Richland Operations Office

Hanford Site - Richland Operations Office

Retrieval Project

Project Code:RL-TW04
Problem Areas:High Level Waste (Primary)
Health / Ecology / Risk
Mixed Waste
Life-Cycle Cost in 2007+: $2,986,000,000
DOE Project Manager: J.E. Kinzer, 509-376-7591, jackson_e_kinzer@rl.gov
Contractor Manager: A.M. Umek, 509-373-5983, anthony_m_tony_umek@rl.gov
For More Information: http://www.em.doe.gov/closure/pbs/rlp795.html

Maximum Public, Worker, and Environmental Risks in the year 2007 and beyond:

Public: Low Worker: High Environment: High

Technical Approach Provided by Project Manager:

The end point targets in the Hanford Strategic Plan addressed by this project include: • Retrieve tank wastes to the extent needed for tank closure, divide into high level and low activity fractions and immobilize. • Transition high cost surplus facilities in the central plateau and south 600 areas to a low cost, stable, deactivated condition. • After the waste has been retrieved from the tanks, the tank farms (including the tanks) will be closed. The technical approach and technology initiatives for the Project to accomplish the Hanford Strategic Plan end point targets are identified below. • Technical Approach - Retrieval Project: The baseline technical approach for the Waste Retrieval Project during Phase I contains the following key elements: 1. Select supernatants that meet the requirements of three LAW envelopes and transfer them to private contractors to demonstrate radio nuclide removal and immobilization of LAW. 2. Select tank sludges, that when washed with water or caustic in-tank, meet contractual HLW feed requirements. Transfer the washed sludges to private contractors for immobilization into a form that meets the repository waste acceptance criteria. 3. Continue to explore new and innovative methods and emerging technologies that could result in significant cost and schedule savings through a combination of technology transfer from industry; lessons learned from the operations of DWPF, WVDP, and foreign experience; and limited technology development. 4. Participate with the other TWRS projects and TWRS systems engineering on tank retrieval sequence, blending, pretreatment, and vitrification options in a continuing effort to optimize total program costs. The Phase II technical approach is still being defined, but current planning is to perform limited laboratory-scale testing using pretreated radioactive waste to the extent required to confirm the product specifications developed for Phase II vitrification. Proven retrieval technology will be applied as the waste retrieval baseline for SST and DST retrieval. Technology enhancements and alternatives will be implemented to improve performance and reliability and address difficult-to-retrieve and potentially environmentally impacting technology. The Retrieval Project relies on EM-50 technology development efforts to provide for improved retrieval technologies. Hydraulic sluicing, similar to past-practice, is the reference technology for SST waste mobilization. Sluicing will be demonstrated in tank 106-C. Sluicing will also be applied to the Initial Single-Shell Tank Retrieval System (ISSTRS). Parallel to the design of the ISSTRS is the development of leak monitoring and mitigation methods to address potential environmental impacts associated with leakage during hydraulic sluicing. Improvements to SST retrieval are needed for difficult-to-retrieve waste or for tanks that may leak beyond allowable limits. Improved retrieval technologies are to be demonstrated in tank 106-C to remove the heel following sluicing. The Hanford Tank Initiative (HTI) will provide demonstration of improved technologies as well as work toward defining closure criteria to determine acceptable waste residual following retrieval activities. Mixer pumps are the reference technology for DST waste mobilization for retrieval. A process test will be performed in tank 101-AZ to demonstrate the capability of mixer pumps to mobilize neutralized current acid waste sludge. Concurrent with this activity, advanced design mixer pumps will be procured and tested with the goal of improved reliability and reduced life-cycle costs. Performance data obtained will be applied to other equipment used by the Initial Tank Retrieval System project, which will provide mixer pump based retrieval systems for 10 DSTs. The following technology needs have been identified and prioritized through the Hanford Site Technology Coordination Group for the Tank Focus Area: - Establish Retrieval Performance Criteria - SST Alternative Retrieval Technologies - Advanced Design Mixer Pumps for Mixer Pump Enhancement - Tank Leak Detection and Mitigation Systems for SSTs - Alternative to Mixer Pumps for better reliability and longer life - High Accuracy Psychometric/Flow Measurements capability to improve process control - Identification and management of Chromium and problem constituents for Hanford HLW vitrification - Avoidance of formation of solids in Phase I liquid tank wastes - Prediction of gel and precipitate formation in Hanford Tank Waste - Enhanced sludge wash data for extended operations of Phase I and for Phase II RFP preparation - Bench-scale radioactive demonstration of Phase I sludge washing.

Post 2006 Project Scope Provided by Project Manager:

Single Shell Tank (SST) System • Waste retrieval from SSTs and MUSTs will continue; scheduled for completion by September 2018. • Storage of wastes within the SST system and transfer of wastes to the DST system will continue until FY2018 • Closure of the SSTs is scheduled for completion by September 2024. • Closure of the SSTs is scheduled for completion by September 2024. • Closure of the SSTs is scheduled for completion by September 2024. Post-closure monitoring will begin in 2034 and continue through the end of the EM mission in 2050. Further post-closure monitoring will be conducted by other programs if required. Double Shell Tank (DST) System • Waste retrieval from DSTs will continue; scheduled for completion in 2028. • Waste will be staged in DSTs and transferred to the private immobilization contractors to support Phase I extended operations. • Closure of the DSTs may begin as early as 2024 and is scheduled for completion by 2034. • Removal of DST waste will continue until all waste is retrieved from DSTs; scheduled for completion in FY2028 • Maintaining DSTs in safe and compliant manner will continue until all waste is retrieved from DSTs; scheduled for completion in FY2028 • Waste will be staged in DSTs and transferred to the private immobilization contractors to support Phase I extended operations. • Waste will be staged in DSTs and transferred to the private immobilization contractors to support Phase I extended operations. • Closure of the DSTs may begin as early as 2024 and is scheduled for completion by 2034. Post-closure monitoring will begin in 2034 and continue through the end of the EM mission in 2050. Further post-closure monitoring will be conducted by other programs if required.

Project End State Provided by Project Manager:

All waste has been retrieved from the SSTs, DSTs, and MUSTs. All tanks have been closed in accordance with regulatory requirements. Specific work activities to close the facilities under this Project to be performed by others at the end of this Project`s mission are identified below.

The full list of science research awards that have the potential to address projects such as this one, which deals with High Level Waste, Health / Ecology / Risk, and Mixed Waste problems, are listed in the Index of Research Awards by Environmental Management Problem Area, in the back of this appendix, under the headings "High Level Waste, Health / Ecology / Risk, and Mixed Waste".

The following awards were identified through systems engineering to have the potential to address the specific needs of this Project. Those research awards that may have the strongest link to this project are designated by the symbol "§".


Award ID
Award Title
§ 55318-CA Improved Analytical Characterization of Solid Waste-Forms by Fundamental Development of Laser Ablation Technology
§ 54656-CA Mixing Processes in High-Level Waste Tanks
§ 54890-CA On-Line Slurry Viscosity and Concentration Measurement as a Real-Time Waste Stream Characterization Tool
§ 54807-GA Studies Related to Chemical Mechanisms of Gas Formation in Hanford High-Level Nuclear Wastes
§ 60424-ID High Temperature Condensed Phase Mass Spectrometric Analysis
§ 55229-IL The NOx System in Nuclear Waste
§ 59977-MD Synthesis and Characterization of Templated Ion Exchange Resins for the Selective Complexation of Actinide Ions
§ 55141-MA Imaging and Characterizing the Waste Materials Inside an Underground Storage Tank Using Seismic Normal Modes
§ 54773-NM Microstructural Properties of High Level Waste Concentrates and Gels with Raman And Infrared Spectroscopies
§ 59990-NM Fundamental Chemistry, Characterization, and Separation of Technetium Complexes in Hanford Waste
§ 59993-NM Dynamic Effects of Tank Waste Aging on Radionuclide-Complexant Interactions
§ 54595-NM f-Element Ion Chelation in Highly Basic Media
§ 59982-NY Reactivity of Peroxynitrite: Implications for Hanford Waste Management and Remediation
§ 55179-NY Acoustic Probe for Solid-Gas-Liquid Suspensions
§ 54674-OH Design and Development of a New Hybrid Spectroelectrochemical Sensor
§ 60219-PA Development of Advanced Electrochemical Emission Spectroscopy for Monitoring Corrosion in Simulated DOE Liquid Waste
§ 55087-TN Design and Synthesis of the Next Generation of Crown Ethers for Waste Separations: An Inter-Laboratory Comprehensive Proposal
§ 59978-TN Thermospray Mass Spectrometry Ionization Processes Fundamental Mechanisms for Speciation, Separation and Characterization of Organic Complexants in DOE Wastes
§ 60217-TN Optically-Based Array Sensors for Selective In Situ Analysis of Tank Waste
§ 54735-TX Development of Inorganic Ion Exchangers for Nuclear Waste Remediation
§ 54621-WA Chemical Speciation of Strontium, Americium, and Curium in High Level Waste: Predictive Modeling of Phase Partitioning During Tank Processing
§ 54628-WA Colloidal Agglomerates in Tank Sludge: Impact on Waste Processing
§ 54646-WA Interfacial Radiolysis Effects in Tank Waste Speciation
§ 54672-WA Radiation Effects in Nuclear Waste Materials
§ 60362-WA Ion-Exchange Processes and Mechanisms in Glasses
§ 60075-WA Particle Generation by Laser Ablation in Support of Chemical Analysis of High Level Mixed Waste from Plutonium Production Operations
60328-CA High Frequency Electromagnetic Impedance Measurements for Characterization, Monitoring and Verification Efforts
60370-CA Rational Design of Metal Ion Sequestering Agents
55411-CA Joint Inversion of Geophysical Data for Site Characterization and Restoration Monitoring
60319-CA Thermodynamics of the Volatilization of Actinide Metals in the High-Temperature Treatment of Radioactive Wastes
54926-CA Novel Ceramic-Polymer Composite Membranes for the Separation of Hazardous Liquid Waste
60141-DC Gamma Ray Imaging for Environmental Remediation
55218-GA Seismic Surface-Wave Tomography of Waste Sites
55247-IL Sensors Using Molecular Recognition in Luminescent, Conductive Polymers
55382-IL Determination of Transmutation Effects in Crystalline Waste Forms
60247-IL Miniature Nuclear Magnetic Resonance Spectrometer for In-Situ and In-Process Analysis and Monitoring
60231-MD Novel Miniature Spectrometer for Remote Chemical Detection
60070-MS The Development of Cavity Ringdown Spectroscopy as a Sensitive Continuous Emission Monitor for Metals
55223-MO De Novo Design of Ligands for Metal Separation
54770-NM New Anion-Exchange Resins for Improved Separations of Nuclear Materials
59996-NM Plutonium Speciation, Solubilization, and Migration in Soils
55171-PA Development of Advanced In-Situ Techniques for Chemistry Monitoring and Corrosion Mitigation in SCWO Environments
54828-SC Processing of High Level Waste: Spectroscopic Characterization of Redox Reactions in Supercritical Water
55205-SC A Fundamental Study of Laser-Induced Breakdown Spectroscopy Using Fiber Optics for Remote Measurements of Trace Metals
55036-TN Colloid Transport and Retention in Fractured Deposits
55119-TN Phase Equilibria Modification by Electric Fields
60197-TN Microsensors for In-situ Chemical, Physical, and Radiological Characterization of Mixed Waste
60096-TN Rational Synthesis of Imprinted Organofunctional Sol-Gel Materials for Toxic Metal Separation
60355-WA Mineral Surface Processes Responsible for the Decreased Retardation (or Enhanced Mobilization) of 137Cs from HLW Tank Discharges
54897-WA The Sonophysics and Sonochemistry of Liquid Waste Quantification and Remediation
55146-WA Adsorption/Membrane Filtration as a Contaminant Concentration and Separation Process for Mixed Wastes and Tank Wastes

The following tree shows how the above awards link to this project. When multiple brances are shown leading to or from a problem area, branches to the left are primary links and branches to the right are secondary.

High Cost Project RL-TW04 - Retrieval Project
                                                    
                                                    
                                                          
Problem Areas Linked to RL-TW04: High Level Waste Health / Ecology / Risk Mixed Waste
                                                          
                                                          
                                                              
Research Awards Linked to RL-TW04:

Pass the mouse over an Award ID for more information, below. Click ID for more detail:

 
54595 54621 54628 54646 54656 54672 54674 54735 54773 54807 54890 55087 55141 55179 55229 55318 59977 59978 59982 59990 59993 60075 60217 60219 60362 60424
 
54770 54828 54897 54926 55036 55119 55146 55205 55218 55223 55247 55382 55411 59996 60070 60096 60141 60197 60231 60247 60319 60328 60355 60370
     
None.
      
54770 54828 54897 55146 55171 55223 55247 60070 60096 60231 60370
 
54672 54674 54735 54807 54890 54926 55087 55119 55179 55205 55318 59978 60197 60247 60319 60362 60424

Next PBS: RL-TW05 - Process Waste Support