Savannah River Operations Office

Savannah River Site

Waste Removal Operations and Tank Closure

Project Code:SR-HL03
Problem Area:High Level Waste
Life-Cycle Cost in 2007+: $684,000,000
DOE Project Manager: H. B. Gnann, 803-208-6076, howard.gnann@srs.gov
Contractor Manager: S. S. Cathey, 803-725-3052, susan.cathey@srs.gov
For More Information: http://www.em.doe.gov/closure/pbs/srp692.html

Maximum Public, Worker, and Environmental Risks in the year 2007 and beyond:

Public: Low Worker: Medium Environment: Low

Technical Approach Provided by Project Manager:

Key HLW waste removal and tank/facility closure technologies are: - Salt dissolution via mechanical agitation (slurry pumps), - Sludge suspension via mechanical agitation (slurry pumps), - Remote process sampling, - Corrosion control of the carbon steel waste tanks, - Heel removal techniques and specialized equipment, and - Grout formulation to chemically bind radioactive contaminants The key technology development needs are: - More cost effective salt removal methods than slurry pumps such as water jetting, hydraulic mining, modified density gradient, etc., - Effective methods to remove tank heels (sludge heel, hardened sludge, zeolite, sand, etc.), and - Enhanced method for retrieval of waste from annulus spaces.

Post 2006 Project Scope Provided by Project Manager:

Waste Removal - Waste will be removed from the remaining 39 tanks and the tanks water washed by FY25. Process facilities will be de-inventoried and flushed out in a similar manner by FY25. Waste Removal Demonstrations - There are no waste removal demonstrations scheduled after FY04. Tank/Facility Closure - The remaining 41 tanks will be closed by FY26. Process facilities will also be closed by FY26. Area Closures - All geographical areas will be closed by FY26 and ready to transition to Environmental Restoration for characterization, remediation (if needed) and final closure activities.

Project End State Provided by Project Manager:

The project will end in FY26 when all waste removal, tank closure, and facility closure activities are complete. All HLW facilities will be transitioned to Environmental Restoration project SR-ER02.

The full list of science research awards that have the potential to address projects such as this one, which deals with High Level Waste problems, are listed in the Index of Research Awards by Environmental Management Problem Area, in the back of this appendix, under the heading "High Level Waste".

The following awards were identified through systems engineering to have the potential to address the specific needs of this Project. Those research awards that may have the strongest link to this project are designated by the symbol "§".


Award ID
Award Title
§ 55318-CA Improved Analytical Characterization of Solid Waste-Forms by Fundamental Development of Laser Ablation Technology
§ 54656-CA Mixing Processes in High-Level Waste Tanks
§ 54890-CA On-Line Slurry Viscosity and Concentration Measurement as a Real-Time Waste Stream Characterization Tool
§ 54982-FL Analysis of Surface Leaching Processes in Vitrified High-Level Nuclear Wastes Using In-Situ Raman Imaging and Atomistic Modeling
§ 54807-GA Studies Related to Chemical Mechanisms of Gas Formation in Hanford High-Level Nuclear Wastes
§ 60424-ID High Temperature Condensed Phase Mass Spectrometric Analysis
§ 55229-IL The NOx System in Nuclear Waste
§ 59977-MD Synthesis and Characterization of Templated Ion Exchange Resins for the Selective Complexation of Actinide Ions
§ 55141-MA Imaging and Characterizing the Waste Materials Inside an Underground Storage Tank Using Seismic Normal Modes
§ 54691-MI Radiation Effects on Materials in the Near-Field of Nuclear Waste Repository
§ 54773-NM Microstructural Properties of High Level Waste Concentrates and Gels with Raman And Infrared Spectroscopies
§ 59990-NM Fundamental Chemistry, Characterization, and Separation of Technetium Complexes in Hanford Waste
§ 59993-NM Dynamic Effects of Tank Waste Aging on Radionuclide-Complexant Interactions
§ 54595-NM f-Element Ion Chelation in Highly Basic Media
§ 59982-NY Reactivity of Peroxynitrite: Implications for Hanford Waste Management and Remediation
§ 55179-NY Acoustic Probe for Solid-Gas-Liquid Suspensions
§ 54674-OH Design and Development of a New Hybrid Spectroelectrochemical Sensor
§ 60219-PA Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste
§ 55087-TN Design and Synthesis of the Next Generation of Crown Ethers for Waste Separations: An Inter-Laboratory Comprehensive Proposal
§ 59978-TN Thermospray Mass Spectrometry Ionization Processes Fundamental Mechanisms for Speciation, Separation and Characterization of Organic Complexants in DOE Wastes
§ 60217-TN Optically-Based Array Sensors for Selective In Situ Analysis of Tank Waste
§ 54735-TX Development of Inorganic Ion Exchangers for Nuclear Waste Remediation
§ 54621-WA Chemical Speciation of Strontium, Americium, and Curium in High Level Waste: Predictive Modeling of Phase Partitioning During Tank Processing
§ 54628-WA Colloidal Agglomerates in Tank Sludge: Impact on Waste Processing
§ 54646-WA Interfacial Radiolysis Effects in Tank Waste Speciation
§ 54672-WA Radiation Effects in Nuclear Waste Materials
§ 60362-WA Ion-Exchange Processes and Mechanisms in Glasses
§ 60050-WA Chemical Speciation of Inorganic Compounds under Hydrothermal Conditions
§ 60075-WA Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations
55014-AL Kinetics and Mechanisms of Metal Retention/Release in Geochemical Processes in Soil
60328-CA High Frequency Electromagnetic Impedance Measurements for Characterization, Monitoring and Verification Efforts
60370-CA Rational Design of Metal Ion Sequestering Agents
55148-CA Hydrologic and Geochemical Controls on the Transport of Radionuclides in Natural Undisturbed Arid Environments as Determined by Accelerator Mass Spectrometry Measurements
55411-CA Joint Inversion of Geophysical Data for Site Characterization and Restoration Monitoring
60319-CA Thermodynamics of the Volatilization of Actinide Metals in the High-Temperature Treatment of Radioactive Wastes
54860-CA Sorption of Heavy Metals and Radionuclides on Mineral Surfaces in the Presence of Organic Co-Contaminants
54655-CA Collaborative Research: Hydrogeological-Geophysical Methods for Subsurface Site Characterization
54926-CA Novel Ceramic-Polymer Composite Membranes for the Separation of Hazardous Liquid Waste
60141-DC Gamma Ray Imaging for Environmental Remediation
55218-GA Seismic Surface-Wave Tomography of Waste Sites
55247-IL Sensors Using Molecular Recognition in Luminescent, Conductive Polymers
55382-IL Determination of Transmutation Effects in Crystalline Waste Forms
60247-IL Miniature Nuclear Magnetic Resonance Spectrometer for In-Situ and In-Process Analysis and Monitoring
60231-MD Novel Miniature Spectrometer for Remote Chemical Detection
54571-MA Removal of Heavy Metals and Organic Contaminants from Aqueous Streams by Novel Filtration Methods
60070-MS The Development of Cavity Ringdown Spectroscopy as a Sensitive Continuous Emission Monitor for Metals
55223-MO De Novo Design of Ligands for Metal Separation
54724-NM Synthesis of New Water-Soluble Metal-Binding Polymers: Combinatorial Chemistry Approach
54741-NM Characterization of Contaminant Transport Using Naturally-Occurring U-Series Disequilibria
54770-NM New Anion-Exchange Resins for Improved Separations of Nuclear Materials
59996-NM Plutonium Speciation, Solubilization, and Migration in Soils
54639-NM Development of an In-Situ Microsensor for the Measurements of Chromium and Uranium in Groundwater at DOE Sites
54793-NY Establishing a Quantitative Functional Relationship Between Capillary Pressure Saturation and Interfacial Area
54828-SC Processing of High Level Waste: Spectroscopic Characterization of Redox Reactions in Supercritical Water
55205-SC A Fundamental Study of Laser-Induced Breakdown Spectroscopy Using Fiber Optics for Remote Measurements of Trace Metals
55036-TN Colloid Transport and Retention in Fractured Deposits
55119-TN Phase Equilibria Modification by Electric Fields
60197-TN Microsensors for In-situ Chemical, Physical, and Radiological Characterization of Mixed Waste
60096-TN Rational Synthesis of Imprinted Organofunctional Sol-Gel Materials for Toxic Metal Separation
60355-WA Mineral Surface Processes Responsible for the Decreased Retardation (or Enhanced Mobilization) of 137Cs from HLW Tank Discharges
54897-WA The Sonophysics and Sonochemistry of Liquid Waste Quantification and Remediation
55146-WA Adsorption/Membrane Filtration as a Contaminant Concentration and Separation Process for Mixed Wastes and Tank Wastes

The following tree shows how the above awards link to this project. When multiple brances are shown leading to or from a problem area, branches to the left are primary links and branches to the right are secondary.

High Cost Project SR-HL03 - Waste Removal Operations and Tank Closure
                    
                    
                    
Problem Areas Linked to SR-HL03: High Level Waste
                    
                    
                      
Research Awards Linked to SR-HL03:

Pass the mouse over an Award ID for more information, below. Click ID for more detail:

 
54595 54621 54628 54646 54656 54672 54674 54691 54735 54773 54807 54890 54982 55087 55141 55179 55229 55318 59977 59978 59982 59990 59993 60050 60075 60217 60219 60362 60424
 
54571 54639 54655 54724 54741 54770 54793 54828 54860 54897 54926 55014 55036 55119 55146 55148 55205 55218 55223 55247 55382 55411 59996 60070 60096 60141 60197 60231 60247 60319 60328 60355 60370

Next PBS: SR-HL04 - In Tank Precipitation/Extended Sludge Processing/Late Wash (ITP/ESP/LW) Operations