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Title: Carbon dioxide capture using resin-wafer electrodeionization

Abstract

The present invention provides a resin-wafer electrodeionization (RW-EDI) apparatus including cathode and anode electrodes separated by a plurality of porous solid ion exchange resin wafers, which when in use are filled with an aqueous fluid. The apparatus includes one or more wafers comprising a basic ion exchange medium, and preferably includes one or more wafers comprising an acidic ion exchange medium. The wafers are separated from one another by ion exchange membranes. The fluid within the acidic and/or basic ion exchange wafers preferably includes, or is in contact with, a carbonic anhydrase (CA) enzyme to facilitate conversion of bicarbonate ion to carbon dioxide within the acidic medium. A pH suitable for exchange of CO.sub.2 is electrochemically maintained within the basic and acidic ion exchange wafers by applying an electric potential across the cathode and anode.

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1347087
Patent Number(s):
9126150
Application Number:
14/500,294
Assignee:
UCHICAGO ARGONNE, LLC (Argonne, IL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Sep 29
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Lin, YuPo J., Snyder, Seth W., Trachtenberg, Michael S., Cowan, Robert M., and Datta, Saurav. Carbon dioxide capture using resin-wafer electrodeionization. United States: N. p., 2015. Web.
Lin, YuPo J., Snyder, Seth W., Trachtenberg, Michael S., Cowan, Robert M., & Datta, Saurav. Carbon dioxide capture using resin-wafer electrodeionization. United States.
Lin, YuPo J., Snyder, Seth W., Trachtenberg, Michael S., Cowan, Robert M., and Datta, Saurav. Tue . "Carbon dioxide capture using resin-wafer electrodeionization". United States. https://www.osti.gov/servlets/purl/1347087.
@article{osti_1347087,
title = {Carbon dioxide capture using resin-wafer electrodeionization},
author = {Lin, YuPo J. and Snyder, Seth W. and Trachtenberg, Michael S. and Cowan, Robert M. and Datta, Saurav},
abstractNote = {The present invention provides a resin-wafer electrodeionization (RW-EDI) apparatus including cathode and anode electrodes separated by a plurality of porous solid ion exchange resin wafers, which when in use are filled with an aqueous fluid. The apparatus includes one or more wafers comprising a basic ion exchange medium, and preferably includes one or more wafers comprising an acidic ion exchange medium. The wafers are separated from one another by ion exchange membranes. The fluid within the acidic and/or basic ion exchange wafers preferably includes, or is in contact with, a carbonic anhydrase (CA) enzyme to facilitate conversion of bicarbonate ion to carbon dioxide within the acidic medium. A pH suitable for exchange of CO.sub.2 is electrochemically maintained within the basic and acidic ion exchange wafers by applying an electric potential across the cathode and anode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 08 00:00:00 EDT 2015},
month = {Tue Sep 08 00:00:00 EDT 2015}
}

Works referenced in this record:

Enzyme systems for gas processing
patent, November 2000


Electrodeionization substrate, and device for electrodeionization treatment
patent, December 2002


Electrodeionization method
patent, September 2004


Single-stage separation and esterification of cation salt carboxylates using electrodeionization
patent, November 2006


Porous solid ion exchange wafer for immobilizing biomolecules
patent, December 2007


Devices using resin wafers and applications thereof
patent, March 2009


Methane production using resin-wafer electrodeionization
patent, March 2014


Novel enzyme compositions for removing carbon dioxide from a mixed gas
patent-application, January 2008


Retention of counterions in the separative bioreactor
patent-application, August 2008