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COMMUNICATIONS Angew. Chem. Int. Ed. 1999, 38, No. 3 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1999 1433-7851/99/3803-0331 $ 17.50+.50/0 331
 

Summary: COMMUNICATIONS
Angew. Chem. Int. Ed. 1999, 38, No. 3 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1999 1433-7851/99/3803-0331 $ 17.50+.50/0 331
COMMUNICATIONS
332 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1999 1433-7851/99/3803-0332 $ 17.50+.50/0 Angew. Chem. Int. Ed. 1999, 38, No. 3
HCSiF and HCSiCl: The First Detection of
Molecules with Formal CSi Triple Bonds**
Miriam Karni, Yitzhak Apeloig, Detlef Schröder,
Waltraud Zummack, Roberto Rabezzana, and
Helmut Schwarz*
Dedicated to Professor Jack D. Dunitz
on the occasion of his 75th birthday
The synthesis and isolation of compounds having multiple
bonds to silicon has been one of the major challenges in main
group chemistry.[1]
The first stable compounds with double
bonds to silicon were synthesized in 1981,[2]
and since then this group of compounds has
been studied extensively, both experimental-
ly[3]
and theoretically.[4]

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry