Convergent synthesis of multiporphyrin light-harvesting rods
Abstract
The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A.sup.1 (A.sup.b+1).sub.b, wherein b is at least 1, A.sup.1 through A.sup.b+1 are covalently coupled rod segments, and each rod segment A.sup.1 through A.sup.1+b comprises a compound of the formula X.sup.1 (X.sup.m+1).sub.m wherein m is at least 1 and X.sup.1 through X.sup.m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.
- Inventors:
- Issue Date:
- Research Org.:
- North Carolina State University, Raleigh, NC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1174435
- Patent Number(s):
- 6603070
- Application Number:
- 09/939,010
- Assignee:
- North Carolina State University (Raleigh, NC)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
- DOE Contract Number:
- FG02-96ER14632
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lindsey, Jonathan S., and Loewe, Robert S. Convergent synthesis of multiporphyrin light-harvesting rods. United States: N. p., 2003.
Web.
Lindsey, Jonathan S., & Loewe, Robert S. Convergent synthesis of multiporphyrin light-harvesting rods. United States.
Lindsey, Jonathan S., and Loewe, Robert S. Tue .
"Convergent synthesis of multiporphyrin light-harvesting rods". United States. https://www.osti.gov/servlets/purl/1174435.
@article{osti_1174435,
title = {Convergent synthesis of multiporphyrin light-harvesting rods},
author = {Lindsey, Jonathan S. and Loewe, Robert S.},
abstractNote = {The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A.sup.1 (A.sup.b+1).sub.b, wherein b is at least 1, A.sup.1 through A.sup.b+1 are covalently coupled rod segments, and each rod segment A.sup.1 through A.sup.1+b comprises a compound of the formula X.sup.1 (X.sup.m+1).sub.m wherein m is at least 1 and X.sup.1 through X.sup.m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 05 00:00:00 EDT 2003},
month = {Tue Aug 05 00:00:00 EDT 2003}
}
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