Halogen free benzoxazine based curable compositions for high T.sub.g applications

Tietze, Roger; Nguyen, Yen-Loan

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A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
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B22 - casting
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B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
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B32 - layered products
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B62 - land vehicles for travelling otherwise than on rails
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C - chemistry
C01 - inorganic chemistry
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C03 - glass
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C22 - metallurgy
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D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
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D06 - treatment of textiles or the like
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D10 - indexing scheme associated with sublasses of section d, relating to textiles
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G - physics
G01 - measuring
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G03 - photography
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G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
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G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
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Title: Halogen free benzoxazine based curable compositions for high T.sub.g applications

Abstract

A method for forming a halogen-free curable composition containing a benzoxazine monomer, at least one epoxy resin, a catalyst, a toughening agent and a solvent. The halogen-free curable composition is especially suited for use in automobile and aerospace applications since the composition, upon curing, produces a composite having a high glass transition temperature.

Inventors:: Tietze, Roger; Nguyen, Yen-Loan

Issue Date:: Tue Aug 16 00:00:00 EDT 2016

Research Org.:: Huntsman Advanced Materials Americas LLC, The Woodlands, TX (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1298003

Patent Number(s):: 9416271

Application Number:: 14/606,481

Assignee:: HUNTSMAN ADVANCED MATERIALS AMERICAS LLC (The Woodlands, TX)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29D - PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE

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B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29C - SHAPING OR JOINING OF PLASTICS
B29C65/02 - by heating, with or without pressure

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29D - PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
B29D22/003 - {Containers for packaging, storing or transporting, e.g. bottles, jars, cans, barrels, tanks}

B - PERFORMING OPERATIONS B29 - WORKING OF PLASTICS B29K - INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
B29K2079/00 - Use of polymers having nitrogen, with or without oxygen or carbon only, in the main chain {, not provided for in groups B29K2061/00 - B29K2077/00}, as moulding material

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G2650/36 - Pre-polymer
C08G59/06 - of polyhydric phenols
C08G59/24 - carbocyclic
C08G59/4014 - {Nitrogen containing compounds}
C08G59/5046 - {heterocyclic}
C08G59/621 - {Phenols}
C08G59/683 - {Phenolates}
C08G73/0233 - {Polyamines derived from

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08K - Use of inorganic or non-macromolecular organic substances as compounding ingredients
C08K5/357 - Six-membered rings

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L21/00 - Compositions of unspecified rubbers
C08L63/00 - Compositions of epoxy resins
C08L75/04 - Polyurethanes
C08L75/08 - from polyethers
C08L79/04 - Polycondensates having nitrogen-containing heterocyclic rings in the main chain

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/1397 - Single layer [continuous layer]

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DOE Contract Number:: FG36-07GO17012

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Jan 27

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Tietze, Roger, and Nguyen, Yen-Loan. Halogen free benzoxazine based curable compositions for high T.sub.g applications.  United States: N. p., 2016. 
        Web.

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                    Tietze, Roger, & Nguyen, Yen-Loan. Halogen free benzoxazine based curable compositions for high T.sub.g applications.  United States.

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                    Tietze, Roger, and Nguyen, Yen-Loan. Tue .  
        "Halogen free benzoxazine based curable compositions for high T.sub.g applications".  United States.  https://www.osti.gov/servlets/purl/1298003.

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@article{osti_1298003,

  title        = {Halogen free benzoxazine based curable compositions for high T.sub.g applications},

  author       = {Tietze, Roger and Nguyen, Yen-Loan},

  abstractNote = {A method for forming a halogen-free curable composition containing a benzoxazine monomer, at least one epoxy resin, a catalyst, a toughening agent and a solvent. The halogen-free curable composition is especially suited for use in automobile and aerospace applications since the composition, upon curing, produces a composite having a high glass transition temperature.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Aug 16 00:00:00 EDT 2016},

  month        = {Tue Aug 16 00:00:00 EDT 2016}

}

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Works referenced in this record:

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition"
patent, June 1991

Schreiber, Herbert; Saur, Wolfgang
US Patent Document 5,021,484
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5021484

Composite densification with benzoxazines
patent, October 1992

Ishida, Hatsuo
US Patent Document 5,152,939
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5152939

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition"
patent, April 1993

Schreiber, Herbert
US Patent Document 5,200,452
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5200452

Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin
patent, January 1994

Mulhaupt, Rolf; Powell, Jeremy H.; Adderley, Christopher S.
US Patent Document 5,278,257
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5278257

Methods and compositions related to stereolithography
patent, June 1997

Crivello, James V.
US Patent Document 5,639,413
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5639413

Ternary systems of benzoxazine, epoxy, and phenolic resins
patent, March 2001

Ishida, Hatsuo; Rimdusit, Sarawut
US Patent Document 6,207,786
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6207786

Epoxy resin composition to seal semiconductors and resin-sealed semiconductor device
patent, April 2001

Tanaka, Masayuki; Tsurumi, Yumiko
US Patent Document 6,214,904
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6214904

Curable compositions containing benzoxazine
patent, September 2003

Musa, Osama M.
US Patent Document 6,620,905
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6620905

Flame-proofing agents
patent, May 2006

Magendie, Franck; Weidmann, Ulrich
US Patent Document 7,053,138
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7053138

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The present invention provides a halogen-free curable composition including a benzoxazine monomer, at least one epoxy resin, a catalyst, a toughening agent and a solvent. The halogen-free curable composition is especially suited for use in automobile and aerospace applications since the composition, upon curing, produces a composite having a high glass transition temperature.
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Similar Records

Title: Halogen free benzoxazine based curable compositions for high T.sub.g applications

Abstract

Citation Formats

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition" patent, June 1991

Composite densification with benzoxazines patent, October 1992

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition" patent, April 1993

Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin patent, January 1994

Methods and compositions related to stereolithography patent, June 1997

Ternary systems of benzoxazine, epoxy, and phenolic resins patent, March 2001

Epoxy resin composition to seal semiconductors and resin-sealed semiconductor device patent, April 2001

Curable compositions containing benzoxazine patent, September 2003

Flame-proofing agents patent, May 2006

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition"
patent, June 1991

Composite densification with benzoxazines
patent, October 1992

"Fire retardant curable 1-oxa-3-aza tetraline (also termed ""3,4-dihydro-1,3-benzoxazine"") derived resin composition"
patent, April 1993

Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin
patent, January 1994

Methods and compositions related to stereolithography
patent, June 1997

Ternary systems of benzoxazine, epoxy, and phenolic resins
patent, March 2001

Epoxy resin composition to seal semiconductors and resin-sealed semiconductor device
patent, April 2001

Curable compositions containing benzoxazine
patent, September 2003

Flame-proofing agents
patent, May 2006