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Quantum interference in resonant Raman spectra of I2 in condensed media M. Ovchinnikov and V. A. Apkarian
 

Summary: Quantum interference in resonant Raman spectra of I2 in condensed media
M. Ovchinnikov and V. A. Apkarian
Department of Chemistry, University of California, Irvine, California 92697-2025
Received 13 December 1996; accepted 24 January 1997
Both B(3
u0) and B (1
1u) surfaces contribute to resonance Raman scattering of iodine, and the
interference between these two channels leads to modulation of the intensity profile of overtone
progressions, as observed experimentally. The effect is simulated through mixed order semiclassical
molecular dynamics. 1997 American Institute of Physics. S0021-9606 97 02613-5
I. INTRODUCTION
Resonance Raman RR spectra of I2 in condensed me-
dia, in solid rare gases,1,2
and in liquids,35
and in particular
in liquid Xe,4
and CCl4,5
have recently been revisited with
the aims of extracting dynamical information on ultrafast
time scales.28

  

Source: Apkarian, V. Ara - Department of Chemistry, University of California, Irvine

 

Collections: Chemistry