Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof
Abstract
A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.
- Inventors:
-
- Orinda, CA
- Corning, NY
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- OSTI Identifier:
- 873443
- Patent Number(s):
- 6160158
- Application Number:
- 09/026473
- Assignee:
- Regents of University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC03-76SF00098
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- fluorination; utilizing; thermodynamically; unstable; fluorides; fluoride; salts; method; fluorinating; carbon; compound; cationic; utilizes; agent; selected; nickel; liquid; anhydrous; hydrogen; desired; organic; undergo; reacted; contacting; chosen; reaction; vessel; time; period; temperature; thermodynamically unstable; organic compound; time period; reaction vessel; fluoride salt; agent selected; carbon compound; reaction time; hydrogen fluoride; nickel fluoride; nickel fluorides; anhydrous hydrogen; /999/
Citation Formats
Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States: N. p., 2000.
Web.
Bartlett, Neil, Whalen, J Marc, & Chacon, Lisa. Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof. United States.
Bartlett, Neil, Whalen, J Marc, and Chacon, Lisa. Sat .
"Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof". United States. https://www.osti.gov/servlets/purl/873443.
@article{osti_873443,
title = {Fluorination utilizing thermodynamically unstable fluorides and fluoride salts thereof},
author = {Bartlett, Neil and Whalen, J Marc and Chacon, Lisa},
abstractNote = {A method for fluorinating a carbon compound or cationic carbon compound utilizes a fluorination agent selected from thermodynamically unstable nickel fluorides and salts thereof in liquid anhydrous hydrogen fluoride. The desired carbon compound or cationic organic compound to undergo fluorination is selected and reacted with the fluorination agent by contacting the selected organic or cationic organic compound and the chosen fluorination agent in a reaction vessel for a desired reaction time period at room temperature or less.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jan 01 00:00:00 EST 2000},
month = {Sat Jan 01 00:00:00 EST 2000}
}
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