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COMMUNICATIONS Angew. Chem. Int. Ed. 2000, 39, No. 22 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2000 1433-7851/00/3922-4127 $ 17.50+.50/0 4127
 

Summary: COMMUNICATIONS
Angew. Chem. Int. Ed. 2000, 39, No. 22 WILEY-VCH Verlag GmbH, D-69451 Weinheim, 2000 1433-7851/00/3922-4127 $ 17.50+.50/0 4127
A Novel CSiP Ring from the Reaction of a
Complexed Phosphinidene and a Silene**
Mark J. M. Vlaar, Andreas W. Ehlers,
Frans J. J. de Kanter, Marius Schakel, Anthony L. Spek,
Martin Lutz, Nadejda Sigal, Yitzhak Apeloig, and
Koop Lammertsma*
Cyclopropanes and their three-membered heterocyclic
analogues have long-been recognized as important chemical
structures. Even three-membered rings containing the sec-
ond-row elements phosphorus and silicon are now well
established. Moreover, many phosphiranes and siliranes are
already known containing a second heteroatom such as O,[1]
N,[2]
or S.[3]
However, no phosphasilirane has yet been isolated.
So far, only 31
P and 29
Si NMR data have been reported by

  

Source: Apeloig, Yitzhak - Department of Chemistry, Technion, Israel Institute of Technology

 

Collections: Chemistry