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Title: Low emissions diesel fuel

Abstract

A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.

Inventors:
 [1];  [2];  [3];  [4]
  1. Knoxville, TN
  2. Oak Ridge, TN
  3. Farragut, TN
  4. Kingston, TN
Issue Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
OSTI Identifier:
871519
Patent Number(s):
5746783
Assignee:
Martin Marietta Energy Systems, Inc. (Oak Ridge, TN)
Patent Classifications (CPCs):
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10L - FUELS NOT OTHERWISE PROVIDED FOR
DOE Contract Number:  
AC05-84OR21400
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
emissions; diesel; fuel; method; matter; composition; controlling; existing; engines; achieved; adding; amount; material; decrease; produced; combustion; specifically; amounts; urea; triazine; compound; methylol; melamines; added; compounds; insoluble; microemulsion; technology; suspend; dissolve; typical; formulation; t-butyl; alcohol; water; oleic; acid; ethanolamine; subject; provides; improved; heavy; major; modifications; diesel engines; diesel engine; provides improved; diesel fuel; oleic acid; /44/

Citation Formats

Compere, Alicia L, Griffith, William L, Dorsey, George F, and West, Brian H. Low emissions diesel fuel. United States: N. p., 1998. Web.
Compere, Alicia L, Griffith, William L, Dorsey, George F, & West, Brian H. Low emissions diesel fuel. United States.
Compere, Alicia L, Griffith, William L, Dorsey, George F, and West, Brian H. Tue . "Low emissions diesel fuel". United States. https://www.osti.gov/servlets/purl/871519.
@article{osti_871519,
title = {Low emissions diesel fuel},
author = {Compere, Alicia L and Griffith, William L and Dorsey, George F and West, Brian H},
abstractNote = {A method and matter of composition for controlling NO.sub.x emissions from existing diesel engines. The method is achieved by adding a small amount of material to the diesel fuel to decrease the amount of NO.sub.x produced during combustion. Specifically, small amounts, less than about 1%, of urea or a triazine compound (methylol melamines) are added to diesel fuel. Because urea and triazine compounds are generally insoluble in diesel fuel, microemulsion technology is used to suspend or dissolve the urea or triazine compound in the diesel fuel. A typical fuel formulation includes 5% t-butyl alcohol, 4.5% water, 0.5% urea or triazine compound, 9% oleic acid, and 1% ethanolamine. The subject invention provides improved emissions in heavy diesel engines without the need for major modifications.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 05 00:00:00 EDT 1998},
month = {Tue May 05 00:00:00 EDT 1998}
}

Works referenced in this record:

High-Alcohol Microemulsion Fuel Performance in a Diesel Engine
conference, October 1990

  • West, B. H.; Compere, A. L.; Griffith, W. L.
  • International Fuels & Lubricants Meeting & Exposition, SAE Technical Paper Series
  • https://doi.org/10.4271/902101

Small-angle neutron scattering from micelles of potassium salts of 18-carbon fatty acids
journal, September 1989


Analytical scattering function of a polydisperse Percus-Yevick fluid with Schulz- ( Γ -) distributed diameters
journal, March 1987


Alcohol partition in a water-in-oil microemulsion from small-angle neutron scattering
journal, June 1992