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Title A preliminary study of the chemistry of pore water extracted from tuff by one-dimensional compression
Creator/Author Kharaka, Y.K. ; Maest, A.S. [eds.] [Geological Survey, Menlo Park, CA (United States)] ; Peters, C.A. ; Yang, I.C. [Geological Survey, Denver, CO (United States)] ; Higgins, J.D. [Colorado School of Mines, Golden, CO (United States)] ; Burger, P.A. [Bureau of Reclamation, Denver, CO (United States)]
Publication Date1992 Oct 01
OSTI IdentifierOSTI ID: 138460; Legacy ID: DE92040952
Report Number(s)CONF-920761--15
DOE Contract NumberAI08-92NV10874
Other Number(s)Other: ON: DE92040952
Resource TypeConference
Resource RelationConference: 7. water-rock interaction conference, Park City, UT (United States), 9-23 Jul 1992; Other Information: PBD: [1992]
Research OrgGeological Survey, Denver, CO (United States)
Sponsoring OrgUSDOE, Washington, DC (United States)
Subject54 ENVIRONMENTAL SCIENCES ;05 NUCLEAR FUELS; GROUND WATER; CHEMICAL ANALYSIS; TUFF; COMPRESSION; YUCCA MOUNTAIN; HIGH-LEVEL RADIOACTIVE WASTES; UNDERGROUND FACILITIES; ROCK-FLUID INTERACTIONS; DILUTION; DISSOLUTION; TRACE AMOUNTS; CARBON DIOXIDE; CLAYS; ZEOLITES; Yucca Mountain Project
Description/AbstractA specially designed and fabricated one-dimensional compression cell is being used to extract water from nonwelded and densely welded tuffs having degrees of saturation greater than 16 and 37 percent respectively. Chemical analyses of pore water obtained at increasing pressures are used to evaluate possible changes in chemistry caused by compression. The extracted pore water varies form a calcium chloride type to a sodium bicarbonate type. The mean concentration of dissolved ions generally decreases during compression. The relative abundance of the major cations varies little with increasing pressure. Possible causes of the pore-water-chemistry changes include: (1) dilution of pore water by low ionic strength adsorbed water from zeolites and clays; (2) dissolution reactions caused by the increase in dissolved carbon dioxide concentrations that may result from pressurization; (3) membrane filtration by zeolites and clays; and (4) ion exchange with the zeolites and clays.
Country of PublicationUnited States
LanguageEnglish
FormatMedium: ED; Size: 6 p.
AvailabilityINIS; OSTI as DE92040952
System Entry Date2008 Sep 04

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