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CHM 7200 Organic Structures and Mechanisms Fall Term 2006 Problem Set 2: This problem set is now available at (www.blackboard.wayne.edu). It will be due
 

Summary: CHM 7200 Organic Structures and Mechanisms Fall Term 2006
Problem Set 2: This problem set is now available at (www.blackboard.wayne.edu). It will be due
in class 7 days (09/22/05) from today (09/15/05). Grades will be administered as follows: 5
(exceptional effort), 4 (complete), 3 (incomplete or inadequate effort), 2 (poor effort), 0
(nonexistent). No late problem sets will be accepted.
1. Problem: a) Illustrate the gauche and anti conformers of Fluoro methanol, which one is more
stable? Why?
b) Write the major products of each reaction with correct stereo chemistry. Why they are
preferable over the other stereo isomer.
i)
(H3C)2PhSi
Ar-CO3H
NaHPO4
A + B
ii)
(H3C)2PhSi
B2H6
H2O2, Base
iii)
+ Br2

  

Source: Andreana, Peter R. - Department of Chemistry, Wayne State University

 

Collections: Chemistry