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Title: Long life reference electrode

Abstract

An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservior and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved.

Inventors:
 [1];  [2]
  1. LaGrange, IL
  2. Woodridge, IL
Issue Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
OSTI Identifier:
866903
Patent Number(s):
4818366
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
DOE Contract Number:  
W-31109-ENG-38
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
life; reference; electrode; external; provided; term; temperature; pressure; arranged; vertical; electrically; insulative; tube; upper; portion; serving; electrolyte; reservior; electrolytic; communication; monitored; flow; restriction; porous; plug; limit; release; piston; equalized; fitted; impart; incremental; selected; suitable; size; weight; slight; prevents; contamination; rate; operating; intervals; month; achieved; electrically insulative; flow rate; reference electrode; upper portion; flow restriction; /204/

Citation Formats

Yonco, Robert M, and Nagy, Zoltan. Long life reference electrode. United States: N. p., 1989. Web.
Yonco, Robert M, & Nagy, Zoltan. Long life reference electrode. United States.
Yonco, Robert M, and Nagy, Zoltan. Sun . "Long life reference electrode". United States. https://www.osti.gov/servlets/purl/866903.
@article{osti_866903,
title = {Long life reference electrode},
author = {Yonco, Robert M and Nagy, Zoltan},
abstractNote = {An external, reference electrode is provided for long term use with a high temperature, high pressure system. The electrode is arranged in a vertical, electrically insulative tube with an upper portion serving as an electrolyte reservior and a lower portion in electrolytic communication with the system to be monitored. The lower end portion includes a flow restriction such as a porous plug to limit the electrolyte release into the system. A piston equalized to the system pressure is fitted into the upper portion of the tube to impart a small incremental pressure to the electrolyte. The piston is selected of suitable size and weight to cause only a slight flow of electrolyte through the porous plug into the high pressure system. This prevents contamination of the electrolyte but is of such small flow rate that operating intervals of a month or more can be achieved.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1989},
month = {Sun Jan 01 00:00:00 EST 1989}
}