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Title: Non-Faradaic electrochemical promotion of catalytic methane reforming for methanol production

Abstract

A method of converting methane to methanol at low temperatures utilizes a reactor including an anode, a cathode, a membrane separator between the anode and cathode, a metal oxide catalyst at the anode and a hydrogen recovery catalyst at the cathode. The method can convert methane to methanol at as rate exceeding the theoretical Faradaic rate due to the contribution of an electrochemical reaction occurring in tandem with a Faradaic reaction.

Inventors:
Issue Date:
Research Org.:
Gas Technology Institute, Des Plaines, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1333285
Patent Number(s):
9499917
Application Number:
14/076,445
Assignee:
Gas Technology Institute (Des Plaines, IL)
Patent Classifications (CPCs):
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25B - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AR0000307
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Nov 11
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Fan, Qinbai. Non-Faradaic electrochemical promotion of catalytic methane reforming for methanol production. United States: N. p., 2016. Web.
Fan, Qinbai. Non-Faradaic electrochemical promotion of catalytic methane reforming for methanol production. United States.
Fan, Qinbai. Tue . "Non-Faradaic electrochemical promotion of catalytic methane reforming for methanol production". United States. https://www.osti.gov/servlets/purl/1333285.
@article{osti_1333285,
title = {Non-Faradaic electrochemical promotion of catalytic methane reforming for methanol production},
author = {Fan, Qinbai},
abstractNote = {A method of converting methane to methanol at low temperatures utilizes a reactor including an anode, a cathode, a membrane separator between the anode and cathode, a metal oxide catalyst at the anode and a hydrogen recovery catalyst at the cathode. The method can convert methane to methanol at as rate exceeding the theoretical Faradaic rate due to the contribution of an electrochemical reaction occurring in tandem with a Faradaic reaction.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 22 00:00:00 EST 2016},
month = {Tue Nov 22 00:00:00 EST 2016}
}

Works referenced in this record:

Electro organic method and apparatus for carrying out same
patent, July 1984


Electrocatalyst for the oxidation of methane and an electrocatalytic process
patent, September 1991


CuC1 thermochemical cycle for hydrogen production
patent, January 2012


Efficient and selective formation of methanol from methane in a fuel cell-type reactor
journal, April 2011