Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations
Abstract
A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1226816
- Patent Number(s):
- 9194920
- Application Number:
- 13/648,751
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2012 Oct 10
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations. United States: N. p., 2015.
Web.
Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., & Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations. United States.
Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Tue .
"Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations". United States. https://www.osti.gov/servlets/purl/1226816.
@article{osti_1226816,
title = {Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations},
author = {Hu, Jian Zhi and Sears, Jr., Jesse A. and Hoyt, David W. and Mehta, Hardeep S. and Peden, Charles H. F.},
abstractNote = {A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 24 00:00:00 EST 2015},
month = {Tue Nov 24 00:00:00 EST 2015}
}
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