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COMMUNICATIONS Angew. Chem. Int. Ed. 2001, 40, No. 21 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001 1433-7851/01/4021-4023 $ 17.50+.50/0 4023
 

Summary: COMMUNICATIONS
Angew. Chem. Int. Ed. 2001, 40, No. 21 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2001 1433-7851/01/4021-4023 $ 17.50+.50/0 4023
Silynes (RCSiR') and Disilynes (RSiSiR'):
Why Are Less Bonds Worth Energetically
More?**
David Danovich, François Ogliaro, Miriam Karni,
Yitzhak Apeloig,* David L. Cooper,* and Sason Shaik*
Dedicated to Professor Zvi Rappoport
on the occasion of his 65th birthday
Since the first isolation in 1981 of stable silaethylene[1]
and
disilene[2]
a variety of new compounds containing doubly
bonded silicon have been synthesized and their chemistry
explored.[3]
The next challenge has become the syntheses of
compounds in which silicon has a triple bond.[4]
Until recently
HSiN was the only known silicon species with a triple bond,
and was prepared by matrix isolation and identified by UV

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry