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11608 J. Am. Chem. SOC.1995,117, 11608-11609 Dilithium Derivative of Tetraphenylsilole: An
 

Summary: 11608 J. Am. Chem. SOC.1995,117, 11608-11609
Dilithium Derivative of Tetraphenylsilole: An
ql-$ Dilithium Structure
Robert West,*$'Honglae Sohn,+Uwe Bankwitz,'
Joseph Calabrese,t Yitzhak Apeloig,g and Thomas Muellerg
Department of Chemistry, University of Wisconsin
Madison, Wisconsin 53706
Department of Chemistry
Technion-Israel Institute of Technology
Haija 32 000, Israel
Central Research and Development
E. I. du Pont de Nemours & Co.
Wilmington, Delaware
Received July 12, 1995
Recent years have seen renewed interest in the problems of
chemical bonding in siloles and silole In 1990 Joo
and co-workers reported the conversion of 1,l-dichloro-2,3,4,5-
tetraphenyl-1-silacyclopentadiene (1) to the disodium salt by
reaction with sodium metaL5 The corresponding dilithium
derivative (2) was recently reported by Boudjouk et a1.2b The

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry