Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof
Abstract
Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO3, BaMnO3−δ, SrMnO3−δ, Mn2SiO4, Mn2MgO4−δ, La0.8Sr0.2O3−δ, La0.8Sr0.2FeO3−δ, Ca9Ti0.1Mn0.9O3−δ, Pr6O11−δ, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li2WO4, Na2WO4, K2WO4, SrWO4, Li2MoO4, Na2MoO4, K2MoO4, CsMoO4, Li2CO3, Na2CO3, K2CO3, or a combination thereof.
- Inventors:
- Issue Date:
- Research Org.:
- North Carolina State University, Raleigh, NC (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); National Science Foundation (NSF)
- OSTI Identifier:
- 2293854
- Patent Number(s):
- 11813592
- Application Number:
- 16/622,627
- Assignee:
- North Carolina State University (Raleigh, NC)
- DOE Contract Number:
- AR0000327; 1254351
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 06/14/2018
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Li, Fanxing, Neal, Luke Michael, Gao, Yunfei, Yusuf, Seif, and Dudek, Ryan. Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof. United States: N. p., 2023.
Web.
Li, Fanxing, Neal, Luke Michael, Gao, Yunfei, Yusuf, Seif, & Dudek, Ryan. Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof. United States.
Li, Fanxing, Neal, Luke Michael, Gao, Yunfei, Yusuf, Seif, and Dudek, Ryan. Tue .
"Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof". United States. https://www.osti.gov/servlets/purl/2293854.
@article{osti_2293854,
title = {Oxygen carrying materials with surface modification for redox-based catalysis and methods of making and uses thereof},
author = {Li, Fanxing and Neal, Luke Michael and Gao, Yunfei and Yusuf, Seif and Dudek, Ryan},
abstractNote = {Redox catalysts having surface medication, methods of making redox catalysts with surface modification, and uses of the surface modified redox catalysts are provided. In some aspects, the redox catalysts include a core oxygen carrier region such as CaMnO3, BaMnO3−δ, SrMnO3−δ, Mn2SiO4, Mn2MgO4−δ, La0.8Sr0.2O3−δ, La0.8Sr0.2FeO3−δ, Ca9Ti0.1Mn0.9O3−δ, Pr6O11−δ, manganese ore, or a combination thereof; and an outer shell having an average thickness of about 1-100 monolayers surrounding the outer surface of the core region. The outer shell can include, for example a salt selected such as Li2WO4, Na2WO4, K2WO4, SrWO4, Li2MoO4, Na2MoO4, K2MoO4, CsMoO4, Li2CO3, Na2CO3, K2CO3, or a combination thereof.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 14 00:00:00 EST 2023},
month = {Tue Nov 14 00:00:00 EST 2023}
}
Works referenced in this record:
Effects of Sodium and Tungsten Promoters on Mg 6 MnO 8 -Based Core–Shell Redox Catalysts for Chemical Looping—Oxidative Dehydrogenation of Ethane
journal, February 2019
- Yusuf, Seif; Neal, Luke; Bao, Zhenghong
- ACS Catalysis, Vol. 9, Issue 4
Intensification of Ethylene Production from Naphtha via a Redox Oxy-Cracking Scheme: Process Simulations and Analysis
journal, October 2018
- Haribal, Vasudev Pralhad; Chen, Yun; Neal, Luke
- Engineering, Vol. 4, Issue 5
Oxidative dehydrogenation of ethane under a cyclic redox scheme – Process simulations and analysis
journal, January 2017
- Haribal, Vasudev Pralhad; Neal, Luke M.; Li, Fanxing
- Energy, Vol. 119
Molten LiCl Layer Supported on MgO: Its Possible Role in Enhancing the Oxidative Dehydrogenation of Ethane
journal, April 2015
- Kristoffersen, Henrik H.; Metiu, Horia
- The Journal of Physical Chemistry C, Vol. 119, Issue 16
Mixed iron-manganese oxides as redox catalysts for chemical looping–oxidative dehydrogenation of ethane with tailorable heat of reactions
journal, November 2019
- Yusuf, Seif; Haribal, Vasudev; Jackson, Daniel
- Applied Catalysis B: Environmental, Vol. 257
Methane conversion
patent, February 1985
- Jones, C. Andrew; Sofranko, John A.
- US Patent Document 4,499,322
Comparison of LaFeO3, La0.8Sr0.2FeO3, and La0.8Sr0.2Fe0.9Co0.1O3 perovskite oxides as oxygen carrier for partial oxidation of methane
journal, December 2008
- Dai, Xiaoping; Yu, Changchun; Wu, Qiong
- Journal of Natural Gas Chemistry, Vol. 17, Issue 4
Screening of different manganese ores for chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU)
journal, December 2015
- Sundqvist, Sebastian; Arjmand, Mehdi; Mattisson, Tobias
- International Journal of Greenhouse Gas Control, Vol. 43
Alkali promoted manganese oxide compositions containing zirconium
patent, September 1988
- Jones, C. Andrew; Sofranko, John A.
- US Patent Document 4,774,380
Methane conversion process
patent, June 1985
- Jones, C. Andrew; Leonard, John J.; Sofranko, John A.
- US Patent Document 4,523,049
Methane conversion
patent, October 1985
- Jones, C. Andrew; Sofranko, John A.
- US Patent Document 4,547,611
Ca1−A MnO3 (A = Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU)
journal, November 2015
- Galinsky, Nathan; Mishra, Amit; Zhang, Jia
- Applied Energy, Vol. 157
Oxidative Dehydrogenation of Ethane: A Chemical Looping Approach
journal, June 2016
- Neal, Luke M.; Yusuf, Seif; Sofranko, John A.
- Energy Technology, Vol. 4, Issue 10
Oxygen transfer agents for the oxidative dehydrogenation of hydrocarbons and systems and processes using the same
patent, November 2018
- Sofranko, John A.; Li, Fanxing; Neal, Luke Michael
- US Patent Document 10,138,182
Combined oxides as oxygen-carrier material for chemical-looping with oxygen uncoupling
journal, January 2014
- Rydén, Magnus; Leion, Henrik; Mattisson, Tobias
- Applied Energy, Vol. 113
Effect of Promoters on Manganese-Containing Mixed Metal Oxides for Oxidative Dehydrogenation of Ethane via a Cyclic Redox Scheme
journal, July 2017
- Yusuf, Seif; Neal, Luke M.; Li, Fanxing
- ACS Catalysis, Vol. 7, Issue 8
Oxidative dehydrogenation of ethane using MoO3/Fe2O3 catalysts in a cyclic redox mode
journal, November 2018
- Novotný, Petr; Yusuf, Seif; Li, Fanxing
- Catalysis Today, Vol. 317
Intensified Ethylene Production via Chemical Looping through an Exergetically Efficient Redox Scheme
journal, September 2019
- Neal, Luke M.; Haribal, Vasudev Pralhad; Li, Fanxing
- iScience, Vol. 19
Modular‐scale ethane to liquids via chemical looping oxidative dehydrogenation: Redox catalyst performance and process analysis
journal, February 2019
- Neal, Luke; Haribal, Vasudev; McCaig, Joseph
- Journal of Advanced Manufacturing and Processing, Vol. 1, Issue 1-2
Effect of promoter in the oxidative coupling of methane over synthesized Mn/SiO2 nanocatalysts via incipient wetness impregnation
journal, November 2010
- Mahmoodi, S.; Ehsani, M. R.; Ghoreishi, S. M.
- Journal of Industrial and Engineering Chemistry, Vol. 16, Issue 6
Alkali promoted manganese oxide compositions containing silica and/or alkaline earth oxides
patent, December 1986
- Jones, C. Andrew; Leonard, John J.; Sofranko, John A.
- US Patent Document 4,629,718
Manganese-containing redox catalysts for selective hydrogen combustion under a cyclic redox scheme
journal, April 2018
- Dudek, Ryan B.; Gao, Yunfei; Zhang, Junshe
- AIChE Journal, Vol. 64, Issue 8
Li-Promoted La x Sr 2– x FeO 4−δ Core–Shell Redox Catalysts for Oxidative Dehydrogenation of Ethane under a Cyclic Redox Scheme
journal, September 2016
- Gao, Yunfei; Neal, Luke M.; Li, Fanxing
- ACS Catalysis, Vol. 6, Issue 11
Chemical looping capabilities of olivine, used as a catalyst in indirect biomass gasification
journal, February 2014
- Lancee, R. J.; Dugulan, A. I.; Thüne, P. C.
- Applied Catalysis B: Environmental, Vol. 145
Manganese silicate based redox catalysts for greener ethylene production via chemical looping – oxidative dehydrogenation of ethane
journal, September 2018
- Yusuf, Seif; Neal, Luke; Haribal, Vasudev
- Applied Catalysis B: Environmental, Vol. 232
Shell catalyst, in particular for oxidation of methanol to formaldehyde, and also method for production thereof
patent, September 2010
- Guckel, Christian; Wanninger, Klaus; Estenfelder, Marvin
- US Patent Document 7,803,972
Alkali Metal-Promoted La x Sr 2– x FeO 4−δ Redox Catalysts for Chemical Looping Oxidative Dehydrogenation of Ethane
journal, January 2018
- Gao, Yunfei; Haeri, Farrah; He, Fang
- ACS Catalysis, Vol. 8, Issue 3
Comparing direct and indirect fluidized bed gasification: Effect of redox cycle on olivine activity
journal, June 2014
- Aranda, G.; van der Drift, A.; Vreugdenhil, B. J.
- Environmental Progress & Sustainable Energy, Vol. 33, Issue 3
Perovskite oxides for redox oxidative cracking of n-hexane under a cyclic redox scheme
journal, June 2019
- Dudek, Ryan B.; Tian, Xin; Blivin, Millicent
- Applied Catalysis B: Environmental, Vol. 246