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Title: Catalyst for converting synthesis gas to light olefins

Abstract

A catalyst and process for making same useful in the catalytic hydrogenation of carbon monoxide in which a silicalite support substantially free of aluminum is soaked in an aqueous solution of iron and potassium salts wherein the iron and potassium are present in concentrations such that the dried silicalite has iron present in the range of from about 5 to about 25 percent by weight and has potassium present in an amount not less than about 0.2 percent by weight, and thereafter the silicalite is dried and combined with amorphous silica as a binder for pellets, the catalytic pellets are used to convert synthesis gas to C.sub.2 -C.sub.4 olefins.

Inventors:
 [1];  [2]
  1. Monroeville, PA
  2. Pittsburgh, PA
Issue Date:
OSTI Identifier:
864274
Patent Number(s):
4340503
Assignee:
United States of America as represented by United States (Washington, DC)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
catalyst; converting; synthesis; gas; light; olefins; process; useful; catalytic; hydrogenation; carbon; monoxide; silicalite; support; substantially; free; aluminum; soaked; aqueous; solution; iron; potassium; salts; concentrations; dried; range; 25; percent; weight; amount; thereafter; combined; amorphous; silica; binder; pellets; convert; -c; catalytic hydrogenation; substantially free; carbon monoxide; aqueous solution; synthesis gas; converting synthesis; potassium salt; convert synthesis; /502/518/

Citation Formats

Rao, V Udaya S., and Gormley, Robert J. Catalyst for converting synthesis gas to light olefins. United States: N. p., 1982. Web.
Rao, V Udaya S., & Gormley, Robert J. Catalyst for converting synthesis gas to light olefins. United States.
Rao, V Udaya S., and Gormley, Robert J. Fri . "Catalyst for converting synthesis gas to light olefins". United States. https://www.osti.gov/servlets/purl/864274.
@article{osti_864274,
title = {Catalyst for converting synthesis gas to light olefins},
author = {Rao, V Udaya S. and Gormley, Robert J},
abstractNote = {A catalyst and process for making same useful in the catalytic hydrogenation of carbon monoxide in which a silicalite support substantially free of aluminum is soaked in an aqueous solution of iron and potassium salts wherein the iron and potassium are present in concentrations such that the dried silicalite has iron present in the range of from about 5 to about 25 percent by weight and has potassium present in an amount not less than about 0.2 percent by weight, and thereafter the silicalite is dried and combined with amorphous silica as a binder for pellets, the catalytic pellets are used to convert synthesis gas to C.sub.2 -C.sub.4 olefins.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 1982},
month = {Fri Jan 01 00:00:00 EST 1982}
}