MIS-based sensors with hydrogen selectivity

Li, Dongmei; Medlin, J. William; McDaniel, Anthony H.; Bastasz, Robert J.

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Title: MIS-based sensors with hydrogen selectivity

Abstract

The invention provides hydrogen selective metal-insulator-semiconductor sensors which include a layer of hydrogen selective material. The hydrogen selective material can be polyimide layer having a thickness between 200 and 800 nm. Suitable polyimide materials include reaction products of benzophenone tetracarboxylic dianhydride 4,4-oxydianiline m-phenylene diamine and other structurally similar materials.

Inventors:

Li, Dongmei ^[1]; Medlin, J. William ^[1]; McDaniel, Anthony H. ^[2]; Bastasz, Robert J. ^[2]

Boulder, CO
Livermore, CA

Issue Date:: Tue Mar 11 00:00:00 EDT 2008

Research Org.:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 970537

Patent Number(s):: 7340938

Application Number:: 11/361,310

Assignee:: The Regents of the University of Colorado (Boulder, CO)

Patent Classifications (CPCs):: G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

Show more

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N27/414 - Ion-sensitive or chemical field-effect transistors, i.e. ISFETS or CHEMFETS
G01N33/005 - {for H2}

Show less

DOE Contract Number:: AC04-94AL85000

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 47 OTHER INSTRUMENTATION

Citation Formats


                    Li, Dongmei, Medlin, J. William, McDaniel, Anthony H., and Bastasz, Robert J. MIS-based sensors with hydrogen selectivity.  United States: N. p., 2008. 
        Web.

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                    Li, Dongmei, Medlin, J. William, McDaniel, Anthony H., & Bastasz, Robert J. MIS-based sensors with hydrogen selectivity.  United States.

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                    Li, Dongmei, Medlin, J. William, McDaniel, Anthony H., and Bastasz, Robert J. Tue .  
        "MIS-based sensors with hydrogen selectivity".  United States.  https://www.osti.gov/servlets/purl/970537.

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@article{osti_970537,

  title        = {MIS-based sensors with hydrogen selectivity},

  author       = {Li, Dongmei and Medlin, J. William and McDaniel, Anthony H. and Bastasz, Robert J.},

  abstractNote = {The invention provides hydrogen selective metal-insulator-semiconductor sensors which include a layer of hydrogen selective material. The hydrogen selective material can be polyimide layer having a thickness between 200 and 800 nm. Suitable polyimide materials include reaction products of benzophenone tetracarboxylic dianhydride 4,4-oxydianiline m-phenylene diamine and other structurally similar materials.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Mar 11 00:00:00 EDT 2008},

  month        = {Tue Mar 11 00:00:00 EDT 2008}

}

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Works referenced in this record:

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Real time measurements of hydrogen desorption and absorption during CO exposures of Pd: hydrogen sticking and dissolution
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Similar Records

Title: MIS-based sensors with hydrogen selectivity

Abstract

Citation Formats

Ultrathin, Gas-Selective Polyimide Membranes Prepared from Multilayer Polyelectrolyte Films journal, January 2003

Real time measurements of hydrogen desorption and absorption during CO exposures of Pd: hydrogen sticking and dissolution journal, May 1998

Surface Heterogeneity of Supported Palladium Catalyst for the Hydrogenation of Acetylene−Ethylene Mixtures † journal, March 1997

Preparation and characterization of SiO2 composite membrane for purification of hydrogen from methanol steam reforming as an energy carrier system for PEMFC journal, July 2003

Ethylene adsorption on Pd( 111 ) studied using infrared reflection–absorption spectroscopy journal, June 2002

Preparation and Characterizaton of SiO 2 Composite Membranes for Purification of Hydrogen for PEMFC journal, July 2002

Theoretical Study of the Adsorption of Acetylene on the (111) Surfaces of Pd, Pt, Ni, and Rh journal, January 2003

Thin oxide films as surface modifiers of MIS field effect gas sensors journal, June 2002

Palladium and platinum gate metal‐oxide‐semiconductor capacitors in hydrogen and oxygen mixtures journal, October 1982

Synthesis, Characterization, and Optical Properties of Metal-Containing Fluorinated Polyimide Films journal, November 1998

The response of palladium metal-insulator-semiconductor devices to hydrogen–oxygen mixtures: comparisons between kinetic models and experiment journal, November 2003

Membrane-based gas separation journal, August 1993

Structure/permeability relationships of polyimide membranes. Applications to the separation of gas mixtures journal, August 1989

Dehydrogenation of acetylene and ethylene studied on clean and oxygen covered palladium surfaces journal, August 1986

The influence of CO on the response of hydrogen sensitive Pd-MOS devices journal, August 1997

Density functional theory studies of the adsorption of ethylene and oxygen on Pt(111) and Pt[sub 3]Sn(111) journal, January 2001

Gas permeability and permselectivity of photochemically crosslinked copolyimides journal, July 1999

Why bother about gas-sensitive field-effect devices? journal, August 1996

Hydrogen sensing in vacuum systems with catalytic field plate MNOS capacitors journal, May 1997

Drift effects in transition metal gate MOS and MISFETs journal, August 1993

Bridging the pressure gap for palladium metal-insulator-semiconductor hydrogen sensors in oxygen containing environments journal, July 1998

Ordered structures of CO on Pd(111) studied by STM journal, June 2002

Hydrogen sensitive mos-structures journal, January 1981

High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation journal, April 2003

Effects of a polyimide coating on the hydrogen selectivity of MIS sensors journal, May 2006

Permeability and permselectivity of gases in fluorinated and non-fluorinated polyimides journal, January 1992

Some studies of molecularly-imprinted polymer membranes in combination with field-effect devices journal, June 1993

Interfacial reactions in polyimide/metal systems journal, April 1991

Effect of methyl substituents on permeability and permselectivity of gases in polyimides prepared from methyl-substituted phenylenediamines journal, July 1992

Application of polymer-coated metal-insulator-semiconductor sensors for the detection of dissolved hydrogen journal, June 2006

Selective isomerization of 2,5-dihydrofuran to 2,3-dihydrofuran using CO-modified, supported Pd catalysts journal, March 2000

Effects of competitive carbon monoxide adsorption on the hydrogen response of metal–insulator–semiconductor sensors: the role of metal film morphology journal, February 2003

Hydrogen sensitive mos-structures part 2: characterization journal, January 1981

Polymer membranes for modification of the selectivity of field-effect gas sensors journal, March 1992

Fabrication of Polymer/Selective-Flake Nanocomposite Membranes and Their Use in Gas Separation journal, October 2004

Gas permeability and permselectivity in polyimides based on 3,3',4,4'-biphenyltetracarboxylic dianhydride journal, November 1989

Ultrathin, Gas-Selective Polyimide Membranes Prepared from Multilayer Polyelectrolyte Films
journal, January 2003

Real time measurements of hydrogen desorption and absorption during CO exposures of Pd: hydrogen sticking and dissolution
journal, May 1998

Surface Heterogeneity of Supported Palladium Catalyst for the Hydrogenation of Acetylene−Ethylene Mixtures ^†
journal, March 1997

Preparation and characterization of SiO2 composite membrane for purification of hydrogen from methanol steam reforming as an energy carrier system for PEMFC
journal, July 2003

Ethylene adsorption on Pd( 111 ) studied using infrared reflection–absorption spectroscopy
journal, June 2002

Preparation and Characterizaton of SiO ₂ Composite Membranes for Purification of Hydrogen for PEMFC
journal, July 2002

Theoretical Study of the Adsorption of Acetylene on the (111) Surfaces of Pd, Pt, Ni, and Rh
journal, January 2003

Thin oxide films as surface modifiers of MIS field effect gas sensors
journal, June 2002

Palladium and platinum gate metal‐oxide‐semiconductor capacitors in hydrogen and oxygen mixtures
journal, October 1982

Synthesis, Characterization, and Optical Properties of Metal-Containing Fluorinated Polyimide Films
journal, November 1998

The response of palladium metal-insulator-semiconductor devices to hydrogen–oxygen mixtures: comparisons between kinetic models and experiment
journal, November 2003

Membrane-based gas separation
journal, August 1993

Structure/permeability relationships of polyimide membranes. Applications to the separation of gas mixtures
journal, August 1989

Dehydrogenation of acetylene and ethylene studied on clean and oxygen covered palladium surfaces
journal, August 1986

The influence of CO on the response of hydrogen sensitive Pd-MOS devices
journal, August 1997

Density functional theory studies of the adsorption of ethylene and oxygen on Pt(111) and Pt[sub 3]Sn(111)
journal, January 2001

Gas permeability and permselectivity of photochemically crosslinked copolyimides
journal, July 1999

Why bother about gas-sensitive field-effect devices?
journal, August 1996

Hydrogen sensing in vacuum systems with catalytic field plate MNOS capacitors
journal, May 1997

Drift effects in transition metal gate MOS and MISFETs
journal, August 1993

Bridging the pressure gap for palladium metal-insulator-semiconductor hydrogen sensors in oxygen containing environments
journal, July 1998

Ordered structures of CO on Pd(111) studied by STM
journal, June 2002

Hydrogen sensitive mos-structures
journal, January 1981

High-Pressure Studies of CO Adsorption on Pd(111) by X-ray Photoelectron Spectroscopy and Sum-Frequency Generation
journal, April 2003

Effects of a polyimide coating on the hydrogen selectivity of MIS sensors
journal, May 2006

Permeability and permselectivity of gases in fluorinated and non-fluorinated polyimides
journal, January 1992

Some studies of molecularly-imprinted polymer membranes in combination with field-effect devices
journal, June 1993

Interfacial reactions in polyimide/metal systems
journal, April 1991

Effect of methyl substituents on permeability and permselectivity of gases in polyimides prepared from methyl-substituted phenylenediamines
journal, July 1992

Application of polymer-coated metal-insulator-semiconductor sensors for the detection of dissolved hydrogen
journal, June 2006

Selective isomerization of 2,5-dihydrofuran to 2,3-dihydrofuran using CO-modified, supported Pd catalysts
journal, March 2000

Effects of competitive carbon monoxide adsorption on the hydrogen response of metal–insulator–semiconductor sensors: the role of metal film morphology
journal, February 2003

Hydrogen sensitive mos-structures part 2: characterization
journal, January 1981

Polymer membranes for modification of the selectivity of field-effect gas sensors
journal, March 1992

Fabrication of Polymer/Selective-Flake Nanocomposite Membranes and Their Use in Gas Separation
journal, October 2004

Gas permeability and permselectivity in polyimides based on 3,3',4,4'-biphenyltetracarboxylic dianhydride
journal, November 1989