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Title: Compositions having reduced thermal conductivities and methods of making the same

Abstract

The present disclosure relates to a composition that includes a film having a network of randomly aligned carbon nanotubes, where the carbon nanotubes have an average diameter between about 0.6 nm and about 2.0 nm and the carbon nanotubes form bundles having an average diameter between about 3 nm and about 50 nm. In addition, the composition is characterized by a power factor α2σ between 1 μW/mK2 and about 3500 μW/mK2 and by ZT=α2σT/k between about 0.02 and about 2.0 over a temperature range between about 100 K and about 500 K.

Inventors:
; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Univ. of Denver, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
2293740
Patent Number(s):
11787697
Application Number:
17/474,409
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO); University of Denver (Denver, CO)
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 09/14/2021
Country of Publication:
United States
Language:
English

Citation Formats

Blackburn, Jeffrey Lee, Ferguson, Andrew John, and Zink, Barry Lee. Compositions having reduced thermal conductivities and methods of making the same. United States: N. p., 2023. Web.
Blackburn, Jeffrey Lee, Ferguson, Andrew John, & Zink, Barry Lee. Compositions having reduced thermal conductivities and methods of making the same. United States.
Blackburn, Jeffrey Lee, Ferguson, Andrew John, and Zink, Barry Lee. Tue . "Compositions having reduced thermal conductivities and methods of making the same". United States. https://www.osti.gov/servlets/purl/2293740.
@article{osti_2293740,
title = {Compositions having reduced thermal conductivities and methods of making the same},
author = {Blackburn, Jeffrey Lee and Ferguson, Andrew John and Zink, Barry Lee},
abstractNote = {The present disclosure relates to a composition that includes a film having a network of randomly aligned carbon nanotubes, where the carbon nanotubes have an average diameter between about 0.6 nm and about 2.0 nm and the carbon nanotubes form bundles having an average diameter between about 3 nm and about 50 nm. In addition, the composition is characterized by a power factor α2σ between 1 μW/mK2 and about 3500 μW/mK2 and by ZT=α2σT/k between about 0.02 and about 2.0 over a temperature range between about 100 K and about 500 K.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 17 00:00:00 EDT 2023},
month = {Tue Oct 17 00:00:00 EDT 2023}
}

Works referenced in this record:

Carbon-Nanotube-Based Thermoelectric Materials and Devices
journal, January 2018


Thermoelectric Properties of Carbon Nanotubes
journal, November 2019


Heat conduction in carbon nanotube materials: Strong effect of intrinsic thermal conductivity of carbon nanotubes
journal, July 2012


Diameter Enlargement of HiPco Single-Wall Carbon Nanotubes by Heat Treatment
journal, September 2001


Observation of extreme phase transition temperatures of water confined inside isolated carbon nanotubes
journal, November 2016


Intrinsic and Extrinsically Limited Thermoelectric Transport within Semiconducting Single‐Walled Carbon Nanotube Networks
journal, February 2019


Modulation of thermal and thermoelectric transport in individual carbon nanotubes by fullerene encapsulation
journal, July 2017


Turning Carbon Nanotubes from Exceptional Heat Conductors into Insulators
journal, March 2009


Customizing the Polarity of Single‐Walled Carbon‐Nanotube Field‐Effect Transistors Using Solution‐Based Additives
journal, November 2019


Thermal conductivity of micromachined low-stress silicon-nitride beams from 77 to 325 K
journal, February 2009


Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties
journal, April 2016


Polymer-Free Carbon Nanotube Thermoelectrics with Improved Charge Carrier Transport and Power Factor
journal, November 2016


Upper bound to the thermal conductivity of carbon nanotube pellets
journal, April 2009


CNT fibers p-doped with F4TCNQ (2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane)
conference, August 2017


Determining absolute Seebeck coefficients from relative thermopower measurements of thin films and nanostructures
journal, February 2020


Phonons in carbon nanotubes
journal, September 2000


Large n- and p-type thermoelectric power factors from doped semiconducting single-walled carbon nanotube thin films
journal, January 2017


Heat transport by long mean free path vibrations in amorphous silicon nitride near room temperature
journal, June 2013