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141Angew. Chem. Int. Ed. 2004, 43, 134 141 www.angewandte.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim *Corrigenda
 

Summary: Angewandte
Chemie
141Angew. Chem. Int. Ed. 2004, 43, 134 ­ 141 www.angewandte.org 2004 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
*Corrigenda
In the Communication "Silynes (RCSiR')
and Disilynes (RSiSiR'): Why Are Less
Bonds Worth Energetically More?" by S.
Shaik et al. (Angew. Chem. 2001, 113,
4146­4150; Angew. Chem. Int. Ed. 2001,
40, 4023­4026) Table 2 included incorrect
numerical data. The correct version of the
table is given below.
Table 2. In situ bond energies for the linear and trans-bent isomers of
HCSiH (1), HSiSiH (2), and HCCH (3) in the linear (L) and trans-bent (B)
isomers.[a]
Bond energies [kcalmolĄ1
]
HCSiH HSiSiH HCCH
Type 1L 1B 2L 2B 3L 3B[b]
1 D(pout) 57.7 56.5 45.5 34.0 88.2 74.1

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry