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Summary: Origin of pseudoelastic behavior in TiMo-based alloys
L. C. Zhang, T. Zhou, S. P. Alpay, and M. Aindowa
Department of Materials Science and Engineering, Institute of Materials Science,
University of Connecticut, Storrs, Connecticut 06269-3136
M. H. Wu
Memry Corporation, Bethel, Connecticut 06801
Received 29 July 2005; accepted 13 October 2005; published online 7 December 2005
High-resolution transmission electron microscopy and in situ x-ray diffraction analyses have been
used to elucidate the compositional sensitivity of the deformation behavior in two -TiMo-based
alloys. The alloy with 8% Mo exhibited conventional elastic/plastic behavior in tension which
corresponds to the irreversible formation of stress-induced orthorhombic martensite. The alloy
with 10% Mo exhibited a pronounced pseudoelastic response with recovery of 80% of the
imposed tensile strain. This phenomenon is associated with the formation of another orthorhombic
martensitic phase, which has not been reported previously, and this nucleates from pre-existing
domains in the matrix. © 2005 American Institute of Physics. DOI: 10.1063/1.2142089
Martensitic phase transformations are diffusionless, first-
order, structural transitions in which the martensite phase is
related to the initial phase by an invariant plane strain.13
Most martensitic phases form irreversibly due to the pinning
of the interfaces by dislocations or other crystal defects.
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