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Title In situ TEM study of ion-beam-induced amorphization of complex silicate structures
Creator/Author Wang, L.M. ; Eby, R.K. ; Janeczek, J. ; Ewing, R.C.
Publication Date1990 Dec 31
OSTI IdentifierOSTI ID: 442204; Legacy ID: DE97002504
Report Number(s)CONF-900936--29
DOE Contract NumberFG04-84ER45099
Other Number(s)Other: ON: DE97002504
Resource TypeConference
Resource RelationConference: 7. international conference on ion beam modification of materials (IBMM-7) and exposition, Knoxville, TN (United States), 9-14 Sep 1990; Other Information: PBD: [1990]
Research OrgNew Mexico Univ., Albuquerque, NM (United States). Dept. of Geology
Sponsoring OrgUSDOE Office of Energy Research, Washington, DC (United States)
Subject36 MATERIALS SCIENCE; SILICATE MINERALS; PHYSICAL RADIATION EFFECTS; AMORPHOUS STATE; ION BEAMS; KRYPTON IONS
Description/AbstractIn-situ TEM with ion irradiation was used to study the radiation- induced amorphization (metamictization) of naturally occurring silicates: neptunite [Na2KLi(Fe,Mn)2Ti2(SiO3)8], titanite (CaTiSiO5), gadolinite (REE2FeBe2Si2O10), zircon (ZrSiO4), and olivine [(Mg, Fe)2SiO4]. They were irradiated with 1.5 MeV Kr{sup +} ions the Argonne HVEM-Tandem Facility at room temperature with electron diffraction pattern monitored in situ. Critical doses required for amorphization of the electron transparent thickness of neptunite, titanite, gadolinite, zircon, and olivine are 1.7, 2.0, 2.3, 4.8, and 6.0x10{sup 14} ions/cm{sup 2}, respectively. Results show a correlation between amorphization dose and the chemical/structural complexity of these 5 minerals. The most complex, neptunite, becomes amorphous at the lowest critical dose. The critical amorphization dose also increases with the melting point.
Country of PublicationUnited States
LanguageEnglish
FormatMedium: ED; Size: 12 p.
AvailabilityOSTI as DE97002504
System Entry Date2009 Nov 10

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