Preparation of lead-zirconium-titanium film and powder by electrodeposition
Abstract
A process for the preparation of lead-zirconium-titanium (PZT) film and powder compositions. The process comprises the steps of providing an electrodeposition bath, providing soluble salts of lead, zirconium and titanium metals to this bath, electrically energizing the bath to thereby direct ions of each respective metal to a substrate electrode and cause formation of metallic particles as a recoverable film of PZT powder on the electrode, and also recovering the resultant film as a powder. Recovery of the PZT powder can be accomplished by continually energizing the bath to thereby cause powder initially deposited on the substrate-electrode to drop therefrom into the bath from which it is subsequently removed. A second recovery alternative comprises energizing the bath for a period of time sufficient to cause PZT powder deposition on the substrate-electrode only, from which it is subsequently recovered. PZT film and powder so produced can be employed directly in electronic applications, or the film and powder can be subsequently oxidized as by an annealing process to thereby produce lead-zirconium-titanium oxide for use in electronic applications.
- Inventors:
-
- Littleton, CO
- Evergreen, CO
- Issue Date:
- Research Org.:
- Midwest Research Institute, Kansas City, MO (United States)
- OSTI Identifier:
- 870135
- Patent Number(s):
- 5462647
- Assignee:
- Midwest Research Institute (Kansas City, MO)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- DOE Contract Number:
- AC36-83CH10093
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- preparation; lead-zirconium-titanium; film; powder; electrodeposition; process; pzt; compositions; comprises; steps; providing; bath; soluble; salts; lead; zirconium; titanium; metals; electrically; energizing; direct; respective; metal; substrate; electrode; formation; metallic; particles; recoverable; recovering; resultant; recovery; accomplished; continually; initially; deposited; substrate-electrode; drop; therefrom; subsequently; removed; alternative; period; time; sufficient; deposition; recovered; produced; employed; directly; electronic; applications; oxidized; annealing; produce; oxide; soluble salts; subsequently removed; metallic particles; time sufficient; process comprises; titanium oxide; soluble salt; substrate electrode; subsequently remove; annealing process; electronic applications; electrodeposition bath; titanium metal; resultant film; respective metal; powder composition; /205/75/
Citation Formats
Bhattacharya, Raghu N, and Ginley, David S. Preparation of lead-zirconium-titanium film and powder by electrodeposition. United States: N. p., 1995.
Web.
Bhattacharya, Raghu N, & Ginley, David S. Preparation of lead-zirconium-titanium film and powder by electrodeposition. United States.
Bhattacharya, Raghu N, and Ginley, David S. Sun .
"Preparation of lead-zirconium-titanium film and powder by electrodeposition". United States. https://www.osti.gov/servlets/purl/870135.
@article{osti_870135,
title = {Preparation of lead-zirconium-titanium film and powder by electrodeposition},
author = {Bhattacharya, Raghu N and Ginley, David S},
abstractNote = {A process for the preparation of lead-zirconium-titanium (PZT) film and powder compositions. The process comprises the steps of providing an electrodeposition bath, providing soluble salts of lead, zirconium and titanium metals to this bath, electrically energizing the bath to thereby direct ions of each respective metal to a substrate electrode and cause formation of metallic particles as a recoverable film of PZT powder on the electrode, and also recovering the resultant film as a powder. Recovery of the PZT powder can be accomplished by continually energizing the bath to thereby cause powder initially deposited on the substrate-electrode to drop therefrom into the bath from which it is subsequently removed. A second recovery alternative comprises energizing the bath for a period of time sufficient to cause PZT powder deposition on the substrate-electrode only, from which it is subsequently recovered. PZT film and powder so produced can be employed directly in electronic applications, or the film and powder can be subsequently oxidized as by an annealing process to thereby produce lead-zirconium-titanium oxide for use in electronic applications.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1995},
month = {Sun Jan 01 00:00:00 EST 1995}
}
Works referenced in this record:
Electrodeposition of Metals from Organic Solutions
journal, January 1957
- Reid, W. E.; Bish, J. M.; Brenner, Abner
- Journal of The Electrochemical Society, Vol. 104, Issue 1