Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers

Babcock, Walter C; Friesen, Dwayne T

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
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C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
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C12 - biochemistry
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C14 - skins
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C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
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F - mechanical engineering
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F28 - heat exchange in general
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G - physics
G01 - measuring
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G03 - photography
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Title: Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers

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Abstract

Novel semiperimeable membranes and thin film composite (TFC) gas separation membranes useful in the separation of oxygen, nitrogen, hydrogen, water vapor, methane, carbon dioxide, hydrogen sulfide, lower hydrocarbons, and other gases are disclosed. The novel semipermeable membranes comprise the polycondensation reaction product of two complementary polyfunctional compounds, each having at least two functional groups that are mutually reactive in a condensation polymerization reaction, and at least one of which is selected from siloxanes, alkoxsilyls and aryloxysilyls. The TFC membrane comprises a microporous polymeric support, the surface of which has the novel semipermeable film formed thereon, preferably by interfacial polymerization.

Inventors:

Babcock, Walter C ^[1]; Friesen, Dwayne T ^[1]

Bend, OR

Issue Date:: Fri Jan 01 00:00:00 EST 1988

Research Org.:: Bend Research Inc

OSTI Identifier:: 866760

Patent Number(s):: 4781733

Assignee:: Bend Research, Inc. (Bend, OR)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D69/125 - {In-situ manufacturing by polymerisation, polycondensation, cross-linking, and/or reaction}
B01D71/56 - Polyamides, e.g. polyester-amides
B01D71/70 - Polymers having silicon in the main chain, with or without sulfur, nitrogen, oxygen or carbon only

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G77/38 - Polysiloxanes modified by chemical after-treatment {

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DOE Contract Number:: AC03-84ER80159

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: semipermeable; thin-film; membranes; comprising; siloxane; alkoxysilyl; aryloxysilyl; oligomers; copolymers; novel; semiperimeable; film; composite; tfc; gas; separation; useful; oxygen; nitrogen; hydrogen; water; vapor; methane; carbon; dioxide; sulfide; hydrocarbons; gases; disclosed; comprise; polycondensation; reaction; product; complementary; polyfunctional; compounds; functional; mutually; reactive; condensation; polymerization; selected; siloxanes; alkoxsilyls; aryloxysilyls; membrane; comprises; microporous; polymeric; support; surface; formed; thereon; preferably; interfacial; membrane comprises; semipermeable membranes; membranes useful; microporous polymeric; interfacial polymerization; semipermeable membrane; permeable membrane; water vapor; carbon dioxide; hydrogen sulfide; reaction product; gas separation; separation membrane; formed thereon; separation membranes; condensation polymerization; polymeric support; permeable membranes; microporous polymer; membranes comprising; film formed; film membranes; film composite; polymerization reaction; porous polymer; /95/96/

Citation Formats


                    Babcock, Walter C, and Friesen, Dwayne T. Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers.  United States: N. p., 1988. 
        Web.

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                    Babcock, Walter C, & Friesen, Dwayne T. Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers.  United States.

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                    Babcock, Walter C, and Friesen, Dwayne T. Fri .  
        "Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers".  United States.  https://www.osti.gov/servlets/purl/866760.

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@article{osti_866760,

  title        = {Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers},

  author       = {Babcock, Walter C and Friesen, Dwayne T},

  abstractNote = {Novel semiperimeable membranes and thin film composite (TFC) gas separation membranes useful in the separation of oxygen, nitrogen, hydrogen, water vapor, methane, carbon dioxide, hydrogen sulfide, lower hydrocarbons, and other gases are disclosed. The novel semipermeable membranes comprise the polycondensation reaction product of two complementary polyfunctional compounds, each having at least two functional groups that are mutually reactive in a condensation polymerization reaction, and at least one of which is selected from siloxanes, alkoxsilyls and aryloxysilyls. The TFC membrane comprises a microporous polymeric support, the surface of which has the novel semipermeable film formed thereon, preferably by interfacial polymerization.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Fri Jan 01 00:00:00 EST 1988},

  month        = {Fri Jan 01 00:00:00 EST 1988}

}

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Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers

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