Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF)
Abstract
A process to produce furandicarboxylic acid (FDCA). The process includes the steps of reacting a C6 sugar-containing reactant in a reaction solution comprising a first organic solvent selected from the group consisting of beta-, gamma-, and delta-lactones, hydrofurans, hydropyrans, and combinations thereof, in the presence of an acid catalyst for a time and under conditions wherein at least a portion of the C6 sugar present in the reactant is converted to 5-(hydroxymethyl)furfural (HMF); oxidizing the HMF into FDCA with or without separating the HMF from the reaction solution; and extracting the FDCA by adding an aprotic organic solvent having a dipole moment of about 1.0 D or less to the reaction solution.
- Inventors:
- Issue Date:
- Research Org.:
- Wisconsin Alumni Research Foundation, Madison, WI (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1351100
- Patent Number(s):
- 9617234
- Application Number:
- 14/974,468
- Assignee:
- Wisconsin Alumni Research Foundation
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- FC02-07ER64494
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Dec 18
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Dumesic, James A., and Motagamwala, Ali Hussain. Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF). United States: N. p., 2017.
Web.
Dumesic, James A., & Motagamwala, Ali Hussain. Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF). United States.
Dumesic, James A., and Motagamwala, Ali Hussain. Tue .
"Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF)". United States. https://www.osti.gov/servlets/purl/1351100.
@article{osti_1351100,
title = {Method to produce furandicarboxylic acid (FDCA) from 5-hydroxymethylfurfural (HMF)},
author = {Dumesic, James A. and Motagamwala, Ali Hussain},
abstractNote = {A process to produce furandicarboxylic acid (FDCA). The process includes the steps of reacting a C6 sugar-containing reactant in a reaction solution comprising a first organic solvent selected from the group consisting of beta-, gamma-, and delta-lactones, hydrofurans, hydropyrans, and combinations thereof, in the presence of an acid catalyst for a time and under conditions wherein at least a portion of the C6 sugar present in the reactant is converted to 5-(hydroxymethyl)furfural (HMF); oxidizing the HMF into FDCA with or without separating the HMF from the reaction solution; and extracting the FDCA by adding an aprotic organic solvent having a dipole moment of about 1.0 D or less to the reaction solution.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 11 00:00:00 EDT 2017},
month = {Tue Apr 11 00:00:00 EDT 2017}
}
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