Photochemical dimerization of organic compounds
Abstract
At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerization in the presence of hydrogen or nitrous oxide.
- Inventors:
-
- Bethany, CT
- Princeton, NJ
- New Haven, CT
- Branford, CT
- Issue Date:
- Research Org.:
- Yale Univ., New Haven, CT (United States)
- OSTI Identifier:
- 868239
- Patent Number(s):
- 5104503
- Assignee:
- Yale University (New Haven, CT)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
- DOE Contract Number:
- FG02-84ER13297
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- photochemical; dimerization; organic; compounds; selectivity; reaction; rate; photosensitized; vapor; phase; dimerizations; including; dehydrodimerizations; hydrodimerizations; cross-dimerizations; saturated; unsaturated; improved; conducting; presence; hydrogen; nitrous; oxide; photochemical dimerization; reaction rate; organic compound; organic compounds; vapor phase; nitrous oxide; unsaturated organic; /204/
Citation Formats
Crabtree, Robert H, Brown, Stephen H, Muedas, Cesar A, and Ferguson, Richard R. Photochemical dimerization of organic compounds. United States: N. p., 1992.
Web.
Crabtree, Robert H, Brown, Stephen H, Muedas, Cesar A, & Ferguson, Richard R. Photochemical dimerization of organic compounds. United States.
Crabtree, Robert H, Brown, Stephen H, Muedas, Cesar A, and Ferguson, Richard R. Wed .
"Photochemical dimerization of organic compounds". United States. https://www.osti.gov/servlets/purl/868239.
@article{osti_868239,
title = {Photochemical dimerization of organic compounds},
author = {Crabtree, Robert H and Brown, Stephen H and Muedas, Cesar A and Ferguson, Richard R},
abstractNote = {At least one of selectivity and reaction rate of photosensitized vapor phase dimerizations, including dehydrodimerizations, hydrodimerizations and cross-dimerizations of saturated and unsaturated organic compounds is improved by conducting the dimerization in the presence of hydrogen or nitrous oxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Jan 01 00:00:00 EST 1992},
month = {Wed Jan 01 00:00:00 EST 1992}
}
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