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Title: SO3 resistant sorbents for removing mercury from flue gas

Abstract

Surface functionalized sorbent particles for vapor-phase mercury removal, especially in the presence of SO3 in, for example, flue gas. The sorbent surface is modified to increase the SO3 resistance of vapor-phase mercury sorbents. The mercury removal efficiency is immune to the presence of SO3, which is not the case with conventional activated carbon as well as brominated activated carbons. The sorbent is based on carbon particles with a metal oxide coating on the surface. The thin metal oxide layer acts as an amenable surface to introduce functional groups. The metal oxide coated carbon was further modified with amine molecules, to increase its resistance towards SO3 poisoning.

Inventors:
;
Issue Date:
Research Org.:
NEI Corp., Somerset, NJ (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1531857
Patent Number(s):
8481455
Application Number:
13/033,482
Assignee:
NEI Corporation (Somerset, NJ)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
FG02-07ER84714
Resource Type:
Patent
Resource Relation:
Patent File Date: 2011-02-23
Country of Publication:
United States
Language:
English

Citation Formats

Jain, Mohit, and Skandan, Ganesh. SO3 resistant sorbents for removing mercury from flue gas. United States: N. p., 2013. Web.
Jain, Mohit, & Skandan, Ganesh. SO3 resistant sorbents for removing mercury from flue gas. United States.
Jain, Mohit, and Skandan, Ganesh. Tue . "SO3 resistant sorbents for removing mercury from flue gas". United States. https://www.osti.gov/servlets/purl/1531857.
@article{osti_1531857,
title = {SO3 resistant sorbents for removing mercury from flue gas},
author = {Jain, Mohit and Skandan, Ganesh},
abstractNote = {Surface functionalized sorbent particles for vapor-phase mercury removal, especially in the presence of SO3 in, for example, flue gas. The sorbent surface is modified to increase the SO3 resistance of vapor-phase mercury sorbents. The mercury removal efficiency is immune to the presence of SO3, which is not the case with conventional activated carbon as well as brominated activated carbons. The sorbent is based on carbon particles with a metal oxide coating on the surface. The thin metal oxide layer acts as an amenable surface to introduce functional groups. The metal oxide coated carbon was further modified with amine molecules, to increase its resistance towards SO3 poisoning.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 09 00:00:00 EDT 2013},
month = {Tue Jul 09 00:00:00 EDT 2013}
}

Works referenced in this record:

Enhanced mercury ion adsorption by amine-modified activated carbon
journal, July 2009


Methods for preparing silica-coated carbon products
patent, April 2003


Elastomeric compounds incorporating partially coated carbon blacks
patent, June 1999


Fine Particles of Tin-Modified Rutile-Type Titanium Dioxide
patent-application, January 2008


Thermoplastic elastomer and thermoplastic elastomer composition
patent-application, September 2006


    Works referencing / citing this record:

    Heavy metal removal
    patent, January 2017


    Method to reduce mercury, acid gas, and particulate emissions
    patent, April 2016