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Theory Predicts Triplet Ground-State Organic Max C. Holthausen*
 

Summary: Theory Predicts Triplet Ground-State Organic
Silylenes
Max C. Holthausen*
Institut fušr Chemie der Humboldt-UniVersitašt
Arbeitsgruppe Quantenchemie
Jašgerstrasse 10/11, 10117 Berlin, Germany
Wolfram Koch
Institut fušr Organische Chemie der
Technischen UniVersitašt
Strasse des 17 Juni 135, 10623 Berlin, Germany
Yitzhak Apeloig*
Department of Chemistry and the Lise Meitner-MinerVa
Center for Computational Quantum Chemistry
Technion-Israel Institute of Technology
Haifa 32000, Israel
ReceiVed October 5, 1998
ReVised Manuscript ReceiVed January 11, 1999
Silylenes, SiR2, are highly important reactive intermediates in
silicon chemistry and to date all known SiR2 species possess a
singlet ground state without any experimentally verified excep-

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry