Synthesis of perhydroxydodecaborate salts and related species
Abstract
New icosahedral borohydrates Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ]; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with a hydroxylating agent, preferably 30%.sub.w hydrogen peroxide.
- Inventors:
-
- Encino, CA
- Los Angeles, CA
- Issue Date:
- Research Org.:
- Univ. of California (United States)
- OSTI Identifier:
- 874138
- Patent Number(s):
- 6323372
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- DOE Contract Number:
- FG03-95ER61975
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- synthesis; perhydroxydodecaborate; salts; related; species; icosahedral; borohydrates; cssub2; closo-bsub12; ohsub12; cscloso-1-h-1-cbsub11; ohsub11; closo-112-hsub2; -112-csub2; bsub10; ohsub10; disclosed; set; forth; preparation; refluxing; boranes; hsub12; sup2-; closo-1-cbsub11; sup-; closo-112-chsub2; ohsub2; hsub10; hydroxylating; agent; 30subw; hydrogen; peroxide; set forth; /999/
Citation Formats
Hawthorne, M Frederick, Peymann, Toralf, and Herzog, Axel Hans-Joachim. Synthesis of perhydroxydodecaborate salts and related species. United States: N. p., 2001.
Web.
Hawthorne, M Frederick, Peymann, Toralf, & Herzog, Axel Hans-Joachim. Synthesis of perhydroxydodecaborate salts and related species. United States.
Hawthorne, M Frederick, Peymann, Toralf, and Herzog, Axel Hans-Joachim. Mon .
"Synthesis of perhydroxydodecaborate salts and related species". United States. https://www.osti.gov/servlets/purl/874138.
@article{osti_874138,
title = {Synthesis of perhydroxydodecaborate salts and related species},
author = {Hawthorne, M Frederick and Peymann, Toralf and Herzog, Axel Hans-Joachim},
abstractNote = {New icosahedral borohydrates Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ]; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with a hydroxylating agent, preferably 30%.sub.w hydrogen peroxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2001},
month = {Mon Jan 01 00:00:00 EST 2001}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthesis of monosubstituted derivatives of closo-decahydrodecaborate(2-). X-ray crystal structures of [closo-2-B10H9CO]- and [closo-2-B10H9NCO]2-
journal, June 1992
- Shelly, Kenneth; Knobler, Carolyn B.; Hawthorne, M. Frederick
- Inorganic Chemistry, Vol. 31, Issue 13
A Study of the Reaction of Hydroxide Ion with B 20 H 18 -2
journal, November 1965
- Hawthorne, M. Frederick; Philling, Richard L.; Garrett, Philip M.
- Journal of the American Chemical Society, Vol. 87, Issue 21