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Title Uranosilite, a new mineral from the uranium deposit at Menzenschwand (Southern Black Forest)
Creator/Author Walenta, K.
Publication Date1983 Jun 01
OSTI IdentifierOSTI ID: 5064951
Other Number(s)Journal ID: CODEN: NJMMA
Resource TypeJournal Article
Resource RelationJournal Name: Neues Jahrb. Mineral., Monatsh.; (Germany, Federal Republic of); Journal Volume: 6
Subject11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; 58 GEOSCIENCES; URANIUM MINERALS; PHYSICAL PROPERTIES; CHEMICAL COMPOSITION; FEDERAL REPUBLIC OF GERMANY; URANIUM RESERVES; EUROPE; MATERIALS; MINERALS; RADIOACTIVE MATERIALS; RADIOACTIVE MINERALS; RESERVES; RESOURCES; WESTERN EUROPE
Description/AbstractUranosilite belongs to the secondary assemblage of the uranium deposit at Menzenschwand in the Black Forest (Germany). It occurs in intimate intergrowth with sudtite and uranophane on quartz and hematite and was first mentioned as an unnamed presumably new species in a paper on studtite. The new mineral forms needle-like crystals of orthorhombic symmetry. Forms (pinacoids and prisms) are visible only by electron microscope with a yellowish white colour. The mineral is characterized by vitrous luster; no cleavage, in determinable hardness; Dsub(x) 3.25 g/cm/sup 3/; optical properties: nsub(..cap alpha..) 1.570 +- 0.002, nsub(..gamma..) 1.584 +- 0.002, elongation (+), probably biaxial negative; slightly anomalous interference colours; unitcell dimensions: a/sub 0/ 11.60, b/sub 0/ 14,68, c/sub 0/ 12.83 A, Z = 6, possible space groups P22/sub 1/2/sub 1/, Pmmb, Pmcb; strongest lines of the powder pattern: 11.58 (9) 100; 7.30 (10) 020; 6.19 (9) 120; 3.50 (8) 123, 140. Result of analysis is: U 31.0, Pb 1.5, K 1.2, Si 28.5, O 38.0, total 100.2% yielding the formula (UO/sub 3/)sub(0.95)(PbO)sub(0.05) (K/sub 2/O)sub(0.10)x7SiO/sub 2/ or simplified UO/sub 3/x7SiO/sub 2/ on the basis of O = 17. The lattice is stable up to 900/sup 0/C. Heating to this temperature, however, is accompanied by a decrease in the indices of refraction which may be explained by the loss of (zeolitic) water in the order of 1H/sub 2/O (per formula unit).
Country of PublicationGermany
LanguageGerman
FormatMedium: X; Size: Pages: 259-269
System Entry Date2009 Dec 16

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