiber vessels and vessels made of replicants Conformable tanks require internal stiffeners (ribs) to efficiently support the pressure and minimize...

68

Evidence of Tetragonal Nanodomains in the high pressure polymorph  

SciTech Connect (OSTI)

The pressure induced P4mm {yields} Pm{bar 3}m phase transition in BaTiO{sub 3} perovskite was investigated by x-ray total scattering. The evolution of the structure was analyzed by fitting pair distribution functions over a pressure range from ambient pressure up to 6.85(7) GPa. Evidence for the existence of tetragonal ferroelectric nanodomains at high pressure was found. The average size of the nanodomains in the high-pressure phase decreases with increasing pressure. Extrapolation of the domain size to pressures higher than studied experimentally suggests a disappearance of the ferroelectric domains at about 9.3(5) GPa and a cubic symmetry of BaTiO{sub 3} high-pressure phase.

Ehm, L.; Borkowski, L.A.; Parise J.B.; Ghose, S.; Chen, Z.

2010-12-17T23:59:59.000Z

69

HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS  

SciTech Connect (OSTI)

It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

Vinayak N. Kabadi

1999-02-20T23:59:59.000Z

70

Notes 11. High pressure floating ring seals  

E-Print Network [OSTI]

Floating ring seals for compressors: leakage and force coefficients, seal lock up and effect on rotor stability, recommendations to reduce seal cross-coupled effects. Long oil seals as pressure barriers in industrial mixers: leakage and force...

San Andres, Luis

2009-01-01T23:59:59.000Z

71

High-pressure Magic Angle Spinning Nuclear Magnetic Resonance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other plastic sealing mechanisms...

72

Energy Systems High Pressure Test Laboratory (Fact Sheet), NREL...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

National laboratories Contact Us If you are interested in working with NREL's Energy Systems High Pressure Test Laboratory, please contact: ESIF Manager Carolyn Elam...

73

High-pressure Infrared Spectra of Tal and Lawsonite  

SciTech Connect (OSTI)

We present high-pressure infrared spectra of two geologically important hydrous minerals: talc, Mg3Si4O10(OH)2 and lawsonite, CaAl2Si2O7(OH)2{center_dot}H2O,{center_dot}at room temperature. For lawsonite, our data span the far infrared region from 150 to 550 cm-1 and extend to 25 GPa. We combine our new spectroscopic data with previously published high-pressure mid-infrared and Raman data to constrain the Gr{umlt u}neisen parameter and vibrational density of states under pressure. In the case of talc, we present high-pressure infrared data that span both the mid and far infrared from 150 to 3800 cm-1 covering lattice, silicate, and hydroxyl stretching vibrations to a maximum pressure of 30 GPa. Both phases show remarkable metastability well beyond their nominal maximum thermodynamic stability at simultaneous high-pressure and high-temperature conditions.

Scott,H.; Liu, Z.; Hemley, R.; Williams, Q.

2007-01-01T23:59:59.000Z

74

High pressure discharges in cavities formed by microfabrication techniques  

SciTech Connect (OSTI)

High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. {copyright} {ital 1997 American Institute of Physics.}

Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J. [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)] [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)

1997-07-01T23:59:59.000Z

75

Hydrous silicate melt at high pressure Mainak Mookherjee1  

E-Print Network [OSTI]

LETTERS Hydrous silicate melt at high pressure Mainak Mookherjee1 , Lars Stixrude2 & Bijaya Karki3 The structure and physical properties of hydrous silicate melts and the solubility of water in melts over most in structure to our finding that the water­silicate system becomes increasingly ideal at high pressure: we find

Stixrude, Lars

76

accompanying high-pressure phase: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

pressure cryocooling Abstract High-pressure methods for solving Gruner, Sol M. 58 High-pressure studies of ammonia hydrates Edinburgh, University of - Research Archive Summary:...

77

Neutron scattering at high pressure D. B. McWhan  

E-Print Network [OSTI]

715 Neutron scattering at high pressure D. B. McWhan Room 1D-234, Murray Hill, New Jersey 07974, U scattering at steady-state and pulsed sources are reviewed. The pressure cells available at most neutron 10 GPa have been made. For elastic scattering, a comparison is made between neutron scattering and X

Paris-Sud XI, Université de

78

Chemistry of nitromethane at very high pressure  

SciTech Connect (OSTI)

Decomposition of nitromethane is reported over the range of 115- 180/degree/C and 0.6-8.5 GPa. About 5 /mu/g of nitromethane is compressed with a diamond-anvil cell, heated to the point that reaction occurs, and held typically 10-20 minutes at the reaction temperature. The cell is cooled and the volatile contents of the cell are frozen as a thin layer in vacuo and an infrared absorption spectrum is recorded. The three volatile products observed are N/sub 2/O, CO/sub 2/, and water, with N/sub 2/O production peaking at 1.5 GPa, 135/degree/C, and 35% of NME; CO/sub 2/ production peaking at 3.5 GPa, 135/degree/C, and 65% of NME, and water yields at 20-50% of NME at the highest pressure measured, 8.5 GPa and 175/degree/C. Water yields were difficult to quantify due to background contamination. Results indicate three different reactions for solid NME dependent primarily on the pressure of the reaction, and that fluid NME does not decompose at 0.6 GPa and 175/degree/C, although the solid decomposes readily at 1.1 GPa and 120/degree/C. The authors conclude that, while various decomposition mechanisms are possible, the initial step CH/sub 3/NO/sub 2/ /yields/ /center dot/CH/sub 3/ + /center dot/NO/sub 2/ is very unlikely. 14 refs., 5 figs.

Agnew, S.F.; Swanson, B.I.; Kenney, J.; Kenney, I.

1989-01-01T23:59:59.000Z

79

Digital pressure transducer for use at high temperatures  

DOE Patents [OSTI]

A digital pressure sensor for measuring fluid pressures at relatively high temperatures includes an electrically conducting fiber coupled to the fluid by a force disc that causes tension in the fiber to be a function of fluid pressure. The tension causes changes in the mechanical resonant frequency of the fiber, which is caused to vibrate in a magnetic field to produce an electrical signal from a positive-feedback amplifier at the resonant frequency. A count of this frequency provides a measure of the fluid pressure.

Karplus, Henry H. B. (Hinsdale, IL)

1981-01-01T23:59:59.000Z

80

High pressure water jet cutting of sugar cane  

E-Print Network [OSTI]

performance was uniform before cutting. A liquid filled bourdon tube gauge was used to deter- mine the prescribed operating pressures. The gauge measured the oil pressure of the intensifier which had a 20 to 1 ratio (Figure 4 ) ~ The gauge pressure...HIGH PRESSURE WATER JET CUTTING OF SUGAR CANE A Thesis by THOMAS DONALD VALCO Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1977 Major Subject...

Valco, Thomas Donald

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Energy Systems High Pressure Test Laboratory (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Energy Systems High Pressure Test Laboratory at the Energy Systems Integration Facility. The purpose of the Energy Systems High Pressure Test Laboratory at NREL's Energy Systems Integration Facility (ESIF) is to provide space where high pressure hydrogen components can be safely tested. High pressure hydrogen storage is an integral part of energy storage technology for use in fuel cell and in other distributed energy scenarios designed to effectively utilize the variability inherent with renewable energy sources. The high pressure storage laboratory is co-located with energy storage activities such as ultra-capacitors, super conducting magnetic flywheel and mechanical energy storage systems laboratories for an integrated approach to system development and demonstration. Hazards associated with hydrogen storage at pressures up to 10,000 psi include oxygen displacement, combustion, explosion, and pressurization of room air due to fast release and physical hazards associated with burst failure modes. A critical understanding of component failure modes is essential in developing reliable, robust designs that will minimize failure risk beyond the end of service life. Development of test protocol for accelerated life testing to accurately scale to real world operating conditions is essential for developing regulations, codes and standards required for safe operation. NREL works closely with industry partners in providing support of advanced hydrogen technologies. Innovative approaches to product design will accelerate commercialization into new markets. NREL works with all phases of the product design life cycle from early prototype development to final certification testing. High pressure tests are performed on hydrogen components, primarily for the validation of developing new codes and standards for high pressure hydrogen applications. The following types of tests can be performed: Performance, Component and system level efficiency, Strength of materials and hydrogen compatibility, Safety demonstration, Model validation, and Life cycle reliability.

Not Available

2011-10-01T23:59:59.000Z

82

Performance Assessment of Pressurized Stairs in High Rise Buildings   

E-Print Network [OSTI]

Pressurized stair cases are an important part of the fire safety strategy of high rise buildings. Long egress times are compensated by creating safe environments within egress staircases allowing the displacement time ...

Bellido, Carlos; Quiroz, Antonio; Panizo, Alfonso; Torero, Jose L

2008-12-17T23:59:59.000Z

83

Low Cost, High Efficiency, High Pressure Hydrogen Storage  

SciTech Connect (OSTI)

A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantum’s then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel system’s performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of “smart tanks” that could monitor health of tank thus allowing for lower design safety factor, and the development of “Cool Fuel” technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

Mark Leavitt

2010-03-31T23:59:59.000Z

84

Poisson's Ratio and the Densification of Glass under High Pressure  

SciTech Connect (OSTI)

Because of a relatively low atomic packing density, (C{sub g}) glasses experience significant densification under high hydrostatic pressure. Poisson's ratio ({nu}) is correlated to C{sub g} and typically varies from 0.15 for glasses with low C{sub g} such as amorphous silica to 0.38 for close-packed atomic networks such as in bulk metallic glasses. Pressure experiments were conducted up to 25 GPa at 293 K on silica, soda-lime-silica, chalcogenide, and bulk metallic glasses. We show from these high-pressure data that there is a direct correlation between {nu} and the maximum post-decompression density change.

Rouxel, T.; Ji, H. [Applied Mechanics Laboratory of the University of Rennes 1, LARMAUR, Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France); Hammouda, T. [Laboratoire Magmas et Volcans, CNRS-OPG , Universite Blaise Pascal, 5 rue Kessler, 63038 Clermont-Ferrand cedex (France); Moreac, A. [IPR, CNRS-Universite de Rennes 1, Campus de Beaulieu, 35042 Rennes cedex (France)

2008-06-06T23:59:59.000Z

85

Experimental Analysis of Water Based Drilling Fluid Aging Processes at High Temperature and High Pressure Conditions  

E-Print Network [OSTI]

! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted to the Office of Graduate Studies of Texas A&M University... Temperature and High Pressure Conditions Copyright 2012 Brandon Scott Zigmond ! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted...

Zigmond, Brandon

2012-10-19T23:59:59.000Z

86

Confinement of hydrogen at high pressure in carbon nanotubes  

DOE Patents [OSTI]

A high pressure hydrogen confinement apparatus according to one embodiment includes carbon nanotubes capped at one or both ends thereof with a hydrogen-permeable membrane to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough. A hydrogen confinement apparatus according to another embodiment includes an array of multi-walled carbon nanotubes each having first and second ends, the second ends being capped with palladium (Pd) to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough as a function of palladium temperature, wherein the array of carbon nanotubes is capable of storing hydrogen gas at a pressure of at least 1 GPa for greater than 24 hours. Additional apparatuses and methods are also presented.

Lassila, David H. (Aptos, CA); Bonner, Brian P. (Livermore, CA)

2011-12-13T23:59:59.000Z

87

Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology  

SciTech Connect (OSTI)

Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

2013-11-01T23:59:59.000Z

88

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

89

High-Pressure Flame Speed Measurements  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame and Droplet

90

Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear  

DOE Patents [OSTI]

Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

1997-01-14T23:59:59.000Z

91

Department of Energy Workshop High Pressure Hydrogen Tank Manufacturing  

E-Print Network [OSTI]

Department of Energy Workshop High Pressure Hydrogen Tank Manufacturing Mark Leavitt Quantum Fuel for integrated module including in-tank regulator · Developed high efficiency H2 fuel storage systems for DOE tank efficiency, the highest weight efficiency ever demonstrated, in partnership with Lawrence

92

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells  

Broader source: Energy.gov [DOE]

DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

93

Ultra-high pressure water jet: Baseline report  

SciTech Connect (OSTI)

The ultra-high pressure waterjet technology was being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The ultra-high pressure waterjet technology acts as a cutting tool for the removal of surface substrates. The Husky{trademark} pump feeds water to a lance that directs the high pressure water at the surface to be removed. The safety and health evaluation during the testing demonstration focused on two main areas of exposure. These were dust and noise. The dust exposure was found to be minimal, which would be expected due to the wet environment inherent in the technology, but noise exposure was at a significant level. Further testing for noise is recommended because of the outdoor environment where the testing demonstration took place. In addition, other areas of concern found were arm-hand vibration, ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, fall hazards, slipping hazards, hazards associated with the high pressure water, and hazards associated with air pressure systems.

NONE

1997-07-31T23:59:59.000Z

94

An experimental investigation of high temperature, high pressure paper drying  

E-Print Network [OSTI]

CONCLUSIONS RECOMMENDATIONS 50 51 REFERENCES APPENDIX A EXPERIMENTAL DATA 52 54 VITA 105 vail LIST OF FIGURES Page Fig. 1 Schematic of test facility 13 Fig. 2 Comparison of Texas A&M drying facility operating ranges to other drying processes... of number of drying passes for drying temperatures of 93, 149, and 204 'C (200, 300, and 400 'F), a contact pressure of 1. 4 MPa (200 psi), a basis weight of 25 g/m' (0. 005 lb/ft'), and contact times between 20 to 180 msec with same side drying...

Patel, Kamal Raoji

2012-06-07T23:59:59.000Z

95

Microhole High-Pressure Jet Drill for Coiled Tubing  

SciTech Connect (OSTI)

Tempress Small Mechanically-Assisted High-Pressure Waterjet Drilling Tool project centered on the development of a downhole intensifier (DHI) to boost the hydraulic pressure available from conventional coiled tubing to the level required for high-pressure jet erosion of rock. We reviewed two techniques for implementing this technology (1) pure high-pressure jet drilling and (2) mechanically-assisted jet drilling. Due to the difficulties associated with modifying a downhole motor for mechanically-assisted jet drilling, it was determined that the pure high-pressure jet drilling tool was the best candidate for development and commercialization. It was also determined that this tool needs to run on commingled nitrogen and water to provide adequate downhole differential pressure and to facilitate controlled pressure drilling and descaling applications in low pressure wells. The resulting Microhole jet drilling bottomhole assembly (BHA) drills a 3.625-inch diameter hole with 2-inch coil tubing. The BHA consists of a self-rotating multi-nozzle drilling head, a high-pressure rotary seal/bearing section, an intensifier and a gas separator. Commingled nitrogen and water are separated into two streams in the gas separator. The water stream is pressurized to 3 times the inlet pressure by the downhole intensifier and discharged through nozzles in the drilling head. The energy in the gas-rich stream is used to power the intensifier. Gas-rich exhaust from the intensifier is conducted to the nozzle head where it is used to shroud the jets, increasing their effective range. The prototype BHA was tested at operational pressures and flows in a test chamber and on the end of conventional coiled tubing in a test well. During instrumented runs at downhole conditions, the BHA developed downhole differential pressures of 74 MPa (11,000 psi, median) and 90 MPa (13,000 psi, peaks). The median output differential pressure was nearly 3 times the input differential pressure available from the coiled tubing. In a chamber test, the BHA delivered up to 50 kW (67 hhp) hydraulic power. The tool drilled uncertified class-G cement samples cast into casing at a rate of 0.04 to 0.17 m/min (8 to 33 ft/hr), within the range projected for this tool but slower than a conventional PDM. While the tool met most of the performance goals, reliability requires further improvement. It will be difficult for this tool, as currently configured, to compete with conventional positive displacement downhole motors for most coil tubing drill applications. Mechanical cutters on the rotating nozzle head would improve cutting. This tool can be easily adapted for well descaling operations. A variant of the Microhole jet drilling gas separator was further developed for use with positive displacement downhole motors (PDM) operating on commingled nitrogen and water. A fit-for-purpose motor gas separator was designed and yard tested within the Microhole program. Four commercial units of that design are currently involved in a 10-well field demonstration with Baker Oil Tools in Wyoming. Initial results indicate that the motor gas separators provide significant benefit.

Ken Theimer; Jack Kolle

2007-06-30T23:59:59.000Z

96

Large volume high-pressure cell with supported moissanite anvils  

SciTech Connect (OSTI)

The recently developed moissanite anvil cell (MAC) has become a useful device for achieving both high-pressure and large sample volume in an anvil cell. We describe two improvements in the basic design of the MAC. First, the loading environment has been optimized by centering the load. Second, a variety of supported systems have been examined to provide anvil stability at high loads with large anvils. Sample volumes that are nearly three orders magnitude greater than allowed by conventional diamond anvil cells can be pressurized and characterized at {approx}50 GPa.

Xu, J.; Mao, H.-k.; Hemley, R.J.; Hines , E. (CIW/GL)

2010-11-16T23:59:59.000Z

97

High Pressure Hydrogen Materials Compatibility of Piezoelectric Films  

SciTech Connect (OSTI)

Abstract: Hydrogen is being considered as a next-generation clean burning fuel. However, hydrogen has well known materials issues, including blistering and embrittlement in metals. Piezoelectric materials are used as actuators in hydrogen fuel technology. We present studies of materials compatibility of piezoelectric films in a high pressure hydrogen environment. Absorption of high pressure hydrogen was studied with Elastic Recoil Detection Analysis (ERDA) and Rutherford Back Scattering (RBS) in lead zirconate titanate (PZT) and barium titanate (BTO) thin films. Hydrogen surface degradation in the form of blistering and Pb mixing was also observed.

Alvine, Kyle J.; Shutthanandan, V.; Bennett, Wendy D.; Bonham, Charles C.; Skorski, Daniel C.; Pitman, Stan G.; Dahl, Michael E.; Henager, Charles H.

2010-12-02T23:59:59.000Z

98

Capillary toroid cavity detector for high pressure NMR  

DOE Patents [OSTI]

A Toroid Cavity Detector (TCD) is provided for implementing nuclear magnetic resonance (NMR) studies of chemical reactions under conditions of high pressures and temperatures. A toroid cavity contains an elongated central conductor extending within the toroid cavity. The toroid cavity and central conductor generate an RF magnetic field for NMR analysis. A flow-through capillary sample container is located within the toroid cavity adjacent to the central conductor to subject a sample material flowing through the capillary to a static magnetic field and to enable NMR spectra to be recorded of the material in the capillary under a temperature and high pressure environment.

Gerald, II, Rex E. (Brookfield, IL); Chen, Michael J. (Downers Grove, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Honer Glen, IL); ter Horst, Marc (Chapel Hill, NC)

2007-09-11T23:59:59.000Z

99

Ultra-high pressure water jet: Baseline report; Summary  

SciTech Connect (OSTI)

The Husky{trademark} is an ultra high pressure waterjet cutting tool system. The pump is mounted on a steel tube frame which includes slots for transport by a forklift. The Husky{trademark} features an automatic shutdown for several conditions such as low oil pressure and high oil temperature. Placement of the Husky{trademark} must allow for a three foot clearance on all sides for operation and service access. At maximum continuous operation, the output volume is 7.2 gallons per minute with an output pressure of 40,000 psi. A diesel engine provides power for the system. The safety and health evaluation during the human factors assessment focused on two main areas: noise and dust.

NONE

1997-07-31T23:59:59.000Z

100

Guest disorder and high pressure behavior of argon hydrates  

SciTech Connect (OSTI)

The structure of argon hydrate was studied at ambient pressure and low temperature, and between 1.7 and 4.2 GPa at 295 K. This analysis produced a single Ar guest atom, positionally disordered off-center in the large cages of sII. Above 1.7 GPa Ar clathrate transformed to a mixture of a body-centered orthorhombic filled-ice phase, which can be viewed as a polytype of ice-Ih, and high pressure forms of pure ice. The guest disorder is further substantiated by analysis of the guest to host ratio in this high pressure filled-ice structure. The bulk modulus of Ar filled-ice found to be 11.7 {+-} 0.4 GPa.

Yang, L.; Tulk, C.A.; Klug, D.D.; Chakoumakos, B.C.; Ehm, L.; Molaison, J.J.; Parise, J.B.; Simonson, J.M. (NRCC); (SBU); (ORNL)

2010-03-29T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Combined technologies enable high-pressure slickline work  

SciTech Connect (OSTI)

Operators conducting wireline operations can combine the attributes of the slickline grease head and conventional stuffing box to enable work in gas wells at wellhead pressures above 15,000 psi. Wireline/slickline work in high-pressure wells requires meeting the dual challenges of well control and freedom of movement (up and down) for the lines. In a notable application of the combined-technology technique, an operator offshore Louisiana attempted to conduct wireline operations in an 18,000-ft gas and condensate well with 15,600 psi wellhead pressure, using a standard slickline stuffing box to contain the pressure. The standard equipment could not perform the needed function, which involved several trips to depths of 5,000 ft and 18,000 ft. Using a combined-technology, flow-tube stuffing box, the operator was able to conduct the wireline operation without incident; the control arrangement resulted in use of only 3 gal of lubricating oil throughout the job. Post-job analysis of the packing showed only the minimal wear normally associated with low-pressure wireline operations. Although slickline work can be performed in low-pressure gas wells without using the flow-tube stuffing box, the device and the oil used with it isolate the stuffing-box packing from the dry gases, reducing friction swell. This isolation speeds up the operation and reduces packing wear.

Davis, G. [Halliburton Energy Services Inc., Dallas, TX (United States); West, T. [Halliburton Energy Services Inc., Houma, LA (United States)

1998-10-01T23:59:59.000Z

102

High Temperature, High Pressure Devices for Zonal Isolation in...  

Open Energy Info (EERE)

remotely and autonomous deployable structures for space and our high temperature composite technology developed for downhole applications. These devices offer several...

103

A temperature compensated pressure transducer for high temperature, high pressure applications  

E-Print Network [OSTI]

will work only if the cliange in deflectiou due to tenrperature ivas constant for all pressures. which is uot the case. At 0 ksi, the rliaphragni deflection is constant (zerol for all possible temperatures. At 40 ksi. however, the deflection is much... temperature. 3, 3 Basic Dimensioning After selecting the basic configuration and material for the transclucer body a diaphragm cap, it ivas next necessary to determine the actual defle& tion of the diaphragni and any thermally induced affects. Prior to a...

Lippka, Sandra Margaret

1991-01-01T23:59:59.000Z

104

High-temperature pressure-coupled ultrasonic waveguide  

DOE Patents [OSTI]

A pressure coupled ultrasonic waveguide is provided to which one end may be attached a transducer and at the other end a high temperature material for continuous ultrasonic testing of the material. The ultrasonic signal is coupled from the waveguide into the material through a thin, dry copper foil.

Caines, M.J.

1981-02-11T23:59:59.000Z

105

Dissociation of methane under high pressure Guoying Gao,1,a  

E-Print Network [OSTI]

Dissociation of methane under high pressure Guoying Gao,1,a Artem R. Oganov,2,a Yanming Ma,1,b Hui Received 15 May 2010; accepted 18 August 2010; published online 12 October 2010 Methane is an extremely of methane under extreme conditions are of great fundamental interest. Using the ab initio evolutionary

Oganov, Artem R.

106

Surface roughening of superalloys by high pressure pure waterjet  

SciTech Connect (OSTI)

A high pressure waterjet has been used to study the surface roughening of superalloys as preparation for thermal spraying. Designed experiments for Mar-M 509 and Rene 80 were carried out for the effects of jet pressure and mass of water delivered per unit area. Comparisons were made of several superalloys in terms of erosion, surface roughness and topology. The mechanism of jet erosion of Rene 80 was studied in relation to its metallurgical microstructure. An MCrAlY coating by shrouded plasma spray was made over a waterjet prepared surface with excellent bonding and having an ideally clean interface.

Taylor, T.A. [Praxair Surface Technologies Inc., Indianapolis, IN (United States)

1995-12-31T23:59:59.000Z

107

Experimental Investigation on High-pressure, High-temperature Viscosity of Gas Mixtures  

E-Print Network [OSTI]

Modeling the performance of high-pressure, high-temperature (HPHT) natural gas reservoirs requires the understanding of gas behavior at such conditions. In particular, gas viscosity is an important fluid property that directly affects fluid flow...

Davani, Ehsan

2012-02-14T23:59:59.000Z

108

Aging study of boiling water reactor high pressure injection systems  

SciTech Connect (OSTI)

The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200{degrees}C (2,200{degrees}F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission`s Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed.

Conley, D.A.; Edson, J.L.; Fineman, C.F. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

1995-03-01T23:59:59.000Z

109

High Pressure Burn Rate Measurements on an Ammonium Perchlorate Propellant  

SciTech Connect (OSTI)

High pressure deflagration rate measurements of a unique ammonium perchlorate (AP) based propellant are required to design the base burn motor for a Raytheon weapon system. The results of these deflagration rate measurements will be key in assessing safety and performance of the system. In particular, the system may experience transient pressures on the order of 100's of MPa (10's kPSI). Previous studies on similar AP based materials demonstrate that low pressure (e.g. P < 10 MPa or 1500 PSI) burn rates can be quite different than the elevated pressure deflagration rate measurements (see References and HPP results discussed herein), hence elevated pressure measurements are necessary in order understand the deflagration behavior under relevant conditions. Previous work on explosives have shown that at 100's of MPa some explosives will transition from a laminar burn mechanism to a convective burn mechanism in a process termed deconsolidative burning. The resulting burn rates that are orders-of-magnitude faster than the laminar burn rates. Materials that transition to the deconsolidative-convective burn mechanism at elevated pressures have been shown to be considerably more violent in confined heating experiments (i.e. cook-off scenarios). The mechanisms of propellant and explosive deflagration are extremely complex and include both chemical, and mechanical processes, hence predicting the behavior and rate of a novel material or formulation is difficult if not impossible. In this work, the AP/HTPB based material, TAL-1503 (B-2049), was burned in a constant volume apparatus in argon up to 300 MPa (ca. 44 kPSI). The burn rate and pressure were measured in-situ and used to calculate a pressure dependent burn rate. In general, the material appears to burn in a laminar fashion at these elevated pressures. The experiment was reproduced multiple times and the burn rate law using the best data is B = (0.6 {+-} 0.1) x P{sup (1.05{+-}0.02)} where B is the burn rate in mm/s and P is the pressure in units of MPa. Details of the experimental method, results and data analysis are discussed herein and briefly compared to other AP based materials that have been measured in this apparatus.

Glascoe, E A; Tan, N

2010-04-21T23:59:59.000Z

110

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE andHighWells | Department

111

Modified approaches for high pressure filtration of fine clean coal  

SciTech Connect (OSTI)

Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

1995-12-31T23:59:59.000Z

112

High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates  

E-Print Network [OSTI]

High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates

DeCampo, J A; Raft, P D

1972-01-01T23:59:59.000Z

113

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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114

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2M HILLAdministrationHighHighHigh-Pressure

115

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

116

Thermodynamic properties of hydrocarbon liquids at high pressures and temperatures  

SciTech Connect (OSTI)

Understanding the organic/inorganic interface in the Earth's crust requires values of the thermodynamic properties of hydrocarbon species in crude oil, coal, and natural gas at elevated temperatures and pressures. Values of the apparent standard partial molal Gibbs free energies and enthalpies of formation and the standard partial molal entropies and heat capacities of these organic species can be computed as a function of temperature at 1 bar using the equations of state adopted by Helgeson et al (1991). The pressure dependence of the thermodynamic properties can be calculated from a modified version of the Parameters From Group Contributions (PFGC) equation of state. To improve the accuracy of these predictions, critical evaluation of high-pressure density experiments reported in the literature was used in the present study to characterize b[sub j] as a function of pressure and temperature. The revised PFGC equation of state permits accurate calculation of the standard partial molal volumes of the major hydrocarbon species in the aliphatic, aromatic, and naphthenic fractions of crude oil, as well as fatty acids, phenols, and naphthenic acids at temperatures and pressures to 500 C and 5 kbar. Combining the revised PFGC equation of state and parameters with the standard partial molal properties of these species at one bar and those of aqueous species and minerals permits calculation of the apparent standard partial molal Gibbs Free energies of reaction, and thus equilibrium constants for a wide variety of chemical equilibria among organic liquids, solids, and gases, aqueous species, and minerals at temperatures and pressures characteristic of both diagenetic and low-grade metamorphic processes in the Earth's crust.

Aagaard, P. (Univ. of Oslo (Norway). Dept. of Geology); Oelkers, E.H. (Univ. Paul Sabatier, Toulouse (France). Lab. de Geochimie); Helgeson, H.C. (Univ. of California, Berkeley, CA (United States). Dept. of Geology and Geophysics)

1992-01-01T23:59:59.000Z

117

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications.

Bailey, John M. (Dunlap, IL); Zadoks, Abraham L. (Peoria, IL)

1993-11-30T23:59:59.000Z

118

Intermittently-fed high-pressure gasifier process  

DOE Patents [OSTI]

An improved gasifier is described which is adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications. 3 figures.

Bailey, J.M.; Zadoks, A.L.

1993-11-30T23:59:59.000Z

119

High pressure liquid chromatographic method for CP amide analysis  

SciTech Connect (OSTI)

A method has been developed for the analysis of the 5-carboxamidotetrazolatopentaamminecobalt(III) perchlorate contaminant of the explosive CP (2-(5-cyanotetrazolato)-pentaamminecobalt(III) perchlorate). The analysis utilizes a Zn/Hg reduction of the cobalt (III) complexes to allow a high pressure liquid chromatographic (HPLC) analysis of the reaction products; the product analysis is directly related to the weight percent of impurity present in the explosive. The technique is described and shortcomings pointed out.

Loyola, V. M.; Womelsduff, J. E.

1981-02-01T23:59:59.000Z

120

Toroid cavities as NMR detectors in high pressure probes  

SciTech Connect (OSTI)

A cylindrical toroid cavity has been developed for application as an NMR detector for high sensitivity and high resolution spectroscopy in metal vessel probes. Those probes are used for in situ investigations at high temperature and pressure. Since the transmitted r.f. field is completely confined within the torus, the cavity can be placed inside the pressurized system without magnetic coupling to the metal vessel. Resonance frequencies up to 400 MHz make the toroid cavity detector especially suited for use in {sup 1}H and {sup 19}F spectroscopy. Typically achieved static {sup 1}H linewidths, measured on CHCl{sub 3} using cavities in Be-Cu pressure vessels, are 2.0 Hz. On the basis of theoretical considerations that include the radial dependence of the r.f. field within cylindrical or circular toroid detectors, equations were evolved to predict the signal intensity as a function of the pulse width. The equations precisely describe the deviations from the sinusoidal approximation, which is generally used for signal intensities derived from Helmholtz or solenoid coils.

Woelk, K.; Rathke, J.W.; Klingler, R.J.

1993-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Devices and process for high-pressure magic angle spinning nuclear magnetic resonance  

DOE Patents [OSTI]

A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.

Hoyt, David W; Sears, Jr., Jesse A; Turcu, Romulus V.F.; Rosso, Kevin M; Hu, Jian Zhi

2014-04-08T23:59:59.000Z

122

Practical features of illumination with high pressure sodium lamps  

SciTech Connect (OSTI)

A number of concerns raised about the health effects of high pressure sodium lamps (HPS) are discussed. The notion of a ''natural'' human photic environment based on sunlight is disputed. Humans are better adapted to the ''greenish'' spectral composition of forest light than to direct sunlight. It is ironic that the artificial light source which has received the most disapproval, cool white flourescent lamp, has a spectral composition similar to that of forest light. HPS is also available in a full range of colors. Some successful examples of HPS--from North Division High School, in Milwaukee, Wisconsin, to museum exhibits at National Geographic in Washington--are listed.

Corth, R.

1983-06-01T23:59:59.000Z

123

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame andHigh-Pressure

124

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlameHigh-Pressure MOF

125

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlameHigh-Pressure

126

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A high pressure apparatus constructed for measuring the rates of reactions in liquids under pressures ranging from 1 atm to 2000 atm has been used to measure the complexation kinetics of molybdenum hexacarbonyl reacting with 2,2-bipyridine, 4,4{prime}-dimethyl-2-2{prime}-bipyridine and 4,4{prime}-diphenyl-2-2{prime} bipyridine in toluene. Pentacarbonyl reaction intermediates are created by a 10 nsec flash of frequency tripled Nd:YAG laser light. Measured activation volumes for chelate ligand ring closure indicate a change in mechanism from associative interchange to dissociative interchange as steric hindrance increases. A similar high pressure kinetics study of molybdenum carbonyl complexation by several substituted phenanthrolines is now well advanced that indicates that with the more rigid phenanthroline ligands steric effects from bulky substituents have less effect on the ring closure mechanism than in the case of the bipyridine ligands. An experimental concentration dependence of the fluorescence quantum yield of cresyl violet has been harmonized with previously published contradictory reports. Fluorescence of cresyl violet in various solvents and in micellar systems has also been systematically explored.

Eyring, E.M.

1991-11-25T23:59:59.000Z

127

Design and development of a high resolution differential pressure transducer for use at high temperature and high pressure  

E-Print Network [OSTI]

are multiple diaphragms attached at the edges. Flat and corrugated diaphragms are discussed at length by Giovanni (1982). The three most common detection systems are strain gauges, capacitance gauges, and linear variable differential transformers (LVDT... be necessary to connect the resistor and ratio transformer to. the same secondary coil to balance the voltage of the . two secondary coils. Samplers Inlet Inert Fluid Inlet Pressure Housing Electrical Feedthrough LVDT Coils Magnetic Core Pressure...

Childers, Laren Paul

1984-01-01T23:59:59.000Z

128

High pressure behavior of otavite (CdCo3)  

SciTech Connect (OSTI)

The high-pressure, room temperature behavior of otavite (CdCO{sub 3}) was investigated by angle-dispersive synchrotron radiation powder diffraction up to 40 GPa, Raman spectroscopy up to 23 GPa and quantum mechanical calculations based on density functional theory. The calcite-type structure of CdCO{sub 3} is stable up to at least {approx}19 GPa as shown by Raman spectroscopy. The compression mechanism was obtained from structure refinements against the diffraction data. The quantum mechanical calculations propose a calcite-aragonite phase transition to occur at about 30 GPa. The existence of a pressure-induced phase transition is supported by the Raman and diffraction experiments. Evidence for the transformation is given by broadening of X-ray reflections and external Raman bands starting from about 19 GPa in both experiments.

Minch, R.; Ehm, L.; Seoung, D.H.; Winkler, B.; Knorr, K.; Peters, L.; Borkowski, L.A.; Parise, J.B.; Lee, Y.; Dubrovinsky, L.; Depmeier, W.

2010-08-24T23:59:59.000Z

129

High pressure generation by hot electrons driven ablation  

SciTech Connect (OSTI)

A previous model [Piriz et al. Phys. Plasmas 19, 122705 (2012)] for the ablation driven by the hot electrons generated in collisionless laser-plasma interactions in the framework of shock ignition is revisited. The impact of recent results indicating that for a laser wavelength ? = 0.35 ?m the hot electron temperature ?{sub H} would be independent of the laser intensity I, on the resulting ablation pressure is considered. In comparison with the case when the scaling law ?{sub H}?(I?{sup 2}){sup 1/3} is assumed, the generation of the high pressures needed for driving the ignitor shock may be more demanding. Intensities above 10{sup 17} W/cm{sup 2} would be required for ?{sub H}=25?30 keV.

Piriz, A. R. [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energéticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain)] [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energéticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Piriz, S. A. [Facultad de Ciencias Físicas, Universidad Complutense de Madrid, 28040 Madrid (Spain)] [Facultad de Ciencias Físicas, Universidad Complutense de Madrid, 28040 Madrid (Spain); Tahir, N. A. [GSI Helmholtzzentrum für Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)] [GSI Helmholtzzentrum für Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)

2013-11-15T23:59:59.000Z

130

FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS  

E-Print Network [OSTI]

FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS DETERMINATION DU and Technology, Norway ABSTRACT Pressure drop experiments on natural gas flow at 80 to 120 bar pressure and high of natural gas at typical operating pressures (100-180 bar). At such Reynolds numbers the classical Colebrook

Gudmundsson, Jon Steinar

131

Dislocations and Plasticity in bcc Transition Metals at High Pressure  

SciTech Connect (OSTI)

Using first-principles electronic structure calculations, quantum-based atomistic simulations and atomistically informed dislocation dynamics (DD) simulations, we have studied individual dislocation behavior and the multiscale modeling of single-crystal plasticity in the prototype bcc transition metals Ta, Mo and V under both ambient and high pressure conditions. The primary focus in this work is on the pressure-dependent structure, mobility and interaction of a/2<111> screw dislocations, which dominate the plastic deformation properties of these materials. At the electronic scale, first-principles calculations of elasticity, ideal strength and generalized stacking fault energy surfaces have been used to validate quantum-based multi-ion interatomic potentials. At the atomistic scale, these potentials have been used in flexible Green's function boundary condition simulations to study the core structure, Peierls stress {tau}{sub P}, thermally activated kink-pair formation and mobility below {tau}{sub P}, and phonon-drag mobility above {tau}{sub P}. These results have then been distilled into analytic velocity laws and used directly in predictive microscale DD simulations of flow stress and resolved yield stress over wide ranges of pressure, temperature and strain rate.

Yang, L H; Tang, M; Moriarty, J A

2009-01-23T23:59:59.000Z

132

High pressure low heat rate phosphoric acid fuel cell stack  

SciTech Connect (OSTI)

A high pressure phosphoric acid fuel cell stack assembly is described comprising: (a) a stack of fuel cells for producing electricity, the stack including cathode means, anode means, and heat exchange means; (b) means for delivering pressurized air to the cathode means; (c) means for delivering a hydrogen rich fuel gas to the anode means for electrochemically reacting with oxygen in the pressurized air to produce electricity and water; (d) first conduit means connected to the cathode means for exhausting a mixture of oxygen-depleted air and reaction water from the cathode means; (e) second conduit means connected to the first conduit means for delivering a water fog to the first conduit means for entrainment in the mixture of oxygen-depleted air and reaction water to form a two phase coolant having a gaseous air phase and an entrained water droplet phase; (f) means for circulating the coolant to the heat exchange means to cool the stack solely through vaporization of the water droplet phase in the heat exchange means whereby a mixed gas exhaust of air and water vapor is exhausted from the heat exchange means; and (g) means for heating the mixed gas exhaust and delivering the heated mixed gas exhaust at reformer reaction temperatures to an autothermal reformer in the stack assembly for autothermal reaction with a raw fuel to form the hydrogen rich fuel.

Wertheim, R.J.

1987-07-07T23:59:59.000Z

133

System Study: High-Pressure Core Spray 1998–2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure core spray (HPCS) at 8 U.S. commercial boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCS results.

T. E. Wierman

2013-10-01T23:59:59.000Z

134

System Study: High-Pressure Safety Injection 1998–2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure safety injection system (HPSI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPSI results.

T. E. Wierman

2013-10-01T23:59:59.000Z

135

Low-Cost High-Pressure Hydrogen Generator  

SciTech Connect (OSTI)

Electrolysis of water, particularly in conjunction with renewable energy sources, is potentially a cost-effective and environmentally friendly method of producing hydrogen at dispersed forecourt sites, such as automotive fueling stations. The primary feedstock for an electrolyzer is electricity, which could be produced by renewable sources such as wind or solar that do not produce carbon dioxide or other greenhouse gas emissions. However, state-of-the-art electrolyzer systems are not economically competitive for forecourt hydrogen production due to their high capital and operating costs, particularly the cost of the electricity used by the electrolyzer stack. In this project, Giner Electrochemical Systems, LLC (GES) developed a low cost, high efficiency proton-exchange membrane (PEM) electrolysis system for hydrogen production at moderate pressure (300 to 400 psig). The electrolyzer stack operates at differential pressure, with hydrogen produced at moderate pressure while oxygen is evolved at near-atmospheric pressure, reducing the cost of the water feed and oxygen handling subsystems. The project included basic research on catalysts and membranes to improve the efficiency of the electrolysis reaction as well as development of advanced materials and component fabrication methods to reduce the capital cost of the electrolyzer stack and system. The project culminated in delivery of a prototype electrolyzer module to the National Renewable Energy Laboratory for testing at the National Wind Technology Center. Electrolysis cell efficiency of 72% (based on the lower heating value of hydrogen) was demonstrated using an advanced high-strength membrane developed in this project. This membrane would enable the electrolyzer system to exceed the DOE 2012 efficiency target of 69%. GES significantly reduced the capital cost of a PEM electrolyzer stack through development of low cost components and fabrication methods, including a 60% reduction in stack parts count. Economic analysis indicates that hydrogen could be produced for $3.79 per gge at an electricity cost of $0.05/kWh by the lower-cost PEM electrolyzer developed in this project, assuming high-volume production of large-scale electrolyzer systems.

Cropley, Cecelia C.; Norman, Timothy J.

2008-04-02T23:59:59.000Z

136

Stationary High-Pressure Hydrogen Storage | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage » SearchEnergyDepartmentScopingOverviewFranklin M. Orr,EnergyHigh-Pressure

137

System Study: High-Pressure Coolant Injection 1998-2012  

SciTech Connect (OSTI)

This report presents an unreliability evaluation of the high-pressure coolant injection system (HPCI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCI results.

T. E. Wierman

2013-10-01T23:59:59.000Z

138

Acceptance test procedure for High Pressure Water Jet System  

SciTech Connect (OSTI)

The overall objective of the acceptance test is to demonstrate a combined system. This includes associated tools and equipment necessary to perform cleaning in the 105 K East Basin (KE) for achieving optimum reduction in the level of contamination/dose rate on canisters prior to removal from the KE Basin and subsequent packaging for disposal. Acceptance tests shall include necessary hardware to achieve acceptance of the cleaning phase of canisters. This acceptance test procedure will define the acceptance testing criteria of the high pressure water jet cleaning fixture. The focus of this procedure will be to provide guidelines and instructions to control, evaluate and document the acceptance testing for cleaning effectiveness and method(s) of removing the contaminated surface layer from the canister presently identified in KE Basin. Additionally, the desired result of the acceptance test will be to deliver to K Basins a thoroughly tested and proven system for underwater decontamination and dose reduction. This report discusses the acceptance test procedure for the High Pressure Water Jet.

Crystal, J.B.

1995-05-30T23:59:59.000Z

139

Very low pressure high power impulse triggered magnetron sputtering  

DOE Patents [OSTI]

A method and apparatus are described for very low pressure high powered magnetron sputtering of a coating onto a substrate. By the method of this invention, both substrate and coating target material are placed into an evacuable chamber, and the chamber pumped to vacuum. Thereafter a series of high impulse voltage pulses are applied to the target. Nearly simultaneously with each pulse, in one embodiment, a small cathodic arc source of the same material as the target is pulsed, triggering a plasma plume proximate to the surface of the target to thereby initiate the magnetron sputtering process. In another embodiment the plasma plume is generated using a pulsed laser aimed to strike an ablation target material positioned near the magnetron target surface.

Anders, Andre; Andersson, Joakim

2013-10-29T23:59:59.000Z

140

Smart Onboard Inspection of High Pressure Gas Fuel Cylinders  

SciTech Connect (OSTI)

The use of natural gas as an alternative fuel in automotive applications is not widespread primarily because of the high cost and durability of the composite storage tanks. Tanks manufactured using carbon fiber are desirable in weight critical passenger vehicles because of the low density of carbon fiber. The high strength of carbon fiber also translates to a weight reduction because thinner wall designs are possible to withstand the internal pressure loads. However, carbon fiber composites are prone to impact damage that over the life of the storage tank may lead to an unsafe condition for the vehicle operator. A technique that potentially may be a reliable indication of developing hazardous conditions in composite fuel tanks is imbedded fiber optics. The applicability of this technique to onboard inspection is discussed and results from preliminary lab testing indicate that fiber optic sensors can reliably detect impact damage.

Beshears, D.L.; Starbuck, J.M.

1999-09-27T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b  

E-Print Network [OSTI]

Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b , Shun 2009 Editor: L. Stixrude Keywords: electrical conductivity wadsleyite oxygen fugacity frequency water The electrical conductivity of wadsleyite aggregates has been determined under the broad range of thermodynamic

142

High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases  

DOE Patents [OSTI]

A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

1990-10-16T23:59:59.000Z

143

High-pressure coal fuel processor development. Final report  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

1992-12-01T23:59:59.000Z

144

Pressure Resistance Welding of High Temperature Metallic Materials  

SciTech Connect (OSTI)

Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

2010-10-01T23:59:59.000Z

145

A multi-purpose modular system for high-resolution microscopy at high hydrostatic pressure  

E-Print Network [OSTI]

We have developed a modular system for high-resolution microscopy at high hydrostatic pressure. The system consists of a pressurised cell of volume ~100 microlitres, a temperature controlled holder, a ram and a piston. We have made each of these components in several versions which can be interchanged to allow a wide range of applications. Here, we report two pressure cells with pressure ranges 0.1-700MPa and 0.1-100MPa, which can be combined with hollow or solid rams and pistons. Our system is designed to work with fluorescent samples (using a confocal or epifluorescence microscope), but also allows for transmitted light microscopy via the hollow ram and piston. The system allows precise control of pressure and temperature [-20-70C], as well as rapid pressure quenching. We demonstrate its performance and versatility with two applications: time-resolved imaging of colloidal phase transitions caused by pressure changes between 0.1MPa and 101MPa, and imaging the growth of Escherichia coli bacteria at 50MPa. We ...

Vass, Hugh; Herzig, Eva M; Ward, F Bruce; Clegg, Paul S; Allen, Rosalind J

2009-01-01T23:59:59.000Z

146

GFOC Project results: High Temperature / High Pressure, Hydrogen Tolerant Optical Fiber  

SciTech Connect (OSTI)

Tests results are given for exposure of multimode optical fiber to high temperatures (300 deg. C) and high partial pressure (15 bar) hydrogen. These results demonstrate that fluorine down doped optical fibers are much more hydrogen tolerant than traditional germanium doped multimode optical fibers. Also demonstrated is the similar hydrogen tolerance of carbon coated and non-carbon coated fibers. Model for reversible H2 impact in fiber versus T{sup o}C and H2 pressure is given. These results have significant impact for the longevity of use for distributed temperature sensing applications in harsh environments such as geothermal wells.

E. Burov; A. Pastouret; E. Aldea; B. Overton; F. Gooijer; A. Bergonzo

2012-02-12T23:59:59.000Z

147

On the atomic line profiles in high pressure plasmas  

SciTech Connect (OSTI)

In a previous contribution to this journal [H. P. Stormberg, J. Appl. Phys. 51(4), 1963 (1980)], Stormberg presented an analytical expression for the convolution of Lorentz and Levy line profiles, which models atomic radiative transitions in high pressure plasmas. Unfortunately, the derivations are flawed with errors and the final expression, while correct, is accompanied by misguiding comments about the meaning of the symbols used therein, in particular the “complex error function.” In this paper, we discuss the broadening mechanisms that give rise to Stormberg's model and present a correct derivation of his final result. We will also provide an alternative expression, based on the Faddeeva function, which has decisive computational advantages and emphasizes the real-valuedness of the result. The MATLAB/Octave scripts of our implementation have been made available on the publisher's website for future reference.

Janssen, J. F. J.; Gnybida, M.; Rijke, A. J.; Dijk, J. van [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)] [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands); Suijker, J. L. G. [Philips Lighting R and D Category Professional Lamps, P.O. Box 80020, 5600 JM Eindhoven (Netherlands)] [Philips Lighting R and D Category Professional Lamps, P.O. Box 80020, 5600 JM Eindhoven (Netherlands)

2013-11-14T23:59:59.000Z

148

High pressure studies on nanocrystalline aurivillius oxides lead and mercury chalcogenides;.  

E-Print Network [OSTI]

??The high pressure and high temperature play a vital role in newlineunderstanding the physical properties of the solids including such classes of newlinematerials like semiconductors… (more)

Freny joy K M

2015-01-01T23:59:59.000Z

149

anomalous high-pressure behavior: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

than recently predicted. McMahon, Jeffrey M 2011-01-01 105 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

150

Three precision differential pressure indicators for operation at high temperatures and pressures  

E-Print Network [OSTI]

, the design did have a 7 Pa sensitivity which is especially imoortant as the sensing transformer was located outside the pressure containment. This feature eliminates the need for electrical feedthroughs which usually limit the operating conditions... was constructed and the sensitivity increased to ? 5 -1 2x10 Pa using the same transformer. Based on the designs tested, a new differential pressure indicator was proposed. Using a diaphragm with a linear variable differential transformer outside the pressure...

Osburn, Douglas Clayton

1981-01-01T23:59:59.000Z

151

Preconcentrator with high volume chiller for high vapor pressure particle detection  

SciTech Connect (OSTI)

Apparatus and method for collecting particles of both high and low vapor pressure target materials entrained in a large volume sample gas stream. Large volume active cooling provides a cold air supply which is mixed with the sample gas stream to reduce the vapor pressure of the particles. In embodiments, a chiller cools air from ambient conditions to 0-15.degree. C. with the volumetric flow rate of the cold air supply being at least equal to the volumetric flow rate of the sample gas stream. In further embodiments an adsorption media is heated in at least two stages, a first of which is below a threshold temperature at which decomposition products of the high vapor pressure particle are generated.

Linker, Kevin L

2013-10-22T23:59:59.000Z

152

Equations of state of ice VI and ice VII at high pressure and high temperature  

SciTech Connect (OSTI)

High-pressure H{sub 2}O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H{sub 2}O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V{sub 0} = 14.17(2) cm{sup 3}?mol{sup ?1}, K{sub 0} = 14.05(23) GPa, and ?{sub 0} = 14.6(14) × 10{sup ?5} K{sup ?1} for ice VI and V{sub 0} = 12.49(1) cm{sup 3}?mol{sup ?1}, K{sub 0} = 20.15(16) GPa, and ?{sub 0} = 11.6(5) × 10{sup ?5} K{sup ?1} for ice VII.

Bezacier, Lucile; Hanfland, Michael [European Synchrotron Radiation Facility, 6 rue Jules Horowitz, 38000 Grenoble (France); Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Hervé; Daniel, Isabelle [Laboratoire de Géologie de Lyon, UMR 5276 CNRS, Ecole Normale Supérieure de Lyon – Université Claude Bernard Lyon 1, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex (France)

2014-09-14T23:59:59.000Z

153

High-pressure cell for neutron diffraction with in situ pressure control at cryogenic temperatures  

SciTech Connect (OSTI)

Pressure generation at cryogenic temperatures presents a problem for a wide array of experimental techniques, particularly neutron studies due to the volume of sample required. We present a novel, compact pressure cell with a large sample volume in which load is generated by a bellow. Using a supply of helium gas up to a pressure of 350 bar, a load of up to 78 kN is generated with leak-free operation. In addition, special fiber ports added to the cryogenic center stick allow for in situ pressure determination using the ruby pressure standard. Mechanical stability was assessed using finite element analysis and the dimensions of the cell have been optimized for use with standard cryogenic equipment. Load testing and on-line experiments using NaCl and BiNiO{sub 3} have been done at the WISH instrument of the ISIS pulsed neutron source to verify performance.

Jacobsen, Matthew K.; Ridley, Christopher J.; Bocian, Artur; Kamenev, Konstantin V., E-mail: k.kamenev@ed.ac.uk [School of Engineering and CSEC, University of Edinburgh, Edinburgh (United Kingdom); Kirichek, Oleg; Manuel, Pascal; Khalyavin, Dmitry [ISIS, Rutherford Appleton Laboratory, Harwell Oxford (United Kingdom)] [ISIS, Rutherford Appleton Laboratory, Harwell Oxford (United Kingdom); Azuma, Masaki [Materials and Structures Laboratory, Tokyo Institute of Technology, Tokyo (Japan)] [Materials and Structures Laboratory, Tokyo Institute of Technology, Tokyo (Japan); Attfield, J. Paul [School of Chemistry and CSEC, University of Edinburgh, Edinburgh (United Kingdom)] [School of Chemistry and CSEC, University of Edinburgh, Edinburgh (United Kingdom)

2014-04-15T23:59:59.000Z

154

High Performance Fuel Desing for Next Generation Pressurized Water Reactors  

SciTech Connect (OSTI)

The use of internally and externally cooled annular fule rods for high power density Pressurized Water Reactors is assessed. The assessment included steady state and transient thermal conditions, neutronic and fuel management requirements, mechanical vibration issues, fuel performance issues, fuel fabrication methods and econmic assessment. The investigation was donducted by a team from MIT, Westinghouse, Gamma Engineering, Framatome ANP, and AECL. The analyses led to the conclusion that raising the power density by 50% may be possible with this advanced fuel. Even at the 150% power level, the fuel temperature would be a few hundred degrees lower than the current fuel temperatre. Significant economic and safety advantages can be obtained by using this fuel in new reactors. Switching to this type of fuel for existing reactors would yield safety advantages, but the economic return is dependent on the duration of plant shutdown to accommodate higher power production. The main feasiblity issue for the high power performance appears to be the potential for uneven splitting of heat flux between the inner and outer fuel surfaces due to premature closure of the outer fuel-cladding gap. This could be overcome by using a very narrow gap for the inner fuel surface and/or the spraying of a crushable zirconium oxide film at the fuel pellet outer surface. An alternative fuel manufacturing approach using vobropacking was also investigated but appears to yield lower than desirable fuel density.

Mujid S. Kazimi; Pavel Hejzlar

2006-01-31T23:59:59.000Z

155

High Temperature Electrolysis Pressurized Experiment Design, Operation, and Results  

SciTech Connect (OSTI)

A new facility has been developed at the Idaho National Laboratory for pressurized testing of solid oxide electrolysis stacks. Pressurized operation is envisioned for large-scale hydrogen production plants, yielding higher overall efficiencies when the hydrogen product is to be delivered at elevated pressure for tank storage or pipelines. Pressurized operation also supports higher mass flow rates of the process gases with smaller components. The test stand can accommodate planar cells with dimensions up to 8.5 cm x 8.5 cm and stacks of up to 25 cells. It is also suitable for testing other cell and stack geometries including tubular cells. The pressure boundary for these tests is a water-cooled spool-piece pressure vessel designed for operation up to 5 MPa. Pressurized operation of a ten-cell internally manifolded solid oxide electrolysis stack has been successfully demonstrated up 1.5 MPa. The stack is internally manifolded and operates in cross-flow with an inverted-U flow pattern. Feed-throughs for gas inlets/outlets, power, and instrumentation are all located in the bottom flange. The entire spool piece, with the exception of the bottom flange, can be lifted to allow access to the internal furnace and test fixture. Lifting is accomplished with a motorized threaded drive mechanism attached to a rigid structural frame. Stack mechanical compression is accomplished using springs that are located inside of the pressure boundary, but outside of the hot zone. Initial stack heatup and performance characterization occurs at ambient pressure followed by lowering and sealing of the pressure vessel and subsequent pressurization. Pressure equalization between the anode and cathode sides of the cells and the stack surroundings is ensured by combining all of the process gases downstream of the stack. Steady pressure is maintained by means of a backpressure regulator and a digital pressure controller. A full description of the pressurized test apparatus is provided in this report. Results of initial testing showed the expected increase in open-cell voltage associated with elevated pressure. However, stack performance in terms of area-specific resistance was enhanced at elevated pressure due to better gas diffusion through the porous electrodes of the cells. Some issues such as cracked cells and seals were encountered during testing. Full resolution of these issues will require additional testing to identify the optimum test configurations and protocols.

J.E. O'Brien; X. Zhang; G.K. Housley; K. DeWall; L. Moore-McAteer

2012-09-01T23:59:59.000Z

156

Microdischarge-assisted ignition of dielectric-barrier high-pressure glow discharges  

E-Print Network [OSTI]

in the ignition of high-pressure arc lamps8 and volume dc discharges.6 Here, we employ a hybrid discharge source of uniform, nonequilibrium glow plasmas for a variety of applications at pressures of 100

Raja, Laxminarayan L.

157

An apparatus for studying scintillator properties at high isostatic pressures  

SciTech Connect (OSTI)

We describe the design and operation of a unique hydraulic press for the study of scintillator materials under isostatic pressure. This press, capable of developing a pressure of a gigapascal, consists of a large sample chamber pressurized by a two-stage hydraulic amplifier. The optical detection of the scintillation light emitted by the sample is performed, through a large aperture optical port, by a photodetector located outside the pressure vessel. In addition to providing essential pressure-dependent studies on the emission characteristics of radioluminescent materials, this apparatus is being developed to elucidate the mechanisms behind the recently observed dependency of light-yield nonproportionality on electronic band structure. The variation of the light output of a Tl:CsI crystal under 511-keV gamma excitation and hydrostatic pressure is given as an example.

Gaume, R. M. [College of Optics and Photonics (CREOL) and NanoScience Technology Center, University of Central Florida, Orlando, Florida 32816 (United States); Lam, S.; Gascon, M.; Feigelson, R. S. [Department of Materials Science and Engineering, Stanford University, Stanford, California 94305 (United States); Setyawan, W. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Curtarolo, S. [Department of Mechanical Engineering and Materials Science, Duke University, Durham, North Carolina 27708 (United States)

2013-01-15T23:59:59.000Z

158

Plasma etching of cavities into diamond anvils for experiments at high pressures and high temperatures  

SciTech Connect (OSTI)

We describe a method for precisely etching small cavities into the culets of diamond anvils for the purpose of providing thermal insulation for samples in experiments at high pressures and high temperatures. The cavities were fabricated using highly directional oxygen plasma to reactively etch into the diamond surface. The lateral extent of the etch was precisely controlled to micron accuracy by etching the diamond through a lithographically fabricated tungsten mask. The performance of the etched cavities in high-temperature experiments in which the samples were either laser heated or electrically heated is discussed.

Weir, S.T.; Cynn, H.; Falabella, S.; Evans, W.J.; Aracne-Ruddle, C.; Farber, D.; Vohra, Y.K. (LLNL); (UAB)

2012-10-23T23:59:59.000Z

159

Instrumentation development for neutron scattering at high pressure.  

E-Print Network [OSTI]

??Neutron scattering at extremes of pressure is a powerful tool for studying the response of structural and magnetic properties of materials on microscopic level to… (more)

Fang, Junwei

2012-01-01T23:59:59.000Z

160

Experiment Hazard Class 5.3 High Pressure Vessels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stresses calculated using ASME Code Case 2286 July 17 1998. Verify that pressure relief devices have ASME "UV" certification or documentation of operability tests demonstrating...

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

High voltage ignition of high pressure microwave powered UV light sources  

SciTech Connect (OSTI)

Industrial microwave powered (electrodeless) light sources have been limited to quiescent pressures of {approximately}300 Torr of buffer gas and metal-halide fills. The predominant reason for such restrictions has been the inability to microwave ignite the plasma due to the collisionality of higher pressure fills and/or the electronegativity of halide bulb chemistries. Commercially interesting bulb fills require electric fields for ionization that are often large multiples of the breakdown voltage for air. Many auxiliary ignition methods are evaluated for efficiency and practicality before the choice of a high-voltage system with a retractable external electrode. The scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to its operating point (T{sub e} {approx} 0.5 eV). This process is currently being used in a new generation of lamps, which are using multi-atmospheric excimer laser chemistries and pressure and constituent enhanced metal-halide systems. At the present time, production prototypes produce over 900 W of radiation in a 30 nm band, centered at 308 nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce over 1 kW of radiation in 30 nm wide bands, centered about the wavelength of interest.

Frank, J.D.; Cekic, M.; Wood, C.H. [Fusion U.V. Curing Systems Corp., Gaithersburg, MD (United States)

1997-12-31T23:59:59.000Z

162

The effect of condensate dropout on pressure transient analysis of a high-pressure gas condensate well  

E-Print Network [OSTI]

'or the degree of MASTER OF SCIENCE August 1986 Major Subject : Petr oleum Engineering THE EFFECT OF CONDENSATE DROPOUT ON PRESSURE TRANSIENT ANALYSIS OF A HIGH-PRESSURE GAS CONDENSATE WELL A thesis by FREDERIC JEAN-LOUiS SRIENS Approved as to style... Condensate Well. (August 1986) Frederic Jean~Louis Briens, ingenieur Ecole Centrale Chairman of Advisory Committee: Dr. Ching H. Wu Pressure transient analysis techniques are often used to determine the i'low proper ties of gas wells. Through the analysis...

Briens, Frederic Jean-Louis

1986-01-01T23:59:59.000Z

163

Flash High-Pressure Condensate to Regenerate Low-Pressure Steam  

SciTech Connect (OSTI)

This revised ITP tip sheet on regenerating low-pressure steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

164

Technical and economic evaluation of ten high temperature, high pressure particulate cleanup systems for pressurized fluidized bed combustion  

SciTech Connect (OSTI)

The objective of this analysis was to provide a technical and economic evaluation of the ten high temperature, high pressure (HTHP) systems for the purpose of prioritizing them according to performance, cost, and general viability of achieving commercial status. The scope primarily included reviewing/normalizing test experience to date, normalizing commercial designs, developing normalized capital and operating costs for each system, performing trade-off studies, and performing an evaluation utilizing in-house and outside inputs. The HTHP particulate cleanup system must be capable of the same stringent operating requirements as a conventional system, except it must do so at HTHP conditions. Utilities will demand nearly the same reliability as found in conventional equipment. Regarding particulate cleanup, the system must meet NSPS requirements at the stack, and also meet turbine inlet requirements. The ten devices evaluated were: Electrostatic Precipitator - Cottrell Environmental Sciences (CES); Ceramic Felt Filter - Acurex Corporation; Ceramic Cross Flow Filter - Westinghouse; Shallow Static Granular Bed Filter - Ducon/Westinghouse; Electrostatic Granular Bed Filter - General Electric (GE); Moving Granular Bed Filter - Combustion Power Company (CPC); Dry Plate Scrubber - Air Pollution Technology (APT); Magnetic Granular Bed Filter - Exxon; Electrocyclone - General Electric; and Acoustic Agglomerator - Aerojet/Pennsylvania State University (PSU). The test data for the ten devices were normalized to standard conditions with a reference inlet particle loading and size distribution. The purpose of system design normalization is to provide, for each of the HTHP concepts, a scaled-up commercial design which reflects a consistent design approach. 104 figures, 136 tables.

Rubow, L.N.; Borden, M.; Buchanan, T.L.; Cramp, J.A.C.; Fischer, W.H.; Klett, M.G.; Maruvada, S.M.; Nelson, E.T.; Weinstein, R.E.; Zaharchuk, R.

1984-07-01T23:59:59.000Z

165

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

Experiments have been developed for measuring the rates of chemical reactions liquids and in supercritical Co[sub 2]. A pulsed (Q-switch) Nd:YAG laser at 355 nm was the pump beam for laser flash photolysis studies of molybdenum and tungsten hexacarbonyls undergoing ligand displacement reactions by bidentate chelating agents such as 2,2[prime]-bipyridine in toluene. Experiments were carried out at 0.1 to 150 MPa. In the case of molybdenum complexes, the reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2[prime]-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Similar high pressure flash photolysis experiments with tungsten hexacarbonyl have also been completed. The concentration dependence of the fluorescence and nonradiative decay quantum yields for cresyl violet in several solvent have been reported as well as stability constants for the complexation of lithium ion by four different crown ethers dissolved in a room temperature molten salt.

Eyring, E.M.

1993-06-21T23:59:59.000Z

166

A Flow-Through High-Pressure Electrical Conductance Cell for Determining of Ion Association of Aqueous Electrolyte Solutions at High Temperature and Pressure  

SciTech Connect (OSTI)

A flow-through high-pressure electrical conductance cell was designed and constructed to measure limiting molar conductances and ion association constants of dilute aqueous solutions with high precision at high temperatures and pressures. The basic concept of the cell employs the principle developed at the University of Delaware in 1995, but overall targets higher temperatures (to 600 C) and pressures (to 300 MPa). At present the cell has been tested by measuring aqueous NaCl and LiOH solutions (10{sup {minus}3} to 10{sup {minus}5} mol.kg{sup {minus}1}) to 405 C and 33 MPa with good results.

Bianchi, H.; Ho, P.C.; Palmer, D.A.; Wood, R.H.

1999-09-12T23:59:59.000Z

167

High-pressure gasification of Montana subbituminous coal  

SciTech Connect (OSTI)

A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

Goyal, A.; Bryan, B.; Rehmat, A.

1991-01-01T23:59:59.000Z

168

Materials for High-Pressure Fuel Injection Systems  

SciTech Connect (OSTI)

The high-level goal of this multi-year effort was to facilitate the Advanced Combustion Engine goal of 20% improvement (compared to 2009 baseline) of commercial engine efficiency by 2015. A sub-goal is to increase the reliability of diesel fuel injectors by investigating modelbased scenarios that cannot be achieved by empirical, trial and error methodologies alone. During this three-year project, ORNL developed the methodology to evaluate origins and to record the initiation and propagation of fatigue cracks emanating from holes that were electrodischarge machined (EDM), the method used to form spray holes in fuel injector tips. Both x-ray and neutron-based methods for measuring residual stress at four different research facilities were evaluated to determine which, if any, was most applicable to the fuel injector tip geometry. Owing to the shape and small volumes of material involved in the sack area, residual stress data could only be obtained in the walls of the nozzle a few millimeters back from the tip, and there was a hint of only a small compressive stress. This result was consistent with prior studies by Caterpillar. Residual stress studies were suspended after the second year, reserving the possibility of pursuing this in the future, if and when methodology suitable for injector sacks becomes available. The smooth specimen fatigue behavior of current fuel injector steel materials was evaluated and displayed a dual mode initiation behavior. At high stresses, cracks started at machining flaws in the surface; however, below a critical threshold stress of approximately 800 MPa, cracks initiated in the bulk microstructure, below the surface. This suggests that for the next generation for high-pressure fuel injector nozzles, it becomes increasingly important to control the machining and finishing processes, especially if the stress in the tip approaches or exceeds that threshold level. Fatigue tests were also conducted using EDM notches in the gage sections. Compared to the smooth specimens, EDM notching led to a severe reduction in total fatigue life. A reduction in fatigue life of nearly four orders of magnitude can occur at an EDM notch the approximate size of fuel injector spray holes. Consequently, the initiation and propagation behavior of cracks from small spray holes is relevant for generation of design quality data for the next generation diesel fuel injection devices. This is especially true since the current design methodologies usually rely on the less conservative smooth specimen fatigue testing results, and since different materials can have varying levels of notch fatigue resistance.

Blau, P.; Shyam, A.; Hubbard, C.; Howe, J.; Trejo, R.; Yang, N. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center; Pollard, M. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center

2011-09-30T23:59:59.000Z

169

Structure and elasticity of serpentine at high-pressure Mainak Mookherjee a,  

E-Print Network [OSTI]

volcanoes, high electrical conductivities, magnetic and seismic anomalies. Using theoretical methods, we. Evidence of pressure- induced hydrogen bonding is absent in serpentine, as evident from reduction of O K is the bulk modulus, prime indicates pressure derivatives, and O refers to zero pressure. Our best

Stixrude, Lars

170

Effect of high-pressure on molecular magnetism   

E-Print Network [OSTI]

The effect of pressure on a number of magnetically interesting compounds such as single-molecule magnets and dimeric copper and manganese molecules has been investigated to probe the validity of ambient magneto-structural ...

Prescimone, Alessandro

2010-01-01T23:59:59.000Z

171

Instrumentation development for neutron scattering at high pressure   

E-Print Network [OSTI]

Neutron scattering at extremes of pressure is a powerful tool for studying the response of structural and magnetic properties of materials on microscopic level to applied stresses. However, experimental neutron studies ...

Fang, Junwei

2012-11-29T23:59:59.000Z

172

anultra high pressure: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

c. Y Christian P Burger (i&Iember) Randall Getger ( Member) 5wc Fr. Walter F. Bradley (Head of Department) May 1991 ABSTRACT A Temperature Compensated Pressure Transducer for...

173

Modeling and simulation of a high pressure hydrogen storage tank with dynamic wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

174

Modeling and simulation of a high pressure hydrogen storage tank with Dynamic Wall.  

E-Print Network [OSTI]

??Hydrogen storage is one of the divisions of hydrogen powered vehicles technology. To increase performances of high pressure hydrogen storage tanks, a multilayered design is… (more)

Cumalioglu, Ilgaz

2005-01-01T23:59:59.000Z

175

An in situ tensile test apparatus for polymers in high pressure hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

Alvine, K. J., E-mail: kyle.alvine@pnnl.gov; Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

2014-10-15T23:59:59.000Z

176

An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen  

SciTech Connect (OSTI)

Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

2014-10-10T23:59:59.000Z

177

Split stream boilers for high-temperature/high-pressure topping steam turbine combined cycles  

SciTech Connect (OSTI)

Research and development work on high-temperature and high-pressure (up to 1,500 F TIT and 4,500 psia) topping steam turbines and associated steam generators for steam power plants as well as combined cycle plants is being carried forward by DOE, EPRI, and independent companies. Aeroderivative gas turbines and heavy-duty gas turbines both will require exhaust gas supplementary firing to achieve high throttle temperatures. This paper presents an analysis and examples of a split stream boiler arrangement for high-temperature and high-pressure topping steam turbine combined cycles. A portion of the gas turbine exhaust flow is run in parallel with a conventional heat recovery steam generator (HRSG). This side stream is supplementary fired opposed to the current practice of full exhaust flow firing. Chemical fuel gas recuperation can be incorporated in the side stream as an option. A significant combined cycle efficiency gain of 2 to 4 percentage points can be realized using this split stream approach. Calculations and graphs show how the DOE goal of 60 percent combined cycle efficiency burning natural gas fuel can be exceeded. The boiler concept is equally applicable to the integrated coal gas fuel combined cycle (IGCC).

Rice, I.G. [Rice (I.G.), Spring, TX (United States)

1997-04-01T23:59:59.000Z

178

Development of Designer Diamond Technology for High Pressure High Temperature Experiments in Support of Stockpile Stewardship Program  

SciTech Connect (OSTI)

The role of nitrogen in the fabrication of designer diamond was systematically investigated by adding controlled amount of nitrogen in hydrogen/methane/oxygen plasma. This has led to a successful recipe for reproducible fabrication of designer diamond anvils for high-pressure high-temperature research in support of stockpile stewardship program. In the three-year support period, several designer diamonds fabricated with this new growth chemistry were utilized in high-pressure experiments at UAB and Lawrence Livermore National Laboratory. The designer diamond anvils were utilized in high-pressure studies on heavy rare earth metals, high pressure melting studies on metals, and electrical resistance measurements on iron-based layered superconductors under high pressures. The growth chemistry developed under NNSA support can be adapted for commercial production of designer diamonds.

Vohra, Yogesh, K.

2009-10-28T23:59:59.000Z

179

High Pressure Neutron Powder Diffraction Study of Superhydrated Natrolite  

SciTech Connect (OSTI)

Neutron powder diffraction data were collected on a sample of natrolite and a 1:1 (v/v) mixture of perdeuterated methanol and water at a pressure of 1.87(11) GPa. The natrolite sample was superhydrated, with a water content double that observed at ambient pressure. All of the water deuterium atoms were located and the nature and extent of the hydrogen bonding elucidated for the first time. This has allowed the calculation of bond valence sums for the water oxygen atoms, and from this, it can be deduced that the key energetic factor leading to loss of the additional water molecule upon pressure release is the poor coordination to sodium cations within the pores.

Colligan,M.; Lee, Y.; Vogt, T.; Celestian, A.; Parise, J.; Marshall, W.; Hriljac, J.

2005-01-01T23:59:59.000Z

180

Constant pressure high throughput membrane permeation testing system  

DOE Patents [OSTI]

The disclosure relates to a membrane testing system for individual evaluation of a plurality of planar membranes subjected to a feed gas on one side and a sweep gas on a second side. The membrane testing system provides a pressurized flow of a feed and sweep gas to each membrane testing cell in a plurality of membrane testing cells while a stream of retentate gas from each membrane testing cell is ported by a retentate multiport valve for sampling or venting, and a stream of permeate gas from each membrane testing cell is ported by a permeate multiport valve for sampling or venting. Back pressure regulators and mass flow controllers act to maintain substantially equivalent gas pressures and flow rates on each side of the planar membrane throughout a sampling cycle. A digital controller may be utilized to position the retentate and permeate multiport valves cyclically, allowing for gas sampling of different membrane cells over an extended period of time.

Albenze, Erik J.; Hopkinson, David P.; Luebke, David R.

2014-09-02T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High-temperature fiber optic cubic-zirconia pressure sensor - article no. 124402  

SciTech Connect (OSTI)

There is a critical need for pressure sensors that can operate reliably at high temperatures in many industrial segments such as in the combustion section of gas turbine engines for both transportation and power generation, coal gasifiers, coal fired boilers, etc. Optical-based sensors are particularly attractive for the measurement of a wide variety of physical and chemical parameters in high-temperature and high-pressure industrial environments due to their small size and immunity to electromagnetic interference. A fiber optic pressure sensor utilizing single-crystal cubic zirconia as the sensing element is reported. The pressure response of this sensor has been measured at temperatures up to 1000{sup o}C. Additional experimental results show that cubic zirconia could be used for pressure sensing at temperatures over 1000{sup o}C. This study demonstrates the feasibility of using a novel cubic-zirconia sensor for pressure measurement at high temperatures.

Peng, W.; Pickrell, G.R.; Wang, A.B. [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States)

2005-12-15T23:59:59.000Z

182

Engine with hydraulic fuel injection and ABS circuit using a single high pressure pump  

DOE Patents [OSTI]

An engine system comprises a hydraulically actuated fuel injection system and an ABS circuit connected via a fluid flow passage that provides hydraulic fluid to both the fuel injection system and to the ABS circuit. The hydraulically actuated system includes a high pressure pump. The fluid control passage is in fluid communication with an outlet from the high pressure pump.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2001-01-01T23:59:59.000Z

183

Instrumentation development for magneto-transport and neutron scattering measurements at high pressure and low temperature   

E-Print Network [OSTI]

High pressure, high magnetic field and low temperature techniques are required to investigate magnetic transitions and quantum critical behaviour in different ferromagnetic materials to elucidate how novel forms of ...

Wang, Weiwei

2013-07-01T23:59:59.000Z

184

High-temperature, high-pressure bonding of nested tubular metallic components  

DOE Patents [OSTI]

This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Quinby, Thomas C. (Kingston, TN)

1980-01-01T23:59:59.000Z

185

An Innovative High-Temperature High-Pressure Measurement While Drilling (MWD) Tool  

SciTech Connect (OSTI)

Measurement while drilling (MWD) tools specified to 150 C (302 F) that provide wellbore surveys, real-time inclination, and natural gamma ray detection are a commodity item in the oilfield services industry. MWD tools specified to 175 C (347 F) that routinely demonstrate highly reliable operation are available from only a few service companies. Commercial MWD tools that reliably operate to 200 C (392 F) for extended periods of time and offer features like real-time gamma ray, retrievability, and reseatability are nonexistent. Need for these higher temperature tools will increase as wells become hotter in the search for new oil and gas resources. The goal of this project was to design a retrievable and reseatable high-pressure/high-temperature MWD tool with real-time continuous inclination, vibration detection, annular pressure, and gamma ray detection. This report describes the development of such a tool from concept, through feasibility, and into field testing and preliminary development planning. It describes the challenges encountered in the design of the tool, along with testing results and decisions about the commercial viability of the tool in the configuration in which it was developed. The decision was made not to commercialize the tool developed under this project because of a combination of battery technology problems and modulation power consumption at the required depths.

Brian Boling

2007-06-01T23:59:59.000Z

186

Speed of sound in liquids at high pressure  

E-Print Network [OSTI]

In this paper, a new general formula for the sound speed in adiabatic conditions ( S = const ) has been established. The sound speed depends on the mass density {\\rho} (p,T ) and the internal energy per unit mass E(p,T ), both expressed as functions of the pressure p and the temperature T . This formula has been compared with experimental data on the example of triolein over the pressure range up to 450 MPa. For experimental data, phenomenological approximate formulas have been proposed. Those formulas have two versions, depending on the 2 and 3 parameters. Both versions have been developed with the help of the new expression (Eq.8) for the sound speed. The explicit form of both approximate curves can be regarded as the result of purely phenomenological modeling. However, in this paper, these new analytical expressions have been obtained by applying the heuristic procedure described in Appendix.

P., Kielczynski; S, Piekarski

2013-01-01T23:59:59.000Z

187

Solid Nitrogen at Extreme Conditions of High Pressure and Temperature  

SciTech Connect (OSTI)

We review the phase diagram of nitrogen in a wide pressure and temperature range. Recent optical and x-ray diffraction studies at pressures up to 300 GPa and temperatures in excess of 1000 K have provided a wealth of information on the transformation of molecular nitrogen to a nonmolecular (polymeric) semiconducting and two new molecular phases. These newly found phases have very large stability (metastability) range. Moreover, two new molecular phases have considerably different orientational order from the previously known phases. In the iota phase (unlike most of other known molecular phases), N{sub 2} molecules are orientationally equivalent. The nitrogen molecules in the theta phase might be associated into larger aggregates, which is in line with theoretical predictions on polyatomic nitrogen.

Goncharov, A; Gregoryanz, E

2004-04-05T23:59:59.000Z

188

Electron Matter Wave Interferences at High Vacuum Pressures  

E-Print Network [OSTI]

The ability to trap and guide coherent electrons is gaining importance in fundamental as well as in applied physics. In this regard novel quantum devices are currently developed that may operate under low vacuum conditions. Here we study the loss of electron coherence with increasing background gas pressure. Thereby optionally helium, hydrogen or nitrogen is introduced in a biprism interferometer where the interference contrast is a measure for the coherence of the electrons. The results indicate a constant contrast that is not decreasing in the examined pressure range between $10^{-9}$ mbar and $10^{-4}$ mbar. Therefore no decoherence was observed even under poor vacuum conditions. Due to scattering of the electron beam with background H$_2$-molecules a signal loss of 94 % was determined. The results may lower the vacuum requirements for novel quantum devices with free coherent electrons.

Schütz, Georg; Pooch, Andreas; Stibor, Alexander

2015-01-01T23:59:59.000Z

189

High-Pressure Tube Trailers and Tanks | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGHBraytonMaterials forPressure

190

Heat transfer and pressure drop data for high heat flux densities to water at high subcritical pressures  

E-Print Network [OSTI]

Local surface ooeffioients of heat t-ansfer, overall pressure drop data and mean friction factor are presented for heat flamms up to 3.52106 BtuAr ft2 for water flowing in a nickel tabe isder the following conditions: mass ...

Rohsenow, Warren M.

1951-01-01T23:59:59.000Z

191

Particulate removal from high-temperature, high-pressure combustion gases  

SciTech Connect (OSTI)

The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

Henry, R.F.; Saxena, S.C.; Podolski, W.F.

1983-10-01T23:59:59.000Z

192

Development of a High-Pressure/High-Temperature Downhole Turbine Generator  

SciTech Connect (OSTI)

The objective of this project as originally outlined has been to achieve a viable downhole direct current (DC) power source for extreme high pressure, high temperature (HPHT) environments of >25,000 psi and >250 C. The Phase I investigation posed and answered specific questions about the power requirements, mode of delivery and form factor the industry would like to see for downhole turbine generator tool for the HPHT environment, and noted specific components, materials and design features of that commercial system that will require upgrading to meet the HPHT project goals. During the course of Phase I investigation the scope of the project was HPHT downhole DC power. Phase I also investigated the viability of modifying a commercial expanded, without additional cost expected to the project, to include the addition of HT batteries to the power supply platform.

Timothy F. Price

2007-02-01T23:59:59.000Z

193

High pressure testing of see-through labyrinth seals  

E-Print Network [OSTI]

of labyrinth tooth Impedance Inches of water [UT'] [L) [L) [FT/L] [FT/L] [FT/L] [FT/L] [L] [L] [F] [F] [UT ] [L] [F/L] [L] K;; m, N NT pe PR PS R Direct stiffness Cross-coupled stiffness Stiffness Coefficient Seal Length Stator... the exit-labyrinth seals. Section A-A in Figure 4 gives the location of swirl brakes. Btmor Inlet Annulus Back Pr'asnua Anfsrlur Shaker Btmgars (2 (9 90 ) Thmmomuple Pressure Traraduccfs (2 e sf ) et Prrmnlrf Btrg Pmmum Therm ocormles Transducers...

Picardo, Arthur Michael

2003-01-01T23:59:59.000Z

194

High-Pressure Hydrogen Tanks | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGHBraytonMaterials forPressure Hydrogen

195

Lithium pellet injection into high pressure magnetically confined plasmas  

E-Print Network [OSTI]

The ablation of solid pellets injected into high temperature magnetically confined plasmas is characterized by rapid oscillations in the ablation rate, and the formation of field aligned filaments in the ablatant. High ...

Böse, Brock (Brock Darrel)

2010-01-01T23:59:59.000Z

196

Development test report for the high pressure water jet system nozzles  

SciTech Connect (OSTI)

The high pressure water jet nozzle tests were conducted to identify optimum water pressure, water flow rate, nozzle orifice size and fixture configuration needed to effectively decontaminate empty fuel storage canisters in KE-Basin. This report gives the tests results and recommendations from the these tests.

Takasumi, D.S.

1995-09-28T23:59:59.000Z

197

Alternated high-and low-pressure nitriding of austenitic stainless steel: Mechanisms and results  

E-Print Network [OSTI]

Alternated high- and low-pressure nitriding of austenitic stainless steel: Mechanisms and results G a gas mixture of (N2 /H2):(50/50) in pressure, was applied to stainless-steel AISI 304. In the first or plasma nitriding of metal parts, in par- ticular those made of steel and cast iron, is extensively ap

198

Persistent global proton aurora caused by high solar wind dynamic pressure  

E-Print Network [OSTI]

Persistent global proton aurora caused by high solar wind dynamic pressure K. M. Laundal1 and N] Global images of the proton aurora taken with the SI-12 camera onboard the IMAGE satellite reveal a very direct relationship between the solar wind dynamic pressure and the intensity of the global proton aurora

Bergen, Universitetet i

199

Fermi Surface of Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory  

E-Print Network [OSTI]

Fermi Surface of ­Uranium at Ambient Pressure Gregory S. Boebinger, National High Magnetic Field Laboratory DMR-Award 0654118 DC Field Facility User Program The fermi surface of ­Uranium has been measured surface of alpha-uranium at ambient pressure, Phys. Rev. B Rapid Commun., 80, 241101 (2009). B//c-axis B

Weston, Ken

200

Fractal characterisation of high-pressure and hydrogen-enriched CH4air turbulent premixed flames  

E-Print Network [OSTI]

Fractal characterisation of high-pressure and hydrogen-enriched CH4­air turbulent premixed flames measurements were performed to obtain the flame front images, which were further analyzed for fractal of the flame front curvature as a function of the pressure. Fractal dimension showed a strong dependence

Gülder, �mer L.

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

SOLAR RADIATION PRESSURE EFFECTS ON VERY HIGH-ECCENTRIC FORMATION J. Fontdecaba Baig1  

E-Print Network [OSTI]

SOLAR RADIATION PRESSURE EFFECTS ON VERY HIGH-ECCENTRIC FORMATION FLYING J. Fontdecaba Baig1 , G. M this particular relative motion is the scoop of this paper. Main perturbation in HEO orbits are solar radiation. Key words: formation flying, HEO orbits, solar radiation pressure. 1. INTRODUCTION Formation flying

Paris-Sud XI, Université de

202

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH  

E-Print Network [OSTI]

Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

Stixrude, Lars

203

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

Eyring, E.M.

1992-09-22T23:59:59.000Z

204

APPLICATION OF CERAMICS TO HIGH PRESSURE FUEL SYSTEMS  

SciTech Connect (OSTI)

Diesel fuel systems are facing increased demands as engines with reduced emissions are developed. Injection pressures have increased to provide finer atomization of fuel for more efficient combustion, Figure 1. This increases the mechanical loads on the system and requires tighter clearances between plungers and bores to prevent leakage. At the same time, fuel lubricity has decreased as a byproduct of reducing the sulfur levels in fuel. Contamination of fuel by water and debris is an ever-present problem. For oil-lubricated fuel system components, increased soot loading in the oil results in increased wear rates. Additionally, engine manufacturers are lengthening warranty periods for engines and systems. This combination of factors requires the development of new materials to counteract the harsher tribological environment.

Mandler, Jr., William F.

2000-08-20T23:59:59.000Z

205

Integrated-fin gasket for palm cubic-anvil high pressure apparatus  

SciTech Connect (OSTI)

We described an integrated-fin gasket technique for the palm cubic-anvil apparatus specialized for the high-pressure and low-temperature measurements. By using such a gasket made from the semi-sintered MgO ceramics and the tungsten-carbide anvils of 2.5 mm square top, we successfully generate pressures over 16 GPa at both room and cryogenic temperatures down to 0.5 K. We observed a pressure self-increment for this specific configuration and further characterized the thermally induced pressure variation by monitoring the antiferromagnetic transition temperature of chromium up to 12 GPa. In addition to enlarge the pressure capacity, such a modified gasket also improves greatly the surviving rate of electrical leads hanging the sample inside a Teflon capsule filled with the liquid pressure-transmitting medium. These improvements should be attributed to the reduced extrusion of gasket materials during the initial compression.

Cheng, J.-G. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Matsubayashi, K.; Nagasaki, S.; Hisada, A.; Hirayama, T.; Uwatoko, Y. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Hedo, M. [Faculty of Science, University of Ryukyus, Senbaru, Nishihara, Okinawa 903-0213 (Japan); Kagi, H. [Graduate School of Science, University of Tokyo, 7-3-1, Hongo Bunkyo-Ku, Tokyo 113-0033 (Japan)

2014-09-15T23:59:59.000Z

206

High-pressure cell for neutron reflectometry of supercritical and subcritical fluids at solid interfaces  

SciTech Connect (OSTI)

A new high-pressure cell design for use in neutron reflectometry (NR) for pressures up to 50 MPa and a temperature range of 300 473 K is described. The cell design guides the neutron beam through the working crystal without passing through additional windows or the bulk fluid, which provides for a high neutron transmission, low scattering background, and low beam distortion. The o-ring seal is suitable for a wide range of subcritical and supercritical fluids and ensures high chemical and pressure stability. Wafers with a diameter of 5.08 cm (2 in.) and 5 mm or 10 mm thickness can be used with the cells, depending on the required pressure and momentum transfer range. The fluid volume in the sample cell is very small at about 0.1 ml, which minimizes scattering background and stored energy. The cell design and pressure setup for measurements with supercritical fluids are described. NR data are shown for silicon/silicon oxide and quartz wafers measured against air and subsequently within the high-pressure cell to demonstrate the neutron characteristics of the high-pressure cell. Neutron reflectivity data for supercritical CO2 in contact with quartz and Si/SiO2 wafers are also shown.

Carmichael, Justin R [ORNL; Rother, Gernot [ORNL; Browning, Jim [ORNL; Ankner, John Francis [ORNL; Banuelos, Jose Leo [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David [Ohio State University

2012-01-01T23:59:59.000Z

207

Radiochemical Transformation of High Pressure Methane under Gamma, Electron, and Neutron Irradiation  

E-Print Network [OSTI]

The chemical effects of irradiation on high pressure methane and noble gas mixtures were investigated using gamma, electron beam, and neutron irradiation sources. The gamma source used was the La-140 source from the Nuclear Science Center (NSC...

Clemens, Jeffrey Tyler

2014-05-01T23:59:59.000Z

208

Design strategies for optimizing high burnup fuel in pressurized water reactors  

E-Print Network [OSTI]

This work is focused on the strategy for utilizing high-burnup fuel in pressurized water reactors (PWR) with special emphasis on the full array of neutronic considerations. The historical increase in batch-averaged discharge ...

Xu, Zhiwen, 1975-

2003-01-01T23:59:59.000Z

209

Microplasma Discharges in High Pressure Gases Scaling Towards the Sub-micron Regime  

E-Print Network [OSTI]

Atmospheric pressure microplasmas are uniquely characterized by their very high energy densities and also by their small discharge sizes. These properties allow for unique applications in plasma processing technologies. We have investigated...

Chitre, Aditya Rajeev

2012-02-14T23:59:59.000Z

210

Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators  

SciTech Connect (OSTI)

This revised ITP tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

Not Available

2006-01-01T23:59:59.000Z

211

Innovative fuel designs for high power density pressurized water reactor  

E-Print Network [OSTI]

One of the ways to lower the cost of nuclear energy is to increase the power density of the reactor core. Features of fuel design that enhance the potential for high power density are derived based on characteristics of ...

Feng, Dandong, Ph. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

212

High Pressure PEM Electrolysis: Status, Key Issues, and Challenges  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE and SUSTAINABLEIssuesHigh

213

Design of high pressure metering and regulating stations  

SciTech Connect (OSTI)

Metering and regulating stations effectively serve as the cash registers of the natural gas industry. While the potential for lost revenue resulting from improper design is a serious consideration, it is not the only one. The potential exists for problems such as excessive noise levels, inaccurate reflection of lost and unaccounted-for gas, and numerous potentially hazardous situations. The best time to limit the potential for problems is during the design process. This, together with the critical nature of these stations, dictates that proper design is imperative. Proper design of metering and regulating stations is a constantly changing and extremely complicated subject. There are virtually an infinite number of situations that the designer can encounter in evaluating his design. In view of this, it is impossible to develop a cookbook method of designing these stations that covers all possible situations. The emphasis of this paper is to briefly touch on the major aspects of metering and regulating station design. Steps involved in station design are: 1. Collection of data on the proposed station. 2. Determination of piping configuration. 3. Selection of measurement equipment. 4. Selection of pressure regulating and overpressure protection equipment. 5. Communication of the final design to field personnel.

Rehler, D.A. [Oklahoma Natural Gas Co., Enid, OK (United States)

1995-12-01T23:59:59.000Z

214

Vehicle having hydraulic and power steering systems using a single high pressure pump  

DOE Patents [OSTI]

A vehicle comprises a plurality of wheels attached to a vehicle housing. Also attached to the vehicle housing is a power steering system, including a fluid flow circuit, which is operably coupled to a number of the wheels. An internal combustion engine attached to the vehicle housing is connected to a hydraulically actuated system that includes a high pressure pump. An outlet of the high pressure pump is in fluid communication with the fluid flow circuit.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2001-06-22T23:59:59.000Z

215

DEVELOPMENT OF ASME SECTION X CODE RULES FOR HIGH PRESSURE COMPOSITE HYDROGEN PRESSURE VESSELS WITH NON-LOAD SHARING LINERS  

SciTech Connect (OSTI)

The Boiler and Pressure Vessel Project Team on Hydrogen Tanks was formed in 2004 to develop Code rules to address the various needs that had been identified for the design and construction of up to 15000 psi hydrogen storage vessel. One of these needs was the development of Code rules for high pressure composite vessels with non-load sharing liners for stationary applications. In 2009, ASME approved new Appendix 8, for Section X Code which contains the rules for these vessels. These vessels are designated as Class III vessels with design pressure ranging from 20.7 MPa (3,000 ps)i to 103.4 MPa (15,000 psi) and maximum allowable outside liner diameter of 2.54 m (100 inches). The maximum design life of these vessels is limited to 20 years. Design, fabrication, and examination requirements have been specified, included Acoustic Emission testing at time of manufacture. The Code rules include the design qualification testing of prototype vessels. Qualification includes proof, expansion, burst, cyclic fatigue, creep, flaw, permeability, torque, penetration, and environmental testing.

Rawls, G.; Newhouse, N.; Rana, M.; Shelley, B.; Gorman, M.

2010-04-13T23:59:59.000Z

216

High Temperature and Pressure reactive flows through porous media.  

E-Print Network [OSTI]

of Ceramic Matrix Composite (CMC), used as high temperature material for combustion chamber or stagnation and chemical composition (Gas Chromatograph, Mass Spectrometer, Infra-Red spectrometer) in stationary and transient conditions. The tests on metallic and composite samples have been conducted with N2, CH4, H2+CH4

Boyer, Edmond

217

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect (OSTI)

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

218

THE PLASMA WINDOW: A WINDOWLESS HIGH PRESSURE VACUUM INTERFACE FOR VARIOUS ACCELERATOR APPLICATIONS.  

SciTech Connect (OSTI)

The Plasma Window is a stabilized plasma arc used as an interface between accelerator vacuum and pressurized targets. There is no solid material introduced into the beam and thus it is also capable of transmitting particle beams and electromagnetic radiation with low loss and of sustaining high beam currents without damage. Measurements on a prototype system with a 3 mm diameter opening have shown that pressure differences of more than 2.5 atmospheres can be sustained with an input pressure of {approx} 10{sup -6} Torr. The system is capable of scaling to higher-pressure differences and larger apertures. Various plasma window applications for synchrotron light sources, high power lasers, internal targets, high current accelerators such as the HAWK, ATW, APT, DARHT, spallation sources, as well as for a number of commercial applications, will be discussed.

HERSHCOVITCH,A.I.; JOHNSON,E.D.; LANZA,R.C.

1999-03-29T23:59:59.000Z

219

Predictive modeling and high-pressure-high-temperature synthesis of perovskites containing monovalent silver  

SciTech Connect (OSTI)

The program POTATO, which was developed to model distorted perovskite structures, has been used to assess the stability of hypothetical compositions and guide the synthesis of new materials at high pressures and high temperatures. The initial result of this effort is the synthesis of two new perovskites, Ca{sub 2}NdAgTi{sub 4}O{sub 12} and NdAgTi{sub 2}O{sub 6}, which were synthesized at 14--14.5 GPa and 1000 C using the uniaxial split sphere anvil type press (USSA-2000). Both compounds are perovskites distorted from the ideal cubic structure by octahedral tilting distortions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} contains a random distribution of Ca{sup 2+}/Nd{sup 3+}/Ag{sup +} ions on the A-site, whereas NdAgTi{sub 2}O{sub 6} has a partially ordered distribution of Nd{sup 3+}/Ag{sup +} ions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} adopts the GdFeO{sub 3} structure. NdAgTi{sub 2}O{sub 6} belongs to the tetragonal space group P4/nbm. This structure can be derived from the simple cubic perovskite structure by rotations of the octahedra about the c-axis and partial ordering of Nd{sup 3+} and Ag{sup +} ions into alternating layers, perpendicular to the c-axis.

Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Woodward, P.M. [Brookhaven National Lab., Upton, NY (United States). Physics Dept.] [Brookhaven National Lab., Upton, NY (United States). Physics Dept.

1998-10-01T23:59:59.000Z

220

Behavior of a hollow core photonic crystal fiber under high radial pressure for downhole application  

SciTech Connect (OSTI)

Pressure fiber sensors play an important role in downhole high pressure measurements to withstand long term operation. The purpose of this paper is to present an application of hollow core photonic crystal fiber (HC-PCF) as a high pressure sensor head for downhole application based on dispersion variation. We used a high pressure stainless steel unit to exert pressure on the sensor. The experimental results show that different wavelengths based on sagnac loop interferometer have additive sensitivities from 5?×?10{sup ?5}?nm/psi at 1480?nm to 1.3?×?10{sup ?3}?nm/psi at 1680?nm. We developed a simulation to understand the reason for difference in sensitivity of wavelengths and also the relationship between deformation of HC-PCF and dispersion variation under pressure. For this purpose, by using the finite element method, we investigated the effect of structural variation of HC-PCF on spectral transformation of two linear polarizations under 1000?psi pressure. The simulation and experimental results show exponential decay behavior of dispersion variation from ?3.4?×?10{sup ?6} 1/psi to ?1.3?×?10{sup ?6} 1/psi and from ?5?×?10{sup ?6} 1/psi to ?1.8?×?10{sup ?6} 1/psi, respectively, which were in a good accordance with each other.

Sadeghi, J., E-mail: j-sadeghi@sbu.ac.ir; Chenari, Z.; Ziaee, F. [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Latifi, H., E-mail: latifi@sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, 1983963113 Tehran (Iran, Islamic Republic of); Department of Physics, Shahid Beheshti University, Evin, 1983963113 Tehran (Iran, Islamic Republic of); Santos, J. L., E-mail: josantos@fc.up.pt [INESC Porto—Instituto de Engenharia de Sistemas e Computadores do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Departamento de Física, da Faculdade de Ciências, da Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

2014-02-17T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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221

Working with SRNL - Our Facilities- High Pressure Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched FerromagnetismWaste and MaterialsWenjun1 Table 1.14Working WithGloveboxMetalGammaHigh

222

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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223

High-Pressure MOF Research Yields Structural Insights  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-OrderFlame

224

Progress Report for UNLV High Pressure Science and Engineering Center  

SciTech Connect (OSTI)

In this report we present results of an in-depth analysis of the SP error densities for 29 satellites. These satellites were divided into three groups--Low Earth Orbit (LEO), Near Circular Orbit (NCO) and Highly Eccentric Orbit (HEO). Included in the first group were those satellites with eccentricities of less than 0.2 and perigees below 450km. The second group included satellites in near circular orbits (eccentricities of less than 0.015) and perigees from 700km to 1500km. The third group consisted of those satellites that were in highly eccentric orbits, namely those with eccentricities greater than 0.2. These satellites have perigees far into the thermosphere. Table 1 contains a summary of the orbit characteristics for the 29 satellites. In our study we attempted to unravel and elucidate the networks of relationships above. The satellite groupings and the report are organized in a way that reflects these efforts. We begin in Section 2 with a summary of the methods used in our analysis. One objective in this study was to establish a baseline for future work in satellite orbit propagators. Section 2 contains descriptions of the SP, truth orbits, and the satellite observation data used to establish this baseline. In the report we show how satellite error densities evolve in time up to thirty-six hours. We present error profiles, error histograms, rms errors and 95/9970 confidence limits for the along-track cross-track, and radial axes of motion for satellites in each of the three groupings. We present results of a regression analysis that establishes a physical model of the error densities. We also link the errors in the various regimes to the quality and quantity of the observational data.

Mailhiot, C.; Pepper, D.; Lindle, D.; Nicol, M.

1998-11-20T23:59:59.000Z

225

An RF-only ion-funnel for extraction from high-pressure gases  

E-Print Network [OSTI]

An RF ion-funnel technique has been developed to extract ions from a high-pressure (10 bar) noble-gas environment into vacuum ($10^{-6}$ mbar). Detailed simulations have been performed and a prototype has been developed for the purpose of extracting $^{136}$Ba ions from Xe gas with high efficiency. With this prototype, ions have been extracted for the first time from high-pressure xenon gas and argon gas. Systematic studies have been carried out and compared to the simulations. This demonstration of extraction of ions with mass comparable to that of the gas generating the high-pressure into vacuum has applications to Ba tagging from a Xe-gas time-projection chamber (TPC) for double beta decay as well as to the general problem of recovering trace amounts of an ionized element in a heavy (m$>40$ u) carrier gas.

Thomas Brunner; Daniel Fudenberg; Victor Varentsov; Amanda Sabourov; Giorgio Gratta; Jens Dilling; Ralph DeVoe; David Sinclair; William Fairbank Jr.; Joshua B Albert; David J Auty; Phil S Barbeau; Douglas Beck; Cesar Benitez-Medina; Martin Breidenbach; Guofu F Cao; Christopher Chambers; Bruce Cleveland; Matthew Coon; Adam Craycraft; Timothy Daniels; Sean J Daugherty; Tamar Didberidze; Michelle J Dolinski; Matthew Dunford; Lorenzo Fabris; Jacques Farine; Wolfhart Feldmeier; Peter Fierlinger; Razvan Gornea; Kevin Graham; Mike Heffner; Mitchell Hughes; Michael Jewell; Xiaoshan S Jiang; Tessa N Johnson; Sereres Johnston; Alexander Karelin; Lisa J Kaufman; Ryan Killick; Thomas Koffas; Scott Kravitz; Reiner Kruecken; Alexey Kuchenkov; Krishna S Kumar; Douglas S Leonard; Francois Leonard; Caio Licciardi; Yi-Hsuan H Lin; Jiajie Ling; Ryan MacLellan; Michael G Marino; Brian Mong; David Moore; Allen Odian; Igor Ostrovskiy; Christian Ouellet; Andreas Piepke; Andrea Pocar; Fabrice Retiere; Peter C Rowson; Maria P Rozo; Alexis Schubert; Erica Smith; Victor Stekhanov; Michal Tarka; Tamer Tolba; Delia Tosi; Karl Twelker; Jean-Luc L Vuilleumier; Josiah Walton; Timothy Walton; Manuel Weber; Liangjian J Wen; Ubi Wichoski; Liang Yang; Yung-Ruey Yen

2014-12-03T23:59:59.000Z

226

Development of a High Pressure/High Temperature Down-hole Turbine Generator  

SciTech Connect (OSTI)

As oil & natural gas deposits become more difficult to obtain by conventional means, wells must extend to deeper more heat-intensive environments. The technology of the drilling equipment required to reach these depths has exceeded the availability of electrical power sources needed to operate these tools. Historically, logging while drilling (LWD) and measure while drilling (MWD) devices utilized a wireline to supply power and communication from the operator to the tool. Lithium ion batteries were used in scenarios where a wireline was not an option, as it complicated operations. In current downhole applications, lithium ion battery (LIB) packs are the primary source for electrical power. LIB technology has been proven to supply reliable downhole power at temperatures up to 175 °C. Many of the deeper well s reach ambient temperatures above 200 °C, creating an environment too harsh for current LIB technology. Other downfalls of LIB technology are cost, limitations on charge cycles, disposal issues and possible safety hazards including explosions and fires. Downhole power generation can also be achieved by utilizing drilling fluid flow and converting it to rotational motion. This rotational motion can be harnessed to spin magnets around a series of windings to produce power proportional to the rpm experienced by the driven assembly. These generators are, in most instances, driven by turbine blades or moyno-based drilling fluid pumps. To date, no commercially available downhole power generators are capable of operating at ambient temperatures of 250 °C. A downhole power g enerator capable of operation in a 250 °C and 20,000 psi ambient environment will be an absolute necessity in the future. Dexter Magnetic Technologies’ High-Pressure High-Temperature (HPHT) Downhole Turbine Generator is capable of operating at 250 °C and 20, 000 psi, but has not been tested in an actual drilling application. The technology exists, but to date no company has been willing to test the tool.

Ben Plamp

2008-06-30T23:59:59.000Z

227

Homogeneous carbon doping of magnesium diboride by high-temperature, high-pressure synthesis  

SciTech Connect (OSTI)

We have used high-pressure, high-temperature synthesis at 1500–1700?°C and 10?MPa to create homogeneously C-substituted MgB{sub 2} from a B{sub 4}C + Mg mixture. X-ray diffraction analysis showed large peak-shifts consistent with a decrease in the a lattice parameter for the B{sub 4}C-derived MgB{sub 2} as compared to an undoped sample (0.033–0.037?Å, depending on the sample). Microstructural investigation showed a three-phase mixture in the B{sub 4}C-derived ingots: MgB{sub 2?x}C{sub x} (with 0.178?

Susner, M. A., E-mail: susner.1@osu.edu; Bohnenstiehl, S. D.; Dregia, S. A.; Sumption, M. D.; Yang, Y.; Collings, E. W. [Department of Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210 (United States); Donovan, J. J. [Center for Advanced Materials Characterization in Oregon (CAMCOR), University of Oregon, Eugene, Oregon 97403 (United States)

2014-04-21T23:59:59.000Z

228

Valve assembly for use with high temperature and high pressure fluids  

DOE Patents [OSTI]

The valve assembly for use with high temperature and high pressure fluids has inner and outer spaced shells and a valve actuator support of inner and outer spaced members which are connected at their end portions to the inner and outer shells, respectively, to extend substantially normal to the longitudinal axis of the inner shell. A layer of resilient heat insulating material covers the outer surfaces of the inner shell and the inner actuator support member and is of a thickness to only occupy part of the spaces between the inner and outer shells and inner and outer actuator support members. The remaining portion of the space between the inner and outer shells and the space between the inner and outer members is substantially filled with a body of castable, rigid refractory material. A movable valve member is disposed in the inner shell. A valve actuator assembly is supported in the valve actuator support to extend into the inner shell for connection with the movable valve member for movement of the movable valve member to positions from a fully open to a fully closed position to control flow of fluid through the inner shell. An anchor mneans is disposed adjacent opposite sides of the axis of the valve actuator support and attached to the inner shell so that relative radial movement between the inner and outer shell is permitted by the layer of resilient heat insulating material and relative longitudinal movement of the inner shell to the outer shell is permitted in opposite directions from the anchor means to thereby maintain the functional integrity of the movable valve member by providing an area of the inner shell surrounding the movable valve member longitdinally stationary, but at the same time allowing radial movement.

De Feo, Angelo (Totowa, NY)

1982-01-01T23:59:59.000Z

229

Development of high temperature, high pressure rotating shaft seals: Final report  

SciTech Connect (OSTI)

Rotating shaft seals used in coal gasification equipment are exposed to difficult environmental conditions including temperature from 430/sup 0/C to 816/sup 0/C (800/sup 0/F to 1500/sup 0/F), high pressure (to 10 MPa or 1500 psig), and high levels of particulate contamination (50,000 to 100,000 ppM). The program reported upon was designed to develop long-life seals that would not require external flushing or cooling. The approach taken was to develop unbalanced face that would remain closed and prevent particulate entry into the interface. Wear resistant materials and coatings with low friction coefficients are required. Significant results of the program are enumerated: The selected material combination was a rotating runner of Kentanium K162B mating against a non-rotating seal ring of Kentanium K162B. Kentanium is the trade name of a series of hard carbide alloys with pure titanium carbide as the principal ingredient. Nickel and nickel molybdenum are used as binder materials. Kentanium retains most of its strength at temperatures ..mu..p to 1100/sup 0/C (2000/sup 0/F). Since hard materials are required to resist wear and withstand the temperatures, mechanical compliance must be built into the seal configuration for the opposed faces to follow runner nutations and remain closed. Environmental and frictional heating caused the formation of very small particles of titanium oxide which lodged in the face wave formations and acted as an interfacial lubricant. The results of this program provide encouragement and optimism that dry contact face seals can be developed for long unattended operation in the hostile environment of a coal gasification plant. 40 refs., 98 figs., 20 tabs.

Heshmat, H.; Shapiro, W.

1987-06-01T23:59:59.000Z

230

Raman spectroscopy on single and multi-walled nanotubes under high pressure  

E-Print Network [OSTI]

dependence of the high-energy Raman modes in single and multi-walled carbon nanotubes was measuredRaman spectroscopy on single and multi-walled nanotubes under high pressure C. Thomsen, S. Reich, H properties of carbon nanotubes have become of scienti c interest since it was recognized that the low atomic

Nabben, Reinhard

231

Diffraction studies of order?disorder at high pressures and temperatures  

SciTech Connect (OSTI)

Recent developments at synchrotron X-ray beamlines now allow collection of data suitable for structure determination and Rietveld structure refinement at high pressures and temperatures on challenging materials. These include materials, such as dolomite (CaMg(CO{sub 3}){sub 2}) that tends to calcine at high temperatures, and Fe-containing materials, such as the spinel MgFe{sub 2}O{sub 4}, which tend to undergo changes in oxidation state. Careful consideration of encapsulation along with the use of radial collimation produced powder diffraction patterns virtually free of parasitic scattering from the cell in the case of large volume high-pressure experiments. These features have been used to study a number of phase transitions, especially those where superior signal-to-noise discrimination is required to distinguish weak ordering reflections. The structures adopted by dolomite, and CaSO4, anhydrite, were determined from 298 to 1466 K at high pressures. Using laser-heated diamond-anvil cells to achieve simultaneous high pressure and temperature conditions, we have observed CaSO{sub 4} undergo phase transitions to the monazite type and at highest pressure and temperature to crystallize in the barite-type structure. On cooling, the barite structure distorts, from an orthorhombic to a monoclinic lattice, to produce the AgMnO{sub 4}-type structure.

Parise, John B.; Antao, Sytle M.; Martin, Charles D.; Crichton, Wilson (SBU); (ESRF)

2008-06-18T23:59:59.000Z

232

High-pressure behavior of amorphous selenium from ultrasonic measurements and Raman spectroscopy  

SciTech Connect (OSTI)

The high-pressure behavior of melt-quenched amorphous selenium (a-Se) has been investigated via ultrasonic measurements and Raman scattering at room temperature. The ultrasonic measurements were conducted on a-Se in a multi-anvil apparatus with two different sample assemblies at pressures of up to 4.5 and 4.8?GPa. We discovered that similar kinks occur in the slopes of the pressure dependence characteristics of the travel time and the sound velocity in both shear and longitudinal waves in the 2.0–2.5?GPa range. These kinks are independent of the sample assemblies, indicating an intrinsic transformation of the a-Se. Additionally, we deduced the pressure-volume relationship of a-Se from the sound velocity characteristics using the Birch–Murnaghan equation of state, and the results agreed well with those of previous reports. In situ high-pressure Raman scattering measurements of a-Se were conducted in a diamond anvil cell with an 830?nm excitation line up to a pressure of 4.3?GPa. We found that the characteristic band of a-Se at ?250?cm{sup ?1} experienced a smooth shift to a lower frequency with pressure, but a sharp slope change in the band intensity versus pressure occurred near 2.5?GPa. The results of X-ray diffraction and differential scanning calorimetry measurements indicate that the samples remain in their amorphous states after decompression. Thus, we proposed that the abnormal compression behavior of a-Se in the 2.0–2.5?GPa range can be attributed to pressure-induced local atomic reconfiguration, implying an amorphous-amorphous transition of the elementary selenium.

He, Z.; Liu, X. R.; Hong, S. M., E-mail: hpswjtu@gmail.com, E-mail: smhong@home.swjtu.edu.cn [Laboratory of High Pressure Physics, Southwest Jiaotong University, Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Chengdu 610031 (China); Wang, Z. G. [National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, Chinese Academy of Engineering Physics, Mianyang 621900 (China); Zhu, H. Y. [State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012 (China); Peng, J. P. [School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 610031 (China)

2014-07-07T23:59:59.000Z

233

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both  

E-Print Network [OSTI]

Standard test method for determination of susceptibility of metals to embrittlement in hydrogen containing environments at high pressure, high temperature, or both

American Society for Testing and Materials. Philadelphia

1998-01-01T23:59:59.000Z

234

High-resolution thermal expansion measurements under helium-gas pressure  

SciTech Connect (OSTI)

We report on the realization of a capacitive dilatometer, designed for high-resolution measurements of length changes of a material for temperatures 1.4 K Less-Than-Or-Slanted-Equal-To T Less-Than-Or-Slanted-Equal-To 300 K and hydrostatic pressure P Less-Than-Or-Slanted-Equal-To 250 MPa. Helium ({sup 4}He) is used as a pressure-transmitting medium, ensuring hydrostatic-pressure conditions. Special emphasis has been given to guarantee, to a good approximation, constant-pressure conditions during temperature sweeps. The performance of the dilatometer is demonstrated by measurements of the coefficient of thermal expansion at pressures P Asymptotically-Equal-To 0.1 MPa (ambient pressure) and 104 MPa on a single crystal of azurite, Cu{sub 3}(CO{sub 3}){sub 2}(OH){sub 2}, a quasi-one-dimensional spin S = 1/2 Heisenberg antiferromagnet. The results indicate a strong effect of pressure on the magnetic interactions in this system.

Manna, Rudra Sekhar; Wolf, Bernd; Souza, Mariano de; Lang, Michael [Physics Institute, Goethe University Frankfurt(M), SFB/TR49, D-60438 Frankfurt am Main (Germany)

2012-08-15T23:59:59.000Z

235

Detecting and modeling cement failure in high pressure/ high temperature wells using finite-element method  

E-Print Network [OSTI]

conditions and are investigated simultaneously to more accurately predict cement failure. The results of this study show the relevant dependency of stress principles with temperature and pressure. These results clarify the deformation caused by any...

Shahri, Mehdi Abbaszadeh

2006-04-12T23:59:59.000Z

236

Revisit of the relationship between the elastic properties and sound velocities at high pressures  

SciTech Connect (OSTI)

The second-order elastic constants and stress-strain coefficients are defined, respectively, as the second derivatives of the total energy and the first derivative of the stress with respect to strain. Since the Lagrangian and infinitesimal strain are commonly used in the two definitions above, the second-order elastic constants and stress-strain coefficients are separated into two categories, respectively. In general, any of the four physical quantities is employed to characterize the elastic properties of materials without differentiation. Nevertheless, differences may exist among them at non-zero pressures, especially high pressures. Having explored the confusing issue systemically in the present work, we find that the four quantities are indeed different from each other at high pressures and these differences depend on the initial stress applied on materials. Moreover, the various relations between the four quantities depicting elastic properties of materials and high-pressure sound velocities are also derived from the elastic wave equations. As examples, we calculated the high-pressure sound velocities of cubic tantalum and hexagonal rhenium using these nexus. The excellent agreement of our results with available experimental data suggests the general applicability of the relations.

Wang, Chenju; Yan, Xiaozhen [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); Xiang, Shikai, E-mail: skxiang@caep.ac.cn; Chen, Haiyan [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Gu, Jianbing; Yu, Yin [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Kuang, Xiaoyu [Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); International Centre for Materials Physics, Academia Sinica, Shenyang 110016 (China)

2014-09-14T23:59:59.000Z

237

Numerical investigation of high-pressure combustion in rocket engines using Flamelet/Progress-variable models  

E-Print Network [OSTI]

The present paper deals with the numerical study of high pressure LOx/H2 or LOx/hydrocarbon combustion for propulsion systems. The present research effort is driven by the continued interest in achieving low cost, reliable access to space and more recently, by the renewed interest in hypersonic transportation systems capable of reducing time-to-destination. Moreover, combustion at high pressure has been assumed as a key issue to achieve better propulsive performance and lower environmental impact, as long as the replacement of hydrogen with a hydrocarbon, to reduce the costs related to ground operations and increase flexibility. The current work provides a model for the numerical simulation of high- pressure turbulent combustion employing detailed chemistry description, embedded in a RANS equations solver with a Low Reynolds number k-omega turbulence model. The model used to study such a combustion phenomenon is an extension of the standard flamelet-progress-variable (FPV) turbulent combustion model combined ...

Coclite, A; De Palma, P; Pascazio, G

2015-01-01T23:59:59.000Z

238

A primary high-pressure air flow measurement standard in Taiwan  

SciTech Connect (OSTI)

A high-pressure air-flow national measurement standard is constructed in Taiwan with a capacity of 8400 Nm{sup 3}/h and a projected measurement uncertainty of {plus_minus}0.2% in the pressure range of 1 {approximately} 84 bars. it is a blow-down type facility, and its main purpose is to serve as the primary standard of a larger-flowrate natural gas flow measurement facility to be built in the future by Chinese Petroleum Company (CPC). The system has a gyroscopic weighing platform suitable for high precision gravimetric measurements and several sonic nozzles with different throat diameters situated in a chamber to be the reference flow meters. A set of two turbine meters, 50mm and 100mm, are sued as the transfer standard. The facility has two test sections separated by the nozzle chamber and four different calibration modes could be arranged. To make calibration, the storage tank, the temperature control loop, and two sets of pressure regulating valve establish a pressurized air flow with stable temperature and pressure in the test section. The control of the air-flow diversion, connect-disconnect mechanism, sonic nozzle array is made through a hydraulic power unit operating at 200 bars. Real time measurements of temperature, pressure, flow signal, and time are collected through a Honeywell 9000-series PLC and a FIX DMAC data acquisition/control software. This paper describes the key components of the test facility and presents the preliminary results of performance assessment.

Jiunn-Haur Shaw; Fong-Ruey Yang; Yao-Fu Chen [Industrial Technology Research Inst., Hsinchu (Taiwan, Province of China)

1995-12-31T23:59:59.000Z

239

Structural changes in nano-crystalline mackinawite (FeS) at high - pressure.  

SciTech Connect (OSTI)

The high-pressure behavior of nanocrystalline mackinawite (FeS) with particle sizes of 6, 7 and 8 nm has been investigated by high-energy X-ray total scattering and pair distribution function analysis. An irreversible first-order structural phase transition from tetragonal mackinawite to orthorhombic FeS-II was observed at about 3 GPa. The transition is induced by the closure of the van der Waals gap in the layered mackinawite structure. A grain size effect on the transition pressure and the compressibility was observed.

Ehm, L.; Michael, F. M.; Antao, S. M.; Martin, C. D.; Lee, P. L.; Shastri, S. D.; Chupas, P. J.; Parise, J. B.; Stony Brook Univ.

2009-02-01T23:59:59.000Z

240

Rotor Design for High Pressure Magic Angle Spinning Nuclear Magnetic Resonance  

SciTech Connect (OSTI)

High pressure magic angle spinning (MAS) nuclear magnetic resonance (NMR) with a sample spinning rate exceeding 2.1 kHz and pressure greater than 165 bar has never been realized. In this work, a new sample cell design is reported, suitable for constructing cells of different sizes. Using a 7.5 mm high pressure MAS rotor as an example, internal pressure as high as 200 bar at a sample spinning rate of 6 kHz is achieved. The new high pressure MAS rotor is re-usable and compatible with most commercial NMR set-ups, exhibiting low 1H and 13C NMR background and offering maximal NMR sensitivity. As an example of its many possible applications, this new capability is applied to determine reaction products associated with the carbonation reaction of a natural mineral, antigorite ((Mg,Fe2+)3Si2O5(OH)4), in contact with liquid water in water-saturated supercritical CO2 (scCO2) at 150 bar and 50 deg C. This mineral is relevant to the deep geologic disposal of CO2, but its iron content results in too many sample spinning sidebands at low spinning rate. Hence, this chemical system is a good case study to demonstrate the utility of the higher sample spinning rates that can be achieved by our new rotor design. We expect this new capability will be useful for exploring solid-state, including interfacial, chemistry at new levels of high-pressure in a wide variety of fields.

Turcu, Romulus V.F.; Hoyt, David W.; Rosso, Kevin M.; Sears, Jesse A.; Loring, John S.; Felmy, Andrew R.; Hu, Jian Z.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Safety analysis of high pressure 3He-filled micro-channels for thermal neutron detection.  

SciTech Connect (OSTI)

This document is a safety analysis of a novel neutron detection technology developed by Sandia National Laboratories. This technology is comprised of devices with tiny channels containing high pressure {sup 3}He. These devices are further integrated into large scale neutron sensors. Modeling and preliminary device testing indicates that the time required to detect the presence of special nuclear materials may be reduced under optimal conditions by several orders of magnitude using this approach. Also, these devices make efficient use of our {sup 3}He supply by making individual devices more efficient and/or extending the our limited {sup 3}He supply. The safety of these high pressure devices has been a primary concern. We address these safety concerns for a flat panel configuration intended for thermal neutron detection. Ballistic impact tests using 3 g projectiles were performed on devices made from FR4, Silicon, and Parmax materials. In addition to impact testing, operational limits were determined by pressurizing the devices either to failure or until they unacceptably leaked. We found that (1) sympathetic or parasitic failure does not occur in pressurized FR4 devices (2) the Si devices exhibited benign brittle failure (sympathetic failure under pressure was not tested) and (3) the Parmax devices failed unacceptably. FR4 devices were filled to pressures up to 4000 + 100 psig, and the impacts were captured using a high speed camera. The brittle Si devices shattered, but were completely contained when wrapped in thin tape, while the ductile FR4 devices deformed only. Even at 4000 psi the energy density of the compressed gas appears to be insignificant compared to the impact caused by the incoming projectile. In conclusion, the current FR4 device design pressurized up to 4000 psi does not show evidence of sympathetic failure, and these devices are intrinsically safe.

Ferko, Scott M.; Galambos, Paul C.; Derzon, Mark Steven; Renzi, Ronald F.

2008-11-01T23:59:59.000Z

242

A cryogenic high pressure cell for inelastic neutron scattering measurements of quantum fluids and solids  

SciTech Connect (OSTI)

We present our new development of a high pressure cell for inelastic neutron scattering measurements of helium at ultra-low temperatures. The cell has a large sample volume of ~140 cm3, and a working pressure of ~70 bar, with a relatively thin wall-thickness (1.1 mm) - thanks to the high yield strength aluminum used in the design. Two variants of this cell have been developed; one with permanently joined components using electron-beam welding and explosion welding, methods that have little or no impact on the global heat treatment of the cell, and another with modular and interchangeable components, which include a capacitance pressure gauge, that can be sealed using traditional indium wire technique. The performance of the cell has been tested in recent measurements on superfluid liquid helium near the solidification line.

Carmichael, Justin R [ORNL; Omar Diallo, Souleymane [ORNL

2013-01-01T23:59:59.000Z

243

Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection  

SciTech Connect (OSTI)

A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cell’s infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct radiation from a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system is demonstrated with three case studies. First, we titrated water into supercritical CO2 (scCO2) to generate an infrared calibration curve and determine the solubility of water in CO2 at 50 °C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO2 at 50 °C and 90 bar. Transmission-mode spectra were used to quantify changes in the clay’s sorbed water concentration as a function of scCO2 hydration, and ATR measurements provided insights into competitive residency of water and CO2 on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg2SiO4) in water-bearing scCO2 at 50 °C and 90 bar. Immediately after water dissolved in the scCO2, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 hours, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO2 and minerals relevant to underground storage of CO2 (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

Thompson, Christopher J.; Martin, Paul F.; Chen, Jeffrey; Benezeth, Pascale; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S.

2014-04-17T23:59:59.000Z

244

Automated high-pressure titration system with in situ infrared spectroscopic detection  

SciTech Connect (OSTI)

A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cell's infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct the light path of a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system was demonstrated with three case studies. First, we titrated water into supercritical CO{sub 2} (scCO{sub 2}) to generate an infrared calibration curve and determine the solubility of water in CO{sub 2} at 50?°C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO{sub 2} at 50?°C and 90 bar. Transmission-mode spectra were used to quantify changes in the clay's sorbed water concentration as a function of scCO{sub 2} hydration, and ATR measurements provided insights into competitive residency of water and CO{sub 2} on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg{sub 2}SiO{sub 4}) in water-bearing scCO{sub 2} at 50?°C and 90 bar. Immediately after water dissolved in the scCO{sub 2}, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 h, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO{sub 2} and minerals relevant to underground storage of CO{sub 2} (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

Thompson, Christopher J., E-mail: chris.thompson@pnnl.gov; Martin, Paul F.; Chen, Jeffrey; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States)] [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Benezeth, Pascale [Géosciences Environnement Toulouse (GET), CNRS-Université de Toulouse, 31400 Toulouse (France)] [Géosciences Environnement Toulouse (GET), CNRS-Université de Toulouse, 31400 Toulouse (France)

2014-04-15T23:59:59.000Z

245

Design, modeling, fabrication and testing of a piezoelectric microvalve for high pressure, high frequency hydraulic applications  

E-Print Network [OSTI]

A piezoelectrically-driven hydraulic amplification microvalve for use in high specific power hydraulic pumping applications was designed, fabricated, and experimentally characterized. High frequency, high force actuation ...

Roberts, David C. (David Christopher)

2002-01-01T23:59:59.000Z

246

ANALYSIS OF HIGH PRESSURE TESTS ON WET GAS FLOW METERING WITH A VENTURI METER  

E-Print Network [OSTI]

ANALYSIS OF HIGH PRESSURE TESTS ON WET GAS FLOW METERING WITH A VENTURI METER P. Gajan , Q, 64018 Pau cedex, France pierre.gajan@onera.fr Abstract This work deals with the flow metering of wet gas on the CEESI facilities are presented. They are performed at 75 bars with 0.6 beta ratio Venturi meter

247

High-pressure phases of FeTiO3 from first principles N. C. Wilson  

E-Print Network [OSTI]

2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

248

Stability of very-high pressure arc discharges against perturbations of the electron temperature  

SciTech Connect (OSTI)

We study the stability of the energy balance of the electron gas in very high-pressure plasmas against longitudinal perturbations, using a local dispersion analysis. After deriving a dispersion equation, we apply the model to a very high-pressure (100 bar) xenon plasma and find instability for electron temperatures, T{sub e}, in a window between 2400 K and 5500-7000 K x 10{sup 3} K, depending on the current density (10{sup 6}-10{sup 8} A/m{sup 2}). The instability can be traced back to the Joule heating of the electron gas being a growing function of T{sub e}, which is due to a rising dependence of the electron-atom collision frequency on T{sub e}. We then analyze the T{sub e} range occurring in very high-pressure xenon lamps and conclude that only the near-anode region exhibits T{sub e} sufficiently low for this instability to occur. Indeed, previous experiments have revealed that such lamps develop, under certain conditions, voltage oscillations accompanied by electromagnetic interference, and this instability has been pinned down to the plasma-anode interaction. A relation between the mechanisms of the considered instability and multiple anodic attachments of high-pressure arcs is discussed.

Benilov, M. S. [Departamento de Fisica, Ciencias Exactas e Engenharia, Universidade da Madeira, Largo do Municipio, Funchal 9000 (Portugal); Hechtfischer, U. [Philips Lighting, BU Automotive Lamps, Technology, Philipsstrasse 8, Aachen 52068 (Germany)

2012-04-01T23:59:59.000Z

249

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR  

E-Print Network [OSTI]

OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN of computer simulations as an optimal design tool which lessens the costs in time and effort in experimental vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor

250

Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics  

E-Print Network [OSTI]

Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics Chien details the development of an integrated AC electro-osmotic (ACEO) microfluidic pump for dilute (100 mM) biological solutions in separate microfluidic devices, with potential applications in portable

Bazant, Martin Z.

251

Metastable high-pressure transformations of orthoferrosilite Fs82 Przemyslaw Dera a,e,  

E-Print Network [OSTI]

Metastable high-pressure transformations of orthoferrosilite Fs82 Przemyslaw Dera a,e, , Gregory J Institution of Washington, USA e Hawaii Institute of Geophysics and Planetology, School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, USA a r t i c l e i n f o Article history: Received

Duffy, Thomas S.

252

High pressure studies on uranium and thorium silicide compounds: Experiment S. Yagoubi a,b,c,  

E-Print Network [OSTI]

High pressure studies on uranium and thorium silicide compounds: Experiment and theory S. Yagoubi a, USi3, as well as some non-stoichiometric phases presented in Table 1. Among the thoriumB-type) that a ferromagnetic ordering is reported, with TC = 127 K and a saturated moment of 0.1 lB [3]. Concerning the thorium

Svane, Axel Torstein

253

Acceptance test report for high pressure water jet system feed pump  

SciTech Connect (OSTI)

This document summarizes results of WHC-SD-SNF-ATP-016, Rev. 0 ``Acceptance Test Procedure High Pressure Water Jet System``, conducted on December 20, 1995 and December 22, 1995. This jet supplies water at 15,000 psi @ 15 gpm to nozzles to clean surfaces of empty fuel storage canisters.

Crystal, J.B.

1996-03-12T23:59:59.000Z

254

Thermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee  

E-Print Network [OSTI]

are concerned with the exchange of thermal energy across an interface between two materials. This topic-nonmetal interface, a two-temperature model predicts a thermal resistance of Rep = 1/ gL in series with the phononThermal conductance of metal-diamond interfaces at high pressure Gregory T. Hohensee Department

Cahill, David G.

255

Design of a continuous fiber ceramic composite heat exchanger for high-temperature, high-pressure applications  

SciTech Connect (OSTI)

A conceptual design of a continuous fiber ceramic composite (CFCC) heat exchanger for high-temperature, high-pressure applications is presented. The CFCC materials under consideration are SiC reinforced with SiC fibers manufactured using the continuous vapor infiltration process and alumina reinforced with SiC or alumina fibers manufactured using the directed metal oxidation process. These composite materials are highly resistant to high-temperature corrosive environment and possess a greater creep strength than metallic materials. Heat exchangers constructed of CFCC material may be utilized for high-temperature, high-pressure applications such as air/gas heaters in advanced energy systems and high-temperature energy recovery systems. This paper presents a design of a gas-to-air CFCC heat exchanger for the high temperature advanced furnace (HITAF) in the high-performance power system (HIPPS). The 1.38 MPa (200 psia) air is heated from 760 C (1,400 F) to 982 C (1,800 F) using the combustion products at 1,650 C (3,000 F). The heat exchanger is of a cross-parallel/counter flow type in which the tube-side air flow makes a combined parallel and counter flow arrangement with a cross-flowing combustion gas in such a way that the maximum CFCC tube temperature will not exceed a 1,260 C (2,300 F) design limit. The main heat transfer mechanism from the external hot gas to the tube-side air is that of gaseous radiation for the first few rows of the tubes, followed by convective heat transfer across the remainder of the tube bundle. The design characteristics of this high-temperature, high-pressure CFCC heat exchanger with supporting thermal, flow, structural, and vibrational analyses are presented in detail in the paper.

Cho, S.M.; Seltzer, A.H.; Narayanan, T.V. [Foster Wheeler Development Corp., Livingston, NJ (United States); Shah, A.C.; Weddell, J.K. [DuPont Lanxide Composites Inc., Newark, DE (United States)

1996-12-31T23:59:59.000Z

256

Manufacturing and properties of newly developed 9%CrMoVNiNbN high-pressure low-pressure rotor shaft forging  

SciTech Connect (OSTI)

In order to obtain the improved strength and toughness for high-pressure low-pressure rotor shaft forging, fundamental studies using laboratory heats were performed on the 9CrMoV base materials, and effects of chemistry on toughness and creep rupture strength were investigated. From the investigation, it is showed that the superclean 9CrMoVNiNbN steel with reduced Si and Mn contents and Ni addition provides a superior strength versus toughness balance. Based on these fundamental studies, a trial high-pressure low-pressure rotor shaft forging with diameter of low-pressure section of 1,750 mm and diameter of high-pressure section of 1,200 mm was successfully manufactured from the diameter of 1,800 mm, and the weight of 65 ton ESR ingot. From the evaluation test results of this trial rotor forging, homogeneous distribution of chemistry was confirmed and low impurity contents was observed in the whole forging. The superior strength and toughness were confirmed with good creep rupture strength. The FATT at the center of low-pressure section was {minus}3 C with the tensile strength level of 870 MPa. From the results of fracture toughness test, low cycle fatigue test, and isothermal aging test, superior mechanical properties were demonstrated. Thus, the superclean 9CrMoVNiNbN steel with reduced Si and Mn contents and Ni addition, is particularly suitable for the high-pressure low-pressure rotor material for advanced combined cycle power plants.

Azuma, Tsukasa; Tanaka, Yasuhiko; Ishiguro, Tohru; Yoshida, Hajime; Ikeda, Yasumi [Japan Steel Works, Muroran (Japan)

1997-12-31T23:59:59.000Z

257

Innovative high pressure gas MEM's based neutron detector for ICF and active SNM detection.  

SciTech Connect (OSTI)

An innovative helium3 high pressure gas detection system, made possible by utilizing Sandia's expertise in Micro-electrical Mechanical fluidic systems, is proposed which appears to have many beneficial performance characteristics with regards to making these neutron measurements in the high bremsstrahlung and electrical noise environments found in High Energy Density Physics experiments and especially on the very high noise environment generated on the fast pulsed power experiments performed here at Sandia. This same system may dramatically improve active WMD and contraband detection as well when employed with ultrafast (10-50 ns) pulsed neutron sources.

Martin, Shawn Bryan; Derzon, Mark Steven; Renzi, Ronald F.; Chandler, Gordon Andrew

2007-12-01T23:59:59.000Z

258

Use of high hydrostatic pressure to produce high quality and safe fresh pork sausage  

E-Print Network [OSTI]

and Functionality Improvement . . . . . . . . . . . . . . . . . . . . . Thermal Processing . Response Surface Methodology 22 22 22 23 23 24 26 26 27 30 32 111 THEORETICAL CONSIDERATIONS 33 31 3. 2 3. 3 Theory of Linear Viscoelasticity 3. 1. 1... with yeast extract (TSA) and Modified oxford agar (MOX) with supplements . . . . . . . . . . . . . . . . 73 5. 2 Survival of three individual strains of L. monocytogenes in fresh pork sausage exposed to a hydrostatic pressure of 414 MPa at 25'C for various...

Huang, Mei

2012-06-07T23:59:59.000Z

259

High Temperature, high pressure equation of state density correlations and viscosity correlations  

SciTech Connect (OSTI)

Global increase in oil demand and depleting reserves has derived a need to find new oil resources. To find these untapped reservoirs, oil companies are exploring various remote and harsh locations such as deep waters in Gulf of Mexico, remote arctic regions, unexplored deep deserts, etc. Further, the depth of new oil/gas wells being drilled has increased considerably to tap these new resources. With the increase in the well depth, the bottomhole temperature and pressure are also increasing to extreme values (i.e. up to 500 F and 35,000 psi). The density and viscosity of natural gas and crude oil at reservoir conditions are critical fundamental properties required for accurate assessment of the amount of recoverable petroleum within a reservoir and the modeling of the flow of these fluids within the porous media. These properties are also used to design appropriate drilling and production equipment such as blow out preventers, risers, etc. With the present state of art, there is no accurate database for these fluid properties at extreme conditions. As we have begun to expand this experimental database it has become apparent that there are neither equations of state for density or transport models for viscosity that can be used to predict these fundamental properties of multi-component hydrocarbon mixtures over a wide range of temperature and pressure. Presently, oil companies are using correlations based on lower temperature and pressure databases that exhibit an unsatisfactory predictive capability at extreme conditions (e.g. as great as {+-} 50%). From the perspective of these oil companies that are committed to safely producing these resources, accurately predicting flow rates, and assuring the integrity of the flow, the absence of an extensive experimental database at extreme conditions and models capable of predicting these properties over an extremely wide range of temperature and pressure (including extreme conditions) makes their task even more daunting.

Tapriyal, D.; Enick, R.; McHugh, M.; Gamwo, I.; Morreale, B.

2012-07-31T23:59:59.000Z

260

The High-Pressure Characterization of Energetic Materials: 2-Methyl-5-Nitramino-2H-Tetrazole  

SciTech Connect (OSTI)

The isothermal structural properties, equation of state, and vibrational dynamics of 2MNT were studied under high-pressure using synchrotron XRD and optical Raman and IR microspectroscopy. Analysis of the XRD patterns revealed no indication of a phase transition to near 15 GPa and the pressure-volume isotherm remained smooth to 15 GPa. Near 15 GPa, significant sample damage was observed from the X-ray beam which precluded the acquisition of patterns above this pressure. XRD and Raman spectroscopic measurements showed the monoclinic ambient condition phase of 2MNT remains the dominant phase to near 20 GPa, although a shift of the NO{sub 2} IR active vibrational modes to lower frequencies suggested a subtle geometry modification not reflected in the XRD data.

J Ciezak

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


261

Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures  

SciTech Connect (OSTI)

Ignition times were determined in high-pressure shock-tube experiments for various stoichiometric mixtures of two multicomponent model fuels in air for the validation of ignition delay simulations based on chemical kinetic models. The fuel blends were n-heptane (18%)/isooctane (62%)/ethanol (20%) by liquid volume (14.5%/44.5%/41% by mole fraction) and n-heptane (20%)/toluene (45%)/isooctane (25%)/diisobutylene (10%) by liquid volume (17.5%/55%/19.5%/8.0% by mole fraction). These fuels have octane numbers comparable to a standard European gasoline of 95 RON and 85 MON. The experimental conditions cover temperatures from 690 to 1200 K and pressures at 10, 30, and 50 bar. The obtained ignition time data are scaled with respect to pressure and compared to previous results reported in the literature. (author)

Fikri, M.; Herzler, J.; Starke, R.; Schulz, C.; Roth, P. [IVG, Universitaet Duisburg-Essen, D-47048 Duisburg (Germany); Kalghatgi, G.T. [Shell Global Solutions U.K., P.O. Box 1, Chester CH1 3SH (United Kingdom)

2008-01-15T23:59:59.000Z

262

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

263

High-pressure structural and elastic properties of Tl{sub 2}O{sub 3}  

SciTech Connect (OSTI)

The structural properties of Thallium (III) oxide (Tl{sub 2}O{sub 3}) have been studied both experimentally and theoretically under compression at room temperature. X-ray powder diffraction measurements up to 37.7?GPa have been complemented with ab initio total-energy calculations. The equation of state of Tl{sub 2}O{sub 3} has been determined and compared to related compounds. It has been found experimentally that Tl{sub 2}O{sub 3} remains in its initial cubic bixbyite-type structure up to 22.0?GPa. At this pressure, the onset of amorphization is observed, being the sample fully amorphous at 25.2?GPa. The sample retains the amorphous state after pressure release. To understand the pressure-induced amorphization process, we have studied theoretically the possible high-pressure phases of Tl{sub 2}O{sub 3}. Although a phase transition is theoretically predicted at 5.8?GPa to the orthorhombic Rh{sub 2}O{sub 3}-II-type structure and at 24.2?GPa to the orthorhombic ?-Gd{sub 2}S{sub 3}-type structure, neither of these phases were observed experimentally, probably due to the hindrance of the pressure-driven phase transitions at room temperature. The theoretical study of the elastic behavior of the cubic bixbyite-type structure at high-pressure shows that amorphization above 22?GPa at room temperature might be caused by the mechanical instability of the cubic bixbyite-type structure which is theoretically predicted above 23.5?GPa.

Gomis, O., E-mail: osgohi@fis.upv.es; Vilaplana, R. [Centro de Tecnologías Físicas, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); Santamaría-Pérez, D. [Departamento de Física Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr. Moliner 50, 46100 Burjassot (Spain); Earth Sciences Department, University College London, Gower Street, WC1E 6BT London (United Kingdom); Ruiz-Fuertes, J. [Departamento de Física Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigación, C/Dr. Moliner 50, 46100 Burjassot (Spain); Geowissenschaften, Goethe-Universität, Altenhöferallee 1, 60438 Frankfurt am Main (Germany); Sans, J. A.; Manjón, F. J.; Mollar, M. [Instituto de Diseño para la Fabricación y Producción Automatizada, MALTA Consolider Team, Universitat Politècnica de València, 46022 València (Spain); and others

2014-10-07T23:59:59.000Z

264

Phase transition and metallization of FeO at high pressures and temperatures  

SciTech Connect (OSTI)

Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component of the core. Therefore its high pressure-temperature behavior, including its electronic structure, is essential to understanding the nature and evolution of Earth's deep interior. We performed X-ray diffraction and radiometric measurements on wuestite in a laser-heated diamond anvil cell, finding an insulator-metal transition at high pressures and temperatures. Our data show a negative slope for this apparently isostructural phase boundary, which is characterized by a volume decrease and emissivity increase. The metallic phase of FeO is stable at conditions of the lower mantle and core, which has implications for the high P-T character of Fe-O bonds, magnetic field propagation, and lower mantle conductivity.

Fischer, Rebecca A.; Campbell, Andrew J.; Lord, Oliver T.; Shofner, Gregory A.; Dera, Przemyslaw; Prakapenka, Vitali B. (Maryland); (UC); (UCL)

2012-05-10T23:59:59.000Z

265

Studies of local and intermediate range structure in crystalline and amorphouse materials at high pressure using high-energy x-rays.  

SciTech Connect (OSTI)

The method of high-energy total elastic X-ray scattering to determine the atomic structure of nanocrystalline, highly disordered, and amorphous materials is presented. The current state of the technique, its potential, and limitations are discussed with two successful studies on the pressure induced phase transition in mackinawite (FeS) and the high-pressure behavior of liquid gallium.

Ehm, L.; Antao, M.; Chen, J.; Locke, D. R.; Michel, F. M.; Martin, C. D.; Yu, T.; Lee, P. L.; Chupas, P. J.; Shastri, S. D.; Guo, Q.; Parise, J. B.; Stony Brook Univ.; BNL

2007-06-01T23:59:59.000Z

266

Studies of Local and Intermediate Range Structure in Crystalline and Amorphous Materials at High Pressure Using High-Energy X-rays  

SciTech Connect (OSTI)

The method of high-energy total elastic X-ray scattering to determine the atomic structure of nanocrystalline, highly disordered, and amorphous materials is presented. The current state of the technique, its potential, and limitations are discussed with two successful studies on the pressure induced phase transition in mackinawite (FeS) and the high-pressure behavior of liquid gallium.

Ehm,L.; Antao, S.; Chen, J.; Locke, D.; Michel, F.; Martin, D.; Yu, T.; Parise, J.; Lee, P.; et al.

2007-01-01T23:59:59.000Z

267

Dark Matter Directionality Revisited with a High Pressure Xenon Gas Detector  

E-Print Network [OSTI]

An observation of the anisotropy of dark matter interactions in a direction-sensitive detector would provide decisive evidence for the discovery of galactic dark matter. Directional information would also provide a crucial input to understanding its distribution in the local Universe. Most of the existing directional dark matter detectors utilize particle tracking methods in a low-pressure gas time projection chamber. These low pressure detectors require excessively large volumes in order to be competitive in the search for physics beyond the current limit. In order to avoid these volume limitations, we consider a novel proposal, which exploits a columnar recombination effect in a high-pressure gas time projection chamber. The ratio of scintillation to ionization signals observed in the detector carries the angular information of the particle interactions. In this paper, we investigate the sensitivity of a future directional detector focused on the proposed high-pressure Xenon gas time projection chamber. We study the prospect of detecting an anisotropy in the dark matter velocity distribution. We find that tens of events are needed to exclude an isotropic distribution of dark matter interactions at 95% confidence level in the most optimistic case with head-to-tail information. However, one needs at least 10-20 times more events without head-to-tail information for light dark matter below 50 GeV or one between 200 GeV and 400 GeV. For an intermediate mass range, we find it challenging to observe anisotropy of dark matter distribution.

Gopolang Mohlabeng; Kyoungchul Kong; Jin Li; Adam Para; Jonghee Yoo

2015-03-13T23:59:59.000Z

268

Study of liquid gallium at high pressure using synchrotron x-ray  

SciTech Connect (OSTI)

Liquid gallium has been studied at high pressure up to 2 GPa and ambient temperature in a diamond anvil cell using high energy synchrotron x-ray beam. The total x-ray scattering data of liquid gallium were collected up to Q = 12 A{sup -1} and analyzed using pair distribution functions (PDF). The results indicate that the first nearest neighbor peak and second nearest neighbor (shoulder) peak of PDF in liquid gallium does not change with pressure, whereas the higher order (i.e., third and fourth) nearest neighbor peaks shift towards shorter distance with increasing pressure. Reverse Monte Carlo modeling based on the observed data shows that the coordination number in the liquid gallium increases with pressure from 10.5 at 0.3 GPa to 11.6 at 2 GPa. An atomic arrangement similar to the crystalline phase of Ga(II) with coordination number of 12 is proposed for the locally dense-packed rigid unit in liquid gallium. The volume compression data derived from the structure modeling yield a bulk modulus of 12.1(6) GPa for liquid gallium.

Yu, Tony; Guo Quanzhong; Parise, John [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Chen Jiuhua [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Ehm, Lars [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States); Huang Shu [Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Luo Shengnian [Physics Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2012-06-01T23:59:59.000Z

269

Comparison of high pressure transient PVT measurements and model predictions. Part I.  

SciTech Connect (OSTI)

A series of experiments consisting of vessel-to-vessel transfers of pressurized gas using Transient PVT methodology have been conducted to provide a data set for optimizing heat transfer correlations in high pressure flow systems. In rapid expansions such as these, the heat transfer conditions are neither adiabatic nor isothermal. Compressible flow tools exist, such as NETFLOW that can accurately calculate the pressure and other dynamical mechanical properties of such a system as a function of time. However to properly evaluate the mass that has transferred as a function of time these computational tools rely on heat transfer correlations that must be confirmed experimentally. In this work new data sets using helium gas are used to evaluate the accuracy of these correlations for receiver vessel sizes ranging from 0.090 L to 13 L and initial supply pressures ranging from 2 MPa to 40 MPa. The comparisons show that the correlations developed in the 1980s from sparse data sets perform well for the supply vessels but are not accurate for the receivers, particularly at early time during the transfers. This report focuses on the experiments used to obtain high quality data sets that can be used to validate computational models. Part II of this report discusses how these data were used to gain insight into the physics of gas transfer and to improve vessel heat transfer correlations. Network flow modeling and CFD modeling is also discussed.

Felver, Todd G.; Paradiso, Nicholas Joseph; Evans, Gregory Herbert; Rice, Steven F.; Winters, William Stanley, Jr.

2010-07-01T23:59:59.000Z

270

High pressure pair distribution function studies of Green River oil shale.  

SciTech Connect (OSTI)

The compression behavior of a silicate-rich oil shale from the Green River formation in the pressure range 0.0-2.4 GPa was studied using in situ high pressure X-ray pair distribution function (PDF) measurements for the sample contained within a Paris-Edinburgh cell. The real-space local structural information in the PDF, G(r), was used to evaluate the compressibility of the oil shale. Specifically, the pressure-induced reduction in the medium- to long-range atom distances ({approx}6-20 {angstrom}) yielded an average sample compressibility corresponding to a bulk modulus of ca. 61-67 GPa. A structural model consisting of a three phase mixture of the principal crystalline oil shale components (quartz, albite and Illite) provided a good fit to the ambient pressure PDF data (R {approx} 30.7%). Indeed the features in the PDF beyond {approx} {angstrom}, were similarly well fit by a single phase model of the highest symmetry, highly crystalline quartz component. The factors influencing the observed compression behavior are discussed.

Chapman, K. W.; Chupas, P. J.; Locke, D. R.; Winans, R. E.; Pugmire, R. J.; Univ. of Utah

2008-01-01T23:59:59.000Z

271

Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up  

SciTech Connect (OSTI)

Washington University in St. Louis and its project partners are developing a unique pressurized oxy-combustion process that aims to improve efficiency and costs by reducing the recycling of flue gas to near zero. Normally, in the absence of recycled flue gas or another inert gas, combustion of fuel and oxygen results in a dramatic increase in temperature of the combustion products and radiant energy, as compared to combustion in air. High heat flux to the boiler tubes may result in a tube surface temperatures that exceed safe operating limits. In the Staged Pressurized Oxy-Combustion (SPOC) process, this problem is addressed by staging the delivery of fuel and by novel combustion design that allows control of heat flux. In addition, the main mode of heat transfer to the steam cycle is by radiation, as opposed to convection. Therefore, the requirement for recycling large amounts of flue gas, for temperature control or to improve convective heat transfer, is eliminated, resulting in a reduction in auxiliary loads. The following report contains a detailed summary of scientific findings and accomplishments for the period of Oct. 1, 2013 to Sept 30, 2014. Results of ASPEN process and CFD modelling activities aimed at improving the SPOC process and boiler design are presented. The effects of combustion pressure and fuel moisture on the plant efficiency are discussed. Combustor pressure is found to have only a minor impact beyond 16 bar. For fuels with moisture content greater than approx 30%, e.g. coal/water slurries, the amount of latent heat of condensation exceeds that which can be utilized in the steam cycle and plant efficiency is reduced significantly. An improved boiler design is presented that achieves a more uniform heat flux profile. In addition, a fundamental study of radiation in high-temperature, high-pressure, particle-laden flows is summarized which provides a more complete understanding of heat transfer in these unusual conditions and to allow for optimization. The results reveal that for the SPOC design, absorption and emission due to particles is the dominant factor for determining the wall heat flux. The mechanism of “radiative trapping” of energy within the high-temperature flame region and the approach to utilizing this mechanism to control wall heat flux are described. This control arises, by design, from the highly non-uniform (non-premixed) combustion characteristics within the SPOC boiler, and the resulting gradients in temperature and particle concentration. Finally, a simple method for estimating the wall heat flux in pressurized combustion systems is presented.

Axelbaum, Richard; Xia, Fei; Gopan, Akshay; Kumfer, Benjamin

2014-09-30T23:59:59.000Z

272

Apparatus and method for enhanced chemical processing in high pressure and atmospheric plasmas produced by high frequency electromagnetic waves  

DOE Patents [OSTI]

An apparatus and method for creating high temperature plasmas for enhanced chemical processing of gaseous fluids, toxic chemicals, and the like, at a wide range of pressures, especially at atmospheric and high pressures includes an electro-magnetic resonator cavity, preferably a reentrant cavity, and a wave guiding structure which connects an electro-magnetic source to the cavity. The cavity includes an intake port and an exhaust port, each having apertures in the conductive walls of the cavity sufficient for the intake of the gaseous fluids and for the discharge of the processed gaseous fluids. The apertures are sufficiently small to prevent the leakage of the electro-magnetic radiation from the cavity. Gaseous fluid flowing from the direction of the electro-magnetic source through the guiding wave structure and into the cavity acts on the plasma to push it away from the guiding wave structure and the electro-magnetic source. The gaseous fluid flow confines the high temperature plasma inside the cavity and allows complete chemical processing of the gaseous fluids at a wide range of pressures.

Efthimion, Philip C. (Bedminister, NJ); Helfritch, Dennis J. (Flemington, NJ)

1989-11-28T23:59:59.000Z

273

DEVELOPMENT OF A LOW PRESSURE, AIR ATOMIZED OIL BURNER WITH HIGH ATOMIZER AIR FLOW  

SciTech Connect (OSTI)

This report describes technical advances made to the concept of a low pressure, air atomized oil burner for home heating applications. Currently all oil burners on the market are of the pressure atomized, retention head type. These burners have a lower firing rate limit of about 0.5 gallons per hour of oil, due to reliability problems related to small flow passage sizes. High pressure air atomized burners have been shown to be one route to avoid this problem but air compressor cost and reliability have practically eliminated this approach. With the low pressure air atomized burner the air required for atomization can be provided by a fan at 5--8 inches of water pressure. A burner using this concept, termed the Fan-Atomized Burner or FAB has been developed and is currently being commercialized. In the head of the FAB, the combustion air is divided into three parts, much like a conventional retention head burner. This report describes development work on a new concept in which 100% of the air from the fan goes through the atomizer. The primary advantage of this approach is a great simplification of the head design. A nozzle specifically sized for this concept was built and is described in the report. Basic flow pressure tests, cold air velocity profiles, and atomization performance have been measured. A burner head/flame tube has been developed which promotes a torroidal recirculation zone near the nozzle for flame stability. The burner head has been tested in several furnace and boiler applications over the tiring rate range 0.2 to 0.28 gallons per hour. In all cases the burner can operate with very low excess air levels (under 10%) without producing smoke. Flue gas NO{sub x} concentration varied from 42 to 62 ppm at 3% 0{sub 2}. The concept is seen as having significant potential and planned development efforts are discussed.

BUTCHER,T.A.

1998-01-01T23:59:59.000Z

274

Engineering properties of miniature cement - fly ash compacts prepared by high pressure compaction  

E-Print Network [OSTI]

ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY HDOBPvvIi va vGI ge(iD(vI oannItI au NId(R E)L xrP1IeRPvT 9(evP(n uDnuPnnBIrv au vGI eI0DPeIBIrvR uae vGI i...IteII au LEHNFA -M Ho2FYoF EDtDRv 3456 L(7ae HDO7I8v? oP1Pn FrtPrIIePrt ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY E99ea1Ii (R va RvTnI (ri 8arvIrv OT? LP...

Bormann, Jeffrey Ray

1985-01-01T23:59:59.000Z

275

High Pressure Water Jet System Performance Assessment Project A-2A  

SciTech Connect (OSTI)

Performance assessment for canister cleaning system in the KE Basin. Information obtained from this assessment will be used to design any additional equipment used to clean canisters. After thorough review of the design, maintenance history and operational characteristics of the 105 K East (KE) canister cleaning system, Bartlett recommends that the high pressure water jet system (HPWJS) be modified as outlined in section 5.0, and retained for future use. Further, it is recommended that Spent Nuclear Fuel (SNF) Project consider use of a graded approach for canister cleaning, based on individual canister type and characteristics. This approach would allow a simple method to be used on canisters not needing the more rigorous, high-pressure method. Justification is provided in section 5.0. Although Bartlett has provided some preliminary cost estimates, it is recommended that SNF Project perform a detailed cost-benefit analysis to weigh the alternatives presented.

FARWICK, C.C.

1999-12-03T23:59:59.000Z

276

Ground state properties and high pressure behavior of plutonium dioxide: Systematic density functional calculations  

E-Print Network [OSTI]

Plutonium dioxide is of high technological importance in nuclear fuel cycle and is particularly crucial in long-term storage of Pu-based radioactive waste. Using first-principles density-functional theory, in this paper we systematically study the structural, electronic, mechanical, thermodynamic properties, and pressure induced structural transition of PuO$_{2}$. To properly describe the strong correlation in the Pu $5f$ electrons, the local density approximation$+U$ and the generalized gradient approximation$+U$ theoretical formalisms have been employed. We optimize the $U$ parameter in calculating the total energy, lattice parameters, and bulk modulus at the nonmagnetic, ferromagnetic, and antiferromagnetic configurations for both ground state fluorite structure and high pressure cotunnite structure. The best agreement with experiments is obtained by tuning the effective Hubbard parameter $U$ at around 4 eV within the LDA$+U$ approach. After carefully testing the validity of the ground state, we further in...

Zhang, Ping; Zhao, Xian-Geng

2010-01-01T23:59:59.000Z

277

High-Q silica zipper cavity for optical radiation pressure driven MOMS switch  

SciTech Connect (OSTI)

We design a silica zipper cavity that has high optical and mechanical Q (quality factor) values and demonstrate numerically the feasibility of a radiation pressure driven micro opto-mechanical system (MOMS) directional switch. The silica zipper cavity has an optical Q of 4.0 × 10{sup 4} and an effective mode volume V{sub mode} of 0.67?{sup 3} when the gap between two cavities is 34 nm. The mechanical Q (Q{sub m}) is determined by thermo-elastic damping and is 2.0 × 10{sup 6} in a vacuum at room temperature. The opto-mechanical coupling rate g{sub OM} is as high as 100 GHz/nm, which allows us to move the directional cavity-waveguide system and switch 1550-nm light with 770-nm light by controlling the radiation pressure.

Tetsumoto, Tomohiro; Tanabe, Takasumi, E-mail: takasumi@elec.keio.ac.jp [Department of Electronics and Electrical Engineering, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi Kohoku, Yokohama 223-8522 (Japan)

2014-07-15T23:59:59.000Z

278

The NEXT experiment: A high pressure xenon gas TPC for neutrinoless double beta decay searches  

E-Print Network [OSTI]

Neutrinoless double beta decay is a hypothetical, very slow nuclear transition in which two neutrons undergo beta decay simultaneously and without the emission of neutrinos. The importance of this process goes beyond its intrinsic interest: an unambiguous observation would establish a Majorana nature for the neutrino and prove the violation of lepton number. NEXT is a new experiment to search for neutrinoless double beta decay using a radiopure high-pressure xenon gas TPC, filled with 100 kg of Xe enriched in Xe-136. NEXT will be the first large high-pressure gas TPC to use electroluminescence readout with SOFT (Separated, Optimized FuncTions) technology. The design consists in asymmetric TPC, with photomultipliers behind a transparent cathode and position-sensitive light pixels behind the anode. The experiment is approved to start data taking at the Laboratorio Subterr\\'aneo de Canfranc (LSC), Spain, in 2014.

D. Lorca; J. Martín-Albo; F. Monrabal; for the NEXT Collaboration

2012-10-15T23:59:59.000Z

279

Computations of high-pressure steam flow in the turbine bypass valve  

SciTech Connect (OSTI)

The objective of the present study is to investigate the steam flow behavior through the high-pressure turbine bypass valve. Efforts have mainly been directed at investigating the process of steam flow and property variations aforementioned bypass valve as well as to obtain correlations between the flow rate and the valve opening ratio. Modeling of the high-pressure turbulent steam flow was performed on a three-dimensional non-staggered grid system by employing the finite volume method and by solving the three-dimensional, turbulent, compressible Navier-Stokes, and energy equations. Through this research, numerous data have been acquired and analyzed. These efforts enable one to obtain a correlation data set for the valve opening versus flow rate coefficient of the valve. One of the significant accomplishments is to use the model presented here to further improve a design of a turbine bypass flow valve.

Amano, R.S.; Draxler, G.R.

1999-07-01T23:59:59.000Z

280

Engine having hydraulic and fan drive systems using a single high pressure pump  

DOE Patents [OSTI]

An engine comprises a hydraulic system attached to an engine housing that includes a high pressure pump and a hydraulic fluid flowing through at least one passageway. A fan drive system is also attached to the engine housing and includes a hydraulic motor and a fan which can move air over the engine. The hydraulic motor includes an inlet fluidly connected to the at least one passageway.

Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Ion current detector for high pressure ion sources for monitoring separations  

DOE Patents [OSTI]

The present invention relates generally to any application involving the monitoring of signal arising from ions produced by electrospray or other high pressure (>100 torr) ion sources. The present invention relates specifically to an apparatus and method for the detection of ions emitted from a capillary electrophoresis (CE) system, liquid chromatography, or other small-scale separation methods. And further, the invention provides a very simple diagnostic as to the quality of the separation and the operation of an electrospray source. 7 figs.

Smith, R.D.; Wahl, J.H.; Hofstadler, S.A.

1996-08-13T23:59:59.000Z

282

Impedance-matching experiments using high-pressure, laser-driven shock waves  

SciTech Connect (OSTI)

A high-power laser was used to produce shock waves with pressures of 300 to 700 GPa. A series of impedance-matching experiments on aluminum-copper systems with 10% accuracy indicate several areas in which the experiment can be improved to reduce the errors. Several such improvements are now being made, including upgrading both the laser and recording systems and modifying the target characterization techniques.

Veeser, L.R.; Reeves, G.A.; Holmes, N.C.; Trainor, R.J.; Anderson, R.A.

1981-01-01T23:59:59.000Z

283

Pb nanowire formation on Al/lead zirconate titanate surfaces in high-pressure hydrogen  

SciTech Connect (OSTI)

Thin films of Al on lead zirconate titanate (PZT) annealed in high-pressure hydrogen at 100C exhibit surface Pb nanowire growth. Wire diameter is approximately 80 nm and length can exceed 100 microns. Based on microstructural analysis using electron microscopy and ion scattering, a vapor-solid scheme with hydrogen as a carrier gas was proposed as a growth mechanism. We expect that these observations may lead to controlled Pb nanowires growth through pattering of the Al film.

Alvine, Kyle J.; Shutthanandan, V.; Arey, Bruce W.; Wang, Chong M.; Bennett, Wendy D.; Pitman, Stan G.

2012-07-12T23:59:59.000Z

284

Investigation of a high pressure implosive technique for metal powder compaction  

E-Print Network [OSTI]

Permanent Address ? 314 Brookside Dr. , Bryan, Texas 77801 Donald R. Garrett received his Bachelor of Science degree from the United States Military Academy in 1958. Mr. Garrett was a military training instructor in the U. S. A. F. and a jet aircraft in...INVESTIGATION OF A HIGH PRESSURE IMPLOSIVE TECHNIQUE FOR METAL POWDER COMPACTION A Thesis DONALD RICHARD GARRETT Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER...

Garrett, Donald Richard

1970-01-01T23:59:59.000Z

285

High-R Walls for New Construction Structural Performance: Wind Pressure Testing  

SciTech Connect (OSTI)

This technical report is focused primarily on laboratory testing that evaluates wind pressure performance characteristics for wall systems constructed with exterior insulating sheathing. This research and test activity will help to facilitate the ongoing use of non-structural sheathing options and provide a more in-depth understanding of how wall system layers perform in response to high wind perturbations normal to the surface.

DeRenzis, A.; Kochkin, V.

2013-01-01T23:59:59.000Z

286

Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

Moskovitz, Yevgeny [Middle Tennessee State University; Yang, Hui [Middle Tennessee State University

2015-01-01T23:59:59.000Z

287

High-pressure shock behavior of WC and Ta2O5 powders.  

SciTech Connect (OSTI)

Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

Knudson, Marcus D. (Sandia National Laboratories, Albuquerque, NM); Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Root, Seth (Sandia National Laboratories, Albuquerque, NM)

2011-10-01T23:59:59.000Z

288

Five-dimensional visualization of phase transition in BiNiO{sub 3} under high pressure  

SciTech Connect (OSTI)

Colossal negative thermal expansion was recently discovered in BiNiO{sub 3} associated with a low density to high density phase transition under high pressure. The varying proportion of co-existing phases plays a key role in the macroscopic behavior of this material. Here, we utilize a recently developed X-ray Absorption Near Edge Spectroscopy Tomography method and resolve the mixture of high/low pressure phases as a function of pressure at tens of nanometer resolution taking advantage of the charge transfer during the transition. This five-dimensional (X, Y, Z, energy, and pressure) visualization of the phase boundary provides a high resolution method to study the interface dynamics of high/low pressure phase.

Liu, Yijin, E-mail: liuyijin@slac.stanford.edu, E-mail: wyang@ciw.edu [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Wang, Junyue; Yang, Wenge, E-mail: liuyijin@slac.stanford.edu, E-mail: wyang@ciw.edu [Center of High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai 201203 (China); High Pressure Synergetic Consortium, Geophysical Laboratory, Carnegie Institution of Washington, 9700 S Cass Avenue, Argonne, Illinois 60439 (United States); Azuma, Masaki [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama 226-8503 (Japan); Mao, Wendy L. [Geological and Environmental Sciences, 450 Serra Mall, Stanford University, Stanford, California 94305 (United States); SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Photon Science, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States)

2014-01-27T23:59:59.000Z

289

Ultra high pressure liquid chromatography column permeability and changes of the eluent properties  

SciTech Connect (OSTI)

The behavior of four similar liquid chromatography columns (2.1 mm i.d. x30, 50, 100, and 150 mm, all packed with fine particles, average d{sub p} {approx} 1.7 {micro}m, of bridged ethylsiloxane/silica hybrid-C{sub 18}, named BEH-C{sub 18}) was studied in wide ranges of temperature and pressure. The pressure and the temperature dependencies of the viscosity and the density of the eluent (pure acetonitrile) along the columns were also derived, using the column permeabilities and applying the Kozeny-Carman and the heat balance equations. The heat lost through the external surface area of the chromatographic column was directly derived from the wall temperature of the stainless steel tube measured with a precision of C in still air and C in the oven compartment. The variations of the density and viscosity of pure acetonitrile as a function of the temperature and pressure was derived from empirical correlations based on precise experimental data acquired between 298 and 373 K and at pressures up to 1.5 kbar. The measurements were made with the Acquity UPLC chromatograph that can deliver a maximum flow rate of 2 mL/min and apply a maximum column inlet pressure of 1038 bar. The average Kozeny-Carman permeability constant of the columns was 144 {+-} 3.5%. The temperature hence the viscosity and the density profiles of the eluent along the column deviate significantly from linear behavior under high-pressure gradients. For a 1000 bar pressure drop, we measured {Delta}T = 25-30 K, ({Delta}{eta}/{eta}) {approx_equal} 100%, and ({Delta}{rho}/{rho}) {approx_equal} 10%. These results show that the radial temperature profiles are never fully developed within 1% for any of the columns, even under still-air conditions. This represents a practical advantage regarding the apparent column efficiency at high flow rates, since the impact of the differential analyte velocity between the column center and the column wall is not maximum. The interpretation of the peak profiles recorded in UPLC is discussed.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

2008-01-01T23:59:59.000Z

290

Effects of high pressure-dependent leakoff and high process-zone stress in coal-stimulation treatments  

SciTech Connect (OSTI)

Hydraulic fracturing in coals has been studied extensively over the last two decades; however, there are factors that were often ignored or incorrectly diagnosed, resulting in screenouts. Assuming that a majority of the perforations are open and there are no problems with the stimulation fluids, screenouts during coal hydraulic-fracture treatments can be attributed to either high pressure-dependent leakoff (PDL), high process-zone stress (PZS) or in some cases both. The objective of this work is to discuss, help identify, and present solutions to address these reservoir-related issues such that screenouts can be avoided in optimized refracture treatments and new well stimulations. The tools for identifying these reservoir-related parameters include a diagnostic fracture-injection test (DFIT) and a grid-oriented fully functional 3D fracture simulator with shear decoupling. An example for each respective case is presented in this paper. In the first example, in which high PZS was considered to be the dominant reason for screenout or pressure out, the well was restimulated successfully by implementing the solutions presented in this paper. In the second example, in which high PDL was considered to be the main reason for screenout, there were several wells in the same project area that exhibited the same behavior resulting in screenouts. After implementing the solutions presented in this paper to address high PDL, all new wells were stimulated successfully without any issues.

Ramurthy, M.; Lyons, B.; Hendrickson, R.B.; Barree, R.D.; Magill, D.R. [Halliburton, Denver, CO (United States)

2009-08-15T23:59:59.000Z

291

A diamond-window XAFS cell for studies of high-temperature, high-pressure aqueous solutions  

SciTech Connect (OSTI)

We describe a method to collect x-ray absorption fine structure (XAFS) spectra of ions in a supercritical water solvent. Supercritical water (SCW), at temperatures above water{close_quote}s critical point of 374{degree}C, is an interesting solvent for chemical reactions and hazardous waste destruction due to the high solubility of organics and the aggressive oxidizing environment. XAFS may provide a better understanding of the solvent environment in SCW. The XAFS cell used in these studies was composed of a block of high-nickel alloy, Hastelloy C-22, containing two windows for transmission of the x-ray beam and a single optical view window. All internal wetted surfaces were platinum plated. The maximum operating conditions for this design were 500{degree}C and 700 bar. The x-ray transmission windows consisted of CVD (chemical vapor deposition) diamond windows (3 mm diameter {times}0.5 mm thick) that were brazed to the tip of a standard 1/4-in. high-pressure, coned-shape fitting. Spectra are reported for strontium and rubidium ions in a supercritical water solvent. This cell design could be used for a variety of other solvent systems at high temperatures and high pressures. {copyright} {ital 1996 American Institute of Physics.}

Fulton, J.L.; Pfund, D.M. [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States)] [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States); Ma, Y. [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)] [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)

1996-09-01T23:59:59.000Z

292

High Sensitivity Combined with Extended Structural Coverage of Labile Compounds via Nanoelectrospray Ionization at Subambient Pressures  

SciTech Connect (OSTI)

Subambient pressure ionization with nanoelectrospray (SPIN) has proven to be effective in producing ions with high efficiency and transmitting them to low pressures for high sensitivity mass spectrometry (MS) analysis. Here we present evidence that not only does the SPIN source improve MS sensitivity but also allows for gentler ionization conditions. The gentleness of a conventional heated capillary electrospray ionization (ESI) source and the SPIN source was compared by the liquid chromatography mass spectrometry (LC-MS) analysis of colominic acid. Colominic acid is a mixture of sialic acid polymers of different lengths containing labile glycosidic linkages between monomer units necessitating a gentle ion source. By coupling the SPIN source with high resolution mass spectrometry and using advanced data processing tools, we demonstrate much extended coverage of sialic acid polymer chains as compared to using the conventional ESI source. Additionally we show that SPIN-LC-MS is effective in elucidating polymer features with high efficiency and high sensitivity previously unattainable by the conventional ESI-LC-MS methods. ?

Cox, Jonathan T.; Kronewitter, Scott R.; Shukla, Anil K.; Moore, Ronald J.; Smith, Richard D.; Tang, Keqi

2014-10-07T23:59:59.000Z

293

Apparatus and method for fatigue testing of a material specimen in a high-pressure fluid environment  

DOE Patents [OSTI]

The invention provides fatigue testing of a material specimen while the specimen is disposed in a high pressure fluid environment. A specimen is placed between receivers in an end cap of a vessel and a piston that is moveable within the vessel. Pressurized fluid is provided to compression and tension chambers defined between the piston and the vessel. When the pressure in the compression chamber is greater than the pressure in the tension chamber, the specimen is subjected to a compression force. When the pressure in the tension chamber is greater than the pressure in the compression chamber, the specimen is subjected to a tension force. While the specimen is subjected to either force, it is also surrounded by the pressurized fluid in the tension chamber. In some examples, the specimen is surrounded by hydrogen.

Wang, Jy-An; Feng, Zhili; Anovitz, Lawrence M; Liu, Kenneth C

2013-06-04T23:59:59.000Z

294

Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer  

SciTech Connect (OSTI)

The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

Babij, Micha?; Kowalski, Zbigniew W., E-mail: zbigniew.w.kowalski@pwr.wroc.pl; Nitsch, Karol; Gotszalk, Teodor [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland)] [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland); Silberring, Jerzy [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)] [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)

2014-05-15T23:59:59.000Z

295

Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle  

DOE Patents [OSTI]

The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

Butcher, Thomas A. (Port Jefferson, NY); Celebi, Yusuf (Middle Island, NY); Fisher, Leonard (Colrain, MA)

2000-09-15T23:59:59.000Z

296

Synthesis, structural characterization and high pressure phase transitions of monolithium hydronium sulfate  

SciTech Connect (OSTI)

A three dimensional lithium hydronium sulfate LiSO{sub 4}{center_dot}H{sub 3}O [1], [space group Pna2{sub 1}a=8.7785(12) A, b=9.1297(12) A, c=5.2799(7) A, V=423.16(10) A{sup 3}] was synthesized via solvothermal methods using 1,5-naphthalenedisulfonic acid (1,5-NSA) as the source of sulfate ions. The structure of [1], determined by single crystal X-ray diffraction techniques, consists of corner sharing LiO{sub 4} and SO{sub 4} tetrahedra, forming an anionic 3-D open framework that is charge balanced by hydronium ions positioned within channels running along [001] and forming strong H-bonding with the framework oxygen atoms. Compound [1] undergoes two reversible phase transitions, involving reorientation of SO{sub 4}{sup 2-} ions at pressures of approximately 2.5 and 5 GPa at room temperature, as evident from characteristic discontinuous frequency drops in the {nu}{sub 1} mode of the Raman spectra. Additionally, compound [1] forms dense {beta}-lithium sulfate at 300 Degree-Sign C, as evident from temperature dependent powder XRD and combined reversible TGA-DSC experiments. - Graphical abstract: Left: View of corner-shared LiO{sub 4} and SO{sub 4} tetrahedra along [001] direction with hydronium ions situated in the channels. Right: (a) Photograph of the loaded DAC (b) Ambient pressure Raman spectrum of compound [1] (c) Evolution of the {nu}{sub 1} mode with the increasing and decreasing pressure indicating transitions to high-pressure phases at {approx}2.5 (red curves) and {approx}5 GPa (blue curves) and at {approx}3.5 GPa upon decompression. Highlights: Black-Right-Pointing-Pointer A 3-D lithium hydronium sulfate is synthesized by solvothermal methods. Black-Right-Pointing-Pointer Two high pressure phase transition occurs due to rotation of sulfate groups. Black-Right-Pointing-Pointer The framework undergoes a high temperature structural transformation, to form {beta}-Li{sub 2}SO{sub 4} phase.

Banerjee, Debasis, E-mail: debasis.banerjee@stonybrook.edu [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Plonka, Anna M. [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Kim, Sun Jin [Nano-Materials Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650 (Korea, Republic of); Xu Wenqian [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Parise, John B. [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Mineral Physics Institute, Stony Brook University, Stony Brook, NY 11790-2100 (United States)

2013-01-15T23:59:59.000Z

297

Trace element partitioning between baddeleyite and carbonatite melt at high pressures and high temperatures  

E-Print Network [OSTI]

as the heavy rare earth elements (HREE) prefer to enter baddeleyite rather than carbonate melts (D>1), whereas the light rare earth elements (LREE) and other trace elements behave incompatibly (D in carbonatite melts. Baddeleyite is known to accumulate the high field strength elements (HFSE) and some rare

298

High-temperature treatment of In-doped CZT crystals grown by the high-pressure Bridgman method  

SciTech Connect (OSTI)

We evaluated the effect of high-temperature treatment of Cd0.9Zn0.1Te:In single crystals using Hall-effect measurements, medium- and high-temperature annealing under various deviations from stoichiometry, and infra-red (IR) transmission microscopy Annealing at ~730 K sharply increased the electrical conductivity (by ~1-2 orders-of-magnitude). Plots of the temperature- and cadmium-pressure dependences of the electrical conductivity, carrier concentration, and mobility were obtained. Treating previously annealed Cd-samples under a Te overpressure at 1070 K allowed us to restore their resistance to its initial high values. The main difference in comparing this material with CdTe was its lowered electron density. We explained our results within the framework of Kröger’s theory of quasi-chemical reactions between point defects in solids.

Bolotnikov A.; Fochuk, P.; Nakonechnyi, I.; Kopach, O.; Verzhak, Ye.; Panchuk, O.; Komar, V.; Terzin, I.; Kutnij, V.; Rybka, A.; Nykoniuk, Ye.; Camarda, G.C.; Cui, Y.; Hossain, A.; Kim, K.H.; Yang, G.; James, R.B.

2012-08-12T23:59:59.000Z

299

Complete temperature profiles in ultra-high pressure liquid chromatography columns  

SciTech Connect (OSTI)

The temperature profiles were calculated along and across seven packed columns (lengths 30, 50, 100, and 150 mm, i.d., 1 and 2.1 mm, all packed with Acquity UPLC, BEH-C{sub 18} particles, average d{sub p} {approx} 1.7 {micro}m) and their stainless steel tubes (o.d. 4.53 and 6.35 mm). These columns were kept horizontal and sheltered from forced air convection (i.e., under still air conditions), at room temperature. They were all percolated with pure acetonitrile, either under the maximum pressure drop (1034 bar) or at the maximum flow rate (2 mL/min) permitted by the chromatograph. The heat balance equation of chromatographic columns was discretized and solved numerically with minimum approximation. Both the compressibility and the thermal expansion of the eluent were taken into account. The boundary conditions were determined from the experimental measurements of the column inlet pressure and of the temperature profile along the column wall, which were made with a precision better than {+-}0.1 K. These calculation results provide the 3-D temperature profiles along and across the columns. The axial and radial temperature gradients are discussed in relationship with the experimental conditions used. The temperature map obtained permits a prediction of the chromatographic data obtained under a very high pressure gradient.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

2008-01-01T23:59:59.000Z

300

Use of Z-pinch sources for high-pressure shock wave studies  

SciTech Connect (OSTI)

In this paper, we will discuss the use of z-pinch sources for shock wave studies at multi-Mbar pressures. Experimental plans to use the technique for absolute shock Hugoniot measurements are discussed. Recent developments have demonstrated the use of pulsed power techniques for producing intense radiation sources (Z pinches) for driving planar shock waves in samples with spatial dimensions significantly larger than possible with other radiation sources. Initial indications are that using Z pinch sources for producing Planckian radiation sources in secondary hohlraums can be used to drive shock waves in samples with diameters to a few millimeters and thickness approaching one millimeter in thickness. These dimensions provides the opportunity to measure both shock velocity and the particle velocity behind the shock front with accuracy comparable to that obtained with gun launchers. In addition, the peak hohlraum temperatures of nearly 150 eV that are now possible with Z pinch sources result in shock wave pressures approaching 45 Mbar in high impedance materials such as tungsten and 10-15 Mbar in low impedance materials such as aluminum and plastics. In this paper, we discuss the use of Z pinch sources for making accurate absolute EOS measurements in the megabar pressure range.

Konrad, C.H.; Asay, J.R.; Hall, C.A. [and others

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
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301

“Multi-temperature” method for high-pressure sorption measurements on moist shales  

SciTech Connect (OSTI)

A simple and effective experimental approach has been developed and tested to study the temperature dependence of high-pressure methane sorption in moist organic-rich shales. This method, denoted as “multi-temperature” (short “multi-T”) method, enables measuring multiple isotherms at varying temperatures in a single run. The measurement of individual sorption isotherms at different temperatures takes place in a closed system ensuring that the moisture content remains constant. The multi-T method was successfully tested for methane sorption on an organic-rich shale sample. Excess sorption isotherms for methane were measured at pressures of up to 25 MPa and at temperatures of 318.1 K, 338.1 K, and 348.1 K on dry and moisture-equilibrated samples. The measured isotherms were parameterized with a 3-parameter Langmuir-based excess sorption function, from which thermodynamic sorption parameters (enthalpy and entropy of adsorption) were obtained. Using these, we show that by taking explicitly into account water vapor as molecular species in the gas phase with temperature-dependent water vapor pressure during the experiment, more meaningful results are obtained with respect to thermodynamical considerations. The proposed method can be applied to any adsorbent system (coals, shales, industrial adsorbents) and any supercritical gas (e.g., CH{sub 4}, CO{sub 2}) and is particularly suitable for sorption measurements using the manometric (volumetric) method.

Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Krooss, Bernhard M. [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)] [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)

2013-08-15T23:59:59.000Z

302

Low loss hollow optical-waveguide connection from atmospheric pressure to ultra-high vacuum  

SciTech Connect (OSTI)

A technique for optically accessing ultra-high vacuum environments, via a photonic-crystal fiber with a long small hollow core, is described. The small core and the long bore enable a pressure ratio of over 10{sup 8} to be maintained between two environments, while permitting efficient and unimpeded delivery of light, including ultrashort optical pulses. This delivery can be either passive or can encompass nonlinear optical processes such as optical pulse compression, deep UV generation, supercontinuum generation, or other useful phenomena.

Ermolov, A.; Mak, K. F.; Tani, F.; Hölzer, P.; Travers, J. C. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)] [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Russell, P. St. J. [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany) [Max Planck Institute for the Science of Light, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany); Department of Physics, University of Erlangen-Nuremberg, Günther-Scharowsky-Str. 1, 91058 Erlangen (Germany)

2013-12-23T23:59:59.000Z

303

High-pressure coal fuel processor development. Task 1, Proof of principle testing  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

304

A compact bellows-driven diamond anvil cell for high-pressure, low-temperature magnetic measurements  

SciTech Connect (OSTI)

We present the design of an efficient bellows-controlled diamond anvil cell that is optimized for use inside the bores of high-field superconducting magnets in helium-3 cryostats, dilution refrigerators, and commercial physical property measurement systems. Design of this non-magnetic pressure cell focuses on in situ pressure tuning and measurement by means of a helium-filled bellows actuator and fiber-coupled ruby fluorescence spectroscopy, respectively. We demonstrate the utility of this pressure cell with ac susceptibility measurements of superconducting, ferromagnetic, and antiferromagnetic phase transitions to pressures exceeding 8 GPa. This cell provides an opportunity to probe charge and magnetic order continuously and with high resolution in the three-dimensional Magnetic Field–Pressure–Temperature parameter space.

Feng, Yejun [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States) [The Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States); Silevitch, D. M.; Rosenbaum, T. F. [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)] [The James Franck Institute and Department of Physics, The University of Chicago, Chicago, Illinois 60637 (United States)

2014-03-15T23:59:59.000Z

305

High-Throughput Thin Film Approach for Screening of Temperature-Pressure-Composition Phase Space  

SciTech Connect (OSTI)

Many solar energy technologies, for example CIGS and CdTe photovoltaics, utilize materials in thin film form. The equilibrium phase diagrams for these and other more novel solar energy materials are not known or are irrelevant because of the non-equilibrium character of the thin film growth processes. We demonstrate a high-throughput thin film approach for screening of temperature-pressure-composition phase diagrams and phase spaces. The examples in focus are novel solar absorbers Cu-N, Cu-O and p-type transparent conductors in the Cr2O3-MnO system. The composition axis of the Cr2O3-MnO phase diagram was screened using a composition spread method. The temperature axis of the Mn-O phase diagram was screened using a temperature spread method. The pressure axes of the Cu-N and Cu-O phase diagrams were screened using rate spread method with the aid of non-equilibrium growth phenomena. Overall these three methods constitute an approach to high-throughput screening of inorganic thin film phase diagrams. This research is supported by U.S. Department of Energy as a part of two NextGen Sunshot projects and an Energy Frontier Research Center.

Zakutayev, A.; Subramaniyan, A.; Caskey, C. M.; Ndione, P. F.; Richards, R. M.; O'Hayre, R.; Ginley, D. S.

2013-01-01T23:59:59.000Z

306

Evolution of Nickel-Manganese-Silicon Dominated Phases in Highly Irradiated Reactor Pressure Vessel Steels  

SciTech Connect (OSTI)

Formation of a high density of Ni-Mn-Si nm-scale precipitates in irradiated reactor pressure vessel steels, both with and without Cu, could lead to severe embrittlement. Models long ago predicted that these precipitates, which are not treated in current embrittlement regulations, would emerge only at high fluence. However, the mechanisms and variables that control Ni-Mn- Si precipitate formation, and their detailed characteristics, have not been well understood. High flux irradiations of six steels with systematic variations in Cu and Ni were carried out at ˜ 295±5°C to high and very high neutron fluences of ˜ 1.3x1020 and 1.1x1021 n/cm2. Atom probe tomography (APT) shows that significant mole fractions of these precipitates form in the Cu bearing steels at ˜ 1.3x1020 n/cm2, while they are only beginning to develop in Cu-free steels. However, large mole fractions, far in excess of those found in previous studies, are observed at 1.1x1021 n/cm2 at all Cu levels. The precipitates diffract, and in one case are compositionally and structurally consistent with the Mn6Ni16Si7 G-phase. At the highest fluence, the large precipitate mole fractions primarily depend on the steel Ni content, rather than Cu, and lead to enormous strength increases up to about 700 MPa. The implications of these results to light water reactor life extension are discussed briefly.

Peter B Wells; Yuan Wu; Tim Milot; G. Robert Odette; Takuya Yamamoto; Brandon Miller; James Cole

2014-11-01T23:59:59.000Z

307

Engineering development of a lightweight high-pressure scarifier for tank waste retrieval  

SciTech Connect (OSTI)

The Retrieval Process Development and Enhancements Program (RPD&E) is sponsored by the U.S. Department of Energy Tanks Focus Area to investigate existing and emerging retrieval processes suitable for the retrieval of high-level radioactive waste inside underground storage tanks. This program, represented by industry, national laboratories, and academia, seeks to provide a technical and cost basis to support site-remediation decisions. Part of this program has involved the development of a high-pressure waterjet dislodging system and pneumatic conveyance integrated as a scarifier. Industry has used high-pressure waterjet technology for many years to mine, cut, clean, and scarify materials with a broad range of properties. The scarifier was developed as an alternate means of retrieving waste inside Hanford single-shell tanks, particularly hard, stubborn waste. Testing of the scarifier has verified its ability to retrieve a wide range of tank waste ranging from extremely hard waste that is resistant to other dislodging means to soft sludge and even supernatant fluid. Since the scarifier expends water at a low rate and recovers most of the water as it is used, the scarifier is well suited for retrieval of tanks that leak and cannot be safely sluiced or applications where significant waste dilution is not acceptable. Although the original scarifier was effective, it became evident that a lighter, more compact version that would be compatible with light weight deployment systems under development, such as the Light Duty Utility Arm, was needed. At the end of FY 95, the Light Weight Scarifier (LWS) was designed to incorporate the features of the original scarifier in a smaller, lighter end effector. During FY 96, the detailed design of the LWS was completed and two prototypes were fabricated.

Hatchell, B.K.

1997-09-01T23:59:59.000Z

308

The deterioration in heat transfer to fluids at supercritical pressure and high heat fluxes  

E-Print Network [OSTI]

At slightly supercritical pressure and in the neighborhood of the pseudo-critical temperature (defined as the temperature corresponding to the peak in specific heat at the operating pressure), the heat transfer coefficient ...

Shiralkar, B. S.

1968-01-01T23:59:59.000Z

309

Experimental observation of standing wave effect in low-pressure very-high-frequency capacitive discharges  

SciTech Connect (OSTI)

Radial uniformity measurements of plasma density were carried out by using a floating double probe in a cylindrical (21?cm in electrode diameter) capacitive discharge reactor driven over a wide range of frequencies (27–220 MHz). At low rf power, a multiple-node structure of standing wave effect was observed at 130?MHz. The secondary density peak caused by the standing wave effect became pronounced and shifts toward the axis as the driving frequency further to increase, indicative of a much more shortened standing-wave wavelength. With increasing rf power, the secondary density peak shift toward the radial edge, namely, the standing-wave wavelength was increased, in good qualitative agreement with the previous theory and simulation results. At higher pressures and high frequencies, the rf power was primarily deposited at the periphery of the electrode, due to the fact that the waves were strongly damped as they propagated from the discharge edge into the center.

Liu, Yong-Xin; Gao, Fei; Liu, Jia; Wang, You-Nian, E-mail: ynwang@dlut.edu.cn [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

2014-07-28T23:59:59.000Z

310

Energy savings with solid-state ballasted high-pressure sodium lamps  

SciTech Connect (OSTI)

The performance of three types of solid-state ballasts used to operate high-pressure sodium lamps is discussed. Each type of solid-state ballast has been designed to operate an HPS lamp of a different wattage (150, 200, and 400 watts). The performance of these ballasts compared to standard core-coil ballasts operating the same HPS lamps shows that system efficiency improves as much as 17%. The solid-state ballasted HPS system also demonstrates excellent regulation with respect to input voltage and output power. These new ballasts can dim the HPS lamps and reduce flicker from more than 60% to less than 3%. Refitting street lighting with these new HPS systims provides an attractive return on initial capital investment.

Verderber, R.R.; Morse, O.

1981-04-01T23:59:59.000Z

311

Dynamics of multiple double layers in high pressure glow discharge in a simple torus  

SciTech Connect (OSTI)

Parametric characterization of multiple double layers is done during high pressure glow discharge in a toroidal vessel of small aspect ratio. Although glow discharge (without magnetic field) is known to be independent of device geometry, but the toroidal boundary conditions are conducive to plasma growth and eventually the plasma occupy the toroidal volume partially. At higher anode potential, the visibly glowing spots on the body of spatially extended anode transform into multiple intensely luminous spherical plasma blob structures attached to the tip of the positive electrode. Dynamics of multiple double layers are observed in argon glow discharge plasma in presence of toroidal magnetic field. The radial profiles of plasma parameters measured at various toroidal locations show signatures of double layer formation in our system. Parametric dependence of double layer dynamics in presence of toroidal magnetic field is presented here.

Kumar Paul, Manash, E-mail: manashkr@gmail.com [Department of Physics, National Institute of Technology Agartala, Tripura–799 046 (India); Sharma, P. K.; Thakur, A.; Kulkarni, S. V.; Bora, D. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat–382 428 (India)

2014-06-15T23:59:59.000Z

312

Autoignition of toluene reference fuels at high pressures modeled with detailed chemical kinetics  

SciTech Connect (OSTI)

A detailed chemical kinetic model for the autoignition of toluene reference fuels (TRF) is presented. The toluene submechanism added to the Lawrence Livermore Primary Reference Fuel (PRF) mechanism was developed using recent shock tube autoignition delay time data under conditions relevant to HCCI combustion. For two-component fuels the model was validated against recent high-pressure shock tube autoignition delay time data for a mixture consisting of 35% n-heptane and 65% toluene by liquid volume. Important features of the autoignition of the mixture proved to be cross-acceleration effects, where hydroperoxy radicals produced during n-heptane oxidation dramatically increased the oxidation rate of toluene compared to the case when toluene alone was oxidized. Rate constants for the reaction of benzyl and hydroperoxyl radicals previously used in the modeling of the oxidation of toluene alone were untenably high for modeling of the mixture. To model both systems it was found necessary to use a lower rate and introduce an additional branching route in the reaction between benzyl radicals and O{sub 2}. Good agreement between experiments and predictions was found when the model was validated against shock tube autoignition delay data for gasoline surrogate fuels consisting of mixtures of 63-69% isooctane, 14-20% toluene, and 17% n-heptane by liquid volume. Cross reactions such as hydrogen abstractions between toluene and alkyl and alkylperoxy radicals and between the PRF were introduced for completion of chemical description. They were only of small importance for modeling autoignition delays from shock tube experiments, even at low temperatures. A single-zone engine model was used to evaluate how well the validated mechanism could capture autoignition behavior of toluene reference fuels in a homogeneous charge compression ignition (HCCI) engine. The model could qualitatively predict the experiments, except in the case with boosted intake pressure, where the initial temperature had to be increased significantly in order to predict the point of autoignition. (author)

Andrae, J.C.G. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom); Bjoernbom, P. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Cracknell, R.F.; Kalghatgi, G.T. [Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom)

2007-04-15T23:59:59.000Z

313

High-pressure X-ray diffraction and X-ray emission studies on iron-bearing silicate perovskite under high pressures  

SciTech Connect (OSTI)

Iron-bearing silicate perovskite is believed to be the most abundant mineral of the Earth's lower mantle. Recent studies have shown that Fe{sup 2+} exists predominantly in the intermediate-spin state with a total spin number of 1 in silicate perovskite in the lower part of the lower mantle. Here we have measured the spin states of iron and the pressure-volume relation in silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}] at pressure conditions relevant to the lowermost mantle using in situ X-ray emission and X-ray diffraction in a diamond cell. Our results showed that the intermediate-spin Fe{sup 2+} is stable in the silicate perovskite up to {approx} 125 GPa but starts to transition to the low-spin state at approximately 135 GPa. Concurrent X-ray diffraction measurements showed a decrease of approximately 1% in the unit cell volume in the silicate perovskite [(Mg{sub 0.6},Fe{sub 0.4})SiO{sub 3}], which is attributed to the intermediate-spin to the low-spin transition. The transition pressure coincides with the pressure conditions of the lowermost mantle, raising the possibility of the existence of the silicate perovskite phase with the low-spin Fe{sup 2+} across the transition from the post-perovskite to the perovskite phases in the bottom of the D{double_prime} layer.

Lin, Jung-Fu; Speciale, Sergio; Prakapenka, Vitali B.; Dera, Przemek; Lavina, Babara; Watson, Heather C. (NIU); (UC); (Texas); (GFZ)

2010-06-22T23:59:59.000Z

314

High pressure elastic properties of minerals from ab initio simulations: The case of pyrope, grossular and andradite silicate garnets  

SciTech Connect (OSTI)

A computational strategy is devised for the accurate ab initio simulation of elastic properties of crystalline materials under pressure. The proposed scheme, based on the evaluation of the analytical stress tensor and on the automated computation of pressure-dependent elastic stiffness constants, is implemented in the CRYSTAL solid state quantum-chemical program. Elastic constants and related properties (bulk, shear and Young moduli, directional seismic wave velocities, elastic anisotropy index, Poisson's ratio, etc.) can be computed for crystals of any space group of symmetry. We apply such a technique to the study of high-pressure elastic properties of three silicate garnet end-members (namely, pyrope, grossular, and andradite) which are of great geophysical interest, being among the most important rock-forming minerals. The reliability of this theoretical approach is proved by comparing with available experimental measurements. The description of high-pressure properties provided by several equations of state is also critically discussed.

Erba, A., E-mail: alessandro.erba@unito.it; Mahmoud, A.; Dovesi, R. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy)] [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Università di Torino, via Giuria 5, IT-10125 Torino (Italy); Belmonte, D. [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)] [DISTAV, Università di Genova, Corso Europa 26, 16132 Genoa (Italy)

2014-03-28T23:59:59.000Z

315

Advanced Production Surface Preparation Technology Development for Ultra-High Pressure Diesel Injection  

SciTech Connect (OSTI)

In 2007, An Ultra High Injection Pressure (UHIP) fueling method has been demonstrated by Caterpillar Fuel Systems - Product Development, demonstrating ability to deliver U.S. Environment Protection Agency (EPA) Tier 4 Final diesel engine emission performance with greatly reduced emissions handling components on the engine, such as without NOx reduction after-treatment and with only a through-flow 50% effective diesel particulate trap (DPT). They have shown this capability using multiple multi-cylinder engine tests of an Ultra High Pressure Common Rail (UHPCR) fuel system with higher than traditional levels of CEGR and an advanced injector nozzle design. The system delivered better atomization of the fuel, for more complete burn, to greatly reduce diesel particulates, while CEGR or high efficiency NOx reduction after-treatment handles the NOx. With the reduced back pressure of a traditional DPT, and with the more complete fuel burn, the system reduced levels of fuel consumption by 2.4% for similar delivery of torque and horsepower over the best Tier 4 Interim levels of fuel consumption in the diesel power industry. The challenge is to manufacture the components in high-volume production that can withstand the required higher pressure injection. Production processes must be developed to increase the toughness of the injector steel to withstand the UHIP pulsations and generate near perfect form and finish in the sub-millimeter size geometries within the injector. This project resulted in two developments in 2011. The first development was a process and a machine specification by which a high target of compressive residual stress (CRS) can be consistently imparted to key surfaces of the fuel system to increase the toughness of the steel, and a demonstration of the feasibility of further refinement of the process for use in volume production. The second development was the demonstration of the feasibility of a process for imparting near perfect, durable geometry to these same feature surfaces to withstand the pulsating UHIP diesel injection without fatigue failure, through the expected life of the fuel system's components (10,000 hours for the pump and common rail, 5000 hours for the injector). The potential to Caterpillar of this fueling approach and the overall emissions reduction system is the cost savings of the fuel, the cost savings of not requiring a full emissions module and other emissions hardware, and the enabling of the use of biodiesel fuel due to the reduced dependency on after-treatment. A proprietary production CRS generating process was developed to treat the interior of the sac-type injector nozzle tip region (particularly for the sac region). Ninety-five tips passed ultra high pulsed pressure fatigue testing with no failures assignable to treated surfaces or materials. It was determined that the CRS impartation method does not weaken the tip internal seat area. Caterpillar Fuel Systems - Product Development accepts that the CRS method initial production technical readiness level has been established. A method to gage CRS levels in production was not yet accomplished, but it is believed that monitoring process parameters call be used to guarantee quality. A precision profiling process for injector seat and sac regions has been shown to be promising but not yet fully confirmed. It was demonstrated that this precision profiling process can achieve form and geometry to well under an aggressively small micron peak-to-valley and that there are no surface flaws that approach an even tighter micron peak-to-valley tolerance. It is planned to purchase machines to further develop and move the process towards production. The system is targeted towards the high-power diesel electric power generators and high-power diesel marine power generators, with displacement from 20 liters to 80 liters and with power from 800 brake horsepower (BHP) to 3200BHP (0.6 megawatts to 2.4 megawatts). However, with market adoption, this system has the potential to meet EPA exhaust standards for all diesel engines nine liters and up, or 300B

Grant, Marion B.

2012-04-30T23:59:59.000Z

316

Advanced Models of LWR Pressure Vessel Embrittlement for Low Flux-HighFluence Conditions  

SciTech Connect (OSTI)

Neutron embrittlement of reactor pressure vessels (RPVs) is an unresolved issue for light water reactor life extension, especially since transition temperature shifts (TTS) must be predicted for high 80-year fluence levels up to approximately 1,020 n/cm{sup 2}, far beyond the current surveillance database. Unfortunately, TTS may accelerate at high fluence, and may be further amplified by the formation of late blooming phases that result in severe embrittlement even in low-copper (Cu) steels. Embrittlement by this mechanism is a potentially significant degradation phenomenon that is not predicted by current regulatory models. This project will focus on accurately predicting transition temperature shifts at high fluence using advanced physically based, empirically validated and calibrated models. A major challenge is to develop models that can adjust test reactor data to account for flux effects. Since transition temperature shifts depend on synergistic combinations of many variables, flux-effects cannot be treated in isolation. The best current models systematically and significantly under-predict transition temperature at high fluence, although predominantly for irradiations at much higher flux than actual RPV service. This project will integrate surveillance, test reactor and mechanism data with advanced models to address a number of outstanding RPV embrittlement issues. The effort will include developing new databases and preliminary models of flux effects for irradiation conditions ranging from very low (e.g., boiling water reactor) to high (e.g., accelerated test reactor). The team will also develop a database and physical models to help predict the conditions for the formation of Mn-Ni-Si late blooming phases and to guide future efforts to fully resolve this issue. Researchers will carry out other tasks on a best-effort basis, including prediction of transition temperature shift attenuation through the vessel wall, remediation of embrittlement by annealing, and fracture toughness master curve issues.

Odette, G. Robert; Yamamoto, Takuya

2013-06-17T23:59:59.000Z

317

High pressure synthesis of late rare earth RFeAs(O,F) superconductors; R = Tb and Dy   

E-Print Network [OSTI]

New TbFeAs(O,F) and DyFeAs(O,F) superconductors with critical temperatures T-c = 46 and 45 K and very high critical fields, >= 100 T, have been prepared at 1100-1150 degrees C and 10-12 GPa, demonstrating that high pressure may be used to synthesise...

Attfield, J.P.; Huxley A.D.; Sokolov D.A.; Rodgers J.A.; Penny G.B.S.; Bos J.W.G.

2008-01-01T23:59:59.000Z

318

ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR OXIDATION  

E-Print Network [OSTI]

ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR) by devolatilizing Pittsburgh #8 coal at #12;ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) high

Fletcher, Thomas H.

319

Real-gas effects in the expansibility factor for subsonic differential-pressure flowmeters at high pressure  

SciTech Connect (OSTI)

Real-gas corrections in the expansibility factor are expressed by an equation of state (EOS). In this paper a virial EOS is introduced, with low-order virial coefficients calculated from a cubic EOS. The approach is composition-independent. EOS-dependent cancellations between real-gas effects are revealed. The current Intl. Organization for Standardization (ISO) standard is not always reliable for high-accuracy orifice measurements of gases with arbitrary composition.

Finjord, J. (Rogaland U. Center (NO))

1991-08-01T23:59:59.000Z

320

High Temperature and Pressure Steam-H2 Interaction with Candidate Advanced LWR Fuel Claddings  

SciTech Connect (OSTI)

This report summarizes the work completed to evaluate cladding materials that could serve as improvements to Zircaloy in terms of accident tolerance. This testing involved oxidation resistance to steam or H{sub 2}-50% steam environments at 800-1350 C at 1-20 bar for short times. A selection of conventional alloys, SiC-based ceramics and model alloys were used to explore a wide range of materials options and provide guidance for future materials development work. Typically, the SiC-based ceramic materials, alumina-forming alloys and Fe-Cr alloys with {ge}25% Cr showed the best potential for oxidation resistance at {ge}1200 C. At 1350 C, FeCrAl alloys and SiC remained oxidation resistant in steam. Conventional austenitic steels do not have sufficient oxidation resistance with only {approx}18Cr-10Ni. Higher alloyed type 310 stainless steel is protective but Ni is not a desirable alloy addition for this application and high Cr contents raise concern about {alpha}{prime} formation. Higher pressures (up to 20.7 bar) and H{sub 2} additions appeared to have a limited effect on the oxidation behavior of the most oxidation resistant alloys but higher pressures accelerated the maximum metal loss for less oxidation resistant steels and less metal loss was observed in a H{sub 2}-50%H{sub 2}O environment at 10.3 bar. As some of the results regarding low-alloyed FeCrAl and Fe-Cr alloys were unexpected, further work is needed to fundamentally understand the minimum Cr and Al alloy contents needed for protective behavior in these environments in order to assist in alloy selection and guide alloy development.

Pint, Bruce A [ORNL

2012-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

High-Pressure Micellar Solutions of Symmetric and Asymmetric Styrene?Diene Diblocks in Compressible Near Critical Solvents: Micellization Pressures and Cloud Pressures Respond but Micellar Cloud Pressures Insensitive to Copolymer Molecular Weight, Concentration, and Block Ratio Changes  

SciTech Connect (OSTI)

Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical nonmicellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Concentration-dependent pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size, and ratio. The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

Winoto, Winoto [University of Wyoming, Laramie; Tan, Sugata [University of Wyoming, Laramie; Shen, Youqin [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

2009-01-01T23:59:59.000Z

322

Time resolved optical spectroscopy to examine chemical decomposition of energetic materials under static high pressure and pulsed heating conditions  

SciTech Connect (OSTI)

The study of the deflagration or detonation reactions of energetic materials is challenging due to the high pressure, high temperature, and time domain under which the reactions occur. Experimental measurements are presented that demonstrate the ability to continuously monitor the global reaction times and reaction sequences associated with chemical reactions under these conditions. Time resolved absorption spectroscopy is used in conjunction with a high pressure gem anvil cell to probe the real-time chemical processes during pulsed-heating. Samples are initiated by a rapid thermal jump induced by absorption of a single laser pulse. Time resolved absorption spectroscopy of 3,6 trinitroethylamine tetrazine reaction is demonstrated by the real time measurement of the decrease in the {pi}-{pi}* absorption at 100 ns temporal resolution during laser heating at pressures up to 3.5 GPa.

Russell, T.P. [Naval Research Lab., Washington, DC (United States). Chemistry Div.; Allen, T.M.; Gupta, Y.M. [Washington State Univ., Pullman, WA (United States). Shock Dynamics Center

1996-07-01T23:59:59.000Z

323

High-pressure Storage Vessels for Hydrogen, Natural Gas andHydrogen...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Gas and Blends - Materials Testing and Design Requirements for Hydrogen Components and Tanks International Hydrogen Fuel and Pressure Vessel Forum 2010 Proceedings Hydrogen...

324

The effect of high-pressure injection of gas on the reservoir volume factor of a crude oil  

E-Print Network [OSTI]

THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By+ BAXTER DS'kONEYCUTT o Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August, i957 Major Subject: Petroleum Engineering THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By BAXTER D. HONEYCUTT Appro d as to style...

Honeycutt, Baxter Bewitt

1957-01-01T23:59:59.000Z

325

High-Efficiency, Ultra-High Pressure Electrolysis With Direct Linkage to PV Arrays - Phase II SBIR Final Report  

SciTech Connect (OSTI)

In this Phase II SBIR, Avalence LLC met all proposed objectives. Because the original Phase III partner pulled out of the project, several alternative sites/partners were used to achieve the goals. The on-site operation and PV measurements were performed on a smaller unit at General Motors proving grounds in Milford, MI. The actual equipment targeted for AC Transit will be delivered to Robins Air Force Base in September of 2009 to support the fueling of a fuel cell powered fork lift and 'Bobcat'. In addition the Transit Agency Site Requirements and Constraints were performed for the Greater New Haven Transit District (GNHTD) for the Hamden, CT Public Works building that will be the site for a similar fueling station to be delivered in the Spring of 2010. The Detailed Design Package was also based on the Design for the GNHTD unit. The work on this project successfuly demonstrated the potential of Avalence's high pressure technology to address the need for renewably produced hydrogen fuel for transportation applications. Several follow-on projects in a numerber of related applications are now underway as a result of this SBIR project.

Martin A Shimko

2009-08-08T23:59:59.000Z

326

Novel, fiber optic, hybrid pressure and temperature sensor designed for high-temperature gen-IV reactor applications  

SciTech Connect (OSTI)

A novel, fiber optic, hybrid pressure-temperature sensor is presented. The sensor is designed for reliable operation up to 1050 C, and is based on the high-temperature fiber optic sensors already demonstrated during previous work. The novelty of the sensors presented here lies in the fact that pressure and temperature are measured simultaneously with a single fiber and a single transducer. This hybrid approach will enable highly accurate active temperature compensation and sensor self-diagnostics not possible with other platforms. Hybrid pressure and temperature sensors were calibrated by varying both pressure and temperature. Implementing active temperature compensation resulted in a ten-fold reduction in the temperature-dependence of the pressure measurement. Sensors were also tested for operability in a relatively high neutron radiation environment up to 6.9x10{sup 17} n/cm{sup 2}. In addition to harsh environment survivability, fiber optic sensors offer a number of intrinsic advantages for nuclear power applications including small size, immunity to electromagnetic interference, self diagnostics / prognostics, and smart sensor capability. Deploying fiber optic sensors on future nuclear power plant designs would provide a substantial improvement in system health monitoring and safety instrumentation. Additional development is needed, however, before these advantages can be realized. This paper will highlight recent demonstrations of fiber optic sensors in environments relevant to emerging nuclear power plants. Successes and lessons learned will be highlighted. (authors)

Palmer, M. E.; Fielder, R. S.; Davis, M. A. [Luna Innovations, Incorporated, 2851 Commerce St., Blacksburg, VA 24060 (United States)

2006-07-01T23:59:59.000Z

327

First principle study of elastic and thermodynamic properties of FeB{sub 4} under high pressure  

SciTech Connect (OSTI)

The elastic properties, elastic anisotropy, and thermodynamic properties of the lately synthesized orthorhombic FeB{sub 4} at high pressures are investigated using first-principles density functional calculations. The calculated equilibrium parameters are in good agreement with the available experimental and theoretical data. The obtained normalized volume dependence of high pressure is consistent with the previous experimental data investigated using high-pressure synchrotron x-ray diffraction. The complete elastic tensors and crystal anisotropies of the FeB{sub 4} are also determined in the pressure range of 0–100?GPa. By the elastic stability criteria and vibrational frequencies, it is predicted that the orthorhombic FeB{sub 4} is stable up to 100 GPa. In addition, the calculated B/G ratio reveals that FeB{sub 4} possesses brittle nature in the range of pressure from 0 to 100?GPa. The calculated elastic anisotropic factors suggest that FeB{sub 4} is elastically anisotropic. By using quasi-harmonic Debye model, the compressibility, bulk modulus, the coefficient of thermal expansion, the heat capacity, and the Grüneisen parameter of FeB{sub 4} are successfully obtained in the present work.

Zhang, Xinyu, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn; Ning, Jinliang; Sun, Xiaowei; Li, Xinting; Ma, Mingzhen; Liu, Riping, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Qin, Jiaqian, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330 (Thailand); State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China)

2013-11-14T23:59:59.000Z

328

Inter-stage and Performance Tests of a Two-stage High-pressure Turbine  

E-Print Network [OSTI]

traverse system in TPFL. Performance tests were conducted for varying pressure ratio, at fixed rotational speed and for varying rotational speed with fixed pressure ratio and the efficiency was plotted against u/c_0. Each condition was tested and measured...

Sharma, Kapil

2011-08-08T23:59:59.000Z

329

Effect of high pressure homogenization on the physical properties of milk  

E-Print Network [OSTI]

Milk was homogenized at pressures ranging from 17.2 MPa to 100 MPa to determine the effect of homogenization pressure on the fat globule size distribution, viscosity, color, and temperature changes in milk. Milk containing 0, 1.5 and 3.0% milk fat...

Gonzalez De Cossio, Carlos

1994-01-01T23:59:59.000Z

330

An improved measurement of electron-ion recombination in high-pressure xenon gas  

E-Print Network [OSTI]

We report on results obtained with the NEXT-DEMO prototype of the NEXT-100 high-pressure xenon gas time projection chamber (TPC), exposed to an alpha decay calibration source. Compared to our previous measurements with alpha particles, an upgraded detector and improved analysis techniques have been used. We measure event-by-event correlated fluctuations between ionization and scintillation due to electron-ion recombination in the gas, with correlation coeffcients between -0.80 and -0.56 depending on the drift field conditions. By combining the two signals, we obtain a 2.8 % FWHM energy resolution for 5.49 MeV alpha particles and a measurement of the optical gain of the electroluminescent TPC. The improved energy resolution also allows us to measure the specific activity of the radon in the gas due to natural impurities. Finally, we measure the average ratio of excited to ionized atoms produced in the xenon gas by alpha particles to be $0.561\\pm 0.045$, translating into an average energy to produce a primary scintillation photon of $W_{\\rm ex}=(39.2\\pm 3.2)$ eV.

NEXT Collaboration; L. Serra; M. Sorel; V. Álvarez; F. I. G. Borges; M. Camargo; S. Cárcel; S. Cebrián; A. Cervera; C. A. N. Conde; T. Dafni; J. Díaz; R. Esteve; L. M. P. Fernandes; P. Ferrario; A. L. Ferreira; E. D. C. Freitas; V. M. Gehman; A. Goldschmidt; J. J. Gómez-Cadenas; D. González-Díaz; R. M. Gutiérrez; J. Hauptman; J. A. Hernando Morata; D. C. Herrera; I. G. Irastorza; L. Labarga; A. Laing; I. Liubarsky; N. Lopez-March; D. Lorca; M. Losada; G. Luzón; A. Marí; J. Martín-Albo; G. Martínez-Lema; A. Martínez; T. Miller; F. Monrabal; M. Monserrate; C. M. B. Monteiro; F. J. Mora; L. M. Moutinho; J. Muñoz Vidal; M. Nebot-Guinot; D. Nygren; C. A. B. Oliveira; J. Pérez; J. L. Pérez Aparicio; M. Querol; J. Renner; L. Ripoll; A. Rodríguez; J. Rodríguez; F. P. Santos; J. M. F. dos Santos; D. Shuman; A. Simón; C. Sofka; J. F. Toledo; J. Torrent; Z. Tsamalaidze; J. F. C. A. Veloso; J. A. Villar; R. Webb; J. T. White; N. Yahlali

2015-02-03T23:59:59.000Z

331

Equation of state of rhenium and application for ultra high pressure calibration  

SciTech Connect (OSTI)

The isothermal equation of state of rhenium has been measured by powder X-ray diffraction experiments up to 144?GPa at room temperature in a diamond anvil cell. A helium pressure transmitting medium was used to minimize the non-hydrostatic stress on the sample. The fit of pressure-volume data yields a bulk modulus K{sub 0}?=?352.6?GPa and a pressure derivative of the bulk modulus K?{sub 0}=4.56. This equation of state differs significantly from a recent determination [Dubrovinsky et al., Nat. Commun. 3, 1163 (2012)], giving here a lower pressure at a given volume. The possibility of using rhenium gasket X-ray diffraction signal, with the present equation of state, to evaluate multi-Mbar pressures in the chamber of diamond anvil cells is discussed.

Anzellini, Simone; Dewaele, Agnès; Occelli, Florent; Loubeyre, Paul [CEA, DAM, DIF, F-91297 Arpajon (France); Mezouar, Mohamed [European Synchrotron Radiation Facility, BP220, 38043 Grenoble Cedex (France)

2014-01-28T23:59:59.000Z

332

High pressure dynamics of hydrated protein in bio-protective trehalose environment  

E-Print Network [OSTI]

We present a pressure dependence study of the dynamics of lysozyme protein powder immersed in deuterated $\\alpha$,$\\alpha$-trehalose environment via quasi-elastic neutron scattering (QENS). The goal is to assess the baro-protective benefits of trehalose on bio-molecules by comparing the findings with those of a trehalose-free reference study. While the mean-square displacement of the trehalose-free protein (hydrated to $d_{D_2O}\\simeq$40 w\\%) as a whole, is reduced by increasing pressure, the actual observable relaxation dynamics in the pico-(ps) to nano-seconds (ns) time range remains largely unaffected by pressure - up to the maximum investigated pressure of 2.78(2) Kbar. Our observation is independent of whether or not the protein is mixed with the deuterated sugar. This suggests that the hydrated protein's conformational states at atmospheric pressure remain unaltered by hydrostatic pressures, below 2.78 Kbar. We also found the QENS response to be totally recoverable after ambient pressure conditions are restored. Circular dichroism and neutron diffraction measurements confirm that the protein structural integrity is conserved and remains intact, after pressure is released. We observe however a clear narrowing of the quasi-elastic neutron (QENS) response as the temperature is decreased from 290 K to 230 K in both cases, which we parametrize using the Kohlrausch-Williams-Watts (KWW) stretched exponential model. Only the fraction of protons that are immobile on the accessible time window of the instrument, referred to as the elastic incoherent structure factor or (EISF) is observably sensitive to pressure, increasing only marginally but systematically with increasing pressure.

S. O. Diallo; Q. Zhang; H. O'Neill; E. Mamontov

2014-09-11T23:59:59.000Z

333

The Unique High-Pressure Behavior of Curium Probed Further Using Alloys  

SciTech Connect (OSTI)

The changing role of the 5f electrons across the actinide series has been of prime interest for many years. The remarkable behavior of americium's 5f electrons under pressure was determined experimentally a few years ago and it precipitated a strong interest in the heavy element community. Theoretical treatments of americium's behavior under pressure followed and continue today. Experimental and theoretical findings regarding curium's behavior under pressure have shown that the pressure behavior of curium was not a mirror image of that for americium. Rather, one of the five crystallographic phases observed with curium (versus four for americium) was a unique monoclinic structure whose existence is due to a spin stabilization effect by curium's 5f{sup 7} electronic configuration and its half-filled 5f-shell. We review briefly the behavior of pure curium under pressure but focus on the pressure behaviors of three curium alloys with the intent of comparing them with pure curium. An important experimental finding confirmed by theoretical computations, is that dilution of curium with its near neighbors is sufficient to prevent the formation of the unique C2/c phase that appears in pure Cm metal under pressure. As this unique C2/c phase is very sensitive to having a 5f{sup 7} configuration to maximize the magnetic spin polarization, dilution of this state with adjacent actinide neighbors reduces its stability.

Heathman, S. [European Commission Joint Research Centre; Haire, Richard {Dick} G [ORNL; LeBihan, T. [CEA-Centre de Valduc, Is-sur-Tille, France; Ahuja, R. [Uppsala University, Uppsala, Sweden; Li, S. [Virginia Commonwealth University, Richland; Luo, W. [Uppsala University, Uppsala, Sweden; Johansson, B. [Royal Institute of Technology, Stockholm, Sweden

2007-01-01T23:59:59.000Z

334

High-pressure behavior and thermoelastic properties of niobium studied by in situ x-ray diffraction  

SciTech Connect (OSTI)

In situ synchrotron energy dispersive x-ray diffraction (XRD) experiments on Nb have been conducted at pressures up to 6.4?GPa and temperatures up to 1073?K. From the pressure-volume-temperature measurements, thermoelastic parameters were derived for the first time for Nb based on the thermal pressure (?P{sub th}) equation of state (EOS), modified high-T Birch-Murnaghan EOS, and Mie-Grüneisen-Debye EOS. With the pressure derivative of the bulk modulus K{sub T}{sup ?} fixed at 4.0, we obtained the ambient isothermal bulk modulus K{sub T0}?=?174(5) GPa, the temperature derivative of bulk modulus at constant pressure (?K{sub T}/?T){sub P}=?0.060(8) GPa K{sup ?1} and at constant volume (?K{sub T}/?T){sub V}=?0.046(8)?GPa K{sup ?1}, the volumetric thermal expansivity ?{sub T}(T)=2.3(3)×10{sup ?5}+0.3(2)×10{sup ?8}T (K{sup ?1}), as well as the pressure dependence of thermal expansion (??/?P){sub T}=(?2.0±0.4)×10{sup ?6} K{sup ?1?}GPa{sup ?1}. Fitting the present data to the Mie-Grüneisen-Debye EOS with Debye temperature ?{sub 0}?=?276.6?K gives ?{sub 0}?=?1.27(8) and K{sub T0}?=?171(3) GPa at a fixed value of q?=?3.0. The ambient isothermal bulk modulus and Grüneisen parameter derived from this work are comparable to previously reported values from both experimental and theoretical studies. An in situ high-resolution, angle dispersive XRD study on Nb did not indicate any anomalous behavior related to pressure-induced electronic topological transitions at ?5?GPa as has been reported previously.

Zou, Yongtao, E-mail: yongtao.zou@stonybrook.edu, E-mail: yongtaozou6@gmail.com; Li, Baosheng [Mineral Physics Institute, State University of New York, Stony Brook, New York 11794 (United States); Qi, Xintong [Department of Materials Science and Engineering, State University of New York, Stony Brook, New York 11794 (United States); Wang, Xuebing; Chen, Ting [Department of Geosciences, State University of New York, Stony Brook, New York 11794 (United States); Li, Xuefei [Mineral Physics Institute, State University of New York, Stony Brook, New York 11794 (United States); Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education, Jilin Normal University, Siping 136000 (China); Welch, David [Department of Materials Science and Engineering, State University of New York, Stony Brook, New York 11794 (United States); Condensed Matter Physics and Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973 (United States)

2014-07-07T23:59:59.000Z

335

Physics of the Earth and Planetary Interiors xxx (2004) xxxxxx High pressure crystal chemistry of hydrous ringwoodite  

E-Print Network [OSTI]

Physics of the Earth and Planetary Interiors xxx (2004) xxx­xxx High pressure crystal chemistry of hydrous ringwoodite and water in the Earth's interior Joseph R. Smytha,, Christopher M. Holla, Daniel J November 2002; received in revised form 12 May 2003; accepted 18 August 2003 Abstract The crystal chemistry

Smyth, Joseph R.

336

Physics of the Earth and Planetary Interiors 143144 (2004) 271278 High pressure crystal chemistry of hydrous ringwoodite  

E-Print Network [OSTI]

Physics of the Earth and Planetary Interiors 143­144 (2004) 271­278 High pressure crystal chemistry of hydrous ringwoodite and water in the Earth's interior Joseph R. Smytha,, Christopher M. Holla, Daniel J November 2002; received in revised form 12 May 2003; accepted 18 August 2003 Abstract The crystal chemistry

Jacobsen, Steven D.

337

Iron under Earth's core conditions: Liquid-state thermodynamics and high-pressure melting curve from ab initio calculations  

E-Print Network [OSTI]

Hugoniot curves cross the melting line, and the sound speed and Gru¨neisen parameter along the HugoniotIron under Earth's core conditions: Liquid-state thermodynamics and high-pressure melting curve-augmented-wave implementation are used to calculate the free energy and a range of other thermodynamic properties of liquid iron

Alfè, Dario

338

High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials  

E-Print Network [OSTI]

nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

Duffy, Thomas S.

339

In vitro corrosion and cytotoxicity on microcrystalline, nanocrystalline and amorphous NiTi alloy fabricated by high pressure torsion  

E-Print Network [OSTI]

In vitro corrosion and cytotoxicity on microcrystalline, nanocrystalline and amorphous NiTi alloy Amorphous Metals and alloys Corrosion and ion release Cytotoxicity Bulk nanocrystalline and amorphous Ni50 discs by high pressure torsion (HPT) technique. Then their corrosion resistance, surface wettability

Zheng, Yufeng

340

Vehicle Technologies Office 2013 Merit Review: A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines  

Broader source: Energy.gov [DOE]

A presentation given by the University of Michigan at the 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting about a university consortium to research efficient and clean high-pressure lean burn engines.

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

An investigation of high pressure/late cycle injection of CNG (compressed natural gas) as a fuel for rail applications  

SciTech Connect (OSTI)

This report describes a demonstration effort to investigate the use of natural gas in a medium-speed diesel engine. The effort was unique in the sense that natural gas was injected directly into the combustion chamber late in the compression stroke, as a high pressure gas rather than through low pressure fumigation or low pressure injection early in the compression stroke. Tests were performed on a laboratory two-cylinder, two-stroke cycle medium-speed diesel engine in an attempt to define its ability to operate on the high pressure/late cycle injection concept and to define the performance and emission characteristics of the engine under such operation. A small quantity of No.-2 diesel fuel was injected into the cylinder slightly before the gas injection to be used as an ignition source for the gas. Pilot (diesel fuel) and main (natural gas) timing and injection duration were systematically varied to optimize engine performance. The test demonstrated that the medium-speed engine was capable of attaining full rated speed and load (unlike the low pressure approach) with very low percentages of pilot injection with the absence of knock. Thermal efficiency was as much as 10 percent less than thermal efficiency levels obtained with neat diesel fuel. This was primarily due to the placement and injection characteristics of the pilot and main injectors. Optimization of the injection system would undoubtedly result in increased thermal efficiency. 11 figs., 4 tabs.

Wakenell, J.F.; O'Neal, G.G.; Baker, Q.A.; Urban, C.M.

1988-04-01T23:59:59.000Z

342

Network Rigidity in GeSe2 Glass at High Pressure  

SciTech Connect (OSTI)

Acoustic measurements using synchrotron radiation have been performed on glassy GeSe2 up to pressures of 9.6 GPa. A minimum observed in the shear-wave velocity, associated anomalous behavior in Poisson's ratio, and discontinuities in elastic moduli at 4 GPa are indicative of a gradual structural transition in the glass. This is attributed to a network rigidity minimum originating from a competition between two densification mechanisms. At pressures up to 3 GPa, a conversion from edge- to corner-sharing tetrahedra results in a more flexible network. This is contrasted by a gradual increase in coordination number with pressure, which leads to an overall stiffening of the glass.

Antao,S.; Benmore , C.; Li, B.; Wang, L.; Bychkov, E.; Parise, J.

2008-01-01T23:59:59.000Z

343

High pressure feeder and method of operating to feed granular or fine materials  

SciTech Connect (OSTI)

A coal feed system to feed pulverized low rank coals containing up to 25 wt % moisture to gasifiers operating up to 1000 psig pressure is described. The system includes gas distributor and collector gas permeable pipes imbedded in the lock vessel. Different methods of operation of the feed system are disclosed to minimize feed problems associated with bridging and packing of the pulverized coal. The method of maintaining the feed system and feeder device exit pressures using gas addition or extraction with the pressure control device is also described.

Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

2014-10-07T23:59:59.000Z

344

An Estimate of the Thermodynamic Pressure in High-Energy Collisions  

E-Print Network [OSTI]

We introduce a novel approach to estimate the thermodynamic pressure from heavy-ion collisions based on recently measured higher-order moments of particle multiplicities by the STAR experiment. We start with fitting the experimental results in the most-central collisions. Then, we integrate them back to lower ones. For example, we find that the first-order moment, the mean multiplicity, is exactly reproduced from the integral of variance, the second-order moment. Therefore, the zero-order moment, the thermodynamic pressure, can be estimated from the integral of the mean multiplicity. the possible comparison between such a kind of pressure (deduced from the integral of particle multiplicity) and the lattice pressure and the relating of Bjorken energy density to the lattice energy density are depending on lattice QCD at finite baryon chemical potential and first-principle estimation of the formation time of the quark-gluon plasma (QGP).

Tawfik, Abdel Nasser

2015-01-01T23:59:59.000Z

345

An examination of possible reversible combustion at high temperatures and pressures for a reciprocating engine  

E-Print Network [OSTI]

ratio of 18. Although the temperatures and pressures considered are well beyond practical values for the materials and designs of today, the general result of the study is that conditions can be identified to eliminate the combustion irreversibility....

Patrawala, Kaushik Tanvir

2009-05-15T23:59:59.000Z

346

Analytical and experimental evaluation of the leakage and stiffness characteristics of high pressure pocket damper seals  

E-Print Network [OSTI]

This thesis presents numerical predictions for the leakage and direct stiffness coefficients of pocket damper seals. Modifications made to earlier flow-prediction models are discussed. Leakage and static pressure measurements on straight...

Gamal Eldin, Ahmed Mohamed

2004-09-30T23:59:59.000Z

347

Vacuum ultra-violet emission of plasma discharges with high Xe partial pressure using a cathode protective layer with high secondary electron emission  

SciTech Connect (OSTI)

In this work, the mechanism of the vacuum ultra-violet (VUV) emission of plasma discharges, with high Xe partial pressure and high ion-induced secondary electrons emission protective layer, is studied by measuring the VUV light emission directly and comparing it with two-dimensional simulations. From the panel measurement, we find that the high intensity of excimer VUV mainly contributes to the high luminous efficacy of SrCaO-plasma display panels (PDP) at a low sustain voltage. The unchanged Xe excitation efficiency indicates that the electron temperature is not decreased by the high secondary electrons emission protective layer, even though the sustain voltage is much lower. From the two-dimensional simulations, we can find that the ratio of excimer VUV to resonant VUV, which is determined by the collision rate in the discharge, is only significantly affected by the Xe partial pressure, while it is independent of the sustain voltage and the secondary-electrons-emission capability of protective layer. The unchanged average electron energy at the moment when the electric field becomes maximum confirms that the improvement of the VUV production efficiency mainly is attributed to the increase in electron heating efficiency of a PDP with high ion-induced secondary electrons emission protective layer. Combining the experimental and the simulation results, we conclude about the mechanism by which the VUV production is improved for the plasma display panel with a high Xe partial pressure and a cold cathode with high ion-induced secondary electrons emission.

Zhu, Di [School of Electronics and Information Engineering, Tianjin Polytechnic University, Tianjin (China); Song, Le, E-mail: songle@tju.edu.cn [State Key Laboratory of Precision Measuring Technology and Instruments, Tianjin University, Tianjin (China); Zhang, Xiong [School of Electronic Science and Engineering, Southeast University, Nanjing (China); Kajiyama, Hiroshi [Graduate School of Advanced Science of Matter, Hiroshima University, Higashi-hiroshima, Hiroshima (Japan)

2014-02-14T23:59:59.000Z

348

In situ multipurpose time-resolved spectrometer for monitoring nanoparticle generation in a high-pressure fluid  

SciTech Connect (OSTI)

We developed a multipurpose time-resolved spectrometer for studying the dynamics of nanoparticles generated by pulsed-laser ablation (PLA) in a high-pressure fluid. The apparatus consists of a high-pressure optical cell and three spectrometers for in situ measurements. The optical cell was designed for experiments at temperatures up to 400 K and pressures up to 30 MPa with fluctuations within {+-}0.1% h{sup -1}. The three spectrometers were used for the following in situ measurements at high pressures: (i) transient absorption spectrum measurements from 350 to 850 nm to investigate the dynamics of nanoparticle generation from nanoseconds to milliseconds after laser irradiation, (ii) absorption spectrum measurements from 220 to 900 nm to observe the time evolution of nanoparticles from seconds to hours after laser ablation, and (iii) dynamic light scattering measurements to track nanoparticles with sizes from 10 nm to 10 {mu}m in the time range from seconds to hours after laser ablation. By combining these three spectrometers, we demonstrate in situ measurements of gold nanoparticles generated by PLA in supercritical fluids. This is the first report of in situ time-resolved measurements of the dynamics of nanoparticles generated in a supercritical fluid.

Wei, Shaoyu [Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526 Higashi-hiroshima (Japan); Saitow, Ken-ichi [Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, 739-8526 Higashi-hiroshima (Japan); Natural Science Center for Basic Research and Development (N-BARD), 1-3-1 Kagamiyama, 739-8526 Higashi-hiroshima (Japan)

2012-07-15T23:59:59.000Z

349

Uranium partitioning between liquid iron and silicate melt at high pressures: implications for uranium solubility in planetary cores  

E-Print Network [OSTI]

We have investigated the partitioning of U between silicate melt and Fe liquid at pressures of 3.0 to14.5 GPa and temperatures of 1660 to 2500 oC. The solubility of U in liquid Fe is in the range of 0.6 to 800 ppm and increases with temperature (T) and pressure (P). When P = or > 7 GPa and T > Tmelt of the silicate phase (olivine), the U concentration in Fe is 3 to 5 times greater than for run products where T Tmelt of the silicate phase), then > 2.4 ppb U could have entered the core. Alternatively, if a core with same composition formed by percolation (T Uranium; partition coefficients; high pressure; dynamos; planetary cores; heat sources, LA-ICP-MS.

Xuezhao Bao; Richard A. Secco; Joel E. Gagnon; Brian J. Fryer

2006-06-29T23:59:59.000Z

350

The nonlinear anomalous lattice elasticity associated with the high-pressure phase transition in spodumene: A high precission static compression study  

E-Print Network [OSTI]

The high-pressure behavior of the lattice elasticity of spodumene, LiAlSi2O6, was studied by static compression in a diamond-anvil cell up to 9.3 GPa. Investigations by means of single-crystal XRD and Raman spectroscopy within the hydrostatic limits of the pressure medium focus on the pressure ranges around similar to 3.2 and similar to 7.7 GPa, which have been reported previously to comprise two independent structural phase transitions. While our measurements confirm the well-established first-order C2/c-P2(1)/c transformation at 3.19 GPa (with 1.2% volume discontinuity and a hysteresis between 0.02 and 0.06 GPa), both unit-cell dimensions and the spectral changes observed in high-pressure Raman spectra give no evidence for structural changes related to a second phase transition. Monoclinic lattice parameters and unit-cell volumes at in total 59 different pressure points have been used to re-calculate the lattice-related properties of spontaneous strain, volume strain, and the bulk moduli as a function of pr...

Ullrich, A; Miletich, R; 10.1007/s00269-009-0300-8

2010-01-01T23:59:59.000Z

351

Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment  

SciTech Connect (OSTI)

In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

Rich Ciora; Paul KT Liu

2012-06-27T23:59:59.000Z

352

Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity  

DOE Patents [OSTI]

This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70.degree. C. to 90.degree. C., at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%.

Premuzic, Eugene T. (East Moriches, NY); Lin, Mow (Rocky Point, NY)

1996-02-20T23:59:59.000Z

353

Process for producing modified microorganisms for oil treatment at high temperatures, pressures and salinity  

DOE Patents [OSTI]

This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. The processes are comprised of steps which successively limit the carbon sources and increase the temperature, pressure and salinity of the media. This is done until microbial strains are obtained that are capable of growing in essentially crude oil as a carbon source and at a temperature range from about 70 C to 90 C, at a pressure range from about 2,000 to 2,500 psi and at a salinity range from about 1.3 to 35%. 68 figs.

Premuzic, E.T.; Lin, M.

1996-02-20T23:59:59.000Z

354

Inelastic X-ray scattering experiments on B[subscript 4]C under high static pressures  

SciTech Connect (OSTI)

Boron K-edge inelastic X-ray scattering experiments were performed on clean B{sub 4}C and shock impact recovered boron carbide up to 30 GPa and at ambient temperature to understand the pressure induced bonding changes. The spectral features corresponding to the boron site in the interlinking chain remained unchanged up to 30 GPa. The results of our experiments indicate that pressure induces less distortion to the boron sites and the local amorphization observed in the previous reports are due to the rearrangement of carbon atoms under extreme conditions without affecting the boron environment.

Kumar, Ravhi S.; Dandekar, Dattatraya; Leithe-Jasper, Andres; Tanaka, Takaho; Xiao, Yuming; Chow, Paul; Nicol, Malcolm F.; Cornelius, Andrew L. (UNLV); (MXPL-M); (CIW); (USARL)

2010-05-04T23:59:59.000Z

355

High-pressure late cycle direct injection of natural gas in a rail medium speed diesel engine  

SciTech Connect (OSTI)

The performance of an Electro-Motive Division (EMD) 567B, two-cylinder locomotive research engine, when operated on high-pressure/late-cycle injection of natural gas, is presented in this paper. A redesign and fabrication of the fuel system was undertaken to facilitate the consumption of natural gas. A small percentage of No.2 diesel fuel (DF-2) was used to ignite the natural gas. Engine performance, while running natural gas, resulted in matching rated speed and power with slightly lower thermal efficiency. Full power was achieved with a ratio of 99 percent natural gas and 1 percent diesel fuel. However, at high natural gas to diesel fuel ratios, audible knock was detected. The primary objective of the project was to establish technical feasibility of, and basic technology for, operating medium-speed rail diesel engines on high-pressure natural gas. Secondary objectives were to attain adequate engine performance levels for rail application, develop a system oriented toward retrofit of in-service locomotives, and realize any potential improvements in thermal efficiency due to use of the high-pressure/late-cycle approach.

Wakenell, J.F.; O'Neal, G.B.; Baker, Q.A.

1987-01-01T23:59:59.000Z

356

Manufacturing Cost Analysis of Novel Steel/Concrete Composite Vessel for Stationary Storage of High-Pressure Hydrogen  

SciTech Connect (OSTI)

A novel, low-cost, high-pressure, steel/concrete composite vessel (SCCV) technology for stationary storage of compressed gaseous hydrogen (CGH2) is currently under development at Oak Ridge National Laboratory (ORNL) sponsored by DOE s Fuel Cell Technologies (FCT) Program. The SCCV technology uses commodity materials including structural steels and concretes for achieving cost, durability and safety requirements. In particular, the hydrogen embrittlement of high-strength low-alloy steels, a major safety and durability issue for current industry-standard pressure vessel technology, is mitigated through the use of a unique layered steel shell structure. This report presents the cost analysis results of the novel SCCV technology. A high-fidelity cost analysis tool is developed, based on a detailed, bottom-up approach which takes into account the material and labor costs involved in each of the vessel manufacturing steps. A thorough cost study is performed to understand the SCCV cost as a function of the key vessel design parameters, including hydrogen pressure, vessel dimensions, and load-carrying ratio. The major conclusions include: The SCCV technology can meet the technical/cost targets set forth by DOE s FCT Program for FY2015 and FY2020 for all three pressure levels (i.e., 160, 430 and 860 bar) relevant to the hydrogen production and delivery infrastructure. Further vessel cost reduction can benefit from the development of advanced vessel fabrication technologies such as the highly automated friction stir welding (FSW). The ORNL-patented multi-layer, multi-pass FSW can not only reduce the amount of labor needed for assembling and welding the layered steel vessel, but also make it possible to use even higher strength steels for further cost reductions and improvement of vessel structural integrity. It is noted the cost analysis results demonstrate the significant cost advantage attainable by the SCCV technology for different pressure levels when compared to the industry-standard pressure vessel technology. The real-world performance data of SCCV under actual operating conditions is imperative for this new technology to be adopted by the hydrogen industry for stationary storage of CGH2. Therefore, the key technology development effort in FY13 and subsequent years will be focused on the fabrication and testing of SCCV mock-ups. The static loading and fatigue data will be generated in rigorous testing of these mock-ups. Successful tests are crucial to enabling the near-term impact of the developed storage technology on the CGH2 storage market, a critical component of the hydrogen production and delivery infrastructure. In particular, the SCCV has high potential for widespread deployment in hydrogen fueling stations.

Feng, Zhili [ORNL; Zhang, Wei [ORNL; Wang, Jy-An John [ORNL; Ren, Fei [ORNL

2012-09-01T23:59:59.000Z

357

Development of a Low Pressure, Air Atomized Oil Burner with High Atomizer Air Flow: Progress Report FY 1997  

SciTech Connect (OSTI)

This report describes technical advances made to the concept of a low pressure, air atomized oil burner for home heating applications. Currently all oil burners on the market are of the pressure atomized, retention head type. These burners have a lower firing rate limit of about 0.5 gallons per hour of oil, due to reliability problems related to small flow passage sizes. High pressure air atomized burners have been shown to be one route to avoid this problem but air compressor cost and reliability have practically eliminated this approach. With the low pressure air atomized burner the air required for atomization can be provided by a fan at 5-8 inches of water pressure. A burner using this concept, termed the Fan-Atomized Burner or ''FAB'' has been developed and is currently being commercialized. In the head of the FAB, the combustion air is divided into three parts, much like a conventional retention head burner. This report describes development work on a new concept in which 100% of the air from the fan goes through the atomizer. The primary advantage of this approach is a great simplification of the head design. A nozzle specifically sized for this concept was built and is described in the report. Basic flow pressure tests, cold air velocity profiles, and atomization performance have been measured. A burner head/flame tube has been developed which promotes a toroidal recirculation zone near the nozzle for flame stability. The burner head has been tested in several furnace and boiler applications over the firing rate range 0.2 to 0.28 gallons per hour. In all cases the burner can operate with very low excess air levels (under 10%) without producing smoke. Flue gas NO{sub x} concentration varied from 42 to 62 ppm at 3% O{sub 2}. The concept is seen as having significant potential and planned development efforts are discussed.

Butcher, T.A.

1998-01-01T23:59:59.000Z

358

Process for CO.sub.2 capture using zeolites from high pressure and moderate temperature gas streams  

DOE Patents [OSTI]

A method for separating CO.sub.2 from a gas stream comprised of CO.sub.2 and other gaseous constituents using a zeolite sorbent in a swing-adsorption process, producing a high temperature CO.sub.2 stream at a higher CO.sub.2 pressure than the input gas stream. The method utilizes CO.sub.2 desorption in a CO.sub.2 atmosphere and effectively integrates heat transfers for optimizes overall efficiency. H.sub.2O adsorption does not preclude effective operation of the sorbent. The cycle may be incorporated in an IGCC for efficient pre-combustion CO.sub.2 capture. A particular application operates on shifted syngas at a temperature exceeding 200.degree. C. and produces a dry CO.sub.2 stream at low temperature and high CO.sub.2 pressure, greatly reducing any compression energy requirements which may be subsequently required.

Siriwardane, Ranjani V. (Morgantown, WV); Stevens, Robert W. (Morgantown, WV)

2012-03-06T23:59:59.000Z

359

High-pressure sound velocities and elasticity of aluminous MgSiO3 perovskite to 45 GPa: Implications for lateral heterogeneity in Earth's  

E-Print Network [OSTI]

High-pressure sound velocities and elasticity of aluminous MgSiO3 perovskite to 45 GPa lateral variations of seismic wave speeds in Earth's lower mantle are due at least in part to a chemical, J. M., J. Zhang, J. Shu, S. V. Sinogeikin, and J. D. Bass (2005), High-pressure sound velocities

Jackson, Jennifer M.

360

Energy dissipation via quantum-chemical hysteresis during high-pressure compression: A first-principles molecular dynamics study of phosphates  

E-Print Network [OSTI]

-phosphates (TPs) and zinc phosphates (ZPs) to changes in pressure p and temperature T is studied through firstEnergy dissipation via quantum-chemical hysteresis during high-pressure compression: A first to signifi- cant energy dissipation, which contributes to the high friction coefficients of ZP anti-wear pads

Mueser, Martin

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

High-pressure synthesis and structure of a new aurate, CaAu{sub 2}O{sub 4}  

SciTech Connect (OSTI)

A novel aurate, CaAu{sub 2}O{sub 4}, after synthesis under high-pressure conditions was recovered to room temperature by quenching. The structure, determined with synchrotron powder X-ray diffraction and single-crystal X-ray data by model building, was refined using the Rietveld techniques. It contains corner-shared AuO{sub 4} square planes and CaO{sub 8} dodecahedra. 25 refs., 2 figs., 1 tab.

Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)

1995-06-01T23:59:59.000Z

362

Micro-Structured Sapphire Fiber Sensors for Simultaneous Measurements of High-T and Dynamic Gas Pressure in Harsh Environments  

SciTech Connect (OSTI)

This is the final report for the program “Micro-Structured Sapphire Fiber Sensors for Simultaneous Measurements of High Temperature and Dynamic Gas Pressure in Harsh Environments”, funded by NETL, and performed by Missouri University of Science and Technology, Clemson University and University of Cincinnati from October 1, 2009 to September 30, 2014. Securing a sustainable energy economy by developing affordable and clean energy from coal and other fossil fuels is a central element to the mission of The U.S. Department of Energy’s (DOE) National Energy Technology Laboratory (NETL). To further this mission, NETL funds research and development of novel sensor technologies that can function under the extreme operating conditions often found in advanced power systems. The main objective of this research program is to conduct fundamental and applied research that will lead to successful development and demonstration of robust, multiplexed, microstructured silica and single-crystal sapphire fiber sensors to be deployed into the hot zones of advanced power and fuel systems for simultaneous measurements of high temperature and gas pressure. The specific objectives of this research program include: 1) Design, fabrication and demonstration of multiplexed, robust silica and sapphire fiber temperature and dynamic gas pressure sensors that can survive and maintain fully operational in high-temperature harsh environments. 2) Development and demonstration of a novel method to demodulate the multiplexed interferograms for simultaneous measurements of temperature and gas pressure in harsh environments. 3) Development and demonstration of novel sapphire fiber cladding and low numerical aperture (NA) excitation techniques to assure high signal integrity and sensor robustness.

Xiao, Hai; Tsai, Hai-Lung; Dong, Junhang

2014-09-30T23:59:59.000Z

363

METC/3M Cooperative Agreement CRADA 94-024 high temperature high pressure filter materials exposure test program. Volume 2, Final report  

SciTech Connect (OSTI)

This report is a summary of the results of activities of the particulate monitoring group in support of the METC/3M CRADA 94024. Online particulate monitoring began in June 1994 and ended in October, 1994. The particulate monitoring group participated in four MGCR runs (No. 7 through No. 10). The instrument used in measuring the particle loadings (particle counts and size distribution) is the Particle Measuring Systems Classical Scattering Aerosol Spectrometer Probe High Temperature and High Pressure (PMS Model CSASP-100-HTHP). This PMS unit is rated to operate at temperatures up to 540{degree}C and gage pressures up to 2.0 MPa. Gas stream conditions, temperature at 540{degree}C, gage pressure at 2.93 MPa, and gas flowrate at 0.0157 SCM per second, precluded the direct measurement of particulate loadings in the gas stream with the PMS unit. A side stream was extracted from the gas stream after it came over to the MGCR, Modular Gas Cleanup Rig, from the FBG, pressurized Fluidized-Bed Gasifier, but before it entered the filter testing vessel. A sampling probe of 0.635 cm O.D. thin wall stainless steel tubing was used for extracting the sample gas isokinetically based on the expected flowrate. The sample gas stream was further split into two streams; one was directed to the PMS unit and the other to the alkali monitor unit. The alkali monitor unit was not used during runs No. 7 through No. 10.

NONE

1995-06-01T23:59:59.000Z

364

METC/Shell Cooperative Agreement CRADA 93-011 high temperature high pressure filtration and sorbent test program. Volume 2, Final report  

SciTech Connect (OSTI)

This report is a summary of the results of activities of the particulate monitoring group in support of the METC/Shell CRADA 93-011. Online particulate monitoring began in August 1993 and ended in October 1994. The particulate monitoring group participated in six MGCR runs (No. 5 through No. 10). The instrument used in measuring the particle loadings (particle counts and size distribution) is the Particle Measuring Systems Classical Scattering Aerosol Spectrometer Probe High Temperature and High Pressure (PMS Model CSASP-100-HTHP). This PMS unit is rated to operate at temperatures up to 540{degree}C and gage pressures up to 2.07 MPa. Gas stream conditions, temperature at 540{degree}C, gage pressure at 2.93 MPa, and gas flowrate at 0.0157 SCM per second, precluded the direct measurement of particulate loadings in the gas stream with the PMS unit. A side stream was extracted from the gas stream after it came over to the MGCR, (Modular Gas Cleanup Rig), from the FBG, pressurized fluidized-bed gasifier, but before it entered the filter testing vessel. A sampling probe of 0.635 cm O.D. thin wall stainless steel tubing was used for extracting the sample gas isokinetically based on the expected flowrate. The sample gas stream was further split into two streams; one was directed to the PMS unit and the other to the alkali monitor unit.

NONE

1995-06-01T23:59:59.000Z

365

Crystal Chemistry of NaMgF3 Perovskite at High Pressure and Temperature  

SciTech Connect (OSTI)

The crystal structure of NaMgF{sub 3} perovskite (neighborite) has been studied at 4 GPa and temperatures up to 1000 C using the Rietveld structure-refinement method. In situ synchrotron X-ray powder diffraction data was collected using monochromatic radiation. The orthorhombic (Pbnm) to cubic (Pm{bar 3}m) transition was observed when the temperature increased from 900 to 1000 C. Structure refinements show that the ratio of polyhedral volumes of the A and B sites (V{sub A}/V{sub B}) of the orthorhombic phase increases with temperature, approaching the ideal value (5) for the cubic structure. However, this ratio becomes smaller at 4 GPa compared to the result from previous studies at the same temperature but ambient pressure, indicating that pressure makes it more difficult to transform from the orthorhombic phase to the cubic phase in this kind of perovskite.

Chen,J.; Liu, H.; Martin, C.; Parise, J.; Weidner, D.

2005-01-01T23:59:59.000Z

366

Electron beam melting at high pressures with a vacuum separator/plasma lens  

SciTech Connect (OSTI)

Plasmas can be used to provide a vacuum-atmosphere interface or separation between vacua regions as an alternative to differential pumping. Vacuum-atmosphere interface utilizing a cascade arc discharge was successfully propagated from vacuum through such a plasma interface and out into atmospheric pressure. This plasma device also functions as an effective plasma lens. Such a device can be adopted for use in electron beam melting.

Hershcovitch, A. [Brookhaven National Laboratory, Upton, NY (United States)

1995-12-31T23:59:59.000Z

367

Electron beam melting at high pressures with a vacuum separator/plasma lens  

SciTech Connect (OSTI)

Plasmas can be used to provide a vacuum-atmosphere interface or separation between vacua regions as an alternative to differential pumping. Vacuum-atmosphere interface utilizing a cascade arc discharge was successfully demonstrated and a 175 keV electron beam was successfully propagated from vacuum through such a plasma interface and out into atmospheric pressure. This plasma device also functions as an effective plasma tens. Such a device can be adopted for use in electron beam melting.

Hershcovitch, A.

1995-12-31T23:59:59.000Z

368

Evidence for plasma phase transition in high pressure hydrogen from ab-initio simulations  

SciTech Connect (OSTI)

We have performed a detailed study of molecular dissociation in liquid hydrogen using both Born-Oppenheimer molecular dynamics with Density Functional Theory and Coupled Electron-Ion Monte Carlo simulations. We observe a range of densities where (dP/d{rho}){sub T} = 0 that coincides with sharp discontinuities in the electronic conductivity, which is clear evidence of the plasma phase transition for temperatures 600K {le} T {le} 1500K. Both levels of theory exhibit the transition, although Quantum Monte Carlo predicts higher transition pressures. Based on the temperature dependence of the discontinuity in the electronic conductivity, we estimate the critical point of the transition at temperatures slightly below 2000 K. We examine the influence of proton zero point motion by using Path Integral Molecular Dynamics with Density Functional Theory; the main effect is to shift the transition to lower pressures. Furthermore, we calculate the melting curve of molecular hydrogen up to pressures of 200 GPa, finding a reentrant melting line in good agreement with previous calculations. The melting line crosses the metalization line at 700 K and 220 GPa using density functional energetics and at 550 K and 290 GPa using Quantum Monte Carlo energetics.

Morales, M; Pierleoni, C; Schwegler, E; Ceperley, D

2010-02-08T23:59:59.000Z

369

Pulsed laser kinetic studies of liquids under high pressure. Progress report, November 29, 1990--November 25, 1991  

SciTech Connect (OSTI)

A high pressure apparatus constructed for measuring the rates of reactions in liquids under pressures ranging from 1 atm to 2000 atm has been used to measure the complexation kinetics of molybdenum hexacarbonyl reacting with 2,2-bipyridine, 4,4{prime}-dimethyl-2-2{prime}-bipyridine and 4,4{prime}-diphenyl-2-2{prime} bipyridine in toluene. Pentacarbonyl reaction intermediates are created by a 10 nsec flash of frequency tripled Nd:YAG laser light. Measured activation volumes for chelate ligand ring closure indicate a change in mechanism from associative interchange to dissociative interchange as steric hindrance increases. A similar high pressure kinetics study of molybdenum carbonyl complexation by several substituted phenanthrolines is now well advanced that indicates that with the more rigid phenanthroline ligands steric effects from bulky substituents have less effect on the ring closure mechanism than in the case of the bipyridine ligands. An experimental concentration dependence of the fluorescence quantum yield of cresyl violet has been harmonized with previously published contradictory reports. Fluorescence of cresyl violet in various solvents and in micellar systems has also been systematically explored.

Eyring, E.M.

1991-11-25T23:59:59.000Z

370

Research and Development of High Temperature Light Water Cooled Reactor Operating at Supercritical-Pressure in Japan  

SciTech Connect (OSTI)

This paper summarizes the status and future plans of research and development of the high temperature light water cooled reactor operating at supercritical-pressure in Japan. It includes; the concept development; material for the fuel cladding; water chemistry under supercritical pressure; thermal hydraulics of supercritical fluid; and the conceptual design of core and plant system. Elements of concept development of the once-through coolant cycle reactor are described, which consists of fuel, core, reactor and plant system, stability and safety. Material studies include corrosion tests with supercritical water loops and simulated irradiation tests using a high-energy transmission electron microscope. Possibilities of oxide dispersion strengthening steels for the cladding material are studied. The water chemistry research includes radiolysis and kinetics of supercritical pressure water, influence of radiolysis and radiation damage on corrosion and behavior on the interface between water and material. The thermal hydraulic research includes heat transfer tests of single tube, single rod and three-rod bundles with a supercritical Freon loop and numerical simulations. The conceptual designs include core design with a three-dimensional core simulator and sub-channel analysis, and balance of plant. (authors)

Yoshiaki Oka [Nuclear Engineering Research Laboratory, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo, 112-0006 (Japan); Katsumi Yamada [Isogo Nuclear Engineering Center, Toshiba Corporation, 8, Shinsugita-cho, Isogo-ku, Yokohama, 235-8523 (Japan)

2004-07-01T23:59:59.000Z

371

High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points  

SciTech Connect (OSTI)

Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

Winoto, Winoto [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Tan, Sugata [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

2009-01-01T23:59:59.000Z

372

High-pressure dissociation of silver mercury iodide, Ag{sub 2}HgI{sub 4}  

SciTech Connect (OSTI)

High-pressure X-ray diffraction has been used to probe the behavior of the superionic conductor silver mercury iodide (Ag{sub 2}HgI{sub 4}) at pressures up to 5GPa and at temperatures from 295 to 370K. Significant changes in the diffraction spectra, indicative of structural transitions, are observed around 0.7 and 1.3GPa across the range of temperatures studied. The change at 0.7GPa is shown to correspond to the dissociation of silver mercury iodide into silver iodide and mercury iodide, i.e., Ag{sub 2}HgI{sub 4}->2AgI+HgI{sub 2}. The second transition, at 1.3GPa, is due to a structural phase transition within HgI{sub 2}. Rietveld analysis of the diffraction data is used to confirm and refine all the known crystal structures.

Parfitt, D.C. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); Hull, S. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom)]. E-mail: s.hull@rl.ac.uk; Keen, D.A. [Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Crichton, W. [ESRF, 6 Rue Jules Horowitz, BP 220, 38043 Grenoble CEDEX 9 (France)

2004-10-01T23:59:59.000Z

373

'Devil's Staircase'-Type Phase Transition in NaV{sub 2}O{sub 5} under High Pressure  

SciTech Connect (OSTI)

The 'devil's staircase'-type phase transition in the quarter-filled spin-ladder compound NaV{sub 2}O {sub 5} has been discovered at low temperature and high pressure by synchrotron radiation x-ray diffraction. A large number of transitions are found to successively take place among higher-order commensurate phases with 2a x 2b x zc type superstructures. The observed temperature and pressure dependence of modulation wave number q{sub c}, defined by 1/z, is well reproduced by the axial next nearest neighbor Ising model. The q{sub c} is suggested to reflect atomic displacements presumably coupled with charge ordering in this system.

Ohwada, K.; Fujii, Y.; Takesue, N.; Isobe, M.; Ueda, Y.; Nakao, H.; Wakabayashi, Y.; Murakami, Y.; Ito, K.; Amemiya, Y. (and others)

2001-08-20T23:59:59.000Z

374

Synthesis of new Diamond-like B-C Phases under High Pressure and Temperatures  

SciTech Connect (OSTI)

A cubic BC3 (c-BC3) phase was synthesized by direct transformation from graphitic phases at a pressure of 39 GPa and temperature of 2200 K in a laser-heated diamond anvil cell (DAC). A combination of x-ray diffraction (XRD), electron diffraction (ED), transmission electron microscopy (TEM) imaging, and electron energy loss spectroscopy (EELS) measurements lead us to conclude that the obtained phase is hetero-nano-diamond, c-BC3. The EELS measurements show that the atoms inside the cubic structure are bonded by sp3 bonds.

Ming, L. C. [University of Hawaii] [University of Hawaii; Zinin, P. V. [University of Hawaii] [University of Hawaii; Sharma, S. K. [University of Hawaii] [University of Hawaii

2014-04-22T23:59:59.000Z

375

MICROSTRUCTURE AND MECHANICAL PROPERTY PERFORMANCE OF COMMERCIAL GRADE API PIPELINE STEELS IN HIGH PRESSURE GASEOUS HYDROGEN  

SciTech Connect (OSTI)

The continued growth of the world s developing countries has placed an ever increasing demand on traditional fossil fuel energy sources. This development has lead to increasing research and development of alternative energy sources. Hydrogen gas is one of the potential alternative energy sources under development. Currently the most economical method of transporting large quantities of hydrogen gas is through steel pipelines. It is well known that hydrogen embrittlement has the potential to degrade steel s mechanical properties when hydrogen migrates into the steel matrix. Consequently, the current pipeline infrastructure used in hydrogen transport is typically operated in a conservative fashion. This operational practice is not conducive to economical movement of significant volumes of hydrogen gas as an alternative to fossil fuels. The degradation of the mechanical properties of steels in hydrogen service is known to depend on the microstructure of the steel. Understanding the levels of mechanical property degradation of a given microstructure when exposed to hydrogen gas under pressure can be used to evaluate the suitability of the existing pipeline infrastructure for hydrogen service and guide alloy and microstructure design for new hydrogen pipeline infrastructure. To this end, the 2 Copyright 2010 by ASME microstructures of relevant steels and their mechanical properties in relevant gaseous hydrogen environments must be fully characterized to establish suitability for transporting hydrogen. A project to evaluate four commercially available pipeline steels alloy/microstructure performance in the presences of gaseous hydrogen has been funded by the US Department of Energy along with the private sector. The microstructures of four pipeline steels were characterized and then tensile testing was conducted in gaseous hydrogen and helium at pressures of 800, 1600 and 3000 psi. Based on measurements of reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 800 and 3000 psi. This paper will describe the work performed on four commercially available pipeline steels in the presence of gaseous hydrogen at pressures relevant for transport in pipelines. Microstructures and mechanical property performances will be compared. In addition, recommendations for future work related to gaining a better understanding of steel pipeline performance in hydrogen service will be discussed.

Stalheim, Mr. Douglas [DGS Metallurgical Solutions Inc; Boggess, Todd [Secat; San Marchi, Chris [Sandia National Laboratories (SNL); Jansto, Steven [Reference Metals Company; Somerday, Dr. B [Sandia National Laboratories (SNL); Muralidharan, Govindarajan [ORNL; Sofronis, Prof. Petros [University of Illinois

2010-01-01T23:59:59.000Z

376

The development and operational testing of an experimental reactor for gas-liquid-solid reaction systems at high temperatures and pressures  

E-Print Network [OSTI]

shaft. With the impeller in place and rotating, gas was drawn into the top port and ejected at the impeller mount. The reactor pressure was monitored via the transducer port. The transducer was a Viatran Pressure Transducer, model 103. The liquid...THE DEVELOPMENT AND OPERATIONAL TESTING OF AN EXPERIMENTAL REACTOR FOR GAS-LIQUID-SOLID REACTION SYSTEMS AT HIGH TEMPERATURES AND PRESSURES A Thesis by RICHARD KENNETH HESS Submitted to the Graduate College of Texas A&M University in partial...

Hess, Richard Kenneth

2012-06-07T23:59:59.000Z

377

A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy  

SciTech Connect (OSTI)

The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon, E-mail: simon.penner@uibk.ac.at [Institute of Physical Chemistry, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck (Austria)

2014-08-15T23:59:59.000Z

378

The autoignition of iso-cetane at high to moderate temperatures and elevated pressures: Shock tube experiments and kinetic modeling  

SciTech Connect (OSTI)

Iso-cetane (2,2,4,4,6,8,8-heptamethylnonane, C{sub 16}H{sub 34}) is a highly branched alkane reference compound for determining cetane ratings. It is also a candidate branched alkane representative in surrogate mixtures for diesel and jet fuels. Here new experiments and kinetic modeling results are presented for the autoignition of iso-cetane at elevated temperatures and pressures relevant to combustion in internal combustion engines. Ignition delay time measurements were made in reflected shock experiments in a heated shock tube for {phi} = 0.5, 1.0, and 1.5 iso-cetane/air mixtures at temperatures ranging from 879 to 1347 K and pressures from 8 to 47 atm. Ignition delay times were measured using electronically excited OH emission, monitored through the shock tube end wall, and piezoelectric pressure transducer measurements, made at side wall locations. A new kinetic mechanism for the description of the oxidation of iso-cetane is presented that is developed based on a previous mechanism for iso-octane. Computed results from the mechanism are found in good agreement with the experimental measurements. To our knowledge, the ignition time measurements for iso-cetane presented here are the first of their kind. (author)

Oehlschlaeger, Matthew A.; Steinberg, Justin [Department of Mechanical, Aerospace, and Nuclear Engineering, Rensselaer Polytechnic Institute, 110 8th St., JEC 2049, Troy, NY 12180 (United States); Westbrook, Charles K.; Pitz, William J. [Lawrence Livermore National Laboratory, Livermore, CA (United States)

2009-11-15T23:59:59.000Z

379

Planetary fluids He and NH/sub 3/ at high shock pressures and temperatures  

SciTech Connect (OSTI)

Liquid He at 4.3 K and 1 atm was shocked to 16 GPa (160 kbar) and 12,000 K and double-shocked to 56 GPa and 21,000 K. Liquid perturbation theory was used to determine an effective interatomic potential from which the equation of state of He can be obtained over a wide range of densities and temperatures in the envelopes of the outer planets. A new fast optical pyrometer and a cryogenic specimen holder for liquid NH/sub 3/ were developed to measure shock temperatures of 4400 and 3600 K at pressures of 59 and 48 GPa. These conditions correspond to those in the ice layers in Uranus and Neptune. The shock temperature data are in reasonable agreement with an equation of state by Ree based on an intermolecular potential derived from NH/sub 3/ Hugoniot data.

Nellis, W.J.; Radousky, H.B.; Mitchell, A.C.; Holmes, N.C.; Ross, M.; Young, D.A.

1985-04-01T23:59:59.000Z

380

E-Print Network 3.0 - aluminum high pressure Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DIVISION Summary: contribution if spaceframe designs are developed for high-volume automobile markets. Aluminum has the potential... components are made using cast aluminum,...

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Gram-scale separation of curium from americium using alpha-hydroxyisobutyric acid in high-pressure cation columns  

SciTech Connect (OSTI)

Quantities of heavy element (americium and curium) up to 2.3 g have been successfully separated by chromatographic elution from cation resin using alpha-hydroxyisobutyrate in equipment originally designed for decigram-scale separations of /sup 252/Cf and heavier elements. The high-pressure ion exchange process was reliable and relatively easy to operate. Overall curium recoveries of 80 to 90% were readily achieved with decontamination from americium by factors of 400 to 500. The product and waste streams are both in forms readily coupled to further processing steps.

Bigelow, J.E.; Benker, D.E.; Chattin, F.R.; King, L.J.; Knauer, J.B.; Ross, R.G.; Stacy, R.G.; Wiggins, J.T.

1984-01-01T23:59:59.000Z

382

Engineering task plan for the development of a high pressure water drill system for BY-105 saltwell screen installation  

SciTech Connect (OSTI)

This engineering task plan identifies the activities required for developing an ultra high pressure water drill system for installation of a saltwell screen in Tank BY-105. A water drill system is needed to bore through the hard waste material in this tank because of the addition of Portland cement in the 1960s and/or 1970s. The activities identified in this plan include the design, procurement, and qualification testing of the water drill along with readiness preparations including developing operating procedures, training Operations personnel, and conducting an assessment of readiness.

RITTER, G.A.

1999-02-24T23:59:59.000Z

383

Thermodynamics of the ferromagnetic phase transition in nearly half metallic CoS2 at high pressures  

SciTech Connect (OSTI)

The volume change and heat capacity at the ferromagnetic phase transition in COS2 were measured at high pressures using X-rays generated by the Argonne synchrotron light source and by ac-calorimetry, respectively. The transition entropy, calculated on the basis of these experimental data, drops along the transition line due to quantum degradation, as required by Nernst's law. The volume change increases strongly along the transition line, which is explained by specifics of the compressibility difference of coexisting phases that results from nearly half metallic nature of the ferromagnetic phase of COS2. (C) 2013 Elsevier Ltd. All rights reserved.

Elkin, F. S. [Institute for High Pressure Physics of Russian Academy of Sciences; Zibrov, I. P. [Institute for High Pressure Physics of Russian Academy of Sciences; Novikov, A. P. [Institute for High Pressure Physics of Russian Academy of Sciences; Khasanov, S. S. [Institute for Solid State Physics Russian Academy of Sciences; Sidorov, V. A. [Institute for High Pressure Physics of Russian Academy of Sciences; Petrova, A. E. [Institute for High Pressure Physics of Russian Academy of Sciences; Lograsso, Thomas A. [Ames Laboratory; Thompson, J. D. [Los Alamos National Laboratory; Stishov, S. M. [Institute for High Pressure Physics of Russian Academy of Sciences

2013-12-06T23:59:59.000Z

384

Design and Operation of an In Situ High Pressure Reaction Cell for X-Ray Absorption Spectroscopy  

SciTech Connect (OSTI)

The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

Bare, Simon R.; Mickelson, G. E.; Modica, F. S. [UOP LLC, Des Plaines, IL, 60016 (United States); Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 6044 (United States)

2007-02-02T23:59:59.000Z

385

Microstructure and thermal stability of copper -carbon nanotube composites consolidated by High Pressure Torsion  

E-Print Network [OSTI]

Microstructure and thermal stability of copper - carbon nanotube composites consolidated by High as the hardness of the pure and composite materials were determined. Due to the pinning effect of CNTs­matrix nanocomposites [3,4]. Carbon nanotubes (CNTs) are promising disperse phase in these composites because their high

Gubicza, Jenõ

386

US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems  

SciTech Connect (OSTI)

The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

Dennis, R.A.

1997-05-01T23:59:59.000Z

387

Studies of the mechanism of Coal Hydrogenation by Electron Spin Resonance. Quarterly technical progress report, March 1-May 31, 1980. [For high-temperature, high pressure measurements  

SciTech Connect (OSTI)

This is the first quarterly report on the program Studies of Coal Hydrogenation by Electron Spin Resonance. This quarter has been devoted to constructing apparatus for high temperature-high pressure electron paramagnetic resonance (EPR) measurements, characterizing the performance of the microwave cavity, and carrying out preliminary room temperature studies on coals and coal products. At the start of this program, there were no microwave cavities available to study high pressure-high temperature reactions. A system was constructed which can be used to study coal hydrogenation, and satisfies the conditions described in the report. This cavity was constructed using funding from Rockwell International, and will be used on this program. Because of the dependence of the work to be done with this device for this program, the construction is described in detail. This report, therefore, considers the design philosophy, construction of the device, a preliminary discussion of its performance, and application of the cavity for room temperature studies on several varieties of coal.

Goldberg, Ira B.

1980-07-01T23:59:59.000Z

388

Chemical Processing in High-Pressure Aqueous Environments. 9. Process Development for Catalytic Gasification of Algae Feedstocks  

SciTech Connect (OSTI)

Through the use of a metal catalyst, gasification of wet algae slurries can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In a pressurized-water environment (20 MPa), near-total conversion of the organic structure of the algae to gases has been achieved in the presence of a supported ruthenium metal catalyst. The process is essentially steam reforming, as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high levels of methane, as dictated by thermodynamic equilibrium. As opposed to earlier work, biomass trace components were removed by processing steps so that they did not cause processing difficulties in the fixed catalyst bed tubular reactor system. As a result, the algae feedstocks, even those with high ash contents, were much more reliably processed. High conversions were obtained even with high slurry concentrations. Consistent catalyst operation in these short-term tests suggested good stability and minimal poisoning effects. High methane content in the product gas was noted with significant carbon dioxide captured in the aqueous byproduct in combination with alkali constituents and the ammonia byproduct derived from proteins in the algae. High conversion of algae to gas products was found with low levels of byproduct water contamination and low to moderate loss of carbon in the mineral separation step.

Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.

2012-07-26T23:59:59.000Z

389

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

390

Modeling high-pressure adsorption of gas mixtures on activated carbon and coal using a simplified local-density model  

SciTech Connect (OSTI)

The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO{sub 2} sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO{sub 2} on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO{sub 2} on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties.

Fitzgerald, J.E.; Robinson, R.L.; Gasem, K.A.M. [Oklahoma State University, Stillwater, OK (United States). School of Chemical Engineering

2006-11-07T23:59:59.000Z

391

Ultra-High Pressure Driver and Nozzle Survivability in the RDHWT/MARIAH II Hypersonic Wind Tunnel  

SciTech Connect (OSTI)

An ultra-high pressure device provides a high enthalpy (> 2500 kJ/kg), low entropy (< 5 kJ/kg-K) air source for the RDHWT/MARIAH II Program Medium Scale Hypersonic Wind Tunnel. The design uses stagnation conditions of 2300 MPa (330,000 Psi) and 750 K (900 F) in a radial configuration of intensifiers around an axial manifold to deliver pure air at 100 kg/s mass flow rates for run times suitable for aerodynamic, combustion, and test and evaluation applications. Helium injection upstream of the nozzle throat reduces the throat wall recovery temperature to about 1200 K and reduces the oxygen concentration at the nozzle wall.

Costantino, M.; Brown, G.; Raman, K.; Miles, R.; Felderman, J.

2000-06-02T23:59:59.000Z

392

Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks  

SciTech Connect (OSTI)

Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

2004-07-01T23:59:59.000Z

393

RESEARCH ARTICLE Quantitative X-ray measurements of high-pressure fuel sprays  

E-Print Network [OSTI]

in the STAR-CD software. 1 Introduction Diesel engines have been the preferred power train for heavy heavy duty diesel injector A. I. Rami´rez � S. Som � Suresh K. Aggarwal � A. L. Kastengren � E. M. El in the near-nozzle region of a diesel engine injector. The technique provides high spatial and temporal

Aggarwal, Suresh K.

394

RUI: Structure and Behavior of RF-Driven Plasma Filaments in High-Pressure Gases  

SciTech Connect (OSTI)

The filamentary discharge seen within commercial plasma globes is commonly enjoyed, yet not well understood. We investigate filament properties in a plasma globe using a variable high voltage amplifier. Results from the 3-year grant period and their physics are discussed.

Burin, Michael [CSUSM

2014-11-18T23:59:59.000Z

395

HIGH PRESSURE VAPOR TRANSPORT OF ZnGeP 2 : II. THREEDIMENSIONAL SIMULATION OF GASDYNAMICS UNDER  

E-Print Network [OSTI]

grant #DMS­9201252. 2 To appear in the proceedings of the International Symposium on Experimental for Research in Scientific Computation Department of Mathematics North Carolina State University Raleigh, NC Carolina State University Raleigh, NC, USA Abstract The fluid dynamics in a vertical reactor for high

396

Pressure-induced valence change in YbAl3: A combined high-pressure inelastic x-ray scattering and theoretical investigation  

E-Print Network [OSTI]

4Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, New Mexico 87545, USA 5 HPCAT, Carnegie-ray emission RXES measurements were performed on the intermediate-valence com- pound YbAl3 under pressure of up-liquid coherence and the crossover to the local-moment regime have been studied by transport,15 inelastic nuclear

Svane, Axel Torstein

397

Laser-driven formation of a high-pressure phase in amorphous silica  

SciTech Connect (OSTI)

A combination of electron diffraction and infrared reflectance measurements shows that synthetic silica transforms partially into stishovite under high-intensity (GW/cm2) laser irradiation, probably by the formation of a dense ionized plasma above the silica surface. During the transformation the silicon coordination changes from four-fold to six-fold and the silicon-oxygen bond changes from mostly covalent to mostly ionic, such that optical properties of the transformed material differ significantly from those of the original glass. This phase transformation offers one suitable mechanism by which laser-induced damage grows catastrophically once initiated, thereby dramatically shortening the service lifetime of optics used for high-power photonics applications such as inertial confinement fusion.

Salleo, Alberto; Taylor, Seth T.; Martin, Michael C.; Panero, Wendy R.; Jeanloz, Raymond; Genin, Francois Y.; Sands, Timothy

2002-05-31T23:59:59.000Z

398

Qualitative and quantitative analysis of low molecular weight phenols by high pressure liquid chromatography  

E-Print Network [OSTI]

. A. , Bethany College Chairman of Advisory Comnittee: Dr. Lloyd W. Rooney A high performance liquid chromatographic (HPI C) method was de- veloped for the separation and identification of substituted benzoic and cinnamic acids (phenolic acids...). The 8 commonly occurring phenolic acids chosen as standards were: gallic, protocatechuic, p-hydroxyben- zoic, vanillic, caffeic, p-coumaric, feruli c and ci nnami c acids. Separation was on a nonpolar C18 substituted, silica based column with elution...

Hahn, David Henry

2012-06-07T23:59:59.000Z

399

High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground Hawaii HIGH PERFORMANCE and SUSTAINABLEIssues |

400

Inside Ice Under High Pressure | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadore Perlman,Bios High EnergyElianeScienceScience| U.S. DOE

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Study of high pressure gas filled RF cavities for muon collider  

E-Print Network [OSTI]

Muon collider is a considerable candidate of the next-generation high-energy lepton collider machine. Operating an RF cavity in a multi-Tesla magnet is a critical requirement in a muon accelerator and a cooling channel. However, the maximum RF gradient in a vacuum RF cavity is strongly limited by an external magnetic field. Dense hydrogen gas filled RF cavity has been proposed since it is functional of generating a high RF accelerating gradient in a strong magnetic field and making an ionization cooling process at the same time. A critical issue of the cavity is a beam- induced plasma that consumes a considerable amount of RF power. The gas filled RF test cell was made and measured the RF loading due to a beam-induced plasma by using an intense proton beam at Fermilab. By doping an electronegative gas in dense hydrogen, the plasma loading effect is significantly mitigated. The result shows that the cavity is functional with a muon collider beam. Recent progress is shown in this presentation.

Yonehara, Katsuya

2015-01-01T23:59:59.000Z

402

Effect of high pressure homogenization on the milk fat globule membrane and its relation with the emulsion stability of milk  

E-Print Network [OSTI]

pressure and heating temperature. Emulsion stability of milk increased with increased homogenization pressure and heat treatment, but was not affected by the milk fat concentrations used. Homogenization of milk increased the milk fat surface area...

Cano Ruiz, Maria Elena

1996-01-01T23:59:59.000Z

403

Mechanical and transport properties of rocks at high temperatures and pressures. Task II: fracture permeability of crystalline rocks as a function of temperature, pressure, and hydrothermal alteration  

SciTech Connect (OSTI)

The primary objective is to measure and understand the variation of the fracture permeability of quartzite subjected to hydrothermal conditions. Pore fluids will consist of distilled water and aqueous Na/sub 2/CO/sub 3/ solutions at temperatures to 250/sup 0/C, fluid pressures to 20 MPa and effective normal stresses to 70 MPa. Fluid flow rates will be controllable to rates at least as small as 0.2 ml/day (approx. 4 fracture volumes). Experiments are designed to assess what role, if any, pressure solution may play at time scales of those of the experiments (less than or equal to 2 weeks). Secondary objectives are: (1) continue simulated fracture studies, incorporating inelastic deformation into model and characterize the nature of inelastic deformation occurring on loaded tensile fractures in quartzite; (2) continue dissolution experiment, with emphasis on dissolution modification of tensile fracture surfaces on quartzite; and (3) study natural fractures in a quartzite exhibiting hydrothermal dissolution features.

Not Available

1981-01-01T23:59:59.000Z

404

Effect of Ti doping on high pressure behavior of BiMn{sub 2}O{sub 5}  

SciTech Connect (OSTI)

Our high pressure x-ray diffraction studies on BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} show iso-structural phase transition above 12 GPa similar to the one observed in undoped BiMn{sub 2}O{sub 5}; however anisotropic compressional behavior is found to be more enhanced in the doped case. Unlike undoped system, an anomalous lattice expansion along c axis has been observed in BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} above 12 GPa; whereas the b lattice parameter has been found to be more compressible as compared to BiMn{sub 2}O{sub 5}. As doping with Ti reduces the magnetic interactions among Mn ions, the observed changes are suggestive of having adverse magnetic implications in the observed iso-structural phase transition.

Pandey, K. K., E-mail: kkpandey@barc.gov.in; Poswal, H. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 40008 (India); Kumar, Ravi [Centre for Materials Science and Engineering, National Institute of Technology, Hamirpur-177005 (India)

2014-04-24T23:59:59.000Z

405

Assessment of Computer Simulation Software and Process Data for High Pressure Die Casting of Magnesium  

SciTech Connect (OSTI)

Computer software for the numerical simulation of solidification and mold filling is an effective design tool for cast structural automotive magnesium components. A review of commercial software capabilities and their validation procedures was conducted. Aside form the software assessment, the program addressed five main areas: lubricant degradation, lubricant application, gate atomization, and heat transfer at metal mold interfaces. A test stand for lubricant application was designed. A sensor was used for the direct measurement of heat fluxes during lubricant application and casting solidification in graphite molds. Spray experiments were conducted using pure deionized water and commercial die lubricants. The results show that the sensor can be used with confidence for measuring heat fluxes under conditions specific to the die lube application. The data on heat flux was presented in forms suitable for use in HPDC simulation software. Severe jet breakup and atomization phenomena are likely to occur due to high gate velocities in HPDC. As a result of gate atomization, droplet flow affects the mold filling pattern, air entrapment, skin formation, and ensuing defects. Warm water analogue dies were designed for obtaining experimental data on mold filling phenomena. Data on break-up jet length, break-up pattern, velocities, and droplet size distribution were obtained experimentally and was used to develop correlations for jet break-up phenomena specific to die casting gate configurations.

Sabau, Adrian S [ORNL; Hatfield, Edward C [ORNL; Dinwiddie, Ralph Barton [ORNL; Kuwana, Kazunori [University of Kentucky; Viti, Valerio [University of Kentucky, Lexington; Hassan, Mohamed I [University of Kentucky, Lexington; Saito, Kozo [University of Kentucky

2007-09-01T23:59:59.000Z

406

Three-dimensional discrete ordinates radiation transport calculations of neutron fluxes for beginning-of-cycle at several pressure vessel surveillance positions in the high flux isotope reactor  

SciTech Connect (OSTI)

The objective of this research was to determine improved thermal, epithermal, and fast fluxes and several responses at mechanical test surveillance location keys 2, 4, 5, and 7 of the pressure vessel of the Oak Ridge National Laboratory High Flux Isotope Reactor (HFIR) for the beginning of the fuel cycle. The purpose of the research was to provide essential flux data in support of radiation embrittlement studies of the pressure vessel shell and beam tubes at some of the important locations.

Pace, J.V. III; Slater, C.O.; Smith, M.S.

1993-11-01T23:59:59.000Z

407

The analysis of cracks in high-pressure piping and their effects on strength and lifetime of construction components at the Ignalina nuclear plant  

SciTech Connect (OSTI)

A number of cracks and damages of other sorts have been identified in the high-pressure parts at the Ignalina Nuclear Plant. They are caused by inadequate production- and repair technologies, as well as by thermal, chemical and mechanical processes of their performance. Several techniques are available as predictions of cracks and other defects of pressurized vessels. The choice of an experimental technique should be based on the level of its agreement with the actual processes.

Aleev, A.; Petkevicius, K.; Senkus, V. [and others

1997-04-01T23:59:59.000Z

408

Phase transitions and equation of state of CsI under high pressure and the development of a focusing system for x-rays  

SciTech Connect (OSTI)

The phase transitions and equation of state of ionic solid cesium iodide were studied under high pressure and room temperature in a diamond anvil cell. The studies were carried out using both energy dispersive and angular dispersive diffraction methods on synchrotron radiation sources over the pressure range from atmospheric pressure to over 300 gigapascals (3 million atmospheres). CsI undergoes a distinct phase transition at about 40 GPa, a pressure that is much lower than the reported insulator-metal transition at 110 GPa, from the atmospheric pressure B2(CsCl) structure to an orthorhombic structure. At higher pressures, a continuous distortion in the structure was observed with a final structure similar to a hcp lattice under ultra high pressure. No volume discontinuity was observed at the insulator-metal transition. The newly found transition sequence is different from the result of previous static compression studies. The current structure has a smaller unit cell volume than the previous assignment. This has resolved a long existing controversy among the previous static compression studies, the dynamic compression studies, and the theoretical studies. The current results also explain the apparent discrepancy between the present study and the previous static studies. We also present the development of a focusing system for high energy x-rays (> 12 keV) that is particularly suited for high pressure diffraction studies. This system uses a pair of multilayer coated spherical mirrors in a Kirkpatrick-Baez geometry. A focused beam size less than 10 micron in diameter can be readily achieved with sufficient intensity to perform diffraction studies. 93 refs., 46 figs., 15 tabs.

Wu, Yan.

1990-11-01T23:59:59.000Z

409

Influence of viscous friction heating on the efficiency of columns operated under very high pressures  

SciTech Connect (OSTI)

When columns packed with very fine particles are operated at high mobile phase velocities, the friction of the mobile phase percolating through the column bed generates heat. This heat dissipates along and across the column and axial and radial temperature gradients appear. The wall region of the column tends to be cooler than its center, and due to the influence of temperature on the mobile phase viscosity and on the equilibrium constant of analytes, the band velocity is not constant across the column. This radial heterogeneity of the temperature distribution across the column contributes to band broadening. This phenomenon was investigated assuming a cylindrically symmetrical column and using the general dispersion theory of Aris, which relates the height equivalent to the theoretical plate (HETP) contribution due to a radial heterogeneity of the column to the radial distribution of the linear velocities of a compound peak and to the radial distribution of its apparent dispersion coefficients in the column bed. The former is known from the temperature gradient across the column, the temperature dependencies of the mobile phase viscosity, and the retention factor of the compound. The latter is derived from the known expression of the transverse reduced HETP equation for the column. The values of the HETP calculated with the Aris model and a classical HETP equation were compared to those measured on a 2.1 x 50 mm Acquity BEH-C{sub 18} column, run at flow rates of 0.6, 0.95, 1.30, and 1.65 mL/min, with pure acetonitrile as the mobile phase and naphtho[2,3-a]pyrene as the retained compound. These two sets of data are in generally good agreement, although the experimental values of the HETP tend to increase faster with increasing mobile phase velocity than the calculated values.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

2009-01-01T23:59:59.000Z

410

Investigation on the effects of ultra-high pressure and temperature on the rheological properties of oil-based drilling fluids  

E-Print Network [OSTI]

Designing a fit-for-purpose drilling fluid for high-pressure, high-temperature (HP/HT) operations is one of the greatest technological challenges facing the oil and gas industry today. Typically, a drilling fluid is subjected to increasing...

Ibeh, Chijioke Stanley

2009-05-15T23:59:59.000Z

411

Production management techniques for water-drive gas reservoirs. Field number 1, onshore gulf coast over-pressured, high yield condensate reservoir. Topical report, July 1993  

SciTech Connect (OSTI)

To develop improved completion and reservoir management strategies for water-drive gas reservoirs, the study conducted on an overpressured high yield gas condensate reservoir is reported. The base recovery factor for the field was projected to be only 47.8%, due to high residual gas saturation and a relatively strong aquifer which maintained reservoir pressure.

Hower, T.L.

1993-07-01T23:59:59.000Z

412

On the Accuracy of van der Waals Inclusive Density-Functional Theory Exchange-Correlation Functionals for Ice at Ambient and High Pressures  

E-Print Network [OSTI]

Density-functional theory (DFT) has been widely used to study water and ice for at least 20 years. However, the reliability of different DFT exchange-correlation (xc) functionals for water remains a matter of considerable debate. This is particularly true in light of the recent development of DFT based methods that account for van der Waals (vdW) dispersion forces. Here, we report a detailed study with several xc functionals (semi-local, hybrid, and vdW inclusive approaches) on ice Ih and six proton ordered phases of ice. Consistent with our previous study [Phys. Rev. Lett. 107, 185701 (2011)] which showed that vdW forces become increasingly important at high pressures, we find here that all vdW inclusive methods considered improve the relative energies and transition pressures of the high-pressure ice phases compared to those obtained with semi-local or hybrid xc functionals. However, we also find that significant discrepancies between experiment and the vdW inclusive approaches remain in the cohesive properties of the various phases, causing certain phases to be absent from the phase diagram. Therefore, room for improvement in the description of water at ambient and high pressures remains and we suggest that because of the stern test the high pressure ice phases pose they should be used in future benchmark studies of simulation methods for water.

Biswajit Santra; Ji?í Klimeš; Alexandre Tkatchenko; Dario Alfè; Ben Slater; Angelos Michaelides; Roberto Car; Matthias Scheffler

2014-08-14T23:59:59.000Z

413

Development of Larger Diameter High Pressure CNG Cylinder Manufactured by Piercing and Drawing for Natural Gas Vehicle  

Broader source: Energy.gov [DOE]

These slides were presented at the International Hydrogen Fuel and Pressure Vessel Forum on September 27 – 29, 2010, in Beijing, China.

414

Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service  

E-Print Network [OSTI]

1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

415

The high pressure synthesis and structure of a new aurate, CaAu{sub 2}O{sub 4}  

SciTech Connect (OSTI)

A novel aurate CaAu{sub 2}O{sub 4} has been synthesized by high pressure-temperature technique. The sample was contained in an Au capsule and heated to 1000{approximately}1200{degrees}C at 12{approximately}15 GPa in the split-sphere multi-anvil apparatus (USSA-2000). Electron probe Microanalysis of small crystals indicated an oxide ratio of 0.96(6) CaO:1.01(2) Au{sub 2}O{sub 3}. The compound is pale yellow, with a = 5.991141(1), c = 10.04983(3) {angstrom}, Z = 4, 14{sub 1}/a. The structure was solved using both synchroton x-ray powder diffraction and single crystal x-ray data. It consists of corner-linked AuO{sub 4} square planes and distorted CaO{sub 8} dodecahedra; in the figure Ca{sup 2+} ions (circles) are filled in the cavities surrounded by staggered square planar AuO{sub 4} units.

Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)

1995-12-31T23:59:59.000Z

416

Pulsed laser kinetic studies of liquids under high pressure. Final technical report, April 1, 1990--March 31, 1993  

SciTech Connect (OSTI)

Experiments have been developed for measuring the rates of chemical reactions liquids and in supercritical Co{sub 2}. A pulsed (Q-switch) Nd:YAG laser at 355 nm was the pump beam for laser flash photolysis studies of molybdenum and tungsten hexacarbonyls undergoing ligand displacement reactions by bidentate chelating agents such as 2,2{prime}-bipyridine in toluene. Experiments were carried out at 0.1 to 150 MPa. In the case of molybdenum complexes, the reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Similar high pressure flash photolysis experiments with tungsten hexacarbonyl have also been completed. The concentration dependence of the fluorescence and nonradiative decay quantum yields for cresyl violet in several solvent have been reported as well as stability constants for the complexation of lithium ion by four different crown ethers dissolved in a room temperature molten salt.

Eyring, E.M.

1993-06-21T23:59:59.000Z

417

High-Pressure Synchtron Radiation X-Ray Diffraction Studies of Pentaerythritol Tetranitrate C(CH[subscript 2]ONO[subscript 2 ])[subscript 4  

SciTech Connect (OSTI)

A high-pressure x-ray diffraction study of nanocrystalline pentaerythritol tetranitrate, C(CH{sub 2}ONO{sub 2}){sub 4}, (PETN), has been performed in a diamond-anvil cell at ambient temperature using synchrotron radiation. Pressure-induced alterations in the profiles of the diffraction lines, including their positions, widths and intensities were followed up to 30 GPa in a compressino cycle. The spectral changes in the diffraction patterns at low pressures indicated continuous densification of the tetragonal structure (space group P{bar 4}2{sub 1}c). The diffraction patterns confirmed that PETN compressed from ambient pressure to 7.4 GPa by 17%. At 8.2 GPa and above, several new diffraction lines appeared in the patterns. These lines suggest that the lattice undergoes an incomplete stress-induced structural transformation from the tetragonal to an orthorhombic structure (most probably space group P2{sub 1}22{sub 1}). The mixture of both structures appeared to persist to 30 GPa. The progressive broadening of the diffraction lines as the pressure increased beyond 10 GPa is attributed to the combined diffraction lines of a mixture of two coexisting PETN phases and inhomogeneous pressure distribution within the sample.

Lipinska-Kalita, K.E.; Pravica, M.; Nicol, M. (UNLV)

2006-02-02T23:59:59.000Z

418

ccsd-00005161,version1-6Jun2005 Metastability Exchange Optical Pumping of Helium-3 at High Pressures and 1.5 T  

E-Print Network [OSTI]

ccsd-00005161,version1-6Jun2005 Metastability Exchange Optical Pumping of Helium-3 at High Pressures and 1.5 T: Comparison of two Optical Pumping Transitions M. Abboud, A. Sinatra, G. Tastevin, and P, France Abstract: At low magnetic field, metastability exchange optical pumping of helium-3 is known

Paris-Sud XI, Université de

419

GEOPHYSICAL RESEARCH LETTERS, VOL. 24, NO. 24, PAGES 3269-3272, DECEMBER 15, 1997 Ab initio elasticity of three high-pressure polymorphs  

E-Print Network [OSTI]

. Full elastic constant tensors of three high- pressure polymorphs of silica: stishovite, CaCl2-type stishovite to the CaCl2 structure at 47 GPa. At this phase transition, the isotropically averaged shear wave of two. The trans- formation of the CaCl2 phase to the columbite phase at 98 GPa is accompanied

Stixrude, Lars

420

Large volume high-pressure cell for inelastic neutron scattering W. Wang, D. A. Sokolov, A. D. Huxley, and K. V. Kamenev  

E-Print Network [OSTI]

Large volume high-pressure cell for inelastic neutron scattering W. Wang, D. A. Sokolov, A. D for inelastic neutron scattering measurements of quantum fluids and solids Rev. Sci. Instrum. 84, 015101 (2013) TOF-SEMSANS--Time-of-flight spin-echo modulated small-angle neutron scattering J. Appl. Phys. 112

Hall, Christopher

Note: This page contains sample records for the topic "100w high pressure" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Effect of H2O on the density of silicate melts at high pressures: Static experiments and the application of a  

E-Print Network [OSTI]

Effect of H2O on the density of silicate melts at high pressures: Static experiments in revised form 1 March 2012; available online 13 March 2012 Abstract Density of ultramafic silicate melts­Murnaghan equation of state and a newly devel- oped equation of state for silicate melts based on the model of hard

422

Reviving Abandoned Reservoirs with High-Pressure Air Injection: Application in a Fractured and Karsted Dolomite Reservoir  

SciTech Connect (OSTI)

Despite declining production rates, existing reservoirs in the United States contain vast volumes of remaining oil that is not being effectively recovered. This oil resource constitutes a huge target for the development and application of modern, cost-effective technologies for producing oil. Chief among the barriers to the recovery of this oil are the high costs of designing and implementing conventional advanced recovery technologies in these mature, in many cases pressure-depleted, reservoirs. An additional, increasingly significant barrier is the lack of vital technical expertise necessary for the application of these technologies. This lack of expertise is especially notable among the small operators and independents that operate many of these mature, yet oil-rich, reservoirs. We addressed these barriers to more effective oil recovery by developing, testing, applying, and documenting an innovative technology that can be used by even the smallest operator to significantly increase the flow of oil from mature U.S. reservoirs. The Bureau of Economic Geology and Goldrus Producing Company assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The Permian Basin, the largest oil-bearing basin in North America, contains more than 70 billion barrels of remaining oil in place and is an ideal venue to validate this technology. We have demonstrated the potential of HPAI for oil-recovery improvement in preliminary laboratory tests and a reservoir pilot project. To more completely test the technology, this project emphasized detailed characterization of reservoir properties, which were integrated to access the effectiveness and economics of HPAI. The characterization phase of the project utilized geoscientists and petroleum engineers from the Bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. The successful development of HPAI technology has tremendous potential for increasing the flow of oil from deep carbonate reservoirs in the Permian Basin, a target resource that can be conservatively estimated at more than 1.5 billion barrels. Successful implementation in the field chosen for demonstration, for example, could result in the recovery of more than 34 million barrels of oil that will not otherwise be produced. Geological and petrophysical analysis of available data at Barnhart field reveals the following important observations: (1) the Barnhart Ellenburger reservoir is similar to most other Ellenburger reservoirs in terms of depositional facies, diagenesis, and petrophysical attributes; (2) the reservoir is characterized by low to moderate matrix porosity much like most other Ellenburger reservoirs in the Permian Basin; (3) karst processes (cave formation, infill, and collapse) have substantially altered stratigraphic architecture and reservoir properties; (4) porosity and permeability increase with depth and may be associated with the degree of karst-related diagenesis; (5) tectonic fractures overprint the reservoir, improving overall connectivity; (6) oil-saturation profiles show that the oil-water contact (OWC) is as much as 125 ft lower than previous estimations; (7) production history and trends suggest that this reservoir is very similar to other solution-gas-drive reservoirs in the Permian Basin; and (8) reservoir simulation study showed that the Barnhart reservoir is a good candidate for HPAI and that application of horizontal-well technology can improve ultimate resource recovery from the reservoir.

Robert Loucks; Stephen C. Ruppel; Dembla Dhiraj; Julia Gale; Jon Holder; Jeff Kane; Jon Olson; John A. Jackson; Katherine G. Jackson

2006-09-30T23:59:59.000Z

423

Field test of two high-pressure direct-contact downhole steam generators. Volume II. Oxygen/diesel system  

SciTech Connect (OSTI)

A field test of an oxygen/diesel fuel, direct contact steam generator has been completed. The field test, which was a part of Project DEEP STEAM and was sponsored by the US Department of Energy, involved the thermal stimulation of a well pattern in the Tar Zone of the Wilmington Oil Field. The activity was carried out in cooperation with the City of Long Beach and the Long Beach Oil Development Company. The steam generator was operated at ground level, with the steam and combustion products delivered to the reservoir through 2022 feet of calcium-silicate insulated tubing. The objectives of the test included demonstrations of safety, operational ease, reliability and lifetime; investigations of reservoir response, environmental impact, and economics; and comparison of those points with a second generator that used air rather than oxygen. The test was extensively instrumented to provide the required data. Excluding interruptions not attributable to the oxygen/diesel system, steam was injected 78% of the time. System lifetime was limited by the combustor, which required some parts replacement every 2 to 3 weeks. For the conditions of this particular test, the use of trucked-in LOX resulted in liess expense than did the production of the equivalent amount of high pressure air using on site compressors. No statistically significant production change in the eight-acre oxygen system well pattern occurred during the test, nor were any adverse effects on the reservoir character detected. Gas analyses during the field test showed very low levels of SOX (less than or equal to 1 ppM) in the generator gaseous effluent. The SOX and NOX data did not permit any conclusion to be drawn regarding reservoir scrubbing. Appreciable levels of CO (less than or equal to 5%) were measured at the generator, and in this case produced-gas analyses showed evidence of significant gas scrubbing. 64 figures, 10 tables.

Moreno, J.B.

1983-07-01T23:59:59.000Z

424

Field test of two high-pressure, direct-contact downhole steam generators. Volume I. Air/diesel system  

SciTech Connect (OSTI)

As a part of the Project DEEP STEAM to develop technology to more efficiently utilize steam for the recovery of heavy oil from deep reservoirs, a field test of a downhole steam generator (DSG) was performed. The DSG burned No. 2 diesel fuel in air and was a direct-contact, high pressure device which mixed the steam with the combustion products and injected the resulting mixture directly into the oil reservoir. The objectives of the test program included demonstration of long-term operation of a DSG, development of operational methods, assessment of the effects of the steam/combustion gases on the reservoir and comparison of this air/diesel DSG with an adjacent oxygen/diesel direct contact generator. Downhole operation of the air/diesel DSG was started in June 1981 and was terminated in late February 1982. During this period two units were placed downhole with the first operating for about 20 days. It was removed, the support systems were slightly modified, and the second one was operated for 106 days. During this latter interval the generator operated for 70% of the time with surface air compressor problems the primary source of the down time. Thermal contact, as evidenced by a temperature increase in the production well casing gases, and an oil production increase were measured in one of the four wells in the air/diesel pattern. Reservoir scrubbing of carbon monoxide was observed, but no conclusive data on scrubbing of SO/sub x/ and NO/sub x/ were obtained. Corrosion of the DSG combustor walls and some other parts of the downhole package were noted. Metallurgical studies have been completed and recommendations made for other materials that are expected to better withstand the downhole combustion environment. 39 figures, 8 tables.

Marshall, B.W.

1983-05-01T23:59:59.000Z

425

METC/3M Cooperative Agreement CRADA 94-024 high temperature high pressure filter materials exposure test program. Volume 1, Final report  

SciTech Connect (OSTI)

In conjunction with shakedown, operation, and desulfurization testing at the Morgantown Energy Technology Center (METC) 10 in. Fluid Bed Gasification and Cleanup facility, a series of tests was completed in cooperation with the Minnesota Mining and Manufacturing Company (3M). This cooperative research and development agreement (CRADA) between METC and 3M was to evaluate exposure of 3M SICONEX{trademark} fiber-reinforced ceramic and NEXTEL{trademark} 312 and 550 ceramic fabric materials to a gasifying environment at high temperatures (1000--1100{degree}F) and high pressure (300 psia). Minnesota Mining and Manufacturing Company (3M) provided two 60 mm I.D. {times} 0.5 m SICONEX{trademark} spools and one each of the NEXTEL{trademark} 312 and 550 ceramic fabrics for exposure to coal gas from the METC gasifier. METC installed the materials in a vessel existing in the METC Cleanup Facility and provided process data in exchange for ceramic filter and ash/char characterization. Details of the CRADA are found in CRADA 94-024. This report contains METC`s contribution to CRADA 94-024. Four gasifier runs were conducted over a five month period to accumulate 483 hours of operation. During this time, 2 LayCer{trademark} 70/3 filters were used for filtering the coal gas while the SICONEX{trademark} and NEXTEL{trademark} were exposed along side of the filters. During one 89 hour test, one Laycer{trademark} 70/3 candle was installed with a 3M ceramic composite filter. The face velocity through the candles was maintained nominally at 2.5 ft/min throughout the testing.

NONE

1995-06-01T23:59:59.000Z

426

Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system  

DOE Patents [OSTI]

In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

2002-01-01T23:59:59.000Z

427

High-pressure single-crystal X-ray diffraction of Tl{sub 2}SeO{sub 4}  

SciTech Connect (OSTI)

The effect of pressure on the crystal structure of thallium selenate (Tl{sub 2}SeO{sub 4}) (Pmcn, Z=4), containing the Tl{sup +} cations with electron lone pairs, has been studied with single-crystal X-ray diffraction in a diamond anvil cell up to 3.64 GPa at room temperature. No phase transition has been observed. The compressibility data are fitted by a Murnaghan equation of state with the zero-pressure bulk modulus B{sub 0}=29(1) GPa and the unit-cell volume at ambient pressure V{sub 0}=529.6(8) A{sup 3} (B'=4.00). Tl{sub 2}SeO{sub 4} is the least compressible in the c direction, while the pressure-induced changes of the a and b lattice parameters are quite similar. These observations can be explained by different pressure effects on the nine- and 11-fold coordination polyhedra around the two non-equivalent Tl atoms. The SeO{sub 4}{sup 2-} tetrahedra are not rigid units and become more distorted. Their contribution to the compressibility is small. The effect of pressure on the isotypical oxide materials A{sub 2}TO{sub 4} with the {beta}-K{sub 2}SO{sub 4} structure is discussed. It appears that the presence of electron lone pairs on the Tl{sup +} cation does not seem to influence the compressibility of Tl{sub 2}SeO{sub 4}. - Graphical abstract: Pressure dependence of normalized lattice parameters and unit-cell volumes in Tl{sub 2}SeO{sub 4} (Pmcn, Z=4). The solid line is the Murnaghan equation of state.

Grzechnik, Andrzej [Departamento de Fisica de la Materia Condensada, Universidad del Pais Vasco, E-48080 Bilbao (Spain)], E-mail: andrzej.grzechnik@ehu.es; Breczewski, Tomasz; Friese, Karen [Departamento de Fisica de la Materia Condensada, Universidad del Pais Vasco, E-48080 Bilbao (Spain)

2008-11-15T23:59:59.000Z

428

High-pressure single-crystal elasticity study of CO{sub 2} across phase I-III transition  

SciTech Connect (OSTI)

Sound velocities and elastic moduli of solid single-crystal CO{sub 2} were measured at pressures up to 11.7(3) GPa by Brillouin spectroscopy. The aggregate adiabatic bulk modulus (K{sub S}), shear modulus (G), and their pressure derivatives for CO{sub 2} Phase I are K{sub S0}?=?3.4(6) GPa, G{sub 0}?=?1.8(2) GPa, (dK{sub S}/dP){sub 0}?=?7.8(3), (dG/dP){sub 0}?=?2.5(1), (d{sup 2}K{sub S}/dP{sup 2}){sub 0}?=??0.23(3) GPa{sup ?1}, and (d{sup 2}G/dP{sup 2}){sub 0}?=??0.10(1) GPa{sup ?1}. A small increase of elastic properties was observed between 9.8(1) and 10.5(3) GPa, in agreement with the CO{sub 2} I-III transition pressure determined from previous x-ray diffraction experiments. Above the transition pressure P{sub T}, we observed a mixture dominated by CO{sub 2}-I, with minor CO{sub 2}-III. The CO{sub 2}-I + III mixture shows slightly increased sound velocities compared to pure CO{sub 2}-I. Elastic anisotropy calculated from the single-crystal elasticity tensor exhibits a decrease with pressure beginning at 7.9(1) GPa, which is lower than P{sub T}. Our results coincide with recent X-ray Raman observations, suggesting that a pressure-induced electronic transition is related to local structural and optical changes.

Zhang, Jin S., E-mail: zhang72@illinois.edu; Bass, Jay D. [Department of Geology, University of Illinois, Urbana-Champaign, Illinois 61801 (United States); Shieh, Sean R. [Departments of Earth Sciences and Physics and Astronomy, University of Western Ontario, London, Ontario N6A 5B7 (Canada); Dera, Przemyslaw [Hawaii Institute of Geophysics and Planetology, University of Hawaii at Manoa, Honolulu, Hawaii 96822 (United States); Prakapenka, Vitali [Center for Advanced Radiation Sources, University of Chicago, Chicago, Illinois 60637 (United States)

2014-04-07T23:59:59.000Z

429

Structural characterization of Green River oil-shale at high-pressure using pair distribution function analysis and small angle x-ray scattering.  

SciTech Connect (OSTI)

The compression behavior of a silicate-rich oil shale from the Green River formation in the pressure range 0.0-2.4 GPa was studied using in situ high pressure X-ray pair distribution function (PDF) measurements for the sample contained within a Paris-Edinburgh cell. The real-space local structural information in the PDF, G(r), was used to evaluate the compressibility of the oil shale. Specifically, the pressure-induced reduction in the medium- to long-range atom distances (6-20 {angstrom}) yielded an average sample compressibility corresponding to a bulk modulus of ca. 61-67 GPa. A structural model consisting of a three phase mixture of the principal crystalline oil shale components (quartz, albite and Illite) provided a good fit to the ambient pressure PDF data (R 30.7%). Indeed the features in the PDF beyond 6 {angstrom}, were similarly well fit by a single phase model of the highest symmetry, highly crystalline quartz component.

Locke, D. R.; Chupas, P. J.; Chapman, K. W.; Pugmire, R. J.; Winans, R. E.; Univ. of Utah

2008-01-01T23:59:59.000Z

430

Assessment of kinetic modeling for lean H2/CH4/O2/diluent flames at high pressures  

E-Print Network [OSTI]

) and HO2 + H with the main branching reactions. Methane addition is shown to influence the pressure: Hydrogen; Methane; Syngas; Flame speed; Chemical mechanism 1. Introduction The H2/O2 reaction system CO, CO2, H2O, CH4 and other small hydrocarbons (synthetic gas or "syngas") from coal or biomass

Ju, Yiguang

431

Pore evolution during high pressure atomic vapor deposition D. D. Hass Y. Y. Yang H. N. G. Wadley  

E-Print Network [OSTI]

The development of physical vapor deposition systems that employ inert gas jets to entrain and deposit atomic conditions can contain a higher volume fraction of porosity and a different pore morphology to coatings created by conventional, low pressure (\\10-4 Pa) deposition processes. A recent direct simulation Monte

Wadley, Haydn

432

Pressure &Pressure & TemperatureTemperature  

E-Print Network [OSTI]

to measure atmospheric pressure, and thermometer toprobe to measure atmospheric pressure, and thermometer toprobe to measure atmospheric pressure, and thermometer toprobe to measure atmospheric pressure, and thermometer to measure air temperature.measure air temperature.measure air temperature.measure air temperature

California at Santa Cruz, University of

433

Pressure reducing regulator  

DOE Patents [OSTI]

A pressure reducing regulator that controls its downstream or outlet pressure to a fixed fraction of its upstream or inlet pressure. The regulator includes a housing which may be of a titanium alloy, within which is located a seal or gasket at the outlet end which may be made of annealed copper, a rod, and piston, each of which may be made of high density graphite. The regulator is insensitive to temperature by virtue of being without a spring or gas sealed behind a diaphragm, and provides a reference for a system in which it is being used. The rod and piston of the regulator are constructed, for example, to have a 1/20 ratio such that when the downstream pressure is less than 1/20 of the upstream pressure the regulator opens and when the downstream pressure exceeds 1/20 of the upstream pressure the regulator closes.

Whitehead, John C. (Davis, CA); Dilgard, Lemoyne W. (Willits, CA)

1995-01-01T23:59:59.000Z

434

Proceedings of the International Conference on Lasers `95, eds. V.J. Corcoran and T.A. Goldman, STS Press, McLean VA, 1996, pp. 225-231. OPTIMIZING HIGH PRESSURE CHEMICAL OXYGEN-IODINE LASERS  

E-Print Network [OSTI]

Press, McLean VA, 1996, pp. 225-231. OPTIMIZING HIGH PRESSURE CHEMICAL OXYGEN-IODINE LASERS David L laser model was baselined to existing oxygen-iodine research assessment and device improvement chemical(1) generator. It may be possible to improve high pressure RADICL performance by increasing the number of large

Carroll, David L.

435

A study of diesel combustion process under the condition of EGR and high-pressure fuel injection with gas sampling method  

SciTech Connect (OSTI)

It is well known that a high-pressure fuel injection is effective for the reduction in particulates and smoke emissions. Exhaust gas recirculation (EGR) is effective for the reduction in NO{sub x} emission. In this study an experiment aiming to understand more comprehensive combustion under the condition of EGR and high-pressure fuel injection was carried out by using gas sampling method for the purpose of understanding what occurred inside the spray before and after combustion. The number of combustion cycles in this engine can be controlled in order to change EGR conditions by adjusting the residual gas concentration in the cylinder. Main results were: (1) close to the nozzle tip, the sampling gas data showed little reaction which implies that combustion never occurs in this area during the injection period; (2) in the case of high-pressure fuel injection O{sub 2} concentration decreased faster and air dilution was more active and earlier, this may cause the decrease of smoke emissions due to accelerated soot oxidation; (3) in the case of EGR, combustion was poor since oxygen concentration was insufficient, thus, inactivity of oxidation reaction caused reduction in NO{sub x} emission; (4) in the case of increasing the amounts of N{sub 2} gas while keeping the O{sub 2} content constant (same amount as without EGR), NO{sub x} emission decreased without deterioration of smoke emission and Pmi.

Shimazaki, Naoki; Hatanaka, Hirokazu; Yokota, Katsuhiko; Nakahira, Toshio

1996-09-01T23:59:59.000Z

436

Modeling of thermal processes in very high pressure liquid chromatography for column immersed in a water bath: Application of the selected models  

SciTech Connect (OSTI)

Currently, chromatographic analyses are carried out by operating columns packed with sub-2 {micro}m particles under very high pressure gradients, up to 1200 bar for 5 cm long columns. This provides the high flow rates that are necessary for the achievement of high column efficiencies and short analysis times. However, operating columns at high flow rates under such high pressure gradients generate a large amount of heat due to the viscous friction of the mobile phase stream that percolates through a low permeability bed. The evacuation of this heat causes the formation of significant or even large axial and radial gradients of all the physico-chemical parameters characterizing the packing material and the mobile phase, eventually resulting in a loss of column efficiency. We previously developed and successfully applied a model combining the heat and the mass balances of a chromatographic column operated under very high pressure gradients (VHPLC). The use of this model requires accurate estimates of the dispersion coefficients at each applied mobile phase velocity. This work reports on a modification of the mass balance model such that only one measurement is now necessary to accurately predict elution peak profiles in a wide range of mobile phase velocities. The conditions under which the simple equilibrium-dispersive (ED) and transport-dispersive (TD) models are applicable in VHPLC are also discussed. This work proves that the new combination of the heat transfer and the ED model discussed in this work enables the calculation of accurate profiles for peaks eluted under extreme conditions, like when the column is thermostated in a water bath.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL; Kaczmarski, Krzysztof [University of Tennessee and Rzeszow University of Technology, Poland

2010-01-01T23:59:59.000Z

437

Ab initio studies of high-pressure structural transformations in silica B. B. Karki and M. C. Warren  

E-Print Network [OSTI]

CaCl2 phase occurs at 47 GPa, the transition from the CaCl2 to the Pnc2 structure at 98 GPa of the rutile and CaCl2 phases are determined as a function of pressure. The results are in excellent agreement. In situ Raman spectroscopy3 has revealed the rutile- to-CaCl2 transition at about 50 GPa which is much

Stixrude, Lars

438

Multiferroic CuCrO{sub 2} under high pressure: In situ X-ray diffraction and Raman spectroscopic studies  

SciTech Connect (OSTI)

The compression behavior of delafossite compound CuCrO{sub 2} has been investigated by in situ x-ray diffraction (XRD) and Raman spectroscopic measurements up to 23.2 and 34?GPa, respectively. X-ray diffraction data show the stability of ambient rhombohedral structure up to ?23?GPa. Material shows large anisotropy in axial compression with c-axis compressibility, ?{sub c}?=?1.26?×?10{sup ?3}(1) GPa{sup ?1} and a-axis compressibility, ?{sub a}?=?8.90?×?10{sup ?3}(6) GPa{sup ?1}. Our XRD data show an irreversible broadening of diffraction peaks. Pressure volume data when fitted to 3rd order Birch-Murnaghan equation of state give the value of bulk modulus, B{sub 0}?=?156.7(2.8) GPa with its pressure derivative, B{sub 0}{sup ?} as 5.3(0.5). All the observed vibrational modes in Raman measurements show hardening with pressure. Appearance of a new mode at ?24?GPa indicates the structural phase transition in the compound. Our XRD and Raman results indicate that CuCrO{sub 2} may be transforming to an ordered rocksalt type structure under compression.

Garg, Alka B., E-mail: alkagarg@barc.gov.in; Mishra, A. K.; Pandey, K. K.; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai 400085 (India)

2014-10-07T23:59:59.000Z

439

OPTIMIZATION AND DESIGN GUIDELINES FOR HIGH FLUX MICRO-CHANNEL HEAT SINKS FOR LIQUID AND GASEOUS SINGLE-PHASE FLOW  

E-Print Network [OSTI]

forced convection micro-channel heat sinks for minimum pump power at high heat fluxes. Results gained orders of magnitude, especially for high heat flux devices. Using water and air as coolants, designs for heat fluxes of >10 kW/cm2 and >100 W/cm2 respectively with pump/fan power expenses less than 1

Müller, Norbert

440

Elastic properties, sp{sup 3} fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides  

SciTech Connect (OSTI)

Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon sp{sup 2} versus sp{sup 3} content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp{sup 3} fraction, the shear modulus ? of dl-BC{sub 4}, containing 10% carbon atoms with sp{sup 3} bonds, and dl-B{sub 3}C{sub 2}, containing 38% carbon atoms with sp{sup 3} bonds, were found to be ??=?19.3?GPa and ??=?170?GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp{sup 3} bonds during the deposition processes.

Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung [Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, Hawaii 96822 (United States); Liu, Yongsheng [Science and Technology on Thermostructure Composite Materials Laboratory, Northwestern Polytechnical University, Xi'an Shanxi (China); Ciston, Jim [National Center for Electron Microscopy, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Hong, Shiming [Laboratory of High Pressure Physics, Southwest Jiaotong University, Chengdu, Sichuan (China)

2014-10-07T23:59:59.000Z

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441

A corrosion control concept by scale engineering: a novel green inhibitor applied for high temperature and pressure aqueous supercritical CO2 systems  

SciTech Connect (OSTI)

Traditional corrosion inhibitors are bio-toxic chemicals with organic components that bond to the fresh metal surface and thus isolate them from corrosive environments. The shortcoming of these inhibitors is that they are less effective in high-temperature and high-pressure environments, and where corrosion scale is formed or particulates are deposited. In this paper, we describe a novel green inorganic inhibitor made of environmentally friendly and cost-effective geo-material that was developed for high-temperature and high-pressure environments, particularly under scale-forming conditions. It inhibits corrosion by enhancing the protectiveness of corrosion scale. In contrast to traditional corrosion inhibitors which are efficient for bare surface corrosion but not effective with scale, the novel inhibitor has no effect on bare surface corrosion but greatly improves corrosion inhibition under scale-formation conditions. This is because a homogeneous scale doped with inhibitor component forms. This enhanced corrosion scale demonstrated excellent protection against corrosion. In high-pressure CO{sub 2} systems (pCO{sub 2}=10 Mpa, T=50 C and [NaCl]=1 wt%) without inhibitor, the bare-surface corrosion rate decreases from ca. 10 mm/y to 0.3 mm/year due to formation of scale. Application of a six hundred ppm solution ofthe new inorganic inhibitor reduced the corrosion rate to 0.01 mm/year, an additional factor of 30. The current inhibitor product was designed for application to CO{sub 2} systems that form corrosion scale, including but not limited to oil and gas wells, offshore production of oil and gas, CO{sub 2} sequestration and enhanced geothermal production involving CO{sub 2}.

Jiabin, Han [Los Alamos National Laboratory; Carey, James W [Los Alamos National Laboratory; Zhang, Jinsuo [Los Alamos National Laboratory

2011-01-27T23:59:59.000Z

442

Pulsed CO{sub 2} laser with an X-ray preioniser based on a high-voltage low-pressure glow discharge  

SciTech Connect (OSTI)

An X-ray preioniser with an electron beam energy density of 0.1 J cm{sup -2} based on a high-voltage (20 - 40 kV) low-pressure glow discharge is developed for