Hydrogenation with monolith reactor under conditions of immiscible liquid phases
Abstract
The present invention relates to an improved for the hydrogenation of an immiscible mixture of an organic reactant in water. The immiscible mixture can result from the generation of water by the hydrogenation reaction itself or, by the addition of, water to the reactant prior to contact with the catalyst. The improvement resides in effecting the hydrogenation reaction in a monolith catalytic reactor from 100 to 800 cpi, at a superficial velocity of from 0.1 to 2 m/second in the absence of a cosolvent for the immiscible mixture. In a preferred embodiment, the hydrogenation is carried out using a monolith support which has a polymer network/carbon coating onto which a transition metal is deposited.
- Inventors:
-
- Whitehall, PA
- Zionsville, PA
- Allentown, PA
- Issue Date:
- Research Org.:
- Air Products and Chemicals, Inc. (Allentown, PA)
- OSTI Identifier:
- 874871
- Patent Number(s):
- 6479704
- Assignee:
- Air Products and Chemicals, Inc. (Allentown, PA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- FC07-00CH11018
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- hydrogenation; monolith; reactor; conditions; immiscible; liquid; phases; relates; improved; mixture; organic; reactant; water; result; generation; reaction; addition; prior; contact; catalyst; improvement; resides; effecting; catalytic; 100; 800; cpi; superficial; velocity; 01; msecond; absence; cosolvent; embodiment; carried; support; polymer; networkcarbon; coating; transition; metal; deposited; transition metal; liquid phase; catalytic reactor; immiscible liquid; /999/
Citation Formats
Nordquist, Andrew Francis, Wilhelm, Frederick Carl, Waller, Francis Joseph, and Machado, Reinaldo Mario. Hydrogenation with monolith reactor under conditions of immiscible liquid phases. United States: N. p., 2002.
Web.
Nordquist, Andrew Francis, Wilhelm, Frederick Carl, Waller, Francis Joseph, & Machado, Reinaldo Mario. Hydrogenation with monolith reactor under conditions of immiscible liquid phases. United States.
Nordquist, Andrew Francis, Wilhelm, Frederick Carl, Waller, Francis Joseph, and Machado, Reinaldo Mario. Tue .
"Hydrogenation with monolith reactor under conditions of immiscible liquid phases". United States. https://www.osti.gov/servlets/purl/874871.
@article{osti_874871,
title = {Hydrogenation with monolith reactor under conditions of immiscible liquid phases},
author = {Nordquist, Andrew Francis and Wilhelm, Frederick Carl and Waller, Francis Joseph and Machado, Reinaldo Mario},
abstractNote = {The present invention relates to an improved for the hydrogenation of an immiscible mixture of an organic reactant in water. The immiscible mixture can result from the generation of water by the hydrogenation reaction itself or, by the addition of, water to the reactant prior to contact with the catalyst. The improvement resides in effecting the hydrogenation reaction in a monolith catalytic reactor from 100 to 800 cpi, at a superficial velocity of from 0.1 to 2 m/second in the absence of a cosolvent for the immiscible mixture. In a preferred embodiment, the hydrogenation is carried out using a monolith support which has a polymer network/carbon coating onto which a transition metal is deposited.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 2002},
month = {Tue Jan 01 00:00:00 EST 2002}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Mass transfer and selectivity in liquid-phase hydrogenation of nitro compounds in a monolithic catalyst reactor with segmented gas-liquid flow
journal, October 1986
- Hatziantoniou, Vasilios; Andersson, Bengt; Schoon, Nils Herman
- Industrial & Engineering Chemistry Process Design and Development, Vol. 25, Issue 4
The segmented two-phase flow monolithic catalyst reactor. An alternative for liquid-phase hydrogenations
journal, February 1984
- Hatziantoniou, Vasilios; Andersson, Bengt
- Industrial & Engineering Chemistry Fundamentals, Vol. 23, Issue 1