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Physica A 330 (2003) 150159
Accurate solution for the many body
Noam Agmon, Alexander V. Popov1
Department of Physical Chemistry and the Fritz Haber Research Center, The Hebrew University,
Jerusalem 91904, Israel
Dedicated to Shlomo Havlin on his 60th birthday
An accurate semi-analytic solution for reversible di usion-in uenced kinetics is presented in
the pseudo-unimolecular target limit. It is shown to exhibit excellent agreement with Brownian
simulations of the A + B C + D reaction.
c 2003 Elsevier B.V. All rights reserved.
PACS: 82.20.-w; 82.20.Uv; 82.20.Wt
Keywords: Di usion; Kinetics; Many-body; Reversible reactions
This paper reports the solution to a di cult problem in solution-phase kinetics, the
kinetics of the di usion-in uenced reversible ABCD reaction
A + B