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Searching for Microporous, Strongly Basic Catalysts: Experimental and Calculated 29
 

Summary: Searching for Microporous, Strongly Basic Catalysts:
Experimental and Calculated 29
Si NMR Spectra of Heavily
Nitrogen-Doped Y Zeolites
Fulya Dogan,
Karl D. Hammond,
Geoffrey A. Tompsett,
Hua Huo,
W. Curtis Conner, Jr.,
Scott M. Auerbach,,
and Clare P. Grey*,
Department of Chemistry, State UniVersity of New York at Stony Brook, Stony Brook,
New York 11794-3400, Department of Chemical Engineering, UniVersity of Massachusetts,
Amherst, Massachusetts 01003-3110, and Department of Chemistry, UniVersity of Massachusetts,
Amherst, Massachusetts 01003-9336
Received April 18, 2009; E-mail: cgrey@notes.cc.sunysb.edu
Abstract: Nitrogen substituted zeolites with high crystallinity and microporosity are obtained by nitrogen
substitution for oxygen in zeolite Y. The substitution reaction is performed under ammonia flow by varying
the temperature and reaction time. We examine the effect of aluminum content and charge-compensating
cation (H+

  

Source: Auerbach, Scott M. - Department of Chemistry, University of Massachusetts at Amherst

 

Collections: Chemistry