Nickel-titanium-phosphate cathodes
Abstract
Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.
- Inventors:
-
- Westmont, IL
- Downers Grove, IL
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 985709
- Patent Number(s):
- 7465520
- Application Number:
- 10/858,806
- Assignee:
- UChicago Argonne LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- W-31-109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Belharouak, Ilias, and Amine, Khalil. Nickel-titanium-phosphate cathodes. United States: N. p., 2008.
Web.
Belharouak, Ilias, & Amine, Khalil. Nickel-titanium-phosphate cathodes. United States.
Belharouak, Ilias, and Amine, Khalil. Tue .
"Nickel-titanium-phosphate cathodes". United States. https://www.osti.gov/servlets/purl/985709.
@article{osti_985709,
title = {Nickel-titanium-phosphate cathodes},
author = {Belharouak, Ilias and Amine, Khalil},
abstractNote = {Cathode materials having an improved electronic conductivity allowing for faster kinetics in the electrochemical reaction, as well as higher conductivity to meet the power requirements for many consumer applications, especially at low temperatures. The cathode material comprises a compound from the family of compounds where the basic unit is generally represented by Li.sub.xNi.sub.0.5TiOPO.sub.4. The structure of Li.sub.xNi.sub.0.5TiOPO.sub.4 includes corner sharing octahedra [TiO.sub.6] running along the C-axis. The structure is such that nearly three Li atoms are being inserted in Li.sub.xNi.sub.0.5TiOPO.sub.4. A cell in accordance with the principles of the present invention is rechargable and demonstrates a high capacity of lithium intercalation and fast kinetics.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 16 00:00:00 EST 2008},
month = {Tue Dec 16 00:00:00 EST 2008}
}
Works referenced in this record:
Ab initio determination and Rietveld refinement of the crystal structure of Ni 0.50 TiO ( PO 4 )
journal, March 1999
- Gravereau, P.; Chaminade, J. P.; Manoun, B.
- Powder Diffraction, Vol. 14, Issue 1
Preparation and structural characterization of two new titanium phosphates NaCaTi(PO) AND NiTiOPO
journal, January 1998
- Eljazouli, A.; Krimi, S.; Manoun, B.
- Annales de Chimie Science des Mat�riaux, Vol. 23, Issue 1-2