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Chemical Shielding Tensors for a Silicon-Carbon Double Bond

Summary: Chemical Shielding Tensors for a Silicon-Carbon
Double Bond
Jarrod J. Buffy, Robert West,*, Michael Bendikov, and
Yitzhak Apeloig*,
Department of Chemistry, UniVersity of Wisconsin-Madison
Madison, Wisconsin 53706
Department of Chemistry and the Lise Meitner-MinerVa
Center for Computational Quantum Chemistry
Technion-Israel Institute of Technology, Haifa 32000, Israel
ReceiVed September 15, 2000
Measurements of NMR chemical shielding tensors (CST) have
been important in aiding the understanding of the nature of the
chemical bond and in particular for multiple bonding involving
heavier main group elements. Chemical shielding tensors have
been reported and interpreted for compounds containing SidSi,1
CdP, and CtP4
bonds. Although stable silenes,
R2SidCR2, have been known since 1981,5 no information on


Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology


Collections: Chemistry