Process for reducing organic compounds with calcium, amine, and alcohol
Abstract
Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.
- Inventors:
- Issue Date:
- Research Org.:
- Purdue Univ., West Lafayette, IN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 865547
- Patent Number(s):
- 4533760
- Application Number:
- 06/643,649
- Assignee:
- Purdue Research Foundation (West Lafayette, IN)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC02-81ER10989
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 1984 Aug 23
- Country of Publication:
- United States
- Language:
- English
- Subject:
- /999/585/
Citation Formats
Benkeser, Robert A., Laugal, James A., and Rappa, Angela. Process for reducing organic compounds with calcium, amine, and alcohol. United States: N. p., 1985.
Web.
Benkeser, Robert A., Laugal, James A., & Rappa, Angela. Process for reducing organic compounds with calcium, amine, and alcohol. United States.
Benkeser, Robert A., Laugal, James A., and Rappa, Angela. Tue .
"Process for reducing organic compounds with calcium, amine, and alcohol". United States. https://www.osti.gov/servlets/purl/865547.
@article{osti_865547,
title = {Process for reducing organic compounds with calcium, amine, and alcohol},
author = {Benkeser, Robert A. and Laugal, James A. and Rappa, Angela},
abstractNote = {Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 01 00:00:00 EST 1985},
month = {Tue Jan 01 00:00:00 EST 1985}
}
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